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Report EUR 26769 EN
2 01 4
Hans Saveyn, Peter Eder, Elena Garbarino, Lenka Muchova, Ole Hjelmar, Hans van der Sloot, Rob Comans, André van Zomeren, Jiri Hyks, Anke Oberender
Study on methodological aspects regarding limit values for pollutants in aggregates in the context of the possible development of end-of-waste criteria under the EU Waste Framework Directive Appendix Part 1
European Commission
Joint Research Centre
Institute for Prospective Technological Studies
Contact information
Hans Saveyn
Address: Edificio Expo. c/ Inca Garcilaso, 3. E-41092 Seville (Spain)
E-mail: [email protected]
Tel.: +34 954 488 470
Fax: +34 954 488 426
https://ec.europa.eu/jrc
https://ec.europa.eu/jrc/en/institutes/ipts
This publication is a Technical Report by the Joint Research Centre of the European Commission.
Legal Notice
This publication is a Technical Report by the Joint Research Centre, the European Commission’s in-house science service.
It aims to provide evidence-based scientific support to the European policy-making process. The scientific output expressed
does not imply a policy position of the European Commission.Neither the European Commission nor any person
acting on behalf of the Commission is responsible for the use which might be made of this publication.
JRC91036
EUR 26769 EN
ISBN 978-92-79-39781-3 (PDF)
ISSN 1831-9424 (online)
doi:10.2791/11763
Luxembourg: Publications Office of the European Union, 2014
© European Union, 2014
Reproduction is authorised provided the source is acknowledged.
European Commission
Joint Research Centre
Institute for Prospective Technological Studies
Study on methodological aspects regarding limit values for pollutants in aggregates in the context
of the possible development of end-of-waste criteria under the EU Waste Framework Directive
Final Report September 2014
Appendix Part 1:
Leaching data
JRC-IPTS
Hans Saveyn1, Peter Eder1, Elena Garbarino1, Lenka Muchova1, Ole Hjelmar2, Hans van der Sloot3, Rob Comans4, André van Zomeren4, Jiri Hyks2, Anke Oberender2
1. European Commission, Joint Research Centre, Institute for Prospective Technological
Studies IPTS), Spain 2. DHI, Denmark
3. Hans van der Sloot Consultancy, The Netherlands 4. ECN, The Netherlands
Final Report Appendix Part 1: Leaching data
A possible methodology for setting pollutant limit values for aggregates in the EoW framework JRC-IPTS 2
TABLE OF CONTENTS
Appendix 1 RecCon Appendix 2 RecBrick Appendix 3 RecGls Appendix 4 MixC&D Appendix 5 RecAsph Appendix 6 BFSlag Appendix 7 BOFSlag Appendix 8 EAFSlag Appendix 9 PSlag Appendix 10 CFA Appendix 11 CBA Appendix 12 MSWIFA Appendix 13 MSWIBA Appendix 14 ArtAggr Appendix 15 NatAggr Appendix 16 LimeStone Appendix 17 GranTyr Appendix 18 Comparison of BOF data with FEHS data Appendix 19 Comparison of INTRON data with this work Appendix 20 MSWIBA - Organic Note that no or limited leaching data were available at the time of study on:
Recycled tiles and ceramics
BF, BOF and EAF dust
Boiler slag from coal combustion
Fluid bed combustion ash (from coal combustion)
Boiler ash from incineration of household waste
Final Report Appendix Part 1: Leaching data
A possible methodology for setting pollutant limit values for aggregates in the EoW framework JRC-IPTS 3
Final Report Appendix 1: RecCon Appendix Part 1: Leaching data
A possible methodology for setting pollutant limit values for aggregates in the EoW framework JRC-IPTS 4
0.0001
0.001
0.01
0.1
1
10
100
1000
2 4 6 8 10 12 14
Co
nce
ntr
ati
on
(m
g/L)
pH
pH dependent concentration of Al
0.1
1
10
0.01 0.1 1 10 100
Co
nce
ntr
ati
on
(m
g/L)
L/S (L/kg)
Al concentration as function of L/S
0.001
0.01
0.1
1
10
100
1000
10000
2 4 6 8 10 12 14
Re
lea
se
(m
g/k
g)
pH
pH dependent release of Al
0.001
0.01
0.1
1
10
100
1000
10000
0.01 0.1 1 10 100
(Cu
mu
lati
ve
) re
lea
se
(m
g/k
g)
L/S (L/kg)
(Cumulative) release of Al
1
10
100
1000
10000
100000
2 4 6 8 10 12 14
Co
nce
ntr
ati
on
(m
g/L)
pH
pH dependent concentration of Ca
1
10
100
1000
10000
0.01 0.1 1 10 100
Co
nce
ntr
ati
on
(m
g/L)
L/S (L/kg)
Ca concentration as function of L/S
1
10
100
1000
10000
100000
1000000
2 4 6 8 10 12 14
Re
lea
se
(m
g/k
g)
pH
pH dependent release of Ca
1
10
100
1000
10000
100000
1000000
0.01 0.1 1 10 100
(Cu
mu
lati
ve
) re
lea
se
(m
g/k
g)
L/S (L/kg)
(Cumulative) release of Ca
Final Report Appendix 1: RecCon Appendix Part 1: Leaching data
A possible methodology for setting pollutant limit values for aggregates in the EoW framework JRC-IPTS 5
0.0001
0.001
0.01
0.1
1
10
100
1000
2 4 6 8 10 12 14
Co
nce
ntr
ati
on
(m
g/L)
pH
pH dependent concentration of Fe
0.00001
0.0001
0.001
0.01
0.1
1
0.01 0.1 1 10 100
Co
nce
ntr
ati
on
(m
g/L)
L/S (L/kg)
Fe concentration as function of L/S
0.0001
0.001
0.01
0.1
1
10
100
1000
10000
2 4 6 8 10 12 14
Re
lea
se
(m
g/k
g)
pH
pH dependent release of Fe
0.0001
0.001
0.01
0.1
1
10
100
1000
10000
0.01 0.1 1 10 100Cu
mu
lati
ve
re
lea
se
(m
g/k
g)
L/S (L/kg)
Cumulative release of Fe
0.001
0.01
0.1
1
10
100
1000
2 4 6 8 10 12 14
Co
nce
ntr
ati
on
(m
g/L)
pH
pH dependent concentration of Mg
0.001
0.01
