Site Visit Report - Environmental Protection Agency ... · Site Visit Report The site visit ... Monitoring & Analytical Methods Sampling Location ... 1.96 130 127.79 317.14 153.89

Site Visit Report

The site visit process is a sample on a particular day of an installation's compliance with some of its licence conditions. Where non-compliance against a particular condition has not been reported, this should not be construed to mean that there is full compliance with that condition of the licence.

Instructions and actions arising from the visit shall be addressed, or where applicable noted, by the licensee in order to ensure compliance, to improve the environmental performance of the installation and to provide clarification on certain issues.

The licensee shall take the actions specified to close out the non-compliances and observations raised in this Site Visit Report.

Licensee

Name of Installation Medite Europe Limited

Licensee Medite Europe Limited

Licence Register No. P0027-02

CRO Number 80984

Site Address Redmondstown, Clonmel, Tipperary

Site Visit Reference No. SV08076

Report Detail

Issue Date 14/10/2016

Prepared By David Matthews

Site Visit Detail

Date Of Inspection 26/07/2016 Announced No

Time In 14:00 Time Out 13:00

Visited by on behalf of the EPA Exova Ltd.

Licensee Personnel and Role See report

Photo Taken No Samples Taken Yes Video Taken No

Site Visit Report - SV08076 - Medite Europe Limited Page 1 of 83

Scope

This is a report on monitoring of emissions to atmosphere at this site. Please find the detailed technical report attached.

Media

Air

Site Areas Inspected

See report

Documents Inspected

See report



ISO/IEC 17025 Accredited Legal Entity, UKAS Accredited Testing Laboratory No. 4279

Exova (UK) Ltd trading as Exova Catalyst & Exova Catalyst Ireland

Unit C5, Emery Court, The Embankment Business Park, Stockport, SK4 3GL

EMISSIONS REPORTEPA AIR EMISSIONS COMPLIANCE MONITORING

Exova Catalyst Ireland, Unit D8 North City Business Park, North Road, Finglas, Dublin 11

T: +353 86 853 8247E: [email protected]

Your Exova Catalyst Ireland Contact: Nick Kenny (+353 86 853 8247)

Clonmel

RedmondstownMedite Europe Ltd

IrelandCo Tipperary

EPA Office of Environmental Enforcement

EP 35 - Face Dryer Stage 1

DELETE & COVER ME

(Prepared on behalf of the EPA by Exova Catalyst - EPA Contract No. OEE-14-DS)-

-

Team Leader

Deputy Regional Manager

TE1 TE2 TE3 TE4MM 08 922

MCERTS Level 2

Patrick O'Brien

Report Approved by

MM 10 1074MCERTS Level 2

Stack Emissions Testing Report Commissioned by

26th - 27th July 2016

Job Reference Number

CDU-0666-CAR16-01

Installation Name & Address

Dates of the Monitoring Campaign

Report Written by

John Glennon

19th September 2016

Report Date

TE1 TE2 TE3 TE4

Version

Stack Reference

Industrial Emissions Licence: P0027-02

Signature of Report Approver

Version 1

CAT-RT (Version BO)Site Visit Report - SV08076 - Medite Europe Limited Page 4 of 83

TITLE PAGE

CONTENTS

Summary of Sampling Deviations

EXECUTIVE SUMMARY

Monitoring Objectives

Monitoring Results

Monitoring Dates & Times

Process Details

Monitoring & Analytical Methods

Sampling Location

Plant Photos / Sample Points

APPENDIX 1 - Monitoring Personnel & List of Equipment

APPENDIX 2 - Raw Data, Sampling Equations & Charts

The testing performed fully meets the technical requirements in Irish

EPA Guidance Note, AG2.

9

3

5

6

8

Opinions and interpretations expressed herein are outside the scope of

Exova Catalyst Ireland's ISO 17025 accreditation.

This test report shall not be reproduced, except in full, without the

written approval of Exova Catalyst Ireland.

7

CONTENTS

4

2

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Job Number: CDU-0666-CAR16-01, Version 1

Sample Date/s: 26th - 27th July 2016



Overall Aim of the Monitoring Campaign

Special Requirements

Target Parameters

Exova Catalyst Ireland were commissioned by EPA Office of Environmental Enforcement to carry out stack emissions testing for

Medite Europe Ltd on the EP 35 - Face Dryer Stage 1 at Clonmel.

The aim of the monitoring campaign was to demonstrate compliance with a set of emission limit values (ELVs) as specified in

the Site's Licence.

There were no special requirements.

Total Particulate Matter | Condensable VOCs | Cadmium & Thallium | Heavy Metals | Mercury | Dioxins & Furans |

Formaldehyde | Isocyanates | Oxides of Nitrogen (as NO₂) | Carbon Monoxide |

MONITORING OBJECTIVES

Executive Summary

Medite Europe Ltd, Clonmel


26th - 27th July 2016

(Page 1 of 7)

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where MU = Measurement Uncertainty associated with the Result

Parameter

Total Particulate Matter ¹

Condensable VOCs ¹ - -

Cadmium & Thallium ¹ - -

Heavy Metals ¹ - -

Mercury ¹ - -

Dioxins & Furans (NATO I-TEQ) - R1 Dioxins & Furans ¹

Formaldehyde ¹ - -

Isocyanates ¹ < <

Oxides of Nitrogen (as NO₂) ¹ - -

Carbon Monoxide ¹ - -

Oxygen Wet Dry

Water Vapour

Stack Gas Temperature

Stack Gas Velocity 2

1 & 2

- -

NOTE: VOLUMETRIC FLOW RATE & VELOCITY DATA TAKEN FROM THE PRELIMINARY VELOCITY TRAVERSE.

¹ Reference Conditions (REF) are: 273K, 101.3kPa, without correction for water vapour content.

2 Agreed volumetric flow rate with the EPA (this result was not measured by Exova as part of the monitoring campaign).

-

Limit

179800

1281.08

39.80

7.8125.52 g/hr 3150

0.071

20mg/m³

ng/m³

0.0001 0.05

4134.85

-g/hr

1.10

20.0

0.001

1.24

% v/v

0.79


`

g/hr 320.565.42

+/-

Units Result

Concentration

0.0007

MU

0.01

0.0018

mg/m³ 0.05 -

g/hr

g/hr

0.1

Limit

+/-

0.04

mg/m³

Executive Summary

0.29 0.12

Mass Emission

201.96

-

MONITORING RESULTS


0.5 g/hr 11.58 -

2399.4

g/hr

-

Dioxins & Furans Upper Limit (worst case where <LOD = LOD)

0.001 0.17

Units

0.0003 0.053

mg/m³

14.70 100 6008.4

-

877.7

Result Limit

37.09

µg/hr

-

mg/m³

MU

0.0002

m³/hr

18.58

174540

m³/hr

mg/m³

mg/m³

20.80

7819

1.06

200.81mg/m³

g/hr

0.070 0.20.01

1.96 130 127.79 317.14

153.89

-12.8m/s

(Page 2 of 7)

0.95 600

% v/v

10.66

162000

% v/v

°C

g/hr

Volumetric Flow Rate (ACTUAL)

0.246

Volumetric Flow Rate (REF)

mg/m³

8424

-

-

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Parameter

R1 - -

R1 - -

R1 - -

R1 - -

R1 - -

(NATO) R1 - -

R1 - -

R1 < <

R1 - -

R1 - -

R1 -

R1

All results are expressed at the respective reference conditions.

Isocyanates mg/m³ 0.01 g/hr 1.06 27/07/2016 09:55 - 10:25 30

Dioxins & Furans

Heavy Metals

09:20 - 09:50

0.25

Date(s)

Mass Emission

g/hr

27/07/2016

µg/hr

127.79

39.80

mg/m³

ng/m³

% v/v

15:31 - 16:00

Velocity & Volumetric Flow Rate 26/07/2016

0.0370.0002

(Page 3 of 7)

0.29

Mercury

mg/m³

Units


MONITORING DATE(S) & TIMES

mins

Concentration

27/07/2016

Sampling

877.74

37.1Condensable VOCs


26th - 27th July 2016

Executive Summary

Sampling

Times

g/hr

27/07/2016

10:35 - 11:35

09:20 - 09:50

6008.4

mg/m³ 0.17

10:35 - 11:35

mg/m³

60

10:35 - 11:35

g/hr

0.0011

g/hr

27/07/2016

27/07/2016

1

0.0018

25.5 4134.9 27/07/2016

30

08:40 - 09:10

Oxides of Nitrogen (as NO₂)

60Cadmium & Thallium

36026/07/2016

Formaldehyde mg/m³ g/hr

60

11:00 - 17:00

mg/m³

Units

Total Particulate Matter 5.42

g/hr 30

30

Duration

26/07/2016

g/hr

19.63

Carbon Monoxide

0.79

26/07/2016

200.811.24 15:31 - 16:00

Oxygen

26/07/2016mg/m³

g/hrmg/m³

15:31 - 16:00

30

30

30

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Standard Operating Conditions

Value


Feedstock (if applicable)

Process Status

Parameter

Visible

100 % of capacity

Woodchip

Fuel

(Page 4 of 7)

Executive Summary

PROCESS DETAILS


26th - 27th July 2016

Abatement System

Abatement System Running Status

Plume Appearance

Cyclone

Capacity (of 100%) and Tonnes / Hour

Continuous or Batch Process

N/A

On

Continuous

Drying Process

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0.0011 ng/m³

Isocyanates

CAT

CAT-TP-05 YesEN 14790

1

0.0065 mg/m³

Dry Paramagnetic Cell by Horiba PG-350ECATOxygen

CAT-TP-05

NDIR by Horiba PG-350E

ANALYSIS LABORATORIES

Chemiluminescence by Horiba PG-350E

Deviation

0.1 % v/v

EN 15058

0.41 mg/m³CAT-TP-39

CAT

CAT Yes

Yes

EN 14789 CAT-TP-39 Yes

All

Scientific Analysis Laboratories Ltd (SAL)

RPS Laboratories Ltd (RPS)

Yes

(with short name reference as appears in the table above)

Exova Catalyst (CAT)

ISO 17025 Accreditation Number: 0605

0.1 %

Gravimetric

US EPA CTM36

Water Vapour

Yes

Yes

EN 14792

Yes

Dioxins & Furans CAT

IC

Total Particulate Matter EN 13284-1

CAT-TP-19

CAT

Yes

Yes

Yes

SOP 1C

HPLC

0.54 mg/m³




Yes

Carbon Monoxide

Yes

CAT-TP-17

CAT Yes

CAT SAL

Yes

Analytical

TechniqueProcedure

Heavy Metals

YesCAT-AP-05CAT

Yes SAL

Yes

OX-IR

Analytical

M112

Technical

Mercury

ICP-MS

CAT-TP-03


Yes CATEN 14385

US EPA M316

(Page 5 of 7)

Testing ISO

Cadmium & Thallium

Yes

Standard

Yes

Yes CAT

CAT

CAT-TP-01

EN 1948

Lab

Yes

CAT-TP-07

Yes

Yes

GC-HRMS

ISO

Lab

Yes 0.027 mg/m³

CAT

Executive Summary

Testing

0.004 mg/m³

CAT

Yes

SALOX-IR

Analysis

CAT-TP-23In House

Analysis

17025 Analysis

RPS

RPS

CAT-TP-06

EN 14385

Yes

Yes

ICP-MS

Monitoring

CAT

Parameter

Procedure

CAT-TP-06

Yes

0.001 mg/m³

Condensable VOCs

0 mg/m³

LOD

Yes

CAT-TP-06 Yes

MID 14385


Gravimetric

MCERTS

17025

Testing

0.21 mg/m³

CV-AFS

RPS

(Average)

M31

M31

Formaldehyde

Yes

26th - 27th July 2016

Ratio highest to lowest velocities between 3 and 5 : 1.

0.027 mg/m³

CAT-TP-39

MONITORING & ANALYTICAL METHODS

1 The sample points where the angle of swirl was > 15° were omitted from the sampling exercise.

SUMMARY OF SAMPLING DEVIATIONS

Parameter Run

All

M119

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Duct Characteristics Location of Sampling Platform

Platform Details

Sampling Location / Platform Improvement Recommendations

EN 15259 Homogeneity Test Requirements

No

-

Parameter

There are no obstructions present which hamper insertion of sampling equipment

-

m²

m

Yes

Yes

SUITABILITY OF SAMPLING LOCATION

Executive Summary

cm

-

Permanent

Platform has 2 levels of handrails (approx. 0.5m & 1.0m high)

-

Sufficient working area to manipulate probe and operate the measuring instruments

Type

2.20

Width

Sample Port Size

There is no requirement to perform a EN 15259 Homogeneity Test on this Stack.

Circular

Value

Vertical

No

Safe Access Available

(Page 6 of 7)

Permanent / Temporary Platform

Inside / Outside

General Platform Information

Platform has vertical base boards (approx. 0.25m high)

Units

Outside

Yes

24

The sampling location does not meet all of the Flow Criteria requirements in the EPA Guidance Note AG1 and EN 15259.

Area

m

3.80

Orientation of Duct

Irish EPA Technical Guidance Note AG1 / EN 15259 Platform Requirements

Yes

Platform has chains / self closing gates at top of ladders

Value

Easy Access Available

Depth

Port Depth

Yes

4" BSP

Value

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PLANT PHOTOS

(Page 7 of 7)

Photo 2

SAMPLE POINTS

Photo 1

Photo 4Photo 3

Executive Summary

where = isokinetic point sampled at

= isokinetic point not sampled at

= combustion gases sample point

= non-isokinetic sample point Line A

Line B

A1

A3

A2

A6

A5

A4

B3 B2 B1

B6 B5 B4

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APPENDIX 1 - Stack Emissions Monitoring Personnel, List of Equipment & Methods and Technical Procedures Used

APPENDIX 2 - Summaries, Calculations, Raw Data and Charts

APPENDICES

APPENDIX CONTENTS

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Bioaerosols Temperature Logger -

Electronic Refrigerator -

Servomex 4900

-

-

Stopwatch

Mercury

-

-

CAT 3.59

SELECT FTIR

SELECT Horiba Model (2)

MM 10 1074 TE1 TE2 TE3 TE4

Technician James Magann MCERTS Level 1 MM 15 1330 TE1

CAT 39.9

Position

Digital Temperature Meter

Instrumental Analysers

Oven Box (1)

CAT 3.97

METHODS & TECHNICAL PROCEDURES USED

CAT 7.23

Eco Physics CLD 822Mh

CAT-TP-39

CAT-TP-39

MID 14385

EN 14385

EN 1948

Stack Thermocouple (1)

Gasmet Sampling SystemCAT 5.51

ABB AO2020-URAS26

Condensable VOCs

CAT 3.97-

-

CAT 21S.46

Miscellaneous Items


Heated Probe (3) -

CAT 6.1

Bernath 3006 FID -

-

- 1m Heated Line (2)Heated Probe (2)

Equipment Type

Control Box DGM (2)

-

John Glennon MCERTS Level 2

Mass Flow Controller (2) CAT 6.21

Technical Endorsements

Team Leader

Equipment Type

MCERTS Number

Equipment I.D.

