Sr. No. Name of Annexure Page No....85 85 4 Pigment Orange 34 15793-73-4 LD50 Oral, Rat 8250 mg/kg 86 86 5 Pigment Orange 36 12236-62-3 LD50 Oral, Rat 8210 mg/kg 87 87 6 Pigment Orange

14

LIST OF ANNEXURES

Sr. No. Name of Annexure Page No.

I Detail of Total Area and List of Products with their Production Capacity,

CAS No. and LD 50 Values

15-20

II Layout Map of the Plant 21

III Brief Process Description/Mass Balance/Chemical Reaction 22-174

IV Detail of Storage of Raw Material and their Copnsumption with CAS No. 175-198

V Details of Effluent Treatment Scheme and Disposal with Flow Diagram 199-201

VI Details of Hazardous Waste Generation & Disposal 202

VII Details of Water Consumption, Waste Water Generation and Treatment

with Flow Diagram

203-204

VIII Details of Stack and Vents 205

IX Storage, Transportation and Handling of Hazardous Chemicals 206-207

X Risk of Accident from Other Hazardous and their Controls 208

XI Socio - Economic Impacts 209

XII Proposed Terms of Reference for EIA Studies 210-211

XIII Lease of Plot 212

15

Annexure : I

I.1 Detail of Area

Sr.No. Description Capacity

1 Proposed Capacity 1200 MT/Month

2 Total Area 12000 Sq.M.

3 Lease Area 12000 Sq.M.

4 No. of well to be drilled 1

I. 2 List of Products with their Capacity, CAS No. & LD 50 Values :-

Sr.No

.of

Total

Prod

ucts

Cate

gory

wise

Sr.N

o. of

Prod

ucts

Grou

p

wise

Sr.N

o. of

Prod

ucts

Name of the Products CAS no. /

CI no.

Quanti

ty

MT/M

onth

LD50 /LC50

1.Total No. of Products : Category : A+B = 147;

Total Production capacity of All Products : 1200 MT/Month

Category-A: Pigments (Group 1+2+3+4+5 = 106 )

Group-1: Pigment Red = 49

1 1 1 Pigment Red 2 6041-94-7

200

LD50 Oral, Rat 8110 mg/kg

2 2 2 Pigment Red 3 2425-85-6 LD50 Oral, Rat 8180 mg/kg




6 6 6 Pigment Red 14 6471-50-7 NA

7 7 7 Pigment Red 38 6358-87-8 dermal route (LD50 > 2000

mg/kg bw)

8 8 8 Pigment Red 48:1 7585-41-3 LD50 Oral, Rat 8160 mg/kg




12 12 12 Pigment Red 48:5 N.A. NA

13 13 13 Pigment Red 49 1248-18-6 NA

14 14 14 Pigment Red 49:1 1103-38-4 NA

15 15 15 Pigment Red 49:2 1103-39-5 NA

16 16 16 Pigment Red 49:3 6371-67-1 NA

16

17 17 17 Pigment Red 52:1 17852-99-2 NA

18 18 18 Pigment Red 52:2 12238-31-2 NA

19 19 19 Pigment Red 53 2092-56-0 NA

20 20 20 Pigment Red 53:1 5160-02-1. LD50 Oral, Rat 8190 mg/kg

21 21 21 Pigment Red 53:3 73263-40-8 L.D.50 ACUTE ORAL(RATS) :

ABOUT 5,000mg/KG

22 22 22 Pigment Red 57:1 5281-04-9. LD50 Oral, Rat 8140 mg/kg

23 23 23 Pigment Red 63:1 6417-83-0 NA

24 24 24 Pigment Red 63:2 35355-77-2 LD50 rat (oral): > 2.000 mg/kg

25 25 25 Pigment Red 81 12224-98-5 LD50 rat : 8260 mg/kg


27 27 27 Pigment Red 81:x 63022-06-0 LD50 rat (oral): > 2.000 mg/kg

28 28 28 Pigment Red 81:y N.A. LD50 rat (oral): > 2.000 mg/kg






34 34 34 Pigment Red 123 24108-89-2 LD50 rat (oral): > 2.000 mg/kg



37 37 37 Pigment Red 168 4378-61-4 NA






43 43 43 Pigment Red 178 3049-71-6 LD50 Species: rat Value: > 5,000

mg/kg


45 45 45 Pigment Red 188 61847-48-1 LD50 rat (oral): > 2.000 mg/kg


47 47 47 Pigment Red 254 122390-98-

1 LD50 Oral, Rat 8380 mg/kg

48 48 48 Pigment Red 256 79102-65-1 Oral LD50: >10 g/kg (rats)

practically non-toxic

49 49 49 Pigment Red 264 122390-98-

1 LD50 Oral, Rat 8320 mg/kg

Group-2: Pigment Yellow = 32

17

50 50 1 Pigment Yellow 1 2512-29-0

200

LD50 Oral, Rat. >10000mg/kg

51 51 2 Pigment Yellow 3 6486-23-3 LD50 Oral, Rat 8252mg/kg

52 52 3 Pigment Yellow 12 6358-85-6 LD50 Oral, Rat .>5000mg/kg



55 55 6 Pigment Yellow 16 5979-28-2 Not Listed

56 56 7 Pigment Yellow 17 4531-49-1 LD50 Oral, Rat 8230 mg/kg


58 58 9 Pigment Yellow 62 12286-66-7 LD50 rat (oral): > 5,000 mg/kg

59 59 10 Pigment Yellow 63 14569-54-1 Not Listed







66 66 17 Pigment Yellow 101 2387-03-3. LD50 rat (oral): > 2.000 mg/kg

67 67 18 Pigment Yellow 120 29920-31-8 oral route (LD50 > 15 000

mg/kg bw)

68 68 19 Pigment Yellow 121 61968-85-2 NA

69 69 20 Pigment Yellow 138 30125-47-4 LD50 rat (oral): > 5.000 mg/kg


71 71 22 Pigment Yellow 151` 31837-42-0 LD50 Oral, Rat 8330 mg/kg




75 75 26 Pigment Yellow 174 78952-72-4 LD50 Oral, Rat =980mg/kg

76 76 27 Pigment Yellow 180 77804-81-0 LD50 Oral, Rat 5000mg/kg

77 77 28 Pigment Yellow 181 74441-05-7 oral route (LD50 > 5000 mg/kg

bw)


79 79 30 Pigment Yellow 183 23792-68-9 LD50 Species: rat (male/female)

Value: > 5,000 mg/kg

80 80 31 Pigment Yellow 191 129423-54-7 Oral LD50 value of 5 mg/kg or

greater in rats.

81 81 32 Pigment Yellow 191:1 154946-66-4 LD50 Oral, Rat 2000mg/kg

Group-3: Pigment Orange = 8

82 82 1 Pigment Orange 5 3468-63-1 200

LD50 Oral, Rat 8120 mg/kg

83 83 2 Pigment Orange 13 3520-72-7 LD50 Oral, Rat 8190 mg/kg

18







Group-4: Pigment Blue = 10

90 90 1 Pigment Blue 1 1325-87-7

200

NA

91 91 2 Pigment Blue 15 147-14-8 LD50 Oral, Rat. >3200mg/kg

92 92 3 Pigment Blue 15:1 147-14-8 LD50 Oral, Rat. >3200mg/kg

93 93 4 Pigment Blue 15:2 147-14-8 LD50 Oral, Rat. >3200mg/kg

94 94 5 Pigment Blue 15:3 147-14-8 LD50 Oral, Rat 2000mg/kg



97 97 8 Pigment Blue 16 574-93-6 LD50 Oral, Rat 2000mg/kg

98 98 9 Pigment Blue 60 81-77-6 LD50 Oral, Rat > 980 mg/kg

99 99 10 Pigment Blue 62 57485-98-0 LD50 Oral, Rat 2000mg/kg

Group-5: Pigment Violet = 7

100 100 1 Pigment Violet 1 1326-03-0

200

LD50 Oral, Rat 2000mg/kg

101 101 2 Pigment Violet 1x N.A. LD50 Oral, Rat 2000mg/kg

102 102 3 Pigment Violet 3 1325-82-2 LD50 Oral, Rat 2000mg/kg

103 103 4 Pigment Violet 19 1047-16-1 LD50 Oral, Rat 8420 mg/kg


105 105 6 Pigment Violet 27 12237-62-6 LD50 Oral, Rat. >3200mg/kg


Total of Category-A ( Group 1 + 2 + 3 + 4 + 5 ) 1000

Category-B: Solvent Dyes

Group-1: Red Solvent Dyes = 13

107 1 1 Solvent Red 19E 6368-72-5

200

NA

108 2 2 Solvent Red 23 85-86-9 NA

109 3 3 Solvent Red 24 85-83-6 Acute oral toxicity: LD50(Rat):

8110mg/kg


8160mg/kg

111 5 5 Solvent Red 111 82-38-2 Acute Toxicity: Oral-dog LD

50:>8 g/kg


8260mg/kg

113 7 7 Solvent Red 151 144013-41-1 NA

19


8220mg/kg


8230mg/kg


8260mg/kg


8190mg/kg

118 12 12 Solvent Red 207 15958--69-6 NA

119 13 13 Solvent Red 227 2944-28-7 NA

Group-2: Yellow Solvent Dyes = 12

120 14 1 Solvent Yellow 2 6370-43-0 NA



123 17 4 Solvent Yellow 33 8003-22-3 Skin, rabbit: LD50 = >2 gm/kg.






129 23 10 Solvent Yellow 157 27908-75-4 Acute oral toxicity: LD50(Rat):

8200mg/kg

130 24 11 Solvent Yellow 163 106768-99-

4

LD50 rat (oral): > 2,000 mg/kg

(OECD Guideline 423)

131 25 12 Solvent Yellow 167 N.A. NA

Group-3: Orange Solvent Dyes = 3

132 26 1 Solvent Orange 60 61969-47-9 Acute oral toxicity: LD50(Rat):

8090mg/kg

133 27 2 Solvent Orange 63 16294-75-0 Acute oral toxicity: LD50(Rat):

8190mg/kg

134 28 3 Solvent Orange 105 31482-56-1 LD50 Intraperitoneal Rat=3060

MG/KG

Group-4: Blue Solvent Dyes = 6

135 29 1 Solvent Blue 35 17354-14-2 NA

136 30 2 Solvent Blue 36 14233-37-5 Acute oral toxicity: LD50(Rat):

8080mg/kg

137 31 3 Solvent Blue 97 61969-44-6 Acute oral toxicity: LD50(Rat):

8200mg/kg

138 32 4 Solvent Blue 101 6737-68-8 NA

139 33 5 Solvent Blue 102 15403-56-2 NA

20

140 34 6 Solvent Blue 104 116-75-6 Not acutely toxic via the oral

route (LD50 > 5000 mg/kg bw)

Group-5: Violet Solvent Dyes = 4

141 35 1 Solvent Violet 13 81-88-1 LD50 Oral, Rat. >500mg/kg

142 36 2 Solvent Violet 14 67577-84-8 Acute oral toxicity: LD50(Rat):

8110mg/kg

143 37 3 Solvent Violet 38 63512-14-1 NA

144 38 4 Solvent Violet 59 6408-72-6 Acute oral toxicity: LD50(Rat):

8220mg/kg

Group-6: Green Solvent Dyes = 3

145 39 1 Solvent Green 3 128-80-3 LD50 = 3660 mg/kg ( Rat )

146 40 2 Solvent Green 28 71839-01-5 LD50 = 3660 mg/kg ( Rat )

147 41 3 Solvent Green 33 10671-57-8 NA

Total of Category-B ( Group 1 + 2 + 3 + 4 + 5 + 6 ) 200

Total All Products Category - A(106) + Category-B (41) = 147 1200

21

Annexure : II

Construction Works

Layout Map of the Plant with Area Teble :-

Sr.No. Particular Area in Sq Mtrs

1 Process (Pigment and Solvent) 3675

2 Storage ( Raw Material and Finished Produst) 1102

3 Administration Office & Lab 200

4 Parking 500

5 Effluent treatment Plant 750

6 Green Belt 3960

7 Open Space for Roads, Loading & unloading 2058

Total Land Area 12,000

22

Annexure : III

Production and Manufacturing Process with Chemical Reaction and Mass Balance Detail

A Pigments Total Number of Pigments

(1 + 2 + 3 + 4 + 5 ) = 106

Total Quantity per Month

( 1 + 2 + 3 + 4 + 5 ) = 1000 MT per Month

1 Pigment Red Quantity per Month = 200 MT per Month

1) Pigment Red 2 cas no.6041-94-7:-

Manufacturing Process: -

2,5 DCA cas no.95-82-9 is Diazotized with HCL & Sodium Nitrite at 0 to 5 0C. Then coupled with

Naphthol AS cas no. 92-77-3. Coupled mass is stirred till coupling reaction gets complete. Then

reaction mass is heated up to 60 to 65 0C& filtered. Filtrate is sent to ETP for further treatment.

Then wet cake is washed with hot water. washing water is reused in next batch for Diazo

preparation. & wet cake is dried in spin flash dryer, pulverized & packed.

a. Diazotization of DCPNA

DCPNA

C6H5CI2N + 2HCI + NaNO2

Diazotization DCPNA Diazo

C6H3CI3N2 + NaCI + 2H2O

Mol.Wt. 162 + 73 + 69 185.5 + 58.5 + 36

b. Coupling with Naphthol AS

DCPNA Diazo + Naphthol AS + C.S. Flacks

C6H3CI3N2 + C17H13NO2+ NaOH

Coupling Pigment Red 2

C23H15CI2N3O2+ H2O + NaCI

Mol.Wt. 185.5 + 263 +40 436 + 18 + 58.5

Raw Material Consumption & Mass Balance for One TON Product: -

Sr.No. Input Qty.in Kgs Output Qty.in Kgs

1 Recycled Water 3000 Effluent to ETP 2955

2 ICE 2000 Washing water for Re-Use 3000

3 DCPNA 390 Water Evaporation in Drying 3000

4 HCI 385 Finish Product 1000

5 Sodium Nitrite 170

6 Naphthol AS 610

7 C.S. Flacks 200

8 Fresh Water for Washing 3000

TOTAL 9955 TOTAL 9955

23



Red G Base/ MNPT89-62-3 is Diazotized with HCL & Sodium Nitrite at 0 to 5 0C. Then coupled

with B-Naphthol. Cas no. 135-19-3 Coupled mass is stirred till coupling reaction gets complete. Then



preparation. & wet cake is dried in spin flash dryer, pulverized & packed

a. Diazotization of Red G Base

b. Coupling with B-Naphthol





3 Red G Base 525 Water Evaporation in Drying 3000



6 B-Naphthol 490

7 C.S. Flacks 200



Red G Base

C7H8N2O2 + 2HCI + NaNO2

Diazotization Red G Base Diazo

C7H6CIN3O2 + NaCI + 2H2O

Mol.Wt. 152+ 73 + 69 199.5 + 58.5 + 36

Red G Base Diazo + B-Naphthol + C.S. Flacks

C7H6CIN3O2 + C10H8O+ NaOH


C17H13N3O3 + H2O + NaCI

Mol.Wt. 199.5 + 144 +40 307 + 18 + 58.5

24



OCPNA cas no.121-87-9 is Diazotized with HCL & Sodium Nitrite at 0 to 5 0C. Then coupled with

B-Naphthol cas no.135-19-3 . Coupled mass is stirred till coupling reaction gets complete. Then




a. Diazotization of OCPNA






3 OCPNA 550 Water Evaporation in Drying 3000



6 B-Naphthol 445

7 C.S. Flacks 200



OCPNA

C6H5CIN2O2 + 2HCI + NaNO2

Diazotization OCPNA Diazo

C6H3CI2N3O2 + NaCI + 2H2O

Mol.Wt. 172.5+ 73 + 69 220 + 58.5 + 36

OCPNA Diazo + B-Naphthol + C.S. Flacks

C6H3CI2N3O2 + C10H8O + NaOH


C16H10CIN3O3+ H2O + NaCI

Mol.Wt. 220 + 144 + 40 327.5 + 18 + 58.5

25

4) Pigment Red 5 cas no.6410-41-9 :-


Fast Red ITR cas no.6410-41-9 is Diazotized with HCL & Sodium Nitrite at 0 to 5 0C. Then coupled

with Naphthol AS ITR cas no.92-72-8. Coupled mass is stirred till coupling reaction gets complete.

Then reaction mass is heated up to 60 to 65 0C& filtered. Filtrate is sent to ETP for further

treatment. Then wet cake is washed with hot water. washing water is reused in next batch for Diazo


a. Diazotization of Fast Red ITR

Fast Red ITR

C11H18N2O3S + 2HCI + NaNO2

Diazotization Fast Red ITR Diazo

C11H18CIN2O3S + NaCI + 2H2O

Mol.Wt. 258 + 73 + 69 305.5 + 58.5 + 36

b. Coupling with Naphthol ASITR

Fast Red ITR Diazo + Naphthol ASITR + C.S. Flacks

C11H18CIN2O3S +C19H16CINO4 + NaOH


C30H31CIN4O7S+ H2O + NaCI

Mol.Wt. 305.5 + 357.5 + 40 626.5 + 18 + 58.5





3 Fast Red ITR 450 Water Evaporation in Drying 3000



6 Naphthol ASITR 555

7 C.S. Flacks 200



26

5) Pigment Red 12 cas no.6410-32-8: -


2-Methyl,4-Nitro Toludine [PNPT 99-52-5] is Diazotized with HCL & Sodium Nitrite at 0 to 5 0C.

Then coupled with Naphthol ASD cas no. Coupled mass is stirred till coupling reaction gets complete.

Then reaction mass is heated up to 60 to 65 0C& filtered. Filtrate is sent to ETP for further treatment.



a. Diazotization of PNPT

PNPT


Diazotization PNPT Diazo


Mol.Wt. 152 + 73 + 69 199.5 + 58.5 + 36

b. Coupling with Naphthol ASD

PNPT Diazo + Naphthol AS D + C.S. Flacks

C7H6CIN3O2 +C18H15NO2+ NaOH



Mol.Wt. 199.5 + 277 +40 440 + 18 + 58.5





3 PNPT 360 Water Evaporation in Drying 3000



6 Naphthol ASD 680

7 C.S. Flacks 200



27

6)Pigment Red 14[ CAS No.6471-50-7 ]: -


p-Chloro-O-nitro aniline [PCONA CAS No.89-63-4] is Diazotized with HCL & Sodium Nitrite at 0

to 5 0C. Then coupled with Naphthol ASD [ CAS No. 135-61-5]. Coupled mass is stirred till coupling

reaction gets complete. Then reaction mass is heated up to 60 to 65 0C& filtered. Filtrate is sent to

ETP for further treatment. Then wet cake is washed with hot water. washing water is reused in next

batch for Diazo preparation. & wet cake is dried in spin flash dryer, pulverized & packed

a. Diazotization of PCONA


PCONA Diazo + Naphthol ASDL + C.S. Flacks

C6H3CI2N3O2 +C18H15NO2+ NaOH


C24H17CIN4O4 + H2O + NaCI

Mol.Wt. 220 + 277 +40 460.5 + 18 + 58.5


Sr.No. Input Qty.in

Kgs

Output Qty.in Kgs



3 PCONA 405 Water Evaporation in

Drying

3000



6 Naphthol ASD 610

7 C.S. Flacks 200



PCONA


Diazotization PCONA Diazo


Mol.Wt. 172.5+ 73 + 69 220 + 58.5 + 36

28



3,3-Dichloro Benzidine [3,3-DCB cas no.91-94-4] is double Diazotized with HCL & Sodium Nitrite

at 0 to 5 0C. Then coupled with 2 mole 1-p-tolyl-3-methyl-5-pyrazolone [PCEP / Carb Ethox.cas

no.99-33-8 ]. Coupled mass is stirred till coupling reaction gets complete. Then reaction mass is

heated up to 60 to 65 0C& filtered. Filtrate is sent to ETP for further treatment. Then wet cake is

washed with hot water. washing water is reused in next batch for Diazo preparation. & wet cake is

dried in spin flash dryer, pulverized & packed

a. Diazotization of 3,3-DCB

3,3-DCB

C12 H10 N2CI2+ 4HCI + 2NaNO2

Diazotization 3,3-DCB Diazo

C12 H6 N4CI4 + 2NaCI + 4 H2O

Mol.Wt. 253 + 146 + 138 348 + 117 + 72

b. Coupling with PCEP

3-3-DCB Diazo + PCEP + C.S. Flacks

C12 H6 N4CI4 +2[C12H12N2O3] +2NaOH


C36H28Cl2N8O6+ 2H2O + 2NaCI

Mol.Wt. 348 + 464 +80 739 + 36 + 117





3 3,3-DCB 350 Water Evaporation in Drying 3000



6 PCEP 640

7 C.S.Flacks 200



29

8) Pigment Red 48:1 cas no.7585-41-3:-


2B Acid cas no.88-51-7 is Diazotized with HCL & Sodium Nitrite at 0 to 5 0C. Then coupled with

BON Acid cas no.92-70-6. Coupled mass is stirred till coupling reaction gets complete. Then in

reaction mass, Barium Chloride is added & is heated up to 75 to 80 0C to form Barium Salt& filtered.

Filtrate is sent to ETP for further treatment. Then wet cake is washed with hot water. washing water

is reused in next batch for Diazo preparation. & wet cake is dried in spin flash dryer, pulverized &

packed

a. Diazotization of 2B Acid

2B Acid

C7H8CINO3S + 2HCI + NaNO2

Diazotization 2B Acid Diazo

C7H6CI2N2O3S + NaCI + 2 H2O

Mol.Wt. 221.5+ 73 + 69 269 + 58.5 + 36

b. Coupling with BON Acid

2B Acid Diazo+ BON Acid +C.S.Flacks

C7H6CI2N2O3S I+ C11H8O3+3NaOH +BaCI2

Coupling Pigment Red 48:1

C18H11CIN2O6S.Ba + 3H2O + 3NaCI

Mol.Wt. 269 + 188 + 120 + 208 555.5 + 54 + 175.5





3 2B Acid 550 Water Evaporation in Drying 3000



6 BON Acid 468

7 C.S.Flacks 200

8 Barium Chloride 200



30



2B Acid cas no 88-51-7. is Diazotized with HCL & Sodium Nitrite at 0 to 5 0C. Then coupled

with BON Acid cas no.92-70-6 . Coupled mass is stirred till coupling reaction gets complete. Then in

reaction mass, Calcium Chloride is added & is heated up to 75 to 80 0C to form Calcium Salt&

filtered. Filtrate is sent to ETP for further treatment. Then wet cake is washed with hot water.

washing water is reused in next batch for Diazo preparation. & wet cake is dried in spin flash dryer,

pulverized & packed


2B Acid




Mol.Wt. 221.5 + 73 + 69 269 + 58.5 + 36


2B Acid Diazo+ BON Acid + C.S. Flacks

C7H6CI2N2O3S I+ C11H8O3+3NaOH +CaCI2


C18H11CIN2O6S.Ca + 3H2O + 3NaCI

Mol.Wt. 269 + 188 + 120 + 111 458.5 + 54 + 175.5








6 BON Acid 468

7 C.S.Flacks 200

8 Calcium Chloride 250



31



2B Acid cas no 88-51-7 . is Diazotized with HCL & Sodium Nitrite at 0 to 5 0C. Then coupled

with BON Acid cas no.92-70-6. Coupled mass is stirred till coupling reaction gets complete. Then in

reaction mass, Strontium Chloride is added & is heated up to 75 to 80 0C to form Strontium Salt&



pulverized & packed


2B Acid




Mol.Wt. 221.5 + 73 + 69 269 + 58.5 + 36



C7H6CI2N2O3S I+ C11H8O3+3NaOH +SrCI2


C18H11CIN2O6S.Sr + 3H2O + 3NaCI

Mol.Wt. 269 + 188 + 120 + 158.5 505.5 + 54 + 175.5








6 BON Acid 468

7 C.S.Flacks 200

8 Strontium Chloride 240



32

11) Pigment Red 48:4 cas no. 5280-66-0:-




reaction mass, Manganese Chloride is added & is heated up to 75 to 80 0C to form Manganese Salt&



pulverized & packed


2B Acid




Mol.Wt. 221.5 + 73 + 69 269 + 58.5 + 36



C7H6CI2N2O3S I+ C11H8O3+3NaOH +MnCI2


C18H11CIN2O6S.Mn + 3H2O + 3NaCI

Mol.Wt. 269 + 188 + 120 + 126 473.5 + 54 + 175.5








6 BON Acid 468

7 C.S.Flacks 200

8 Manganese Chloride 245



33

12) Pigment Red 48:5 [ cas no. N.A.]:-




reaction mass, Magnesium Chloride is added & is heated up to 75 to 80 0C to form Magnesium Salt&



pulverized & packed


2B Acid




Mol.Wt. 221.5 + 73 + 69 269 + 58.5 + 36


2B Acid Diazo+ BON Acid + C.S. Flacks

C7H6CI2N2O3S I+ C11H8O3+3NaOH +MgCI2


C18H11CIN2O6S.Mg + 3H2O + 3NaCI

Mol.Wt. 269 + 188 + 120 + 95 442.5 + 54 + 175.5








6 BON Acid 468

7 C.S.Flacks 200

8 Magnesium Chloride 245



34

13) Pigment Red 49 [ cas no.1248-18-6]: -


Tobias Acid cas no.81-16-3 is Diazotized with HCL & Sodium Nitrite at 0 to 5 0C. Then coupled

with B-Naphthol cas no.135-19-3 Coupled mass is stirred till coupling reaction gets complete. Then

in reaction mass, Sodium Hydroxide is added & is heated up to 75 to 80 0C to form Sodium Salt &



pulverized & packed

a. Diazotization of Tobias Acid

Tobias Acid

C10H9NO3S + 2HCI + NaNO2

Diazotization Tobias Acid Diazo

C10H7CIN2O3S + NaCI + 2 H2O

Mol.Wt. 223 + 73 + 69 270.5 + 58.5 + 36


2B Acid Diazo+ B-Naphthol+C.S. Flacks

C10H7CIN2O3S + C10H8O +2NaOH


C20H13N2O4S.Na + 2H2O + NaCI

Mol.Wt. 270.5 + 144 + 80 400 + 36 + 58.5





3 Tobias Acid 600 Water Evaporation in Drying 3000



6 B-Naphthol 395

7 C.S.Flacks 200

8 Sodium Hydroxide 245



35

14) Pigment Red 49:1 [ cas no.1103-38-4]: -


Tobias AcidCAS No.81-16-3 is Diazotized with HCL & Sodium Nitrite at 0 to 5 0C. Then coupled

with B-Naphthol 135-19-3. Coupled mass is stirred till coupling reaction gets complete. Then in

reaction mass, Barium Chloride is added & is heated up to 75 to 80 0C to form Barium Salt & filtered.



packed


Tobias Acid




Mol.Wt. 223 + 73 + 69 270.5 + 58.5 + 36



C10H7CIN2O3S + C10H8O+2NaOH + 1/2BaCl2


C20H13N2O4S.Ba1/2 + 2H2O + 2NaCI

Mol.Wt. 270.5 + 144 + 80 + 104.5 446 + 36 + 117








6 B-Naphthol 395

7 C.S.Flacks 200

8 Barium chloride 245



36

15) Pigment Red 49:2 cas no. 1103-39-5: -


Tobias Acid CAS No.81-16-3 is Diazotized with HCL & Sodium Nitrite at 0 to 5 0C. Then coupled

with B-Naphthol 135-19-3. Coupled mass is stirred till coupling reaction gets complete. Then in




pulverized & packed


Tobias Acid




Mol.Wt. 223 + 73 + 69 270.5 + 58.5 + 36



C10H7CIN2O3S + C10H8O+2NaOH +1/2CaCI2


C20H13N2O4S.Ca1/2 + 2H2O + 2NaCI

Mol.Wt. 270.5 + 144 + 80 + 55 396.5 + 36 + 117

Raw Material Consumption & Mass Balance for One TON Product : -







6 B-Naphthol 395

7 C.S.Flacks 200




37

16)Pigment Red 49:3 [ CAS NO.6371-67-1]: -


2-Amino-1-naphthalene Sulphonic acid. [ Tobias Acid CAS No.81-16-3] is Diazotized with HCL &

Sodium Nitrite at 0 to 5 0C. Then coupled with B-Naphthol [ CAS NO.135-19-3]. Coupled mass is

stirred till coupling reaction gets complete. Then in reaction mass, Strontium Chloride is added & is

heated up to 75 to 80 0C to form Calcium Salt& filtered. Filtrate is sent to ETP for further treatment.




