SAFETY DATA SHEET - University of California, Davis · ABX Pentra Iron CP - R1 SAFETY DATA SHEET Product name A91A00567E-R1 Conforms to Regulation (EC) No. 1907/2006 (REACH), Annex

ABX Pentra Iron CP - R1

SAFETY DATA SHEET

Product name

A91A00567E-R1

Conforms to Regulation (EC) No. 1907/2006 (REACH), Annex II - United Kingdom (UK)

:

1.1 Product identifier

1.3 Details of the supplier of the safety data sheet

e-mail address of personresponsible for this SDS

:

Product description : 60 mL

1.2 Relevant identified uses of the substance or mixture and uses advised against

SECTION 1: Identification of the substance/mixture and of thecompany/undertaking

1.4 Emergency telephone number

National advisory body/Poison Centre

Supplier

Telephone number : + 800 67 14 15 16

EN

Telephone number UnitedKingdom (UK)

: +44 (0)20 7771 5310

Diagnostic reagent for quantitative in-vitro determination of Iron in serum or plasma.

[email protected]

HORIBA ABX SASParc Euromédecine - Rue du CaducéeBP 729034184 MONTPELLIER CEDEX 4 - FRANCETel: +33 (0) 4 67 14 15 16Fax: +33 (0) 4 67 14 15 17

Product is part of kit A11A01637:

Classification Xi; R36:

:Human health hazards Irritating to eyes.

See Section 11 for more detailed information on health effects and symptoms.

SECTION 2: Hazards identification2.1 Classification of the substance or mixture

Product definition : Mixture

See Section 16 for the full text of the R phrases or H statements declared above.

Classification according to Directive 1999/45/EC [DPD]

The product is classified as dangerous according to Directive 1999/45/EC and its amendments.

2.2 Label elements

Hazard symbol or symbols

Safety phrases Not applicable.

R36- Irritating to eyes.Risk phrases

:

:

:

IrritantIndication of danger :

Date of issue/Date of revision : 1/1324/01/2013.



SECTION 2: Hazards identification

:Other hazards which donot result in classification

Not available.

Supplemental labelelements

: Not applicable.

2.3 Other hazards

Substance/mixture Mixture

Occupational exposure limits, if available, are listed in Section 8.

:

Identifiers 67/548/EECProduct/ingredientname

There are no additional ingredients present which, within the current knowledge of the supplier and in theconcentrations applicable, are classified as hazardous to health or the environment, are PBTs or vPvBs or have beenassigned a workplace exposure limit and hence require reporting in this section.

SECTION 3: Composition/information on ingredients

aminocaproic acid EC: 200-469-3CAS: 60-32-2

5-10 Xi; R36/37/38 Skin Irrit. 2, H315Eye Irrit. 2, H319STOT SE 3, H335

[1]

acetic acid EC: 200-580-7CAS: 64-19-7Index: 607-002-00-6

<10 R10C; R35

Flam. Liq. 3, H226Skin Corr. 1A, H314Eye Dam. 1, H318

[1] [2]

Isotridecanol,ethoxylated

EC: 500-241-6CAS: 69011-36-5

1-5 Xi; R41 Eye Dam. 1, H318 [1]

Dodecan-1-ol,ethoxylated

EC: 500-002-6CAS: 9002-92-0

3-5 Xn; R22Xi; R41, R38

Acute Tox. 4, H302Eye Dam. 1, H318

[1]

thiourea EC: 200-543-5CAS: 62-56-6Index: 612-082-00-0

0,5-1 Carc. Cat. 3; R40Repr. Cat. 3; R63Xn; R22N; R51/53

Acute Tox. 4, H302Carc. 2, H351Repr. 2, H361dAquatic Chronic 2,H411

[1]

See Section 16 forthe full text of the R-phrases declaredabove.

% TypeRegulation (EC) No.1272/2008 [CLP]

Classification

See Section 16 for thefull text of the Hstatements declaredabove.

[1] Substance classified with a health or environmental hazard[2] Substance with a workplace exposure limit[3] Substance meets the criteria for PBT according to Regulation (EC) No. 1907/2006, Annex XIII[4] Substance meets the criteria for vPvB according to Regulation (EC) No. 1907/2006, Annex XIII

Type

Immediately flush eyes with plenty of water, occasionally lifting the upper and lowereyelids. Check for and remove any contact lenses. Continue to rinse for at least 10minutes. Get medical attention.

4.1 Description of first aid measures

Eye contact :

SECTION 4: First aid measures





Wash out mouth with water. Remove dentures if any. Remove victim to fresh airand keep at rest in a position comfortable for breathing. If material has beenswallowed and the exposed person is conscious, give small quantities of water todrink. Stop if the exposed person feels sick as vomiting may be dangerous. Do notinduce vomiting unless directed to do so by medical personnel. If vomiting occurs,the head should be kept low so that vomit does not enter the lungs. Get medicalattention if adverse health effects persist or are severe. Never give anything bymouth to an unconscious person. If unconscious, place in recovery position and getmedical attention immediately. Maintain an open airway. Loosen tight clothing suchas a collar, tie, belt or waistband.

Skin contact Flush contaminated skin with plenty of water. Remove contaminated clothing andshoes. Get medical attention if symptoms occur. Wash clothing before reuse.Clean shoes thoroughly before reuse.

