Embed Size (px)
Citation preview
CERTIFIED # P 322 798 320
JUNE 10, 1994
e.2.
i t J iF i i g
UNITED STATES ENVIRONMENTAL PROTECTION AGENCY REGION v n - :i}PERFUNt 726 ivflNNESOTA AVENUE KANSAS CITY KS 65101
ATTN GLENN M CURTIS
'"^N T6 1994
|WJ)«IMHCB
Other: ?/r^fl. ta^-r'^>9-.
Dea' Mr. Curtis:
Encoded is the revised Operation and Maintenance (0&N:>) Plan for the DICO, Inc. facility in Des Moines, Iowa. This document addresses the requirements set forth in the work order and incorporates the USEPA comments from your letter of December 30,1993.
Also, enclosed are the resuhs of the wipe samples conducted on the inventory stored in Buildiag No. Z. All resuhs are not detectab!'^ tn we will proceed ;/ith washing the remaining invsntory as described in the second monthly progress report.
If you have any questions concerning this please call me at (217) 221-4461.
Sincerely,
tJOClA
^Jamcs P. Fechter Environmental Engineer
JPF:djk
cc Jerry Shanholtzer Cheri Holley File
Enclosure 30221125
1 1 IN Superfund
2701 SPRUCE STREET. QUINCY, ILLINOIS 62301 USA
TELEPHONE: (217) 228-6011 • FAX: (217) 228-9871
OPERATION AND MAMTENANCE PLAN
FOR
DTCO, INC. DES MOINES, IOWA
BUILDINGS NO. 1-5
MAINTENANCE BUILDING
MAINTENANCE OF INTERIOR SURFACE COATINGS
OPE'^lTON AND MAINT CilANCE FLAN DICO, INC.
DES MOLVES, IOWA
TABLJ: OF CONTEir S
1.0 INTRODUCTION
20 BACKGROUND
3.0 OBJECTIVE
4.0 OPERATION AND MAINTENANCE PLAN
4.1 EMPLOYEE AWARENESS
4.2 PREVENTIVE ACTIONS
4.3 MONTHLY INSPECTIONS
4.4 ANNUAL INSPECTIONS
4.5 PERIODIC SAMPLING ACTIVITIES
5.0 DAMAGE REPAIR AND GUIDELINES
5.1 DAMAGE BY SCRATCHES/ABRASIONS
5.2 DETERIORATION/FAILURE OF COATING PRODUCT
6.0 EMERGENCY ACTIONS AND PROCEDURES
6.1 FIRE
6.2 STRUCTURAL DAMAGE
6.3 EMERGENCY PROCEDURE NOTIFICATIONS
t ABLE OF CONTENTS continued
HGUREl.O OPERABLE UNIT BOUNDARIES
nGURE2.0 PLANT LAYOUT
APPENDIX A. COATING PRODUCT INFORMATION
1. FLOORS
2. WALLS AND CEILINGS
APPENDK B. EMPLOYEE AWARENESS LOG
APPENDIX C MONTHLY INSPECTION REPORT
APPENDIX D. ANNUAL INSPECTION REPORT
APPENDIX E. PERIODIC SAMPLING TABLE
APPENDIX F. FIRE ALARM EMERGENCY RESPONSE PLAN
APPENDIX G. EMERGENCY EVACUATION PROCEDURES
APPENDIX H. TORNADO SAFETY GUIDELINES
APPENDIX I. NOTIFICATION LETTERS
OPERATION J ^ : J ) M A I N : ^ ^ N A N C E PLAN DICO, ':iiC.
DES MOL'^S, .OWA
1.0 INTRODUCTION
Titan Wheel International, Inc./Dyneer Corporation Environmental Engineering Department has prepared this Operation and Maintenance (O&M) Plan in accordance with the United States Environmental Protection Agency (USEPA) administrative order issued for the DICO fedlity in Des Moines, Iowa. This O&M Plan will set forth the actions necessary to ensure the protectiveness and integrity of the removal actions performed.
2.0 BACKGROUND
The DICO facility is part of the larger "Des Moines TCE Site" as defined by the USEPA. This site was placed on the USEPA's National Priorities List (NPL) in 1983 as a "Super Fund" site which includes a portion of the Des Moines Water Works (DMWW) property, the industrial area north of the Raccoon River, the Tuttle Street landfill to the east, and the Frank DdKiydt Woods to the south. The Des Moines TCE Site was divided into
^ • o u r Operable Units (OU). OUl includes groundwater underlying the site that is contaminated with TCE. 0U2, also known as the South Area Source Control (SASC), covers sections of the DICO property and a portion of the Frank DePuydt Woods. A northern plume of contaminated groimdwater is identified as 0U3. 0U4 includes Buildings No. 1 through No. 5 and the Maintenance Building, soil and sediment surrounding the former Aldrin tank and South Pond areas, and the soil pile disking operations. The relevant sections of 0U4 are displayed on Figure I.
Builduigs No. 1 through No. 5 were the location of pesticide formulation and distribution operations from the mid 1950's through 1970, under the name of DiChem, Inc. Work performed under a contract with Shell OU Company included heating Aldrin to a liquid form in a tank and then sprayed onto fertilizer. The product was then marketed by ^hell. Other similar work was perforr<^i under contracts with Chevron Chemicals Company, Monsanto, and American Oil Products. This included preparing, packaging, and storing heibiddes and pesticides which contained Chlordane and Heptachlor. During these operations the materials were owned solely by the company for which the formulation activities were performed. Furthermore, the mentioned companies provided instructions and supervision of the formulation operations, equipment, processes, and other related procedures. These operations ceased by DiChem in the early 1970's.
The initial investigation into the conditions of the interior surfaces of Buildings No. 1 through No. 5 was conducted in September, 1991. This investigation consisted of wipe sampling interior surfaces of Buildings No. 3 and No. 4, and the Maintenance Building. A second investigation of Buildings No. 1 through No. 5 was conducted to determine more precisely which buildings ciontained pesticides. A third investigation was performed in January, 1992 by order of and oversight by USEPA addressing all the buildings.
Analysis of the samples indicated the presence of pesticides in all six building imeriors at generally low ncentrations. The highest pesticide concentrations were from the former Aldrin tank annex. Dust samples
were analyzed and presented similar results. The dust contained low concentrations of pesticides with the highest levels found in the former Aldrin tank annex.
Along with the wipe samples, insulation samples were collected and analyzed for the presence of PCBs. Wiih the exception of Building No. 1, PCBs were detected in ceiling insulation samples from all the buildings. Wall insulation samples taken in Buildings No. 3,4 and 5 also indicated the presence of PCBs. One wipe sample, taken on the floor of Building No 4, showed concentrations of PCBs wbUe all remaining sample analyses showed up not detectable.
Hie investigations indicated the presence of residual pesticides within all six buildings and the presence of PCBs in the insulation of all the buildings, except Building No. 1. The source of the residual pesticides is the prior pesticide processing operations and, as is expected, the higher concentrations correspond with areas of pesticide operations. The presence of PCBs within the buildings is a result of the affected insulation, specifically, the liner panels which show the highest concentrations.
As a result of these investigations, the USEPA issued an administrative order to address the contaminants present within the buildings. This administrative order required DICO to conduct removal actions that would protect human health and the environment from the actual or threatened release of hazardous substances at the DICO fiudlity. Remedial activities took place in the Spring of 1994 to address the requirements of the administrative order.
The goal of the remediation activities was to remove as much residual pesticide as possible from the interior surfaces of the buildings prior to encapsulating all surfaces with appropriate coatings. These actions served to protect human health and the environment by preventing exposure of any hazardous substances that may remain upon the interior building surfaces. The following actions were taken during the remediation actions:
Residual and loose material was cleaned from the floors. Building walls, roof/building beams, trusses, and ceilings were dry vacuumed to remove lose material. Dirt, dust, and oil and grease was cleaned from interior surfaces. Damaged insulation was repaired or replaced. Floors were wet scrubbed with a mild acid solution. Sur&ces were prepared and then encapsulated with a coating. Metal panels were installed along walls which had exposed insulation. The Aldrin tank annex was removed along with the Aldrin tank itself Surrounding soil was excavated for disposal.
Air sampling was performed upon completion to ensure the encapsulation was effective.
The coatings employed for the walls and ceilings was an epoxy paint while an urethane coating was applied to the floors. MSDSs and other product information is provided in .^pendbc A.
3.0 OBJECTIVE
In order to mamtain long term effectiveness of the encapsulated surfaces, this O&M Plan will set forth practices to ensure all efforts are made to prevent damage to the surfaces and, in the case of damage, institute repairs in a safe and effective manner. Furthermore, actions to be taken in the event of an emergency are outlined.
4.0 OPERATION AND MAINTENANCE PLAN
I his O&M Plan and associated records will be available on-site at the DICO fiicility at all times for inspection by "representatives of the USEPA, the Iowa Department of Natural Resources (IDNR), and any other local or federal agency that my have the authority to review this information. Plant management will be familiar with the contents and requirements of this Plan, while the Plam Engineer will be responsible for the institution and adherence to the requirements and guidelines of this document.
