SAFETY DATA SHEET PM/V621 - PRECISION YACHT VARNISH · PM/V621 - PRECISION YACHT VARNISH Hazard statements H226 Flammable liquid and vapour. H317 May cause an allergic skin reaction

Revision date: 01/12/2016 Revision: 10 Supersedes date: 17/09/2013

SAFETY DATA SHEETPM/V621 - PRECISION YACHT VARNISH

According to Regulation (EC) No 1907/2006, Annex II, as amended by Regulation (EU) No 453/2010

SECTION 1: Identification of the substance/mixture and of the company/undertaking

1.1. Product identifier

Product name PM/V621 - PRECISION YACHT VARNISH

Product number PM/V621/10

1.2. Relevant identified uses of the substance or mixture and uses advised against

Identified uses Paint.

1.3. Details of the supplier of the safety data sheet

Supplier Precision Yacht PaintTeal & Mackrill Ltd.Lockwood StreetHullYorkshire+44(0)1482 [email protected]

Contact person Technical Department -, 08.30 - 16.30 hrs Mon - Thurs, 08.30 - 15.00 hrs Fri, as above

1.4. Emergency telephone number

Emergency telephone +44 (0) 1482 381456 Precision Yacht Paint (08.30 - 16.30 hrs Mon - Thurs, 08.30 - 15.00 hrsFri)

SDS No. 11573

SECTION 2: Hazards identification

2.1. Classification of the substance or mixtureClassification (EC 1272/2008)Physical hazards Flam. Liq. 3 - H226

Health hazards Skin Sens. 1 - H317 STOT SE 3 - H336 STOT RE 1 - H372

Environmental hazards Aquatic Chronic 2 - H411

Classification (67/548/EEC or1999/45/EC)

N;R51/53. R10,R66,R67.

2.2. Label elements

Pictogram

Signal word Danger

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PM/V621 - PRECISION YACHT VARNISH

Hazard statements H226 Flammable liquid and vapour.H317 May cause an allergic skin reaction.H336 May cause drowsiness or dizziness.H372 Causes damage to organs through prolonged or repeated exposure.H411 Toxic to aquatic life with long lasting effects.

Precautionary statements P102 Keep out of reach of children.P101 If medical advice is needed, have product container or label at hand.P271 Use only outdoors or in a well-ventilated area.P273 Avoid release to the environment.P280 Wear protective gloves/ protective clothing/ eye protection/ face protection.P501 Dispose of contents/ container in accordance with national regulations.

Contains Reaction mass of bis(1,2,2,6,6-pentamethyl-4-piperidyl) sebacate and methyl 1,2,2,6,6-pentamethyl-4-piperidyl sebacate

Supplementary precautionarystatements

P210 Keep away from heat, hot surfaces, sparks, open flames and other ignition sources. Nosmoking.P240 Ground/ bond container and receiving equipment.P241 Use explosion-proof electrical equipment.P242 Use only non-sparking tools.P243 Take precautionary measures against static discharge.P260 Do not breathe vapour/ spray.P261 Avoid breathing vapour/ spray.P264 Wash contaminated skin thoroughly after handling.P270 Do not eat, drink or smoke when using this product.P272 Contaminated work clothing should not be allowed out of the workplace.P302+P352 IF ON SKIN: Wash with plenty of water.P303+P361+P353 IF ON SKIN (or hair): Take off immediately all contaminated clothing.Rinse skin with water/ shower.P304+P340 IF INHALED: Remove person to fresh air and keep comfortable for breathing.P312 Call a POISON CENTER/ doctor if you feel unwell.P314 Get medical advice/ attention if you feel unwell.P321 Specific treatment (see medical advice on this label).P333+P313 If skin irritation or rash occurs: Get medical advice/ attention.P362+P364 Take off contaminated clothing and wash it before reuse.P370+P378 In case of fire: Use foam, carbon dioxide, dry powder or water fog to extinguish.P391 Collect spillage.P403+P233 Store in a well-ventilated place. Keep container tightly closed.P403+P235 Store in a well-ventilated place. Keep cool.P405 Store locked up.

2.3. Other hazards

This product does not contain any substances classified as PBT or vPvB.

SECTION 3: Composition/information on ingredients

3.2. Mixtures

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WHITE SPIRIT 30-60%

CAS number: — EC number: 919-446-0 REACH registration number: 01-2119458049-33-XXXX

ClassificationFlam. Liq. 3 - H226STOT SE 3 - H336STOT RE 1 - H372Asp. Tox. 1 - H304Aquatic Chronic 2 - H411

Classification (67/548/EEC or 1999/45/EC)Xn;R65. N;R51/53. R10,R66,R67.

LOW AROMATIC WHITE SPIRIT 5-10%

CAS number: — EC number: 919-857-5 REACH registration number: 01-2119463258-33-XXXX

ClassificationFlam. Liq. 3 - H226STOT SE 3 - H336Asp. Tox. 1 - H304

Classification (67/548/EEC or 1999/45/EC)Xn;R65. R10,R66,R67.

Mixture of branched and linear C7-C9 alkyl 3-[3-(2H-benzotriazol-2-yl)-5-(1,1-dimethylethyl)-4-hydroxyphenyl]propionates

1-5%

CAS number: 127519-17-9 EC number: 407-000-3

ClassificationAquatic Chronic 2 - H411

Reaction mass of bis(1,2,2,6,6-pentamethyl-4-piperidyl)sebacate and methyl 1,2,2,6,6-pentamethyl-4-piperidylsebacate

1-5%

CAS number: — EC number: 915-687-0 REACH registration number: 01-2119491304-40-0000

M factor (Acute) = 1 M factor (Chronic) = 1

ClassificationSkin Sens. 1A - H317Aquatic Acute 1 - H400Aquatic Chronic 1 - H410

LOW AROMATIC WHITE SPIRIT <1%

CAS number: — EC number: 918-317-6 REACH registration number: 01-2119474196-32-0000

ClassificationAsp. Tox. 1 - H304

Classification (67/548/EEC or 1999/45/EC)Xn;R65. R10,R66.

