Smarter Stabilization Solutions for Polyoleﬁns · • To be the world’s most innovative supplier of solutions to the polymer industry •To be our customers’ ﬁrst choice as

Smarter Stabilization Solutions for

Polyolefins

Addivant™ is a global specialty chemicals company with leading positions

in diversified markets. We build the chemistry that makes other products

more durable, safer, cleaner and more efficient, in the building and

construction, electrical and electronics, consumer, agricultural, industrial

and transportation industries.

With more than 500 employees around the world, Addivant™ provides

products and services in more than 100 countries and maintains worldwide

manufacturing and research facilities as well as global sales offices.

GLOBAL SOLUTIONS

• To be the world’s most innovative supplier of solutions to the polymer industry

• To be our customers’ first choice as a committed supplier

• To offer the best cost-performance solutions through real innovation

• To invest in line with our customers’ growth strategies

• To offer the best service locally through integrated plants and supply chains

We are a leading global supplier of Antioxidants, Intermediates

& Inhibitors, Polymer Modifiers and UV Stabilizer solutions. As

the only manufacturer to market all major families of stabilizer,

we offer the widest range of performance-based polymer

additives in the industry. Our goal is to be the most innovative

supplier of stabilizer solutions worldwide.

• Technical expertise that adds value

• Customized, cost-effective dust-free solutions

• Service worldwide

• Regulatory compliance and corporate responsibility

• Committed to future growth

OUR STRENGTHS

OUR VISION

OUR PRODUCTS

Smarter Stabilization Solutions for Polyolefins | 03

We continue to add technical and expert resources to accelerate the delivery of

true innovation. With a significant number of registered active patents, we

continue to strongly invest in innovation to improve product performance and

cost optimization, and to maintain our position at the forefront of polymer

additive technology. ‘Greener is better’ is at the heart of our product

development, new products will always be greener than what came before.

We are proud of the launch of our WESTON® LPP (Liquid Productivity Platform)

which opens a new chapter in cost-performance stabilization solutions.

Expertise that adds valueWe are the world’s largest supplier of powder-free solutions. Our broad

product range combined with our technical expertise allows us to create

unique blends. We are willing to work with our polyolefins customers to

address their issues and develop synergistic and customized solutions

depending on their individual requirements. A variety of product and physical

forms are available including Addivant ’s patented Non Dust Blends (NDB®)

and liquid additives to offer dust-free, ease of handling and significant

productivity improvements.

A global supplier offering local serviceAddivant ’s Antioxidant and UV Stabilizer

solutions are manufactured in multiple locations,

with sales, technical, and laboratory facilities

around the world. This organization brings us

close to our customers in all regions, allowing us

to offer better service and shorter lead times.

As our customers invest heavily in the new,

emerging markets, we have been focusing

especially on our structure in those regions to

guarantee service levels. Our new technical

application centre in China is the latest example

to add to our existing locations in the Middle East,

South Korea, USA, Brazil, Europe and Taiwan. We

have also consolidated our Customer Care and

shipping points and ensured we field a highly

trained sales and distribution team.WESTON® LPP liquid antioxidants

Generally less expensive than powder antioxidants

Easier to handle

Operate in an enclosed system unlike powders

Allow precise dosing versus powder

Allow for faster changeover between

polymer grades

Make adding multiple additives simpler

Do not accumulate in the hopper or the

extrusion unit

Allow for longer storage life versus powders

Are less expensive to store

04 | Smarter Stabilization Solutions for Polyolefins |

DELIVERING TRUE INNOVATION

Antioxidants

PhenolicsANOX® 20ANOX® 70ANOX® 330ANOX® 1315ANOX® IC-14ANOX® PP18LOWINOX® 1790LOWINOX® AH25LOWINOX® CA22LOWINOX® TBM6LOWINOX® TBP6