0.1
1
0.01 0.1 1 10 100
Co
nce
ntr
ati
on
(m
g/L)
L/S (L/kg)
Mg concentration as function of L/S
0.0001
0.001
0.01
0.1
1
10
100
1000
10000
2 4 6 8 10 12 14
Re
lea
se
(m
g/k
g)
pH
pH dependent release of Mg
0.0001
0.001
0.01
0.1
1
10
100
1000
10000
0.01 0.1 1 10 100Cu
mu
lati
ve
re
lea
se
(m
g/k
g)
L/S (L/kg)
Cumulative release of Mg
Final Report Appendix 1: RecCon Appendix Part 1: Leaching data
A possible methodology for setting pollutant limit values for aggregates in the EoW framework JRC-IPTS 6
0.00001
0.0001
0.001
0.01
0.1
1
10
100
2 4 6 8 10 12 14
Co
nce
ntr
ati
on
(m
g/L)
pH
pH dependent concentration of Mn
0.00001
0.0001
0.001
0.01
0.1
1
0.01 0.1 1 10 100
Co
nce
ntr
ati
on
(m
g/L)
L/S (L/kg)
Mn concentration as function of L/S
0.000001
0.00001
0.0001
0.001
0.01
0.1
1
10
100
1000
2 4 6 8 10 12 14
Re
lea
se
(m
g/k
g)
pH
pH dependent release of Mn
0.000001
0.00001
0.0001
0.001
0.01
0.1
1
10
100
1000
0.01 0.1 1 10 100
(Cu
mu
lati
ve
) re
lea
se
(m
g/k
g)
L/S (L/kg)
(Cumulative) release of Mn
0.1
1
10
100
1000
10000
2 4 6 8 10 12 14
Co
nce
ntr
ati
on
(m
g/L)
pH
pH dependent concentration of Si
0.1
1
10
100
0.01 0.1 1 10 100
Co
nce
ntr
ati
on
(m
g/L)
L/S (L/kg)
Si concentration as function of L/S
0.1
1
10
100
1000
10000
100000
2 4 6 8 10 12 14
Re
lea
se
(m
g/k
g)
pH
pH dependent release of Si
0.1
1
10
100
1000
10000
100000
0.01 0.1 1 10 100Cu
mu
lati
ve
re
lea
se
(m
g/k
g)
L/S (L/kg)
Cumulative release of Si
Final Report Appendix 1: RecCon Appendix Part 1: Leaching data
A possible methodology for setting pollutant limit values for aggregates in the EoW framework JRC-IPTS 7
0.0001
0.001
0.01
0.1
1
10
100
2 4 6 8 10 12 14
Re
lea
se
(m
g/k
g)
pH
pH dependent release of Ba
0.0001
0.001
0.01
0.1
1
10
100
0.01 0.1 1 10 100
(Cu
mu
lati
ve
) re
lea
se
(m
g/k
g)
L/S (L/kg)
(Cumulative) release of Ba
0.001
0.01
0.1
1
10
100
2 4 6 8 10 12 14
Co
nce
ntr
ati
on
(m
g/L)
pH
pH dependent concentration of Sr
0.1
1
10
100
0.01 0.1 1 10 100
Co
nce
ntr
ati
on
(m
g/L)
L/S (L/kg)
Sr concentration as function of L/S
0.01
0.1
1
10
100
1000
2 4 6 8 10 12 14
Re
lea
se
(m
g/k
g)
pH
pH dependent release of Sr
0.01
0.1
1
10
100
1000
0.01 0.1 1 10 100Cu
mu
lati
ve
re
lea
se
(m
g/k
g)
L/S (L/kg)
Cumulative release of Sr
0.001
0.01
0.1
1
10
100
2 4 6 8 10 12 14
Co
nce
ntr
ati
on
(m
g/L)
pH
pH dependent concentration of Ba
0.01
0.1
1
10
0.01 0.1 1 10 100
Co
nce
ntr
ati
on
(m
g/L)
L/S (L/kg)
Ba concentration as function of L/S
Final Report Appendix 1: RecCon Appendix Part 1: Leaching data
A possible methodology for setting pollutant limit values for aggregates in the EoW framework JRC-IPTS 8
0.1
1
10
100
1000
2 4 6 8 10 12 14
Co
nce
ntr
ati
on
(m
g/L)
pH
pH dependent concentration of Cl
0.1
1
10
100
1000
0.01 0.1 1 10 100
Co
nce
ntr
ati
on
(m
g/L)
L/S (L/kg)
Cl concentration as function of L/S
0.1
1
10
100
1000
10000
2 4 6 8 10 12 14
Re
lea
se
(m
g/k
g)
pH
pH dependent release of Cl
0.1
1
10
100
1000
10000
0.01 0.1 1 10 100
(Cu
mu
lati
ve
) re
lea
se
(m
g/k
g)
L/S (L/kg)
(Cumulative) release of Cl
0.00001
0.0001
0.001
0.01
0.1
1
10
2 4 6 8 10 12 14
Co
nce
ntr
ati
on
(m
g/L)
pH
pH dependent concentration of P
0.0001
0.001
0.01
0.1
1
0.01 0.1 1 10 100
Co
nce
ntr
ati
on
(m
g/L)
L/S (L/kg)
P concentration as function of L/S
0.0001
0.001
0.01
0.1
1
10
100
2 4 6 8 10 12 14
Re
lea
se
(m
g/k
g)
pH
pH dependent release of P
0.0001
0.001
0.01
0.1
1
10
100
0.01 0.1 1 10 100Cu
mu
lati
ve
re
lea
se
(m
g/k
g)
L/S (L/kg)
Cumulative release of P
Final Report Appendix 1: RecCon Appendix Part 1: Leaching data
A possible methodology for setting pollutant limit values for aggregates in the EoW framework JRC-IPTS 9
1
10
100
1000
10000
2 4 6 8 10 12 14
Co
nce
ntr
ati
on
(m
g/L)
pH
pH dependent concentration of K
1
10
100
1000
10000
0.01 0.1 1 10 100
Co
nce
ntr
ati
on
(m
g/L)
L/S (L/kg)
K concentration as function of L/S
1
10
100
1000
10000
100000
2 4 6 8 10 12 14
Re
lea
se
(m
g/k
g)
pH
pH dependent release of K
1
10
100
1000
10000
100000
0.01 0.1 1 10 100
(Cu
mu
lati
ve
) re
lea
se
(m
g/k
g)
L/S (L/kg)
(Cumulative) release of K
1
10
100
1000
10000
2 4 6 8 10 12 14
Co
nce
ntr
ati
on
(m
g/L)
pH
pH dependent concentration of Na
0.1
1
10
100
1000
10000
0.01 0.1 1 10 100
Co
nce
ntr
ati
on
(m
g/L)
L/S (L/kg)
Na concentration as function of L/S
1
10
100
1000
10000
100000
2 4 6 8 10 12 14
Re
lea
se
(m
g/k
g)
pH
pH dependent release of Na
1
10
100
1000
10000
100000
0.01 0.1 1 10 100
(Cu
mu
lati
ve
) re
lea
se
(m
g/k
g)
L/S (L/kg)
(Cumulative) release of Na
Final Report Appendix 1: RecCon Appendix Part 1: Leaching data
A possible methodology for setting pollutant limit values for aggregates in the EoW framework JRC-IPTS 10
0.0001
0.001
0.01
0.1
1
10
100
2 4 6 8 10 12 14
Co
nce
ntr
ati
on
(m
g/L)
pH
pH dependent concentration of Cr
0.001
0.01
0.1
1
10
0.01 0.1 1 10 100
Co
nce
ntr
ati
on
(m
g/L)
L/S (L/kg)
Cr concentration as function of L/S
0.0001
0.001
0.01
0.1
1
10
100
1000
2 4 6 8 10 12 14
Re
lea
se
(m
g/k
g)
pH
pH dependent release of Cr
0.0001
0.001
0.01
0.1
1
10
100
1000
0.01 0.1 1 10 100
(Cu
mu
lati
ve
) re
lea
se
(m
g/k
g)
L/S (L/kg)
(Cumulative) release of Cr
0.00001
0.0001
