Polyols and Polymers Brch51 Annex3

8/18/2019 Polyols and Polymers Brch51 Annex3

1/117

Photographs of Baseline Monitoring Sampling carried out in 10 km radius of study area around

project site of Polyols & Polymers at D-2/CH-266,267,268, Ta. Vagra, Dist. Bharuch, Gujarat,

India for EIA for proposed synthetic resin manufacturing unit.

(Duration – Oct 2014 to Dec 2014)

Photographs of AAQM station installations

Vav Village - Primary School


2/117





Galenda Village - Panchayat Office Project Site


3/117





Geo Engineering Survey photographs

Plate3.1 and 3.2: Measurement of water level


4/117





Jolva Village Pond GIDC Reservoir


5/117





Vadadla Village Pond Vav Village

Photographs of soil sampling


6/117

Photographs of Baseline Mon

project site of Polyols & Poly

India for EIA for proposed syn

Plate 4.2: Soil sampling with spir

Photographs of noise monitori

itoring Sampling carried out in 10 km radius

ers at D-2/CH-266,267,268, Ta. Vagra, Dis

thetic resin manufacturing unit.


al auger

g

of study area around

. Bharuch, Gujarat,


7/117




Janiyadra Village -

Jolva Village- Noise near int





Noise Koliad

rnal village road Jolva Village- Noi


. Bharuch, Gujarat,

illage

se near temple


8/117





Vav Village

Photographs of water sampling for aquatic studies


9/117





Padariya Village


10/117




Project Site





Water Lily -


. Bharuch, Gujarat,

Jolva Pond


11/117





Padariya Village


12/117





Eutrophicated Pond - Padariya Village Dragon Fly - in Vav village pond


13/117





Photographs of Plankton species

Balantidium sp - GIDC Reservoir Calanus Sp - GIDC Reservoir


14/117





Euglena sp - Vav Village

Photographs of sampling of marine water and sediments


15/117






16/117





Photographs of Benthos


17/117





Chaetoceros sp. Tetrastrum sp.

Photographs of Socio-economic survey


18/117





Jolva Village Gram Panchayat & Bank Facility


19/117


20/117


21/117

Plot Plan:

M/s. POLYOLS AND POLYMERS

at Plot No. D2/CH-266,267,268, Dahej - II, Tal – Vagra,Dist - Bharuch, State – Gujarat, India

Predominant Wind

Direction - SWto NE

SN 1. Leakage from the 10 KL Tank - Stability Class D (8.33)

Affected Area

Damage distances for toxic effect from Evaporating puddle ---

Orange: 108 meters --- (85 ppm = IDLH)Acrylonitrile- 10 KL (1 Tank of 10 KL at site)


22/117

Plot Plan:



Predominant Wind

Direction - SWto NE

SN 2. Leakage from the 10 KL Tank - Stability Class F (2.2)

Damage distances for toxic effect from Evaporating puddleRed : 26 meters --- (333 ppm)

---

Affected Area

---Acrylonitrile- 10 KL (1 Tank of 10 KL at site)


23/117

Plot Plan:



Predominant WindDirection - SWto NE


Red : 11 meters ----- (37.5 kW/(sq m))

Orange: 23 meters -----(4.0 kW/(sq m))

Yellow: 31 meters ----- (1.6 kW/(sq m))Acrylonitrile- 10 KL (1 Tank of 10 KL at site)


24/117

Plot Plan:



Predominant Wind

Direction - SWto NE


Damage distances for Thermal Radiation from Pool FireRed : < 10 meters(10.9 yards)(37.5 kW/(sq m))

Orange: 24 meters ------ (4.0 kW/(sq m))

Yellow: 36 meters ------- 1.6 kW s m cry on r e- an o a s e


25/117

Plot Plan:



Predominant Wind

Direction - SWto NE

Affected Area


Damage distances for Toxic Area from Vapor Cloud Yellow: 162 meters --- (20 ppm)

orma e y e - nos. an a s e


26/117

Plot Plan:



Predominant Wind

Direction - SWto NE


Damage distances for Thermal Radiation from Pool FireRed : 12 meters --- (37.5 kW/(sq m))

Orange: 26 meters --- (4.0 kW/(sq m))

------ .Methyl Ethyl Ketone - 10 KL (1 Tank of 10 KL at site)


27/117

Plot Plan:



Predominant Wind

Direction - SWto NE


Red :


28/117

Plot Plan:



Predominant Wind

Direction - SWto NE

SN 8. Catastrophic Failure of Hydrogenation reactor - Stability Class D (8.33)

Red : LOC was never exceeded (8.0 psi =

destruction of buildings)

Orange: LOC was never exceeded (3.5 psi

= serious injury likely)

Yellow: 24 meters --- (0.5 psi)Hydrogen - 2 Cylinders bank of 30 cylinders


29/117

Plot Plan:



Predominant Wind

Direction - SWto NE

SN 9. Catastro hic Failure of H dro enation reactor - Stabilit Class F 2.2

Red : LOC was never exceeded --- (8.0 psi =

Damage distances for Overpressure (blast force) from vapor cloud explosion


Orange: LOC was never exceeded --- (3.5 psi




30/117

Plot Plan:



Predominant Wind

Direction - SWto NE

” - Red : LOC was never exceeded --- (8.0 psi =

. - .

Damage distances for Overpressure (blast force) from vapor cloud explosion


Orange: LOC was never exceeded --- (3.5 psi




31/117

Plot Plan:



Predominant Wind

Direction - SWto NE

SN 11. Leakage from 20 KL storage tank- Stability Class D (8.33)

---

Damage distances for Thermal radiation from pool fire .


Yellow: 42 meters --- (1.6 kW/(sq m))Styrene - 40 MT (20 KL - 2 nos. of tank at site)


32/117

Plot Plan:



Predominant Wind

Direction - SWto NE

SN 12. Leaka e from 20 KL stora e tank- Stabilit ClassF 2.2

Red : less than 10 meters 10.9 ards ---

Damage distances for Thermal radiation from pool fire

(37.5 kW/(sq m))


Yellow: 46 meters --- (1.6 kW/(sq m))Styrene - 40 MT (20 KL - 2 nos. of tank at site)


33/117

Plot Plan:



Predominant Wind

Direction - SWto NE

SN 13. Leakage from 20 KL storage tank- Stability Class D (8.33)

Red : 17 meters --- 37.5 kW s m



Yellow: 48 meters --- (1.6 kW/(sq m))

Xylene- 20 MT (20 KL - 1no. of tank at site)


34/117

Plot Plan:



Predominant Wind

Direction - SWto NE

SN 14. Leakage from 20 KL storage tank- Stability Class F (2.2)

Red : less than 10 meters 10.9 ards ---


(37.5 kW/(sq m))


Yellow: 51 meters --- (1.6 kW/(sq m))Xylene- 20 MT (20 KL - 1no. of tank at site)


35/117

Plot Plan:



Predominant WindDirection - SWto NE

SN 15. Leakage from 200 meters length Natural Gas pipeline -Stability Class F (2.2)

Dama e distances for Thermal radiation from et fireRed : 10 meters --- (37 kW/(sq m))

range: me ers --- sq m

Yellow: 49 meters --- (1.6 kW/(sq m))Natural Gas - pipeline supply

CONSEQUENCEANALYSIS FORSELECTEDCHEMICALSINVENTORY


36/117

CONSEQUENCE ANALYSIS FOR SELECTED CHEMICALS INVENTORY

For proposed new Synthetic Resins Manufacturing unit of M/s. POLYOLS & POLYMERS PVT. LTD.

