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i RELATIONSHIP BETWEEN DECOMPOSITION LEVEL AND INDUCED SOLIDIFICATION OF PEAT BASED ON LABORATORY INVESTIGATION JUNITA BINTI ABD RAHMAN A thesis submitted in Fulfilment of the requirements for the award of the Degree of Master of Civil Engineering Faculty of Civil and Environmental Engineering University Tun Hussein Onn Malaysia JULY 2015

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Page 1: relationship between decomposition level and induced solidification

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RELATIONSHIP BETWEEN DECOMPOSITION LEVEL AND INDUCED

SOLIDIFICATION OF PEAT BASED ON LABORATORY INVESTIGATION

JUNITA BINTI ABD RAHMAN

A thesis submitted in

Fulfilment of the requirements for the award of the

Degree of Master of Civil Engineering

Faculty of Civil and Environmental Engineering

University Tun Hussein Onn Malaysia

JULY 2015

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ABSTRACT

Over 60 % of Pontian district is covered by peat. Peat is considered as a poor quality

soil for construction due to the high moisture content and low bearing capacity.

Solidification of peat is important in this area before any construction work could

start thus, will increase the population rate in the district. The degree of

decomposition affects the porosity of peat while the porosity is affected by both

particle size and structure of the peat. The pores between the decomposed materials

in peat can be filled and bound using ordinary portland cement (OPC) and coal ash

(fly ash, FA and bottom ash, BA). Different decomposition levels of peat require

different amounts of filler and binder to achieve the optimum strength. The peats are

categorized as fabric for the less decomposed peat, hemic for the moderately

decomposed and sapric for the mostly decomposed peat. The Pontian peat has high

moisture content with fabric peat having 970 %, hemic peat, 417 % and sapric peat,

720 %. All peat was found acidic with pH 3-4.5 while the binders and filler are in

alkaline state. The physico-chemical and mechanical properties of peat were

identified according to British (BS 1377, 1990) and US (ASTM, 2000) standards.

Chemical tests were adopted from previous researchers to identify the chemical

properties. The mixtures of peat-binder-filler were subjected to the unconfined

compressive strength (UCS) test, bender element (BE) test and the same chemical

tests as applied for the original sample. The mix ratios examined were of four types

being 100 % OPC, 50 % OPC 50 % BA, 50 % OPC 25 % BA 25 % FA and 25 %

OPC 50 % BA 25 % FA. Two water-binder ratios were used, i.e. 1 and 3. Curing

periods of 7, 14, 28 and 56 days were applied for all samples. The moisture content

of the peat was controlled at 300 % before mixing. The scanning electron microscope

(SEM) result shows that over time, the peat was filled with calcium silicate hydrate

(CSH) and calcium aluminate hydrate (CAH) which were products of cement

hydration. The strength gain for fabric peat is 157 kPa, while hemic peat, 737 kPa

and sapric peat, 121 kPa. It is concluded that regardless the peat decomposition level,

the optimum for a peat-binder-filler mixture to get the significant strength, should

consist of i) 23 - 34 % of particles, being combination of peat fiber and BA with size

ranging from 2 mm to 0.15 mm, ii) OPC with equal amount of dry mass of the peat

and iii) 25 % of FA by the total mass of binder. This combination was found to be

effective for the peat-binder-filler mixture.

Keywords: Peat decomposition level, bottom ash, fly ash, OPC, solidification.

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ABSTRAK

Lebih 60 % daripada daerah Pontian adalah terdiri dari tanah gambut. Tanah gambut

lazimnya dikenali sebagai tanah yang tidak berkualiti bagi sebarang kerja-kerja

binaan disebabkan oleh kandungan lembapan yang sangat tinggi dan kapasiti galas

yang rendah. Pemejalan tanah gambut di kawasan ini adalah penting sebelum

sebarang kerja-kerja pembinaan boleh dimulakan dimana ia akan meningkatkan

tahap populasi di daerah ini. Tahap penguraian tanah gambut memberi kesan kepada

tahap keliangan tanah manakala tahap keliangan pula dipengaruhi oleh saiz zarah dan

struktur tanah gambut tersebut. Liang-liang diantara bahan yang telah terurai boleh

dipenuhi dan diikat menggunakan semen portland biasa (OPC) dan abu arang batu

(abu atas, FA dan abu bawah, BA). Tahap penguraian tanah gambut yang berbeza

memerlukan jumlah pengisi dan pengikat yang berbeza bagi mencapai kekuatan yang

optimum. Tanah gambut dikategorikan sebagai gambut fabrik bagi yang kurang

terurai, gambut hemik bagi separa terurai dan gambut saprik bagi yang paling terurai.

Tanah gambut Pontian mempunyai kadar kelembapan yang tinggi dengan gambut

fabrik 970 %, gambut hemic, 417 % dan gambut saprik, 720 %. Semua jenis gambut

didapati berasid dengan pH 3-4.5 sementara pengikat dan pengisi adalah dalam tahap

alkali. Sifat fizik-kimia dan mekanikal tanah gambut dikenalpasti berdasarkan

standard British (BS 1377, 1990) dan US (ASTM, 2000). Ujian kimia pula diadaptasi

dari kajian-kajian terdahulu bagi mengenalpasti sifat-sifat kimia bahan. Campuran

tanah gambut-pengikat-pengisi adalah tertakluk kepada ujian kekuatan mampatan tak

terkurung (UCS), ujian unsur terbengkok (BE) dan ujian kimia yang sama seperti

yang telah dilakukan keatas sampel asal. Terdapat empat nisbah campuran yang diuji

iaitu 100 % OPC, 50 % OPC 50 % BA, 50 % OPC 25 % BA 25 % FA dan 25 %

OPC 50 % BA 25 % FA. Dua jenis nisbah air-pengikat digunakan iaitu 1 dan 3.

Tempoh bertenang 7, 14, 28 dan 56 hari telah diaplikasi pada semua sampel.

Kandungan lembapan tanah gambut telah dikawal pada 300 % sebelum pencampuran

dibuat. Keputusan dari imbasan mikroskop elektron (SEM) menunjukkan dengan

bertambahnya masa, tanah gambut telah diisi dengan calcium silicate hydrate (CSH)

dan calcium aluminate hydrate (CAH), dimana ia adalah hasil dari proses

penghidratan simen. Kekuatan yang telah dicapai oleh gambut fabrik ialah 157 kPa,

gambaut hemik, 737 kPa dan gambut saprik, 121 kPa. Kesimpulannya, bagi sebarang

jenis tanah gambut, campuran optimum bagi sebatian gambut-pengikat-pengisi

mendapatkan kekuatan yang signifikan mestilah terdiri daripada, i) 23 - 34 %

partikel, kombinasi fiber dari tanah gambut dan abu bawah dengan saiz julat dari 2

mm ke 0.15 mm, ii) kuantiti OPC yang sama banyak dengan jisim tanah gambut

kering, dan iii) 25 % FA berasaskan jisim keseluruhan sebatian. Kombinasi

campuran ini didapati efektif bagi sebatian gambut-pengikat-pengisi.

