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Presentazione di PowerPoint - nanocalibrate.eu Scuola... · [email protected] Researchers PhD Students Tech.&Admin. Staff Others (Prof., Directors) Personnel # Professors 5 Research

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Page 1: Presentazione di PowerPoint - nanocalibrate.eu Scuola... · info@nano-lab.it Researchers PhD Students Tech.&Admin. Staff Others (Prof., Directors) Personnel # Professors 5 Research

www.nano-lab.it

[email protected]

Page 2: Presentazione di PowerPoint - nanocalibrate.eu Scuola... · info@nano-lab.it Researchers PhD Students Tech.&Admin. Staff Others (Prof., Directors) Personnel # Professors 5 Research

www.nano-lab.it

[email protected]

Page 3: Presentazione di PowerPoint - nanocalibrate.eu Scuola... · info@nano-lab.it Researchers PhD Students Tech.&Admin. Staff Others (Prof., Directors) Personnel # Professors 5 Research

Pasqualantonio Pingue

www.nano-lab.it

[email protected]

Page 4: Presentazione di PowerPoint - nanocalibrate.eu Scuola... · info@nano-lab.it Researchers PhD Students Tech.&Admin. Staff Others (Prof., Directors) Personnel # Professors 5 Research

Pasqualantonio Pingue

www.nano-lab.it

[email protected]

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Pasqualantonio Pingue

Page 6: Presentazione di PowerPoint - nanocalibrate.eu Scuola... · info@nano-lab.it Researchers PhD Students Tech.&Admin. Staff Others (Prof., Directors) Personnel # Professors 5 Research

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Pasqualantonio Pingue

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Pasqualantonio Pingue

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Researchers

PhD

Students

Tech.&Admin. Staff

Others (Prof., Directors)

Personnel #

Professors 5

Research Directors 4

Chief Operating Officer 1

Researchers 54

PhDs 38

Administration Staff 7

Tecnical Staff 9

Undergraduate Students 27

145

Pasqualantonio Pingue

Page 9: Presentazione di PowerPoint - nanocalibrate.eu Scuola... · info@nano-lab.it Researchers PhD Students Tech.&Admin. Staff Others (Prof., Directors) Personnel # Professors 5 Research

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Pasqualantonio Pingue

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Pasqualantonio Pingue

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Pasqualantonio Pingue

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Pasqualantonio Pingue

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Pasqualantonio Pingue

Page 14: Presentazione di PowerPoint - nanocalibrate.eu Scuola... · info@nano-lab.it Researchers PhD Students Tech.&Admin. Staff Others (Prof., Directors) Personnel # Professors 5 Research

Pasqualantonio Pingue

270 x 170 pixels10 minutes

nanowire-based detectorgraphene-based detector

THZ IMAGING

Page 15: Presentazione di PowerPoint - nanocalibrate.eu Scuola... · info@nano-lab.it Researchers PhD Students Tech.&Admin. Staff Others (Prof., Directors) Personnel # Professors 5 Research

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Pasqualantonio Pingue

Page 16: Presentazione di PowerPoint - nanocalibrate.eu Scuola... · info@nano-lab.it Researchers PhD Students Tech.&Admin. Staff Others (Prof., Directors) Personnel # Professors 5 Research

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Pasqualantonio Pingue

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Pasqualantonio Pingue

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Lab 0.5

Pasqualantonio Pingue

CBE reactor

Page 19: Presentazione di PowerPoint - nanocalibrate.eu Scuola... · info@nano-lab.it Researchers PhD Students Tech.&Admin. Staff Others (Prof., Directors) Personnel # Professors 5 Research

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Optical image SEM micrograph

Graphene on copper

Pasqualantonio Pingue

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Pasqualantonio Pingue

CVD systems

Page 21: Presentazione di PowerPoint - nanocalibrate.eu Scuola... · info@nano-lab.it Researchers PhD Students Tech.&Admin. Staff Others (Prof., Directors) Personnel # Professors 5 Research

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Pasqualantonio Pingue

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1. Giacobbe F, Monica L, Geraci D. (2009): Risk assessment model of occupational exposure to nanomaterials. Hum. Exp.Toxicol. 28: 401-6;2. Zalk DM, Paik SY, Swuste P (2009) Evaluating the Control Banding Nanotool: a qualitative risk assessment method forcontrolling nanoparticle exposures. J Nanopart. Res. 11:1685–17043. Van Duuren-Stuurman B, Vink SR, Verbist KJM, Heussen HGA, Brouwer DH, Kroese DED, Van Niftrik MFJ, Tielemans E andFransman W (2011) Stoffenmanager Nano version 1.0: a web-based tool for risk prioritization of airborne manufactured nanoobjects. Ann. Occup. Hyg., 1:1–17

Pasqualantonio Pingue

Page 23: Presentazione di PowerPoint - nanocalibrate.eu Scuola... · info@nano-lab.it Researchers PhD Students Tech.&Admin. Staff Others (Prof., Directors) Personnel # Professors 5 Research

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[email protected] assessment for NANOWIRES:different tools different results…

Pasqualantonio Pingue

Risk Assessment

Risk evaluation Global risk Action

28 MEDIUMNecessary but not

urgent

Stoffen Manager Nano Tool 1.0

Task weighted Time and frequency weighted

Hazard class

Exposure classRisk

scoreHazard class Exposure class

Risk score

E 1 I E 2 I

Control Banding

Global Risk Recommended controls Control

RL2Hood or local vacuum

systemNo

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Pasqualantonio Pingue

Department of Occupational and Environmental Medicine, Epidemiology and Hygiene

National Institute for Insurance against Accidents at Work

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[email protected] Banding ISO

Pasqualantonio Pingue

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[email protected] Control Banding Matrix

Pasqualantonio Pingue

Page 27: Presentazione di PowerPoint - nanocalibrate.eu Scuola... · info@nano-lab.it Researchers PhD Students Tech.&Admin. Staff Others (Prof., Directors) Personnel # Professors 5 Research

Case studies

www.nano-lab.it

[email protected] measurements of the exposure

to nanomaterials!