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2-METHYLPENTANE-2,4-DIOL <1%

CAS number: 107-41-5 EC number: 203-489-0

ClassificationSkin Irrit. 2 - H315Eye Irrit. 2 - H319

Classification (67/548/EEC or 1999/45/EC)Xi;R36/38

ZIRCONIUM SALT, 2-ETHYLHEXANOIC ACID <1%

CAS number: 22464-99-9 EC number: 245-018-1 REACH registration number: 01-2119979088-21-0002

ClassificationRepr. 2 - H361d

Classification (67/548/EEC or 1999/45/EC)Repr. Cat. 3;R63.

XYLENE, MIXED ISOMERS <1%

CAS number: 1330-20-7 EC number: 215-535-7 REACH registration number: 01-2119488216-32-xxxx

ClassificationFlam. Liq. 3 - H226Acute Tox. 4 - H312Acute Tox. 4 - H332Skin Irrit. 2 - H315Eye Irrit. 2 - H319STOT SE 3 - H335STOT RE 2 - H373Asp. Tox. 1 - H304

Classification (67/548/EEC or 1999/45/EC)Xn;R20/21,R65. Xi;R36/37/38. R10.

Low Aromatic White Spirit <1%

CAS number: 64742-48-9 EC number: 265-150-3 REACH registration number: 01-2119457273-39

ClassificationFlam. Liq. 3 - H226Asp. Tox. 1 - H304

Classification (67/548/EEC or 1999/45/EC)Xn;R65. R10,R66.

PHTHALIC ANHYDRIDE <1%


ClassificationAcute Tox. 4 - H302Skin Irrit. 2 - H315Eye Dam. 1 - H318Resp. Sens. 1 - H334Skin Sens. 1 - H317STOT SE 3 - H335

Classification (67/548/EEC or 1999/45/EC)Xn;R22 R42/43 Xi;R37/38,R41

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ZIRCONIUM PROPIONATE <1%


ClassificationNot Classified

Classification (67/548/EEC or 1999/45/EC)-

2,6-Di-tert-butyl-p-cresol <1%

CAS number: 128-37-0 EC number: 204-881-4 REACH registration number: 01-2119565113-46-xxxx

M factor (Acute) = 1

ClassificationAquatic Acute 1 - H400Aquatic Chronic 1 - H410

Classification (67/548/EEC or 1999/45/EC)N;R50/53.

The Full Text for all R-Phrases and Hazard Statements are Displayed in Section 16.

SECTION 4: First aid measures

4.1. Description of first aid measures

General information Get medical attention immediately. Show this Safety Data Sheet to the medical personnel.

Inhalation Remove affected person from source of contamination. Move affected person to fresh air andkeep warm and at rest in a position comfortable for breathing. Maintain an open airway.Loosen tight clothing such as collar, tie or belt. When breathing is difficult, properly trainedpersonnel may assist affected person by administering oxygen. Place unconscious person ontheir side in the recovery position and ensure breathing can take place.

Ingestion Rinse mouth thoroughly with water. Remove any dentures. Give a few small glasses of wateror milk to drink. Stop if the affected person feels sick as vomiting may be dangerous. Do notinduce vomiting unless under the direction of medical personnel. If vomiting occurs, the headshould be kept low so that vomit does not enter the lungs. Never give anything by mouth to anunconscious person. Move affected person to fresh air and keep warm and at rest in aposition comfortable for breathing. Place unconscious person on their side in the recoveryposition and ensure breathing can take place. Maintain an open airway. Loosen tight clothingsuch as collar, tie or belt.

Skin contact Rinse with water.

Eye contact Rinse immediately with plenty of water. Remove any contact lenses and open eyelids wideapart. Continue to rinse for at least 10 minutes.

Protection of first aiders First aid personnel should wear appropriate protective equipment during any rescue. If it issuspected that volatile contaminants are still present around the affected person, first aidpersonnel should wear an appropriate respirator or self-contained breathing apparatus. Washcontaminated clothing thoroughly with water before removing it from the affected person, orwear gloves. It may be dangerous for first aid personnel to carry out mouth-to-mouthresuscitation.

4.2. Most important symptoms and effects, both acute and delayed

General information See Section 11 for additional information on health hazards. The severity of the symptomsdescribed will vary dependent on the concentration and the length of exposure.

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Inhalation A single exposure may cause the following adverse effects: Headache. Nausea, vomiting.Central nervous system depression. Drowsiness, dizziness, disorientation, vertigo. Narcoticeffect. During application and drying, solvent vapours will be emitted. Vapours in highconcentrations are narcotic.

Ingestion Gastrointestinal symptoms, including upset stomach. Fumes from the stomach contents maybe inhaled, resulting in the same symptoms as inhalation.

Skin contact Prolonged contact may cause dryness of the skin. Discoloration of the skin.

Eye contact May cause temporary eye irritation.

4.3. Indication of any immediate medical attention and special treatment needed

Notes for the doctor Treat symptomatically.

SECTION 5: Firefighting measures

5.1. Extinguishing media

Suitable extinguishing media The product is flammable. Extinguish with alcohol-resistant foam, carbon dioxide, dry powderor water fog. Use fire-extinguishing media suitable for the surrounding fire.

Unsuitable extinguishingmedia

Do not use water jet as an extinguisher, as this will spread the fire.

5.2. Special hazards arising from the substance or mixture

Specific hazards Containers can burst violently or explode when heated, due to excessive pressure build-up.Flammable liquid and vapour. Vapours may be ignited by a spark, a hot surface or an ember.Vapours may form explosive mixtures with air. Fire-water run-off in sewers may create fire orexplosion hazard.

Hazardous combustionproducts

Thermal decomposition or combustion products may include the following substances:Harmful gases or vapours.

5.3. Advice for firefighters

Protective actions duringfirefighting

Avoid breathing fire gases or vapours. Evacuate area. Keep upwind to avoid inhalation ofgases, vapours, fumes and smoke. Ventilate closed spaces before entering them. Coolcontainers exposed to heat with water spray and remove them from the fire area if it can bedone without risk. Cool containers exposed to flames with water until well after the fire is out.If a leak or spill has not ignited, use water spray to disperse vapours and protect men stoppingthe leak. Avoid discharge to the aquatic environment. Control run-off water by containing andkeeping it out of sewers and watercourses. If risk of water pollution occurs, notify appropriateauthorities.

Special protective equipmentfor firefighters

Wear positive-pressure self-contained breathing apparatus (SCBA) and appropriate protectiveclothing. Firefighter's clothing conforming to European standard EN469 (including helmets,protective boots and gloves) will provide a basic level of protection for chemical incidents.

