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7/21/2019 Revised Midterm Report Chemical Product Design
1/91
XGFPHS_FYB_ FGIDGH_FB
\BYHS ^XSF@FHS @DS IF_B_YHS SHKFH@
Shvfshi Efithre Shpdrt
LSDX^ 2LSDX^ ^HS_DGGHK:
BOMEBI @BYMDGV (22>0>>3)
BGF@BM (22>0>22902)
@BSF_ SBZBGBM Z. (22>0>>8338)EBXMFCFVB _MD@B (22>0>2>828)
SFZAV ^BGIX _. (>6>08898)
OMHEFOBK HGLFGHHSFGL IH^BSYEHGY
HGLFGHHSFGL @BOXKYV
XGFPHS_FYB_ FGIDGH_FB
IH^DA
3>29
7/21/2019 Revised Midterm Report Chemical Product Design
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ffXgfvhrsftbs Fgidghsfb
KF_Y D@ ODGYHGY
Kfst d` Odgthgt ............................................................................................... ffKfst d` @flurhs ................................................................................................ fv
Kfst d` Ybckhs ................................................................................................. v
OMB^YHS FFGYSDIXOYFDG .............................................................. 2
2.2. Cboalrdugi ................................................................................. 2
2.3. @dreukbtfdg d` ^rdckhe ............................................................... 9
2.?. Fihgtf`fobtfdg d` ^rdckhe ............................................................. 8
2.9. Kfeftbtfdg d` ^rdckhe .................................................................. 8
OMB^YHS FFKFYHSBYXSH SHPFH\ ................................................. 0
OMB^YHS FFFGHHI_ ............................................................................. 2
@flurh ?.8. BgswhrsSbtfd Cbshi dg Ruhstfdg ? ............................................ 3>
@flurh ?.0. Bgswhrs Sbtfd Cbshi dg Ruhstfdg 9 ............................................ 32
@flurh ?.
7/21/2019 Revised Midterm Report Chemical Product Design
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vXgfvhrsftbs Fgidghsfb
KF_Y D@ YBCKH_
Ybckh 2.2. Ebfg ^brbehthr d` Irfgafgl \bthr ................................................ =
Ybckh 2.3. Biiftfdgbk brbehthr d` Irfgafgl \bthr ....................................... 6
Ybckh 2.?. Odepbrfsdg d` _deh Ehtmdis d` urf`yfgl \bthr ......................... 22
Ybckh ?.2. Ghhis Fgthrprhtbtfdg @rde Oustdehr _tbthehgt ............................. 39
Ybckh ?.3. Oustdehr Ghhis ............................................................................ 30
Ybckh ?.?. Yfiy Xp Ghhis .............................................................................. 3
Ybckh 9.2. Kfst d` Ehtrfos ............................................................................... ??
Ybckh 9.3.Ebtrfx d` Ghhis bgi Ehtrfos .......................................................... ?9
Ybckh 9.?. Kfst d` Ehtrfos rde Hxfstfgl ^rdiuot ............................................ ?0
Ybckh 9.9. Kfst d` _phof`fobtfdg ...................................................................... ?.>>< phrohgt d` tmh pkbght's wbthr fs
bvbfkbckh td `uhk bgi `hhi fts 0.= cfkkfdg phdpkh. Iuh td lhdlrbpmy, okfebth,
hglfghhrfgl, rhlukbtfdg, bgi odephtftfdg `dr rhsdurohs, sdeh rhlfdgs shhe
rhkbtfvhky `kusm wftm `rhsmwbthr, wmfkh dtmhrs `boh irdulmt bgi ihcfkftbtfgl
pdkkutfdg. Fg euom d` tmh ihvhkdpfgl wdrki, okhbg wbthr fs hftmhr mbri td odeh cy
dr b odeedifty tmbt rhqufrhs kbcdrfdus wdra dr sflgf`fobgt ourrhgoy td dctbfg.
\mfkh, Fg Fgidghsfb, 2> dut d` 2,>>>
Fgidghsfbgs su``hr `rde wbthr-cdrgh ifshbshs suom bs omdkhrb, iyshgthry bgi
typmdfi `hvhr. Dtmhr ibtb bksd sbfi tmbt fg Fgidghsfb, bcdut ,>>> ihbtms bggubkky fg
Fgidghsfb. \bthr odgtbefgbtfdg mbs chhg rhpdrthi fg cdtm sur`boh bs whkk bs
lrdugi wbthr sdurohs fg tmh odugtry. Boodrifgl td b `rhsmwbthr rhshbromhr bt tmh
Fgidghsfbg Shshbrom Fgstftuth (KF^F), Fgidghsfb mbs tmh wdrst irfgafgl wbthr fg
_dutmhbst Bsfb.
\bthr fs hsshgtfbk fg hvhry sftubtfdg. Fg hehrlhgofhs dr fg b ifsbsthr
odgiftfdg suom bs `kddi, vdkobgd hruptfdg, hto tmbt bggubkky mbpphg fg Fgidghsfb ft
7/21/2019 Revised Midterm Report Chemical Product Design
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3
Xgfvhrsftbs Fgidghsfb
fs d`thg gdt bvbfkbckh fg bihqubth qubgtfty dr qubkfty, tmus orhbtfgl b ebjdr mhbktm
mbzbri. ^hdpkh obg survfvh kdglhr wftmdut `ddi tmbg wftmdut wbthr. Ymus tmh
prdvfsfdg d` wbthr ihebgis feehifbth btthgtfdg `rde tmh stbrt d` b hehrlhgoy
sftubtfdg suom bs ifsbsthr. Ymh bfe fs td bssurh bvbfkbcfkfty d` hgdulm wbthr td
bkkdw su``fofhgt ifstrfcutfdg bgi td hgsurh tmbt ft fs sb`h td irfga. Bihqubth stdrblh
bgi cboaup systhes `dr bkk bsphots d` wbthr suppky eust ch bssurhi, sfgoh
fgthrruptfdgs fg tmh suppky eby ch ifsbstrdus. Yd bvdfi odgtbefgbtfdg, bkk sdurohs
d` wbthr ushi cy rh`ulhhs bgi ifsbsthr vfotfes eust ch shpbrbthi `rde sbgftbtfdg
`bofkftfhs bgi dtmhr sdurohs d` odgtbefgbtfdg. Ft fs fepdrtbgt, mdwhvhr, td chbr fg
efgi tmh `bot tmbt iuh td if``fouktfhs fg prhifotfgl tmh kf`hspbg d` b rh`ulhh obep,
tmh edst bpprdprfbth bkthrgbtfvh wfkk bkwbys ch tmh dgh wmfom bibpts chtthr td b
odst-h``hotfvh kdgl thre shrvfoh.
\bthr bvbfkbcfkfty wfkk lhghrbkky ch tmh ihthrefgfgl `botdr fg drlbgfzfgl tmh
suppky d` su``fofhgt qubgtftfhs d` sb`h wbthr. Ft eby ch ghohssbry td ebah sphofbk
brrbglhehgts `dr tmh fihgtf`fobtfdg bgi ihvhkdpehgt d` ghw sdurohs, wbthr
hxtrbotfdg, stdrblh bgi ifstrfcutfdg. Ehbsurhehgt wfkk ch rhqufrhi td prdthot tmh
wbthr `rde odgtbefgbtfdg bgi fg sdeh ofrouestbgohs trhbtehgt wfkk ch ghhihi td
ebah ftsb`h td irfga. Ymh sb`hty d` tmh wbthr eust ch bssurhi rflmt tmrdulm td
odgsueptfdg bt mdeh.
\bthr qubkfty fs bkwbys if``foukt td boohss. Bkwbys bssueh tmbt bkk wbthr
bvbfkbckh iurfgl bg hehrlhgoy fs odgtbefgbthi, hsphofbkky f` bvbfkbckh sdurohs brh
sur`boh wbthr cdifhs (kbahs, pdgis ,rfvhrs, hto.). Feehifbth botfdg eust ch tbahg
td stdp `urtmhr pdkkutfdg bgi td rhiuoh odgtbefgbtfdg. F` ft fs prdvhg tmbt bvbfkbckh
sdurohs brh fgbihqubth (fg thres d` qubkfty dr qubgtfty), brrbglhehgts eust ch
ebih td `fgi bkthrgbtfvh sdurohs bgi, f` ghohssbry, td fepdrt wbthr td tmh sfth (cytruoa, cbrlh, pfphkfghsdr bgy dtmhr rhkhvbgt ehbgs). \mhrh hvhg tmh edst cbsfo
ghhis `dr wbthr obggdt sb`hky ch eht cy tmh hxfstfgl rhsdurohs bt tmh sfth dr fts
surrdugifgls, bgi wmhg tfeh fs ghhihi `dr `urtmhr hxpkdrbtfdg bgi ihvhkdpehgt d`
ghw sdurohs, rh`ulhhs bgi ifsbsthr vfotfes smduki ch edvhi td b edrh suftbckh
kdobtfdg.
Yfehky bgi bihqubth prdvfsfdg d` okhbg wbthr td rh`ulhhs d` sphofbk
fepdrtbgoh lfvhg tmbt tmhy mbvh trbiftfdgbkky `bohi if``fouktfhs fg `ukky hxhrofsfgl
7/21/2019 Revised Midterm Report Chemical Product Design
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?
Xgfvhrsftbs Fgidghsfb
tmhfr rflmts bgi brh vhry prdgh td hxpkdftbtfdg. Ymh rflmt d` wbthr `dr rh`ulhhs
rhvdkvhs brdugi XIMS (Xgfvhrsbk Ihokbrbtfdg d` Muebg Sflmts, 269=) Brtfokh
38: Hvhrydgh mbs tmh rflmt td b stbgibri d` kfvfgl bihqubth `dr tmh mhbktm bgi
whkk-chfgl d` mfeshk` bgi mfs `befky.
Ymh rflmt td lht wbthr wbs hxpkfoftky rhodlgfzhi bgi mbs chodeh bg
fgthrgbtfdgbk prfdrfty wmhg fg kbth 3>>3 HOD_DO (Hodgdefos bgi _dofbk
Odugofk), b XG drlbg bgi tmh suphrvfsdry cdiy `dr Fgthrgbtfdgbk Odvhgbgt dg
Hodgdefo, _dofbk bgi Oukturbk Sflmts (OH_OS), bidpthi b Lhghrbk Odeehgt
strhssfgl Ymh muebg rflmt td irfgafgl wbthr fs `ugibehgtbk `dr kf`h bgi mhbktm.
Ymdulm ft fs fepdrtbgt td prdvfih bihqubth qubgtftfhs d` wbthr, tmh wbthr
qubkfty bgi mylfhgh fs bksd d` tmh utedst fepdrtbgoh. Hvhg f` tmh wbthr tmbt fs
prdvfihi fs gdt odgtbefgbthi, tmh trbgs`hr d` wbthr chtwhhg vhsshks, tmh stdrblh d`
wbthr fg tmh mdeh, bgi tduomfgl tmh fgsfih d` wbthr vhsshks wftm tmh mbgis brh rfsa
`botdrs `dr odgtbefgbtfdg. Ft fs bksd fepdrtbgt `dr tmh wbthr td ch rhbifky
boohssfckh, bgi tmh tbps smduki ch ohgtrbkky kdobthi. F` tmh wbthr tbps brh `br bwby,
omfkirhg eflmt mbvh td fgthrrupt tmhfr somddkfgl td odkkhot wbthr `dr tmhfr `befkfhs.
Fg biiftfdg, f` tmh wbthr tbps brh vhry `br bwby, tmh pmysfobk curihg d` wbthr
odkkhotfdg lrdws feehgshky. @dr hxbepkh, f` b phrsdg irbws wbthr `dr bkk d` tmhfr
`befkys ghhis (brdugi =>K) `rde b whkk kdobthi 3>> ehthrs `rde tmhfr mdeh, tmhy
eby ush up td 2/0 d` mfs/mhr rbtfdghi obkdrfhs `dr tmh iby dg tmfs dgh tbsa. Ymh
XGMOS tmhrh`drh rhodeehgis tmbt bkk mdushmdkis mbvh boohss td b wbthr tbp tmbt
fs khss tmbg 3>> ehthrs bwby. Xg`drtugbthky, ebgy phdpkh fg ifsbsthr odgiftfdg id
gdt ehht tmfs stbgibri.
Ymfs fs hsshgtfbk `dr ifsbsthr vfotfes td rhohfvh bg bihqubth qubgtfty d` lddi
qubkfty wbthr chobush wbthr mbs bg fepbot dg sd ebgy vftbk shotdrs d` sdofhty,fgokuifgl gutrftfdg, mhbktm, hiuobtfdg bgi sbgftbtfdg. Hgsurfgl tmbt tmh rh`ulhhs
rhohfvh bg bihqubth qubgtfty d` wbthr fs bg fepdrtbgt puckfo mhbktm fssuh chobush
kboa d` okhbg wbthr fs odrrhkbthi wftm tmh prhshgoh d` ifshbshs suom bs ifbrrmhb bgi
omdkhrb.
@rde tmh ibtb tmbt wh mbvh hxpkbfghi bcdvh, td odvhr bgi `uk`fkk bihqubth
qubgtfty d` lddi qubkfty wbthr suppky `dr rh`ulhhs fg ifsbsthr rhkfh`, wbthr purf`fhr
fs usubkky ehgtfdghi bs tmh sdkutfdg. Boodrifgl td tmh rhohgtky puckfsmhi rhpdrt cy
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Xgfvhrsftbs Fgidghsfb
Yhom_of Shshbrom Fgidghsfb \bthr ^urf`fhr Ebraht @drhobst & Dppdrtugftfhs
3>2=, tmh ihebgi `dr wbthr purf`fhrs fs fgorhbsfgl bgi wbthr purf`fhr ebraht
rhvhguhs brh hxphothi td lrdw cy dvhr twd `dkis, fgorhbsfgl bt tmh OBLS
(Odepdugi bggubk Lrdwtm Sbth) d` brdugi 29% iurfgl 3>2?.
Xg`drtugbthky, edst d` hxfstfgl wbthr purf`fhr prdiuot ush tmh ibglhr
sucstbgoh suom bs omkdrfgh td purf`y tmh wbthr, ft fs sd ibglhr tmbt tmh usfgl d`
omkdrfgh dg wbthr purf`yfgl prdohss mbs chhg `drcfiihg. Dg tmh dtmhr sfih, tmh
hxfstfgl wbthr purf`fhr prdiuot mbs if``foukt bgi odepkfobthi dphrbtfdg prdohiurh,
ghhikdgl tfeh prdohss td prdiuoh purf`fhi wbthr, tmh purf`fhi wbthr tmbts gdt
lddi fg qubkfty, if``foukt d` ebfgthgbgoh prdohiurh, tmh hxphgsfvh d` wbthr
purf`fhr, bgi d` odursh tmh purf`fhi wbthr dutput tmbt fs stfkk iduct`uk. @rde tmbt
whbaghss d` hxfstfgl wbthr purf`fhr prdiuot wh wbgt td ebah b wbthr purf`fhr
tmbts omhbphr sd ft obg chodeh bg fgokusfvh prdiuot `dr rh`ulhhs bgi bksd edrh
h``hotfvh bgi mhbktmy tmbg tmh hxfstfgl wbthr purf`fhr.
2.3. @dreukbtfdg d` rdckhe
Ymh odgohpt d` ihsflgfgl tmfs wbthr purf`fhr prdiuot `dr ifsbsthr vfotfes fg
Omhefobk ^rdiuot Ihsflg _ucjhot fs td odvhr tmh whbaghss d` tmh hxfstfgl wbthr
purf`fhr bgi `uk`fkk tmh crbgi ghw ghhis d` wbthr purf`fhr ushr fg Fgidghsfb
hsphofbkky `dr fgorhbsfgl tmh suppky d` okhbg bgi irfgafgl wbthr wmhg ifsbsthr
mbpphg. \mfkh, tmhrh brh sdeh whbaghss tmbt mbvh chhg fihgtf`fhi `rde tmh
hxfstfgl wbthr purf`fhr prdiuot bs tmhsh `dkkdws: if``foukt bgi odepkfobthi
dphrbtfdg prdohiurh, tmh kdgl tfeh prdohss ghhihi td prdiuoh purf`fhi wbthr, tmh
purf`fhi wbthr tmbt gdt lddi fg qubkfty, if``foukt d` ebfgthgbgoh prdohiurh, tmh
hxphgsfvh prfoh d` wbthr purf`fhr, tmh purf`fhi wbthr dutput tmbt fs stfkk iduct`ukbksd tmh usfgl d` ibglhr sucstbgoh suom bs omkdrfgh td purf`fhi tmh wbthr. @rde
tmbt wh wbgt td ebah b wbthr purf`fhr tmbt obg rhsdkvh tmh prdckhes.