STACK EMISSIONS MONITORING PERSONNEL

APPENDIX 1

EN 14789

Heavy Metals

Mass View (1) -

20m Heated Line (2)

EN 15058

Parameter

Total Particulate Matter

EN 14385

Tubes Kit Thermocouple -

Carbon Monoxide

EN 14790

US EPA CTM36

-

SELECT Logger 2 -

Dual Channel Heater Controller -

CAT-TP-39

Isocyanates

Water Vapour

15m Heated Line (1)

CAT 17.10

Formaldehyde

CAT 4.491

-

Umbilical (2) Servomex 5200MP

Oxygen


Equipment I.D.

1m Heated Line (3)

Control Box DGM (1)

CAT 4.605

Extractive Sampling

LIST OF EQUIPMENT

MCERTS Accreditation

Single Channel Heater Controller

CAT-TP-01

Barometer

Digital Manometer (2)

Umbilical (1)

Box Thermocouples (2)

Box Thermocouples (1)

-


CAT 20.71

-

EN 13284-1

Technical ProcedureStandard

Heated Probe (1)

-

-

CAT 12.105

CAT 3.59

-

Mass View (2)

CAT 12.84

-

CAT 4.705

5m Heated Line (1) -

JCT JCC P1 Cooler

CAT 13.27

Mass Flow Controller (1)

500g / 1Kg Check Weights CAT 17.10

Last Impinger Arm CAT 4.404

Callipers

- 20m Heated Line (1)

S-Pitot (2) CAT 21P.92

SELECT Logger 1

Cadmium & Thallium

Site Balance

M&C PSS

Dioxins & Furans

CAT 20.71

Laboratory Balance CAT 1.18 / 1.18a

Tape Measure CAT 16.95

Equipment I.D.

-

CAT 14.53

-

S-Pitot (1)

L-Pitot

-

CAT-TP-19

CAT-TP-07

CAT-TP-06

CAT-TP-06

CAT-TP-06

CAT-TP-23

CAT-TP-05

CAT-TP-17

In House

Horiba PG-350E Digital Manometer (1)

Oven Box (2)

1m Heated Line (1)

Name

-

CAT 23.26

EN 14792

US EPA M316

Equipment Type

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General Stack Details

Stack Gas Composition & Molecular Weights

CO₂ (Estimated)

O₂

Moisture (H₂O)

Where: p = M / 22.41

pi = r x p

Calculation of Stack Gas Densities

Where: P STD = sum of component concentrations, kg/m³ (not including water vapour)

P STW = sum of all wet concentrations / 100 x density, kg/m³ (including water vapour)

P Actual = P STD x (TSTP / (PSTP)) x ((Pstatic + Pb) / Ta)

P ActualW (at each sampling point) = P STW x (Ts / Ps) x (Pa / Ta)

Calculation of Stack Gas Volumetric Flowrate, Q

m²

PRELIMINARY STACK SURVEY: CALCULATIONS

Stack Diameter / Depth, D

Gas Volumetric Flowrate (from Traverse)

162000

kg/m³

-

Mass

Component

m³/hr

Result

°C

Units

Pa

Fraction

Density

Dry

0.08565

20.80 32.00

Conc

132.7

Molar Conc

3.80

mStack Width, W

Stack Area, A

-

Volume

kPa

kPa

0.84

Value

2.20

100.9

Average Stack Gas Temperature, Ta

0.010

°C

Average Stack Static Pressure, Pstatic

m³/hr

REF ¹

1.219

Dry Density (Actual), P Actual

m³/hr

Gas Volumetric Flowrate (STP, Dry)

Gas Volumetric Flowrate (Actual)

kg/m³

20.0

Average Barometric Pressure, Pb

m

Actual

kg/m³

0.7914 28.01

101.3

Result

1.9635

Stack Details (from Traverse)

APPENDIX 2

0.05

Units

Average Pitot Tube Calibration Coefficient, Cp

ppm kg/m³

Average Stack Gas Pressure

Conc

10.66

Conc

M

Wet

r% v/v

kg/m³

m³/hr

Total Pressure

Average Wet Density (Actual), P ActualW

10.66

79.14 0.98913

1.287

70.71

Dry Density (STP), P STD

18.02

Determinand

0.0006

20.0

100.9

Temperature

N₂

1.4277 0.29696-

Units

0.00118

Gas Volumetric Flowrate (STP, Wet)

Moisture

kPa

0.1066

18.58

p pi

-

1.2498

44.01

144737

-

-

0.2080

-0.0

% v/v

Units

10.66

kg/m³ 1.236

Duct gas flow conditions

162000

174540

1.195

Wet Density (STP), P STW

-

Gas Volumetric Flowrate REF ¹

%

0.8037

0.06

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Sample Runs

- -

- -

- -

- -

- -

- -

- -

- -

Blank Runs

- -

- -

General Sampling Information

FORMAT: Number Used / Number Required


Reference Conditions

Reference Conditions are: 273K, 101.3kPa, without correction for water vapour content.

APPENDIX 2

877.7

mg/m³ 5.42

Run 1

Maximum

mg/m³ 0.77

A3

Positioning of Filter

Mean

320.6

1.08 1.08

320.6

±% v/v

1 / 2

Number of Sampling Points Used 1 / 12

Titanium

Filter Housing Material Borosilicate Glass

Probe Material

Parameter Units

Run 1

Water Vapour

Concentration

Mass Emission

Standard

47mm Glass Fibre

0.77

Parameter

EN 13284-1

Sample Point I.D.'s

10.11

Number of Sampling Lines Used

CAT-TP-01

% v/v

Value

g/hr 877.7

TOTAL PARTICULATE MATTER: RESULTS SUMMARY

Filter Size and Material

Out Stack

Technical Procedure

Parameter Units

Uncertainty ±g/hr


Mean

10.11


Parameter

Concentration

5.42

Blank 1

Uncertainty

Uncertainty ±mg/m³ 1.96 1.96

Units

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Absolute pressure of stack gas, Ps

Volume of water vapour collected, Vwstd

Volume of gas metered dry, Vmstd

Moisture content, Bwo & Rwv

Bwo as a percentage

Reported Water Vapour, checked with Tables in EN 14790, Rwv

Volume of gas metered wet, Vmstw

Volume of gas metered at Oxygen Reference Conditions, Vmstd@X%O₂ & Vmstw@X%O₂

Molecular weight of dry gas stream, Md

CO₂ (Estimated)

O₂

Molecular weight of stack gas (wet), Ms

Total flow of stack gas: Actual (Qa), Wet (Qstw), Dry (Qstd), Wet@O₂REF (QstwO₂), Dry@O₂REF (QstdO₂)

Percent isokinetic, %I

g/gmol 28.84

34.97

0.3592

761.3

m³

g/gmol 27.75

-

0.06

3563.6

IED & Incinerates Hazardous Material? (Yes = no positive O₂ correction)

Bwo = Vwstd / (Vmstd + Vwstd) 0.1011

N/A

N/A

-

Ps = (Pb + (Pstatic / 13.6) 755.5

N₂

- N/A

No

Pitot tube velocity constant, Kp

m³

m³

Average pressure drop across orifice, ∆H

Average stack gas temperature, Ts

46.9

Qstw = ((Qa)(Ps)(Cf)) / ((Ts) + 273)

Conversion factor (K/mm.Hg), Cf

Total mass collected in impingers (silica trap)

mmHg

g

mmHg

6.01

°C 57.0

Vs = ((Kp)(Cp)(√∆P)(√Ts + 273)) / (√(Ms)(Ps)) 15.62

mm

m³/min

min 30

m³/min 2634.4

Area of stack, As m²

%

Average of velocity heads, ∆Pavg mmH₂O

Total sampling time, q

3.80

Qa = (60)(As)(Vs)

Run 1

-

0.6666

Ms = Md(1 - (Rwv/100)) + 18(Rwv/100)

% v/v

0.6534

% v/v

20.80

Velocity of stack gas, Vs

Velocity pressure coefficient, Cp

g

TOTAL PARTICULATE MATTER: ISOKINETIC SAMPLING CALCULATIONS

Test Units

Total mass collected in impingers (liquid trap)

9.7

17.97

4.24

28.34

m³/min

99.7

m/s

-

m³/min

O₂ Reference Factor wet (O₂REFw) = (21 - REF%O₂) / (21 - ACT%O₂w)

0.9310

10.11

Md = 0.44(%CO₂)+0.32(%O₂)+0.28(%N₂)

Stack static pressure, Pstatic

N/A

-

% v/v

m³

% v/v

17.3

Barometric pressure, Pb

53.0

Nozzle diameter, Dn

mmH₂O

0.0660

Volume of gas sample through gas meter, Vm m³

Gas meter correction factor, Yd

43.3g

N/AVmstd@X%oxygen = (Vmstd) / (O₂REFd)

N/A

-

Vmstw = (Vmstd)(100/(100 - Rwv))

% v/v 20.86

% wet oxygen measured in gas stream, ACT%O₂w

0.84

Vmstd = ((0.3592)(Vm)(Pb + (∆H/13.6))(Yd)) / (Tm + 273)

-78.2

0.5873

Average square root of velocity heads, √∆P

QstwO₂ = ((Qa)(Ps)(Cf)) / ((Ts) + 273) / (O₂REFw)

%I = (4.6398E⁶)(Ts+273)(Vmstd) / (Ps)(Vs)(An)(q)(1 - (Rwv/100))

Vwstd = (0.001246)(Vlc)

Average dry gas meter temperature, Tm °C

Total mass of liquid collected, Vlc

% v/v

APPENDIX 2

% v/v

% v/v

mmH₂O

% oxygen reference condition, REF%O₂ % v/v N/A

% dry oxygen measured in gas stream, ACT%O₂d

O₂ Reference Factor dry (O₂REFd) = (21 - REF%O₂) / (21 - ACT%O₂d)

Vmstw@X%oxygen = (Vmstw) / (O₂REFw)

mm²

m³

Total

2930.6

Qstd = ((Qa)(Ps)(Cf)(1 - (Rwv/100))) / ((Ts) + 273)

79.14

√mmH₂O

Nozzle area, An

N/A

QstdO₂ = ((Qa)(Ps)(Cf)(1 - (Rwv/100))) / ((Ts) + 273) / (O₂REFd) m³/min N/A

10.11

m³

CAT-RT (Version BO)

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Sample Runs

Filter I.D. Number

Probe Rinse I.D. Number

Where: ISO stands for Manual Isokinetic Sampling Train

Blank Runs

Filter I.D. Number

Probe Rinse I.D. Number

Start Probe Rinse Mass

0.00021

5.42

Sampling Device

3.54

0.77

0.00333

-

2.94040

Start Filter Mass

3.18239

-

Total Mass on Filter

mg/m³

0.21

0.14667

Total Mass on Filter

End Filter Mass

-

Parameter

-

End Probe Rinse Mass

47-32937

g

Units

g

g

0.6534

Total Mass in Probe Rinse

09:20 - 09:50

Average Volume Sampled (REF)

PR-47-32938

Start Filter Mass

g

0.15146

0.15479

PR-47-32937

mg/m³

m³

Balance Uncertainty / LOD

Calculated Concentration

TOTAL PARTICULATE MATTER: SAMPLING DETAILS

Balance Uncertainty / LOD

47-32938

mg 0.50

0.21


g

3.18260

0.14625

-

Blank Dates -

mg/m³

Total Mass Collected

Parameter Units

Sampling Dates

ISO

End Probe Rinse Mass

End Filter Mass

Sampling Times

Blank 1

Run 1

APPENDIX 2

-

g

g

27/07/2016

0.6534

g

-

Total Mass in Probe Rinse

Start Probe Rinse Mass

g 0.00042

Volume Sampled (REF) m³

0.00008

mg

g

mg/m³

g

g

2.94032


27/07/2016

CAT-RT (Version BO)

Page 15 of 79

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Sample Runs

MU Acceptable

Test Conditions Units

Allowable Weighing Uncertainty

95 - 115

180

0.27

Weighing Uncertainty Criteria

160

ELV [Daily ELV for IED] mg/m³ 35.00

Weighing Uncertainty Acceptable

Isokinetic Variation

Yes

Run 1

TOTAL PARTICULATE MATTER: QUALITY ASSURANCE

No

%

Yes

± mg/m³

Run 1

Post-Sampling Leak Rate

Leak Test Results

Yes

-

0.41

150

Mean Sampling Rate l/min 20.69

Leak Test Acceptable

l/min 0.30

Allowable Leak Rate

Run 1

Measurement Uncertainty (MU)

-

Silica Gel (Concurrent Water Vapour) Units

Allowable Isokinetic Range %

Allowable MU

(PAGE 1 OF 2)

Units

Units

Filter Temperatures

Units

Yes

Units Run 1

Ambient Temperature Recorded? -

- Yes

Run 1

Are Water Droplets Present

l/min

°C

mg/m³ 1.75

Water Droplets

%

Run 1

20

°C

Yes

APPENDIX 2

Isokinetic Criterion Compliance

Units

Pre-Sampling Leak Rate l/min 0.14

Overall Weighing Uncertainty

Less than 50% Faded

Units

± mg

Run 1

-

°C

%

99.7%

10.7

0.41

%

Isokineticity Acceptable

Maximum Filter Temperature

Pre-Conditioning Temperature

Post-Conditioning Temperature

Run 1

Overall Weighing Uncertainty

MU (Concurrent Water Vapour)

CAT-RT (Version BO)

Page 16 of 79

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Blank Runs

Method Deviations

1

wx

wx

- - - - -

- - - - -

- - - - -

- - - - -

Yes

Post-Sampling Leak Rate l/min 0.18


The sample points where the angle of swirl was > 15° were omitted from the sampling exercise.


