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Power Plants and Incinerators

Power Plants and Incinerators - Dalmia Seven

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Page 1: Power Plants and Incinerators - Dalmia Seven

Power Plants and Incinerators

Page 2: Power Plants and Incinerators - Dalmia Seven

Power Plants and IncInerators

Making the most of scarce resources, preserving the environment, and using energy in an efficient way are the megatrends of our times.

Fluctuating prices

for fossile fuels,

uncertainties about

the usage of nuclear

power, and the threat

of climate change

have led to a global

rethinking of key

questions.

• What are the best sources to provide energy, electricity, and heat?

• How can we regain and maintain economic growth without further damage to the environment?

• And finally, how do we ensure our standard of living for an ever growing population?

Well-constructed

boilers and modern

power plants contribute

valuable energy and

give their share in an

integrated approach to

waste management.

Controlled incineration processes under technically optimized circumstances provide one part of the answer.

DALMIA SEVEN is not only a new name, but a new promise: to bring tradition and innovation together for the purpose of serving the Indian market in an optimal and unprecedented way.It is a joint venture between Dalmia Refractories, India’s trusted and leading refractory maker and Seven Refractories of Europe, a young European manufacturer, which unites innovative technology with multi-national experience across various refractory industries.

DALMIA SEVEN understands your specific requirements and serves them innovatively with the most advanced technology.

Page 3: Power Plants and Incinerators - Dalmia Seven

technIcal facts

Our servicesAside from the high quality and the proven reliability of our products we can support end users and engineering companies with vast knowledge of the application and technical services.

Our solutions for• Grates fired or stoker type

for municipal waste

• Bubbling fluidized beds (BFB)

• Circulating fluidized beds (CFB)

• Pulverized coal fired boilers

• Biomass gasifiers

• Water cooled grates for biomass

• Rotary kiln incinerators

• Waste gas stacks and flares

• LEAF generators (Low emission alternative fuel)

The construction of modern, highly developed boilers is a technical challenge. For decades, boiler manufacturers have pushed the limits of technology, increased efficiency rates and allowed for a wide range of fuels.

The heart of the boiler, the firechamber, is one of the main components to ensure perfect combustion and optimal performance of the appliance. Boilers are lined with a wide range of high performance refractory lining to ensure smooth operations even in high temperatures and other adverse conditions.

As a response to the world demand of energy, more

and more boilers for Power Plants are constructed.

Industrialized nations have realized the benefits of

local power generation and the use of CO2-neutral,

renewable fuels as well as controlled waste incine-

ration.

Refractory products used for power incinerators are developed with a range of adverse conditions to be considered:

• Abrasion resistance

• Thermal shock from sudden and large changes in temperature

• Heat transfer

• Resistance against alkali and other chemicals,

mainly from the variety of fuels

• Corrosion

Continuous measuring of technical data while testing in internal laboratory

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Page 4: Power Plants and Incinerators - Dalmia Seven

Abrasion resistance1.

Thermal shock2.

In the combustion process, various fuels are transformed into ashes and other residues potentially abrasive for the process equipment and refractory lining.

Fluidized bed boilers also add sand into the furnace to promote combustion. The circulation of sand and ashes in the furnace is an important threat to the life of linings and demands optimal refractories to ensure the long lifespan of the furnace.

The lining must properly resist against abrasion at the operative temperature in order to ensure not only their own life but, in particular also protection of furnace water and steam pressure parts where they are installed.

For a specific rating against international requirements resistance of our materials is measured according to ASTM C704 in volume

Uneven operating conditions of boilers and incinerators have a direct impact on the life span of the linings and the furnace in general.

While refractory suppliers always recommend stable conditions, these may not easily be kept within the boiler process.

Several parameters may affect thermal shock resistance.

loss (cm3) after standardized exposure to a stream of SiC abrasive ceramic sand. Materials used in boilers should show losses below 15 cm3, and typically below 10 cm3 for BFB and CFB applications.

For very aggressive abrasion conditions special materials with losses as low as 5 cm3 are available; this can be reached through a balanced combination of aggregate (the coarse grains), matrix (the fine grains) and binding system.

• High conductivity helps reduce gradients across linings which are at the origin of thermal stresses.

• Dimensional stability: materials with small temperature induced dimensional changes develop less thermal stresses.

• Strength helps resist stresses and generally helps withstand thermal shock induced stresses.

• Some aggregates can naturally absorb thermally induced cracks and shocks.

Heat transfer 3.

Linings must comply with the design parameters of boilers and incinerators to ensure that the required heat flow can be extracted from the combustion.

Silicon carbide based materials are normally employed to reach thermal conductivity > 5 W/mK. Values as high as 12 W/mK can be offered in case of need. These values can be achieved by means of a high level of SiC.

A recent trend is to replace thick and high SiC linings with thinner linings of high strength without SiC.

Abrasion in a combustion

chamber

TX

Tinside

QTwall

Twall

wall

Toutside

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Page 5: Power Plants and Incinerators - Dalmia Seven

Refractory attacked by alkali

Refractory NOT attacked by alkali

Resistance against alkali 4.

Among the various corrosion drivers linked to the type of fuels alkali have become the most important because of the increasing use of wastes and new type of fuels: waste polymeric materials, biomass, paper, and industrial sludge are the most critical.

Alkali salts are easily vaporized at normal combustion temperature; in the vapor phase they can penetrate linings, attack them by forming new complex compounds which are normally molten and very sticky or precipitate in lower temperature layers/conditions with consequent local volume increase, degradation of strength and finally spalling of refractories.

Our alkali resistant materials are formulated to be only partially or not affected at all by alkali vapors in the combustion:

1. Reduced open porosity to prevent penetration of alkali

2. SiC doped materials develop a partially oxidized glassy layer which reduces porosity

3. ZrO doped materials react in a controlled way with alkali and develop also a protecting glassy phase layer on the hot face

4. Refractories with a chemically balanced matrix can withstand alkali salts penetration without reacting or being attacked

5. Combinations of some of the above technologies

Corrosion5.

Several types of corrosion may affect furnaces in some areas depending on the type of fuel and on the operative conditions of combustion.