Tobias Acid




Mol.Wt. 223 + 73 + 69 270.5 + 58.5 + 36


Tobias Acid Diazo+ B-Naphthol+C.S. Flacks

C10H7CIN2O3S + C10H8O+3NaOH +SrCI2


C17H13CIN2O4S.Sr1/2 + 3H2O + 3NaCI

Mol.Wt. 270.5 + 144 + 120 + 158.5 463.5 + 54 + 175.5








6 B-Naphthol 390

7 C.S. Flacks 200




38

17) Pigment Red 52:1 cas no.17852-99-2: -


C Acid cas no.88-53-9 is Diazotized with HCL & Sodium Nitrite at 0 to 5 0C. Then coupled with

BON Acid cas no.92-70-6 Coupled mass is stirred till coupling reaction gets complete. Then in




pulverized & packed

a. Diazotization of C Acid

C Acid


Diazotization C Acid Diazo


Mol.Wt. 221.5 + 73 + 69 269 + 58.5 + 36


C Acid Diazo+ BON Acid +C.S. Flacks

C7H6CI2N2O3S + C11H8O3+2NaOH +1/2CaCI2


C18H12CIN2O6S.Ca1/2 + 2H2O + 2NaCI

Mol.Wt. 269 + 188 + 80 + 55.5 439.5 + 36 + 117





3 C Acid 550 Water Evaporation in Drying 3000



6 BON Acid 455

7 C.S. Flacks 200




39

18) Pigment Red 52:2 [ cas no.12238-31-2]: -


C Acid cas no.88-53-9 is Diazotized with HCL & Sodium Nitrite at 0 to 5 0C. Then coupled with


reaction mass, Manganese Chloride is added & is heated up to 75 to 80 0C to form Manganese Salt&



pulverized & packed


C Acid




Mol.Wt. 221.5 + 73 + 69 269 + 58.5 + 36


C Acid Diazo+ BON Acid +C.S. Flacks

C7H6CI2N2O3S + C11H8O3+2NaOH +1/2 MnCI2


C18H12CIN2O6S.Mn/2 + 2H2O + 2NaCI

Mol.Wt. 269 + 188 + 80 + 62.5 446.5 + 36 + 117








6 BON Acid 455

7 C.S. Flacks 200




40

19) Pigment Red 53 cas no. 2092-56-0 :-


C-Acid cas no.88-53-9 is Diazotized with HCL & Sodium Nitrite at 0 to 5 0C. Then coupled with

B-Naphthol cas no.135-19-3. Coupled mass is stirred till coupling reaction gets complete. Then in

reaction mass, Sodium Hydroxide is added & is heated up to 75 to 80 0C to form sodium Salt&



pulverized & packed


C Acid




Mol.Wt. 221.5 + 73 + 69 269 + 58.5 + 36


C Acid Diazo+ B-Naphthol+C.S. Flacks

C7H6CI2N2O3S + C10H8O+2NaOH


C17H12CIN2O4S.Na + 2H2O + NaCI

Mol.Wt. 269 + 144 + 80 399 + 36 + 58.5





3

C- Acid

560 Water Evaporation in Drying 3000



6 B-Naphthol 435

7 C.S. Flacks 200




41

20) Pigment Red 53:1 cas no.5160-02-1 :-


C-Acid cas no.88-53-9 is Diazotized with HCL & Sodium Nitrite at 0 to 5 0C. Then coupled with

B-Naphthol cas no.135-19-3. Coupled mass is stirred till coupling reaction gets complete. Then in

reaction mass, Barium Chloride is added & is heated up to 75 to 80 0C to form Barium Salt& filtered.



packed


C Acid




Mol.Wt. 221.5 + 73 + 69 269 + 58.5 + 36



C7H6CI2N2O3S + C10H8O+2NaOH +1/2BaCI2


C17H13N2O4S.Ba1/2 + 2H2O + 2NaCI

Mol.Wt. 269 + 144 + 80 + 104 444 + 36 + 117





3 C- Acid 560 Water Evaporation in Drying 3000



6 B-Naphthol 435

7 C.S. Flacks 200

8 Barium Chloride 245



42

21) Pigment Red 53:3 [ CAS NO.73263-40-8]: -


2-amino-4-methyl-5-chloro benzene Sulphonic acid [C Acid CAS No.88-53-9] is Diazotized with

HCL & Sodium Nitrite at 0 to 5 0C. Then coupled with B-Naphthol [ CAS NO.135-19-3]. Coupled mass

is stirred till coupling reaction gets complete. Then in reaction mass, Strontium Chloride is added &

is heated up to 75 to 80 0C to form Calcium Salt& filtered. Filtrate is sent to ETP for further




C Acid




Mol.Wt. 221.5 + 73 + 69 269 + 58.5 + 36



C7H6CI2N2O3S + C10H8O+3NaOH +SrCI2


C17H13CIN2O4S.Sr1/2 + 3H2O + 3NaCI

Mol.Wt. 269 + 144 + 120 + 158.8 462.5 + 54 + 175.5








6 B-Naphthol 390

7 C.S. Flacks 200




43

22) Pigment Red 57:1 cas no. 5281-04-9: -


4B Acid cas no88-44-8 . is Diazotized with HCL & Sodium Nitrite at 0 to 5 0C. Then coupled

with BON Acid cas no.92-70-6. Coupled mass is stirred till coupling reaction gets complete. Then in




pulverized & packed


4B Acid




Mol.Wt. 187 + 73 + 69 234.5 + 58.5 + 36


4B Acid Diazo+ BON Acid +C.S. Flacks

C7H7CIN2O3S + C11H8O3+ 3NaOH + CaCI2


C18H12N2O6S.Ca + 3H2O + 3NaCI

Mol.Wt. 234.5+ 188 + 120 + 111 424 + 54 + 175.5








6 BON Acid 475

7 C.S. Flacks 200




44

23) Pigment Red 63:1[ cas no.6417-83-0]: -


Tobias Acid [ cas no.81-16-3]is Diazotized with HCL & Sodium Nitrite at 0 to 5 0C. Then coupled

with BON Acid [cas no.92-70-6]. Coupled mass is stirred till coupling reaction gets complete. Then in




pulverized & packed


Tobias Acid




Mol.Wt. 223 + 73 + 69 270.5 + 58.5 + 36


Tobias Acid Diazo+ BON Acid +C.S. Flacks

C10H7CIN2O3S + C11H8O3+ 3NaOH + CaCI2



Mol.Wt. 270.5 + 188 + 120 + 111 460 + 54 + 175.5








6 BON Acid 475

7 C.S. Flacks 200




45

24) Pigment Red 63:2 [ CAS No.35355-77-2]: -


2-Amino-1-Naphthalenesulphonic Acid [Tobias Acid CAS No.81-18-3] is Diazotized with HCL &

Sodium Nitrite at 0 to 5 0C. Then coupled with BON Acid [CAS No.92-70-6]. Coupled mass is stirred

till coupling reaction gets complete. Then in reaction mass, Manganese Chloride is added & is

heated up to 75 to 80 0C to form Manganese Salt& filtered. Filtrate is sent to ETP for further




Tobias Acid




Mol.Wt. 223 + 73 + 69 270.5 + 58.5 + 36


Tobias Acid Diazo+ BON Acid +C.S. Flacks

C10H7CIN2O3S + C11H8O3+ 2NaOH + 1/2MnCI2


C21H14N2O6S.Mn1/2 + 2H2O + 2NaCI

Mol.Wt. 270.5 + 188 + 80 + 62.5 448 + 36 + 117








6 BON Acid 475

7 C.S. Flacks 200




46

25) Pigment Red 81 PMA salt [ cas no. 12224-98-5.]:-


2 Moles of 3-[(ethyl amino)-4-methyl Phenol [ EAMP]Cas No.120-37-6 is condensed with

phthalic Anhydride Cas No.85-44-9 in Ethanol cas no.64-17-5 .Then ethanol is distilled out for

recycle & Product is washed with Hot Water & washing water is reused in next batch for isolation in

next batch & wet cake converted into phosphomolybdic acid salt then it is dried in spin flash dryer,

pulverized & packed

a. Condensation of EAMP with Phthalic Anhydride: -

EAMP Phthalic Anhydride +

Ethanol

2[ C9H13NO ] + C8H4O3 + C2H5OH

Condensation Pigment Red 81 Hydroxide

hydride

C28H31N2O3PMA Salt + H5O3

Mol.Wt. 2 x 151 + 148 + 46 443+PMA salt + 53


Sr.No. Input Qty.in

Kgs

Output Qty.in

Kgs

1 EAMP 600 Finish Product 1000

2 Phthalic Anhydride 515 Ethanol Recovery for Re-use 950

3 Ethanol 1000 Washing water for Re-Use 2000

4 Phosphomolybdic acid [ PMA] 100 Evaporation loss 1265

5 Water for Washing 3000


47

26) Pigment Red 81:1 SMT salt [ cas no.80083-40-5]:-





next batch & wet cake converted into Silicotungstomolybdic [SMT ] acid salt then it is dried in spin

flash dryer, pulverized & packed



Ethanol

2[ C9H13NO ] + C8H4O3 + C2H5OH

Condensation Pigment Red 81:1 Hydroxide

hydride

C28H31N2O3SMT Salt + H5O3

Mol.Wt. 2 x 151+ 148 + 46 443+SMT salt + 53


Sr.No. Input Qty.in

Kgs

Output Qty.in

Kgs




4 Silicotungstomolybdic [SMT ] acid 100 Evaporation loss 1265



48

27) Pigment Red 81:x PM salt[ cas no.63022-06-0 .]:-





next batch & wet cake converted into Phosphoric molybdic [PM]acid salt then it is dried in spin flash

dryer, pulverized & packed



Ethanol

2[ C9H13NO ] + C8H4O3 + C2H5OH

Condensation Pigment Red 81:x Hydroxide

hydride

C28H31N2O3PM Salt + H5O3

Mol.Wt. 2 x 151+ 148 + 46 443+PM salt + 53


Sr.No. Input Qty.in

Kgs

Output Qty.in

Kgs




4 Phosphoric molybdic [PM]acid 100 Evaporation loss 1265



49

28) Pigment Red 81:y SM salt [ cas no.N.A.]:-





next batch & wet cake converted into Silicomolybdic [SM]acid salt then it is dried in spin flash dryer,

pulverized & packed



Ethanol

2[ C9H13NO ] + C8H4O3 + C2H5OH


hydride

C28H31N2O3SM Salt + H5O3

Mol.Wt. 2 x 151 + 148 + 46 443+SM salt + 53


Sr.No. Input Qty.in

Kgs

Output Qty.in

Kgs




4 Silicomolybdic [SM]acid 100 Evaporation loss 1265



50

29) Pigment Red 81:2 SM Salt[ cas no..75627-12-2]:-





next batch & wet cake converted into Silicomolybdic [SM]acid salt then it is dried in spin flash dryer,

pulverized & packed



Ethanol

2[ C9H13NO ] + C8H4O3 + C2H5OH


hydride


Mol.Wt. 2 x 151 + 148 + 46 443+SM salt + 53


Sr.No. Input Qty.in

Kgs

Output Qty.in

Kgs




4 Silicomolybdic [SM]acid 100 Evaporation loss 1265



51

30) Pigment Red 81:3 PM Salt [ cas no.68310-07-6 .]:-





next batch & wet cake converted into Phosphoric molybdic [PM]acid salt then it is dried in spin flash




Ethanol

2[ C9H13NO ] + C8H4O3 + C2H5OH


hydride

C28H31N2O3pM Salt + H5O3

Mol.Wt. 2 x 151+ 148 + 46 443+PM salt + 53


Sr.No. Input Qty.in

Kgs

Output Qty.in

Kgs




4 Phosphoric molybdic [PM]acid 80 Evaporation loss 1245



52

31) Pigment Red 81:4 PTMA salt[ cas no.85959-61-1 .]:-





next batch & wet cake converted into Phosphotungstomolybdic [PTMA] acid salt then it is dried in

spin flash dryer, pulverized & packed



Ethanol

2[ C9H13NO ] + C8H4O3 + C2H5OH


hydride

C28H31N2O3PTMA Salt + H5O3

Mol.Wt. 2 x 151 + 148 46 443+PTMA salt 53


Sr.No. Input Qty.in

Kgs

Output Qty.in

Kgs




4 Phosphotungstomolybdic [PTMA] acid 80 Evaporation loss 1245



53



2,4,5-Trichloroaniline [TCA cas no.636-30-6] is Diazotized with HCL & Sodium Nitrite at 0 to 5 0C. Then coupled with Naphthol ASD cas no.135-61-5 . Coupled mass is stirred till coupling reaction

gets complete. Then in reaction mass is heated up to 75 to 80 0C to& filtered. Filtrate is sent to ETP

for further treatment. Then wet cake is washed with hot water. washing water is reused in next


a. Diazotization of TCA

TCA


Diazotization TCA Diazo

C6H2CI4N2 + NaCI + 2 H2O

Mol.Wt. 196.5+ 73 + 69 244 + 58.5 + 36


TCA Diazo+ Naphthol ASD +C.S. Flacks

C6H2CI4N2 + C18H15NO2 + NaOH


C24H16CI3N3O2 + H2O + NaCI

Mol.Wt. 244 + 277 + 40 484.5 + 18 + 58.5


Sr.No. Input Qty.in

Kgs

Output Qty.in Kgs



3 TCA 410 Water Evaporation in

Drying

3000



6 Naphthol ASD 575

7 C.S. Flacks 200



54

33) Pigment Red 122 [ CAS NO. 980-26-7 /16043-40-6.]: -


1. Dimethyl Succinosuccinate [DMSS CAS No.6289-46-9] is condensed with 2 moles of p-

Toluidine in methanol under efflux condition to form 2,5-diaryl amino-3,6-dihydroxy

terephthalate [ DADHT].

2. Then resulting product is oxidised with resist salt to form 2,5-di-p-toluidino-terephthalic

acid dimethyl ester [DTTA-DME dimethyl ester CAS No.114508-42-8].

3. Then it is hydrolyzed in alkaline condition & aqueous medium to form 2,5-Bis-(p-toluidino)

terephthalic acid [DTTP Acid CAS.No. 10291-28-8]

4. Then it is further cyclised in presence of Poly phosphoric acid then finally pigmentation is

done in presence of IBA/DMF as per Quinacridone as Pigment Red 122

1.Condensation of DMSS with p-Toluidine: -

DMSS + 2[p-Toluidine]

C10H12O6 + 2[C7H9N]

Condensation

DADHT

C24H26N2O4 + 2H2O

Mol.Wt.228 + 2X[107] Methanol 406 + 36

2.Oxidation Of DADHT with Resist Salt: -

DADHT

C24H26N2O4 + O2

Condensation

DTTA dimethyl ester

C24H24N2O4 + H2O2

Mol.Wt. 406 + 32 Resist Salt 404 + 34

3.Hydrolysis of DTTA dimethyl ester:-

DTTA dimethyl ester

C24H24N2O4 + 2NaOH +2HCL

Hydrolysis

DTTP Acid

C22H20N2O4 + 2NaCI + 2CH3OH

Mol.Wt. 404 + 80 + 73 Methanol 376 + 117 + 64

4.Cyclisation of DTTP Acid with Poly Phosphoric Acid & Pigmentation to form Pigment Red 122:-

DTTP Acid Poly Phosphoric

acid

C22H20N2O4 +

H3PO4.P2O5

Cyclisation

Pigment Red 122 Triphosphoric Acid

monohydrate

C22H16N2O2 + H5P3O10.H2O

Mol.Wt. 376 + 238 DMF /IBA 340 + 274

55


Sr.No. Input Qty.in

Kgs

Output Qty.in

Kgs

1 Methanol 5500 Finish Product 1000

2 Dimethyl

Succinosuccinate


3 p-Toluidine 880 Methanol Recovery for Re-Use 5225

4 Resist Salt 300 Washing water for Re-Use 7000

5 NaOH 275 Effluent to ETP 7500

6 HCL 250 DMF /IBA Recovery for Re-Use 6650

7 Poly Phosphoric Acid 1800 Inorganic & solvent residue 680

8 DMF / IBA 7000

9 Water for Reaction 7000

10 Water for Isolation 7000


56

34) Pigment Red 123 [ CAS NO.24108-89-2]: -


Perylene Tetracarboxydianhydride[ PTCDA cas no.128-69-8] is condensed with 2 mole of 3,5-

Dimethylaniline [ 3,5-DMA cas no.108-69-0] in aqueous medium in reflux condition at 95--1000C for

4-5 hrs till condensation reaction gets complete. Then reaction mass is cooled up to 350C by adding

water for isolation. Then reaction mass is filtered. filtrate is sent to ETP & MEE. Then wet cake is

washed with hot water. washing water is reused in next batch for isolation in next batch & wet cake

is dried in spin flash dryer, pulverized & packed

a. Condensation of Perylene Tetracarboxydianhydride with 3,5-Dimethylaniline: -

PTCDA 3,5-DMA

C24H8O6+ 2[C8H11N]

Condensation Pigment Red 149

C40H26N2O4 + 2H2O

Mol.Wt. 392 + 2x 121 Water+ Pipyridine 598 + 36


Sr.No. Input Qty.in

Kgs

Output Qty.in

Kgs

1 Water 3000 Finish Product 1000

2 PTCDA 650 Water Evaporation in Drying 2500

3 3,5-DMA 395 Washing water for Re-Use 3000

4 Pipyridine 10 Effluent to ETP 2555



7


57

35) Pigment Red 144 cas no. 5280-78-4: -


2,5-DichloroAniline [DCA cas no ] is Diazotized with HCL & Sodium Nitrite at 0 to 5 0C. Then

coupled with 3-Hydroxy,2-Naphthoyl Chloride. Coupled mass is stirred till coupling reaction gets

complete. Then 2 moles of this monodye is condensed with 1 mole of 2-Chloro,1,4-

Diaminobenzene 615-66-7 & heated up to 75 to 80 0C & filtered. Filtrate is sent to ETP for further



a. Diazotization of DCA

MCA


Diazotization MCADiazo

C6H3CI3N2 + NaCI + 2 H2O

Mol.Wt. 162 + 73 + 69 209.5 + 58.5 + 36

b. Coupling with 3-H,2-Naphthoyl Chloride

DCA Diazo + 3-H,2-Naphthoyl Chloride +C.S.

Flacks

C6H3CI3N2 + C11H7CIO2 + NaOH

Coupling Mono Dye

C17H9CI3N2O2 + H2O + NaCI

Mol.Wt. 209.5 + 206.5 + 40 379.5 + 18 + 58.5

c.Condensation with DABC

2 mole Mono Dye + DABC

2[C17H9CI3N2O2] + C6H7CIN2 + 2NaOH


C40H23CI5N6O4 + 2H2O +2NaCI

Mol.Wt. 759 + 142.5 + 80 828.5 + 36 + 117


Sr.No. Input Qty.in

Kgs

Output Qty.in Kgs



3 DCA 490 Water Evaporation in Drying 3000



6 3-H,2-Naphthoyl Chloride 500

7 C.S. Flacks 250

8 DABC 180



58



Fast Red KD Base cas no.120-35-4is Diazotized with HCL & Sodium Nitrite at 0 to 5 0C. Then coupled

with Naphthol AS LC cas no.137-92-1. Coupled mass is stirred till coupling reaction gets complete.

Then reaction mass is heated up to 75 to 80 0C & filtered. Filtrate is sent to ETP for further



a. Diazotization of Fast Red KD Base

Fast Red KD Base


Diazotization Fast Red KD Base Diazo

C14H12CIN3O2 + NaCI + 2 H2O

Mol.Wt. 242 + 73 + 69 289.5 + 58.5 + 36

b. Coupling with Naphthol AS LC

Fast Red KD Base Diazo+ Naphthol ASLC +C.S.

Flacks

C14H12CIN3O2 + C19H16CINO4 + NaOH


C33H27CIN4O6 + H2O + NaCI

Mol.Wt. 289.5 + 357.5 + 40 610.5 + 18 + 58.5


Sr.No. Input Qty.in

Kgs

Output Qty.in Kgs



3 Fast Red KD Base 400 Water Evaporation in

Drying

3000



6 Naphthol AS LC 595

7 C.S. Flacks 200



59

37) Pigment Red 168 [ cas no. 4378-61-4 ] :-

Anthanthrone Cas No.641-13-4 is Brominated with Liquid Bromine Cas No.7726-95-6 in

water.Then filtered & Product is washed with Hot Water & washing water is reused in next batch

for reaction in next batch & wet cake then it is dried in spin flash dryer, pulverized & packed

a. Bromination of Anthanthrone: -

Anthanthrone + Liquid Bromine

C22H10O2 ] + 2Br2

Bromination Pigment Red 168

C22H8Br2O2 + 2HBr

Mol.Wt. 306 + 320 464 + 162


Sr.No. Input Qty.in

Kgs

Output Qty.in

Kgs

1 Anthanthrone 800 Finish Product 1000

2 Liquid Bromine 205

3 Water for Reaction 2000 Washing water for Re-Use 3000

4 Water for Washing 3000 Evaporation loss 2005

5


60

38) Pigment Red 169 CF [cas no. 12237-63-7 ] :-





next batch & wet cake converted into ferrous iron copper cyanide complex.[CF]acid salt then it is




Ethanol

2[ C9H13NO ] + C8H4O3 + C2H5OH


hydride

C28H31N2O3 CF Salt + H5O3

Mol.Wt. 2 x 151 + 148 + 46 443+CF salt + 53


Sr.No. Input Qty.in

Kgs

Output Qty.in

Kgs




4 ferrous iron copper cyanide complex 80 Evaporation loss 1245



61

39) Pigment Red 170 [cas no 2786-76-7 ]: -


p-Aminobenzamide2835-68-9 is Diazotized with HCL & Sodium Nitrite at 0 to 5 0C. Then

coupled with Naphthol AS PH92-74-0. Coupled mass is stirred till coupling reaction gets complete.

Then reaction mass is heated up to 75 to 80 0C & filtered. Filtrate is sent to ETP for further



a. Diazotization of p-Aminobenzamide

p-Aminobenzamide

C7H8N2 + 2HCI + NaNO2

Diazotization PAB Diazo

C7H6CIN3 + NaCI + 2 H2O

Mol.Wt. 136 + 73 + 69 183.5 + 58.5 + 36

b. Coupling with Naphthol AS PH

PAB Diazo + Naphthol AS PH +C.S. Flacks

C7H6CIN3 + C19H17NO3 + NaOH



Mol.Wt. 183.5 + 307 + 40 454 + 18 + 58.5


Sr.No. Input Qty.in

Kgs

Output Qty.in Kgs



3 p-Aminobenzamide 305 Water Evaporation in

Drying

3000



6 Naphthol AS PH 688

7 C.S. Flacks 200



62

40)Pigment Red 175 cas no6985-92-8 : -


Methyl-2-aminobenzoate [MAB cas no 134-20-3. ]is Diazotized with HCL & Sodium Nitrite at 0

to 5 0C. Then coupled with 2,3-dihydro-2-naphthylformamido Benzoimidazolone [DHNFBZ casa no.