0.001
0.01
0.1
1
10
2 4 6 8 10 12 14
Co
nce
ntr
ati
on
(m
g/L)
pH
pH dependent concentration of Cu
0.0001
0.001
0.01
0.1
1
0.01 0.1 1 10 100
Co
nce
ntr
ati
on
(m
g/L)
L/S (L/kg)
Cu concentration as function of L/S
0.0001
0.001
0.01
0.1
1
10
100
2 4 6 8 10 12 14
Re
lea
se
(m
g/k
g)
pH
pH dependent release of Cu
0.0001
0.001
0.01
0.1
1
10
100
0.01 0.1 1 10 100
(Cu
mu
lati
ve
) re
lea
se
(m
g/k
g)
L/S (L/kg)
(Cumulative) release of Cu
Final Report Appendix 1: RecCon Appendix Part 1: Leaching data
A possible methodology for setting pollutant limit values for aggregates in the EoW framework JRC-IPTS 11
0.00001
0.0001
0.001
0.01
0.1
1
10
2 4 6 8 10 12 14
Co
nce
ntr
ati
on
(m
g/L)
pH
pH dependent concentration of Mo
0.001
0.01
0.1
1
0.01 0.1 1 10 100
Co
nce
ntr
ati
on
(m
g/L)
L/S (L/kg)
Mo concentration as function of L/S
0.00001
0.0001
0.001
0.01
0.1
1
10
100
2 4 6 8 10 12 14
Re
lea
se
(m
g/k
g)
pH
pH dependent release of Mo
0.00001
0.0001
0.001
0.01
0.1
1
10
100
0.01 0.1 1 10 100
(Cu
mu
lati
ve
) re
lea
se
(m
g/k
g)
L/S (L/kg)
(Cumulative) release of Mo
0.00001
0.0001
0.001
0.01
0.1
1
10
100
2 4 6 8 10 12 14
Co
nce
ntr
ati
on
(m
g/L)
pH
pH dependent concentration of Ni
0.0001
0.001
0.01
0.1
1
0.01 0.1 1 10 100
Co
nce
ntr
ati
on
(m
g/L)
L/S (L/kg)
Ni concentration as function of L/S
0.00001
0.0001
0.001
0.01
0.1
1
10
100
1000
2 4 6 8 10 12 14
Re
lea
se
(m
g/k
g)
pH
pH dependent release of Ni
0.00001
0.0001
0.001
0.01
0.1
1
10
100
1000
0.01 0.1 1 10 100
(Cu
mu
lati
ve
) re
lea
se
(m
g/k
g)
L/S (L/kg)
(Cumulative) release of Ni
Final Report Appendix 1: RecCon Appendix Part 1: Leaching data
A possible methodology for setting pollutant limit values for aggregates in the EoW framework JRC-IPTS 12
0.00001
0.0001
0.001
0.01
0.1
1
2 4 6 8 10 12 14
Co
nce
ntr
ati
on
(m
g/L)
pH
pH dependent concentration of Pb
0.0001
0.001
0.01
0.1
1
0.01 0.1 1 10 100
Co
nce
ntr
ati
on
(m
g/L)
L/S (L/kg)
Pb concentration as function of L/S
0.00001
0.0001
0.001
0.01
0.1
1
10
2 4 6 8 10 12 14
Re
lea
se
(m
g/k
g)
pH
pH dependent release of Pb
0.00001
0.0001
0.001
0.01
0.1
1
10
0.01 0.1 1 10 100
(Cu
mu
lati
ve
) re
lea
se
(m
g/k
g)
L/S (L/kg)
(Cumulative) release of Pb
0.00001
0.0001
0.001
0.01
0.1
1
2 4 6 8 10 12 14
Co
nce
ntr
ati
on
(m
g/L)
pH
pH dependent concentration of Sb
0.00001
0.0001
0.001
0.01
0.1
1
0.01 0.1 1 10 100
Co
nce
ntr
ati
on
(m
g/L)
L/S (L/kg)
Sb concentration as function of L/S
0.00001
0.0001
0.001
0.01
0.1
1
10
2 4 6 8 10 12 14
Re
lea
se
(m
g/k
g)
pH
pH dependent release of Sb
0.00001
0.0001
0.001
0.01
0.1
1
10
0.01 0.1 1 10 100
(Cu
mu
lati
ve
) re
lea
se
(m
g/k
g)
L/S (L/kg)
(Cumulative) release of Sb
Final Report Appendix 1: RecCon Appendix Part 1: Leaching data
A possible methodology for setting pollutant limit values for aggregates in the EoW framework JRC-IPTS 13
0.000001
0.00001
0.0001
0.001
0.01
0.1
1
2 4 6 8 10 12 14
Co
nce
ntr
ati
on
(m
g/L)
pH
pH dependent concentration of Se
0.0001
0.001
0.01
0.1
1
0.01 0.1 1 10 100
Co
nce
ntr
ati
on
(m
g/L)
L/S (L/kg)
Se concentration as function of L/S
0.00001
0.0001
0.001
0.01
0.1
1
2 4 6 8 10 12 14
Re
lea
se
(m
g/k
g)
pH
pH dependent release of Se
0.00001
0.0001
0.001
0.01
0.1
1
0.01 0.1 1 10 100Cu
mu
lati
ve
re
lea
se
(m
g/k
g)
L/S (L/kg)
Cumulative release of Se
0.00001
0.0001
0.001
0.01
0.1
1
2 4 6 8 10 12 14
Co
nce
ntr
ati
on
(m
g/L)
pH
pH dependent concentration of Sn
0.0001
0.001
0.01
0.1
1
0.01 0.1 1 10 100
Co
nce
ntr
ati
on
(m
g/L)
L/S (L/kg)
Sn concentration as function of L/S
0.00001
0.0001
0.001
0.01
0.1
1
10
2 4 6 8 10 12 14
Re
lea
se
(m
g/k
g)
pH
pH dependent release of Sn
0.00001
0.0001
0.001
0.01
0.1
1
10
0.01 0.1 1 10 100
(Cu
mu
lati
ve
) re
lea
se
(m
g/k
g)
L/S (L/kg)
(Cumulative) release of Sn
Final Report Appendix 1: RecCon Appendix Part 1: Leaching data
A possible methodology for setting pollutant limit values for aggregates in the EoW framework JRC-IPTS 14
0.00001
0.0001
0.001
0.01
0.1
1
2 4 6 8 10 12 14
Co
nce
ntr
ati
on
(m
g/L)
pH
pH dependent concentration of V
0.00001
0.0001
0.001
0.01
0.1
1
0.01 0.1 1 10 100
Co
nce
ntr
ati
on
(m
g/L)
L/S (L/kg)
V concentration as function of L/S
0.00001
0.0001
0.001
0.01
0.1
1
10
2 4 6 8 10 12 14
Re
lea
se
(m
g/k
g)
pH
pH dependent release of V
0.00001
0.0001
0.001
0.01
0.1
1
10
0.01 0.1 1 10 100
(Cu
mu
lati
ve
) re
lea
se
(m
g/k
g)
L/S (L/kg)
(Cumulative) release of V
0.00001
0.0001
0.001
0.01
0.1
1
10
2 4 6 8 10 12 14
Co
nce
ntr
ati
on
(m
g/L)
pH
pH dependent concentration of Zn
0.0001
0.001
0.01
0.1
1
0.01 0.1 1 10 100
Co
nce
ntr
ati
on
(m
g/L)
L/S (L/kg)
Zn concentration as function of L/S
0.0001
0.001
0.01
0.1
1
10
100
2 4 6 8 10 12 14
Re
lea
se
(m
g/k
g)
pH
pH dependent release of Zn
0.0001
0.001
0.01
0.1
1
10
100
0.01 0.1 1 10 100
(Cu
mu
lati
ve
) re
lea
se
(m
g/k
g)
L/S (L/kg)
(Cumulative) release of Zn
Final Report Appendix 1: RecCon Appendix Part 1: Leaching data
A possible methodology for setting pollutant limit values for aggregates in the EoW framework JRC-IPTS 15
0.1
1
10
100
1000
2 4 6 8 10 12 14
Co
nce
ntr
ati
on
(m
g/L)
pH
pH dependent concentration of S
0.1
1
10
100
0.01 0.1 1 10 100
Co
nce
ntr
ati
on
(m
g/L)