4.1 EMPLOYEE AWARENESS
DICO personnel whose positions will require working within Buildings No. 1 through No. 5 and the Maintenance Building vdll be informed of the purpose and importance of avoiding damage to the sur&ce coatings. They will be allowed to review this document, if they desire, to be aware of the potentiaUy hazardous substances that may exist beneath the surface coatings. A statement explaining the situation and a sign-off log is provided in Appendix B. The statement will be read by any DICO employee who will work in Buildings No. 1 through No. 5 and the Maintenance Building, and they will have the option to review this document. The log with appropriate signatures will be kept on file at DICO with other information relevant to this Plan, as detailed in Section 4.0.
To supplement the verbal instructions provided to employees, signs will be posted at pedestrian entranceways. Hiese signs will express the same information that the votal statement contains in regards to personnel awareness. Signs will be of the following format:
ATTENTION
ANY DAMAGE TO SURFACE COATINGS WITHIN THIS BUILDING IS TO BE
REPORTED IMMEDIATELY TO PLANT MANAGEMENT.
4 J PREVENTIVE ACTIONS
To physically minimize potential damage several measures Iiave been taken. First, as part of the remediation efforts, metal panels were installed along walls with exposed insulation. This will prevent damage to the insulation by equipment or personnel during normal facility operations, thus preventing possible exposure to hazardous substances.
Additional preventive measures include maintaining an approximate 12 foot aisle between interior walls and storage areas within the buildings. Within this aisle, storage of equipment or materials, plant operations, and forklift paiking vnll be prohibited. This will aid in preventing opportunities for damage to the surface coatings. DICO employees who need to be aware of this practice, i.e., forklift operators, will be verbally instructed and signs will be posted expressing these requirements.
^ A'iONTHLV INSPECTIONS
A monthly inspection, performed by the Plant Engineer, will be conducted to ensure the integrity of the surface coatings has not been compromised. These monthly inspections will primarily focus on likely areas of potential damage such as aisle floor space and wall surfaces up to sbc feet. A monthly inspection checklist is providt J in Appendbc C that details the required information for the monthly report. These records will be kept with assodated information as described in Section 4.0. In the case damage is discovered and requires repairs, action win be taken as described in Section 5.
4A ANNUAL INSPECTIONS
Annual inspections will be conducted by the Plant Engineer. These inspections will cover the requirements outlined in the monthly inspections plus efforts to inspect as much of the surface coating area as possible. These effints wall include inspecting areas behind or below equipment and material, moving equipment or material to inspect the floor area, and accessing high wall and ceiling areas by lifr or ladder. Thou^ all efforts will be made for inspection activities, extreme efforts that may interrupt plant operations may be avoided.
These annual reports will include the checklist provided in i^pendbc D and an attached report describing methods and the results of inspecting the more inaccessible areas previously described. The report and other
: information will be forwarded to USEPA Region Vn at the following address: peranent ]
USEPA-REGION v n WASTE MANAGEMENT DIVISION - SUPERFUND BRANCH
726 MINNESOTA AVENUE KANSAS CITY, KANSAS 66101
The report and other information will be kept on file at DICO as described in Section 4.0. In the case damage is discovered and repairs are required, the actions taken, as presented in Section 5, will also be forwarded to the USEPA and kept on file.
4.5 PERIODIC SAMPUNGACTIVmES
As required by the administrative order, periodic sampling will be conducted to ensure that the encapsulation has remained effective in preventing dangerous levels of hazardous substances. Wipe samples will be collected from the coated surface areas of all six buildings eveiy two years and these analytical results and sampling processes will be included in that years' annual report.
Sampling locations will be at the discretion of the plant engineer, but these locations will be detailed on the plant am provided in Figure 2 (or other similar diagram). The sample location diagrams will be included in the ^ ^ i a g r i
-ra ncual report containing sampling activities, also kept on file at DICO. The sample locations wiU be varied each mpling episode so that representative sampling results will be provided for each building. For each sampling >isode the following samples will be taken:
BI^LDINGNO,
1 2 3 4 5
. WALLS
1 1 1 2 2
MAINTENANCE 1
FLOORS
1 2 1 2 2 1
(!Kn.TNG
Tliese samples will be taken by a qualified contractor and analyzed by a qualified laboratory. Analysis will inchide Aldrin, Dieldrin, Heptachlor, Chlordane, 2,4-D, 2,4, 5-T. 2, 3, 7, 8-TCDD, and PCBs.
In order to remain consistent over progressive sampling periods the following labeling and recording wiU be employed. Samples will be labeled as WS-X-X, where WS indicates Wipe Sample, the first X represents the sampling episode, and the second X represents the sample number for that sampling episode. Thus WS-2-5 would represent the fifth wipe sample taken during the second sampling period (sampling to be included in the fourth annual report). A table (provided in Appendix E) to summarize sample collection, a diagram showing sample locations, and the analytical results will be kept together as a package for filing and reporting equirements. tf
«.0 AMAGE REPAIR AND GUI )J:LU:I^J
uough employee awareness, monthly inspections, and detailed annual inspections, any damage to the ^capsulated surfaces will quickly be discovered. It is expected that possible damage to the coatings can be described in one of two ways; scratches or abrasions caused by equipment or material, or deterioration/failure of the coating product. The following sections will detail how this damage will be addressed.
5.1 DAMAGE BV SCRATCHES/ABRASIONS
Though all efforts are being taken to prevent damage by equipment or personnel, the event may occur. It is expected that damage by plant operations will take the form of scratches or abrasions that are limited in extent and depth. The scratch or abrasion may or may not penetrate the coating but, in either case, steps will be taken to rq>air the damage so potential of any exposure will be limited.
Repairs of scratches or abrasions will require reapplication of coating to the damaged area. Preparation of the area will be limited to just washing the surrounding area free of dirt, oil or grease, or other loose material in the area. More vigorous efforts at preparation may increase chances of exposing the underlying surfrice. The coating to be applied will be the same as the original, or, of equal or better quality and confirmed compatible with the original. The new coating will be applied as recommended by the manufacturer by DICO personnel.
All these actions will be detailed in a report that will be filed at DICO and forwarded with the next submittal of an annual report. The repair report will include the following:
Date of discovery Cause of damage (if known) Date of repair Method of repair (coating used, application procedure, etc.) Coating Specifications/MSDS (if different from original) Diagram showing exact location of damage Name and position of DICO personnel responsible for repair and report.
5.2 DETERIORATION/FAILURE OF COATING PRODUCT
Though not expected or likely, deterioration or failure of the coatings may occur over longer periods of time. This may be caused by poor performance of the coating or extreme weathering conditions that will manifest as cracking, spoiling, or bubbling. Most likely, if this occurs, it will affect certain significant areas of the interior sur&ce in localized areas.
Since damage of this type would require removal of the affected surface coatings and subsequent preparation for recoating, an outside contractor, with proper training in remedial activities may be required. If this situation may arise, discussions between DICO management and USEPA representatives may be required to determine a proper course of action. Whatever the action decided upon, sdl efforts wiU be documented in a report that will
include all the information listed in Sect >. 1 and other relevant information. This report will be kept on file at ICO and ibrwarde*! in the next innuai lii.' section report.
If the damaged coating is a result of poor performance of the coating, a more acceptable coating will be used for ^repairs in place of the original. The new coating will be compatible with the existing material and application will take place as recommended by the manufacturer. If it is detennined damage is a resuh of excessive weathering, such as exposure to sunli^t or temperature changes, efforts will be made to better control these elements to prevent future damage.
<t.a Ei«IERGENCY ACTIONS AS > PROC^. JURIES
Pertaining to the encapsulation of potentially hazardous substance at the DICO facility, an emergency event may be considered one that allows potential exposure suddenly and in quantities that may be harmful to human health and the environment. The two most likely scenarios for this evem would be a fire within Buildings No. 1 through No. 5 and/or the Maintenance Building, or any event that causes significant damage to the structure of any of the sbc buildings. The following sections describe the actions to be taken in an emergency situation.
5.1 FIRE
A fire at the DICO facility within Buildings No. 1 through No. 5 and the Maintenance Building would have the potential to release hazardous substances. Either by combustion of the sur&ce coatings or damage to the structure of the buildings, or a combination thereof, potentially hazardous substances may be released.
Small, localized fires will be attended to by DICO persoimel with hand-held fire extinguishers when it is apparent the fire can be quickly controlled. As soon as a fire is detected, personnel will respond according to the Fire Alarm Emergency Response Plan in Appendbc F and Emergency Evacuation Procedures in Appendix G. Special emphasis will be put in evacuating and organizing persoimel so that smoke and fumes are avoided.
If a fire will require service of the Des Moines Fire Department, they will be contacted immediately. Also, as soon as possible, fire and evacuation procedures (Appendix F and G) will be instituted immediately. As described in Section 6.3, the Des Moines Fire Department will be aware of potential hazards at the facility. The LTSEPA Region VII will be notified of any serious fire for further guidance.
6.2 STRUCTURAL DAMAGE
Significant damage may occur to Buildings No. 1 through No. 5 and the Maintenance Building which could cause the potential to release the hazardous substances encapsulated in the interiors. This may take the form of damage by storm or tornado, or possibly earthquakes.
