Safety data sheet Page 1/4 according to 1907/2006/EC ...sds.staples.com/msds/932600.pdfPage 1/4 Printing date 07.07.2011 Revision: 07.07.2011 Version number 3 Safety data sheet according

Page 1/4

Printing date 07.07.2011Revision: 07.07.2011

Version number 3

Safety data sheetaccording to 1907/2006/EC, Article 31

DR

* 1 Identification of the substance/mixture and of the company/undertaking

· Product identifier

· Trade name: PF 6250 blue 300%· Registration number

The ingredients of this ink have been pre-registered according to 1907/2006/EC (REACH)· Relevant identified uses of the substance or mixture and uses advised against

Currently no such applications are identified· Application of the substance / the preparation pigmented highlighter ink

· Details of the supplier of the safety data sheet· Manufacturer/Supplier:

DOKUMENTAL GmbH & Co KG SchreibfarbenWoellnerstraße 26D-67065 LudwigshafenPhone + 49(0)621/5402321Fax + 49(0)621/5402391www. dokumental.de

· Further information obtainable from:Technical Service, Dr. B. PolzinTel.: +49-621-5402322Mobile +49-1726204412E-Mail: [email protected]

· Emergency telephone number:GBK Gefahrgut Büro GmbH++49 (0) 6132 / 84463Ingelheim, Deutschland

* 2 Hazards identification

· Classification of the substance or mixture

· Classification according to Directive 67/548/EEC or Directive 1999/45/EC Not applicable.· Information concerning particular hazards for human and environment:

The product does not have to be labelled due to the calculation procedure of the "GeneralClassification guideline for preparations of the EU" in the latest valid version.

· Classification system:The classification is according to the latest editions of the EU-lists, and extended by company andliterature data.

· Label elements

· Labelling according to EU guidelines:Observe the general safety regulations when handling chemicals.The product is not subject to identification regulations under EU Directives and the Ordinance onHazardous Materials (German GefStoffV).

· Other hazards· Results of PBT and vPvB assessment· PBT: Not applicable.· vPvB: Not applicable.

3 Composition/information on ingredients

· Chemical characterization: MixturesMixture of the following substances, containing non-hazardous substances and colouring agents.

· Description: Mixture of substances listed below with nonhazardous additions.· Dangerous components:

CAS: 33203-82-6EINECS: 251-403-5

3,7-bis(diethylamino)phenoxazin-5-iumchloride T R25 Acute Tox. 3, H301

≤1,0%

· Additional information: For the wording of the listed risk phrases refer to section 16.

4 First aid measures

· Description of first aid measures· General information: No special measures required.· After inhalation: Supply fresh air; consult doctor in case of complaints.· After skin contact: Generally the product does not irritate the skin.· After eye contact: Rinse opened eye for several minutes under running water.· After swallowing: If symptoms persist consult doctor.· Information for doctor:· Most important symptoms and effects, both acute and delayed

No further relevant information available.(Contd. on page 2)

EU

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Version number 3


Trade name: PF 6250 blue 300%

(Contd. of page 1)

DR

· Indication of any immediate medical attention and special treatment neededNo further relevant information available.

5 Firefighting measures

· Extinguishing media· Suitable extinguishing agents: Use fire extinguishing methods suitable to surrounding conditions.· Special hazards arising from the substance or mixture No further relevant information available.· Advice for firefighters· Protective equipment: No special measures required.

6 Accidental release measures

· Personal precautions, protective equipment and emergency procedures Wear protective clothing.· Environmental precautions: Do not allow to enter sewers/ surface or ground water.· Methods and material for containment and cleaning up:

Absorb with liquid-binding material (sand, diatomite, acid binders, universal binders, sawdust).· Reference to other sections

No dangerous substances are released.See Section 7 for information on safe handling.See Section 8 for information on personal protection equipment.See Section 13 for disposal information.

7 Handling and storage

· Handling:· Precautions for safe handling

No special measures required.Ensure good ventilation/exhaustion at the workplace.

· Information about fire - and explosion protection: No special measures required.

· Conditions for safe storage, including any incompatibilities· Storage:· Requirements to be met by storerooms and receptacles: No special requirements.· Information about storage in one common storage facility: Not required.· Further information about storage conditions: None.· Specific end use(s) No further relevant information available.

8 Exposure controls/personal protection

· Additional information about design of technical facilities: No further data; see item 7.

· Control parameters· Ingredients with limit values that require monitoring at the workplace:

The product does not contain any relevant quantities of materials with critical values that have tobe monitored at the workplace.

· Additional information: The lists valid during the making were used as basis.

· Exposure controls· Personal protective equipment:· General protective and hygienic measures:

The usual precautionary measures are to be adhered to when handling chemicals.· Respiratory protection: Not required.· Protection of hands:

The glove material has to be impermeable and resistant to the product/ the substance/ thepreparation.Due to missing tests no recommendation to the glove material can be given for the product/ thepreparation/ the chemical mixture.Selection of the glove material on consideration of the penetration times, rates of diffusion andthe degradation

· Material of glovesThe selection of the suitable gloves does not only depend on the material, but also on further marksof quality and varies from manufacturer to manufacturer. As the product is a preparation of severalsubstances, the resistance of the glove material can not be calculated in advance and has thereforeto be checked prior to the application.

· Penetration time of glove materialThe exact break trough time has to be found out by the manufacturer of the protective gloves and hasto be observed.

· Eye protection: Goggles recommended during refilling EU

(Contd. on page 3)

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Version number 3



(Contd. of page 2)

DR

* 9 Physical and chemical properties

· Information on basic physical and chemical properties· General Information· Appearance:

Form: FluidColour: According to product specification

· Odour: Product specific· Odour threshold: Not determined.