Blank 1

0.40

Units Blank 1

mg/l

-

Run Number

-

Yes

3.5

0.12

(PAGE 2 OF 2)

Validity of Blank vs ELV

Acetone / Water Rinse Value

mg/m³

10

Allowable Leak Rate

Allowable Blank

Units

Nature of Deviation

(x = deviation applies to the associated run, wx = deviation also applies to the concurrent water vapour run)

2.7

Pre-Sampling Leak Rate

l/min

l/minExpected Sampling Rate 20.00

Acetone / Water Rinse Blank Units Blank

Blank Acceptable

Leak Test Results

APPENDIX 2

TOTAL PARTICULATE MATTER: QUALITY ASSURANCE

Allowable Blank

mg/l

-

Yes

l/min

Blank Acceptable

CAT-RT (Version BO)

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Sampled Volume (Actual)

Sampled Gas Temperature

Sampled Gas Pressure

Sampled Gas Humidity

Leak

Mass of Particulate

Uncollected Mass





Leak

Mass of Particulate

Uncollected Mass

Sampled Volume (STP)

Leak

Mass of Particulate

Uncollected Mass


Leak

Mass of Particulate

Uncollected Mass

O₂ Correction Factor

Stack Gas O₂ Content

MU for O₂ Correction

Combined uncertainty

Expanded uncertainty (95% confidence), without Oxygen Correction

Expanded uncertainty (95% confidence), with Oxygen Correction

Expanded uncertainty (95% confidence), estimated with Method Deviations

Reported Uncertainty





Oxygen Correction Part of MU Budget

Measured Quantities

-

mg

%

Units

- N/A

Overall MU For O₂ Measurement

mg/m³

18.6

3.540

1.53

≤1%

mg/m³

-

0.50

0.4418

Run 1

≤2%

% v/v

Symbol Units

Uncertainty in Measurement Units Sensitivity Coefficient

%

mg/m³

mg/m³

0.2143

9.23

uVm m³

Measured Quantities Symbol

m um

0.5ρm 100.7

mg/m³

Measured Quantities

% 1.45

N/A

N/A

1.96

0.045

kPa

1.45

0.0Hm

Units

% N/A

Parameter Units

N/A

-uL %

%

≤2%

%

mg/m³ 0.142

3.54

mg/m³

Run 1

uHm

%

Uncertainty as a Percentage

N/A

36.2

1.0

0.29

-

Run 1 Requirement of Standard

Run 1

2.00

Measured Quantities

uUCM mg -

Units

0.69

%

Measured Quantities

%

Vm

0.5873

Symbol

uTm

Run 1

36.2

1.53

mg/m³

K 2.0

0.6666

L

% 0.61

Run 1

1.96

1.00

UCM

m³

0.0454

<5% of ELV

Run 1

mg

APPENDIX 2

TOTAL PARTICULATE MATTER: MEASUREMENT UNCERTAINTY CALCULATIONS

Value Standard uncertainty

0.0133

Lr mg

1.01

290.3

L

%

mg/m³

0.50

UCM

Units Run 1

Tm

Vm

% v/v

uρm

≤1%

Uncertainty in Result

mg/m³ 0.51

≤1%

% 1.00

0.14

CAT-RT (Version BO)

Page 18 of 79

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Sample Runs

- -

- -

- -

- -

- -

- -

- -

- -

Blank Runs

- -

- -






In HouseStandard

2399.4

Technical Procedure CAT-TP-23

Units

2399.4

CONDENSABLE VOCS: RESULTS SUMMARY

6008.4

1.08

Units


47mm Glass FibreFilter Size and Material

Uncertainty

Units

ISO 17025 Accredited Analysis?

±mg/m³

Maximum

12/08/2016

31.19

Mean

31.19

Concentration

Titanium

Parameter

Name of Analytical Laboratory


Yes


OX-IR

1.08

1 / 2

Filter Housing Material

APPENDIX 2


Borosilicate Glass

Parameter

Absorption Solution HPLC Grade Water

Parameter


Sample Point I.D.'s

10.11

±% v/v

37.09

Run 1

14.70

g/hr

Out Stack

14.70

6008.4

Impinger Material

Run 1

10.11

Blank 1

Probe Material

Parameter

±g/hr

Concentration mg/m³

Mass Emission

A3

Uncertainty

Analytical Laboratory's Procedure

Value

Mean

mg/m³ 37.09

Uncertainty

Borosilicate Glass

SAL

Date of Sample Analysis

Water Vapour % v/v

CAT-RT (Version BO)

Page 19 of 79

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Bwo as a percentage





CO₂ (Estimated)

O₂




Total mass collected in impingers (silica trap) g


0.6534

15.62

Nozzle area, An 28.34

N/A

g

-

% v/v


10.11

% v/v

0.1011

QstwO₂ = ((Qa)(Ps)(Cf)) / ((Ts) + 273) / (O₂REFw)

Vs = ((Kp)(Cp)(√∆P)(√Ts + 273)) / (√(Ms)(Ps))



3563.6

N₂


m³

Vwstd = (0.001246)(Vlc)

Md = 0.44(%CO₂)+0.32(%O₂)+0.28(%N₂) g/gmol 28.84


QstdO₂ = ((Qa)(Ps)(Cf)(1 - (Rwv/100))) / ((Ts) + 273) / (O₂REFd)

20.80

minTotal sampling time, q

27.75

% v/v

%

Volume of gas sample through gas meter, Vm

-

m³ N/A

0.06

79.14

% v/v N/A

N/A

-

Qa = (60)(As)(Vs) m³/min


Bwo = Vwstd / (Vmstd + Vwstd)

-

17.97

Area of stack, As

-

N/A

57.0


3.80

6.01Nozzle diameter, Dn

4.24

Ms = Md(1 - (Rwv/100)) + 18(Rwv/100)

Qstw = ((Qa)(Ps)(Cf)) / ((Ts) + 273)

0.6666


N/A

No

2930.6


mm²

-

°C



mmHg

Average dry gas meter temperature, Tm

Ps = (Pb + (Pstatic / 13.6)

m³

% v/v N/A

53.0

Total

755.5

20.86


17.3

Vmstd@X%oxygen = (Vmstd) / (O₂REFd)

% v/v


Vmstd = ((0.3592)(Vm)(Pb + (∆H/13.6))(Yd)) / (Tm + 273)

0.0660

mmHg


Run 1

g

-Gas meter correction factor, Yd

mmH₂O

m³

CONDENSABLE VOCS: ISOKINETIC SAMPLING CALCULATIONS

43.3

761.3

-78.2

9.7

Test Units

0.9310


APPENDIX 2

mmH₂O

10.11

% v/v

% oxygen reference condition, REF%O₂

N/A


2634.4

m³/min N/A

m³

m³ 0.5873

% v/v

46.9

g/gmol

m³

% wet oxygen measured in gas stream, ACT%O₂w % v/v


m³/min

m³/min

m³/min


m²

0.3592

30

0.84

mmH₂O

√mmH₂O

mm

m/s

°C

34.97

99.7

Average of velocity heads, ∆Pavg

CAT-RT (Version BO)

Page 20 of 79

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Sample Runs

-

-

-

-

-

-

-

-


Blank Runs

-

-

-

-

µg/ml

27/07/2016

µg/ml

Parameter

Laboratory Result for Back Impinger

Parameter

67.00

Volume Sampled (REF)

Sampling Device

mg/m³

0.6534

ISO

246.7

09:20 - 09:50

Volume in Front Impingers

Run 1

-

Volume in Impingers ml

APPENDIX 2

m³

µg/ml

24232.4

Calculated Concentration mg/m³ 31.19

-

Laboratory Result for Impingers

µg

7703.5

Volume in Back Impinger ml

304.2

Units



µg

108.5

Mass in Back Impinger

ml

67.00

71.00

µg

Mass in Front Impingers 16528.9

Laboratory Result for Front Impingers


Blank Dates

20381.4

-

CONDENSABLE VOCS: SAMPLING DETAILS

Sampling Times

Sampling Dates

37.09

27/07/2016

Units


m³ 0.6534

µg

-

Blank 1

CAT-RT (Version BO)

Page 21 of 79

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Sample Runs

0 0 0 0

Run 1

Silica Gel (Concurrent Water Vapour)

Yes

-

% Yes

Units

-

Units

%

Run 1

Units

Test Conditions

Absorption Efficiency Acceptable

Allowable Leak Rate

99.7

%

%

l/min 0.14


20.69

MU Acceptable

10.7

Isokinetic Criterion Compliance Units

95 - 115

Allowable MU

Run 1


Leak Test Acceptable -

Allowable Isokinetic Range %

150

Yes


Ambient Temperature Recorded?


Post-Sampling Leak Rate l/min

%

Less than 50% Faded

Run 1

N/A

°C

Yes



N/A

Water Droplets

20


Absorption Efficiency

Units

Yes

-

CONDENSABLE VOCS: QUALITY ASSURANCE

(PAGE 1 OF 2)

Leak Test Results Units

Run 1

Allowable Absorption Efficiency

% 68.2

-

Run 1

Run 1

%

Filter Temperatures

Units

No

0.41

APPENDIX 2

0.30

Mean Sampling Rate

Run 1Absorption Efficiency

l/min

Units

l/min

CAT-RT (Version BO)

Page 22 of 79

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Blank Runs

Method Deviations

1

wx

wx

- - - - -

- - - - -

- - - - -

- - - - -

20.00Expected Sampling Rate l/min

APPENDIX 2



Allowable Leak Rate

Blank 1

10.0

Blank Acceptable - No


l/min 0.12

mg/m³


0.40l/min

Nature of Deviation


Units Blank 1

0.18

Allowable Blank

Units

Run Number


Leak Test Acceptable - Yes

CONDENSABLE VOCS: QUALITY ASSURANCE(PAGE 2 OF 2)

Leak Test Results

CAT-RT (Version BO)

Page 23 of 79

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Leak

Laboratory Result





Leak

Laboratory Result


Leak

Laboratory Result


Leak

Laboratory Result













N/A

Units Run 1



Measured Quantities

%

mg/m³

m³

mg/m³

%

0.5873

290.3

m³0.6666

0.5

0.69

1.00

-

% v/v N/A

% N/A

-

%

Sensitivity Coefficient

Vm

≤2%

0.3105

10.00

10.00

Measured Quantities

39.6

63.15

Run 1

≤1%

%

-

Measured Quantities

7.54

Units

Measured Quantities

mg/m³

% 0.50

1.00

mg/m³

Run 1

N/A

2.00

L

0.9724

Run 1

Tm

Symbol

CONDENSABLE VOCS: MEASUREMENT UNCERTAINTY CALCULATIONS

uVm

uTm K 2.0

mg/m³ 3.709

mg/m³

uHm

uρm

Run 1

0.0

%

% N/A

%

mg/m³ 3.709

14.70


% v/v

%

L

% 39.6

1.45

14.70mg/m³

mg/m³ N/A

Symbol

3.85


20.3

Units

Symbol Units

Parameter Units Run 1

Run 1

No Requirement

Lr

Units

APPENDIX 2

1.0

Vm

Measured Quantities

-

Hm

mg/m³

1.00

Uncertainty in Measurement Units

0.311

%

uLr

0.0133

uL

ρm 100.7


Run 1

1.45

≤1%

≤2%

Requirement of Standard

≤1%

%

kPa

Lr

CAT-RT (Version BO)

Page 24 of 79

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Sample Runs

- -

- -

- -

- -

- -

- -

- -

- -

Blank Runs

- -

< <






1.15

0.1

Run 1

Impinger Material Borosilicate Glass

Concentration

0.1

Name of Analytical Laboratory RPS

mg/m³

Borosilicate Glass

Nitric Peroxide

Sample Point I.D.'s

Uncertainty

1.15

Maximum

0.0011

Absorption Solution

47mm Quartz Fibre

Uncertainty

EN 14385

ISO 17025 Accredited Analysis? Yes

Value

Date of Sample Analysis 09/08/2016

10.88

Units

M31

Number of Sampling Points Used

Out Stack

±% v/v


±mg/m³

Filter Housing Material

Units

Number of Sampling Lines Used 1 / 1

Probe Material Titanium

0.0008

Parameter

Mean

Technical Procedure

Mean

% v/vWater Vapour

Parameter

0.0003

APPENDIX 2

Run 1

±g/hr

CADMIUM & THALLIUM: RESULTS SUMMARY

1 / 1

0.0011

Uncertainty

Mass Emission

0.0003

mg/m³

A3



Standard

CAT-TP-06

Units



10.88

Parameter

g/hr

0.0008

Parameter

0.2

Concentration

0.2

Blank 1

CAT-RT (Version BO)

Page 25 of 79

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Bwo as a percentage





CO₂ (Estimated)

O₂








47.0

mmH₂O 17.28

5.0

mmH₂O -78.2

m³/min

Nozzle diameter, Dn


2877.9

Area of stack, As m² 3.80

Qstd = ((Qa)(Ps)(Cf)(1 - (Rwv/100))) / ((Ts) + 273) m³/min


Qstw = ((Qa)(Ps)(Cf)) / ((Ts) + 273)




Test


15.34

4.16


755.5


g/gmol

N/A

% v/v


1.1309

No

m³/min

°C 21.4

m³

20.80

m³ 0.1381

min 60

mmHg

m/s

% v/v 10.88

m³

-

10.88

98.6

761.3



Average stack gas temperature, Ts °C

g 105.8

mmHg

mm

QstwO₂ = ((Qa)(Ps)(Cf)) / ((Ts) + 273) / (O₂REFw) m³/min N/A

g/gmol

N/A

0.1088

Total


N₂

% v/v

79.14

Ms = Md(1 - (Rwv/100)) + 18(Rwv/100)


28.84

m³/min

% v/v

0.84-

% v/v

m³


Run 1Units

APPENDIX 2

CADMIUM & THALLIUM: ISOKINETIC SAMPLING CALCULATIONS


-

m³

g

Average pressure drop across orifice, ∆H mmH₂O

0.9310

g

110.8

N/A

20.86

1.3020


-

N/A

Nozzle area, An

34.97


m³

-

1.2690

N/A

28.34

% v/v

m³ N/A

N/A

% v/v



Vs = ((Kp)(Cp)(√∆P)(√Ts + 273)) / (√(Ms)(Ps))

Vmstd = ((0.3592)(Vm)(Pb + (∆H/13.6))(Yd)) / (Tm + 273)

6.01

3499.6

-


Vwstd = (0.001246)(Vlc)


%

Md = 0.44(%CO₂)+0.32(%O₂)+0.28(%N₂)

2564.8

mm²

N/A


Pitot tube velocity constant, Kp -

27.66

% v/v

0.06

0.3592

Qa = (60)(As)(Vs)

Average square root of velocity heads, √∆P √mmH₂O

57.0

CAT-RT (Version BO)