Kata kunci: tahap penguraian tanah gambut, abu atas, abu bawah, OPC, pemejalan

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TABLE OF CONTENTS

TITLE i

DECLARATION ii

DEDICATION iii

ACKNOWLEDGEMENTS iv

ABSTRACT v

TABLE OF CONTENTS vii

LIST OF FIGURES x

LIST OF TABLES xiv

LIST OF SYMBOLS AND

ABBREVIATION

xvi

CHAPTER 1 INTRODUCTION 1

1.1 Overview 1

1.2 Background of study 2

1.3 Statement of the problem 4

1.4 Objectives 5

1.5 Scopes of the study 5

1.6 Significance of the study 5

1.7 Organization of the thesis 6

CHAPTER 2 LITERATURE REVIEW 7

2.1 Introduction 7

2.2 Peat soil 7

2.2.1 Definition and review 7

2.2.2 Decomposition level of peat 9

2.3 Peat solidification 13

2.4 Selection of binder 13

2.4.1 Cement 14

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2.4.2 Fly ash 18

2.5 Filler 21

2.5.1 Bottom ash 21

2.6 Factors affecting solidification of peat 23

2.7 Relationship between different

decomposition level of peat and binder

25

2.8 Testing for solidified peat 29

CHAPTER 3 MATERIALS AND METHODS 34

3.1 Introduction 34

3.2 Flow of study 35

3.3 Test 36

3.3.1 Experimental Procedures 38

3.3.1.1 Physical Properties

Determination

38

3.3.1.2 Chemical Properties

Determination

42

3.3.1.3 Engineering properties 48

3.4 Field Sampling 52

3.4.1 Soil sample 52

3.4.2 Binders and filler 56

3.5 Mixing of treated samples 57

3.5.1 Peat 57

3.5.2 Binder and filler preparation 58

3.5.3 Mixing plan 59

3.6 Summary 62

CHAPTER 4 RESULTS AND DISCUSSION 63

4.1 Introduction 63

4.2 Preparing the peat for mixing -

controlling the moisture content

63

4.3 Identification of the physico-chemical

properties of raw materials

66

4.4 The effectiveness of solidification

concept

69

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ix

4.4.1 Strength analysis of solidified peat 69

4.4.2 Solidified peat stiffness 75

4.4.3 Shear wave velocity of solidified

peat

78

4.5 Physico-chemical effect to solidified

peat

82

4.5.1 Neutralization concept 83

4.5.2 Microscopic image 87

4.5.3 Chemical composition pre and post

solidification

94

4.5.4 Effect of curing days 101

4.6 Establishment of the relationship

between decomposition level and the

induced solidification of peat

102

CHAPTER 5 CONCLUSIONS AND

RECOMMENDATIONS

107

5.1 Introduction 107

5.2 Conclusions 107

5.3 Recommendations 109

REFERENCES 110

APPENDIX 126

VITA

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LIST OF FIGURES

FIGURE

NO.

TITLE PAGE

1.1 Pontian district 1

1.2 Population at Johor in 20 years: 1991- 2

1.3 Examples of road and building affected by

settlement of peat at Pontian on 2013

3

2.1 Peat distributions in the world 8

2.2 Distribution of peat swamp in Malaysia 8

2.3 SEM images of peats 10

2.4 Profile morphology of drained organic soil 11

2.5 Typical XRD pattern of OPC 15

2.6 Simplified illustration of hydration of cement paste 18

2.7 Fly ash 21

2.8 Bottom ash application in US in 2007 22

2.9 Particle size distributions for filler 23

2.10 Unconfined compressive stress- vertical strain

relationships of the stabilized peat specimen

27

2.12 Graph showing stress-strain of four materials 29

2.13 The derivation of E0, Ep and E50 from UCS stress-

strain curve

30

2.14 Shear Wave Velocity Data at Sherman Island 31

2.15 Scanning electron micrographs of the (a) untreated

peat, and stabilized peat at (b) 7 (c) 14 and (d) 28

days of curing in water

31

2.16 Scanning electron micrographs of treated peat 32

2.17 XRD pattern of 5 samples over time 32

3.1 Cone penetration instrument 38

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xi

3.2 Specific Gravity Test: Small Pycnometer method 39

3.3 FESEM instrument 41

3.4 Electronic inverted microscope 41

3.5 pH meter and samples 42

3.6 Completely burnt peat at 450oC 43

3.7 XRF instrument 44

3.8 The Perkin Elmer FTIR spectrometer 46

3.9 Thermogravimetric analysis equipment 47

3.10 Unconfined Compressive Strength test equipment

with sample

48

3.11 The pattern of stress-strain curve that indicate the

properties of UCS sample prepared

48

3.12 Vane used in this work 49

3.13 Spring used for laboratory vane shear test 49

3.14 Schematic diagram of laboratory vane shear 49

3.15 Laboratory vane shear 50

3.16 Bender element setup 51

3.17 Actual soft-sample 51

3.18 Villagers normally embank up to 2 m to avoid

subsidence after some years of housing construction

53

3.19 Road failures due to peat settlement at Pontian 53

3.20 Pontian site 54

3.21 Sample collection 55

3.22 Site layout - plan view 56

3.23 The fly ash is forwarded to ash pool while the land

is filled with bottom ash

57

3.24 Fibers that have been taken out from peat sample

before mixing process

58

3.25 Labelling of specimen 61

4.1 Specimen of fabric peat with 200 % OPC at

moisture content of 805 %

64

4.2 Projection of undrained shear stress versus

percentage of OPC

64

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xii

4.3 Peat was dried at 100oC 65

4.4 Dried peat unable to re-absorb water 65

4.5 Peat dried at room temperature 65

4.6 Moisture content versus time taken for controlling

the water content of peat using air drying technique

65

4.7 Particle size distributions of peat, binders and filler 67

4.8 qu versus curing days 69

4.9 Unconfined compressive strength versus water to

binder ratio

72

4.10 Unconfined compressive stress–vertical strain

relationships of the stabilized peat specimens

74

4.11 Young’s modulus (E) - unconfined compressive

strength

75

4.12 Modulus strain versus qu 77

4.13 Modulus strain versus qu (Hoo, 2013) 77

4.14 Stress-strain curves for optimum mixture of

solidified fabric peat and solidified clay at D28

77

4.15 Shear wave velocity and unconfined compressive

strength, qu versus curing days

78

4.16 Shear wave velocity, vs versus curing days 78

4.17 Particle size distributions of peat and clay 79

4.18 The poor signal received by the H(1)50OPC_50FA

with the specimen size of 38 x 76 mm

80

4.19 The good signal received by the H(1)50OPC_50FA

with modified method

80

4.20 qu versus Vs 81

4.21 Process flowchart of peat solidification 82

4.22 pH versus curing days 84

4.23 pH of peat and solidified peat 85

4.24 Vane shear of peat with OPC at D3 86

4.25 SEM of peat-OPC mixture (magnification 2000x,

2 kV)