Remove victim to fresh air and keep at rest in a position comfortable for breathing. Ifnot breathing, if breathing is irregular or if respiratory arrest occurs, provide artificialrespiration or oxygen by trained personnel. It may be dangerous to the personproviding aid to give mouth-to-mouth resuscitation. Get medical attention if adversehealth effects persist or are severe. If unconscious, place in recovery position andget medical attention immediately. Maintain an open airway. Loosen tight clothingsuch as a collar, tie, belt or waistband. In case of inhalation of decompositionproducts in a fire, symptoms may be delayed. The exposed person may need to bekept under medical surveillance for 48 hours.

Notes to physician In case of inhalation of decomposition products in a fire, symptoms may be delayed.The exposed person may need to be kept under medical surveillance for 48 hours.

Ingestion

Inhalation :

:

:

:

Specific treatments

Protection of first-aiders : No action shall be taken involving any personal risk or without suitable training. Itmay be dangerous to the person providing aid to give mouth-to-mouth resuscitation.

4.2 Most important symptoms and effects, both acute and delayed

Potential acute health effects

Inhalation : Exposure to decomposition products may cause a health hazard. Serious effectsmay be delayed following exposure.

No known significant effects or critical hazards.:Ingestion

Skin contact : No known significant effects or critical hazards.

Irritating to eyes.:Eye contact

Over-exposure signs/symptoms

Skin contact

Ingestion

Inhalation No specific data.

No specific data.

No specific data.

:

:

:

Eye contact : Adverse symptoms may include the following:irritationwateringredness

4.3 Indication of any immediate medical attention and special treatment needed

No specific treatment.:


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Promptly isolate the scene by removing all persons from the vicinity of the incident ifthere is a fire. No action shall be taken involving any personal risk or without suitabletraining.

Hazardous thermaldecomposition products

Hazards from thesubstance or mixture

Decomposition products may include the following materials:carbon dioxidecarbon monoxidenitrogen oxides

In a fire or if heated, a pressure increase will occur and the container may burst.

Fire-fighters should wear appropriate protective equipment and self-containedbreathing apparatus (SCBA) with a full face-piece operated in positive pressuremode. Clothing for fire-fighters (including helmets, protective boots and gloves)conforming to European standard EN 469 will provide a basic level of protection forchemical incidents.

Special protectiveequipment for fire-fighters

Use an extinguishing agent suitable for the surrounding fire.

5.1 Extinguishing media

:

:

:

None known.

Suitable extinguishingmedia

:

Unsuitable extinguishingmedia

:

SECTION 5: Firefighting measures

5.2 Special hazards arising from the substance or mixture

5.3 Advice for firefighters

Special protective actionsfor fire-fighters

:

6.2 Environmentalprecautions

Stop leak if without risk. Move containers from spill area. Approach the releasefrom upwind. Prevent entry into sewers, water courses, basements or confinedareas. Wash spillages into an effluent treatment plant or proceed as follows.Contain and collect spillage with non-combustible, absorbent material e.g. sand,earth, vermiculite or diatomaceous earth and place in container for disposalaccording to local regulations. Dispose of via a licensed waste disposal contractor.Contaminated absorbent material may pose the same hazard as the spilt product.

Avoid dispersal of spilt material and runoff and contact with soil, waterways, drainsand sewers. Inform the relevant authorities if the product has caused environmentalpollution (sewers, waterways, soil or air).

Large spill :

Stop leak if without risk. Move containers from spill area. Dilute with water and mopup if water-soluble. Alternatively, or if water-insoluble, absorb with an inert drymaterial and place in an appropriate waste disposal container. Dispose of via alicensed waste disposal contractor.

Small spill :

6.3 Methods and materials for containment and cleaning up

SECTION 6: Accidental release measures6.1 Personal precautions, protective equipment and emergency procedures

For non-emergencypersonnel

:

For emergency responders :

No action shall be taken involving any personal risk or without suitable training.Evacuate surrounding areas. Keep unnecessary and unprotected personnel fromentering. Do not touch or walk through spilt material. Avoid breathing vapour ormist. Provide adequate ventilation. Wear appropriate respirator when ventilation isinadequate. Put on appropriate personal protective equipment.

If specialised clothing is required to deal with the spillage, take note of anyinformation in Section 8 on suitable and unsuitable materials. See also Section 8 foradditional information on hygiene measures.

:




SECTION 6: Accidental release measures6.4 Reference to othersections

See Section 1 for emergency contact information.See Section 8 for information on appropriate personal protective equipment.See Section 13 for additional waste treatment information.

:

Store between the following temperatures: 2 to 8°C (35,6 to 46,4°F). Store inaccordance with local regulations. Store in original container protected from directsunlight in a dry, cool and well-ventilated area, away from incompatible materials(see section 10) and food and drink. Keep container tightly closed and sealed untilready for use. Containers that have been opened must be carefully resealed andkept upright to prevent leakage. Do not store in unlabelled containers. Useappropriate containment to avoid environmental contamination.

SECTION 7: Handling and storageThe information in this section contains generic advice and guidance. The list of Identified Uses in Section 1 should beconsulted for any available use-specific information provided in the Exposure Scenario(s).

7.1 Precautions for safe handling

Protective measures :

Advice on generaloccupational hygiene

:

7.2 Conditions for safestorage, including anyincompatibilities

7.3 Specific end use(s)

Recommendations :

:Industrial sector specificsolutions

Not available.

Not available.

Put on appropriate personal protective equipment (see Section 8). Do not ingest.Avoid contact with eyes, skin and clothing. Avoid breathing vapour or mist. Keep inthe original container or an approved alternative made from a compatible material,kept tightly closed when not in use. Empty containers retain product residue and canbe hazardous. Do not reuse container.

