1
Uses: Oxidant precursor to nylon, rocket propellant, analytical reagent, woodworking aging agent, etching and cleaning agent. Often used for nitration. Tips : 304L Coriolis is a lesser known but good option for this acid. Commercially used around 68%. Above 86% is called fuming acid. Often used for passivation of piping and equipment. C22/C276 not a good fit. Possible Materials: 304L 316L - dilute Tantalum Tefzel Zirconium Platinum Avoid: C22/C276 Titanium Possible Materials: C22/C276 Titanium Tantalum Tefzel Platinum Zirconium – very dilute only Avoid: 316L 304L Uses: Cleaner and disinfectant. Uses: Chemical reagent in the large-scale production of vinyl chloride for PVC plastic, and MDI and TDI for polyurethane. Can be used for pickling. Used in battery production. Tips: Very aggressive acid. Ask whether process introduces ferric or cupric ions (if so, avoid Zirconium). Possible Materials: C22/C276 – dilute only Tantalum Tefzel – with no organics Zirconium – with no oxidizing ions Platinum Avoid: 316L 304L Titanium Super Duplex Product: Hydrochloric Acid Other names: Muriatic Acid = C22/C276 Titanium 80 60 50 40 30 0% 1% 2% 4% 6% 8% 10% 12% 14% 16% 0 70 TEMPERATURE ( 0 C) CONCENTRATION Product: Nitric Acid Other names: N/A Product: Sodium Hypochlorite Other names: Bleach = 316L = Zirconium = 304L = Tantalum Platinum 180 160 140 120 100 60 40 20 0 0 5% 20% 40% 65% 75% 85% 90% 93% 98% 100% -20 80 TEMPERATURE ( 0 C) CONCENTRATION Uses: Preparation of metal acetates, used in some printing processes; vinyl acetate monomer, employed in the production of plastics; cellulose acetate, used in making photographic films and textiles; volatile organic esters (such as ethyl and butyl acetates), widely used as solvents for biochemical processes, resins, paints, and lacquers. Tips: Commonly sold by the rail car or tanker truck. Focusing on loading and unloading applications will offer a good start. Ask about piping used for process. Ferric & Cupric ions good for Ti, bad for Zr. Tefzel should not be used. Possible Materials: 316L C22/C276 Titanium Tantalum Zirconium Platinum Super Duplex Avoid: Tefzel 304L Product: Acetic Acid Other names: N/A = 316L = C22/C276 = Titanium Zirconium Platinum 180 160 140 120 100 60 40 20 0 0 5% 20% 40% 65% 75% 85% 90% 93% 98% 100% -20 80 TEMPERATURE ( 0 C) CONCENTRATION Uses: Most often used as a feed to other processes where the Chlorine ion and Hydrogen are needed for other chemical reactions. Tips: Piping may be stainless steel but often this alloy is not recommended for the flow instrument. There are various types of brines (not all the same) with varying levels of corrosivity. Acid Brine – Low pH is much more corrosive. Possible Materials: C22/C276 Tantalum Titanium Zirconium Platinum Super Duplex Avoid: 316L 304L Product: Brine Other names: salt water, sodium chloride solution Tips: Titanium is often a good fit for this application. Titanium is better than Zirconium. Uses: Used to manufacture a wide range of consumer products. Includes organic chemicals such as polyvinyl chloride and the intermediates for the production of plastics. Possible Materials: C22/C276 – must be dry Titanium – must be wet Tantalum Tefzel – wet Cl 2 only Avoid: 316L 304L Zirconium Platinum Titanium – if no water Product: Chlorine Other names: Cl 2 17 CI = Tefzel 180 160 140 120 100 60 40 20 0 0 5% 20% 40% 65% 75% 85% 90% 93% 98% 100% -20 80 TEMPERATURE ( 0 C) CONCENTRATION = Tantalum Tips: If anhydrous, then may not be too corrosive although a small amount of water (even vapor) can affect the composition and become corrosive. Avoid platinum. Tantalum may be a safe alternative if the customer does not have good control on the process. Titanium may be flammable for dry chlorine. = Tantalum Zirconium Platinum = Super Duplex = Titanium / C22 180 160 140 120 100 60 