· Important information on protection of health andenvironment, and on safety. -

-

· pH-value at 20°C: 8,1

· Change in conditionMelting point/Melting range: Undetermined.Boiling point/Boiling range: 100°C

· Flash point: 160°C

· Flammability (solid, gaseous): Not applicable.

· Ignition temperature: 400°C

· Decomposition temperature: Not determined.

· Self-igniting: Product is not selfigniting.

· Danger of explosion: Product does not present an explosion hazard.

· Explosion limits:Lower: 0,9 Vol %Upper: Not determined.

· Vapour pressure at 20°C: 23 hPa

· Density at 20°C: 1,08 g/cm³· Relative density Not determined.· Vapour density Not determined.· Evaporation rate Not determined.

· Solubility in / Miscibility withwater: Not miscible or difficult to mix.

· Segregation coefficient (n-octanol/water): Not determined.

· Viscosity:Dynamic at 20°C: 11 mPasKinematic: Not determined.

· Solvent content:Organic solvents: 27,0 %Water: 17,3 %

Solids content: 0,1 %· Other information ST: 37,3 mN/m

10 Stability and reactivity

· Reactivity· Chemical stability· Thermal decomposition / conditions to be avoided:

No decomposition if used according to specifications.· Possibility of hazardous reactions No dangerous reactions known.· Conditions to avoid No further relevant information available.· Incompatible materials: No further relevant information available.· Hazardous decomposition products: No dangerous decomposition products known.

* 11 Toxicological information

· Information on toxicological effects· Acute toxicity:· Primary irritant effect:· on the skin: No irritant effect.· on the eye: No irritating effect.· Sensitization: No sensitizing effects known.· Additional toxicological information:

The product is not subject to classification according to the calculation method of the General EUClassification Guidelines for Preparations as issued in the latest version.

(Contd. on page 4) EU

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Version number 3



(Contd. of page 3)

DR

When used and handled according to specifications, the product does not have any harmful effects toour experience and the information provided to us.

* 12 Ecological information

· Toxicity· Acquatic toxicity: No further relevant information available.· Persistence and degradability No further relevant information available.· Behaviour in environmental systems:· Bioaccumulative potential No further relevant information available.· Mobility in soil No further relevant information available.· Additional ecological information:· General notes:

Water hazard class 1 (German Regulation) (Self-assessment): slightly hazardous for waterDo not allow undiluted product or large quantities of it to reach ground water, water course orsewage system.

· Results of PBT and vPvB assessment· PBT: Not applicable.· vPvB: Not applicable.· Other adverse effects No further relevant information available.

13 Disposal considerations

· Waste treatment methods· Recommendation Smaller quantities can be disposed of with household waste.

· Uncleaned packaging:· Recommendation: Disposal must be made according to official regulations.

* 14 Transport information

· Land transport ADR/RID (cross-border)· ADR/RID class: -

· Maritime transport IMDG:· IMDG Class: - · Marine pollutant: No

· Air transport ICAO-TI and IATA-DGR:· ICAO/IATA Class: - · Packaging group: -

· Special precautions for user Not applicable.· Transport in bulk according to Annex II of MARPOL73/78 and the IBC Code Not applicable.

15 Regulatory information

· Safety, health and environmental regulations/legislation specific for the substance or mixture

· National regulations:

· Technical instructions (air):Class Share in %

I ≤1.0NK 25-50

· Waterhazard class: Water hazard class 1 (Self-assessment): slightly hazardous for water.· Chemical safety assessment: A Chemical Safety Assessment has not been carried out.

16 Other informationThis information is based on our present knowledge. However, this shall not constitute a guaranteefor any specific product features and shall not establish a legally valid contractual relationship.

· Relevant phrasesH301 Toxic if swallowed.

R25 Toxic if swallowed.· * Data compared to the previous version altered.

EU

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Printing date 07/07/2011Reviewed on 07/07/2011

Material Safety Data Sheetacc. to ISO/DIS 11014

DR



· Trade name: PF 6250 blue 300%· Relevant identified uses of the substance or mixture and uses advised against



DOKUMENTAL GmbH & Co KG SchreibfarbenWoellnerstraße 26D-67065 LudwigshafenPhone + 49 (0)621/5402321Fax + 49 (0)621/5402391www. dokumental.de

· Information department:Technical Service, Dr. B. PolzinTel.: +49-621-5402322Mobile +49-1726204412E-Mail: [email protected]

· Emergency telephone number:GBK Gefahrgut Büro GmbH++49 (0) 6132 / 84463Ingelheim, Deutschland24-hour-Emergency- Telephone-Number (GBK Contract ID: 94050): (001) 352 323 3500



· Description: Mixture of the substances listed below with nonhazardous additions.· Dangerous components:

33203-82-6 3,7-bis(diethylamino)phenoxazin-5-iumchloride ≤1.0%· Additional information: For the wording of the listed risk phrases refer to section 16.





· Classification system:The classification was made according to the latest editions of international substances lists, andexpanded upon from company and literature data.

· Label elements

· Labelling according to EU guidelines:Observe the general safety regulations when handling chemicals.The product is not subject to identification regulations according to directives on hazardousmaterials.

· Classification system:· NFPA ratings (scale 0 - 4)

01

0Health = 0Fire = 1Reactivity = 0

· HMIS-ratings (scale 0 - 4)

HEALTH

FIRE

REACTIVITY

0

1

0

Health = 0Fire = 1Reactivity = 0


· General information: No special measures required.· After inhalation: Supply fresh air; consult doctor in case of complaints.· After skin contact: Generally the product does not irritate the skin.· After eye contact: Rinse opened eye for several minutes under running water.

(Contd. on page 2) USA

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(Contd. of page 1)

DR

· After swallowing: If symptoms persist consult doctor.