L/S (L/kg)
S concentration as function of L/S
0.1
1
10
100
1000
10000
2 4 6 8 10 12 14
Re
lea
se
(m
g/k
g)
pH
pH dependent release of S
0.1
1
10
100
1000
10000
0.01 0.1 1 10 100Cu
mu
lati
ve
re
lea
se
(m
g/k
g)
L/S (L/kg)
Cumulative release of S
1
10
100
1000
2 4 6 8 10 12 14
Co
nce
ntr
ati
on
(m
g/L)
pH
pH dependent concentration of SO4
0.1
1
10
100
1000
0.01 0.1 1 10 100
Co
nce
ntr
ati
on
(m
g/L)
L/S (L/kg)
SO4 concentration as function of L/S
0.1
1
10
100
1000
10000
2 4 6 8 10 12 14
Re
lea
se
(m
g/k
g)
pH
pH dependent release of SO4
0.1
1
10
100
1000
10000
0.01 0.1 1 10 100
(Cu
mu
lati
ve
) re
lea
se
(m
g/k
g)
L/S (L/kg)
(Cumulative) release of SO4
Final Report Appendix 1: RecCon Appendix Part 1: Leaching data
A possible methodology for setting pollutant limit values for aggregates in the EoW framework JRC-IPTS 16
11.5
12
12.5
13
13.5
14
0.01 0.1 1 10 100
pH
L/S (L/kg)
pH development as function of L/S
Final Report Appendix 2: RecBrick Appendix Part 1: Leaching data
A possible methodology for setting pollutant limit values for aggregates in the EoW framework JRC-IPTS 17
0.01
0.1
1
10
100
2 4 6 8 10 12 14
Co
nce
ntr
ati
on
(m
g/L)
pH
pH dependent concentration of Al
0.1
1
10
100
1 10
Co
nce
ntr
ati
on
(m
g/L)
L/S (L/kg)
Al concentration as function of L/S
0.1
1
10
100
1000
2 4 6 8 10 12 14
Re
lea
se
(m
g/k
g)
pH
pH dependent release of Al
0.1
1
10
100
1000
1 10
Re
lea
se
(m
g/k
g)
L/S (L/kg)
Release of Al
0.1
1
10
100
1000
10000
2 4 6 8 10 12 14
Co
nce
ntr
ati
on
(m
g/L)
pH
pH dependent concentration of Ca
1
10
100
1000
10000
0.1 1 10 100
Co
nce
ntr
ati
on
(m
g/L)
L/S (L/kg)
Ca concentration as function of L/S
1
10
100
1000
10000
100000
1000000
2 4 6 8 10 12 14
Re
lea
se
(m
g/k
g)
pH
pH dependent release of Ca
1
10
100
1000
10000
100000
1000000
0.1 1 10 100
(Cu
mu
lati
ve
) re
lea
se
(m
g/k
g)
L/S (L/kg)
(Cumulative) release of Ca
Final Report Appendix 2: RecBrick Appendix Part 1: Leaching data
A possible methodology for setting pollutant limit values for aggregates in the EoW framework JRC-IPTS 18
0.001
0.01
0.1
1
10
100
1000
2 4 6 8 10 12 14
Co
nce
ntr
ati
on
(m
g/L)
pH
pH dependent concentration of Fe
0.1
1
10
100
1000
2 4 6 8 10 12 14
Co
nce
ntr
ati
on
(m
g/L)
pH
pH dependent concentration of K
0.01
0.1
1
10
100
1000
10000
2 4 6 8 10 12 14
Re
lea
se
(m
g/k
g)
pH
pH dependent release of Fe
1
10
100
1000
10000
100000
2 4 6 8 10 12 14
Re
lea
se
(m
g/k
g)
pH
pH dependent release of K
0.001
0.01
0.1
1
10
100
2 4 6 8 10 12 14
Co
nce
ntr
ati
on
(m
g/L)
pH
pH dependent concentration of Mg
0.0001
0.001
0.01
0.1
1
10
2 4 6 8 10 12 14
Co
nce
ntr
ati
on
(m
g/L)
pH
pH dependent concentration of Mn
0.01
0.1
1
10
100
1000
2 4 6 8 10 12 14
Re
lea
se
(m
g/k
g)
pH
pH dependent release of Mg
0.001
0.01
0.1
1
10
100
2 4 6 8 10 12 14
Re
lea
se
(m
g/k
g)
pH
pH dependent release of Mn
Final Report Appendix 2: RecBrick Appendix Part 1: Leaching data
A possible methodology for setting pollutant limit values for aggregates in the EoW framework JRC-IPTS 19
0.1
1
10
100
1000
2 4 6 8 10 12 14
Co
nce
ntr
ati
on
(m
g/L)
pH
pH dependent concentration of Si
0.001
0.01
0.1
1
2 4 6 8 10 12 14
Co
nce
ntr
ati
on
(m
g/L)
pH
pH dependent concentration of Sn
1
10
100
1000
10000
2 4 6 8 10 12 14
Re
lea
se
(m
g/k
g)
pH
pH dependent release of Si
0.001
0.01
0.1
1
10
2 4 6 8 10 12 14
Re
lea
se
(m
g/k
g)
pH
pH dependent release of Sn
0.0001
0.001
0.01
0.1
1
10
2 4 6 8 10 12 14
Co
nce
ntr
ati
on
(m
g/L)
pH
pH dependent concentration of Mn
0.001
0.01
0.1
1
1 10
Co
nce
ntr
ati
on
(m
g/L)
L/S (L/kg)
Mn concentration as function of L/S
0.001
0.01
0.1
1
10
100
2 4 6 8 10 12 14
Re
lea
se
(m
g/k
g)
pH
pH dependent release of Mn
0.001
0.01
0.1
1
10
100
1 10
Re
lea
se
(m
g/k
g)
L/S (L/kg)
Release of Mn
Final Report Appendix 2: RecBrick Appendix Part 1: Leaching data
A possible methodology for setting pollutant limit values for aggregates in the EoW framework JRC-IPTS 20
1
10
100
1000
0.1 1 10
Co
nce
ntr
ati
on
(m
g/L)
L/S (L/kg)
S concentration as function of L/S
1
10
100
1000
10000
0.1 1 10Cu
mu
lati
ve
re
lea
se
(m
g/k
g)
L/S (L/kg)
Cumulative release of S
1
10
100
2 4 6 8 10 12 14
Co
nce
ntr
ati
on
(m
g/L)
pH
pH dependent concentration of S
1
10
100
1000
10000
2 4 6 8 10 12 14
Re
lea
se
(m
g/k
g)
pH
pH dependent release of S
1
10
100
1000
10000
0.1 1 10 100
Co
nce
ntr
ati
on
(m
g/L)
L/S (L/kg)
SO4 concentration as function of L/S
Depletion of gypsum
1
10
100
1000
10000
2 4 6 8 10 12 14
Co
nce
ntr
ati
on
(m
g/L)
pH
pH dependent concentration of SO4
0.1
1
10
100
1000
10000
0.1 1 10 100(Cu
mu
lati
ve
) re
lea
se
(m
g/k
g)
L/S (L/kg)
(Cumulative) release of SO4
0.1
1
10
100
1000
10000
2 4 6 8 10 12 14
Re
lea
se
(m
g/k
g)
pH
pH dependent release of SO4
Final Report Appendix 2: RecBrick Appendix Part 1: Leaching data
A possible methodology for setting pollutant limit values for aggregates in the EoW framework JRC-IPTS 21
0.1
1
10
2 4 6 8 10 12 14
Co
nce
ntr
ati
on
(m
g/L)
pH
pH dependent concentration of Cl
0.1
1
10
100
1000
0.1 1 10 100
Co
nce
ntr
ati
on
(m
g/L)
L/S (L/kg)
Cl concentration as function of L/S
1
10
100
1000
10000
100000
2 4 6 8 10 12 14
Re
lea
se
(m
g/k
g)
