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www.brenntag.de POLYMERS DACH Tribologically optimized Compounds

POLYMERS DACH - Anmelden · POLYMERS DACH Tribologically optimized ... 1 MPa, 1 m/s, dry/steel ASTM G 137 10-6 mm³/Nm 0.2 0.5 0.33 0.5 Coefficient of friction µ at 1 MPa, 1 m/s,

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Page 1: POLYMERS DACH - Anmelden · POLYMERS DACH Tribologically optimized ... 1 MPa, 1 m/s, dry/steel ASTM G 137 10-6 mm³/Nm 0.2 0.5 0.33 0.5 Coefficient of friction µ at 1 MPa, 1 m/s,

www.brenntag.de

POLYMERSDACH

Tribologically optimizedCompounds

Page 2: POLYMERS DACH - Anmelden · POLYMERS DACH Tribologically optimized ... 1 MPa, 1 m/s, dry/steel ASTM G 137 10-6 mm³/Nm 0.2 0.5 0.33 0.5 Coefficient of friction µ at 1 MPa, 1 m/s,

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Page 3: POLYMERS DACH - Anmelden · POLYMERS DACH Tribologically optimized ... 1 MPa, 1 m/s, dry/steel ASTM G 137 10-6 mm³/Nm 0.2 0.5 0.33 0.5 Coefficient of friction µ at 1 MPa, 1 m/s,

3

TRIBOFORCE® .................................................................................................................... 5

Physical, mechanical and tribological properties ........................................................... 6

Continuous service temperatures and chemical resistance ............................................ 7

Diagrams TRIBOFORCE® PA66 UNGEFÄRBT

Tensile test C0200, C0203 ....................................................................................................8Specific wear rate ws / Coefficient of friction µ .................................................................9Tensile modulus / Tensile strength ...................................................................................10Elongation at break / Charpy impact strength unnotched ..............................................11Linear wear rate w C0200, C0201 ......................................................................................12Linear wear rate w C0202, C0203 ......................................................................................13Coefficient of friction µ C0200, C0201 ..............................................................................14Coefficient of friction µ C0202, C0203 ..............................................................................15

Contents

Page 4: POLYMERS DACH - Anmelden · POLYMERS DACH Tribologically optimized ... 1 MPa, 1 m/s, dry/steel ASTM G 137 10-6 mm³/Nm 0.2 0.5 0.33 0.5 Coefficient of friction µ at 1 MPa, 1 m/s,

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Page 5: POLYMERS DACH - Anmelden · POLYMERS DACH Tribologically optimized ... 1 MPa, 1 m/s, dry/steel ASTM G 137 10-6 mm³/Nm 0.2 0.5 0.33 0.5 Coefficient of friction µ at 1 MPa, 1 m/s,

TRIBOFORCE®

Tribologically optimized compounds

TRIBOFORCE® is our product series of tribologically op-timized compounds. With a complex combination of different additives, these materials define a new class in wear behaviour. Exceptional wear resistance and low coefficients of friction, coupled with excellent dimen-sional stability, make TRIBOFORCE® the ideal material for bearings to withstand extreme requirements.

A broad polymer and temperature spectrum

Users can choose between TRIBOFORCE® materials with different base polymers, covering a temperature range of - 40 °C to 260 °C, and short-term service temperatures of up to 300 °C are even possible as well.

Excellent sliding and bearing materials

TRIBOFORCE® materials are the preferred materials for toothed wheels, slidings and bearings, and in almost all cases, it is possible to get by without lubrication. By substituting our new additive combinations for conventional lubricants such as PTFE, we are also able to produce TRIBOFORCE® materials with a high mechanical strength.

Practical tribological tests

In addition, users can have wear measurements carried out on tribological test rigs. Virtually all the operating conditions speci-fied by the customer can be simulated on the test rig, permitting the friction and wear behaviour to be established in this way. Elaborate test series can then be dispensed with.

Application Options

The product series is used, e.g., for components in the automotive industry, machine and plant construction, materials handling technology, industry, sports and leisure, etc., as

toothed wheelsbearing bushesplanetary gearball bearings and bearing cagesslide rails and coatingsrollscouplingsdeflection wheelsthrust washersimpellersjointsgasketsvalvesfuel distributors

TRIBOFORCE® Features

Ideal toothed wheel, sliding and bearing materials for high demands

Exceptional wear resistanceLow coefficients of frictionExcellent dimensional stabilityOutstanding tribological behavior

compared to metalsWide range of temperaturesFree choice of polymer-additive combinationsTypes available for injection moulding and

extrusion

Page 6: POLYMERS DACH - Anmelden · POLYMERS DACH Tribologically optimized ... 1 MPa, 1 m/s, dry/steel ASTM G 137 10-6 mm³/Nm 0.2 0.5 0.33 0.5 Coefficient of friction µ at 1 MPa, 1 m/s,

