Safety Data Sheet PLANIBOND EBA PART A 1. IDENTIFICATION

Safety Data Sheet

PLANIBOND EBA PART A

Safety Data Sheet dated: 2/10/2016 - version 3

Date of first edition: 5/26/2015

1. IDENTIFICATION

Product identifier

Mixture identification:

Trade name: PLANIBOND EBA PART A

Recommended use of the chemical and restrictions on use

Recommended use: Epoxy resins

Restrictions on use: N.A.

Name, address, and telephone number of the chemical manufacturer, importer, or other responsible party

Company: MAPEI CORP. (USA and Puerto Rico)

1144 East Newport Center Drive

33442 - Deerfield Beach - FL - USA

Phone: 954-246-8888

Emergency 24 hour numbers:

(USA) CHEMTREC 1-800-424-9300(Canada) CANUTEC 1-613-996-6666

2. HAZARD(S) IDENTIFICATION

Classification of the chemical

Label elements

Skin Irrit. 2 Causes skin irritation.

Eye Irrit. 2A Causes serious eye irritation.

Skin Sens. 1A May cause an allergic skin reaction.

Muta. 2 Suspected of causing genetic defects if inhaled, in contact with skin and if swallowed.

Aquatic Chronic 2 Toxic to aquatic life with long lasting effects.

Symbols:

Warning

Code Description

H315 Causes skin irritation.

H317 May cause an allergic skin reaction.

H319 Causes serious eye irritation.

H341.G Suspected of causing genetic defects if inhaled, in contact with skin and if swallowed.

H411 Toxic to aquatic life with long lasting effects.

Code Description

P201 Obtain special instructions before use.

P202 Do not handle until all safety precautions have been read and understood.

P261.1 Avoid breathing mist/vapours/spray.

P264.2 Wash skin thoroughly after handling.

P272 Contaminated work clothing should not be allowed out of the workplace.

P273 Avoid release to the environment.

P280.I Wear protective gloves and eye protection.

P302+P352.A IF ON SKIN: Wash with plenty of water.

P305+P351+P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.

P308+P313 IF exposed or concerned: Get medical advice/attention.

Page n. of1 82/10/2016 Production Name PLANIBOND EBA PART ADate

Ingredient(s) with unknown acute toxicity:

None

Hazards not otherwise classified identified during the classification process:

None

This product contains titanium dioxide which IARC has classified as a Group 2B carcinogen (possibly carcinogenic to humans). Evidence isbased on sufficient animal testing as a result of long-term inhalation at high concentrations of respirable amounts of titanium dioxide.Because this product is in liquid or paste form, it does not pose a dust hazard; therefore, this classification is not relevant. (Note: sanding ofthe hardened product may create a dust hazard)

P321.A Specific treatment (see supplementary instructions on this label).

P333+P313 If skin irritation or rash occurs: Get medical advice/attention.

P337+P313 If eye irritation persists: Get medical advice/attention.

P362+P364 Take off contaminated clothing and wash it before reuse.

P391 Collect spillage.

P405 Store locked up.

P501.A Dispose of contents/container in accordance with applicable regulations.

3. COMPOSITION/INFORMATION ON INGREDIENTS

Substances

N.A.

Mixtures

Hazardous components within the meaning of 29 CFR 1910.1200 and related classification:

List of components

Quantity Name Ident. Numb. Classification

70-80 % Bisphenol A epoxy resin CAS:25085-99-8 Skin Sens. 1B; Skin Irrit. 2, H315; Eye Irrit.2A, H319; Aquatic Chronic 2, H411

20-30 % o-Cresylglycidyl ether CAS:2210-79-9 Skin Irrit. 2, H315; Skin Sens. 1A, H317;Muta. 2, H341

0.1-1 % Titanium dioxide CAS:13463-67-7 Carc. 2, H351

4. FIRST AID MEASURES

Description of first aid measures

In case of skin contact:

Immediately take off all contaminated clothing.

Obtain medical attention if skin related symptoms persist.

Remove contaminated clothing immediately and dispose of safely.

After contact with skin, wash immediately with soap and plenty of water.

In case of eyes contact:

After contact with the eyes, rinse with water with the eyelids open for a sufficient length of time, then consult an opthalmologistimmediately.

Protect uninjured eye.

In case of Ingestion:

Do not induce vomiting, get medical attention showing the SDS and the hazard label.

In case of Inhalation:

Remove casualty to fresh air and keep warm and at rest.

Most important symptoms/effects, acute and delayed

Eye irritation

Eye damages

Skin Irritation

Erythema

Indication of any immediate medical attention and special treatment needed

In case of accident or unwellness, seek medical advice immediately (show directions for use or safety data sheet if possible).

5. FIRE-FIGHTING MEASURES

Extinguishing media

Suitable extinguishing media:

Water.

Carbon dioxide (CO2).

Unsuitable extinguishing media:

None in particular.