SECTION 6: Accidental release measures

6.1. Personal precautions, protective equipment and emergency procedures

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Personal precautions No action shall be taken without appropriate training or involving any personal risk. Keepunnecessary and unprotected personnel away from the spillage. Wear protective clothing asdescribed in Section 8 of this safety data sheet. Follow precautions for safe handlingdescribed in this safety data sheet. Wash thoroughly after dealing with a spillage. Ensureprocedures and training for emergency decontamination and disposal are in place. Do nottouch or walk into spilled material. Evacuate area. Provide adequate ventilation. No smoking,sparks, flames or other sources of ignition near spillage. Promptly remove any clothing thatbecomes contaminated. Avoid inhalation of dust and vapours. Use suitable respiratoryprotection if ventilation is inadequate.

6.2. Environmental precautions

Environmental precautions Avoid discharge into drains or watercourses or onto the ground. Avoid discharge to theaquatic environment.

6.3. Methods and material for containment and cleaning up

Methods for cleaning up Wear protective clothing as described in Section 8 of this safety data sheet. Clear up spillsimmediately and dispose of waste safely. Eliminate all ignition sources if safe to do so. Nosmoking, sparks, flames or other sources of ignition near spillage. Do not allow material toenter confined spaces, due to the risk of explosion. Absorb small quantities with paper towelsand evaporate in a safe place. Once evaporation is complete, place paper in a suitable wastedisposal container and seal securely. Flush contaminated area with plenty of water. Washthoroughly after dealing with a spillage. Dangerous for the environment. Do not empty intodrains. For waste disposal, see Section 13.

6.4. Reference to other sections

Reference to other sections For personal protection, see Section 8. See Section 11 for additional information on healthhazards. See Section 12 for additional information on ecological hazards. For waste disposal,see Section 13.

SECTION 7: Handling and storage

7.1. Precautions for safe handling

Usage precautions Keep out of the reach of children. Read and follow manufacturer's recommendations. Wearprotective clothing as described in Section 8 of this safety data sheet. Keep away from food,drink and animal feeding stuffs. Handle all packages and containers carefully to minimisespills. Keep container tightly sealed when not in use. Avoid the formation of mists. Theproduct is flammable. Keep away from heat, hot surfaces, sparks, open flames and otherignition sources. No smoking. In use may form flammable/explosive vapour-air mixture.Vapours may accumulate on the floor and in low-lying areas. Use explosion-proof electrical,ventilating and lighting equipment. Use only non-sparking tools. Take precautionary measuresagainst static discharges. Avoid discharge to the aquatic environment. Do not handle until allsafety precautions have been read and understood. Do not handle broken packages withoutprotective equipment. Do not reuse empty containers.

Advice on generaloccupational hygiene

Wash promptly if skin becomes contaminated. Take off contaminated clothing. Washcontaminated clothing before reuse. Do not eat, drink or smoke when using this product.Wash at the end of each work shift and before eating, smoking and using the toilet. Changework clothing daily before leaving workplace.

7.2. Conditions for safe storage, including any incompatibilities

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Storage precautions Store locked up. Eliminate all sources of ignition. Take precautionary measures against staticdischarges. Earth container and transfer equipment to eliminate sparks from static electricity.Keep away from oxidising materials, heat and flames. Keep only in the original container.Keep container tightly closed, in a cool, well ventilated place. Keep containers upright. Protectcontainers from damage. Bund storage facilities to prevent soil and water pollution in theevent of spillage. The storage area floor should be leak-tight, jointless and not absorbent.

Storage class Flammable liquid storage.

7.3. Specific end use(s)

Specific end use(s) The identified uses for this product are detailed in Section 1.2.

SECTION 8: Exposure Controls/personal protection

8.1. Control parametersOccupational exposure limitsWHITE SPIRIT

Long-term exposure limit (8-hour TWA): WEL 350 mg/m³

LOW AROMATIC WHITE SPIRIT


2-METHYLPENTANE-2,4-DIOL

Long-term exposure limit (8-hour TWA): WEL 25 ppm 123 mg/m³Short-term exposure limit (15-minute): WEL 25 ppm 123 mg/m³

ZIRCONIUM SALT, 2-ETHYLHEXANOIC ACID

Long-term exposure limit (8-hour TWA): WEL 5 mg/m³Short-term exposure limit (15-minute): WEL 10 mg/m³

XYLENE, MIXED ISOMERS

Long-term exposure limit (8-hour TWA): WEL 50 ppm 220 mg/m³Short-term exposure limit (15-minute): WEL 100 ppm 441 mg/m³

Low Aromatic White Spirit


PHTHALIC ANHYDRIDE

Long-term exposure limit (8-hour TWA): WEL 4 mg/m3(Sen)Short-term exposure limit (15-minute): WEL 12 mg/m3(Sen)

ZIRCONIUM PROPIONATE

Long-term exposure limit (8-hour TWA): WEL 5 mg/m³Short-term exposure limit (15-minute): WEL 10 mg/m³

2,6-Di-tert-butyl-p-cresol

Long-term exposure limit (8-hour TWA): WEL 10 mg/m³WEL = Workplace Exposure Limit

WHITE SPIRIT

DNEL Consumer - Oral; Long term systemic effects: 26 mg/kg/dayConsumer - Dermal; Long term systemic effects: 26 mg/kg/dayConsumer - Inhalation; Long term systemic effects: 71 mg/m³Consumer - Inhalation; Short term systemic effects: 570 mg/m³Industry - Inhalation; Short term systemic effects: 570 mg/m³Industry - Inhalation; Long term systemic effects: 330 mg/m³Industry - Dermal; Long term systemic effects: 44 mg/kg/day

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PNEC No PNEC available. Substance is a hydrocarbon UVCB. Standard tests for thisendpoint are intended for single substances and are not appropriate for the riskassessment of this complex substance.


