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PTT 205 HEAT AND MASS TRANSFER Heat Exchangers

PTT 205 HEAT AND MASS TRANSFER Heat Exchangersportal.unimap.edu.my/portal/page/portal30/Lecturer Notes... · of a cooler fluid and decrease that of a hotter fluid. 1. ... 1-1 counterflow

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PTT 205

HEAT AND MASS TRANSFER

Heat Exchangers

Heat transfer equipments:

i) Heat exchangers

ii) Evaporators

iii) Dryers

iv) Agitated vessel

Topic Outline

• Types of heat exchangers

• Log Mean Temperature Different (LMTD)

• Correction Factor of LMTD

• Heat Exchanger Effectiveness

• Fouling Factors

• Design of heat exchanger

HEAT EXCHANGERS

• Types of heat exchangers:

1. Double pipe heat exchanger

2. Shell and tube exchanger

3. Plate-type exchanger

4. Crossflow exchanger

• The function of a heat exchanger is to increase the temperature

of a cooler fluid and decrease that of a hotter fluid.

1. Double pipe heat exchanger

• The simplest configuration (Fig 1.1)

• One fluid flow through the inside pipe, and the second fluid

flows through the annular space between the outside and the

inside pipe.

• The fluid can be in co-current or countercurrent flow.

• Useful for small flow rates and when not more than 100 – 150

ft2 of surface is required.

Fig. 1.1 Double pipe heat exchanger

2. Shell and Tube Exchanger

• The most important type of exchanger in use in oil refineries and larger chemical processes and is suited for higher-pressure applications.

• Useful for larger flow rates as compared to double pipe heat exchanger.

• The simplest configuration: 1-1 counterflow exchanger (one shell pass and one tube pass) – refer to Figure 1.2.

• consists of a shell (a large pressure vessel) with a bundle of tubes inside it.

• One fluid runs through the tubes, and another fluid flows over the tubes (through the shell) to transfer heat between the two fluids.

• The cold fluid enters and flow inside through all the tubes in parallel in one pass

• The hot fluid enters at the other end and flow counterflow across the outside the tubes in the shell side.

• Cross-baffles – increase the shell side heat transfer coefficient

Fig 1.2 Shell and tube heat exchanger

(1 shell pass and 1 tube passes (1-1 exchanger))

Fig 1.3 Shell and tube heat exchanger

(1 shell pass and 2 tube passes (1-2 exchanger))

• The liquid on the tube side flows in two passes

• The shell-side liquid flows in one pass

• In the first pass of the tube side, the cold fluid is flowing counterflow to the hot shell-side fluid

• In the second pass of the tube side, the cold fluid flows in parallel (co-current)

Fig 1.4 Shell and tube heat exchanger

(2 shell pass and 4 tube passes (2-4 exchanger))

Fig. 1.5 Shell and tube heat exchanger

Fig. 1.6 Hellical baffle

3. Plate heat exchanger

• Use metal plates to transfer heat between two fluids

• Consist of many corrugated stainless steel sheets separated by polymer gaskets and clamped in a steel frame.

• The corrugation induce turbulence for improve heat transfer

• The space between plates is equal to the depth of the corrugations (2 - 5 mm)

• The plates are compressed in a rigid frame to create an arrangement of parallel flow channels with alternating hot and cold fluids.

• Major advantage over a conventional heat exchanger in that the fluids are exposed to a much larger surface area because the fluids spread out over the plates.

Fig. 1.6 Plate heat exchanger

• A common device used to heat or cool a gas such as air

• One of the fluids, which is a liquid, flows inside through the tubes, and the exterior gas flows across the tube bundle by forced or sometimes natural convection.

4. Cross-flow exchanger

Fig. 1.7 Cross-flow heat exchangers: (a) one fluid mixed (gas) and one fluid unmixed; (b) both fluids unmixed.

• The fluid inside the tubes is considered to be unmixed, since it is

confined and cannot mix with any other stream.

• The gas flow outside the tubes is mixed, since it can move about

freely between the tubes, and there will be a tendency for the gas

temperature to equalize in the direction normal to the flow.

• For the unmixed fluid inside the tubes, there will be a

temperature gradient both parallel and normal to the direction of

flow.

• A second type of cross-flow heat exchanger shown in Fig. 1.7(b)

is typically used in air- conditioning and space-heating

applications.

