SAFETY DATA SHEET - Brandenburg Industrial Service Co. data sheets/paint pr… · SAFETY DATA SHEET Date of issue/Date of revision 13 April 2015 Version 3 I Section 1. Identification

06/05/2015 12:33PM FAX 17735216860+ S S I

SAFETY DATA SHEET

Date of issue/Date of revision 13 April 2015

Version 3

I Section 1. Identification Product name

Product code

Other means of identification

Product type

2.8/3.5 voe 2K HS POLYURETHANE TOPCOAT (AUE-360) SF BLACK

AU36-FP901

Not available.

Liquid.

Releyant jdentlfled MS@s of the 5yb1tan'°e pr mjxtyre and usea adyjsgd against

Product use

Use of the substance/ mixture

Uses advised against

Supplier

Emergeas:l! telephone number

Technical Phone Number

Industrial applications.

Coating. Paints. Painting-related materials.

Not applicable.

PPG Industries, Inc. One PPG Place, Pittsburgh, PA 15272

(412) 434-4515 (U.S.) (514) 645-1320 (Canada) 01-800-00-21-400 (Mexico)

1-600-64 7 ·6050

Section 2. Hazards identification

li!l 0009/0023

OSHA/HCS status This material Is considered hazardous by the OSHA Hazard Communication Standard (29 CFR 1910.1200).

Classification of the substance or mixture

~!:IS label elements Hazard pictograms

Sign3l word

FLAMMABLE LIQUIDS· Category 3 ACUTE TOXICITY (oral) - Category 4 ACUTE TOXICITY (inhalation) Category 4 CARCINOGENICITY - Category 2 Percentage of the mixture consisting of lngredient(s) of unknown toxicity: 58. 7%

Warning

United States

06/05/2015 2:34PM (GMT-04:00)

06/05/2015 12:33PM FAX 17735216860+ S S I li!l 0010/0023

Product code AU36·FP901 Date of IHue 13 April 2015 Version 3

Product name 2.8/3.5 VOC 2K HS POLYURETHANE TOPCOAT (AUE-360) SF BLACK

Section 2. Hazards identification Hazard statements

Precayt!!WllCll litllt'ments Prevention

Response

Storage

Disposal

Supplemental label elements

Hazards not otherwise classified

Flammable liquid and vapor. Hanmlul ii swallowed or If Inhaled. Suspected of causing cancer.

Obtain special Instructions before use. Do not handle until all safety precautions have been read and understood. Use personal protective equ'1pment as required. Wear protective gloves. Wear eye or lace protection. Keep away from heat, hot surfaces, sparks, open flames and other ignition sources. No smoking. Use explosion-proof electrical, ventllatlng, lighting and all material-handling equipment. Use only nonsparking tools. Take precautionary measures against static discharge. Keep container tightly closed. Use only outdoors or in a well-ventilated area. Avoid breathing vapor. Do not eat, drink or smoke when using this product. Wash hands thoroughly after handling.

IF exposed or concerned: Get medical attention. IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing. Call a POISON CENTER or physician ii you feel unwell. IF SWALLOWED: Call a POISON CENTER or physician ii you feel unwell. Rinse mouth. IF ON SKIN (or hair): Take off Immediately all contaminated clothing. Rinse skin with water or shower.

Store locked up. Store in a well-ventilated place. Keep cool.

Dispose of contents and container in accordance with all local, regional, national and international regulations.

Repeated exposure to high vapor concentrations may cause irritation of the respiratory system and penmanent brain and nervous system damage. Inhalation of vapor/aerosol concentrations above the recommended exposure limits causes headaches, drowsiness and nausea and may lead to unconsciousness or death. Avoid contact with skin and clothing. Wash thoroughly after handling. Emits toxic fumes when heated.

Prolonged or repeated contact may dry skin and cause irritation.

I Section 3. Composition/information on ingredients Mixture Substance/mixture

Product name : 2.8/3.5 voe 2K HS POLYURETHANE TOPCOAT (AUE-360) SF BLACK

Ingredient name % CAS number

lll!iptan-2-one 10 - 30 110-43-0 2-methoxy-1-methylethyl acetate 5 -10 108-65-6 pentane-2,4-dione 1 - 5 123-54-6 n·butyl acetate 1 - 5 123-86-4 carbon black, respirable powder 0.1 - 1 1333-86-4 methyl methacrylate 0.1 - 1 B0-62-6 2-hydroxyethyl acrylate 0.1 - 1 818-61-1 n-butyl acrylate 0.1 - 1 141-32-2

SUB codes represent substances without registered CAS Numbers.