DNEL Consumer - Oral; Long term systemic effects: 300 mg/kg/dayConsumer - Dermal; Long term systemic effects: 300 mg/kg/dayIndustry - Inhalation; Long term systemic effects: 1500 mg/m³Industry - Dermal; Long term systemic effects: 300 mg/kg/dayConsumer - Inhalation; Long term systemic effects: 900 mg/m³


Mixture of branched and linear C7-C9 alkyl 3-[3-(2H-benzotriazol-2-yl)-5-(1,1-dimethylethyl)-4-hydroxyphenyl]propionates (CAS: 127519-17-9)

DNEL Workers - Inhalation; Long term systemic effects: 0.35 mg/m³Workers - Dermal; Long term systemic effects: 0.5 mg/kg/dayGeneral population - Inhalation; Long term systemic effects: 0.085 mg/m³General population - Dermal; Long term systemic effects: 0.25 mg/kg/dayGeneral population - Oral; Long term systemic effects: 0.025 mg/kg/day

Reaction mass of bis(1,2,2,6,6-pentamethyl-4-piperidyl) sebacate and methyl 1,2,2,6,6-pentamethyl-4-piperidylsebacate

DNEL Workers - Inhalation; Long term systemic effects: 3.53 mg/m³Workers - Dermal; Long term systemic effects: 2 mg/kg/dayGeneral population - Inhalation; Long term systemic effects: 0.87 mg/m³General population - Dermal; Long term systemic effects: 1 mg/kg/dayGeneral population - Oral; Long term systemic effects: 0.5 mg/kg/day


DNEL Industry - Inhalation; Long term systemic effects: 1500 mg/m³Industry - Dermal; Long term systemic effects: 300 mg/kg/dayConsumer - Oral; Long term systemic effects: 300 mg/kg/dayConsumer - Inhalation; Long term systemic effects: 900 mg/m³Consumer - Dermal; Long term systemic effects: 300 mg/kg/day


Diethylene glycol dibenzoate (CAS: 120-55-8)

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DNEL Workers, Industry/Professional - Dermal; Short term systemic effects: 160mg/kg/dayIndustry/Professional, Workers - Inhalation; Short term systemic effects: 35.08mg/m³Industry/Professional, Workers - Dermal; Long term systemic effects: 1.7 mg/kg/dayIndustry/Professional, Workers - Inhalation; Long term systemic effects: 5.8 mg/m³General population - Dermal; Short term systemic effects: 8 mg/kg/dayGeneral population - Inhalation; Short term systemic effects: 8.7 mg/m³General population - Oral; Short term systemic effects: 80 mg/kg/dayGeneral population - Dermal; Long term systemic effects: 0.8 mg/kg/dayGeneral population - Inhalation; Long term systemic effects: 1.4 mg/m³General population - Oral; Long term systemic effects: 0.8 mg/kg/day

PNEC - Fresh water; 0.0029 mg/l- Marine water; 0.00029 mg/l- Intermittent release; 0.029 mg/l- Sediment (Freshwater); 0.103 mg/kg- Sediment (Marinewater); 0.103 mg/kg- Soil; 1 mg/kg- STP; 10 mg/l

Dipropylene glycol dibenzoate (CAS: 27138-31-4)

DNEL Industry/Professional, Workers - Dermal; Short term systemic effects: 170mg/kg/dayIndustry/Professional, Workers - Inhalation; Short term systemic effects: 35.08mg/m³Industry/Professional, Workers - Dermal; Long term systemic effects: 10 mg/kg/dayIndustry/Professional, Workers - Inhalation; Long term systemic effects: 8.8 mg/m³General population - Inhalation; Short term systemic effects: 8.7 mg/m³General population - Dermal; Short term systemic effects: 80 mg/kg/dayGeneral population - Oral; Short term systemic effects: 80 mg/kg/dayGeneral population - Dermal; Long term systemic effects: 0.22 mg/kg/dayGeneral population - Oral; Long term systemic effects: 5 mg/kg/day

PNEC - Soil; 1 mg/kg- Marine water; 0.00037 mg/l- Fresh water; 0.0037 mg/l- STP; 10 mg/l- Intermittent release; 0.037 mg/l- Sediment (Freshwater); 1.49 mg/kg- Sediment (Marinewater); 0.149 mg/kg

XYLENE, MIXED ISOMERS (CAS: 1330-20-7)

DNEL Consumer - Oral; Long term systemic effects: 1.6 mg/kg/dayConsumer - Dermal; Long term systemic effects: 108 mg/kg/dayConsumer - Inhalation; Long term systemic effects: 14.8 mg/m³Industry - Dermal; Long term systemic effects: 180 mg/kg/dayIndustry - Inhalation; Long term systemic effects: 77 mg/m³Industry - Inhalation; Short term local effects: 289 mg/m³

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PNEC - Fresh water; 0.327 mg/l- Marine water; 0.327 mg/l- Intermittent release; 0.327 mg/l- Sediment (Freshwater); 12.46 mg/kg- Sediment (Marinewater); 12.46 mg/kg- Soil; 2.31 mg/kg- STP; 6.58 mg/kg

2,6-Di-tert-butyl-p-cresol (CAS: 128-37-0)

DNEL Industry - Dermal; : 0.5 mg/kg/dayIndustry - Inhalation; : 3.5 mg/kg/day

PNEC - Fresh water; 0.000199 mg/l- Marine water; 0.0000199 mg/l- Sediment; 0.0996 mg/l- Soil; 0.04769 mg/l

8.2. Exposure controls

Protective equipment

Appropriate engineeringcontrols

Provide adequate ventilation. Personal, workplace environment or biological monitoring maybe required to determine the effectiveness of the ventilation or other control measures and/orthe necessity to use respiratory protective equipment. Use process enclosures, local exhaustventilation or other engineering controls as the primary means to minimise worker exposure.Personal protective equipment should only be used if worker exposure cannot be controlledadequately by the engineering control measures. Ensure control measures are regularlyinspected and maintained. Ensure operatives are trained to minimise exposure. Theengineering controls also need to keep gas, vapour or dust concentrations below any lowerexplosive limits. Use explosion-proof ventilating equipment.

Eye/face protection Eyewear complying with an approved standard should be worn if a risk assessment indicateseye contact is possible. Personal protective equipment for eye and face protection shouldcomply with European Standard EN166. Unless the assessment indicates a higher degree ofprotection is required, the following protection should be worn: Tight-fitting safety glasses.

Hand protection Chemical-resistant, impervious gloves complying with an approved standard should be worn ifa risk assessment indicates skin contact is possible. The most suitable glove should bechosen in consultation with the glove supplier/manufacturer, who can provide informationabout the breakthrough time of the glove material. To protect hands from chemicals, glovesshould comply with European Standard EN374. Considering the data specified by the glovemanufacturer, check during use that the gloves are retaining their protective properties andchange them as soon as any deterioration is detected. Frequent changes are recommended.