The first response by DICO management will be to safely evacuate plant personnel so that dust that may be generated by any damage is avoided. Tornado Safety Guidelines are provided in Appendbc H and Emergency evacuation Procedures are in Appendbc G When the potential for damage to the sbc buildings has ceased and sufficient time has passed for dust to settie, an inspection will be performed by the plant engineer to assess the extoit of damage. If damage is such that potentially hazardous substances has been released, USEPA Region Vn will be notified for further guidance.
6 3 EMERGENCY PROCEDURE NOTIFICATIONS
In order to comply with emergency planning and notification requirements of SARA Titie m, the Des Moines Fire Department, Des Moines Police Department, the Local Emergency Response Committee, and Methodist Medical Hospital will be sent a letter describing the potential exposure possibilities to hazardous substances at
the ate and any other infonnation they in^y r M.uest. This h ; :er Oi\ tice i.>d any return confirmation letters by the indicated cJitities will be included i i Appendix I. This will ensui^; that in the case of an emergency the local ^gendes wiU be aware, Li %dvanc3, of'^ny p A mtial hazards ;uat n ay *jcist.
FICURE 1.0 OPERABLE UNIT BOUNDARIES
FIGURE 2.0 PLANT LAYOUT
UJ
o l i . u. o
H ®
cP" If
® 31
® ©
i_n
FIGURE 2 . 0 PLANT LA70DT
APPEND (X A . COATING PRODUCT INFORMATION
FLOORS
TENNANT -, 701 North Lilac Drive,
P.O. Box 1452 ft4inneapolis. MN 55440-1452
f S E X S W H ¥ B ! M HDMBER; Cbeitrec: (800)-424-9300 {24br8.) District of Coluabia: (202)-483-7616 (24 hrs.) m m : ONDTEC (613)-996-6666 (24 brs.)
mrisavx nromnoR: By: loija Gill
($12)-540-1381 (days) (612)-544-5163 (nights) (€12)-763-9734 (oiqhts)
Issue Date: 01/01/92 ^i^ersedes: 12/01/18
Pat ..* 1
I . I D E N T I F I C A T I O N
1 HEALTH
FIKE
mcnvm
SPECIU.
HA2illD lATING • D S S M BBOSSa
1 NFPA
1 - 2
3
0
0
HHIS
2
3
0
I
4 « Extreie 3 « High 2 B Moderate 1 « Sl ight 0 B Insignif icant X B Ask s u p e n i s o r
for guidance.
IPROOUCT NAME/NUMBER:I TENNANT STS ( 4 2 0 ) - S t d . T r a f f i c Two>Coat Sys tem
PART NUMBER: 08511
MATERIAL USE: F l o o r C o a t i n g f o r Woo(3 and C o n c r e t e
EMICAL FAMILY: U r e t h a n e P r e p o l y n e r
•IPARTMENT OF TRANSPORTATION U.N. # : UN1866 HAZARD CLASSIFICATION: Flammable L i q u i d SHIPPING NAME: R e s i n S o l u t i o n
I . r > H Y S I C A . I * D A . T A .
BOILING POINT: 295F. /146C.
DENSITY: .98 g/ml
SOLUBILITY IN WATER: Not Soluble
OOOR THRESHOLD: N.Av.
PHYSICAL FORM: Liquid
FREEZE POINT: N.Av. /N.Av.
% VOLATILE: 55% by wt
VAPOR PRESSURE: 6 mm Hg § 20 Deg.C.
pH: N.Av.
VAPOR DENSITY: Heavier , THAN AIR
APPEARANCE AND ODOR: Clear/Asomatic *
COEFFICIENT OF H20/0IL DISTRIBUTION: N.AV.
EVAPORATION RATE: Slower, THAN n-BUTYL ACETATE
MECHANICAL IMPACT: N.Av. STATIC DISCHARGE: N.Av.
NOTE - N.Ap. denotes Not Applicable - N.Av. denotes Not Available
Page 3 PRODUCT #TENNAilT STS (420) - Sidi Traffic Two-Coat System
IV. FIRE .A.ND EXPXiOSlON MA.Zi^RD DATA. FLAMMABLE: Yes (WHrflS Division 2, Class B) FLASH POINT: 80F. / 27C. (SETA FLASH)
FLAMMABLE LIHITS: L.E.L. 1.0% U;E.t. 7.6%
AUT0I6NITI0N TEMPERATURE: N.Av./N.Av.
EXTINGUISHIHG MEDIA: Use National Fire Protection Association (N.F.P.A.) Class B extinguishers (Carbon dioxide, dry chemical or foam).
SPECIAL FIRE FIGHTING PROCEDURES: ffater nay be ineffective, but may be used to cool closed containers to prevent pressure buildup or possible auto ignition when exposed to extre^.heat (fog nozzles preferred). Hear self-contained breathing apparatus. For combustion products/ see Section V beloW under HZD decomposition products.
tmUSUAL FIRE AND EXPLOSION HAZARDS: Keep containers tightly closed. Isolate from heat» electrical equipment, sparks and open flame. Closed containers may explode when exposed to extreme heat. Do not ctpply to hot surfaces.
V - R E A C T I V I T V D A T A
^^TABILITY: stable HAZARDOUS POLYMERIZATION: Will Not Occur
CONDITIONS TO AVOID: N.Av.
INCOMPATIBILITY (Materials to avoid)i Strong oxidizing agents.
HAZARDOUS DECOMPOSITION PRODUCTS: Carbon dioxide, carbon monoxide and nitrogen oxides in varying quantities.
V I . H E A ] L i T » H A Z A R D D A T A THRESHOLD LIMIT VALUE: See Section III for individual ingredients.
EFFECTS OF OVEREXPOSURE: PRIMARY ROUTE(S) OF ENTRY:Inhalation iK Skin Contact
SKIN CONTACT AND ABSORPTION: Contains materials which nay cause skin irritation.
EYE CONTACT: Contains materials which may cause eye irritation and eye injury.
NOTE - N.Ap. denotes Not Applicable - N.Av. denotes Not Available
PRODUCT'VTENNANT STS (420) - S tu . T r a i f i c Two-Coat System ^^*
V I I . • E > 3 R E V E N T I V E M E A . S U I % E S
^ ' £ 3 ± H c^ar ILM^SLI^ . R3kroGeic3,\:L3r^!5 STEPS TO BE TAKEN IF MATERIAL IS RELEASED OR SPILLED: Remove all sources of ignition (flames, hot surfaces and electrical, static or frictional sparks). Avoid breathing vapors. Ventilate ai?ea. Remove with inert absorbent/scrub with soap and water.
WAST:;^ DISPOSAL METHOD: Dispose of in accordance with federal, state and local regulations.
sci-a.! Rarc3-t^^"t±on I n f c93rznei-^±on RESPIRATORY PROTECTION (specify type): Wear a chemical respirator approved for organic vapors (NIOSH 23C or equivalent) during the application and until the work area has been exhausted of all vapors. VENTILATION: Provide local exhaust ventilation to keep vapor concentrations below TLV (see Section II). PROTECTIVE GLOVES: Impervious gloves; i.e., rubber EYE PROTECTION: Chemical splash goggles SKIN PROTECTION:
^^otective clothing, such as uniforms or coveralls and protective gloves. ^»under clothing when soiled.
S p ^ c 3 ± e i X P3r^c:a.u.-b.±<Dns PRECAUTIONS TO BE TAKEN IN HANDLING AND STORAGE: Store in a cool (below 100 deg. F.) dry place. Store large quantities in buildings designed and protected for storage of NFPA Class IC Flammable liquids.
OTHER PRECAUTIONS: Do not take internally. Avoid prolonged contact with skin; contaminated clothing should be removed Immediately. Avoid free fall of liquid in excess of a few inches. Do not spray apply this product.
This Material Safety Data Sheet (MSDS) has been prepared in compliance with the Federal OSHA Hazard Communication Standard 29 CFR 1910.1200.
The Information and recommendations contained herein are based upon data believed to .be correct. However, no guaranty or warranty of any kind expressed or Implied in made with respect to the information contained herein.
NOTE - N.Ap. denotes Not Applicable - N.Av. denotes Not Available
WALLS AND CEILINGS
Pitt'Guaixl^ 97-Line Direct-Tb-Rust Coating
PRODUCT DESCRIPTION PROOUCTS PU-Quatd^ DIrectToflust Coating 97-147 Beige (Component A) 97-148 Gray (Component A) 97-149 Catafyet (Component B)
TYPE Polyamide-epoxy, two component
RECOMMENDED USE Intended for interior^xterlor use where one coat high build barrier type protection te tequired for properly prepared metal stdjstrates such as steel, aluminum, or hot dipped galvanized steel, and for use on prc^Mrly prepared masonry. Its excellent
itting properties allow applicallon and performance over tightly adhering
rust. Excellent performance Is obtained over sandblasted steel surfaces.
Setf-prlming: Does not require topcoating to achieve Its banler properties, but may be lopcoated for esthetic reasons. See "Application Limitations". Consult your Pittaburgtfi Paints Sales Representative (f your requirements differ from those contained in PPG coating systems.
