of 8/8
Safety Data Sheet VRLA Rechargeable Battery / Portable Jump Starters Utilizing Same Updated August 24, 2017 SECTION 1: PRODUCT AND COMPANY IDENTIFICATION Product Name: Valve Regulated Lead-Acid Rechargeable Battery, Maintenance Free Battery Company: Clore Automotive Address: 8735 Rosehill Rd., Suite 220, Lenexa, KS 66215 E-mail: [email protected] Phone: 913.310.1050 Emergency: CHEMTEL – 888.255.3924; +1.813.248.0573 Models: ES2500/ES2500C/ES5000/ES5000C/ES1217/ES1230 ES6000/ES8000/ES1224/ES1240 Remark: This item (sealed VRLA rechargeable battery) is considered an article as defined by 29 CFR 1910.1200 (OSHA Hazard Communication Standard). The information contained in this SDS is supplied at the customer’s request for information only. Chemical family: This product is a non-spillable, wet lead acid storage battery. May also include gel absorbed electrolyte type lead acid battery types. SECTION 2: HAZARDS IDENTIFICATION GHS Label Elements: Signal Word: Danger

Safety Data Sheet VRLA Rechargeable Battery / … SDS... · Safety Data Sheet VRLA Rechargeable Battery / Portable Jump Starters Utilizing Same Updated August 24, 2017 SECTION 1:

  • View
    235

  • Download
    0

Embed Size (px)

Text of Safety Data Sheet VRLA Rechargeable Battery / … SDS... · Safety Data Sheet VRLA Rechargeable...

  • SafetyDataSheetVRLARechargeableBattery/

    PortableJumpStartersUtilizingSameUpdatedAugust24,2017

    SECTION1:PRODUCTANDCOMPANYIDENTIFICATIONProductName: ValveRegulatedLead-AcidRechargeableBattery,MaintenanceFreeBatteryCompany: CloreAutomotiveAddress: 8735RosehillRd.,Suite220,Lenexa,KS66215E-mail: [email protected]: 913.310.1050Emergency: CHEMTEL888.255.3924;+1.813.248.0573Models: ES2500/ES2500C/ES5000/ES5000C/ES1217/ES1230 ES6000/ES8000/ES1224/ES1240Remark: Thisitem(sealedVRLArechargeablebattery)isconsideredanarticleas definedby29CFR1910.1200(OSHAHazardCommunicationStandard). TheinformationcontainedinthisSDSissuppliedatthecustomersrequest forinformationonly.Chemicalfamily:Thisproductisanon-spillable,wetleadacidstoragebattery.Mayalsoincludegelabsorbedelectrolytetypeleadacidbatterytypes.SECTION2:HAZARDSIDENTIFICATIONGHSLabelElements:

    SignalWord:Danger

  • Category GHSCodes DescriptionHealth

    STOTRE2AcuteTox.4Repr.1A

    SkinCorr.1AFlam.Gas1

    AquaticChronic1AquaticAcute1

    H302H314H332H360H373H220H410P260P301/330/331P303/361/353

    -Harmfulifswallowed.-Causessevereskinburnsandeyedamage.-Harmfulifinhaled.-Maydamagefertilityortheunbornchild.-Maycausedamagetoorgansthroughprolongedorrepeatedexposure.-Extremelyflammablegas(hydrogen).-Verytoxictoaquaticlifewithlonglastingeffects.-Donotbreathedust/fume/gas/mist/vapors/spray.-IFSWALLOWED:rinsemouth.DoNOTinducevomiting.-IFONSKIN(orhair):Remove/Takeoffimmediatelyallcontaminatedclothing.Rinseskinwithwater/shower.-IFINHALED:Removevictimtofreshairandkeepatrestinapositioncomfortableforbreathing.-IFINEYES:Rinsecautiouslywithwaterforseveralminutes.Removecontactlenses,ifpresentandeasytodo.Continuerinsing.ImmediatelycallaPOISONCENTERordoctor/physician.