· Suitable extinguishing agents: Use fire fighting measures that suit the environment.· Special hazards arising from the substance or mixture No further relevant information available.· Protective equipment: No special measures required.








· Information about protection against explosions and fires: No special measures required.· Storage:· Requirements to be met by storerooms and receptacles: No special requirements.· Information about storage in one common storage facility: Not required.· Further information about storage conditions: None.· Specific end use(s) No further relevant information available.

* 8 Exposure controls/personal protection

· Additional information about design of technical systems: No further data; see item 7.· Components with limit values that require monitoring at the workplace:


· Additional information: The lists that were valid during the creation were used as basis.· Personal protective equipment:· General protective and hygienic measures:

The usual precautionary measures for handling chemicals should be followed.· Breathing equipment: Not required.· Protection of hands:




· Eye protection: Goggles recommended during refilling.


· General Information· Appearance:

Form: FluidColor: According to product specification

· Odor: Product specific(Contd. on page 3)

USA

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(Contd. of page 2)

DR

· Odour threshold: Not determined.


· pH-value at 20°C (68 °F): 8.1

· Change in conditionMelting point/Melting range: Undetermined.Boiling point/Boiling range: 100°C (212 °F)

· Flash point: 160°C (320 °F)


· Ignition temperature: 400°C (752 °F)


· Auto igniting: Product is not selfigniting.


· Explosion limits:Lower: 0.9 Vol %Upper: Not determined.

· Vapor pressure at 20°C (68 °F): 23 hPa (17 mm Hg)

· Density at 20°C (68 °F): 1.08 g/cm³ (9.013 lbs/gal)· Relative density Not determined.· Vapour density Not determined.· Evaporation rate Not determined.

· Solubility in / Miscibility withWater: Not miscible or difficult to mix.

· Segregation coefficient (n-octonol/water): Not determined.

· Viscosity:Dynamic at 20°C (68 °F): 11 mPasKinematic: Not determined.

· Solvent content:Organic solvents: 27.0 %Water: 17.3 %

Solids content: 0.1 %· Other information ST: 37,3 mN/m


· Thermal decomposition / conditions to be avoided:No decomposition if used according to specifications.

· Incompatible materials: No further relevant information available.· Hazardous decomposition products: No dangerous decomposition products known.

* 11 Toxicological information

· Acute toxicity:· Primary irritant effect:· on the skin: No irritant effect.· on the eye: No irritating effect.· Sensitization: No sensitizing effects known.· Additional toxicological information:

The product is not subject to classification according to internally approved calculation methodsfor preparations:When used and handled according to specifications, the product does not have any harmful effectsaccording to our experience and the information provided to us.


· Acquatic toxicity: No further relevant information available.· Persistence and degradability No further relevant information available.· Behavior in environmental systems:· Bioaccumulative potential No further relevant information available.· Additional ecological information:· General notes:

Water hazard class 1 (Self-assessment): slightly hazardous for water(Contd. on page 4)

USA

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(Contd. of page 3)

DR

Do not allow undiluted product or large quantities of it to reach ground water, water course orsewage system.


· Waste treatment methods· Recommendation: Smaller quantities can be disposed of with household waste.

· Uncleaned packagings:· Recommendation: Disposal must be made according to official regulations.


· DOT regulations:· Hazard class: -

· Land transport ADR/RID (cross-border):· ADR/RID class: -



* 15 Regulatory information

· Sara· Section 355 (extremely hazardous substances):

None of the ingredient is listed.

· Section 313 (Specific toxic chemical listings):None of the ingredients is listed.

· TSCA (Toxic Substances Control Act):All ingredients are listed.

· Proposition 65· Chemicals known to cause cancer:

None of the ingredients is listed.

· Chemicals known to cause reproductive toxicity for females:None of the ingredients is listed.

· Chemicals known to cause reproductive toxicity for males:None of the ingredients is listed.

· Chemicals known to cause developmental toxicity:None of the ingredients is listed.

· Cancerogenity categories· EPA (Environmental Protection Agency)


· IARC (International Agency for Research on Cancer)None of the ingredients is listed.

· NTP (National Toxicology Program)None of the ingredients is listed.

· TLV (Threshold Limit Value established by ACGIH)None of the ingredients is listed.

· MAK (German Maximum Workplace Concentration)None of the ingredients is listed.

· NIOSH-Ca (National Institute for Occupational Safety and Health)None of the ingredients is listed.

· OSHA-Ca (Occupational Safety & Health Administration)None of the ingredients is listed.

· Product related hazard informations:Observe the general safety regulations when handling chemicals.The product is not subject to identification regulations according to directives on hazardousmaterials.


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(Contd. of page 4)

DR



I ≤1.0NK 25-50

· Water hazard class: Water hazard class 1 (Self-assessment): slightly hazardous for water.


· * Data compared to the previous version altered. USA

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Version number 2


DR



· Trade name: PF 6210 green 300%· Registration number







2 Hazards identification





· Label elements

· Labelling according to EU guidelines:Observe the general safety regulations when handling chemicals.The product is not subject to identification regulations under EU Directives and the Ordinance onHazardous Materials (German GefStoffV).





CAS: 35869-60-4EINECS: 252-770-4

C.I. Basic Yellow 40 Xi R41 Eye Dam. 1, H318

≤ 2,5%



· Description of first aid measures· General information: No special measures required.· After inhalation: Supply fresh air; consult doctor in case of complaints.· After skin contact: Generally the product does not irritate the skin.· After eye contact: Rinse opened eye for several minutes under running water.· After swallowing: If symptoms persist consult doctor.· Information for doctor:· Most important symptoms and effects, both acute and delayed

No further relevant information available.(Contd. on page 2)

EU

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Version number 2


Trade name: PF 6210 green 300%

(Contd. of page 1)

DR











· Information about fire - and explosion protection: No special measures required.







