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Properties of X-Rays
Reference:
“Elements of X-ray Diffraction”, 3nd Edition, B.D. Cullity,and S.R. Stock, Prentice Hall, NJ 2001. -- Chapter 1
http://en.wikipedia.org/wiki/X-rayhttp://chemistry.tutorvista.com/nuclear-chemistry/x-rays.html#
X-ray source:
Tube source: http://en.wikipedia.org/wiki/X-ray_tube http://www.youtube.com/watch?v=7Shle-b0W0E http://www.youtube.com/watch?v=vruuVFH_Vro&feature=related
Rotation anode source http://en.wikipedia.org/wiki/X-ray_tube http://en.rigaku-mechatronics.com/technology/technology01.html
Synchrotron radiation sourcehttp://www.nsrrc.org.tw/
Liquid metal jet X-ray sourcehttp://www.excillum.com/Technology/metal-jet-technology.html
http://www.arpansa.gov.au/radiationprotection/basics/xrays.cfm
Vacuum, thermionic emission, high voltage, and a target
Braking radiation CharacteristicX-ray
Auger electrons
v
Target
v0
v1
1121
20 /2/2/ hchmvmvE
v2
2222
21 /2/2/ hchmvmvE
Braking radiation:
x
I
Vemv 2/20
swhchmv /2/ max20
V1
V2
V2 > V1
KL M
Characteristic X-ray
KL M
Auger Electrons
Excitationsource
K
L1
L2
L3
K
L1
L2
L3
CharacteristicsX-Ray photon
k
L1
L2
L3
Augerelectron
Radiativetransition
NonradiativetransitionM} {
K K2 K1
K (L) shell excitation K (L) radiation, etc.
331 LKLKK hhWWh
31
111
LKKK
222 LKLKK hhWWh
22
111;
LKKK
I
K
K
Cooling anode Better heat dissipation higher power (applied potential electron beam current (Typical tube source: 50 kV and 40 mA→2 kW
Critical potential Characteristic X-ray
water
http://www.antonine-education.co.uk/Pages/Physics_GCSE/Unit_3/Triple_01_X-rays/triple_01.htm
Rotation Anode SourceRotating the anode more cooling time for the part hitby energetic electrons higher power is allowed!
Rotating anode and cooling higher power
Cr Fe Cu Mo
Z 24 26 29 42
K1, Å 2.2896 1.9360 1.5405 0.70926
K2, Å 2.2935 1.9399 1.5443 0.71354
K, Å 2.2909 1.9373 1.5418 0.71069
K1 , Å 2.0848 1.7565 1.3922 0.63225
, filt. V, 0.4mil Mn, 0.4mil Ni, 0.6 mil Nb, 3mils
, filt. Ti (Z = 22) Cr (Z = 24) Co (Z = 27)
Y (Z = 39)
Resolution, Å 1.15 0.95 0.75 0.35
Critical potential, kV 5.99 7.11 8.98 20.0
Operating conditions, kV: 30-40 35-45 35-45 50-55
Target materials and associated constants
1 mil =0.001 inch = 0.025 mm
Synchrotron radiation source
Lorentz force: )( BvEqF
Electromagnetic radiation produced by relativistic chargedparticles accelerated in circular orbits.
http://www.nsrrc.org.tw/english/lightsource.aspx
http://www.nsrrc.org.tw/english/lightsource.aspx
Undulators ultra-brilliant, single-wavelength radiation from the resulting interference patterns
Absorption:
IdxdI : linear absorption coefficient
)exp(0 xIIdxI
dI I0: X-ray intensity at x = 0
= (/) ; : density;(/): mass absorption coefficient
I0
I
dx
Lambert-Beer law
http://www.helsinki.fi/~serimaa/xray-luento/xray-absorption.html
Reference:
Multicomponent system μ/ρ:For a substance containing several elements
3
33
2
22
1
11 www
wi is the weight fraction of the element i
http://physics.nist.gov/PhysRefData/XrayMassCoef/tab3.html
mm (/): true absorption; (m/): scattering
Small for Z >26
I0
I
Scattering (elastic: same wavelength,Compton scattering: different wavelength )
Fluorescence (longer wavelength)
x
http://www.helsinki.fi/~serimaa/xray-luento/xray-absorption.html
True absorption:
For fluorescent, photoelectron is not necessary as long as the electrons at the ground state are excited to a higher energy level
Sharp discontinuities at K, LI, LII, LIII, M,… absorption edges!
