25
Presenter :Yu-Cheng Cheng Date:2015/6/11

Presenter :Yu-Cheng Cheng Date:2015/6/11. OUTLINE Introduction Experimental Results and discussion Conclusion 1

Embed Size (px)

Citation preview

Page 1: Presenter :Yu-Cheng Cheng Date:2015/6/11. OUTLINE  Introduction  Experimental  Results and discussion  Conclusion 1

Presenter :Yu-Cheng Cheng

Date:2015/6/11

Page 2: Presenter :Yu-Cheng Cheng Date:2015/6/11. OUTLINE  Introduction  Experimental  Results and discussion  Conclusion 1

2

OUTLINE

Introduction

Experimental

Results and discussion

Conclusion

Page 3: Presenter :Yu-Cheng Cheng Date:2015/6/11. OUTLINE  Introduction  Experimental  Results and discussion  Conclusion 1

3

Introduction

Ultrahigh molecular weight polyethylene (UHMWPE) fiber is a new kind of high performance fiber developed in the recent two decades.

Its distinctive properties are low friction coefficient, high wear resistance, high mechanical properties and, especially high strength can be reached by the UHMWPE fiber due to orientation of its very long polymeric chains.

Page 4: Presenter :Yu-Cheng Cheng Date:2015/6/11. OUTLINE  Introduction  Experimental  Results and discussion  Conclusion 1

4

OUTLINE

Introduction

Experimental

Results and discussion

Conclusion

Page 5: Presenter :Yu-Cheng Cheng Date:2015/6/11. OUTLINE  Introduction  Experimental  Results and discussion  Conclusion 1

5

Experimental

Materials

Experimental Setup

Sample Preparation

Page 6: Presenter :Yu-Cheng Cheng Date:2015/6/11. OUTLINE  Introduction  Experimental  Results and discussion  Conclusion 1

6

Materials

UHMWPE powder

1,2-Dichloroethane

Cyclopentane

Irganox 1010

Page 7: Presenter :Yu-Cheng Cheng Date:2015/6/11. OUTLINE  Introduction  Experimental  Results and discussion  Conclusion 1

7

Materials

UHMWPE powder

1,2-Dichloroethane

Cyclopentane

Irganox 1010

Page 8: Presenter :Yu-Cheng Cheng Date:2015/6/11. OUTLINE  Introduction  Experimental  Results and discussion  Conclusion 1

8

Materials

UHMWPE powder

1,2-Dichloroethane

Cyclopentane

Irganox 1010

Page 9: Presenter :Yu-Cheng Cheng Date:2015/6/11. OUTLINE  Introduction  Experimental  Results and discussion  Conclusion 1

9

Materials

UHMWPE powder

1,2-Dichloroethane

Cyclohexane

Irganox 1010

Page 10: Presenter :Yu-Cheng Cheng Date:2015/6/11. OUTLINE  Introduction  Experimental  Results and discussion  Conclusion 1

10

Experimental

Materials

Experimental Setup

Page 11: Presenter :Yu-Cheng Cheng Date:2015/6/11. OUTLINE  Introduction  Experimental  Results and discussion  Conclusion 1

11

Experimental Setup

UHMWPE powder

Autoclave

Cyclohexane

Irganox 1010CO2

O2 Steel nozzle

Page 12: Presenter :Yu-Cheng Cheng Date:2015/6/11. OUTLINE  Introduction  Experimental  Results and discussion  Conclusion 1

12

OUTLINE

Introduction

Experimental

Results and discussion

Conclusion

Page 13: Presenter :Yu-Cheng Cheng Date:2015/6/11. OUTLINE  Introduction  Experimental  Results and discussion  Conclusion 1

13

Results and discussion

Structural transformation

SEM

DSC

XRD

Mechanical properties

Page 14: Presenter :Yu-Cheng Cheng Date:2015/6/11. OUTLINE  Introduction  Experimental  Results and discussion  Conclusion 1

14

Structural transformation

Structural transformation of (a) FS-F and (b) GS-F

Page 15: Presenter :Yu-Cheng Cheng Date:2015/6/11. OUTLINE  Introduction  Experimental  Results and discussion  Conclusion 1

15

Results and discussion

Structural transformation

SEM

DSC

XRD

Mechanical properties

Page 16: Presenter :Yu-Cheng Cheng Date:2015/6/11. OUTLINE  Introduction  Experimental  Results and discussion  Conclusion 1

16

SEM

Fig. 2(a) not a single one but a bunch of thinner fibers.Fig. 2(b) with smooth surface, round shape and some crevices could be observed.

Page 17: Presenter :Yu-Cheng Cheng Date:2015/6/11. OUTLINE  Introduction  Experimental  Results and discussion  Conclusion 1

17

Results and discussion

Structural transformation

SEM

DSC

XRD

Mechanical properties

Page 18: Presenter :Yu-Cheng Cheng Date:2015/6/11. OUTLINE  Introduction  Experimental  Results and discussion  Conclusion 1

18

DSC

The melting point of the raw material powder was 142.0 °C.

Page 19: Presenter :Yu-Cheng Cheng Date:2015/6/11. OUTLINE  Introduction  Experimental  Results and discussion  Conclusion 1

19

Results and discussion

Structural transformation

SEM

DSC

XRD

Mechanical properties

Page 20: Presenter :Yu-Cheng Cheng Date:2015/6/11. OUTLINE  Introduction  Experimental  Results and discussion  Conclusion 1

20

XRD

The prominent peaks located at 19.4°, 21.5°, and 23.9°were corresponding to (100), (110) and (200) crystal lattice planes of UHMWPE, respectively.

Page 21: Presenter :Yu-Cheng Cheng Date:2015/6/11. OUTLINE  Introduction  Experimental  Results and discussion  Conclusion 1

21

Results and discussion

Structural transformation

SEM

DSC

XRD

Mechanical properties

Page 22: Presenter :Yu-Cheng Cheng Date:2015/6/11. OUTLINE  Introduction  Experimental  Results and discussion  Conclusion 1

22

Mechanical properties

It can be concluded that the breaking strength and Young׳s modulus of FS-F were significantly lower while the breaking elongation of FS-F was higher than the GS-F׳s.

Page 23: Presenter :Yu-Cheng Cheng Date:2015/6/11. OUTLINE  Introduction  Experimental  Results and discussion  Conclusion 1

23

OUTLINE

Introduction

Experimental

Results and discussion

Conclusion

Page 24: Presenter :Yu-Cheng Cheng Date:2015/6/11. OUTLINE  Introduction  Experimental  Results and discussion  Conclusion 1

24

Conclusion The UHMWPE microfiber was successfully

fabricated by flash-spinning using 1,2-Dichloroethane and cyclopentane as solvent.

The FS-F had lower strength and modulus, which was still higher than most of the other polymer fibers, but higher specific surface area and breaking elongation than the GS-F׳s.

The exactly intrinsic characteristic proved the FS-F to be suitable for various potential applications such as filter, microsensors, protective clothing and so on.

Page 25: Presenter :Yu-Cheng Cheng Date:2015/6/11. OUTLINE  Introduction  Experimental  Results and discussion  Conclusion 1

25

Thank you for your attention