Specific hazards arising from the chemical

Do not inhale explosion and combustion gases.

Burning produces heavy smoke.

Hazardous combustion products: N.A.Page n. of2 82/10/2016 Production Name PLANIBOND EBA PART ADate

Hazardous combustion products: N.A.

Explosive properties: N.A.

Oxidizing properties: N.A.

Special protective equipment and precautions for fire-fighters

Use suitable breathing apparatus.

Collect contaminated fire extinguishing water separately. This must not be discharged into drains.

Move undamaged containers from immediate hazard area if it can be done safely.

6. ACCIDENTAL RELEASE MEASURES

Personal precautions, protective equipment and emergency procedures

Wear personal protection equipment.

Remove persons to safety.

See protective measures under point 7 and 8.

Methods and material for containment and cleaning up

Suitable material for taking up: absorbing material, organic, sand

Wash with plenty of water.

7. HANDLING AND STORAGE

Precautions for safe handling

Avoid contact with skin and eyes, inhalation of vapours and mists.

Exercise the greatest care when handling or opening the container.

Don't use empty container before they have been cleaned.

Before making transfer operations, assure that there aren't any incompatible material residuals in the containers.

Contamined clothing should be changed before entering eating areas.

Do not eat or drink while working.

See also section 8 for recommended protective equipment.

Conditions for safe storage, including any incompatibilities

Storage temperature: N.A.

Incompatible materials:

None in particular.

Instructions as regards storage premises:

Adequately ventilated premises.

8. EXPOSURE CONTROLS/PERSONAL PROTECTION

Control parameters

Appropriate engineering controls: N.A.

Individual protection measures

Eye protection:

Use close fitting safety goggles, don't use eye lens.

Protection for skin:

Use clothing that provides comprehensive protection to the skin, e.g. cotton, rubber, PVC or viton.

Protection for hands:

Use protective gloves that provides comprehensive protection, e.g. P.V.C., neoprene or rubber.

Respiratory protection:

N.A.

List of components with OEL value

Component OEL Type Country Ceiling Long Termmg/m3

Long Termppm

Short Termmg/m3

Short Termppm

Behaviour Note

Titanium dioxide OSHA 15

ACGIH 10 A4 - Not Classifiable as aHuman Carcinogen;lowerrespiratory tract irritation;

9. PHYSICAL AND CHEMICAL PROPERTIES

Information on basic physical and chemical properties

Physical state: Liquid

Appearance and colour: Viscous white

Odour: characteristic

Odour threshold: N.A.

pH: N.A.

Melting point / freezing point: N.A.

Initial boiling point and boiling range: N.A.

Flash point: >100 °C (212 °F)


Evaporation rate: N.A.

Upper/lower flammability or explosive limits: N.A.

Vapour density: N.A.

Vapour pressure: N.A.

Relative density: 1.17 g/cm3

Solubility in water: N.A.

Solubility in oil: N.A.

Partition coefficient (n-octanol/water): N.A.

Auto-ignition temperature: N.A.

Decomposition temperature: N.A.

Viscosity: N.A.



Solid/gas flammability: N.A.

Other information

Substance groups relevant properties: N.A.

Miscibility: N.A.

Fat Solubility: N.A.

Conductivity: N.A.

10. STABILITY AND REACTIVITY

Reactivity

Stable under normal conditions

Chemical stability

Data not Available.

Possibility of hazardous reactions

None.

Conditions to avoid

Stable under normal conditions.

Incompatible materials

None in particular.

Hazardous decomposition products

None.

11. TOXICOLOGICAL INFORMATION

Information on toxicological effects

Toxicological information of the mixture:

There is no toxicological data available on the mixture. Consider the individual concentration of each component to assesstoxicological effects resulting from exposure to the mixture.

Toxicological information on main components of the mixture:

o-Cresylglycidyl ether a) acute toxicity LC50 Inhalation Rat = 6090mg/m3 4h

Titanium dioxide a) acute toxicity LD50 Oral Rat > 10000mg/kg

If not differently specified, the information required in the regulation and listed below must be considered as N.A.

a) acute toxicity

b) skin corrosion/irritation

c) serious eye damage/irritation

d) respiratory or skin sensitisation

e) germ cell mutagenicity

f) carcinogenicity

g) reproductive toxicity

h) STOT-single exposure

i) STOT-repeated exposure

j) aspiration hazard

Substance(s) listed on the IARC Monographs:

Titanium dioxide Group 2B

Substance(s) listed as OSHA Carcinogen(s):


Titanium dioxide

Substance(s) listed as NIOSH Carcinogen(s):

Titanium dioxide

Substance(s) listed on the NTP report on Carcinogens:

None

12. ECOLOGICAL INFORMATION

Toxicity

Adopt good working practices, so that the product is not released into the environment.

Eco-Toxicological Information:

Persistence and degradability

Bioaccumulative potential

Mobility in soil

Other adverse effects

N.A.