pH
pH dependent release of Cl
1
10
100
1000
10000
100000
0.1 1 10 100
(Cu
mu
lati
ve
) re
lea
se
(m
g/k
g)
L/S (L/kg)
(Cumulative) release of Cl
0.001
0.01
0.1
1
2 4 6 8 10 12 14
Co
nce
ntr
ati
on
(m
g/L)
pH
pH dependent concentration of P
0.01
0.1
1
10
2 4 6 8 10 12 14
Re
lea
se
(m
g/k
g)
pH
pH dependent release of P
0.01
0.1
1
2 4 6 8 10 12 14
Co
nce
ntr
ati
on
(m
g/L)
pH
pH dependent concentration of Sr
0.1
1
10
2 4 6 8 10 12 14
Re
lea
se
(m
g/k
g)
pH
pH dependent release of Sr
Final Report Appendix 2: RecBrick Appendix Part 1: Leaching data
A possible methodology for setting pollutant limit values for aggregates in the EoW framework JRC-IPTS 22
0.1
1
10
100
1000
2 4 6 8 10 12 14
Co
nce
ntr
ati
on
(m
g/L)
pH
pH dependent concentration of Na
0.1
1
10
100
1000
0.1 1 10 100
Co
nce
ntr
ati
on
(m
g/L)
L/S (L/kg)
Na concentration as function of L/S
1
10
100
1000
10000
100000
2 4 6 8 10 12 14
Re
lea
se
(m
g/k
g)
pH
pH dependent release of Na
1
10
100
1000
10000
100000
0.1 1 10 100
(Cu
mu
lati
ve
) re
lea
se
(m
g/k
g)
L/S (L/kg)
(Cumulative) release of Na
0.1
1
10
100
1000
2 4 6 8 10 12 14
Co
nce
ntr
ati
on
(m
g/L)
pH
pH dependent concentration of K
0.1
1
10
100
1000
0.1 1 10 100
Co
nce
ntr
ati
on
(m
g/L)
L/S (L/kg)
K concentration as function of L/S
1
10
100
1000
10000
100000
2 4 6 8 10 12 14
Re
lea
se
(m
g/k
g)
pH
pH dependent release of K
1
10
100
1000
10000
100000
0.1 1 10 100
(Cu
mu
lati
ve
) re
lea
se
(m
g/k
g)
L/S (L/kg)
(Cumulative) release of K
Final Report Appendix 2: RecBrick Appendix Part 1: Leaching data
A possible methodology for setting pollutant limit values for aggregates in the EoW framework JRC-IPTS 23
0.01
0.1
1
10
2 4 6 8 10 12 14
Co
nce
ntr
ati
on
(m
g/L)
pH
pH dependent concentration of Ba
0.01
0.1
1
0.1 1 10 100
Co
nce
ntr
ati
on
(m
g/L)
L/S (L/kg)
Ba concentration as function of L/S
0.001
0.01
0.1
1
10
100
2 4 6 8 10 12 14
Re
lea
se
(m
g/k
g)
pH
pH dependent release of Ba
0.001
0.01
0.1
1
10
100
0.1 1 10 100
(Cu
mu
lati
ve
) re
lea
se
(m
g/k
g)
L/S (L/kg)
(Cumulative) release of Ba
0.0001
0.001
0.01
0.1
1
2 4 6 8 10 12 14
Co
nce
ntr
ati
on
(m
g/L)
pH
pH dependent concentration of As
0.0001
0.001
0.01
0.1
1
0.1 1 10
Co
nce
ntr
ati
on
(m
g/L)
L/S (L/kg)
As concentration as function of L/S
0.00001
0.0001
0.001
0.01
0.1
1
10
100
1000
2 4 6 8 10 12 14
Re
lea
se
(m
g/k
g)
pH
pH dependent release of As
0.00001
0.0001
0.001
0.01
0.1
1
10
100
1000
0.1 1 10
(Cu
mu
lati
ve
) re
lea
se
(m
g/k
g)
L/S (L/kg)
(Cumulative) release of As
Final Report Appendix 2: RecBrick Appendix Part 1: Leaching data
A possible methodology for setting pollutant limit values for aggregates in the EoW framework JRC-IPTS 24
0.001
0.01
0.1
1
2 4 6 8 10 12 14
Co
nce
ntr
ati
on
(m
g/L)
pH
pH dependent concentration of Cd
0.1
1
10
2 4 6 8 10 12 14
Co
nce
ntr
ati
on
(m
g/L)
pH
pH dependent concentration of Cl
0.00001
0.0001
0.001
0.01
0.1
1
2 4 6 8 10 12 14
Re
lea
se
(m
g/k
g)
pH
pH dependent release of Cd
1
10
100
1000
10000
100000
2 4 6 8 10 12 14
Re
lea
se
(m
g/k
g)
pH
pH dependent release of Cl
0.001
0.01
0.1
1
2 4 6 8 10 12 14
Co
nce
ntr
ati
on
(m
g/L)
pH
pH dependent concentration of Cr
0.01
0.1
1
0.1 1 10 100
Co
nce
ntr
ati
on
(m
g/L)
L/S (L/kg)
Cr concentration as function of L/S
0.001
0.01
0.1
1
10
100
2 4 6 8 10 12 14
Re
lea
se
(m
g/k
g)
pH
pH dependent release of Cr
0.001
0.01
0.1
1
10
100
0.1 1 10 100
(Cu
mu
lati
ve
) re
lea
se
(m
g/k
g)
L/S (L/kg)
(Cumulative) release of Cr
Final Report Appendix 2: RecBrick Appendix Part 1: Leaching data
A possible methodology for setting pollutant limit values for aggregates in the EoW framework JRC-IPTS 25
0.001
0.01
0.1
1
2 4 6 8 10 12 14
Co
nce
ntr
ati
on
(m
g/L)
pH
pH dependent concentration of Cu
0.001
0.01
0.1
1
0.1 1 10
Co
nce
ntr
ati
on
(m
g/L)
L/S (L/kg)
Cu concentration as function of L/S
0.001
0.01
0.1
1
10
100
2 4 6 8 10 12 14
Re
lea
se
(m
g/k
g)
pH
pH dependent release of Cu
0.001
0.01
0.1
1
10
100
0.1 1 10
(Cu
mu
lati
ve
) re
lea
se
(m
g/k
g)
L/S (L/kg)
(Cumulative) release of Cu
0.001
0.01
0.1
1
2 4 6 8 10 12 14
Co
nce
ntr
ati
on
(m
g/L)
pH
pH dependent concentration of Mo
0.001
0.01
0.1
1
0.1 1 10
Co
nce
ntr
ati
on
(m
g/L)
L/S (L/kg)
Mo concentration as function of L/S
0.001
0.01
0.1
1
10
100
2 4 6 8 10 12 14
Re
lea
se
(m
g/k
g)
pH
pH dependent release of Mo
0.001
0.01
0.1
1
10
100
0.1 1 10Cu
mu
lati
ve
re
lea
se
(m
g/k
g)
L/S (L/kg)
Cumulative release of Mo
Final Report Appendix 2: RecBrick Appendix Part 1: Leaching data
A possible methodology for setting pollutant limit values for aggregates in the EoW framework JRC-IPTS 26
0.0001
0.001
0.01
0.1
1
2 4 6 8 10 12 14
Co
nce
ntr
ati
on
(m
g/L)
pH
pH dependent concentration of Ni
0.0001
0.001
0.01
0.1
1
0.1 1 10
Co
nce
ntr
ati
on
(m
g/L)
L/S (L/kg)
Ni concentration as function of L/S
0.001
0.01
0.1
1
10
2 4 6 8 10 12 14
Re
lea
se
(m
g/k
g)
pH
pH dependent release of Ni
0.001
0.01
0.1
1
10
0.1 1 10
(Cu
mu
lati
ve
) re
lea
se
(m
g/k
g)
L/S (L/kg)
(Cumulative) release of Ni
0.0001
0.001
0.01
0.1
1
10
2 4 6 8 10 12 14
Co
nce
ntr
ati
on
(m
g/L)
pH
pH dependent concentration of Pb
0.0001
0.001
0.01
0.1
1
0.1 1 10
Co
nce
ntr
ati
on
(m