Among others, the following factors are mainly responsible for chemical attacks:

• Carbon monoxide

• Fluorine

• Chlorine

• Sulfur

• Chemical processing wastes

Coarse aggregate is not attacked

Balanced matrix can withstand penetrated alkali without reaction

Reduced pore size ensures less penetration

SiC /ZrO promoted surface passivation prevents alkali penetration

Penetrated alkali condensate in a shallow layer

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Page 6: Power Plants and Incinerators - Dalmia Seven

DALMIA SEVEN offers a wide range of products for roof and wall lining on membrane walls:

• DS Flow 65 NH CO

• DS Flow 51 NM

• DS Flow 75 NR

• DS Flow 92 NB

• DS Flow 70 ND

• DS Gun 85 NX

• DS Trow 85 CX -3

• DS Flow 60 N SiC H -3

• DS Patch 85 C SiC

some key aPPl Icat Ions for cooled Parts

Example of a membrane wall lining arrangement

Gunning installation

Membrane walls are widely used in several type of boilers. They do not need thermal insulation; pressurized steam or water run through pipes and extract heat from the combustion chamber and furnace ducts. Pipes often need protection against abrasion, they are therefore lined with one layer dense material resistant to abrasion. In order to ensure the designed heat flow linings must have limited thickness (30 – 70 mm) and the required thermal conductivity.

Linings must also be able to withstand the furnace burning conditions such as thermal shock, CO, chemical attacks, etc.

Roof and wall lining on membrane wallsThin linings on water and steam cooled pipes are typically applied in different zones on walls or roofs of several types of boilers. Anchors are installed in the form of studs on pipes or small Y or V anchors welded on the fin in between.

Thin linings can be installed by casting self flow castables, by patching or by gunning. Gunning can be an option in the case of walls, but it becomes a preferred solution for roofs because of the convenient installation.

Typical applications involve medium to high alumina products, but also SiC materials are widely used in case high thermal conductivity and slag resistance are required.

Lining by gunning of a membrane wall roof in an incinerator

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Page 7: Power Plants and Incinerators - Dalmia Seven

Fluidized bed combustion chambers

The lower combustion chamber is the area where both air, fuel, sand and limestone are injected into the fluidized bed. The ignition of the boiler is also initiated in this critical zone. Linings are therefore exposed to several types of stresses such as abrasion, thermal shock, reducing atmosphere and chemical attack. Linings in the lower combustion chamber range between 25 and 70 mm, and their construction as well as performance are key to optimal combustion conditions overall.

In the air plenum that feeds the air nozzles there is only limited exposure to high temperature, thermal shock is a main concern and special attention should be placed upon the construction and installation.

Re-lined lower combustion chamber below free board

DS products: Application areas

DS Flow 51 NM lower combustion chamber walls

DS Flow 65 NH CO lower combustion chamber walls

DS Cast 50/55 NM hearth with nozzles, hearth corners, fuel chute

DS Cast 80 NX fuel chute, hearth corners, hearth with nozzles, slag outlet

DS Plast 70 CH CO burner, lower combustion walls

DS Cast 70 NH burner

DS Cast 80 RX 5 slag outlet

DS Flow 60 N SiC H -3 walls

DS 1300 HS plenum

Roof of the air plenum

Color Zones Material type Attention toRoofs with abrasion LC self flowing castable or gunning high abrasion, alkali

Cyclone inlet LC self flowing castable or patching high abrasion, alkaliTarget zone LC self flowing castable or patching extreme abrasion, alkali

Cross over duct LC self flowing castable or gunning some alkaliConv. cage box Self flowing castable or gunning some alkali

Cone LC self flowing castable abrasion, alkaliReturn leg and intrex LC self flowing castable abrasion, alkaliSuperheater & liftleg LC self flowing castable abrasion, alkali

Color Zones Material type Attention toAbrasion roofs LC castable or gunning high abrasion, alkali

Inlet walls LC castable or plastic high abrasion, alkaliTarget zone LC castable, plastic or dense bricks extreme abrasion, alkali

Cone RC or MC castable abrasion, alkaliLoop seal RC or MC castable abrasion, alkaliReturn leg RC or MC castable abrasion, alkaliOutlet duct RC castable or gunning some alkali

Backup insulation, 2nd layer Castable density 0-7 - 0.8 insulationBackup insulation, 3rd layer Thermo insulating board insulation

Color Zones Material type Attention toAbrasion roofs LC castable or gunning high abrasion, alkali

Inlet walls LC castable or plastic high abrasion, alkaliTarget zone LC castable, plastic or dense bricks extreme abrasion, alkali

Cone RC or MC castable abrasion, alkaliLoop seal RC or MC castable abrasion, alkaliReturn leg RC or MC castable abrasion, alkali

Cyclone exit RC castable or gunning some alkaliOutlet duct RC castable or gunning some alkali

Backup insulation, 2nd layer Castable density 0-7 - 0.8 insulationBackup insulation, 3rd layer Thermo insulating board insulation

Color Zones Material type Attention toCombustion rotary chamber LC or UC castable chemical corrosion

Ash hopper RC castable thermal shock, abrasionOutgas duct Insulating castable insulation, strengthInsulation Insulating castable or gunning mix insulation, strength

Color Zones Material type Attention toBurner throat Plastic or LC castable thermal shock

combustion chamber LC castable, gunning mix, plastic abrasion, chemical corrosionroof before baffle Gunning mix or plastic abrasion, chemical corrosion

post combustion chamber after baffle RC or LC castable abrasion, chemical corrosionroof after baffle Gunning mix or plastic abrasion, chemical corrosion

Outgas duct Insulating castable insulationInsulation (2nd layer) Insulating castable or gunning mixInsulation (3rd layer) Insulating board

baffle wall thermal shock

Color Zones Material type Attention toBurner throats Plastic or LC castable high temperature, thermal shock

Combustion chamber walls LC castable with or without SiC or SK 34 bricks alkali attack, thermal shockFuel chute LC castable abrasion

Preheating chamber LC castable with SiC thermal shock, stickingGrate transition LC castable with high SiC slag sticking, abrasion, thermal flow

Combustion chamber roof; neck LC castable or gunning with or without SiC alkali attackUpper walls LC castable or gunning with or without SiC alkali attack