40 20 0 0 5% 20% 40% 65% 75% 85% 90% 93% 98% 100% -20 80 TEMPERATURE ( 0 C) CONCENTRATION = Tantalum = Platinum = C22/C276 = Zirconium 180 160 140 120 80 60 40 20 0 5% 10% 15% 20% 25% 30% 35% 40% 0 100 TEMPERATURE ( 0 C) CONCENTRATION Possible Materials: 316L - dilute C22/C276 Tefzel Zirconium Platinum Avoid: Titanium Tantalum 304L Uses: Detergents, synthetic resins, dyes, petroleum catalysts, insecticides, antifreeze, aluminum reduction, water treatment, pigments, paints, enamels, printing inks, coated fabrics, paper, explosives, cellophane, acetate, viscose textiles, lubricants, non-ferrous metals and batteries. Possible Materials: 316L C22/C276 Tantalum – 98% max Tefzel – 98% max Zirconium – 50% max Platinum Avoid: Titanium 304L Uses: Reactant in organic chemicals, pulping agent in P&P, dissolves lining, desulfurization in petrochem, saponification, pH control, aluminum production, CIP cleaner. 120 110 100 90 80 60 50 40 30 0% 5% 20% 40% 65% 75% 85% 90% 93% 98% 100% 0 70 TEMPERATURE ( 0 C) CONCENTRATION = 316L = Tefzel, and Platinum = C22/C276 Product: Sodium Hydroxide Other names: Caustic Soda, NaOH Product: Sulfuric Other names: Tower or Chamber Acid Acid dilutions can raise temperature rapidly. Do not exceed temperature changes of more than 30º F per hour. No temperatures below 32°F and over 248°F at any time, even when not in use. Includes transit, storage, outdoor installations. No steam cleaning. No vacuums in the line. Tefzel Restrictions for Coriolis This is meant to be used a quick reference to direct which wetted materials and products will work for some of the most common corrosive fluids. The corrosion guide provides a more exhaustive list of options and should be referenced if there are any questions or if the application is on the transition between materials. DISCLAIMER NOTE. = 316L = C22/C276 = Tefzel = Tantalum = Platinum = Zirconium 180 150 93 66 52 38 20 0 0 5% 20% 40% 65% 75% 85% 90% 93% 98% 100% -20 54 TEMPERATURE ( 0 C) CONCENTRATION Tips: Common to buy very concentrated (typically around 50%) and dilute on site. F0100 option needed on mags with caustic concentration above 50% — use dual concentration curve. Dilution can have exothermic effect which can have large thermal change (Tefzel delamination issue). No Tantalum or titanium (ask about cleaning fluid used). Chloride contamination is common. Observe chloride limits for some wetted materials. 50% and higher is solid at 70°F. Tips: Sizing should be carefully considered due to highly erosive fluid properties to metals. Keep fluid velocity below 8 ft/s to reduce likelihood of removing oxide layer. Very dependent on concentration. Use alloys, like Tantalum, if wide concentration range expected (if crossing oxide layer). Concentrations above 98% are not common as the acid will quickly revert to a lower concentration. CHEMICAL CORROSION QUICK REFERENCE GUIDE DOWNLOADS Emerson Automation Solutions offers the largest portfolio of flow products to meet the installation needs for corrosive applications. Multiple wetted materials including tantalum, alloy C22, and platinum are available across the flow portfolio to handle even the most corrosive fluids. Emerson has more than 35 years of experience and hundreds of thousands of successful installations in corrosive applications. MICRO MOTION CORROSION GUIDE http://www.emerson.com/micromotioncorrosionguide ROSEMOUNT CORROSION GUIDE http://www.emerson.com/rosemountcorrosionguide www.emerson.com PRODUCTS AVAILABLE 316L C22 Tantalum 304L Titanium Zirconium Platinum Super Duplex Tefzel Coriolis Flow Meters Fork Density Meters Magnetic Flow Meters * ** **** Vortex Flow Meters *** Roxar Corrosion Instruments***** *=316 **=C-276 ***=Chemical Vapor Deposition (CVD) via special order ****=304 *****=More wetted materials may be available via special order