86

4.26 Particles and its sizes in the peat-binder-filler 87

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xiii

mixture

4.27 H(1)50OPC_25BA_25FA 90

4.28 H(1)_100OPC 90

4.29 Illustration of binding of OPC with organic matter

in peat

91

4.30 SEM photos of 10 % OPC at different curing time

(Horpibulsuk, 2012)

91

4.31 Bleeding phenomenon due to thyxothropic effect of

S(3)_50OPC_50BA at D56

93

4.32 Average penetration for mixture of peat and BA 93

4.33 Mass percentage versus time and heating

temperature

96

4.34 TGA on Pontian peat 97

4.35 TGA on solidified peat 98

4.36 FTIR reading for peat 99

4.37 FTIR reading for solidified peat (optimum

formulation)

100

4.38 Moisture content versus curing days 101

4.39 Illustration of fine particles filling porous spaces in

BA and peat

102

4.40 Undrained sheer strength versus percentage of

binder/ filler in a mixture

104

4.41 FESEM images for peat-binders at D3 104

4.42 Flowchart of peat solidification 106

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xiv

LIST OF TABLES

TABLE

NO.

TITLE PAGE

2.1 General definitions of peat 7

2.2 USDA classification of peat 9

2.3 Degree of Humification of Peat 10

2.4 Physical and chemical properties of peat 12

2.5 Prices comparison of binders and fillers in Malaysia

as year 2010

14

2.6 Main chemical compounds of Portland cement 16

2.7 Hydration reaction of OPC 17

2.8 Typical chemical compounds of Class C and Class F 20

2.9 Influencing parameters to classify fly ash 20

2.10 Comparison of binder and strength gained 28

3.1 List of test description 36

3.2 Common functional groups on FTIR spectra of peat 46

3.3 Height of BE sample for specific UC strength, qu 51

3.4 Peat profile at Pontian site 55

3.5 Mixing portion for peat-binder- filler admixture 60

3.6 Calculation of mixture in peat-binder-filler admixture 61

3.7 Summary of testing 62

4.1 Physico-chemical and engineering properties of peat 66

4.2 Physico-chemical properties of binders and fillers 67

4.3 Deformation and failure patterns 74

4.4 Microscopic images of peat under low magnification 86

4.5 Microscopic images of peat under high magnification 87

4.6 Summary of patterns in solidified peat 87

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xv

4.7 SEM images and qu of solidified peat at D28 with

different mixing portion and techniques

90

4.8 XRF analysis on peat, binder and filler 92

4.9 XRF analysis on 3 main oxides in mixture of

solidified peat with different mixing proportion

93

4.10 Explanation of optimum mixture 103

4.11 Calculation of solid content in an optimized mixture

based on 100 g of dry peat

103

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LIST OF SYMBOLS AND ABBREVIATION

AASHTO American Association of State Highway and Transportation

Officials

Al2O3 aluminium oxide

ASTM American Society for testing and Materials International

Standard

BA Bottom ash

BE Bender Element

BS Bristish Standard

C Cement

C2S Dicalcium silicate

C2SHx, C3S2Hx Hydrated calcium silicates

C3A Tricalcium aluminate

C3S Tricalcium silicate

C4AF Tetracalcium aliminofferrite

CaO calcium oxide

CH calcium hydroxide

CILAS Particle Size Analyzer

CSH calcium silicate hydrate

Cl Chlorine

Cu Undrained shear strength

Cv Coefficient of consolidation

D Diameter

e Void ratio

Eo Initial Tangent Modulus

Ep secant modulus at peak stress

E50 50 % of peak stress

EC Electrical conductivity

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xvii

e.g. For example

EDS Energy-dispersive X-ray Spectroscopy

ET ettringite

et al and other people

etc and others

F Fibric peat

FA Fly ash

Fe2O3 feric oxide

FESEM Field Emission Scanning Electron Microscope

FTIR Fourier Transform Infrared Spectroscopy

g Gram

Gmax maximum shear modulus

Gs Specific gravity

GWT Ground water table

H Hemic peat

i.e. In other words

i.e. that is

kg Kilogram

kN Kilo Newton

kPa Kilo Pascal

L Length

LL Liquid limit

LOI Loss on ignition

MARDI Malaysia Agricultural Research and Development Institute

Mg Mega gram (1000 kg)

mm Milimeter

MSCS Malaysian Soil Classification System

N Ignition loss

oC degree celcius

OC Organic content

OPC Ordinary Portland cement

qu Unconfined compressive strength

RECESS Research Centre for Soft Soils

S Sapric peat

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xviii

SEM Scanning electron microscopy

SiO2 silica dioxide

SO3 sulfur dioxide

TGA Thermogravimetric Analysis

UCS Unconfined compressive strength

USCS unified soil classification systems

USDA United States Department of Agriculture

UTHM Universiti Tun Hussein Onn Malaysia

vs shear wave velocity

vp compression wave velocity

W (%) percent moisture content

w Water content

w/c Water-cement ratio

wn Natural water content

WS Weight of dry soil

XRF X – Ray fluorescence

ZnO zinc oxide

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CHAPTER 1

INTRODUCTION

1.1 Overview

Over 60 % of Pontian district is covered with peat as shown in Figure 1.1. Figure

1.2 shows that Pontian has least population compared with other towns in Johor. It

reflects that peat area is not a preferred inhabitants place due to limitation of the road

network and infrastructure. Engineers are reluctant to construct on peat due to

challenging accessibility to the sites and other problems related to the unique

characteristics of peat. Report from National Audit Department (2011) stated that

most projects that have been delayed and reconstructed were due to peat settlement.

Hence, it is important to have peat treatment in this area to catalyze the population

rate and to avoid unbalanced district population over time i,e, some cities to be more

congested compared to the others.

Figure 1.1 Pontian district (Jabatan Pertanian Pontian, 2012)

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CHAPTER 2

LITERATURE REVIEW

2.1 Introduction

This chapter describes the type of peat soil, binder and filler with its properties.

The correlation between all these substances is critically discussed here.

2.2 Peat soil

2.2.1 Definition and review

Peat is generally referred as cumulative of decomposed plant material but it actually

has various definitions, depending on the scope of usage. The standard definitions

are as given in Table 2.1:

Table 2.1 General definitions of peat

Purpose of

application Definition Reference

Geotechnical

engineering

Peat = Organic content > 75 %

Organic soils, clay or sand = organic content <

75 %

*ASTM

D4427 – 92

Agriculture Peat = Organic content > 20 %.