List of Eco-Toxicological properties of the product

No Data Available

N.A.

N.A.

N.A.

13. DISPOSAL CONSIDERATIONS

Waste treatment methods

Waste must be handled in accordance with all federal, state, provincial, and local regulations. Consult authorities before disposal.

14. TRANSPORT INFORMATION

UN number

ADR-UN number: 3082

DOT-UN Number: UN3082

IATA-Un number: 3082

IMDG-Un number: 3082

UN proper shipping name

ADR-Shipping Name: ENVIRONMENTALLY HAZARDOUS SUBSTANCE, LIQUID, N.O.S. (Bisphenol A epoxy resin)

DOT-Proper Shipping Name: Environmentally hazardous substance, liquid, n.o.s. (Bisphenol A epoxy resin)

IATA-Technical name: ENVIRONMENTALLY HAZARDOUS SUBSTANCE, LIQUID, N.O.S. (Bisphenol A epoxy resin)

IMDG-Technical name: ENVIRONMENTALLY HAZARDOUS SUBSTANCE, LIQUID, N.O.S. (Bisphenol A epoxy resin)

Transport hazard class(es)

ADR-Class: 9

DOT-Hazard Class: 9

IATA-Class: 9

IMDG-Class: 9

Packing group

ADR-Packing Group: III

DOT-Packing group: III

IATA-Packing group: III

IMDG-Packing group: III

Environmental hazards

Marine pollutant: Yes

Environmental Pollutant: N.A.

Transport in bulk according to Annex II of MARPOL73/78 and the IBC Code

N.A.

Special precautions

Department of Transportation (DOT):

DOT-Special Provision(s): 8, 146, 173, 335, IB3, T4, TP1

DOT-Label(s): 9

DOT-Symbol: N/A

DOT-Cargo Aircraft: N/A



DOT-Passenger Aircraft: N/A

DOT-Bulk: N/A

DOT-Non-Bulk: N/A

Road and Rail (ADR-RID):

ADR exempt: No

ADR-Label: 9

ADR-Hazard identification number: 90

ADR-Tunnel Restriction Code: 3 (E)

Air (IATA):

IATA-Passenger Aircraft: 964

IATA-Cargo Aircraft: 964

IATA-Label: 9

IATA-Subrisk: -

IATA-Erg: 9L

IATA-Special Provisions: A97 A158

Sea (IMDG):

IMDG-Stowage Code: Category A

IMDG-Stowage Note: -

IMDG-Subrisk: -

IMDG-Special Provisions: 274 335

IMDG-Page: N/A

IMDG-Label: 9

IMDG-EMS: F-A, S-F

IMDG-MFAG: N/A

15. REGULATORY INFORMATION

USA - Federal regulations

TSCA - Toxic Substances Control Act

SARA - Superfund Amendments and Reauthorization Act

CERCLA - Comprehensive Environmental Response, Compensation, and Liability Act

CAA - Clean Air Act

CWA - Clean Water Act

USA - State specific regulations

TSCA inventory:

All the components are listed on the TSCA inventory

TSCA listed substances:

Bisphenol A epoxy resin is listed in TSCA Section 8b

o-Cresylglycidyl ether is listed in TSCA Section 8b, Section 8a - PAIR

Titanium dioxide is listed in TSCA Section 8b

Section 302 - Extremely Hazardous Substances:

no substances listed

Section 304 - Hazardous substances:


Section 313 - Toxic chemical list:


Substance(s) listed under CERCLA:


CAA listed substances:


CWA listed substances:



California Proposition 65

Massachusetts Right to know

Pennsylvania Right to know

New Jersey Right to know

Canada- Federal regulations

DSL - Domestic Substances List

NDSL - Non Domestic Substances List

NPRI - National Pollutant Release Inventory

Substance(s) listed under California Proposition 65:

Titanium dioxide Listed as carcinogen

Substance(s) listed under Massachusetts Right to know:

Titanium dioxide

Substance(s) listed under Pennsylvania Right to know:

Titanium dioxide

Substance(s) listed under New Jersey Right to know:

Titanium dioxide

DSL Inventory:

All the substances are listed in the DSL.

NDSL Inventory:


Substances listed in NPRI:


16. OTHER INFORMATION


Product code: 2254

Additional classification information

HMIS Health: 1 = Slight

HMIS Health - Is health hazard chronic?: No

HMIS Flammability: 1 = Combustible if heated

HMIS Reactivity: 0 = Minimal

HMIS P.P.E.: Safety glasses, gloves

NFPA Health: 1 = Slight

NFPA Flammability: 1 = Combustible if heated

NFPA Reactivity: 0 = Minimal

NFPA Special Risk: N.A.