Eating, drinking and smoking should be prohibited in areas where this material ishandled, stored and processed. Workers should wash hands and face beforeeating, drinking and smoking. Remove contaminated clothing and protectiveequipment before entering eating areas. See also Section 8 for additionalinformation on hygiene measures.

:

Store away from light.Other information :

Product/ingredient name Exposure limit values

Recommended monitoringprocedures

Occupational exposure limits

If this product contains ingredients with exposure limits, personal, workplaceatmosphere or biological monitoring may be required to determine the effectivenessof the ventilation or other control measures and/or the necessity to use respiratoryprotective equipment. Reference should be made to European Standard EN 689 formethods for the assessment of exposure by inhalation to chemical agents andnational guidance documents for methods for the determination of hazardoussubstances.

:

acetic acid EU OEL (Europe, 12/2009). Notes: list of indicativeoccupational exposure limit values

TWA: 10 ppm 8 hour(s). TWA: 25 mg/m³ 8 hour(s).

SECTION 8: Exposure controls/personal protectionThe information in this section contains generic advice and guidance. The list of Identified Uses in Section 1 should beconsulted for any available use-specific information provided in the Exposure Scenario(s).

8.1 Control parameters




SECTION 8: Exposure controls/personal protection

Hand protection

Use a properly fitted, air-purifying or air-fed respirator complying with an approvedstandard if a risk assessment indicates this is necessary. Respirator selection mustbe based on known or anticipated exposure levels, the hazards of the product andthe safe working limits of the selected respirator.

Chemical-resistant, impervious gloves complying with an approved standard shouldbe worn at all times when handling chemical products if a risk assessment indicatesthis is necessary. >8 hours (breakthrough time): Protective gloves according to EN374 nitrile rubber

Safety eyewear complying with an approved standard should be used when a riskassessment indicates this is necessary to avoid exposure to liquid splashes, mistsor dusts. Recommended: Tighly sealed goggles according to EN 166

Eye/face protection

Respiratory protection :

:

:

Skin protection

Personal protective equipment for the body should be selected based on the taskbeing performed and the risks involved and should be approved by a specialistbefore handling this product.

:

Environmental exposurecontrols

: Emissions from ventilation or work process equipment should be checked to ensurethey comply with the requirements of environmental protection legislation. In somecases, fume scrubbers, filters or engineering modifications to the processequipment will be necessary to reduce emissions to acceptable levels.

Appropriate engineeringcontrols

: No special ventilation requirements. Good general ventilation should be sufficient tocontrol worker exposure to airborne contaminants. If this product containsingredients with exposure limits, use process enclosures, local exhaust ventilation orother engineering controls to keep worker exposure below any recommended orstatutory limits.

Wash hands, forearms and face thoroughly after handling chemical products, beforeeating, smoking and using the lavatory and at the end of the working period.Appropriate techniques should be used to remove potentially contaminated clothing.Wash contaminated clothing before reusing. Ensure that eyewash stations andsafety showers are close to the workstation location.

8.2 Exposure controls

Hygiene measures :

No DELs available.

Predicted effect concentrations

No PECs available.

Derived effect levels

Individual protection measures

Body protection :

Other skin protection Appropriate footwear and any additional skin protection measures should beselected based on the task being performed and the risks involved and should beapproved by a specialist before handling this product.

Not available.

Physical state

Melting point/freezing point

Initial boiling point and boilingrange

Liquid.

Not available.

Acetic acid.Odour

pH

Colourless to light yellow.Colour

4,5

Not available.Odour threshold

:

:

:

:

:

:

:

9.1 Information on basic physical and chemical properties

Appearance

SECTION 9: Physical and chemical properties





Vapour pressure

Relative density

Vapour density

Solubility(ies)

1,049 g/cm3 [20°C (68°F)]

Not available.

Not available.

Easily soluble in the following materials: cold water and hot water.

Evaporation rate Not available.

Auto-ignition temperature

Flash point

Not applicable.

Not applicable.

Not available.

Not available.

Not available.

Viscosity Not available.

Partition coefficient: n-octanol/water

Upper/lower flammability orexplosive limits

Explosive properties

:

:

:

:

:

:

:

:

:

:

:

Not available.Oxidising properties :

9.2 Other information

Decomposition temperature : Not available.

No additional information.

Flammability : Non-flammable.

10.6 Hazardousdecomposition products

10.4 Conditions to avoid No specific data.

Under normal conditions of storage and use, hazardous decomposition productsshould not be produced.

The product is stable.10.2 Chemical stability

No specific data.

:

:

:

10.5 Incompatible materials :

10.3 Possibility ofhazardous reactions

: Under normal conditions of storage and use, hazardous reactions will not occur.

SECTION 10: Stability and reactivity10.1 Reactivity : No specific test data related to reactivity available for this product or its ingredients.

Acute toxicity

acetic acid LC50 Inhalation Vapour Rat 11000 mg/m3 4 hoursLD50 Dermal Rabbit 1060 mg/kg -LD50 Oral Rat 3310 mg/kg -

Product/ingredient name Result Species Dose Exposure

Irritation/Corrosion

Product/ingredient name Result Score Exposure ObservationSpecies

SECTION 11: Toxicological information11.1 Information on toxicological effects




SECTION 11: Toxicological information


Inhalation : Exposure to decomposition products may cause a health hazard. Serious effectsmay be delayed following exposure.