At Plot No. D-2/CH/266,267, & 268 Dahej II Ind. Estate, Jolva, District Bharuch, Gujarat, India

TABLE OF CONTENTS

1 TOLUENE.................................................................................................................................................................................22 METHYL ISOBUTYL KETONE (MIBK)..................................................................................................................................... 33 CYCLOHEXANONE..................................................................................................................................................................44 METHYL ETHYL KETONE........................................................................................................................................................ 55 ETHYL ACETATE.....................................................................................................................................................................66 ACRYLO NITRILE.....................................................................................................................................................................77 ETHYL ACRYLATE...................................................................................................................................................................9

8 ETHYLENE DIAMINE................................................................................................................................................................ 109 HYDROGEN-HYDROGENATION REACTOR.......................................................................................................................... 1110 HYDROGEN-HYDROGEN CYLINDER BANK.......................................................................................................................... 1211 ISOPROPYL ALCOHOL (IPA) .................................................................................................................................................. 1312 METHYL METHACRYLATE...................................................................................................................................................... 1413 BUTYL ACETATE.....................................................................................................................................................................1514 BUTANOL.................................................................................................................................................................................1615 STYRENE.................................................................................................................................................................................1716 ACETIC ACID............................................................................................................................................................................18

17 BUTYL METHACRYLATE......................................................................................................................................................... 1918 FORMALDEHYDE..................................................................................................................................................................... 2019 XYLENE.................................................................................................................................................................................... 2220 PHENOL.................................................................................................................................................................................... 2321 SULFURIC ACID.......................................................................................................................................................................24



37/117




1 TOLUENE

Scenario

Most Credible Scenario of Toluene,leakage through 10mm hole

Input Data

Stability Class D F

Temperature,degC atm atm

Pressure,barg 4 4

Wind Speed,m/s 8.33 2.2

Atmospheric Temperature,degC 45 10 Amount of Toluene,KL 20 20

pool Area,m2 58.7 57.3

Output

Flash Fire Envelope,m


38/117




2 METHYL ISOBUTYL KETONE(MIBK)

Scenario

Most Credible Scenario of MIBK,leakage through 10mm hole

Input Data

Stability Class D F


Pressure,barg 4 4

Wind Speed,m/s 8.33 2.2 Atmospheric Temperature,degC 45 10

Amount of MIBK,KL 20 20


Output



39/117




3 CYCLOHEXANONE

ScenarioMost Credible Scenario of Cyclohexanone,leakage through 10mm hole

Input Data

Stability Class D F


Pressure,barg 4 4


AtmosphericTemperature,degC 45 10

Amount of Cyclohexanone,KL 20 20

pool Area,m2 56 56

Output



40/117




4 METHYL ETHYL KETONE

Flammability Effect:

Scenario

MEK Leak Through 10mm hole

Input Data

Stability Class D F

Temperature,degC Atm Atm

Pressure,barg Atm AtmWind Speed,m/s 8.33 2.2

Atmospheric Temperature,degC 45 10

Leak Size,mm 10 10


Output



41/117




5 ETHYL ACETATEScenario

Most Credible Scienario of Ethyl Acetate,Spillage from 200Lit Drum

Input Data

Stability Class D F


Pressure,barg atm atm


Amount of Ethyl Acetate,Lits 200 200

pool Area,m2 20 20

Output



42/117




• The storage area shall be well ventilated.

6 ACRYLO NITRILEScenario

Most Credible Scenario of ACN,Leakage from 10mm hole

Input Data

Stability Class D F




Amount of ACN,KL 10 10

IDLH,ppm 85 85

LD50,ppm 333 333

Output

Evaporation Rate ,gm/s 0.62 0.0455



43/117




Flammable Effect:

Atmospheric Stability Class D Atmospheric Stability Class F

Discussion:

• The discharge rate through leak is 1.23kg/s.Thetotal material released is 1225kgs.

• The evaporating pool will release ACN vapors to atmosphere which will disperse in downwind direction.

• LC50 distances are 49 & 26m for atmospheric condition D & F respectively.

• The cloud will reach these distance within 3 mins of release. The concentration at this point will be 333ppm for 1-2mins and subsequently it decreases below IDLH value.(As seen in below fig)



44/117




7 ETHYL ACRYLATE

Scenario

Most Credible Scenario of Ethyl Acrylate,Leakage from 10mm hole

Input Data

Stability Class D F





Amount of Ethyl Acetate,KL 10 10

Output

Evaporation Rate ,gm/s 0.405 0.0271

Flash FireEnvelope,m


45/117




8 ETHYLENE DIAMINEScenario

Most Credible Scenario of Ethylene Diamine one drum damage

Input Data

Stability Class D F




AtmosphericTemperature,degC 45 10

Amount of Ethylene Diamine,KL 10 10

Output

Evaporation Rate ,gm/s 0.038

Material Solidify



46/117




• If the explosive mixture is not ignited immediately then the spilled material will be evaporated at rate of 0.038kg/s

• The storage area shall be well ventilated

9 HYDROGEN-HYDROGENATION REACTORScenario

Hydrogenation Reactor Catastrophic Failure

Input Data

Stability Class D F


Pressure,barg 300 300



Volume of reactor,m3 5 5

Output

ReleasedQuantity,Kg 10.7 10.7

Explosion

Distance to overpressure level 8.0psi,..m - -

Distance to overpressure level 3.5psi,..m


47/117




10 HYDROGEN-HYDROGEN CYLINDER BANKScenarioHydrogen Cylinders Tubing Leak,(Leak Size 0.75 in)

Input DataStability Class D FTemperature,degC 300 300Pressure,bar 100 100Wind Speed,m/s 8.33 2.2 Atmospheric Temperature,degC 45 10Volume of c linder,m3 0.047 0.047

OutputReleased Quantity,Kg 1.08 1.22Ex losionDistance to overpressure level 8.0psi,..m - -Distance to overpressure level 3.5psi,..m - -Distance to overpressure level 0.5psi,..m - 25Jet FireFlame Len th,m 1 1Distance to radiation level 37.5kw/m2,..m


48/117




11 ISOPROPYL ALCOHOL(IPA)Scenario

Most Credible Scenario of IPA,leakage through 10mm hole

Input Data

Stability Class D F


Pressure,barg 4 4


Amount of IPA,KL 20 20


Output



49/117

CO S QU C SS O S C C C S O



12 METHYL METHACRYLATEScenario

Most Credible Scenario of Methyl Methacrylate,leakage through 10mm hole

Input Data

Stability Class D F


Pressure,barg 4 4



Amount of Methyl Methacrylate,KL 10 10


Output



50/117

Q



13 BUTYL ACETATE

Scenario

Most Credible Scenario of Butyl Acetate,leakage through 10mm hole

Input Data

Stability Class D F


Pressure,barg 4 4Wind Speed,m/s 8.33 2.2


Amount of Butyl Acetate,KL 10 10


Output



51/117



14 BUTANOL

Scenario

Most Credible Scenario of Butanol,leakage through 10mm hole

Input Data

Stability Class D F


Pressure,barg 4 4



Amount of Butanol,KL 10 10


Output



52/117



15 STYRENE

Scenario

Most Credible Scenario of styrene,leakage through 10mm hole

Input Data

Stability Class D F


Pressure,barg 4 4



Amount of styrene,KL 20 20


Output



53/117



16 ACETIC ACID

Scenario

Most Credible Scenario of Acetic Acid,leakage through 10mm hole

Input Data

Stability Class D F


Pressure,barg 4 4



Amount of Acetic Acid,KL 10 10

pool Area,m2 53.27 Solid

Output



54/117



17 BUTYL METHACRYLATE

ScenarioMost Credible Scienario of Butyl Acrylate,Spillage from 200Lit Drum

Input Data

Stability Class D F





Amount of Butyl Acrylate,Lits 200 200

pool Area,m2 20 20

Output



55/117



• The storage area shall be well ventilated.