**USDA (Soil

Taxonomy)

Soil science Peat = Organic content > 35 %

**USDA (Soil

Taxonomy)

*USDA = United States Department of Agriculture

ASTM = American Society for Testing and Materials

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Based on the global chart of total peat deposit around the world, Malaysia is

the 9th

country with the highest total area of peat soil (Figure 2.1). The total area of

peat soil in Malaysia is about 2.6 million hectares (26,000 km2), of which 13 % are in

Malaysian Peninsular, over 80 % in Sarawak and about 5 % in Sabah as shown in

Figure 2.2 (Leete, 2006).

Figure 2.1 Peat distributions in the world (source: http://www.wetlands.org)

Figure 2.2 Distribution of peat swamp in Malaysia (Leete, 2006)

Technically, any material that contains carbon is called 'organic'. An organic

soil is one that contains a significant amount of organic material recently derived

from plant remains. The term peat refers to highly organic soils derived primarily

from plant remains. It normally has a dark brown to black colour, a spongy

consistency, and an organic odor. Plant fibers are sometimes visible but in the

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advanced stages of decomposition, they may not be evident. Peat is an organic soil

with organic content of more than 75 % as defined by ASTM D4427 (Table 2.1).

2.2.2 Decomposition level of peat

There are several types of peat classification system for example, United

State Department of Agriculture (USDA) (Table 2.2) and Van Post scale (Table

2.3). Both systems are comparable as depicted in Table 2.2. According to Van Post

scale, peat classification is determined based on the appearance of soil water that is

extruded when the soil is squeezed by hand. Degree of decomposition (humification)

is expressed in terms of a ten-class scale on which higher numbers indicate stronger

peat decomposition. The peat classification according to the USDA classification

system will be used throughout this thesis.

Table 2.2 USDA classification of peat

Type of peat Fiber content Von Post Scale

Fibric peat Over 66 % H4 or less

Hemic peat 33 - 66 % H5- H6

Sapric peat Less than 33 % H7 and above

The degree of decomposition varies between peat mosses since some plants

or some parts of the plants are more resistant than others. Also, the degree of

decomposition of peat depends on combination of conditions, such as the chemistry

of the water supply, the temperature of the region, aeration and the biochemical

stability of the peatforming plant (Huat et al., 2011). These variations make peat

possesses wider range of physical properties such as colour, texture, density, specific

gravity and water content.

Boelter (1968) reported that the physical properties of peat are highly affected

by the porosity and the distribution of the pore size. Both parameters are related to

grain size distribution. The degree of decomposition affects the porosity of peat and

the porosity is affected by both the particle size and structure of peat. With an

increase in the decomposition, the particle size of organic matters decreases (Boelter,

1968). Qualititatively, Scanning Electron Micrograph (SEM) is commonly used to

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observe this physical variation of peat. The arrangement of particles seen to be

relatively loose in fibrous peat compared to the more decomposed peat, for example,

sapric as seen in Figure 2.3. The morphology, structure of peat is shown in Figure

2.4. The remnants of logs and woody plant can be seen clearly in fibrous peat but

almost absent in sapric peat.

Table 2.3 Degree of Humification of Peat (Von Post and Granlund 1926)

Degree of

humification

Description

H1 Completely undecomposed peat which releases almost clear water. Plant remains

easily identifiable. No amorphous material present.

H2 Almost completely undecomposed peat which releases clear or yellowish water.

Plant remains still easily identifiable. No amorphous material present.

H3 Very slightly decomposed peat which releases muddy brown water but for which

no peat passes between the fingers. Plant remains still identifiable and no

amorphous material present.

H4 Slightly decomposed peat which, when squeezed, releases very muddy dark

water. No peat is passed between the fingers but the plant remains are slightly

pasty and have lost some of their identifiable features.

H5 Moderately decomposed peat which, when squeezed, releases very “muddy”

water with a very small amount of amorphous granular peat escaping between the

fingers. The structure of the plant remains is quite indistinct although it is still

possible to recognize certain features. The residue is very pasty.

H6 Moderately decomposed peat which a very indistinct plant structure. When

squeezed, about one-third of the peat escapes between the fingers. The structure

more distinctly than before squeezing.

H7 Highly decomposed peat. Contains a lot of amorphous material with very faintly

recognizable plant structure. When squeezed, about one – half of the peat escapes

between the fingers. The water, if any is released, is very dark and almost pasty.

H8 Very highly decomposed peat with large quantity of amorphous material with

very indistinct plant structure. When squeezed, about two thirds of the peat

escapes between the fingers. A small quantity of pasty water may be released.

The plant material remaining in the hand consists of residues such as roots and

fibers that resist decomposition.

H9 Practically fully decomposed peat in which there is hardly any recognizable plant

structure. When squeezed it is fairly uniform paste.

H10 Completely decomposed peat with no discernible plant structure. When

squeezed, all the wet peat escapes between the fingers.

(a) (b) (c)

Figure 2.3 SEM images of peats: (a) fibrous, (b) sapric and (c) hemic (Huat et al.,

2011)

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Figure 2.4 Profile morphology of drained organic soil (Mutalib et al., 1992)

According to Hartford (1993), bulk density of organic soils or peat tends to

increase with decomposition. Slightly decomposed organic soils (fibric peat) have

larger pore spaces and higher rates of saturated water movement compared to well-

decomposed sapric peat which may have hydraulic conductivity rates lower than clay

soils (Robert, 1996).

Among three types of peat, namely: fibric, hemic and sapric, fibric or fibrous

peat generally has very high natural water content due to its natural water-holding

capacity. Soil fabric, characterized by organic coarse particles, holds a considerable

amount of water because the course particles are generally very loose, and the organic

particle itself is hollow and largely full of water. Previous researches have indicated that

high water content of fibrous peat results in high buoyancy and high pore volume

leading to low bulk density and low bearing capacity (Huat, 2004; Islam, 2009).

Table 2.4 lists the physical and chemical properties of peat. The comparison

shows that the same type of peat may have a variety of natural water content, bulk

density, specific gravity and acidity. Thus, the mentioned parameters cannot be used in

determining the peat decomposition level. The higher moisture content of peat, normally

reflect the ability of the fiber to retain water. Peat generally is acidic but, the level of

acidity is influenced by the climate, the microbial activity in that specific location and

type of plants that involved in peat accumulation. According to Mal and Maksimenok

(1974), the formation of humic acid in peat is depending on the type of plant and

temperature. Higher temperature increases the rate of formation of humic acid. The

deeper the peat layer, the less temperature recorded thus resulting to humic acid

production is stop or minimum. This causes the quantity of humic acid remain as the

decomposing process continue.