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Xgfvhrsftbs Fgidghsfb
2.?. Fihgtf`fobtfdg d` ^rdckhe
@rde tmh hxfstfgl wbthr purf`fhr prdiuot obg ch fihgtf`fhi sdeh brh bs
`dkkdws:
b.
Ymh ghhis d` okhbg bgi irfgafgl wbthr `dr tmh vfotfe ifsbsthr fg ifsbsthr
rhkfh`.
c. Edst d` hxfstfgl wbthr purf`fhr ghhi kdgl tfeh dg purf`yfgl prdohss td
prdiuoh irfgafgl wbthr.
o. Edst d` hxfstfgl wbthr purf`fhr fs sd hxphgsfvh sd ft obgtch rhbomhi cy
efiikh-kdw okbss sdofhty
i.
Edst d` hxfstfgl wbthr purf`fhr fs gdt pdrtbckh sd ft ebah tmh phdpkh
if``foukt td pkboh bgi dphrbth tmh hxfstfgl wbth purf`fhr
h.
_deh d` tmh hxfstfgl wbthr purf`fhr stfkk usfgl tmh mbre`uk omhefobk
sucstbgoh suom bs omkdrfgh td purf`y tmh wbthr.
2.9. Kfeftbtfdg d` rdckhe
Fg drihr td ebah stuiy bcdut wbthr purf`fhr idhs gdt hxthgi, fg tmfs omhefobk
prdiuot ihsflg ft wfkk ch kfefthi cy:
b.
Ymfs wbthr purf`fhr fs ihsflghi td `uk`fkk tmh mhbktmy bgi irfgafgl wbthr
`dr ifsbsthr
c.
Ymfs wbthr purf`fhr prdiuot fs ihsflghi bgi `dreukbthi td prdiuoh tmh
mhbktmy bgi irfgafgl wbthr.
o.
Ymfs wbthr purf`fhr prdiuot fs ihsflghi bgi purpdshi td ch fgokusfvh bgi
mhbktmy fssuh.
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0Xgfvhrsftbs Fgidghsfb
OMB^YHS FF
KFYHSBYXSH SHPFH\
3.2. Ih`fgftfdg d` \bthr
\bthr fs omhefobk odepdugi wftm tmh omhefobk `dreukb M3D. B wbthr
edkhoukh odgtbfgs dgh dxylhg bgi twd myirdlhg btdes odgghothi cy odvbkhgt
cdgis. \bthr fs b kfqufi bt becfhgt thephrbturh bgi prhssurh. \bthr odvhrs :
b.
Okhbg wbthr
Okhbg wbthr fs wbthr tmbts qubkf`fhi `dr ibfky botfvftfhs suom bs
cbtmfgl, wbsmfgl okdtmhs, hto.
7/21/2019 Revised Midterm Report Chemical Product Design
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2>. Ft odgsfsts d` ebfg pbrbehthr bgi
biiftfdgbk pbrbehthr d` irfgafgl wbthr. Ymh ebfg pbrbehthrs ebfgky rhkbthi td
pbrbehthr vbkuh rhkbthi td mhbktm (efordcfdkdlfobk pbrbehthr, bgdrlbgfo omhefobk
pbrbehthr) bgi gdg-mhbktm (pmysfobk pbrbehthr bgi omhefobk pbrbehthr bs whkk).
7/21/2019 Revised Midterm Report Chemical Product Design
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=
Xgfvhrsftbs Fgidghsfb
Ybckh 2.2. Ebfg ^brbehthr d` Irfgafgl \bthr
Gd ^brbehthr Pbkuh XgftEbxfeue Odgthgt
^hreftthi2 ^brbehthr Shkbthi td Mhbktm
b. Efordcfdkdlfobk ^brbehthr
2) H.OdkfXgft/2>>
ek sbepkh>
3) Odkf`dre CbothrfbXgft/2>>
ek sbepkh>
c. Bgdrlbgfo Omhefobk
2) Brshg el/k >.>2
3) @kudrfih el/k 2.8
?) Omrdefue el/k >.>8
9) Obiefue el/k >.>>?
8) Gftrfth (bs GD3-) el/k ?
0) Gftrbth (bs GD?-) el/k 8>
.>.>2
3 ^brbehthr Gdt Shkbthi td Mhbktm
b. ^mysfobk ^brbehthr
2) Didr Didrkhss
3) Odkdr YOX 28
?) Ydtbk Ifssdkvhi _dkfi(YI_)
el/k 8>>
9) Yurcfifty GYX 8
8) Ybsth Ybsthkhss
0) YhephrbturhdO
Btedspmhrfo
Yhephrbturh +- ?
c. Omhefobk ^brbehthr
2) Bkuefgfue el/k >.3
3) @hrrue el/k >.?
?) Beedgfb el/k 2.8
9) Omkdrfih el/k 38>
8) Ebglbg el/k >.9
0) Bofifty pM 0.8-=.8
6) Odpphr el/k 3
(_duroh : ^hrehgahs, 3>2>)
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6
Xgfvhrsftbs Fgidghsfb
Ybckh 3.3. Biiftfdgbk ^brbehthr d` Irfgafgl \bthr
Gd ^brbehthr Pbkuh XgftEbxfeue Odgthgt
^hreftthi
2 Omhefobk
Bgdrlbgfo sucstbgoh
Ehroury el/k >.>>2
Bgtfedg el/k >.>3
Cbrfue el/k >..8
Edkycihgue el/k >.>.>>
Yfecbk el/k >.>2
Xrbgfue el/k >.>28Drlbgfo sucstbgoh
AEgD9 el/k 2>
Ihthrlhgt el/k >.>8
Omkdrfgbthi bkabghs el/k
Obrcdg thtrbomkdrfih el/k >.>>9
Ifomkdrdehtmbgh el/k >.>3
2,3-Ifomkdrdhtmbgh el/k >.>8
Brdebtfo myirdobrcdgs el/k
Chgzhgh el/k >.>2
Ydkuhgh el/k >..8
Htmykchgzhgh el/k >.?
_tyrhgh el/k >.>3
Omkdrfgbthi chgzhghs el/k
2,3-Ifomkdrdchgzhgh el/k 2
2,9-Ifomkdrdchgzhgh el/k >.?
If(3>htmykmhxyk)pmtmbkbth el/k >.>>=
Borykbefih el/k >.>>>8
Hpfomkdrdmyirfg el/k >.>>>9
Mhxbomkdrdcutbifhgh el/k >.>>>0
HIYB el/k >.0
GYB el/k >.3
^hstfsfih
Bkbomdr el/k >.>3
Bifobrc el/k >.>2
Bkirfg el/k >.>>>>?
Btrbzfgh el/k >.>>3
Obrcd`urbg el/k >.>>
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2>
Xgfvhrsftbs Fgidghsfb
Ybckh 3.3. Biiftfdgbk ^brbehthr d` Irfgafgl \bthr (odgtfguhi)
Gd ^brbehthr Pbkuh XgftEbxfeue Odgthgt
^hreftthi
Omkdribgh el/k >.>>>3
Omkdrdtdkurdg el/k >.>?IIY el/k >.>>2
Ifsfg`hotbgt bgi Fts
Cyprdiuot
Omkdrfgh el/k 8
Crdebth el/k >.>2
Omkdrbth el/k >...3
Crded`dre el/k >.2
ICOE el/k >.2
CIOE el/k >.>0
Omkdrd`dre el/k >.?
3 Sbifdbotfvfty
Lrdss bkpmb botfvfty Cq/k >.2
Lrdss chtb botfvfty Cq/k 2
(_duroh : ^hrehgahs, 266>)
Fg Fgidghsfb, edgftdrfgl bgi suphrvfsfdg d` irfgafgl wbthr qubkfty fs obrrfhicy twd fgstftutfdg : kdobk mhbktm ihpbrthehgt bgi wbthr suppky odepbgy (^BE).
Ymdulm edgftdrfgl bkrhbiy bgi odgtfguhs td ch idgh, ugtfk gdw ft mbs yht td ch
hvbkubthi tmh hxthgt wmhtmhr tmh wbthr qubkfty ehht tmh rhqufrhehgt `rde
^hrehgahs dr gdt.
3.9. \bthr urf`fobtfdg
_fgoh tmh qubkfty d` wbthr fs if``hrhgt fg hvhry brhb bgi fts mbri td odgtrdk,
wbthr `rde ugfeprdvhi sdurohs fs d`thg suppkfhi td odeeugftfhs. Ymhrh`drh,
wbthr ghhi td ch prdohsshi td ombglh ft fgtd irfgafgl wbthr stbgibri. \bthr
purf`fobtfdg fs tmh prdohss d` rhedvfgl odgtbefgbgts bgi ugihsfrbckh omhefobks,
sdkfis, bgi lbs bs whkk `rde odgtbefgbthi wbthr.\bthr purf`fobtfdg eby bksd
ihsflghi `dr dtmhr purpdshs, fgokuifgl ehhtfgl tmh rhqufrhehgts d` ehifobk,
pmbrebodkdlfobk, omhefobk, bgi fgiustrfbk bppkfobtfdgs. Cut fts odeedgky ushi td
prdohss `rhsm-wbthr fgtd irfgafgl wbthr, sfgoh irfgafgl fs dgh d` ebfg muebg
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ghhi. Ymh purf`fobtfdg prdohss wfkk rhiuoh tmh odgohgtrbtfdg d` pbrtfoukbth ebtthr
kfah susphgihi pbrtfokhs, cbothrfb, vfrushs, bgi pbrbsfths. Hgvfrdgehgtbk prdckhe
`bohi cy tmh wdrki gdwbibys ebahs wbthr purf`fobtfdg prdohss fs vhry fepdrtbgt
`dr muebg.
3.8. Lhghrbk \bthr ^urf`fobtfdg Ehtmdis
Ymhrh brh sd ebgy ehtmdis td purf`y wbthr. Ymhy brh if``hrhgt fg prdohss
bgi ehombgfse cut mbs dgh ldbk, rfsh dr kdwhr sdeh sucstbgohs odgthgt fg wbthr
fgtd stbgibri khvhk. Ymh ehtmdis td purf`y wbthr odvhr efordcfdkdlfobk, omhefobk,
bgi pmysfobk fgokuifgl ifsfg`hotfdg (omkdrfgbtfdg, sdkbr ifsfg`hotfdg, XP
frrbifbtfdg, bgi cdfkfgl), pbrtfokh `fktrbtfdg (`fkthr thomgdkdly), bisdrptfdg, bgi
dtmhrs (odblukbtfdg, `kdooukbtfdg). Ymh omdfoh d` tmh ehtmdi wfkk ihphgi dg
if``hrhgt `botdrs suom bs odst, hbsh td ush, bvbfkbcfkfty, bgi prbotfobkfty.
Ybckh 3.?. Odepbrfsdg d` _deh Ehtmdis d` ^urf`yfgl \bthr
YrhbtehgtBvbfkbcfkfty bgi
^rbotfobkfty
Yhomgfobk
if``fouktyOdst
Cdfkfgl \bthr Pbrfhs Kdw-edihrbth Pbrfhs
Omhefobk Yrhbtehgt
(Omkdrfgh) Mflm td edihrbth Kdw-edihrbth Edihrbth
_dkbr Ifsfg`hotfdg Mflm Kdw-edihrbth Kdw
XP Kbep Yrhbtehgt Pbrfhs Kdw-edihrbth Edihrbth-mflm
@fktrbtfdg Pbrfhs Kdw-edihrbth Pbrfhs
(_duroh : Sby, 3>22)
3.8.2. Omkdrfgbtfdg
Omkdrfgbtfdg fs b ehtmdi fg wmfom biifgl tmh omkdrfgh sucstbgoh td tmh
`rhsm-wbthr td afkks cbothrfb, vfrushs, hto. Fts odeedg bgi omhbp ehtmdi cut
hxtrhehky tdxfo. F` tmh odgohgtrbtfdg fs tdd kdw, omkdrfgh kboas botfvfty blbfgst
ohrtbfg drlbgfse kfah prdtdzdbk oysts. Cut f` tmh odgohgtrbtfdg fs tdd mflm, ft obg
ibeblh dur mhbktm. Fts smduki ch gdthi tmbt omkdrfgbtfdg idhs gdt ihorhbsh
pmysfobk dr omhefobk odgtbefgbtfdg.
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3.8.3. Bisdrptfdg
Bisdrptfdg prdohsshs brh wfihky ushi fg wbthr purf`fobtfdg. Botfvbthi
obrcdg fs tmh edst fepdrtbgt bisdrchgt bppkfhi fg wbthr purf`fobtfdg. Fts wfihky
ushi td rhedvh drlbgfo sucstbgohs `rde if``hrhgt typhs d` wbthr, fgokuifgl
irfgafgl wbthr.
Bt tmh chlfggfgl, tbsth bgi didr odepdugis whrh ebfg tbrlht d` bisdrchgt
fg bisdrptfdg prdohss, wmhrhbs kbthr tmh bppkfobtfdg d` bisdrchgt (suom bs bot fvbthi
obrcdg) wbs bksd prdvhi td ch h``fofhgt `dr rhedvbk d` wfih rbglh d` `urtmhr
drlbgfo efordpdkkutbgts, suom bs pmhgdk.
Botfvbthi obrcdg `fkthrfgl utfkfzhs b `dre d` pdwihr botfvbthi obrcdg (^BO)
wftm b mflm sur`boh brhb, bgi bisdrcs ebgy odepdugis, fgokuifgl ebgy tdxfo
odepdugis. \bthr pbssfgl tmrdulm botfvbthi obrcdg fs odeedgky ushi fg odgohrt
wftm mbgi puephi `fkthrs td biirhss drlbgfo odgtbefgbtfdg, tbsth, dr dcjhotfdgbckh
didrs. Botfvbthi obrcdg `fkthrs brhg't usubkky ushi bs tmh prfebry purf`fobtfdg
thomgfquhs d` pdrtbckh wbthr purf`fobtfdg ihvfohs, cut rbtmhr bs shodgibry ehbgs
td odepkhehgt bgdtmhr purf`fobtfdg thomgfquh. Ft fs edst odeedgky fepkhehgthi
`dr prh dr pdst-`fkthrfgl, fg b shpbrbth sthp, `dr tmh biiftfdg d` omhefobk
ifsfg`hotbgts ushi td odgtrdk cbothrfb dr vfrushs tmbt `fkthrs obggdt rhedvh.
Botfvbthi ombrodbk obg rhedvh omkdrfgh `rde trhbthi wbthr, rhedvfgl bgy rhsfiubk
prdthotfdg rhebfgfgl fg tmh wbthr prdthotfgl blbfgst pbtmdlhgs, bgi smduki gdt, fg
lhghrbk, ch ushi wftmdut obrh`uk tmdulmt b`thr omhefobk ifsfg`hotfdg trhbtehgts fg
pdrtbckh wbthr purf`fobtfdg prdohssfgl.
3.8.?. Cdfkfgl
Crfglfgl tmh wbthr up td cdfkfgl pdfgt wfkk sthrfkfzh tmh wbthr. Hvhg
thephrbturh d` 88dO wfkk fgbotfvbth edst cbothrfb. Cdfkfgl wbthr `dr 28 td 3>
efguths afkks 66.6% d` bkk kfvfgl tmfgls bgi vbpdrfzhs edst omhefobks. Efghrbks,
ehtbks, sdkfi, bgi tmh odgtbefgbtfdg obg bksd chodeh edrh odgohgtrbthi. Ft fs
lrhbt ehtmdi cut ft tbahs qufth b kdgl tfeh bgi ihphgt dg tmh qubgtfty d` wbthr.
Ymh edrh wbthr cdfkhi, tmh edrh pdwhr ghhihi fg `dre d` mhbt rhqufrhi td cdfk tmh
wbthr.
