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Thermodynamic Processes • States of a thermodynamic system can be changed by interacting with its surrounding through work and heat. When this change occurs in a system, it is said that the system is undergoing a process. • A thermodynamic cycle is a sequence of different processes that begins and ends at the same thermodynamic state.
Power plant, CH. 1, Prepared by DR Assim AL Daraje Introduction to Cycles Analysis
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Different Processes •Some sample processes: Isothermal process: temperature is constant T=C Isobaric process: pressure is constant, P=C Isentropic process: entropy is constant, s=C Isochoric or Isometric Process: Constant-volume process, v=C Adiabatic process: no heat transfer, Q=0, where Q is constant
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1
2 1
1 2
Isothermal process: T=constantEnergy balance U=Q-W, for ideal gas U= H=0since both are functions of temperature only
Q=W, W= P
ln ln
Isobaric process:
mRT dVdV dV mRTV V
V PmRT mRTV P
∆ ∆ ∆
= =
= =
∫ ∫ ∫
→
→2
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2 1 2 1 2 1
2 2 1 1 2 1
P=constant
U=Q-W, W= PdV=P dV=P(V )
( ) ( ) ( )( ) ( )
V
Q U P V V U U P V VU PV U PV H H H
∆ −
= ∆ + − = − + −= + − + = − = ∆
∫ ∫
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Types of Cycles
1- Gas Power Systems – Brayton
2- Heat Engine (Steam plant) –Rankine
3- Internal Combustion Engines – Otto, Diesel, Stirling, Atckison.
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T-v Phase Diagram
Diagram courtesy of Jerry M. Seitzman, 2001. 5
@ Constant Pressure T > Tsat ⇒ “superheated vapor” T = Tsat ⇒ “two-phase liquid-vapor” T < Tsat ⇒ “compressed liquid”
T-v Phase Diagram
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P-v Phase Diagram
@ Constant Temperature P < Psat ⇒ “superheated vapor” P = Psat ⇒ “two-phase liquid-vapor” P > Psat ⇒ “compressed liquid” 7
Saturated Liquid Vapor Mixture (SLVM)
Quality is a function of the horizontal distances on P-v and T-v diagrams
gf
g
vapliq
vap
mmm
mmm
x+
=+
=
mass of vapor
mass of liquid
fg
fmix
fg
fmix
fg
fmix
fg
fmix
vvvv
ssss
hhhh
uuuux
−−
=−−
=−−
=−−
=
Quality:
( )( )
( )( )fgfmix
fgfmix
fgffgfmix
fgffgfmix
vvxvv
uuxuu
ssxsxsss
hhxhxhhh
−+=
−+=
−+=+=
−+=+=
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Property Evaluation Evaluate the remaining properties
– If “superheated vapor,” then go to superheated tables – If “compressed liquid” or “sub-cooled,” then go to
compressed liquid tables • If data does not exist, assume the following: v = vf h = hf u = uf s = sf where the saturated liquid property is evaluated at the
given temperature since pressure does not impact liquids that much
– If “liquid-vapor,” then continue using the “two-phase liquid-vapor” tables and find quality
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Example 1 Given: Steam at 2.0 kPa is saturated at 17.5 oC. In what state will the steam be at 40 oC if
the pressure is 2.0 kPa?
Analysis:
@ P = 2.0 kPa = 0.02 bar, and T = 40oC
Psat > P → “superheated vapor”
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Example - Cont’d Given: Steam initially at 1 MPa and 200 oC expands in a turbine to 40 oC and 83% quality.
What is the change in entropy?
Analysis:
s1 = 6.6940 kJ/kg-K (from superheated table for 1 MPa, 200 oC)
@ 40 oC, s2,f = 0.5725 kJ/kg-K; s2,g = 8.257 kJ/kg-K
s2 = s2,f +x2(s2,g-s2,f)
= 0.5725+0.83*(8.257- 0.5725)
s2 = 6.9506 kJ/kg-K
s2 - s1 = (6.9506 – 6.694) kJ/kg-K
s2 - s1 = 0.2566 kJ/kg-K
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Example 2 Given: A 3 kg mixture of water and water vapor at 70 oC is held at constant pressure while
heat is added. The enthalpy of the water increases by 50 kJ/kg. What is the change in entropy?
Analysis:
∆s = 0.1458 kJ/kg-K
∆s =δQrev
T∫ → ∆s =QTo
=50 kJ/kg
(70 + 273)K
integrate
Heat flow = enthalpy change since
Q = ∆H
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Example 3 Given: 3 kg of steam with a quality of 30% has a pressure of 12.056 bar. At that pressure, the
specific volume of a saturated fluid is vf = 1.5289 cm3/g. The specific volume of the vapor is vg = 14.1889 cm3/g. What is the specific volume of the steam?
Analysis:
vf = 1.5289 cm3/g
vg = 14.1889 cm3/
vmix = vf +x(vg-vf)
= 1.5289 +0.30*(14.1889 - 1.5289) cm3/g
vmix = 5.3269 cm3/g
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Problem 4 Given: 1 kg of steam is initially at 400 oC and 800 kPa. The steam expands adiabatically to
200 oC and 400 kPa in a closed process, performing 450 kJ of work, given the following information. Which law does this process violate: (zeroth law, first law, second law, first and second law)?
at 400 oC and 800 kPa at 200 oC and 400 kPa u = 2959.7 kJ/kg u = 2646.8 kJ/kg h = 3267.1 kJ/kg h = 2860.5 kJ/kg s = 7.5716 kJ/kg-K s = 7.1706 kJ/kg Analysis:
(1) Zeroth law not applicable, does not deal with thermal equilibrium
(2) Check first law
∆E = ∆U + ∆KE + ∆PE = Q − Wnegligible
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