18 FORMALDEHYDE

ScenarioMost Credible Scenario of Formaldehyde,Spillage from 10mm hole

Input Data

Stability Class D F

Temperature,degC 45 10

Pressure,barg 4 4



Amount of Formaldehyde,KL 50 50

IDLH,ppm 20

Output

Solution Release rate,kg/hr 1.44 1.44

Formaldehyde release rate,kg/hr 0.0133 0.0133



56/117



Toxic Effect:

Atmospheric Stability Class D Atmospheric Stability Class F

Discussion:

• It is assumed that after isolation and control of the formaldehyde solution leak(ie 15mins) still there will be release of formaldehyde gas from spilled solution but it is assumed that it will be negligible as all 37% formaldehyde is releasedduring the leak.

• The IDLH distance for stability class D & F is 45 and 162m. For atmospheric class ‘D’ the area of dispersion is notwide and it is patchy ,hence ALOHA has not given the map. For class ‘F’ also the spread of area along the line of concentration is not more than 5m.

• At thesedistances thehorizontal spreadof vapour cloud isnot morethan10mmaximum.

The Area is patchy hence not

shown.



57/117



19 XYLENEScenario

Most Credible Scienario of xylene,Spillage from 10mm hole

Input Data

Stability Class D F


Pressure,barg atm atmWind Speed,m/s 8.33 2.2


Amount of xylene,KL 20 20


Output



58/117



20 PHENOLScenario

Most Credible Scenario of Phenol,Spillage from 10mm hole

Input Data

Stability Class D F

Temperature,degC 45 10

Pressure,barg 4 4Wind Speed,m/s 8.33 2.2


Amount of Phenol,KL 40 40

IDLH,ppm 250 250

LD50,ppm 2500 2500

Output

Evaporation rate,kg/hr 0.01026

Material Solidify

Distance toLD50,m


59/117



21 SULFURIC ACIDScienaro 1

Catastrophic Failure of Sulfuric acid Tank

Input Data

Stability Class D F


Pressure,kg/cm2g 1 1


Volume of vessel,m3 10 10

Diameter,m 2 2

Height,m 3 3

ERPG2,mg/m3 10 10

Output

Evaporation Rate,kg/min 1.5 0.105

LC50 Distance,m


60/117

WK SUN MON TUE WED THU FRI SAT WK SUN MON TUE WED THU FRI SAT WK SUN MON TUE WED THU FRI SAT

41 1 2 3 4 45 1 50 1 2 3 4 5 6

42 5 6 7 8 9 10 11 46 2 3 4 5 6 7 8 51 7 8 9 10 11 12 13

43 12 13 14 15 16 17 18 47 9 10 11 12 13 14 15 52 14 15 16 17 18 19 20

44 19 20 21 22 23 24 25 48 16 17 18 19 20 21 22 53 21 22 23 24 25 26 27

45 26 27 28 29 30 31 49 23 24 25 26 27 28 29 54 28 29 30 31

50 30

DECEMBERNOVEMBEROCTOBER

Project: Baseline Environmental Studies

Client: Polyols & Polymers

Conducted by: Siddhi Green Excellence Pvt Ltd, Ankleshwar

Duration for Baseline Environmental Studies –Oct 2014 to Dec 2014 (Post monsoon)

AAQM monitoring dates for stations – Jolva, Vadadla, Galenda, Dahej, Ambetha

Project: Baseline Environmental Studies

Client: Polyols & Polymers

Conducted by: Siddhi Green Excellence Pvt Ltd, Ankleshwar

Duration for Baseline Environmental Studies –Oct 2014 to Dec 2014 (Post monsoon)


61/117

Project: Proposed new manufacturing unit for synthetic organic products

Proponent: M/s. Polyols & Polymers

Project site: Plot No. D-2/CH/266, 267 & 268, Dahej – II - Industrial estate

Village: Jolva, Taluka - Vagra, Dist. Bharuch, State - Gujarat, India

Documents: List of Partners for proposed project

List of Partners:

Sr.No. List of partners Contact No. Address1 Prabir Kumar Dutt

Bhupendra Mohan Dutt

9377001193 81, Bhagyoday Society Chala,

Vapi:396191

2 Mrs. Archana Dutt

Kali Bhusan Sadananda Dutt

(0260) 2462985 81, Bhagyoday Society Chala,

Vapi:396191

3 Mr. Supratik Dutt

Prabir Kumar Dutt

9824141616 81, Bhagyoday Society Chala,

Vapi:396191

4 Patel Navnitbhai DurlabhbhaiPatel Durlabhbhai Zinabhai

9427870258 At & Po. Kalwada, Dist. ValsadI.T. PAN No. :

AHNPP7136L/Ward-2, Valsad

5 Patel Gitaben Navnitbhai

Dayabhai Ghelabhai Patel

(02632) 273708 At & Po. Kalwada, Dist. Valsad

I.T. PAN No. :

ASGPP&031C/Ward-2, Valsad


62/117

Area Profile of Vagra sub-district of Bharuch district, Gujarat state

Number of Households 16,767 Average Household Size(per Household) 5.0

Population-Total 82,647 Proportion of Urban Population (%) 0

Population-Rural 82647 Sex Ratio 913

Population-Urban 0 Sex Ratio(0-6 Year) 962

Population(0-6Years) 12,813 Sex Ratio (SC) 940

SC Population 4,459 Sex Ratio (ST) 932

ST Population 21,276 Proportion of SC (%) 5.0

Literates 50,838 Proportion of ST (%) 26.0

Illiterates 31,809 Literacy Rate (%) 73.0

Total Workers 35,269 Work Participation Rate (%) 43.0

Main Worker 28,201 % of Main Workers 34.0

Marginal Worker 7,068 % of Marginal Worker 9.0

Non Worker 47,378 % of non Workers 57.0

CL (Main+Marginal) 8,939 Proportion of CL (%) 25.0

Al (Main+Marginal) 13,801 Proportion of AL (%) 39.0

HHI (Main+Marginal) 328 Proportion of HHI (%) 1.0


63/117


64/117


65/117

tw*$$clRT

r:

j.-1.'