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3.8.9. XP ^urf`fobtfdg
^drtbckh XP wbthr purf`fobtfdg wbs pbthgthi fg 2666 cy Myird-^mdtdg, Fgo.
wmhg tmh `frst phrsdgbk XP wbthr purf`fhr wbs fgtrdiuohi. @hhi wbthr `kdws pbstbg uktrb vfdkht kflmt cukc bgi tmh XP rbys wfkk ihstrdy tmh IGB fg drlbgfses,
fgokuifgl cbothrfb bgi vfrushs. H``hotfvhghss d` XP purf`fobtfdg fs ihthrefghi cy
wbthr okbrfty, `kdwrbth, bgi XP Sby dutput. Ymh kflmt sduroh eust ch su``fofhgtky
crflmt bgi tmh `hhi wbthr eust mbvh tmh prdphr `kdw td ch h``hotfvh. Ymh ebfg
bivbgtblh d` XP purf`fobtfdg fs hghrly odsts brh sebkkhr tmbg tmdsh `dr cdfkfgl
wbthr.
Ifsbivbgtblh d` XP purf`fobtfdg fs XP dgky afkks eforddrlbgfses. XP
obggdt rhedvh sbkts, efghrbks, mhbvy ehtbks, phstfofihs, bgi dtmhr fgdrlbgfo
odepdugis `rde wbthr. Bksd f` tmh `hhi wbthr fs turcfi, ifssdkvhi sdkfis tmbt
ebahs wbthr turcfi wfkk ckdoa XP kflmt, ebafgl ft euom khss h``hotfvh. _d ft wfkk
ch chtthr f` tmh `hhi wbthr fs okhbr. odgohrg wftm XP pdrtbckh wbthr purf`fobtfdg fs
tmbt sdeh pbtmdlhgs brh mugirhis d` tfehs khss shgsftfvh td XP kflmt tmbg dtmhrs.
@flurh 3.2. _photrue d` Kflmt Shlbrifgl Ifsfg`hotfdg H``hotfvhghss
(_duroh : @rbgakfg, _., mttp://odkistdrblh.ebocdgsbf.ode/bip-kfcrbry/^uckfo/prdjhots/wbthr-
`fktrbtfdg-cis/idouehgts/\bthr-^urf`fobtfdg-Odepbrfsdg.ppsx1 30tm@hc 3>29)
3.8.8. @fktrbtfdg
@fktrbtfdg sfhvhs dut odgtbefgbgts cy edkhoukbr sfzh bgi whflmt. Ymfs
ehtmdi orhbths b cbrrfhr td rhedvh odgtbefgbgts. @fktrbtfdg usubkky fs ifvfihi fgtd
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uktrb`fktrbtfdg bgi rhvhrsh dsedsfs. ^drh sfzh fs hxtrhehky sebkk dg rhvhrsh
dsedsfs systhes bgi b cft kbrlhr dg uktrb`fktrbtfdg systhes. Ymh pdrh sfzh b``hots
tmh bedugt d` prhssurh, bgi tmhrh`drh hghrly, rhqufrhi td pusm tmh wbthr tmrdulm
tmh ehecrbgh.
@flurh 3.3. @fktrbtfdg ^rdohss H``hotfvhghss
(_duroh : @rbgakfg, _., mttp://odkistdrblh.ebocdgsbf.ode/bip-kfcrbry/^uckfo/prdjhots/wbthr-
`fktrbtfdg-cis/idouehgts/\bthr-^urf`fobtfdg-Odepbrfsdg.ppsx1 30tm@hc 3>29)
Xktrb `fktrbtfdg fs lddi hsphofbkky f` tmh wbthr fs `rde kbahs, strhbes, bgi
whkks. Ft rhedvhrs cbothrfb, vfrushs, pbrbsfths, phstfofihs, ehifobtfdgs, bklbh, ifrt,
sfkt, bgi dtmhr susphgihi sdkfis. Xktrb`fktrbtfdg mbs kdw hghrly rhqufrhehgt.
Ehbgwmfkh fg rhvhrsh dsedsfs, mflm prhssurh `hhi wbthr fs `drohi blbfgst b ihgsh,
ehecrbgh sur`boh. \bthr edkhoukhs if``ush tmrdulm tmh ehecrbgh khbvfgl tmh
odgohgtrbthi sbkts, dtmhr fdgs, bgi odgtbefgbgts chmfgi. Fts ihsflghi `dr gdg
pdrtbckh wbthr.
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@flurh 3.?. _fzh Ebtthrs Shlbrifgl Xktrb`fktrbtfdg bgi Shvhrsh Dsedsfs H``hotfvhghss
(_duroh : @rbgakfg, _., mttp://odkistdrblh.ebocdgsbf.ode/bip-kfcrbry/^uckfo/prdjhots/wbthr-`fktrbtfdg-cis/idouehgts/\bthr-^urf`fobtfdg-Odepbrfsdg.ppsx1 30
tm@hc 3>29)
3.8.0. Odblukbtfdg bgi @kdooukbtfdg
Fg prdohss d` odblukbtfdg bgi `kdooukbtfdg, tmrhh ebfg ehombgfse doours fg
shrfhs, stbrt `rde ihstbcfkfzbtfdg, tmhg prhofpftbtfdg, bgi odprhofpftbtfdg.
Odblukbtfdg bgi `kdooukbtfdg usubkky chodeh tmh `frst prdohss td purf`y wbthr. Fgodblukbtfdg, tmh bttbomehgt d` sebkk pbrtfokhs td dgh bgdtmhr bgi td sur`bohs fs
prdedthi fg bqubtfo hgvfrdgehgt. \mhg eford `kdoas odkkfih tmhy `dre
bllrhlbths wmfom brh kbrlhr struoturhs, bgi brh lhghrbkky stbthi bs `kdoas.
Fgdrlbgfo odblukbgts wmfom gdrebkky brh frdg dr bkuefgfue sbkts brh biihi td
chlfg omhefobk odblukbtfdg. Ymfs prdohss fs ghhihi td rhedvh sebkk pbrtfoukbth.
Odblukbtfdg wfkk ch `dkkdwhi cy `kdooukbtfdg. @kdooukbtfdg fs b pmbsh wmhrh tmh
`kdoa chlfg td `dre `rde hvhr kbrlhr pbrtfokhs. @kdooukbtfdg mbpphgs fg skdwhr
efxfgl stblh. Ymh pbrtfokhs wfkk `dre kbrlhr pbrtfokhs wmfkh tmh wbthr fs lhgtky
efxhi. Ymhg ft wfkk ch odecfghi wftm dtmhr ehtmdis.
3.8.
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prdvhg td ch h``hotfvh `dr wbthr purf`yfgl prdohss. Ehecrbgh suom bs X@/E@
prdohss obg ch cbrrfhr td pbrtfoukbth odgtbefgbgts bs whkk bs tmh biihi bisdrchgt,
wmfkh pdwihr-botfvbthi obrcdg rhedvh ifssdkvhi drlbgfos fgokuifgl phstfsfihs,
pmbrebohutfobks.
3.0. \bthr urf`fhr
\bthr purf`fhr fs b ihvfoh ushi td prdohss ugtrhbthi sdurohs d` wbthr (rfvhrs,
kbah, hto) fgtd irfgafgl wbthr. \bthr purf`fhr fs hsshgtfbk td dctbfg wbthr tmbt ehht
sphof`fobtfdg td ch odgsuehi. Fgsfih wbthr purf`fhr, tmhrh brh wbthr purf`yfgl
prdohss tmbt ush ehtmdis ehgtfdghi bcdvh. Ymh omdfoh d` ehtmdis odgtbfg ebgy
bsphot, fgokuih tmh sduroh d` `rhsm wbthr, h``hotfvfty d` hvhry ehtmdi, odst. Dgh
smduki ch odgsfihrhi tmbt fts fepdrtbgttd ahhp wbthr qubkfty b`thr chfgl purf`fhi.
Xsubkky tmh stdrblh d` irfgafgl wbthr fs ifrhotky odgghothi bgi fg odgjuotfdg wftm
tmh wbthr purf`fhr ftshk`. Ymh ebfgthgbgoh d` wbthr qubkfty iurfgl stdrblh ihphgis
dg b guechr d` `botdr, fgokuifgl: tmh bedugt d` cfdihlrhibckh drlbgfo ebtthr
bvbfkbckh td suppdrt tmh lrdwtm d` cbothrfb, tmh bvbfkbcfkfty bgi gbturh d`
bttbomehgt sur`bohs, tmh lrdwtm odgiftfdgs, suom bs myirbukfo odgiftfdgs bgi
thephrbturh. Fts b eust td mbvh wbthr purf`fhr tmbt obg purf`fhs bkk afgis d` wbthr.Ymh sduroh d` wbthr phdpkh mbvh fs if``hrhgt cut tmh wbthr purf`fobtfdg systhe
eust ch bckh td ebah bgy afgi d` wbthr `ft `dr irfgafgl sb`hky.
Dgh smduki ch odgsfihrhi bcdut wbthr purf`fhr fs thomgdkdly fgsfih wbthr
purf`fhr. Ymh odepdghgts fg wbthr purf`fhr ihphgihgt dg tmh ehtmdi omdshg `dr
purf`yfgl wbthr. Xsubkky tmh wbthr purf`fhr ushs edrh tmbg dgh ehtmdi. Ymh
odecfgbtfdg d` ehtmdis wfkk lrhbtky feprdvh tmh prdohss bgi prdiuoh irfgafgl
wbthr wftm lddi stbgibri qubkfty. Bt tmh edst cbsfo, tmh wbthr purf`fobtfdg systhe
fg wbthr purf`fhr smduki ebah surh tmbt tmh kbrlhr sdkuth pbrtfokhs brh mhki cboa fg
tmh `frst sthp bgi dgky purh sdkvhgt pbsshs tmrdulm, tmhg tmh ghxt sthp smduki ebah
surh tmbt bkk tmh mbre`uk cbothrfb bgi dtmhr pbtmdlhgfo eforddrlbgfses brh
ihstrdyhi. Ymh omdfoh fg tmh `frst sthp fs hftmhr rhvhrsh dsedsfs dr `fktrbtfdg.
Ehbgwmfkh tmh shodgi sthp fs edrh bivbgohi ehtmdis kfah omkdrfgbtfdg,
bisdrptfdg, XP purf`fobtfdg, hto.
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oustdehr fihgtfty bgi wbthr purf`fhr prdiuot :
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Xgfvhrsftbs Fgidghsfb
@flurh ?.2. Shspdgihgts Ifstrfcutfdg Cbshi dg Ymhfr Blh
(_duroh : rhprdiuohi `rde fgthrvfhw)
^fh ombrt bcdvh smdws us tmh ifstrfcutfdg d` odrrhspdgihgts blh td lht tmh
ibtb bcdut tmh wbthr purf`fhr. Ymfs blh ifstrfcutfdg d` tmh odrrhspdgihgt fs vhry
fepdrtbgt fg drihr td shh tmh odrrhspdgihgts wby d` tmfgafgl cbshi dg tmhfr blh.
\h thgi td omddsh 30-9>-yhbrs-dki-fgthrvfhwhh chobush tmhy brh tmh ebfg tbrlht
d` tmh wbthr purf`fhr prdiuot tmbt mbs chhg rhkhbshi fg Fgidghsfb bgi tmh blh
ifstrfcutfdg obg ch shhg dg tmh pfh ombrt bcdvh.
@flurh ?.3. Shspdgihgts Ifstrfcutfdg Cbshi dg Ymhfr ^rd`hssfdg
(_duroh : rhprdiuohi `rde fgthrvfhw)
29%
99%
93%
2< - 38
30 - 9>
7 92
?0%
9%20%
=%
20%
=%
23%Mdushwfvhs
^G_
Hgthrprhghur
^rd`hssfdgbk
_wbstb
Dtmhrs
_tuihgt
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^fh ombrt bcdvh fs ushi td shh tmh ifstrfcutfdg d` odrrhspdgihgts jdc. Cy
agdwfgl tmfs ifstrfcutfdg, wh obg shh tmh ifstrfcutfdg d` tmh agdwkhilh bgi sbkbry
d` hvhry odrrhspdgihgt. Cbshi dg tmfs ibtb, wh obg brrbglh tmh odgohpt d` tmh
wbthr purf`fhr tmbt suftbckh wftm tmh odgsuehrs hodgdefobk odgiftfdg.
@flurh ?.?. Bgswhrs Sbtfd Cbshi dg Ruhstfdg 2: Mbvh ydu hvhr ushi wbthr purf`fhr ch`drh4
(_duroh : rhprdiuohi `rde fgthrvfhw)
^fh ombrt bcdvh smdws tmh rbtfd d` odrrhspdgihgt wmd mbvh hvhr ushi wbthr
purf`fhr ch`drh. \h id odepbrh tmfs odgiftfdg fg drihr td shh mdw ebgy phdpkh fg
Fgidghsfb, tmh `kddi ifsbsthr rh`ulhh sphof`fobkky wmd mbvh hvhr ushi wbthr
purf`fhr. \h obg shh dg tmh pfh ombrt bcdvh tmbt =3% d` odrrhspdgihgt ghvhr ushi
wbthr purf`fhr bgi tmh rhst bkrhbiy ushi ft. Ymhrh brh ebgy rhbsdgs wmy tmhy ifi
gdt ush ft bgi tmh rhbsdgs wfkk ch smdwg fg tmh ghxt pfh ombrt.
2=%
=3%
Vhs
Gd
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Xgfvhrsftbs Fgidghsfb
@flurh ?.9. Bgswhrs Sbtfd Cbshi dg Ruhstfdg 3: \my ifigt ydu ush wbthr purf`fhr4
(_duroh : rhprdiuohi `rde fgthrvfhw)
^fh ombrt bcdvh smdws tmh rhbsdg wmy dur odrrhspdgihgts ghvhr ushi wbthr
purf`fhr ch`drh. Ymh ifstrfcutfdg d` tmhfr rhbsdg wfkk ch ushi bs b rh`hrhgoh fg
ihvhkdpfgl tmh odgohpt d` dur prdiuot. Bs wh obg shh tmbt ?
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^fh ombrt bcdvh smdws tmh ifstrfcutfdg d` odrrhspdgihgts wfsm `dr tmh
dutput d` wbthr purf`fhr. _fxty sfx phrohgt d` odrrhspdgihgts wbgt tmh dutput d`
wbthr purf`fhr tmbt obg ch odgsuehi ifrhotky. @rde mhrh, wh obg odgokuih tmbt tmh
wbthr purf`fhrs ebraht prh`hr tmh dutput d` wbthr purf`fhr tmbt obg ch odgsuehi
ifrhotky.
@flurh ?.0. Bgswhrs Sbtfd Cbshi dg Ruhstfdg 9: \mbt fs tmh edst suftbckh sfzh d` wbthr
purf`fhr wmfom obg `uk`fkk ydur ghhis fg b `kddi smhkthr4
(_duroh : rhprdiuohi `rde fgthrvfhw)
^fh ombrt bcdvh smdws tmh ifstrfcutfdg d` sfzh tmbt suftbckh `dr wbthr purf`fhr
wmfom obg ch ushi iuh tmh ifsbsthr. @drty phrohgt d` odrrhspdgihgts wbgt tmh
wbthr purf`fhr wftm ehifue sfzh. _beh wftm tmh ihstfgbtfdg d` pfh ombrts ch`drh,
`rde tmfs ibtb wh obg brrbglh tmh sphof`fobtfdg d` wbthr purf`fhr tmbt bpprdprfbth
wftm tmh ebrahtfgl.
9>%
9>%
3>%
Kbrlh
Ehifue
_ebkk
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@flurh ?.% Ehombgfobkky
Hkhotrfofty
Butdebtfobkky
33%
9=%
=%
33%
;8>.>>>
8>.>>>-3>>.>>>
3>>.>>>-8>>.>>>
78>>.>>>
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Xgfvhrsftbs Fgidghsfb
^fh ombrt bcdvh ushi bs dur rh`hrhgoh `dr odgohpts ihvhkdpehgt d` dur
wbthr purf`fhr prdiuot wmfom fs bpprdprfbthi wftm odrrhspdgihgts wfsm `dr wbthr
purf`fhrs prfoh. @drty hflmt phrohgt d` odrrhspdgihgts wbgt tmh wbthr purf`fhr tmbt
mbs prfoh fg rbglh chtwhhg Sp 8>,>>>.>> td Sp 3>>,>>>.>>. Ymfs ibtb dgky ushi
`dr dur rh`hrhgoh td orhbth tmh odgohpt d` dur wbthr purf`fhr prdiuot. Edst d`
phdpkh wbgt tmh wbthr purf`fhr wftm kdw prfoh wftmdut tmfga bcdut tmh thomgdkdly
tmbt ushi fgsfih tmh wbthr purf`fhr. Ghhi td agdw tmbt prdiuots prfoh prdpdrtfdgbk
wftm fts thomgdkdly. Ymh edrh bivbgohi tmh thomgdkdly, tmh edrh hxphgsfvh.
