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Polymer Modifier Solutions Guide
Delivering Innovation Worldwide
A New Business A New Energy A New Direction
Chemtura is a global specialty chemicals company with leadingpositions in diversified markets. We build the chemistry that makesother products more durable, safer, cleaner and more efficient, inthe building and construction, electrical and electronics, consumer,agricultural, industrial and transportation industries.
With more than 4,400 employees around the world, Chemturaprovides products and services in more than 100 countries andmaintains worldwide manufacturing and research facilities aswell as global sales offices.
Global Solutions
Our Vision- To be the world’s most innovative supplier of solutions to the polymer industry- To be our customers’ first choice as a committed supplier- To offer the best cost-performance solutions through real innovation- To invest in line with our customers’ growth strategies- To offer the best service locally through integrated plants and supply chains
We are a leading supplier of coupling agents, compatibilizers andimpact modifiers which improve the physical characteristics of manythermoplastic polymers including rigidity, strength and durability tomeet the most demanding customer and consumer requirements.
Our products are used to enhance most major thermoplasticmaterials: Acrylonitrile Butadiene Styrene (ABS), Styrene BlockCopolymers (SBC, SEBS, SIS), Styrene Acrylonitrile (SAN),Thermoplastic Urethane (TPU), Polycarbonate (PC), Polyesters (PBT,PET), Polymethyl Methacrylate (PMMA), Polyamides (PA),Polypropylene (PP), Polyethylene (PE) and Polyphenylene Ether(PPE) and we are committed to offering the broadest and bestrange of products in the industry.
Our ProductsAs one of the world’s top providers ofpolymer modifiers, our Polybond® productsimprove mechanical properties of glass andmineral filled polyolefins,polypropylene/clay nanocomposites,wood/plastic composites and improvedispersion in polyolefin masterbatches andflame retardant compounds. Theseproducts are also used to improvepolyolefin/metal adhesion, polyolefin/inkadhesion and in coextrusion tie layers.Royaltuf® impact modifiers are widely usedto toughen polyamides and provide afavorable balance of properties, includingexcellent room temperature and lowtemperature impact.
03Polymer Modifiers Solution Guide
With over 100 technologists in the Antioxidants and UV Stabilizer Solutionsbusiness alone, we have more than 4,000 active patents and will continue tostrongly invest in innovation to maintain our position at the forefront of newproduct development and offer the possibility to:
- Improve the cost / performance of our customers’ products
- Offer better performing replacements for competitive products
- Expand into new applications or new markets
Expertise that adds valueOur broad product range, combined with our technical expertise, allows us tooffer multiple solutions to best meet the needs of the customer application. Most of our product solutions are kept in stock and can be shipped within 24hours in order to support the most demanding development projects. With ourgrowing technology team, we stand ready to fully support your developmentprojects, over the phone or in person.
Delivering True Innovation
04 | Polymer Modifiers Solution Guide
Polymer Modifiers Solution Guide | 05
We appreciate that our success also relies on being an easy company to workwith. This is why we have established multiple production sites, sales andtechnical offices and laboratories around the world, to bring us close to ourcustomers in all the regions, offering better service and shorter lead times. As our customers invest heavily in the new, emerging markets, we have beenfocusing especially on our structure in those regions to guarantee service levels.
Our new technical application centre in China is thelatest example to add to our existing locations in theMiddle East, South Korea, USA, Brazil, Europe andTaiwan. We have also consolidated our CustomerCare and shipping points and ensured we field ahighly trained sales and distribution team.
Service Worldwide
Manufacturing Centers
Emerging Regions
Technical Centers
Regional Headquarters
Sales & Customer Care Offices
Technical supportOur global network of technical experts are not only specialists in polymerapplications, they are also specialized in using 6 Sigma and Lean Technology tohelp customers solve production or processing problems, and will traincustomers to use these tools for the future.
Committed to future growthChemtura is committed to growing its Antioxidantand UV Stabilizer Solutions business. We continuethe expansion of our manufacturing plants, mostrecently investing in expansions in the Middle East,South Korea and France with future expansionsplanned for our polymer modifiers.
Our continued investment in innovation isparamount with an exciting channel of new andinnovative technology currently underdevelopment. We have consolidated our NorthAmerican R&D facilities at our Morgantown, WVmanufacturing site to create our PolymerModifier R&D Center of Excellence, whichincludes state of the art development andanalytical testing equipment.
Regulatory compliance and corporate responsibilityChemtura is committed to the concept of Sustainable Development – to minimizethe imprint that our operations and businesses leave on our collective health andsafety and on the environment.
Investment in regulatory compliance and advocacy, including REACH*, is apriority. We commit resources to support this, maintaining a strong regulatoryteam and actively participating in industry advocacy groups. In short, we careabout the future…for all of us.