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Table 2.4 Physical and chemical properties of peat

Peat type Natural water

Content

(w,%)

Bulk

density

(Mg/m3)

Specific

gravity

(Gs )

Acidity

(pH)

Reference

Fabric 1168 - 1.44 5.3 O’Kelly and Pichan

(2013)

Peat 500 - 800 1.03 - - H. Hayashi et al.

(2012)

Fabric 598.5 1.21 3.75 Kolay et al.(2011)

Fibric 605-1290 0.87-1.04 1.41-1.7 - Moayedi et al.

(2011)

Fibric 850 0.95-1.03 1.1-1.8 - Asadi et al., (2009,

2010)

Fabric 700-850 1.59 1.343 4.6 Deboucha and

Hashim (2009)

Fabric 668 - 1.4 3.51 Wong et al. (2008)

Fabric 510-850 - 1.53-1.65 - Mesri and Ajlouni

(2007) 1000-1340 1.5-1.64

Hemic 230-500 - 1.48-1.80 - Zainorabidin

and Ismail (2003)

Fabric and hemic 1090-1210 - - - Jelisic and

Leppänen (2000)

Fibric (Middleton) 510-850 0.99-1.1 1.47-1.64 4.2 Ajlouni (2000)

Fibric (James Bay) 1000-1340 0.85-1.02 1.37-1.55 5.3

Peat (Netherlands) 669 0.97 1.52 - Termatt and

Topolnicki (1994)

Fibric 700-800 ~1.00 - - Hansbo (1991)

Peat 630-1200 - 1.58-1.71 - Nakayama et al.

(1990)

Peat 400-1100 0.99-1.1 1.47 4.2 Yamaguchi 1990

Peat 419 1 1.61 - Jones et al. (1986)

Peat 125-375 0 1.55-1.63 5-7 Yamaguchi et al.

(1985)

Fibric 660-1590 - 1.53-1.68 - Lefebvre et al.

(1984)

Peat portage 600 0.96 1.72 7.3 Edil and Mochtar

(1984) Peat waupaca 460 0.96 1.68 6.2

Fibric peat

(Middleton)

510 0.91 1.41 7

Fibric peat

(Noblesville)

173-757 0.84 1.56 6.4

Coarse Fibric 202-1159 1.05 1.5 4.17 Berry (1983)

Fine Fibric 660 1.05 1.58 6.9 NG and Eischen

(1983) Fine Fibric 418 1.05 1.73 6.9

Hemic granular 336 1.05 1.72 7.3

Fibric sedge 350 - - 4.3 Levesque et al.

(1980) Fibric sphagnum 778 - - 3.3

Fibric peat 660-890 0.94-1.15 - - Olson and Mesri

(1970) Hemic peat 200-875 1.04-1.23 - -

Hemic to Fibric 850 - 1.5 - Keene and

Zawodniak (1968)

Hemic and Fibric

355-425 - 1.73 6.7 Adams (1965)

500-1500 0.88-1.22 1.5-1.6 - Lea and Browner

(1963)

Page 23: relationship between decomposition level and induced solidification

13

2.3 Peat solidification

Soft soil stabilization or solidification is a term that refers to treatment of peat

where the soil is expected to be strengthened for construction above ground. The

challenge in the peat stabilization is on finding the best binder, filler and ratio for the

admixture. Several studies on binder and filler for soft soil stabilization have been

done for centuries, which include the use of recycle waste product, rice husk and

many more. This study is limited to cement and fly ash as binders while bottom ash

as filler.

Peat stabilization depends upon the water content; physical, chemical and

mineralogical properties; nature and amount of organic content and pH of pore water.

Tremblay et al., (2002) reported that the properties of treated organic soils by binder

and filler depend not only on the content of the organic matter but also on the nature

or the type of the organic matter. The strength gained will also depend upon the

decomposition of the organic compound to organic acid due to biological activity.

The engineering behaviour of fine-grained soil is mostly influenced by their specific

surface area (Santamarina et al., 2002). Kazemian (2011) reported the specific

surface area of sapric, hemic and fibrous peat is 93, 69 and 50 m2/g, respectively. As

the specific surface of peat increases, a greater surface area is available (sapric peat)

for reaction when considered on a unit mass or volume basis. Hence, higher shear

strength is obtained when compared with the other two peats, fabric and hemic

(Kazemian,2011).

2.4 Selection of binder

Referring to Oxford Dictionary (Soanes, 2008), binder is defined as a substance that

used to make other substances or materials stick or mix together. In civil engineering,

binder is described as a material which has properties of holding solid particles

together to constitute a coherent mass.

Binders may be hydraulic or non-hydraulic. A hydraulic binder is self curing

when in contact with water, while a non-hydraulic binder requires a catalyst to

initiate curing. A hydraulic binder will stabilize almost any soil. The mechanical

mixing of the binder into the soil must be precise to avoid heterogeneous condition.

Non-hydraulic binders generally react with clay minerals in the soil, which result in

Page 24: relationship between decomposition level and induced solidification

14

stabilized material with improved geotechnical properties. Cement is a hydraulic

binder. Interaction of the binder with the soft soil leads to a material which has better

engineering properties than the original soil (Hebib and Farrell, 2003).

The cost of the raw materials for binders and filler in this study, would form a

significant influence in modeling the construction material. Table 2.5 shows the

price of the most common binders and fillers used in peat treatment. Based on

financial comparison , OPC, fly ash and bottom ash are still the competitive materials

to be used in solidification of peat.

Table 2.5 Prices comparison of binders and fillers in Malaysia as at year 2010

(Kalantari, 2010)

Material Price (RM/m

3)

OPC* 23.00

Fly ash - class C 15.20

Fly ash - class F* 0.00

Blast furnace slag 22.70

Sand 6.10

Bottom ash* 0.00

Sodium bentonite 130.40

Steel fiber 56.70

* materials use in this study

2.4.1 Cement

It is generally recognized that peat can be solidified by Ordinary Portland Cement

(OPC) (Consoli et al., 2002, Tremblay et al., 2002, Rotta et al., 2003, Rao and

Shivananda, 2005 and Ahnberg, 2006). The finer the grain size of cement, the more

reactive it will be (Sha'abani and Kalantari, 2012).

Figure 2.5 shows the XRD analysis of OPC that indicate the presence of

calcium silicate hydrate (CSH), calcium hydroxide (CH) and ettringite (ET) which

are the major reaction products that influence the stabilized soil (Nontananandh et

al., 2005). XRF result indicates that OPC contains calcium, silica and aluminium

compounds which will transform to hardened solid mass when it interact with water,

over time.