^ j w ^ r .^^^ood
COLORS . 97-147lf149 Beige, approximates Pittsburgh* Paints Interior pastel color t24BS. 97-148/149 Gray, approximates Pittsburgh* Paints standard Light Gray cofor represented on the HDM color card, F. Adv. 621. These products discolor with age. See 'Application Limitations".
TINTING Cannot be field tinted.
SHEEN !5-45 typical (60" gloss meter) loss is not controlled.
PERCENT SOLIDS BY WEIGHT (MIXED)
915% ± 2.0%
4/89
PERCENT SOLIDS BY VOLUME (MIXED) 853% 1 2J0%
FEDERAL ACCEPTANCES These products have been approved by the United Stales Department of Agriculture (USDA) for use on structural non-food contact or Incidental food contact surfaces in establishments operating under tlieir Meat and Poultry Inspection Progiani.
ENVIRONMENTAL STATEMENT Formulated to contain less than 006% lead in the dried film. Each batch Is tested to verify that lead contamination has not occurred.
APPLICATION DATA
PPG COATING SYSTEMS For details of coating systems involving these products, see PPG Heavy Duty Coatings 3-rlng binder. Systems number 221-HD, 222-HD, 223-HD. 224-HD, 226-HD and 230-HD are applicable.
SURFACE PREPARATION Nen-lmmerslon service: MINIMUM SURFACE PREPARATION for ferrous metal substrates is WIRE BRUSHINQ (SSPC-SP 2, Hand 1bol Cleaning) to remove all loose ruist and paint as always. Service life Is indirect proportion to quality of surface preparation. Concrete surfaces should be acid etched or brush blasted.
Immersion service: While Metal Blast (SSPC-SP 5) is mandatory for ferrous substrates.
MIXING DIRECTIONS Mix cotiiponenls thoroughly bolore blond-Ing. Add 97-149 Component "B ' lo 9M47 or 97-148 Component "A" and blend well prior to use. Due to the high viscosity ol both components, a mechanical nilx?r should bo used. Improper mixing (such as hand mixing or stirring witii a slick Or spatul^ may lead to improper cure.
APPLICATION METHODS Air or altiess spray preferred. Small areas may be brushed. Roller application may be made using special reduction techniques.
APPLICATION EQUIPMENT Airless spray: Equipment capable ot mairv lalning a minimum of 1500 psi at the tip. 0017" (0.43mm) to 0.021" (0£3mm) orince. Conventional spray: DeVilbiss MBC-510 or JGA gt!n, 704 or 765 air cap with E or EX tip nnd needle. Sinks model 18 gun. 63PE air nozzle, 66 material nozzle or equivalent equipment.
Brush: Use a Gold Sttlptf Mark V polyestei/nylon brush. Roller: Use a Gold Striped Mark V loller cover.
THINNING Airless: Thin 10% by volume with PPG 97-725. Thinner. Conventional spray: Depending upon job conditions, thin up to 25% by volume with PPG 97-725. Thinner. Brush or roller: Thin 15-20% by volume witli PPG 97-734. Thinner. NOTE: When recoating alkyd systems where PPG 97-725, Thinner, creates a Hfling problem. PPG 97-727. Thinner, may be used to thin Pitt-Guard DTR Coating. The use of 97-727 provides less flow of the applied coating, shorter pot life and may result In pinlioles if the sutntrate Is at a temperature ol 100''F (37.7°C) or higher. Therefore, the PPG 97-725, Thinner, should be used whenever possible.
DRYING 1IME ASTM D-ieno, 77"F (25"'C) and 50% Relative Humidity Dry to touch: 8 hours Dry to hnndle: Overnigtil Recoat: Overnight Immersion Service: 7 days minimum Curing is retarded below 60''F (155<'C)
E-13
f — wi
A l h l ^ H l
or LIFE r A five UB gallon mix has ^ four hour vork-ing pot life at 77<*F (250C)/50% -iSi. when
hmed 25% with PPG 97-725. Thinner. Higher temperature or less thinning will shwten this l ima
RECOMMENDED WET FILM PER COAT
Unthinned &9-a2 mils
RECOMMENDED DRY FILM PER COAT
5-7.niii8
RECOMMENDED SPREADING RATE
195-274 sq. n. (1&1—25.4m*) at 5J0-7J0 mils dry film per U.8. gallon (178 L).
Coverage figures do not Include bss due to mixing, transfer or application of paint, nor loss due io surlace Irregularities or porosity.
CLEANUP
PPG 97-725, Thinner or 97-727, Thinner.
APPLICATION PRECAUTIONS
Apply only when air, product, and surface ^wnperatures are above 50<'F (lO'C). and ^Pmface temperature is at least S'F (H'C)
above tlie disw point.
Avoid exterior painting late in the day when dew or condensation Is likely to fonn or when rain threatens.
LIMITATIONS IN-SERVICE TEMPERATURE LIMITS
Dry: 250«F (122°C) Maximum
Immeralon aerv lce: 150*F (66°C) Maximum
.*.; CCutlon mi J t.4 U8»^ wh<in 6..lect-I j coatings lO. UvO on all galvanized metal
i> if c 48. • e je sutistrates ntay hive a ' tor/-ap,jn 7d stabilizer \/hl -!h Is ujed to •uevent white rusting during storage and shipping. In solvent degreasing operations, some of these stabilizers are not soluble in Ihe solvents. The stabilizers remain on the surface and prevent the paint from gaining maximum adhesion. Such stabilizers must t>e removed by either brush blasting or ciiemlcai trealmenL Contact your PPG Technical Service Representative or call 1-800-441-9695 for additional and current information on galvanized steeL
Hot rolled steel presents another potential adhesion problem. Due to Ihe difference in coefficient of expansion between steel and mill scale, disbanding ol the mill scale wilt occur over a period of time. Tills dis-bondment will be very rapid under thermal cycling conditions and when aggressive exposures such as frequent wet conditions or chemical environmenis are Invohted. The initial adhesion of mill scale to steel varies dramatically. For this reason, hot rolled steel should be prepared by abrasive blast cleaning whenever possible.
Like most poiyamide-epoxies, PHt-Guard DTR Coating loses gloss and chalks on exterior exposure. Film integrity is not affected. The solvents contained in Pitt-Guard u r n Coating may lift some aged alkyd films. A test patch Is recommended prior to application. Alkyd-oll coatings do not gain suitable adhesion when applied to Pitt-Guard DTR Coating. They are not recommended as topcoats.
The chemistry of this product causes Ihe film lo yellow. Yellowing continues as the film ages and may vary with application conditions. The color drift does not detract from coating performance.
When colorfastness is an Issue. Pitt-Guard DTR Coating sliould be lopcoated.
WEIGHT PER U.S. GALLON (MIXED)
97-147—12.2 lbs. (5.53kgs) ± 0.4 lbs. (182 gms) 97-148—12.0 lbs. (5.45kgs) ± 0.4 lbs. (162 gms)
FLASH POINTS
97-147.97-148 and 97-149,85"'F (29.4»C) Pensky^Martens
APPUCATION LIMITATIONS
Do not apply over toose or flaking rust or paint. All loose rust must be removed by wire brushing or other mechanical means. Not recommended for use In swimming pools.
PACKAGING Materials are packaged separately as 97-148 or 97-147, Component "A" and 97-149. Component "B". Full fill one U.S. Gallon (a78 L) and live U.S. Gallon ( ia9 L) containers are available.
E-14
MAi'ERxM . J \ l£xTl )ATM SHE5T COATINGS AND RE ^ N S GROUP
8£'C>.^I0.I X PPO INDUSTRIES INC. 260 KAPPA DRIVE PITTSBURGH. PA 15238
MSOS CONTACT: HANAOER, INDUSTRIAL HYGIENE AND PROOUCT SArETY
MANUFACTURER'S NAME PRODUCT SAFETY LOC.
EMERGENCY TELEPHONE:
FilODUCT Xi FORMATION CODE/IDENTITY ! 9 7 - F TRADE NAME: PITT GUARD 'A* CWPONENTS CHEMICAL FAMILY: POLYAHIDE US-DOIrPAINT, FLAHHAOLE LIQUID DATE or PREPARATION: 11/09/87 CUSTOMER PART ff: i
•»-r
V-U1 TM<I
(«12) 963-5822 (30«) 843-1300
SECTION I I - INGREDIENTS
ClAT TITANIUM OIOXIOE « NORMAL BUTYL ALCOHOL METHYL ISOBUTYL KETONE FILM FORMERS, RESINS, AND ADDITIVES
MAXIMUM XUT.
50 IS
1 10 30
CAS NO.
NOT EST. 13«6S'67-7 71-36-3 108-10-1 PROTRIETARY
E X P O S U R E L i ACGIH TLV OSHA PEL
NOT EST. NOT EST. 10.00Mg/H3 15.00Mg/M3 50.00PPM 100.00PPM 50.00PPM 100.00PPH NOT EST. NOT EST.