Physical, mechanical and tribological properties

TRIBOFORCE® PA66 C0200 PA66 C0201 PA66 C0202 PA66 C0203

Density ISO 1183 g/cm³ 1.51 1.25 1.37 1.41

Tensile strength ISO 527 MPa 160 160 160 200

Tensile strength conditioned ISO 527 | ISO 1110 MPa 120 115 115 145

Elongation at break ISO 527 % 1.5 2.6 2.0 1.7

Elongation at break conditioned ISO 527 | ISO 1110 % 2.7 5.3 4.3 3.5

Tensile modulus ISO 527 MPa 16 000 11 000 14 500 21 500

Tensile modulus conditioned ISO 527 | ISO 1110 MPa 10 000 7 400 8 700 13 000

Charpy impact strength unnotched ISO 179/1eU kJ/m² 20 40 30 40

Charpy impact strength unnotched cond. ISO 179/1eU | ISO 1110 kJ/m² 25 55 45 50

Charpy impact strength notched ISO 179/1eA kJ/m² 3 – – –

Specific wear rate ws at1 MPa, 1 m/s, dry/steel ASTM G 137 10-6 mm³/Nm 0.2 0.5 0.33 0.5

Coefficient of friction µ at1 MPa, 1 m/s, dry/steel ASTM G 137 1 0.2 0.3 0.28 0.26

Surface resistivity DIN IEC 60093 Ohm 104 - 105 105 - 106 104 - 105 < 103

Humidity absorption ISO 1110 % 1.6 2.2 2.0 1.9

Melting temperature ISO 3146 (10K/min) °C 260 260 260 260

Moulding shrinkage ISO 2941) % 0.1 - 0.4 0.1 - 0.4 0.1 - 0.4 0.1 - 0.4

TRIBOFORCE® PPS C1800 PPS C1801 PPS C1802 PEEK C23002) PEEK C23013)

Density ISO 1183 g/cm³ 1.61 1.5 1.48 1.59 1.57

Tensile strength ISO 527 MPa 115 125 140 145 165

Elongation at break ISO 527 % 1 1.2 0.8 2.2 1.9

Tensile modulus ISO 527 MPa 16 000 15 000 22 500 13 000 14 300

Charpy impact strength unnotched ISO 179/1eU kJ/m² 15 18 18 35 32

Charpy impact strength notched ISO 179/1eA kJ/m² 2 4 5 4 –

Specific wear rate ws at

1 MPa, 1 m/s, dry/steel18 MPa, 1 m/s, dry/steel6 MPa, 2 m/s, 75 °C, dry/steel

ASTM G 137 10-6 mm³/Nm 0.1––

0.10.20.2

0.10.20.2

0.1––

0.1––

Coefficient of friction µ at

1 MPa, 1 m/s, dry/steel18 MPa, 1 m/s, dry/steel6 MPa, 2 m/s, 75 °C, dry/steel

ASTM G 137 1 0.2––

0.20.1

0.05

0.30.150.05

0.2––

0.2––

Coefficient of Linear Thermal Expansion (CLTE)

longitudinaltransverse

ISO 1135923 °C - 55 °C α * 10-6/K

1145

––

––

––

––

Melting temperature ISO 3146 (10K/min) °C 275 275 275 340 340

Moulding shrinkage ISO 2941) % 0.05 - 0.2 0.15 - 0.3 0.15 - 0.3 0.05 - 0.2 0.05 - 0.2

Unless otherwise stated, the values refer to uncoloured materials, dam 23 °C.1) Internal test method in accordance with ISO 294 (test specimen 60 mm x 60 mm x 2 mm) | 2) For extrusion | 3) Injection moulding gradeData sheets and processing guidelines for our TRIBOFORCE® products can be found at www.brenntag.de.