Pasqualantonio Pingue

NanoLab project:• Developing novel tools for risk prevention and safety management of NMs in R&D laboratories, on the basis of a precautionary approachaiming to ensure a safe and successful research on NMs;• Involving researchers in RA on NMs !• Communicate the RA to the workersof the research laboratories.

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Pasqualantonio Pingue

Fast Mobility Particle Sizer

Condensation Particle Counter

Page 29: Presentazione di PowerPoint - nanocalibrate.eu Scuola... · info@nano-lab.it Researchers PhD Students Tech.&Admin. Staff Others (Prof., Directors) Personnel # Professors 5 Research

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Pasqualantonio Pingue

Nano Micro Orifice Uniform Deposit Impactor

Nanoparticle Surface Area Monitor

Fast Mobility Particle Sizer

Hand-held Condensation Particle Counter

IPA Measurement system

Ozone Measurements

Real-time measurements of T, Humidity, Air velocity

Personal Samplers

Page 30: Presentazione di PowerPoint - nanocalibrate.eu Scuola... · info@nano-lab.it Researchers PhD Students Tech.&Admin. Staff Others (Prof., Directors) Personnel # Professors 5 Research

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Pasqualantonio Pingue

Reference Background

Growth in CBE reactor

Sample mounting/unmounting

NWs phases

Page 31: Presentazione di PowerPoint - nanocalibrate.eu Scuola... · info@nano-lab.it Researchers PhD Students Tech.&Admin. Staff Others (Prof., Directors) Personnel # Professors 5 Research

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Pasqualantonio Pingue

Reference Background

Inside the Glove Box

Personal counter (worker)

NWs: Sample Cleavage

PPE & CPE !Personal Protective Equipments

Collective Protective Equipments

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Pasqualantonio Pingue

MATERIALS NEST CB ISO NANOLAB H&S TOOLWorking Phases LAB HB EB CB ISO 2014

NANOWIRES

1 CBE GROWTH 0.5 D-E 3 4 5 3

2 LOADING/UNLOADING SAMPLE 0.5 D-E 3 4 5 4

3 SAMPLE CLEAVAGE 0.5 D-E 2 4 5 3

4 CBE REACTOR CLEANING 0.5 D-E 3 4 5 4 5NANOPARTICLES

1CORE SYNTHESIS in LIQUID 1.9 C 1 2 1

2AGGREGATION in LIQUID 1.9 C 1 2 1

3EXTERNAL SHELL SYNTHESIS in LIQUID 1.9 C 1 2 1

4LYOPHILIZATION PROCESS 1.9 C 1 2 1

GRAPHENE

1SAMPLE PREPARATION 0.3 D 2 4 1

2CVD GROWTH 0.3 D 4 5 1

3CVD REACTOR CLEANING 0.3 D 3 4 2

4CVD PARTS CLEANING in a OVEN 0.3 D 2 4 1

CONTROL BANDING NANOTOOL ISO 2014 = CB ISO

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Pasqualantonio Pingue

MATERIALS NEST CB ISO NANOLAB H&S TOOLWorking Phases LAB HB EB CB ISO 2014

NANOWIRES

1 CBE GROWTH 0.5 D-E 3 4 5 3

2 LOADING/UNLOADING SAMPLE 0.5 D-E 3 4 5 4

3 SAMPLE CLEAVAGE 0.5 D-E 2 4 5 3

4 CBE REACTOR CLEANING 0.5 D-E 3 4 5 4 5NANOPARTICLES

1CORE SYNTHESIS in LIQUID 1.9 C 1 2 1

2AGGREGATION in LIQUID 1.9 C 1 2 1

3EXTERNAL SHELL SYNTHESIS in LIQUID 1.9 C 1 2 1

4LYOPHILIZATION PROCESS 1.9 C 1 2 1

GRAPHENE

1SAMPLE PREPARATION 0.3 D 2 4 1

2CVD GROWTH 0.3 D 4 5 1

3CVD REACTOR CLEANING 0.3 D 3 4 2

4CVD PARTS CLEANING in a OVEN 0.3 D 2 4 1

CONTROL BANDING NANOTOOL ISO 2014 = CB ISO

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Pasqualantonio Pingue

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Pasqualantonio Pingue

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Page 37: Presentazione di PowerPoint - nanocalibrate.eu Scuola... · info@nano-lab.it Researchers PhD Students Tech.&Admin. Staff Others (Prof., Directors) Personnel # Professors 5 Research

“The concentrations measured in the city of Pisa were about 4 times higher than the

seaside resort of Marina di Pisa. Cars, buses, scooters, smokers and exhaust power

generator could be identified as typical local sources of particulates in the city, where

exposure concentrations have reached short-term peaks of > 1,000,000 1/cm³.”

Persönliche Exposition gegenüber ultrafeinen Partikeln im Alltag - eine Pisa Studie Christof Asbach, Ana Maria Todea: Institut für Energie- und Umwelttechnik e.V. (IUTA), DUISBURG (GER)

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Pasqualantonio Pingue: [email protected]