Any concentration shown as a range is to protect confidentiality or is due to batch variation.

There are no additional Ingredients present whic:h, within the c:urrent knowledge of the supplier and in the concentrations applicable, are classified as hazardous to health or the environment and hence require reporting in this section.

Unitod States Page: 211s J

06/05/2015 2:34PM (GMT-04:00)

06/05/2015 12:33PM FAX 17735216860+ S S I l1ll 0011/0023

Product code AU36·FP901 Date ot Issue 13 April 2015 Version 3


Section 3. Composition/information on ingredients Occupational exposure llrnlts, If available, are listed In Section 8.

[SE!Ction 4. First aid measures If ingestion, irritation, any type of overexposure or symptoms of overexposure occur during or persists after use of this product. contact a POISON CONTROL CENTER, EMERGENCY ROOM OR PHYSICIAN immediately; have Safety Data Sheet information available. Never give anything by mouth to an unconscious or convulsing person.

pescrjptjon of necessarv fjrst ajd measures

Eye contact

Inhalation

Skin contact

Ingestion

Check for and remove any contact lenses. Immediately flush eyes with running water for at least 15 minutes, keeping eyelids open. Seek immediate medical attention. Remove to fresh air. Keep person warm and at rest. If not breathing, if breathing is irregular or if respiratory arrest occurs, provide artificial respiration or oxygen by trained personnel.

Remove contaminated clothing and shoes. Wash skin thoroughly with soap and water or use recognl::i:ed skin cleanser. Do NOT use solvents or thinners. If swallowed, seek medical advice Immediately and show this container or label. Keep person warm and at rest. Do NOT induce vomiting.

Most jmportant symptoro11tettects. acyte and deland

pgtentlal acute health effects

Eye contact

lnhalatlon

Skin contact

Ingestion

No known significant effects or critical hazards.

Harmful if inhaled.

Defattlng to the skin. May cause skin dryness and irritation.

Harmful if swallowed.

Oyer:expgsure signs/symptoms

Eye contact No specific data.

Inhalation No specific data.

Skin contact

Ingestion

Adverse symptoms may include the following: Irritation dryness cracking

No specific data.

!nd!gatlon of Immediate medjcal attention and spe~igl trtatment needed If necessary

Notes to physician In case of inhalation of decomposition products in a fire, symptoms may be delayed. The exposed person may need to be kept under medical surveillance tor 48 hours.

Specific treatments No specific treatment.

Protection of first-aiders No action shall be taken involving any personal risk or without suitable training. If it is suspected that fumes are still present, the rescuer should wear an appropriate mask or self-contained breathing apparatus. It may be dangerous to the person providing aid to give mouth-to-mouth resuscitation.

See toxicological Information (Section 11)

Unitod States Page: 31151

J

06/05/2015 2:34PM (GMT-04:00)

06/05/2015 12:33PM FAX 17735216860+ S S I li!l 0012/0023

Product code AU36-FP901 Date of issue 13 Aprll 2015 Version 3


I Section 5. Fire-fighting measures Extjnguishjng m1dia

Suitable extinguishing media

Unsuitable extinguishing media

Specific hazards arising from the chemical

Ha:tardous thermal decomposition products

Special protective actions for fire-fighters

Use dry chemical. co,, water spray (fog) or foam.

Do not use water jet.

Flammable liquid and vapor. In a fire or if heated, a pressure increase will occur and the container may burst, with the risk of a subsequent explosion. Vapors may accumulate in low or confined areas or travel a considerable distance to a source of ignition and flash back. Runoff to sewer may create fire or explosion hazard.

Decomposition products may include the following materials: carbon dioxide carbon monoxide nitrogen oxides

Promptly isolate the scene by removing all persons from the vicinity of the incident if there is a fire. No action shall be taken involving any personal risk or without suitable training. Move containers from fire area if this can be done without risk. Use water spray to keep fire-exposed containers cool.

Special protective Fire-fighters should wear appropriate protective equipment and self-contained breathing equipment for fire-fighters apparatus (SCBA) with a full face-piece operated in positive pressure mode.

