Present Proposal Updated

8/9/2019 Present Proposal Updated

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The Study ofThe Study ofThe Constituents ofThe Constituents of

AgarwoodAgarwood SmokeSmoke


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The Study of Constitutions ofThe Study of Constitutions of AgarwoodAgarwood SmokeSmoke

Mr.TossanatMr.Tossanat AuttamaprakromAuttamaprakrom 50101101865010110186

Mr.HassalMr.Hassal SamaSama 50101107005010110700

Advisor :Advisor :Asst.Asst. Dr.PakamasDr.Pakamas JaspattananonthJaspattananonth

DepartmentDepartmentofofChemical EngineeringChemical Engineering,,

FFacultyacultyofofEngineering,Engineering,

Prince ofPrince of SongklaSongkla University ,University , HatyaiHatyai Campus.Campus.


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50101101865010110186 50101107005010110700

::....


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(()) (())

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[Resin]

Sesquiterpene alcohol Dihydroagarofuran, b.Agarofuran, a-Agarofuran,Agarospirol Agarol [1]

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71 1


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1. 2.

3.

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1. 2.

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13

18-21 1.5-1.8

5-10


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2 2


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VOCs

2 1.Non-chlorinated VOCs Non-halognated hydrocarbons

(Volatile Organic

Compounds, VOCs) [2]

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(Volatile Organic

Compounds, VOCs) [2]

VOCs VOCs Benzene Hemopoietic system,

red blood cell, nerve Carbon

tetrachloride(CCl4)Liver, CNS

Chloroform(trichlor

omethane, CHCl3)

Liver, Kidney, heart

muscle, eyes, skin

Dichlorobenzene(methylene chloride,DCM)

Liver, kidney, blood,skin, eyes, upperrespiratory tract

-

Ethyl alcohol Liver, CNS nerve,

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1 VOCs


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(Particulate Matter) [3]

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(Particulate Matter) [3]

3 PM10 PM2.5


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SPME

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SPME (SolidPhase

Microextraction) [4] Adsorption / Desorption Solvent Volatile Nonvolatile Headspace

(Volatile Organic 24


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SPME (SolidPhase

Microextraction) [4]

4.1 SPME

25

4.2

SPME


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SPME (SolidPhase


4.3 Solid Phas


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SPME (SolidPhase


4.4 Fiber Holder SPME

:


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SPME (SolidPhase


4.5 Fiber Holder SPME

:


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GC-MS

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-

(Gas Chromatography-MassSpectrometry)[5]

Fingerprint (Massnumber) Library

(Quantitative analysis) (Qualitative analysis) GC-MS 2 GC (Gas

chromatography) Mass30


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:

Gas ChromatographyGas Chromatography (GC)[5]

(Volatile organic compounds) 2

Stationary phase Mobile phase GC 3 1. Injector 2.Oven

3.Detector 31


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5.1Gas Chromatography(GC) 32

:

Gas Chromatography


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:

SpectrometryMassSpectrometer (MS)[5] Detector GC (Mass number)

MS 1.)Ionization Source 2.) Mass Analyzer

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55..22 Mas Mas Spectrometer (MS)Spectrometer (MS) 34

:

Gas Chromatography


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-


5.3 GC: HewlettPackard 5890 Series II MS:

HewlettPackard 5972A 35


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5.4 GC: HewlettPackard 5890 Series II MS:HewlettPackard 5972A

-


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Aquilaria crassna

GC-MS SPME

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66 Aquilaria crassna39


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Thermocouple

Flow Reactor Experiment7

SPME

Polymer

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77..11 Flow Reactor ExperimentFlow Reactor Experiment

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77..22 Tube Furnaceor ElectricTubular FurnaceTube Furnaceor ElectricTubular Furnace

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8.1 HS-SPME Collects volatilesandparticulate[10] 8.2SPME Collects volatiles[10]

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2

/

..52

..52

..52

..53

..53

.53

..53

..53

..53

..53

1. 2. Flow Reactor3. 4. Flow Reactor GC-MS 5.

polymer fusedsilica fiber H/S-SPME GC-MS6.

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()

1 Flow reactorexperiment 4,000

2. HS-SPME Fused Silica Fiber 10,000

3.

GC-MS 3,000 17,000

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[1] . 2532. .Available online: http://www.ton-kla.com/node/59, 14 2552.[2] . 2544. . Availableonline:http://monitor.onep.go.th/document/voc.htm, 22 2552.[3] . 2552. (ParticulateMatter). Available online: http://www.aqnis.pcd.go.th /basic/pollution_pm.htm, 22 2552.[4] . SolidPhase Microextraction (SPME) :E-mail:[email protected],

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[6] , . -/-: : E-mail: [email protected][7] Winyu Chitsamphandhvej. 2005. Qualitative Analysisof Volatile compositions of Dokputhachad (JasminumAuriculatum) by using HS-SPME/GC-MS. 31st Congress onScience and Technology of Thailand. 18 20 October 2005.[8] Hiroaki Takemoto , Michiho Ito Tomohiro ,Shiraki ,Toru Yagura and Gisho Honda. 2006. Sedative effects ofvapor inhalation of agarwood oil and spikenard extract and

(())

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[9] Ajay Dalai, Greg Schoenau, Dharani Das and PhaniAdapa. Volatile Organic Compounds emitted during High-temperature Alfalfa Drying. Biosystems Engineering. 2006:94 (1), 5766.[10] C. Tran and P. J. Marriott. Characterization of incensesmoke by solid phase microextraction-Comprehensive two-dimensional gas chromatography (GC v GC). AtmosphericEnvironment. 2007: 41 5756-5768.[11] Sombat Nopichai, Yuthapong Udnan, Prinya Masawatand Surat Boonphong. 2008.Volatile compounds from

Russula delica Fr. NU Science Journal. 2008: 5(2): 240 247.

(())

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Documents

Present Proposal Updated