· Exposure controls· Personal protective equipment:· General protective and hygienic measures:

The usual precautionary measures are to be adhered to when handling chemicals.· Respiratory protection: Not required.· Protection of hands:




· Eye protection: Goggles recommended during refilling EU

(Contd. on page 3)

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Version number 2



(Contd. of page 2)

DR






-










· Vapour pressure at 20°C: 0,1 hPa






Solids content: 1,4 %· Other information ST: 37mN/m




11 Toxicological information

· Information on toxicological effects· Acute toxicity:· Primary irritant effect:· on the skin: No irritant effect.· on the eye: No irritating effect.· Sensitization: No sensitizing effects known.· Additional toxicological information:

The product is not subject to classification according to the calculation method of the General EUClassification Guidelines for Preparations as issued in the latest version.


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Version number 2



(Contd. of page 3)

DR

When used and handled according to specifications, the product does not have any harmful effects toour experience and the information provided to us.

12 Ecological information

· Toxicity· Acquatic toxicity: No further relevant information available.· Persistence and degradability No further relevant information available.· Behaviour in environmental systems:· Bioaccumulative potential No further relevant information available.· Mobility in soil No further relevant information available.· Additional ecological information:· General notes:

Water hazard class 1 (German Regulation) (Self-assessment): slightly hazardous for waterDo not allow undiluted product or large quantities of it to reach ground water, water course orsewage system.



· Waste treatment methods· Recommendation Smaller quantities can be disposed of with household waste.











NK 10-25

· Waterhazard class: Water hazard class 1 (Self-assessment): slightly hazardous for water.· Chemical safety assessment: A Chemical Safety Assessment has not been carried out.


· Relevant phrasesH318 Causes serious eye damage.

R41 Risk of serious damage to eyes.· * Data compared to the previous version altered.

EU

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DR



· Trade name: PF 6210 green 300%· Relevant identified uses of the substance or mixture and uses advised against









35869-60-4 C.I. Basic Yellow 40 ≤ 2.5%· Additional information: For the wording of the listed risk phrases refer to section 16.






· Label elements

· Labelling according to EU guidelines:Observe the general safety regulations when handling chemicals.The product is not subject to identification regulations according to directives on hazardousmaterials.


01



HEALTH

FIRE

REACTIVITY

0

1

0



· General information: No special measures required.· After inhalation: Supply fresh air; consult doctor in case of complaints.· After skin contact: Generally the product does not irritate the skin.· After eye contact: Rinse opened eye for several minutes under running water.


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(Contd. of page 1)

DR

· After swallowing: If symptoms persist consult doctor.










· Information about protection against explosions and fires: No special measures required.· Storage:· Requirements to be met by storerooms and receptacles: No special requirements.· Information about storage in one common storage facility: Not required.· Further information about storage conditions: None.· Specific end use(s) No further relevant information available.




· Additional information: The lists that were valid during the creation were used as basis.· Personal protective equipment:· General protective and hygienic measures:

The usual precautionary measures for handling chemicals should be followed.· Breathing equipment: Not required.· Protection of hands:








· Odor: Product specific(Contd. on page 3)

USA

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(Contd. of page 2)

DR

· Odour threshold: Not determined.


· pH-value at 20°C (68 °F): 6.5









· Vapor pressure at 20°C (68 °F): 0.1 hPa






Solids content: 1.4 %· Other information ST: 37mN/m





· Acute toxicity:· Primary irritant effect:· on the skin: No irritant effect.· on the eye: No irritating effect.· Sensitization: No sensitizing effects known.· Additional toxicological information:

The product is not subject to classification according to internally approved calculation methodsfor preparations:When used and handled according to specifications, the product does not have any harmful effectsaccording to our experience and the information provided to us.


· Acquatic toxicity: No further relevant information available.· Persistence and degradability No further relevant information available.· Behavior in environmental systems:· Bioaccumulative potential No further relevant information available.· Additional ecological information:· General notes:

Water hazard class 1 (Self-assessment): slightly hazardous for water(Contd. on page 4)

USA

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(Contd. of page 3)

DR

Do not allow undiluted product or large quantities of it to reach ground water, water course orsewage system.


· Waste treatment methods· Recommendation: Smaller quantities can be disposed of with household waste.

























· Product related hazard informations:Observe the general safety regulations when handling chemicals.The product is not subject to identification regulations according to directives on hazardousmaterials.


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(Contd. of page 4)

DR



NK 10-25

· Water hazard class: Water hazard class 1 (Self-assessment): slightly hazardous for water.



Page 1/5


Version number 1


DR



· Trade name: PF 6240 pink 300%· Registration number









· Classification according to Directive 67/548/EEC or Directive 1999/45/EC

R52/53: Harmful to aquatic organisms, may cause long-term adverse effects in the aquaticenvironment.

· Information concerning particular hazards for human and environment:The product has to be labelled due to the calculation procedure of the "General Classificationguideline for preparations of the EU" in the latest valid version.


· Label elements

· Labelling according to EU guidelines:The product has been classified and marked in accordance with EU Directives / Ordinance on HazardousMaterials.

· Risk phrases:52/53 Harmful to aquatic organisms, may cause long-term adverse effects in the aquatic environment.

· Safety phrases:60 This material and its container must be disposed of as hazardous waste.61 Avoid release to the environment. Refer to special instructions/safety data sheets.





CAS: 989-38-8EINECS: 213-584-9

C.I. Basic Red 1 Xn R22; Xi R41; N R50/53 Acute Tox. 3, H301; Eye Dam. 1, H318; Aquatic Acute 1, H400;

Aquatic Chronic 1, H410

≤1,0%



· Description of first aid measures· After inhalation: Supply fresh air; consult doctor in case of complaints.· After skin contact: Generally the product does not irritate the skin.