I Section 6. Accidental release measures Personal ptfcautjons. protectjye eq11!pment and emerqenc;y procedyres

For non-emergency No action shall be taken involving any personal risk or without suitable training. personnel Evacuate surrounding areas. Keep unnecessary and unprotected personnel from

entering. Do not touch or walk through spilled material. Shut off all ignition sources. No flares, smoking or flames in hazard area. Avoid breathing vapor or mist. Provide adequate ventilation. Wear appropriate respirator when ventilation is inadequate. Put on appropriate personal protective equipment.

For emergency responders If specialised clothing is required to deal with the spillage. take note of any information in Section 8 on suitable and unsuitable materials. See also the information in "For non· emergency personnel".

Environmental precautions Avoid dispersal of spilled material and runoff and contact with soil, waterways, drains and sewers. Inform the relevant authorities if the product has caused environmental pollution (sewers, waterways, soil or air).

Methods and majerlals for containment and cleanjng up

Small spill Stop leak if without risk. Move containers from spill area. Use spark-proof tools and explosion-proof equipment. Dilute with water and mop up if water-soluble. Alternatively, or if water-insoluble, absorb with an inert dry material and place in an appropriate waste disposal cont~iner. Dispose of via a licensed waste disposal contractor.

United States Page: 4115 J

06/05/2015 2:34PM (GMT-04:00)

06/05/2015 12:33PM FAX 17735216860+ S S I li!l 0013/0023

Product code AU36-FP901 Date of Issue 13 Aprll 2015 Version 3


Section 6. Accidental release measures Large spill Stop leak if without risk. Move containers from spill area. Use spark-proof tools and

explosion-proof equipment. Approach release from upwind. Prevent entry into sewers. water courses, basements or confined areas. Wash spillages into an effluent treatment plant or proceed as follows. Contain and collect spillage with non-combustible, absorbent material e.g. sand, earth, vermiculite or diatomaceous earth and place in container for disposal according to local regulations (see Section 13), Dispose of via a licensed waste disposal contractor. Contaminated absorbent material may pose the same hazard as the spilled product. Note: see Section 1 for emergency contact information and Section 13 for waste disposal.

!section 7. Handling and storage Precaytlons for safe handling

Protective measures

Special precautions

Advice on general occupational hygiene

Conditions for safe storage, including any incompatibilities

Put on appropriate personal protective equipment (see Section 8). Avoid exposure • obtain special in$truction$ before use. Oo not handle until all safety precautions have been read and understood. Do not get in eyes or on skin or clothing. Do not inge$1. Avoid breathing vapor or mist. Use only with adequate ventilation. Wear appropriate respirator when ventilation is inadequate. Do not enter storage areas and confined spaces unless adequately ventilated. Keep in the original container or an approved alternative made from a compatible material, kept tightly closed when not In use. Store and use away from heat, sparks, Open flame or any other ignition source. Use explosion-proof electrical (ventilating, lighting and material handling) equipment. Use only non-sparking tools. Take precautionary measures against electrostatic discharges. Empty containers retain product residue and can be hazardous. Do not reuse container. Vapors may accumulate in low or confined areas or travel a considerable distance to a source of ignition and nash back. Vapors are heavier than air and may spread along floors. If this material is part of a multiple component system, read the Safety Data Sheet(s) for the other component or components before blending as the resulting mixture may have the hazards of all of its parts. Eating, drinking and smoking should be prohibited In areas where this material is handled, stored and processed. Workers should wash hands and face before eating, drinking and smoking. Remove contaminated clothing and protective equipment before entering eating areas. See also Section a for additjonal information on hygiene measures.

Do not store above the following temperature: 35'C (95'F). Store in accordance with local regulations. Store in a segregated and approved area. Store in original container protected from direct sunlight in a dry, cool and well.ventilated area, away from incompatible materials (see Section 10) and food and drink. Eliminate all ignition sources. Separate from oxidizing materials. Keep container tightly closed and sealed until ready for use. Containers that have been opened must be carefully resealed and kept upright to prevent leakage. Do not store in unlabeled containers. Use appropriate containment to avoid environmental contamination.