:Ingestion

Skin contact :

:Eye contact

Carcinogenicity

No known significant effects or critical hazards.

Mutagenicity


Teratogenicity


Reproductive toxicity


Symptoms related to the physical, chemical and toxicological characteristics

Skin contact

Ingestion


:

:

:

Eye contact :

aminocaproic acid Eyes - Mild irritant Rabbit - 24 hours 500milligrams

-

acetic acid Eyes - Mild irritant Rabbit - 0,5 minutes 5milligrams

-

Skin - Mild irritant Human - 24 hours 50milligrams

-

Skin - Mild irritant Rabbit - 24 hours 50milligrams

-

Skin - Severe irritant Rabbit - 525milligrams

-

Dodecan-1-ol, ethoxylated Eyes - Severe irritant Rabbit - 24 hours 750Micrograms

-

Skin - Moderate irritant Human - 72 hours 6milligramsIntermittent

-

Skin - Mild irritant Rabbit - 24 hours 500milligrams

-

Skin - Moderate irritant Rabbit - 24 hours 500milligrams

-

Sensitisation


Not available.Information on the likelyroutes of exposure

:

Delayed and immediate effects and also chronic effects from short and long term exposure

No specific data.

No specific data.

Adverse symptoms may include the following:irritationwateringredness



Irritating to eyes.





Potential chronic health effects

No known significant effects or critical hazards.General :

No known significant effects or critical hazards.Carcinogenicity :

No known significant effects or critical hazards.Mutagenicity :

No known significant effects or critical hazards.Teratogenicity :


Developmental effects : No known significant effects or critical hazards.

Fertility effects : No known significant effects or critical hazards.

Short term exposure

Long term exposure

Potential immediateeffects

Potential delayed effects :

:



:

Other information :

Not available.

Not available.

Not available.

Not available.

Not available.

LogPow BCF Potential

12.3 Bioaccumulative potential

Product/ingredient name

aminocaproic acid -2,95 - lowacetic acid -0,31 - lowthiourea -2.38 to 0.95 1,995262314 low

12.1 Toxicity

acetic acid Acute EC50 73400 ug/L Fresh water Algae - Navicula seminulum 96 hoursAcute EC50 65000 ug/L Fresh water Daphnia - Daphnia magna -

Neonate - <24 hours48 hours

Acute LC50 50,1 ul/L Marine water Crustaceans - Artemia sp. 48 hoursAcute LC50 75000 ug/L Fresh water Fish - Lepomis macrochirus -

5,3 to 7,2 cm - 3,5 to 3,9 g96 hours

Dodecan-1-ol, ethoxylated Acute LC50 1000 to 2500 ug/L Crustaceans - Idotea balthica 48 hoursAcute LC50 6460 ug/L Fresh water Daphnia - Daphnia magna 48 hoursAcute LC50 1500 ug/L Fresh water Fish - Salmo salar - Parr - 8,2 to

11,7 cm - 5,1 to 14,1 g96 hours

thiourea Acute EC50 4800 ug/L Fresh water Algae - Scenedesmus abundans 96 hoursAcute LC50 9000 ug/L Fresh water Daphnia - Daphnia magna - <24

hours48 hours

Product/ingredient name SpeciesResult Exposure

12.2 Persistence and degradability

SECTION 12: Ecological information

12.4 Mobility in soil

Conclusion/Summary : Not available.





Mobility Not available.:

12.6 Other adverse effects No known significant effects or critical hazards.

PBT : Not applicable.

vPvB : Not applicable.

Soil/water partitioncoefficient (KOC)

Not available.:

12.5 Results of PBT and vPvB assessment

:

The classification of the product may meet the criteria for a hazardous waste.Hazardous waste :

:Methods of disposal

SECTION 13: Disposal considerationsThe information in this section contains generic advice and guidance. The list of Identified Uses in Section 1 should beconsulted for any available use-specific information provided in the Exposure Scenario(s).

13.1 Waste treatment methods

Product

Packaging

Methods of disposal :

Special precautions :

The generation of waste should be avoided or minimised wherever possible. Wastepackaging should be recycled. Incineration or landfill should only be consideredwhen recycling is not feasible.

This material and its container must be disposed of in a safe way. Care should betaken when handling emptied containers that have not been cleaned or rinsed out.Empty containers or liners may retain some product residues. Avoid dispersal ofspilt material and runoff and contact with soil, waterways, drains and sewers.

The generation of waste should be avoided or minimised wherever possible.Significant quantities of waste product residues should not be disposed of via thefoul sewer but processed in a suitable effluent treatment plant. Dispose of surplusand non-recyclable products via a licensed waste disposal contractor. Disposal ofthis product, solutions and any by-products should at all times comply with therequirements of environmental protection and waste disposal legislation and anyregional local authority requirements.

-

-

-

-

-

-

-

Not regulated.

--

-

-

Not regulated.

-

Not regulated. Not regulated.

SECTION 14: Transport information

ADR/RID IMDG IATA

14.1 UN number

14.2 UN propershipping name

14.3 Transporthazard class(es)

14.4 Packinggroup

ADN/ADNR

14.5Environmentalhazards

No. No. No. No.





- - - -Additionalinformation

14.6 Specialprecautions foruser

Not available. Not available. Not available. Not available.

Other EU regulations

Not applicable.Annex XVII - Restrictionson the manufacture,placing on the market anduse of certain dangeroussubstances, mixtures andarticles

:

Europe inventory : All components are listed or exempted.

