Report of Doppler-Free Saturation

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    Doppler-Free Saturation

    Spectroscopy

    Group: 66

    Karakoc, Deniz (03657305)

    Wang, Bo (03662383)

    Luchko, Ivan (03663869)

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    1. Introduction

    We learn the theory and experiment of Doppler-free saturated

    absorption spectroscopy, using it to observe and measure the

    hyperfine structure of 7  and .

    2. Hyperfine Structure of Rubidium

    The level scheme for the 5/ → 5/ transition in 7  and  could be shown in Figure 6 form manual like below.

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      Hyperfine Coupling constant 

    We can calculate the hyperfine structure shift by using the

    equation 24 in manual.

    ∆ v = A 2 + [3( + 1) 4(+1)(+1)8(21)(21) ] Where C = F(F + 1) J(J + 1) I (I + 1). A and B are thehyperfine coupling constant that descript the magnetic dipole

    and electric quadrupole interaction between electron and

    Nucleus.

      Hyperfine Shift

    By using the equation above, we could calculate the energy

    shift of 5/ in 7  and  . For convenience, we write thisenergy shift as a function of A and B.∆ v = a ∗ A + b ∗ B The result is listed below.

    7    5/ 

    F C a b F C a b3 4.5 2.25 0.25 4 7.5 3.75 0.25

    2 -1.5 -0.75 -0.75 3 -0.5 -0.25 -0.55

    1 -5.5 -2.75 0.25 2 -6.5 -3.25 -0.1

      Cross-Over Line

    Three additional cross-over lines will also be observed in

    experiment. The frequency of these cross-over line is in the

    middle of the lines above. For convenience, we add them into

    the table.

    7    

    5/ 

    F a b F a b

    3 2.25 0.25 4 3.75 0.252,3 0.75 -0.25 3,4 1.75 -0.151,3 -0.25 0.25 2,4 0.25 0.075

    2 -0.75 -0.75 3 -0.25 -0.551,2 -1.75 -0.25 2,3 -1.75 -0.3251 -2.75 0.25 2 -3.25 -0.1

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    3. Analysis of Data

    The shot form Oscilloscope is listed below. The left part

    come form  7  and the right part come form . 

    a. Energy Calibration

    The first thing is to determine the relation

    between Energy and time in Oscilloscope.

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    We use the signal form the Fabry-Perot

    interferometer, the green one, to calibrate.

    The frequency difference between two

    adjacent peaks is the free spectral range,500 MHz.

     After finding the Peaks, we fit it linearly like

    below.

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    Then we could plot the D2 line based on

    Frequency.

    b. Cross-over Line

     As the rubidium atoms are under roomtemperature, they follow the Maxwell –

    Boltzmann distribution. The cross-over line

    comes from the atoms with speed of−

     

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    on z direction. Base on Maxwell –Boltzmann

    distribution, like below, their population are

    much high than the ones with 0 speed on z

    direction. Therefore their amplitude is larger.

    For short, we will note the transition line

    7 : 5/, = 2 → 5 /, = 3 as (3), andthe cross over line between 7 : 5/, =

    2 →5/, = 2 and

    7 : 5/, = 2 →5/, = 3 as (2,3).c. Rb87

    The shot of Rb87 D2 line is listed below.

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    From left to right, these peaks are (1), (1,2),

    (2), (1,3), (2,3), (3). After fit the peaks with

    Lorentz, we got relative frequency of these

    peaks.

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    Then by using the table we got before, we

    could fit these six peaks with a 2D plane to

    find out the Hyperfine Coupling constant A

    and B of 7 5/.

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    Compare the official values from “Rubidium 87 DLine Data, Daniel A. Steck” the error is smaller than5%.

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    d. Rb85

    The analysis is similar. From left to right,

    these peaks are (2), (2, 3), (3), (2, 4), (3, 4),

    (4). After fit the peaks with Lorentz, we got

    relative frequency of these peaks. Here the

    peak (2) are too small to fit, so we dropped

    it.

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    Then by using the table we got before, we could fit

    these six peaks with a 2D plane to find out the

    Hyperfine Coupling constant A and B of 5/.

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    Compare the official values from “Rubidium 85 DLine Data, Daniel A. Steck” the error is smaller than5% too.