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www.brenntag.de
POLYMERSDACH
Tribologically optimizedCompounds
2
3
TRIBOFORCE® .................................................................................................................... 5
Physical, mechanical and tribological properties ........................................................... 6
Continuous service temperatures and chemical resistance ............................................ 7
Diagrams TRIBOFORCE® PA66 UNGEFÄRBT
Tensile test C0200, C0203 ....................................................................................................8Specific wear rate ws / Coefficient of friction µ .................................................................9Tensile modulus / Tensile strength ...................................................................................10Elongation at break / Charpy impact strength unnotched ..............................................11Linear wear rate w C0200, C0201 ......................................................................................12Linear wear rate w C0202, C0203 ......................................................................................13Coefficient of friction µ C0200, C0201 ..............................................................................14Coefficient of friction µ C0202, C0203 ..............................................................................15
Contents
4
TRIBOFORCE®
Tribologically optimized compounds
TRIBOFORCE® is our product series of tribologically op-timized compounds. With a complex combination of different additives, these materials define a new class in wear behaviour. Exceptional wear resistance and low coefficients of friction, coupled with excellent dimen-sional stability, make TRIBOFORCE® the ideal material for bearings to withstand extreme requirements.
A broad polymer and temperature spectrum
Users can choose between TRIBOFORCE® materials with different base polymers, covering a temperature range of - 40 °C to 260 °C, and short-term service temperatures of up to 300 °C are even possible as well.
Excellent sliding and bearing materials
TRIBOFORCE® materials are the preferred materials for toothed wheels, slidings and bearings, and in almost all cases, it is possible to get by without lubrication. By substituting our new additive combinations for conventional lubricants such as PTFE, we are also able to produce TRIBOFORCE® materials with a high mechanical strength.
Practical tribological tests
In addition, users can have wear measurements carried out on tribological test rigs. Virtually all the operating conditions speci-fied by the customer can be simulated on the test rig, permitting the friction and wear behaviour to be established in this way. Elaborate test series can then be dispensed with.
Application Options
The product series is used, e.g., for components in the automotive industry, machine and plant construction, materials handling technology, industry, sports and leisure, etc., as
toothed wheelsbearing bushesplanetary gearball bearings and bearing cagesslide rails and coatingsrollscouplingsdeflection wheelsthrust washersimpellersjointsgasketsvalvesfuel distributors
TRIBOFORCE® Features
Ideal toothed wheel, sliding and bearing materials for high demands