Reasonable care has been taken in the preparation of this information, but the manufacturer makes no warranty of merchantability or anyother warranty, expressed or implied, with respect to this information. The manufacturer makes no representations and assumes no liabilityfor any direct, incidental or consequential damages resulting from its use. The information herein is presented in good faith and believed tobe accurate as of the effective date given. It is the buyer's responsibility to ensure that its activities comply with Federal, State or provincial,and local laws.

Code Description




H341 Suspected of causing genetic defects .

H341.G Suspected of causing genetic defects if inhaled, in contact with skin and if swallowed.

H351 Suspected of causing cancer .

H411 Toxic to aquatic life with long lasting effects.


for any direct, incidental or consequential damages resulting from its use. The information herein is presented in good faith and believed tobe accurate as of the effective date given. It is the buyer's responsibility to ensure that its activities comply with Federal, State or provincial,and local laws.

This document was prepared by a competent person who has received appropriate training.

It is the duty of the user to ensure that this information is appropriate and complete with respect to the specific use intended.

This SDS cancels and replaces any preceding release.

Legend to abbreviations and acronyms used in the safety data sheet:

ADR: European Agreement concerning the International Carriage of Dangerous Goods by Road.

RID: Regulation Concerning the International Transport of Dangerous Goods by Rail.

IMDG: International Maritime Code for Dangerous Goods.

IATA: International Air Transport Association.

IATA-DGR: Dangerous Goods Regulation by the "International Air Transport Association" (IATA).

ICAO: International Civil Aviation Organization.

ICAO-TI: Technical Instructions by the "International Civil Aviation Organization" (ICAO).

GHS: Globally Harmonized System of Classification and Labeling of Chemicals.

CLP: Classification, Labeling, Packaging.

EINECS: European Inventory of Existing Commercial Chemical Substances.

INCI: International Nomenclature of Cosmetic Ingredients.

CAS: Chemical Abstracts Service (division of the American Chemical Society).

GefStoffVO: Ordinance on Hazardous Substances, Germany.

LC50: Lethal concentration, for 50 percent of test population.

LD50: Lethal dose, for 50 percent of test population.

DNEL: Derived No Effect Level.

PNEC: Predicted No Effect Concentration.

TLV: Threshold Limiting Value.

TWATLV: Threshold Limit Value for the Time Weighted Average 8 hour day. (ACGIH Standard).

STEL: Short Term Exposure limit.

STOT: Specific Target Organ Toxicity.

WGK: German Water Hazard Class.

KSt: Explosion coefficient.

Paragraphs modified from the previous revision:

- 1. IDENTIFICATION OF THE SUBSTANCE/PREPARATION AND OF THE COMPANY/UNDERTAKING

- 3. COMPOSITION/INFORMATION ON INGREDIENTS

- 11. TOXICOLOGICAL INFORMATION

- 15. REGULATORY INFORMATION


Safety Data Sheet

PLANIBOND EBA PART B


Date of first edition: 5/26/2015

1. IDENTIFICATION

Product identifier

Mixture identification:

Trade name: PLANIBOND EBA PART B

Recommended use of the chemical and restrictions on use

Recommended use: Hardener for epoxy products

Restrictions on use: N.A.

Name, address, and telephone number of the chemical manufacturer, importer, or other responsible party

Company: MAPEI CORP. (USA and Puerto Rico)

1144 East Newport Center Drive

33442 - Deerfield Beach - FL - USA

Phone: 954-246-8888

Emergency 24 hour numbers:

(USA) CHEMTREC 1-800-424-9300(Canada) CANUTEC 1-613-996-6666

2. HAZARD(S) IDENTIFICATION

Classification of the chemical

Label elements

Skin Irrit. 2 Causes skin irritation.

Eye Dam. 1 Causes serious eye damage.

Skin Sens. 1A May cause an allergic skin reaction.

Repr. 2 Suspected of damaging fertility. Suspected of damaging the unborn child.

Symbols:

Danger

Code Description



H318 Causes serious eye damage.

H361fd Suspected of damaging fertility. Suspected of damaging the unborn child.

Code Description

P201 Obtain special instructions before use.

P202 Do not handle until all safety precautions have been read and understood.

P261.B Avoid breathing dust.

P264.2 Wash skin thoroughly after handling.

P272 Contaminated work clothing should not be allowed out of the workplace.

P280.I Wear protective gloves and eye protection.

P302+P352.A IF ON SKIN: Wash with plenty of water.

P305+P351+P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.

P308+P313 IF exposed or concerned: Get medical advice/attention.

P310.A Immediately call a POISON CENTER.

P321.A Specific treatment (see supplementary instructions on this label).

P333+P313 If skin irritation or rash occurs: Get medical advice/attention.