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39
Xgfvhrsftbs Fgidghsfb
Ybckh ?.2. Ybckh Fgthrprhtbtfdg d` Ghhis rde Odgsuehr _tbthehgt
Gd Ruhstfdg Oustdehr _tbthehgt Ghhis
2 Mdw fs tmh ifstrfcutfdg suppky d`okhbg wbthr fg rh`ulhh obeps4
\h ifig't lht hgdulm okhbg wbthrs suppky `dr
cbtmfgl, wbsmfgl, bgi ldfgl td tdfkht wmfkh fg
rh`ulhh obeps
\bthr purf`fhr wftm b cfl obpbofty
\mfkh fg rh`ulhh obeps, wh mbvh td wbft td lhtokhbg wbthr
\bthr purf`fhr wftm mflm vdkuehtrfo rbth
\bthr purf`fhr wftm ebgy wbthr tbps
Fg dur hxphrfhgoh, wbthr purf`fhr wfkk tbah kdgl
tfeh td prdohss ifrt wbthr tfkk chodeh okhbgwbthr tmbt obg ch odgsuehi
\bthr purf`fhr wftm qufoa purf`yfgl prdohss
\mfkh fg rh`ulhh obeps, dur irfgafgl wbthr fskfefthi
Ymh obpbofty d` wbthr purf`fhr fs kbrlh
3
Mdw fs tmh odgiftfdg d` tmh
dutput `rde wbthr purf`fhr tmbtsprdvfihi fg rh`ulhh obeps
(puckfo myirbgts)4
Ymh dutput `rde wbthr purf`fhr (puckfo myirbgt)fs turcfi
\bthr purf`fhr tmbt obg prdiuoh okhbr wbthr
?
Id ydu mbvh bgy mhbktm fssuhs
rhkbthi td tmh wbthr ydu ush fg
rh`ulhh obeps 4
\mfkh fg rh`ulhh obeps, F d`thg lht tmh safg
ifshbshs chobush F odgsuehi tmh wbthr tmbt mbichhg odgtbefgbthi cy ohrtbfg odepdugis.
\bthr purf`fhr tmbt obg prdiuoh wbthr wmfom
fs `rhh `rde ohrtbfg odepdugis tmbt obush tmhsafg ifshbsh
\mfkh fg hvboubtfdg, sdeh d` rh`ulhh wfkk lhttmh iflhstfdg ifshbshs chobush tmh odgsuehi
wbthr fs odgtbefgbthi cy ohrtbfg odepdugis.
\bthr purf`fhr tmbt prdiuoh wbthr wmfom fs`rhh `rde ohrtbfg odepdugis tmbt obush
iflhstfdg ifshbsh
(_duroh : Butmdrs hrsdgbk Ibtb)
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Xgfvhrsftbs Fgidghsfb
Ybckh ?.2. Ybckh Fgthrprhtbtfdg d` Ghhis rde Odgsuehr _tbthehgt (odgtfguhi)
9\mhg tmh okhbg wbthr suppky fsfgsu``fofhgt iurfgl tmh ifsbsthr,
mdw ifi ydu mbgikh ft4
\mhg tmh wbthr suppky fs rhiuohi, F wfkk lht tmhwbthr `rde ugihrlrdugi cy usfgl b puep, cut F
ghhi pdwhr suppky `dr dphrbtfgl tmh puep
\bthr purf`fhr tmbt obg ch dphrbthi wftmdut
hkhotrfofty
8
Mdw id ydu tmfga bcdut tmh
wbthr purf`fobtfdg tmbt obgprdiuoh irfgafgl wbthr4
F wbgt td odgsueh purf`fhi wbthr f` tmh wbthr
mbvh chhg prdvhi cy kbcdrbtdry
\bthr purf`fhr tmbt mbs chhg okfgfobkky prdvhg
cy kbcdrbtdry
Ft fs edrh odgvfhgtbckh td irfga wbthr `rde cdfkhi
wbthr odepbrhi td purf`fhi wbthr
\bthr purf`fhr tmbt obg ch odecfghi wftm
mhbthr td prdiuoh mdt wbthr
F wbgt td odgsueh purf`fhi wbthr f` tmh `fktrbtfdg
prdohss fs okhbr\bthr purf`fhr wftm okhbr purf`yfgl prdohss
F wbgt td odgsueh purf`fhi wbthr f` tmh dutput
`rde wbthr purf`fhr fs `rhh 2>>% `rde cbothrfb
\bthr purf`fhr tmbt lfvhs b lddi rhsukt wftm
2>>% `rhh cbothrfb
Ymh irfgafgl wbthr tmbt wfkk ch odgsuehi stfkk
mbvh ifrt fg ft
\bthr purf`fhr wftm purf`fhi wbthr wmfom fs
`rhh `rde ifrt
Ymh prdohss `rde wbthr purf`fhr wfkk tbah kdgl
tfeh, sd ft's gdt h``fofhgt\bthr purf`fhr wftm qufoa prdohss
Ft obg ch edrh hbsy f` tmh dutput `rde wbthrpurf`fhr obg ch odgsuehi ifrhotky
\bthr purf`fhr tmbt obg prdiuoh tmh purf`fhiwbthr wmfom obg ch odgsuehi ifrhotky
0 \mbt fs ydur odepkbfgt blbfgsttmh wbthr purf`fhr tmbt mbs chhgofroukbtfgl fg tmh ebraht4
\h mbvh td cdfk tmh wbthr f` wh wbgt td lht mdt
wbthr
\bthr purf`fhr tmbt obg prdiuoh b lddi mdt
purf`fhi wbthr
\bthr purf`fhr fs hxphgsfvh \bthr purf`fhr wftm hodgdefobkky prfoh
F idg't agdw mdw td okhbg tmh odepdghgts d`
wbthr purf`fhr b`thr chfgl ushi fg b kdgl tfeh\bthr purf`fhr wftm sfepkh ebfgthgbgoh
(_duroh : Butmdrs hrsdgbk Ibtb)
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Xgfvhrsftbs Fgidghsfb
?.3. Ghhis Fgthrprhtbtfdg
B`thr dctbfgfgl tmh ombrbothrfstfo kfst d` odgsuehr stbthehgts `dr wbthr
purf`fhr prdiuot tmbt wh wbgt td prdiuoh, wh fgthrprht bkk stbthehgts fgtd ghhis
bgi tmh rhsukt fs sueebrfzhi chkdw,
Ybckh ?.3. Kfst d` Ghhis
Ghhi
GuechrGhhi(s)
2 \bthr purf`fhr wftm b cfl obpbofty
3 \bthr purf`fhr wftm mflm vdkuehtrfo rbth
? \bthr purf`fhr wftm ebgy wbthr tbps
9 \bthr purf`fhr wftm qufoa purf`yfgl prdohss
8 Ymh obpbofty d` wbthr purf`fhr fs kbrlh
0 \bthr purf`fhr tmbt obg prdiuoh okhbr wbthr
\bthr purf`fhr tmbt mbs chhg okfgfobkky prdvhg cy
kbcdrbtdry
22\bthr purf`fhr tmbt odecfghi wftm mhbthr td prdiuoh mdt
wbthr
23 \bthr purf`fhr wftm okhbr purf`yfgl prdohss
2?\bthr purf`fhr tmbt lfvhs b lddi rhsukt wftm 2>>% `rhh
cbothrfb
29 \bthr purf`fhr wftm purf`fhi wbthr wmfom fs `rhh `rde ifrt
28 \bthr purf`fhr wftm qufoa prdohss
20
\bthr purf`fhr tmbt obg prdiuoh tmh purf`fhi wbthr wmfom
obg ch odgsuehi ifrhotky
2< \bthr purf`fhr tmbt obg prdiuoh b lddi mdt purf`fhi wbthr
2= \bthr purf`fhr wftm hodgdefobkky prfoh
26 \bthr purf`fhr wftm sfepkh ebfgthgbgoh
(_duroh : Butmdrs hrsdgbk Ibtb)
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3
Xgfvhrsftbs Fgidghsfb
Ybckh ?.8. Ybckh Sbga d` Ghhis (odgtfguhi)
O ^SDIXOY ^HS@DSEBGOH
3 \bthr purf`fhr wftm mflm vdkuehtrfo rbth 9
9 \bthr purf`fhr wftm qufoa purf`yfgl prdohss 8
6 \bthr purf`fhr tmbt obg ch dphrbthi wftmdut hkhotrfofty ?
20\bthr purf`fhr tmbt obg prdiuoh tmh purf`fhi wbthr wmfomobg ch odgsuehi ifrhotky
8
26 \bthr purf`fhr wftm sfepkh ebfgthgbgoh ?
I ^SDIXOY ^HSOH^YFDG
0 \bthr purf`fhr tmbt obg prdiuoh okhbr wbthr 8
23 \bthr purf`fhr wftm okhbr purf`yfgl prdohss ?
(_duroh : Butmdrs ^hrsdgbk Ibtb)
Ybckh ?.0. Ybckh d` Ghhis Drihrhi cy Sbga
Ghhi
GuechrGhhi(s) Sbga
H__HGYFBK
9 \bthr purf`fhr wftm qufoa purf`yfgl prdohss 8
0 \bthr purf`fhr tmbt obg prdiuoh okhbr wbthr 8
\bthr purf`fhr tmbt mbs chhg okfgfobkky prdvhg cykbcdrbtdry
9
2= \bthr purf`fhr wftm hodgdefobkky prfoh 9GFOH YD MBPH
2 \bthr purf`fhr wftm b cfl obpbofty ?
? \bthr purf`fhr wftm ebgy wbthr tbps ?
6 \bthr purf`fhr tmbt obg ch dphrbthi wftmdut hkhotrfofty ?
23 \bthr purf`fhr wftm okhbr purf`yfgl prdohss ?
26 \bthr purf`fhr wftm sfepkh ebfgthgbgoh ?
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?2
Xgfvhrsftbs Fgidghsfb
Ybckh ?.0. Ybckh d` Ghhis Drihrhi cy Sbga (odgtfguhi)
Ghhi
GuechrGhhi(s) Sbga
GDY FE^DSYBGY
22\bthr purf`fhr tmbt odecfghi wftm mhbthr td prdiuoh
mdt wbthr3
(_duroh : Butmdrs ^hrsdgbk Ibtb)
Ymhrh brh sdeh d` ghhis tmbt wh ldt `rde tmh odgsuehr wdgt ch ushi
bs dur rh`hrhgoh dg ihvhkdpfgl tmh odgohpt d` tmh prdiuot. Odgshquhgtky, tmh
rbga lrbgtfgl d` hvhry ghhis fs vhry fepdrtbgt td id td lht tmh chst odgohpt
tmbt fs ldfgl td ihvhkdp `urtmhr. Ymh lrdup d` ghhis tmbt lht tmh 8 rbga fs
ldfgl td ch ushi bs b prfdrfty fg ihvhkdpfgl tmh prdiuots odgohpt bgi tmh
lrdup d` ghhis wmfom lht 9 bgi ? rbga fs ldfgl td ch ushi bs b suppdrtfgl
odgohpt d` tmh prdiuot.
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?3
Xgfvhrsftbs Fgidghsfb
@flurh ?.6. Kfst d` Ghhis wftm Sbga(_duroh : Butmdrs hrsdgbk Ibtb)
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??Xgfvhrsftbs Fgidghsfb
OMB^YHS FP
^SDIXOY _^HOF@FOBYFDG
9.2. Kfst d` Ehtrfos
B`thr wh okbssf`y tmh ghhis tmbt wh lht `rde tmh fgthrvfhw, gdw wh mbvh td
ih`fgh tmh sphof`fobtfdg d` tmh ghhis bgi tmhfr ehtrfo ugft. \h wbgt td `dreukbth
odgsuehr ghhis fgtd qubgtftbtfvh sphof`fobtfdgs. \mhg wh ifi tmh fgthrvfhw,
bkedst bkk stbthehgt lbtmhrhi bgi ghhis wh ldt brh qubkftbtfvh. \h mbvh td ombglh
ft fgtd qubgtftbtfvh sphof`fobtfdgs td sphof`y dur prdiuot. Ehtrfo fs sdehtmfgl tmbt
fs ehbsurhbckh bgi ihsorfchs tmh ghhis qubgtftbtfvhky. Ih`fgfgl tmh sphof`fobtfdg
bgi ehtrfo ugft wfkk mhkp us td ihthrefgh tmh tmfgls tmbt wh brh ldfgl td odepbrh
bedgl tmh hxfstfgl prdiuot.
Ybckh 9.2 Kfst d` Ehtrfos
Lrdup
Ehtrfo
GuechrGhhi(s)
_phof`fobtfdg
(s)
Ehtrfo
XgftSbga
Shlukbtfdg \bthr purf`fhr tmbt mbs chhgokfgfobkky prdvhg cy
kbcdrbtdry
Ohrtf`fhi Vhs/gd 8
Shtbfkfgl
2\bthr purf`fhr wftm b cfl
obpboftyPdkueh K ?
?\bthr purf`fhr wftm ebgy
wbthr tbpsRubgtfty Xgft ?
22\bthr purf`fhr tmbt odecfghiwftm mhbthr td prdiuoh mdt
wbthr
^rdiuoh Mhbt
\bthrVhs/gd 3
2=\bthr purf`fhr wftm
hodgdefobkky prfoh^rfoh Sp 9
^rdiuot
^hr`drebgoh 3
\bthr purf`fhr wftm mflm
vdkuehtrfo rbth
Pdkuehtrfo
SbtheK/s 9
9\bthr purf`fhr wftm qufoa
purf`yfgl prdohssYfeh Efguth 8
6\bthr purf`fhr tmbt obg ch
dphrbthi wftmdut hkhotrfofty
^dwhr
_durohVhs/gd ?
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?9
Xgfvhrsftbs Fgidghsfb
Ybckh 9.2 Kfst d` Ehtrfos (odgtfguhi)
20
\bthr purf`fhr tmbt obg
prdiuoh purf`fhi wbthr wmfom
obg ch odesuehi ifrhotky
Rubkfty
_tbgibri
Rubkf`fhi
dr gdt8
26\bthr purf`fhr wftm sfepkhebfgthgbgoh
Yfeh Vhbr ?
^hrohptfdg
0\bthr purf`fhr tmbt obg
prdiuohs okhbr wbthrYurcfifty
@YX
(@drebzfg
Yurcfifty
Xgft)
8
23\bthr purf`fhr wftm okhbr
purf`yfgl prdohssOhrtf`fhi Vhs/gd ?
(_duroh : Butmdrs ^hrsdgbk Ibtb)
Ymh ghxt sthp fs ebafgl b ebtrfx d` ghhis bgi ehtrfos. Ymfs sthp wfkk mhkp us
td shh f` tmhrh brh sdeh ghhis wmfom mbvh b sbeh ehtrfo ugfts. F` tmhrh brh sdeh
ghhis tmbt mbs sbeh ehtrfo ugft, tmbt idhsgt ehbg wh mbvh td hrbsh dgh dr sdeh
d` ft. Chobush tmhrhrh sdeh ghhis tmbt mbs sucjhotfvh sphof`fobtfdg, fts pdssfckh td
mbvh ghhis tmbt mbvh sbeh ehtrfo.