Backup insulation, 2nd layer Insulating castable, density 0.7 - 0.8 insulationBackup insulation, 3rd layer Thermo insulating board insulation

Color Zones Material type Attention toBurner throat Plastic or LC castable thermal shock

Combustion chamber LC castable, gunning mix, plastic abrasion, chemical corrosionRoof before baffle Gunning mix or plastic abrasion, chemical corrosion

Post combustion chamber after baffle RC or LC castable abrasion, chemical corrosionRoof after baffle Gunning mix or plastic abrasion, chemical corrosion

Outgas duct Insulating castable insulationInsulation (2nd layer) Insulating castable or gunning mixInsulation (3rd layer) Insulating board

Baffle wall thermal shock

Color Zones Material type Attention toFuel feeding LC or RC castable abrasion, thermal shock, CO

Lower combustion chamber walls Self flowing or patching abrasion, thermal shock, COHearth with nozzles RC or LC castable abrasion, thermal shock, CO

Hearth corners RC or LC castable abrasion, thermal shock, COBurner LC castable or plastic abrasion, thermal shock, CO

Slag hopper LC castable or plastic or dense bricks abrasionWindbox Medium weight insulating castable, plastic thermal shock

Backup insul. layer 2 Insulating castable, density 0.7 - 0.8 insulation

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Page 8: Power Plants and Incinerators - Dalmia Seven

DS products: Application areas

DS Flow 75 NR target zone, separator inlet

DS Flow 92 NB target zone

DS Flow 51 NM inlet, cone, crossover duct, return duct, intrex, liftleg, convection cage

DS Flow 70 ND inlet, cone, dipleg, intrex

DS Flow 60 N SiC H -3 sloping walls, intrex

DS Gun 85 NX, DS Gun 55 RM, DS Gun 57 RH 01 V CO

roofs of inlet, separator and intrex, crossover duct, convection cage box

DS Gun 50 NM crossover duct, convection cage

DS Trow 85 CX -3 roofs, corners, target zone, intrex

DS Cast 59 ND, DS Cast 99 CF LCS

stripper cooler

tyPIcal key aPPl Icat Ions for uncooled Parts

Color Zones Material type Attention toRoofs with abrasion LC self flowing castable or gunning high abrasion, alkali

Cyclone inlet LC self flowing castable or patching high abrasion, alkaliTarget zone LC self flowing castable or patching extreme abrasion, alkali

Cross over duct LC self flowing castable or gunning some alkaliConv. cage box Self flowing castable or gunning some alkali

Cone LC self flowing castable abrasion, alkaliReturn leg and intrex LC self flowing castable abrasion, alkaliSuperheater & liftleg LC self flowing castable abrasion, alkali

Color Zones Material type Attention toAbrasion roofs LC castable or gunning high abrasion, alkali

Inlet walls LC castable or plastic high abrasion, alkaliTarget zone LC castable, plastic or dense bricks extreme abrasion, alkali

Cone RC or MC castable abrasion, alkaliLoop seal RC or MC castable abrasion, alkaliReturn leg RC or MC castable abrasion, alkaliOutlet duct RC castable or gunning some alkali

Backup insulation, 2nd layer Castable density 0-7 - 0.8 insulationBackup insulation, 3rd layer Thermo insulating board insulation

Color Zones Material type Attention toAbrasion roofs LC castable or gunning high abrasion, alkali

Inlet walls LC castable or plastic high abrasion, alkaliTarget zone LC castable, plastic or dense bricks extreme abrasion, alkali

Cone RC or MC castable abrasion, alkaliLoop seal RC or MC castable abrasion, alkaliReturn leg RC or MC castable abrasion, alkali

Cyclone exit RC castable or gunning some alkaliOutlet duct RC castable or gunning some alkali

Backup insulation, 2nd layer Castable density 0-7 - 0.8 insulationBackup insulation, 3rd layer Thermo insulating board insulation

Color Zones Material type Attention toCombustion rotary chamber LC or UC castable chemical corrosion

Ash hopper RC castable thermal shock, abrasionOutgas duct Insulating castable insulation, strengthInsulation Insulating castable or gunning mix insulation, strength

Color Zones Material type Attention toBurner throat Plastic or LC castable thermal shock

combustion chamber LC castable, gunning mix, plastic abrasion, chemical corrosionroof before baffle Gunning mix or plastic abrasion, chemical corrosion

post combustion chamber after baffle RC or LC castable abrasion, chemical corrosionroof after baffle Gunning mix or plastic abrasion, chemical corrosion

Outgas duct Insulating castable insulationInsulation (2nd layer) Insulating castable or gunning mixInsulation (3rd layer) Insulating board

baffle wall thermal shock

Color Zones Material type Attention toBurner throats Plastic or LC castable high temperature, thermal shock

Combustion chamber walls LC castable with or without SiC or SK 34 bricks alkali attack, thermal shockFuel chute LC castable abrasion

Preheating chamber LC castable with SiC thermal shock, stickingGrate transition LC castable with high SiC slag sticking, abrasion, thermal flow

Combustion chamber roof; neck LC castable or gunning with or without SiC alkali attackUpper walls LC castable or gunning with or without SiC alkali attack

Backup insulation, 2nd layer Insulating castable, density 0.7 - 0.8 insulationBackup insulation, 3rd layer Thermo insulating board insulation

Color Zones Material type Attention toBurner throat Plastic or LC castable thermal shock

Combustion chamber LC castable, gunning mix, plastic abrasion, chemical corrosionRoof before baffle Gunning mix or plastic abrasion, chemical corrosion

Post combustion chamber after baffle RC or LC castable abrasion, chemical corrosionRoof after baffle Gunning mix or plastic abrasion, chemical corrosion

Outgas duct Insulating castable insulationInsulation (2nd layer) Insulating castable or gunning mixInsulation (3rd layer) Insulating board

Baffle wall thermal shock

Color Zones Material type Attention toFuel feeding LC or RC castable abrasion, thermal shock, CO

Lower combustion chamber walls Self flowing or patching abrasion, thermal shock, COHearth with nozzles RC or LC castable abrasion, thermal shock, CO

Hearth corners RC or LC castable abrasion, thermal shock, COBurner LC castable or plastic abrasion, thermal shock, CO

Slag hopper LC castable or plastic or dense bricks abrasionWindbox Medium weight insulating castable, plastic thermal shock

Backup insul. layer 2 Insulating castable, density 0.7 - 0.8 insulation

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Compact separator, dipleg, intex

Cyclones are a challenging refractory application mainly because of abrasion and sometimes also alkali attack. Aside from the materials used, engineering and installation are key elements for good performance.