26848-40-8

]. Coupled mass is stirred till coupling reaction gets complete. Then reaction mass is heated up to 75

to 80 0C & filtered. Filtrate is sent to ETP for further treatment. Then wet cake is washed with hot

water. washing water is reused in next batch for Diazo preparation. & wet cake is dried in spin flash


a. Diazotization of Methyl-2-aminobenzoate

MAB

C8H9NO2 + 2HCI + NaNO2

Diazotization MAB Diazo


Mol.Wt. 151+ 73 + 69 198.5 + 58.5 + 36

b. Coupling with DHNFBZ

MAB Diazo + DHNFBZ +C.S. Flacks

C8H7CIN2O2 + C18H13N3O3 + NaOH



Mol.Wt. 215.5 + 319 + 40 481 + 18 + 58.5


Sr.No. Input Qty.in

Kgs

Output Qty.in Kgs



3 Methyl-2-aminobenzoate 325 Water Evaporation in

Drying

3000



6 DHNFBZ 665

7 C.S. Flacks 200



63

41) Pigment Red 176 cas no 12225-06-8: -


Fast Red KD Base cas no. 120-35-4 is Diazotized with HCL & Sodium Nitrite at 0 to 5 0C. Then

coupled with 2,3-dihydro-2-naphthylformamido Benzoimidazolone [DHNFBZ cas no 26848-40-8].

Coupled mass is stirred till coupling reaction gets complete. Then reaction mass is heated up to 75




a. Diazotization of Fast Red KD Base

Fast Red KD


Diazotization Fast Red KD Diazo


Mol.Wt. 242 + 73 + 69 289.5 + 58.5 + 36

b. Coupling with DHNFBZ

Fast Red KD Diazo + DHNFBZ +C.S. Flacks

C14H12CIN3O2 + C18H13N3O3 + NaOH



Mol.Wt. 289.5 + 319 + 40 572 + 18 + 58.5


Sr.No. Input Qty.in

Kgs

Output Qty.in Kgs



3 Fast Red KD Base 445 Water Evaporation in

Drying

3000



6 DHNFBZ 565

7 C.S. Flacks 200



64

42) Pigment Red 177 [ CAS NO. 4051-63-2]: -


Bromamine Acid [cas no.116-81-4] is self-condensed in Poly Propylene Glycol as a solvent in

reflux condition with KOH & sodium chlorate at 125--1300C for 4-5 hrs till condensation reaction

gets complete. Then reaction mass is cooled up to 350C & isolated by Water. Then reaction mass is

filtered. filtrate is distilled for recovery of Poly Propylene Glycol for recycle & remaining mass sent to

ETP & MEE. Then wet cake is washed with hot water. washing water is reused in next batch for

isolation in next batch & wet cake is dried in spin flash dryer, pulverized & packed

a. Bromination: -

Anthraquinone 2KOH Sodium

Chlorate

C22H10O2 + 2KOH + NaCIO3


C28H16N2O4 + 2KBr +NaCI +H2O +O4

Mol.Wt. 306 + 2x 56 + 106 PPG 444.44 + 238 + 58.5 + 18 + 64


Sr.No. Input Qty.in

Kgs

Output Qty.in

Kgs

1 Poly Propylene Glycol 2500 PPG recovery 2250

2 Bromamine Acid 1100 Finish Product 1000

3 KOH 250 Water Evaporation in Drying 2500

4 Sodium Chlorate 50 Washing water for Re-Use 3150



7


65



Perylene Tetracarboxydianhydride [PTCDA cas no.128-69-8] is condensed with 2 mole of Para

amino Azobenzene [ PAAB cas no.60-09-3] in aqueous medium in reflux condition at 95--1000C for 4-

5 hrs till condensation reaction gets complete. Then reaction mass is cooled up to 350C by adding




a. Condensation of Perylene Tetracarboxydianhydride with Para Aminoazobenzene : -

PTCDA + PAAB

C24H8O6 + 2[C12H11N3]


C48H26N6O4 + 2H2O



Sr.No. Input Qty.in

Kgs

Output Qty.in

Kgs



3 PAAB 515 Washing water for Re-Use 3000




7


66



Perylene Tetracarboxydianhydride[ PTCDA cas no.128-69-8] is condensed with 2 mole of

Mono methyl amine [ MMA cas no.74-89-5] in aqueous medium in reflux condition at 95--1000C for





a. Condensation of Perylene Tetracarboxydianhydride with Mono methyl amine: -

PTCDA + MMA

C24H8O6 + 2[CH5N]


C26H14N2O4 + 2H2O



Sr.No. Input Qty.in

Kgs

Output Qty.in

Kgs



3 MMA 150 Washing water for Re-Use 3000


5 Acetic Acid 55




67

45) Pigment Red 188 cas no. 61847-48-1: -


4-Carbomethoxy-3-Amino, 2, 5 Dichloro Benzanilide [OPLA cas no.59673-82-4] is Diazotized with

HCL & Sodium Nitrite at 0 to 5 0C. Then coupled with Naphthol ASOL cas no.135-62-6. Coupled mass

is stirred till coupling reaction gets complete. Then reaction mass is heated up to 75 to 80 0C &



pulverized & packed

a. Diazotization of OPLA

OPLA

C15H12CIN2O3+ 2HCI + NaNO2

Diazotization OPLA Diazo

C15H10CI2N3O3 + NaCI + 2 H2O

Mol.Wt. 339 + 73 + 69 386.5 + 58.5 + 36

b. Coupling with Naphthol ASOL

OPLA Diazo + Naphthol ASOL +C.S. Flacks

C15H10CI2N3O3 + C18H15NO3 + NaOH


C33H24CI2N4O6+ H2O + NaCI

Mol.Wt. 386.5 + 293 + 40 643 + 18 + 58.5


Sr.No. Input Qty.in

Kgs

Output Qty.in Kgs



3 OPLA 555 Water Evaporation in

Drying

3000



6 Naphthol ASOS 445

7 C.S. Flacks 200



68



1. Dimethyl Succinosuccinate [DMSS CAS No.6289-46-9] is condensed with 2 moles of 4-Chloro

aniline [CAS No.106-47-8] in methanol under efflux condition to form 2,5-di(p-chloroanilino-

3,6-dihydroxy terephthalate [ DPCADHT].

2. Then resulting product is oxidised with resist salt to form 2,5-di-p-chloroanilino-terephthalic

acid dimethyl ester [DPCADHT dimethyl ester].

3. Then it is hydrolyzed in alkaline condition & aqueous medium to form 2,5-Bis-(p-Chloro

anilino) terephthalic acid [DPCADHT Acid CAS.No. 41680-76-6]

4. Then it is further cyclised in presence of Poly phosphoric acid then finally pigmentation is

done in presence of IBA/DMF as per Quinacridone as Pigment Red 202

1.Condensation of DMSS with p-Chloroaniline: -

DMSS + 2[p-Chloroaniline]

C10H12O6 + 2[C6H6CIN]

Condensation

DPCADHT

C22H20N2CI2O4 + 2H2O

Mol.Wt.228 + 2X[127.5] Methanol 447 + 36

2.Oxidation Of DPCADHT with Resist Salt: -

DPCADHT

C22H20N2CI2O4 + O2

Condensation

DPCADHT dimethyl ester

C22H18N2CI2O4 + H2O2


3.Hydrolysis of DPCADHT dimethyl ester:-

DPCADHT dimethyl ester

C22H18N2CI2O4 + 2NaOH +2HCL

Hydrolysis

DPCADHT Acid

C20H14CI2N2O4 + 2NaCI + 2CH3OH

Mol.Wt. 445 + 80 + 73 Methanol 417 + 117 + 64

4.Cyclisation of DPCADHT Acid with Poly Phosphoric Acid & Pigmentation to form Pigment Red

202:-

DPCADHT Acid Poly Phosphoric

acid

C20H14CI2N2O4 + H3PO4.P2O5

Cyclisation

Pigment Red 202 Triphosphoric Acid

monohydrate

C20H10CI2N2O2 + H5P3O10.H2O

Mol.Wt. 417 + 238 DMF /IBA 381 + 274

69


Sr.No. Input Qty.in

Kgs

Output Qty.in

Kgs


2 Dimethyl

Succinosuccinate


3 4-Chloroaniline 860 Methanol Recovery for Re-Use 5225


5 NaOH 275 Effluent to ETP 7710



8 DMF / IBA 7000




70



2 moles of p-Chloro Benzo nitrile [ PCBN cas no.623-03-0] is condensed with 1 mole of Di-

Isopropyl Succinate [ DIPS cas no.924-88-9] in Tetra Amyl Alcohol in reflux condition at 85-900C for


water for isolation. Then reaction mass is filtered.From filtrate, Tetra Amyl Alcohol & Methyl tetra

butyl ether[MTBE Methanol] which generated in reaction is recovered for Re-use &remaining is sent

to ETP & MEE. Then wet cake is washed with hot water. washing water is reused in next batch for

isolation in next batch & wet cake is dried in spin flash dryer, pulverized & packed

a. Condensation of p-Chloro Benzo nitrile with Di-Isopropyl Succinate: -

2 [PCBN] + DIPS

2[C7H4NCI + C10H18O4

Condensation Pigment Red 254 + MTBE

Methanol

C18H10CI2N2O2 + C6H16O2

Mol.Wt.2 [ 137.5 ] + 202 Tetraamyl Alcohol

+KOH

357 + 120


Sr.No. Input Qty.in

Kgs

Output Qty.in

Kgs

1 Tetra Amyl alcohol 3800 Finish Product 1000

2 PCBN 810 Water Evaporation in Drying 1995

3 KOH 180 Tetra Amyl Alcohol Recovery for re-

Use

3610

4 DIPS 411 MTBE Methanol Recovery for re-Use 600

5 Water for Isolation 3000 Washing water for Re-Use 3000

6 Water for Washing 3000 Effluent to ETP 1000

7


71

48) Pigment Red 256 [ CAS no.79102-65-1.]: -


2-Amino-2,5-dichloro-N-N-dimethylbenenesulphonazamide [ ADCDMBSA CAS NO. 26175-68-8]

is Diazotized with HCL & Sodium Nitrite at 0 to 5 0C. Then coupled with Naphthol ASOL [ CAS NO.

135-62-6 ] Coupled mass is stirred till coupling reaction gets complete. Then reaction mass is heated

up to 75 to 80 0C & filtered. Filtrate is sent to ETP for further treatment. Then wet cake is washed

with hot water. washing water is reused in next batch for Diazo preparation. & wet cake is dried in

spin flash dryer, pulverized & packed

a. Diazotization of ADCDMBSA

ADCDMBSA

C8H10CI2N2O2S + 2HCI + NaNO2

Diazotization ADCDMBSA Diazo


Mol.Wt. 269 + 73 + 69 316.5 + 58.5 + 36

b. Coupling with Naphthol ASOL

ADCDMBSA Diazo + Naphthol ASOL +C.S. Flacks

C8H8CI3N3O2S + C18H15NO3 + NaOH


C26H22CI2N4O5S+ H2O + NaCI

Mol.Wt. 316.5 + 277 + 40 573 + 18 + 58.5


Sr.No. Input Qty.in

Kgs

Output Qty.in Kgs



3 AMSBA 518 Water Evaporation in

Drying

3000



6 Naphthol ASRL 492

7 C.S. Flacks 200



72



2 moles of 4-Phenylbenzonitrile [ PPBN cas no.2920-38-9] is condensed with 1 mole of Di-

Isopropyl Succinate [ DIPS cas no.924-88-9] in Tetra Amyl Alcohol in reflux condition at 85-900C for


water for isolation. Then reaction mass is filtered.From filtrate, Tetra Amyl Alcohol & Methyl tetra

butyl ether [MTBE Methanol] which generated in reaction is recovered for Re-use &remaining is

sent to ETP & MEE. Then wet cake is washed with hot water. washing water is reused in next batch

for isolation in next batch & wet cake is dried in spin flash dryer, pulverized & packed

a. Condensation of 4-Phenylbenzonitrile with Di-Isopropyl Succinate: -

2 [PPBN] + DIPS

2[C13H9NC I + C10H18O4

Condensation Pigment Red 264 + MTBE

Methanol

C30H20N2O2 + C6H16O2

Mol.Wt.2 [ 179 ] + 202 Tetraamyl Alcohol

+KOH

440 + 120


Sr.No. Input Qty.in

Kgs

Output Qty.in

Kgs

1 Tetra Amyl alcohol 3800 Finish Product 1000

2 PPBN 835 Water Evaporation in Drying 2030

3 KOH 180 Tetra Amyl Alcohol Recovery for re-

Use

3610

4 DIPS 425 MTBE Methanol Recovery for re-Use 600

5 Water for Isolation 3000 Washing water for Re-Use 3000


7


73

2 Pigment Yellow Quantity per Month = 200 MT per Month

50) Pigment Yellow 1 [CAS NO.2512-29-0]: -


xis Diazotized with HCL & Sodium Nitrite at 0 to 5 0C. Then coupled with Acetoacetanilide

[AAA cas no.102-01-2]. Coupled mass is stirred till coupling reaction gets complete. Then reaction

mass is heated up to 60 to 65 0C& filtered. Filtrate is sent to ETP for further treatment. Then wet

cake is washed with hot water. Washing water is reused in next batch for Diazo preparation. & wet

cake is dried in spin flash dryer, pulverized & packed

a. Diazotization of MNPT

MNPT

C7 H8 N2O2 + 2HCI + NaNO2

Diazotization MNPT Diazo

C7 H6 N3CIO2 + NaCI + 2 H2O

Mol.Wt. 152 + 73 + 69 199.5 + 58.5 + 36

b. Coupling with Acetoacetanilide

MNPT Diazo + Acetoacetanilide

+C.S.Flacks

C7 H6 N3CIO2 + C10 H11 NO2 +NaOH

Coupling Pigment Yellow 1

C17 H16 N4 O4 + H2O + NaCI

Mol.Wt. 199.5 + 177 + 40 340 + 18 + 58.5





3 MNPT 450 Water Evaporation in Drying 3000



6 Acetoacetanilide 510

7 C.S.Flacks 200



74

51) Pigment Yellow 3 [ CAS NO. 6486-23-3 ] :-


P-Chloro, O-nitro Aniline [PCONA cas no.89-63-4] is Diazotized with HCL & Sodium Nitrite at 0

to 5 0C. Then coupled with AAOCA [cas no.93-70-9]. Coupled mass is stirred till coupling reaction

gets complete. Then reaction mass is heated up to 60 to 65 0C& filtered. Filtrate is sent to ETP for

further treatment. Then wet cake is washed with hot water. washing water is reused in next batch

for Diazo preparation. & wet cake is dried in spin flash dryer, pulverized & packed


PCONA

C6 H5 N2O2.CI + 2HCI + NaNO2


C6 H3 N3CI2O2 + NaCI + 2 H2O

Mol.Wt. 172.5 + 73 + 69 220 + 58.5 + 36

b. Coupling with AAOCA

PCONA Diazo + AAOCA + C.S.Flacks

C6 H3 N3CI2O2 + C10 H10CINO2 + NaOH


C16 H12 N4 O4.CI2 + H2O + NaCI

Mol.Wt. 220 + 211.5 + 40 395 + 18 + 58.5





3 PCONA 410 Water Evaporation in Drying 3000



6 AAOCA 510

7 C.S.Flacks 200



75

52) Pigment Yellow 12 [ cas no.6358-85-6]:-


3,3-Dichlorobenzidine [3,3-DCB cas no.91-94-1] is double Diazotized with HCL & Sodium Nitrite at 0

to 5 0C. Then coupled with 2 mole Acetoacetanilide[ cas no.102-01-2]. Coupled mass is stirred till

coupling reaction gets complete. Then reaction mass is heated up to 60 to 65 0C& filtered. Filtrate is

sent to ETP for further treatment. Then wet cake is washed with hot water. washing water is reused

in next batch for Diazo preparation. & wet cake is dried in spin flash dryer, pulverized & packed


3,3-DCB

C12 H10 N2CI2 + 4HCI + 2NaNO2


C12 H6 N4CI4 + 2NaCI + 4 H2O

Mol.Wt. 253 + 146 + 138 348 + 117 +72

b. Coupling with AAA

3,3-DCB Diazo + 2 [AAA] + C.S. Flacks

C12 H6 N4CI4+ 2[C10 H11 NO2 +2NaOH


C32 H26CI2N6 O4+ 2H2O + 2NaCI

Mol.Wt. 348 + 354 +80 629 + 36 + 117








6 AAA 730

7 C.S. Flacks 190



76

53) Pigment Yellow 13 [cas no.5102-83-0]:-


3,3-Dichlorobenzidine [3,3-DCB cas no.91-94-1] is double Diazotized with HCL & Sodium Nitrite at 0

to 5 0C. Then coupled with 2 mole Acetoacet Meta Xylidin [ AAMX cas no.97-36-9]. Coupled mass is

stirred till coupling reaction gets complete. Then reaction mass is heated up to 60 to 65 0C& filtered.



packed


3,3-DCB



C12 H6 N4CI4 + 2NaCI + 4 H2O

Mol.Wt. 253+ 146 + 138 348 + 117 + 72

b. Coupling with AAMX

3,3-DCB Diazo + 2 [AAMX] + C.S. Flacks

C12 H6 N4CI4+ 2[C12 H15 NO2+2NaOH



Mol.Wt. 348 + 410 +80 685 + 36 + 117








6 AAMX 715

7 C.S.Flacks 200



77



3,3-Dichlorobenzidine [3,3-DCB 91-94-1] is double Diazotized with HCL & Sodium Nitrite at 0 to 5 0C.

Then coupled with 2 mole O-Acetoacetotoluidine [ AAOT cas no.93-68-5]. Coupled mass is stirred

till coupling reaction gets complete. Then reaction mass is heated up to 60 to 65 0C& filtered.



packed


3,3-DCB



C12 H6 N4CI4 + 2NaCI + 4 H2O

Mol.Wt. 253 + 146 + 138 348 + 117 + 72

b. Coupling with AAOT

3,3-DCB Diazo + 2 [AAOT] + C.S. Flacks

C12 H6 N4CI4+ 2[C11 H13 NO2 + 2NaOH



Mol.Wt. 348 + 410 +80 685 + 36 + 117








6 AAOT 715

7 C.S.Flacks 200



78



2 Mole 2,4-Dichloroaniline [ cas no.554-00-7]is Diazotized with HCL & Sodium Nitrite at 0 to 5 0C.

Then coupled with Naphthol ASIRG[ cas no.4433-79-8]. Coupled mass is stirred till coupling reaction




a. Diazotization of 2,4-DCA

2,4-DCA

2[C6 H5 NCI2] + 4HCI + 2NaNO2

Diazotization 2,4-DCA Diazo

C12 H6 N4CI6 + 2NaCI + 4 H2O

Mol.Wt. 324 + 146 + 138 419 + 117 + 72

b. Coupling with Naphthol ASIRG

2,4-DCA Diazo+ Naphthol ASIRG+C.S.

Flacks

C12 H6 N4CI6 + C22 H24 N2O4 +2NaOH



Mol.Wt. 419 + 380 +80 726 + 36 + 117





3 2,4-DCA 650 Water Evaporation in Drying 3000



6 Naphthol ASIRG 425

7 C.S.Flacks 200



79

56) Pigment Yellow 17 [cas no.4531-49-1:-


3,3-Dichloro Benzidine [3,3-DCB cas no.91-94-1] is double Diazotized with HCL & Sodium Nitrite at

0 to 5 0C. Then coupled with 2 mol of O-Acetoacetanilide[ cas no.92-15-9]. Coupled mass is stirred

till coupling reaction gets complete. Then reaction mass is heated up to 60 to 65 0C& filtered.



packed


3,3-DCB



C12 H6 N4CI4 + 2NaCI + 4 H2O

Mol.Wt. 253+ 146 + 138 348 + 117 + 72

b. Coupling with O-Acetoacetanilide

3-3-DCB Diazo+ O-AA +C.S. Flacks

C12 H6 N4CI4 + [C11 H13 NO3 +2NaOH


C34 H30CI2N6 O6 + 2H2O + 2NaCI

Mol.Wt. 348 + 207 +80 689 + 36 + 117








6 OAA 625

7 C.S.Flacks 200



80

57)Pigment Yellow 61[ cas no.12286-65-6]:-


O-Nitro Aniline PSA [ ONAPSA cas no.616-84-2] is Diazotized with HCL & Sodium Nitrite at 0 to

5 0C. Then coupled with AAA[cas no.102-01-2]. Coupled mass is stirred till coupling reaction gets

complete. Then in reaction mass, Calcium Chloride is added & is heated up to 75 to 80 0C to form

Calcium Salt& filtered. Filtrate is sent to ETP for further treatment. Then wet cake is washed with

hot water. washing water is reused in next batch for Diazo preparation. & wet cake is dried in spin


a. Diazotization of ONAPSA

ONAPSA

C6 H6 N2O5S + 2HCI + NaNO2

Diazotization ONAPSA Diazo

C6 H4 N3O5SCI + NaCI + 2 H2O

Mol.Wt. 218 + 73 + 69 265.5 + 58.5 + 36

b. Coupling with AAA

ONAPSA Diazo+ AAA +C.S.Flacks

C6H4N3O5SCI +C10H11NO2+2XNaOH +1/2CaCI2



Mol.Wt. 265.5 + 177 + 80 + 55 424.5 + 36 + 117





3 ONAPSA 450 Water Evaporation in Drying 3000



6 AAA 510

7 C.S.Flacks 200




81



O-Nitro Aniline PSA [ ONAPSA cas no.616-84-2] is Diazotized with HCL & Sodium Nitrite at 0 to

5 0C. Then coupled with AAOT[ cas no.93-68-5]. Coupled mass is stirred till coupling reaction gets

complete. Then in reaction mass, Calcium Chloride is added & is heated up to 75 to 80 0C to form

Calcium Salt & filtered. Filtrate is sent to ETP for further treatment. Then wet cake is washed with

hot water. washing water is reused in next batch for Diazo preparation. & wet cake is dried in spin


a. Diazotization of ONAPSA

ONAPSA

C6 H6 N2O5S + 2HCI + NaNO2

Diazotization ONAPSA Diazo

C6 H4 N3O5SCI + NaCI + 2 H2O

Mol.Wt. 218 + 73 + 69 265.5 + 58.5 + 36

b. Coupling with AAOT

ONAPSA Diazo+ AAOT +C.S.Flacks

C6H4N3O5SCI +C11H13NO2 +2XNaOH +1/2CaCI2



Mol.Wt. 265.5+ 191 + 80 + 55 439.5 + 36 + 117





3 ONAPSA 450 Water Evaporation in Drying 3000



6 AAOT 500

7 C.S.Flacks 200




82



3,3-Dichloro Benzidine [3,3-DCB cas no.91-94-1] is double Diazotized with HCL & Sodium Nitrite at 0

to 5 0C. Then coupled with 2 mol of AAOCA[ 93-70-9]. Coupled mass is stirred till coupling reaction





3,3-DCB



C12 H6 N4CI4 + 2NaCI + 4 H2O

Mol.Wt. 253+ 146 + 138 348 + 117 + 72

b. Coupling with AAOCA

3-3-DCB Diazo+ AAOCA + C.S. Flacks

C12 H6 N4CI4+ 2[C10H10NO2CI ]+ 2NaOH


C32H24CI4N6 O4 + 2H2O + 2NaCI

Mol.Wt. 348 + 2 X 211.5 + 80 698 + 36 + 117








6 AAOCA 685

7 C.S.Flacks 200



83



M-Nitro P-Methoxy Aniline [MNPA cas no.96-96-8] is Diazotized with HCL & Sodium

Nitrite at 0 to 5 0C. Then coupled with Acetoacet-2-anisidide[AAOA cas no.92-15-9]. Coupled

mass is stirred till coupling reaction gets complete. Then reaction massis heated up to 75 to

80 0C to form Calcium Salt& filtered. Filtrate is sent to ETP for further treatment. Then wet

cake is washed with hot water. washing water is reused in next batch for Diazo preparation.