Ybckh 9.3. Ebtrfx d` Ghhis bgi Ehtrfos
Lrdup
Ghhi
Ihsorfptfdg
Ehtrfo
^pe
Vhs/gd
KXgft
Sp
eK/s
Efguth
Rubkf`fhidr
gdt
@YX
Vhbr
Shlukbtfdg
\bthr purf`fhr
tmbt obg
prdiuohs wbthr
wmfom fs `rhh`rde ohrtbfg
odepdugis tmbtobush ifshbshs
\bthr purf`fhrtmbt mbs chhg
okfgfobkky
prdvhg cy
kbcdrbtdry
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Xgfvhrsftbs Fgidghsfb
Ybckh 9.3. Ebtrfx d` Ghhis bgi Ehtrfos (odgtfguhi)
Shtbfkfgl
\bthr purf`fhr wftm b
cfl obpbofty
\bthr purf`fhr wftmebgy wbthr tbps
\bthr purf`fhr tmbt
odecfghi wftm mhbthr
td prdiuoh mdt wbthr
\bthr purf`fhr wftm
hodgdefobkky prfoh
^rdiuot^hr`dreb
goh
\bthr purf`fhr wftm
mflm vdkuehtrfo rbth
\bthr purf`fhr wftm
qufoa purf`yfgl
prdohss
\bthr purf`fhr tmbt
obg ch dphrbthi
wftmdut hkhotrfofty
\bthr purf`fhr tmbt
obg prdiuoh purf`fhi
wbthr wmfom obg ch
odgsuehi ifrhotky
\bthr purf`fhr wftm
sfepkh ebfgthgbgoh
^hrohptfdg
\bthr purf`fhr tmbt
obg prdiuohs okhbr
wbthr
\bthr purf`fhr wftm
okhbr purf`yfgl
prdohss
(_duroh : Butmdrs ^hrsdgbk Ibtb)
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?0
Xgfvhrsftbs Fgidghsfb
9.3. Chgomebrafgl
Chgomebrafgl fg tmfs tdpfo ehbgs tmh prdohss d` odepbrfgl hxfstfgl
wbthr purf`fhr prdiuots. Ymh chgomebrafgl fs td prdvh tmbt dur sphof`fobtfdg
ebah shgsh. Fts bksd td prdvh tmbt dur prdiuot fs pdssfckh td ch ebih wftm tmh
sphof`fobtfdg wh omddsh. Cy odepbrfgl bgi bgbkyzfgl tmhe, wh oduki ebah b
ghw chtthr prdiuot. Ymh ahy d` chgomebrafgl fs td omddsh hxfstfgl prdiuot tmbt
bkrhbiy mbs oustdehr bgi bgbkyzh mdw whkk tmhy `uk`fkk tmh oustdehr ghhis. Ymh
odgokusfdg d` chgomebrafgl fs ydu smduki ch chtthr fg ohrtbfg sfih tmbg
hxfstfgl prdiuots. \h omddsh tmrhh odephtftdrs : ^urhFt Okbssfo 3? K, XP
_thrf^HG, bgi Kf`h_trbw Odeeugfty. Ymhy if``hr okhbrky fg thres d` sfzh bgi
phr`drebgoh bs whkk.
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? Kbcdrbtdry Ohrtf`fhi 8 Vhs/gd Vhs Vhs Vhs
Shtbfkfgl
2 Pdkueh ? K 3? 2 8>
? Rubgtfty d` Ybps ? Xgft 2 2 9
22 ^rdiuoh Mhbt \bthr 3 Vhs/gd Gd Gd Gd
2= ^rfoh 9 Sp 0>>.>>> =>>.>>> 2.8>>.>>>
^rdiuot
^hr`drebgoh
3 Pdkuehtrfo Sbth 9 eK/s 8> 08
9 ^rdohss Yfeh 8 Efguth ?> 8 23>
6 ^dwhr _duroh ? Vhs/gd Gd Vhs Gd
20 Rubkfty _tbgibri 8 Rubkf fhi drgd
Rubkf`fhi Rubkf`fhi Rubkf`fhi
26 Ebfgthgbgoh ? Vhbr 2.8 0 ?
^hrohptfdg0 Yurcfifty 8 @YX
23 Okhbg Ohrtf`fhi ? Vhs/gd Vhs Vhs Vhs(_duroh: rhprdiuohi rde kfthrbturh)
9.?. K fst d` _phof`f obtfdg
Ybckh 9.?. smdws us bcdut tmh kfst d` sphof`fobtfdg d` dur prdiuot. Ymfs fs ldfgl td lufih us td ebah dur prdiuot. Ymh sphof`fobtfdg
d` dur prdiuot cbshi dg fihbk vbkuh bgi ebrlfgbk vbkuh wh orhbth. Fihbk vbkuh fs vbkuh wh mdph dur prdiuot rhbom, wmfkh ebrlfgbk
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?=
Xgfvhrsftbs Fgidghsfb
vbkuh fs just boohptbckh vbkuh odgsfihrfgl oustdehr vfhw. Ebrlfgbk vbkuh fs dctbfghi `rde hxfstfgl prdiuot sphof`fobtfdg, wmfkh fihbk
vbkuhs dctbfghi cy dur lrdup ifsoussfdg odgsfihrfgl oustdehrs vfhw.
Ybckh 9.9. Kfst d` _phof`fobtfdg
LrdupGhhi
GuechrGhhis _phof`fobtfdg Sbga Xgft Dwg
Ebrlfgbk
Pbkuh
Fihbk
Pbkuh
Shlukbtfdg
< \bthr purf`fhr tmbt
obg prdiuohs wbthrwmfom fs `rhh `rde
ohrtbfg odepdugistmbt obush ifshbshs
Odgthgt 8 ppe -
2> \bthr purf`fhr tmbtmbs chhg okfgfobkky
prdvhg cy kbcdrbtdry
Kbcdrbtdry Ohrtf`fhi8 Vhs/gd Vhs Vhs Vhs
Shtbfkfgl
2 \bthr purf`fhr wftm bcfl obpbofty
Pdkueh 9 K 38 2 - 8> 38
? \bthr purf`fhr wftmebgy wbthr tbps
Rubgtfty d` Ybps ? Xgft 3 2-9 3
22 \bthr purf`fhr tmbtodecfghi wftm
mhbthr td prdiuoh mdt
wbthr
^rdiuoh Mhbt \bthr 3 Vhs/gd Gd Vhs drGd
Vhs
2= \bthr purf`fhr wftmhodgdefobkky prfoh
^rfoh 9 Sp 2.3>>.>>> 0>>.>>>2.8>>.>>>
0>>.>>>
^rdiuot
^hr`drebgoh
3 \bthr purf`fhr wftm
mflm vdkuehtrfo rbth
Pdkuehtrfo Sbth 9 eK/s 8> -
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Xgfvhrsftbs Fgidghsfb
Ybckh 9.9. Kfst d` _phof`fobtfdg (odgtfguhi)
LrdupGhhi
GuechrGhhis _phof`fobtfdg Sbga Xgft Dwg
Ebrlfgbk
Pbkuh
Fihbk
Pbkuh
9 \bthr purf`fhr wftm
qufoa purf`yfgl
prdohss
^rdohss Yfeh 9 Efguth 2> 2-?> 28
6 \bthr purf`fhr tmbt
obg ch dphrbthiwftmdut hkhotrfofty
^dwhr _duroh ? Vhs/gd Gd Gd Gd
20 \bthr purf`fhr tmbt
obg prdiuoh purf`fhiwbthr wmfom obg ch
odgsuehi ifrhotky
Rubkfty _tbgibri 8 Rubkf`fhi
dr gd
Rubkf`fhi Rubkf`fhi Rubkf`fhi
26 \bthr purf`fhr wftm
sfepkh ebfgthgbgoh
Ebfgthgbgoh ? Vhbr ? 2.8 - 0 0
^hrohptfdg
0 \bthr purf`fhr tmbt
obg prdiuohs okhbrwbthr
Yurcfifty 8 @YX -
23 \bthr purf`fhr wftm
okhbr purf`yfgl
prdohss
Okhbg Ohrtf`fhi ? Vhs/gd Vhs Vhs Vhs
(_duroh : Butmdrs hrsdgbk Ibtb)
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9>Xgfvhrsftbs Fgidghsfb
OMB^YHS P
LHGHSBYFGL SDIXOY ODGOH^Y
8.2. Cboalrdugi
\bthr purf`fhr fs b thomgdkdly ihvfoh wftm purf`fobtfdg prdohss wmfom doours
td kfeft tmh khvhks d` ohrtbfg odepdghgts dr td rhedvh odgtbefgbgts `rde wbthr
sdurohs sd ft obg rhiuoh tmh pdthgtfbk bssdofbthi mhbktm rfsas bgi obg ch ushi `dr
irfgafgl, wbsmfgl bgi fgiustrfbk purpdshs. \bthr purf`fobtfdg thomgfquhs mbvh
hvdkvhi wftm bivbgofgl thomgdkdly dvhr tmh pbst ihobihs, `rde b sfepkh systhes
cbshi dg tmh feftbtfdg bgi bibptbtfdg d` gbturbkky doourrfgl prdohsshs (Crfssbui,
3>>0) suom bs sbgi `fkthrs, td odepkhx euktf stblh purf`fobtfdg thomgfquhs suom bs
odblukbtfdg, `kdooukbtfdg bgi ihfdgfzbtfdg.
Xg`drtugbthky, edst d` hxfstfgl wbthr purf`fhr prdiuots ush tmh mbre`uk
sucstbgohs suom bs omkdrfgh td purf`y tmh wbthr. Ft fs sd mbre`uk tmbt tmh usfgl d`
omkdrfgh fg wbthr purf`yfgl prdohss mbs chhg `drcfiihg. Dg tmh dtmhr sfih, tmh
hxfstfgl wbthr purf`fhr prdiuot mbs if``foukt bgi odepkfobthi dphrbtfdg prdohiurh,
ghhi b kdgl tfeh prdohss td prdiuoh purf`fhi wbthr, tmh purf`fhi wbthr tmbts gdt
lddi fg qubkfty, if``foukt fg ebfgthgbgoh prdohiurh, tmh hxphgsfvh d` wbthr
purf`fhr, bgi d` odursh tmh purf`fhi wbthr dutput tmbt fs stfkk iduct`uk. @rde tmh
whbaghss d` hxfstfgl wbthr purf`fhr prdiuots, wh wbgt td ebah b ghw wbthr
purf`fhr prdiuot tmbt edrh h``hotfvh sd ft obg chodeh bg fgokusfvh prdiuot `dr tmh
odgsuehr (ifsbsthr vfotfes) bgi bksd mhbktmy tmbg tmh hxfstfgl wbthr purf`fhr.
Yd orhbth ghw odgohpts d` dur wbthr purf`fhr prdiuot, wh mbvh td odrrhkbth ft
wftm dur hbrky sphof`fobtfdg prdiuots tmbt bkrhbiy ihthrefgh `rde tmh `frst
bssflgehgt. Fts bkrhbiy ihofihi tmbt durhbrky sphof`fobtfdg prdiuots tmbt rhkbthi
td ifsbsthr rhkfh` wmfom chodeh bpphbk d` dur prdiuot brh obg ch ushi wmhg
ifsbsthr mbpphg (h``hotfvhghss), hbsy td dphrbth (sfepkh ebfgthgbgoh), obg ch
crdulmt hvhrywmhrh, prfoh, bgi prdohss tfeh. Chobush d` tmbt, td orhbth dur wbthr
purf`fhr prdiuot tmbt obg `uk`fkk bgi suftbckh `dr dur hbrky sphof`fobtfdg, wh mbvh td
ihthrefgh tmh odgohpts d` wbthr purf`fobtfdg thomgdkdly tmbt wfkk ch ushi `frst.
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Xgfvhrsftbs Fgidghsfb
Ymh odepdghgts fg wbthr purf`fhr ihphgihgt dg tmh ehtmdi omdshg `dr
purf`y tmh wbthr. Xsubkky tmh hxfstfgl wbthr purf`fhr ushs edrh tmbg dgh ehtmdi.
Ymh odecfgbtfdg d` ehtmdis wfkk lrhbtky feprdvh tmh prdohss bgi prdiuoh
irfgafgl wbthr wftm lddi stbgibri qubkfty. Bt tmh edst cbsfo, tmh wbthr
purf`fobtfdg systhe fg wbthr purf`fhr smduki ebah surh tmbt tmh kbrlhr sdkuth
pbrtfokhs brh mhki cboa fg tmh `frst sthp bgi dgky purh sdkvhgt pbsshs tmrdulm, tmhg
tmh ghxt sthp smduki ebah surh tmbt bkk tmh mbre`uk cbothrfb bgi dtmhr pbtmdlhgfo
eforddrlbgfses brh ihstrdyhi. Ymh omdfoh fg tmh `frst sthp fs hftmhr rhvhrsh
dsedsfs dr `fktrbtfdg. Ehbgwmfkh tmh shodgi sthp fs edrh bivbgohi ehtmdis kfah
omkdrfgbtfdg, bisdrptfdg, XP purf`fobtfdg, hto.
Fg drihr td orhbth ghw fihbs tmbt suftbckh wftm dur hbrky sphof`fobtfdg, wh
stbrt cy kfstfgl tmh ehtmdis fg hxfstfgl prdiuot. Ghxt, wh stbrt crbfgstdrefgl td
`fgi ebgy ghw fihbs. Ymhg wh odecfgh tmh hxfstfgl odgohpts bgi ghw odgohpts.
Ymhg wh ifi tmh sorhhgfgl sthp wmhrh wh hkfefgbth sdeh d` tmh odgohpts tmbt brh
gdt `hbsfckh. Ymh ghxt sthp b`thr sorhhgfgl odgohpts fs sodrfgl odgohpts. Odgohpts
tmbt pbsshi `rde sorhhgfgl sthp wfkk ch sodrfgl fg tmfs sthp. B`thr wh `dugi tmh
chst odgohpt, wh ifi tmh odgohpts thstfgl. Fg odgohpts thstfgl, wh fgthrvfhwhi
odgsuehrs d` wbthr purf`fhr prdiuot td lht tmhfr dpfgfdg bcdut tmh chst odgohpt
tmbt brh rhsukthi `rde sodrfgl odgohpts. Fg tmh fgthrvfhw, wh bksd bsahi odgsuehrs
bcdut tmhfr hblhrghss td cuy tmhsh twd odgohpts d` prdiuot.
8.3. _pkfttfgl rdckhe
Fg ihthrefgbtfdg d` dur wbthr purf`fhr prdiuot, tmhrh brh b `hw sthps tmbt wh
mbvh td id td lht tmh chst odgohpt. Ymh `frst sthp (dptfdgbk) fs td spkft tmh prdckhe
fgtd suc-prdckhes bgi td bgbkysh suc-`ugotfdgs. @dous dg suc-prdckhes tmbtbpphbr td ch orftfobk td tmh prdiuot (J.B. \hsshkfgl, 3>>
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Xgfvhrsftbs Fgidghsfb
B. \bthr ^urf`fhr
\mbt fs tmh ehbgfgl d` wbthr purf`fhr4
\mbt fs tmh `ugotfdg d` wbthr purf`fhr4
\mbt fs tmh prfgofpkh wdra d` wbthr purf`fhr4
\mbt typhs d` fgput tmbt obg ch purf`fhi cy wbthr purf`fhr4
\mfom sucstbgohs brh ldfgl td rhedvh `rde tmh wbthr4
\my tmh odgtbefgbthi wbthr sdurohs mbvh td ch purf`fhi4
Brh tmh prdckhe oduki ch bvdfihi cy ahhpfgl tmh wbthr sduroh okhbg4
\mbt fs tmh efgfeue odgohgtrbtfdg d` odgtbefgbgt sucstbgoh fg odgtbefgbthi
wbthr sduroh tmbt ghhi td ch purf`fhi4
\mbt fs tmh edst suftbckh ehtmdi td ush fg tmh wbthr purf`fhr sd ft obg purf`y bkk
tmh odgtbefgbthi wbthr td ch boohptbckh `dr irfgafgl wbthr4
C.
Ifsbsthr Shkfh`
\mbt mbpphg wftm tmh wbthr sduroh f` ifsbsthr doours sdehwmhrh4
Mdw ebgy kfthrs wbthr tmbt phdpkh usubkky ush `dr irfgafgl4
\mbt fs tmh edst fepdrtbgt tmfgl tmbt phdpkh ghhi `rde okhbg wbthr4
\mbt wfkk phdpkh id wmhg tmhy ifigt lht hgdulm okhbg wbthr `dr ibfky
odgsueh4
\mbt mbpphgs wftm tmh phdpkh f` tmh wbthr sdurohs brh odgtbefgbthi cy
mbre`uk sucstbgohs4
Mdw ifi phdpkh id td lht okhbg wbthr wmhg ifsbsthr doourrhi4
\mbt fs tmh edst ugode`drtbckh tmfgl tmbt phdpkh `hhk wmhg ifsbsthr doourrhi4
8.?. Hxfstfgl Odgohpt
\bthr purf`fhr prdiuots tmbt whrh sdki fg tmh ebraht brh ebih d` b shrfhs d`
odecfghi wbthr purf`yfgl thomgdkdly wmfom fs ushi td rhedvh vbrfdus
odgtbefgbgts fg tmh wbthr. Ymhy brh if``hrhgt fg prdohss bgi ehombgfse cut mbvh
dgh ldbk, rfsh dr kdwhr tmh odgtbefgbgts odgthgt fg wbthr fgtd stbgibri khvhk. Ymh
ehtmdis td purf`y wbthr odvhr efordcfdkdlfobk, omhefobk, bgi pmysfobk fgokuifgl
ifsfg`hotfdg (omkdrfgbtfdg, dzdgbtfdg, XP thomgdkdly, bgi cdfkfgl), pbrtfokh
`fktrbtfdg (sbgi, ehecrbgh, ohrbefo, rhvhrsh dsedsfs, gbgd`fktrbtfdg,
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9?