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Page 9: Power Plants and Incinerators - Dalmia Seven

tyPIcal key aPPl Icat Ions for uncooled Parts

Despite the trend towards full membrane wall systems to extract more heat and thereby increase overall efficiency, traditional uncooled furnace shells are still widely used.

DS products Application areasDS Plast 70 AKX burner throat, uncooled partsDS Plast 70 CH CO burner throat, uncooled partsDS Cast 38 RM 4 uncooled parts, low thermal stressDS Cast 75 RM 4 uncooled parts with thermal stressDS Patch 75/85 C SiC cooled parts, thin linings over tubesDS Cast 57 N SiC 5 slag outlet area

Furnace chamber of pulverized coal fired boilers

This type of furnace for coal burning dominates the electric power industry. Major coal fired plants have increasing size and their pressurized circuits are operated at increasing temperature and pressure.

Limited areas are protected by refractory linings. In any case their reliability is highly important as it may affect operations. The most demanding zones are the slag outlet and the burners where high thermal shock resistance is required.

Pulverized coal boiler improved

These are conditions where thick linings are needed; they normally feature multiple layers, dedicated anchoring, thermal insulation together with the typical properties to withstand the aggressive furnace atmosphere of boilers and incinerators.

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DS Plast

70 AKX

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Page 10: Power Plants and Incinerators - Dalmia Seven

Notice: smaller and newer

units especially for biomass

applications are mostly built

by cooled parts where thin

linings are applied to ensure

protection of pipes against

chemical attack, slag and

abrasion, but also to ensure

the required thermal flow.

Partial re-lining of a grate combustion

DS products: Application areasDS Cast 80 NX fuel chute, grate transition zone exit sideDS Cast 50/55 NM fuel chute, side wall, upper walls, sometimes preheating zoneDS Gun 50 RM 5 upper wallsDS Flow 35 N SIC M -3 upper walls, side wallsDS Cast 65 N SiC -3 grate transition zoneDS Cast 30 N SiC B preheating zone wallDS Cast 30 N SiC D preheating zone wallDS Plast 70 CH CO burner throatDS Cast 70 NH burner throatDS Cast 65 ND/ NX roof and neckDS Flow 50 ND 51 Z roof and neckDS Cast 50 ND 15 Y roof and neckDS Gun 57 RH 01 V CO roof, neck and side wallsDS 1000 insulating back layer

Color Zones Material type Attention toRoofs with abrasion LC self flowing castable or gunning high abrasion, alkali

Cyclone inlet LC self flowing castable or patching high abrasion, alkaliTarget zone LC self flowing castable or patching extreme abrasion, alkali

Cross over duct LC self flowing castable or gunning some alkaliConv. cage box Self flowing castable or gunning some alkali

Cone LC self flowing castable abrasion, alkaliReturn leg and intrex LC self flowing castable abrasion, alkaliSuperheater & liftleg LC self flowing castable abrasion, alkali

Color Zones Material type Attention toAbrasion roofs LC castable or gunning high abrasion, alkali

Inlet walls LC castable or plastic high abrasion, alkaliTarget zone LC castable, plastic or dense bricks extreme abrasion, alkali

Cone RC or MC castable abrasion, alkaliLoop seal RC or MC castable abrasion, alkaliReturn leg RC or MC castable abrasion, alkaliOutlet duct RC castable or gunning some alkali

Backup insulation, 2nd layer Castable density 0-7 - 0.8 insulationBackup insulation, 3rd layer Thermo insulating board insulation

Color Zones Material type Attention toAbrasion roofs LC castable or gunning high abrasion, alkali

Inlet walls LC castable or plastic high abrasion, alkaliTarget zone LC castable, plastic or dense bricks extreme abrasion, alkali

Cone RC or MC castable abrasion, alkaliLoop seal RC or MC castable abrasion, alkaliReturn leg RC or MC castable abrasion, alkali

Cyclone exit RC castable or gunning some alkaliOutlet duct RC castable or gunning some alkali

Backup insulation, 2nd layer Castable density 0-7 - 0.8 insulationBackup insulation, 3rd layer Thermo insulating board insulation

Color Zones Material type Attention toCombustion rotary chamber LC or UC castable chemical corrosion

Ash hopper RC castable thermal shock, abrasionOutgas duct Insulating castable insulation, strengthInsulation Insulating castable or gunning mix insulation, strength

Color Zones Material type Attention toBurner throat Plastic or LC castable thermal shock

combustion chamber LC castable, gunning mix, plastic abrasion, chemical corrosionroof before baffle Gunning mix or plastic abrasion, chemical corrosion

post combustion chamber after baffle RC or LC castable abrasion, chemical corrosionroof after baffle Gunning mix or plastic abrasion, chemical corrosion

Outgas duct Insulating castable insulationInsulation (2nd layer) Insulating castable or gunning mixInsulation (3rd layer) Insulating board

baffle wall thermal shock

Color Zones Material type Attention toBurner throats Plastic or LC castable high temperature, thermal shock

Combustion chamber walls LC castable with or without SiC or SK 34 bricks alkali attack, thermal shockFuel chute LC castable abrasion

Preheating chamber LC castable with SiC thermal shock, stickingGrate transition LC castable with high SiC slag sticking, abrasion, thermal flow

Combustion chamber roof; neck LC castable or gunning with or without SiC alkali attackUpper walls LC castable or gunning with or without SiC alkali attack

Backup insulation, 2nd layer Insulating castable, density 0.7 - 0.8 insulationBackup insulation, 3rd layer Thermo insulating board insulation

Color Zones Material type Attention toBurner throat Plastic or LC castable thermal shock

Combustion chamber LC castable, gunning mix, plastic abrasion, chemical corrosionRoof before baffle Gunning mix or plastic abrasion, chemical corrosion

Post combustion chamber after baffle RC or LC castable abrasion, chemical corrosionRoof after baffle Gunning mix or plastic abrasion, chemical corrosion

Outgas duct Insulating castable insulationInsulation (2nd layer) Insulating castable or gunning mixInsulation (3rd layer) Insulating board

Baffle wall thermal shock

Color Zones Material type Attention toFuel feeding LC or RC castable abrasion, thermal shock, CO

Lower combustion chamber walls Self flowing or patching abrasion, thermal shock, COHearth with nozzles RC or LC castable abrasion, thermal shock, CO

Hearth corners RC or LC castable abrasion, thermal shock, COBurner LC castable or plastic abrasion, thermal shock, CO

Slag hopper LC castable or plastic or dense bricks abrasionWindbox Medium weight insulating castable, plastic thermal shock

Backup insul. layer 2 Insulating castable, density 0.7 - 0.8 insulation

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Stoker type and grate combustion chambers

Stoker and grate furnaces are typically used to produce energy from waste under strictly controlled conditions.