QUICK REFERENCE GUIDE DOWNLOADS PRODUCTS AVAILABLE · C22/C276 not a good ˜t. Possible Materials: 304L acetate, viscose textiles, lubricants, non-ferrous metals and batteries. 316L

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Page 1: QUICK REFERENCE GUIDE DOWNLOADS PRODUCTS AVAILABLE · C22/C276 not a good ˜t. Possible Materials: 304L acetate, viscose textiles, lubricants, non-ferrous metals and batteries. 316L

Uses: Oxidant precursor to nylon, rocket propellant, analytical reagent, woodworking aging agent, etching and cleaning agent.Often used for nitration.

Tips :■ 304L Coriolis is a lesser known but good option for this acid.

■ Commercially used around 68%. Above 86% is called fuming acid.

■ Often used for passivation of piping and equipment.

■ C22/C276 not a good �t.

Possible Materials:■ 304L■ 316L - dilute■ Tantalum■ Tefzel■ Zirconium■ Platinum

Avoid:■ C22/C276■ Titanium

Possible Materials:■ C22/C276■ Titanium■ Tantalum■ Tefzel■ Platinum■ Zirconium – very dilute only

Avoid:■ 316L■ 304L

Uses: Cleaner and disinfectant.

Uses: Chemical reagent in the large-scale production of vinyl chloride for PVC plastic, and MDI and TDI for polyurethane. Can be used for pickling.Used in battery production.

Tips:■ Very aggressive acid.

■ Ask whether process introducesferric or cupric ions(if so, avoid Zirconium).

Possible Materials:■ C22/C276 – dilute only■ Tantalum■ Tefzel – with no organics■ Zirconium – with no oxidizing ions■ Platinum

Avoid:■ 316L■ 304L■ Titanium■ Super Duplex

Product: Hydrochloric Acid

Other names: Muriatic Acid

= C22/C276Titanium

80

60

50

40

30

0% 1% 2% 4% 6% 8% 10% 12% 14% 16%

0

70

TE

MP

ER

AT

UR

E (0 C

)

CONCENTRATION

Product: Nitric Acid

Other names: N/A

Product: Sodium Hypochlorite

Other names: Bleach

= 316L

= Zirconium

= 304L

= TantalumPlatinum

180

160

140

120

100

60

40

20

0

0 5% 20% 40% 65% 75% 85% 90% 93% 98% 100%

-20

80

TE

MP

ER

AT

UR

E (0 C

)

CONCENTRATION

Uses: Preparation of metal acetates, used in some printing processes;vinyl acetate monomer, employed in the production of plastics; cellulose acetate, used in making photographic �lms and textiles; volatile organic esters (such as ethyl and butyl acetates), widely used as solvents forbiochemical processes, resins, paints, and lacquers.

Tips: ■ Commonly sold by the rail car

or tanker truck. Focusing on loading and unloading applicationswill offer a good start.

■ Ask about piping used for process.

■ Ferric & Cupric ions good for Ti,bad for Zr. Tefzel should not be used.

Possible Materials:■ 316L■ C22/C276■ Titanium■ Tantalum■ Zirconium■ Platinum■ Super Duplex

Avoid:■ Tefzel■ 304L

Product: Acetic Acid

Other names: N/A

= 316L

= C22/C276

= Titanium Zirconium Platinum

180

160

140

120

100

60

40

20

0

0 5% 20% 40% 65% 75% 85% 90% 93% 98% 100%

-20

80

TE

MP

ER

AT

UR

E (0 C

)

CONCENTRATION

Uses: Most often used as a feed to other processes where the Chlorine ion and Hydrogen are needed for other chemical reactions.

Tips: ■ Piping may be stainless steel

but often this alloy is notrecommended for the �owinstrument.

■ There are various typesof brines (not all the same)with varying levels of corrosivity.

■ Acid Brine – Low pH is muchmore corrosive.

Possible Materials:■ C22/C276■ Tantalum■ Titanium■ Zirconium■ Platinum■ Super Duplex

Avoid:■ 316L■ 304L

Product: Brine

Other names: salt water, sodium chloride solution

Tips:■ Titanium is often a good

�t for this application.

■ Titanium is better than Zirconium.

Uses: Used to manufacture a wide range of consumer products. Includes organic chemicals such as polyvinyl chloride and the intermediates for the production of plastics.

Possible Materials:■ C22/C276 – must be dry■ Titanium – must be wet■ Tantalum■ Tefzel – wet Cl2 only

Avoid:■ 316L■ 304L■ Zirconium■ Platinum■ Titanium – if no water

Product: Chlorine

Other names: Cl217CI

= Tefzel

180

160

140

120

100

60

40

20

0

0 5% 20% 40% 65% 75% 85% 90% 93% 98% 100%

-20

80

TE

MP

ER

AT

UR

E (0 C

)

CONCENTRATION

= Tantalum

Tips:■ If anhydrous, then may not be too

corrosive although a small amountof water (even vapor) can affect the composition and become corrosive.

■ Avoid platinum.

■ Tantalum may be a safe alternativeif the customer does not have good control on the process.

■ Titanium may be �ammable fordry chlorine.