M 1 T S PPG IPEL
NOT EST. 10.00Hg/H3 SO.OOPPM 50.00PPM NOT EST.
CARCINOGENIC ACCORDING TO CRITERIA ESIABLISHED BY: * « NIP •* B IARC 8 > OSHA ff > OTHER SECTION I I I - PHYSICAL/CHEMICAL CHARACTERISTICS
BOILING RANGE : 1U • 194 OEG.C S0LUBILI1Y IN UA1ER: <1 S VAPOR PRESSURE: <15 imillg UT/GAL (LBS): 12-13 (U.S.) VAPOR DENSITY ; HEAVIER THAN AIR pH: U/l X VOl/VOLUHE : 24-25 X SOLID BY WEIGHT: 86-88 EVAP RATE(BuOAc-IOO): <15 SPECIFIC GRAVITY: 1.4 • 1.6
SECTION IV - FIRE AND EXPLOSION HAZARD DATA US-DOT CATEGORY: FLAMMABLE FLASHPOINT: 85 DEG. F PMCC FlAHHAniE LIMITS: LEL 1.3 UEL U/l
EXTINGUISHING MEDIA; USE NATIONAL FIRE PROTECTION ASSOCIATION (NFPA) CLASS B EXTINGUISHERS (CARaOfl DIOXIDE. DRY CHEMICAL, OR UNIVERSAL AOUEOUS FILM FORMING FOAM) DESIGNED 10 EXTINGUISH NFPA CLASS IC FLAMMABLE LIQUID FIRES.
UNUSUAL FIRE AND EXPLOSION HAZARDS; KEEP CONTAINERS TIGHTLY CLOSED. ISOLATE FROH HEAT, ELECTRICAL EOUIPHENT, SPARKS, AND OPEN FLAMES. CLOSED CONTAINERS HAY EXPLODE UHEH EXPOSED TO EXTREME HEAT. DO HOT APPLY ON HOI SURFACES. TOXIC GASES HAY FORM WHEN PROOUCT IS fONTACTED BY FIAHE OR HOT SURFACES.
SPECIAL FIRE FIGHTING PROCEDURES: WATER SPRAY MAY BE INEFFECTIVE. WATER SPRAY HAY BE USED TO COOL CLOSED CONTAINERS TO PREVENT PRESSURE BUILDUP AND POSSIBLE AUIOIGNITIOH OR EXPLOSION WHEN EXPOSED TO EXTREME HEAT. IF WATER IS USED, FOR NOZZLES ARE PREFERABLE. FIRE-FIGHTERS SHOULD WEAR SELF CONTAINED BREATHING APPARATUS.
SECTION V - REACTIVITY DATA STABILITY; STABLE HAZARDOUS POLYMER IZAUON; NOI EXPECTED TO OCCUR INCOHPAIIBILITY (HATERIALS AHD CONDIHOMS 10 AVOID);
AVOID CONTACT UITH STRONG ALKALIES. STRONG MINERAL ACIDS, OR STRONG OXIDIZING AGENTS. HAZARDOUS DECOMPOSITION PRODUCTS;
HAY PRODUCE HAZARDOtS DECOHPOSITION PRODUCTS WHEN HFATED. FLAME-CUTTING ON SURFACES COATED UITH THIS PROOUCT HAY PRODUCE FUMES
Carbon Monoxide, Oxides of Nitrogen SECTION VI •> SPILL OR LEAK PROCEDURES
STEPS TO BE TAKEN IN CASE HA1ERIAL IS RELEASED OR SPILLED: PROVIDE HAXIHUH VENTILATION. ONLY PERSONNEL EQUIPPED WITH PROPER RESPIRATORY ANO SKIN ANO EYE PROTECTION SHOULD BE PERMITTED IN THE AREA. REMOVE ALL SOURCES OF IGHIIIOU. TAKE UP SPILLED MATERIAL WITH SAWDUST, VERMtCULITE, OR OTHER ABSORBENT MATERIAL AND PLACE INTO CONTAINERS FOR DISPOSAL.
WASTE DISPOSAL METHOD; WASTE MATERIAL MUST BE DISPOSED OF IN ACCORDANCE WITH FEDERAL, STATE, AND LOCAL ENVIRONMENTAL COHIROL REGULATIONS. EMPTY CONTAINERS SHOULD BE RECYCLED OR DISPOSED OF THtOUCH AN APPROVED WASTE HAHAGEHENT FACILTY.
SECTION VII - HEALTH HAZARD DATA EFFECTS OF OVEREXPOSURE FROH;
INGESTION; HARMFUL OR FATAL IF SWALLOWED.
WELDING, BRAZING, OR INCLUDING:
EYE CONTACT:
SKIN CONTACT: CAUSES SEVERE EYE IRRITATION.
HAY CAUSE MODERATE SKIN IRRITATION. HAY BE ABSORBED THROUGH THE SKIN.
INHALATION: VAPOR AND SPRAY MIST HARMFUL IF INHALED. VAPOR IRRITATES EYES, NOSE, ANO THROAT.
CONTINUED ON PAGE 2
IN - rxANT HAZARD | RATI NO
t C A L I I I FLAraiARILITY PEACTIVITV PmiTCCTIVE COUIPnENT
3 3 0
>AGE 2 i j ZAP Continuation Of Manufaeturtr's Code - S T ^ F 0 .lE uF PREP: i1/09/8« mJ^W
k'- REPEATED EXPOSUKE TO HIGH VAPOR COHCEHTRAUOIIS AM CAUSE IRRITATION OF THE RESPIRATORY ' SYSTEM ANO PERMANENT BRAIN ANO NERVOUS SYSTEM DAMAGE. INTENTIONAL MISUSE BY DELtriERATELV COHCEHiRATlHG AW> ..IKMLING THE CONTENTS CAN BE HARMFUL OR FATAL.
CNROHIC OVEREXPOSURE: AVOID LONG-TERM AND REPEATED CONTACT. THIS PRODUCT CONTAINS TITANIUM OIOXIOE. ANIMALS INHALING MASSIVE QUANTITIES OF TITANIUM DIOXIDE DUST IH A LONG-TERN STUDY DEVELOPED LUNG TUMORS. STUDIES WIIH HUtlAUS-INVOLVED IH MANUFACTURE OF THIS PIGMENT INDICATE NO INCREASED RISK OF CANCER FROM EXPOSURE. POTENTIAL FOR INHALATION OF TITAKIUM DIOXIDE DUSTS FROM COATINGS IS VERY LIMITED ANO OVEREXPOSURES ARE NOT EXPECTED.
yjCWS A W SYMPTOMS OF OVEREXPOSURE: EYE WATERING, HEADACHES, NAUSEA. DIZZINESS. AND LOSS OF COORDINATION ARE INDICATIONS THAT SOLVENT LEVELS ARE TOO HIGH. REDNESS, ITCHINO. BURH'NG SENSATION AND VISUAL DISTURBANCES MAY INDICATE EXCESSIVE EYE CONTACT. DRYNESS. ITCHING. rRACKINC, BURNING. REDNESS, AHD SWELLING ARE CONDITIONS ASSOCIATED WITH EXCESSIVE SKIN CONTACT.
t^lPH WHPITIPMS ^^'^'g^feafegEV^h '^ ' ^ ^ i S ^ A l D PROCEDURES
IF SWALLOWED, DO NOT INDUCE VOMITING. BYE WWTWT;
y c i a CONTACT;
INHALATION:
OTHER:
IN CASE OF EYE CONTACT. FLUSH EYES IHHEDIATELY UITH PLENTY OF WATER FOR AT LEAST 30 MINUTES.
IN CASE OF SKIN CONTACT, FLUSH IMMEDIATELY WITH PLENTY OF WATER FOLLOWED BY WASHING WITH SOAP AND WATER.
IF AFFECTED BY INHALATION OF VAPOR OR SPRAT HIST, REMOVE TO FRESH AIR. APPLY ARTIFICIAL RESPIRATION AND OIHER SUPPORTIVE HEASURES AS REQUIRED.
IF ANY OF THE FOLLOWING OCCUR DURING OR FOLLOWING USE OF THIS PRODUCT, CONTACT A POISON CONTROL CENTER, EHERGENCY ROOM OR PHYSICIAN IMMEDIATELY; HAVE MATERIAL SAFETY DATA SHEET INFORMATION AVAILABLE. 'INGESTION 'EXCESSIVE EXPOSURE TO A CORKOSIVE MATERIAL. • PERSISTENT SKIH/EYE IRRITATION OR BREAIHIHG OirFICULTIES.
SECTION IX - PROTECTION INFORMATION PERSONAL PROTECTIVE EQUIPMENT FOR;
EYE PROTECTION; WEAR CHEMICAL-TYPE SPLASH GOGGLES OR FULL FACE SHIELD.