Other skin and bodyprotection

Appropriate footwear and additional protective clothing complying with an approved standardshould be worn if a risk assessment indicates skin contamination is possible.

Hygiene measures Provide eyewash station and safety shower. Contaminated work clothing should not beallowed out of the workplace. Wash contaminated clothing before reuse. Clean equipmentand the work area every day. Good personal hygiene procedures should be implemented.Wash at the end of each work shift and before eating, smoking and using the toilet. Whenusing do not eat, drink or smoke. Preventive industrial medical examinations should be carriedout. Warn cleaning personnel of any hazardous properties of the product.

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Respiratory protection Respiratory protection complying with an approved standard should be worn if a riskassessment indicates inhalation of contaminants is possible. Ensure all respiratory protectiveequipment is suitable for its intended use and is ‘CE’-marked. Check that the respirator fitstightly and the filter is changed regularly. Gas and combination filter cartridges should complywith European Standard EN14387. Full face mask respirators with replaceable filter cartridgesshould comply with European Standard EN136. Half mask and quarter mask respirators withreplaceable filter cartridges should comply with European Standard EN140.

Environmental exposurecontrols

Keep container tightly sealed when not in use. Emissions from ventilation or work processequipment should be checked to ensure they comply with the requirements of environmentalprotection legislation. In some cases, fume scrubbers, filters or engineering modifications tothe process equipment will be necessary to reduce emissions to acceptable levels.

SECTION 9: Physical and Chemical Properties

9.1. Information on basic physical and chemical properties

Appearance Viscous liquid. Clear, yellowish liquid.

Colour Straw.

Odour Organic solvents.

Flash point 38 approx.°C CC (Closed cup).

Upper/lower flammability orexplosive limits

: 0.8

Vapour density heavier than air

Relative density 0.92 @ @ 20°C

Solubility(ies) Insoluble in water

Viscosity 2.5 (Rotothinner) P @ 25°C

9.2. Other information

Volatility 51

Volatile organic compound This product contains a maximum VOC content of 395 g/litre.

SECTION 10: Stability and reactivity

10.1. Reactivity

Reactivity There are no known reactivity hazards associated with this product.

10.2. Chemical stability

Stability Stable at normal ambient temperatures and when used as recommended. Stable under theprescribed storage conditions.

10.3. Possibility of hazardous reactions

Possibility of hazardousreactions

The following materials may react strongly with the product: Oxidising agents.

10.4. Conditions to avoid

Conditions to avoid Avoid heat, flames and other sources of ignition. Containers can burst violently or explodewhen heated, due to excessive pressure build-up. Static electricity and formation of sparksmust be prevented. Do not pressurise, cut, weld, drill, grind or otherwise expose containers toheat or sources of ignition.

10.5. Incompatible materials

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Materials to avoid Oxidising materials. Acids - oxidising.

10.6. Hazardous decomposition products

Hazardous decompositionproducts

Does not decompose when used and stored as recommended. Thermal decomposition orcombustion products may include the following substances: Harmful gases or vapours.

SECTION 11: Toxicological information

11.1. Information on toxicological effectsAcute toxicity - oralNotes (oral LD₅₀) Based on available data the classification criteria are not met.

Acute toxicity - dermalNotes (dermal LD₅₀) Based on available data the classification criteria are not met.

Acute toxicity - inhalationNotes (inhalation LC₅₀) Based on available data the classification criteria are not met.

Skin corrosion/irritationAnimal data Based on available data the classification criteria are not met.

Serious eye damage/irritationSerious eye damage/irritation Based on available data the classification criteria are not met.

Respiratory sensitisationRespiratory sensitisation Based on available data the classification criteria are not met.

Skin sensitisationSkin sensitisation Based on available data the classification criteria are not met.

Germ cell mutagenicityGenotoxicity - in vitro Based on available data the classification criteria are not met.

CarcinogenicityCarcinogenicity Based on available data the classification criteria are not met.

IARC carcinogenicity None of the ingredients are listed or exempt.

Reproductive toxicityReproductive toxicity - fertility Based on available data the classification criteria are not met.

Reproductive toxicity -development

Based on available data the classification criteria are not met.

Specific target organ toxicity - single exposureSTOT - single exposure STOT SE 3 - H336 May cause drowsiness or dizziness.

Target organs Central nervous system

Specific target organ toxicity - repeated exposureSTOT - repeated exposure STOT RE 1 - H372 Causes damage to organs through prolonged or repeated exposure.

Aspiration hazardAspiration hazard Based on available data the classification criteria are not met.

General information The severity of the symptoms described will vary dependent on the concentration and thelength of exposure.

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Inhalation A single exposure may cause the following adverse effects: Headache. Nausea, vomiting.Central nervous system depression. Drowsiness, dizziness, disorientation, vertigo. Narcoticeffect. During application and drying, solvent vapours will be emitted. Vapours in highconcentrations are narcotic.

Ingestion Gastrointestinal symptoms, including upset stomach. Fumes from the stomach contents maybe inhaled, resulting in the same symptoms as inhalation.

Skin contact Prolonged contact may cause dryness of the skin. Discoloration of the skin.

Eye contact May cause temporary eye irritation.

Route of entry Ingestion Inhalation Skin and/or eye contact


Medical considerations Skin disorders and allergies.

Toxicological information

Toxicological information on ingredients.

WHITE SPIRIT

Acute toxicity - oral

Acute toxicity oral (LD₅₀mg/kg)

15,000.0

Species Rat

Notes (oral LD₅₀) Conclusive data but not sufficient for classification.

Acute toxicity - dermal

Acute toxicity dermal (LD₅₀mg/kg)

3,400.0

Species Rabbit

Notes (dermal LD₅₀) Conclusive data but not sufficient for classification.

Acute toxicity - inhalation

Acute toxicity inhalation(LC₅₀ vapours mg/l)

13.1

Species Rat

Skin corrosion/irritation

Animal data Erythema/eschar score: Very slight erythema - barely perceptible (1). Oedemascore: Very slight oedema - barely perceptible (1). Not irritating.

Extreme pH Not irritating. Not corrosive to skin.

Serious eye damage/irritation

Serious eyedamage/irritation

Not irritating.