Exceptional wear resistanceLow coefficients of frictionExcellent dimensional stabilityOutstanding tribological behavior
compared to metalsWide range of temperaturesFree choice of polymer-additive combinationsTypes available for injection moulding and
extrusion
Physical, mechanical and tribological properties
TRIBOFORCE® PA66 C0200 PA66 C0201 PA66 C0202 PA66 C0203
Density ISO 1183 g/cm³ 1.51 1.25 1.37 1.41
Tensile strength ISO 527 MPa 160 160 160 200
Tensile strength conditioned ISO 527 | ISO 1110 MPa 120 115 115 145
Elongation at break ISO 527 % 1.5 2.6 2.0 1.7
Elongation at break conditioned ISO 527 | ISO 1110 % 2.7 5.3 4.3 3.5
Tensile modulus ISO 527 MPa 16 000 11 000 14 500 21 500
Tensile modulus conditioned ISO 527 | ISO 1110 MPa 10 000 7 400 8 700 13 000
Charpy impact strength unnotched ISO 179/1eU kJ/m² 20 40 30 40
Charpy impact strength unnotched cond. ISO 179/1eU | ISO 1110 kJ/m² 25 55 45 50
Charpy impact strength notched ISO 179/1eA kJ/m² 3 – – –
Specific wear rate ws at1 MPa, 1 m/s, dry/steel ASTM G 137 10-6 mm³/Nm 0.2 0.5 0.33 0.5
Coefficient of friction µ at1 MPa, 1 m/s, dry/steel ASTM G 137 1 0.2 0.3 0.28 0.26
Surface resistivity DIN IEC 60093 Ohm 104 - 105 105 - 106 104 - 105 < 103
Humidity absorption ISO 1110 % 1.6 2.2 2.0 1.9
Melting temperature ISO 3146 (10K/min) °C 260 260 260 260
Moulding shrinkage ISO 2941) % 0.1 - 0.4 0.1 - 0.4 0.1 - 0.4 0.1 - 0.4
TRIBOFORCE® PPS C1800 PPS C1801 PPS C1802 PEEK C23002) PEEK C23013)
Density ISO 1183 g/cm³ 1.61 1.5 1.48 1.59 1.57
Tensile strength ISO 527 MPa 115 125 140 145 165
Elongation at break ISO 527 % 1 1.2 0.8 2.2 1.9
Tensile modulus ISO 527 MPa 16 000 15 000 22 500 13 000 14 300
Charpy impact strength unnotched ISO 179/1eU kJ/m² 15 18 18 35 32
Charpy impact strength notched ISO 179/1eA kJ/m² 2 4 5 4 –
Specific wear rate ws at
1 MPa, 1 m/s, dry/steel18 MPa, 1 m/s, dry/steel6 MPa, 2 m/s, 75 °C, dry/steel
ASTM G 137 10-6 mm³/Nm 0.1––
0.10.20.2
0.10.20.2
0.1––
0.1––
Coefficient of friction µ at
1 MPa, 1 m/s, dry/steel18 MPa, 1 m/s, dry/steel6 MPa, 2 m/s, 75 °C, dry/steel
ASTM G 137 1 0.2––
0.20.1
0.05
0.30.150.05
0.2––
0.2––
Coefficient of Linear Thermal Expansion (CLTE)
longitudinaltransverse
ISO 1135923 °C - 55 °C α * 10-6/K
1145
––
––
––
––
Melting temperature ISO 3146 (10K/min) °C 275 275 275 340 340
Moulding shrinkage ISO 2941) % 0.05 - 0.2 0.15 - 0.3 0.15 - 0.3 0.05 - 0.2 0.05 - 0.2
Unless otherwise stated, the values refer to uncoloured materials, dam 23 °C.1) Internal test method in accordance with ISO 294 (test specimen 60 mm x 60 mm x 2 mm) | 2) For extrusion | 3) Injection moulding gradeData sheets and processing guidelines for our TRIBOFORCE® products can be found at www.brenntag.de.
Continuous service temperatures, chemical resistance
CONTINUOUS SERVICE TEMPERATURES TRIBOFORCE® PA66 PPS PEEK
To 130 °C
130 °C to 200 °C
200 °C to 260 °C
To 300 °C, temporary
CHEMICAL RESISTANCE
Aqueous
Biological media
Salt spray (fog)
Hydrolysis resistant
Suitable for superheated steam sterilization to 200 °C
Oil
Petrol
Weak mineral acids
Diluted alkaline solutions
Concentrated alkaline solutions
Nitric acid and other oxidising acids
Strain [%]
Stre
ss [
MPa
]
120
240
0.0 2.01.0 3.0 4.0 5.0 6.0
100
80
60
40
20
0
140
160
180
220
200
Tensile test TRIBOFORCE® PA66 C0200 UNGEFÄRBT (dry)
Stre
ss [
MPa
]
120
240
100
80
60
40
20
0
140
160
180
220
200
Tensile test TRIBOFORCE® PA66 C0203 UNGEFÄRBT (dry)
Strain [%]