*Registration Evaluation Authorization of Chemicals
06 | Polymer Modifiers Solution Guide
Polymer ModifiersSelection Guide
Acrylic Acid GraftedPolypropylenePolybond® 1001N
Polybond® 1002
Polybond® 1103
High Density PolyethylenePolybond® 1009
Maleic Anhydride GraftedPolypropylenePolybond® 3000
Polybond® 3002
Polybond® 3150
Polybond® 3200
High Density PolyethylenePolybond® 3009
Polybond® 3029
Polybond® 3039
Polybond® 3049
Linear Low Density PolyethylenePolybond® 3149
EPDMRoyaltuf® 485
Royaltuf® 498
SAN GraftedEPDMRoyaltuf® ESG 115B R-2
Royaltuf® 372P20
ABS
Gla
ss/M
iner
alFi
lled
PE
Gla
ss/M
iner
alFi
lled
PP
Ole
fin/P
A B
lend
s
PC PBT
Poly
amid
es
SAN
Woo
d/N
atur
alFi
ber F
illed
PE
Woo
d/N
atur
alFi
ber F
illed
PP
Ink
Adhe
sion
Met
al a
dhes
ion
Mas
terb
atch
Dis
pers
ion
Aid
Non
-Hal
ogen
FR
Enha
ncem
ent
• •• •• •• •
• • • • • • •• • • • • • •• • • • • • •• • • • • • •
• • • • • • •• • • • • • •• • • • • • •• • • • • • •• • • • • • •
••
• • • •• • • •
Polymer Modifiers Solution Guide | 07
Polybond® Typical Properties
Polybond® 1001N PP AA High - 40 Pellet
Polybond® 1002 PP AA High - 20 Pellet
Polybond® 1009 HDPE AA High 5 - Pellet
Polybond® 1103 PP AA High - 400 Pellet
Polybond® 3000 PP MA High 400 1020 Pellet
Polybond® 3002 PP MA Low - 10 Pellet
Polybond® 3009 HDPE MA Low 5 - Pellet
Polybond® 3029 HDPE MA Medium 4 - Micro-Pellet
Polybond® 3039 HDPE MA High 4 - Pellet
Polybond® 3049 HDPE MA High 2 - Pellet
Polybond® 3150 PP MA Medium 53 - Pellet
Polybond® 3200 PP MA High 115 - Pellet
Polybond® 3149 LLDPE MA High 12-30 - Pellet
Base
Res
in
Func
tiona
lity
Func
tiona
l Lev
elFT
IR
MFR
@ 1
90°C
,2.
16kg
g/1
0 m
in
MFR
@ 2
30°C
,2.
16kg
g/1
0 m
in
Phys
ical
For
m
Royaltuf® Typical Properties
Royaltuf® 485 Semi-Crystaline EPDM MA Medium 30 - Pellet
Royaltuf® 498 Amorphous EPDM MA High 30 - Pellet
Royaltuf® ESG 115B R-2 Semi-Crystaline EPDM SAN Medium - - Crumb
Royaltuf® 372P20 Semi-Crystaline EPDM SAN Medium - 20 Pellet
Base
Res
in
Func
tiona
lity
Func
tiona
l Lev
elFT
IR
Moo
ney
Visc
osity
ML(
1+4)
@ 1
25 o
C
MFR
@ 2
65°C
,21
.6kg
g/1
0 m
in
Phys
ical
For
m
ESG 115B R-2 and 372P20differ only in morphology.Continuous phase of ESG115B R-2 is EPDM whilethat of 372P20 is SAN.