PhosphitesALKANOX® 240ULTRANOX® 626ULTRANOX® 627AVWESTON® TNPPWESTON® 399WESTON® 618/619WESTON® 705WESTON® 705T

ThioestersNAUGARD® DSTDPNAUGARD® DLTDPNAUGARD® 412S

AminesNAUGARD® 445NAUGARD® Q / NAUGARD® SUPER QGENOX® EP

Metal DeactivatorsLOWINOX® MD24NAUGARD® XL-1

Blends

Binary BlendsWESTON® 500 SERIESWESTON® 800 SERIESANOX® BB011ANOX® BB021ANOX® BB140ANOX® BB2777ULTRANOX® 817ULTRANOX® 877

Non Dust BlendsANOX® NDB®

Polymer Modifiers

POLYBOND™ Product LineMALEIC ANHYDRIDE GRAFTEDPolypropylenePOLYBOND® 3000POLYBOND® 3002POLYBOND® 3150POLYBOND® 3200

High Density PolyethylenePOLYBOND® 3009POLYBOND® 3029POLYBOND® 3039

Linear Low Density PolyethylenePOLYBOND® 3149

Acrylic Acid GraftedPOLYPROPYLENEPOLYBOND® 1001POLYBOND® 1002POLYBOND® 1103

High Density PolyethylenePOLYBOND® 1009

UV Light Stabilizers

Benzophenone UV AbsorberLOWILITE® 22

Benzotriazole UV AbsorbersLOWILITE® 26LOWILITE® 27LOWILITE® 28LOWILITE® 234

Other UV AbsorbersLOWILITE® Q 84LOWILITE® NDB® Q21

Hindered Amine Light Stabilizers (HALS)LOWILITE® 19LOWILITE® 62LOWILITE® 77LOWILITE® 92LOWILITE® 94

BlendsLOWILITE® 6294LOWILITE® 7500LOWILITE® 7794

Product Overview


ANTIOXIDANTS SELECTOR GUIDE

General Purpose Antioxidants and BlendsANOX® 20General purpose phenolic antioxidant providing excellent long term heat ageing

ANOX® PP18General purpose phenolic antioxidant with good solubility

ALKANOX® 240General purpose phosphite providing good processing stability

WESTON® TNPPCost-effective, high purity liquid phosphite

WESTON® 399Cost-effective liquid phosphite with increased hydrolytic stability

WESTON® 705Innovative nonylphenol-free, high purity liquid phosphite

WESTON® 705TInnovative nonylphenol-free liquid phosphite with increasedhysrolytic stability

NAUGARD® DLTDPGeneral purpose thio-synergist for applications requiringlong term stability

NAUGARD® DSTDPGeneral purpose thio-synergist with lower volatility

ANOX® BB011General purpose phenolic/phosphite blend for long term stability

ANOX® BB021General purpose phenolic/phosphite blend providing optimum balance of processing and long term stability

Performance Antioxidants and BlendsANOX® 1315Liquid high hindered phenolic antioxidant

ANOX® 70High hindered phenolic antioxidant providing good long stability in black applications

ANOX® IC-14High hindered phenolic antioxidant providing good anti-gasfading properties and low color

ANOX® 330High hindered phenolic antioxidant providing excellent extraction resistance, low water carry-over and long term stability

LOWINOX® AH25Hydroquinone providing good scorch resistance in wire and cable applications

LOWINOX® CA22Low hindered phenolic antioxidant especially for medical applications