•In this type the gas flows across a finned-tube bundle and is

unmixed, since it is confined in separate flow channels between

the fins as it passes over the tubes. The fluid in the tubes is

unmixed.

Log Mean Temperature Difference (LMTD)

Correlation Factors

•For counter-current flow, LMTD for 1-1 exchanger with one shell

pass and one tube pass is given by:

Where:

ΔTlm = log mean temperature difference

ΔT1 = T1 - t1

ΔT2 = T2 – t2

T1 = inlet shell-side fluid temperature

T2 = outlet shell-side fluid temperature

t1 = outlet tube-side temperature

t2 = inlet tube-side temperature

T1

t1 T2

t2

Temperature cross

----------------- Eq. (1)

ΔT1 ΔT2

2

1

21

lnT

T

TTTlm

•For co-current flow, LMTD for 1-1 exchanger with one shell pass

and one tube pass is given by:

Where:

ΔTlm = log mean temperature difference

ΔT1 = T1 - t1

ΔT2 = T2 - t2

T1 = inlet shell-side fluid temperature

T2 = outlet shell-side fluid temperature

t1 = inlet tube-side temperature

t2 = outlet tube-side temperature

T1 t1

T2

t2

Temperature cross

----------------- Eq. (2)

2

1

21

lnT

T

TTTlm

ΔT1 ΔT2

Example 1

Water at a rate of 68kg/min is heated from 35 to 75 °C by

an oil having a specific heat of 1.9 kJ/kg.°C. The fluids

are used in a counterflow double-pipe heat exchanger, and

the oil enters the exchangers at 110 ° and leaves at 75 °.

The overall heat-transfer coefficient is 320 W/m2.C.

Calculate the heat exchanger area.

Correction of LMTD in Multipass

Exchanger

• Multipass exchangers have more tube passes than shell passes.

• The LMTD as given in Eq (1 & 2) does not apply in this case

and it is customary to define a correction factor, FT.

• The relationship between LMTD and FT is define as below:

Where is define as the correct mean temperature drop.

• The general equation for heat transfer across surface of an

exchanger is:

lmTm TFT

mT

moomii TAUTAUq

---------------- Eq. (3)

----------------- Eq. (4)

• Figure 4.9-4 (Geankoplis, 4th ed.) shows the correction factor to

LMTD for:

a) 1-2 and 1-4 exchangers

b) 2-4 exchangers

• Two dimensionless ratios are used as follows:

• Using the nomenclature of Eqs. (5 & 6), the of Eq. (1) can be

written as:

cico

hohi

TT

TTZ

cihi

cico

TT

TTY

ciho

cohi

cihocohilm

TT

TT

TTTTT

ln

----------------- Eq. (5 & 6)

---------------- Eq. (7)

Figure 4.9-4(a) Correction factor to LMTD for 1-2 and 1-4 exchangers (Geankoplis, 4th ed.)

Figure 4.9-4(b) Correction factor to LMTD for 2-4 exchangers (Geankoplis, 4th ed.)

Example 2 Temperature Correction Factor for a Heat

Exchanger

A 1-2 heat exchanger containing one shell pass and two tube passes

heats 2.52 kg/s of water from 21.1 to 54.4 0C by using hot water

under pressure entering at 115.6 and leaving at 48.9 0C. The outside

surface area of the tubes in the exchanger is Ao = 9.30 m2.

a) Calculate the mean temperature different ΔTm in the exchanger

and the overall heat transfer coefficient Uo.

b) For the same temperatures but using a 2-4 exchanger, what would

be the ΔTm?

Solution:

The temperatures are as follows:

Thi = 115.6 0C Tho = 48.9 0C Tci = 21.2 0C

Tco = 54.4 0C

Heat balance on the cold water, assume Cpm of water of 4187 J/kg.K

and Tco – Tci = (54.4 – 21.1) 0C = 33.3 0C = 33.3 K

q = mCpm(Tco – Tci) = (2.52)(4187)(54.4 – 21.1) = 348 200 W

The log mean temperature difference using Eq. (1) is

Calculate the Z and Y values using Eq (5 & 6)

KCTlm 3.423.42

1.219.48

4.546.115ln

1.219.484.546.115

From Figure 4.9-4(a), FT = 0.74

Using Eq. (3),

Rearranging Eq. (4) to solve for Uo and substituting the known

values, we have

b) for 2-4 exchanger, refer to Fig. 4.9-4(b), FT = 0.94, Then,

Hence, in this case the 2-4 exchanger utilizes more of the

available temperature driving force.