& wet cake is dried in spin flash dryer, pulverized & packed

a. Diazotization of MNPA

b. Coupling with AAOA





3 MNPA 440 Water Evaporation in Drying 3000



6 AAOA 510

7 C.S.Flacks 200




MNPA


Diazotization MNPA Diazo

C7H6N3O3CI + NaCI + 2 H2O

Mol.Wt. 168 + 73 + 69 215.5 + 58.5 + 36

ONAPSA Diazo+ AAOA + C.S.Flacks

C7H6N3O3CI + C11H13NO3 +NaOH



Mol.Wt. 215.5 + 207 + 40

386 + 18 + 58.5

84



P-Chloro O-Nitro Aniline [ PCONA cas no.89-63-4] is Diazotized with HCL & Sodium Nitrite at 0

to 5 0C. Then coupled with Acetoacet-2-Anisidine [ AAOA cas no. 92-15-9]. Coupled mass is stirred

till coupling reaction gets complete. Then in reaction mass is heated up to 75 to 80 0C & filtered.



packed


PCONA

C6 H5N2O5CI + 2HCI + NaNO2


C6 H3 N3O5CI2 + NaCI + 2 H2O

Mol.Wt. 172.5 + 73 + 69 220 + 58.5 + 36


PCONA Diazo+ AAOA +C.S.Flacks

C6H3N3O5CI2 + C11H13NO3 +NaOH


C17H15N4O5CI + H2O + NaCI

Mol.Wt. 220 + 207 + 40 390.5 + 18 + 58.5








6 AAOA 510

7 C.S.Flacks 200




85



2-Methoxy, -4-Nitroaniline [ MNOA cas no.97-52-9] is Diazotized with HCL & Sodium Nitrite at

0 to 5 0C. Then coupled with Acetoacet-2-Anisidine [ AAOA cas no. 92-15-9]. Coupled mass is stirred




packed

a. Diazotization of MNOA

MNOA


Diazotization MNOA Diazo


Mol.Wt. 168 + 73 + 69 215.5 + 58.5 + 36


MNOA Diazo + AAOA +C.S.Flacks

C7H3N3O3CI + C11H13NO3 +NaOH



Mol.Wt. 215.5 + 207 + 40 386 + 18 + 58.5





3 MNOA 465 Water Evaporation in Drying 3000



6 AAOA 515

7 C.S.Flacks 200




86

63) Pigment Yellow 83 cas no.5567-15-7:-


3,3-Dichloro Benzidine [3,3-DCB c91-94-1 ]as no.] is double Diazotized with HCL & Sodium Nitrite at

0 to 5 0C. Then coupled with 2 mol of AADMCA cas no.4433-79-8. Coupled mass is stirred till





3,3-DCB



C12 H6 N4CI4 + 2NaCI + 4 H2O

Mol.Wt 253 + 146 + 138 348 + 117 + 72

b. Coupling with AADMCA

3-3-DCB Diazo+ AADMCA + C.S. Flacks

C12 H6 N4CI4+ 2[C12H14NO4CI ]+ 2NaOH


C36H32CI4N6 O+ 2H2O + 2NaCI

Mol.Wt. 348 + 2 X 271.5 +80 818 + 36 + 117








6 AADMCA 685

7 C.S.Flacks 200



87

64) Pigment Yellow 93 cas no5580-57-4:-


3-Amino-4-chloro-N-(3-chloro-2-methylphenyl) Benzamide is Diazotized with HCL & Sodium

Nitrite at 0 to 5 0C. Then coupled with N, N-(2-chloro-5-methylbenzene-1,4-diyl) bis(3-

oxobutanamide). Coupled mass is stirred till coupling reaction gets complete. Then reaction mass is

heated up to 75 to 80 0C & filtered. Filtrate is sent to ETP for further treatment. Then wet cake is



a. Diazotization of OAPC

OAPC

C14H12N2OCI2+ 2HCI + NaNO2

Diazotization OAPCDiazo

C14H10N3OCI3 + NaCI + 2 H2O

Mol.Wt. 295 + 73 + 69 342.5 + 58.5 + 36

b. Coupling with N,N-CMBT

OACP Diazo+ N,N-CMBT +C.S.Flacks

2[C14H10N3OCI3] + C15H17N2CIO4 +NaOH


C43H35N8O6CI5 + 2H2O + 2NaCI

Mol.Wt. 685 + 324 + 80 937.5 + 36 + 117





3 OAPC 620 Water Evaporation in Drying 3000



6 NN-CMBT 340

7 C.S. Flacks 335



88

65) Pigment Yellow 97 cas no.12225-18-2: -


2,5-Dimethoxyaniline-4-Sulphoanilide [DMASA cas no. is Diazotized with HCL & Sodium

Nitrite at 0 to 5 0C. Then coupled with NAPTHOL AS-IRG cas no.4433-79-8].Coupled mass is stirred




packed

a. Diazotization of DMASA

DMASA

C14H16N2O4S + 2HCI + NaNO2

Diazotization DMASA Diazo

C14H14N3O4CIS + NaCI + 2 H2O

Mol.Wt. 308 + 73 + 69 355.5 + 58.5 + 36

b. Coupling with NAPTHOL AS-IRG

DMASA Diazo+ NAPTHOL AS-IRG +C.S.Flacks

C14H14N3O4CIS + C12H14ClNO4+NaOH


C26H27N4O8SCI + H2O + NaCI

Mol.Wt. 355.5 + 271.5 + 40 591 + 18 + 58.5





3 DMASA 470 Water Evaporation in Drying 3000



6 NAPTHOL AS-IRG 515

7 C.S.Flacks 200




89

66) Pigment Yellow 101 [ CAS No.: 2387-03-3]


2-hydroxynaphthalene-1-carbaldehyde and dihydrazine sulfate are suspended in water and

methanol at room temperature. Stir it for 1 hour and then heat it to reflux temperature. Maintain

reflux for 5 hours. Cool for filtration.Filter the pigment slurry and wash with water up to salt

free.Filtrate sent to solvent recovery and wash water are sent to ETP.Wet cake is then dried and

pulverized and then sent to packaging.

Chemical Reaction:

2-hydroxynaphthalene-1-carbaldehyde

and dihydrazine sulfate + dihydrazine

sulfate +

C11H8O2 + H10N4O4S

Condensate Pigment Yellow 101

C22H16N2O2 + H2O + H2SO4 + 2NH2

Mol.Wt.( 2 x 172) + 162 340 + 18 + 116 + 32


Sr.No. Input Qty.in

Kgs

Output Qty.in

Kgs

1 2-hydroxynaphthalene-1-

carbaldehyde

1052 Finished Product 1000

2 Dihydrazine 90 Methanol Recovery 3600

3 Methanol 4000 Aqueous Effluent to ETP 2522

4 Water 3500 Drying Loss 1520


90

67) Pigment Yellow 120 [ cas no.29920-31-8]: -


5-Aminoisophthalic acid dimethyl ester [5-AIPA-DME cas no.99-27-4]is Diazotized with HCL &

Sodium Nitrite at 0 to 5 0C. Then coupled with 5-Acetylacetamino Benzoimidazolone[AABI cas

no.26576-46-5]. Coupled mass is stirred till coupling reaction gets complete. Then in reaction mass

is heated up to 75 to 80 0C & treated with Aluminum Hydroxide to form Aluminum Salt & filtered.



packed

a. Diazotization of 5-AIPA-DME

5-AIPA-DME


Diazotization 5-AIPA-DME Diazo


Mol.Wt. 209 + 73 + 69 256.5 + 58.5+ 36

b. Coupling with AABI

5-AIPA-DME Diazo + AABI +C.S. Flacks

C10H8N2O4CI + C11H11N3O3 +NaOH



Mol.Wt. 256.5 + 233 + 40 453 + 18 + 58.5





3 5-AIPA-DME 490 Water Evaporation in Drying 3000



6 AABI 510

7 C.S. Flacks 220

8 Aluminum Hydroxide 135



91

68) Pigment Yellow 121 [ cas no. 61968-85-2]:-


3,3-Dichloro Benzidine [3,3-DCB cas no.] is double Diazotized with HCL & Sodium Nitrite at 0 to 5 0C.

Then coupled with 2,4-Dimethylacetanilide [ AAMX cas no.97-36-9] . Coupled mass is stirred till





3,3-DCB



C12 H6 N4CI4 + 2NaCI + 4 H2O

Mol.Wt. 253 +146 + 138 348 + 117 + 72

b. Coupling with AAMX

3-3-DCB Diazo + AAMX + C.S. Flacks

C12H6N4CI4 +2[C12H15NO2] + 2NaOH


C34H29CI3N6O4 + 2H2O + 2NaCI

Mol.Wt. 348 +2 X 205 +80 691 + 36 + 117








6 AAMX 625

7 C.S. Flacks 200



92

69) Pigment Yellow 138 [ CAS NO.30125-47-4]: -


2 moles of Tetrachloro Phthalic Anhydride [TCPA CAS No.117-08-8] & 8-amino Quinaldine

[CAS No.18978-78-4] is condensed in the presence of ODCB or Xylene & Benzoic Acid in reflux

condition at 140-142 0C& removing water from separator during reaction for 4-5 hrs till

condensation reaction gets complete. Then reaction mass is cooled up to 350C by adding water &

methanol for isolation. Then ODCB / Xylene is distilled out for recycle in next batch & remaining

mass is filtered. From Filtrate, methanol is again distilled out for recycle in next batch & remaining

filtrate is sent to ETP & MEE. Then wet cake is washed with hot water. washing water is reused in

next batch for isolation in next batch & wet cake is dried in spin flash dryer, pulverized & packed

a. Condensation of Tetrachloro Phthalic Anhydride with 8-amino Quinaldine

TCPA 8-amino Quinaldine

2 x [C8CI4O3] + C10H10N2

Condensation Pigment Yellow 138

C22H6CI8N2O2 + 2H2O + C4 H 4 O 3

Mol.Wt. 2X 286 + 158 ODCB/Xylene Benzoic Acid 641 + 36 + 53


Sr.No. Input Qty.in

Kgs

Output Qty.in

Kgs

1 ODCB / Xylene 3000 Finish Product 1000

2 Tetrachloro Phthalic

Anhydride


3 8-amino Quinaldine 275 ODCB / Xylene Recovery for Re-Use 2850

4 Benzoic Acid 30 Methanol Recovery for Re-use 950

5 Methanol 1000 Washing water for Re-Use 3000

6 Water for Isolation 2000 Effluent to ETP 1755



93

70) Pigment Yellow 139 [ CAS NO.36888-99-0]: -


1,2-Dicyanobenzene /Phthalonitrile [ CAS No.91-15-6] is condensed with 2 Mole of Barbituric

acid [CAS No.67-52-7] in aqueous media with HCI in reflux condition for 4-5 hrs till condensation

reaction gets complete. Then reaction mass is cooled up to 350C by adding water for isolation. Then

mass is filtered. Filtrate is send in ETP for further treatment & recovery of Ammonium Chloride in

MEE. Then wet cake is washed with hot water. washing water is reused in next batch for isolation in

next batch & wet cake is dried in spin flash dryer, pulverized & packed

a. Condensation of Phthalonitrile with Barbituric Acid

Phthalonitrile 2[Barbituric acid]

C8H4O2+ 2[ C4H4N2O3] + HCI

Condensation Pigment Yellow 139

C16H9N5O6 + NH4CI

Mol.Wt. 128 2 x 128 + 36.5 HCL/Water 367 + 53.5


Sr.No. Input Qty.in

Kgs

Output Qty.in

Kgs


2 Phthalonitrile 350 Water Evaporation in Drying 2000

3 Barbituric acid 700 Effluent to ETP for Ammonium

Chloride recovery

1225

4 HCL 175 Washing water for Re-Use 3000



94

71) Pigment Yellow 151[cas no.31837-42-0]: -


Anthranillic acid[cas no.118-92-3] is Diazotized with HCL & Sodium Nitrite at 0 to 5 0C. Then

coupled with 5-Acetylacetamino Benzoimidazolone[AABI cas no. 26576-46-5]. Coupled mass is

stirred till coupling reaction gets complete. Then in reaction mass is heated up to 75 to 80 0C &



pulverized & packed

a. Diazotization of Anthranillic Acid

Anthranillic acid


Diazotization Anthranillic acid Diazo


Mol.Wt. 137 + 73 + 69 184.5 + 58.5 + 36


Anthranillic acid Diazo + AABI +C.S. Flacks




Mol.Wt. 184.5 + 233 + 40 381 + 18 + 58.5





3 Anthranillic Acid 490 Water Evaporation in Drying 3000



6 AABI 510

7 C.S. Flacks 220




95

72) Pigment Yellow 153 [ cas no. 29204-84-0 ]: -

2,3-Dinitroso-n-phenylbutanamide [cas No.N.A,] is metalized with Nickel Chloride in aqueous media

& is heated up to 95 to 100 0C to form Nickel Salt& filtered. Filtrate is sent to ETP for further

treatment. Then wet cake is washed with hot water. washing water is reused in next batch. & wet


a. Metallization of 2,3-Dinitroso-n-phenylbutanamide

DNPBN

2[C10H11N3O3] +NiCI2 + 2NaOH

Metallization Pigment Yellow 153

C20H20N6NiO6 + 2NaCI + 2H2O

Mol.Wt. 2 x221 + 129.5 + 80 499.5 + 117 + 36



1 Recycled Water 3000 Pigment Yellow 153 1000

2 2,3-Dinitroso-n-

phenylbutanamide

775 Drying Loss 3175

3 C.S. Flacks 200 Washing water for Re-Use 3000

4 Nickel Chloride 200



96

73) Pigment Yellow 154 [cas no.68134-22-5]: -


2-Aminotriflurotoluene [ ATFT cas no.88-17-5] is Diazotized with HCL & Sodium Nitrite at 0 to 5 0C. Then coupled with 5-Acetylacetamino Benzoimidazolone [AABI cas no.26576-46-5]. Coupled

mass is stirred till coupling reaction gets complete. Then in reaction mass is heated up to 75 to 80 0C

& filtered. Filtrate is sent to ETP for further treatment. Then wet cake is washed with hot water.


pulverized & packed

a. Diazotization of ATFT

ATFT

C7H6NF3 + 2HCI + NaNO2

Diazotization ATFT Diazo

C7H4N2F3CI + NaCI + 2 H2O

Mol.Wt. 161 + 73 + 69 208.5 + 58.5 + 36


ATFT Diazo + AABI +C.S. Flacks

C7H4N2F3CI + C11H11N3O3 +NaOH


C18H14N5F3O3 + H2O + NaCI

Mol.Wt. 208.5 + 233 + 40 405 + 18 + 58.5





3 ATFT 490 Water Evaporation in Drying 3000



6 AABI 510

7 C.S. Flacks 220




97

74) Pigment Yellow 155[ cas no.68516-73-4]: -


2 Mol of 2-Amino, Dimethyl Terephthalate [ ADMT cas no.5372-81-6] is Diazotized with HCL &

Sodium Nitrite at 0 to 5 0C. Then coupled with N,N-Diacetoacetyl-p-Diamino Benzene [ DAPDAB cas

no.25731-73-5 ].Coupled mass is stirred till coupling reaction gets complete. Then in reaction mass

is heated up to 75 to 80 0C & filtered. Filtrate is sent to ETP for further treatment. Then wet cake is



a. Diazotization of ADMT

ADMT

2[C10H11NO4] +4HCI + 2NaNO2

Diazotization ADMT Diazo

C20H18N4O8CI2 + 2NaCI + 4H2O

Mol.Wt. 418 + 146 + 138 513 + 117 + 72

b. Coupling with DAPDAB

ADMT Diazo + DAPDAB +C.S. Flacks

C20H18N4O8CI2 + C14H16N2O4 +2NaOH


C34H32N6O12 + 2H2O + 2NaCI

Mol.Wt. 513 + 276 + 80 716 + 36 + 117





3 ADMT 615 Water Evaporation in Drying 3000



6 DAPDAB 400

7 C.S. Flacks 240



98

75) Pigment Yellow 174 [cas no. 78952-72-4]:-


Pigment yellow 13 & Pigment Yellow 14 is mixed 50% each in Blender & Packed



1 Pigment yellow 13 500 Effluent to ETP Nil

2 ICE Pigment Yellow 14 500 Washing water for Re-Use Nil

TOTAL 1000 TOTAL

99

76) Pigment Yellow 180[CAS NO. 77804-81-0]:


2-[Ethylene Dioxy] Dianiline [2-EDDA cas no.52411-34-4] is double Diazotized with HCL &

Sodium Nitrite at 0 to 5 0C. Then coupled with 2 mole 5-Aetoacetamino Benzoimidazolone [AABI cas

no.26576-46-5]. Coupled mass is stirred till coupling reaction gets complete. Then reaction mass is

heated up to 60 to 65 0C& filtered. Filtrate is sent to ETP for further treatment. Then wet cake is



a. Diazotization of 2-EDDA

2-EDDA

C14 H16 N2O2+ 4HCI + 2NaNO2

Diazotization 2-EDDA Diazo

C14 H12N4CI2O2+ 2NaCI + 4 H2O

Mol.Wt. 244+ 146 + 138 339 + 117 + 72


2-EDDADiazo + AABI + C.S. Flacks

C14 H12N4CI2O2 +2[C11H11N3O3] + 2NaOH


C36H32N10O8+ 2H2O + 2NaCI

Mol.Wt. 339 + 466 +80 732 + 36 + 117





3 2-EDDA 380 Water Evaporation in Drying 3000



6 AABI 600

7 C.S.Flacks 200



100

77) Pigment Yellow 181[cas no.: 74441-05-7] -


Para Amino Benzoyl Benzamide [PABB cas no.74441-06-8]is Diazotized with HCL & Sodium Nitrite

at 0 to 5 0C. Then coupled with 5-Acetoacetylylamino Benzoimidazolone[AABI]. Coupled mass is

stirred till coupling reaction gets complete. Then in reaction mass is heated up to 75 to 80 0C &



pulverized & packed

a. Diazotization of PABB

PABB


Diazotization PABB Diazo


Mol.Wt. 255+ 73 + 69 302.5 + 58.5 + 36


PABB Diazo + AABI +C.S. Flacks




Mol.Wt. 302.5 + 233 + 40 499 + 18 + 58.5





3 PABB 490 Water Evaporation in Drying 3000



6 AABI 510

7 C.S. Flacks 220




101

78) Pigment Yellow 182 [ CAS NO. 67906-31-4]: -


2-amino-diethyl terephthalate [ADMT cas no.27210-70-4]is Diazotized with HCL & Sodium Nitrite

at 0 to 5 0C. Then coupled with N-[acetoacetyl-6-methoxy-7-amino-quinoxaline,2,3-dione [AAMAQ].

Coupled mass is stirred till coupling reaction gets complete. Then in reaction mass is heated up to 75




a. Diazotization of ADMT

ADMT


Diazotization ADMT Diazo


Mol.Wt. 209 + 73 + 69 256.5 + 58.5 + 36

b. Coupling with AAMAQ

ADMT Diazo + AAMAQ +C.S. Flacks




Mol.Wt. 256.5 + 275 + 40 496 + 18 + 58.5





3 ADMT 490 Water Evaporation in Drying 3000



6 AAMAQ 510

7 C.S. Flacks 220




102



3,4-Dichloroaniline,6-sulphonic Acid [ DCASA cas no.6331-96-0] is Diazotized with HCL &

Sodium Nitrite at 0 to 5 0C. Then coupled with 1,3-Sulphophenyl-3-methyl Pyrazolone [1,3-SPMP cas

no.119-17-5

]. Coupled mass is stirred till coupling reaction gets complete. Then in reaction mass, Calcium

Chloride is added & is heated up to 75 to 80 0C to form Calcium Salt& filtered. Filtrate is sent to ETP

for further treatment. Then wet cake is washed with hot water. washing water is reused in next


a. Diazotization of DCASA

DCASA

C6 H5CI2NO3S + 2HCI + NaNO2

Diazotization DCASA Diazo


Mol.Wt. 242 + 73 + 69 289.5 + 58.5 + 36

b. Coupling with 1,3-PMP

DCASA Diazo+ 1,3-SPMP +C.S.Flacks

C6H3CI3N2O3S + C10H10N2O4S+2XNaOH

+1/2CaCI2


C16H12N4O7S2.Ca + 2H2O + 2NaCI

Mol.Wt. 289.5 + 254 + 80 + 55 545 + 36 + 117





3 DCASA 460 Water Evaporation in Drying 3000



6 1,3-SPMP 490

7 C.S.Flacks 200




103

80) Pigment Yellow 191 cas no. 129423-54-7 : -


2B Acid cas no.88-51-7, is Diazotized with HCL & Sodium Nitrite at 0 to 5 0C. Then coupled with

1,3- SPMP cas no.119-17-5. Coupled mass is stirred till coupling reaction gets complete. Then in




pulverized & packed


2B Acid




Mol.Wt. 221.5 + 73 + 69 269 + 58.5 + 36

b. Coupling with 1,3-SPMP

2B Acid Diazo+ 1,3-SPMP +C.S. Flacks

C7H6CI2N2O3S +C10H10N2O4S +2XNaOH +1/2CaCI2


C17H14CIN4O7S2.Ca + 2H2O + 2NaCI

Mol.Wt. 269 + 254 + 80 + 55 505.5 +36 + 117








6 1,3-SPMP 495

7 C.S. Flacks 200




104

81) Pigment Yellow 191:1[CAS NO.: 154946-66-4] : -


2B Acid is Diazotized with HCL & Sodium Nitrite at 0 to 5 0C. Then coupled with 1,3- SPMP.

Coupled mass is stirred till coupling reaction gets complete. Then in reaction mass, Ammonium

Chloride is added & is heated up to 75 to 80 0C to form Ammonium Salt & filtered. Filtrate is sent to

ETP for further treatment. Then wet cake is washed with hot water. washing water is reused in next



2B Acid




Mol.Wt. 221.5 + 73 + 69 269 + 58.5 + 36

b. Coupling with 1,3-SPMP

2B Acid Diazo+ 1,3-SPMP +C.S. Flacks

C7H6CI2N2O3S +C10H10N2O4S +3XNaOH +2NH4CI

Coupling Pigment Yellow 191:1

C17H21CIN6O7S2 + 3H2O + 3NaCI

Mol.Wt. 269 + 254 + 120 + 107 520.5 + 54 + 175.5








6 1,3-SPMP 495

7 C.S. Flacks 200

8 Ammonium Chloride 160



105

3 Pigment Orange Quantity per Month = 200 MT per Month

82) Pigment Orange 5 cas no.3468-63-1: -


2,4-Dinitro Aniline [2,4-DNA cas no.97-02-9] is Diazotized with HCL & Sodium Nitrite at 0 to 5 0C. Then coupled with Beta Naphthol cas no.135-19-3. Coupled mass is stirred till coupling reaction

gets complete. Then in reaction is heated up to 75 to 80 0C to & filtered. Filtrate is sent to ETP for



a. Diazotization of 2,4-DNA

2,4-DNA

C6H5N3O4+ 2HCI + NaNO2

Diazotization 2,4-DNA Diazo


Mol.Wt. 183 + 73 + 69 230.5 + 58.5 + 36

b. Coupling with Naphthol AS-OL

2,4-DNA Diazo+ Beta Naphthol +C.S. Flacks

C6H3CIN4O4 + C10H8O + NaOH

Coupling Pigment Orange 5


Mol.Wt. 230.5 + 114 + 40 338 + 18 + 58.5


Sr.No. Input Qty.in

Kgs

Output Qty.in Kgs



3 2,4-DNA 518 Water Evaporation in

Drying

3000



6 Beta Naphthol 435

7 C.S. Flacks 200



106

83) Pigment Orange 13 [ 3520-72-7]:-


3,3-Dichloro Benzidine [3,3-DCB] is double Diazotized with HCL & Sodium Nitrite at 0 to 5 0C.

Then coupled with 2 mole PMP.Coupled mass is stirred till coupling reaction gets complete. Then





3,3-DCB



C12 H6 N4CI4 + 2NaCI + 4 H2O

Mol.Wt. 253 + 146+ 138 348 + 117 + 72

b. Coupling with PMP

3-3-DCB Diazo + PMP + C.S. Flacks

C12 H6 N4CI4 +2[C10H10N2O] +2NaOH



Mol.Wt. 348 + 348 +80 623 + 36 + 117








6 PMP 510

7 C.S.Flacks 200



107

84) Pigment Orange 16 [CAS NO.: 6505-28-8]:-


Ortho Dianisidine [ODA] is double Diazotized with HCL & Sodium Nitrite at 0 to 5 0C. Then

coupled with 2 mole Acetoacetanilide [AOA].Coupled mass is stirred till coupling reaction gets

complete. Then reaction mass is heated up to 60 to 65 0C& filtered. Filtrate is sent to ETP for further



a. Diazotization of OAD

b. Coupling with AOA

ODA Diazo + AOA + C.S. Flacks

C14H12CI2N4O2 +2[C10H11NO2] +2NaOH


C34H32N6O6+ 2H2O + 2NaCI

Mol.Wt. 339 + 354 +80 620 + 36 + 117





3 ODA 495 Water Evaporation in Drying 3000



6 AOA 500

7 C.S.Flacks 200



OAD

C14H16N2O2 + 4HCI + 2NaNO2

Diazotization ODA Diazo

C14H12CI2N4O2 + 2NaCI + 4 H2O

Mol.Wt. 244 + 146 + 138 339 + 117 + 72

108

85) Pigment Orange 34 [CAS NO. 15793-73-4] :-


3,3-Dichloro Benzidine [3,3-DCB] is double Diazotized with HCL & Sodium Nitrite at 0 to 5 0C.

Then coupled with 2 mole 1-p-tolyl-3-methyl-5-pyrazolone [PTMP].Coupled mass is stirred till





3,3-DCB



C12 H6 N4CI4 + 2NaCI + 4 H2O

Mol.Wt. 253 +146 + 138 348 + 117 + 72

b. Coupling with PTMP

3-3-DCB Diazo + PTMP + C.S. Flacks

C12 H6 N4CI4 +2[C11H11N2O] +2NaOH



Mol.Wt. 348 + 376 +80 651 + 36 + 117








6 PTMP 518

7 C.S.Flacks 200



109

86) Pigment Orange 36 cas no 12236-62-3:-


PCONA cas no. 89-63-4is Diazotized with HCL & Sodium Nitrite at 0 to 5 0C. Then coupled with

AABI cas no 26576-46-5.Coupled mass is stirred till coupling reaction gets complete. Then reaction

mass is heated up to 60 to 65 0C& filtered. Filtrate is sent to ETP for further treatment. Then wet

cake is washed with hot water. washing water is reused in next batch for Diazo preparation. & wet



PCONA




Mol.Wt. 172.5+ 73 + 69 220 + 58.5 + 36


PCONA Diazo + AABI + C.S. Flacks

C6H3CI2N3O2 + C11H11N3O3+ NaOH


C17H13CIN6O5+ H2O + NaCI

Mol.Wt. 220 + 233 +40 416.5 + 18 + 58.5








6 AABI 500

7 C.S.Flacks 200



110

87) Pigment Orange 43 [ CAS No.: 4424-06-0] :-

Manufacturing Process:

In SS reactor charge 1.4.5.8-naphthalenetetracarboxylicacid- 1,8-monoanhydride, 1,2-

diaminobenzene and water. Heat the mass to 100 temp. in 4 hrs. then further heat it to 145-150

temp. in 4 hrs. Maintain this temperature for 6 hrs. to complete condensation reaction. After

complete condensation reaction mass is cool to 100 temp. in 4 hrs and further it cool to room

temperature and pigment is isolated. Filter the pigment slurry and wash with water. ML and wash

water are sent to ETP. Wet cake is then dried and pulverized and then sent to packaging.

Chemical Reaction :-

1.4.5.8-naphthalenetetracarboxylicacid-

1,8-monoanhydride + , 1,2-

diaminobenzene

C14H10O7 + 2 (C6H8N2)

Condensate Pigment Orange 43

C26H16N4O2 + 5H2O

Mol.Wt. 286 + (2x 108) 412 + 90


Sr.No. Input Qty.in

Kgs

Output Qty.in

Kgs

1 1.4.5.8-

naphthalenetetracarboxylicacid-

1,8-monoanhydride

730 Finished Product 1000

2 1,2-diaminobenzene 552 Aqueous Effluent to ETP 3232

3 Water 3025 Drying Loss 1575

4 Water For washing 1500


111

88) Pigment Orange 62 [ cas no.52846-56-7]:-


P-Nitro Aniline [PNA cas no.100-01-6] is Diazotized with HCL & Sodium Nitrite at 0 to 5 0C. Then

coupled with AABI [ cas no.26576-46-5]. Coupled mass is stirred till coupling reaction gets complete.