Page n. of1 92/11/2016 Production Name PLANIBOND EBA PART BDate

Ingredient(s) with unknown acute toxicity:

None

Hazards not otherwise classified identified during the classification process:

None

This product contains titanium dioxide which IARC has classified as a Group 2B carcinogen (possibly carcinogenic to humans). Evidence isbased on sufficient animal testing as a result of long-term inhalation at high concentrations of respirable amounts of titanium dioxide.Because this product is in liquid or paste form, it does not pose a dust hazard; therefore, this classification is not relevant. (Note: sanding ofthe hardened product may create a dust hazard)

P362+P364 Take off contaminated clothing and wash it before reuse.

P405 Store locked up.

P501.A Dispose of contents/container in accordance with applicable regulations.

3. COMPOSITION/INFORMATION ON INGREDIENTS

Substances

N.A.

Mixtures

Hazardous components within the meaning of 29 CFR 1910.1200 and related classification:

List of components

Quantity Name Ident. Numb. Classification

30-40 % Fatty acids, tall-oil, polymers with bisphenol A,diethylenetriamine, epichlorohydrin andtetraethylenepentamine

CAS:68951-85-9 Skin Irrit. 2, H315; Eye Irrit. 2A, H319

1-5 % Titanium dioxide CAS:13463-67-7 Carc. 2, H351

1-5 % Dipropylene glycol dibenzoate CAS:27138-31-4 Aquatic Chronic 3, H412

1-5 % Diethylene triamine CAS:111-40-0 Skin Corr. 1B, H314; Acute Tox. 4, H312; EyeDam. 1, H318; Skin Sens. 1B, H317; Repr. 2,H361; STOT SE 3, H335; Aquatic Chronic 3,H412; Acute Tox. 4, H302; Acute Tox. 2,H330

1-5 % 2,4,6-Tri(dimethylaminomethyl)phenol CAS:90-72-2 Skin Corr. 1B, H314; Skin Sens. 1A, H317;Aquatic Chronic 3, H412

0.1-1 % 3-(Dimethylamino)-propylamine CAS:109-55-7 Flam. Liq. 3, H226; Skin Corr. 1B, H314; SkinSens. 1, H317; Acute Tox. 4, H302; AcuteTox. 4, H312

0.1-1 % Bisphenol A CAS:80-05-7 Repr. 2, H335; STOT SE 3, H318; Eye Dam.1, H317; Skin Sens. 1, H317

4. FIRST AID MEASURES

Description of first aid measures

In case of skin contact:

Immediately take off all contaminated clothing.

Obtain medical attention if skin related symptoms persist.

Remove contaminated clothing immediately and dispose of safely.

After contact with skin, wash immediately with soap and plenty of water.

In case of eyes contact:

After contact with the eyes, rinse with water with the eyelids open for a sufficient length of time, then consult an opthalmologistimmediately.

Protect uninjured eye.

In case of Ingestion:

Do not induce vomiting, get medical attention showing the SDS and the hazard label.

In case of Inhalation:

Remove casualty to fresh air and keep warm and at rest.

Most important symptoms/effects, acute and delayed

Eye irritation

Eye damages

Skin Irritation

Erythema

Indication of any immediate medical attention and special treatment needed

In case of accident or unwellness, seek medical advice immediately (show directions for use or safety data sheet if possible).

5. FIRE-FIGHTING MEASURES

Extinguishing media

Suitable extinguishing media:

Water.

Carbon dioxide (CO2).

Unsuitable extinguishing media:

None in particular.Page n. of2 92/11/2016 Production Name PLANIBOND EBA PART BDate

None in particular.

Specific hazards arising from the chemical

Do not inhale explosion and combustion gases.

Burning produces heavy smoke.

Hazardous combustion products: N.A.



Special protective equipment and precautions for fire-fighters

Use suitable breathing apparatus.

Collect contaminated fire extinguishing water separately. This must not be discharged into drains.

Move undamaged containers from immediate hazard area if it can be done safely.

6. ACCIDENTAL RELEASE MEASURES

Personal precautions, protective equipment and emergency procedures

Wear personal protection equipment.

Remove persons to safety.

See protective measures under point 7 and 8.

Methods and material for containment and cleaning up

Suitable material for taking up: absorbing material, organic, sand

Wash with plenty of water.

7. HANDLING AND STORAGE

Precautions for safe handling

Avoid contact with skin and eyes, inhalation of vapours and mists.

Exercise the greatest care when handling or opening the container.

Don't use empty container before they have been cleaned.

Before making transfer operations, assure that there aren't any incompatible material residuals in the containers.

Contamined clothing should be changed before entering eating areas.

Do not eat or drink while working.

See also section 8 for recommended protective equipment.

Conditions for safe storage, including any incompatibilities

Storage temperature: N.A.

Incompatible materials:

None in particular.

Instructions as regards storage premises:

Adequately ventilated premises.

8. EXPOSURE CONTROLS/PERSONAL PROTECTION

Control parameters

Appropriate engineering controls: N.A.

Individual protection measures

Eye protection:

Use close fitting safety goggles, don't use eye lens.

Protection for skin:

Use clothing that provides comprehensive protection to the skin, e.g. cotton, rubber, PVC or viton.