    Handling P210P260P264P280P403P405P391P273P501

    -Keepawayfromheat/sparks/openflames/hotsurfaces.Nosmoking.-Donotbreathedust/fume/gas/mist/vapors/spray.-Washthoroughlyafterhandling.-Wearprotectivegloves/protectiveclothing/eyeprotection/faceprotection.-Storeinwell-ventilatedarea-Storelockedup.-Collectspillage.-Avoidreleasetotheenvironment.-Disposeofcontents/containerinaccordancewithlocal/regional/national/internationalregulation.

    Note:Thebatteryhaspassedthevibrationtest,pressuredifferentialtestandleakagetestat55CaccordingtorecommendationsontheTRANSPORTOFDANGEROUSGOODSModelRegulation

  • 17thSPECIALPROVISION238.ItisnotrestrictedaccordingtoIATADangerousGoodsRegulation(DGR)56thperspecialprovisionA67andisnotrestrictedaccordingtoIMDGCODEperspecialprovision238.

    SECTION3:INFORMATIONONINGREDIENTS

    Ingredient CASNo. Concentration(%byWt.) HazardousLabelInorganicLead/LeadCompounds

    7439-92-1 ~72% T

    SulfuricAcid 7664-93-9 ~20% CFiberglassSeparator 65997-17-3 ~2% /

    SiliconDioxide(Gelbatteriesonly) 7631-86-9 ~10%ofacidWt. /

    ContainerPlastic(ABSorPP)

    9003-56-9(ABS) ~5% /9003-07-0(PP) /Note:Inorganicleadandelectrolyte(waterandsulfuricacidsolution)aretheprimarycomponentsofallCloreAutomotiveportablejumpstarterbatteries.Otheringredientsmaybepresentdependentuponbatterytype.ABSistheprimarycasematerialofourjumpstarterbatteries.SECTION4:FIRST-AIDMEASURESTakeproperprecautionstoensureyourownhealthandsafetybeforeattemptingtorescueavictimandprovidefirstaid.SkinContact:Electrolyte:Flushwithlargeamountsofwaterforatleast15minutes;removecontaminatedclothingcompletely,includingshoes,anddonotwearagainuntilcleaned.Ifacidissplashedonshoes,removeanddiscardiftheycontainleather.Leadcompounds:Washimmediatelywithsoapandwater.Leadcompoundsarenotreadilyabsorbedthroughtheskin.EyeContact:ElectrolyteandLeadcompounds:Flushimmediatelywithlargeamountsofwaterforatleast15minutes;consultphysicianimmediately.InhalationExposure:Electrolyte:Ifsulfuricacidmistorvaporisinhaled,movetoanareawithfreshairandwarmyourselfusingablanket.Seekmedicaladvice/attentionimmediately.Leadcompounds:Removefromexposure,gargle,washnoseandlips;consultphysician.

  • OralExposure:Electrolyte:Ifthisliquidisswallowed,washyourmouthwithplentyofwaterimmediately,thendrinkplentyofwater.Obtainmedicaladviceorattention.Donotinducevomitingwhenswallowed.Inaddition,donotperformanyaction,suchasaneutralizationprocess.Leadcompounds:Consultphysicianimmediately.

    SECTION5:FIREFIGHTINGMEASURES

    FlashPoint:NotApplicableFlammableLimits:LEL=4.1%(hydrogengasinair);UEL=74.1%ExtinguishingMedia:SmallfireFoamhalogenand/ornon-flammablegasfireextinguisherLargefire:Largequantitiesofsprinkledand/oratomizedwater.(Inthiscase,topreventenvironmentaldamage,flushwatermustbetreatedappropriately.)Particularhazards:Irritant,corrosiveand/ortoxicgasesmayescapefromaburningbattery.Properfirefighting:Ifpossible,disconnectfrompowerfirstifbatteriesareonchargeorremoveignitionsourceandremovebatteriesfromthefiresource.Wherepossible,extinguishthefirefromwellventilatedareaupwindfromfire.Waterusedtoextinguishfiremustbetreatedappropriatelytopreventenvironmentaldamage.Cooldownburntbatteriesusingplentyofwater.FireFightingProcedures:Usepositivepressure,self-containedbreathingapparatus.Bewareofacidsplatterduringwaterapplicationandwearacid-resistantclothing,gloves,faceandeyeprotection.Ifbatteriesareoncharge,shutoffpowertothechargingequipment,but,notethatstringsofseriesconnectedbatteriesmaystillposeriskofelectricshockevenwhenchargingequipmentisshutdown.