Respiratory sensitisation

Respiratory sensitisation There is evidence that the material can lead to respiratory hypersensitivity.

Skin sensitisation

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Skin sensitisation Guinea pig maximization test (GPMT) - Guinea pig: Not sensitising. Buehler test -Guinea pig: Not sensitising.

Germ cell mutagenicity

Genotoxicity - in vitro Bacterial reverse mutation test: Negative.

Genotoxicity - in vivo Chromosome aberration: Negative.

Carcinogenicity

Carcinogenicity NOAEL 300 mg/kg, Oral, Rat There is no evidence that the product can causecancer.

Reproductive toxicity

Reproductive toxicity -fertility

One-generation study - NOAEL >3000 mg/kg/day, Oral, Rat P This substance hasno evidence of toxicity to reproduction.


Developmental toxicity: - NOAEC: >300 ppm, Inhalation, Rat Read-across data.This substance has no evidence of toxicity to reproduction.

Specific target organ toxicity - single exposure

STOT - single exposure Central nervous system depression including narcotic effects such as drowsiness,narcosis, reduced alertness, loss of reflexes, lack of coordination and vertigo.


Specific target organ toxicity - repeated exposure

STOT - repeated exposure NOAEL 1056 mg/kg, Oral, Rat

Aspiration hazard

Aspiration hazard Kinematic viscosity <= 20.5 mm2/s.

Inhalation Vapours may cause drowsiness and dizziness.

Ingestion Harmful: may cause lung damage if swallowed. May cause stomach pain orvomiting.

Skin contact May cause defatting of the skin, but is not an irritant. Not a skin sensitiser.

Eye contact No specific health hazards known.

Route of entry Skin and/or eye contact. Inhalation





5,100.0

Species Rat

ATE oral (mg/kg) 5,100.0



5,100.0

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Species Rabbit

ATE dermal (mg/kg) 5,100.0



5,100.0

Species Rat

ATE inhalation (vapoursmg/l)

5,100.0


Skin corrosion/irritation Not irritating.



Not irritating.


Respiratory sensitisation Not sensitising.

Skin sensitisation

Skin sensitisation Not sensitising.


Genotoxicity - in vitro Chromosome aberration: Negative. This substance has no evidence of mutagenicproperties.

Carcinogenicity

Carcinogenicity Based on available data the classification criteria are not met.



Fertility: - , Inhalation, Rat This substance has no evidence of toxicity toreproduction.


Developmental toxicity: - : , Inhalation, Rat This substance has no evidence oftoxicity to reproduction.


STOT - repeated exposure Not available.

Aspiration hazard


Inhalation Vapours may cause drowsiness and dizziness. Central nervous system depression.

Ingestion Harmful: danger of serious damage to health by prolonged exposure if swallowed.

Skin contact Product has a defatting effect on skin. May cause allergic contact eczema.


Route of entry Inhalation Dermal

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Mixture of branched and linear C7-C9 alkyl 3-[3-(2H-benzotriazol-2-yl)-5-(1,1-dimethylethyl)-4-hydroxyphenyl]propionates



2,100.0

Species Rat




2,100.0

Species Rat



Acute toxicity inhalation(LC₅₀ dust/mist mg/l)

5.8

Species Rat

ATE inhalation(dusts/mists mg/l)

5.8




3,230.0

Species Rat




3,170.0

Species Rat





5,000.0

Species Rat



5,000.0

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Species Rabbit


Animal data Erythema/eschar score: Very slight erythema - barely perceptible (1)., Well definederythema (2). Oedema score: No oedema (0). Slightly irritating.



Not irritating.



Skin sensitisation

Skin sensitisation Guinea pig maximization test (GPMT) - Guinea pig: Not sensitising.


Genotoxicity - in vitro Chromosome aberration: Negative. This substance has no evidence of mutagenicproperties.

Carcinogenicity

Carcinogenicity , Inhalation, Rat There is no evidence that the product can cause cancer. Does notcontain any substances known to be carcinogenic.



Fertility: - , Inhalation, Rat This substance has no evidence of toxicity toreproduction.


Developmental toxicity: - : , Inhalation, Rat This substance has no evidence oftoxicity to reproduction.


STOT - repeated exposure Not available.

Aspiration hazard


Inhalation Vapours may cause drowsiness and dizziness. Central nervous system depression.

Ingestion Harmful: danger of serious damage to health by prolonged exposure if swallowed.

Skin contact Product has a defatting effect on skin. May cause allergic contact eczema.


Route of entry Inhalation Ingestion.




3,700.0

Species Rat


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8,560.0

Species Rabbit


Skin corrosion/irritation Irritating to skin.

Animal data Moderately irritating.

Dipropylene glycol dibenzoate



3,914.0

Species Rat




2,000.0

Species Rat




200.0

Species Rat


200.0


Animal data Not irritating.



Slightly irritating.

Skin sensitisation





3,523.0

Species Rat



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11.0



Severely irritating to skin. Irritation of eyes is assumed. No testing is needed.



Skin sensitisation


Carcinogenicity

Carcinogenicity There is no evidence that the product can cause cancer.



This substance has no evidence of toxicity to reproduction.

Aspiration hazard


Inhalation Harmful by inhalation.

Ingestion Pneumonia may be the result if vomited material containing solvents reaches thelungs.

Skin contact Harmful in contact with skin.

Eye contact May cause severe eye irritation.

Target organs Central nervous system Liver

2-BUTANONE OXIME

Other health effects Carcinogen Category 2.



2,528.0

Species Rat




General information Known or suspected carcinogen for humans.

Skin contact May cause sensitisation by skin contact. Harmful in contact with skin.

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PHTHALIC ANHYDRIDE



1,530.0

Species Rat




3,160.0

Species Rabbit




Moderately irritating.




10,700.0

Species Guinea pig



2,000.0

Species Rat

SECTION 12: Ecological Information

Ecological information on ingredients.

WHITE SPIRIT

Ecotoxicity Dangerous for the environment if discharged into watercourses.


Ecotoxicity The product is not expected to be hazardous to the environment.

12.1. Toxicity

Toxicity Aquatic Chronic 2 - H411 Toxic to aquatic life with long lasting effects.