Page 7: POLYMERS DACH - Anmelden · POLYMERS DACH Tribologically optimized ... 1 MPa, 1 m/s, dry/steel ASTM G 137 10-6 mm³/Nm 0.2 0.5 0.33 0.5 Coefficient of friction µ at 1 MPa, 1 m/s,

Continuous service temperatures, chemical resistance

CONTINUOUS SERVICE TEMPERATURES TRIBOFORCE® PA66 PPS PEEK

To 130 °C

130 °C to 200 °C

200 °C to 260 °C

To 300 °C, temporary

CHEMICAL RESISTANCE

Aqueous

Biological media

Salt spray (fog)

Hydrolysis resistant

Suitable for superheated steam sterilization to 200 °C

Oil

Petrol

Weak mineral acids

Diluted alkaline solutions

Concentrated alkaline solutions

Nitric acid and other oxidising acids

Page 8: POLYMERS DACH - Anmelden · POLYMERS DACH Tribologically optimized ... 1 MPa, 1 m/s, dry/steel ASTM G 137 10-6 mm³/Nm 0.2 0.5 0.33 0.5 Coefficient of friction µ at 1 MPa, 1 m/s,

Strain [%]

Stre

ss [

MPa

]

120

240

0.0 2.01.0 3.0 4.0 5.0 6.0

100

80

60

40

20

0

140

160

180

220

200

Tensile test TRIBOFORCE® PA66 C0200 UNGEFÄRBT (dry)

Stre

ss [

MPa

]

120

240

100

80

60

40

20

0

140

160

180

220

200

Tensile test TRIBOFORCE® PA66 C0203 UNGEFÄRBT (dry)

Strain [%]

0.0 2.01.0 3.0 4.0 5.0 6.0

Diagrams

23 °C 100 °C 160 °C

23 °C 120 °C

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Page 9: POLYMERS DACH - Anmelden · POLYMERS DACH Tribologically optimized ... 1 MPa, 1 m/s, dry/steel ASTM G 137 10-6 mm³/Nm 0.2 0.5 0.33 0.5 Coefficient of friction µ at 1 MPa, 1 m/s,

Temperature [°C]

0.00

0.30

Sliding speed 2 m/s

Surface pressure 6 MPa

Sliding speed 2 m/s

Surface pressure 6 MPa

0.05

0.10

0.15

0.25

0.20

Specific wear rate ws TRIBOFORCE® PA66 UNGEFÄRBT

Spec

ific

wea

r ra

te w

s [10

-6 m

m3 /

Nm

] Co

effici

ent

of

fric

tio

n µ

[-]

0.8

0.2

0.6

0.4

Coefficient of friction µ TRIBOFORCE® PA66 UNGEFÄRBT

Temperature [°C]

25

25

75

75

50

50

100

100

125

125

150

150

175

175

C0200

C0202

C0201

C0203

C0200

C0202

C0201

C0203 9

Page 10: POLYMERS DACH - Anmelden · POLYMERS DACH Tribologically optimized ... 1 MPa, 1 m/s, dry/steel ASTM G 137 10-6 mm³/Nm 0.2 0.5 0.33 0.5 Coefficient of friction µ at 1 MPa, 1 m/s,

Tensile modulus TRIBOFORCE® PA66 UNGEFÄRBT (dry 23 °C)

Tensile strength TRIBOFORCE® PA66 UNGEFÄRBT (dry 23 °C)

Ten

sile

mo

du

lus

[MPa

]

10 000

25 000

5 000

0

15 000

20 000

Ten

sile

str

eng

th [

MPa

]

100.0

250.0

50.0

0.0

150.0

200.0

C0200

C0200

C0201

C0201

C0202

C0202

C0203

C0203

Diagrams

10

Page 11: POLYMERS DACH - Anmelden · POLYMERS DACH Tribologically optimized ... 1 MPa, 1 m/s, dry/steel ASTM G 137 10-6 mm³/Nm 0.2 0.5 0.33 0.5 Coefficient of friction µ at 1 MPa, 1 m/s,

Elongation at break TRIBOFORCE® PA66 UNGEFÄRBT (dry 23 °C)

Charpy impact strength unnotched TRIBOFORCE® PA66 UNGEFÄRBT (dry 23 °C)

Elo

ng

atio

n a

t b

reak

[%

]

1.00

3.00

50.00

2.50

40.00

30.00

20.00

10.00

0.00

0.50

0.00

1.50

2.00

Char

py

imp

act

stre

ng

th u

nn

otc

hed

[kJ

/m²]

C0200

C0200

C0201

C0201

C0202

C0202

C0203

C0203

11

Page 12: POLYMERS DACH - Anmelden · POLYMERS DACH Tribologically optimized ... 1 MPa, 1 m/s, dry/steel ASTM G 137 10-6 mm³/Nm 0.2 0.5 0.33 0.5 Coefficient of friction µ at 1 MPa, 1 m/s,

12

Linear wear rate w TRIBOFORCE® PA66 C0200 UNGEFÄRBT

Linear wear rate w TRIBOFORCE® PA66 C0201 UNGEFÄRBT

Lin

ear

wea

r ra

te w

m/h

]Li

nea

r w

ear

rate

w [

µm

/h]