KCTFT mTm 3.313.31)3.42(74.0

F).bu/h.ft (211.K W/m1196)3.31)(30.9(

348200 o22

mo

oTA

qU

K 8.39C8.39)3.42(94.0 lmTm TFT

Heat Exchanger Effectiveness – NTU Method

•The LMTD is used in equation if the inlet and outlet temperatures of the two fluids are known and can be determined by a heat balance.

•The surface area can be determined if U is known.

•However, when the temperature of the fluids leaving the exchanger are not known, the tedious trial-and-error procedure is necessary.

•To solve these cases, a method called the heat exchanger effectiveness is used which does not involve any of the outlet temperatures.

•The Effectiveness – NTU (Number of Transfer Unit) method is a procedure for evaluating the performance of heat exchangers if heat transfer area, A and construction details are known .

lmTUAq

•Heat balance for the cold (C ) and hot (H ) fluids is:

•Calling

, then CH > CC

•Designate CC as Cmin or minimum heat capacity.

•If there is an infinite area available for heat transfer, TCo = THi , the effectiveness ε is

•If the hot fluid is the minimum fluid, THo = TCi , and

)(

)(

)(

)(

min

max

CiHi

HoHi

CiHiC

HoHiH

TTC

TTC

TTC

TTC

)(

)(

)(

)(

min

max

CiHi

CiCo

CiHiH

CiCoC

TTC

TTC

TTC

TTC

)()()()( CoCiCpHoHiHp TTmCTTmCq ----------- Eq. (8)

CCp

HHp

CmC

CmC

)(

)(

----------- Eq. (10)

----------- Eq. (9)

• In both equations the denominators are the same and the

numerator gives the actual heat transfer:

• Note that Eq. (11) uses only inlet temperatures.

• For the case of a single-pass, counterflow exchanger, combining

Eqs (9 & 10):

• We consider first the case when the cold fluid is the minimum

fluid. Using the present nomenclature,

)( min CiHi TTCq

----------- Eq. (13)

----------- Eq. (12)

----------- Eq. (11)

)(

)(

)(

)(

minmin CiHi

CiCoC

CiHi

HoHiH

TTC

TTC

TTC

TTC

CoHi

CiHo

CoHiCiHoCiCoC

TT

TT

TTTTUATTCq

ln

•Combining Eq. (8) with the left side of Eq. (12) and solving for

THi.

•Subtracting TCo from both sides,

•From Eq. (8) for Cmin = CC and Cmax = CH ,

•This can be rearranged to give the following:

)(11

)(1

CiCoCiCoCoCiCoHi TTTTTTTT

)(1

CiCoCiHi TTTT

----------- Eq. (14)

----------- Eq. (16)

----------- Eq. (15)

----------- Eq. (17)

)(max

minCiCoHiHo TT

C

CTT

)(max

minCiCoCiHiCiHo TT

C

CTTTT

•Substituting Eq. (14) into Eq. (17),

•Finally, substituting Eq. (15) and Eq. (18) into Eq. (13), rearranging, taking the antilog of both sides, and solving for ε,

•We define NTU as the number of transfer unit as follows:

•The same results would have been obtained if CH = Cmin

)(1

max

minCiCoCiCoCiHo TT

C

CTTTT

----------- Eq. (19)

----------- Eq. (18)

----------- Eq. (20)

max

min

minmax

min

max

min

min

1exp1

1exp1

C

C

C

UA

C

C

C

C

C

UA

UA

NTUminC

•For parallel flow we obtain:

•Figure 4.9-7 (Geankoplis, 4th ed.) shows the heat exchanger

effectiveness, ε for

a)counterflow exchanger – using Eq. (19)

b)parallel flow exchanger – using Eq. (21)

max

min

max

min

min

1

1exp1

C

C

C

C

C

UA

----------- Eq. (21)

Figure 4.9-7 Heat exchanger effectiveness, ε:

a)counterflow exchanger; b)parallel flow exchanger

(Geankoplis, 4th ed.)

Example 3 Effectiveness of heat exchanger

Water flowing at a rate of 0.667 kg/s enters a countercurrent heat exchanger at 308 K and is heated by an oil stream entering at 383 K at a rate of 2.85 kg/s (cp = 1.89 kJ/kg.K). The overall U = 300 W/m2.K and the area A = 15.0 m2. Calculate the heat transfer rate and the exit water temperature.