United States Page: 5/151

06/05/2015 2:34PM (GMT-04:00)

06/05/2015 12:34PM FAX 17735216860+ S S I li!J 0014/0023

Product code AU36-FP901 Date of issue 13 April 2015 Version 3

Product name 2.8/3.5 VOC 2K HS POLYURETHANE TOPCOAT (AUE·360) SF BLACK

!section 8. Exposure controls/personal protection Control parameters

Qi;s;:ur;iat!onal exr;iosure limits

Ingredient name

!'reptan-2-one

2-methoxy-1-methylethyl acetate

pentane-2,4-dione

n-butyl acetate

carbon black, respirable powder

methyl methacrylate

2-hydroxyethyl acrylate

n-butyl acrylate

Kay to 11bbraviatic:u1& • Acceptable Maximum Peak A

ACGIH c

;; American Conference of Govemmenteil lndustrieil Hygienist.. • Ceiling Limit

F 1Pi::L

OSHA R z

;; F1,1mt!I

"' lntomt1I Pormlsslblo i=.xposure Limit • Occup::itlonal Snfety and Health Administrl'Jtion, .. Re"'plmbl11t • OSHA 29CFR 1910.1200 SubpartZ ·Toxic and Hazardous Substances

Consult local authorities for acceptable exposure limits.

Exposure limits

ACG!H TLV (United States, 4/2014). TWA: 233 mgim' 8 hours. TWA: 50 ppm 8 hours.

OSHA PEL (United States, 2/2013). TWA: 465 mg/m' 8 hours. TWA: 100 ppm 8 hours.

!PEL (PPG, 4/2009). TWA: 50 ppm

ACGIH TLV (United States, 412014). Absorbed through skin. TWA: 25 ppm 8 hours.

ACGIH TLV (United States, 4/2014). STEL: 200 ppm 15 minutes. TWA: 150 ppm 8 hours.

OSHA PEL (United States, 2/2013). TWA: 710 mg/m' 8 hours. TWA: 150 ppm 8 hours.

ACGIH TLV (United States, 412014). TWA: 3 mg/m' 8 hours. Form: lnhalable

fraction OSHA PEL (United StatH, 2/2013). TWA: 3.5 mg/m' 8 hours.

ACGIH TLV (United States, 4/2014). Skin sensitizer.

STEL: 100 ppm 15 minutes. TWA: 50 ppm 8 hours.

OSHA PEL (United States, 2/2013). TWA: 410 rng/m' 8 hours. TWA: 100 ppm 8 hours.

!PEL (PPG, 10/2012). Absorbed through skin. TWA: 0.5ppm STEL: 1.5 ppm

ACGIH TLV (United States, 4/2014). Skin sensitizer. TWA: 2 ppm 8 hours.

s SR SS

STEL TD TLV TWA

;:; Potentie:I e:kin 11bsorption m R.e:i11pltatoty s.&n:i11!tlzatlon er Skin sun:siltluitlon • Short term Exposure limit V8lues i:::i ToU..1 dust 11 Th1111shold Limit Value • Tlmo Wolghtod Avorago

United State$ Page: 6/151

06/05/2015 2:34PM (GMT-04:00)

06/05/2015 12:34PM FAX 17735216860+ S S I li!l 0015/0023

Product code AU36·FP901 Date of Issue 13 April 2015 Version 3 Product name 2.8/3.5 VOC 2K HS POLYURETHANE TOPCOAT (AUE-360) SF BLACK

Section 8. Exposure controls/personal protection Recommended monitoring procedures

Appropriate engineering controls

Environmental exposure controls

lndlyldual protection measures

HygienEt measures

Eye/face protection Skin protection

Hand protection

Gloves

Body protection

Other skin protection

Respiratory protection

If this product contains ingredients with exposure limits, personal, workplace atmosphere or biological monitoring may be required to determine the effectiveness of the ventilation or other control measures and/or the necessity to use respiratory protective equipment. Reference should be made to appropriate monitoring standards. Reference to national guidance documents for methods for the determination of hazardous substances will also be required.

Use only with ad0quate v00tilation. Use process enclosures. local exhaust ventilation or other engineering controls to keep worker exposure to airborne contaminants below any recommended or statutory limits. The engineering controls also need to keep gas, vapor or dust concentrations below any lower explosive limits. Use explosion-proof ventilation equipment. Emissions from ventilation or work process equipment should be checked to ensure they comply with the requirements of environmental protection legislation. In some cases, fume scrubbers, filters or engineering modifications to the process equipment will be necessary to reduce emissions to acceptable levels.

Wash hands, forearms and face thoroughly after handling chemical products. before eating, smoking and using the lavatory and at the end of the working period. Appropriate techniques should be used to remove potentially contaminated clothing. Wash contaminated clothing before reusing. Ensure that eyewash stations and safety showers are close to the workstation location. Safety glasses with side shields.