WHITE SPIRIT

Toxicity Dangerous for the environment if discharged into watercourses Toxic to aquaticorganisms

Acute toxicity - fish LC₅₀, 96 hours: 10 - 30 mg/l, Onchorhynchus mykiss (Rainbow trout)

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Acute toxicity - aquaticinvertebrates

EC₅₀, 48 hours: 10 - 22 mg/l, Daphnia magna

Acute toxicity - aquaticplants

IC₅₀, 72 hours: 4.6 - 10 mg/l, Pseudokirchneriella subcapitata

Acute toxicity -microorganisms

EC₅₀, 48 hours: 43.98 mg/l, Activated sludge

Chronic toxicity - fish earlylife stage

NOEC, 28 days: 0.13 mg/l, Freshwater fish

Chronic toxicity - aquaticinvertebrates

NOEC, < 21 days: 0.28 mg/l, Daphnia magna


Acute toxicity - fish LC50, > 96 hours: 1000 mg/l, Onchorhynchus mykiss (Rainbow trout)Substance did not cause acute toxicity to fish


Substance did not cause acute toxicity to the freshwater invertebratesEC₅₀, 48 hours: >1000 mg/l, Daphnia magna


EC₅₀, > 72 hours: 1000 mg/l, Freshwater algaeSubstance did not cause acute toxicity to the freshwater green algae


EC₅₀, >: 100 mg/l, Activated sludge


NOEC, 28 days: 0.131 mg/l, Onchorhynchus mykiss (Rainbow trout)


NOEC, 28 days: 0.23 mg/l, Daphnia magna


Acute aquatic toxicity

LE(C)₅₀ 0.1 < L(E)C50 ≤ 1

M factor (Acute) 1

Chronic aquatic toxicity

M factor (Chronic) 1


Acute toxicity - fish LC50, > 96 hours: 1000 mg/l, Onchorhynchus mykiss (Rainbow trout)Substance did not cause acute toxicity to fish


Substance did not cause acute toxicity to the freshwater invertebratesEC₅₀, 48 hours: >1000 mg/l, Daphnia magna


EC₅₀, > 72 hours: 1000 mg/l, Freshwater algaeSubstance did not cause acute toxicity to the freshwater green algae


EC₅₀, >: 100 mg/l, Activated sludge

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NOEC, 28 days: 0.131 mg/l, Onchorhynchus mykiss (Rainbow trout)


NOEC, 28 days: 0.23 mg/l, Daphnia magna


Acute toxicity - fish LC50, 96 hours: 10700 mg/l, Pimephales promelas (Fat-head Minnow)


EC₅₀, 48 hours: 3200 mg/l, Daphnia magna


Acute toxicity - fish LC50, 96 hours: 3.7 mg/l,


EC₅₀, 48 hours: 19.3 mg/l, Daphnia magna


EC₅₀, 72 hours: 4.9 mg/l, Freshwater algaeNOEC, 72 hours: 1.0 mg/l, Freshwater algae


Acute toxicity - fish LC₅₀, 96 hours: 2.6 mg/l, Fish


EC₅₀, 48 hours: 3.62 mg/l, Daphnia magna


IC₅₀, 72 hours: 3.2 mg/l, Algae

2-BUTANONE OXIME

Acute toxicity - fish LC₅₀, 96 hours: >100 mg/l, Fish


EC₅₀, 48 hours: 201 mg/l, Daphnia magna


IC₅₀, 72 hours: 11.8 mg/l, Algae

PHTHALIC ANHYDRIDE


NOEC, 21 days: 16 mg/l, Daphnia magnaEC₅₀, 48 hours: >640 mg/l, Daphnia magna


NOEC, 72 hours: 32 mg/l, AlgaeNOEC, 72 hours: >100 mg/l, Algae


EC₅₀, 3 hours: >1000 mg/l, Activated sludge


Acute aquatic toxicity

LE(C)₅₀ 0.1 < L(E)C50 ≤ 1

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M factor (Acute) 1

Chronic aquatic toxicity

NOEC 0.01 < NOEC ≤ 0.1

Degradability Rapidly degradable

12.2. Persistence and degradability

Persistence and degradability The degradability of the product is not known.


WHITE SPIRIT

Persistence anddegradability

The product is readily biodegradable.

Phototransformation Scientifically unjustified.

Stability (hydrolysis) Scientifically unjustified.

Biodegradation - Degradation 75: 28 days




Phototransformation Oxidises rapidly by photo-chemical reactions in air

Biodegradation - 80 Degradation (%): 28 daysTest - 301F Ready Biodegradability - Manometric Respiratory Test




Phototransformation Oxidises rapidly by photo-chemical reactions in air

Biodegradation - 80 Degradation (%): 28 daysTest - 301F Ready Biodegradability - Manometric Respiratory Test


Biodegradation - 87 Degradation (%): 28 days

Biological oxygen demand 0.650 g O₂/g substance

Chemical oxygen demand 0.00223 g O₂/g substance




12.3. Bioaccumulative potential

Bioaccumulative potential No data available on bioaccumulation.


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WHITE SPIRIT

Bioaccumulative potential Substance is a hydrocarbon UVCB. Standard tests for this endpoint are intendedfor single substances and are not appropriate for this complex substance.

Partition coefficient Technically not feasible.


Bioaccumulative potential The product contains potentially bioaccumulating substances.

Partition coefficient log Pow: 5 - 6.7


Bioaccumulative potential The product contains potentially bioaccumulating substances.

Partition coefficient : 5 - 6.7


Partition coefficient log Pow: 0.58


Partition coefficient log Kow: 3.12 - 3.2

2-BUTANONE OXIME

Bioaccumulative potential The product is not bioaccumulating.


PHTHALIC ANHYDRIDE

Bioaccumulative potential BCF: 3.4,



Bioaccumulative potential BCF: ~ 330 to 1800,

Partition coefficient log Pow: ~ 5.1

12.4. Mobility in soil

Mobility Volatile liquid. The product contains organic solvents which will evaporate easily from allsurfaces.


WHITE SPIRIT

Adsorption/desorptioncoefficient

Scientifically unjustified.

Henry's law constant Volatilisation is dependent on Henry's Law constant (HLC) which is not applicableto complex substances.

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Surface tension 24 - 27 mN/m @ 25°C


Mobility The product contains volatile organic compounds (VOCs) which will evaporateeasily from all surfaces. Readily absorbed into soil.


Not available.