Solution

Assuming that the exit water temperature is about 370 K,

the cp for water at an average temperature of (308 + 370)/2 = 339 K is 4.192 kJ/kg.K (Appendix A.2).

Then (mcp)H = CH = 2.85(1.89 x 103) = 5387 W/K and

(mcp)C = CC = 0.667(4.192 x 103) = 2796 W/K = Cmin.

Since CC is the minimum, Cmin /Cmax = 2796 / 5387 = 0.519.

Using Eq. (20), NTU = UA/Cmin = 300 (15.0)/2796 = 1.607

Using Fig. 4.9-7(a) for a counterflow exchanger, ε = 0.71.

Substituting into Eq. (11)

q = ε Cmin (THi – TCi) = 0.71 (2796)(383 – 308) = 148 900 W

Using Eq. (8), q = 128 900 = 2796 (TCo – 308)

Solving TCo = 361.3 K

Fouling Factors and Typical Overall U Values

• After a period of operation, the heat transfer surface for a heat

exchanger may become coated with various deposits present in the

flow system, dirt, soot or the surface may become corroded as a

result of the interaction between the fluids and the material used

for construction of the heat exchanger.

• Biological growth such as algae can occur with cooling water in

the biological industries.

• These deposits offer additional resistance to the flow of heat and

reduce the overall heat transfer coefficient U.

• To avoid or lessen these fouling problems, chemical inhibitors are

often added to minimize corrosion, salt deposition and algae

growth.

• It is necessary to oversize an exchanger to allow for the reduction

in performance during operation.

•The effect of fouling is allowed for in design by including the resistance of the fouling on the inside and outside of the tube in Eq. (22).

Where:

hdi = fouling coefficient for inside of the tube (W/m2.K)

hdo = fouling coefficient for outside of the tube (W/m2.K)

•Fouling coefficients or fouling factors must be obtained experimentally by determining the value of U for both clean and dirty conditions in the heat exchanger. The fouling factor, Rf is define as:

doo

i

oo

i

AA

iio

dii

i

hA

A

hA

A

Ak

Arr

hh

U

lm

11

1----------- Eq. (22)

cleandirty

fUU

R11

----------- Eq. (23)

•Typical Fouling Coefficients is shown in Table 1 and the typical

values of overall heat transfer coefficients are given in Table 2.

Table 1 Typical Fouling Coefficients

hd

(W/m2.K)

hd

(btu/h.ft2.0F)

Distilled and seawater

City water

Muddy water

Gases

Vaporizing liquids

Vegetable and gas oils

11350

5680

1990-2840

2840

2840

1990

2000

1000

350-500

500

500

350

Table 2 Typical Values of Overall Heat Transfer

Coefficient in Shell and Tube Exchanger

U

(W/m2.K)

U

(btu/h.ft2.0F)

Water to water

Water to brine

Water to organic liquids

Water to condensing steam

Water to gasoline

Water to gas oil

Water to vegetable oil

Gas oil to gas oil

Steam to boiling water

Water to air (finned tube)

Light organics to light organics

Heavy organics to heavy organics

1140 – 1700

570 – 1140

570 – 1140

1420 – 2270

340 – 570

140 – 340

110 – 285

110 – 285

1420 – 2270

110 – 230

230 – 425

55 - 230

200 – 300

100 – 200

100 – 200

250 – 400

60 – 100

25 – 60

20 – 50

20 – 50

250 – 400

20 – 40

40 – 75

10 – 40

Design of a Shell and Tube Exchangers

Example 4

Water at the rate of 3.783 kg/s is heated from 37.78 to 54.44 °C in a shell-tube heat exchanger. On the shell side one pass is used with water as the heating fluid, 1.892 kg/s, entering the heat exchanger at 93.33 °C. The overall heat transfer coefficient is 1419 W/m2.°C, and the average water velocity in the 1.905-cm diameter tubes is 0.366 m/s. Because of the space limitations, the tube length must not longer than 2.438 m. Calculate the number of tube passes, the number of tubes per pass, and the length of the tubes, consistent with restriction.

Use a split-ring floating head type. The bundle diametrical clearance = 68 mm

Hence, shell diameter, Ds = 826 + 68 = 894 mm.