Chemical-resistant, impervious gloves complying with an approved standard should be worn at all times when handling chemical products if a risk assessment indicates this is necessary. Considering the parameters specified by the glove manufacturer, check during use that the gloves are still retaining their protective properties. It should be noted that the time to breakthrough for any glove material may be different for different glove manufacturers. In the case of mixtures, consisting of several substances, the protection time of the gloves cannot be accurately estimated. F'Or prolonged or repeated handling, use the following type of gloves:

Recommended: butyl rubber

Personal protective equipment for the body should be selected based on the task being performed and the risks involved and should be approved by a specialist before handling this product. When there is a risk of ignition from static electricity, wear antistatic protective clothing. For the greatest protection from static discharges, clothing should Include anti-static overalls, boots and gloves. Appropriate footwear and any additional skin protection measures should be selected based on the task being performed and the risks involved and should be approved by a specialist before handling this product. Respirator selection must be based on known or anticipated exposure levels, the hazards of the product and the safe working limits of the selected respirator. If workers are exposed to concentrations above the exposure limit, they must use appropriate, certified respirators. Use a properly fitted, air-purifying or air-fed respirator complying with an approved standard if a risk assessment indicates this is necessary.


06/05/2015 2:34PM (GMT-04:00)

06/05/2015 12:34PM FAX 17735216860+ S S I

Product code AU36·FP901 Date of Issue 13 April 2015 Version 3

Product name 2.8/3.5 VOC 2K HS POLYURETHANE TOPCOAT (AUE·360) SF BLACK

\section 9. Physical and chemical properties Appearaace

Physical state

Color

Odor

Odor threshold pH

Melting point

Boiling point

Flash point

Auto·lgnltlon temperature

Decomposition temperature

Flammability (solid, gas)

Lower and upper explO$i11e (flammable) limits

Evaporation rate

Vapor pressure

Vapor density

Relative density

Density ( lbs I gal )

Solubility

Liquid.

Not available.

Not available.

Not available. Not available.

Not available.

:>37.7S"C (>100"F)

Closed cup: 31.11"C (88'F)

Not available.

Not available.

Not available

Lower: 1.3%

0.41 (butyl acetate • 1)

0.47 kPa (3.5 mm Hg) [room temperature]

Not available.

1.02

8.51

Insoluble in the following materials: cold water.

Partition coefficient: n- Not available. octanol/water

Viscosity Kinematic (40'C (104'F)): >0.21 cm'/s (>21 cSt)

Volatility 46% (v/v), 38.82% (w/w)

% Solid. (wiw) 61.18

I Section 1 O. Stability and reactivity

li!J 0016/0023

Reactivity No specific test data related to reactivity available for this product or its Ingredients.

Chemical stablllty

Possibility of ha~ardous reactions

Conditions to avoid

Incompatible materials

Hazardous decomposition products

The product is stable.

Under normal conditions of storage and use, hazardous reactions will not occur.

When exposed to high temperatures may produce hazardous decomposition products.

Refer to protective measures listed in sections 7 and 6.

Keep away from the following materials to prevent strong exothermic reactions: oxldl:?Jng agents, strong alkalis, strong acids.

Decomposition products may include the following materials: carbon monoxide, carbon dioxide, smoke, oxides of nitrogen.

United States Page: 8/15 I

06/05/2015 2:34PM (GMT-04:00)

06/05/2015 12:34PM FAX 17735216860+ S S I li!J 0017 /0023

Product code AU36-FP901 Date of Issue 13 April 2015 Version 3


Section 11. Toxicological information Information on tox!cologjcal effects

Acute> toxicitl£

Product/ingredient name

lll'eptan-2-one

2-methoxy-1-methylethyl acetate

pentane-2.4-dione

n-butyl acetate

carbon black, respirable powder

methyl methacrylate

2-hydroxyethyl acrylate

n-butyl acrylate

Conclusion/Summary

Irritation/Corrosion

Conclusion/Summary Skin Eyes Respiratory

Sensjtizatlon

Conclusl9n£§1100WiU:lr! Skin

Respiratory

Mutagenjcjty

Conclusion/Summary

Cars;jnoqenjcjtv

Conclusion/Summary

Classification

Result Species

LD50 Dermal Rabbit LD50 Oral Rat LD50 Dermal Rabbit

LD50 Oral Rat LC50 Inhalation Vapor Rat LDSO Dermal Rabbit LD50 Oral Rat LC50 Inhalation Vapor Rat LC50 Inhalation Vapor Rat LD50 Dermal Rabbit LD50 Oral Rat LD50 Dermal Rabbit

LD50 Oral Rat LC50 Inhalation V;ipor Rat LDSO Dermal Rabbit LD50 Oral Rat LDSO Dermal Rabbit LD50 Oral Rat LC50 Inhalation Gas. Rat LCSO Inhalation V;ipor Rat LDSO Dermal Rabbit LD50 Oral Rat

There are no data available on the mixture itself.