These incinerators are widely operated, especially for high capacities, and the optimal construction of the lining is a cornerstone to ensure optimal working conditions.

Several configurations are available according to the design of the different engineering companies.

High SiC content and low porosity materials are normally recommended by the engineering companies especially to reduce the sticking in the grate transition or on the walls and also to ensure heat extraction. Other possible issues in the lower part of the combustion chamber are abrasive wear and water steam while alkali attack may appear in the linings above.

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Page 11: Power Plants and Incinerators - Dalmia Seven

The older generation of separators in CFB are uncooled and lined with thick linings either by bricks or monolithic refractories. Even though membrane walls become more and more popular, several traditional cyclones are still built and regularly operated nowadays.

DS products Application areasDS Cast 80 NX inlet walls, target zone , loop sealDS Cast 52 RM inlet floor, cone, loop seal, outlet ductDS Cast 50 NM inlet floor, cone, loop seal, return legDS Cast 58 NM roof, cyclone inlet, cyclone drumDS Cast 43 RM 5 -10 outlet ductDS Gun 85 NX, DS Gun 55 RM, DS Gun 57 RH 01 V CO

roofs, inlet walls, cyclone drum, cyclone exit

DS Gun 47 RM 5 roofs, outlet ductDS Trow 85 CX -3 target zone, high abrasionDS Plast 70 CH CO cyclone drum, inlet, exit, loop sealDS 1000 insulating back layer

Lining of the cyclone

In loop seal and return leg temperatures are lower than in combustion chambers and separators, but due to concentration of sand and ashes abrasion and alkali are still an issue.

From cyclone to loop seal

Cyclones, loop seal and return leg with thick linings

Color Zones Material type Attention toRoofs with abrasion LC self flowing castable or gunning high abrasion, alkali

Cyclone inlet LC self flowing castable or patching high abrasion, alkaliTarget zone LC self flowing castable or patching extreme abrasion, alkali

Cross over duct LC self flowing castable or gunning some alkaliConv. cage box Self flowing castable or gunning some alkali

Cone LC self flowing castable abrasion, alkaliReturn leg and intrex LC self flowing castable abrasion, alkaliSuperheater & liftleg LC self flowing castable abrasion, alkali

Color Zones Material type Attention toAbrasion roofs LC castable or gunning high abrasion, alkali

Inlet walls LC castable or plastic high abrasion, alkaliTarget zone LC castable, plastic or dense bricks extreme abrasion, alkali

Cone RC or MC castable abrasion, alkaliLoop seal RC or MC castable abrasion, alkaliReturn leg RC or MC castable abrasion, alkaliOutlet duct RC castable or gunning some alkali

Backup insulation, 2nd layer Castable density 0-7 - 0.8 insulationBackup insulation, 3rd layer Thermo insulating board insulation

Color Zones Material type Attention toAbrasion roofs LC castable or gunning high abrasion, alkali

Inlet walls LC castable or plastic high abrasion, alkaliTarget zone LC castable, plastic or dense bricks extreme abrasion, alkali

Cone RC or MC castable abrasion, alkaliLoop seal RC or MC castable abrasion, alkaliReturn leg RC or MC castable abrasion, alkali

Cyclone exit RC castable or gunning some alkaliOutlet duct RC castable or gunning some alkali

Backup insulation, 2nd layer Castable density 0-7 - 0.8 insulationBackup insulation, 3rd layer Thermo insulating board insulation

Color Zones Material type Attention toCombustion rotary chamber LC or UC castable chemical corrosion

Ash hopper RC castable thermal shock, abrasionOutgas duct Insulating castable insulation, strengthInsulation Insulating castable or gunning mix insulation, strength

Color Zones Material type Attention toBurner throat Plastic or LC castable thermal shock

combustion chamber LC castable, gunning mix, plastic abrasion, chemical corrosionroof before baffle Gunning mix or plastic abrasion, chemical corrosion

post combustion chamber after baffle RC or LC castable abrasion, chemical corrosionroof after baffle Gunning mix or plastic abrasion, chemical corrosion

Outgas duct Insulating castable insulationInsulation (2nd layer) Insulating castable or gunning mixInsulation (3rd layer) Insulating board

baffle wall thermal shock

Color Zones Material type Attention toBurner throats Plastic or LC castable high temperature, thermal shock

Combustion chamber walls LC castable with or without SiC or SK 34 bricks alkali attack, thermal shockFuel chute LC castable abrasion

Preheating chamber LC castable with SiC thermal shock, stickingGrate transition LC castable with high SiC slag sticking, abrasion, thermal flow

Combustion chamber roof; neck LC castable or gunning with or without SiC alkali attackUpper walls LC castable or gunning with or without SiC alkali attack

Backup insulation, 2nd layer Insulating castable, density 0.7 - 0.8 insulationBackup insulation, 3rd layer Thermo insulating board insulation

Color Zones Material type Attention toBurner throat Plastic or LC castable thermal shock

Combustion chamber LC castable, gunning mix, plastic abrasion, chemical corrosionRoof before baffle Gunning mix or plastic abrasion, chemical corrosion

Post combustion chamber after baffle RC or LC castable abrasion, chemical corrosionRoof after baffle Gunning mix or plastic abrasion, chemical corrosion

Outgas duct Insulating castable insulationInsulation (2nd layer) Insulating castable or gunning mixInsulation (3rd layer) Insulating board