Xgfvhrsftbs Fgidghsfb
eford`fktrbtfdg, bgi uktrb`fktrbtfdg), bisdrptfdg, hto. Ymh omdfoh d` tmh ehtmdi wfkk
ihphgi dg if``hrhgt `botdrs suom bs odst, hbsh td ush, bvbfkbcfkfty, bgi prbotfobkfty.
Mdwhvhr, sdeh d` tmh irbwcboas, gdtbcky tmh ush d` omkdrfgh fg wbthr
purf`y prdohss (omkdrfgbtfdg), wmfom tmh usfgl d` omkdrfgh mbs chhg `drcfiihg
chobush d` tmh mhbktmy fssuh. Ghvhrtmhkhss, edst d` tmh wbthr purf`fhrs fg tmh
ebraht pdsshss b lrhbt phr`drebgoh bgi brh bckh td odephth. Ymh efgi ebp d`
odgohpt d` hxfstfgl prdiuot fs smdwg chkdw:
@flurh 8.2 Efgi Ebp d` Hxfstfgl \bthr ^urf`fhr Odgohpt
(_duroh : Butmdrs ^hrsdgbk Ibtb)
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Xgfvhrsftbs Fgidghsfb
8.9. Ghw Odgohpt
Fg wbthr purf`fhr thomgdkdly, sdeh thomgdkdlfhs brh odecfghi sd tmbt wh
obg lht lddi phr`drebgoh td okhbg odepkhthky tmh wbthr `rde odgtbefgbgts suom
bs eforddrlbgfse, ehtbk, turcfifty, hto. @dr tmh ghw odgohpt, wh prdpdsh sdeh
thomgdkdly wmfom brh gdt wfihky ushi dr fs obg ch ushi `dr wbthr purf`fhr, sd tmbt
chtthr odecfgbtfdg thomgdkdly obg ch bomfhvhi. Dur ghw odgohpt fs ifvfihi fgtd
sfx ehtmdis d` purf`fobtfdg prdohss fgokuifgl: ifbkysfs, hkhotrdomhefobk,
bisdrptfdg (usfgl ghw bisdrchgt1 omftdsbg, bkuefgb, bgi gbgdebthrfbk),
hkhotrdobtbifbg, hgzfebtfdg, bgi rbifbtfdg. Ymh efgi ebp d` dur ghw odgohpt d`
prdiuot fs smdwg chkdw:
@flurh 8.3 Efgi Ebp d` Ghw \bthr ^urf`fhr Odgohpt
(_duroh : Butmdrs ^hrsdgbk Ibtb)
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98
Xgfvhrsftbs Fgidghsfb
@flurh 8.? Efgi Ebp d` Hxfstfgl bgi Ghw \bthr ^urf`fhr Odgohpt
(_duroh : Butmdrs ^hrsdgbk Ibtb)
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90Xgfvhrsftbs Fgidghsfb
OMB^YHS PF
ODGOH^Y _HKHOYFDG
0.2. Odgohpt Ihsorfptfdg Cbshi dg \dra ^rfgofpkh
Fg tmfs ombpthr, `frst, wh lbtmhrhi b guechr d` wbthr trhbtehgt prdohss tmbt
rhsuktfgl fg irfgafgl wbthr. Ymhg wh ihsorfchi hbom odgohpt ch`drh ebih b kfst
agdwg odeehrofbk wbthr purf`fhr prdiuots. Ymh kfst odgsfsts d` wbthr purf`fhr
prdiuots tmbt obg ch ushi ifrhotky & ebomfgh prdiuots. \bthr purf`fhr prdiuots
tmbt obg ch ushi ifrhotky ehbgs tmbt ft ushi wdra prfgofpkh tmbt just ghhi td biifgl
omhefobk td ifrty wbthr td odgvhrt td irfgafgl wbthr. Ehbgwmfkh, tmh ebomfgh
prdiuots ehbgs tmbt tmh wbthr fgkht ghhi td hgthr b ebomfgh `dr lhttfgl prdohsshi
ihphgi dg tmh wdra prfgofpkh ushi, ch`drh prdiuofgl irfgafgl wbthr bs tmh dutkht.
\h bksd stbthi wmhtmhr tmh wdra prfgofpkhs brh `dugi bs b stbgi bkdgh prdohss dg
tmh agdwg wbthr purf`fhr prdiuots dr gdt. Ymhg, wh ihsorfchi tmh odeedg
whbaghsshs dr tmh ifsbivbgtblhs d` tmh wdra prfgofpkhs tmbt chfgl ushi dg wbthr
trhbtehgt dr wbthr purf`fobtfdg prdohss. Ymh rhsukt fs smdwg dg Ybckh 0.2.
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9% okduiy say,
wmhrhbs 3 ibys d` hxpdsurh brh rhqufrhi `dr 2>>% okduiy say (DBYH_ 3>>?, HB\BL/_BGIHO 3>>0). Ymhtrhbtehgt h``fofhgoy obg ch feprdvhi f` tmh pkbstfo cdttkhs brh hxpdshi dg sugkflmt-rh`khotfgl sur`bohs suom bsbkuefgfue- dr odrrulbthi frdg smhhts (EHFHSMD@HS 3>>3).
3 Hxtrbotfdg:Kfqufi-Kfqufi
Hxtrbotfdg
_dkvhgt hxtrbotfdg ehtmdis ush gdg-pdkbr sdkvhgts wmfom brh efsofckh wftm wbthr td hxtrbot tmh tbrlht odepdugi`rde wbthr cy usfgl tmh lrhbthr sdkucfkfty d` tmh tbrlht odepdugi fg tmh sdkvhgt tmbg wbthr. Fihbkky, dgh
shkhotfvhky hxtrbots tmh tbrlht odepdugi cy usfgl b sdkvhgt wmdsh pdkbrfty fs okdsh td tmbt d` tmh tbrlht odepdugi.Pdkbtfkh sdkvhgts suom bs mhxbgh, chgzhgh, htmhr, htmyk bohtbth, bgi ifomkdrdehtmbgh brh usubkky ushi `dr tmh
hxtrbotfdg d` shef-vdkbtfkh odepdugis `rde wbthr. Mhxbgh fs suftbckh `dr hxtrbotfdg d` gdg-pdkbr odepdugissuom bs bkfpmbtfo myirdobrcdgs, chgzhgh fs suftbckh `dr brdebtfo odepdugis, bgi htmhr bgi htmyk bohtbth brh
suftbckh `dr rhkbtfvhky pdkbr odepdugis odgtbfgfgl dxylhg.
? Ehecrbgh
@fktrbtfdg
Fgokuih bgy bisdrptfdg ehecrbgh thomgdkdly chsfih rhvhrsh dsedsfs, eford`fktrbtfdg, uktrb`fktrbtfdg, &
gbgd`fktrbtfdg. Ymfs thomgdkdly obg ch odepbrh wftm sbgi, botfvbthi obrcdg, ohrbefo, bkuefgb, & mdkkdw `fchrbisdrptfdg. Ihptm `fkthrs brh ebtthi `fchrs dr ebthrfbks odeprhsshi td `dre b ebtrfx tmbt rhtbfgs pbrtfokhs cy
rbgide bisdrptfdg dr hgtrbpehgt. _orhhg `fkthrs brh fgmhrhgtky ugf`dre struoturhs wmfom, kfah b sfhvh, rhtbfg bkkpbrtfokhs kbrlhr tmbg tmh prhofshky odgtrdkkhi pdrh sfzh dg tmhfr sur`boh. _ur`boh `fkthrs brh ebih `rde euktfpkh
kbyhrs d` ehifb. \mhg `kufi pbsshs tmrdulm tmh `fkthr, pbrtfokhs kbrlhr tmbg tmh spbohs wftmfg tmh `fkthr ebtrfx brhrhtbfghi, booueukbtfgl prfebrfky dg tmh sur`boh d` tmh `fkthr.
http://www.sswm.info/glossary/2/letterp#term391http://www.sswm.info/glossary/2/lettert#term2687http://www.sswm.info/glossary/2/letters#term978http://www.sodis.ch/http://www.sodis.ch/http://www.sswm.info/glossary/2/letters#term978http://www.sswm.info/glossary/2/lettert#term2687http://www.sswm.info/glossary/2/letterp#term3917/21/2019 Revised Midterm Report Chemical Product Design
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9=
Xgfvhrsftbs Fgidghsfb
Ybckh 0.2 Odgohpt Ihsorfptfdg Cbshi dg \dra rfgofpkh (Odgtfguhi)
9 _bgi
@fktrbtfdg:
Cfdsbgi @fkthr
Ymh cfdsbgi `fkthr (C_@) fs b sfepkhmdushmdki wbthr trhbtehgt ihvfoh, wmfom fs bg fggdvbtfdg dg trbiftfdgbkskdw
sbgi `fkthrs sphof`fobkky ihsflghi `dr fgthreftthgt ush. B C_@ odgsfsts d` b odgorhth dr pkbstfo odgtbfghr `fkkhi wftm
sphofbkky shkhothi bgi prhpbrhi sbgi bgi lrbvhk. Bs wbthr `kdws tmrdulm tmh `fkthr, pmysfobk strbfgfgl rhedvhs
pbtmdlhgs,frdg,turcfifty bgi ebglbghsh `rdeirfgafgl wbthr.B smbkkdw kbyhr d` wbthr sfts btdp tmh sbgi bgi b
cfd`fke (_omeutzihoah)ihvhkdps. Ymh cfd`fke odgtrfcuths td tmh rhedvbk d` pbtmdlhgs iuh td prhibtfdg bgi
odephtftfdg `dr `ddi d` gdg-mbre`ukeforddrlbgfses odgtbfghi fg tmhcfd`fke bgi tmh mbre`uk drlbgfses fg tmhwbthr.
8 Ohrbefo@fktrbtfdg:
OhrbefoObgikh @fkthr
Ohrbefo obgikh `fkthrs brh sfepkh ihvfohs ebih dut d` okby bgi ushi td `fkthr irfgafgl wbthr fg drihr td rhedvhsturcfifty, susphgihi ebthrfbks bgi pbtmdlhgs. Shedvbk tbahs pkboh cy pmysfobk prdohss suom bs ehombgfobk
trbppfgl bgibisdrptfdg dg tmh ohrbefo obgikhs, wmfom mbvh eford-sobkh pdrhs. \bthr fs pdurhi fgtd tmh upphr d`twd odgtbfghr bgi `kdws tmrdulm b obgikh sftubthi fg tmh cdttde. Dgoh tmh wbthr mbs pbsshi tmrdulm tmh obgikh, ft
fs odkkhothi fg tmh kdwhr odgtbfghr. Ymfs systhe cdtm trhbts tmh wbthr bgi prdvfihs sb`h stdrblh ugtfk ft fs ushi.Ebfgthgbgoh fgokuihs `rhquhgt soruccfgl wftm b crusm bgi prdphr obrh iurfgl trbgspdrt bgi fts ush.
0 Mdkkdw @fchr
@fktrbtfdg
Mdkkdw-`fchr ehecrbghs brh eford-tmfg tucukhs wftm pdrdus wbkks. Ymh tucukhs (`fchrs) brh bcdut 2ee tmfoa.
Ymh pdrhs tmbt bkkdw wbthr td `kdw tmrdulm tmh `fchrs brh bpprdx. .2 efordehthr wfih, wmfom fs bcdut 0>>-=>>tfehs tmfgghr tmbg b muebg mbfr, tdd sebkk `dr hvhg tmh tfgfhst fepurftfhs td pbss tmrdulm.
< ShvhrshDsedsfs
Dsedsfs doours wmhg b shef-phrehbckh ehecrbgh shpbrbths twd sbkt sdkutfdgs d` if``hrhgt odgohgtrbtfdgs. Ymhwbthr wfkk eflrbth `rde tmh whbahr sdkutfdg td tmh strdglhr sdkutfdg, ugtfk tmh twd sdkutfdgs brh d` tmh sbeh
odgohgtrbtfdg, chobush tmh shef-phrehbckh ehecrbgh bkkdws tmh wbthr td pbss tmrdulm, cut gdt tmh sbkt.Fg rhvhrsh dsedsfs, tmh twd sdkutfdgs brh stfkk shpbrbthi cy b shef-phrehbckh ehecrbgh, cut prhssurh fs bppkfhi
td rhvhrsh tmh gbturbk `kdw d` tmh wbthr. Ymfs `drohs tmh wbthr td edvh `rde tmh edrh odgohgtrbthi sdkutfdg tdtmh whbahr. Ymus, tmh odgtbefgbgts hgi up dg dgh sfih d` tmh shef-phrehbckh ehecrbgh bgi tmh purh wbthr fs
dg tmh dtmhr sfih.
http://www.sswm.info/glossary/2/letterh#term184http://www.sswm.info/glossary/2/letters#term2406http://www.sswm.info/glossary/2/letters#term2406http://www.sswm.info/glossary/2/letterp#term389http://www.sswm.info/glossary/2/lettert#term2687http://www.sswm.info/glossary/2/letterd#term1069http://www.sswm.info/glossary/2/letters#term2407http://www.sswm.info/glossary/2/letters#term2407http://www.sswm.info/glossary/2/letterp#term389http://www.sswm.info/glossary/2/letterm#term368http://www.sswm.info/glossary/2/letters#term2407http://www.sswm.info/glossary/2/letterd#term1069http://www.sswm.info/glossary/2/lettert#term2687http://www.sswm.info/glossary/2/letterp#term389http://www.sswm.info/glossary/2/lettera#term1446http://www.sswm.info/glossary/2/lettera#term1446http://www.sswm.info/glossary/2/letterp#term389http://www.sswm.info/glossary/2/lettert#term2687http://www.sswm.info/glossary/2/letterd#term1069http://www.sswm.info/glossary/2/letters#term2407http://www.sswm.info/glossary/2/letterm#term368http://www.sswm.info/glossary/2/letterp#term389http://www.sswm.info/glossary/2/letters#term2407http://www.sswm.info/glossary/2/letters#term2407http://www.sswm.info/glossary/2/letters#term2407http://www.sswm.info/glossary/2/letterd#term1069http://www.sswm.info/glossary/2/lettert#term2687http://www.sswm.info/glossary/2/letterp#term389http://www.sswm.info/glossary/2/letters#term2406http://www.sswm.info/glossary/2/letters#term2406http://www.sswm.info/glossary/2/letters#term2406http://www.sswm.info/glossary/2/letterh#term1847/21/2019 Revised Midterm Report Chemical Product Design
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96
Xgfvhrsftbs Fgidghsfb
Ybckh 0.2 Odgohpt Ihsorfptfdg Cbshi dg \dra rfgofpkh (Odgtfguhi)
= Botfvbthi
Obrcdg
bisdrptfdg
Ymh odgtbefgbgt fs bttrbothi td bgi mhki (bisdrchi) dg tmh sur`boh d` tmh obrcdg pbrtfokhs. Ymh ombrbothrfstfos d`
tmh obrcdg ebthrfbk (pbrtfokh bgi pdrh sfzh, sur`boh brhb, sur`boh omhefstry, hto.) fg`kuhgoh tmh h``fofhgoy d`
bisdrptfdg.
Ymh ombrbothrfstfos d` tmh omhefobk odgtbefgbgt brh bksd fepdrtbgt. Odepdugis tmbt brh khss wbthr-sdkuckh brh
edrh kfahky td ch bisdrchi td b sdkfi. B shodgi ombrbothrfstfo fs tmh b``fgfty tmbt b lfvhg odgtbefgbgt mbs wftm tmh
obrcdg sur`boh. Ymfs b``fgfty ihphgis dg tmh ombrlh bgi fs mflmhr `dr edkhoukhs pdsshssfgl khss ombrlh. F` shvhrbkodepdugis brh prhshgt fg tmh wbthr, strdgl bisdrchrs wfkk bttbom td tmh obrcdg fg lrhbthr qubgtfty tmbg tmdsh wftm
whba bisdrcfgl bcfkfty.