There are no data available on the mixture itllelf. There are no data available on the mixture itself. There are no data available on the mixture Itself.




There are no data available on the mixture Itself.

Dose

10.206 g/kg 1.6 g/kg >5 g/kg

8532 mg/kg 1225 ppm 787.4 mg/kg 55 mg/kg >21.1 mg/I 2000 ppm >17600 mg/kg 10.768 g/kg >3 g/kg

>15400 mg/kg 78000 mg/m' >5 g/kg 7872 mg/kg 0.154 g/kg 0.54 g/kg 2730 ppm 1970 ppm 2 g/kg 900 mg/kg

United States

Exposure

--. . 4 hours -. 4 hours 4 hours . . . -4 hours -. -. 4 hour.;; 4 hours . .

Page: 91151

06/05/2015 2:34PM (GMT-04:00)

06/05/2015 12:34PM FAX 17735216860+ S S I li!l 0018/0023



Section 11. Toxicological information Product/ingredient name OSHA IARC NTP

Rirbon black, respirable . 26 -powder methyl methacrylate . 3 . n-butyl acrylate . 3 -

Carc:lnog4'1n Clasalflcaitlon eodo:

IARC: 1, ;!A, 21!1, 3, 4 NYf;I: Known to bo"' human e;a.rclnogen; Ro••on11bly ilntlclpatod to bn n humiln carcinogen OSHA:+ Not llstod/not ragulatod: •

Reproductive toxicjtv

Conclusion/Summary

I!lll'l!'!Senlclly Conclusion/Summary


There are no data available on the mixture itself. SDecific taraAt oraan to>eicitv lsinale axcosure)

Name

n-buty\ acetate methyl methacrylate n-butyl acrylate

Specjfjc target grqan toxicity (repeated exposure\

Not available.

Category

Category3 Category3 Category 3

Targm pmans Contains material which causes damage to the following organs: mucous membranes, brain,. Contains material which may cause damage to the following organs; kidneys, the nervous system, peripheral nervous system, upper respiratory tract, Immune system, skin, central nervous system (CNS), eye, lens or cornea.

Atp!ration hazard

Not available.

Information on the likely routes of exposure

p9tentjal ac11Je health eff11ct1

Eye contact No known significant effects or critical hazards. Harmful if inhaled. Inhalation

Skin contact Ingestion

Defatting to the skin. May cause skin dryness and irritation. Harmful if swallowed.

Oyer-exposure signs/symptoms

Eye contact No specific data. Inhalation No specific data. Skin contact Adverse symptoms may include the following;

irritation dryness cracking

Ingestion No specific data.

United States Page: 1011s J

06/05/2015 2:34PM (GMT-04:00)

06/05/2015 12:34PM FAX 17735216860+ S S I li!l 0019/0023

Product code AU36-FP901 Date of issue 13 Aprll 2015 Version 3


Section 11. Toxicological information Delayed and jmmedjate effects and alsQ Cbt2DiC efftcts from short and long term exposure

Conclusion/Summary

SbQrt l!l!•!.l! !!XQQSU[l!

Potential Immediate effects Potential delayed effects

Loog teem exposyrjl Potential immediate effects Potential delayed effects

Pl?tentlal chronic health effects

General

Carcinogenicity

Mutagenicity Teratogenicity Developmental effects Fertility effects

Nymerjc;rl measyres pf toxicjty

Acute toxlclt)l estimates

Route

Oral Dermal Inhalation (gases) Inhalation (vapors) Inhalation idusts and mists\

There are no data available on the mixture itself. Exposure to component solvent vapor concentrations In excess of the stated occupational exposure limit may result in adverse health effects such as mucous membrane and respiratory system irritation and adverse effects on the kidneys, liver and central nervous system. Symptoms and signs include headache, dizziness, fatigue, muscular weakness, drowsiness and, in extreme cases, loss of consciousness. Solvents may cause some of the above effects by absorption through the skin. There is some evidence that repeated exposure to organic solvent vapors in combination with constant loud noise can cause greater hearing loss than expected from exposure to noise alone. If splashed in the eyes, the liquid may cause irritation and reversible damage. Ingestion may cause nausea, diarrhea and vomiting. This takes into account, where known, delayed and immediate effects and also chronic effects of components from short-term and long-term exposure by oral, inhalation and dermal routes of exposure and eye contact.