= TantalumZirconiumPlatinum

= Super Duplex

= Titanium /C22

180

160

140

120

100

60

40

20

0

0 5% 20% 40% 65% 75% 85% 90% 93% 98% 100%

-20

80

TE

MP

ER

AT

UR

E (0 C

)

CONCENTRATION

= Tantalum

= Platinum

= C22/C276

= Zirconium

180

160

140

120

80

60

40

20

0 5% 10% 15% 20% 25% 30% 35% 40%

0

100

TE

MP

ER

AT

UR

E (0 C

)

CONCENTRATION

Possible Materials:■ 316L - dilute■ C22/C276■ Tefzel■ Zirconium■ Platinum

Avoid:■ Titanium ■ Tantalum■ 304L

Uses: Detergents, synthetic resins, dyes, petroleum catalysts, insecticides, antifreeze, aluminum reduction, water treatment, pigments, paints, enamels, printing inks, coated fabrics, paper, explosives, cellophane, acetate, viscose textiles, lubricants, non-ferrous metals and batteries.

Possible Materials:■ 316L■ C22/C276■ Tantalum – 98% max■ Tefzel – 98% max■ Zirconium – 50% max■ Platinum

Avoid:■ Titanium■ 304L

Uses: Reactant in organic chemicals, pulping agent in P&P, dissolves lining, desulfurization in petrochem, saponi�cation, pH control, aluminum production, CIP cleaner.

120

110

100

90

80

60

50

40

30

0% 5% 20% 40% 65% 75% 85% 90% 93% 98% 100%

0

70

TE

MP

ER

AT

UR

E (0 C

)

CONCENTRATION

= 316L

= Tefzel, and Platinum

= C22/C276

Product: Sodium Hydroxide

Other names: Caustic Soda, NaOH

Product: Sulfuric

Other names: Tower or Chamber Acid

■ Acid dilutions can raise temperature rapidly. Do not exceed temperature changes of more than 30º F per hour.

■ No temperatures below 32°F and over 248°F at any time, evenwhen not in use. Includes transit, storage, outdoor installations.

■ No steam cleaning.

■ No vacuums in the line.

Tefzel Restrictions for Coriolis

This is meant to be used a quick reference to direct which wetted materials and products will work for some of the most common corrosive �uids. The corrosion guide provides a more exhaustive list of options and should be referenced if there are any questions or if the application is on the transition between materials.

DISCLAIMER NOTE.

= 316L

= C22/C276

= Tefzel

= Tantalum

= Platinum

= Zirconium

180

150

93

66

52

38

20

0

0 5% 20% 40% 65% 75% 85% 90% 93% 98% 100%

-20

54

TE

MP

ER

AT

UR

E (0 C

)

CONCENTRATION

Tips:■ Common to buy very concentrated (typically

around 50%) and dilute on site. F0100 option needed on mags with caustic concentration above 50% — use dual concentration curve.

■ Dilution can have exothermic effect which can have large thermal change (Tefzel delamination issue).

■ No Tantalum or titanium (ask about cleaning �uid used).

■ Chloride contamination is common.

■ Observe chloride limits for some wetted materials.

■ 50% and higher is solid at 70°F.

Tips:■ Sizing should be carefully considered due

to highly erosive �uid properties to metals. Keep �uid velocity below 8 ft/s to reduce likelihood of removing oxide layer.

■ Very dependent on concentration.

■ Use alloys, like Tantalum, if wide concentration range expected (if crossing oxide layer).

■ Concentrations above 98% are not commonas the acid will quickly revert to a lower concentration.

CHEMICAL CORROSION

QUICK REFERENCE GUIDE DOWNLOADS

Emerson Automation Solutions offers the largest portfolio of flow products to meet the installation needs

for corrosive applications. Multiple wetted materials including tantalum, alloy C22, and platinum are available

across the flow portfolio to handle even the most corrosive fluids. Emerson has more than 35 years of

experience and hundreds of thousands of successful installations in corrosive applications.

MICRO MOTION CORROSION GUIDEhttp://www.emerson.com/micromotioncorrosionguide

ROSEMOUNT CORROSION GUIDEhttp://www.emerson.com/rosemountcorrosionguide

www.emerson.com

PRODUCTS AVAILABLE316L C22 Tantalum 304L Titanium Zirconium Platinum Super Duplex Tefzel

Coriolis Flow Meters ✔ ✔ ✔ ✔ ✔ ✔ ✔

Fork Density Meters ✔ ✔ ✔ ✔ ✔ ✔

Magnetic Flow Meters ✔* ✔** ✔ ✔**** ✔ ✔

Vortex Flow Meters ✔ ✔ ✔*** ✔

Roxar Corrosion Instruments***** ✔ ✔

*=316 **=C-276 ***=Chemical Vapor Deposition (CVD) via special order ****=304 *****=More wetted materials may be available via special order