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Shell Deer Park Refining Company Deer Park Refining Limited Partnership Shell Deer Park Refinery Delayed Coker Incident March 4, 2004 Brian Evans, Process Engineer Bottom of the Barrel Seminar April 19, 2005

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Shell Deer Park Refining CompanyDeer Park Refining Limited Partnership

Shell Deer Park Refinery

Delayed Coker Incident

March 4, 2004

Brian Evans, Process Engineer

Bottom of the Barrel Seminar

April 19, 2005

Shell Deer Park Refining CompanyDeer Park Refining Limited Partnership

Outline• Unit Information• Incident Details• Resulting Impacts

– Plugged Gasoil Product Systems– Partially Coked Drum– Another Drum Filled With Resid– Fractionator Tray Damage

• Investigation Findings• Recommendations

Shell Deer Park Refining CompanyDeer Park Refining Limited Partnership

Delayed Coker Information• Capacity: 88 MBD• Feed: Maya Vacuum Resid• 6 Drums, 3 Heaters, 1 Frac, 1 B/D• Drums: 28’ ID x 121’ F/F, 89’ T/T• Startup in 1995, 4 Drums (FW design)• 2001: Expansion to 6 Drums• 43 MBD Gasoil Hydrotreater

Shell Deer Park Refining CompanyDeer Park Refining Limited Partnership

Incident Details• Prior Status: Drums 1&2 and Heater 1 down for

drum repairs; Drums 3&5 coking, Drum 4 quenching, Drum 6 preparing to warmup

• Frac experienced an upset causing a large, rapid temperature drop (105°F in first 16 minutes)

• Charge Pumps began to cavitate, flow was lost to both Heaters

• Heaters tripped, but some flow was still going to 2 coking drums

• Drum inlet temperatures quickly dropped and never recovered

• Frac Bottom Level got out of control, carrying over resid into HGO and LGO product systems

Shell Deer Park Refining CompanyDeer Park Refining Limited Partnership

Incident Details (cont’d)• Bypassed GOHT to prevent Resid in feed• Fought Heaters for hours due to Charge

Pump cavitation• Bypassed Drum 5 after 3 hours – Partially

Coked “Tarry” Drum• Bypassed Drum 3 after 9 hours – mostly

cooler resid inside• All Fresh Feed cut out after 9 hours• Note: Drum 4 quench was not normal; more

on this later…

Shell Deer Park Refining CompanyDeer Park Refining Limited Partnership

Coker Simplified Flow Scheme

C O

C O

W AX TAILINGSFROM BLOW DOW N

PITCH FEEDCHARGE HEATERS

COKEDRUMS

MAINFRAC

W GC

NAPHTHATO

GAS PLANT

TO GASPLANT

LGO TO GOHT

HGO TO GOHT

HGOP/A

SPONGEOIL

LOOP REFLUX

VAPOR LINES800°F

22-24 PSIG

585°F

925°F

W ASHOIL

895°F

250-260°F16-18 PSIG

Shell Deer Park Refining CompanyDeer Park Refining Limited Partnership

Plugged Product Lines• Carryover of Resid from Frac plugged:

– HGO Product and Pumparound lines– LGO Product lines– Gasoil to Storage lines– Blowdown lines to Frac– MDO lines

• The plugged lines were critical path for restarting, resulting in 8 day S/D

Shell Deer Park Refining CompanyDeer Park Refining Limited Partnership

Plugged Lines: Mitigation• Removed insulation• Wrapped thousands of feet of piping

with temporary electric tracing• Heated the piping until the material

flowed again• This process took days and cost big $$.• There is no quick and easy way to

unplug lines containing solid Resid.