There are no data available on tho mixture itself.


Prolonged or repeated contact can defat the skin and lead to irritation, cracking and/or dermatitis. Suspected of causing cancer. Risk of cancer depends on duration and level of exposure. No known significant effects or critical hazards. No known significant effects or critical hazards. No known significant effects or critical hazards. No known significant effects or critical hazards.

ATE value

1883.2 mg/kg 7427.7 mg/kg 8816.B ppm 21.55 mg/I 2.939 ma/I

United St<1tes Page: 11/151

06/05/2015 2:34PM (GMT-04:00)

06/05/2015 12:34PM FAX 17735216860+ S S I li!l 0020/0023

Product code AU36-FP901 Date of issue 13 April 2015 Version 3


Section 12. Ecological information

Product/ingredient name Result

2-methoxy-1-methylethyl Acute LC50 161 mg/I Fresh water acetate

Persistence and dtgradabi!itv

Not available.

Eli!!il!CCumulative ootential

Product/Ingredient name

Jl'eptan-2-one 2-methoxy-1-methylethyl acetate pentane-2,4-dione n-butyl acetate methyl melhaorylate 2-hydroxyethyl acrylate n-butyl acrylate

Moblllty In soil Soil/water partition coefficient (Koc)

LogP..,

1.98 0.56

0.4 1.78 1.38 -0.21 2.36

Not available.

!section 13. Disposal considerations

BCF

--

-----

Species

Fish

Potential

low low

low low low low low

Exposure

96 hours

Disposal methods The generation of waste should be avoided or minimized wherever possible. Disposal of this product, solutions and any by·products should at all times comply with the requirements of environmental protection and waste disposal legislation and any regional local authority requirements. Dispose of surplus and non-recyclable products via a licensed waste disposal contractor. Waste should not be disposed of untreated to the sewer unless fully compliant with the requirements of all authorities with jurisdiction. Waste packaging should be recycled. Incineration or landfill should only be considered when recycling is not feasible. This material and its container must be disposed of in a safe way. Care should be taken when handling emptied containers that have not been cleaned or rinsed out. Empty containers or liners may retain some product residues. Vapor from product residues may create a highly flammable or explosive atmosphere inside the container. Do not cut, weld or grind used containers unless they have been cleaned thoroughly intemally. Avoid dispersal of spilled material and runoff and contact with soil, waterways, drains and sewers.

Disposal should be In accordance with applicable regional, national and local laws and regulations,

Refer to Section 7: HANDLING AND STORAGE and Section 8: EXPOSURE CONTROLS/PERSONAL PROTECTION for additional handling information and protection of employees. Section 6. Accidental release measures

United States Page: 12115 I

06/05/2015 2:34PM (GMT-04:00)

06/05/2015 12:35PM FAX 17735216860+ S S I l1ll 0021/0023



14. Transport information DOT IMDG IATA

UN number UN1263 UN1263 UN1263

UN proper shipping PAINT PAINT PAINT name

Transport hazard class 3 3 3 (es)

Packing group 111 Ill 111

environmental hazards No. No. No.

Marine pollutant Not applicable. Not applicable. Not applicable. substances

Additional information DOT None identified.

IMDG None identified.

IATA None identified.

Special precautions for user : Transport within user's premises: always transport in closed containers that are upright and secure. ensure that persons transporting the product know what to do in the event of an accident or spillage.

[Section 15. Regulatory information United States inventory (TSCA Sb) : All components are listed or exempted.

Australia inventory (AICS) : At least one component is not listed.

Canada Inventory ( DSL) : All components are listed or exempted.

China inventory (IECSC) : All components are listed or exempted.

Europe Inventory ( REACH ) : Please contact your supplier for information on the inventorY status of this material.

Japan inventory (ENCS)

Korea Inventory (KECI)

New Zealand ( NZloC )

Philippines inventory (PICCS)

Unjted States

U.S. Federal regulations

: At least one component is not listed.