Page 26 of 79

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Sample Runs

Cadmium

-

-

Mass in Back Impinger <

-

-

-

-

Thallium

-

<


-

-

-

-

Cadmium & Thallium Combined

-

-

-


Blank Runs

Cadmium

<

<


<

<

<

Thallium

<

<


<

<

<

Cadmium & Thallium Combined

<

<

<

0.05

g/hr

µg

mg/m³

-


µg


10:35 - 11:35

0.0007

µg 0.50


Mass in Front Impingers

0.0004

0.46


Sampling Dates

Sampling Device

Total Mass Collected µg

Sampling Times

µg

Reported Concentration

0.0004

0.0004

0.55

µg

0.40

0.04

0.06

0.0008

m³

Run 1

µg

Units

0.89

Mass on Filter / in Rinse µg 0.80

0.01

1.2690

0.01

µg


-

0.0011

mg/m³

mg/m³

0.0008

0.01

mg/m³

g/hr

Blank 1

0.11

Mass on Filter / in Rinse

µg 0.45

µg

0.04

CADMIUM & THALLIUM: SAMPLING DETAILS

mg/m³



mg/m³

ISO





-

27/07/2016


27/07/2016



APPENDIX 2

Mass Emission

m³

µg

mg/m³


µg

mg/m³ 0.0004

µg



Blank Dates -

Parameter

0.0011


µg


Parameter

Units

0.01

0.08

0.0007

Mass Emission

mg/m³


Reported Concentration mg/m³

0.0004

1.2690

0.99

Mass on Filter / in Rinse µg 0.40

mg/m³

Calculated Concentration mg/m³ 0.0004

1.35

CAT-RT (Version BO)

Page 27 of 79

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Sample Runs

Units Run 1

%

Units

Units

Less than 50% Faded

Run 1

% Yes


Allowable Isokinetic Range

Exit Temperature Acceptable

l/min

- Yes

Maximum Temperature Recorded 18

% 95 - 115

µg/m³



Maximum Filter Temperature °C

Run 1

- Yes

Yes

Measurement Uncertainty (MU) % 10.6


Units

180

98.6

Water Droplets Units

5

Run 1

°C

°C 30

Units Run 1

Ambient Temperature Recorded? Yes-

Allowable Detection Limit

-

Allowable Leak Rate

%

APPENDIX 2

0.40

l/min


Pre-Sampling Leak Rate l/min

20.20

%

20

Leak Test Results Run 1

0.4

Yes

(PAGE 1 OF 2)

µg/m³


Where the emissions are < 30% of the ELV, MID 14385 does not require the 90% absorption efficiency requirement to be applied


0.21

Filter Temperatures

Units Run 1

Units


Run 1

l/min

100.0

Run 1

N/A

0.16

Thallium % 100.0

-

Thallium

MU Acceptable


%

-

µg/m³

Run 1

Units

Mean Sampling Rate

Allowable MU

Units

Detection Limit

Cadmium


Detection Limit Acceptable

Impingers Exit Temperature

Cadmium

Maximum Allowable Temperature


No

-

Test Conditions

N/A

0.4

%

Yes

CADMIUM & THALLIUM: QUALITY ASSURANCE

CAT-RT (Version BO)

Page 28 of 79

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Blank Runs

Method Deviations

1

wx

wx

- - - - -

- - - - -

- - - - -

- - - - -

Allowable Blank

0.40

APPENDIX 2

Blank 1



0.0050

Validity of Blank vs ELV Units

mg/m³

l/min 20.00Expected Sampling Rate

Allowable Leak Rate


Leak Test Results


0.20



-

0.18

l/min

Nature of Deviation Run Number

CADMIUM & THALLIUM: QUALITY ASSURANCE(PAGE 2 OF 2)

Yes

Yes

l/min

Units Blank 1

Blank Acceptable -

CAT-RT (Version BO)

Page 29 of 79

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Leak

Laboratory Result





Leak

Laboratory Result


Leak

Laboratory Result


Leak

Laboratory Result













%

- N/A

Units Run 1

% -

m³

1.04 uL

Measured Quantities Requirement of Standard

%

≤1%0.68

2.00

≤2%

%

1.04

≤1%

% 1.00

Run 1

uLr % -

Tm 294.4

uρm

uVm

Run 1 Run 1

ρm

mg/m³ 0.0002

mg/m³ 0.0003

0.0003

L mg/m³ 0.0000

% v/v N/A

- N/A

Overall MU For O₂ Measurement % N/A

% 15.6

mg/m³


%

Measured Quantities


Vm 1.3020

0.5

Hm 0.0

CADMIUM & THALLIUM: MEASUREMENT UNCERTAINTY CALCULATIONS

Symbol

Symbol Units

uTm


≤2%

≤1%

0.50


kPa

0.0260

Measured Quantities

m³ 0.00

Run 1

1.1309


Units Run 1

%

7.50 No Requirement

Vm

K

L

100.7

Measured Quantities Units Run 1

1.00


Units

mg/m³

0.0001

% 30.5

mg/m³ 0.0001

mg/m³ 0.0000

mg/m³ N/A

mg/m³ 0.0000

% N/A

Parameter Units

% 30.5

Lr mg/m³ 0.0001 1.00

Run 1

Standard uncertainty

APPENDIX 2

uHm % v/v 1.0

2.0

Lr

Value

7.50

CAT-RT (Version BO)

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Sample Runs

- -

- -

- -

- -

- -

- -

- -

- -

Blank Runs

- -

- -






11.6Uncertainty

Units

Nitric Peroxide

Run 1

APPENDIX 2


10.88

Uncertainty ±% v/v 1.15 1.15

Borosilicate Glass

Mass Emission g/hr

Blank 1

Mean


Maximum


% v/v


0.005

47mm Quartz Fibre

Parameter Units

09/08/2016

39.8

0.246

A3

Parameter

±g/hr

EN 14385

Mean

CAT-TP-06

0.246


Analytical Laboratory's Procedure M31


Titanium


Impinger Material

0.071

HEAVY METALS: RESULTS SUMMARY

Water Vapour

Out Stack


10.88

Parameter

11.6



Probe Material

Sample Point I.D.'s

Technical Procedure

Absorption Solution


Value


0.005

0.071Uncertainty ±mg/m³

39.8


Standard

CAT-RT (Version BO)

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Bwo as a percentage





CO₂ (Estimated)

O₂





Average of velocity heads, ∆Pavg mmH₂O


17.28

QstdO₂ = ((Qa)(Ps)(Cf)(1 - (Rwv/100))) / ((Ts) + 273) / (O₂REFd) m³/min

%

N/A

min 60

N/A

4.16

Average stack gas temperature, Ts °C

3.80


HEAVY METALS: ISOKINETIC SAMPLING CALCULATIONS

Test Units Run 1

Barometric pressure, Pb 761.3


N₂

-

g 110.8

g 5.0

% v/v

m³ 1.2690

m³/min


10.88% v/v

IED & Incinerates Hazardous Material? (Yes = no positive O₂ correction) -

2564.8

Nozzle area, An mm² 28.34

Bwo = Vwstd / (Vmstd + Vwstd) m³

2877.9

98.6

Vwstd = (0.001246)(Vlc) m³


N/A

-

47.0

% v/v



Vs = ((Kp)(Cp)(√∆P)(√Ts + 273)) / (√(Ms)(Ps)) m/s

m³/min N/AQstwO₂ = ((Qa)(Ps)(Cf)) / ((Ts) + 273) / (O₂REFw)

-

Average dry gas meter temperature, Tm °C 21.4


No

10.88

Total mass collected in impingers (liquid trap) g


Qstw = ((Qa)(Ps)(Cf)) / ((Ts) + 273)

N/A

15.34

Nozzle diameter, Dn mm 6.01

m²

0.06

57.0



Md = 0.44(%CO₂)+0.32(%O₂)+0.28(%N₂)

-

0.1381


m³

0.1088

g/gmol 28.84

Ms = Md(1 - (Rwv/100)) + 18(Rwv/100) g/gmol 27.66

N/A

- 0.84

N/A


Qa = (60)(As)(Vs) m³/min 3499.6

Vmstw@X%oxygen = (Vmstw) / (O₂REFw) m³


- 0.3592



20.86

20.80

mmHg 755.5

Total % v/v

mmHg

0.9310


1.3020

105.8

mmH₂O

m³

% dry oxygen measured in gas stream, ACT%O₂d % v/v

% v/v

APPENDIX 2

% v/v 79.14

% v/v

m³/min

Stack static pressure, Pstatic mmH₂O -78.2

N/A

Area of stack, As


% v/v N/A

Vmstd = ((0.3592)(Vm)(Pb + (∆H/13.6))(Yd)) / (Tm + 273) m³ 1.1309


34.97

CAT-RT (Version BO)

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Sample Runs

Arsenic

-

-


-

-

-

-

Cobalt

<

<


<

<

<

<

Chromium

-

-

Mass in Back Impinger -

-

-

-

-

Copper

-

-


-

-

-

-

Manganese

-

-


-

-

-

-



µg

Total Mass Collected µg 0.56

mg/m³

0.0004

Mass on Filter / in Rinse µg

µg

Units Run 1


mg/m³ 0.0143

0.07

0.0185

0.0185

Mass in Front Impingers µg 6.86

0.50

Reported Concentration mg/m³ 0.0033



µg

108.00

11.00

4.17Total Mass Collected

Mass Emission

m³ 1.2690

HEAVY METALS: SAMPLING DETAILS

Parameter

0.0033Calculated Concentration mg/m³

0.01

Calculated Concentration mg/m³

Sampling Times

27/07/2016

µg 0.15

Sampling Device - ISO

0.53

Sampling Dates

APPENDIX 2

(PAGE 1 OF 5)

-

4.00

- 10:35 - 11:35



µg

g/hr

Mass Emission


µg 0.25

µg

108.26

mg/m³

mg/m³ 0.0004

Mass Emission g/hr 2.99

3.00

0.25


20.32

Mass Emission

µg


mg/m³

g/hr




µg

mg/m³ 0.0143


µg

µg 18.11Total Mass Collected

0.10

0.02

2.31

µgTotal Mass Collected

0.01



Mass Emission


g/hr

g/hr

0.0853

0.0853

13.82

CAT-RT (Version BO)

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Sample Runs (continued)

Nickel

-

-


-

-

-

-

Lead

-

-


-

-

-

-

Antimony

-

<


-

-

-

-

Vanadium

<

<


<

<

<

<


µg 0.25

µgTotal Mass Collected

0.0063

mg/m³

µg

mg/m³

1.06

Run 1

0.1164

18.86

µg


g/hr 1.02

0.03

µg 0.01

µg

mg/m³



µg

147.76


Mass Emission

0.01

mg/m³

0.05

0.40


0.0003


g/hr

µg

0.14


Mass Emission



Mass Emission g/hr

0.0008

µg

Mass Emission g/hr

mg/m³

1.00


0.0008

0.05

µg


mg/m³


Units

µg 7.00

0.51

µg 147.00

µg 0.43

Calculated Concentration 0.0063


8.03

Parameter

APPENDIX 2

HEAVY METALS: SAMPLING DETAILS(PAGE 2 OF 5)

Mass in Front Impingers µg



1.02

0.01

0.1164


0.0003

mg/m³

µg

mg/m³

CAT-RT (Version BO)

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Sample Runs (continued)

Heavy Metals Combined

-

-

-


Blank Runs

Arsenic

<

<


<

<

<

Cobalt

<

<


<

<

<

m³


µg



µg


µg


0.50


0.06

311.80

mg/m³

Blank Dates

1.2690

mg/m³

- 27/07/2016

µg

APPENDIX 2

(PAGE 3 OF 5)

Parameter



0.57

Run 1

mg/m³

UnitsParameter


mg/m³

0.50

0.01

0.0004

0.0004

0.02


µg

0.04

0.55Total Mass Collected


0.2457

µg

µg


0.0004mg/m³

Units Blank 1



CAT-RT (Version BO)

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Blank Runs (continued)

Chromium

<

-


-

-

-

Copper

<

-


-

-

-

Manganese

-

<


-

-

-

Nickel

<

<


<

<

<

Lead

<

-


-

-

-

Antimony

<

<


<

<

<

Vanadium

<

<


<

<

<

0.0005

0.59



mg/m³

0.0003

0.0014

mg/m³



0.0005

mg/m³


mg/m³

µg

0.42

µg


µg


0.02

0.0005


mg/m³


mg/m³

µg

mg/m³


mg/m³


0.07

µg

µg

µg


0.0008

0.04


0.40


mg/m³

mg/m³

0.65

0.0005

Reported Concentration mg/m³ 0.0004

µgMass on Filter / in Rinse

0.0004

0.50




0.0008

0.04

0.0005

µg

0.60

mg/m³

mg/m³

µg

µg

0.65

µg 0.50

0.0005

µg

µg

0.55

µg 0.18

0.21

0.60

0.01

µg

µg

mg/m³

0.02




µg

0.01

0.01

0.60



µg

APPENDIX 2

µg 1.73

0.99

µg

0.60


0.0014




µg

1.10

0.01


Units Blank 1



µg

µg



µg

0.03


(PAGE 4 OF 5)

Parameter



CAT-RT (Version BO)

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Blank Runs (continued)

Heavy Metals Combined

-

-

-

Units Blank 1


0.0053

(PAGE 5 OF 5)

Parameter

APPENDIX 2

µg


mg/m³ 0.0053

6.70



CAT-RT (Version BO)

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Sample Runs

0.4

% N/A <1% Total

% N/A <1% Total

100.0

-

0.4

% 10.6

Arsenic

µg/m³

Chromium

Absorption Efficiency Units Run 1

Vanadium

Detection Limit


µg/m³

20


% N/A <1% Total

Cobalt

0.4

Run 1

90

Units

µg/m³

Units

Run 1

Allowable Detection Limit


MU Acceptable % Yes

Units

%

Mean Sampling Rate

98.6

%

Nickel

Lead

Chromium %

Arsenic

l/min 0.40

l/min

- Yes

Nickel %

(PAGE 1 OF 2)

Copper %

100.0

Manganese

0.5

HEAVY METALS: QUALITY ASSURANCE

99.6

% 100.0

l/min 20.20

0.21

0.16

0.3

Antimony µg/m³ 0.5



Cobalt



Antimony

Allowable Leak Rate

µg/m³

µg/m³

0.5

99.8

%

0.6

Lead

0.5

Copper

Yes

APPENDIX 2

µg/m³

Water Droplets

µg/m³

Manganese

Vanadium µg/m³

µg/m³

Run 1

Detection Limit Acceptable -


Run 1

5

Are Water Droplets Present - No

Yes

Allowable MU %

CAT-RT (Version BO)

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Blank Runs

Method Deviations

1

wx

wx

- - - - -

- - - - -

- - - - -

- - - - -

APPENDIX 2

18

% 98.6

Less than 50% Faded %

°C


Yes




Allowable Blank mg/m³


0.0500

Nature of Deviation Run Number

Run 1Test Conditions Units

Allowable Leak Rate

Silica Gel (Concurrent Water Vapour) Units Run 1

30



%

HEAVY METALS: QUALITY ASSURANCE

20.00

- Yes

°C 180

Impingers Exit Temperature Units Run 1

Filter Temperatures Units

Units Run 1

95 - 115

(PAGE 2 OF 2)

Blank 1



Units

Yes

Isokineticity Acceptable - Yes

Expected Sampling Rate

0.18


Leak Test Results


l/min

Run 1


-

Blank Acceptable -

0.20

l/min

Maximum Temperature Recorded °C

0.40

Yes


l/min

l/min

- Yes

Units Blank 1


CAT-RT (Version BO)