SKIN PROTECTION: WEAR PROTECTIVE CLOTHING. INCLUDING IMPERMEABLE APRON ANO GLOVES CONSTRUCIED OF:
POLYVINYL ALCOHOL, LATEX RUBBER OR NITRILE RUBBER KESPIRATORY PROTECTION;
OVEREXPOSURE TO VAPORS HAY BE PREVENTED BY ENSURING VENTILATION CONTROLS, VAPOR EXHAUST OR FRESH AIR ENTRY. NIOSH/MSHA-APPROVED (TC-23C-) PAINT SPRAY OR AIR StirPLIED (TC-19C-) RESPIRATORS HAY ALSO REDUCE EXPOSURE. READ RESPIRATOR HANUFACTURER'S INSTRUCTIONS AND LITERATURE CAREFULLY TO DEIERHIHE THE TYPE OF AIRBORNE COHIAHINANIS AGAINST WHICH THE RESPIRATOR IS EFFECTIVE ANO HOW IT IS TO BE PROPERLY FITTED. '
OTHER EQUIPMENT: CLEAN OR DISCARD CONTAMINATED CLOTHING ANO SHOES.
VENTILATION REQUIREMENTS: PROVIDE GENERAL DILUTION OR LOCAL EXHAUST VENTILATION IN VOLUME ANO PATTERN TO KEEP THE CONCENTRATION OF iN(.h..:;lENTS LISTED IN SECTION II BELOW THE LOWEST SUGGESTED EXPOSURE LIMITS, THE LEL IN SECTION IV BELOW THE STATED LIMIT, AND TO RLMOVE DECOMPOSITION PROOUCTS DURING WELDING OR FLAHE CUTTING ON SURFACES COATED WITH THi; PROOUCT.
SECTION X - SPECIAL PRECAUTIONS HANDLING AND STORAGE PRECAUTIONS;
DO NOT STORE ABOVE 120 DEGREES F. STORE LARGE QUANTITIES IN BUILDINGS DESIGNED AND PROTECTED FOR STORAGE OF NFPA CLASS IC FLAMMABLE LIQUIDS.
OTHER PRECAUTIONS; IF THIS MATERIAL IS PART OF A MULTIPLE COMPONENT COATING SYSTEM, READ THE MATERIAL SAFETY DATA SHEET(S) FOR THE OTHER COMPONENT OR COMPONENTS BEFORE BLENDING AS THE RESULTING MIXTURE HAY HAVE THE HAZARDS OF ALL OF ITS PARTS. CONTAINERS SHOULD BE GROUNDED WHEN POURING. AVOID FREE FALL OF LIQUIDS IN EXCESS OF A FEW INCHES ALL CHEMICAL SUBSTANCES IM THIS PROOUCT COMPLY WITH All APPIICABIE RULES OR OfiOERS UHOER THE ENVIRONMENTAL PROTECTION AGENCY'S TOXIC SUBSTANCES CONTROL ACT.
THIS MATERIAL SAFETY DATA SHEET HAS BEEN PREPARED IN ACCORDANCE WITH THE OSHA HAZARD COMMUNICATION STANDARD (29 CFR 1910.1200}
U/l a UNKNOWN INFORMATION N/A > NOT APPLICABLE NOT ESI. s KOI ESTABLISHED
(CUSTOMER NO.) LOCATION : 8797/F//////1109
MiiTERIAL BAFExY DATA BHEET COATINGS M<D RESIIIB GROUP
^ | f »
'1
•i!
SECTION X tiANUFACTURER'S NAME: PPG IttOUSTRtES l*tC. PRODUCT SAFETY LOC.I 260 KAPPA DRIVE
PITTSBURGH, P A 15238 MSOS CONTACT: NANAGEH. INDUSTRIAL HYGIENE
AND PROOUCT SAFETY
PRODUCT XMFORMAjJXON C00E/IDENTI1T t 97-1 :49 TRADE NAME: PITT GUARD COMP. B CHEMICAL FAMILY: EPOXY US-DOT:PAINT • FIAHHABIE LIQUID DATE OF PREPARATION: 5/16/88 CUSTOMER PART it
( 0 4 0 4 8 8 E )
EHERGENCY TELEPHONE: (412) 969-5822 (304) 843-1300
SECTION IX - INGREDIENTS APPROX. E X P O S U R E
W T . CAS NO. ACGIH TLV OSHA PEL L I M I T S
PPC IPEL
SILICA. CRYSTALLINE QUART! 30 7631-86-9 .10Hg/N3 .10Ng/M3 .10Mg/N3 NITROETHANE 5 79-24-3 100.00PPH 100.00PPM 100.00PPN FILM FORMERS, RESINS, AND AODIT'VES 65 PROPRIETARY NOT EST. NOT EST. NOT EST.
THE FOLLOWING HAZARDOUS MATERIALS ARE COMPONENTS OF OIIE OR MORE OF THE ABOVE INGREDIENTS. OUARTI 30 14808-60-7 .10Mg/N3 .10Mg/M3 .10Mg/M3
SECTION III • BOILING RANGE : 138 • 202 DEO.C VAPOR PRESSURE: 14.1 DnHg VAPOR DENSITY : HEAVIER THAN AIR X VOL/VOLUME t 5.60 EVAP RATE(BuOAc*100): 11
SECTION IV US-DOT CATEG(mY: FLAMMABLE FLASHPOINT: 85 DEG. F PMCC
PHYSICAL/CHEMICAL CHARACTERISTICS SOLUBILITY IN WATER: 0.1 X
/ WT/6AL (LBS): 11.63 (U.S.) pH: U/l X SOLID BY WEIGHT: 95.93 (FORMULA VALUE.NOT A SALES SPECI SPECIFIC GRAVITY: 1.39
- FIRE AND EXPLOSION lUVZARO DATA FLAMMABLE LIMITS: LEL 3.4 UEL U/l
WELDING, BRAZING, OR
EXTINGUISHING MEDIA: USE NATIONAL FIRE PROTECTION ASSOCIATION (NFPA) CLASS B EXTINGUISHERS (CARBON DIOXIDE. DRY CHEMICAL. OR UNIVERSAL AOUEOUS FILM FORMING FOAM) DESICNEp TO EXTINGUISH NFPA CLASS IC FLAMMABLE LIQUID FIRES.
UNUSUAL FIRE ANO EXPLOSION HAZARDS; ' KEEP CONTAINERS TIGHTLY CLOSED. ISOLATE FROM NEAT. ELECTRICAL EQUIPMENT, SPARKS. AND OPEN FLAMES. CLOSED CONTAINERS MAT EXPLOOE WHEN EXPOSED TO EXTREME HEAT. DO NOT APPLY OH HOT SURFACES. TOXIC CASES MAY FORM WHEN PROOUCT IS CONIACIED BY FLAME OR NOT SURFACES.
SPECIAL FIRE FIGHTING PROCEDURES: WATER SPRAY MAY BE INEFFECTIVE. WATER SPRAY HAY BE USED TO COOL CLOSED CONTAINERS TO PREVENT PRESSURE BUILD-UP AND POSSIBLE AUTOIGNITION OR EXPLOSION WHEN EXPOSED TO EXTREME HEAT. IF WATER IS USED. FOG NOZZLES ARE PREFERABLE. FIRE-FIGHTERS SHOULD WEAR SELF CONTAINED BREATHING APPARATUS.
SECTION V - REACTIVITY DATA STABILITY: STABLE HAZARDOUS POLYMERIZATION; NOT EXPECTED TO OCCUR INCOMPATIBILITY (HATERIALS AND CONDITIONS TO AVOID);
AVOID CONTACT UITH STRONG ALKALIES, STRONG MINERAL ACIDS. OR STRONG OXIDIZING AGENTS. HAZARDOUS DECOHPOSITION PRODUCTS:
MAY PRODUCE HAZARDOUS DECOMPOSITION PRODUCTS WHEN HEATED. FLAME-CUTTING ON SURFACES COATED WITH THIS PROOUCT MAY PRODUCE FUMES INCLUDING:
Carlxm Monoxide SECTION VX - P9ZLL OR LEAR PROCEDURES
STEPS TO BE TAKEN IN CASE MATERIAL IS RELEASfcu OR SPILLED: PROVIDE MAXIMUM VENTILATION. ONLY PERSONNEL EQUIPPED WITH PROPER RESPIRATORY AND SKIN AND EYE PROTECTION SHOULD BE PERMITTED IN THE AREA. REMOVE ALL SOURCES OF IGNITION. TAKE UP SPILLED MATERIAL UITH SAWDUST. VERMICULITE, OR OTHER ABSORBENT MATERIAL AND PLACE INTO
; CONTAINERS FOR DISPOSAL. WASTE DISPOSAL METHOD:
WASTE MATERIAL MUST BE DISPOSED OF IN ACCORDANCE UITH FEDERAL. STATE. AND LOCAL ENVIRONMENTAL CONTROL R A U L A T I O N S . EMPTY CONTAINERS SHOULD BE RECYCLED OR DISPOSED OF THROUGH AN APPROVED WASTE MAHAGEMENT FACILTY.
SECTION V I I - HEALTH HAZARD DATA EFFECTS 0^ OVEREXPOSURE FROM:
INGESTION: HARMFUL OR FATAL IF SWALLOWED.
EYE CONTACT: CAUSES EYE IRRITATION.
SKIN CONTACT: HAY CAUSE SLIGHT SKIN IRRITATION.