Black List Chemicals : Not listed

Priority List Chemicals : Not listed

Integrated pollutionprevention and controllist (IPPC) - Air

: Not listed

Integrated pollutionprevention and controllist (IPPC) - Water

: Not listed

Chemical WeaponsConvention List Schedule IChemicals

: Not listed

Chemical WeaponsConvention List Schedule IIChemicals

: Not listed

Chemical WeaponsConvention List Schedule IIIChemicals

: Not listed

International regulations

SECTION 15: Regulatory information15.1 Safety, health and environmental regulations/legislation specific for the substance or mixture

EU Regulation (EC) No. 1907/2006 (REACH)

Annex XIV - List of substances subject to authorisation

Product/ingredient name Carcinogeniceffects

Mutagenic effects Developmentaleffects

Fertility effects

thiourea Carc. Cat. 3; R40 - Repr. Cat. 3; R63 -

15.2 Chemical SafetyAssessment

This product contains substances for which Chemical Safety Assessments are stillrequired.

Substances of very high concern

:

None of the components are listed.




24/01/2013.Date of printing

Date of issue/ Date ofrevision

:

:

R10- Flammable.R40- Limited evidence of a carcinogenic effect.R63- Possible risk of harm to the unborn child.R22- Harmful if swallowed.R35- Causes severe burns.R41- Risk of serious damage to eyes.R36- Irritating to eyes.R38- Irritating to skin.R36/37/38- Irritating to eyes, respiratory system and skin.R51/53- Toxic to aquatic organisms, may cause long-term adverse effects in theaquatic environment.

:Full text of abbreviated Rphrases

Carc. Cat. 3 - Carcinogen category 3Repr. Cat. 3 - Toxic to reproduction category 3C - CorrosiveXn - HarmfulXi - IrritantN - Dangerous for the environment

:Full text of classifications[DSD/DPD]

Revision comments :

Indicates information that has changed from previously issued version.

24/01/2013.

SECTION 16: Other information

Full text of abbreviated Hstatements

:

Abbreviations andacronyms

: ATE = Acute Toxicity EstimateCLP = Classification, Labelling and Packaging Regulation [Regulation (EC) No.1272/2008]DNEL = Derived No Effect LevelEUH statement = CLP-specific Hazard statementPNEC = Predicted No Effect ConcentrationRRN = REACH Registration Number

Classification according to Regulation (EC) No. 1272/2008 [CLP/GHS]

Procedure used to derive the classification according to Regulation (EC) No. 1272/2008 [CLP/GHS]

Classification Justification

Eye Dam. 1, H318 Calculation method

Full text of classifications[CLP/GHS]

:

H226 Flammable liquid and vapour.H302 Harmful if swallowed.H314 Causes severe skin burns and eye damage.H315 Causes skin irritation.H318 Causes serious eye damage.H319 Causes serious eye irritation.H335 May cause respiratory irritation.H351 Suspected of causing cancer.H361d Suspected of damaging the unborn child.H411 Toxic to aquatic life with long lasting effects.

Acute Tox. 4, H302 ACUTE TOXICITY: ORAL - Category 4Aquatic Chronic 2, H411 AQUATIC TOXICITY (CHRONIC) - Category 2Carc. 2, H351 CARCINOGENICITY - Category 2Eye Dam. 1, H318 SERIOUS EYE DAMAGE/ EYE IRRITATION - Category 1Eye Irrit. 2, H319 SERIOUS EYE DAMAGE/ EYE IRRITATION - Category 2Flam. Liq. 3, H226 FLAMMABLE LIQUIDS - Category 3Repr. 2, H361d TOXIC TO REPRODUCTION [Unborn child] - Category 2Skin Corr. 1A, H314 SKIN CORROSION/IRRITATION - Category 1ASkin Irrit. 2, H315 SKIN CORROSION/IRRITATION - Category 2STOT SE 3, H335 SPECIFIC TARGET ORGAN TOXICITY (SINGLE

EXPOSURE) [Respiratory tract irritation] - Category 3

Eye Dam. 1, H318

New MSDS form.





Version

To the best of our knowledge, the information contained herein is accurate. However, neither the above-namedsupplier, nor any of its subsidiaries, assumes any liability whatsoever for the accuracy or completeness of theinformation contained herein.Final determination of suitability of any material is the sole responsibility of the user. All materials may presentunknown hazards and should be used with caution. Although certain hazards are described herein, we cannotguarantee that these are the only hazards that exist.

Notice to reader

: 1



SAFETY DATA SHEET

Product name

A91A00567E-R2


:

1.1 Product identifier

1.3 Details of the supplier of the safety data sheet

e-mail address of personresponsible for this SDS

:

Product description : 20 mL

1.2 Relevant identified uses of the substance or mixture and uses advised against

SECTION 1: Identification of the substance/mixture and of thecompany/undertaking

1.4 Emergency telephone number

National advisory body/Poison Centre

Supplier

Telephone number : + 800 67 14 15 16

EN

Telephone number UnitedKingdom (UK)

: +44 (0)20 7771 5310

Diagnostic reagent for quantitative in-vitro determination of Iron in serum or plasma.

[email protected]

HORIBA ABX SASParc Euromédecine - Rue du CaducéeBP 729034184 MONTPELLIER CEDEX 4 - FRANCETel: +33 (0) 4 67 14 15 16Fax: +33 (0) 4 67 14 15 17

Product is part of kit A11A01637:

Classification Not classified.:

See Section 11 for more detailed information on health effects and symptoms.