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Leak

Laboratory Result





Leak

Laboratory Result


Leak

Laboratory Result


Leak

Laboratory Result













28.7

1.00Lr mg/m³ 0.0172

% 1.00

L

0.0362

2.00

Measured Quantities

mg/m³

Units

0.0065

mg/m³ 0.0184

% 28.7

% 14.7

1.04

- N/A

mg/m³

% N/A

% v/v N/A

mg/m³ 0.0705

L 1.04

0.50

Symbol Units Run 1

mg/m³

≤2%

%

Symbol


%

Measured Quantities Units

APPENDIX 2

Run 1

Run 1

mg/m³

%

Tm 294.4

1.0

m³

Lr 7.00

uTm K

0.0260

0.0015 1.00

0.0015

mg/m³

mg/m³


HEAVY METALS: MEASUREMENT UNCERTAINTY CALCULATIONS



0.68

- N/A

m³

N/A



1.1309

mg/m³

uL %

≤1%

%


≤1%

Run 1

0.0705

-

≤2%

% 7.00

Run 1


≤1%

No Requirement

N/A

%

uLr

Run 1Units

Vm 1.3020


Measured Quantities

0.5

Run 1

0.0

ρm 100.7 uρm kPa

2.0

uHm % v/v

0.22

uVm

% -

%

Vm

0.0172


Hm

CAT-RT (Version BO)

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Sample Runs

- -

- -

- -

- -

- -

- -

- -

- -

Blank Runs

- -

< <






Uncertainty

Water Vapour % v/v 10.88

Uncertainty ±% v/v

±g/hr 0.0

Mean

Units


0.0001

10.88

Impinger Material


Parameter Units


1.15



0.0

APPENDIX 2

MERCURY: RESULTS SUMMARY

0.0002

Uncertainty ±mg/m³ 0.0001

Parameter

Blank 1


0.0001

Parameter


Absorption Solution Nitric Peroxide & Potassium Dichromate

1 / 1

Mass Emission

1.15



0.0

Mean

Standard

Concentration mg/m³ 0.0001

A3


MID 14385

Value

Borosilicate Glass

0.0

Out Stack

Run 1


Maximum

g/hr

Concentration mg/m³ 0.0002


Filter Size and Material 47mm Quartz Fibre


Sample Point I.D.'s

Yes

CAT-RT (Version BO)

Page 41 of 79

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Bwo as a percentage





CO₂ (Estimated)

O₂







110.8

755.5

°C

Area of stack, As 3.80

4.16

10.88

1.3020



57.0

% v/v

%


m³/min

mmHg

0.3592

N₂

% v/v


Volume of gas sample through gas meter, Vm m³

mmHg 761.3

% v/v

Total mass of liquid collected, Vlc g

Vwstd = (0.001246)(Vlc) m³ 0.1381

APPENDIX 2

m²

% v/v N/A

20.86

Vmstd = ((0.3592)(Vm)(Pb + (∆H/13.6))(Yd)) / (Tm + 273) m³


79.14

1.2690

g/gmol

Run 1

mm 6.01

N/A

Nozzle diameter, Dn

28.34Nozzle area, An mm²

QstwO₂ = ((Qa)(Ps)(Cf)) / ((Ts) + 273) / (O₂REFw) m³/min


m³/min

Total sampling time, q min 60



m³/min N/A

-




0.1088

mmH₂O

% v/v

mmH₂O

10.88

N/A

0.84

Units

34.97

m³

-

N/A



Vmstw = (Vmstd)(100/(100 - Rwv)) m³



% v/v

Md = 0.44(%CO₂)+0.32(%O₂)+0.28(%N₂)


- No

- N/A

N/A

m³


Ms = Md(1 - (Rwv/100)) + 18(Rwv/100)

m³

2877.9

m³/min 3499.6

17.28

20.80

√mmH₂O

Qa = (60)(As)(Vs)


98.6

Qstw = ((Qa)(Ps)(Cf)) / ((Ts) + 273)

2564.8


Gas meter correction factor, Yd - 0.9310

N/A

15.34

27.66

% v/v

N/A

0.06

O₂ Reference Factor wet (O₂REFw) = (21 - REF%O₂) / (21 - ACT%O₂w) -

47.0

Total mass collected in impingers (liquid trap) g 105.8

Total mass collected in impingers (silica trap) g 5.0

Pitot tube velocity constant, Kp -

g/gmol 28.84

1.1309

% v/v

Total


MERCURY: ISOKINETIC SAMPLING CALCULATIONS

Test

CAT-RT (Version BO)

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Sample Runs

<

-

Mass in Final Impinger -

-

-

-


Blank Runs

<

<

Mass in Final Impinger <

<

<

<

0.0002

0.03

ISO

µg 0.04

mg/m³

MERCURY: SAMPLING DETAILS

Parameter Units

mg/m³ 0.0001

1.2690

-

Units Blank 1

Mass in Front Impinger/s


Sampling Device


m³

µg

µg

m³


Mass in Front Impinger/s

µg


10:35 - 11:35

Blank Dates -


0.02



0.13

27/07/2016


27/07/2016


Sampling Dates

µg 0.03

mg/m³ 0.0002

Run 1

0.29

1.2690

Parameter

APPENDIX 2

µg

Sampling Times -

µg

-

0.22


µg 0.18

mg/m³ 0.0001

CAT-RT (Version BO)

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Sample Runs



µg/m³ 2.0

Yes

Run 1


Units

Units Run 1


Units

Yes

% 98.6

Run 1


180


Maximum Temperature Recorded

°C 30


Allowable MU

- Yes

Where the emissions are < 30% of the ELV, MID 14385 does not require the 95% absorption efficiency requirement to be applied

Run 1

Filter Temperatures

MERCURY: QUALITY ASSURANCE


-



Less than 50% Faded

%

Impingers Exit Temperature

10.6

Units Run 1


Concentration Acceptable


°C 18

Units Run 1

% 95 - 115


-

0.03

UnitsWater Droplets

Units Run 1

Run 1

- Yes

Run 1

Run 1

-

Units

Concentration in Final Impinger

Pre-Sampling Leak Rate l/min 0.16

No

0.40

86.1

Leak Test Results

Units

%

Allowable Concentration


µg/m³Concentration in Final Impinger

Exit Temperature Acceptable - Yes

MU Acceptable % Yes

20.20


%

°C

APPENDIX 2

Mean Sampling Rate l/min

l/min

%

-

Units

(PAGE 1 OF 2)


Allowable Leak Rate

% 20

Yes

l/min 0.21

N/A

Test Conditions

N/A


CAT-RT (Version BO)

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Blank Runs

Method Deviations

1

wx

wx

- - - - -

- - - - -

- - - - -

- - - - -

20.00

Allowable Leak Rate l/min


-

l/min

0.0050


0.40

Yes

Blank Acceptable

APPENDIX 2

MERCURY: QUALITY ASSURANCE(PAGE 2 OF 2)

l/min

Blank 1


0.20

Nature of Deviation


Run Number




Units

0.18

Yes-

Blank 1




CAT-RT (Version BO)

Page 45 of 79

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Leak

Laboratory Result





Leak

Laboratory Result


Leak

Laboratory Result


Leak

Laboratory Result













Run 1

uρm kPa 0.5

25.2

%


25.2

Run 1

1.00L

mg/m³


% N/A

N/A-


uL %

Hm

Measured Quantities Symbol Symbol


1.3020

Tm

%

%

0.00002mg/m³

No Requirement


%

mg/m³ 0.00001

Vm

Units Run 1

mg/m³ 0.0001


mg/m³

N/A

0.0260uVm m³

0.00

0.00001

0.000001

294.4 uTm K

0.000001

12.9

Measured Quantities

% v/v

0.00001

mg/m³

mg/m³

Run 1

- N/A

1.00

1.04

uHm

0.0001

%

1.1309

≤2%

≤1%

% 0.50

1.00

Run 1

Lr

≤1%

%

mg/m³

%

mg/m³

m³


Units

uLr

0.0

Lr 6.00

0.00003

1.04

6.00

≤2%


Symbol

2.00

ρm


APPENDIX 2

mg/m³

% v/v N/A

-

1.0

0.68

Parameter

100.7

Units Run 1

Run 1

L

2.0

Value

%

≤1%


MERCURY: MEASUREMENT UNCERTAINTY CALCULATIONS

% -

Vm

CAT-RT (Version BO)

Page 46 of 79

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Sample Runs (UPPER NATO I-TEQ)

- -

- -

- -

- -

- -

Sample Runs (UPPER WHO TEQ Humans / Mammals)

- -

- -

- -

- -

- -

Sample Runs (UPPER WHO TEQ Fish)

- -

- -

- -

- -

- -

Sample Runs (UPPER WHO TEQ Birds)

- -

- -

- -

- -

- -

Uncertainty

Uncertainty

ng/m³

Parameter

0.0016

µg/hr 0.3

APPENDIX 2

ng/m³ 0.0018 0.0018

Parameter Units

Mass Emission

0.0020

0.0007

DIOXINS & FURANS: RESULTS SUMMARY


0.0016

(PAGE 1 OF 4)

Uncertainty ±ng/m³ 0.0007


Parameter Units

Concentration ng/m³

0.0008

Mass Emission

±ng/m³

Parameter Units

0.1

Concentration ng/m³ 0.0017

0.3

Uncertainty ±µg/hr 0.1

0.0017

Uncertainty

Run 1 Mean

NOTE: Where the maximum Blank concentration is higher than the Sample concentration, the Blank concentration has been reported.

µg/hr 0.3

Run 1

Mean

0.0020

0.3

Uncertainty ±µg/hr 0.1 0.1

Run 1

Uncertainty ±µg/hr

Concentration

Units Run 1

0.7

0.1

0.0007

Mass Emission µg/hr 0.3 0.3

TEQ1 - UPPER LIMITS (worst case where <LOD = LOD)


Concentration

Mass Emission µg/hr 0.7

0.0041 0.0041

±ng/m³

Mean

±ng/m³ 0.0007

Mean

0.30.3

0.0008

CAT-RT (Version BO)

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Sample Runs (LOWER NATO I-TEQ)

- -

- -

- -

- -

- -

Sample Runs (LOWER WHO TEQ Humans / Mammals)

- -

- -

- -

- -

- -

Sample Runs (LOWER WHO TEQ Fish)

- -

- -

- -

- -

- -

Sample Runs (LOWER WHO TEQ Birds)

- -

- -

- -

- -

- -

Run 1

Uncertainty

Uncertainty

Parameter

Mean

Parameter


±µg/hr 0.1

µg/hr 0.7

Run 1

0.1 0.1

0.0018

Run 1

0.1

±ng/m³

0.0017

Uncertainty

0.0008

0.0020

Uncertainty

Mean

0.0007

APPENDIX 2

Mass Emission µg/hr 0.3

Uncertainty ±µg/hr


0.3



0.1

µg/hr

±µg/hr 0.1

0.3

Units

Concentration ng/m³ 0.00410.0041


Uncertainty ±ng/m³

Mass Emission


0.0016

Uncertainty

Mean

Mass Emission

Parameter Units

±ng/m³ 0.0007

(PAGE 2 OF 4)



TEQ2 - LOWER LIMITS (best case where <LOD = 0)

0.0008

0.0020

±ng/m³

0.7


0.0016

Units

Mass Emission

Run 1

0.0007


Parameter Units

0.3

0.0017

Mean

0.3

0.3

0.0007


µg/hr 0.3

CAT-RT (Version BO)

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Blank Runs (UPPER NATO I-TEQ)

- -

- -

Blank Runs (UPPER WHO TEQ Humans / Mammals)

- -

- -

Blank Runs (UPPER WHO TEQ Fish)

- -

- -

Blank Runs (UPPER WHO TEQ Birds)

- -

- -

Blank Runs (LOWER NATO I-TEQ)

- -

- -

Blank Runs (LOWER WHO TEQ Humans / Mammals)

- -

- -

Blank Runs (LOWER WHO TEQ Fish)

- -

- -

Blank Runs (LOWER WHO TEQ Birds)

- -

- -

0.0041

DIOXINS & FURANS: RESULTS SUMMARY(PAGE 3 OF 4)

Units

0.0017

ng/m³

0.0018

Maximum


ng/m³

0.0041

Parameter

TEQ2 - LOWER LIMITS (best case where <LOD = 0)

Parameter Blank 1


Concentration

ng/m³ 0.0041

Units

Units Blank 1

Blank 1 Maximum

Blank 1

Parameter

0.0017

ng/m³

Maximum

Concentration

0.0020

0.0018

Parameter Units

0.0041

Maximum

0.0017

Concentration

0.0020 0.0020

0.0020

Units Maximum

Concentration

Blank 1

Concentration

Concentration

Maximum

Parameter

Units Blank 1

ng/m³

ng/m³

0.0018


APPENDIX 2

Parameter Units Blank 1

Parameter Maximum


Maximum

TEQ1 - UPPER LIMITS (worst case where <LOD = LOD)


CAT-RT (Version BO)

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- -

- -

- -








1.06

EN 1948

1.06


Water Vapour % v/v

(PAGE 4 OF 4)


APPENDIX 2


Name of Analytical Laboratory SAL

B3

90mm Quartz Fibre

Parameter Value

Borosilicate Glass

Uncertainty ±% v/v



16/08/2016


Mean

9.51

XAD-2

Yes


SOP 1C

9.51



Glassware Material

Out Stack



Absorption Material

Standard


Sample Point I.D.'s

1 / 12

CAT-RT (Version BO)

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Bwo as a percentage





CO₂ (Estimated)

O₂





18.32

Md = 0.44(%CO₂)+0.32(%O₂)+0.28(%N₂) g/gmol

QstdO₂ = ((Qa)(Ps)(Cf)(1 - (Rwv/100))) / ((Ts) + 273) / (O₂REFd) m³/min



N/A

48.0

N/A


APPENDIX 2

DIOXINS & FURANS: ISOKINETIC SAMPLING CALCULATIONS


-78.2


g

0.3592


min

N/A

0.84


% v/v 9.51

m³/min

15.76

28.34

591.7

7.7542


Vmstw@X%oxygen = (Vmstw) / (O₂REFw) m³

% v/v 0.06

Ms = Md(1 - (Rwv/100)) + 18(Rwv/100) g/gmol

√mmH₂O


g


N₂ % v/v

N/A


28.84


Test

35.9g


m³

Barometric pressure, Pb mmHg 761.3



mmHg


Qa = (60)(As)(Vs)