Polypropylene Antioxidant

| PP Film | PP Fibers | PP Extrusion

Unfilled PP

Filled PP

Cast & Blown film

Tapes

Strapping

BOPP film

Cracked PP

Non-Cracked PP

PP sheet

PP pipes

• ° • ° ° • ° ° • °° ° °• ° • • • ° • • • •

• • • • • • • •• • • • • • • •

• •• ° • ° ° • °• • ° ° ° ° ° • °

°° ° •

• ° • •

° • • •

•

06 | Smarter Stabilization Solutions for Polyolefins

PP InjectionMolding

Polyethylene

| HDPE | LDPE | LLDPE

Physical Form

Polyolefin Food

Contact

Injection Molding

Rotomolding

Film

Tapes

Pipes

Blow Molding

Wire & Cable

Film

Extrusion Coating

Wire & Cable

Film

Rotomolding

� • • • • • • ° • °PW,GR,AM,NDB

� • ° ° ° ° • • •PW,GR,NDB

� ° • • • • • ° ° • •PW,GR,NDB

� • • ° • °L

� • • ° • °• • ° • °• • ° • °

° ° ° ° °° • ° ° •

° • ° ° °

° °• • •

°

° • •

° •

L

�FL

�FL

�GR,NDB

�PW,GR,NDB

�PW, GR

�L, SE

�PW, GR

�PW, GR

�PW, GR

�PW

L

L

Physical Form:PW PowderGR GranularAM AmorphousFL FlakePL PelletPS PastilleNDB Non Dust BlendL LiquidMP Molten ProductSE Self emulsifying

Polyolefin Food

Contact� = Product has food

contact clearancein polyolefins in atleast one country.

For more specificapprovals, ask oursales/regulatory people.

Symbols

• Recommended use

° Suggested use


Performance Antioxidants and BlendsLOWINOX® 1790Low hindered phenolic antioxidant providing excellent processing stability and anti-gasfading properties

LOWINOX® MD24Phenolic antioxidant with excellent Cu chelating properties

NAUGARD® XL-1High performance, dual-functional phenolic antioxidant/metaldeactivator. Particularly effective in mineral-filled systems.

LOWINOX® TBM6low hindered phenolic antioxidant providing optimum balance betweenscorch resistance, long term heat ageing and crosslinking efficiency.

LOWINOX® TBP6Low hindered phenolic antioxidant providing optimum propertybalance and easier dispersion.

ULTRANOX® 626Solid high performance phosphite with superior processingstability. Provides excellent color stability.

ULTRANOX® 627AVFree flowing granular form of ULTRANOX® 626 phosphite withinorganic neutralizer for improved handling characteristics.

WESTON® 618High performance phosphite with excellent color stability

NAUGARD® 445Aminic antioxidant providing processing and long-term heat stability,especially when used in synergistic combinations with phenolic antioxidants

NAUGARD® Q/NAUGARD® SUPER QAminic antioxidant providing exceptional processing and long-term heat stabilization. Designed for carbon black filled systemssuch as wire & cable and geomembranes

GENOX® EPAmine oxide based antioxidant provides excellent melt flow,color stability, gasfade protection

NAUGARD® 412SHigh performance thio-synergist for applications requiring longterm stability

ANOX® BB2777High performance phenolic/phosphite blend with excellentprocessing and gasfade protection

Binary BlendsWESTON® 500 SERIESCost-effective, high purity liquid phosphite blends based on WESTONTNPP

WESTON® 800 SERIESHigh performance liquid blends based on Weston 705



Unfilled PP

Filled PP

Cast & Blown film

Tapes

Strapping

BOPP film

Cracked PP

Non-Cracked PP

PP sheet

PP pipes

° ° ° ° • • °• °• •

° • •

• • • • •

° ° ° ° °

• •

°

° ° •• •

• • • ° ° •

ANTIOXIDANTS SELECTOR GUIDEANTIOXIDANTS SELECTOR GUIDE


PP InjectionMolding

�PW

�PW,NDB

PW, GR

�PW, GR

�GR

�FL, GR

PW, GR

PS

�PW

PW

�PW, GR

�L

�L


Polyolefin Food

Contact

� = Product has foodcontact clearancein polyolefins in atleast one country.

For more specificapprovals, ask oursales/regulatorypeople.

Symbols

• Recommended use

° Suggested use

�PW, GR

�PW, GR

Polyethylene


Physical Form

Polyolefin Food

Contact

Injection Molding

Rotomolding

Film

Tapes

Pipes

Blow Molding

Wire & Cable

Film

Extrusion Coating

Wire & Cable

Film

Rotomolding

• •° ••• • •

• •• • • • • •• • • • • •

° °

• • ° • °• • ° • °

° •

• •

° ° ° °

°


Molecular Weight Melting Range (ºC) TGA (ºC,% mass loss)

Phenolics

ANOX® 20CAS No. 6683-19-8.