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Version number 1


Trade name: PF 6240 pink 300%

(Contd. of page 1)

DR

· After eye contact: Rinse opened eye for several minutes under running water.· After swallowing: If symptoms persist consult doctor.· Information for doctor:· Most important symptoms and effects, both acute and delayed

No further relevant information available.· Indication of any immediate medical attention and special treatment needed

No further relevant information available.




· Personal precautions, protective equipment and emergency procedures Wear protective clothing.· Environmental precautions:

Inform respective authorities in case of seepage into water course or sewage system.Do not allow to enter sewers/ surface or ground water.

· Methods and material for containment and cleaning up:Absorb with liquid-binding material (sand, diatomite, acid binders, universal binders, sawdust).

· Reference to other sectionsSee Section 7 for information on safe handling.See Section 8 for information on personal protection equipment.See Section 13 for disposal information.


· Handling:· Precautions for safe handling Ensure good ventilation/exhaustion at the workplace.· Information about fire - and explosion protection: No special measures required.







· Exposure controls· Personal protective equipment:· General protective and hygienic measures: Wash hands before breaks and at the end of work.· Respiratory protection: Not required.· Protection of hands:





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Version number 1



(Contd. of page 2)

DR

· Eye protection: Goggles recommended during refilling






-










· Vapour pressure at 20°C: 0,1 hPa






Solids content: 0,8 %· Other information ST: 35,1 mN/m





· Information on toxicological effects· Acute toxicity:· LD/LC50 values relevant for classification:

989-38-8 C.I. Basic Red 1Oral LD50 250 mg/kg (rat)


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(Contd. of page 3)

DR

· Primary irritant effect:· on the skin: No irritant effect.· on the eye: No irritating effect.· Sensitization: No sensitizing effects known.


· Toxicity· Acquatic toxicity:

989-38-8 C.I. Basic Red 1EC50 / 48h 0,1-0,5 mg/l (Daphnie)LC50 / 96h 1-5 mg/l (Fish)

· Persistence and degradability No further relevant information available.· Behaviour in environmental systems:· Bioaccumulative potential No further relevant information available.· Mobility in soil No further relevant information available.· Ecotoxical effects:· Remark: Harmful to fish· Additional ecological information:· General notes:

Water hazard class 2 (German Regulation) (Self-assessment): hazardous for waterDo not allow product to reach ground water, water course or sewage system.Danger to drinking water if even small quantities leak into the ground.Harmful to aquatic organisms



· Waste treatment methods· Recommendation

Must not be disposed together with household garbage. Do not allow product to reach sewage system.











NK 10-25

· Waterhazard class: Water hazard class 2 (Self-assessment): hazardous for water.· Chemical safety assessment: A Chemical Safety Assessment has not been carried out.



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(Contd. of page 4)

DR

· Relevant phrasesH301 Toxic if swallowed.H318 Causes serious eye damage.H400 Very toxic to aquatic life.H410 Very toxic to aquatic life with long lasting effects.

R22 Harmful if swallowed.R41 Risk of serious damage to eyes.R50/53 Very toxic to aquatic organisms, may cause long-term adverse effects in the aquatic

environment.· * Data compared to the previous version altered.

EU

Page 1/5



DR



· Trade name: PF 6240 pink 300%· Relevant identified uses of the substance or mixture and uses advised against









989-38-8 C.I. Basic Red 1 ≤1.0%· Additional information: For the wording of the listed risk phrases refer to section 16.




Harmful to aquatic organisms, may cause long-term adverse effects in the aquatic environment.· Information concerning particular hazards for human and environment:

The product has to be labelled due to the calculation procedure of the "General Classificationguideline for preparations of the EU" in the latest valid version.


· Label elements

· Labelling according to EU guidelines:The product has been classified and marked in accordance with directives on hazardous materials.

· Risk phrases:Harmful to aquatic organisms, may cause long-term adverse effects in the aquatic environment

· Safety phrases:This material and its container must be disposed of as hazardous waste.Avoid release to the environment. Refer to special instructions/Safety data sheets


01



HEALTH

FIRE

REACTIVITY

0

1

0


USA(Contd. on page 2)

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(Contd. of page 1)

DR


· After inhalation: Supply fresh air; consult doctor in case of complaints.· After skin contact: Generally the product does not irritate the skin.· After eye contact: Rinse opened eye for several minutes under running water.· After swallowing: If symptoms persist consult doctor.




· Personal precautions, protective equipment and emergency procedures Wear protective clothing.· Environmental precautions:

Inform respective authorities in case of seepage into water course or sewage system.Do not allow to enter sewers/ surface or ground water.

· Methods and material for containment and cleaning up:Absorb with liquid-binding material (sand, diatomite, acid binders, universal binders, sawdust).



· Handling:· Precautions for safe handling Ensure good ventilation/exhaustion at the workplace.· Information about protection against explosions and fires: No special measures required.· Storage:· Requirements to be met by storerooms and receptacles: No special requirements.· Information about storage in one common storage facility: Not required.· Further information about storage conditions: None.· Specific end use(s) No further relevant information available.




· Additional information: The lists that were valid during the creation were used as basis.· Personal protective equipment:· General protective and hygienic measures: Wash hands before breaks and at the end of work.· Breathing equipment: Not required.· Protection of hands:







Form: Fluid(Contd. on page 3)

USA

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(Contd. of page 2)

DR

Color: According to product specification· Odor: Product specific· Odour threshold: Not determined.


· pH-value at 20°C (68 °F): 6.6









· Vapor pressure at 20°C (68 °F): 0.1 hPa






Solids content: 0.8 %· Other information ST: 35,1 mN/m





· Acute toxicity:· LD/LC50 values that are relevant for classification:

989-38-8 C.I. Basic Red 1Oral LD50 250 mg/kg (rat)

· Primary irritant effect:· on the skin: No irritant effect.· on the eye: No irritating effect.· Sensitization: No sensitizing effects known.