SECTION 2: Hazards identification2.1 Classification of the substance or mixture

Product definition : Mixture

See Section 16 for the full text of the R phrases or H statements declared above.

Classification according to Directive 1999/45/EC [DPD]

The product is not classified as dangerous according to Directive 1999/45/EC and its amendments.

2.2 Label elements

Supplemental labelelements

: Not applicable.

Hazard symbol or symbols

Safety phrases Not applicable.

This product is not classified according to EU legislation.Risk phrases

:

:

:

Not applicable.Indication of danger :

2.3 Other hazards




SECTION 2: Hazards identification:Other hazards which do

not result in classificationNot available.

Substance/mixture Mixture:

SECTION 3: Composition/information on ingredients

[1] Substance classified with a health or environmental hazard[2] Substance with a workplace exposure limit[3] Substance meets the criteria for PBT according to Regulation (EC) No. 1907/2006, Annex XIII[4] Substance meets the criteria for vPvB according to Regulation (EC) No. 1907/2006, Annex XIII

Type

Wash out mouth with water. Remove victim to fresh air and keep at rest in a positioncomfortable for breathing. If material has been swallowed and the exposed personis conscious, give small quantities of water to drink. Do not induce vomiting unlessdirected to do so by medical personnel. Get medical attention if symptoms occur.

Skin contact

Immediately flush eyes with plenty of water, occasionally lifting the upper and lowereyelids. Check for and remove any contact lenses. Get medical attention if irritationoccurs.

Flush contaminated skin with plenty of water. Remove contaminated clothing andshoes. Get medical attention if symptoms occur.

4.1 Description of first aid measures

Remove victim to fresh air and keep at rest in a position comfortable for breathing.Get medical attention if symptoms occur.

Notes to physician Treat symptomatically. Contact poison treatment specialist immediately if largequantities have been ingested or inhaled.

Ingestion

Inhalation

Eye contact

:

:

:

:

:

Specific treatments

Protection of first-aiders : No action shall be taken involving any personal risk or without suitable training.


4.2 Most important symptoms and effects, both acute and delayed


Inhalation : No known significant effects or critical hazards.

No known significant effects or critical hazards.:Ingestion

Skin contact : No known significant effects or critical hazards.

No known significant effects or critical hazards.:Eye contact

Over-exposure signs/symptoms

Skin contact

Ingestion


No specific data.

No specific data.

:

:

:

Eye contact : No specific data.

4.3 Indication of any immediate medical attention and special treatment needed

No specific treatment.:


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Promptly isolate the scene by removing all persons from the vicinity of the incident ifthere is a fire. No action shall be taken involving any personal risk or without suitabletraining.

Hazardous thermaldecomposition products

Hazards from thesubstance or mixture

Decomposition products may include the following materials:carbon dioxidecarbon monoxide

In a fire or if heated, a pressure increase will occur and the container may burst.

Fire-fighters should wear appropriate protective equipment and self-containedbreathing apparatus (SCBA) with a full face-piece operated in positive pressuremode. Clothing for fire-fighters (including helmets, protective boots and gloves)conforming to European standard EN 469 will provide a basic level of protection forchemical incidents.

Special protectiveequipment for fire-fighters

Use an extinguishing agent suitable for the surrounding fire.

5.1 Extinguishing media

:

:

:

None known.

Suitable extinguishingmedia

:

Unsuitable extinguishingmedia

:

SECTION 5: Firefighting measures

5.2 Special hazards arising from the substance or mixture

5.3 Advice for firefighters

Special protective actionsfor fire-fighters

:

6.2 Environmentalprecautions

Stop leak if without risk. Move containers from spill area. Prevent entry into sewers,water courses, basements or confined areas. Wash spillages into an effluenttreatment plant or proceed as follows. Contain and collect spillage with non-combustible, absorbent material e.g. sand, earth, vermiculite or diatomaceous earthand place in container for disposal according to local regulations. Dispose of via alicensed waste disposal contractor.

Avoid dispersal of spilt material and runoff and contact with soil, waterways, drainsand sewers. Inform the relevant authorities if the product has caused environmentalpollution (sewers, waterways, soil or air).

Large spill :

Stop leak if without risk. Move containers from spill area. Dilute with water and mopup if water-soluble. Alternatively, or if water-insoluble, absorb with an inert drymaterial and place in an appropriate waste disposal container. Dispose of via alicensed waste disposal contractor.

Small spill :

6.3 Methods and materials for containment and cleaning up

SECTION 6: Accidental release measures6.1 Personal precautions, protective equipment and emergency procedures

For non-emergencypersonnel

:

For emergency responders :

6.4 Reference to othersections

See Section 1 for emergency contact information.See Section 8 for information on appropriate personal protective equipment.See Section 13 for additional waste treatment information.

No action shall be taken involving any personal risk or without suitable training.Evacuate surrounding areas. Keep unnecessary and unprotected personnel fromentering. Do not touch or walk through spilt material. Put on appropriate personalprotective equipment.

If specialised clothing is required to deal with the spillage, take note of anyinformation in Section 8 on suitable and unsuitable materials. See also Section 8 foradditional information on hygiene measures.

:

:




SECTION 6: Accidental release measures

Store between the following temperatures: 2 to 8°C (35,6 to 46,4°F). Store inaccordance with local regulations. Store in original container protected from directsunlight in a dry, cool and well-ventilated area, away from incompatible materials(see section 10) and food and drink. Keep container tightly closed and sealed untilready for use. Containers that have been opened must be carefully resealed andkept upright to prevent leakage. Do not store in unlabelled containers. Useappropriate containment to avoid environmental contamination.