*


66/117

Utility

10.00

26.5

20.00

20.00

Lab on FF

48.00

P2

(FOR

CAR)

COMMON

OPEN PLOT30.0

38.33

18.00

1. HYDROGEN TROLLY

2. HYDROGEN REACTOR

3. RM STORAGE BAGS

4. RM STORAGE DRUMS

5. FG STORAGE DRUMS

6. FG STORAGE BAGS

7. EXPLOSIVE RM STORAGE AREA

8. BOILER, THF, CP, DG, ALL UTILITIES

8

GREEN BELT AREA

Proposed Plant Layout: M/s. POLYOLS AND POLYMERSat Plot No. D2/CH-266,267,268, Dahej - II, Tal – Vagra, Dist - Bharuch, State – Gujarat, India

1 4 5

2 3 6

7

Petroleum

ClassA U/g

tankfarm

Tank

farm

area

20.00


67/117

M/s. POLYOLS & POLYMERSPlot No. D-2/CH/266, 267 & 268, Dahej – II - Industrial estate

Village: Jolva, Taluka - Vagra, Dist. Bharuch

List of Raw Material (For proposed New Unit)

Sr No Product Name Proposed

production

capacity

MT/Month

Raw materials Consumption

Kg/kg of

product

MT/Month

1 (a) Acrylic resin 60 Methyl methacrylate 0.330 19.80

Butyl methacrylate 0.460 27.60

Acrylic Acid 0.240 14.40

Poly Vinyl Alcohol 0.0003 0.02

Benzoyl peroxide (Initiator) 0.021 1.26

1 (b) Acrylic Polyols 150 Toluene 0.50 75.0

Acrylic monomers 0.49 73.5

Benzoyl peroxide (Initiator) 0.01 1.5

1 (c) Acrylic emulsion 150 Methyl methacrylate 0.396 59.40

Sodium lauryl sulphate 0.008 1.20

Ammonium persulphate 0.001 0.15

Other acrylic monomers which shall be used in product no. 1 (a), (b), (c) as per product spec. are :

Acrylonitrile, Methyl Acrylate, Ethyl Acrylate, Butyl Acrylate, 2 ethyl Hexyl Acrylate, Methoxyethyl

Acrylate, Dimethyl amino Acrylate, Methacrylic Acid, Ethyl methacrylate, Isobutyl methacrylate, 2

ethyl hexyl methacrylate Lauryl methacrylate Stearic methacrylate Di methyl amino methacrylate


68/117




production

capacity

MT/Month


Kg/kg of

product

MT/Month

4 Oil based polyester

Polyols (L)

1500 Castor oil 0.800 1200.0

Ketonic Resin 0.199 298.5

Di butyl tinoxide 0.001 1.5Optional raw materials which shall be used in product no. 4 as per product spec. are :Acrylic Polyols, Glycerol,

Trimethylolpropane Propoxylate

5 (a) Phenol formaldehyde

resin

(a) Phenol

formaldehyde / alkyl

phenol formaldehyde

resin – NOVOLACS

750 Phenol /

Para tertiary butyl phenol/

Nonyl phenol

0.970 727.5

Formaldehyde (37%) /

paraformaldehyde

0.672 504.0

Oxalic acid / hydrochloric

acid - catalyst

0.020 15.0

5 (b) Phenol formaldehyde

resin (b) alkyl Phenol

formaldehyde resin

resole

300 Para tertiary butyl phenol 1.000 300.0

Formaldehyde (37%) /

paraformaldehyde

0.730 219.0

Caustic Soda flakes 0.018 5.4


69/117




production

capacity

MT/Month


Kg/kg of

product

MT/Month

*Other optional diols :Ethylene Glycol( EG ), Propylene Glycol ( PG), 1,4Butanediol (BD), 1,5Pentanediol (PD), Di ethylene Glycol

(DEG ), 3 Methyl -1,5pentanediol(MPD), 2,2,4 Trimethyl-1,3 Pentanediol ( TMPD), Tri ethylene glycol (TEG),

Hexyleneglycol (HG), Tri ethylene glycol (TEG), NPG ester,esterdiol, Bisphenol A, Propoxylated Bisphenol A#Other optional difunctional acids :-Maleic Anhydride, Succinic Anhydride, 1,2,3,6 Tetra hydro Pthalic acid anhydride , Fumaric Acid, Succinic

Acid, Di glycolic Acid, Adipic Acid, Pthalic Anhydride, Iso Pthalic Acid, Terepthalic Acid, Azelaic Acid

Sebacic Acid, Trimellitic Anhydride (TMA) ,Citric Acid ,Tri mellitic Acid, Styrene, Xylene\

Other High Functionality Alcohols: Pentaerythritol Sorbitol Di pentaerythritol &

Mono functional acids Benzoic Acid Pelargonic Acid p-Tertiary butyl benzoic Acid

8 (a),9 Rosin Based Resins (a)Modified Phenolic

Resin &

Turpentine

600 Gum Rosin 0.7 420.0Para Tertiary butyl Phenol/

Nonyl phenol

0.325 195.0

Para Formaldehyde 0.173 103.8

Pentaerythritol 0.135 81.0

8 (b),9 Rosin Based Resins

(b) Maleic Resin &

600 Gum Rosin 0.8 480.0

Pentaerythritol 0.125 75.0


70/117





Documents: Manufacturing Process for proposed project

Product-1: (a) Acrylic resins:

Acrylic Resins are formed by addition polymerization reactions.. Unlike condensation

polymerization , addition polymerization leads to high mol weight polymers. There is also no

release of water or other small molecules characteristic of condensation polymers.

Thermoplastic Acrylic Resins

Process:

Reaction:

Process consists of charging DM water in the reactor and dissolving the PVA under stirring.

On completion of the dissolution the contents of the reactor are heated to the desired

temperature. MMA , n-BMA and acrylic acid are slowly added along with the initiator at ameasured rate, taking care not to let the temperature rise beyond a certain required level..

When the required temperature level is reached – the reactants are maintained at that

temperature for the required time.

Cooling & Washing:

At the end of the reaction period the contents are cooled and discharged into a neutch filter

and drain the water. The resin is further washed with water to free the resin of any


71/117






Flow sheet:

Dissolution

Heating

Cooling

Filtration

Washing

Poly vinyl alcohol 0.300kg

DM water 1000kg

Methyl Meth Acrylate 330 kgn- Butyl Meth Acrylate 460 kg

Acrylic acid 240 kgBenzyl peroxide 21 kg

Filtrate 1021 kg sent to ETP

Effluent 500 kg sent to ETPWater 500 kg

1000.3kg

2051.3 kg

2051.3 kg

1030.3 kg


72/117






Product-1: (b) Acrylic polyols

Process:

Reaction:

In this process of manufacture the reactions are taken in a solvent in which the produced resin

is soluble. Solvent (toluene/ MEK/ Butanol). This is an addition polymerization reaction. Theacrylic monomers required along with the initiator are added slowly in the solvent in the

reaction vessel fitted with stirrer system and reflux condenser.

Cooling & Packing:

As this is an exothermic reaction the temperature of the contents of the reactor rises and is

controlled by jacket cooling as and when required When the required temperature is reached,

the reactants are allowed to be maintained for a required time and then cooled and packed in

barrels.