Page 25: relationship between decomposition level and induced solidification

15

Figure 2.5 Typical XRD pattern of OPC (Tsakiridis et al., 2008)

Bergado et al., (1996) noted that there are two major chemical reactions in

cement stabilization namely primary hydration reaction of cement and water, and

secondary pozzolanic reaction between cement and soil minerals. The hydration

reaction leads to initial gain in strength as the cementation product is formed due to

drying up of water. Moreover, pozzolanic reaction, which is also understood as

solidification, will harden the soil skeleton with increase in strength over time.

When tricalcium silicate (C3S) and dicalcium silicate (C2S) are mixed with

water or original water in the soil, calcium ions are quickly released into the solution.

The formation of hydroxide ions and the production of OH- ions direct to the

formation of CSH gel with a corresponding increase in strength. The increase in

strength is governed by the ratio of C3S to C2S. On the other hand, when Ca(OH)2 is

produced by cement hydration, the constituent becomes active and reacts

spontaneously with its own lime content (Janz and Johansson, 2002, Huat et al., 2011

and Kazimeien et al., 2011). The calcium hydroxide that forms from this reaction

will be absorbed into the soil particles. Ion exchange will take place and the soil will

be modified into somewhat drier and coarser structure due to the slaking process and

flocculation of the soil particle that take place (Saitoh et al., 1985). The slaking

process occurs when calcium oxide is mixed with water. The main chemical

compounds in portland cement are described in detail in Table 2.6.

Page 26: relationship between decomposition level and induced solidification

16

Table 2.6 Main chemical compounds of Portland cement (Jackson, 1996)

The calcium hydroxide is not consumed during the hardening process and is

free to react with any minerals present in the soil or even filler. The reaction which

takes place in soil-cement stabilizations is presented in equation 2.1 to equation 2.4.

CS + HO CSH (Hydrated gel) + Ca(OH)2 (2.1)

(Primary cementitious product)

Ca(OH)2 Ca2+

+ 2(OH)- (2.2)

Ca2+

+ 2(OH)- + SiO2 (Soil silica) CSH (2.3)

(Secondary cementitious product)

Ca2+

+ 2(OH)- + Al2O3 (Soil alumina) CAH (2.4)

(Secondary cementitious product)

Name of

compound

Chemical

composition

Usual

abbreviation Descriptions

Tricalcium

silicate 3CaO.SiO2 C2S

Hydrates and hardens rapidly and is largely

responsible for initial set and early strength.

Portland cement with higher percentage of

C2S will exhibit higher early strength.

Dicalcium

silicate 2CaO.SiO2 C2S

Hydrates and hardens slowly and is largely

responsible for strength increases beyond one

week.

Tricalcium

aluminate 3CaO.Al2O3 C3A

Hydrates and hardens the quickest. Liberates a

large amount of heat almost immediately and

contributes somewhat to early strength.

Gypsum is added to portland cement to retard

C3A hydration. Without gypsum, C2A

hydration would cause portland cement to set

almost immediately after adding water.

Tetracalcium

aliminoferrite

4CaO.Al2O3

Fe2O3 C4AF

Hydrates rapidly but contributes very little to

strength. Its use allows lower kiln

temperatures in portland cement

manufacturing. Most portland cement colour

effects are due to C4AF.

Page 27: relationship between decomposition level and induced solidification

17

The cement hydration and pozzolanic reaction can last for months, or even

years, after mixing. Thus, the strength of cement-treated soil tends to increase with

time as long as the reactions still occur. The hydration of portland cement is rather

more complex than that of the individual constituent minerals. A simplified

illustration of the development of hydrate structure in cement paste is given in

Figure 2.6 and the detail of hydration reaction is presented in Table 2.7.

Table 2.7 Hydration reaction of OPC (Xiao and Li, 2009)

Hydration

stage

Kinetics of hydration Main chemical

phenomena

Chemical reaction

I. Dissolution Ion dissolution dominating Initial rapid

chemical reaction of

C3A

C3A + 3(CSH2) + 26H

C6AS3H32

II. Dynamic

balance

A competition process of the

dissolution precipitation

CH nucleation Ca2+

+ OH- Ca(OH)2

III. Setting The formation of hydration

product C-S-H dominating

Chemical reaction

control of C3S

C3S + 11H C3S2H8 +

3CH

IV.

Hardening

Continuous formation of

hydration products, large

increase in the volume of

solids

C3S hydration;

phase transferfrom

AFt to AFm

C3S + 11H C3S2H8 + 3CH

2C2S + 9H C3S2H8 + CH

C6AS3H32 C4ASH12 +

2CaSO4

C6AS3H32 + 2C3A + 4H

3C4ASH12

V. Hardening

deceleration

Chemical reaction slows

down, diffusion control

The second reaction

of C3A; C3S and

other components

of hydration

C3A + 3(CSH2) + 26H

C6AS3H32

C3S + 11H C3S2H8 + 3CH

2C2S + 9H C3S2H8 + CH

Cement is also commonly used to optimised soil acidity, as well as to

improve the physical condition of the soil (Mohamed et al., 2002). The pozzolanic

reaction increases the pH of pore water due to dissolution of the hydrated lime. The

strong base dissolves both soil silica and alumina from soil minerals (Sposito, 2008).

Care must be taken to ensure homogeneous mixing, because cement, unlike lime,

does not diffuse into the surrounding soil mass (Kazimien et al., 2011).

Thermogravimetric analysis (TGA) is often use to determine the presence of

Ca(OH)2 in OPC or solidified soil. Ca(OH)2 content was determined based on the

weight loss between 450 and 580°C (El-Jazairi and Illston, 1977 and 1980, Wang et

al., 2004). The change of the cementitious products can be expressed by the change

of Ca(OH)2 since they are the hydration products, i.e the ettringite (Horpibulsuk,

2012).

Page 28: relationship between decomposition level and induced solidification

18

Figure 2.6 Simplified illustration of hydration of cement paste (Newman, 2003)

2.4.2 Fly Ash

Pozzolan is a material that contains siliceous or siliceous and aluminous material

which, in itself, possesses little or no cementitious value. With the presence of water,

pozzolan will react chemically with calcium hydroxide at room temperature to form

compounds possessing cementitious properties (Mehta, 1987). Small amount of

secondary pozzolanic materials is added to the admixture to promote secondary

pozzolanic reactions. This is the reason of the long term strength gain of the

cemented soil. In this study, fly ash (Figure 2.7) was used as the secondary

pozzolanic material. Although research has been carried out for peat soil stabilization

by using admixtures like cement, lime and fly ash; but very few literature is available

on fly ash utilization, particularly on its use as a stabilization material (Kolay et al.,

2011)

Page 29: relationship between decomposition level and induced solidification

19

Fly ash is a by-product from the burning of coal in thermal power stations. It

is the non-combustible portion of coal that is collected at the combustion chamber.