Velocity pressure coefficient, Cp -

2674.4


% dry oxygen measured in gas stream, ACT%O₂d % v/v

°C

% v/v

Total % v/v 20.86

No


Vwstd = (0.001246)(Vlc) m³ 0.7373

m³ 0.0951

Units Run 1

7.0169

Gas meter correction factor, Yd - 0.9310

555.8

27.81

mmH₂O


m³ 8.1511

% v/v

-

mmH₂O

N/A

755.5

-

24.1

N/A

mmH₂OAverage of velocity heads, ∆Pavg

- 34.97

4.28


20.80

-

Nozzle area, An


m³ N/A

%I = (4.6398E⁶)(Ts+273)(Vmstd) / (Ps)(Vs)(An)(q)(1 - (Rwv/100)) % 97.8



79.14

3593.9

3.80

-

N/A

% v/v

Average stack gas temperature, Ts °C 57.0

360

mm²

Vmstd = ((0.3592)(Vm)(Pb + (∆H/13.6))(Yd)) / (Tm + 273) m³

9.51


Nozzle diameter, Dn mm 6.01

Qstw = ((Qa)(Ps)(Cf)) / ((Ts) + 273) m³/min 2955.4

CAT-RT (Version BO)

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2378-TCDD

12378-PeCDD

123478-HxCDD

123678-HxCDD

123789-HxCDD

1234678-HPeCDD

OCDD

Total Dioxins

2378-TCDF

12378-PeCDF

23478-PeCDF

123478-HxCDF

123678-HxCDF

234678-HxCDF

123789-HxCDF

1234678-HPeCDF

1234789-HPeCDF

OCDF

Total Furans

Totals

Total Concentration

Limit of Detection

Where: ND stands for Non Detected

DL stands for Analytical Detection Limit

TEQ1 refers to Non Detected Congeners at the Detection Limit

TEQ2 refers to Non Detected Congeners at Zero

% Rec stands for the Recovery Percentage of the Sample

-

- 0.0014

-

-

0.0003

0.0017

0.0003

0.0001

0.0080

0.0080

0.0109

0.0014

0.0003

-

0.0042

0.0003

113

127

- -

0.000001

0.0003

0.0028

0.000001

0.0002

-0.0030

ng

ng

-

- 0.0012

0.0075

-

0.0003

-

0.0001

0.000002

0.0022

0.0050

0.0050

-

0.0001

0.0001

0.0096

0.0001

0.000001

0.0028

0.0075

0.0003

ng

780.0030

0.0022

0.0022

0.0030

0.0002

0.0000

0.0001

99

0.0030

0.0020

0.00300.0030

0.0020

0.0003

0.0003

0.0003

0.0030

0.0003

0.0003

0.0003

TEQ2 TEQ1

0.0003

0.0050

0.00002

0.00001

11:00 - 17:00Sampling Times

Sampling Dates

Sampling Device

0.000008

0.0004

0.0003

0.000002

0.0051

0.0019

0.0020

0.0030

0.0540

0.0030 0.0030

0.0030

0.000008

0.0020

0.0039 0.0047

0.0002

0.0002

0.0001

0.0003

0.0001

0.0015

0.0001

96

0.0047 0.0149

0.0080 0.000001

0.0022

0.0003

1230.0080

0.0015

0.0022

0.0050

0.000001

0.0003

0.0003

ng

0.0002

-

0.0011

0.0030

Units

-

0.0012

0.00420.0216

0.0020

0.0003

0.0055

0.0003

0.0050

0.0055

0.0003

0.0003

0.0002

ng/m³

0.0051 0.0039

0.0012

0.0093

0.0012

0.0093 0.0202

0.0026

0.0096

0.0012

RUN 1

0.000001

ng

ng

0.0030

0.0001

0.000002

0.0020

0.0003

0.0003

0.0001

0.0001

0.0020

0.00002

0.0001

0.0008

0.0003

0.0001

-

-

0.0061ng

0.000005

TEQ1

Parameter

0.00002

0.0003

0.0030

0.0011

0.0002

0.0003

0.00002

0.00001

TEQ2TEQ2

0.0008

26/07/2016

Volume Sampled (REF) m³

Value

ng

0.0001

0.0030

0.0055

7.7542

NATO

I-TEQ

WHO Humans /

Mammals

WHO

Fish

WHO

Birds

DL TEQ1 TEQ2Parameter Units Result

APPENDIX 2

ISO

TEQ1

-ng

0.0022

ng

0.0004

0.0055

0.0002

ng

0.00020.0002

0.0003

ng

0.0005

0.0008

0.0001

0.0000

0.0001

0.000005

0.0003

0.0028

0.0003

0.0003

-

100

121

106

109

0.0149

0.0003

DIOXINS & FURANS: SAMPLING DETAILS

0.0020

0.0075

0.0050ng

78

75

0.0030

0.0021

0.0002

0.0001

0.0002

0.0054 0.0054

0.000001

0.0002

0.00001

0.0028

0.0109

0.0014

ng

ng

0.0003

0.0002

0.00001ng

ng

0.0061

0.0080

0.0003

0.0002

0.000002

-

0.0020

% Rec

0.0001

0.0003

0.0057 0.0057

0.0008

0.0001

0.000001

0.0020

0.0002

0.0017

0.0001

116

0.0011

ng

ng

- -

ng 0.0756 0.0202

0.0026

ng/m³ -

0.00010.0080

0.0005

CAT-RT (Version BO)

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2378-TCDD

12378-PeCDD

123478-HxCDD

123678-HxCDD

123789-HxCDD

1234678-HPeCDD

OCDD

Total Dioxins

2378-TCDF

12378-PeCDF

23478-PeCDF

123478-HxCDF

123678-HxCDF

234678-HxCDF

123789-HxCDF

1234678-HPeCDF

1234789-HPeCDF

OCDF

Total Furans

Totals

Total Concentration

Where: ND stands for Non Detected

DL stands for Analytical Detection Limit

TEQ1 refers to Non Detected Congeners at the Detection Limit

TEQ2 refers to Non Detected Congeners at Zero

% Rec stands for the Recovery Percentage of the Sample

BLANK 1

0.00002

0.0006

0.0006 0.0006

0.0058

0.0005 0.0005 0.0005

TEQ2 TEQ1TEQ2

Sampling Device -

0.0135 0.0135

-

-

0.0050

0.00200.0020

ng 0.0050 0.00050.0005

0.0035

-

0.0001

0.0018 0.0018

Parameter Units Result

0.000008

0.0080

ng

0.00002

0.00001

0.0020

0.0001 0.0001 0.0001

0.000001

0.0001

0.0060

0.0005

TEQ1

Parameter

0.0062 0.0065

0.0002

0.0073

0.0141 0.0141

0.0008 0.0008 0.0008

ISO

WHO

Fish

% RecDL

0.00330.0020

0.0006

0.0020

0.00002

0.0035

0.00001

ng

Units

0.0001

0.000002 0.0000020.0080 0.0080

0.0044 0.0044

WHO

Birds

- 0.0041

ng

0.0002

0.0002

ng

0.0020

0.0002

0.000002 0.0000020.00001

TEQ2 TEQ1

0.0050

99

0.0008

0.000001 0.000001

0.0012

0.0026

ng 0.0727 - 0.0097 0.0097 0.0073

0.0001

0.0020

0.0006 96

106

0.0080 0.0001

ng 0.0075

0.0050 0.0001

0.0006ng 0.0058 0.0021

-

0.0006 0.00060.00120.0012

-

0.000001 0.000001 0.000001

0.0002

0.0006

103

0.0120

0.0017

0.0156 0.0322- 0.0322

ng/m³

0.1002

-

0.0006

m³

Value

0.0018 0.0018 0.0041

0.0012

ng

99

0.0004

0.0110

TEQ1 TEQ2

0.0055

0.00200.0020

ng

0.00002

0.0020

0.0020

0.00001

0.0002

121

0.0020 0.0020 0.0020ng 0.0020

0.0002

0.0055

0.0020

0.0008

0.0020 0.0020

0.0035

0.0002

ng

0.0002

0.0275

0.0002

7.7542

Sampling Dates - 26/07/2016


APPENDIX 2

DIOXINS & FURANS: SAMPLING DETAILS

ng 0.0035

0.0058

0.0055

0.0050

0.0004 0.0002

0.0006 0.0006 0.0006

ng 0.00020.0002

0.0020 0.0020

76

0.0020

0.0006 0.0006

0.0120 0.0120

0.0050

0.0077

0.0001 0.0001

0.0005

0.0062

0.000020.0002 0.00002

0.0055

WHO Humans /

Mammals

ng

NATO

I-TEQ

0.0033

0.0001

-

0.0050

0.0002

106

0.0010

0.0035

0.000008

(Continued)

1060.0002

0.0020

0.0035 0.0035

0.0065

0.0035

0.0001

0.0010

0.0001

0.0001

-0.0004 0.0008

0.0006 0.0006

0.0156

0.0004

1220.0001

102

0.000001

-

-

0.0001

0.0008

0.0001 0.0001 0.0001 0.00001

ng

ng 0.0008 0.0008 0.0008

0.0001

ng

0.0001ng

0.0110 0.0110

0.0005

0.0091 0.0091 0.0263 0.0263

0.00001

0.0017

1010.0077

0.0006

128

ng

0.000001

CAT-RT (Version BO)

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Sample Runs


%


-

No

l/min





Less than 50% Faded

-

Condenser Exit Temperature Units Run 1

19

%

Units


APPENDIX 2

DIOXINS & FURANS: QUALITY ASSURANCE

MU Acceptable %

0.24

Units

Run 1

%

Allowable Isokinetic Range 95 - 115


Run 1


(PAGE 1 OF 2)

Yes

11.2

20

l/min 0.40Post-Sampling Leak Rate

°C 120

Silica Gel (Concurrent Water Vapour) Units

Run 1

MU (Concurrent Water Vapour) Units Run 1

Yes

Units Run 1

97.8

% Yes

Allowable MU

l/min

21.08

Run 1

%

Units

Water Droplets


Units

Mean Sampling Rate

-

-

°C 20

Run 1

Maximum Temperature Recorded °C

Leak Test Results

Allowable Leak Rate l/min 1.05

Yes


Filter Temperatures

Test Conditions

Yes

CAT-RT (Version BO)

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Blank Runs

Method Deviations

1

wx

wx

- - - - -

- - - - -

- - - - -

- - - - -

-

APPENDIX 2

(PAGE 2 OF 2)

Units Blank 1

Expected Sampling Rate l/min 20.00

0.0100

Allowable Leak Rate

Blank 1



l/min

Blank Acceptable

Validity of NATO I-TEQ Blank vs ELV

Allowable Blank ng/m³

DIOXINS & FURANS: QUALITY ASSURANCE


Run Number


l/min 1.00

Nature of Deviation

0.23Sampling Leak Rate

Yes

Leak Test Acceptable Yes

-

CAT-RT (Version BO)

Page 55 of 79

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Leak

Laboratory Result





Leak

Laboratory Result


Leak

Laboratory Result


Leak

Laboratory Result













Symbol UnitsRun 1

Tm

%

Run 1

0.0 % v/v 1.0

0.0000L

ng/m³ 0.0002

L

%

kPa 0.5

uVm 0.163

0.67


%

uL

ng/m³

Hm

2.0297.1

39.8%

ng/m³

%

Units

Measured Quantities

ng/m³

1.90


1.00

8.1511

≤1%

-

APPENDIX 2

DIOXINS & FURANS (NATO I-TEQ): MEASUREMENT UNCERTAINTY CALCULATIONS

Value

UnitsParameter

≤1%

Vm

%

%

uHm

Run 1

1.00

uTm

N/A

K

%

20.4

≤1%

1.00

Symbol

%

- N/A

0.0007

ng/m³

-

Measured Quantities

ρm

N/A

- N/A

% v/v N/A

ng/m³

ng/m³ 0.0002

N/A

%

Lr

%

Units Run 1

0.0004


Measured Quantities


39.8

m³ 7.0169

Units Run 1


Measured Quantities

10.00 No Requirement

0.0007

ng/m³

ng/m³ 0.0000

Vm


0.00

1.90

Lr 10.00

ng/m³ 0.0000

Run 1

Symbol

100.7

m³

uρm

%


≤2%

≤5%


uLr

Run 1

0.50

%

0.0002

2.00


CAT-RT (Version BO)

Page 56 of 79

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Sample Runs

- -

- -

- -

- -

- -

- -

- -

- -

Blank Runs

- -

< <






11.10

APPENDIX 2

FORMALDEHYDE: RESULTS SUMMARY





Mean

Parameter

CAT-TP-19

Maximum

Concentration

Blank 1

mg/m³ 0.02

Standard

Out Stack

Filter Size and Material 47mm Quartz Fibre


Units Run 1


Uncertainty

1281.1

Parameter

±mg/m³


0.02

Parameter Value

Water Vapour

B3

11.10

Units

Sample Point I.D.'s

US EPA M316

Technical Procedure

Mean

CAT-AP-05

1 / 1


7.81

Mass Emission g/hr 4134.9

±g/hr

Impinger Material Polyethylene

Absorption Solution HPLC Grade Water


1281.1


% v/v

mg/m³ 25.52

7.81

25.52

4134.9

Uncertainty

Concentration


Name of Analytical Laboratory CAT


CAT-RT (Version BO)

Page 57 of 79

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Bwo as a percentage





CO₂ (Estimated)

O₂




% v/v


Nozzle area, An

m³/min

mmHg 755.5

Barometric pressure, Pb mmHg


Gas meter correction factor, Yd -

761.3


g

m³ 0.6643

27.64



m³/min




Qstw = ((Qa)(Ps)(Cf)) / ((Ts) + 273)

3560.6

59.2

m³ N/A


Units Run 1

20.86

- 34.97

N/A

FORMALDEHYDE: ISOKINETIC SAMPLING CALCULATIONS

Test

°C 26.3

% 101.4

APPENDIX 2

g/gmol 28.84


m³/min N/A


Md = 0.44(%CO₂)+0.32(%O₂)+0.28(%N₂)

N₂ % v/v 79.14

N/A

28.34

N/A

Ms = Md(1 - (Rwv/100)) + 18(Rwv/100)

g

15.61

Nozzle diameter, Dn mm

3.80

4.23




Total % v/v

% v/v 20.80

Vmstd = ((0.3592)(Vm)(Pb + (∆H/13.6))(Yd)) / (Tm + 273)

Total mass collected in impingers (silica trap) g

0.9310

m³ 0.0738

-

% v/v

5.5

53.7

mmH₂O



% v/v

-

N/A

m³ 0.1110

- N/A

No

% v/v

% oxygen reference condition, REF%O₂ % v/v

m³ N/A

N/A


°C


mm²

-



mmH₂O 17.87

Qa = (60)(As)(Vs)

6.01


2603.0


m³ 0.5906

11.10

m/s

m³ 0.6912

% v/v 11.10





min 30

2928.1

-78.2

0.06

48.1


0.84


57.0

Average pressure drop across orifice, ∆H mmH₂O

g/gmol

Vs = ((Kp)(Cp)(√∆P)(√Ts + 273)) / (√(Ms)(Ps))