http://www.helsinki.fi/~serimaa/xray-luento/xray-absorption.html
Use of absorption for filtering function
http://www.helsinki.fi/~serimaa/xray-luento/xray-absorption.html
X-Ray detectors:
Proportional Counters ()Microchannel PlatesSemiconductor Detectors () Scintillators () PhosphorsNegative Electron Affinity Detectors (NEADs)Single Photon Calorimeters
http://imagine.gsfc.nasa.gov/docs/science/how_l2/xray_detectors.html
Important aspects of a detector: (1) Losses (2) Efficiency (3) Energy resolution
v
Timev
Time
Random loss(Inevitable)
Serious loss
Losses
v
v
Random losses (always there)
Resolving time of the detector electronic: ts
the maximum rate without losses: 1/ts.Losses as rate .
Quanta Absorbed /second
Qua
nta
Det
ecte
d /s
econ
d
Countingloss
Detector 1
Detector 2 Use filtersNoise?
Efficiency:
fabs,w:
fabs,d: effective excitation ( signals)flosses: counting losses
window
1 1- fabs,w
]1][)1[(production signalfor fraction Effective ,, lossesdabswabs fff
~ 1
Different detector: different wavelength range to detect!
Efficiency of a 10-cm-long gas ionization chamber as a function of energy, for different gases at normal pressure.
For most of the detectors Voltage produced energy of X-ray quanta.
Cou
ntin
g ra
te
Pulse amplitudeV
W
V
WR
R resolution
Resolution
Energy Resolution:
Gas filled detector:Proportional and Geiger counter
RC
Wire anodecathode
X-rays
electron-ion pairs produced:
ie
En E: X-ray energy; ei: effective ionization potential
ei for He, Ar, and Xe: 27.8, 26.4, and 20.8 eV; Using CuK radiation, Ar gas: n = 8040/26.4 = 304
Gain may be defines as
n
NG N: # of electrons reaching wire anode; n: # of electron
produced by X-ray quanta
Typical Gain ~ 104-105.G = 104
Cu radiation on Ar gas filled proportional counter304104 = 3.04106.Typical F 10-10 farad.
V0049.010
106.11004.310
196
C
NeV
Small voltage need further electronic amplification
Bias larger enough (~ several KV) avalanches (G saturated) “Geiger counter” (long deadtime)
Scintillation Counter detector:
http://www.bruker-axs.de/fileadmin/user_upload/xrfintro/sec1_6.html
http://wanda.fiu.edu/teaching/courses/Modern_lab_manual/scintillator.html
Scintillator (usually Tl doped NaI)
UV
photoelectron
http://en.wikipedia.org/wiki/Scintillation_counter
Relatively high count rate detector (>100,000 cps is possible) poor energy resolution
Semiconductor detector:
Find more on:http://wwwmayr.informatik.tu-muenchen.de/konferenzen/Jass04/courses/4/Tobias%20Eggert/TalkIoffe.pdf
Excellent energyresolution
Usually coolingis required!
Reasonable countrate
http://144.206.159.178/ft/787/31793/552178.pdf
Si, Ge semiconductor detector (LN2 cooling required )!Spectrometry application!
For spectrometry application without LN2 coolingSi drift detector
Position sensitive X-Ray detector
Inel
Safety Precautions Electric shock Radiation Hazard: user’s responsibility (your own and others) * Four main causes of accidents (1) Poor equipment configuration, e.g. unused beam ports not covered, interlock system is not engaged. (2) Manipulation of equipment when energized, e.g. adjustment of samples or alignment of optics when x-ray beam is on. (3) Equipment failure, e.g. shutter failure, warning light failure. (4) Inadequate training or violation of procedure
Failure to follow proper procedures has been the result of: rushing to complete a job, fatigue illness, personal problems, lack of communication, or complacency
* Radiological Signs
* Everyone should participate the safety training course offered by the University before actually doing X-ray or other radiation related experiments.