The particles themselves are spherical and smooth with the size ranging from

0.5 µm to 300 µm which is finer than cement particles. Fly ash is one of the

component in cement that have the characteristics to reduces permeability, greater

corrosion resistance, substantially higher fire resistance (up to 2400° F), high

compressive and tensile strengths, a rapid strength gain, and lower shrinkage. This

translates to higher durability of cement.

There are two types of fly ash which are Class C and Class F. Class C fly ash

exhibits considerable true cohesive strength due to cementitious reactions. Due to

this property, self-cementing ash could define as a very economical stabilization

agent, for a wide range of application. When exposure to water, Class C fly ash

reacts with water immediately and hydrates forming cementitious products that are

similar to those produced during the hydration of Portland cement. Type C fly ash

exhibits self hardening when mixed with water due to its higher calcium content

(Collins, 1988).

McLaren & DiGioia (1987) reported the shear strength of fly ash. Class F fly

ash is a frictional material, its shear strength is mainly derived from friction between

particles. According to the ASTM C618, the classification of the fly ash is based on

the specified major element oxide content (Mattigod et al., 1990). Class F fly ash

must contain at least 70 % sum of SiO2, Al2O3 and Fe2O3 and it normally produced

by Bituminous or Anthracite Coal which has low CaO. For the Class C fly ash, sum

of SiO2, Al2O3 and Fe2O3 is less than 70 % but more than 50 % and commonly

generated from the combustion of Lignite or Sub-bituminous coal with a high CaO.

Hydration properties of a fly ash depend on some factors including the coals

source, boiler design, and type of ash collection system. The coal source controls the

amount and type of inorganic matter present in the coal, thus dominating the

chemical composition of the ash. Bituminous coals and some lignite coals have low

calcium contents. The ash (Class F fly ash,) which is produced from bituminous

coals and some lignite coals contain rarely amount of calcium.

Class F ash does not show self-cementing characteristic. But, the presence of

lime from OPC can cause a pozzolanic reaction which produces cementitious

products ( Kevan, 1993). The chemical composition of fly ash is dependent on both

the mineral composition of coal and boiler operation conditions (Miller & Linak,

Page 30: relationship between decomposition level and induced solidification

20

2002).The comparison between chemical composition of class C fly ash and class F

fly ash is shown in Table 2.8. The amount of calcium compounds are higher in Sub-

bituminous coals and the ashes produced through combustion of these coals typically

contain from 20 to 35 % calcium oxide, as determined by ASTM C - 311 (sampling

and testing fly Ash or Natural Pozzolans for Use as a Mineral Admixture in Portland

Cement Concrete). Addition of fly ash in this study is to understand the secondary

pozzolanic effect and the correlation with the solidification of peat.

Table 2.8 Typical chemical compounds of Class C and Class F (Halstead, 1986)

Chemical Compound Class C Class F

SiO2 39.9 54.9

Al2O3 16.7 25.8

Fe2O3 5.8 6.9

CaO 24.3 8.7

MgO 4.6 1.8

SO3 3.3 0.6

Na2O & K2O 1.3 0.6

The most influencing factor that divide these two classes of fly ashes are their

amount of calcium, silica (SiO2), alumina (Al2O3), and iron contents (Fe2O3) among

other factors. Some of the most influential parameters that divide the two types of fly

ashes are shown in Table 2.9.

Table 2.9 Influencing parameters to classify fly ash (Samsuri 1997)

Properties Fly ash class

F C

Sio2 + Al2O3 + Fe2O3, min, % 70 50

SO3, max, % 5.0 5.0

Moisture content, max, % 3.0 3.0

Loss on ignition, max, % 6.0 6.0

Past researches show that addition of fly ash in cement, or lime when mixed

with mineral soils can improve the performance of the final product (Sukumar et al.

2008; Douglas 2004; Sobhan, and Mashnad 2002; Little 1999).

Page 31: relationship between decomposition level and induced solidification

21

Figure 2.7 Fly ash

2.5 Filler

Fillers are used to increase the amount of solid particles in wet peat for the binder to

join. Practically, the filler produce insignificant chemical reactions in cement

hydrolysis due to the large size of the particles but it enhance the strength of the

cemented peat by increasing the contact surface areas for the cementation bonds to

form, thereby producing a stabilized soil structure. In addition, the filler reduces void

ratio of cemented peat by filling the spaces within the loose peat during the

cementation process. Economically, it is feasible to reduce the cost of peat

stabilization by including the filler into the cemented peat.

Peat normally requires big quantities of stabilizer or binder. This is because

peat contains fewer solid particles to stabilize. Since it is the solid particles that

provide structure, a greater quantity of binder need to be added. Moreover, peat has

considerably high water content, which is usually not less than 200%. The large

amount of water in the soil implies larger voids, requiring more binder. Filler is

introduced to lessen the amount of binder needed in filling the void in peat during

soil stabilization (Wong, 2008).

2.5.1 Bottom ash

Bottom ash is recommended as sands replacement as it has almost all of sand

properties but with relatively higher pozzolanic effect. According to the Unified Soil

Classification System (USCS), BA is classified as well graded sand (Marto et al.,

2010). Bottom ash is the secondary by-product from a coal burning power plant and

categorized as non-hazardous scheduled waste under the Scheduled Waste SW104

Page 32: relationship between decomposition level and induced solidification

22

(Environmental Quality Act) (Rashid et al. 2010). The low density of bottom ash,

around 700 kg/m3 creates a lighter product. The usage of bottom ash is still an

ongoing study but a few industries found it is effective to use bottom ash in their

sector as reported in Figure 2.8.

The main components of the bottom ash are glass, magnetic metals, minerals,

synthetic ceramics, paramagnetic metals and unburned organic matter. The 4–25 mm

size fraction (Figure 2.9) accounts for approximately 50 % of the bottom ash weight

and comprises mainly of glass. 50 % of the glass fraction consists of synthetic

ceramics 26 % and minerals 8 %, and it is suitable as secondary building materials or

for glass recycling industry. Magnetic metals, 1–6 mm particle in size accumulate

6 % of this fraction (Chimenos,1999).

The main chemical element in bottom ash consists of SiO2, Al2O3, CaO and

Fe2O3, which are the essential pozzolanic oxide compounds with the total of 92.64 %.

Such an indication confirms the suitability of bottom ash as a natural pozzolan due to

the sum of the oxide compounds exceeds 70% as recommended by ASTM C 618

Standard (Billong et al., 2009).