Shell Deer Park Refining CompanyDeer Park Refining Limited Partnership

Drum 5 – “Tarry” Drum• Drum 5 had been coking for about 11

hours prior to the heater trips• Drum was fed for 3 hours after that• Estimated 4 MB Resid in the drum that

didn’t finish coking• As soon as drum was bypassed,

steamed at 7 Mlb/hr for about 4 days• Had to wait because Blowdown system

was not available due to plugging

Shell Deer Park Refining CompanyDeer Park Refining Limited Partnership

Drum 5 – “Tarry Drum” (cont’d)• After weighing our options, decided to

quench the drum as best we could• Quenching itself went pretty well.• However, as anticipated, drum would

not drain afterwards• Since we did get a substantial amount

of cooling during quenching, we decided to unhead and try cutting.

Shell Deer Park Refining CompanyDeer Park Refining Limited Partnership

Drum 5 – “Tarry” Drum (cont’d)• Unheading was performed remotely• Small amount of “black lava” oozed out

the bottom as chute was raised• Cutting was very difficult and took

hours; lots of hot spots• However, in the end the material was

safely and successfully removed• Left with a giant “lava mountain”

Shell Deer Park Refining CompanyDeer Park Refining Limited Partnership

Drum 3 – Full of Uncoked Resid• Fed “cool” Resid for 9 hours after heat loss• After bypassing steamed at 10+ Mlb/hr for over a

week• Temperatures suggested that Resid was still hot

enough to flow• Several potential options considered• In the end, it was decided to build a special

temporary system to drain the Resid out• Resid would be blended with cutter right out of

the drum and pumped to MFO tanks• Ratio of cutter/Resid would be controlled to

prevent plugging, etc.

Shell Deer Park Refining CompanyDeer Park Refining Limited Partnership

Drum 3 Drain System

Flushing OilFrom Dubbs Tank Farm (P-2124)

DRAIN

20-30PSIG

DRUM#3

26C

16C

15C

17C

12C

11C

1C 2C

6C

7CGO/9C

20C21C22C

BLOWDOWN

HCGOQUENCH

ALTQUENCH

STEAM

QUENCHWATER

STEAMCOKE

CONDENSATE

ATMVENT

PITCHFEED

3C

5C

4C

8C

STEAM

CCLGO

MFO From DU-2 andDubbs Tank Farm

AP-Tanks

14"

3"

ChopperPump -

chop coketo 2" chunk

(Dieseldriver)

TI

350 oFavg

2-3 MBPD

7-10.5 MBPD180 oF

avg100 oFavg

PI

4"

8"

Temporary Facility To Transfer Drum 3 Material To MFO

Tower Pumpout

Disk Attrition MillPump

(Diesel Driver)Transfer Pump(Diesel driver)

FI

3"

2"

Flushing oilSystem

PC

125 psig

Dead Head - 172 psigMAWP - 175 psig

Dead Head - 211 psigDead Head - 264 psig

MAWP - 275 psig

FC

Shell Deer Park Refining CompanyDeer Park Refining Limited Partnership

Drum 3 Draining System• System worked like a charm• Draining/blending process took approximately 2

days• After level was verified to be below 13’ level

indicator, draining was stopped• Estimated 1.5 MB of Resid still inside• Shortly after that, hot feed was switched into

Drum 3• Foam front moved quickly up the drum, started

antifoam• Had to cut feed and double antifoam rate to stop

foam front; cycle lasted almost 24 hrs

Shell Deer Park Refining CompanyDeer Park Refining Limited Partnership

Problems on Unit Restart• During restreaming of the unit, a couple of

issues were observed– Frac Bottom Temperature was much lower than

normal (feed heat integration w/ HGO)– No pressure drop in HGO section of tower

• Determined that bottom 9 trays severely damaged

• Had to raise column pressure and fire heaters harder to get feed rate up

• Have been fighting this ever since, but managing to keep going

Shell Deer Park Refining CompanyDeer Park Refining Limited Partnership

Investigation Findings• Cause of Temperature Drop

– Drum 4 Coke Condensate Valve didn’t fully close– PLC indication showed that valve had closed– During Drum 4 quench, water flowed through

Coke Condensate and into Frac feed zone– Essentially, we “quenched” the Frac– Trays damaged due to pressure surge from water

vaporization• Resid Carryover

– Guidelines were not clear on when it is acceptable to cut out fresh feed

– Operators were under the impression that they could not cut out feed completely