Then reaction mass is heated up to 60 to 65 0C& filtered. Filtrate is sent to ETP for further



a. Diazotization of PNA

PNA


Diazotization PNA Diazo


Mol.Wt. 138 + 73 + 69 185.5 + 58.5 + 36






3 PNA 375 Water Evaporation in Drying 3000



6 AABI 625

7 C.S.Flacks 200



PNA Diazo + AABI + C.S. Flacks

C6H4CIN3O2 + C11H11N3O3+ NaOH


C17H14N6O5+ H2O + NaCI

Mol.Wt. 208.5 + 233 +40 382 + 18 + 58.5

112

89) Pigment Orange 64 cas no.72102-84-2:-


Methyl aminolone cas no.67014-36-2 is Diazotized with HCL & Sodium Nitrite at 0 to 5 0C. Then

coupled with Barbituric Acid cas no.67-52-7. Coupled mass is stirred till coupling reaction gets

complete. Then reaction mass is heated up to 60 to 65 0C& filtered. Filtrate is sent to ETP for further



a. Diazotization of Methyl aminolone

Methyl aminolone

C8H7N3O + 2HCI + NaNO2

Diazotization Methyl aminolone Diazo

C8H5CIN4O + NaCI + 2H2O

Mol.Wt. 161 + 73 + 69 208.5 + 58.5 + 36

b. Coupling with Barbituric Acid

MAO Diazo + Barbituric Acid + C.S. Flacks

C8H5CIN4O + C4H4N2O3+ NaOH



Mol.Wt. 208.5 + 128 +40 300 + 18 + 58.5





3 Methyl aminolone 500 Water Evaporation in Drying 3000



6 Barbituric Acid 510

7 C.S.Flacks 200



113

4 Pigment Blue Quantity per Month = 200 MT per Month

90) Pigment Blue 1[ CAS NO. 1325-87-7]: -


3,4,9,10-Perylene Tetracorboxylic Acid Diamide [ PTCBAD cas no.81-33-4] is condensed with

2 moles of 4-Methoxybenzyl Chloride [PMBCI cas no.824-94-2] in aqueous media in reflux condition

at 85-900C for 4-5 hrs till condensation reaction gets complete. Then reaction mass is cooled up to

350C by adding water for isolation. Then reaction mass is filtered. filtrate is sent to ETP & MEE. Then

wet cake is washed with hot water. washing water is reused in next batch for isolation in next batch

& wet cake is dried in spin flash dryer, pulverized & packed

a. Condensation of PTCBAD with PMBCI: -

PTCBAD PMBCI 2 KOH

C24H10N2O4 +2[C8H9CIO] + 2KOH

Condensation Pigment Blue 1

C40H26N2O6 + 2H2O + 2KCI

Mol.Wt.390 + 2[156.5] + 112 630 + 36 + 149


Sr.No. Input Qty.in

Kgs

Output Qty.in

Kgs



3 PTCBAD 780 KCI Recovery for re-Use 800

4 PMBCI 250 Washing water for Re-Use 3000


6 TOTAL 7300 TOTAL 7300

114

91) Pigment Copper Phthalocyanine Blue 15 [cas no.147-14-8]:-


Crude copper Phthalocyanine is produced by condensing phthalic anhydride [cas no.85-44-

9], cuprous chloride and Urea [cas no.57-13-6] in presence of ammonium molybdate as catalyst in

the presence cuprous chloride & ammonium molybdate as a catalyst in solvent like Nitrobenzene,

Dichloro Benzene at reflux condition at 170-1800C for 8-9 hrs till condensation reaction gets

complete. During the reaction ammonia and carbon dioxide gas are evolved due to decomposition

of urea, which are scrubbed in a two-stage water scrubbing system. After the condensation

reaction, over, the product is transferred to Venulath dryer for recovery of solvent, where Trichloro

benzene is distilled out using vacuum and crude copper Phthalocyanine blue is obtained as cake.

This crude product is then stirred with 15 % Sulphuric acid and water. The mass is heated using live

steam to 90 0C. During the process, inorganic impurities get dissolved in water while the product,

which is insoluble, remains in the solid form. The slurry from the purification is taken to the filter

press where the dissolved impurities are removed as filtrate, which is taken to the effluent

treatment plant. The cake is then washed with water and the washings are also taken for treatment.

The wet cake is then taken to the spin flash dryer. The product is obtained as a fine powder, which is

then sent for packing.

Condensation of Phthalic Anhydride with Urea: -

Phthalic Anhydride+ Urea +

CuCI

4[C8H4O3]+ 8[CH4N2O] + CuCl

Condensation Pigment Blue15 crude

C32H16CuN8 + 4[(NH4)2CO3 +4CO2 + HCI

Mol.Wt.4X148 + 8[60] + 99 NB/DCB/ONT

AmmoniumMolybdate

575.5 + 4x96 + 4x44 + 36.5

Synthesis & Recovery of Ammonium Sulphate from reaction as by Product :-

Ammo. Carbonate + Spent

H2SO4

4[(NH4)2CO3 + 4[H2SO4]

Neutralization Ammonium Sulphate

4[(NH4)2SO4+ 2CO2 + 4H2O

Mol.Wt.4X96 + 4[98] 528 + 4x96 + 72

115


Sr.No. Input Qty.in

Kgs

Output Qty.in

Kgs

1 NB / DCB 3500 Finish Product 1000

2 Phthalic Anhydride 1110 Water Evaporation in Drying 3000

3 Urea 890 NB / DCB Recovery for re-Use 3325

4 Cuprous Chloride 205 45% Spent H2SO4 5800

5 Ammonium Molybdate 2.5 Ammonium Sulphate Recovery 1750

6 Steam 1800 Water Evaporation in Drying 0

7 45% Spent H2SO4 5800 Washing water for Re-Use 4000

8 Process water 10000 Effluent to ETP in MEE 8432



116

92) Pigment Alpha Blue 15:1[ cas no. 147-14-8]:-


Note:-There is No any Chemical Reaction Only removing of inorganic Impurities From CPC [

cas no. 147-14-8] is carried out.Take Sulphuric acid (98%) in a reaction vessel. Then slowly charge

Copper Phthalocyanine crude. Maintain temperature just below 850C. So that as to dissolve it too

completely. The mass is stirred further for 2-3 hrs. at 600Cand then cooled to room temperature by

external circulation of water in jacket.Recycled water is then introduced as a thin spray into the

vessel slowly; take care to maintain the temperature below 600C.The CPC separate out in the

required form and is filtered off.After filtration process whatever mother liquor generated that

contains approximate 38-40% of Sulphuric acid which is re-used in to the manufacture of CPC blue.

Cake washed by hot Water which is re-used in next batch. The CPC cake is dried, Pulversed &

packed.


Pigment Blue15 crude

C32H16CuN8 + H2SO4

Acid Pasting Pigment Alpha Blue 15:1

C32H16CuN8 + Spent H2SO4

Mol.Wt.575.5 + 98 Water 575.5 + 98


Sr.No. Input Qty.in

Kgs

Output Qty.in

Kgs

1 CPC Blue Crude 1100 Finish Product 1000

2 Sulphuric Acid 98% 5000 Water Evaporation in Drying 3000

3 ICE 4000 45% Spent H2SO4 9500

4 Process Water for Dumping 8000 Ammonium Sulphate Recovery 1450

5 Ammonium Hydroxide 1500 Water Evaporation in Drying 6650

6 Process water 2000 Washing water for Re-Use 5000



117

93) Pigment Beta Blue 15:2 [ cas no. 147-14-8]: -


Note: -There is No any Chemical Reaction Only removing of inorganic Impurities From CPC

is carried out.Take Solvent like Xylene/IBA/MCB in a reaction vessel. Then slowly charge Copper

Phthalocyanine crude. Maintain temperature just below 850C. So that as to dissolve it too

completely. The mass is stirred further for 2-3 hrs. at 800C and then cooled to room temperature by

external circulation of water in jacket &mass is filtered off.After filtration solvent is distilled out foe

re-use. Cake washed by hot Water which is re-used in next batch. The CPC cake is dried, Pulversed &

packed.



C32H16CuN8 + H2SO4



Mol.Wt.575.5 + 98 Water 575.5 + 98


Sr.No. Input Qty.in

Kgs

Output Qty.in

Kgs


2 Solvent 5000 Water Evaporation in Drying 3000

3 Surfactant 10 Solvent Recovery 4750

4 Water for Washing 15000 Washing water for Re-Use 8000

Effluent to ETP 4360


118

94) Pigment Beta Blue 15:3 Beta Blue [ cas no. 147-14-8]: -








packed.



C32H16CuN8 + H2SO4

Acid Pasting Pigment Alpha Blue 15 ;3


Mol.Wt.575.5 + 98 Water 575.5 + 98


Sr.No. Input Qty.in

Kgs

Output Qty.in

Kgs







119

95) Pigment Beta Blue 15:4[ cas no. 147-14-8]: -








packed.



C32H16CuN8 + H2SO4



Mol.Wt.575.5 + 98 Water 575.5 + 98


Sr.No. Input Qty.in

Kgs

Output Qty.in

Kgs







120

96) Pigment Beta Blue 15:6 [ cas no. 147-14-8]: -








packed.



C32H16CuN8 + H2SO4



Mol.Wt.575.5 + 98 Water 575.5 + 98


Sr.No. Input Qty.in

Kgs

Output Qty.in

Kgs







121

97) Pigment Blue 16 [ cas no. 574-93-6]: -


Copper Phthalocyanine [cas n. 147-14-8]is chlorinated by Chlorine gas in the presence of

molten Aluminum Chloride & Sodium Chloride under reflux condition at 180-1900C till desired mole

of chlorine [ 15 to 16] takes place. Chlorine & HCL gas evolves is scrubbed in Double effect Scribing

system to recover spent HCL to re-use for self-consumption. After completion of chlorination, mass

is drowning of all GLV mass in drowning vessel & than filter, wash & keep for finishing the green.For

finishing the final green, MS reactor required with steam heating system. In this vessel charge

solvent, emulsifier & do reflux than distilled solvent than filter, wash & dry in SFD.Make blend in

blender for finish Packing.

Chlorination of CPC by AlCI3 & Chlorine Gas: -


C32H16CuN8 + 5AICI3 + NaCI

Chlorination Pigment Blue 16

C32CI16CuN8 + 16 HCI

Mol.Wt.575.5 + 5x133.5+ 58.5 Chlorine Gas 8CI2 1091.5 to 1127 + 584


Sr.No. Input Qty.in

Kgs

Output Qty.in

Kgs


2 AICI3 700 Water Evaporation in Drying 3000

3 NaCI 300 Spent HCL Recovery 18-20% 8000

4 Chlorine Gas 350 Aluminum salt recover 600

5 Water for Drowning 14000 MCB Recovery 450

6 MCB 500 Washing water for Re-Use 7000



122

98) Pigment Blue 60 [ CAS NO. 81-77-6]: -


2 moles of 2-Amino Anthraquinone [ 2-AQ cas no.117-79-3] is self-condensed in Polyethylene

Glycol [PEG] using Sodium Chlorate & KOH in reflux condition at 85-900C for 4-5 hrs till condensation

reaction gets complete. Then reaction mass is cooled up to 350C by adding water for isolation. Then

reaction mass is filtered.From filtrate, PEG is recovered for Re-use &remaining is sent to ETP & MEE.

Then wet cake is washed with hot water. washing water is reused in next batch for isolation in next

batch & wet cake is dried in spin flash dryer, pulverized & packed

a. Condensation of 2-Amino Anthraquinone: -

2-Aminoanthraquinone

2[C14H9NO2 + 2NaCIO3

Condensation Pigment Blue 60

C28H14N2O4 + 2H2O + 2NaCI 2O2

Mol.Wt.2 [ 223 ] + 2[106.5] PEG +KOH 442 + 36 + 117 + 64


Sr.No. Input Qty.in

Kgs

Output Qty.in

Kgs

1 Poly Ethylene Glycol 1350 Finish Product 1000


3 Sodium Chlorate 112 PEG Recovery for re-Use 1280

4 2-Amino Anthraquinone 1020 Washing water for Re-Use 3000

5 Water for Isolation 3000 Effluent to ETP 1420



123

99) Pigment Blue 62 [ CAS NO. 57485-98-0 / 82338-76-9]: -


3,4,9,10-Perylene Tetracorboxylic Acid Diamide [ PTCBAD cas no.81-33-4] is condensed with

2 moles of Benzyl Chloride [BCI cas no.100-44-7] in aqueous media in reflux condition at 85-900C for





a. Condensation of PTCBAD with PMBCI: -

PTCBAD BCI 2 KOH

C24H10N2O4 + 2[C7H7CI] +2 KOH

Condensation Pigment Black 31

C38H22N2O4 + 2H2O + 2KCI

Mol.Wt.390+ 2[126.5] + 112 570 + 36 + 149


Sr.No. Input Qty.in

Kgs

Output Qty.in

Kgs



3 PTCBAD 790 KCI Recovery for re-Use 800

4 BCI 250 Washing water for Re-Use 3000


6 TOTAL 7310 TOTAL 7310

124

5 Pigment Violet Quantity per Month = 200 MT per Month

100) Pigment Violet 1 [ CAS NO..1326-03-0]: -


2 Moles of Diethyl meta amino Phenol [ DEMAP]Cas No.1326-03-0 is condensed with phthalic

Anhydride Cas No.85-44-9 in Ethanol cas no.64-17-5 .Then ethanol is distilled out for recycle &

Product is washed with Hot Water & washing water is reused in next batch for isolation in next

batch & wet cake converted into phosphomolybdic acid [ PMA] salt then it is dried in spin flash


a. Condensation of DEMAP with Phthalic Anhydride: -

DEMAP Phthalic Anhydride +

Ethanol

2[ C10H15NO ] + C8H4O3 + C2H5OH

Condensation Pigment Violet 1 Hydroxide

hydride

C28H31N2O3PMA Salt + H5O3

Mol.Wt. 2 x 165 + 148 + 46 443+PMA salt + 53


Sr.No. Input Qty.in

Kgs

Output Qty.in

Kgs

1 DEMAP 600 Finish Product 1000



4 Phosphomolybdic acid [ PMA] 100 Evaporation loss 1265



125

101) Pigment Violet 1x [ CAS NO..]: -





next batch & wet cake converted into phosphomolybdic acid salt then it is dried in spin flash dryer,

pulverized & packed



Ethanol

2[ C9H13NO ] + C8H4O3 + C2H5OH

Condensation Pigment Red 81 Hydroxide

hydride


Mol.Wt. 2 x 151 + 148 + 46 443+SAM salt + 53


Sr.No. Input Qty.in

Kgs

Output Qty.in

Kgs




4 Silicomolybdic acid [ SM] 100 Evaporation loss 1265



126

102) Pigment Violet 3 [ CAS NO.1325-82-2.]: -


3 Moles of N,N’Dimethyl aniline [ DMA]Cas No.121-69-7 is self-condensed in ethanol Then

ethanol is distilled out for recycle & Product is washed with Hot Water & washing water is reused in

next batch for isolation in next batch & wet cake converted into phosphomolybdic acid salt then it is


a. Condensation of DMA with Self: -

DMA + Ethanol

3[ C9H13NO ] + C2H5OH


hydride

C234H28N3PM Salt + H5O3

Mol.Wt. 3x 111 + 46 443+PM salt + 53


Sr.No. Input Qty.in

Kgs

Output Qty.in

Kgs

1 DMA 600 Finish Product 1000



4 Phosphomolybdic acid [ PM] 100 Evaporation loss 1265



127

103) Pigment Violet 19 [ CAS NO. 1047-16-1.]: -


1.Dimethyl Succinosuccinate [DMSS CAS No.6289-46-9] is condensed with 2 moles of Aniline in

methanol under efflux condition to form dimethyl 2,5-dianilino-3,6-dihydro-terephthalate [ DADHT].

2.Then resulting product is oxidised with resist salt to form 2,5-dianilino-3,6-dihydro-terephthalate

dimethyl ester [DADHT dimethyl ester].

3.Then it is hydrolyzed in alkaline condition & aqueous medium to form 2,5-Bis-(p-anilino)

terephthalic acid [DADHT Acid]

4.Then it is further cyclised in presence of Poly phosphoric acid then finally pigmentation is done in

presence of IBA/DMF as per Quinacridone as Pigment Violet 19

1.Condensation of DMSS with Aniline: -

DMSS + 2[Aniline]

C10H12O6 + 2[C6H7N]

Condensation

DADHT

C22H22N2O4 + 2H2O

Mol.Wt.228 + 2X[93] Methanol 378 + 36


DADHT

C22H22N2O4 + O2

Condensation

DADTA dimethyl ester

C22H20N2O4 + H2O2


3.Hydrolysis of DADTA dimethyl ester:-

DADTA dimethyl ester

C22H20N2O4 + 2NaOH +2HCL

Hydrolysis

DADTA Acid

C20H18N2O4 + 2NaCI + 2CH3OH

Mol.Wt. 376 + 80 + 73 Methanol 376 + 117 + 64

4.Cyclisation of DADTA Acid with Poly Phosphoric Acid & Pigmentation to form Pigment Red 122:-

DADTA Acid Poly Phosphoric

acid

C20H18N2O4 + H3PO4.P2O5

Cyclisation

Pigment Violet 19 Triphosphoric Acid

monohydrate

C20H12N2O2 + H5P3O10.H2O

Mol.Wt. 376 + 238 DMF /IBA 340 + 274

128


Sr.No. Input Qty.in

Kgs

Output Qty.in

Kgs


2 Dimethyl

Succinosuccinate


3 Aniline 830 Methanol Recovery for Re-Use 5225


5 NaOH 275 Effluent to ETP treatment in MEE 7500



8 DMF / IBA 7000




129

104) Pigment Violet 23 [ CAS NO. 6358-30-1.]: -


1. Carbazole [ cas no.86-74-8] undergoes with Diethylsulphate [DES cas no.64-67-5] in the presence

of Mono Chloro Benzene [MCB] & NaOH under efflux condition to form N-Ethyl Carbazole

2.Then N-Ethyl Carbazole undergoes Nitration with Nitric Acid in the presence of Mono Chloro

Benzene [MCB] to form 3-Nitro-N-Ethyl Carbazole

3.Then 3-Nitro-N-Ethyl Carbazole undergoes Hydrogenation in presence of Ortho Dichloro Benzene

using Raney Nickel as catalyst to form3-Amino-N-Ethyl Carbazole

4.Then 3-Amino-N-Ethyl Carbazole is further condensed &cyclised with Chloranil in presence of

methanol to form Pigment Violet 23

1.Ethylationof Carbazole with Diethyl Sulphate[DES]: -

Carbazole + DES

C12H9N + C4H10O4S + 2NaOH

Ethylation

N-Ethyl Carbazole

C14H13N+ H2O +Na2SO4 +C2H5OH

Mol.Wt.167 + 154 + 80 MCB 195 + 18 + 142 + 46


N-Ethyl Carbazole

C14H13N + HNO3

Nitration

3-Nitro-N-Ethyl Carbazole

C14H12N2O2 + HO2

Mol.Wt. 195 + 63 MCB 240 + 18

3.Hydrolysis of DADTA dimethyl ester: -

3-Nitro-N-Ethyl Carbazole

C14H12N2O2 + H2

Hydrogenation

3-Amino-N-Ethyl Carbazole

C14H14N2 + O2

Mol.Wt. 240 + 2 ODCB /Al/Ni 210 + 32

4.Cyclisation of DADTA Acid with Poly Phosphoric Acid & Pigmentation to form Pigment Violet 23:-

3-Amino-N-Ethyl Chloranil

Carbazole

2[C14H14N2] + C6CI4O2 2NaOH

Condensation&

Cyclisation

Pigment Violet 23

C34H26CI2N4O2 + 2NaCI + 2H2O

Mol.Wt. 420 + 246 + 80 Methanol 593 + 117 + 36

130


Sr.No. Input Qty.in

Kgs

Output Qty.in

Kgs

1 Mono Chloro Benzene 1000 Finish Product 1000

2 Carbazole 800 Water Evaporation in Drying 2500

3 Di Ethyl Sulphate 470 Methanol Recovery for Re-Use 4750

4 NaOH Flacks 500 MCB Recovery for Re-Use 950

5 Nitric Acid 45% 600 ODCB Recovery for Re-Use 9500

6 Hydrogen Gas 8 DEG Recovery for Re-Use 950

7 Ortho Dichloro Benzene 10000 Washing water for Re-Use 8000

8 Sodium acetate 50 Effluent to ETP treatment in MEE 15778

9 Methanol 5000 Raney Nickel Recovery 8

10 Raney Nickel 8 Inorganic & solvent residue 680

11 DEG 1000

12 ICE 1000

13 Process Water for

Reaction

15000



131

105) Pigment Violet 27 [ CAS NO.12237-62-6]: -


2 Moles of Methyl Violet react with 2Moles of Copper Sulfate in Presence of Sodium Ferocynide the

result of Product will be Pigment Violet 27 (2Moles) , 2Moles of Sodium Sulfate and 1Mol of

Ferocynide. Product is washed with Hot Water & washing water, then it is dried in spin flash dryer,

pulverized & packed

a. Chemical Reaction : -

Methyl Violet + Copper Sulfate + Sodium

Fero

Cynide

2(C24H27N3) + 2(CuSo4) +

Na4Fe(CN)6

Condensatio

n

Pig.Violet 27 + Sodium Sulfate + Fero

Cynide

2(C24H27N3)+ 2Na2So4 +

Fe(CN)6

2(357) + 2(159) + 303` 2 (357) + 2(142) + 211


Sr.No. Input Qty.in

Kgs

Output Qty.in

Kgs

1 Methyl Violet 714 Finish Product 714

2 Copper Sulfate 159 Washing water for Re-Use 2000

3 Sodium FeroCynide 303 Evaporation loss 962



132

106) Pigment Violet 29 [ CAS NO.81-33-4.]: -


3 Moles of N,N’Dimethyl aniline [ DMA]Cas No.121-69-7 is self-condensed in ethanol Then

ethanol is distilled out for recycle & Product is washed with Hot Water & washing water is reused in

next batch for isolation in next batch & wet cake converted into ferrous iron copper cyanide

complex salt then it is dried in spin flash dryer, pulverized & packed

a. Condensation of DMA with Self: -

DMA + Ethanol

3[ C9H13NO ] + C2H5OH


hydride

C234H28N3CF Salt + H5O3

Mol.Wt. 2 x 111 + 46 443+CF salt + 53


Sr.No. Input Qty.in

Kgs

Output Qty.in

Kgs

1 DMA 600 Finish Product 1000



4 Ferrous Iron copper cyanide [ PM] 100 Evaporation loss 1265



133

B Solvents Dyes Total Number of Dyes

(1 + 2 + 3 + 4 + 5 + 6 ) = 41

Total Quantity per Month

( 1 + 2 + 3 + 4 + 5 + 6 ) = 200 MT per

Month

1 Red Solvent Dyes Quantity per Month =

Category B : SOLVENTS :-

1. Red Solvent Dyes –

107) Solvent Red 19E [ cas no. 6368-72-5] : -


Garnet GB Base [ cas no.97-56-3] is Diazotized with HCL & Sodium Nitrite at 0 to 5 0C. Then

coupled with n-Ethyl-Naphthalene- amine [ n-ENA cas no.2437-03-8]. Coupled mass is stirred till

coupling reaction gets complete. Then reaction mass is heated up to 75 to 80 0C & filtered. Filtrate is



a. Diazotization of Garnet GB Base

Garnet GB Base


Diazotization Garnet GB Base Diazo


Mol.Wt.225 + 73 + 69 272.5 + 58.5 +36

b. Coupling with n-ENA

Garnet GB Base Diazo + n-ENA +C.S. Flacks

C14H13CIN4 + C12H13N +NaOH

Coupling Solvent Red 19E

C26H25N5 + H2O + NaCI

Mol.Wt. 272.5 + 171 + 40 407 + 18 + 58.5

134





3 Garnet GB Base 500 Water Evaporation in Drying 3000



6 n-ENA 435

7 C.S. Flacks 200




135

108) Solvent Red 23 [CAS No. 85-86-9] :


Dissolve 4-(phenyldiazenyl) aniline in water and hydrochloric acid. Stir it for 1 hr. Cool it to 0

temp. and rapidly sodium nitrite solution. Maintain temp. below 10 and stir for 1 hr. For Coupler

Dissolve naphthalen-2-ol in sodium hydroxide and water solution. Cool to 10 temp. Now, Add above

prepared Diazo solution in coupler solution in about 1-2 hrs. After complete addition pH is 9-10.

During addition maintain temp. 10-15. stir for 1 hr at this temp. Heat the mass to 40 and maintain

for 3 hrs. Further heat it to 90temp. and maintain for 30 minute. Cool to 70 temp. for filtration.

Filter the pigment slurry and wash with water up to salt free. Filtrate and wash water are sent to

ETP. Wet cake is then dried and pulverized and then sent to packaging.