08 | Polymer Modifiers Solution Guide
Polymer ModifiersFeatures & BenefitsPolybond® 1001NFEATURESPolypropylene grafted with acrylic acidMedium melt flowHigh level of functionalityBENEFITSIdeal for improving adhesion to metal
Polybond® 1002FEATURESPolypropylene grafted with acrylic acidLow melt flowHigh level of functionalityBENEFITSIdeal for improving adhesion to metal
Polybond® 1103FEATURESPolypropylene grafted with acrylic acidHigh melt flowHigh level of functionalityBENEFITSLower viscosity for formulations where high melt flow isdesirableIdeal for improving adhesion to metal
Polybond® 1009FEATURESHDPE grafted with acrylic acidModerate melt flowHigh level of functionalityBENEFITSIdeal for improving adhesion to metal
Polybond® 3000FEATURESPP grafted with maleic anhydrideHighest level of functionality availableHighest melt flow availableBENEFITSIdeally suited for long glass fiber applicationsHigh efficiency in glass filled PPWell suited for tie-layer compounds
Polybond® 3002FEATURESPP grafted with maleic anhydrideLow melt flowBENEFITSWell suited for tie-layer compounds
Polybond® 3150FEATURESPP grafted with maleic anhydrideHigher melt flow compared to PB3002Increasing level of functionality compared to PB3002BENEFITSWell suited for tie-layer compoundsIdeal compatibilizer for PP/Nylon blends where improvedhydrolytic stability is desired
Polybond® 3200FEATURESPP grafted with maleic anhydrideHigh melt flowHigh level of functionalityBENEFITSHigh efficiency in glass filled PPHigh efficiency compatibilizer for nylon/PP blendsRecommended for clay PP-Nanocomposites and wood plasticcompositesAlso effective in agricultural fiber and starch formulationsWell suited for tie-layer compounds
Polymer Modifiers Solution Guide | 09
Polybond® 3009FEATURESHDPE grafted with maleic anhydrideLow melt flowMedium level of functionalityLow gel countsBENEFITSIdeal for sheet & film applications
Polybond® 3029FEATURESHDPE grafted with maleic anhydrideLow melt flowHigh level of functionalityBENEFITSIdeal for wood plastic composite or other highly filledapplications
Polybond® 3039FEATURESHDPE grafted with maleic anhydrideLow melt flowHigh level of functionalityNon-dusting micro-pellet formBENEFITSEasy, uniform distribution Ideal for wood plastic composite or other highly filledapplications
Polybond® 3049FEATURESHDPE grafted with maleic anhydrideLow melt flowHighest level of functionalityBENEFITSIdeal for wood plastic composite or other highly filledapplicationsAlso effective in agricultural fiber and starch formulations
Polybond® 3149FEATURESLLDPE grafted with maleic anhydrideModerate melt flowHigh level of functionalityBENEFITSWell suited for wood plastic composites and other highly filledcompounds
Royaltuf® 485FEATURESSemi-Crystaline EPDM grafted with maleic anhydrideMedium level of functionalityFree flowing pelletBENEFITSEffective impact modifier for a wide variety of polyamides5-7% loading for glass filled polyamides20% loading for super-tough polyamides
Royaltuf® 498FEATURESAmorphous EPDM grafted with maleic anhydrideHigh level of functionalityFree flowing pellet dusted to facilitate storage and feedingBENEFITSEffective impact modifier for a wide variety of polyamides5-7% loading for glass filled polyamides20% loading for super-tough polyamidesProvides highest level of impact properties at sub-ambienttemperatures
Royaltuf® ESG 115B R-2FEATURES50% EPDM Rubber grafted with styrene-acrylonitrile (AES)EPDM Rubber in the continuous phaseCrum formBENEFITSProvides excellent impact properties at ambient and sub-ambient temperaturesMaintains polymer properties in UV and thermal environmentsProvides exceptional weather resistant propertiesCompatible with many polar polymers
Royaltuf® 372P20FEATURES50% EPDM Rubber grafted with styrene-acrylonitrile (AES)SAN in the continuous phasePellet formBENEFITSProvides excellent impact properties at ambient and sub-ambient temperaturesMaintains polymer properties in UV and thermal environmentsProvides exceptional weather resistant propertiesCompatible with many polar polymers
10 | Polymer Modifiers Solution Guide
Mod
ifier
Type
CAS
Regi
stry
No.
FDA
Reg
ulat
ion
(21
CFR)
*
PP/AA
PP/AA
HDPE/AA
PP/AA
PP/MA
PP/MA
HDPE/MA
HDPE/MA
HDPE/MA
HDPE/MA
HDPE/MA
PP/MA
PP/MA
EPDM/MA
EPDM/MA
EPDM/SAN
EPDM/SAN
Polybond® 1001N
Polybond® 1002
Polybond® 1009
Polybond® 1103
Polybond® 3000
Polybond® 3002
Polybond® 3009
Polybond® 3029
Polybond® 3039
Polybond® 3049
Polybond® 3149
Polybond® 3150
Polybond® 3200
Royaltuf® 485
Royaltuf® 498
Royaltuf® ESG 115B R-2
Royaltuf® 372P20
25214-24-8
25214-24-8
9010-77-9
9003-07-0
9003-07-0
9002-88-4
9003-07-0
9003-07-0
25038-36-2
25038-36-2
32069-92-4
175.105, 176.180
175.105, 176.180
175.105, 176.180
175.105, 176.180,177.1210,
175.380, 175.390,177.1390
175.105, 176.180,177.1210,
175.300, 175.380,175.390, 177.1390
175.105, 176.180,177.1210,177.1520
175.105, 176.180,177.1210,
175.300, 175.380,175.390,177.1390
175.105, 176.180,177.1210,
175.380, 175.390,177.1390
a
a
a
a
bc
a
bc
a
d
a
b
c
a
bc
Complies
Complies
Complies
Complies
Complies
Complies
Complies
Complies
Lim
itatio
ns
Dire
ctiv
e20
02/7
2/EC
(Eur
ope)
*
Regulatory Summary
It is recommended to verifythe current status bycontacting the ProductSafety and RegulatoryAffairs Department ofChemtura Corporation at866.430.2775. Please referto MSDS for productinventory status
Limitationsa Amount required to
achieve the desired effectb Not to exceed amount
required to achieve thedesired effect
c May not contact foodd To contain no more than
2% by weight ofcopolymer units derivedfrom maleic anhydrides
* Chemtura Corporation has no control over final product composition, processing conditions, or the final applications. It is, therefore, the responsibility of the manufacturer of the end use article to check compliance with any relevant regulation.