Surface tension 24.5 mN/m @ 20°C


Mobility The product contains volatile organic compounds (VOCs) which will evaporateeasily from all surfaces. Readily absorbed into soil.


Not available.

Surface tension 24.5 mN/m @ 20°C

2-BUTANONE OXIME

Mobility The product is soluble in water.

12.5. Results of PBT and vPvB assessmentEcological information on ingredients.

WHITE SPIRIT

Results of PBT and vPvBassessment

This substance is not classified as PBT or vPvB according to current EU criteria.













12.6. Other adverse effects

Other adverse effects None known.


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WHITE SPIRIT

Other adverse effects This substance may contribute to ozone formation in the near surface atmosphere.However, the photochemical formation of ozone depends on a complex interactionof other atmospheric pollutant sources and environmental conditions. Therefore,the contribution of this substance to ozone formation is outside the scope of thissubstance assessment and is more appropriately addressed via EU air qualitydirectives.


Other adverse effects Not known.


Other adverse effects Not known.

2-BUTANONE OXIME

Other adverse effects Not determined.

SECTION 13: Disposal considerations

13.1. Waste treatment methods

General information The generation of waste should be minimised or avoided wherever possible. Reuse or recycleproducts wherever possible. This material and its container must be disposed of in a safeway. Disposal of this product, process solutions, residues and by-products should at all timescomply with the requirements of environmental protection and waste disposal legislation andany local authority requirements. When handling waste, the safety precautions applying tohandling of the product should be considered. Care should be taken when handling emptiedcontainers that have not been thoroughly cleaned or rinsed out. Empty containers or linersmay retain some product residues and hence be potentially hazardous.

Disposal methods Dispose of surplus products and those that cannot be recycled via a licensed waste disposalcontractor. Waste, residues, empty containers, discarded work clothes and contaminatedcleaning materials should be collected in designated containers, labelled with their contents.Incineration or landfill should only be considered when recycling is not feasible. Vapour fromresidual product may create a highly flammable or explosive atmosphere inside the container.Containers should be thoroughly emptied before disposal because of the risk of an explosion.Do not cut or weld used containers unless they have been thoroughly cleaned internally.

SECTION 14: Transport information

14.1. UN number

UN No. (ADR/RID) 1263

14.2. UN proper shipping name14.3. Transport hazard class(es)14.4. Packing group14.5. Environmental hazards14.6. Special precautions for user14.7. Transport in bulk according to Annex II of MARPOL and the IBC Code

SECTION 15: Regulatory information

15.1. Safety, health and environmental regulations/legislation specific for the substance or mixture

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National regulations Health and Safety at Work etc. Act 1974 (as amended).The Chemicals (Hazard Information and Packaging for Supply) Regulations 2009 (SI 2009No. 716).The Carriage of Dangerous Goods and Use of Transportable Pressure EquipmentRegulations 2009 (SI 2009 No. 1348) (as amended) ["CDG 2009"].EH40/2005 Workplace exposure limits.

EU legislation Regulation (EC) No 1907/2006 of the European Parliament and of the Council of 18December 2006 concerning the Registration, Evaluation, Authorisation and Restriction ofChemicals (REACH) (as amended).Commission Regulation (EU) No 453/2010 of 20 May 2010.Regulation (EC) No 1272/2008 of the European Parliament and of the Council of 16December 2008 on classification, labelling and packaging of substances and mixtures (asamended).Dangerous Preparations Directive 1999/45/EC.Dangerous Substances Directive 67/548/EEC.

15.2. Chemical safety assessment

No chemical safety assessment has been carried out.

SECTION 16: Other information

Classification proceduresaccording to Regulation (EC)1272/2008

STOT RE 1 - H372: STOT SE 3 - H336: : Calculation method. Aquatic Chronic 2 - H411: :Calculation method. Flam. Liq. 3 - H226: : Expert judgement.

Training advice Read and follow manufacturer's recommendations. Only trained personnel should use thismaterial.

Revision comments Issued in new format for Reach compliance in accordance with EC 1272/2008 Issued inaccordance with Annex II to REACH, as amended by Commission Regulation (EU) No.453/2010 Revised formulation.

Revision date 01/12/2016

Revision 10

Supersedes date 17/09/2013

SDS number 11573

Signature Initials __________________________

Risk phrases in full Not classified.R10 Flammable.R20/21 Harmful by inhalation and in contact with skin.R36/37/38 Irritating to eyes, respiratory system and skin.R36/38 Irritating to eyes and skin.R43 May cause sensitisation by skin contact.R51/53 Toxic to aquatic organisms, may cause long-term adverse effects in the aquaticenvironment.R52/53 Harmful to aquatic organisms, may cause long-term adverse effects in the aquaticenvironment.R63 Possible risk of harm to the unborn child.R65 Harmful: may cause lung damage if swallowed.R66 Repeated exposure may cause skin dryness or cracking.R67 Vapours may cause drowsiness and dizziness.

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Hazard statements in full H226 Flammable liquid and vapour.H302 Harmful if swallowed.H304 May be fatal if swallowed and enters airways.H312 Harmful in contact with skin.H315 Causes skin irritation.H317 May cause an allergic skin reaction.H318 Causes serious eye damage.H319 Causes serious eye irritation.H332 Harmful if inhaled.H334 May cause allergy or asthma symptoms or breathing difficulties if inhaled.H335 May cause respiratory irritation.H336 May cause drowsiness or dizziness.H361d Suspected of damaging the unborn child.H372 Causes damage to organs through prolonged or repeated exposure.H372 Causes damage to organs through prolonged or repeated exposure if inhaled.H373 May cause damage to organs through prolonged or repeated exposure if inhaled.H400 Very toxic to aquatic life.H410 Very toxic to aquatic life with long lasting effects.H411 Toxic to aquatic life with long lasting effects.

This information relates only to the specific material designated and may not be valid for such material used in combinationwith any other materials or in any process. Such information is, to the best of the company's knowledge and belief, accurateand reliable as of the date indicated. However, no warranty, guarantee or representation is made to its accuracy, reliability orcompleteness. It is the user's responsibility to satisfy himself as to the suitability of such information for his own particular use.

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Documents

SAFETY DATA SHEET PM/V621 - PRECISION YACHT VARNISH · PM/V621 - PRECISION YACHT VARNISH Hazard statements H226 Flammable liquid and vapour. H317 May cause an allergic skin reaction