Baffle wall thermal shock

Color Zones Material type Attention toFuel feeding LC or RC castable abrasion, thermal shock, CO

Lower combustion chamber walls Self flowing or patching abrasion, thermal shock, COHearth with nozzles RC or LC castable abrasion, thermal shock, CO

Hearth corners RC or LC castable abrasion, thermal shock, COBurner LC castable or plastic abrasion, thermal shock, CO

Slag hopper LC castable or plastic or dense bricks abrasionWindbox Medium weight insulating castable, plastic thermal shock

Backup insul. layer 2 Insulating castable, density 0.7 - 0.8 insulation

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Upper cyclone

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Page 12: Power Plants and Incinerators - Dalmia Seven

DS products Application areasDS Cast 88 NR 03 W rotary kiln, waste gas ductDS Cast 50 ND 15 Y rotary kilnDS Cast 75 NR 04 Y rotary kilnDS Shot 50 ND 15 Y rotary kiln, waste duct DS Shot 51 NH 01 X CO rotary kiln, waste duct DS Cast 50 NM slag hopperDS 1000 insulating back layer

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Color Zones Material type Attention toRoofs with abrasion LC self flowing castable or gunning high abrasion, alkali

Cyclone inlet LC self flowing castable or patching high abrasion, alkaliTarget zone LC self flowing castable or patching extreme abrasion, alkali

Cross over duct LC self flowing castable or gunning some alkaliConv. cage box Self flowing castable or gunning some alkali

Cone LC self flowing castable abrasion, alkaliReturn leg and intrex LC self flowing castable abrasion, alkaliSuperheater & liftleg LC self flowing castable abrasion, alkali

Color Zones Material type Attention toAbrasion roofs LC castable or gunning high abrasion, alkali

Inlet walls LC castable or plastic high abrasion, alkaliTarget zone LC castable, plastic or dense bricks extreme abrasion, alkali

Cone RC or MC castable abrasion, alkaliLoop seal RC or MC castable abrasion, alkaliReturn leg RC or MC castable abrasion, alkaliOutlet duct RC castable or gunning some alkali

Backup insulation, 2nd layer Castable density 0-7 - 0.8 insulationBackup insulation, 3rd layer Thermo insulating board insulation

Color Zones Material type Attention toAbrasion roofs LC castable or gunning high abrasion, alkali

Inlet walls LC castable or plastic high abrasion, alkaliTarget zone LC castable, plastic or dense bricks extreme abrasion, alkali

Cone RC or MC castable abrasion, alkaliLoop seal RC or MC castable abrasion, alkaliReturn leg RC or MC castable abrasion, alkali

Cyclone exit RC castable or gunning some alkaliOutlet duct RC castable or gunning some alkali

Backup insulation, 2nd layer Castable density 0-7 - 0.8 insulationBackup insulation, 3rd layer Thermo insulating board insulation

Color Zones Material type Attention toCombustion rotary chamber LC or UC castable chemical corrosion

Ash hopper RC castable thermal shock, abrasionOutgas duct Insulating castable insulation, strengthInsulation Insulating castable or gunning mix insulation, strength

Color Zones Material type Attention toBurner throat Plastic or LC castable thermal shock

combustion chamber LC castable, gunning mix, plastic abrasion, chemical corrosionroof before baffle Gunning mix or plastic abrasion, chemical corrosion

post combustion chamber after baffle RC or LC castable abrasion, chemical corrosionroof after baffle Gunning mix or plastic abrasion, chemical corrosion

Outgas duct Insulating castable insulationInsulation (2nd layer) Insulating castable or gunning mixInsulation (3rd layer) Insulating board

baffle wall thermal shock

Color Zones Material type Attention toBurner throats Plastic or LC castable high temperature, thermal shock

Combustion chamber walls LC castable with or without SiC or SK 34 bricks alkali attack, thermal shockFuel chute LC castable abrasion

Preheating chamber LC castable with SiC thermal shock, stickingGrate transition LC castable with high SiC slag sticking, abrasion, thermal flow

Combustion chamber roof; neck LC castable or gunning with or without SiC alkali attackUpper walls LC castable or gunning with or without SiC alkali attack

Backup insulation, 2nd layer Insulating castable, density 0.7 - 0.8 insulationBackup insulation, 3rd layer Thermo insulating board insulation

Color Zones Material type Attention toBurner throat Plastic or LC castable thermal shock

Combustion chamber LC castable, gunning mix, plastic abrasion, chemical corrosionRoof before baffle Gunning mix or plastic abrasion, chemical corrosion

Post combustion chamber after baffle RC or LC castable abrasion, chemical corrosionRoof after baffle Gunning mix or plastic abrasion, chemical corrosion

Outgas duct Insulating castable insulationInsulation (2nd layer) Insulating castable or gunning mixInsulation (3rd layer) Insulating board

Baffle wall thermal shock

Color Zones Material type Attention toFuel feeding LC or RC castable abrasion, thermal shock, CO

Lower combustion chamber walls Self flowing or patching abrasion, thermal shock, COHearth with nozzles RC or LC castable abrasion, thermal shock, CO

Hearth corners RC or LC castable abrasion, thermal shock, COBurner LC castable or plastic abrasion, thermal shock, CO

Slag hopper LC castable or plastic or dense bricks abrasionWindbox Medium weight insulating castable, plastic thermal shock

Backup insul. layer 2 Insulating castable, density 0.7 - 0.8 insulation

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Kilns of rotary type incineratorsThis type of incinerator is widely used to burn industrial wastes such as dirty soils, hazardous materials and pharmaceutical wastes. The choice of linings depends on the type of waste and their behavior during incineration.

4.