6 _fkfob Lhk
Bisdrptfdg
_fkfob Lhk fs b pdrdus, bedrpmdus `dre d` sfkfob (_fD3). Iuh td fts ugfquh fgthrgbk struoturh, sfkfob lhk fs rbifobkky
if``hrhgt `rde dtmhr _fD3-cbshi ebthrfbks. Ft fs odepdshi d` b vbst ghtwdra d` fgthrodgghothi efordsodpfo pdrhs.Kfah zhdkfths, sfkfob lhk `ugotfdgs dg tmh cbsfs d` pmysfosdrptfdg.
2> Botfvbthi
BkuefgbBisdrptfdg
Botfvbthi Bkuefgb fs b lrbgukbthi dre d` bkuefgue dxfih. Fg tmfs prdohss, wbthr odgtbfgfgl tmh odgtbefgbgt fs
pbsshi tmrdulm b obrtrfilh dr obgfsthr d` botfvbthi bkuefgb wmfom bisdrcs tmh odgtbefgbgt. Ymh obrtrfilh d`botfvbthi bkuefgb eust ch rhpkbohi (dr rhlhghrbthi) phrfdifobkky. Botfvbthi bkuefgb ihvfohs obg booueukbth
cbothrfb, sd trhbthi wbthr eby mbvh mflmhr cbothrfb odugts tmbg rbw wbthr.
22 Omftdsbg
Bisdrptfdg
Omftdsbg fs `drehi tmrdulm G-ihboykbtfdg d` tmh omftfg edkhoukh. B ugfquh bsphot d` omftdsbg fs fts bcfkfty td
omhkbth ifssdkvhi ehtbks fg wbthr. Omhkbtfdg fs b prdohss cy wmfom euktfpkh cfgifgl sfths bkdgl tmh pdkyehr ombfgcfgi wftm tmh ehtbk td rhedvh ft `rde b sdkutfdg. _tuifhs mbvh smdwg tmbt omftdsbg wbs bckh td rhiuoh ehtbk
odgohgtrbtfdgs fg wbthr cy dvhr
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8>
Xgfvhrsftbs Fgidghsfb
Ybckh 0.2 Odgohpt Ihsorfptfdg Cbshi dg \dra rfgofpkh (Odgtfguhi)
2? Gbgdebthrfbk
Bisdrptfdg
Bivbgohs fg gbgdthomgdkdly sullhst tmbt ebgy d` tmh ourrhgt prdckhes fgvdkvfgl wbthr qubkfty oduki ch rhsdkvhi
dr lrhbtky behkfdrbthi usfgl gbgdobtbkysts, gbgdsdrchgts, cfdbotfvh gbgdpbrtfokhs, gbgdstruoturhi obtbkytfo
ehecrbghs bgi gbgdpbrtfokh hgmbgohi `fktrbtfdg bedgl dtmhr prdiuots bgi prdohsshs rhsuktfgl `rde tmh
ihvhkdpehgt d` gbgdthomgdkdly. Gbgdebthrfbks wmfom oduki ch ushi fg wbthr purf`fobtfdg bgi ihsbkfgbtfdgs
fgokuihs ehtbk, ehtbk dxfihs gbgdpbrtfokhs, Lrbpmhgh bgi obrcdg gbgdtuchs. Biiftfdgbkky, gbgdthomgdkdly-
ihrfvhi prdiuots tmbt rhiuoh tmh odgohgtrbtfdgs d` tdxfo odepdugis td suc-ppc khvhks obg bssfst fg tmh bttbfgehgtd` wbthr qubkfty stbgibris bgi mhbktm bivfsdrfhs.
29 XP^urf`fobtfdg
XP purf`fobtfdg wdras bs tmh uktrbvfdkht hghrly heftthi cy tmh kflmt fs bcsdrchi cy tmh ohkks d` tmh efordch,prhvhgtfgl ohkk hgzyehs `rde rhbifglfts IGB. \ftmdut fgtbot IGB, efordchs obgt rhprdiuoh td ebah phdpkh
sfoa. Ymh prdohss fs sfepkh cut h``hotfvh, ihstrdyfgl dvhr 66.6 phrohgt d` mbre`uk eforddrlbgfses.XP kflmt fs lhghrbkky ih`fghi td ch wbvhkhgltm d` hkhotrdeblghtfo rbifbtfdg smdrthr tmbg 9>> ge bgi fs `urtmhr
ifvfihi fgtdXP-B (?28-9>>ge),XP-C (3=>-?28ge) bgiXP-O (3>>-3=> ge).XPB bgiXPC brh rhspdgsfckh`dr sug tbggfgl bgi sugcurgfgl. XPC fs pbrtky `fkthrhi dut cy tmh btedspmhrh bgi dgky b `hw phrohgt rhbom tmh
hbrtm sur`boh. Ymfs fs lddi, chobushXPC kflmt obg ch ifrhotky bcsdrchi cyIGB,wmhrh ft wduki fgiuoh ohkkukbribeblh.XPO bksd phghtrbths ohkks bgi ibeblh tmhIGB,cut ft fs bkedst hgtfrhky `fkthrhi dut cy tmh dzdgh kbyhr.
YmhXP tuchs ushi `dr ifsfg`hotfdg id odgtbfg tmh wmdkh sphotrue d` XP kflmt, fgokuifgl tmhXPC bgi XPO.
Ymh kflmt, wmhg ft rhbomhs efordcfbk ohkkskhbis td ibeblh d` tmh lhghtfo ebthrfbk (IGB), rhgihrfgl tmhe ugbckh
td rhpkfobth.
28 Cdfkfgl Ymh\MD rhodeehgis crfglfgl wbthr td b rdkkfgl cdfk bs bg fgifobtfdg tmbt b ifsfg`hotfdgthephrbturh mbs chhg
bomfhvhi (\MD 3>>=). F` prbotfshi odrrhotky, cdfkfgl fs dgh d` tmh edst h``hotfvh wbthr trhbtehgt ehtmdis td afkk
dr ihbotfvbth bkk okbsshs d` wbthrcdrghpbtmdlhgs,fgokuifgl cbothrfbk spdrhs bgi prdtdzdbg oysts tmbt mbvh smdwgrhsfstbgoh td omhefobk ifsfg`hotfdg bgi vfrushs tmbt brh tdd sebkk td ch ehombgfobkky rhedvhi cyeford`fktrbtfdg
(CKDOA 3>>2). Mhbtfgl wbthr td hvhg 88 O mbs chhg smdwg td afkk dr fgbotfvbth edst pbtmdlhgfo cbothrfb,
vfrushs,mhkefgtms bgiprdtdzdb tmbt brh odeedgky wbthr cdrgh (@HBOMHE ht bk. 26=?).
http://www.sswm.info/glossary/2/letteru#term1017http://www.sswm.info/glossary/2/letteru#term1023http://www.sswm.info/glossary/2/letteru#term1024http://www.sswm.info/glossary/2/letteru#term1025http://www.sswm.info/glossary/2/letteru#term1023http://www.sswm.info/glossary/2/letteru#term1024http://www.sswm.info/glossary/2/letteru#term1024http://www.sswm.info/glossary/2/letteru#term1024http://www.sswm.info/glossary/2/letterd#term80http://www.sswm.info/glossary/2/letteru#term1025http://www.sswm.info/glossary/2/letterd#term80http://www.sswm.info/glossary/2/letteru#term1017http://www.sswm.info/glossary/2/letteru#term1017http://www.sswm.info/glossary/2/letteru#term1024http://www.sswm.info/glossary/2/letteru#term1025http://www.sswm.info/glossary/2/letterl#term1324http://www.sswm.info/glossary/2/letterd#term80http://www.sswm.info/glossary/2/letterw#term1336http://www.sswm.info/glossary/2/lettert#term1002http://www.sswm.info/glossary/2/letterw#term1336http://www.sswm.info/glossary/2/letterp#term389http://www.sswm.info/glossary/2/letterm#term1462http://www.sswm.info/glossary/2/letterb#term38http://www.sswm.info/glossary/2/letterh#term116http://www.sswm.info/glossary/2/letterp#term421http://www.sswm.info/glossary/2/letterp#term421http://www.sswm.info/glossary/2/letterh#term116http://www.sswm.info/glossary/2/letterb#term38http://www.sswm.info/glossary/2/letterm#term1462http://www.sswm.info/glossary/2/letterp#term389http://www.sswm.info/glossary/2/letterw#term1336http://www.sswm.info/glossary/2/lettert#term1002http://www.sswm.info/glossary/2/letterw#term1336http://www.sswm.info/glossary/2/letterd#term80http://www.sswm.info/glossary/2/letterl#term1324http://www.sswm.info/glossary/2/letteru#term1025http://www.sswm.info/glossary/2/letteru#term1024http://www.sswm.info/glossary/2/letteru#term1017http://www.sswm.info/glossary/2/letteru#term1017http://www.sswm.info/glossary/2/letterd#term80http://www.sswm.info/glossary/2/letteru#term1025http://www.sswm.info/glossary/2/letterd#term80http://www.sswm.info/glossary/2/letteru#term1024http://www.sswm.info/glossary/2/letteru#term1024http://www.sswm.info/glossary/2/letteru#term1024http://www.sswm.info/glossary/2/letteru#term1023http://www.sswm.info/glossary/2/letteru#term1025http://www.sswm.info/glossary/2/letteru#term1024http://www.sswm.info/glossary/2/letteru#term1023http://www.sswm.info/glossary/2/letteru#term10177/21/2019 Revised Midterm Report Chemical Product Design
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Xgfvhrsftbs Fgidghsfb
Ybckh 0.2 Odgohpt Ihsorfptfdg Cbshi dg \dra rfgofpkh (Odgtfguhi)
20 Ifstfkkbtfdg Yd rhedvh fepurftfhs `rde wbthr cy ifstfkkbtfdg, tmh wbthr fs usubkky cdfkhi fg b ombechr obusfgl wbthr td
vbpdrfzh, bgi tmh purh (dr edstky purh) sthbe khbvhs tmh gdg vdkbtfkh odgtbefgbgts chmfgi. Ymh sthbe edvhs td b
if``hrhgt pbrt d` tmh ugft bgi fs oddkhi ugtfk ft odgihgshs cboa fgtd kfqufi wbthr. Ymh rhsuktfgl ifstfkkbth irfps fgtd
b stdrblh odgtbfghr.
_bkts, shifehgt, ehtbks - bgytmfgl tmbt wdg't cdfk dr hvbpdrbth - rhebfg fg tmh ifstfkkhr bgi eust ch rhedvhi.
Pdkbtfkh drlbgfo odepdugis (PDOs) brh b lddi hxbepkh d` b odgtbefgbgt tmbt wfkk hvbpdrbth bgi odgihgsh wftmtmh wbthr vbpdr. B vbpdr trbp, obrcdg `fkthr, dr dtmhr ihvfoh eust ch ushi bkdgl wftm b ifstfkkhr td hgsurh b edrh
odepkhth rhedvbk d` odgtbefgbgts.
2< Hkhotrd
omhefobk
Hkhotrdomhefobk wbthr trhbtehgt systhes utfkfzh hkhotrfofty td fgiuoh tmh rhedvbk d` ifssdkvhi odgtbefgbgts fg
tmh wbthr. ^dsftfvhky ombrlhi odgtbefgbgts suom bs obkofue, eblghsfue, sdifue, khbi bgi urbgfue brh obkkhiobtfdgs. Ghlbtfvhky ombrlhi odgtbefgbgts suom bs omkdrfihs, gftrbths, gftrfths, suk`bths bgi `kudrfihs brh obkkhi
bgfdgs. Ymh fgtrdiuotfdg d` b ghlbtfvhky ombrlhi hkhotrdih, dr obtmdih, fgtd tmh wbthr wfkk obush pdsftfvhkyombrlhi obtfdgs td edvh tdwbri ft. B pdsftfvhky ombrlhi hkhotrdih, dr bgdih, wfkk obush ghlbtfvhky ombrlhi
bgfdgs td edvh tdwbri ft. Hkhotrdomhefobk wbthr trhbtehgt systhes tbah bivbgtblh d` tmfs prdphrty cy odecfgfgltmh hkhotrdih wftm fdg hxombglh ehecrbghs.
Ymh prfgofpkh fs tmus sfepkh: Fgtrdiuoh b ghlbtfvhky ombrlhi obtmdih td edvh tmh pdsftfvhky ombrlhi obtfdgs
tmrdulm b obtfdg ehecrbgh, wmhrh tmhy odkkhot bgi odgohgtrbth, khbvfgl trhbthi prdiuot wbthr chmfgi dg tmh
dtmhr sfih d` tmh ehecrbgh. Bkthrgbtfgl bgfdg ehecrbghs wftm obtfdg ehecrbghs orhbths bkthrgbtfgl odgohgtrbth
bgi purf`fobtfdg zdghs. Ymh prdiuot wbthr obg tmhg ch rhkhbshi td b stdrblh tbga, wmhrh ft fs odkkhothi `dr ush.
2= Omhefobk
^rhofpftbtfdg
^rhofpftbtfdg fs b ehtmdi d` obusfgl odgtbefgbgts tmbt brh hftmhr ifssdkvhi dr susphgihi fg sdkutfdg td shttkh dut
d` sdkutfdg bs b sdkfi prhofpftbth, wmfom obg tmhg ch `fkthrhi, ohgtrf`ulhi, dr dtmhrwfsh shpbrbthi `rde tmh kfqufipdrtfdg. ^rhofpftbtfdg fs bssfsthi tmrdulm tmh ush d` b odblukbgt, bg blhgt wmfom obushs sebkkhr pbrtfokhs
susphgihi fg sdkutfdg td lbtmhr fgtd kbrlhr bllrhlbths. @rhquhgtky, pdkyehrs brh ushi bs odblukbgts. \mhg
odkkdfibk ebtthr suom bs heuksf`fhi dfk dr ehtbk chbrfgl pbrtfokhs brh trhbthi wftm ehtbk sbkts bgi kfeh dr GbDM,
tmh ehtbk sbkts bot bs prfebry odblukbgts. Ymh pdsftfvhky ombrlhi ehtbk fdgs odecfgh wftm tmh ghlbtfvh odkkdfi
pbrtfokhs bgi ghutrbkfzh tmhfr ombrlh.
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Xgfvhrsftbs Fgidghsfb
Ybckh 0.2 Odgohpt Ihsorfptfdg Cbshi dg \dra rfgofpkh (Odgtfguhi)
26 Omkdrfgbtfdg Omkdrfgh fgbotfvbths b eforddrlbgfse cy ibeblfgl fts ohkk ehecrbgh. Dgoh tmh ohkk ehecrbgh fs whbahghi, tmh
omkdrfgh obg hgthr tmh ohkk bgi ifsrupt ohkk rhspfrbtfdg bgi IGB botfvfty (twd prdohsshs tmbt brh ghohssbry `dr ohkk
survfvbk). Ymh omkdrfgh obg ch fg `dre d` tbckhts tmbt obg ch ushi ifrhothi ebah odgtbefgbthi wbthr suftbckh dr
irfgafgl. Ymh omkdrfgbtfdg prdohss ftshk` eby lhghrbthi cy usfgl hkhotrfo hghrly tmbt chfgl prdvfihi cy sdkbr
hghrly, cbtthry, dr dtmhr hkhotrfo hghrly rhsdurohs.
Omkdrfgh fs edst h``hotfvh f` tmh wbthr mbs b pM fg tmh rbglh d` 0.>- euom edrh omkdrfgh fs rhqufrhitd mbvh tmh sbeh h``hot tmbg f` tmh wbthr mbi b pM d` . Bt pM dvhr =.8 omkdrfgh chodehs fgh``hotfvh bs b
ifsfg`hotbgt.Ymh wbrehr tmh wbthr, tmh edrh h``hotfvh `rhh-omkdrfgh fs fg ifsfg`hotfgl wbthr bgi dxfifzfgl frdg.
Odkihr wbthr khss tmbg 2>O (8>@) rhqufrhs kdglhr odgtbot tfehs bgi mflmhr odgohgtrbtfdgs d` omkdrfgh
3> Ifbkysfs:Hkhotrdifbkysfs
Hkhotrdifbkysfs if``hrs `rde prhssurh-irfvhg ehecrbgh prdohsshs cy utfkfzfgl hkhotrfobk ourrhgt bs tmh ebfgirfvfgl `droh fg ebtthr shpbrbtfdg. Ymfs kfefts tmh pdssfckh sdkuths tbrlhthi `dr rhodvhry shpbrbtfdg td ombrlhi
pbrtfokhs. Ymh ombrlhi pbrt fokhs eust ch edcfkh, bgi tmh shpbrbtfdg ehifb eust ch bckh td trbgs`hr tmh hkhotrfobkourrhgt wftm rhkbtfvhky kdw rhsfstbgoh. Hkhotrdifbkysfs fs bkedst hxokusfvhky obrrfhi dut dg kfqufis.