Shell Deer Park Refining CompanyDeer Park Refining Limited Partnership

Drums 3&4 Schematic

Valvecracked

open

Shell Deer Park Refining CompanyDeer Park Refining Limited Partnership

Blowdown/Coke Condensate System

LV-31101

M

M

SP-1

MMM MMMMM MM

SP-2 SP-4 SP-8

COKE DRUM

TV-31241

TV-31236

LEAN SPONGE OIL FROM E-31503

RV-31024

V-31005 FV-31024

V-31021A V-31021B

STRIPPING STEAM

QUENCH WATER

V-31017 V-31018

P-31022 P-31023

V-31010

BN-31001

STEAM

CONDENSATE

FV-31057

AC-31003 A/B,C/D,E/F,G/H

AC-31002 A/B

V-31011

FV-31060

LV-31113

P-31024 P-31025

BLOWDOWN GAS TO FLARE

FUEL GAS

P-31026

TO SOUR WATER

STRIPPER

SLOP OIL WAX TAILINGS

AND COKE CONDENSATE

TO MDO COLLECTION

SYSTEM

BALANCE LINE TO FRACTIONATOR

WAX TAILINGS TO V-31006

FRACTIONATOR

LV-31112

ALTERNATE MAKE UP TO T- 31001

PCV-048

DE-

EMU

LSIF

IER

FTFT

LCLC

LCLC

LCLC

TITI

TITI

TITI

FTFT

BLOWDOWN SETTLING DRUM

BLOWDOWN CONDENSER

BLOWDOWN DRUM HEATER

NC

TV-31199

FV-31052

CONDENSATE

STEAME-31008

SLOP OIL EXCHANGER

REFINERY RECYCLE OIL TO V-31006

FRACTIONATOR

REFINERY RECYCLE

OIL

COKE CONDENSATE

DRUM

P-31021 COKE CONDENSATE

PUMP

COKE CONDENSATE

STRAINERS

FLOW FROM FEED FILTERS GOHT UNIT

COKER BLOWDOWN DRUM

SLOP OIL

BLOWDOWN SOUR WATER

BLOWDOWN CIRCULATING OIL COOLER

BLOWDOWN CIRCULATING

OIL PUMP

CLOSES

350 ºF

+350 ºF

++

375 ºF -

-

375 ºF -

-CLOSES

(45 PSIG)

Pump bypass

WAX TAILINGS

PUMP WAS OUT OF SERVICE. VESSEL

WAS BEING PRESSURED OUT.

LOST THIS PUMP AT

11:14

AS TEMP. DROPPED, STARTED SENDING WATER

VALVE # 19D AT COKE DRUM DID NOT

CLOSE (EVEN THOUGH INDICATOR SHOWED CLOSED)

Shell Deer Park Refining CompanyDeer Park Refining Limited Partnership

Investigation Findings (cont’d)• Partially Coked Drums

– No consistent guidelines for when to bypass a drum after heat is lost

– Everyone knew there was a limit, but focus was on troubleshooting the other issues

• General– Communications and decision making

during event were not structured

Shell Deer Park Refining CompanyDeer Park Refining Limited Partnership

Recommendations• Water in the Frac/Temperature Drop

– Convert PLC inputs on Coke Condensate valve from external prox switches to internal limit switches

– Install a low temperature alarm on both Coke Condensate drums

– Consider upgrading other critical structure valves with MOVs that can be interlocked

– Provide operator training on the above items and “how to recognize” water in the Frac

Shell Deer Park Refining CompanyDeer Park Refining Limited Partnership

Recommendations (cont’d)• Develop guidelines for managing Frac level

excursions and Coker feed system• Develop guidelines for when to bypass Coke

Drums after heat is lost• Develop guidelines for when to place the

GOHT on circulation• Develop a structured communication and

decision making process for managing abnormal situations

• Train operators on all of the above

Shell Deer Park Refining CompanyDeer Park Refining Limited Partnership

Questions?