    SECTION6:ACCIDENTALRELEASEMEASURES

    Humanbody:Donottouchthespilledelectrolyteandwalkaroundthespillagesite.Keepoutsidersfromthespillagesite.Environment:Spilledelectrolytemustbetreatedappropriatelytopreventenvironmentaldamage,suchasdirectoutflowingofthespilledelectrolyteintoriver,drain,etc..Neutralization:Neutralizespilledelectrolytewithsodiumbicarbonate,lime,etc.andflushwithlargequantitiesofwater.

    SECTION7:HANDLINGANDSTORAGE

    Handling:Keepawayfromignitionsources,heatandflame.Batteriesmustbepackedinsuchamannerastoeffectivelypreventshortcircuitsandtopreventmovementwhichcouldleadtoshortcircuits.Avoidmechanicalorelectricalabuseandovercharge.Morethanamomentary

  • shortcircuitwillgenerallyreducethebatteryservicelife.Avoidreversingbatterypolaritywithinthebatteryassembly.Storage:Storeinacool,well-ventilatedarea.Keepawayfromignitionsources,heatandflame.Batteriesmustbepackedinsuchamannerastoeffectivelypreventshortcircuitsandtopreventmovementwhichcouldleadtoshortcircuits.MaterialstoAvoid:Strongoxidant,combustiblematerialsandcorrosives.Charging:Thereisapossibleriskofelectricshockfromchargingequipmentandfromstringsofseriesconnectedbatteries,whetherornottheyarebeingcharged.Shutoffpowertochargerswhenevernotinuseandbeforedetachmentofanycircuitconnections.Batteriesbeingchargedwillgenerateandreleaseflammablehydrogengas.Charginglocationshouldbewellventilated.Keepbatteryventcapsinposition.Prohibitsmokingandavoidcreationofflamesandsparksnearby.Wearfaceandeyeprotectionwhennearbatteries.

    SECTION8:EXPOSURECONTROLANDPERSONALPROTECTION NotapplicableforValveRegulatedLeadAcidbattery.

    SECTION9:PHYSICAL/CHEMICALPROPERTIESNotapplicableforValveRegulatedLeadAcidbattery.

    Reference(component)

    Electrolyte(SulfuricAcid) LeadAppearance Clear Silverysolid

    SpecificGravity 1.2801.380(3848%) 11.3BoilingPoint 112deg.C(38%) 1740deg.CMeltingPoint -40deg.Corbelow 327deg.C

    SolidifyingPoint -56.4deg.C(34.6%) -VaporPressure 3.17kPa(30%) 0.1Paorless(25deg.C)

    SECTION10:STABILITYANDREACTIVITY

    Stability:Stableundernormaltemperaturesandpressures.MaterialstoAvoid:Strongoxidant,corrosives.ConditionstoAvoid:Avoidexposuretoheatandopenflame.Avoidmechanicalorelectricalabuseandovercharge.Preventshortcircuits.Preventmovementwhichcouldleadtoshortcircuits.HazardousPolymerization:Willnotoccur.HazardousDecompositionProducts:Sulfuroxides,Sulfuricacidmist,Metaloxides.