Chemical

a. Diazotization of 4-(phenyldiazenyl) (PAAB) :-

PAAB

C12H11N3+ 2HCI + NaNO2

Diazotization PAAB Diazo

C12H9N4Cl + NaCI + 2H2O

Mol.Wt. 197 + 72 + 69 243.5 + 58.5 + 36

b. Coupling with 5-methyl-2-phenylpyrazolidin-3-one :-

PAAB Diazo + 5-methyl-2-phenylpyrazolidin-3-

one

C12H9N4Cl + C10H8O + NaOH

Coupling Solvent Yellow 72


Mol.Wt. 243.5 + 144 + 40 350 + 18 + 58.5


Sr.No. Input Qty.in

Kgs

Output Qty.in

Kgs

1 Re-use Water 2145 Finished Product 1000

2 HCL 1145 Water for Reuse 2145

3 4-(phenyldiazenyl) aniline (PAAB) 575 Drying Loss 1500

4 Sodium Nitrite 507 Aqueous Effluent to ETP 5412

5 Water from Washing 2145


7 Naphthalen-2-ol (Beta Naphthol) 420

8 Water For Washing 2860


136

109) Solvent Red 24 [ cas no. 85-83-6] : -


Garnet GB Base [ cas no.97-56-3] is Diazotized with HCL & Sodium Nitrite at 0 to 5 0C. Then

coupled with Beta Naphthol [cas no.135-19-3]. Coupled mass is stirred till coupling reaction gets

complete. Then reaction mass is heated up to 75 to 80 0C & filtered. Filtrate is sent to ETP for further



a. Diazotization of Garnet GB Base

Garnet GB Base


Diazotization Garnet GB Base Diazo


Mol.Wt.225 + 73 + 69 272.5 + 58.5 + 36

b. Coupling with Beta Naphthol

Garnet GB Base Diazo + B-N +C.S. Flacks

C14H13CIN4 + C10H8O +NaOH

Coupling Solvent Red 24


Mol.Wt. 272.5 + 144 + 40 380 + 18 + 58.5





3 Garnet GB Base 600 Water Evaporation in Drying 3000



6 Beta Naphthol 435

7 C.S. Flacks 200




137

110) Solvent Red 52 [ cas no. 81-39-0]: -


6-Bromo anthrapyridone [6-BAPcas no .81-85-6.] is condensed with p-Toluidine [cas no.106-

49-0] in the presence of Xylene / ODCB under reflux condition till completion of reaction. Then

Xylene / ODCB is distilled out for re-use & product is isolated by methanol. Then mass is filtered.

Filtrate is collected for recovery of methanol for re-use & cake is washed with hot water. Washing

water is re-used in next batch & cake is dried, pulverized

a. Condensation:

6-BAP p-Toluidine

C17H10BrNO2 + C7H9N + KOH

Condensation Sol.Red 52

C24H18N2O2 + KBr + H2O

Mol.Wt.340 + 107 + 56 Xylene /

ODCB

366 + 119 + 18


Sr.No. Input Qty.in Kgs Output Qty.in

Kgs

1 Xylene / ODCB 1000 Finish Product 1000

2 6-BAP 700 Water Evaporation in Drying 1000

3 p-Toluidine 310 Xylene / ODCB Recovery for recycled 950

4 Methanol 2000 Methanol Recovery for recycled 1900

5 Water for washing 5000 Washing water Re-cycle for Re-Use 4160


138



1-Chloro Anthraquinone [1-Chloro AQ cas no .82-44-0.] is condensed with Methane amine

[cas no.74-89-5] in the presence of Xylene / ODCB under reflux condition till completion of reaction.

Then Xylene / ODCB is distilled out for re-use & product is isolated by methanol. Then mass is

filtered. Filtrate is collected for recovery of methanol for re-use & cake is washed with hot water.

Washing water is re-used in next batch & cake is dried, pulverized

a. Condensation:

1-Chloro AQ Methane amine

C14H7CIO2 + CH5N + NaOH


C15H11NO2 + NaCI + H2O

Mol.Wt.242.5 + 31 + 40 Xylene /

ODCB

237 + 58.5 + 18



Kgs


2 1-Chloro AQ 713 Water Evaporation in Drying 1000

3 Methane amine 250 Xylene / ODCB Recovery for recycled 950




139



Tetra Chloro Phthalic Anhydride [TCAP cas no .117-08-8.] is condensed with 1,8-Diamino

Naphthalene [cas no.479-27-6] in the presence of Xylene / ODCB under reflux condition till

completion of reaction. Then Xylene / ODCB is distilled out for re-use & product is isolated by

methanol. Then mass is filtered. Filtrate is collected for recovery of methanol for re-use & cake is

washed with hot water. Washing water is re-used in next batch & cake is dried, pulverized

a. Condensation:

TCAP 1, 8-DAN

C8CI4O3 + C10H10N2


C18H6CI4NO2 + 2 H2O

Mol.Wt.285 + 158 Xylene /

ODCB

408 + 36



Kgs


2 TCAP 685 Water Evaporation in Drying 1000

3 1,8-DAN 350 Xylene / ODCB Recovery for recycled 950




140



6-Bromo anthrapyridone [6-BAPcas no .81-85-6.] is condensed with 3-Chloroaniline [cas

no.108-42-9] in the presence of Xylene / ODCB under reflux condition till completion of reaction.




a. Condensation:

6-BAP 3-Chloroaniline

C17H10BrNO2 + C6H6CIN + KOH


C23H15CIN2O2 + KBr + H2O

Mol.Wt.340 + 127.5 + 56 Xylene /

ODCB

386.5 + 119 + 18



Kgs


2 6-BAP 690 Water Evaporation in Drying 1000

3 3-Chloroaniline 315 Xylene / ODCB Recovery for recycled 950




141



1-Chloro Anthraquinone [1-Chloro AQ cas no .82-44-0.] is condensed with Cyclo Hexylamine

[cas no.108-91-8] in the presence of Xylene / ODCB under reflux condition till completion of

reaction. Then Xylene / ODCB is distilled out for re-use & product is isolated by methanol. Then

mass is filtered. Filtrate is collected for recovery of methanol for re-use & cake is washed with hot

water. Washing water is re-used in next batch & cake is dried, pulverized

a. Condensation:

1-Chloro AQ Cyclo Hexylamine

C14H7CIO2 + C6H13N + NaOH



Mol.Wt.242.5 + 99 + 40 Xylene /

ODCB

305 + 58.5 + 18



Kgs



3 Cyclo hexyl amine 291 Xylene / ODCB Recovery for recycled 950




142



1-Chloro Anthraquinone [1-Chloro AQ cas no .82-44-0.] is condensed with 2-propanol amine

[cas no.175-31-0] in the presence of Xylene / ODCB under reflux condition till completion of

reaction. Then Xylene / ODCB is distilled out for re-use & product is isolated by methanol. Then



a. Condensation:

1-Chloro AQ 2-Propanolamine




Mol.Wt.242.5 + 59 + 40 Xylene /

ODCB

265 + 58.5 + 18



Kgs



3 2-Propanolamine 205 Xylene / ODCB Recovery for recycled 950




143

116) Solvent Red 179 [ cas no. 6829-22-7/ 89106-94-5]: -


1,8-Diamino Naphthalene [1,8-DAN cas no .479-27-6.] is condensed with 1,8-Naphthalic

Anhydride [cas no.81-84-5] in the presence of Xylene / ODCB under reflux condition till completion

of reaction. Then Xylene / ODCB is distilled out for re-use & product is isolated by methanol. Then



a. Condensation:

1,8-DAN 1,8-Naphthalic Anhydride

C10H10N2 + C12H16O3


C22H12N2O + 2H2O


ODCB

320 + 36



Kgs


2 1,8-DAN 445 Water Evaporation in Drying 1000

3 1,8-Naphthalic Anhydride 560 Xylene / ODCB Recovery for recycled 950




144



DEAMAP Aldehyde [cas no .17754-90-4.] is condensed with 2-Amino 2,3-Dihydro1-H-

Benzamidazole-2-Methylpropionitrile [2-A,2,3-DHHBMMP cas No. 17754-90-4.] in the presence of

Xylene / ODCB under reflux condition till completion of reaction. Then Xylene / ODCB is distilled out

for re-use & product is isolated by methanol. Then mass is filtered. Filtrate is collected for recovery

of methanol for re-use & cake is washed with hot water. Washing water is re-used in next batch &

cake is dried, pulverized

a. Condensation:

DEAMAP Aldehyde 2-A,2,3-DHHBMMP

C11H15NO2 + C13H16N4


C23H19N5O + CH3OH + 4H2


ODCB

381 + 32 + 8



Kgs


2 DEAMAP Aldehyde 525 Water Evaporation in Drying 1000

3 2-A,2,3-DHHBMMP 590 Xylene / ODCB Recovery for recycled 950




145

118) Solvent Red 207 [ cas no. 15958--69-6]: -


1, 8-Dichloro Anthraquinone [1,8-DCAQ cas no .82-43-9.] is condensed with 2 moles of Cyclo

Hexylamine [cas No.108-91-8 in the presence of Xylene / ODCB under reflux condition till




a. Condensation:

1,8-DCAQ Cyclo Hexylamine

C14H6CI2O2 + 2[ C6H13N] + 2NaOH


C26H30N2O2 + 2NaCI + 2H2O

Mol.Wt.277 + 2 x 99 + 80 Xylene /

ODCB

402 + 117 + 36



Kgs


2 1,8-DCAQ 725 Water Evaporation in Drying 1000

3 Cyclo Hexylamine 295 Xylene / ODCB Recovery for recycled 950




146


Manufacturing Process :

1-Chloro Anthraquinone [1-Chloro AQ cas no .82-44-0.] is condensed with Aniline [cas No.62-





a. Condensation:

1-Chloro AQ Aniline




Mol.Wt.242.5 + 93 + 40 Xylene /

ODCB

299 + 58.5 + 18



Kgs



3 Aniline 215 Xylene / ODCB Recovery for recycled 950




147

2 Yellow Solvent

Dyes Quantity per Month =

120) Solvent Yellow 2[CAS No.: 6370-43-0]

Manufacturing Process :-

It is mono azo dyes for which first make Aniline is diazotized with sodium nitrite in presence

hydrochloric acid at bellow 0 deg temp. and stir for 2 hr. Then dizo component is coupled with Di

MethylAniline (D.M.A.) in Acidic medium at 5 deg temperature. Stir for 5 hr.

a. Diazotization of Aniline

Aniline

C6H7N1 + HCI + NaNO2


C6H7N=NCL + NaCI

Mol.Wt. 93 + 36 + 69 140 + 58

b. Coupling with D.M.A.

2,4-DNA Diazo DMA

C6H7N=NCL + C8H11N1 + NaOH


C14H15N3 + 2HCL

Mol.Wt. 140 + 121 + 36 225 + 72


Sr.No. Input Qty.in

Kgs

Output Qty.in

Kgs

1 Aniline 415 Finish Product 1000

2 HCL 1000 Washing Regenerate 1005

3 Sodium Nitrite 315 Water Evaporated 10570

4 D.M.A. 545

5 Water 5200

6 Ice 5100


148

121) SOLVENT YELLOW 14 [CAS NO.: 842-07-9]


It is mono azo dyes for which first make Aniline is diazotized with sodium nitrite in presence

hydrochloric acid at bellow 0 deg temp. and stir for 2 hr. Then dizo component is coupled with β

Napthol in Alkaline medium at 5 deg temperature. Stir for 5 hr.

a. Diazotization of Aniline

Aniline

C6H7N1 + HCI + NaNO2


C6H7N=NCL + NaCI

Mol.Wt. 93 + 36 + 69 140 + 58

b. Coupling with BetaNaphthol

2,4-DNA Diazo+ Beta Naphthol

C6H3CIN4O4 + C10H8O1 + NaOH


C16H14N2O + NaCl + H2O

Mol.Wt. 140 + 144 + 40 248 + 58 + 18


Sr.No. Input Qty.in

Kgs

Output Qty.in

Kgs

1 Aniline 415 Finish Product 1000

2 HCL 1000 Washing Regenerate 2125

3 Beta Naphthol 315 Water Evaporated 5747

4 Soda Ash/ NaOH 200

5 Water 3200

6 Ice 3100


149

122) Solvent Yellow 18 [CASNo.6407-78-9] :-


Dissolve 2,4-dimethylaniline in water and hydrochloric acid. Stir it for 1 hr. Cool it to 0 temp.

and rapidly sodium nitrite solution. Maintain temp. below 10 and stir for 1 hr. For Coupler Dissolve 5-

methyl-2-phenylpyrazolidin-3-one in sodium hydroxide and water solution. Cool to 10 temp. Now

add Add above prepared Diazo solution in coupler solution in about 1-2 hrs. After complete addition

pH is 9-10. During addition maintain temp. 10-15. stir for 1 hr. at this temp. Heat the mass to 40 and

maintain for 3 hrs. Further heat it to 90 temp. and maintain for 30 minute. Cool to 70 temp. for

filtration.Filter the pigment slurry and wash with water up to salt free. Filtrate and wash water are

sent to ETP. Wet cake is then dried and pulverized and then sent to packaging.

a. Diazotization of 2,4-dimethylaniline (2,4 Xylidine)

2,4 Xylidine

C8H11N+ 2HCI + NaNO2

Diazotization 2,4 Xylidine Diazo

C8H9N2Cl + NaCI + 2H2O

Mol.Wt. 121 + 73 + 69 168.5 + 58.5 + 36

b. Coupling with P.M.P.

2,4 Xylidine Diazo + P.M.P. + C.S. Flacks

C8H9N2Cl + C10H12N2O + NaOH


C18H18N4O + H2O + NaCI

Mol.Wt. 168.5 + 176 + 39 306 + 18 + 58.5


Sr.No. Input Qty.in

Kgs

Output Qty.in

Kgs

1 Water 3225 Finised Product 1000

2 HCL 1290 Water Reuse for Coupler 1620

3 2,4-dimethylaniline (2,4 Xylidine) 425 Aqueous Effluent to ETP 6950

4 Sodium Nitrite 575 Drying Loss 1500

5 Water For washing (ReUse) 1620

6 sodium hydroxide 130

7 5-methyl-2-phenylpyrazolidin-3-one

(P.M.P.)

580



150

123) Solvent Yellow 33 [ cas no. 8003-22-3]: -


Phthalic Anhydride [ [cas no.85-44-9] is condensed with Quinaldine [ cas no.91-63-4] in the

presence of Xylene / ODCB under reflux condition till completion of reaction. Then Xylene / ODCB is

distilled out for re-use & product is isolated by methanol. Then mass is filtered. Filtrate is collected

for recovery of methanol for re-use & cake is washed with hot water. Washing water is re-used in

next batch & cake is dried, pulverized

a. Condensation:

Phthalic Anhydride Quinaldine

C8H4O3 + C10H9N

Condensation Sol.Yellow 33

C18H11NO2 + H2O

Mol.Wt.148 + 143 Xylene / ODCB 273 + 18


Sr.No. Input Qty.in

Kgs

Output Qty.in

Kgs


2 Phthalic Anhydride 575 Water Evaporation in Drying 1000

3 Quinaldine 500 Xylene / ODCB Recovery for recycled 950




151



1-Chloro-1,8-Naphthalic Anhydride [ [cas no.4053-08-1] is condensed with n-Butyl amine [

cas no.12226-96-9] in the presence of Methanol under reflux condition till completion of reaction.

Then Methanol is distilled out for re-use & product is isolated by water. Then mass is filtered.

Filtrate is collected for re-use & cake is washed with hot water. Washing water is re-used in next

batch & cake is dried, pulverized

a. Condensation:

1-CI-1,8-N.A. + n-Butyl Amine +

NaOH

C12H5CIO3 + 2[ C4H11N]


C20H24N2O2 NaCI+ 2H2O

Mol.Wt.232.5 + 2 X 73 + 40 Methanol 324 + 58.5 + 36


Sr.No. Input Qty.in

Kgs

Output Qty.in

Kgs


2 1-ChIoro-1,8-Naphthaline. A 735 Water Evaporation in Drying 1000

3 n-Butyl Amine 300 Methanol Recovery for recycled 1900

4 C.S.Lye 200 NaCI Recovery 350



152



1-Amino-1,8-Naphthalic Anhydride [ [cas no.6492-86-0] is condensed with 2,4-

Dimethylaniline [ cas no.95-78-3] in the presence of Methanol under reflux condition till completion

of reaction. Then Methanol is distilled out for re-use & product is isolated by water. Then mass is

filtered. Filtrate is collected for re-use & cake is washed with hot water. Washing water is re-used in


a. Condensation:

1-A-1,8-N.A. + 2,5-DMA

C12H7NO3 + C8H11N


C20H16N2O2 + H2O

Mol.Wt.213 + 121 Methanol 316 + 18


Sr.No. Input Qty.in

Kgs

Output Qty.in

Kgs


2 1-Amino-1,8-Naphthaline. A 635 Water Evaporation in Drying 1000

3 2,5 D.M.A. 400 Methanol Recovery for recycled 1900



153

126)Solvent Yellow 72 [CAS No.:61813-98-7]


Dissolve 2-methoxyaniline in water and hydrochloric acid. Stir it for 1hr. Cool it to 0 temp.

and rapidly sodium nitrite solution. Maintain temp. below 10 and stir for 1 hr. Now For Coupler

Dissolve 5-methyl-2-phenylpyrazolidin-3-one in sodium hydroxide and water solution. Cool to 10

temp. Now Add above prepared Diazo solution in coupler solution in about 1-2 hrs. After complete

addition pH is 9-10. During addition maintain temp. 10-15. Stir for 1 hr at this temp. Heat the mass

to 40 and maintain for 3 hrs. Further heat it to 90temp. andn maintain for 30 minute. Cool to 70

temp. for filtration. Filter the pigment slurry and wash with water up to salt free. Filtrate and wash

water are sent to ETP. Wet cake is then dried and pulverized and then sent to packaging.

a. Diazotization of 2-methoxyaniline

2-methoxyaniline

C7H9NO+ 2HCI + NaNO2

Diazotization 2-methoxyaniline Diazo

C7H7N2OCl + NaCI + 2H2O

Mol.Wt. 123 + 72 + 69 169.5 58.5 + 36

b. Coupling with 5-methyl-2-phenylpyrazolidin-3-one

2-methoxyaniline + 5-methyl-2-

phenylpyrazolidin-3-one. + C.S. Flacks

C7H7N2OCl + C10H12N2O + NaOH



Mol.Wt. 169.5 + 176 + 39 308 + 18 + 58.5


Sr.No. Input Qty.in

Kgs

Output Qty.in

Kgs

1 Water 3250 Finished Product 1000

2 HCL 1300 ML+ Washing 7012

3 2-methoxyaniline 410 Water for Reuse 2440

4 Sodium Nitrite 575 Drying Loss 1500

5 Re-use Water 2440

6 Sodium hydroxide 130

7 5-methyl-2-phenylpyrazolidin-3-one 597



154

127) Solvent Yellow 114 [ cas no. 75216-45-4 / 7576-65-0]: -


3-Hydroxy-2-methyl-4-quinolinecarboxylic acid [ [cas no.117-57-7] is condensed with

Phthalic Anhydride [ cas no.85-44-9] in the presence of Xylene / ODCB under reflux condition till




a. Condensation:

1-H-2,4-QCA. + Phthalic Anhydride

C11H9NO3 + C8H4O3


C18H11NO3 + CH3OH + H2O

Mol.Wt.203 + 148 Methanol 289 + 32 + 18


Sr.No. Input Qty.in

Kgs

Output Qty.in

Kgs


2 3-Hydroxy-2-methyl-4-

quinolinecarboxylic acid


3 Phthalic Anhydride 410 Xylene / ODCB Recovery for recycled 1425




155

128) Solvent Yellow 131 [ cas no71819-82-4]: -


In clean reaction charge Methanol, 6-chloro-1H,3H-benzo[de]isochromene-1,3-dione

and 3-aminopropan-1-ol. Heat the reaction mass to reflux temp and maintain for 10 hrs. Cool the

reaction mass to room temp for isolation. Filter the reaction mass and wash with water. Dry the wet

cake and pulverize and sent for packing.

Chemical Reaction :-

6-chloro-1H,3H-benzo[de]isochromene-

1,3-dione + 3-aminopropan-1-ol

C12H5ClO3 + (2 x C2H9NO)

Condensate Solvent Yellow 131

C18H20N2O4 + H2O + HCL

Mol.Wt.232 + (2x75) 412 + 18 +36


Sr.No. Input Qty.in

Kgs

Output Qty.in

Kgs

1 Methanol 2300 Finished Product 1000

2 6-chloro-1H,3H-

benzo[de]isochromene-1,3-dione

727 Methanol Receovery 2080

3 3-aminopropan-1-ol 300 Drying Loss 1500

4 Water for Washing 2300 Aqueous ML 1047


156



tetra-Chloro-phthalic Anhydride [ TCPA cas no.117-08-8] is condensed with Quinaldine [cas

no.91-63-4] in the presence of Xylene / ODCB under reflux condition till completion of reaction.




a. Condensation:

Tetrachloro Phthalic Anhydride

Quinaldine

C8CI4O3 + C10H9N


C18H7CI4NO2 + H2O

Mol.Wt.285 + 143 Xylene / ODCB 410 + 18


Sr.No. Input Qty.in

Kgs

Output Qty.in

Kgs


2 Tetra Chloro Phthalic

Anhydride


3 Quinaldine 455 Xylene / ODCB Recovery for recycled 950




157

130) Solvent Yellow 163 [ cas no. 13676-91-0/106768-99-4]: -


1, 8-Dichloro AQ [cas no.82-43-9] is condensed with Thiophene [cas no.108-98-5] in the





a. Condensation:

1, 8-DCAQ Thiophene

C14H6CI2O2 + 2[C6H6S] + 2 NaOH


C26H16O2S2 2NaCI + 2H2O

Mol.Wt.277 + 2 x 110 + 80 Xylene /

ODCB

424 + 117 + 36


Sr.No. Input Qty.in

Kgs

Output Qty.in

Kgs


2 1, 8-Dichloro AQ 650 Water Evaporation in Drying 1000

3 Thiophene 405 Xylene / ODCB Recovery for recycled 950




158

131) Solvent Yellow 167 [ cas no. NA]: -


1, Chloro A Q [cas no .82-44-0.] is condensed with Thiophene [cas no.108-98-5] in the





a. Condensation:

1-Cl-AQ Thiophene

C14H7CIO2 + C6H6S + NaOH


C20H12O2S NaCI + H2O

Mol.Wt.242.5 110 40 Xylene /

ODCB

316 58.5 18


Sr.No. Input Qty.in

Kgs

Output Qty.in

Kgs


2 1-chloro AQ 685 Water Evaporation in Drying 1000

3 Thiophene 365 Xylene / ODCB Recovery for recycled 950




159

3 Orange Solvent


132) Solvent Orange 60 [ cas no. 61969-47-9]: -


1, 8-Diamino AQ [cas no.85-44-9] is condensed with Phthalic Anhydride [cas no.479-27-6] in

the presence of Xylene / ODCB under reflux condition till completion of reaction. Then Xylene /

ODCB is distilled out for re-use & product is isolated by methanol. Then mass is filtered. Filtrate is

collected for recovery of methanol for re-use & cake is washed with hot water. Washing water is re-

used in next batch & cake is dried, pulverized

a. Condensation:

1,8-DAAQ Phthalic Anhydride

C10H10N2 + C8H4O3

Condensation Sol.Orange 60

C18H10N2O + 2H2O


ODCB

270 + 36


Sr.No. Input Qty.in

Kgs

Output Qty.in

Kgs


2 1, 8-DAAQ 500 Water Evaporation in Drying 1000

3 Phthalic Anhydride 530 Xylene / ODCB Recovery for recycled 950




160

133) Solvent Orange 63 [ cas no. 16294-75-0]: -

Bromo benzanthrone [cas no .81-96-9-.] is condensed with 2-AminoThiophene [cas no.137-





a. Condensation:

Bromobenzonthrone 2-

AminoThiophene

C17H9BrO0 + C6H7NS + NaOH

Condensation Sol.Orange 63

C23H12OS + NaBr + H2O + NH3

Mol.Wt.309 + 125 + 40 Xylene /

ODCB

336 + 103 + 18 + 17



Kgs


2 Bromo benzanthrone 685 Water Evaporation in Drying 1000

3 2-AminoThiophene 365 Xylene / ODCB Recovery for recycled 950




161

134) Solvent Orange 105 cas no. 31482-56-1: -


Para Nitro Aniline [ cas no.100-101-6] is Diazotized with HCL & Sodium Nitrite at 0 to 5 0C.

Then coupled with Coupler M-8 [ cas no.148-87-8]. Coupled mass is stirred till coupling reaction gets

complete. Then reaction mass is heated up to 75 to 80 0C & filtered. Filtrate is sent to ETP for further



a. Diazotization of PNA

b. Coupling with M-8

PNA Diazo+ M-8 +C.S. Flacks

C6H4CIN3O2 + C11H14N2 +NaOH

Coupling Solvent Orange 105


Mol.Wt. 185.5 + 174 + 40 323 + 18 + 58.5





3 PNA 560 Water Evaporation in Drying 3000



6 M-8 435

7 C.S. Flacks 200




PNA


Diazotization PNA Diazo


Mol.Wt.138 + 73 + 69 185.5 + 58.5 + 36

162

4 Blue Solvent


135) Solvent Blue 35 [ cas no. 17354-14-2]: -


Quinizarine [cas no .91-63-4] is condensed with 2 moles of N-Butyl Amine [NBA cas No.109-


Xylene / ODCB is distilled out for re-use & product is isolated by. Then mass is filtered. Filtrate is



a. Condensation:

Quinizarine N-Butyl Amine

C14H8O4 +2 [C4H11N]

Condensation Sol.Blue 35

C22H26N2O2 +2 H2O

Mol.Wt.240 + 2 x 73 Xylene /

ODCB

350 + 36



Kgs


2 Quinizarine 685 Water Evaporation in Drying 1000

3 N-Butyl Amine 438 Xylene / ODCB Recovery for recycled 950




163

136) Solvent Blue 36[ cas no. 14233-37-5]: -


Quinizarine [cas no .91-63-4.] is condensed with 2 moles of 2-Propan Amine [NBA cas No.75-


Xylene / ODCB is distilled out for re-use & product is isolated by. Then mass is filtered. Filtrate is



a. Condensation:

Quinizarine 2-propane amine

C14H8O4 +2 [C3H9N]


C20H22N2O2 +2 H2O


ODCB

322 + 36



Kgs



3 2-propane Amine 448 Xylene / ODCB Recovery for recycled 950




164

137) Solvent Blue 97[ cas no. 61969-44-6 ]: -


Quinizarine [cas no .91-63-4.] is condensed with 2 moles of Diethyl M-Toluidine [DEMT cas

No.24544-08-9] in the presence of Xylene / ODCB under reflux condition till completion of reaction.