SECTION 7: Handling and storageThe information in this section contains generic advice and guidance. The list of Identified Uses in Section 1 should beconsulted for any available use-specific information provided in the Exposure Scenario(s).

7.1 Precautions for safe handling

Protective measures :

Advice on generaloccupational hygiene

:

7.2 Conditions for safestorage, including anyincompatibilities

7.3 Specific end use(s)

Recommendations :

:Industrial sector specificsolutions

Not available.

Not available.

Put on appropriate personal protective equipment (see Section 8).

Eating, drinking and smoking should be prohibited in areas where this material ishandled, stored and processed. Workers should wash hands and face beforeeating, drinking and smoking. Remove contaminated clothing and protectiveequipment before entering eating areas. See also Section 8 for additionalinformation on hygiene measures.

:

Store away from light.Other information :

Recommended monitoringprocedures

Occupational exposure limits

If this product contains ingredients with exposure limits, personal, workplaceatmosphere or biological monitoring may be required to determine the effectivenessof the ventilation or other control measures and/or the necessity to use respiratoryprotective equipment. Reference should be made to European Standard EN 689 formethods for the assessment of exposure by inhalation to chemical agents andnational guidance documents for methods for the determination of hazardoussubstances.

:

No exposure limit value known.

8.2 Exposure controls

No DELs available.

Predicted effect concentrations

No PECs available.

SECTION 8: Exposure controls/personal protectionThe information in this section contains generic advice and guidance. The list of Identified Uses in Section 1 should beconsulted for any available use-specific information provided in the Exposure Scenario(s).

8.1 Control parameters

Derived effect levels




SECTION 8: Exposure controls/personal protection

Hand protection

Use a properly fitted, air-purifying or air-fed respirator complying with an approvedstandard if a risk assessment indicates this is necessary. Respirator selection mustbe based on known or anticipated exposure levels, the hazards of the product andthe safe working limits of the selected respirator.

Chemical-resistant, impervious gloves complying with an approved standard shouldbe worn at all times when handling chemical products if a risk assessment indicatesthis is necessary. >8 hours (breakthrough time): Protective gloves according to EN374 nitrile rubber

Safety eyewear complying with an approved standard should be used when a riskassessment indicates this is necessary to avoid exposure to liquid splashes, mistsor dusts. Recommended: Tighly sealed goggles according to EN 166

Eye/face protection

Respiratory protection :

:

:

Skin protection

Personal protective equipment for the body should be selected based on the taskbeing performed and the risks involved and should be approved by a specialistbefore handling this product.

:

Environmental exposurecontrols

: Emissions from ventilation or work process equipment should be checked to ensurethey comply with the requirements of environmental protection legislation. In somecases, fume scrubbers, filters or engineering modifications to the processequipment will be necessary to reduce emissions to acceptable levels.

Appropriate engineeringcontrols

: No special ventilation requirements. Good general ventilation should be sufficient tocontrol worker exposure to airborne contaminants. If this product containsingredients with exposure limits, use process enclosures, local exhaust ventilation orother engineering controls to keep worker exposure below any recommended orstatutory limits.

Wash hands, forearms and face thoroughly after handling chemical products, beforeeating, smoking and using the lavatory and at the end of the working period.Appropriate techniques should be used to remove potentially contaminated clothing.Wash contaminated clothing before reusing. Ensure that eyewash stations andsafety showers are close to the workstation location.

Hygiene measures :

Individual protection measures

Body protection :

Other skin protection Appropriate footwear and any additional skin protection measures should beselected based on the task being performed and the risks involved and should beapproved by a specialist before handling this product.

Not available.

Physical state

Melting point/freezing point

Initial boiling point and boilingrange

Vapour pressure

Liquid.

Not available.

Not available.

Sulphurous.Odour

pH

Yellow.Colour

Evaporation rate Not available.

Flash point Not applicable.

Not available.

2,5

Not available.Odour threshold

Upper/lower flammability orexplosive limits

:

:

:

:

:

:

:

:

:

:

:

9.1 Information on basic physical and chemical properties

Appearance


Flammability : Non-flammable.





Relative density

Vapour density

Solubility(ies)

1,022 g/cm3 [20°C (68°F)]

Not available.

Easily soluble in the following materials: cold water and hot water.

Auto-ignition temperature Not applicable.

Not available.

Not available.

Viscosity Not available.

Partition coefficient: n-octanol/water

Explosive properties

:

:

:

:

:

:

:

Not available.Oxidising properties :

9.2 Other information

Decomposition temperature : Not available.

No additional information.

10.6 Hazardousdecomposition products

10.4 Conditions to avoid No specific data.

Under normal conditions of storage and use, hazardous decomposition productsshould not be produced.

The product is stable.10.2 Chemical stability

No specific data.

:

:

:

10.5 Incompatible materials :

10.3 Possibility ofhazardous reactions

: Under normal conditions of storage and use, hazardous reactions will not occur.

SECTION 10: Stability and reactivity10.1 Reactivity : No specific test data related to reactivity available for this product or its ingredients.

Acute toxicity


Carcinogenicity


Mutagenicity


Reproductive toxicity


Irritation/Corrosion


Sensitisation


SECTION 11: Toxicological information11.1 Information on toxicological effects





Potential chronic health effects


Inhalation : No known significant effects or critical hazards.

