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EDT
June 2021
Confidential to EDT
Discussion
Topic Background
• Enzyme, technology overview
• Pulp hornification and its mechanisms
• How bad is it?
pRefinase Enzyme Technology
• Mechanisms to mitigate issue
• Benefits for pulp end user
• Benefits for pulp production
Conclusions
• Summary thoughts
Technology Background
• Resulted from 25 years studying enzymatic fiber
modification, its mechanisms, and the issues it might
address
• Early work in mills using never-dried pulp and
comparing results to use of repulped (dried) market
pulp showed dramatic differences
• The discoveries stemmed from investigation of dozens
of different enzymes across a myriad of tree species;
enzyme specificity and tailored blends matter
significantly when using enzymes
• Led to patented and patent-pending technology across
major pulp producing countries which is being
commercialized today
• Not alive, but produced by living organisms
• Biological catalysts
• Unique activities
• Produced by fermentation
• Safe to handle and use
• Growing range of pH applications
What are Enzymes?
5
• We eat enzymes – contained in most liquid food items purchased in stores (cheese, yogurt, juices, wine, beer)
• We wear enzymes (detergents)
• We are filled with enzymes (billions in our bodies)
• Every mill is filled with enzymes…at all times
• Enzymes safely applied in P&P industry for over 100 years
Enzymes are Safe
ILLUSTRATIVE
Temperature & pH Enzymatic Specificity – examples
ProductComposition
Goals fromtreatment:- Better tons- More tons- Cheaper tons- Sustainability
Mill / machine equipment and water loops
Specific recycled orvirgin fiber composition
and morphology
Key application conditions(e.g., temperature, pH,
retention time / kinetics)
Tailored Product Development Inputs
Peeke: Potential of papermaking fibers
The swollen and fibrillated never-dried fiber collapses upon drying,
never to be as large and fibrillated again; this is the hornification that
leads to great strength loss.
http://www.slideshare.net/Peeke/potential-of-papermaking-fibers
Fiber
cross-section
Fiber
surface
• Shrunken fibers with less
surface area & less fibrils
• Reduced reactivity for poor
chemical retention
• Reduced physical strength
• As one can see from the graph above, the effect of hornification greatly reduces final
pulp qualities vs. “never-dried” qualities. Until now, this has been a necessary evil of
pulp drying.
• We find similar patterns
across most physical
properties. It is an objective
of this technology is to
change the way these curves
look.
Dewatering Pressing Drying
• It is only until the drying starts (solids >50%) that the properties of the pulp start to
decrease, and these are not recovered after rewetting.
Air Dried ECF
Dried Pulp
Never-dried Pulp
Topic Background
• Enzyme, technology overview
• Pulp hornification and its mechanisms
• How bad is it?
pRefinase Enzyme Technology
• Mechanisms to mitigate issue
• Benefits for pulp end user
• Benefits for pulp production
Conclusions
• Summary thoughts
Improved drainage and drying
Fewer breaks, due to increased wet web strength
Increased strength
Improved refinability for customer
Improved water retention values
Energy reduction (drying)
Less downtime due to breaks
Avoided use of more expensive fibers for needed wet web strength
Avoided alternate drainage aids
Avoided acidification chemistry for drainage
More/
Better
Tons
pRefinase®
Benefits
Reduced
Cost
EDT pRefinase Patents (US & Canada)
• As one can see from the graph above, the effect of hornification greatly reduces final
pulp qualities vs. “never-dried” qualities. Until now, this has been a necessary evil of
pulp drying.
• As one can see from the graph above, the effect of hornification greatly reduces final
pulp qualities vs. “never-dried” qualities. Until now, this has been a necessary evil of
pulp drying.
• Significant increases were shown in Tensile Index, with the pRefinase-treated and dried
pulp reaching almost the same Tensile Index as the never-dried, untreated pulp.
Topic Background
• Enzyme, technology overview
• Pulp hornification and its mechanisms
• How bad is it?
pRefinase Enzyme Technology
• Mechanisms to mitigate issue
• Benefits for pulp end user
• Benefits for pulp production
Conclusions
• Summary thoughts
• The effect of hornification greatly reduces final pulp qualities vs. “never-dried” qualities.
Until now, this has been a necessary evil of pulp drying.
• Significant increases were shown in tensile strength, with the enzyme-treated and dried
pulp with the tensile strength closer to that for the never-dried, untreated pulp
• Improvements to Elongation with pRefinase were strong that the Elongation of the
dried pulp actually close to that of the never dried pulp without pRefinase.
• Reduced pulp WRV is another effect of pulp drying. Increased pulp WRV is a good
indication of better water absorption and better fiber reactivity to papermaking
additives.
• Treated pulp requires less energy to reach a desired SR and strength level.
41% LESS ENERGY!
Never-dried
• Tensile from the pre-treated pulp is continuously higher
• Less refining required with improved drainage to achieve similar desired tensile
strength values.
Never-dried
Topic Background
• Enzyme, technology overview
• Pulp hornification and its mechanisms
• How bad is it?
pRefinase Enzyme Technology
• Mechanisms to mitigate issue
• Benefits for pulp end user
• Benefits for pulp production
Conclusions
• Summary thoughts
Benefits to Market Pulp Production
• Improved drainage of the pre-treated, never-dried pulp forms,
drains, presses and dries more quickly
• Faster drainage/drying profile also elevates the web
consistency for any process point, thereby providing greater
wet web strength and reduced chances of dryer breaks
• Economic value to pulp production process can be
considerable
− Pulp production – greater TPH throughput and fewer breaks leads to
more total output
− More on-spec production – instances of too-wet final pulp bales can be
reduced
− Production cost – savings from reduced drying energy/ton and avoided
pre-dryer drainage additives to support throughput (e.g., chemicals and
also stronger fibre inclusion to minimize breaks)
• The equal drainage at a higher production rate translated to a 4% reduction
in the steam consumption, creating more tons for the mill and at a lower
production cost
• For a given production rate, total steam consumption was at the lowest points
of the pre-trial data
Topic Background
• Enzyme, technology overview
• Pulp hornification and its mechanisms
• How bad is it?
pRefinase Enzyme Technology
• Mechanisms to mitigate issue
• Benefits for pulp end user
• Benefits for pulp production
Conclusions
• Summary thoughts
Conclusions
• Hornification of virgin pulps upon drying is a significant
issue, creating significantly weaker versions of the
never-dried fibers
• Enzymatic treatment prior to drying provides notable
benefits to both the pulp production process and
eventual pulp end users
− Pulp production – improved drainage, drying and less process
breaks
− Pulp end users – notably better strength values obtained when
using pre-treated market pulp
• Continued work across a broad mix of tree species and
market pulp end uses is ongoing as part of the activities
in this area and may be reported in future updates.