Chemical reaction:


73/117


74/117






Product-1: (c): Acrylic Emulsion:

Process: A typical MMA Emulsion Polymers:

Mix 8 Kg sodium lauryl sulphate in 595 Kg DM water is SS reactor fitted with a stirrer,

reflex condenser, thermometer nitrogen inlet tube and two liquid addition inlets. Solution

ammoniums per sulphate in DM water is prepared and of this solution and methylmethacrylate monomer are added to the flask. The stirrer and nitrogen flow are switched on

and the flask slowly heated to 75°C. The emulsion is maintained at 75°C for 40 minutes after

the end of the monomer addition to complete the reaction. The non-volatile content is

determined and further initiator added if below theoretical, and the hold is continued for a

further hour.

Chemical reaction:


75/117






Flow sheet:

10100

Polymerization

Reflux

Cooling

Packing in barrels

DM Water 595kg

Acrylic emulsion 1000 kg

1000 kg

1000 k

1000 kg

Sodium lauryl sulphate 8 Kg

Ammonium persulphate 1 Kg

Methyl methacrylate 396 kg

P j P d f i i f h i i d


76/117






Product-2 : Hydrogenated Ketonic Resin:

Process:

Reaction:

Process consists of dissolving ketonic resin in the solvent (Butyl acetate/ MEK / ethyl acetate/

IPA/ butanol) and charging the solution along with the catalyst in the Hydrogenation reactor.Necessary amount of hydrogen is charged in the reactor and the reactor will be under

pressure. Temperature of the reactants is increased to the required level. As the reaction

progresses there will be reduction of the pressure in the reactor indicating consumption of

Hydrogen.

Filtration:

At the end of the reaction the solution of hydrogenated ketonic resin is filtered to recover the

catalyst which shall be used in the next batch. The solution is then distilled in a separatereaction vessel

Distillation, Cooling & Packing:

The solvent is distilled out and is condensed and is to be used in the next batch. When the

solvent is distilled out, molten resin is left in the reactor which is poured in trays for cooling

and solidification.

P j P d f i i f h i i d


77/117






Flow sheet:

Dissolution

Cooling

Filtration

Distillation

Cooling

Ketonic resin 900 kg

Butyl acetate 400 kg

Hydrogen gas 100 kgRaney nickel 2 kg

Spent catalyst 3 kg

(Recovered & reuse in next batch)

Butyl acetate 379 kg(Recovered & reuse in next batch)

1300 kg

1402 kg

1399 k

1020 kg

P j t P d f t i it f th ti i d t


78/117






Product-3 : Ketonic resin:

Process:

Reaction:

Process consists of charging water, suspension agent, Ketone (e.g. Cyclohexanone ),

Formaldehyde in the reaction kettle fitted with a stirrer system , condenser. Caustic soda(flaks/lye) is added as a catalyst to start the reaction. It is an exothermic reaction. The temp

rises after addition of the catalyst and is controlled by jacket cooling and is maintained at the

required temp level for required time.

Cooling & washing:

At the end of the reaction the contents of the reactor are cooled and then discharged on a

neutch filter. The resin is then washed with water to free the resin from adhering & catalyst

impurities.Packing:

Then the resin is dried and packed in bags.

Chemical reaction:



79/117






Flow sheet:

Reaction

Cooling

Washing

Cyclohexanone 800 kg

3456kg

1030kg

1030 kg

37%Formaldehyde 1200 kg

Caustic soda 56 kg

Water 1400 kg

Water 5000 kg Effluent 5000 kg sent to ETP

Filtration Filtration

3456kgML

Effluent 2406 kg

sent to ETP

Resin waste 20 kg

Sent to co processing or incineration



80/117






Product-4: Oil Based Polyester Polyols:

Natural oil based polyols- castor oil based polyols

Process:Reaction:

This product is prepared by mixing different polyols e.g Glycerol, Trimethyl prapanol,ketonic

resin polyols or others in castor oil. Castor oil which is a fatty acid containing hydroxyl

groups is taken and mixed with different polyols to impart required properties to the oil based

polyol. This is just a mixing operation and does not involve any reaction.

Chemical reaction:

CH3

(CH2

)5

CH (OH) CH2

CH = CH (CH2

)7

COOH + HO-R1---(-----OOC-R-COOR1 ---)----OH

CH3 (CH2)5 CH (OH) CH2 CH = CH (CH2)7 COO

CASTOR OIL POLYESTER RESIN

Mol. Wt 934 Mol. Wt 650


81/117



82/117






Flow sheet:

Reaction

Reflux

Cooling

1662 kg

1662 kg

37%Formaldehyde 672 kg

Phenol 970 kgOxalic acid 20 kg

Distillate mainly water 662 kg

sent to ETPDistillation

1662 kg

Melting & cooling

1000 kg


83/117



84/117






Flow sheet:

Reaction

Cooling

Neutralization

Layer separation

Distillation

Formaldehyde 730 kg

p- tertiary butyl phenol 1000 kg

Sulphuric acid 30 kgToluene 100 kg

Aq. Layer 783 kg sent to ETP

Toluene 95 kg recovered &

reuse in next batch

1748 kg

1748 kg

1878 kg

1095 kg

NaOH 18 kg



85/117






Product-6 : Polyamide Resins

Process:

Esterification:

Basically this is a Esterification reaction between a dimer acid and di-amine resulting in the

formation of a polyester and water of reaction Process consists of charging all the rawmaterials in a stirred reaction vessel fitted with a condenser.

Heating & Distillation:

The contents of the reaction vessel is heated and after about couple of hours the acid value

and the amine values are checked at periodic intervals till the required acid value and amine

value is achieved. The water of reaction is distilled at the high reaction temperature and

condensed in the condenser. The distillate consists mainly of water and traces of impurities

which is sent to ETPCooling & Packing:

The molten resin is poured in trays and allowed to cool. After cooling and solidification of

the resin, it is broken into lumps and packed in bags.

Chemical reaction:



86/117






(a) Flow sheet for co solvent grade polyamide resins:

Reaction

Heating

1091 k

1091 k

Dimer acid 850 kg

Fatty acid 134 kg

Ethylene diamine/ Tri ethylene

tetra amine 107 kg

Cooling

Distillate mainly water 91kgsent to ETP

Distillation

1091 kg

1000 kg

Cooling



87/117






(b) Flow sheet for Alcohol soluble polyamide resins:

Reaction

Heating

1117 kg

1117kg

Dimer acid 816 kg

Acetic acid 146 kg

Ethylene diamine/ Tri ethylenetetra amine 155 kg

Cooling

Distillate mainly water 117kg

sent to ETPDistillation

1117kg

1000 kg



88/117






(c) Flow sheet for reactive polyamide resins:

Reaction

Heating

Distillation

Packing in barrels

1000 kg

1000 kg

1000 kg

INPUT = OUTPUT

1018 1018

Dimer acid 790 kg

Soya fatty acid 154 kg

Ethylene diamine/ Tri ethylenetetra amine 74kg

Distillate mainly water 18kg

sent to ETP



89/117






Product- 7: Polyester resin saturated / unsaturated / polyester polyols:

Process:Basically this is a Esterification reaction between a di acid and diol resulting in the formation

of a polyester and water of reaction

Reaction:

Process consists of charging all the raw materials in a stirred reaction vessel fitted with acondenser. The contents of the reaction vessel is heated and after about couple of hours the

acid value is checked at periodic intervals till the required acid value is achieved.

Distillation:

The water of reaction is distilled at the high reaction temperature and condensed in the

condenser. The distillate consists mainly of water and traces of impurities which is sent to

ETP & reaming in product is packed in barrels.