:Ingestion

Skin contact :

:Eye contact

No known significant effects or critical hazards.General :

No known significant effects or critical hazards.Carcinogenicity :

No known significant effects or critical hazards.Mutagenicity :

No known significant effects or critical hazards.Teratogenicity :


Teratogenicity


Developmental effects : No known significant effects or critical hazards.

Fertility effects : No known significant effects or critical hazards.

Symptoms related to the physical, chemical and toxicological characteristics

Skin contact

Ingestion


:

:

:

Eye contact :

Not available.Information on the likelyroutes of exposure

:

Delayed and immediate effects and also chronic effects from short and long term exposure

Short term exposure

Long term exposure



:



:

Other information :

Not available.

Not available.

Not available.

Not available.

Not available.

No specific data.

No specific data.

No specific data.




12.1 Toxicity

12.2 Persistence and degradability








Mobility Not available.:

12.3 Bioaccumulative potential

12.6 Other adverse effects No known significant effects or critical hazards.

Not available.

PBT : Not applicable.

vPvB : Not applicable.

12.4 Mobility in soil

Soil/water partitioncoefficient (KOC)

Not available.:

12.5 Results of PBT and vPvB assessment

:

Within the present knowledge of the supplier, this product is not regarded ashazardous waste, as defined by EU Directive 91/689/EEC.

Hazardous waste :

:Methods of disposal

SECTION 13: Disposal considerationsThe information in this section contains generic advice and guidance. The list of Identified Uses in Section 1 should beconsulted for any available use-specific information provided in the Exposure Scenario(s).

13.1 Waste treatment methods

Product

Packaging

Methods of disposal :

Special precautions :

The generation of waste should be avoided or minimised wherever possible. Wastepackaging should be recycled. Incineration or landfill should only be consideredwhen recycling is not feasible.

This material and its container must be disposed of in a safe way. Empty containersor liners may retain some product residues. Avoid dispersal of spilt material andrunoff and contact with soil, waterways, drains and sewers.

The generation of waste should be avoided or minimised wherever possible.Significant quantities of waste product residues should not be disposed of via thefoul sewer but processed in a suitable effluent treatment plant. Dispose of surplusand non-recyclable products via a licensed waste disposal contractor. Disposal ofthis product, solutions and any by-products should at all times comply with therequirements of environmental protection and waste disposal legislation and anyregional local authority requirements.

-

-

-

-

-

Not regulated.

--

-

Not regulated.Not regulated. Not regulated.


ADR/RID IMDG IATA

14.1 UN number

14.2 UN propershipping name

14.3 Transporthazard class(es)

ADN/ADNR




SECTION 14: Transport information- -- -

- - - -

14.4 Packinggroup

Additionalinformation

14.5Environmentalhazards

14.6 Specialprecautions foruser

No. No. No. No.

Not available. Not available. Not available. Not available.

Other EU regulations

Not applicable.Annex XVII - Restrictionson the manufacture,placing on the market anduse of certain dangeroussubstances, mixtures andarticles

:

Europe inventory : All components are listed or exempted.

Black List Chemicals : Not listed

Priority List Chemicals : Not listed

Integrated pollutionprevention and controllist (IPPC) - Air

: Not listed

Integrated pollutionprevention and controllist (IPPC) - Water

: Not listed

Chemical WeaponsConvention List Schedule IChemicals

: Not listed

Chemical WeaponsConvention List Schedule IIChemicals

: Not listed

Chemical WeaponsConvention List Schedule IIIChemicals

: Not listed

International regulations

SECTION 15: Regulatory information15.1 Safety, health and environmental regulations/legislation specific for the substance or mixture

EU Regulation (EC) No. 1907/2006 (REACH)

Annex XIV - List of substances subject to authorisation

15.2 Chemical SafetyAssessment

This product contains substances for which Chemical Safety Assessments are stillrequired.

Substances of very high concern

:

None of the components are listed.




24/01/2013.Date of printing

Date of issue/ Date ofrevision

Version

To the best of our knowledge, the information contained herein is accurate. However, neither the above-namedsupplier, nor any of its subsidiaries, assumes any liability whatsoever for the accuracy or completeness of theinformation contained herein.Final determination of suitability of any material is the sole responsibility of the user. All materials may presentunknown hazards and should be used with caution. Although certain hazards are described herein, we cannotguarantee that these are the only hazards that exist.

Notice to reader

:

:

:

Not applicable.:Full text of abbreviated Rphrases

Not applicable.:Full text of classifications[DSD/DPD]

Revision comments :

Indicates information that has changed from previously issued version.

24/01/2013.

1


Full text of abbreviated Hstatements

:

Abbreviations andacronyms

: ATE = Acute Toxicity EstimateCLP = Classification, Labelling and Packaging Regulation [Regulation (EC) No.1272/2008]DNEL = Derived No Effect LevelEUH statement = CLP-specific Hazard statementPNEC = Predicted No Effect ConcentrationRRN = REACH Registration Number

Classification according to Regulation (EC) No. 1272/2008 [CLP/GHS]

Procedure used to derive the classification according to Regulation (EC) No. 1272/2008 [CLP/GHS]

Classification Justification

Not classified.

Full text of classifications[CLP/GHS]

:

Not applicable.

Not applicable.

Not classified.

New MSDS form.


Documents

SAFETY DATA SHEET - University of California, Davis · ABX Pentra Iron CP - R1 SAFETY DATA SHEET Product name A91A00567E-R1 Conforms to Regulation (EC) No. 1907/2006 (REACH), Annex