: All components are listed or exempted.



United States • TSCA 5(a)2 - Proposed significant new use rules: pentane-2,4-dione Listed

SARA 3021304

SARA 304 RQ : Not applicable.

Composjtjon/jnformatjon on inqr11dients

No products were found.

SARA 3111312


06/05/2015 2:34PM (GMT-04:00)

06/05/2015 12:35PM FAX 17735216860+ S S I li!J 0022/0023

Prl)duct Cl)de AU36-FP901 Date of issue 13 Aprll 2015 Version 3

Prl)duet name 2.8/3.5 VOC 2K HS POLYURETHANE TOPCOAT (AUE-360) SF BLACK

Section 15. Regulatory information Classification Fire hazard

Immediate (acute) health hazard Delayed (chronic) health hazard

cow11si11lli2n/inform"tion on ingr4'dl4'nts

Name Fire Sudden hazard release of

pressure

lll'eptan-2-one Yes. No. 2-methoxy-1-methylethyl acetate Yes. No. pentane-2.4-dione Yes. No. n-butyl acetate Yes. No. carbon black. respirable powder Yes. No. methyl methacrylate Yes. No. 2-hydroxyethyl acrylate No. No. n-butyl acrylate Yes. No.

Reactive Immediate Delayed (ac:ute) (chronic) health health halard hazard

No. Yes. No. No. No. No. No. Yes. No. No. Yes. No. No. No. Yes. No. Yes. No. No. Yes. No. Yes. Yes. No.

Additional environmental Information Is contained on the Environmental Data Sheet for this produc:t, which c:an be obtained from your PPG representative.

Ca!jf<:>rnja Prop. 65 WARNING: This product contains a chemical known to the State of California to cause cancer.

I Section 16. Other information Hazardous M11teri11l Information System (U.S.A.)

Health : 3 Flammablllty : 3 Physical hazards 0 ( • ) ·Chronic •rfucta

Cauth;>n: HMIS® r.t1.tlngs are based on a 0-4 rating su.111, with o rapn,111ontlng mlnlmal hazards or risks, and 4 repro.cantlng slgnific.e1nt ho:i:ords or risks Although HMIS® rating:& aro not raqulrad on MSDS• under29 CFR 1910.1200, tho pl'6parar may choo•• to provide them. HMIS® ratings aro to bo uood with • fully implomontod HMIS® program. HMIS® I• a rogl•torad mark of tho No~Qn•I Point & Coatings Association (NPCA). HMIS<ll) matori•ls mu.y be purchased excluslvely from J. J. K1111111111r (BOO) 327""68158.

The customer Is responsible for determining the PPE code for this material.

National Fire Protection Association (U.S.A.)

Health : 3 Flammablllty : 3 Instability : o Date of previous Issue 2/12/2015. Organization that prepared EHS the MSOS

Key to abbreviations ATE= Acute Toxicity Estimate BCF = Bioconcentration Factor GHS = Globally Harmonl~ed System of Classification and Labelling of Chemicals IATA = International Air Transport Association IBC = Intermediate Bulk Container IMDG = International Maritime Dangerous Goods LogF'ow = logarithm of the octanollwater partition coefficient MARPOL 73178 ~ International Convention for the Prevention of Pollution From Ships, 1973 as modified by the Protocol of 1978. ('Marpol" marine pollution) UN = United Nations

11" Indicates Information that has changed from previously Issued version.

United States Piige: 1411 S I

06/05/2015 2:34PM (GMT-04:00)

06/05/2015 12:35PM FAX 17735216860+ S S I li!J 0023/0023

Product c:ode AU36-FP901 Date of Issue 13 April 2015 Version 3


Section 16. Other information pjsc!ajmer

The information contained in this data sheet Is based on present scientific and technical knowledge. The purpose of this information is to draw attention to the health and safety aspacts concerning the products supplied by PPG, and lo recommend precautionary measures for the storage and handling of the products. No warranty or guarantee is given in respect of the properties of Iha products. No liability can be accepted for any failure to observe the precautionary measures described in this data sheet or for any misuse of the products.

United States Page: 151151

06/05/2015 2:34PM (GMT-04:00)

Documents

SAFETY DATA SHEET - Brandenburg Industrial Service Co. data sheets/paint pr… · SAFETY DATA SHEET Date of issue/Date of revision 13 April 2015 Version 3 I Section 1. Identification