0.0 2.01.0 3.0 4.0 5.0 6.0
Diagrams
23 °C 100 °C 160 °C
23 °C 120 °C
8
Temperature [°C]
0.00
0.30
Sliding speed 2 m/s
Surface pressure 6 MPa
Sliding speed 2 m/s
Surface pressure 6 MPa
0.05
0.10
0.15
0.25
0.20
Specific wear rate ws TRIBOFORCE® PA66 UNGEFÄRBT
Spec
ific
wea
r ra
te w
s [10
-6 m
m3 /
Nm
] Co
effici
ent
of
fric
tio
n µ
[-]
0.8
0.2
0.6
0.4
Coefficient of friction µ TRIBOFORCE® PA66 UNGEFÄRBT
Temperature [°C]
25
25
75
75
50
50
100
100
125
125
150
150
175
175
C0200
C0202
C0201
C0203
C0200
C0202
C0201
C0203 9
Tensile modulus TRIBOFORCE® PA66 UNGEFÄRBT (dry 23 °C)
Tensile strength TRIBOFORCE® PA66 UNGEFÄRBT (dry 23 °C)
Ten
sile
mo
du
lus
[MPa
]
10 000
25 000
5 000
0
15 000
20 000
Ten
sile
str
eng
th [
MPa
]
100.0
250.0
50.0
0.0
150.0
200.0
C0200
C0200
C0201
C0201
C0202
C0202
C0203
C0203
Diagrams
10
Elongation at break TRIBOFORCE® PA66 UNGEFÄRBT (dry 23 °C)
Charpy impact strength unnotched TRIBOFORCE® PA66 UNGEFÄRBT (dry 23 °C)
Elo
ng
atio
n a
t b
reak
[%
]
1.00
3.00
50.00
2.50
40.00
30.00
20.00
10.00
0.00
0.50
0.00
1.50
2.00
Char
py
imp
act
stre
ng
th u
nn
otc
hed
[kJ
/m²]
C0200
C0200
C0201
C0201
C0202
C0202
C0203
C0203
11
12
Linear wear rate w TRIBOFORCE® PA66 C0200 UNGEFÄRBT
Linear wear rate w TRIBOFORCE® PA66 C0201 UNGEFÄRBT
Lin
ear
wea
r ra
te w
[µ
m/h
]Li
nea
r w
ear
rate
w [
µm
/h]
Diagrams
50
40
30
20
10
02.5
5.0
7.5
10.01.0
1.5
2.0
2.5
3.0
Surface pressure p [MPa] Sliding speed v [m/s]
50
40
30
20
10
02.5
5.0
7.5
10.01.0
1.5
2.0
2.5
3.0
Surface pressure p [MPa] Sliding speed v [m/s]
50
40
30
20
10
0
50
40
30
20
10
0
13
Linear wear rate w TRIBOFORCE® PA66 C0202 UNGEFÄRBT
Linear wear rate w TRIBOFORCE® PA66 C0203 UNGEFÄRBT
Lin
ear
wea
r ra
te w
[µ
m/h
]Li
nea
r w
ear
rate
w [
µm
/h]
50
40
30
20
10
02.5
5.0
7.5
10.01.0
1.5
2.0
2.5
3.0
Surface pressure p [MPa] Sliding speed v [m/s]
50
40
30
20
10
02.5
5.0
7.5
10.01.0
1.5
2.0
2.5
3.0
Surface pressure p [MPa] Sliding speed v [m/s]
50
40
30
20
10
0
50
40
30
20
10
0
14
Coeffi
cien
t o
f fr
icti
on
µ [
-]
Coefficient of friction µ TRIBOFORCE® PA66 C0200 UNGEFÄRBT
Coeffi
cien
t o
f fr
icti
on
µ [
-]
Coefficient of friction µ TRIBOFORCE® PA66 C0201 UNGEFÄRBT
Diagrams
0.35
0.30
0.25
0.15
0.10
0.00
0.05
0.20
Surface pressure p [MPa]
Sliding speed v [m/s]
2.5
0.35
0.30
0.25
0.20
0.15
0.10
0.05
5.0
7.5
10.0
3.02.5
2.01.5
1.0
Surface pressure p [MPa]
Sliding speed v [m/s]
2.5
0.35
0.30
0.25
0.20
0.15
0.10
0.05
5.0
7.5
10.0
3.02.5
2.01.5
1.0
0.35
0.30
0.25
0.15
0.10
0.00
0.05
0.20
15
Coeffi
cien
t o
f fr
icti
on
µ [
-]
Coefficient of friction µ TRIBOFORCE® PA66 C0202 UNGEFÄRBT
Coefficient of friction µ TRIBOFORCE® PA66 C0203 UNGEFÄRBT
0.35
0.30
0.25
0.15
0.10
0.00
0.05
0.20
Surface pressure p [MPa]
Sliding speed v [m/s]
2.5
0.35
0.30
0.25
0.20
0.15
0.10
0.05
5.0
7.5
10.0
3.02.5
2.01.5
1.0
Coeffi
cien
t o
f fr
icti
on
µ [
-]
Surface pressure p [MPa]
Sliding speed v [m/s]
2.5
0.35
0.30
0.25
0.20
0.15
0.10
0.05
5.0
7.5
10.0
3.02.5
2.01.5
1.0
0.35
0.30
0.25
0.15
0.10
0.00
0.05
0.20
www.brenntag.de
Business Manager Plastics
Frank DahlkeMobile: +49 173 [email protected]
Sales (Internal)
Stefanie Tarantini Tel.: +49 6371 [email protected]
Brenntag GmbHMaterial Science / PolymersLocation RamsteinCarl-Zeiss-Straße 2a - 466877 Ramstein-MiesenbachGermanyTel.: +49 6371 9635-0Fax: +49 6371 [email protected]
Contact
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