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Port of Rotterdam...Cathodic protection to the ship Vertical layering of water (temperature, oxygen, salinity) ... Stress corrosion test Coupon ladder Coupons (galvanic cells) Micro

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  • 3

    Port of Rotterdam

    More than 50 kilometres !

  • 44

    1400 - 1800

    1800 - 1900

    1929 – 1949

    1948 - 1957

    1960 - 1970

    1970 – 2008

    2008 - 2030

    Development of the port

    1934 - 1946

    1906 - 1922

  • 5

    Salinity in the port

  • 6

    Port in figures

    Total port area 26,000 acres (net 12,500 acres)

    Total employment 350,000 people (140,000 regionally)

    Throughput 430 million tons, 11,1 million TEU (2010)

    Depth up to 75 ft (= 24 m)

    Port is growing westwards from the old town with fresh water of river Rhine into the salt Northsea

    Tidal zone ca. 2 meter in the whole port

  • 7

    Quay walls: total length 70 km

    Replacement value ~ 1.5 billion €

    About 40 km with steel substructures, like combi

    walls, sheet piling, etc.

    Port infrastructure in Rotterdam

  • Asset Management on Quay Walls

    A quay wall’s remaining lifetime and system integrity is

    mainly determined by the quality of the sub and

    superstructure.

    When the quay wall’s integrity is in danger, it’s often

    due to:

    concrete deterioration in the superstructure

    accelerated low water corrosion occurring at

    the substructure

  • 9

    Corrosion rates according to EAU-Curves

    No steel but concrete in the splash-zone

    Extra thickness added to steel parts

    Inspection of a few quay walls every 5 year

    Corrosion strategy (up to 1999)

  • What was discovered ?

    Before cleaning with high pressure After cleaning with high pressure

  • 11

    Unexpected corrosion

    11

    Holes in tubular piles

    Hole, followed by loss of soil

    Original

    thickness

    including

    original coating

  • Probable causes (long list)

    More salty environment

    Galvanic corrosion of combiwalls

    pitting influences on the strength

    Aeration due to extra oxygen by (bow) thrusters or cooling

    Fabrication process of steel parts

    Water flow

    Cathodic protection to the ship

    Vertical layering of water (temperature, oxygen, salinity)

    MIC

    Etc...

  • 13

    Action plan for investigation

    Stress corrosion test

    Coupon ladder

    Coupons (galvanic cells)

    Micro biological influence

    Weakening due to pitting

    Thickness measurement

  • 14

    Stress corrosion test

  • Coupons for galvanic corrosion

    test

  • Coupon ladder test

  • 17

    Results of coupon ladder

    Coupons corrosieladder Amazonehaven

    -18,0

    -16,0

    -14,0

    -12,0

    -10,0

    -8,0

    -6,0

    -4,0

    -2,0

    0,0

    0,000 0,050 0,100 0,150 0,200 0,250 0,300 0,350

    Corrosie in milimeters per jaar

    Die

    pte

    s in

    met

    ers

    t.o

    .v. N

    .A.P

    .

    mm/jr 2003 mm/jr 2005 mm/jr 2008 Diepte (m)

  • 18

    Research influence MIC

    Sampling

  • 19

    Weakening due to pitting

    Kracht- rek diagram 78547-8 Westerkade

    -50000

    0

    50000

    100000

    150000

    200000

    250000

    300000

    0

    0,0

    1

    0,0

    2

    0,0

    3

    0,0

    5

    0,0

    8

    0,1

    0,2

    4

    0,3

    9

    0,6

    7

    0,6

    7

    0,6

    7

    0,6

    7

    0,6

    7

    0,6

    7

    0,6

    7

    0,6

    7

    0,6

    7

    0,6

    7

    0,6

    7

    0,6

    7

    0,6

    7

    0,6

    7

    rek

    kra

    ch

    t N

    coupon 1

    coupon 2

    coupon 3

    coupon 4

  • 20

    Ultrasonic measurements

    Method: Ultrasonic measurement

    Inspection locations: horizontal & vertical

    Amount of inspections: one million points

    Inspection results processed statistically

    Representative values: (incl. pitting!)

  • 21

    Corrosion rate in specific

    conditions

    What is the salinity ( fresh, 10 ppm < brackish

  • Contribution of influences

    Causes / influences Fresh Brackish Salt

    1 Electrochem. Corrosion 5% 5% 9%

    2 Biological activities 5% 9% 18%

    3 Galvanic influence 0% 9% 27%

    4 Fabrication 0% 5% 5%

    5 Aeration 5% 5% 9%

    6 Local high waterflow 0% 5% 9%

    7 Vertical salt-fresh layers 0% 5% 0%

    8 Cath. prot. on board of ship 5% 5% 5%

    9 Splash-zone 18% 18% 18%

    Relative Contribution 38% 66% 100%

    Avg. corrosion [mm/50yr] 3,4 5,9 9,0

    Max. corrosion [mm/50yr] 10,3 17,8 27,0

  • Subsets of uniform

    corrosion conditions and

    uniformized

    measurements

    time [yr]

    co

    rro

    sio

    n[m

    m]

    50

    9

    8

    7

    6

    5

    4

    3

    2

    1

    10

    CP + m

    (+c)

    +d + m

    +d + m

    +cp (+c)

    9 corrosion-scales

    Measures:

    d = extra thickness

    m = monitoring

    cp = start with cath. protection

    CP= Cathodic protection

    (c)= coating if needed

    27

    Factor 2.5

    9

    avg

    max.