Then Xylene / ODCB is distilled out for re-use & product is isolated by. Then mass is filtered. Filtrate

is collected for recovery of methanol for re-use & cake is washed with hot water. Washing water is

re-used in next batch & cake is dried, pulverized

a. Condensation:

Quinizarine DEMT

C14H8O4 +2 [C11H17N]


C36H38N2O2 +2 H2O


ODCB

530 + 36



Kgs



3 Ortho Toluidine 432 Xylene / ODCB Recovery for recycled 950




165



Quinizarine [cas no .91-63-4.] is condensed with 2 moles of Ortho Toluidine [OT cas No.95-53-

4] in the presence of Xylene / ODCB under reflux condition till completion of reaction. Then Xylene /

ODCB is distilled out for re-use & product is isolated by. Then mass is filtered. Filtrate is collected for

recovery of methanol for re-use & cake is washed with hot water. Washing water is re-used in next


a. Condensation:

Quinizarine Ortho Toluidine

C14H8O4 +2 [C7H9N]


C28H22N2O2 +2 H2O


ODCB

418 + 36



Kgs



3 Ortho Toluidine 432 Xylene / ODCB Recovery for recycled 950




166



Quinizarine [cas no .82-44-0.] is condensed with 1mole of propane 2-amine [OT cas No.95-

53-4]& Methane amine [cas no.74-89-5] each respectively in the presence of Xylene / ODCB under

reflux condition till completion of reaction. Then Xylene / ODCB is distilled out for re-use & product

is isolated by. Then mass is filtered. Filtrate is collected for recovery of methanol for re-use & cake is


a. Condensation:

Quinizarine Propane amine Methane

amine

C14H8O4 +C7H9N + CH5N


C18H18N2O2 +2 H2O

Mol.Wt.240 + 107 + 31 Xylene / ODCB 294 + 36



Kgs



3 Propane Amine 212 Xylene / ODCB Recovery for recycled 950

4 Methane Amine 110 Methanol Recovery for recycled 1900

5 Methanol 2000 Washing water Re-cycle for Re-Use 4262

6 Water for washing 5000


167

140) Solvent Blue 104 [ cas no. 116-75-6 ]: -


Quinizarine [cas no .91-63-4.] is condensed with 2 moles of Mesidine [cas No.88-05-1] in the


distilled out for re-use & product is isolated by. Then mass is filtered. Filtrate is collected for



a. Condensation:

Quinizarine Mesidine

C14H8O4 +2 [C9H13N]


C32H30N2O2 +2 H2O

Mol.Wt.240 2 x 135 Xylene / ODCB 474 36



Kgs



3 Propane Amine 568 Xylene / ODCB Recovery for recycled 950




168

5 Violet Solvent Dyes Quantity per Month =

141) Solvent Violet 13 [ cas no. 81-88-1]: -


Quinzarine [cas no .91-63-4.] is condensed with P-Toluidine [cas No.106-49-0] in the


distilled out for re-use & product is isolated by. Then mass is filtered. Filtrate is collected for



a. Condensation:

Quinzarine P-Toluidine

C14H8O4 + C7H9N

Condensation Sol.Violet 13

C21H15NO3 + H2O


ODCB

329 + 18



Kgs


2 Quinzarine 755 Water Evaporation in Drying 1000

3 P-Toluidine 355 Xylene / ODCB Recovery for recycled 950




169


1,8-Dichloro Anthraquinone [1,8-DCAQ cas no .82-46-2.] is condensed with 2 moles of P-

Toluidine [cas No.106-49-0] in the presence of Xylene / ODCB under reflux condition till completion

of reaction. Then Xylene / ODCB is distilled out for re-use & product is isolated by. Then mass is



a. Condensation:

1,8-DCAQ P-Toluidine

C14H6CI2O2 +2 [C7H9N ] + 2KOH


C28H22N2O2 + 2KCI +2 H2O

Mol.Wt.277 + 2 x 107 + 2 x 56 Xylene /

ODCB

418 + 149 + 36



Kgs


2 1,8-DCAQ 725 Water Evaporation in Drying 1000

3 P-Toluidine 315 Xylene / ODCB Recovery for recycled 950




170



Quinizarine [cas no .91-63-4.] is condensed with 2 moles of 2,6-Dibromo P-Toluidine [2,6-

DBPT cas No.6968-24-7] in the presence of Xylene / ODCB under reflux condition till completion of

reaction. Then Xylene / ODCB is distilled out for re-use & product is isolated by. Then mass is



a. Condensation:

Quinizarine + 2,6-DBPT

C14H8O4 +2 [C7H7Br2N ]


C28H18Br4N2O2 +2 H2O


ODCB

734 + 36



Kgs



3 2,6-DBPT 538 Xylene / ODCB Recovery for recycled 950




171

144) Solvent Violet 59 [ cas no. 6408-72-6-]: -


2,3-Dichloro-1,4-Diamino Anthraquinone [DCDA cas no .81-42-5.] is condensed with 2 moles

of Phenol [cas No.] in the presence of Xylene / ODCB under reflux condition till completion of

reaction. Then Xylene / ODCB is distilled out for re-use & product is isolated by. Then mass is



a. Condensation:

DCDA Phenol

C14H8CI2N2O4 +2 [C6H6O ] + 2 KOH


C26H18N2O2 +2 H2O + 2 KCI

Mol.Wt.307 + 2 x 94 + 2 x

56

Xylene /

ODCB

422 + 36 + 2 x 74.5



Kgs


2 DCDA 765 Water Evaporation in Drying 1000

3 Phenol 247 Xylene / ODCB Recovery for recycled 950




172

6 Green Solvent Dyes Quantity per Month =

145) Solvent Green 3[ cas no. 128-80-3 ]: -


Quinizarine [cas no .91-63-4.] is condensed with 2 moles of P-Toluidine [PT cas No.106-49-0]

in the presence of Xylene / ODCB under reflux condition till completion of reaction. Then Xylene /

ODCB is distilled out for re-use & product is isolated by. Then mass is filtered. Filtrate is collected for



a. Condensation:

Quinizarine PT

C14H8O4 +2 [C18H31N]

Condensation Sol.Green 3

C28H22N2O2 +2 H2O

Mol.Wt.240 + 2 x 107 Xylene / ODCB 418 + 36



Kgs



3 PT 346 Xylene / ODCB Recovery for recycled 950




173

146) Solvent Green 28:[ CAS NO.: 71839-01-5] -


In clean reaction charge ODCB, 1,4-dichloro-5,8-dihydroxyanthracene-9,10-dione and 4-

butylaniline. Heat the reaction mass to 160 temp. and maintain for 18 hrs. cool the reaction mass to

room temp and add methanol for isolation. Filter the reaction mass and wash with water. Dry the

wet cake and pulverize and sent for packing.

Chemical Reaction:

1,4-dichloro-5,8-dihydroxyanthracene-

9,10-dione + 4-butylaniline

C14H6Cl2O4 + (2 x C10H15N)

Condensate Solvent Green 28

C34H34N2O4 + 2HCL

Mol.Wt. 309 + (2x149 ) 534 + 73


Sr.No. Input Qty.in

Kgs

Output Qty.in

Kgs

1 ODCB 1500 Finished Product 1000

2 1,4-dichloro-5,8-

dihydroxyanthracene-9,10-dione

680 ODCB Recovery 1350

3 4-butylaniline 327 Methanol Recovery 1350

4 Methanol 1500 Aqueous ML 1607

5 Water for Washing 2800 Drying Loss 1500


174

147) Solvent Green 33[ cas no. 10671-57-8 ]: -


Quinizarine [cas no .91-63-4.] is condensed with 2 moles of Do Decyl Aniline [DDA cas

No.104-42-7] in the presence of Xylene / ODCB under reflux condition till completion of reaction.

Then Xylene / ODCB is distilled out for re-use & product is isolated by. Then mass is filtered. Filtrate

is collected for recovery of methanol for re-use & cake is washed with hsot water. Washing water is

re-used in next batch & cake is dried, pulverized

a. Condensation:

Quinizarine DDA

C14H8O4 +2 [C18H31N]

Condensation Sol.Green 33

C50H66N2O2 +2 H2O

Mol.Wt.240 + 2 x 261 Xylene / ODCB 726 + 36



Kgs



3 DDA 568 Xylene / ODCB Recovery for recycled 950




175

Annexure : IV :-

FACILITIES FOR STORAGE OF RAW MATERIAL

RAW MATERIAL STORAGE AND HANDLING

Raw Materials are received in drums, carboys, bags, tankers. All Storage tanks of Hazardous

flammable substances are located within premises in separate storage area and stored with all

precautionary process instrumentation and safety appliances. Large area is covered by well-

designed ware house which contain Store office, raw material store, finished products store etc. The

personnel protective equipments like Hand gloves, Safety Shoes, goggles,, clothing etc. are provided

to those handling hazardous chemicals as per requirement.

LIST OF RAW MATERIALS :-

Sr.No. Raw Material Consumption

(MT/MT) CAS No.

Category - A : Pigments :-

Group - 1 : Pigment Red

1 Pigment Red 2 :-

2.5 DCA 0.390 95-82-9

HCI 0.385 7647-01-0

Sodium Nitrite 0.170 7632-00-0

Naphthol AS 0.610 92-77-3

C.S. Flacks 0.200 1310-73-2

2 Pigment Red 3

Red G Base 0.525 89-62-3

HCI 0.385 7647-01-0


B-Naphthol 0.490 135-19-3

C.S. Flacks 0.200 1310-73-2

3 Pigment Red 4

OCPNA 0.550 121-87-9

HCI 0.385 7647-01-0


B-Naphthol 0.445 135-19-3

C.S. Flacks 0.200 1310-73-2

4 Pigment Red 5

Fast Red ITR 0.450 6410-41-9

HCI 0.385 7647-01-0


Naphthol ASITR 0.555 92-72-8

176

C.S. Flacks 0.200 1310-73-2

5 Pigment Red 12

PNPT 0.360 99-52-5

HCI 0.385 7647-01-0


Naphthol ASD 0.680 135-61-5

C.S. Flacks 0.200 1310-73-2

6 Pigment Red 14

PCONA 0.405 89-63-4

HCI 0.385 7647-01-0



C.S. Flacks 0.200 1310-73-2

7 Pigment Red 38

3,3-DCB 0.350 91-94-1

HCI 0.415 7647-01-0


PCEP 0.640 99-33-8

C.S.Flacks 0.200 1310-73-2

8 Pigment Red 48:1

2B Acid 0.550 88-51-7

HCI 0.475 7647-01-0


BON Acid 0.468 92-70-6

C.S.Flacks 0.200 1310-73-2

Barium Chloride 0.200 10361-37-2

9 Pigment Red 48:2

2B Acid 0.550 88-51-7

HCI 0.475 7647-01-0


BON Acid 0.468 92-70-6

C.S.Flacks 0.200 1310-73-2

Calcium Chloride 0.250 10043-52-4

10 Pigment Red 48:3

2B Acid 0.550 88-51-7

HCI 0.475 7647-01-0


BON Acid 0.468 92-70-6

177

C.S.Flacks 0.200 1310-73-2

Strontium Chloride 0.240 10042-76-9

11 Pigment Red 48:4

2B Acid 0.550 88-51-7

HCI 0.475 7647-01-0


BON Acid 0.468 92-70-6

C.S.Flacks 0.200 1310-73-2

Manganese Chloride 0.245 7773-01-5

12 Pigment Red 48:5

2B Acid 0.550 88-51-7

HCI 0.475 7647-01-0


BON Acid 0.468 92-70-6

C.S.Flacks 0.200 1310-73-2

Magnesium Chloride 0.245 7791-18-6

13 Pigment Red 49

Tobias Acid 0.600 81-16-3

HCI 0.475 7647-01-0


B-Naphthol 0.395 135-19-3

C.S.Flacks 0.200 1310-73-2

Sodium Hydroxide 0.245 1310-73-2

14 Pigment Red 49:1


HCI 0.475 7647-01-0


B-Naphthol 0.395 135-19-3

C.S.Flacks 0.200 1310-73-2

Barium chloride 0.245 10361-37-2

15 Pigment Red 49:2


HCI 0.475 7647-01-0


B-Naphthol 0.395 135-19-3

C.S.Flacks 0.200 1310-73-2


16 Pigment Red 49:3

178


HCI 0.405 7647-01-0


B-Naphthol 0.390 135-19-3

C.S. Flacks 0.200 1310-73-2


17 Pigment Red 52:1

C Acid 0.550 88-53-9

HCI 0.475 7647-01-0


BON Acid 0.455 92-70-6

C.S. Flacks 0.200 1310-73-2


18 Pigment Red 52:2

C Acid 0.550 88-53-9

HCI 0.475 7647-01-0


BON Acid 0.455 92-70-6

C.S. Flacks 0.200 1310-73-2


19 Pigment Red 53

C- Acid 0.560 88-53-9

HCI 0.475 7647-01-0


B-Naphthol 0.435 135-19-3

C.S. Flacks 0.200 1310-73-2


20 Pigment Red 53:1

C-Acid 0.560 88-53-9

HCI 0.475 7647-01-0


B-Naphthol 0.435 135-19-3

C.S. Flacks 0.200 1310-73-2

Barium Chloride 0.245 10361-37-2

21 Pigment Red 53:3

C Acid 0.598 88-53-9

HCI 0.405 7647-01-0


B-Naphthol 0.390 135-19-3

179

C.S. Flacks 0.200 1310-73-2


22 Pigment Red 57:1

4B Acid 0.530 88-44-8

HCI 0.475 7647-01-0


BON Acid 0.475 92-70-6

C.S. Flacks 0.200 1310-73-2


23 Pigment Red 63:1


HCI 0.475 7647-01-0


BON Acid 0.475 92-70-6

C.S. Flacks 0.200 1310-73-2


24 Pigment Red 63:2


HCI 0.405 7647-01-0


BON Acid 0.475 92-70-6

C.S. Flacks 0.200 1310-73-2


25 Pigment Red 81

EAMP 0.600 120-37-6

Phthalic Anhydride 0.515 85-44-9

Ethanol 1.000 64-17-5

Phosphomolybdic acid [ PMA] 0.100 12026-57-2

26 Pigment Red 81:1

EAMP 0.600 120-37-6


Ethanol 1.000 64-17-5

Silicotungstomolybdic [SMT ] acid 0.100 867-44-7

27 Pigment Red 81:x

EAMP 0.600 120-37-6


Ethanol 1.000 64-17-5

Phosphoric molybdic [PM]acid 0.100 12026-57-2

180

28 Pigment Red 81:y

EAMP 0.600 120-37-6


Ethanol 1.000 64-17-5

Silicomolybdic [SM]acid 0.100 11089-20-6

29 Pigment Red 81:2

EAMP 0.600 120-37-6


Ethanol 1.000 64-17-5

Silicomolybdic [SM]acid 0.100 11089-20-6

30 Pigment Red 81:3

EAMP 0.600 120-37-6


Ethanol 1.000 64-17-5

Phosphoric molybdic [PM]acid 0.080 12026-57-2

31 Pigment Red 81:4

EAMP 0.600 120-37-6


Ethanol 1.000 64-17-5

Phosphotungstomolybdic [PTMA] acid 0.080 1325-80-0

32 Pigment Red 112

TCA 0.410 636-30-6

HCI 0.395 7647-01-0



C.S. Flacks 0.200 1310-73-2

33 Pigment Red 122

Methanol 5.500 67-56-1

Dimethyl Succinosuccinate 0.800 6289-46-9

p-Toluidine 0.880 106-49-0

Resist Salt 0.300 127-68-4

NaOH 0.275 1310-73-2

HCL 0.250 7647-01-0

Poly Phosphoric Acid 1.800 8017-16-1

DMF / IBA 7.000 68-12-2

34 Pigment Red 123

PTCDA 0.650 128-69-8

181

3,5-DMA 0.395 108-69-0

Pipyridine 0.010 110-86-1

35 Pigment Red 144

DCA 0.490 92-82-9

HCI 0.395 7647-01-0


3-H,2-Naphthoyl Chloride 0.500 2243-83-6

C.S. Flacks 0.250 1310-73-2

DABC 0.180 280-57-9

36 Pigment Red 146

Fast Red KD Base 0.400 120-35-4

HCI 0.395 7647-01-0


Naphthol AS LC 0.595 137-92-1

C.S. Flacks 0.200 1310-73-2

37 Pigment Red 168

Anthanthrone 0.800 641-13-4

Liquid Bromine 0.205 7726-95-6

38 Pigment Red 169

EAMP 0.600 120-37-6


Ethanol 1.000 64-17-5

ferrous iron copper cyanide complex 0.080 544-92-3

39 Pigment Red 170

p-Aminobenzamide 0.305 2835-68-9

HCI 0.405 7647-01-0


Naphthol AS PH 0.688 92-74-0

C.S. Flacks 0.200 1310-73-2

40 Pigment Red 175

Methyl-2-aminobenzoate 0.325 134-20-3

HCI 0.405 7647-01-0


DHNFBZ 0.665 26848-40-8

C.S. Flacks 0.200 1310-73-2

41 Pigment Red 176

Fast Red KD Base 0.445 120-35-4

182

HCI 0.405 7647-01-0


DHNFBZ 0.565 26848-40-8

C.S. Flacks 0.200 1310-73-2

42 Pigment Red 177

Poly Propylene Glycol 2.500 25322-69-4

Bromamine Acid 1.100 116-81-4

KOH 0.250 1310-58-3

Sodium Chlorate 0.050 7775-09-9

43 Pigment Red 178

PTCDA 0.650 128-69-8

PAAB 0.515 60-09-3


44 Pigment Red 179

PTCDA 0.950 128-69-8

MMA 0.150 74-89-5


Acetic Acid 0.055 64-19-7

45 Pigment Red 188

OPLA 0.555 59673-82-4

HCI 0.435 7647-01-0


Naphthol ASOS 0.445 135-62-6

C.S. Flacks 0.200 1310-73-2

46 Pigment Red 202

Methanol 5.500 67-56-1


4-Chloroaniline 0.860 106-47-8

Resist Salt 0.300 127-68-4

NaOH 0.275 1310-73-2

HCL 0.250 7647-01-0


DMF / IBA 7.000 68-12-2

47 Pigment Red 254

Tetra Amyl alcohol 3.800 75-85-4

PCBN 0.810 623-03-0

KOH 0.180 1310-58-3

DIPS 0.411 924-88-9

183

48 Pigment Red 256

ADCDMBSA 0.518 26175-68-8

HCI 0.405 7647-01-0


Naphthol ASOL 0.492 135-62-6

49 Pigment Red 264

Tetra Amyl alcohol 3.800 75-85-4

PPBN 0.835 2920-38-9

KOH 0.180 1310-58-3

DIPS 0.425 924-88-6

Group - 2 : Pigment Yellow

50 Pigment Yellow 1

MNPT 0.450 89-62-3

HCI 0.475 7647-01-0


Acetoacetanilide 0.510 102-01-2

51 Pigment Yellow 3

PCONA 0.410 89-63-4

HCI 0.435 7647-01-0


AAOCA 0.510 93-70-9

C.S.Flacks 0.200 1310-73-2

52 Pigment Yellow 12

3,3-DCB 0.264 91-94-4

HCI 0.500 7647-01-0


AAA 0.730 102-01-2

C.S. Flacks 0.190 1310-73-2


3,3-DCB 0.340 91-94-4

HCI 0.435 7647-01-0


AAMX 0.715 97-36-9

C.S.Flacks 0.200 1310-73-2


3,3-DCB 0.340 91-94-4

184

HCI 0.435 7647-01-0


AAOT 0.715 93-68-5

C.S.Flacks 0.200 1310-73-2


2,4-DCA 0.650 554-00-7

HCI 0.675 7647-01-0


Naphthol ASIRG 0.425 4433-79-8

C.S.Flacks 0.200 1310-73-2


3,3-DCB 0.380 91-94-4

HCI 0.485 7647-01-0


AAOA 0.625 92-15-9

C.S.Flacks 0.200 1310-73-2


ONAPSA 0.450 616-84-2

HCI 0.475 7647-01-0


AAA 0.510 102-01-2

C.S.Flacks 0.200 1310-73-2



ONAPSA 0.450 616-84-2

HCI 0.475 7647-01-0


AAOT 0.500 93-68-5

C.S.Flacks 0.200 1310-73-2



3,3-DCB 0.390 91-94-4

HCI 0.485 7647-01-0


AAOCA 0.685 93-70-9

C.S.Flacks 0.200 1310-73-2


MNPA 0.440 96-96-8

HCI 0.475 7647-01-0

185


AAOA 0.510 92-15-9

C.S.Flacks 0.200 1310-73-2



PCONA 0.450 89-63-4

HCI 0.475 7647-01-0


AAOA 0.510 95-15-9

C.S.Flacks 0.200 1310-73-2



MNOA 0.465 97-52-9

HCI 0.475 7647-01-0


AAOA 0.515 95-15-9

C.S.Flacks 0.200 1310-73-2



3,3-DCB 0.390 91-94-4

HCI 0.485 7647-01-0


AADMCA 0.685 4433-79-8

C.S.Flacks 0.200 1310-73-2


OAPC 0.620 59158-04-2

HCI 0.575 7647-01-0


NN-CMBT 0.340 39098-85-6

C.S. Flacks 0.335 1310-73-2


DMASA 0.470 52298-44-9

HCI 0.475 7647-01-0


NAPTHOL AS-IRG 0.515 4433-79-8

C.S.Flacks 0.200 1310-73-2



186

2-hydroxynaphthalene-1-carbaldehyde 1.052 708-06-5

Dihydrazine 0.090 301-01-2

Methanol 4.000 67-56-1


5-AIPA-DME 0.490 99-27-4

HCI 0.475 7647-01-0


AABI 0.510 26576-46-5

C.S. Flacks 0.220 1310-73-2

Aluminum Hydroxide 0.135 21645-51-2


3,3-DCB 0.390 91-94-4

HCI 0.485 7647-01-0


AAMX 0.625 97-36-9

C.S. Flacks 0.200 1310-73-2


ODCB / Xylene 3.000 95-50-1

Tetrachloro Phthalic Anhydride 0.750 117-08-8

8-amino Quinaldine 0.275 18978-78-4

Benzoic Acid 0.030 65-85-0

Methanol 1.000 67-56-1


Phthalonitrile 0.350 91-15-6

Barbituric acid 0.700 67-52-7

HCL 0.175 7647-01-0

71 Pigment Yellow 151`

Anthranillic Acid 0.490 118-92-3

HCI 0.375 7647-01-0


AABI 0.510 26576-46-5

C.S. Flacks 0.220 1310-73-2



2,3-Dinitroso-n-phenylbutanamide 0.775 N.A.

C.S. Flacks 0.200 1310-73-2

Nickel Chloride 0.200 7718-54-9

187


ATFT 0.490 88-17-5

HCI 0.375 7647-01-0


AABI 0.510 26576-46-5

C.S. Flacks 0.220 1310-73-2



ADMT 0.615 5372-81-6

HCI 0.515 7647-01-0


DAPDAB 0.400 25731-73-5

C.S. Flacks 0.240 1310-73-2


Pigment yellow 13 0.500 5102-83-0

ICE Pigment Yellow 14 0.500 5468-75-5


2-EDDA 0.380 52411-34-4

HCI 0.485 7647-01-0


AABI 0.600 26576-46-5

C.S.Flacks 0.200 1310-73-2


PABB 0.490 74441-06-8

HCI 0.475 7647-01-0


AABI 0.510 26576-46-5

C.S. Flacks 0.220 1310-73-2



ADMT 0.490 27210-70-4

HCI 0.475 7647-01-0


AAMAQ 0.510 N.A.