Vwstd = (0.001246)(Vlc)

- 0.3592

CAT-RT (Version BO)

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Sample Runs

-

-

-

-

-

-

-

-


Blank Runs

<

-

<

<

63.24

Parameter Units

APPENDIX 2

mg/m³ 25.52

FORMALDEHYDE: SAMPLING DETAILS

Mass in Back Impinger

-

Laboratory Result for Impingers


Volume in Impingers


µg 16956.5

16221.1

Sampling Dates


735.5

Sampling Device -

ml 304.1

µg/ml 0.05

Volume in Front Impingers

m³ 0.6643

6.76

µg

ml

µg/ml

ISO

µg

108.8

Run 1

Blank Dates

0.02

26/07/2016

Volume in Back Impinger



-

- 08:40 - 09:10

256.5


ml

15.2Total Mass Collected µg

Sampling Times

Laboratory Result for Back Impinger

Laboratory Result for Front Impingers µg/ml

27/07/2016

Average Volume Sampled (REF) m³ 0.6643

mg/m³

CAT-RT (Version BO)

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Sample Runs

0 0 0 0

Run 1

%

0.43

Run 1

0.31

%

Units Run 1

Water Droplets

%

Units


10.9

Units

Absorption Efficiency Acceptable -

Measurement Uncertainty (MU) %

Less than 50% Faded

21.45l/min

Run 1

APPENDIX 2

120

0.24

Units



N/A

l/min

Mean Sampling Rate

Units

Maximum Filter Temperature °C

101.4

Isokineticity Acceptable -

Run 1

Yes


Units

Units



N/A

-

Units Run 1

Yes

20

-

NoAre Water Droplets Present

Run 1

Filter Temperatures

%

Leak Test Results

- Yes

Test Conditions

Allowable MU


Yes

Yes


95.7

(PAGE 1 OF 2)

FORMALDEHYDE: QUALITY ASSURANCE




%

%


%

MU Acceptable

95 - 115

Run 1

Allowable Leak Rate l/min

CAT-RT (Version BO)

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Blank Runs

Method Deviations

1

wx

wx

- - - - -

- - - - -

- - - - -

- - - - -

Blank 1


APPENDIX 2

FORMALDEHYDE: QUALITY ASSURANCE

Blank Acceptable


l/min 0.40

Run Number


Leak Test Results

Blank 1

Allowable Leak Rate

- Yes

20.00l/min



2.0

Nature of Deviation

0.10

(PAGE 2 OF 2)



Units



l/min 0.10

CAT-RT (Version BO)

Page 61 of 79

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Leak

Laboratory Result





Leak

Laboratory Result


Leak

Laboratory Result


Leak

Laboratory Result













% v/v

uρm

Tm

N/A

mg/m³

mg/m³

Vm

% 15.7

1.00

7.50

0.67 ≤1%

1.45


Units Run 1

%


m³

2.00

0.5

L

% v/v

4.01

Measured Quantities

mg/m³

0.50

Units


Symbol

Run 1

Measured Quantities

Measured Quantities

mg/m³

2.04

1.00

7.81

Units

Parameter Units

%

mg/m³ N/A

0.684


Run 1

mg/m³

N/A

1.914

30.6

mg/m³

%

1.00

Units Run 1

UnitsMeasured Quantities

Lr

≤1%

% -

N/A

0.5906

mg/m³

43.22

0.6912

0.0

%

mg/m³ 7.81

FORMALDEHYDE: MEASUREMENT UNCERTAINTY CALCULATIONS

kPa


1.0uHmHm

%

0.0138uVm

Run 1

m³

0.2130


≤2%

% 30.6

1.9143

Run 1

APPENDIX 2

uLr

% -


Measured Quantities

≤2%

Value

uL

≤1%%

%

7.50

Run 1

K

Vm

ρm

2.0299.3

100.7

uTm

L 1.45

SymbolSymbol

%

mg/m³

Run 1

0.213

Lr


No Requirement

-

%

N/A

- N/A

CAT-RT (Version BO)

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Sample Runs

- -

< <

- -

< <

- -

- -

- -

- -

Blank Runs

- -

< <






Concentration

Concentration


0.001

1.1

0.007

g/hr 1.1

Uncertainty ±mg/m³



APPENDIX 2

ISOCYANATES: RESULTS SUMMARY

0.007

Parameter Value

mg/m³

Uncertainty ±g/hr 0.2 0.2


Units Run 1

0.007

Maximum

Filter Housing / Nozzle Material Borosilicate Glass

mg/m³ 0.007

Out Stack

Filter Size and Material 1 2-PP Impregnated 47mm Glass Fibre


B3

Yes


Mean

0.001


MeanParameter

Mass Emission

Name of Analytical Laboratory SAL





Water Vapour % v/v 12.23

Uncertainty ±% v/v 1.00

Standard US EPA CTM36

1 / 1

1 / 1

Technical Procedure

Sample Point I.D.'s

CAT-TP-17

1.00

12.23

CAT-RT (Version BO)

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Bwo as a percentage





CO₂ (Estimated)

O₂




mm 4.97

m³/min

Vs = ((Kp)(Cp)(√∆P)(√Ts + 273)) / (√(Ms)(Ps))

mm² 19.43

Total sampling time, q min 30

m/s 15.66

Average stack gas temperature, Ts °C 57.0

%I = (4.6398E⁶)(Ts+273)(Vmstd) / (Ps)(Vs)(An)(q)(1 - (Rwv/100)) %

Qstd = ((Qa)(Ps)(Cf)(1 - (Rwv/100))) / ((Ts) + 273) m³/min 2578.1

QstwO₂ = ((Qa)(Ps)(Cf)) / ((Ts) + 273) / (O₂REFw) m³/min N/A

QstdO₂ = ((Qa)(Ps)(Cf)(1 - (Rwv/100))) / ((Ts) + 273) / (O₂REFd) m³/min N/A

Qa = (60)(As)(Vs) m³/min

2937.3

3571.8

-

Qstw = ((Qa)(Ps)(Cf)) / ((Ts) + 273)

Nozzle diameter, Dn

Average square root of velocity heads, √∆P √mmH₂O 4.23

Nozzle area, An

101.8


m³

0.3592Conversion factor (K/mm.Hg), Cf

Area of stack, As m² 3.80

Vmstw@X%oxygen = (Vmstw) / (O₂REFw) m³ N/A

Vmstd@X%oxygen = (Vmstd) / (O₂REFd) m³ N/A

% v/v 0.06

% v/v 20.80

Total % v/v 20.86


27.52


Pitot tube velocity constant, Kp - 34.97

Md = 0.44(%CO₂)+0.32(%O₂)+0.28(%N₂) g/gmol 28.84

Velocity pressure coefficient, Cp - 0.84

Ms = Md(1 - (Rwv/100)) + 18(Rwv/100) g/gmol

O₂ Reference Factor wet (O₂REFw) = (21 - REF%O₂) / (21 - ACT%O₂w) -

Total mass collected in impingers (liquid trap) g

APPENDIX 2

ISOCYANATES: ISOKINETIC SAMPLING CALCULATIONS

Test Units Run 1

Barometric pressure, Pb mmHg 761.3

Vmstw = (Vmstd)(100/(100 - Rwv)) m³ 0.4584

g 16.5

IED & Incinerates Hazardous Material? (Yes = no positive O₂ correction) - No

Ps = (Pb + (Pstatic / 13.6) mmHg 755.5

O₂ Reference Factor dry (O₂REFd) = (21 - REF%O₂) / (21 - ACT%O₂d) - N/A

mmH₂O

N₂ % v/v 79.14

12.23% v/v

Vwstd = (0.001246)(Vlc)

Gas meter correction factor, Yd -

% v/v 12.23


0.0561


28.5

Average of velocity heads, ∆Pavg mmH₂O 17.90

N/A

0.9310

N/A

% dry oxygen measured in gas stream, ACT%O₂d % v/v N/A

m³ 0.4650


Bwo = Vwstd / (Vmstd + Vwstd) m³ 0.1223

Vmstd = ((0.3592)(Vm)(Pb + (∆H/13.6))(Yd)) / (Tm + 273) m³ 0.4024

Total mass of liquid collected, Vlc g 45.0



22.3

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Sample Runs

<

<

-

-

-


Blank Runs

<

<

<

<

<

- ISO

ISOCYANATES: SAMPLING DETAILS


0.007

Sampling Times - 09:55 - 10:25

Sampling Dates - 27/07/2016

Sampling Device

APPENDIX 2

µg

Methyl Diisocyanate (MDI) µg

Hexamethylene Diisocyanate (HDI) µg 1.00

0.4584



m³

1.00


Methyl Diisocyanate (MDI)

Hexamethylene Diisocyanate (HDI)

Toluene Diisocyanates (TDI)

µg

µg 1.00

0.007

Parameter

Toluene Diisocyanates (TDI) µg 1.00

1.00

26/07/2016Blank Dates -

1.00


mg/m³

Average Volume Sampled (REF) m³ 0.4584


Units Blank 1

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Sample Runs

Blank Runs

Method Deviations

1

wx

- - - - -

- - - - -

Yes

Allowable Leak Rate

Isokinetic Criterion Compliance Units Run 1

Leak Test Results

Ambient Temperature Recorded? - Yes

Isokinetic Variation % 101.8

Yes

Run 1


Run Number

Expected Sampling Rate l/min

Units

20.00

Allowable Blank mg/m³ 0.0

Filter Temperatures

Blank 1

- Yes

Sampling Leak Rate l/min 0.20

Nature of Deviation

Blank 1

Blank Acceptable -


l/min


0.40

°C


105

Units Run 1




% 95 - 115

Test Conditions Units



Allowable Leak Rate

0.14

APPENDIX 2

ISOCYANATES: QUALITY ASSURANCE

Leak Test Results Units Run 1

l/min


MU Acceptable % Yes

Silica Gel (Concurrent Water Vapour) Units Run 1


Measurement Uncertainty (MU) % 8.2

Units Run 1

0.15

Mean Sampling Rate l/min 14.43

0.29

%Less than 50% Faded

Water Droplets Units


Run 1

- No

% 20Allowable MU

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Leak

Laboratory Result





Leak

Laboratory Result


Leak

Laboratory Result


Leak

Laboratory Result













ρm 100.7

1.00

%

1.00mg/m³


% 2.00

Lr

Units

mg/m³ 0.00

mg/m³ 0.00

Symbol

% 0.68

0.00

12.9

%

Vm

uHm % v/v

0.4024

mg/m³ 0.0004

Lr

% 1.04

6.00

%

Measured Quantities

Vm

0.000

mg/m³ 0.0000

Parameter Units


Measured Quantities

≤2%

Measured Quantities

mg/m³ N/A

≤1%

uL



- N/A

mg/m³ 0.000

m³

No Requirement

K

19.4

mg/m³ 0.00

%

mg/m³

19.4%

%

% N/A

Run 1

-

0.02

0.50


Units

uLr %


0.000L


mg/m³

Units

≤1%

6.00

Run 1

≤1%

-

N/A

N/A

% v/v

% -

0.5

≤2%

Hm

1.00

Run 1

1.0

L 1.04

Run 1

uρm

Run 1

kPa

2.0Tm 294.8

Symbol Units Run 1Run 1

uTm

uVm m³ 0.0093

0.0

APPENDIX 2

0.4650

ISOCYANATES: MEASUREMENT UNCERTAINTY CALCULATIONS

Symbol


Measured Quantities


CAT-RT (Version BO)

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Sample Runs

- -

- -

- -

- -

- -


NOTE: Dilution performed to achieve correct span value





APPENDIX 2

Parameter

1 / 1

127.8

OXIDES OF NITROGEN (as NO₂): RESULTS SUMMARY


413.34

Yes


Parameter Units Mean

04/12/2019

0.79

Uncertainty ±mg/m³

0.79


317.1

Mass Emission

1.96

Sample Point I.D.'s

Heated Head Filter Used

Filtration Type / Size

CAT-TP-39

317.1±g/hr

Standard

Technical Procedure



Span Gas Uncertainty (%)

Run 1

EN 14792

0.1µm Glass Fibre

Uncertainty

2

C1

Span Gas Reference Number CYL 4.0161

Span Gas Expiry Date


Span Gas Start Pressure (bar) 100

Gas Cylinder Concentration (ppm)

Span Gas Type Nitrogen Monoxide

180°C

Nitrogen (5 Grade)Zero Gas Type

1.96

g/hr 127.8

Value

Heated Line Temperature

Date & Result of Last Converter Check 20/08/2015 - 95.5%

CAT-RT (Version BO)

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Graphical Trend of Data

COVER ME WITH CHART/S

APPENDIX 2

OXIDES OF NITROGEN (as NO₂): DATA TREND

0.0

0.2

0.4

0.6

0.8

1.0

1.2

1.4

15

:31

15

:32

15

:33

15

:34

15

:35

15

:36

15

:37

15

:38

15

:39

15

:40

15

:41

15

:42

15

:43

15

:44

15

:45

15

:46

15

:47

15

:48

15

:49

15

:50

15

:51

15

:52

15

:53

15

:54

15

:55

15

:56

15

:57

15

:58

15

:59

16

:00

Co

nce

ntr

atio

n (

mg/

m³)

Oxides of Nitrogen (as NO₂) At Reference Conditions

- Run 1

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Sampling Details

Quality Assurance

Zero Drift 0 0 0

Zero Drift 0 0 0

Zero Drift 0 0 0

Span Drift 0 0 0

Span Drift 0 0 0

Span Drift 0 0 0

Method Deviations

1

x

- - -

- - -

- - -

Span Gas Value ppm

Span Down Sampling Line (Pre) ppm 63.50

Run 1

ppm

ppm

(x = deviation applies to the associated run)

There are no deviations associated with the sampling employed.