CONTINUED ON PAGE 2
iR.riMi Miue 1 mm
KIIIN HtiXMIUH nwtivin miK im ^ t in t i i
11 J t
PACE 2 ? J7^ Ooncfnuatlon ef Nanufaeturcr'a Code • > 7 - 1 1 ^ DATE OF PitEPt 5/16/88
NAY BE ABSORBED THROUGH THE SKIN. PROLONGED OR REPEATED CONTACT MAY CAUSE AN ALlEROtC ^ I N REACTION.
INHALATION: VAPOR ANO SPRAY NIST NAY BE HARMFUL IF INHALED. SANDING ANO GRINDING DUSTS NAY BE HARMFUL IF INHALED. VAPOR IRRITATES EYES, NOSE, ANO THROAT. REPEATED EXPOSURE TO HIGH VAPOR CONCENTRATIONS NAY CAUSE IRRITATION OF THE RESPIRATORY SYSTEM AND PERMANENT BRAIN AND NERVOUS SYSTEM DAMAGE. INTENTIONAL MISUSE BY DELIBERATELY CONCENTRATING AND INHALING THE CONTENTS CAN BE HARMFUL OR FATAL.
CHRONIC OVEREXPOSURE: AVOID LONG-TERM AND REPEATED CONTACT. CONTAINS A FORM OF CRYSTALLINE SILICA. LONO-TERii EXPOSURES TO HIGH LEVELS OF TNIS MATERIAL HAY LEAD TO DISABLING LUNG INJURY KNOW AS SILICOSIS. THIS PROOUCT CONTAINS MITROETHANE. STUDIES WITH LABORATORY ANINALS HAVE SHOWN THAT INGESTION OR INHALATION OF HIGH LEVELS OF NITROETHANE CAUSES KIDNEY AND LIVER DAMAGE ANO CENTRAL NERVOUS SYSTEM EFFECTS.
IICNS AND SYMPTOMS OF OVEREXPOSURE: EYE WATERING, HEADACHES, NAUSEA. DIZZINESS, AND LOSS OF COORDINATION ARE INDICATIONS THAT SOLVENT LEVELS ARE TOO NIGN. REDNESS, ITCHINO, BURNING SENSATION AND VISUAL DISTURBANCES NAY INDICATE EXCESSIVE EYE CONTACT. DRYNESS, ITCHING. CRACKING, BURNINQ, REDNESS. AND SWELLING ARE CONDITIONS ASSOCIATED WITN EXCESSIVE SKIN CONTACT.
MEDICAL CONDITIONS AGGRAVATjO^BY KPOSURE: NOT APPLJCABLE J H V.
IfrnTlwil
SKIN CONTACT:
INHALATION:
B E C T I O t r V I I I - FIRST AID PROCEDURES
IF SWALLOWED, DO NOT INDUCE VOMITING.
IN CASE OF EYE CONTACT. FLUSH EYES IMMEDIATELY WITN PLENTY OF WATER FOR AT LEAST IS MINUTES.
IN CASE OF SKIN CONTACT, FLUSH IHHEDIATELY WITH PLENTY OF WATER FOLLOWED BY WASHING WITH SOAP AND WATER.
IF AFFECTED BY INHALATION OF VAPOR OR SPRAY NIST. REMOVE TO FRESH AIR. APPLY ARTIFICIAL RESPIRATION AND OTHER SUPPORTIVE MEASURES AS REQUIRED.
IF ANY OF THE FOLLOWING OCCUR DURING OR FOLLOWING USE OF THIS PROOUCT, CONTACT A POISON CONTROL CENTER, EHERGENCY ROOM OR PHYSICIAN IHHEDIATELY; HAVE HATERIAL SAFETY DATA SHEET INFORMATION AVAILABLE. 'INGESTION 'EXCESSIVE EXPOSURE TO A CORROSIVE MATERIAL. • PERSISTENT SKIH/EYE IRRITATION OR BREATHING DIFFinHTIES.
SECTION IX - PROTECTION INFORMATION PERSONAL PROTECTIVE EQUIPMENT FOR:
EYE PROTECTION: WEAR CHEMICAL-TYPE SPLASH GOGGLES OR FULL FACE SlilELD.
SKIN PROTECTION: WEAR IMPERHEABLE PROTECTIVE CLOTHING CONSTRUCTED OF NITRILE, NECTRENE OR LATEX RUBBER SUFFICIENT TO COVER THE ENTIRE BODY.
RESPIRATORY PROTECTION: OVEREXPOSURE TO VAPORS NAY BE PREVENTED BY ENSURING VENTILATION CONTROLS. VAPOR EXHAUST OR
, FRESH AIR ENTRY. NIOSH/MSHA-APPROVED (TC-23C-) PAINT SPRAY OR AIR SUPPLIED (TC-19C-) RESPIRATORS MAY ALSO REDUCE EXPOSURE. READ RESPIRAIOR HANUFACIURFR'S INSIRUCTIONS AND LITERATURE CAREFULLY TO DETERMINE THE TYPE »: K..BORHE CONTAMINANTS AGAINST WHICH THE RESPIRATOR IS EFFECTIVE AND HOW IT IS TO BE PROPERLY FITTED.
OTNER EQUIPWNT: * CLEAN OR DISCARD CONTANINATCP CLOTHINO AND SHOES.
VENTILATION REQUIREHENTS: PROVIDE GENERAL DILUTION OR LOCAL EXHAUST VENTILATION IN VOLUME ANO PATTERN TO KEEP THE CONCENTRATION OF INGREDIENTS LISTED IN SECTION II BELOW IHE LOWEST SUGGESTED EXPOSURE LIHITS. THE LEL IN SECTION IV BELOW THE STATED LINIT, AND TO RFMOVE DECOMPOSITION PROOUCTS DURING WELDING OR FLAME CUTTING ON SURFACES COATED WITN THIS PROOUCT.
SECTION X - SPECIAL PRECAUTIONS HAHDLINO AND STORAGE PRECAUTIONS;
00 NOI STORE ABOVE 120 DEGREES F. STORE LARGE QUANTITIES IN BUILDINGS DESIGNED AND PROTECTED FOR STORAGE OF NTPA CLASS IC FLAMMABLE LIQUIDS.
OTHER PRECAUTIONS: IF THIS MATERIAL IS PART OF A HUITIPIE COHPONENT COATING SYSTEH, READ THE MATERIAL SAFETY DATA SHEET(S) FOR THE OTHER COMPONENT OR COMPONENTS BEFORE BLrN?ING AS THF RESULTING NIXTURE NAY HAVE THE HAZARDS OF ALL OF ITS PARTS. CONTAINERS SHOULD BE GROUNDED WHEN POURING. AVOID TREE FALL Of LIQUIDS IN EXCESS OF A FEU INCHES. ALL CHENICAl SUBSTANCES IN THIS PRODUCT CONPLY UITH ALL APPLICABLE RULFS OR ORDERS UNDER THE ENVIROMHENTAL PROTECTION AGENCY'S TOXIC SUBSTANCES CONTROL ACT.