· Acquatic toxicity:989-38-8 C.I. Basic Red 1EC50 / 48h 0.1-0.5 mg/l (Daphnie)LC50 / 96h 1-5 mg/l (Fish)

· Persistence and degradability No further relevant information available.· Behavior in environmental systems:· Bioaccumulative potential No further relevant information available.


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(Contd. of page 3)

DR

· Ecotoxical effects:· Remark: Harmful to fish· Additional ecological information:· General notes:

Water hazard class 2 (Self-assessment): hazardous for waterDo not allow product to reach ground water, water course or sewage system.Danger to drinking water if even small quantities leak into the ground.Harmful to aquatic organisms


· Waste treatment methods· Recommendation:

Must not be disposed of together with household garbage. Do not allow product to reach sewagesystem.










· Section 313 (Specific toxic chemical listings):989-38-8 C.I. Basic Red 181-88-9 C. I. Basic Violet 10



81-88-9 C. I. Basic Violet 10











Page 5/5




(Contd. of page 4)

DR



· Product related hazard informations:The product has been classified and marked in accordance with directives on hazardous materials.

· Risk phrases:Harmful to aquatic organisms, may cause long-term adverse effects in the aquatic environment

· Safety phrases:This material and its container must be disposed of as hazardous waste.Avoid release to the environment. Refer to special instructions/Safety data sheets



NK 10-25

· Water hazard class: Water hazard class 2 (Self-assessment): hazardous for water.



Page 1/6



DR



· Trade name: 29-97-A1 fluorescent yellow concentrate· Relevant identified uses of the substance or mixture and uses advised againstCurrently no such applications are identified

· Application of the substance / the preparation Highlighter Ink

· Details of the supplier of the safety data sheet· Manufacturer/Supplier:SHANGHAI DOKUMENTAL INK Co. Ltd.No. 38 Lane 451 Mao Jia RoadLuodian Town, Baoshan DistrictShanghai 201908 , P.R. ChinaTel.: 86-21-66864551 / 66864542

· Information department:Ms. Cindy SongEmail: [email protected]

· Emergency telephone number:Mr. Bruce GindelbergerTel.: mobile +86-13917914495Email:[email protected]


· Chemical characterization: MixturesMixture of the following substances, containing non-hazardous substances and colouringagents.


584-08-7 potassium carbonate 10-25%26172-55-4 5-chloro-2-methyl-2H-isothiazol-3-one ≤1.0%





Irritant

May cause sensitization by skin contact.· Information concerning particular hazards for human and environment:The product has to be labelled due to the calculation procedure of the "GeneralClassification guideline for preparations of the EU" in the latest valid version.

· Classification system:The classification was made according to the latest editions of international substanceslists, and expanded upon from company and literature data.

· Label elements

· Labelling according to EU guidelines:The product has been classified and marked in accordance with directives on hazardousmaterials.

· Code letter and hazard designation of product:

Irritant

· Hazard-determining components of labelling:5-chloro-2-methyl-2H-isothiazol-3-one

· Risk phrases:May cause sensitization by skin contact.

· Safety phrases:Do not breathe vapour.Avoid contact with skin.Wear suitable gloves.This material and its container must be disposed of as hazardous waste.


Page 2/6



Trade name: 29-97-A1 fluorescent yellow concentrate

(Contd. of page 1)

DR


01



HEALTH

FIRE

REACTIVITY

0

1

0




· Description of first aid measures· After inhalation:Supply fresh air and to be sure call for a doctor.In case of unconsciousness place patient stably in side position for transportation.

· After skin contact: Immediately wash with water and soap and rinse thoroughly.· After eye contact:Rinse opened eye for several minutes under running water. Then consult a doctor.

· After swallowing: If symptoms persist consult doctor.· Information for doctor:· Most important symptoms and effects, both acute and delayedNo further relevant information available.



· Extinguishing media· Suitable extinguishing agents: Use fire fighting measures that suit the environment.· Special hazards arising from the substance or mixtureNo further relevant information available.

· Advice for firefighters· Protective equipment: No special measures required.


· Personal precautions, protective equipment and emergency procedures Wear protective clothing.· Environmental precautions: No special measures required.· Methods and material for containment and cleaning up:Absorb with liquid-binding material (sand, diatomite, acid binders, universal binders,sawdust).Ensure adequate ventilation.



· Handling:· Precautions for safe handlingEnsure good ventilation/exhaustion at the workplace.Prevent formation of aerosols.

· Information about protection against explosions and fires: No special measures required.(Contd. on page 3)

USA

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(Contd. of page 2)

DR



· Additional information about design of technical systems: No further data; see item 7.

· Control parameters· Components with limit values that require monitoring at the workplace:56-81-5 glycerol (10-25%)PEL

TLV

15* 5** mg/m³*total dust **respirable fraction10* ppm*Mist

· Additional information: The lists that were valid during the creation were used as basis.

· Exposure controls· Personal protective equipment:· General protective and hygienic measures:Immediately remove all soiled and contaminated clothing.Wash hands before breaks and at the end of work.

· Breathing equipment:In case of brief exposure or low pollution use respiratory filter device. In case ofintensive or longer exposure use respiratory protective device that is independent ofcirculating air.

· Protection of hands:

Protective gloves

The glove material has to be impermeable and resistant to the product/ the substance/ thepreparation.Due to missing tests no recommendation to the glove material can be given for the product/the preparation/ the chemical mixture.Selection of the glove material on consideration of the penetration times, rates of diffusionand the degradation

· Material of glovesThe selection of the suitable gloves does not only depend on the material, but also onfurther marks of quality and varies from manufacturer to manufacturer. As the product is apreparation of several substances, the resistance of the glove material can not be calculatedin advance and has therefore to be checked prior to the application.