18 - 19

CA

L 2

Span Down Sampling Line (Post)

Units

Span Down Sampling Line (Post) ppm 63.10

ppm -0.40

ppmSpan Down Sampling Line (Post)

ppm

Span Down Sampling Line (Pre) ppm

Yes

-

APPENDIX 2

ppm

Run Ambient Temperature Range

Zero Down Sampling Line (Pre)

Sampling Dates

Temperature Acceptable

ppm -0.10

Average Temperature °C 2.0

Sampling Times -

-

4.0

± ppm 3.17

< °C

Run Number

Conditioning Unit Temperature Units

OXIDES OF NITROGEN (as NO₂): SAMPLING DETAILS & QUALITY ASSURANCE

Parameter

63.3

CA

L 1

Run 1

Zero Down Sampling Line (Post) ppm -0.10

CA

L 1

CA

L 2

ppm

Units

250

3.17

Span Drift Acceptable - Yes

INPUT

Nature of Deviation

15:31 - 16:00

Allowable Temperature

0.00

Instrument Range

Zero Drift

Zero Down Sampling Line (Pre) ppm

°C

ppm

-

Run 1

Zero Down Sampling Line (Post) ppm

Zero Down Sampling Line (Post)

Yes

ppm

ppm

Units

CA

L 3

Span Drift

Allowable Span Drift

Test Conditions Units Run 1

CA

L 3

Allowable Zero Drift

ppm

± ppm

Zero Drift Acceptable

ppm


Span Down Sampling Line (Pre)

Run 1

CAT-RT (Version BO)

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k =

mg/m³

mg/m³

RUN 1 Units

Measurement uncertainty Result 0.88

mg/m³

Uncertainty corrected to std conds. (O₂) 2.19

0.63

% of value

mg/m³ (REF)

mg/m³

0.00

% of full scale

5 %

205.0 mg/m³

Cal gas conc. 63.3 ppm

Conversion 2.05 ppm to mg/m³

MCERTS Range [B] 205.0 mg/m³

Ration NO / NO₂

mg/m³ (STP, dry)Measured concentration

TGN M2 Allowable MU

Limit value

seconds

-

Repeatability at zero 0.00 % full scale

% of value

Zero drift -0.16 % full scale

Atmospheric pressure dependence 0.10 % of value/kPa

Ambient temperature dependence 0.04 % full scale/10K

% full scale

Deviation from linearity 0.29

Span drift -0.63 % full scale

Volume or pressure flow dependence 0.10

2.19

Result of Compliance with Uncertainty Requirement in M2

Uncertainty of calibration gas

Units

% of Value

Range Used [A] 513.1

0.01 mg/m³

Combined interference (from MCERTS Certificate) 0.75

Repeatability at span level 0.10

Performance characteristic RUN 1 Units

Units

Response time 31

mg/m³

mg/m³

Combined uncertainty 1.12

N/A % at ELV

Overall Allowable uncertainty (with O₂) - at 95% Confidence N/A

% full scale/10V

95.5 %

mg/m³

% range

RUN 1

-

Requirement for SRM is that Uncertainty should be <10% of the value at the ELV, on a dry gas basis, or if O₂ correction is applied less than 10% + the

uncertainty associated with the O₂ correction (using sqrt of sum squares to add uncertainty components). Ref EA TGN M2.

mg/m³

Standard deviation of repeatability at span level

Dependence on voltage

0.34 mg/m³

Drift -0.12

Losses in the line (leak)

% at ELV

Result of Compliance with Uncertainty Requirement in M2 COMPLIANT -

RUN 1


Lower of [A] or [B]

mg/m³

Atmospheric pressure dependence 0.06 mg/m³

mg/m³

Lack of fit

Ambient temperature dependence

mg/m³Converter efficiency

Losses in the line (leak) 0.00 mg/m³

Units

Expanded uncertainty (with O₂) - at 95% Confidence N/A

0.01

mg/m³

Dependence on voltage -0.03

mg/m³

% of value

% of value

0.00

% of Value

Standard deviation of repeatability at zero use rep at span

Expanded uncertainty (no O₂) - at 95% Confidence 248.12

Expanded uncertainty (no O₂) - at 95% Confidence 1.69 % at ELV

Overall Allowable uncertainty (no O₂) - at 95% Confidence 10.0 % at ELV

Performance characteristics RUN 1

ppmRange Used

%

0.88

250.0

mg/m³

mg/m³ (REF)

10.0

130.0

OXIDES OF NITROGEN (as NO₂): MEASUREMENT UNCERTAINTY CALCULATIONS

Combined interference

Expanded uncertainty 1.96

Uncertainty of calibration gas blending 0.01

Uncertainty of calibration gas blending 1.40

Uncertainty of calibration gas 2.00

Expanded uncertainty (with O₂) - at 95% Confidence

N/A

-0.23

Performance characteristics RUN 1

Converter efficiency

Number of readings in measurement 30

0.02

Cal gas conc. 130.0

APPENDIX 2

Units

CAT-RT (Version BO)

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Sample Runs

- -

- -

- -

- -

- -







Parameter

Uncertainty

Zero Gas Type

153.9

Yes

Heated Line Temperature 180°C

C1

Heated Head Filter Used

200.8

±mg/m³ 0.95

1.24

200.8

Span Gas Type Carbon Monoxide

Run 1



Span Gas Expiry Date

1 / 1

Nitrogen (5 Grade)

g/hr

APPENDIX 2


Parameter Units


Uncertainty

Concentration

Value

mg/m³ 1.24



153.9

Gas Cylinder Concentration (ppm) 409.64

Span Gas Uncertainty (%) 2


Standard EN 15058

Span Gas Reference Number CYL 2.0097

0.1µm Glass Fibre

0.95

Sample Point I.D.'s

Mean

CARBON MONOXIDE: RESULTS SUMMARY

±g/hr

20/06/2019


Mass Emission

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APPENDIX 2

CARBON MONOXIDE: DATA TREND


0.0

0.2

0.4

0.6

0.8

1.0

1.2

1.4

1.6

1.8

15

:31

15

:32

15

:33

15

:34

15

:35

15

:36

15

:37

15

:38

15

:39

15

:40

15

:41

15

:42

15

:43

15

:44

15

:45

15

:46

15

:47

15

:48

15

:49

15

:50

15

:51

15

:52

15

:53

15

:54

15

:55

15

:56

15

:57

15

:58

15

:59

16

:00

Co

nce

ntr

atio

n (

mg/

m³)

Carbon Monoxide At Reference Conditions

- Run 1

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Sampling Details

Quality Assurance

Zero Drift 0 0 0

Zero Drift 0 0 0

Zero Drift 0 0 0

Span Drift 0 0 0

Span Drift 0 0 0

Span Drift 0 0 0

Method Deviations

1

x

- - -

- - -

- - -

ppm

°C 2.0

Span Gas Value

CA

L 1

Units Run 1


ppm

ppm

0.50


Span Drift

Allowable Span Drift ± ppm



Run Ambient Temperature Range

Span Down Sampling Line (Post) ppm

Zero Drift Acceptable -

ppm

ppm -3.20


Zero Down Sampling Line (Pre) ppm

Yes

Sampling Times

ppm 406.00

Allowable Zero Drift ± ppm

-

ppm

ppm

0.50

-

Yes


Units

409.6

ppm

ppm

Run 1

Average Temperature

Allowable Temperature < °C


ppm

ppm


Units

ppm

Run 1

Test Conditions

20.48

Units Run 1

Run Number



CA

L 2

Temperature Acceptable

Zero Drift

CA

L 3

ppm

Units

APPENDIX 2

CA

L 1

CA

L 2

4.0

CARBON MONOXIDE: SAMPLING DETAILS & QUALITY ASSURANCE

Parameter


ppm

ppm 0.00

Sampling Dates - INPUT

Instrument Range ppm 500

15:31 - 16:00

Run 1

°C 18 - 19

20.48


Conditioning Unit Temperature

CA

L 3

409.20

YesSpan Drift Acceptable -

ppm

Nature of Deviation

CAT-RT (Version BO)

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k =

Requirement for SRM is that Uncertainty should be <6% of the value at the ELV, on a dry gas basis, or if O₂ correction is applied less than 6% + the uncertainty

associated with the O₂ correction (using sqrt of sum squares to add uncertainty components). Ref EA TGN M2.

Measured concentration

TGN M2 Allowable MU

Limit value

Performance characteristics RUN 1 Units

600.0 mg/m³ (REF)

6.0 %

1.39 mg/m³ (STP, dry)

RUN 1 Units

Expanded uncertainty (no O₂) - at 95% Confidence 76.48

Expanded uncertainty (with O₂) - at 95% Confidence N/A % at ELV

Overall Allowable uncertainty (with O₂) - at 95% Confidence N/A % at ELV

1.06 mg/m³ (REF)

1.06 mg/m³

Uncertainty corrected to std conds. (O₂)

Lack of fit 0.27 mg/m³

Drift 0.35 mg/m³

Volume or pressure flow dependence 0.00 mg/m³

Atmospheric pressure dependence 0.05

Result of Compliance with Uncertainty Requirement in M2 N/A -

Losses in the line (leak) 0.00 mg/m³

Uncertainty of calibration gas blending 0.01 mg/m³

% of Value

Expanded uncertainty (no O₂) - at 95% Confidence 0.18 % at ELV

Overall Allowable uncertainty (no O₂) - at 95% Confidence 6.0 % at ELV


RUN 1 Units

Expanded uncertainty (with O₂) - at 95% Confidence N/A % of Value

Uncertainty of calibration gas 0.02 mg/m³

RUN 1 Units

Measurement uncertainty Result 1.39 mg/m³

Combined uncertainty 0.54 mg/m³

Expanded uncertainty 1.96

mg/m³

Ambient temperature dependence -0.03 mg/m³

Combined interference (from MCERTS Certificate) -0.21 mg/m³

Dependence on voltage -0.04 mg/m³

% range

Dependence on voltage -0.35 % full scale/10V

Losses in the line (leak) 0.10 % of value

Uncertainty of calibration gas blending 1.40 % of value

Uncertainty of calibration gas 2.00 % of value


Standard deviation of repeatability at zero use rep at span mg/m³

Standard deviation of repeatability at span level 0.04 mg/m³

Units

Response time 28

% full scale

Repeatability at span level 0.20 % full scale

Deviation from linearity 0.63 % of value

Number of readings in measurement 30

APPENDIX 2

CARBON MONOXIDE: MEASUREMENT UNCERTAINTY CALCULATIONS

% of full scale


Ambient temperature dependence -0.20 % full scale/10K

ppm

Range Used [A] 624.6 mg/m³

Cal gas conc. 409.6 ppm

Conversion 1.25 ppm to mg/m³

RUN 1

-

Repeatability at zero

Performance characteristics

Zero drift 0.12 % full scale



mg/m³

Cal gas conc. 511.7 mg/m³

Combined interference -0.48

MCERTS Range [B] 75.0

seconds

Range Used 500.0

mg/m³

Lower of [A] or [B] 75.0

0.10

CAT-RT (Version BO)

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Sample Runs

- -

- -

- -





Span Gas Type Synthetic Air (5 Grade)

Span Gas Reference Number

Units Run 1

Value

Standard

Nitrogen (5 Grade)


Sample Point I.D.'s C1

EN 14789




Span Gas Expiry Date 07/12/2020


Gas Cylinder Concentration (% v/v) 21.67


Parameter Mean

Parameter

180°C

Span Gas Uncertainty (%) 2

Zero Gas Type

0.1µm Glass Fibre

Heated Head Filter Used Yes

Heated Line Temperature


CYL 11.0228

APPENDIX 2



Concentration % v/v 19.63 19.63

OXYGEN: RESULTS SUMMARY

CAT-RT (Version BO)

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OXYGEN: DATA TREND

APPENDIX 2


0.0

5.0

10.0

15.0

20.0

25.0

15

:31

15

:32

15

:33

15

:34

15

:35

15

:36

15

:37

15

:38

15

:39

15

:40

15

:41

15

:42

15

:43

15

:44

15

:45

15

:46

15

:47

15

:48

15

:49

15

:50

15

:51

15

:52

15

:53

15

:54

15

:55

15

:56

15

:57

15

:58

15

:59

16

:00

Co

nce

ntr

atio

n (

% v

/v)

Oxygen Oxygen

- Run 1

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Sampling Details

Quality Assurance

Zero Drift 0 0 0

Zero Drift 0 0 0

Zero Drift 0 0 0

Span Drift 0 0 0

Span Drift 0 0 0

Span Drift 0 0 0

Method Deviations

1

x

- - -

- - -

- - -


% v/v

% v/v

CA

L 3

4.0

-0.09

Zero Down Sampling Line (Pre) % v/v

CA

L 1


-

Conditioning Unit Temperature Units Run 1

15:31 - 16:00

Parameter

Span Gas Value

Run 1

Span Down Sampling Line (Post) % v/v

Allowable Temperature < °C

0.03

Zero Down Sampling Line (Post) % v/v -0.06

Units Run 1

Sampling Times

Average Temperature

CA

L 2


Zero Drift Acceptable

Instrument Range % v/v 25


CA

L 3

-

Nature of Deviation

Temperature Acceptable - Yes

Span Drift Units

Run Number



% v/v

Allowable Span Drift ± % v/v 1.08

°C 2.0

Yes

Units Run 1

Span Drift Acceptable - Yes

Test Conditions Units Run 1

Run Ambient Temperature Range °C 18 - 19

CA

L 2

Span Down Sampling Line (Pre) % v/v


% v/v

% v/v

21.83

% v/v


% v/v

% v/v

21.94

Span Down Sampling Line (Pre) % v/v

APPENDIX 2

OXYGEN: SAMPLING DETAILS & QUALITY ASSURANCE

% v/v 21.67

% v/v -0.11

Allowable Zero Drift ± % v/v 1.08

Zero Drift

CA

L 1


Sampling Dates - INPUT

CAT-RT (Version BO)

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k =

% range

Dependence on voltage 0.02 % full scale/10V

Losses in the line (leak) 0.00 % of value

Uncertainty of calibration gas

2.50 % of Value


Expanded uncertainty 1.96 0.55 %vol

RUN 1 Units

Standard deviation of repeatability at zero use rep at span %vol

Standard deviation of repeatability at span level 0.00 %vol

Lack of fit 0.00 %vol

Drift -0.11 %vol

Volume or pressure flow dependence 0.00 %vol

Atmospheric pressure dependence %vol

Ambient temperature dependence -0.03 %vol

N/A %vol

6.0 %

0.01

Requirement for SRM is that Uncertainty should be 0.5%vol absolute or 6% relative whichever is the lower, on a dry gas basis. Ref EA TGN M2.

Combined interference (from MCERTS Certificate) 0.00 %vol

Dependence on voltage 0.00 %vol

Losses in the line (leak) 0.00 %vol

Uncertainty of calibration gas 0.25 %vol

RUN 1 Units

Measurement uncertainty Result 21.97 %vol

Combined uncertainty 0.28 %vol

-0.21 % full scale/10K


Ambient temperature dependence


2.00

Expanded uncertainty (no O₂) - at 95% Confidence

% of full scale

Number of readings in measurement 30 -

Repeatability at zero 0.02 % full scale

Repeatability at span level 0.02 % full scale

Deviation from linearity

% full scale


21.97 %vol

Range Used 25.0 %vol

Cal gas conc. 21.7 %vol


Response time 41 seconds

Combined interference 0.00


Measured concentration

TGN M2 Allowable MU

Limit value

% of value


0.03 % of value

Zero drift -0.41

APPENDIX 2

OXYGEN: MEASUREMENT UNCERTAINTY CALCULATIONS

CAT-RT (Version BO)

Page 79 of 79

Medite Europe Ltd

Clonmel






Summary

See report

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