Chemical reaction:



90/117






Flow sheet:

Esterification

Heating

Distillation

Packing in barrels

Polyester polyols 1000 kg

1131 kg

1131 kg

1000 kg

INPUT = OUTPUT

1131 1131

Hexane diol 690 kg

Tri methylol propane 7 kgIsophthalic acid 9 kg

Distillate mainly water 131 kg

Sent to ETP

Adipic acid 425 kg



91/117

j p w g y g p





Product-8 : Rosin based Resins & Product no. 9: Turpentine:

(A) Modified Phenolic Resin:

Process:

Rosin based resins are made by basically Esterification process wherein the yield is 90%. The

distillate is around 10 % which consists of distilled terpene oil and reaction water. This

effluent (distillate) consists of 80% Turpentine is recovered in turpentine recovering system

and 20% Effluent is sent to bio treatment plant for treatment.

Chemical reaction:

R-COOH + R-OH + HCHO -OH – Ph - CH2 – Ph – O - + R-COOH

ADDUCT

CH2OH CH2OH

M.wt: 323 M. Wt: 150 M.Wt: 30

ADDITIONREACTION

ESTERIFICATION WITH PENTAERYTHRYTOL

REDUCTION

C H O R1 (OH)



92/117

j p g y g p





Flow sheet:

Reaction

Heating

Packing

Modified phenolic resin 1000 kg

1333 kg

1000 kg

INPUT = OUTPUT

1333 1333

Gam rosin 700 kgpara tertiary butyl phenol 325 kg

p- Formaldehyde 173 kg

Turpentine 67 kg

Pentaerythritol 135 kg

Effluent 266kg sent to ETP

Condensation

Layer

separation

Cooling

1000 kg



93/117

j p g y g p





(B) Maleic Resin:

Chemical reaction:

R-COOH + CH - C - OH

CH - C - OH

O

REACTION AT

ELEVATED

TEMPERATURE

O

R- CH - C

O

CH - C

O

O

ESTERIFICATION WITH PENTAERYTHRYTOL

REDUCTION

C5H12 O4 - R1– (OH)4R1 = C5H8

ADDUCT OF LAEVOPIMARIC ACID

AND FUMARIC ACID

FUMERIC ACID

M.Wt : 323 M.Wt : 125

M.Wt: 136

R1OOC - R- CH - C

O + H2O

CH - C

OCH3 COOH

CH3



94/117

j p g y g p





Flow sheet:

Reaction

Heating

Packing

1220 kg

1000 kg

INPUT = OUTPUT

1220 1220

Gum rosin 800 kgFumaric acid 295 kg

Turpentine 44 kg

Pentaerythritol 125 kg

Effluent 176kg sent to ETP

Condensation

Layer

separation

Cooling

1000 kg

Maleic resin 1000 kg



95/117

j p g y g p





Product-9: styrene Maleic Anhydride Resins:

Process:

Reaction:

Process consists of charging requisite quantities of toluene, styrene, and maleic anhydride

along with initiator in the reaction vessel fitted with a stirrer system and reflux condenser.

The contents are stirred till a homogenous solution is achieved.

Heating & Cooling:

The mixture is then heated to the required temperature and stirred for a required time to

complete the reaction. At the end of the reaction the contents are cooled to room temp and the

SMA co polymer is precipitated.

Filtration, Drying & Packing:

The copolymer is filtered, dried and is then packed. The filtered toluenes along with theresidual monomers are reused in the next batch and necessary adjustments are made for the

maleic anhydride and styrene present in the toluene.

Chemical reaction:



96/117





Flow sheet:

Reaction

Reflux

Heating

Cooling

Filtration

Styrene 500 kg

Maleic anhydride 550 kg

Filtrate contain toluene 950 kg

& 50kg unreacted styrene

recovered & reuse in next batch

2050 kg

2050 k

2050 kg

2050kg

Toluene 1000 kg



97/117





Product-10: Xylene- Formaldehyde Resins:

Process:

Reaction:

In the basic process xylene as a solvent is added, followed by the calculated amount of

aqueous formaldehyde solution. Than sulfuric acid is added directly into the lower aqueous

phase under smooth agitation. The reaction temperature of the slightly exothermic process is

around 100°C. Therefore the quality of formalin solution is important (concentration, amount

of methanol). The reaction is carried out under reflux for min. 6h. The reaction temperature is

in that time increasing up to 105°C while the formaldehyde get consumed and reacted with

Xylene.

Layer Separation & Neutralization:

After that the aqueous phase is going to be separated, neutralized and disposed. The organicphase has to be neutralized after that with aqueous sodium carbonate solution followed by a

phase separation again.

Packing:

Organic solution is a product & Packing in barrels.



98/117





Flow sheet:

Reaction

Layer separation

Neutralization

Layer separation

Xylene 800kg

Formaldehyde (37%) 970 kg

2060 kg

1020kg

1120k

1000k

Sulphuric acid 290 kg

Aqueous layer 1140kg

Sent to ETPSodium carbonate sol.100 kg

Aqueous layer 120 kg

Sent to ETP

Packing

Neutralization

Sodium carbonate sol.100 kg

Sr.No Chemical Name CAS No. Type of

Hazard

Toxicological

information

LD50

(LC50)

Flash Point BP Sp

Gravity

LEL UEL Solubility With

Water

Incompeteble Material Hazardous

Combustion Products

Heal th F ir e R ea cti ERPG,ppm ppm degC degC % % H F R

Hazards NFPA


99/117

Heal th F ir e R ea cti

vity

RPG,ppm ppm degC degC % % H F R

1 Buty l M etha cr ylate 97 -88 -1Flammable /

ToxicYes yes yes 16000 52.2 160 0.894 2 8

insoluble in cold

and hot water

reactive with oxidicing

agent and reducing

agent ,acids ,alkali. And

with moisture.

2 2 0Carbon Dioxide

Carbon Monoxide

2 Butyl Acetate 123-86-4 Flammable Yes yes No 10768 23.9 126.5 0.9 1.7 7.6Partially soluble

in cold waterNot Available 1 3 0

Carbon Dioxide

Carbon Monoxide

3 Ethyl Acetate 140-78-6 Flammable Yes yes No

5620

(LC50

45000)

open cup 7.2 close

cup -4.477 0.902 2.2 9

Soluble in cold

and hot water

Reactiv with oxidising

agents, acid and alkali2 3 0

Carbon Dioxide

Carbon Monoxide

4 Formaldehyde 37% 50-00-0 Flammable Yes yes No 100open cup 60 close

cup 5098 1.08 6 36.5

Easily Soluble in

hot and cold

water


agent and reducing

agent ,acids ,alkali.

3 2 0Carbon Dioxide

Carbon Monoxide

5 Phenol 108-95-2 Flammable Yes yes No 270open cup 85 close

cup 79182 1.057 1.7 8.6

Soluble in cold

water


agent, metals, acids

,alkali.

4 2 0Carbon Dioxide

Carbon Monoxide

6 Sulphuric Acid 7664-93-9 NonFlammable

Yes No yes 2140 Not Applicable 270 1.84 NA NA Easily Soluble incold water


agent, Reducing

agents, Cumbustiblematerial, Organic

material, metals, acids

,alkali, moisture.