THIS MATERIAL SAFETY DATA SHEET HAS BEEN PREPARED IN ACCORDANCE WITH THE OSHA HAZARD COMMUNICATION STANDARD (29 CFR 1910.1200)
U/l » UNKNOWN INFORMATION N/(l » NOT APPLICABLE NOI EST. « NOT ESTABLISHED
CERT. LTR." CHEMICAL O.K. ON TSCA INVENTORY; CAS NO. NOT AVAILABLE (CUSTOMER NO T. LOCATION : e097/149/////516
APPENDIX B EMPLOYEE AWARENESS LOG
EMPLOYEE AWARENESS LOG DICO. INC. - DES MOINES. IOWA
The follawltig etetenient is to be reaif by nil DICO nniplnyons Hint will pf i i fni in wnik wtll i i i i Buildings No. 1 Utrough No. 5 and the Molntetinnoe t3uildiiig. 11to 0|iata(luii & iv1nlMtonnni;n T'Inn la Rvallable to anyone wlio wishes to leviow I t Tlioii slgnotuie will lepiesoiiL consent to llto loiluwiny
" I hevf l been ve i f ia l l y i n fo rmed and a l lowed t f io op t ion of tov inw ing t l io Opa tn l i on & Mni i i tnnanoe - F l a n for Dul ld lnga No . 1 t h i n u g h No . 5 and t l io Ma i i i leno i ioe Uu i ld iny . I Ids i n fu tmn l i on axpln ina t o m n t l i e Impor tanoo of p ro leo t ing t l io au i foco ooot lnga w i l l i i n t l io bu i ld ingn. I undora lnnd t l i a t If I onose domnga to t l io ooat i i ig or dotoot auc i i domago I am tu rapo i t l l i i a fn fo rma l ion immedia te ly to the P lant Eng ineer or o l i io r respone ib lo personne l . *
DATE EMPLOYEE NAME
(PRINI) EMPLOYEE SIGNAIURE
«
,
•
SS NUMBEI't
EMPLOYEE AWARENESS LOG DICO. INC. • DES MOINES. IOWA
l l i e followltig etatenient is to bo read by nil DICO nniployees titat wil l pni fni in wni Ic witli ln Buildings No. 1 tiirougli No. 5 and tl in Mninlonnnno Building. Tlio Opoinii ' in & MnliitnnnuRn Plnii is available to anyone wlio wishes to review i t Tiioir sigiietuio vyill lepioscnt uonscnt Lo the lulluwing • ta lement
* l have boon verba l l y In fo rmed and a l lowed t l io np t len of rov inwing the O p m n i l o i i 8i Mn in lnnonco Plea fo r Bu i ld ings No. 1 th rough No . 5 end the Ma in tenance ' i u i h l i n g . I h i s i n l n i i i i n l i on oxf i ln ins t o mo the Impor tenoo of p ro leo t ing the su t faco ooat lngs w i l l i i n thu bu ih ih igs . I i i i i dn ts ln i i d t ha t If I oHuse damage to the ooa l i i i g or do loc t suo l i damage I am to l o p o i l Ih is I n ru imn l i on immedia te ly t o the P lant Eng ineer or other respons ib le personne l . *
DATE EMPLOYEE NAME
/ - (PniNI) EMPLOYEE SIONAIUni:
»
•
ssi-iUMuint
EMPLOYEE AWARENESS LOG DICO. INC. - DES MOINES. IOWA
The following etatenient is to be teed by all DICO nniplnyees that wil l pnifnmi woik wilhli i Buildings No. 1 through No. 5 and the MalnlniianRo Building. The Opointinn & MnliKniiniHsn Plan is available to anyone vdio wisiias to review i t Tlioir slgnatUio will rRproseiil nonsoiit lo (hn Inllnwiiig statement
* l have been verba l ly In fo rmed and a l lowed the opt lo i i b f tev low ing t l io Opnrn i ion ft Mn in lonanoe P lan for Bu i ld inge No . 1 th rough N o . 5 end the Maintenenoe l l u i i i l i ng . I l i i s l i i l n r inn l ion exp ia ins
' t o m a tha hnpo t lanoe of p ro tec t ing the su i f oco oont i i igs w i th in t l io l i i i i l i l i i i gs . I i i i i d n i s l m i d tha t If I OMUse damage to the eoat l i tg or de tec t s u c h daniago I a m t u i n p o i l t h i s i n l u i m n t i u n immedia te ly t o the P lant Eng ineer o r other respons ib le p e i s o n n o L "
DATE EMPLOYEE NAME
(PRINI) EMPLOYEE SIGNAI URE S3 NUMBER
EMPLOYEE AWARENESS LOG DICO. INC. - DES MOINES. IOWA
l l i e followiiig etatenient is to be reed by ell DICO anipioyees that will peiforni woilc wil l i in Buildings No. 1 through No. 5 and tl ie Melnlennnoe Building. The Operation & Maintenencn Plan Is available to anyone wito wishes to review I t 1 lieir sigiislui e will repi eseitt oonseiit to the following •tatentent
1 l iava been verba l ly In fo rmed and a l lowed the opt ion o f rev iewing t l i e Opera t ion ft Mn in lnnanee P lan fo r Bu i ld ings No . 1 th rough No . 5 and the Main tenenoe Bu i l d ing . 1 h i s i n fo rma l ion exp ia ins
' t o m e the Impor lanee o l p rn teo l i ng the su r face ooo l ings w i i h i n the bu i ld ings . I unr iorn land tha t If I cause damage to the ooet ing or de tec t such damage I e m to repor t th i s In fo imet ian Immedia te ly to the P lant Eng ineer or o ther respons ib le pe rsonne l . "
DATE EMPLOYEE NAME
(PRINI) EMPLOYEE SIONAIURE
V
SS NUMBER
.• -
»
APPENDIX C MONTHLY INSPECTION REPORT
MONTHLY INSPECTION REPORT DICO, INC. • DES MOINES, lOVv'A
NAME/TITLE OF INSPECTOR:
DATE:
. BUILDING
1 No. 1
Na2
No. 3
No. 4
J No. 5
|. MAINTENANCE
WALLS
..
CEIUN6S AISLES GENERAL COMMENTS
/
NOTES: Check Mark intiicates No Damage Present An 'X " Incficates Damage Is Present; Sped^y General Locatkin In Comments Section
APPENDIX P ANNUAL INSPECTION REPORT
A N N U A L INSPECTION REPORT G E N E R A ^ a ^ S U L T S
DICO. INC. - DES MOINES. IOWA
NAME/THLE OF INSPEC1 OR:
OATE:
B U I L U I N Q
• No. 1
No. 2
No. 3
No. 4
No. 5
MAINTENANCE
W A U . S C E I U N U S A I S L E S G E N E R A L C O M M E N 1 S
NOTES: Cliecic Mai It Indioatas No Damage Present Al l ' ^ ' ' liidioales Damage Is Piasent; Spaoify General Looalion in Coniii iaii ls Sacliuii
INSPECTOR - PROVIDE DETAILED ACCOUNTS OF INSPECTION ACTIVITIES ON FOLLOWING PAGES
A N N U A L l'>4SPECTION REPORT BUILDING No. 1 - DETAILED INSPECTION
FLOORS:
CEILINGS:
WALLS:
ANNUAL INSPECTION REPORT BUILDING No. 2 - DETAILED INSPECTION
FLOORS:
CEIUNGS:
WALLS:
ANNUAL INSPECTION =^E.^ORT BUILDING No. 3 - DETAILED INSPECTION
FLOORS:
CEILINGS:
WALLS:
ANNUAL INSPECTION REPORT BUILDING No. 4 - DETAILED INSPECTION
FLOORS:
CEILINGS:
WALLS:
ANNUAL INSPECTION REPORT BUILDING No. 5 - DETAILED INSPECTION
FLOORS:
CEILINGS:
WALLS:
ANNUAL INSPECTION REPORT MAINTENANCE BUILDING - DETAILED INSPECTION
FLOORS:
CEILINGS:
WALLS:
APPENDIX E PERIODIC SAMPLING TABLE
OMSLOGJ(LS
PERIGDiC SAMPLE SUMMARY DICO, INC.-OES MOINES, lOVUA
SAMPLE IDENTIFICATION
SW- -1
SW- -2
SiN- -3
svy^ -4
SW- -5
SW- -6
SW- -7
SW- -8
SW- -9
SW-
SW-
SW-
SW
SW-
^ SW-
SW-
SW-
SW-
SW- .
SW- •
SW- •
SW- .
SW- •
•10
•11
•12
•13
•14
15
•16
•17
•18
-19
20
21
22
23
SAMPLE DATE
SAMPLE COLLECTOR
SAMP WALL
LELOCATI CEILING
ON* FLOOR
NOTES: • - PROVIDE GENEHAL AREA. SUCH AS NORTH W A U OR SOUTHEAST CEILING CORNER; EXACT LOCATIONS TO BE ON PLANT LAYOUT
Pagel
APPENDIX F FIRE ALARM EMERGENCY RESPONSE PLAN
il
%
r
XZ. II.
Fire Alarm Emergency Response Plan
1. On shift safety desiipiate iv'ill call 9-911.
Report address, 200 S.W. 16th St., report t y p a of cmerjiency, State
your name and title.
2. If necessary the designated safety person will dial 88 and page
to evacuate the building.
3. Send someone to the gate at 17th § Wabash, send someone to the
gate at 16th St. to direct the fire equipment to the proper place.
No one sliall enter die building until the emergency personnel gives
the " all clear ".
Supervisors will do a liead count vhen all employees are in the designated
evacuation gathering place. ( The lot east of the receiving dept.)
V.'hcn the all clear signal is given by the fire chief, your supervisor
vill enter the building and ascertain if conditions are safe to return
to work. If all is well, onployees will return to v.*ork on the supervisors
all clear report.
This planrds to be reviewed with all employees periodically.
APPENDIX G EMERGENCY EVACUATION PROCEDURES
HMEIifiENGT R'AaiMION PRCXTEIXIRE
Tlie safety ilbsignate will sound emergency evacuation on the P.A.
system. Should P.A. be out, this person will contact area supervisors
who will evacuate their individual areas. Evacuation routes will be
posted at all i;atcr fountains and time clocks. Employees will meet in
parking lot East of Recieving until their supervisor can get a proper
count of evacuees. Should this lot be dangerous, ( Fire equipment, etc.)
employees will meet in tlie parking lot Itorth of lOS.
Please remain in this area until the "all clear" is given by your
supen'isor. Gieck on your friends, remember whd tvas working next to you.
Report any missing persons to the supervisor or person in cliargc.
APPENDIX H TORNADO SAFETY GUIDELINES
E I
TOmiADO SAFETY
Tlie factory has been inspected by the Dept. of Public Defense to
determine the Safest place for a tornado shelter area.
It was determined that the safest place is the east side of the
cast wall of tlic paint department, bcDveen the tico doors into the
paint department.
Dico Company has purchased a weather alert radio, and in case of a
tornado warning, wc will announce for all employees to go to the
tornado shelter area.
aClOCATlOf >...r FL08
APPENDIX I NOTIFICATION LETTERS
A . . . - • * * • - • '.• * '
r 1 >
t
!
i
...
1
J I t .