· Penetration time of glove materialThe exact break trough time has to be found out by the manufacturer of the protective glovesand has to be observed.


9 Physical and chemical properties



· Odor: Product specific· Odour threshold: Not determined.

· Important information on protection of healthand environment, and on safety. -

· pH-value: Not determined.

· Change in conditionMelting point/Melting range: Undetermined.


Page 4/6




(Contd. of page 3)

DR

Boiling point/Boiling range: Undetermined.

· Flash point: 160°C (320°F)

· Ignition temperature: 400°C (752°F)





· Vapor pressure at 20°C (68°F): 23 hPa (17 mm Hg)

· Density: Not determined.· Relative density Not determined.· Vapour density Not determined.· Evaporation rate Not determined.



· Viscosity:Dynamic: Not determined.Kinematic: Not determined.


· Other information No further relevant information available.


· Reactivity· Chemical stability· Thermal decomposition / conditions to be avoided:No decomposition if used according to specifications.

· Possibility of hazardous reactions No dangerous reactions known.· Conditions to avoid No further relevant information available.· Incompatible materials: No further relevant information available.· Hazardous decomposition products: No dangerous decomposition products known.


· Information on toxicological effects· Acute toxicity:· Primary irritant effect:· on the skin: No irritant effect.· on the eye: No irritating effect.· Sensitization: Sensitization possible through skin contact.· Additional toxicological information:The product shows the following dangers according to internally approved calculation methodsfor preparations:Irritant


· Toxicity· Acquatic toxicity: No further relevant information available.· Persistence and degradability No further relevant information available.· Behavior in environmental systems:· Bioaccumulative potential No further relevant information available.· Mobility in soil No further relevant information available.· Results of PBT and vPvB assessment· PBT: Not applicable.· vPvB: Not applicable.


Page 5/6




(Contd. of page 4)

DR

· Other adverse effects No further relevant information available.


· Waste treatment methods· Recommendation:Must not be disposed of together with household garbage. Do not allow product to reach sewagesystem.






· Air transport ICAO-TI and IATA-DGR:· ICAO/IATA Class: - · Packaging group: not applicable



· Safety, health and environmental regulations/legislation specific for the substance ormixture

· Sara· Section 355 (extremely hazardous substances):None of the ingredient is listed.



· Proposition 65· Chemicals known to cause cancer:None of the ingredients is listed.




· Cancerogenity categories· EPA (Environmental Protection Agency)None of the ingredients is listed.






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(Contd. of page 5)

DR



· Product related hazard informations:The product has been classified and marked in accordance with directives on hazardousmaterials.

· Hazard symbols:

Irritant


· Risk phrases:May cause sensitization by skin contact.

· Safety phrases:Do not breathe vapour.Avoid contact with skin.Wear suitable gloves.This material and its container must be disposed of as hazardous waste.


· Technical instructions (air):Class Share in %NK 10-25

· Chemical safety assessment: A Chemical Safety Assessment has not been carried out.

16 Other informationThis information is based on our present knowledge. However, this shall not constitute aguarantee for any specific product features and shall not establish a legally validcontractual relationship.


Page 1/5


Version number 3


DR



· Trade name: 29-97-A1 fluorescent yellow concentrate· Registration numberThe ingredients of this ink have been pre-registered according to 1907/2006/EC (REACH)

· Relevant identified uses of the substance or mixture and uses advised againstCurrently no such applications are identified

· Application of the substance / the preparation Highlighter Ink

· Details of the supplier of the safety data sheet· Manufacturer/Supplier:SHANGHAI DOKUMENTAL INK Co. Ltd.No. 38 Lane 451 Mao Jia RoadLuodian Town, Baoshan DistrictShanghai 201908 , P.R. ChinaTel.: 86-21-66864551 / 66864542

· Further information obtainable from:Ms. Cindy SongEmail: [email protected]

· Emergency telephone number:Mr. Bruce GindelbergerTel.: mobile +86-13917914495Email:[email protected]




Xi; Sensitising

R43: May cause sensitisation by skin contact.· Information concerning particular hazards for human and environment:The product has to be labelled due to the calculation procedure of the "GeneralClassification guideline for preparations of the EU" in the latest valid version.

· Classification system:The classification is according to the latest editions of the EU-lists, and extended bycompany and literature data.

· Label elements

· Labelling according to EU guidelines:The product has been classified and marked in accordance with EU Directives / Ordinance onHazardous Materials.

· Code letter and hazard designation of product:

Xi Irritant


· Risk phrases:43 May cause sensitisation by skin contact.

· Safety phrases:23 Do not breathe vapour.24 Avoid contact with skin.37 Wear suitable gloves.60 This material and its container must be disposed of as hazardous waste.


EU(Contd. on page 2)

Page 2/5


Version number 3



(Contd. of page 1)

DR


· Chemical characterization: MixturesMixture of the following substances, containing non-hazardous substances and colouringagents.

· Description: Mixture of substances listed below with nonhazardous additions.· Dangerous components:CAS: 584-08-7EINECS: 209-529-3

potassium carbonate Xi R36/37/38 Skin Irrit. 2, H315; Eye Irrit. 2, H319; STOT SE 3, H335

10-25%

CAS: 26172-55-4EINECS: 247-500-7

5-chloro-2-methyl-2H-isothiazol-3-one T R23/24/25; C R34; Xi R43; N R50/53 Acute Tox. 3, H301; Acute Tox. 3, H311; Acute Tox. 3, H331; Skin Corr. 1B, H314; Aquatic Acute 1, H400; Aquatic

Chronic 1, H410; Skin Sens. 1, H317

≤1,0%



· Description of first aid measures· After inhalation:Supply fresh air and to be sure call for a doctor.In case of unconsciousness place patient stably in side position for transportation.