352 5%365 10%415 50%

110-1251178

301 5%316 10%353 50%

63-73642

346 5%365 10%415 50%

244775

232 5%258 10%314 50%

Liquid485 (avg)

322 5%340 10%379 50%

217-219784

263 5%277 10%325 50%

49-53531

202 1%333 5%349 10%

159-162700

166 5%176 10%202 50%

177-179250

277 5%291 10%337 50%

182-184545

214 5%227 10%267 50%

160-164358

186 5%199 10%236 50%

83-85358

ANOX® 70CAS No. 41484-35-9

ANOX® 330CAS No. 1709-70-2

ANOX® 1315CAS No. 171090-93-0

ANOX® IC-14CAS No. 27676-62-6

ANOX® PP18CAS No. 2082-79-3

LOWINOX® 1790CAS No. 40601-76-1

LOWINOX® AH 25CAS No. 79-74-3

LOWINOX® CA221843-03-4

LOWINOX® TBM6CAS No. 96-69-5

LOWINOX® TBP6CAS No. 90-66-4


PRIMARY ANTIOXIDANTS


Metal Deactivators

284 5%295 10%330 50%

221-232553

343 5%352 10%373 50%

170-180697

LOWINOX® MD24CAS No. 32687-78-8

NAUGARD® XL-1CAS No. 70331-94-1


Amines

305 10%346 50%

98-100406

297 10%465 50%

120-125874

NAUGARD® 445CAS No. 10081-67-1

NAUGARD® Q /NAUGARD® SUPER QCAS No. 26780-96-1

85-105613GENOX® EPCAS No. 204933-93-7



Phosphites

ALKANOX® 240CAS No. 31570-04-4

256 5%271 10%315 50%

180-186646

ULTRANOX® 626CAS No. 26741-53-7

ULTRANOX® 627AVCAS No. 26741-53-7CAS No. 11097-59-9

268 5%288 10%333 50%

170-180604

WESTON® TNPPCAS No. 26523-78-4

WESTON® 399WESTON® 399 IS WESTON® TNPP with <1% by weightTriisopropanolamine (Cas No. 122-20-3)

251 5%274 10%331 50%

Liquid688

WESTON® 705T 325 5%349 10%420 50%

325 5%349 10%420 50%

LiquidProprietaryProprietary


Thioesters

NAUGARD® DSTDPCAS No. 693-36-7

294 10%359 50%

67683

NAUGARD® DLTDPCAS No. 123-28-4

274 10%316 50%

39- 41514

NAUGARD® 412SCAS No. 29598-76-3

331 10%374 50%

471162

WESTON® 618CAS No. 3806-34-6

WESTON® 619WESTON® 619 IS WESTON®618 with<1% by weightTriisopropanolamine(Cas No. 122-20-3))

37-46732

ProprietaryWESTON® 705 LiquidProprietary

SECONDARY ANTIOXIDANTS


Description/Blend Information

Binary Blends

Liquid blend of WESTON® TNPP orWESTON® 399 with ANOX® PP18 in various ratios.

WESTON® 500 SERIES

Synergistic high performance liquid blends of WESTON® 705WESTON® 800 SERIES

Description

Non Dust Blends

ANOX® NDB®’s are completely homogeneous blends of several additivecomponents such as antioxidants, UV stabilizers, sulfur-based thio antioxidantsand other suitable additives, incorporated into a unique, free-flowing,mechanically resistant, pelletized physical form. The ingredients are thoroughlyand intimately mixed ensuring a uniform composition for each NDB®. ANOX®

NDB®’s are customized blends that do not simply replace individual componentsbut actually add additional value to the polymer mix.

