PPTK Haldor Topsoe

8/19/2019 PPTK Haldor Topsoe

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PEMBUATAN AMONIA“HALDOR TOPSOE”

PERANCANGAN PROSES

TEKNIK KIMIA

Andrianno S. U (333513186!Dani"# Pra$o%o (333513&''5!Ua)i Triana L*+i(3335131563!Di)a+ Ro)an,a (333513!

Dari+)an (333513&-'-!Sa)*"# (33351!


2/25

TABEL.1 IMPOR AMONIA INDONESIA

Tahun

Kode HS Deskripsi HS January

Nil!al "#S$%

January&r'()'

"k)%

*e+ruaryNil!al "#S

$%

*e+ruary&r'()'

"k)%

Mar,hNil!al"#S $%

Mar,h&r'()'

"k)%

AprilNil!al"#S $%

-.// -0/1-.....

A22onia in a3ueoussolu'ion

145.6 5/.1 /7.-/ /615 /4818 -0.1 5/058

-./--0/1-....

.A22onia in a3ueous

solu'ion//010 -6/6 4/4-1 1707 45.1. 5-40 4-8/1

-./4-0/1-....

.A22onia in a3ueous

solu'ion88-// 400.1 /01-0 -545 7401/ /80-7 8-1-/

-./1-0/1-....

.A22onia in a3ueous

solu'ion-.7.5 1/45 7087 -058 5747. -.186 /0/08

-./5-0/1-....

.A22onia in a3ueous

solu'ion/750/ /65-7 /8.87 07// /80.4 /-15. //-51

BASIS PRODU/


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April &r'()'"k)%

May Nil!al"#S $%

May&r'()'

"k)%

JuneNil!al"#S $%

June&r'()'

"k)%

JulyNil!al"#S $%

July&r'()'

"k)%

Au)us'Nil!al"#S $%

Au)us'&r'()'

"k)%

Sep'e2+er Nil!al

"#S $%

Sep'e2+er&r'()' "k)%

/8.7- /6-766 //065 560-6 87.5 -67.0 5755 7105 6/6 4.0// /../8

5665 --756 4/1/ 557/4 /8-/. /8..5 48-. /8-00 467/ -778/ -741

47-6/ /.8-168 6-/11 60678 --818 /5750 6014 -8/7/ /408. 15567 -4/0-

6.61 /1580 5-4- --0/0 456- 0-.65 44/5- /.08/ 1.00 /1.5. 711/

/-/0 /1711 /64. /7/-5 40/86 /7.56 087. /.5-/ 7/54 /-/50 /.41/

O,'o+erNil!al "#S $%

O,'o+er&r'()' "k)%

No9e2+erNil!al "#S $%

No9e2+er&r'()' "k)%

De,e2+erNil!al "#S $%

De,e2+er&r'()' "k)%

To'al "#S $% To'al "k)% Toa# (on!

/1.64 -514 ---70 41-. 1/1/5 186. 1805.. 665/8 051-

1/171 /5076 --/78 0/4/ /8814 4451 446857 60141 80'3'

-44/ 401 -16.4 440/7 7584 -066 /578/6/ -615-/ '051

/7.06 -774- 4446. 6/./ /5180 60/1 4//146 /-0586 1805-

/8/81 50.8 /6/01 874. /-615 544/ /0547- /-5857 150-56


4/25

Ta"#. E/SPOR AMONIA INDONESIA

Tahun Kode HS Deskripsi HS January

Nil!al"#S $%

January&r'()'

"k)%

*e+ruary Nil!al"#S $%

*e+ruary

&r'()'"k)%

Mar,hNil!al"#S $%

Mar,h&r'()'

"k)%

AprilNil!al"#S $%

April&r'()'

"k)%

-.// -0/1-..... A22onia ina3ueous solu'ion

. . . . . . . .

-./- -0/1-.....A22onia in

a3ueous solu'ion/ - . . . . . .

-./4 -0/1-.....A22onia in

a3ueous solu'ion. . . . . . . .

-./1 -0/1-.....A22onia in

a3ueous solu'ion604- 1-... . . /..0. 01765 /..0. 01...

-./5 -0/1-.....A22onia in

a3ueous solu'ion/740. /-7... 5477 1/-0. /.8-. 01... 0.11 7/06.


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MayNil!al"#S $%

May&r'()'

"k)%

JuneNil!al"#S $%

June&r'()'

"k)%

JulyNil!al"#S $%

July&r'()'

"k)%

Au)us'Nil!al"#S $%

Au)us'&r'()'

"k)%

Sep'e2+er Nil!al

"#S $%

Sep'e2+er

&r'()'"k)%

O,'o+erNil!al"#S $%

. . . . . . . . . . .

. . . . . . . . . . .

. . . . . . . . . . .

. . 657. 74... -./7. 01... 654. 74... -464. /70... -156.