Seven Refractories packaging machine

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Page 13: Power Plants and Incinerators - Dalmia Seven

Aggresive applications for fluoride and/or chloride wastes:DS Cast 98 URDS Plast 90 AKR DS Cast 95 RBB LW

DS products Application areasDS Plast 70 AKX burner throat, combustion chamber, roofDS Cast 65 NX combustion chamber, baffle wallDS Cast 70 NH baffle wall, burner throatDS Cast 52 RM combustion chamber after baffleDS Gun 60 ND roof before baffleDS Gun 47 RM 5, DS Gun 55 RM

roof after baffle

DS 1300, 1100 LD

Color Zones Material type Attention toRoofs with abrasion LC self flowing castable or gunning high abrasion, alkali

Cyclone inlet LC self flowing castable or patching high abrasion, alkaliTarget zone LC self flowing castable or patching extreme abrasion, alkali

Cross over duct LC self flowing castable or gunning some alkaliConv. cage box Self flowing castable or gunning some alkali

Cone LC self flowing castable abrasion, alkaliReturn leg and intrex LC self flowing castable abrasion, alkaliSuperheater & liftleg LC self flowing castable abrasion, alkali

Color Zones Material type Attention toAbrasion roofs LC castable or gunning high abrasion, alkali

Inlet walls LC castable or plastic high abrasion, alkaliTarget zone LC castable, plastic or dense bricks extreme abrasion, alkali

Cone RC or MC castable abrasion, alkaliLoop seal RC or MC castable abrasion, alkaliReturn leg RC or MC castable abrasion, alkaliOutlet duct RC castable or gunning some alkali

Backup insulation, 2nd layer Castable density 0-7 - 0.8 insulationBackup insulation, 3rd layer Thermo insulating board insulation

Color Zones Material type Attention toAbrasion roofs LC castable or gunning high abrasion, alkali

Inlet walls LC castable or plastic high abrasion, alkaliTarget zone LC castable, plastic or dense bricks extreme abrasion, alkali

Cone RC or MC castable abrasion, alkaliLoop seal RC or MC castable abrasion, alkaliReturn leg RC or MC castable abrasion, alkali

Cyclone exit RC castable or gunning some alkaliOutlet duct RC castable or gunning some alkali

Backup insulation, 2nd layer Castable density 0-7 - 0.8 insulationBackup insulation, 3rd layer Thermo insulating board insulation

Color Zones Material type Attention toCombustion rotary chamber LC or UC castable chemical corrosion

Ash hopper RC castable thermal shock, abrasionOutgas duct Insulating castable insulation, strengthInsulation Insulating castable or gunning mix insulation, strength

Color Zones Material type Attention toBurner throat Plastic or LC castable thermal shock

combustion chamber LC castable, gunning mix, plastic abrasion, chemical corrosionroof before baffle Gunning mix or plastic abrasion, chemical corrosion

post combustion chamber after baffle RC or LC castable abrasion, chemical corrosionroof after baffle Gunning mix or plastic abrasion, chemical corrosion

Outgas duct Insulating castable insulationInsulation (2nd layer) Insulating castable or gunning mixInsulation (3rd layer) Insulating board

baffle wall thermal shock

Color Zones Material type Attention toBurner throats Plastic or LC castable high temperature, thermal shock

Combustion chamber walls LC castable with or without SiC or SK 34 bricks alkali attack, thermal shockFuel chute LC castable abrasion

Preheating chamber LC castable with SiC thermal shock, stickingGrate transition LC castable with high SiC slag sticking, abrasion, thermal flow

Combustion chamber roof; neck LC castable or gunning with or without SiC alkali attackUpper walls LC castable or gunning with or without SiC alkali attack

Backup insulation, 2nd layer Insulating castable, density 0.7 - 0.8 insulationBackup insulation, 3rd layer Thermo insulating board insulation

Color Zones Material type Attention toBurner throat Plastic or LC castable thermal shock

Combustion chamber LC castable, gunning mix, plastic abrasion, chemical corrosionRoof before baffle Gunning mix or plastic abrasion, chemical corrosion

Post combustion chamber after baffle RC or LC castable abrasion, chemical corrosionRoof after baffle Gunning mix or plastic abrasion, chemical corrosion

Outgas duct Insulating castable insulationInsulation (2nd layer) Insulating castable or gunning mixInsulation (3rd layer) Insulating board

Baffle wall thermal shock

Color Zones Material type Attention toFuel feeding LC or RC castable abrasion, thermal shock, CO

Lower combustion chamber walls Self flowing or patching abrasion, thermal shock, COHearth with nozzles RC or LC castable abrasion, thermal shock, CO

Hearth corners RC or LC castable abrasion, thermal shock, COBurner LC castable or plastic abrasion, thermal shock, CO

Slag hopper LC castable or plastic or dense bricks abrasionWindbox Medium weight insulating castable, plastic thermal shock

Backup insul. layer 2 Insulating castable, density 0.7 - 0.8 insulation

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Combustion chambers of flue gas incinerators

Gaseous subproducts of industrial processes must be properly burnt and treated to avoid dangerous emissions. The additional controlled and monitored incineration of flue gas is therefore a common practice for environmental reasons. Dangerous chemicals can be transformed to harmless oxides in this kind of equipment, and the concentrations of dioxins and NOx are reduced to safe levels. This type of incinerator can have different configurations, their combustion chambers are normally static drums, which do not rotate. In the graphs, a horizontal and a vertical configuration are depicted.

The choice of linings depends mainly on the type of chemical contained in the flue gases.

5.

Seven Refractories packaging machine

Detail baffle wall

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Page 14: Power Plants and Incinerators - Dalmia Seven

research and susta Inable develoPment

test Ing Product Ion

Brand name Mineral base Product typeMax. Grain mm

Al₂O₃ % CaO % SiC % (or oth.)