  • SECTION11:TOXICOLOGICALINFORMATION

    RoutesofEntry:Electrolyte:Harmfulbyallroutesofentry.Undernormalconditionsofuse,sulfuricacidvaporsandmistarenotgenerated.Sulfuricacidvaporsandmistmaybegeneratedwhenproductisoverheated,oxidized,orotherwiseprocessedordamaged.Leadcompounds:Undernormalconditionsofuse,leaddust,vapors,andfumesarenotgenerated.Hazardousexposurecanoccuronlywhenproductisheatedabovethemeltingpoint,oxidizedorotherwiseprocessedordamagedtocreatedust,vapor,orfume.AcuteToxicity:InhalationLD50:Electrolyte:LC50rat:375mg/m3;LC50:guineapig:510mg/m3ElementalLead:AcuteToxicityPointEstimate=4500ppmV(basedonleadbullion)OralLD50:Electrolyte:rat:2140mg/kgElementallead:AcuteToxicityEstimate(ATE)=500mg/kgbodyweight(basedonleadbullion)Correspondtosection3

    SECTION12:ECOLOGICALINFORMATION

    EnvironmentalFate:Leadisverypersistentinsoilandsediments.Nodataonenvironmentaldegradation.Mobilityofmetallicleadbetweenecologicalcompartmentsisslow.Bioaccumulationofleadoccursinaquaticandterrestrialanimalsandplantsbutlittlebioaccumulationoccursthroughthefoodchain.Moststudiesincludeleadcompoundsandnotelementallead.EnvironmentalToxicity:AquaticToxicity:Sulfuricacid:24-hrLC50,freshwaterfish(Brachydaniorerio):82mg/L96hr-LOEC,freshwaterfish(Cyprinuscarpio):22mg/LLead:48hrLC50(modeledforaquaticinvertebrates):

  • SECTION14:TRANSPORTINFORMATION

    WeherebycertifythatalllistedCloreAutomotiveportablejumpstarterbatteriesconformtotheUN2800classificationasBatteries,Wet,Non-SpillableasaresultofpassingtheVibrationandPressureDifferentialTestdescribedinD.O.T.,49CFR173.159(f),andIMO/IMDG,andICAO/IATApackinginstruction872andnoteA48,A67,A164andA183.ThebatteriesarenotrestrictedaccordingtoIMO/IMDGcodeperspecialprovision238.CloreAutomotiveportablejumpstarterbatteries,havingmettherelatedconditions,areEXEMPTfromhazardousgoodsregulationsforthepurposeoftransportationbyDOTandIATA/ICAO,andthereforeareunrestrictedfortransportationbyanymeans.Forallmodesoftransportation,eachbatteryouterpackagemustbelabeled"NON-SPILLABLE."ProductsreturnedtoCloreAutomotive,orsubsequentlytransported,thatcontainabatteryorjumpstarter,mustbereturnedintheoriginalpackageorinastrongouterbox,certifiedfortheweightoftheunit,withadequatepackingmaterialtopreventtheunitfrommovementinsidethecarton.Forshipmentsofbatteries,batterypostsmustbeprotectedtopreventanypossibleshortcircuit.Forjumpstarters,thegripsmustbeproperlywrappedaroundtheunitandclampssecuredtopreventashortcircuitintransit.Ifaunitisbeingtransportedwithmetalclamps,gripsmustbeprotectedusingtheoriginallysuppliedgripguards,orthegripswrappedsoastopreventashortcircuit.Inadditionthecartonmustbemarkedwithphrase'Non-spillablebattery'soastocomplywiththerequirementsfortransportingthisasanon-dangerousshipment.

    SECTION15:REGULATORYINFORMATION

    EURegulation:InaccordancewithEU2006/66/ECBatteryDirective,VRLAbatteriesshouldpresentcrossed-outwheeledbinsymbolofleadtogetherwiththeISOrecyclingsymbol.Doesnotcontainanymercury,Hg,(

  • SECTION16:OTHERINFORMATION

    ProductssuchasBatteriesarenotinthescopeofregulationwhichrequiresthepublicationofanEUSafetyDataSheet(91/155/EEC).