ANOX® NDB®

1:1 blend of ALKANOX® 240 and ANOX® 20Powder, Granular, NDB®

ANOX® BB011

2:1 blend of ALKANOX® 240 and ANOX® 20Powder, Granular, NDB®

ANOX® BB021

4:1 blend of ALKANOX® 240 and ANOX® PP18Powder, Granular, NDB®

ANOX® BB140

2:1 blend of ALKANOX® 240 and LOWINOX® 1790Powder, Granular, NDB®

ANOX® BB2777

2:1 blend of ULTRANOX® 626 and ANOX® 20ULTRANOX® 817

2:1 blend of ULTRANOX® 626 and ANOX® PP18ULTRANOX® 877

STANDARD AND CUSTOM BLENDS


BenzophenonesLOWILITE® 22General purpose benzophenone with low volatility

BenzotriazolesLOWILITE® 26General purpose benzotriazole for applicationsrequiring food contact approval

LOWILITE® 27General Purpose benzotriazole with high absorptiontowards the long UV wavelengths

LOWILITE® 28General purpose benzotriazole with low base color

LOWILITE® 234High performance benzotriazole especially for high temperature applications

Nickel Quencher (Blends)LOWILITE® Q84Nickel based UV stabilizer for agricultural applications offering low pesticide interaction

LOWILITE® NDB® Q21Nickel based UV stabilizer for agricultural applications

Hindered Amine Light StabilizersLOWILITE® 19High mol weight HALS providing longterm stability in filled applications

LOWILITE® 62Tertiary, low mol weight HALS for low color applications

LOWILITE® 77Highly effective low mol weight HALS

LOWILITE® 92Liquid secondary, low mol weight HALS for coating applications

LOWILITE® 94General purpose secondary, high mol weight HALS

UV Stabilizer BlendsLOWILITE® 6294Synergistic blend of high molecular weight HALS with thebroadest range of food contact applications

LOWILITE® 7500Optimized Antioxidant/UV stabilizer blendspecifically for PP thick section applications

LOWILITELOWILITE®® 77947794Blend of high and low molecular weight HALS for synergisticperformance in thick sections

• • ° ° °

• • • •

° ° ° °°

° • ° ° • • °

° ° ° ° • • °

• • • • • •• • • • • •

°° ° ° ° ° °

• • • • • •• • •

• • • •



Unfilled PP

Filled PP

Cast & Blown film

Tapes

Strapping

BOPP film

Cracked PP

Non-Cracked PP

PP sheet

PP pipes

LIGHT STABILIZERS SELECTORGUIDE FOR POLYOLEFINS


PP InjectionMolding

� ° • ° • • •PW, FL

� ° • ° • • •PW,NDB

PW

° ° ° ° ° °PW, GR

• • • • • •PW

PW

PW

PW

°PW

• •PW, GR

• •NDB

� • • • • • • • •GR

L

� • • • • • • •PW, GR

Addivant™ UV

Stabilizers are your

best defense against

light degradation. They

enable you to maintain

the appearance of

your products longer,

even under the

scorching sun.


Polyolefin Food Contact� = Product has food

contact clearancein polyolefins in atleast one country.

For more specificapprovals, ask oursales/regulatorypeople.

Symbols

• Recommended use

° Suggested use

Polyethylene


Physical Form

Polyolefin Food

Contact

Injection Molding

Rotomolding

Film

Tapes

Pipes

Blow Molding

Wire & Cable

Film

Extrusion Coating

Wire & Cable

Film

Rotomolding



Benzophenone UV Absorbers

LOWILITE® 22CAS No. 1843-05-6

221 5%231 10%270 50%

47-50326


Nickel Quencher (Blends)

LOWILITE® Q 84CAS No. 014516-71-3

270 5%293 10%

245-280572

LOWILITE® NDB®LOWILITE® NDB® Q21Q21 2:1 Blend of LOWILITE® Q84 and LOWILITE®22

202 5%214 10%251 50%

137-141316


Benzotriazole UV Absorbers


214 5%230 10%267 50%

154-158358LOWILITE® 27CAS No. 3864-99-1

233 5%244 10%286 50%

79-87352LOWILITE® 28CAS No. 25973-55-1

354 5%135-140448LOWILITE® 234CAS No. 70321-86-7


LIGHT STABILIZERS


Hindered Amine Light Stabilizers (HALS)

386 5%405 10%431 50%

310 5%322 10%348 50%

80-1102284LOWILITE® 19CAS No. 106990-43-6

55-70(softening)