C.S. Flacks 0.220 1310-73-2



DCASA 0.460 6331-96-0

188

HCI 0.475 7647-01-0


1,3-SPMP 0.490 119-17-5

C.S.Flacks 0.200 1310-73-2



2B Acid 0.475 88-51-7

HCI 0.275 7647-01-0


1,3-SPMP 0.495 119-17-5

C.S. Flacks 0.200 1310-73-2


81 Pigment Yellow 191:1

2B Acid 0.475 88-51-7

HCI 0.275 7647-01-0


1,3-SPMP 0.495 119-17-5

C.S. Flacks 0.200 1310-73-2

Ammonium Chloride 0.160 12125-02-9

Group - 3 : Pigment Orange

82 Pigment Orange 5

2,4-DNA 0.518 97-02-9

HCI 0.270 7647-01-0


Beta Naphthol 0.435 135-19-3

C.S. Flacks 0.200 1310-73-2

83 Pigment Orange 13

3,3-DCB 0.490 91-94-4

HCI 0.385 7647-01-0


PMP 0.510 89-25-8

C.S.Flacks 0.200 1310-73-2


ODA 0.495 119-90-4

HCI 0.385 7647-01-0


AOA 0.500 102-01-2

C.S.Flacks 0.200 1310-73-2

189


3,3-DCB 0.495 91-94-4

HCI 0.385 7647-01-0


PTMP 0.518 86-92-0

C.S.Flacks 0.200 1310-73-2


PCONA 0.505 89-63-4

HCI 0.385 7647-01-0


AABI 0.500 26576-46-5

C.S.Flacks 0.200 1310-73-2


1.4.5.8-naphthalenetetracarboxylicacid-1,8-

monoanhydride

0.730

128-97-2

1,2-diaminobenzene 0.552 95-54-5


PNA 0.375 100-101-6

HCI 0.385 7647-01-0


AABI 0.625 26576-46-5

C.S.Flacks 0.200 1310-73-2


Methyl aminolone 0.500 67014-36-2

HCI 0.385 7647-01-0


Barbituric Acid 0.510 67-52-7

C.S.Flacks 0.200 1310-73-2

Group - 4 : Pigment Blue

90 Pigment Blue 1

KOH 0.270 1310-58-3

PTCBAD 0.780 81-33-4

PMBCI 0.250 824-94-2

91 Pigment Blue 15

NB / DCB 3.500 7440-03-1


Urea 0.890 57-13-6

Cuprous Chloride 0.205 7758-89-6

Ammonium Molybdate 0.003 12054-85-2

190

Steam 1.800 7732-18-5

45% Spent H2SO4 5.800 7664-93-9

92 Pigment Blue 15:1

CPC Blue Crude 1.100 147-14-8

Sulphuric Acid 98% 5.000 7664-93-9

Ammonium Hydroxide 1.500 1336-21-6



Solvent 5.000 108-90-7

Surfactant 0.010 112-80-1



Solvent 5.000 108-90-7




Solvent 5.000 108-90-7




Solvent 5.000 108-90-7


97 Pigment Blue 16


AICI3 0.700 7446-70-0

NaCI 0.300 7647-14-5

Chlorine Gas 0.350 772-50-5

98 Pigment Blue 60

Poly Ethylene Glycol 1.350 35322-68-3

KOH 0.270 1310-58-3

Sodium Chlorate 0.112 09-09-75

2-Amino Anthraquinone 1.020 117-79-3

99 Pigment Blue 62

KOH 0.270 1310-58-3

PTCBAD 0.790 81-33-4

BCI 0.250 100-44-7

191

Group - 5 : Pigment Violet

100 Pigment Violet 1

DEMAP 0.600 1326-03-0


Ethanol 1.000 64-17-5

Phosphomolybdic acid [ PMA] 0.100 12026-57-2

101 Pigment Violet 1x

EAMP 0.600 120-37-6


Ethanol 1.000 64-17-5

Silicomolybdic acid [ SM] 0.100 11089-20-6


DMA 0.600 121-69-7


Ethanol 1.000 64-17-5

Phosphomolybdic acid [ PM] 0.100 12026-57-2


Methanol 5.500 67-56-1


Aniline 0.830 106-47-8

Resist Salt 0.300 127-68-4

NaOH 0.275 1310-73-2

HCL 0.250 7647-01-0


DMF / IBA 7.000 68-12-2


Mono Chloro Benzene 1.000 108-90-7

Carbazole 0.800 86-74-8

Di Ethyl Sulphate 0.470 64-67-5

NaOH Flacks 0.500 1310-73-2

Nitric Acid 45% 0.600 7697-37-2

Hydrogen Gas 0.008 1333-74-0

Ortho Dichloro Benzene 10.000 95-50-1

Sodium acetate 0.050 127-09-3

Methanol 5.000 67-56-1

Raney Nickel 0.008 12635-27-7

DEG 1.000 111-46-6


Methyl Violet 0.714 8004-87-3

192

Copper Sulfate 0.159 7758-98-7

Sodium FeroCynide 0.303 13601-19-9


DMA 0.600 121-69-7


Ethanol 1.000 64-17-5

Ferrous Iron copper cyanide [ PM] 0.100 14038-43-8

Category - B : Solvent Dyes

Group - 1 : Red Solvent Dyes

107 Solvent Red 19E

Garnet GB Base 0.500 97-56-3

HCI 0.400 7647-01-0


n-ENA 0.435 2437-03-8

C.S. Flacks 0.200 1310-73-2


108 Solvent Red 23

4-(phenyldiazenyl) aniline (PAAB) 0.575 60-09-3



Naphthalen-2-ol (Beta Naphthol) 0.420 135-19-3

109 Solvent Red 24

Garnet GB Base 0.600 97-56-3

HCI 0.400 7647-01-0



C.S. Flacks 0.200 1310-73-2


110 Solvent Red 52

Xylene / ODCB 1.000 95-50-1

6-BAP 0.700 81-85-6

p-Toluidine 0.310 106-49-0

Methanol 2.000 67-56-1

111 Solvent Red 111

Xylene / ODCB 1.000 95-50-1

1-Chloro AQ 0.713 82-44-0

Methane amine 0.250 74-89-5

Methanol 2.000 67-56-1

193

112 Solvent Red 135

Xylene / ODCB 1.000 95-50-1

TCAP 0.685 117-08-8

1,8-DAN 0.350 479-27-6

Methanol 2.000 67-56-1

113 Solvent Red 151

Xylene / ODCB 1.000 95-50-1

6-BAP 0.690 81-85-6

3-Chloroaniline 0.315 108-42-9

Methanol 2.000 67-56-1

114 Solvent Red 168

Xylene / ODCB 1.000 95-50-1

1-Chloro AQ 0.713 82-44-0

Cyclo hexyl amine 0.291 108-91-8

Methanol 2.000 67-56-1

115 Solvent Red 169

Xylene / ODCB 1.000 95-50-1

1-Chloro AQ 0.805 82-44-0

2-propanolamine 0.205 175-31-0

Methanol 2.000 67-56-1

116 Solvent Red 179

Xylene / ODCB 1.000 95-50-1

1,8-DAN 0.445 479-27-6

1,8-Naphthalic Anhydride 0.560 81-84-5

Methanol 2.000 67-56-1

117 Solvent Red 197

Xylene / ODCB 1.000 95-50-1

DEAMAP Aldehyde 0.525 17754-90-4

2-A,2,3-DHHBMMP 0.590 6301-29-7

Methanol 2.000 67-56-1

118 Solvent Red 207

Xylene / ODCB 1.000 95-50-1

1,8-DCAQ 0.725 82-43-9

Cyclo Hexylamine 0.295 108-91-8

Methanol 2.000 67-56-1

119 Solvent Red 227

Xylene / ODCB 1.000 95-50-1

194

1-Chloro AQ 0.795 82-44-0

Aniline 0.215 62-53-3

Methanol 2.000 67-56-1

Group - 2 : Yellow Solvent Dyes

120 Solvent Yellow 2

Aniline 0.415 62-53-3

HCL 1.000 7647-01-0


D.M.A. 0.545 127-19-5


Aniline 0.415 62-53-3

HCL 1.000 7647-01-0


Soda Ash/ NaOH 0.200 1310-73-2


HCL 1.290 7647-01-0

2,4-dimethylaniline (2,4 Xylidine) 0.425 95-68-1


sodium hydroxide 0.130 1310-73-2

5-methyl-2-phenylpyrazolidin-3-one (P.M.P.) 0.580

89-25-8


Xylene / ODCB 1.000 95-50-1


Quinaldine 0.500 91-63-4

Methanol 2.000 67-56-1


Methanol 2.000 67-56-1

1-ChIoro-1,8-Naphthaline. 0.735 4053-08-1

n-Butyl Amine 0.300 12226-96-9

C.S.Lye 0.200 1310-73-2


Methanol 2.000 67-56-1

1-Amino-1,8-Naphthaline. A 0.635 6492-86-0

2,5-DMA 0.400 95-78-3


HCL 1.300 7647-01-0

2-methoxyaniline 0.410 90-04-0


195

Sodium hydroxide 0.130 1310-73-2

5-methyl-2-phenylpyrazolidin-3-one 0.597 89-25-8


Xylene / ODCB 1.500 95-50-1

3-Hydroxy-2-methyl-4-quinolinecarboxylic acid 0.615

117-57-7


Methanol 2.000 67-56-1


Methanol 2.300 67-56-1

6-chloro-1H,3H-benzo[de]isochromene-1,3-dione 0.727

4053-08-1

3-aminopropan-1-ol 0.300 156-87-6


Xylene / ODCB 1.000 95-50-1

Tetra Chloro Phthalic Anhydride 0.605 117-08-8

Quinaldine 0.455 91-63-4

Methanol 2.000 67-56-1


Xylene / ODCB 1.000 95-50-1

1, 8-Dichloro AQ 0.650 82-43-9

Thiophene 0.405 108-98-5

Methanol 2.000 67-56-1


Xylene / ODCB 1.000 95-50-1

1-chloro AQ 0.685 82-44-0

Thiophene 0.365 108-98-5

Methanol 2.000 67-56-1

Group - 3 : Orange Solvent Dyes

132 Solvent Orange 60

Xylene / ODCB 1.000 95-50-1

1, 8-DAAQ 0.500 82-43-9


Methanol 2.000 67-56-1


Xylene / ODCB 1.000 95-50-1

Bromo benzanthrone 0.685 81-96-9

2-AminoThiophene 0.365 137-07-5

196

Methanol 2.000 67-56-1


PNA 0.560 100-101-6

HCI 0.475 7647-01-0


M-8 0.435 148-87-8

C.S. Flacks 0.200 1310-73-2


Group - 4 : Blue Solvent Dyes

135 Solvent Blue 35

Xylene / ODCB 1.000 95-50-1

Quinizarine 0.685 91-63-4

N-Butyl Amine 0.438 109-73-9

Methanol 2.000 67-56-1

136 Solvent Blue 36

Xylene / ODCB 1.000 95-50-1


2-propane Amine 0.448 75-31-0

Methanol 2.000 67-56-1

137 Solvent Blue 97

Xylene / ODCB 1.000 95-50-1


Ortho Toluidine 0.432 95-53-4

Methanol 2.000 67-56-1

138 Solvent Blue 101

Xylene / ODCB 1.000 95-50-1


Ortho Toluidine 0.432 95-53-4

Methanol 2.000 67-56-1


Xylene / ODCB 1.000 95-50-1


Propane Amine 0.212 95-53-4

Methane Amine 0.110 74-89-5

Methanol 2.000 67-56-1


Xylene / ODCB 1.000 95-50-1

197


Propane Amine 0.568 95-53-4

Methanol 2.000 67-56-1

Group - 5 : Violet Solvent Dyes

141 Solvent Violet 13

Xylene / ODCB 1.000 95-50-1

Quinzarine 0.755 91-63-4

P-Toluidine 0.355 106-49-0

Methanol 2.000 67-56-1


Xylene / ODCB 1.000 95-50-1

1,8-DCAQ 0.725 82-46-2

P-Toluidine 0.315 106-49-0

Methanol 2.000 67-56-1


Xylene / ODCB 1.000 95-50-1


2,6-DBPT 0.538 6968-24-7

Methanol 2.000 67-56-1


Xylene / ODCB 1.000 95-50-1

DCDA 0.765 81-42-5

Phenol 0.247 108-95-2

Methanol 2.000 67-56-1

Group - 6 : Green Solvent Dyes

145 Solvent Green 3

Xylene / ODCB 1.000 95-50-1


PT 0.346 106-49-0

Methanol 2.000 67-56-1

146 Solvent Green 28

ODCB 1.500 95-50-1

1,4-dichloro-5,8-dihydroxyanthracene-9,10-dione 0.680

2832-30-6

4-butylaniline 0.327 104-13-2

Methanol 1.500 67-56-1

147 Solvent Green 33

198

Xylene / ODCB 1.000 95-50-1


DDA 0.568 104-42-7

Methanol 2.000 67-56-1

199

Annexure : V

Details of treatment of Effluent (scheme and disposal) :-

1. Industrial Effluent :-

A) Concentrated Effluent

B) Dilute Effluent

Treatment of Effluent :-

A) Concentrated Effluent

a) Effluent Characteristics (Before and After Treatment ).:-

Sr.No Parameter Inlet Outlet

1 PH 6.0-9.5 7.0-7.5

2 COD (mg/L) 2000-5000 80-100

3 BOD (mg/L) 700-900 30-60

4 TDS(mg/L) 15000 150-200

b) Effluent Treatment Process :-

1. Pre-Treatment Section

2. PFET (Polymeric Film Evaporation Technology)

3. MEE (3 Stage Multi effect Evaporator)

1.PRE- TREATMENT SECTION:-

Initially Concentrate Effluent Comes to an equivalisation cum collection Tank( Feed

Tank to ETP process plant). from feed tank, effluent is pumped to DAF through pipe

Flocculation, where Oil & Grease Will be removed. DAF outlet goes to Flash Mixer to

Flocculation and to Clarifier, Where hardness will be removed by Dosing Chemicals.

Clarifier treated water goes to PEET Feed Tank and Clarifier bottom outlet goes to

Sludge sump and sludge will be disposed after dewatering by filter press.

2.PEET SECTION:-

From PEET tank, effluent is pumped to PEET Vessel, where water evaporation is done

at lower temperature under vacuum by passing steam for sensible heating and vapour is re-

compressed by means of centrifugal fan to utilize flash vapour heat. Condensate water (pure

water) is collected separately to Condensate storage tank and concentrate is collected in MEE

Feed tank.

200

3.MEE SECTION:-

From MEE Feed tank, Condensate effluent feed to MEE system where water is boiled

under vacuum by passing steam in three stage multi effect evaporator. TVR (Thermo Vapour

Recompressor) is used to enhance the steam economy. After Super Saturation Stage, salt is

precipitated in Flash vessel, which will be removed in basket Centrifuge at 15% Moisture and

mother Liquor again recirculated in 3rd

effect. Condensate water will be collected in

Condensate storage tank (pure water).

B) Dilute Effluent :-

Dilute Effluent From Washing & Boiler Blow Down comes to another collection cum

equivalisation tank (Feed Tank to RO) where effluent passess through RO and Consentrated

Stream gose to MEE and permeate stream gose for recycle in the plant.

2. Domestic Effluent :-

Domestic Ffluent will be disposed through Septic Tank & Soakpit arrangement.

201

ETP Flow Diagram :-

202

Annexure : VI

Detail of Hazardous Waste Generation & Disposal :

Sr.

no.

Type/Name of

Hazardous

waste

Source of

generation

Category and

Schedule as per

HW Rules.

Quantity

(MT/Month)

Disposal Method

1. ETP Dry Sludge ETP Sch-I/

35.3

15 MT/Month Collection, Storage, Transportation

& Disposal to TSDF Site

2. Used Oils Machineries

&

Equipment

Sch-I/

5.1

50 Lts /Months Collection, Storage, Transportation

& Sale out to Registered refineries

3. Discarded

Bags,

Containers &

Drums

Raw

Materila

storage

Sch-I/

33.1

12000Nos./Month Collection, Storage, Transportation

& Used for in-house packing of

some intermediates & ETP wastes,

& return back to Raw Material

suppliers for same products

4. MEE Salt ETP Sch-I/

33.1

75 MT/Month Collection, Storage, Transport and

send to common TSDF Site for

Disposal or Sale to actual user

having Rule 9 Permission

5 Spent Acid Process Sch-I/

26.3

100 MT/ Month

Collection, Storage, Transportation

& Reuse in own premises in

manufacturing process / Sale to

actual user having Rule 9

Permission

3 HCL

[Hydrochloric

Acid]

Process Sch-2/

Class C15

800 MT/Month

4 Ammonium

Carbonate

Process Sch-2/

--

300

5 Sodium Hypo

chloride

Process Sch-2/

--

320

6 Fly Ash from

Boiler

-- -- 120 MT /Month Collection, Storage, Transportation

and sent to brick manufactuere.

7 Spent Solvents Process 26.4/sch-I 8 MT/Month Collection, Storage, Transportation

& Reuse in own premises in

manufacturing process / Sale to

actual user having Rule 9

Permission

203

Annexure : VII

Water (Expected Source & Completing users) Unit : KLD

1. Water Source : Ground Water

2. Quantity of Water Required :-

Sr.No. Stream Fresh Water

in KLD

Recycled Water

in KLD

Total Water

in KLD

(A) Domestic 8 0 8

(B) Garderning 8 0 8

(C) Industrial 108 269 377

Total 124 269 393

Details of Water Consumtion, Waste Water generation and treatment :-

3. Water Balance :- Water Consumption & wastewater generation:-

SR.

NO. PURPOSE

WATER CONSUMPTION

(KL/Day)

WASTE WATER GENERATION

(KL/Day)

(A) Domestic 8 6

(B) Gardening 8 0

(C) Industrial

Process 200 151

Scrubbing 1 1

Washing 120 117

Boiler 40 4

Cooling Tower 16 2

Total (C) 377 275

TOTAL (A+B+C) 393 281

*Out of Total 393 KLD Water Consumption:

1. Fresh water will be 124 KLD

(Domestic 8KLD + Gardernining 8KLD + Industrial 108KLD)

2. Recycled Water will be 269 KLD (Total Industrial Only)

Domestic

Sewage It is disposed off through septic/soak pit tank.

Industrial

Effluent There shall be no wastewater discharge, treated waste water will be re-use

back, & thereby will be achieved Zero Liquid discharge

204

Water consumption, Waste Water generation and Treatment Diagram :-

205

ANNEXURE-VIII

DETAILS OF STACK AND VENTS

Sr.

No.

Source of emission

With Capacity

Stack

Height

(meter)

Quantity

in No. Type of

Fuel

Quantity

of Fuel

MT/Day

Type of

emissions i.e.

Air Pollutants

Air Pollution Control

Measures

(APCM)

1 Hot Air Gen.

(200000 kcal) 32 Mtrs

4

(U2-8) PNG

320

Cu.mt./

Hrs

PM

SO2

NOx

Adequate stack height

2

Steam Boiler

5 Ton/hr.

32 Mtrs

1

Briquette

/ Coal

2000kg /

Hrs

Adequate stack Multi

cyclone separator

Dust Collector

& Bag filter

3 Thermopack Boiler

(200000 kcal) 30 Mtrs

1

Briquites 2000

Kgs/ Hr.

Adequate stack Multi

cyclone separator

Dust Collector

& Bag filter

4

DG Set

250 KVA × 2 Nos.

(Stand By)

11 Mtrs

2

HSD 100

Lit/hr Adequate stack height

5 Spin Flash Dryer

(Close Loop)

Close

Loop

6

PNG

480

Cu.mt./

Hrs

No N.A.

6 Spray Dryer 15 Mtr.

2

PNG

160

Cu.mt./

Hrs

No

Water Immerserd

Cyclone separator for

Dust Collector

206

ANNEXURE-IX

STORAGE AND HANDLING OF HAZARDOUS CHEMICALS

Sr.

No.

Name of

Hazardous

Chemical

Quantity

No. of

Storages

Tank

Places of

its

Storage

State &

Type of

Hazard

Control Messures

Provided

Max.

That

can be

stored

Actually

stored

(Including

in Process

&

Handling)

1 HCL (30%) 500MT 300MT 10 Tank

Tank

Farm

Area

Liquid &

Corrosive

• Closed handling and

traffereing Systems for

Hazardous Chemicals.

• Dyke wall and material

collection systems are

provided to all

material storage

tank/s.

• Fire Extiguishers and

absorbents will be

available near Storage

tanks and storage area

2 H2SO4 20MT 10MT 1 Tank Storage

Area

Liquid &

Corrosive

3 Acetic Acid 500MT 250MT 10 Tank

Tank

Farm

Area

Liquid &

Corrosive

4 Nitic Acide 50 MT 10MT 1 Tank

Tank

Farm

Area

Liquid &

Corrosive

PRECAUTION DURING STORAGE , TRANSPORTATION AND HANDLING OF HAZARDOUS CHEMICALS :-

1. Liquids :-

• Always use the road tankers having authorization for transporting the said material.

• Vendor asks to provide MSDS to tanker driver

• Tankers clearly mark indentification of material being contained with mentioning

Safety card.

• Diver to have concerned safety office’s contact details to contact hi, in case of

emergency.

• Provide muffler on exhaust while etntering tanker within premises

• Ensure earthing before starting any tranfferring.

• SOP to cover routine checking of Tank farm area to be carried our for checking any

spillage leakage.

• Reading temperature & pressure are noted, recorded & reported immediately for

intakeness.

• Safety instruments like repture disc, Safety Valves checks at defined duration for

intakeness.

• Scheduled testing of tanks to be done for thickness testing.

• Tanks to be painted or regular interval defined as per laws to protect them from

atmospheric corrosion.

207

• Concerned persons are trained properly to use spill kit in case of observing any

spillage inside warehouse.

2. Solids :-

• Vendor asks to provide MSDS to truck driver

• Diver to have concerned safety office’s contact details to contact hi, in case of

emergency.

• Provide muffler on exhaust while etntering tanker within premises

• SOP to cover routine checking of Tank farm area to be carried our for checking any

spillage leakage.

3. Handling Corrosive Chemicals :-

When in contact with human tissues, most corrosive substances reduce chemical

burns while certain other substances produce deep ulceration. Many corrosive substances

have a defeating action on the skin and may cause dermatitis.

The Safegaurds against these hazards are :-

• Preventing or minimizing contact between corrosive substabnces and skin, mucos

membranes and eyes.

• Corrosive substances are not allowed to come in sontact with material that may

react.

• All the contains, Pipes, apparatus, installations and structures used for the

manufacture, storage, transport or use of these substance are protected by suitable

coating, impervious to and unaffected by corrosives.

• All Containers or receptacies are clearly labled to indicate their contents and should

bear the danger symbol for corrosive.

• A high standard of maintance and good house keeping is essential.

• Adequate ventilation and exhaust arrangement whether general or local, should be

provided whenever corrosive toxic gased or dust are present.

• Personal Protective devices are uased depending upon the nature of work viz;

1) Corrosion-resistant and impersious suits, or hand gloves, aprons etc.

2) Respirator, Gas mask or self contained breathing apparatus.

3) Barrier cream when exposure is not severe.

• First Aid Treatment facilities are provided and all concern are instructed to folloe safe

practiced such as ;

1) Proloned washinfg with Water

2) Removing Contaminated Clothing

3) Seeking immediate medical help

• Safety showers and eye washers are provided.

208

ANNEXURE-X

RISK OF ACCIDENT OF THE PROJECT WHICH COULD BE AFFECT HUMAN HELATH OR THE

ENVIROMENT FROM ANY OTHER CAUSES.

Other Hazardos and Control :-

Sr.

No.

Name of the possible

Hazard or Emergency

Its Sources &

Reasons

Its Effects on

Persons,

Property &

Environment

Place of its

Effect

Control Measures

Provided

1 Electricity

(1)Burning

(2)Fire

(3)Shock

Loose

Contacts, weak

Earthing Short

Circuit,

Improper

Insulation

Burning, Shock,

Death

Surrounding

the accident

area

Proper Earthing,

Peridical Checking

of joints, Proper

Insulations of

Equipments etc.

3 Pipe Line Leakage

(1)Corrosion

(2)Toxic gas release

Leaking of Pipe

line due to

corrosion,

Loose contact,

etc.

Physical/

Chemical

Thermal Burn

inhury (Major

/Minor)

Plant Area Proper

maintenance,

Proper Selection of

material for pipe

lines.

4 Structural Failure Inside the

Factory

Injury / Death to

person, damage

to property

In the Factory Automatic

operestio periodic

testing of safety

valves, regular

inspection and

maintenance.

5 Toxic realease from

ourtside

Outside the

factory

Injury/ Death Within &

outside the

unit

Alarm, Evacuation

recue the Welfare

6 Natural Calamity Nature Injury / Death to

persons, damage

to property

Within &

outside the

unit

Alarm, Evacuation

recue the Welfare

209

ANNEXURE-XI

SOCIO - ECONOMIC IMPACTS

1) EMPLOYMENT OPPORTUNITIES :-

The manpower requirement for the proposed project is being expected to generate some

permanent jobs and secondary jobs for the operation and maintenance of plant. This will increase

direct / indirect employment opportunities and ancillary business development to some extent for

the local population.

This phase is expected to create a beneficial impact on the local socio-economic environment.

2) INDUSTRIES :-

Required raw materials and skilled and unskilled laborers will be utilized maximum from the

local area. The increasing industrial activity will boost the commercial and economical status of the

locality, to some extent.

3) PUBLIC HEALTH :-

The company regularly examines, inspects and tests its emission from sources to make sure

that the emission is below the permissible limit. Hence, there will not be any significant change in

the status of sanitation and the community health of the area, as sufficient measures have been

taken and proposed under the EMP.

4) TRANSPORTATION AND COMMUNICATION :-

Since the existing factory is having proper linkage for the transport and communication, the

development of this project will not cause any additional impact.

In brief, as a result of the proposed project there will be no adverse impact on sanitation,

communication and community health, as sufficient measures have been proposed to be taken

under the EMP. The proposed project is not expected to make any significant change in the existing

status of the socio - economic environment of this region.

210

ANNEXURE-XII

PROPOSED TERMS OF REFERENCE FOR EIA STUDIES

1. Project Description :-

• Justification of project.

• Promoters and their back ground

• Project site location along with site map of 5 km area and site details providing various

industries, surface water bodies, forests etc.

• Project cost

• Project location and Plant layout.

• Existing infrastructure facilities

• Water source and utilization including proposed water balance.

• List of Products and their capacity

• List of hazardous chemicals with their toxicity levels.

• Mass balance of each product along with the batch size

• Storage and Transportation of raw materials and products.

2. Description of the Environment and Baseline Data Collection :-

• Micrometeorological data for wind speed, direction, temperature, humidity and rainfall in 5

km area.

• Study of Data from secondary sources.

• Existing environmental status Vis a Vis air, water, noise, soil in 5 km area from the project

site. For SPM, RSPM, SO2, NOx.

• Ground water quality at 5 locations within 5 km.

• Complete water balance

3. Socio Economic Data :-

• Existing socio-economic status, land use pattern and infrastructure facilities available in the

study area were surveyed.

4. Impacts Identification and Mitigatory Measures. :-

• Impact on air and mitigation measures including green belt

• Impact on water environment and mitigation measures

• Soil pollution source and mitigation measures

• Noise generation and control.

• Solid waste quantification and disposal.

• Control of fugitive emissions

211

5. Environmental Management Plan :-

• Details of pollution control measures

• Environment management team

• Proposed schedule for environmental monitoring including post project

6. Risk Assessment :-

• Details on storage facilities

• Identification of hazards

• Consequence analysis

• Recommendations on the basis of risk assessment done

• Disaster Management Plan.

7. Information for Control of Fugitive Emissions

8. Post Project Monitoring Plan for Air, Water, Soil and Noise.

9. Occupational Health and Safety Program for the Project.

212

ANNEXURE-XIII

LEASE OF PLOT :-

213

Documents

Sr. No. Name of Annexure Page No....85 85 4 Pigment Orange 34 15793-73-4 LD50 Oral, Rat 8250 mg/kg 86 86 5 Pigment Orange 36 12236-62-3 LD50 Oral, Rat 8210 mg/kg 87 87 6 Pigment Orange