Diagrams

50

40

30

20

10

02.5

5.0

7.5

10.01.0

1.5

2.0

2.5

3.0

Surface pressure p [MPa] Sliding speed v [m/s]

50

40

30

20

10

02.5

5.0

7.5

10.01.0

1.5

2.0

2.5

3.0

Surface pressure p [MPa] Sliding speed v [m/s]

50

40

30

20

10

0

50

40

30

20

10

0

Page 13: POLYMERS DACH - Anmelden · POLYMERS DACH Tribologically optimized ... 1 MPa, 1 m/s, dry/steel ASTM G 137 10-6 mm³/Nm 0.2 0.5 0.33 0.5 Coefficient of friction µ at 1 MPa, 1 m/s,

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Linear wear rate w TRIBOFORCE® PA66 C0202 UNGEFÄRBT

Linear wear rate w TRIBOFORCE® PA66 C0203 UNGEFÄRBT

Lin

ear

wea

r ra

te w

m/h

]Li

nea

r w

ear

rate

w [

µm

/h]

50

40

30

20

10

02.5

5.0

7.5

10.01.0

1.5

2.0

2.5

3.0

Surface pressure p [MPa] Sliding speed v [m/s]

50

40

30

20

10

02.5

5.0

7.5

10.01.0

1.5

2.0

2.5

3.0

Surface pressure p [MPa] Sliding speed v [m/s]

50

40

30

20

10

0

50

40

30

20

10

0

Page 14: POLYMERS DACH - Anmelden · POLYMERS DACH Tribologically optimized ... 1 MPa, 1 m/s, dry/steel ASTM G 137 10-6 mm³/Nm 0.2 0.5 0.33 0.5 Coefficient of friction µ at 1 MPa, 1 m/s,

14

Coeffi

cien

t o

f fr

icti

on

µ [

-]

Coefficient of friction µ TRIBOFORCE® PA66 C0200 UNGEFÄRBT

Coeffi

cien

t o

f fr

icti

on

µ [

-]

Coefficient of friction µ TRIBOFORCE® PA66 C0201 UNGEFÄRBT

Diagrams

0.35

0.30

0.25

0.15

0.10

0.00

0.05

0.20

Surface pressure p [MPa]

Sliding speed v [m/s]

2.5

0.35

0.30

0.25

0.20

0.15

0.10

0.05

5.0

7.5

10.0

3.02.5

2.01.5

1.0

Surface pressure p [MPa]

Sliding speed v [m/s]

2.5

0.35

0.30

0.25

0.20

0.15

0.10

0.05

5.0

7.5

10.0

3.02.5

2.01.5

1.0

0.35

0.30

0.25

0.15

0.10

0.00

0.05

0.20

Page 15: POLYMERS DACH - Anmelden · POLYMERS DACH Tribologically optimized ... 1 MPa, 1 m/s, dry/steel ASTM G 137 10-6 mm³/Nm 0.2 0.5 0.33 0.5 Coefficient of friction µ at 1 MPa, 1 m/s,

15

Coeffi

cien

t o

f fr

icti

on

µ [

-]

Coefficient of friction µ TRIBOFORCE® PA66 C0202 UNGEFÄRBT

Coefficient of friction µ TRIBOFORCE® PA66 C0203 UNGEFÄRBT

0.35

0.30

0.25

0.15

0.10

0.00

0.05

0.20

Surface pressure p [MPa]

Sliding speed v [m/s]

2.5

0.35

0.30

0.25

0.20

0.15

0.10

0.05

5.0

7.5

10.0

3.02.5

2.01.5

1.0

Coeffi

cien

t o

f fr

icti

on

µ [

-]

Surface pressure p [MPa]

Sliding speed v [m/s]

2.5

0.35

0.30

0.25

0.20

0.15

0.10

0.05

5.0

7.5

10.0

3.02.5

2.01.5

1.0

0.35

0.30

0.25

0.15

0.10

0.00

0.05

0.20

Page 16: POLYMERS DACH - Anmelden · POLYMERS DACH Tribologically optimized ... 1 MPa, 1 m/s, dry/steel ASTM G 137 10-6 mm³/Nm 0.2 0.5 0.33 0.5 Coefficient of friction µ at 1 MPa, 1 m/s,

www.brenntag.de

Business Manager Plastics

Frank DahlkeMobile: +49 173 [email protected]

Sales (Internal)

Stefanie Tarantini Tel.: +49 6371 [email protected]

Brenntag GmbHMaterial Science / PolymersLocation RamsteinCarl-Zeiss-Straße 2a - 466877 Ramstein-MiesenbachGermanyTel.: +49 6371 9635-0Fax: +49 6371 [email protected]

Contact

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