/7.-6 /-4-0- -6/4 -.06. /7.07 /-461. /4571 /.141. /.1/5 0-7/. /.11-

Tahun

-.//

-./-

-./4

-./1

-./5

O,'o+er&r'()'

"k)%

No9e2+erNil!al "#S

$%

No9e2+er&r'()'

"k)%

De,e2+erNil!al "#S

$%

De,e2+er&r'()'

"k)%

To'al "#S$%

To'al "k)%Toa#(on!

. . . . . . . &

. . . . . / - &0&&

. . . . . . . &

/08... 0/8. 74... -64. -/... /--17- 07/765 861065

0-06. -/.66 /76-0. /4./4 /.4-0. /11.16 //-/1-- 1110'


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Ta"# 3 PRODU/SI AMONIA INDONESIA

No Pa+rik Kapasi'as "'on'ahun%

/ PT Kal'i2 Pasi:k A2oniak

"KPA% 77.;...

- PT Pupuk Ku


7/25

Ke+u'uhan A2onia Dala2 Ne)eri

Ta"# ' /EBUTUHAN AMONIADALAM NE2ERI

TahunI2por

"'on'ahun%Ekspor

"'on'ahun%Produksi dala2 Ne)eri

"'on'ahun%Ke+u'uhan dala2 Ne)eri

"'on'ahun%

-.// 66@5/8 . 5;401;... 5;401;.60

-./- 60@141 [email protected] 5;401;... 5;401;.60

-./4 -61@5-/ . 5;401;... 5;401;-65

-./1 /-0@586 07/@765 5;401;... 5;404;-76

-./5 /-5@857 //-/@1-- 5;401;... 5;404;..5


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-./. -.// -./- -./4 -./1 -./5 -./7

5@40-@...

5@40-@5..

5@404@...

5@404@5..

5@401@...

5@401@5..

"B% > -85;65B 5868.0/;//

R .;70

Daa /"**an A)onia da#a) N"4"ri

Da'a Ke+u'uhan A2onia dala2Ne)eri

Finear "Da'a Ke+u'uhan

A2onia dala2 Ne)eri%

Ta*n

/"**an da#a) N"4"ri (ona*n!

Ta*n/"**an da#a) N"4"ri

(ona*n!

-.-5 540./06@47


9/25

Reaksi


10/25

*ase Reak'an "*luida%


11/25

Sia' *isik dan sia' ki2ia Reak'an

Ma++a "ni+ r"#ai7 &06

Ni#ai /a#or %an4 #"iin44i

-35& a#N)3

P"randin4an*daraaan aar9)3*dara "rada: )3aan aar

1&

S** n%a#a a:i 1-5' o;

/"$":aan N%a#a A:i &0-& )+

a; Gas Ala2


12/25

+; Air"H-O%

/""ran4an Si7a

Massa Molar /0@./54 )2ol

Densi'as dan *ase .@880 ),24"Cair Pada -.oC%.@8- ),24"Pada'%

Ti'ik Fe+ur . oC

Ti'ik Didih /.. oC

Kalor Jenis 1/01 Jk);K "Cair pada -.o

C%

/""ran4an Si7a

Ti'ik Didih 66@47 K@ >/85@68o

C@ >4-.@44o

* Ti'ik Fe+ur 74@/5 K@ >-/. oC@ 417 o*

Massa Jenis ". C@ /./@4-5 kPa% /@-5/ )F

Ti'ik Kri'is /-7@/8 K@ 4@4860 MPa

Kapasi'as Kalor -8@/-1 J2ol K

,; N-


13/25

Si7a Rhodiu2dioksidasi 2en


14/25

Ka'alis

Iron O=id" (


15/25

*lo=,har' Keseluruhan Proses


16/25

*lo=,har' Reor2in)


17/25

HTER


18/25

*lo=,har' Sin'esis A2onia


19/25

Proses Sin'esis A2onia

• Pada proses sin'esis a2onia@ di)unakan ->+ed radial o= ,on9er'er yai'u S>4.. dan S>5. yan) 'elah dike2+an)kan dan

diko2ersilkan;• Den)an 2en))an+un)kan kedua reak'or

'erse+u' 2en)hasilkan e:siensi yan)'in))i;


20/25

Reak'or

S93&& ;on>"r"r

•

Tipe *iBed &ed Rea,'or• Aliran Radial *lo=

• Ka'alis Iron OBide "*eO%

• #2pan N- ")% L H- ")%

•

Te2pera'ur 2asuk 1/.C• Te2pera'ur keluar 188C

• Tekanan Operasi /..>4.. a'2


21/25

• Pada S>4.. ,on9er'er 2e2iliki4>radial o= ,a'alys' +eds dan->in'er+ed hea' eB,han)ers;

• Den)an adanya S>4.. ,on9er'erini@ 9olu2e ka'alis yan)di)unakan dapa' +erkuran)hin))a -. di+andin)kan S>-..

den)an kon9ersi 'an) sa2a;


22/25

Ka'alis


23/25

Pen)e2+an)an Teknolo)i Haldor Topsoe saa' ini


24/25

ATR


25/25

Ta+el Per+andin)an Teknolo)i ATR den)an S'ea2Reor2in)

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PPTK Haldor Topsoe