g/L)
L/S (L/kg)
Pb concentration as function of L/S
0.0001
0.001
0.01
0.1
1
10
100
2 4 6 8 10 12 14
Re
lea
se
(m
g/k
g)
pH
pH dependent release of Pb
0.0001
0.001
0.01
0.1
1
10
100
0.1 1 10
(Cu
mu
lati
ve
) re
lea
se
(m
g/k
g)
L/S (L/kg)
(Cumulative) release of Pb
Final Report Appendix 2: RecBrick Appendix Part 1: Leaching data
A possible methodology for setting pollutant limit values for aggregates in the EoW framework JRC-IPTS 27
0.001
0.01
0.1
1
2 4 6 8 10 12 14
Co
nce
ntr
ati
on
(m
g/L)
pH
pH dependent concentration of Sb
0.0001
0.001
0.01
0.1
1
0.1 1 10
Co
nce
ntr
ati
on
(m
g/L)
L/S (L/kg)
Sb concentration as function of L/S
0.00001
0.0001
0.001
0.01
0.1
1
2 4 6 8 10 12 14
Re
lea
se
(m
g/k
g)
pH
pH dependent release of Sb
0.00001
0.0001
0.001
0.01
0.1
1
0.1 1 10Cu
mu
lati
ve
re
lea
se
(m
g/k
g)
L/S (L/kg)
Cumulative release of Sb
0.001
0.01
0.1
1
2 4 6 8 10 12 14
Co
nce
ntr
ati
on
(m
g/L)
pH
pH dependent concentration of Se
0.0001
0.001
0.01
0.1
1
0.1 1 10
Co
nce
ntr
ati
on
(m
g/L)
L/S (L/kg)
Se concentration as function of L/S
0.0001
0.001
0.01
0.1
1
2 4 6 8 10 12 14
Re
lea
se
(m
g/k
g)
pH
pH dependent release of Se
0.0001
0.001
0.01
0.1
1
0.1 1 10Cu
mu
lati
ve
re
lea
se
(m
g/k
g)
L/S (L/kg)
Cumulative release of Se
Final Report Appendix 2: RecBrick Appendix Part 1: Leaching data
A possible methodology for setting pollutant limit values for aggregates in the EoW framework JRC-IPTS 28
0.0001
0.001
0.01
0.1
1
2 4 6 8 10 12 14
Co
nce
ntr
ati
on
(m
g/L)
pH
pH dependent concentration of V
0.001
0.01
0.1
1
0.1 1 10
Co
nce
ntr
ati
on
(m
g/L)
L/S (L/kg)
V concentration as function of L/S
0.001
0.01
0.1
1
10
100
2 4 6 8 10 12 14
Re
lea
se
(m
g/k
g)
pH
pH dependent release of V
0.001
0.01
0.1
1
10
100
0.1 1 10Cu
mu
lati
ve
re
lea
se
(m
g/k
g)
L/S (L/kg)
Cumulative release of V
0.0001
0.001
0.01
0.1
1
10
2 4 6 8 10 12 14
Co
nce
ntr
ati
on
(m
g/L)
pH
pH dependent concentration of Zn
0.0001
0.001
0.01
0.1
1
0.1 1 10
Co
nce
ntr
ati
on
(m
g/L)
L/S (L/kg)
Zn concentration as function of L/S
0.001
0.01
0.1
1
10
2 4 6 8 10 12 14
Re
lea
se
(m
g/k
g)
pH
pH dependent release of Zn
0.001
0.01
0.1
1
10
0.1 1 10
(Cu
mu
lati
ve
) re
lea
se
(m
g/k
g)
L/S (L/kg)
(Cumulative) release of Zn
Final Report Appendix 2: RecBrick Appendix Part 1: Leaching data
A possible methodology for setting pollutant limit values for aggregates in the EoW framework JRC-IPTS 29
0
2
4
6
8
10
12
14
0.1 1 10 100
pH
L/S (L/kg)
pH development as function of L/S
Final Report Appendix 3: RecGls Appendix Part 1: Leaching data
A possible methodology for setting pollutant limit values for aggregates in the EoW framework JRC-IPTS 30
0.001
0.01
0.1
1
2 4 6 8 10 12 14
Co
nce
ntr
ati
on
(m
g/L)
pH
pH dependent concentration of Al
0.001
0.01
0.1
1
1 10
Co
nce
ntr
ati
on
(m
g/L)
L/S (L/kg)
Al concentration as function of L/S
0.01
0.1
1
10
2 4 6 8 10 12 14
Re
lea
se
(m
g/k
g)
pH
pH dependent release of Al
0.01
0.1
1
10
1 10
Re
lea
se
(m
g/k
g)
L/S (L/kg)
Release of Al
0.1
1
10
100
2 4 6 8 10 12 14
Co
nce
ntr
ati
on
(m
g/L)
pH
pH dependent concentration of Ca
0.1
1
10
100
1 10
Co
nce
ntr
ati
on
(m
g/L)
L/S (L/kg)
Ca concentration as function of L/S
1
10
100
1000
2 4 6 8 10 12 14
Re
lea
se
(m
g/k
g)
pH
pH dependent release of Ca
1
10
100
1000
1 10
Re
lea
se
(m
g/k
g)
L/S (L/kg)
Release of Ca
Final Report Appendix 3: RecGls Appendix Part 1: Leaching data
A possible methodology for setting pollutant limit values for aggregates in the EoW framework JRC-IPTS 31
0.01
0.1
1
10
2 4 6 8 10 12 14
Co
nce
ntr
ati
on
(m
g/L)
pH
pH dependent concentration of Fe
0.01
0.1
1
10
0.1 1 10
Co
nce
ntr
ati
on
(m
g/L)
L/S (L/kg)
Fe concentration as function of L/S
0.1
1
10
100
2 4 6 8 10 12 14
Re
lea
se
(m
g/k
g)
pH
pH dependent release of Fe
0.1
1
10
100
0.1 1 10
(Cu
mu
lati
ve
) re
lea
se
(m
g/k
g)
L/S (L/kg)
(Cumulative) release of Fe
0.001
0.01
0.1
1
2 4 6 8 10 12 14
Co
nce
ntr
ati
on
(m
g/L)
pH
pH dependent concentration of Mn
0.001
0.01
0.1
1
0.1 1 10
Co
nce
ntr
ati
on
(m
g/L)
L/S (L/kg)
Mn concentration as function of L/S
0.01
0.1
1
10
2 4 6 8 10 12 14
Re
lea
se
(m
g/k
g)
pH
pH dependent release of Mn
0.01
0.1
1
10
0.1 1 10
(Cu
mu
lati
ve
) re
lea
se
(m
g/k
g)
L/S (L/kg)
(Cumulative) release of Mn
Final Report Appendix 3: RecGls Appendix Part 1: Leaching data
A possible methodology for setting pollutant limit values for aggregates in the EoW framework JRC-IPTS 32
1
10
100
1000
10000
2 4 6 8 10 12 14
Co
nce
ntr
ati
on
(m
g/L)
pH
pH dependent concentration of SO4
1
10
1 10
Co
nce
ntr
ati
on
(m
g/L)
L/S (L/kg)
SO4 concentration as function of L/S
1
10
100
1000
10000
100000
2 4 6 8 10 12 14
Re
lea
se
(m
g/k
g)
pH
pH dependent release of SO4
1
10
100
1000
10000
100000
1 10
Re
lea
se
(m
g/k
g)
L/S (L/kg)
Release of SO4
1
10
100
1000
10000
2 4 6 8 10 12 14
Co
nce
ntr
ati
on
(m
g/L)
pH
pH dependent concentration of Cl
1
10
100
1000
0.1 1 10
Co
nce
ntr
ati
on
(m
g/L)
L/S (L/kg)
Cl concentration as function of L/S
1
10
100
1000
10000
100000
2 4 6 8 10 12 14
Re
lea
se
(m
g/k
g)
pH
pH dependent release of Cl
1
10
100
1000
10000
100000
0.1 1 10
(Cu
mu
lati
ve
) re
lea
se
(m
g/k
g)
L/S (L/kg)
(Cumulative) release of Cl
