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© 2018 Activated Research Company, LLC© 2018 Activated Research Company, LLC
Recent Advances in Catalysis for the Measurement of CO, CO2, and
Formaldehyde
Rajvi Mehta
October 17, 2018
Gulf Coast Conference
© 2018 Activated Research Company, LLC© 2018 Activated Research Company, LLC
Measuring CO, CO2, & Formaldehyde
• Applications• Ethylene/propylene
production
• Air quality
• Transformer oil gas analysis
• Renewable Fuels
• Beverage
• Catalysis
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© 2018 Activated Research Company, LLC© 2018 Activated Research Company, LLC
Measuring CO, CO2, & Formaldehyde
• Applications• Ethylene/propylene
production
• Air quality
• Transformer oil gas analysis
• Renewable Fuels
• Beverage
• Catalysis
• Analytical Techniques• GC-TCD
• GC-MS
• GC-Methanizer-FID
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© 2018 Activated Research Company, LLC© 2018 Activated Research Company, LLC
Packed Capillary
Columns
HP 5890 Agilent Intuvo
GCs
Photo Credit:http://hashahgroup.com/product_agilent_crosslab.php
http://www.dot-red.com/gc-columns/fused-silica-capillary-gc-columns/http://www.aimanalytical.com/5890.html
http://www.businesswire.com/news/home/20160830005184/en/Agilent-Technologies-Introduces-Transformational-Technology-Gas-Chromatography
GC is Evolving to Meet Scientists’ Needs
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© 2018 Activated Research Company, LLC© 2018 Activated Research Company, LLC
Traditional Methanizers
• 16+ parts• 2-6 hour installation
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© 2018 Activated Research Company, LLC© 2018 Activated Research Company, LLC
Recent Advances: Jetanizer™
Traditional Methanizer Jetanizer
16+ parts
1 part
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Agilent
Shimadzu
© 2018 Activated Research Company, LLC© 2018 Activated Research Company, LLC
Jetanizer™: Simple Installation
Traditional Methanizer Jetanizer
2-6 hours 1-5 minutesInstallation time
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© 2018 Activated Research Company, LLC© 2018 Activated Research Company, LLC
Jetanizer™ vs. Methanizer
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© 2018 Activated Research Company, LLC© 2018 Activated Research Company, LLC
Jetanizer™: CO2 Analysis
1 mL sample loop
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© 2018 Activated Research Company, LLC© 2018 Activated Research Company, LLC
Jetanizer™: Hydrocarbon Matrix
1. Methane2. Ethylene3. Acetylene4. Ethane5. Propylene6. Propane
Conventional FID Jet
Luong, J., et al., Analytical Methods, “In-situ Methanation with Flame Ionization Detector for the Determination of Carbon Dioxide in Various Matrices.”
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© 2018 Activated Research Company, LLC© 2018 Activated Research Company, LLC
Jetanizer™: Hydrocarbon Matrix
Luong, J., et al., Analytical Methods, “In-situ Methanation with Flame Ionization Detector for the Determination of Carbon Dioxide in Various Matrices.”
1. Carbon monoxide2. Methane3. Carbon dioxide4. Ethylene5. Acetylene6. Ethane7. Propylene8. Propane
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© 2018 Activated Research Company, LLC© 2018 Activated Research Company, LLC
CO2 in Confined Space
Luong, J., et al., Analytical Methods, “In-situ Methanation with Flame Ionization Detector for the Determination of Carbon Dioxide in Various Matrices.”
Front
Rear
38,000 feet, in flight for 2 h
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© 2018 Activated Research Company, LLC© 2018 Activated Research Company, LLC
CO2 in Carbonated Beverages
Luong, J., et al., Analytical Methods, “In-situ Methanation with Flame Ionization Detector for the Determination of Carbon Dioxide in Various Matrices.”
Fresh drink
Day old drink
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© 2018 Activated Research Company, LLC© 2018 Activated Research Company, LLC
Flue Gas Analysis
Luong, J., et al., Analytical Methods, “In-situ Methanation with Flame Ionization Detector for the Determination of Carbon Dioxide in Various Matrices.”
1. Methane2. CO2
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© 2018 Activated Research Company, LLC© 2018 Activated Research Company, LLC
Jetanizer™: Formaldehyde
Luong, J., et al., Analytical Methods, “In-situ Methanation with Flame Ionization Detector for the Determination of Carbon Dioxide in Various Matrices.”
1. Air2. Methane3. CO24. Ethane5. Formaldehyde6. Propane7. Butane8. Formaldehyde dimer9. Pentane10. Hexane
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1
2
4
5
3
6 97
8
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© 2018 Activated Research Company, LLC© 2018 Activated Research Company, LLC
Polyarc® System: Universal Carbon Response
Microreactor Design and
Stainless Steel 3D Printing
Expertise in Catalysis
Design and Synthesis
First and Only Commercial 3D Printed
Microreactor
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© 2018 Activated Research Company, LLC© 2018 Activated Research Company, LLC
Polyarc® and Jetanizer™
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© 2018 Activated Research Company, LLC© 2018 Activated Research Company, LLC
Questions?Thank you!
ARC can be found at Booth #522.
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