Why Chemtura?Because we offer:
- True innovation and partnership in development- The largest range of Polymer Modifier solutions in the industry- Global reach and supply capabilities- Unbeatable technical expertise and application knowledge- Continued strategic investments in emerging markets- Significant investments in regulatory compliance
Because we are committed:
- To be the world’s most innovative supplier of solutions to the polymer industry
- To be our customers’ first choice as a committed supplier- To offer the best cost-performance solutions through
real innovation- To invest in line with our customers’ growth strategies - To offer the best service locally through integrated plants and
supply chains
Polymer Modifiers Solution Guide | 11
Call us now
The information contained herein is correct to the best of our knowledge. Your attention is directed to the pertinent MaterialSafety Data Sheets for the products mentioned herein.
All sales are subject to Chemtura’s standard terms and conditions of sale, copies of which are available upon request andwhich are part of Chemtura’s invoices and/or order acknowledgements. Except as expressly provided in Chemtura’s standardterms and conditions of sale, no warranty, express or implied, including warranty of merchantability or fitness for a particularpurpose, is made with respect to the product described herein. Nothing contained herein shall constitute permission orrecommendation to practice any invention covered by a patent without license from the owner of the patent.
© Copyright 2010
The tradenames in this brochure are registered trademarks of Chemtura Corporation and/or its subsidiaries.
Antioxidant and UV Stabilizer Solutions Contact Information
Chemtura CorporationWorld Headquarters1818 Market Street, Suite 3700Philadelphia, PA 19103
International Sales Offices
AmericasCustomer Care, U.S.tel. 1-765-497-6100/800-428-7947fax. 1-765-463-2188
Technical Servicetel. 1-304-284-2256fax. 1-304-284-2296email. [email protected]
Braziltel. 55-11-3896-1500fax. 55-11-3896-1502
Mexicotel. 52-55-5010-6601fax. 52-55-5872-7370
Europe, Middle East & AfricaUnited KingdomChemtura Sales UK LtdTenax Road, Trafford Park,Manchester, M17 1WT, UK
Customer Care Europetel. 44-161-875-3800fax. 44-161-875-3290
Technical Service Europetel. 39-335-624-2046fax. 39-0773-615-334email. [email protected]
Russiatel. 7495-580-7775fax. 7495-933-5960
Visit us on the web atwww.chemtura.com
Asia/PacificChemtura Shanghai Co. Ltd.Shanghai Representative OfficeRoom 1703-1705, China Fortune TowerNo. 1568 Century Avenue, Pudong DistrictShanghai, 200122P. R. Chinatel. 86-21-3866-6688fax. 86-21-6876-0700
Customer Care, Asia Pacifictel. 86-21-3866-6511fax. 86-21-6876-0772
Technical Service, Asia Pacifictel. 86-21-38-66-65-39fax. 86-21-68-76-07-73email. [email protected]
Japantel. 81-3-5510-7000fax. 81-3-5510-7004
Koreatel. 82-2-541-1300fax. 82-2-541-3950
Singaporetel. 65-6770-5110fax. 65-6774-2443
Taiwantel. 886-2-2713-1790fax. 886-2-2712-5668
Responsible Care®Chemtura is dedicated to Responsible Care®, the chemical industry's initiative to protect the environment; ensure the safety andsecurity of our operations; and safeguard the health and safety of our employees and neighboring communities. Our goal is to makecontinuous progress toward the vision of no accidents, injuries or harm to the environment. As active and responsible membersof the communities in which we operate, Chemtura is committed to open communication with our employees and neighbors.We monitor the safe production, transportation and use of our products. Our employees are comprehensively trained to do theirjobs safely and with minimum impact on the environment. We care about the future — for all of us. If you have any questions, orwould like to comment on our Responsible Care program, please send an email to [email protected].