Protection for hands:

Use protective gloves that provides comprehensive protection, e.g. P.V.C., neoprene or rubber.

Respiratory protection:

N.A.

List of components with OEL value

Component OEL Type Country Ceiling Long Termmg/m3

Long Termppm

Short Termmg/m3

Short Termppm

Behaviour Note

Titanium dioxide OSHA 15

ACGIH 10 A4 - Not Classifiable as aHuman Carcinogen;lowerrespiratory tract irritation;

Diethylene triamine ACGIH 1 Skin - potential significantcontribution to overallexposure by the cutaneousroute;eye and upperrespiratory tract irritation;

Bisphenol A EU 10 Indicative

9. PHYSICAL AND CHEMICAL PROPERTIES

Information on basic physical and chemical propertiesPage n. of3 92/11/2016 Production Name PLANIBOND EBA PART BDate

Information on basic physical and chemical properties

Physical state: Liquid

Appearance and colour: Paste grey

Odour: like: Amines

Odour threshold: N.A.

pH: N.A.

Melting point / freezing point: N.A.

Initial boiling point and boiling range: N.A.

Flash point: >100 °C (212 °F)

Evaporation rate: N.A.

Upper/lower flammability or explosive limits: N.A.

Vapour density: N.A.

Vapour pressure: N.A.

Relative density: 1.68 g/cm3

Solubility in water: N.A.

Solubility in oil: N.A.

Partition coefficient (n-octanol/water): N.A.

Auto-ignition temperature: N.A.

Decomposition temperature: N.A.

Viscosity: N.A.



Solid/gas flammability: N.A.

Other information

Substance groups relevant properties: N.A.

Miscibility: N.A.

Fat Solubility: N.A.

Conductivity: N.A.

10. STABILITY AND REACTIVITY

Reactivity

Stable under normal conditions

Chemical stability

Data not Available.

Possibility of hazardous reactions

None.

Conditions to avoid

Stable under normal conditions.

Incompatible materials

None in particular.

Hazardous decomposition products

None.

11. TOXICOLOGICAL INFORMATION

Information on toxicological effects

Toxicological information of the mixture:

There is no toxicological data available on the mixture. Consider the individual concentration of each component to assesstoxicological effects resulting from exposure to the mixture.

Toxicological information on main components of the mixture:

Titanium dioxide a) acute toxicity LD50 Oral Rat > 10000mg/kg

Diethylene triamine a) acute toxicity LD50 Skin Rabbit = 672mg/kg

LD50 Oral Rat = 819mg/kg

2,4,6-Tri(dimethylaminomethyl)phenol

a) acute toxicity LD50 Skin Rat = 1280mg/kg


3-(Dimethylamino)-propylamine a) acute toxicity LC50 Inhalation Rat > 431mg/l 4h



Bisphenol A a) acute toxicity LD50 Skin Rabbit = 3000,00000mg/kg


LD50 Skin Rabbit = 3ml/kg

If not differently specified, the information required in the regulation and listed below must be considered as N.A.

a) acute toxicity

b) skin corrosion/irritation

c) serious eye damage/irritation

d) respiratory or skin sensitisation

e) germ cell mutagenicity

f) carcinogenicity

g) reproductive toxicity

h) STOT-single exposure

i) STOT-repeated exposure

j) aspiration hazard

Substance(s) listed on the IARC Monographs:

Titanium dioxide Group 2B

Substance(s) listed as OSHA Carcinogen(s):

Titanium dioxide

Substance(s) listed as NIOSH Carcinogen(s):

Titanium dioxide

Substance(s) listed on the NTP report on Carcinogens:

None

12. ECOLOGICAL INFORMATION

Toxicity

Adopt good working practices, so that the product is not released into the environment.

Eco-Toxicological Information:

Persistence and degradability

Bioaccumulative potential

Mobility in soil

List of components with eco-toxicological properties

Quantity Component Ident. Numb. Ecotox Infos

1-5 % Diethylene triamine CAS: 111-40-0 LC50 a) Aquatic acute toxicity Fish Poecilia reticulata= 248mg/L 96h IUCLID

EC50 a) Aquatic acute toxicity Daphnia Daphnia magna= 16mg/L 48h IUCLID

EC50 a) Aquatic acute toxicity Algae Pseudokirchneriella subcapitata= 1164mg/L 72h IUCLID

EC50 a) Aquatic acute toxicity Algae Pseudokirchneriella subcapitata= 345,60000mg/L 96h EPA

EC50 a) Aquatic acute toxicity Algae Desmodesmus subspicatus= 592mg/L 96h IUCLID

LC50 a) Aquatic acute toxicity Fish Leuiciscus idus= 430,00000mg/L 96h

EC50 a) Aquatic acute toxicity Daphnia Daphnia magna= 37,00000mg/L 24h

EC50 a) Aquatic acute toxicity Daphnia Daphnia magna= 16,00000mg/L 48h

0.1-1 % 3-(Dimethylamino)-propylamine CAS: 109-55-7 EC50 a) Aquatic acute toxicity Daphnia Daphnia magna= 595mg/L 48h IUCLID