3100-4000LOWILITE® 62CAS No. 65447-77-0

225 5%240 10%279 50%

80-85481LOWILITE® 77CAS No. 52829-07-9

257 5%279 10%323 50%

Liquid509LOWILITE® 92CAS No. 41556-26-7

368 5%375 10%450 50%

100-135(softening)

>2500

55-140

80-140



Light Stabilizer Blends

LOWILITE® 6294 1:1 Blend of LOWILITE® 62 and LOWILITE® 94

LOWILITE® 7500 Proprietary

LOWILITE® 7794 1:1 Blend of LOWILITE® 77 and LOWILITE® 94


Addivant™ Polymer

Modifiers are used

worldwide in

applications such

as polyolefin

compounding.

Addivant™ brings

together the industry’s

premier polymer

modifiers. Now you

have one source for

the many chemistries

that enhance your

products’

performance.

POLYBOND™ Product Line

Maleic Anhydride Grafted

PolypropylenePOLYBOND® 3000 High 400 1020 Pellets

POLYBOND® 3002 Low - 10 Pellets

POLYBOND® 3150 Medium 53 - Pellets

POLYBOND® 3200 High 115 255 Pellets

High Density PolyethylenePOLYBOND® 3009 Medium 5 - Pellets

POLYBOND® 3029 High 4 - Pellets

POLYBOND® 3039 High 4 - Micropellets(Powder)

Linear Low Density PolyethylenePOLYBOND® 3149 High 12-30 - Pellets

Acrylic Acid Grafted

PolypropylenePOLYBOND® 1001 High - 40 Pellets

POLYBOND® 1002 High - 20 Pellets

POLYBOND® 1103 High 12-30 - Pellets

High Density PolyethylenePOLYBOND® 1009 High 5 - Pellets

Functionality MFR@ 190°C, MFR@ 230°C, Physical Form2.16Kg g/10 min 2.16 Kg g/10 min


POLYMER MODIFIERS

Because we offer:

• True innovation and partnership in development

• The largest range of Antioxidant and UV Stabilizer products

• Global reach and supply capabilities

• Unbeatable technical expertise and application knowledge

• Continued strategic investments in emerging markets

• Significant investments in regulatory compliance

Because we are committed:

• To be the world’s most innovative supplier of solutions to

the polymer industry

• To be our customers’ first choice as a committed supplier

• To offer the best cost-performance solutions through

real innovation

• To invest in line with our customers’ growth strategies

• To offer the best service locally through integrated plants

and supply chains


WHY ADDIVANT™?

The information contained herein is correct to the best of our knowledge. Your attention isdirected to the pertinent Material Safety Data Sheets for the products mentioned herein.

All sales are subject to Addivant’s standard terms and conditions of sale, copies of which areavailable upon request and which are part of Addivant’s invoices and/or orderacknowledgements. Except as expressly provided in Addivant’s standard terms andconditions of sale, no warranty, express or implied, including warranty of merchantability orfitness for a particular purpose, is made with respect to the product described herein.Nothing contained herein shall constitute permission or recommendation to practice anyinvention covered by a patent without license from the owner of the patent.

© Copyright 2013

The tradenames in this brochure are registered trademarks of Addivant™ and/or its subsidiaries.

Responsible Care®Addivant™ is dedicated to Responsible Care®, the chemical industry's initiative to protect theenvironment; ensure the safety and security of our operations; and safeguard the health andsafety of our employees and neighboring communities. Our goal is to make continuous progresstoward the vision of no accidents, injuries or harm to the environment. As active and responsiblemembers of the communities in which we operate, Addivant™ is committed to opencommunication with our employees and neighbors. We monitor the safe production,transportation and use of our products. Our employees are comprehensively trained to do theirjobs safely and with minimum impact on the environment. We care about the future — for all ofus. If you have any questions, or would like to comment on our Responsible Care program, pleasesend an email to [email protected]. addivant.com/addresses

Documents

Smarter Stabilization Solutions for Polyoleﬁns · • To be the world’s most innovative supplier of solutions to the polymer industry •To be our customers’ ﬁrst choice as