Final Report Appendix 3: RecGls Appendix Part 1: Leaching data
A possible methodology for setting pollutant limit values for aggregates in the EoW framework JRC-IPTS 33
0.001
0.01
0.1
1
10
100
2 4 6 8 10 12 14
Co
nce
ntr
ati
on
(m
g/L)
pH
pH dependent concentration of Ba
0.001
0.01
0.1
1
10
0.1 1 10
Co
nce
ntr
ati
on
(m
g/L)
L/S (L/kg)
Ba concentration as function of L/S
0.001
0.01
0.1
1
10
100
1000
2 4 6 8 10 12 14
Re
lea
se
(m
g/k
g)
pH
pH dependent release of Ba
0.001
0.01
0.1
1
10
100
1000
0.1 1 10
(Cu
mu
lati
ve
) re
lea
se
(m
g/k
g)
L/S (L/kg)
(Cumulative) release of Ba
0.001
0.01
0.1
1
10
100
2 4 6 8 10 12 14
Co
nce
ntr
ati
on
(m
g/L)
pH
pH dependent concentration of As
0.001
0.01
0.1
1
0.1 1 10
Co
nce
ntr
ati
on
(m
g/L)
L/S (L/kg)
As concentration as function of L/S
0.0001
0.001
0.01
0.1
1
10
100
1000
2 4 6 8 10 12 14
Re
lea
se
(m
g/k
g)
pH
pH dependent release of As
0.0001
0.001
0.01
0.1
1
10
100
1000
0.1 1 10
(Cu
mu
lati
ve
) re
lea
se
(m
g/k
g)
L/S (L/kg)
(Cumulative) release of As
Final Report Appendix 3: RecGls Appendix Part 1: Leaching data
A possible methodology for setting pollutant limit values for aggregates in the EoW framework JRC-IPTS 34
0.001
0.01
0.1
1
10
2 4 6 8 10 12 14
Co
nce
ntr
ati
on
(m
g/L)
pH
pH dependent concentration of Cd
0.0001
0.001
0.01
0.1
1
0.1 1 10
Co
nce
ntr
ati
on
(m
g/L)
L/S (L/kg)
Cd concentration as function of L/S
0.001
0.01
0.1
1
10
100
2 4 6 8 10 12 14
Re
lea
se
(m
g/k
g)
pH
pH dependent release of Cd
0.001
0.01
0.1
1
10
100
0.1 1 10
(Cu
mu
lati
ve
) re
lea
se
(m
g/k
g)
L/S (L/kg)
(Cumulative) release of Cd
0.001
0.01
0.1
1
10
100
2 4 6 8 10 12 14
Co
nce
ntr
ati
on
(m
g/L)
pH
pH dependent concentration of Cr
0.001
0.01
0.1
1
0.1 1 10
Co
nce
ntr
ati
on
(m
g/L)
L/S (L/kg)
Cr concentration as function of L/S
0.0001
0.001
0.01
0.1
1
10
100
1000
2 4 6 8 10 12 14
Re
lea
se
(m
g/k
g)
pH
pH dependent release of Cr
0.0001
0.001
0.01
0.1
1
10
100
1000
0.1 1 10
(Cu
mu
lati
ve
) re
lea
se
(m
g/k
g)
L/S (L/kg)
(Cumulative) release of Cr
Final Report Appendix 3: RecGls Appendix Part 1: Leaching data
A possible methodology for setting pollutant limit values for aggregates in the EoW framework JRC-IPTS 35
0.0001
0.001
0.01
0.1
1
10
2 4 6 8 10 12 14
Co
nce
ntr
ati
on
(m
g/L)
pH
pH dependent concentration of Cu
0.001
0.01
0.1
1
10
100
0.1 1 10
Co
nce
ntr
ati
on
(m
g/L)
L/S (L/kg)
Cu concentration as function of L/S
0.001
0.01
0.1
1
10
100
2 4 6 8 10 12 14
Re
lea
se
(m
g/k
g)
pH
pH dependent release of Cu
0.001
0.01
0.1
1
10
100
0.1 1 10
(Cu
mu
lati
ve
) re
lea
se
(m
g/k
g)
L/S (L/kg)
(Cumulative) release of Cu
1
10
100
2 4 6 8 10 12 14
Co
nce
ntr
ati
on
(m
g/L)
pH
pH dependent concentration of Mo
0.1
1
10
100
1000
2 4 6 8 10 12 14
Re
lea
se
(m
g/k
g)
pH
pH dependent release of Mo
0.0001
0.001
2 4 6 8 10 12 14
Co
nce
ntr
ati
on
(m
g/L)
pH
pH dependent concentration of Sn
0.0001
0.001
0.01
0.1
1
2 4 6 8 10 12 14
Re
lea
se
(m
g/k
g)
pH
pH dependent release of Sn
Final Report Appendix 3: RecGls Appendix Part 1: Leaching data
A possible methodology for setting pollutant limit values for aggregates in the EoW framework JRC-IPTS 36
0.001
0.01
0.1
1
2 4 6 8 10 12 14
Co
nce
ntr
ati
on
(m
g/L)
pH
pH dependent concentration of Ni
0.001
0.01
0.1
1
0.1 1 10
Co
nce
ntr
ati
on
(m
g/L)
L/S (L/kg)
Ni concentration as function of L/S
0.01
0.1
1
10
100
2 4 6 8 10 12 14
Re
lea
se
(m
g/k
g)
pH
pH dependent release of Ni
0.01
0.1
1
10
100
0.1 1 10
(Cu
mu
lati
ve
) re
lea
se
(m
g/k
g)
L/S (L/kg)
(Cumulative) release of Ni
0.001
0.01
0.1
1
10
100
1000
10000
2 4 6 8 10 12 14
Co
nce
ntr
ati
on
(m
g/L)
pH
pH dependent concentration of Pb
0.001
0.01
0.1
1
10
0.1 1 10
Co
nce
ntr
ati
on
(m
g/L)
L/S (L/kg)
Pb concentration as function of L/S
0.001
0.01
0.1
1
10
100
1000
10000
100000
2 4 6 8 10 12 14
Re
lea
se
(m
g/k
g)
pH
pH dependent release of Pb
0.001
0.01
0.1
1
10
100
1000
10000
100000
0.1 1 10
(Cu
mu
lati
ve
) re
lea
se
(m
g/k
g)
L/S (L/kg)
(Cumulative) release of Pb
Final Report Appendix 3: RecGls Appendix Part 1: Leaching data
A possible methodology for setting pollutant limit values for aggregates in the EoW framework JRC-IPTS 37
0.001
0.01
0.1
1
2 4 6 8 10 12 14
Co
nce
ntr
ati
on
(m
g/L)
pH
pH dependent concentration of Sb
0.0001
0.001
0.01
0.1
1
0.1 1 10
Co
nce
ntr
ati
on
(m
g/L)
L/S (L/kg)
Sb concentration as function of L/S
0.001
0.01
0.1
1
10
100
2 4 6 8 10 12 14
Re
lea
se
(m
g/k
g)
pH
pH dependent release of Sb
0.001
0.01
0.1
1
10
100
0.1 1 10
(Cu
mu
lati
ve
) re
lea
se
(m
g/k
g)
L/S (L/kg)
(Cumulative) release of Sb
0.001
0.01
0.1
1
10
100
2 4 6 8 10 12 14
Co
nce
ntr
ati
on
(m
g/L)
pH
pH dependent concentration of Zn
0.001
0.01
0.1
1
10
0.1 1 10
Co
nce
ntr
ati
on
(m
g/L)
L/S (L/kg)
Zn concentration as function of L/S
0.01
0.1
1
10
100
1000
2 4 6 8 10 12 14
Re
lea
se
(m
g/k
g)
pH
pH dependent release of Zn
0.01
0.1
1
10
100
1000
0.1 1 10
(Cu
mu
lati
ve
) re
lea
se
(m
g/k
g)
L/S (L/kg)
(Cumulative) release of Zn
Final Report Appendix 3: RecGls Appendix Part 1: Leaching data
A possible methodology for setting pollutant limit values for aggregates in the EoW framework JRC-IPTS 38
0
2
4
6
8
10
12
0.1 1 10