BD 800 °C

g/m³

CCS 800 °C

Mpa

PLC 800 °C

DS Cast 30 N SiC B silicon carbide LCC 6 52.8 2.5 30.8 2.78 60 -0.18DS Cast 30 N SiC D silicon carbide LCC 6 37.0 2.4 30.9 2.53 70 -0.1DS Cast 38 RM 4 chamotte RC 6 38.5 3.1 2.10 45 -0.2DS Cast 43 RM 5 -10 chamotte RC 10 45.7 6.8 2.10 60 -0.15DS Cast 50 ND 15 Y andalusite LCC 6 49 1.2 9.6 2.68 60 -0.05DS Cast 50 NM chamotte LCC 6 49.1 1.7 2.28 75 -0.15DS Cast 55 NM chamotte LCC 6 54.9 2.1 2.34 60 -0.1DS Cast 52 RM chamotte RC 6 47.6 4.3 2.25 65 -0.2DS Cast 57 N SiC 5 silicon carbide LCC 6 20.3 2.5 55.5 2.43 75 -0.15DS Cast 58 NM chamotte LCC 6 58.1 2.4 2.42 75 -0.15DS Cast 59 ND andalusite LCC 6 56.7 2.3 2.38 60 -0.05DS Cast 65 N SiC -3 silicon carbide LCC 3 21.3 1.8 67.2 2.45 80 -0.15DS Cast 65 ND andalusite LCC 6 64.2 1.6 2.46 45 -0.10DS Cast 65 NX bauxite LCC 6 66 2.1 2.47 75 -0.12DS Cast 70 NH high mullite chamotte LCC 6 66.4 1.5 2.62 60 -0.05DS Cast 75 NR 04 Y tabular alumina LCC 6 75.2 1.5 11.9 (ZrO) 2.88* 135* -0.1*DS Cast 75 RM 4 chamotte RC 6 74.2 9.5 2.55 40 -0.15DS Cast 80 NX bauxite LCC 6 80.2 2.6 2.78 115 -0.1DS Cast 80 RX 5 bauxite RC 6 77.2 3.1 2.65 90 -0.15DS Cast 88 NR 03 W tabular alumina LCC 6 88.1 1.5 8.0 (Cr2O3) 3.08 90 -0.05DS Cast 95 RBB LW bubble alumina LW 5 95.9 3.1 1.55 20 -0.2DS Cast 99 CF LCS fused silica no cement 4 99.7 (SiO2) 1.85 60 -0.1DS Cast 98 UR tabular alumina ULCC 6 97.9 0.6 2.9* 100* -0.05*DS Flow 35 N SIC M -3 silicon carbide self flowing 3 33.3 1.8 32.6 2.32 85 -0.2DS Flow 50 ND 51 Z andalusite self flowing 6 55.1 1.5 9.6 /11.9 (ZrO) 2.65 95 -0.05DS Flow 51 NM chamotte self flowing 6 47.6 1.5 2.18 55 -0.15DS Flow 60 N SiC H -3 silicon carbide self flowing 3 30.2 1.8 59.6 2.52 75 -0.2DS Flow 65 NH CO high mullite chamotte self flowing 6 67 2.9 2.43 80 -0.15DS Flow 70 ND andalusite self flowing 6 70 1.5 2.66 100 -0.15DS Flow 75 NR tabular alumina self flowing 6 73.3 1.4 2.64 120 -0.15DS Flow 92 NB brown fused alumina self flowing 6 92.6 1.5 3.1 110 -0.15DS Gun 47 RM 5 chamotte gunning 6 46.2 4.1 2.12 75 -0.15DS Gun 50 NM chamotte gunning 6 51.3 2.2 1.98 75 -0.25DS Gun 50 RM 5 chamotte gunning 6 50.9 9.2 2.1 45 -0.15DS Gun 55 RM chamotte gunning 6 51.7 7.2 2.1 50 -0.2DS Gun 57 RH 01 V CO high mullite chamotte gunning 6 55.7 4.3 5 2.35 80 -0.25DS Gun 60 ND andalusite gunning 6 58.8 2.3 2.48 40 -0.15DS Gun 85 NX bauxite gunning 6 83.8 1.7 2.71 70 -0.25DS 1300 HS light weight raw material LW 4 40.5 13 1.42 20 -0.2DS 1300 light weight raw material LW 6 45 8 1.3 7 -0.2DS 1100 LD light weight raw material LW 4 32 13 0.85 2 -0.3DS 1000 light weight raw material LW 1 25 19 0.9 2 -0.30DS Patch 75 C SiC silicon carbide ramming mix 3 16.3 2.6 (P2O5) 75.4 2.28 80 -0.05DS Patch 85 C SiC silicon carbide ramming mix 3 6.5 2.6 (P2O5) 85 2.27 70 -0.05DS Plast 70 AKX bauxite plastic material 6 69.8 2.4 30 -1.2DS Plast 70 CH CO high mullite chamotte plastic material 6 67.5 3 (P2O5) 2.54 65 -0.6DS Plast 90 AKR tabular alumina plastic material 6 88.4 2.75 40 -1.2DS Shot 50 ND 15 Y andalusite shotcreting 6 47.9 1.2 9.6 / 9.5 (ZrO) 2.7 115 -0.05DS Shot 51 NH 01 X CO high mullite chamotte shotcreting 6 51.5 1.9 14.4 2.47 125 -0.25DS Trow 85 CX -3 bauxite patching/ casting 3 82.6 1.6 (P2O5) 2.8 110 -0.35

green energy

Selection of the raw materials,

dedicated and oriented research,

composition architecture and

on the field technical experts are the

key-points for outstanding efficiency

and reliability of the refractory

linings, excellent control of the

thermal load distribution and low

product variability in time.

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Page 15: Power Plants and Incinerators - Dalmia Seven

• Preliminary study and investigation for the project edition

• Design and architecture, bill of materials, thermal calculation

• Full range of products for lining and maintenance

• Regular, low, ultra-low and no-cement castable

• Regular and dense low-cement gunning mix

• Ramming

• Shotcreting

• Grouting, patching and dry vibrating products

servIces ProvIded

• Supply of mixer, gunning machines, pump, etc.

• Supervision and monitoring by experienced technicians

• Global Research & Development

• Monitoring and targeting of results

• Technical advice from experts

01-2

018

[email protected]

+91 9680774143 | +91 9830525152

Seven Refractories, Karaganda, Kazakhstan

Dalmia Seven Katni, India

IndIa Corporate office:Dalmia Seven Refractories Ltd.4, Scindia House, Connaught PlaceNew Delhi 110001Phone: +91 11 23457100

Plant:Plot No. 8 & 13, Phase-III Lamtara Industrial Area Katni – 483501 Phone: +91 7622 266259, 266306

slovenIaPlant:

Seven Refractories d.o.o.Poslovna cona Risnik 40,6215 DivacaTel. +386 5 739 57 60

kazakhstanPlant:LLP Seven Refractories AsiaQuarter 028, block 1655, Bukhar-Zhirau district100408 Doskey, KaragandaTel. +77 212 404 777

Seven Refractories, Divača, Slovenia