Figure 2.8 Bottom ash application in US in 2007 (source: American Coal Ash

Association, ACAA)

Structural Fills

Embarkments

46.6%

Cement-Raw Feed

for Clinker

11.0%

Road Base

Subbase

Pavement

9.7%

Miscelaneous

Other

8.1%

Aggregate

7.7%

Concrete,

Concrete

Products, Grout

7.1%

Snow and Ice

Control

4.0%

Soil Modification

Stabilization

2.2%

Waste

Stabilization

Solidification

1.3%

Blast Grit, Roofing

Granules

1.0%

Mining

Applications

1.0%Mineral Filler in

Asphalt

0.2%

Agriculture

0.1%

Page 33: relationship between decomposition level and induced solidification

Figure 2.9

2.6 Factors affecting solidification of

The study of soil and cement interaction normally

Clay as inorganic soils reacts with cement nicely and form ettringite as product of

hydration process. This ettringite is the reason why the solidified clay strong and

stiff. However, the solidification of peat is more challenging th

inherent variability and the tendency of humic acids to hinder the hydration

processes and related reactions required for the development of

solidification (Axelsson

Peat consists

macromolecules collectively known as humic substance, that contribute to odour,

taste, as well as acidity in

substances represent one of the most chemicall

their high surface area, and surface charge, and thus have a critical influence on the

chemical and physical properties of soils

low pH of peat in the presence of

if it is to be stabilized by ordinary Portland cement. This is possible due to the fact

that the acid tends to react with calcium liberated from cement hydrolysis to form

insoluble calcium humic acid making it difficult for calcium c

calcium crystallization

Islam, 2008; Chen and Wang,

9 Particle size distributions for filler (Chimenos, 1999)

ffecting solidification of peat

The study of soil and cement interaction normally use clay as the benchmark.

Clay as inorganic soils reacts with cement nicely and form ettringite as product of

hydration process. This ettringite is the reason why the solidified clay strong and

stiff. However, the solidification of peat is more challenging than clay, given their

inherent variability and the tendency of humic acids to hinder the hydration

processes and related reactions required for the development of

(Axelsson et al., 2002).

s of organic matter, some of which are complex aromatic

macromolecules collectively known as humic substance, that contribute to odour,

taste, as well as acidity in water supply (Fong and Mohamed,

substances represent one of the most chemically reactive fractions

their high surface area, and surface charge, and thus have a critical influence on the

d physical properties of soils (Santagata et al., 2008).

low pH of peat in the presence of humic acid tend to interrupt the hydration process,

if it is to be stabilized by ordinary Portland cement. This is possible due to the fact

that the acid tends to react with calcium liberated from cement hydrolysis to form

insoluble calcium humic acid making it difficult for calcium c

calcium crystallization product would strenghten the cemented

; Chen and Wang, 2005).

23

Particle size distributions for filler (Chimenos, 1999)

clay as the benchmark.

Clay as inorganic soils reacts with cement nicely and form ettringite as product of

hydration process. This ettringite is the reason why the solidified clay strong and

an clay, given their

inherent variability and the tendency of humic acids to hinder the hydration

processes and related reactions required for the development of strength following

some of which are complex aromatic

macromolecules collectively known as humic substance, that contribute to odour,

water supply (Fong and Mohamed, 2006). Humic

y reactive fractions of the peat due to

their high surface area, and surface charge, and thus have a critical influence on the

2008). Organic matter and

the hydration process,

if it is to be stabilized by ordinary Portland cement. This is possible due to the fact

that the acid tends to react with calcium liberated from cement hydrolysis to form

insoluble calcium humic acid making it difficult for calcium crystallization. The

ed soil (Hashim and

Page 34: relationship between decomposition level and induced solidification

24

O'kelly and Pichan (2014) stated that addition of more FA produced a

progressively stronger alkaline blend which would inhibit growth of the

microorganisms and microbial activity. However, Mitchell and Santamarina (2005)

stated that microorganisms generally have very rapid rates of generation, mutation

and natural selection, which allows very fast adaptation and extraordinary

biodiversity to develop under ideal environments. This probability provides the

possibility that microorganism in the solidified peat is re-activated after sometime.

Thus, it secretes chemicals that digest organic matter into fragments (Hobbs, 1986;

Pankratov et al., 2011). Nevertheless, the microbial population and activity in peat

material have hardly been explored and are less understood.

Peat usually requires larger stabilizer quantities, because they contain few

solids to stabilize.Therefore, more stabilizers are required to bind the particles

together (Kalantari, 2010). The high water content in peat gives a higher water/total-

cementitious ratio and which in turn lower the strength. The quantity of binder for

soils with high organic content must exceed a certain threshold before any

stabilization is obtained. A possible reason for this threshold effect possibly due to

sufficient binder added to neutralize the humic acids (Janz and Johansson, 2002).

The quantity of natural fiber in peat gives a significant role in peat

solidification. Kalantari (2010) induced polypropylene fiber in hemic and sapric peat.

Hemic peat, as moderately decomposed consist of 33 - 66 % of fiber. The presence

of polypropylene fiber in hemic peat, improves its strength for about 600 %.

Dehghanbanadaki et al. (2013) use well graded sand, poorly graded gravel, coarse

poorly graded sand and fine poorly graded sand as filler to fibric peat. The strength

increased from 17 kPa to 178 kPa as the highest reading shown amongst the samples.

However, certain trend shown that too much of filler in solidified peat, reduced its

strength. The peat was found increasing it strength at dosage of filler 75 - 122 kg/m3

but started to decline at filler dosage of 125 - 150 kg/m3. It was somehow indicated

that maximum allowable quantity of filler should be added for peat solidification.

The behaviour of a soil-fiber composite is governed basically by the fiber

content, geometry, nature, and orientation related to the failure plane (Consoli et al.,

2011). Consoli et al. (2009) have shown that longer fibers provide anchorage, and

under low confining pressures, fiber slippage will occur. These studies have been

carried out in clay with artificial fiber which the size, shape and quantity were

controlled. The artificial fiber normally will not affect to microbial activity and the

Page 35: relationship between decomposition level and induced solidification

108

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APPENDIX

PUBLICATIONS

1) Abd Rahman, J. and Chan, C.M. (2013). Influence of Temperature on the Mass

Losses of Tropical Peat at Different Decomposition Level. Soft soil

Engineering International Confrence 2013. Sarawak.

2) Abd Rahman, J. and Chan, C.M. (2014) (a). A preliminary study of the threshold

limit for cementation of peat at different decomposition levels. Zaytoonah

University International Engineering Conference on Design and Innovation in

Sustainability 2014 (ZEC Infrastructure 2014). Amman, Jordan.

3) Abd Rahman, J. and Chan, C.M. (2014) (b). Effect of Additive to the Moisture

Content at Different Decomposition Level of Peat. Journal of Civil

Engineering Research 2014, 4(3A). 59-62.

4) Abd Rahman, J. and Chan, C.M. (2015). Physico-Chemical Characterization of

Peat at Different Decomposition Levels. Electronic Journal of Geotechnical

Engineering Vol 20, Bund 9. 4011-4019.