^rfgofpbkky, ft lhghrbths bg hkhotrfo ourrhgt tmbt shpbrbths omkdrfih bgi sdifue fdgs bs wbthr pbsshs tmrdulm tmhsysthe. Ymh systhe odeprfshs d` bg bgdih bgi b obtmdih. Ymhsh bttrbot ghlbtfvh bgi pdsftfvhky ombrlhi fdgs
rhsphotfvhky bgi trbp tmhe fg shefphrehbckh ehecrbghs `ftthi dg cdtm hgis. Bs b rhsukt, ft `kusmhs d`` fdgs bgi
rhkhbshs purh wbthr tmbt phdpkh obg ush `dr vbrfdus botfvftfhs.
32 Hgzye:
Hgzyebtfo
Yrhbtehgt
Hgzyehs brh mflmky sphof`fo bgi hxtrhehky h``fofhgt obtbkysts. Ymhy obg shkhotfvhky ihlrbih b tbrlht pdkkutbgt
wftmdut b``hotfgl tmh dtmhr odepdghgts fg tmh h``kuhgt. Hgzyehs trbgs`dre drlbgfo sucstbgohs frrhvhrsfcky fgtd
wbthr-sdkuckh rhsfiuh. Ft fs tmfs botfdg wmfom ehbgs tmbt hgzyehs brh odgsfihrhi b pdwhr`uk okhbgfgl blhgt.Hgzyehs trbgs`dre drlbgfo ebtthr fgtd sebkkhr wbthr-sdkuckh rhsfiuh. Ymfs crdahg-idwg rhsfiuh fs hbsfhr `dr
cbothrfb td bssfefkbth1 tmhsh cbothrfb tmhg trbgs`dre tmh rhsfiuh fgtd gbturbk sucstbgohs iurfgl tmh purf`yfgl
prdohss.
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8?
Xgfvhrsftbs Fgidghsfb
Ybckh 0.2 Odgohpt Ihsorfptfdg Cbshi dg \dra rfgofpkh (Odgtfguhi)
33 Odblukbtfdg Odblukbtfdg rhedvhs ifrt bgi dtmhr pbrtfokhs susphgihi fg wbthr. Bkue bgi dtmhr omhefobks brh biihi td wbthr
td `dre tfgy stfoay pbrtfokhs obkkhi "`kdo" wmfom bttrbot tmh ifrt pbrtfokhs. Ymh odecfghi whflmt d` tmh ifrt bgi tmh
bkue (`kdo) chodeh mhbvy hgdulm td sfga td tmh cdttde iurfgl shifehgtbtfdg. Ymh odeedg odblukbgts ushi fg
wbthr purf`fobtfdg prdohss brh pdkyehrfo myirdxyomkdrfih, bkuefgfue sukpmbth, `hrrfo sukpmbth, bgi
pdkyborykfefih.
Odblukbtfdg ihstbcfkfshs tmh pbrtfokhs ombrlhs. Odblukbgts wftm ombrlhs dppdsfth td tmdsh d` tmh susphgihisdkfis brh biihi td tmh wbthr td ghutrbkfsh tmh ghlbtfvh ombrlhs dg ifsphrshi gdg-shttbckh sdkfis suom bs okby bgi
drlbgfo sucstbgohs. Dgoh tmh ombrlh fs ghutrbkfshi, tmh sebkk-susphgihi pbrtfokhs brh obpbckh d` stfoafgl
tdlhtmhr.
3? Fdg Hxombglh Fdg hxombglh fs b wbthr trhbtehgt ehtmdi wmhrh dgh dr edrh ugihsfrbckh fdgfo odgtbefgbgts brh rhedvhi `rdewbthr cy hxombglh wftm bgdtmhr gdg-dcjhotfdgbckh, dr khss dcjhotfdgbckh fdgfo sucstbgoh. Cdtm tmh odgtbefgbgt
bgi tmh hxombglhi sucstbgoh eust ch ifssdkvhi bgi mbvh tmh sbeh typh d` hkhotrfobk ombrlh (pdsftfvh drghlbtfvh). B typfobk hxbepkh d`fdg hxombglh fs b prdohss obkkhi wbthr sd`thgfgl bfefgl td rhiuoh obkofue bgi
eblghsfue odgthgt.Mbri wbthr odgtbfgfgl b kdt d` obkofue fdgs fs trhbthi dvhr chbis wftm ghlbtfvhky ombrlhi sdifue fdgs. Ymfs
rhsukts fg tmh rhpkbohehgt d` sdifue fdgs cy pdsftfvhky ombrlhi obkofue fdgs bgi tmh wbthr hvhgtubkky lhts
sd`thghi, tmdulm wftm edrh sdifue fdgs. Zhdkfths, ebih `rde sfkfobths, brh bksd ushi fg chobush tmhy obg mdki
pkhgty d` obtfdgs. _fefkbrky, tmhrh brh bgfdg hxombglh rhsfgs tmbt brh chis d` pdkyehr wmhrh obtfdgfo lrdups lht
bttbomhi td tmh sur`boh.
39 Hkhotrdobtbifbg B idss d` sfkvhr, wmfom vbrfhs `rde >.>8 td >.2 el/K, fs `hi td wbthr wftm tmh mhkp d` tmh ifrhot ourrhgt, wmfomrhedvhs bkk eford drlbgfses. Ymfs fs qufth h``hotfvh fg hkfefgbtfgl bkk tmh cbothrfb fg tmh wbthr. Gbgd sfkvhr
bttbomhi td tmh `fkthr rhkhbshs tmh sfkvhr fdgs tmbt `rhquhgtky ihstrdy tmh cbothrfb.
http://www.sswm.info/glossary/2/letterc#term2400http://www.sswm.info/glossary/2/letterc#term132http://www.sswm.info/glossary/2/lettero#term385http://www.sswm.info/glossary/2/letteri#term1458http://www.sswm.info/glossary/2/letteri#term1458http://www.sswm.info/glossary/2/letteri#term1458http://www.sswm.info/glossary/2/letteri#term1458http://www.sswm.info/glossary/2/lettero#term385http://www.sswm.info/glossary/2/letterc#term132http://www.sswm.info/glossary/2/letterc#term24007/21/2019 Revised Midterm Report Chemical Product Design
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Xgfvhrsftbs Fgidghsfb
Ybckh 0.2 Odgohpt Ihsorfptfdg Cbshi dg \dra rfgofpkh (Odgtfguhi)
38 Dzdgbtfdg Dzdgbtfdg fs b omhefobk wbthr trhbtehgt thomgfquh cbshi dg tmh fg`usfdg d` dzdgh fgtd wbthr. Dzdgh fs b lbs
odepdshi d` tmrhh dxylhg btdes (D?), wmfom fs dgh d` tmh edst pdwhr`uk dxfibgts. Dzdgfsbtfdg fs b typh d`
bivbgohi dxfibtfdg prdohss,fgvdkvfgl tmh prdiuotfdg d` vhryrhbotfvh dxylhg sphofhs bckh td bttboa b wfih rbglh
d` drlbgfo odepdugis bgi bkkeforddrlbgfses.Dzdgh fs prdiuohi wftm tmh ush d`hghrlycy sucjhotfgl dxylhg
(D3) td mflm hkhotrfo vdktblh dr tdXP rbifbtfdg.
Ymh h``hotfvhghss d` dzdgh rhsukts `rde fts pdwhr`uk dxfifsfgl h``hot dg omhefobks bgieforddrlbgfses obushicy tmh lhghrbtfdg d` rhbotfvh dxylhg sphofhs iurfgl dzdgh trbgs`drebtfdg td dxylhg. Dzdgh ifrhotky bttboas tmh
sur`boh d`eforddrlbgfses bgi ihstrdys tmhfr ohkk wbkks. Ymh ohkks tmus kddsh tmhfr oytdpkbse bgi obg gd kdglhr
rhbotfvbth tmheshkvhs (_YXOAF ht bk. 3>>8).
30 Eford
@fktrbtfdg
B eford`fktrbtfdg `fkthr mbs b pdrh sfzh brdugi >.2 efordg. Ymh prfgofpkh d` eford `fktrbtfdg bgi uktrb `fktrbtfdg fspmysfobk shpbrbtfdg. Ymh hxthgt td wmfom ifssdkvhi sdkfis, turcfifty bgi efordrlbgfses brh rhedvhi fs
ihthrefghi cy tmh sfzh d` tmh pdrhs fg tmh ehecrbghs. _ucstbgohs tmbt brh kbrlhr tmbg tmh pdrhs fg tmh ehecrbghsbrh `ukky rhedvhi. _ucstbgohs tmbt brh sebkkhr tmbg tmh pdrhs d` tmh ehecrbghs brh pbrtfbkky rhedvhi, ihphgifgl
dg tmh odgstruotfdg d` b rh`ush kbyhr dg tmh ehecrbgh.
3< Gbgd@fktrbtfdg
B gbgd`fktrbtfdg `fkthr mbs b pdrh sfzh brdugi >.>>2 efordg. Ymh Gbgd `fktrbtfdg ehecrbgh thomgdkdly fs prhssurhcbshi thomgdkdly tmbt fs ehbgt `dr tmh shpbrbtfdg d` sdkuckh fdgs `rde wbthr cy ush d` shef phrehbckh ehecrbgh
wmhrh ft prdiuohs sbeh qubgtfty prdiuot bt 8> td % d` tmh bppkfhi prhssurh bs SD. Ymhsh Gbgd-`fktrbtfdgsysthes ebah h``hotfvh ush d` mflm prhssurh `dr tmh shpbrbtfdg d` odgtbefgbgts `rde wbthr suppky. Bs wbthr fs
`drohi tmrdulm ehecrbghs mbvfgl tfgy mdkhs(.>>>2 efordg fg sfzh), cbothrfb, vfrbk odgtbefgbgts, PDOs, _DOs
bgi dtmhr ugwbgthi wbthr odgtbefgbgts brh h``hotfvhky rhedvhi.
3= Xktrb`fktrbtfdg Bg uktrb`fktrbtfdg `fkthr mbs b pdrh sfzh brdugi >.>2 efordg. B sfepkh prdohiurh obkkhi "kdw prhssurh"uktrb`fktrbtfdg phrefts tmh okbrf`fobtfdg bgi ifsfg`hotfdg d` wbthr fg b sfglkh sthp. B ehecrbgh cbrrfhr bots kfah b
`fkthr `dr bkk pbrtfokhs dvhr 2>-3> ge fg sfzh: pdkkhg, bklbh, cbothrfb, vfrushs, lhres bgi drlbgfo edkhoukhs. Ymhuktrb`fktrbtfdg prdohiurh fs ehombgfobk: ft rhiuohs trhbtehgt wbsth bgi tmh ghhi td ush omhefobks, wmfkh
odgshrvfgl tmh efghrbk hqufkfcrfue d` tmh wbthr.(_duroh : Butmdrs hrsdgbk Ibtb bgi lbtmhr rde bgy sdurohs)
http://www.sswm.info/glossary/2/lettera#term1059http://www.sswm.info/glossary/2/letterr#term1107http://www.sswm.info/glossary/2/letterm#term368http://www.sswm.info/glossary/2/lettere#term1370http://www.sswm.info/glossary/2/letteru#term1017http://www.sswm.info/glossary/2/letterm#term368http://www.sswm.info/glossary/2/letterr#term1107http://www.sswm.info/glossary/2/letterm#term368http://www.sswm.info/glossary/2/letterm#term368http://www.sswm.info/glossary/2/letterr#term1107http://www.sswm.info/glossary/2/letterm#term368http://www.sswm.info/glossary/2/letteru#term1017http://www.sswm.info/glossary/2/lettere#term1370http://www.sswm.info/glossary/2/letterm#term368http://www.sswm.info/glossary/2/letterr#term1107http://www.sswm.info/glossary/2/lettera#term10597/21/2019 Revised Midterm Report Chemical Product Design
60/91
88
Xgfvhrsftbs Fgidghsfb
0.3. Odgohpt _orhhgfgl
B`thr `fgifgl ebgy hxfstfgl odgohpts bgi lhghrbtfgl ghw odgohpts, wh
bkrhbiy lht vbrfdus odgohpts. Dgky dgh bgi tmh chst odgohpt wfkk ch ushi bsodgohpt d` dur prdiuot. Ymh ghxt sthp wh id fs odgohpt sorhhgfgl. Ymh ldbk d`
odgohpt sorhhgfgl fs td gbrrdw tmh guechr d` odgohpt qufoaky bgi ihvhkdp tmh
chst odgohpt. Fg odgohpt sorhhgfgl, wh smduki odepbrh tmh odgohpts wftm ebgy
orfthrfbs fgokuifgl thomgfobk bgi sucjhotfvh orfthrfb kfah ode`drt bgi sb`hty. Fg
idfgl odgohpt sorhhgfgl, `fvh sthps mbvh td ch idgh :
^rhpbrh tmh shkhotfdg ebtrfx
Sbth tmh odgohpts
Sbga tmh odgohpts
Odecfgh bgi feprdvh tmh odgohpts
_hkhot dgh dr edrh odgohpts
@rde `fgifgl hxfstfgl odgohpts bgi ghw odgohpts, wh lht 3= prdiuot
odgohpts. Fts bkk cbshi dg wdra prfgofpkh. _deh odgohpts brh dg if``hrhgt khvhk
wftm dtmhr odgohpts. Eford`fktrbtfdg, gbgd`fktrbtfdg, bgi uktrb`fktrbtfdg brh odgohpts
tmbt odeh `rde if``hrhgt `fkthr ehifb pdrh sfzh. \mfkh ehecrbgh `fktrbtfdg, sbgi
`fktrbtfdg, ohrbefo `fktrbtfdg, bgi mdkkdw `fktrbtfdg brh odgohpts tmbt odeh `rde
`fkthr ehifb ebthrfbk. Bkk odgohpts brh boohpthi bs kdgl bs fts rhkbthi td wdra
prfgofpkh td purf`y wbthr. Mhrh fs tmh kfst d` prdiuot odgohpts :
Ybckh 0.3 ^rdiuot Odgohpts
Odgohpt
Guechr
^rdiuot Odgohpt
2 Sbifbtfdg
3 Hxtrbotfdg
? Ehecrbgh @fktrbtfdg
9 _bgi @fktrbtfdg
8 Ohrbefo @fktrbtfdg
0 Mdkkdw @fchr @fktrbtfdg
< Shvhrsh Dsedsfs
= Botfvbthi Obrcdg Bisdrptfdg
7/21/2019 Revised Midterm Report Chemical Product Design
61/91
80
Xgfvhrsftbs Fgidghsfb
Ybckh 0.3 ^rdiuot Odgohpts (odgtfguhi)
Odgohpt
Guechr
^rdiuot Odgohpt
6 _fkfob Lhk Bisdrptfdg
2> Bkuefgb Bisdrptfdg
22 Omftdsbg Bisdrptfdg
23 Zhdkfth Bisdrptfdg
2? Gbgdebthrfbk Bisdrptfdg
29 XP ^urf`fobtfdg
28 Cdfkfgl
20 Ifstfkkbtfdg
2< Hkhotrdomhefobk
2= Omhefobk ^rhofpftbtfdg
26 Omkdrfgbtfdg
3> Ifbkysfs
32 Hgzfeh
33 Odblukbtfdg
3? Fdg Hxombglh
39 Hkhotrdobtbifbg
38 Dzdgbtfdg
30 Eford`fktrbtfdg
3< Gbgd`fktrbtfdg
3= Xktrb`fktrbtfdg(_duroh : Butmdrs ^hrsdgbk Ibtb bgi lbtmhr `rde bgy sdurohs)
_orhhgfgl F
Odgohpts tmbt bkrhbiy chhg kfsthi bcdvh odehs `rde hxfstfgl prdiuot
odgohpts bgi ghw prdiuot odgohpts. Ymh ghw fihbs brh lhghrbthi `rde dur lrdup
crbfgstdrefgl. Ymh odgohpts tmbt odehs `rde crbfgstdrefgl eby ch kdlfo,
rhiugibgt, `ddkfsm, dr vbluh. Gdw, wh ghhi td hkfefgbth sdeh d` tmhe td hbsh us
`dr tmh ghxt sthp. Hkfefgbthi odgohpts brh tmh dghs tmbt obg ch okbssf`fhi fgtd
rhiugibgt (S), `ddkfsm (@), dr vbl