3 0 2 Not Available

7 Styrene 100-42-5 Flammable Yes yes yes 2650open cup 36.7

close cup 31.1145.2 0.906 1.1 6.1

Very slightly

Soluble in cold

water

Not Available 2 3 2Carbon Dioxide

Carbon Monoxide

8 Xylene 1330-20-7 Flammable Yes yes No 4300open cup 37.8

close cup 24138.5 0.864 1 7

insoluble in cold

and hot water

Reactive with oxidicing

agent, acids .2 3 0

Carbon Dioxide

Carbon Monoxide

9 Acetic Acid 64-19-7 Flammable Yes yes No 3310open cup 43 close

cup 39118.1 1.049 4 19.9

Easily Soluble in

Hot and cold

water


agent, metals, acids

,alkali.

3 2 0Carbon Dioxide

Carbon Monoxide

10 Ethylne Diamine 107-15-3 Flammable Yes yes No 500 34 117.2 0.9 4.2Easily Soluble in

cold waterNot Available 3 3 0

Carbon Dioxide and

nitrogen oxides

NO,NO2

Carbon Monoxide

11 Cyclohexanone 108-94-1 Flammable Yes yes No 1516open cup 46 close

cup 43.889155.6 0.948 1.1 9.4

Partially Soluble

in Hot and cold

water


agent, acids ,alkali.1 2 0

Carbon Dioxide

Carbon Monoxide

12 Toluene 108-88-3 Flammable Yes yes No 636open cup 16 close

cup 4.4444110.6 0.864 1.1 7.1

Practically

insoluble in

water


agent.2 3 0

Carbon Dioxide

Carbon Monoxide

Sr.No Chemical Name CAS No. Type of

Hazard

Toxicological

information

LD50

(LC50)

Flash Point BP Sp

Gravity

LEL UEL Solubility With

Water

Incompeteble Material Hazardous

Combustion Products

Heal th F ir e R ea cti ERPG,ppm ppm degC degC % % H F R

Hazards NFPA


100/117

vity

,pp pp g g

13 Hydrogen Gas 1333-74-0Extreamly

FlammableNo yes No

Not

Available

No Information

Available-252.8 4 75 soluble in water


agent.0 4 0 Not Available

14 Acrylonitrile 1017-13-1Flammable /

ToxicYes Yes No STEL 10 333 0 77 0.806 3.1 17

Very slightly

soluble in cold

water, hot

water

incompatible with

oxidizing agents, such

as metals, acids, alkalis

3 3 1Carbon Dioxide

Carbon Monoxide

15Methyl Ethyl

Ketone(MEK)78-93-3

Flammable/To

xicYes Yes No STEL:300ppm 6480 -9 79.6 0.805 1.8 10

Soluble in cold

water

Reactive with oxidizing

agents, metals, acids,

alkalis.

1 3 0Carbon Oxides

( CO2,CO)

16IPA (Isopropyl

Alcohol)67-63-0 Flammable Yes Yes No NA NA 11.67 82.5 0.785 2 12.7

Easily soluble in

cold water, hot

water,

Reactive with oxidizing

agents, acids, alkalis.1 3 0

Carbon Oxides

( CO2,CO)

17 Ethyl Acrylate 140-88-5Flammable/To

xicYes yes yes TWA 25ppm (1414) 9 99.4 0.923 1.4 13

Partially soluble

in cold water

The product may

undergo hazardous

decomposition,

condensation or

polymerization, it may

react violently with

water to emit

toxic ases

2 3 2Carbon Oxides

( CO2,CO)

18Methyl

Methacrylate80-62-6

Flammable/To

xicYes yes yes TWA 100 ppm

7872mg/

kg19 100 0.936 2.1 12.5

Partially soluble

in cold water

Reactive with metals,

acids, alkalis2 3 3

Carbon Oxides

( CO2,CO)

19 Butanol 71-36-3 Flammable Yes yes no NA NA 36.1 117.7 0.81 1.4 11.2

Easily soluble in

methanol,

diethyl ether.

Partially soluble

in cold water,

hot water, n-

octanol

Highly reactive with

oxidizing agents,

reducing agents.

Slightly reactive to

reactive with organic

materials, acids, alkalis

1 3 0Carbon Oxides

( CO2,CO)

20 MIBK 108-10-1 Flammble No yes No NA NA 14 115.9 0.8 1.4 7.5 ImiscibleAvoid oxidizing &

reducing agents1 3 0

Carbon Oxides

( CO2,CO)

Rapid EIA for Proposed Synthetic Organic Chemicals Manufacturing unit

at D-2/CH-266,267,268, Ta. Vagra, Dist. BharuchDetails of Hazardous Chemicals Inventory, hazardous properties Polyols Polymers

Full name of the raw

material

B.P.°C, M.P.°C Fl . P.°C LD50 mg/Kg or

LC50 mg/l

Vapour

pressure

Source As per Haz. Chemicals rules,2000Sr. No. State i.e,

solid /

Liquid/

Inventory Equipment consider No. of container

&Size at site

Storage ParametersMAH

threshold

qty.MT


101/117

Consumption

MT/Month

No. of

days

No. MT Pressure

kg/cm2

Temp °C

1 Acetic acid L 87.6 3 Al or SS Tank - AGT 1 10 Atm. 30-40°C BP 118.1°CMP 16.6°C 39 LD50- 3310 mg/kg LC50-

5620 mg/l-1h

1.5 kPa@

20°C

indigenous Sch-1,part-I(b)-HF & Part-II

2 Acrylic Acid L 14.4 0 Drum 1 0.2 Atm. 30-40°C BP 141 °C MP 14°C 50 LD50-33500 mg/kg LC50-

5300 mg/l- 2h

0.5 kPa@

20°C

indigenous Sch-1,part-I(a)-Toxic & Part-II

3 Acryl amide S 73.5 5 1 MT Jumbo bag 15 15 Atm. 30-40°C BP 125 °C MP 84.5°C 138 LD50- 124 mg/kg NA indigenous Sch-1,part-I(a)-Toxic & Part-II

4 acrylonitrile L 73.5 8 CS Tank - AGT 1 20 20 Atm. 30-40°C BP 77.3°CMP -82°C -1.11 LD50- 78 mg/kg LC50-

11.1 kPa@ indigenous Sch-1,part-I(b)-VHF

5 Benzoyl peroxide S 2.76 5 50 kg bag 10 0.5 Atm. 30-40°C BP 103°CMP-104.5°C NA LD50- 7710 mg/kg NA indigenous Sc-I, part-II

6 Bisphenol-A S 207 3 1 MT Jumbo bag 20 20 Atm. 30-40°C BP 220°CMP 158-159°C 227 LD50- 2000-5000 mg/kg

LC50- 170 mg/l-6h

NA indigenous Sc-I, part-II

7 Butanol L 3.15 95 CS or SS Tank -

AGT

1 10 Atm. 30-40°C BP 117.7°CMP -89.5 28.9 LD50- 790 mg/kg 0.6 kPa@

20°C

indigenous Sch-1,part-I(b)-HF

8 Butyl acetate L 3.15 95 CS or SS Tank -

AGT

1 10 Atm. 30-40°C BP 126.5, MP -77.9 23.9 LD50- 10768 mg/kg 1.3 kPa@

20°C


9 butyl acrylate L 73.5 8 Drum 100 20 Atm. 30-40°C BP 145°CMP -64.6°C 29 LD50- 900 mg/kg