· After skin contact: Immediately wash with water and soap and rinse thoroughly.· After eye contact:Rinse opened eye for several minutes under running water. Then consult a doctor.

· After swallowing: If symptoms persist consult doctor.· Information for doctor:· Most important symptoms and effects, both acute and delayedNo further relevant information available.



· Extinguishing media· Suitable extinguishing agents:Use fire extinguishing methods suitable to surrounding conditions.

· Special hazards arising from the substance or mixtureNo further relevant information available.

· Advice for firefighters· Protective equipment: No special measures required.


· Personal precautions, protective equipment and emergency procedures Wear protective clothing.· Environmental precautions: No special measures required.· Methods and material for containment and cleaning up:Absorb with liquid-binding material (sand, diatomite, acid binders, universal binders,sawdust).Ensure adequate ventilation.



· Handling:· Precautions for safe handlingEnsure good ventilation/exhaustion at the workplace.Prevent formation of aerosols.

· Information about fire - and explosion protection: No special measures required.(Contd. on page 3)

EU

Page 3/5


Version number 3



(Contd. of page 2)

DR




· Control parameters· Ingredients with limit values that require monitoring at the workplace:The product does not contain any relevant quantities of materials with critical values thathave to be monitored at the workplace.


· Exposure controls· Personal protective equipment:· General protective and hygienic measures:Immediately remove all soiled and contaminated clothingWash hands before breaks and at the end of work.

· Respiratory protection:In case of brief exposure or low pollution use respiratory filter device. In case ofintensive or longer exposure use self-contained respiratory protective device.

· Protection of hands:

Protective gloves

The glove material has to be impermeable and resistant to the product/ the substance/ thepreparation.Due to missing tests no recommendation to the glove material can be given for the product/the preparation/ the chemical mixture.Selection of the glove material on consideration of the penetration times, rates of diffusionand the degradation

· Material of glovesThe selection of the suitable gloves does not only depend on the material, but also onfurther marks of quality and varies from manufacturer to manufacturer. As the product is apreparation of several substances, the resistance of the glove material can not be calculatedin advance and has therefore to be checked prior to the application.

· Penetration time of glove materialThe exact break trough time has to be found out by the manufacturer of the protective glovesand has to be observed.

· Eye protection: Goggles recommended during refilling





· Important information on protection of healthand environment, and on safety. -

-

· pH-value: Not determined.

· Change in conditionMelting point/Melting range: Undetermined.Boiling point/Boiling range: Undetermined.


· Ignition temperature: 400°C(Contd. on page 4)

EU

Page 4/5


Version number 3



(Contd. of page 3)

DR





· Vapour pressure at 20°C: 23 hPa

· Density: Not determined.· Relative density Not determined.· Vapour density Not determined.· Evaporation rate Not determined.



· Viscosity:Dynamic: Not determined.Kinematic: Not determined.


· Other information No further relevant information available.


· Reactivity· Chemical stability· Thermal decomposition / conditions to be avoided:No decomposition if used according to specifications.

· Possibility of hazardous reactions No dangerous reactions known.· Conditions to avoid No further relevant information available.· Incompatible materials: No further relevant information available.· Hazardous decomposition products: No dangerous decomposition products known.


· Information on toxicological effects· Acute toxicity:· Primary irritant effect:· on the skin: No irritant effect.· on the eye: No irritating effect.· Sensitization: Sensitization possible through skin contact.· Additional toxicological information:The product shows the following dangers according to the calculation method of the General EUClassification Guidelines for Preparations as issued in the latest version:Irritant

· Sensitisation May cause sensitisation by skin contact.


· Toxicity· Acquatic toxicity: No further relevant information available.· Persistence and degradability No further relevant information available.· Behaviour in environmental systems:· Bioaccumulative potential No further relevant information available.· Mobility in soil No further relevant information available.· Results of PBT and vPvB assessment· PBT: Not applicable.· vPvB: Not applicable.


Page 5/5


Version number 3



(Contd. of page 4)

DR

· Other adverse effects No further relevant information available.


· Waste treatment methods· RecommendationMust not be disposed together with household garbage. Do not allow product to reach sewagesystem.





· Air transport ICAO-TI and IATA-DGR:· ICAO/IATA Class: - · Packaging group: not applicable



· Safety, health and environmental regulations/legislation specific for the substance ormixture


· Technical instructions (air):Class Share in %NK 10-25

· Chemical safety assessment: A Chemical Safety Assessment has not been carried out.

16 Other informationThis information is based on our present knowledge. However, this shall not constitute aguarantee for any specific product features and shall not establish a legally validcontractual relationship.

· Relevant phrasesH301 Toxic if swallowed.H311 Toxic in contact with skin.H314 Causes severe skin burns and eye damage.H315 Causes skin irritation.H317 May cause an allergic skin reaction.H319 Causes serious eye irritation.H331 Toxic if inhaled.H335 May cause respiratory irritation.H400 Very toxic to aquatic life.H410 Very toxic to aquatic life with long lasting effects.

R23/24/25 Toxic by inhalation, in contact with skin and if swallowed.R34 Causes burns.R36/37/38 Irritating to eyes, respiratory system and skin.R43 May cause sensitisation by skin contact.R50/53 Very toxic to aquatic organisms, may cause long-term adverse effects in the aquatic

environment.· * Data compared to the previous version altered.

EU

Documents

Safety data sheet Page 1/4 according to 1907/2006/EC ...sds.staples.com/msds/932600.pdfPage 1/4 Printing date 07.07.2011 Revision: 07.07.2011 Version number 3 Safety data sheet according