    Corrosion scales and measures

  • 25

    Overview

    23. ...........

    3. ...................2. Biological activity1. Galvanic working

    0-hypothesis( 9 main causes )

    Probable causesExperts:

    in lab in situMeasurements on

    specific aspects:

    Tuning in practice:

    = uniform group

  • Then from scale to degradation

    Uniform group of measurements are placed on the

    corrosion scales (example: average 1,9 mm after 16

    years)

    26

  • Scale defenition

    0,000

    1,000

    2,000

    3,000

    4,000

    5,000

    6,000

    7,000

    8,000

    9,000

    10,000

    0 2 4 6 8 10 12 14 16 18 20 22 24 26 28 30 32 34 36 38 40 42 44 46 48 50 52 54

    Inspection year

    co

    rro

    sio

    n s

    ca

    lel

    schaal 1

    schaal 2

    schaal 3

    schaal 4

    schaal 5

    schaal 6

    schaal 7

    schaal 8

    schaal 9

    wanddikte

    Then from scale to degradation

  • Then from scale to degradation

    Uniform group of measurements are placed on the

    corrosion scales

    Extrapolation of corrosion within scales (example

    between scale 3 and 4)

    28

  • Standard Corrosion Scales

    0,000

    1,000

    2,000

    3,000

    4,000

    5,000

    6,000

    7,000

    8,000

    9,000

    10,000

    0 2 4 6 8 10 12 14 16 18 20 22 24 26 28 30 32 34 36 38 40 42 44 46 48 50 52 54

    Year

    To

    tal a

    ve

    rag

    e c

    orr

    os

    ion

    [m

    m]

    standard scale 1 Input new Quaywall

    9

    8

    7

    6

    5

    4

    2

    3

    1

    Then from scale to degradation

  • Then from scale to degradation

    Uniform group of measurements are placed on the

    corrosion scales

    Extrapolation of corrosion within scales

    Translation of corrosion to degradation (example

    remaining safety factor 1,30)

    Prediction of remaining lifetime

    30

  • Then from scale to degradation

    Degradatio nline

    1,00

    1,10

    1,20

    1,30

    1,40

    1,50

    1,60

    1,70

    0 2 4 6 8 10 12 14 16 18 20 22 24 26 28 30 32 34 36 38 40 42 44 46 48 50 52 54

    Year

    Safe

    ty f

    acto

    r

    Degradationline

    beheerfase 1

    Beheerfase 2

    Beheerfase 3

    maintenance phase 1

    maintenance phase 2

    maintenance phase 3

  • Input for KMS

    KMS: Quay wall modelling system

    Port of Rotterdam’s next step in asset management

    Supports the asset manager

    Combines technical risk and business value in order to prioritise maintenance measure

    Degradation model is part of KMS

  • Degradation model in KMS

  • Ongoing research to improve the

    steel model

    Research in 2013 A + B + C + D

    Coupon frame Measurement waterconditions Coupontest Galvanostat/Potentostat-measurement

    H1 hypothesis Divice: Hach LangeZ1AL L3 Locations Standard coupons

    Houston O2

    Boston pH exhibition coupons in lab

    Corpus Christy Ec

    Sohar T under variation of:

    P.O.L.B Bart's (Microbiology ) pH

    Rotterdam (reference) TUpper layer O2

    Mid. Layer

    S235JO Sheetpiles

    S465 Piles

    "Bart's test":

    Research on presence on

    Bottom layer sulfate reducer

    Coupontest on site

    USA Sohar and the

    Netherlans (for the

    reference)

    Water measurements:

    O2 - pH - Redox

    EC - temp Lab test

    coupons

    Electrical chemical

    test for

    determination of

    accelerated

    corrosion rates

    Presentation corrosion research

    potentiostat

    device

    coupon weighting and measuring of

    water conditions, is always in

    combination

  • Risks on CP systems

    Unsufficient protection

    Caused by anodes that don’t work properly

    Incomplete coverage of structure

    Caused by mechanical damage

    Decrease of the anode lifetime

    Caused by higher load on anode than designed due to

    changing conditions

    | 37

  • Monitoring of CP systems

    Visual inspections with divers

    mV measurement

    Weighing of anode to measure

    consumption in time

    US thickness measurement

    Condition monitoring

    | 38

  • Monitoring water conditions

    Water conditions determine how

    efficient the system will work

    Monitoring of:

    Conductivity / Salanity

    Temperture of the water

    pH

    Dissolved oxygen

    39

  • Results of monitoring @PoR

    mV is more than sufficient

    Brackish/ fresh water :

    anode consumption is lower

    than in salt conditions

    In salt water, the

    consumption is less at end

    of life of the anode

    Development of anode

    model

    40

  • Thanks for your attention !