0.5 kPa@ indigenous Sch-1,part-I(b)-HF

10 Butyl methacrylate L 27.6 22 Drum 100 20 Atm. 30-40°C BP 160°CMP -75°C 52.2 LD50-16000 mg/kg 0.7 kPa@

°


10 Caustic soda flakes S 22 68 Jambo Bag 50 50 Atm. 30-40°C BP 1388°C MP 323°C NA NA NA indigenous Sc-I, part-II

11 Cyclohexanone L 240 5 CS or SS Tank -

AGT

2 40 Atm. 30-40°C BP 155.6°CMP -31°C 43.89 LD50- 1516 mg/kg 0.7 kPa @

26.7°C

imported / indigenous Sch-1,part-I(b)-HF

12 Di butyl tinoxide S 1.5 4 Drum 1 0.2 Atm. 30-40°C MP >300°C NA oral-LD50-44.9 mg/kg NA indigenous Sch-1,part-I(a)-highly Toxic

13 Ethyl acetate L 3.15 19 Drum 10 2 Atm. 30-40°C BP 77°C, MP -83°C -4.4 LD50- 5620 mg/kg, LC50-

16000 mg/l -6h

12.4 kPa@

20°C

indigenous Sch-1,part-I(b)-VHF, Sc-I, part-II

14 ethyl acrylate L 73.5 8 CS or SS Tank -

AGT

2 20 Atm. 30-40°C BP 99.4°CMP -72°C -2 LD50- 800 mg/kg

LC50- 1414 mg/l-4h

29 mmHg

@20°C

indigenous Sch-1,part-I(b)-VHF

15 Ethyl methacrylate L 73.5 8 Drum 100 20 Atm. 30-40°C BP 118-119°CMP -60°C 19 LD50- 13424 mg/kg

LC50- 8300 ppm-4h

20hPa @

20°C

indigenous Sc-I,part-I(b)-VHFpart-II

16 Ethylene Diamine L 93 3 Drum 50 10 Atm. 30-40°C BP 117.2°CMP 8.5°C 34 LD50- 500 mg/kg, LC50-

424.3 mg/l-4h

10.7 mmHg

@20°C

indigenous Sch-1,part-I(b)-HF, Sc-I, part-II

17 ethylene glycol L 207 3 Drum 100 20 Atm. 30-40°C BP 197.6°CMP -13°C 111 LD50- 4700 mg/kg

LC50- 200 mg/m-4h

6 mmHg @

20°C

indigenous Sc-I, part-II

18 Formaldehyde (37%) L 1083 3 CS or SS Tank -

AGT

2 100 Atm. 30-40°C BP 98°C MP -15°C 50 LD50-100 mg/kg, LC50-

64000 mg/l -4h

2.4 @20°C indigenous Sch-1,part-I(b)-HF, Sc-I, part-II

19 Hydrogen gas G 14.7 10 Cylinder 30 5 2 150-200 30-40°C BP -252.8°C MP -259°C NA NA NA indigenous Sc-I, part-II

20 Iso Propyl Alcohol L 3.15 190 CS or SS Tank -

AGT

1 20 Atm. 30-40°C BP 82.5°CMP -88.5°C 11.7 LD50- 5045 mg/kg 4.4 kPa@

20°C


21 methacrylic acid L 73.5 8 Drum 100 20 Atm. 30-40°C BP 163°CMP 16°C 77 LD50- 1250 mg/kg 0.975 mm

Hg @20°C

indigenous Sch-1,part-I(b)-F

22 methyl acrylate L 73.5 8 Drum 100 20 Atm. 30-40°C BP 80.5°CMP -76.5°C -3.89 LD50- 277 mg/kg NA indigenous Sch-1,part-I(b)-VHF

23 methyl cyclohexanone L 240 3 Drum 100 20 Atm. 30-40°C BP 162-163°CMP -13.9°C 48 LD50- 1980 mg/kg 1hPa @

20°C

imported / indigenous Sch-1,part-I(b)-HF

24 Methyl Ethyl Ketone L 240 1 CS Tank - AGT 1 10 Atm. 30-40°C BP 79.6°C, MP -86°C -9 LD50-2737 mg/kg, LC50-

23500 mg/m-8h

10.3 kPa@

20°C

imported / indigenous Sch-1,part-I(b)-VHF

25 methyl isobutyl ketone L 240 3 CS Tank - AGT 1 20 Atm. 30-40°C BP 115.9°CMP -84°C 14 LD50- 1600 mg/kg

LC50- 8000 mg/l-4h

15.7 mmHg

@20°C

imported / indigenous Sch-1,part-I(b)-VHF

26 Methyl methacrylate L 79.2 8 CS or SS Tank -

AGT

1 20 Atm. 30-40°C BP 100°CMP -48°C 13 LD50-7872 mg/Kg LC50-

5303.3 mg/l-4h

29 mmHg

@20°C


27 Paraformaldehyde S 1083 1 Jambo Bag 50 50 Atm. 30-40°C MP 120-170 °C 70 LD50-800 mg/kg, LC50-

1070 mg/m-4h

NA imported / indigenous Sch-1,part-I(b)-F

28 Phenol L 727.5 2 CS Tank - AGT 1 40 Atm. 30-40°C BP 182°C, MP 42°C 79 LD50-dermal- 630 mg/kg NA imported Sch-1,part-I(a)- Toxic, Sch-1,part-I(b)-F,

Sc-I, part-II29 Poly Vinyl Alcohol S 0.02 750 50 kg bag 10 0.5 Atm. 30-40°C MP 200°C 79 LD50->20000 mg/kg NA indigenous Sch-1,part-I(b)-F

30 propylene glycol L 207 3 Drum 100 20 Atm. 30-40°C BP 188°CMP -59°C 99 LD50- 20000mg/kg 0 kPa@

20°C


31 Styrene L 336 4 CS Tank - AGT 2 40 cool 15-21°C BP 145.2°CMP -30.6°C 31.1 LD50-2650 mg/kg,

LC50-12000 mg/l-4h

4.5 mmHg

@20°C

imported/ indigenous Sch-1,part-I(b)-HF, Sc-I, part-II

32 Sulphuric acid L 35.1 9 CS Tank - AGT 1 10 Atm. 30-40°C BP 270-340°C, MP -35°C NA LD50- 2140 mg/kg,

LC50-510mg/m-2h

NA indigenous Corrosive,Sc-I , part -II

33 Toluene L 91.5 13 CS Tank -UGT 2 40 Atm. 30-40°C BP 110.6°C, MP -95°C 4.44 LD50-636 mg/kg, LC50-

49000 mg/m-4h

3.8 kPa @

25°C


34 Xylene L 199.5 3 CS Tank -UGT 1 20 Atm. 30-40°C BP 138.5°CMP -47.4°C 24 LD50- 4300 mg/kg 0.9 kPa@

20°C

indigenous Sch-1,part-I(b)-HF, Sc-I, part-II

35 Terpentine-Product L 67 9 CS Tank -AGT 1 20 Atm. 30-40°C BP 165°C 35 LD50- 5760 mg/kg - - -

Liquid /

Gas