0.1-1 % Bisphenol A CAS: 80-05-7 LC50 a) Aquatic acute toxicity Fish Pimephales promelas3,60000mg/L 96h EPA

LC50 a) Aquatic acute toxicity Fish Oncorhynchus mykiss= 4mg/L 96h IUCLID

LC50 a) Aquatic acute toxicity Fish Brachydanio rerio= 9,90000mg/L 96h IUCLID

EC50 a) Aquatic acute toxicity Daphnia Daphnia magna= 10,20000mg/L 48h IUCLID

EC50 a) Aquatic acute toxicity Algae Pseudokirchneriella subcapitata= 2,50000mg/L 96h IUCLID

EC50 a) Aquatic acute toxicity Daphnia Daphnia Magna= 3,90000mg/L 48h

N.A.

N.A.


Mobility in soil

Other adverse effects

N.A.

N.A.

13. DISPOSAL CONSIDERATIONS

Waste treatment methods

Waste must be handled in accordance with all federal, state, provincial, and local regulations. Consult authorities before disposal.

14. TRANSPORT INFORMATION

UN number

ADR-UN number: 2735

DOT-UN Number: UN2735

IATA-Un number: 2735

IMDG-Un number: 2735

UN proper shipping name

ADR-Shipping Name: AMINES, LIQUID, CORROSIVE, N.O.S. or POLYAMINES, LIQUID, CORROSIVE, N.O.S. (Diethylene triamine -2,4,6-Tri(dimethylaminomethyl)phenol)

DOT-Proper Shipping Name: Amines, liquid, corrosive, n.o.s., or Polyamines, liquid, corrosive, n.o.s. (Diethylene triamine - 2,4,6-Tri(dimethylaminomethyl)phenol)

IATA-Technical name: AMINES, LIQUID, CORROSIVE, N.O.S. or POLYAMINES, LIQUID, CORROSIVE, N.O.S. (Diethylene triamine -2,4,6-Tri(dimethylaminomethyl)phenol)

IMDG-Technical name: AMINES, LIQUID, CORROSIVE, N.O.S. or POLYAMINES, LIQUID, CORROSIVE, N.O.S. (Diethylene triamine -2,4,6-Tri(dimethylaminomethyl)phenol)

Transport hazard class(es)

ADR-Class: 8

DOT-Hazard Class: 8

IATA-Class: 8

IMDG-Class: 8

Packing group

ADR-Packing Group: III

DOT-Packing group: III

IATA-Packing group: III

IMDG-Packing group: III

Environmental hazards

Marine pollutant: No

Environmental Pollutant: N.A.

Transport in bulk according to Annex II of MARPOL73/78 and the IBC Code

N.A.

Special precautions

Department of Transportation (DOT):

DOT-Special Provision(s): IB3, T7, TP1, TP28

DOT-Label(s): 8

DOT-Symbol: N/A


DOT-Passenger Aircraft: N/A

DOT-Bulk: N/A

DOT-Non-Bulk: N/A

Road and Rail (ADR-RID):

ADR exempt: No

ADR-Label: 8

ADR-Hazard identification number: 80

ADR-Tunnel Restriction Code: 3 (E)

Air (IATA):

IATA-Passenger Aircraft: 852

IATA-Cargo Aircraft: 856

IATA-Label: 8

IATA-Subrisk: -

IATA-Erg: 8L




Sea (IMDG):

IMDG-Stowage Code: Category A

IMDG-Stowage Note: "Separated from" acids.

IMDG-Subrisk: -

IMDG-Special Provisions: 223 274

IMDG-Page: N/A

IMDG-Label: N/A

IMDG-EMS: F-A, S-B

IMDG-MFAG: N/A

15. REGULATORY INFORMATION

USA - Federal regulations

TSCA - Toxic Substances Control Act

SARA - Superfund Amendments and Reauthorization Act

CERCLA - Comprehensive Environmental Response, Compensation, and Liability Act

CAA - Clean Air Act

CWA - Clean Water Act

USA - State specific regulations

California Proposition 65

Massachusetts Right to know

TSCA inventory:

All the components are listed on the TSCA inventory

TSCA listed substances:

Fatty acids, tall-oil, polymers with bisphenolA, diethylenetriamine, epichlorohydrin andtetraethylenepentamine

is listed in TSCA Section 8b

Titanium dioxide is listed in TSCA Section 8b

Dipropylene glycol dibenzoate is listed in TSCA Section 8b

Diethylene triamine is listed in TSCA Section 8b

2,4,6-Tri(dimethylaminomethyl)phenol is listed in TSCA Section 8b

3-(Dimethylamino)-propylamine is listed in TSCA Section 8b

Bisphenol A is listed in TSCA Section 8b

Section 302 - Extremely Hazardous Substances:


Section 304 - Hazardous substances:


Section 313 - Toxic chemical list:

Bisphenol A

Substance(s) listed under CERCLA:


CAA listed substances:

Bisphenol A is listed in CAA Section 112(b) - HON

CWA listed substances:


Substance(s) listed under California Proposition 65:

Titanium dioxide Listed as carcinogen

Diethylene triamine Listed as carcinogen

Substance(s) listed under Massachusetts Right to know:

Titanium dioxide

Diethylene triamine


Pennsylvania Right to know

New Jersey Right to know

Canada- Federal regulations

DSL - Domestic Substances List

NDSL - Non Domestic Substances List

NPRI - National Pollutant Release Inventory

3-(Dimethylamino)-propylamine

Bisphenol A

Substance(s) listed under Pennsylvania Right to know:

Titanium dioxide

Diethylene triamine


Bisphenol A

Substance(s) listed under New Jersey Right to know:

Titanium dioxide

Diethylene triamine


Bisphenol A

DSL Inventory:

All the substances are listed in the DSL.

NDSL Inventory:


Substances listed in NPRI:


16. OTHER INFORMATION


Product code: 2255

Additional classification information

HMIS Health: 2 = Moderate

HMIS Health - Is health hazard chronic?: Yes


Code Description

H226 Flammable liquid and vapour.

H302 Harmful if swallowed.

H312 Harmful in contact with skin.

H314 Causes severe skin burns and eye damage.



H318 Causes serious eye damage.


H330 Fatal if inhaled.

H335 May cause respiratory irritation.

H351 Suspected of causing cancer .

H361 Suspected of damaging fertility or the unborn child <state route of exposure if it is conclusively proven that no other routes of exposurecause the hazard>.

H361fd Suspected of damaging fertility. Suspected of damaging the unborn child.

H412 Harmful to aquatic life with long lasting effects.



HMIS Reactivity: 0 = Minimal

HMIS P.P.E.: Safety glasses, gloves

NFPA Health: 2 = Moderate

NFPA Flammability: 1 = Combustible if heated

NFPA Reactivity: 0 = Minimal

NFPA Special Risk: N.A.

Reasonable care has been taken in the preparation of this information, but the manufacturer makes no warranty of merchantability or anyother warranty, expressed or implied, with respect to this information. The manufacturer makes no representations and assumes no liabilityfor any direct, incidental or consequential damages resulting from its use. The information herein is presented in good faith and believed tobe accurate as of the effective date given. It is the buyer's responsibility to ensure that its activities comply with Federal, State or provincial,and local laws.

This document was prepared by a competent person who has received appropriate training.

It is the duty of the user to ensure that this information is appropriate and complete with respect to the specific use intended.

This SDS cancels and replaces any preceding release.

Legend to abbreviations and acronyms used in the safety data sheet:

ADR: European Agreement concerning the International Carriage of Dangerous Goods by Road.

RID: Regulation Concerning the International Transport of Dangerous Goods by Rail.

IMDG: International Maritime Code for Dangerous Goods.

IATA: International Air Transport Association.

IATA-DGR: Dangerous Goods Regulation by the "International Air Transport Association" (IATA).

ICAO: International Civil Aviation Organization.

ICAO-TI: Technical Instructions by the "International Civil Aviation Organization" (ICAO).

GHS: Globally Harmonized System of Classification and Labeling of Chemicals.

CLP: Classification, Labeling, Packaging.

EINECS: European Inventory of Existing Commercial Chemical Substances.

INCI: International Nomenclature of Cosmetic Ingredients.

CAS: Chemical Abstracts Service (division of the American Chemical Society).

GefStoffVO: Ordinance on Hazardous Substances, Germany.

LC50: Lethal concentration, for 50 percent of test population.

LD50: Lethal dose, for 50 percent of test population.

DNEL: Derived No Effect Level.

PNEC: Predicted No Effect Concentration.

TLV: Threshold Limiting Value.

TWATLV: Threshold Limit Value for the Time Weighted Average 8 hour day. (ACGIH Standard).

STEL: Short Term Exposure limit.

STOT: Specific Target Organ Toxicity.

WGK: German Water Hazard Class.

KSt: Explosion coefficient.

Paragraphs modified from the previous revision:

- 1. IDENTIFICATION OF THE SUBSTANCE/PREPARATION AND OF THE COMPANY/UNDERTAKING

- 3. COMPOSITION/INFORMATION ON INGREDIENTS

- 11. TOXICOLOGICAL INFORMATION

- 12. ECOLOGICAL INFORMATION

- 15. REGULATORY INFORMATION

- 16. OTHER INFORMATION


Documents

Safety Data Sheet PLANIBOND EBA PART A 1. IDENTIFICATION