pH
L/S (L/kg)
pH development as function of L/S
Final Report Appendix 4: MixC&D Appendix Part 1: Leaching data
A possible methodology for setting pollutant limit values for aggregates in the EoW framework JRC-IPTS 39
0.001
0.01
0.1
1
10
100
1000
2 4 6 8 10 12 14
Co
nce
ntr
ati
on
(m
g/L)
pH
pH dependent concentration of Al
1
10
1 10 100
Co
nce
ntr
ati
on
(m
g/L)
L/S (L/kg)
Al concentration as function of L/S
0.01
0.1
1
10
100
1000
10000
2 4 6 8 10 12 14
Re
lea
se
(m
g/k
g)
pH
pH dependent release of Al
0.01
0.1
1
10
100
1000
10000
1 10 100
(Cu
mu
lati
ve
) re
lea
se
(m
g/k
g)
L/S (L/kg)
(Cumulative) release of Al
1
10
100
1000
10000
2 4 6 8 10 12 14
Co
nce
ntr
ati
on
(m
g/L)
pH
pH dependent concentration of Ca
1
10
100
1000
1 10 100
Co
nce
ntr
ati
on
(m
g/L)
L/S (L/kg)
Ca concentration as function of L/S
1
10
100
1000
10000
100000
2 4 6 8 10 12 14
Re
lea
se
(m
g/k
g)
pH
pH dependent release of Ca
1
10
100
1000
10000
100000
1 10 100
(Cu
mu
lati
ve
) re
lea
se
(m
g/k
g)
L/S (L/kg)
(Cumulative) release of Ca
Final Report Appendix 4: MixC&D Appendix Part 1: Leaching data
A possible methodology for setting pollutant limit values for aggregates in the EoW framework JRC-IPTS 40
0.001
0.01
0.1
1
10
100
1000
2 4 6 8 10 12 14
Co
nce
ntr
ati
on
(m
g/L)
pH
pH dependent concentration of Fe
0.01
0.1
1
10
100
1000
10000
2 4 6 8 10 12 14
Re
lea
se
(m
g/k
g)
pH
pH dependent release of Fe
1
10
100
1000
2 4 6 8 10 12 14
Co
nce
ntr
ati
on
(m
g/L)
pH
pH dependent concentration of Si
1
10
100
1000
10000
100000
2 4 6 8 10 12 14
Re
lea
se
(m
g/k
g)
pH
pH dependent release of Si
0.00001
0.0001
0.001
0.01
0.1
1
10
100
2 4 6 8 10 12 14
Co
nce
ntr
ati
on
(m
g/L)
pH
pH dependent concentration of Mn
0.0001
0.001
0.01
0.1
1
10
100
1000
2 4 6 8 10 12 14
Re
lea
se
(m
g/k
g)
pH
pH dependent release of Mn
0.001
0.01
0.1
1
10
2 4 6 8 10 12 14
Co
nce
ntr
ati
on
(m
g/L)
pH
pH dependent concentration of P
0.01
0.1
1
10
100
2 4 6 8 10 12 14
Re
lea
se
(m
g/k
g)
pH
pH dependent release of P
Final Report Appendix 4: MixC&D Appendix Part 1: Leaching data
A possible methodology for setting pollutant limit values for aggregates in the EoW framework JRC-IPTS 41
0.001
0.01
0.1
1
10
100
1000
2 4 6 8 10 12 14
Co
nce
ntr
ati
on
(m
g/L)
pH
pH dependent concentration of Mg
0.1
1
1 10
Co
nce
ntr
ati
on
(m
g/L)
L/S (L/kg)
Mg concentration as function of L/S
0.01
0.1
1
10
100
1000
10000
2 4 6 8 10 12 14
Re
lea
se
(m
g/k
g)
pH
pH dependent release of Mg
0.01
0.1
1
10
100
1000
10000
1 10
Re
lea
se
(m
g/k
g)
L/S (L/kg)
Release of Mg
0.01
0.1
1
10
100
1000
2 4 6 8 10 12 14
Co
nce
ntr
ati
on
(m
g/L)
pH
pH dependent concentration of Cl
0.01
0.1
1
10
100
1000
1 10 100
Co
nce
ntr
ati
on
(m
g/L)
L/S (L/kg)
Cl concentration as function of L/S
0.1
1
10
100
1000
10000
2 4 6 8 10 12 14
Re
lea
se
(m
g/k
g)
pH
pH dependent release of Cl
0.01
0.1
1
10
100
1000
10000
1 10 100
(Cu
mu
lati
ve
) re
lea
se
(m
g/k
g)
L/S (L/kg)
(Cumulative) release of Cl
Final Report Appendix 4: MixC&D Appendix Part 1: Leaching data
A possible methodology for setting pollutant limit values for aggregates in the EoW framework JRC-IPTS 42
1
10
100
1000
10000
1 10 100
Co
nce
ntr
ati
on
(m
g/L)
L/S (L/kg)
S concentration as function of L/S
1
10
100
1000
10000
2 4 6 8 10 12 14
Co
nce
ntr
ati
on
(m
g/L)
pH
pH dependent concentration of S
1
10
100
1000
10000
100000
2 4 6 8 10 12 14
Re
lea
se
(m
g/k
g)
pH
pH dependent release of S
1
10
100
1000
10000
100000
1 10 100Cu
mu
lati
ve
re
lea
se
(m
g/k
g)
L/S (L/kg)
Cumulative release of S
1
10
100
1000
10000
2 4 6 8 10 12 14
Co
nce
ntr
ati
on
(m
g/L)
pH
pH dependent concentration of SO4
1
10
100
1000
10000
100000
2 4 6 8 10 12 14
Re
lea
se
(m
g/k
g)
pH
pH dependent release of SO4
1
10
100
1000
10000
0.01 0.1 1 10
Co
nce
ntr
ati
on
(m
g/L)
L/S (L/kg)
SO4 concentration as function of L/S
10
100
1000
10000
100000
0.01 0.1 1 10(Cu
mu
lati
ve
) re
lea
se
(m
g/k
g)
L/S (L/kg)
(Cumulative) release of SO4
Final Report Appendix 4: MixC&D Appendix Part 1: Leaching data
A possible methodology for setting pollutant limit values for aggregates in the EoW framework JRC-IPTS 43
1
10
100
1 10 100
Co
nce
ntr
ati
on
(m
g/L)
L/S (L/kg)
Na concentration as function of L/S
1
10
100
2 4 6 8 10 12 14
Co
nce
ntr
ati
on
(m
g/L)
pH
pH dependent concentration of Na
1
10
100
1000
2 4 6 8 10 12 14
Re
lea
se
(m
g/k
g)
pH
pH dependent release of Na
1
10
100
1000
1 10 100
(Cu
mu
lati
ve
) re
lea
se
(m
g/k
g)
L/S (L/kg)
(Cumulative) release of Na
1
10
100
1000
2 4 6 8 10 12 14
Co
nce
ntr
ati
on
(m
g/L)
pH
pH dependent concentration of K
1
10
100
1 10 100
Co
nce
ntr
ati
on
(m
g/L)
L/S (L/kg)
K concentration as function of L/S
1
10
100
1000
10000
2 4 6 8 10 12 14
Re
lea
se
(m
g/k
g)
pH
pH dependent release of K
1
10
100
1000
10000
1 10 100
(Cu
mu
lati
ve
) re
lea
se
(m
g/k
g)
L/S (L/kg)
(Cumulative) release of K
Final Report Appendix 4: MixC&D Appendix Part 1: Leaching data
A possible methodology for setting pollutant limit values for aggregates in the EoW framework JRC-IPTS 44
0.001
0.01
0.1
1
10
2 4 6 8 10 12 14
Co
nce
ntr
ati
on
(m
g/L)
pH
pH dependent concentration of Ba
0.01
0.1
1
1 10
Co
nce
ntr
ati
on
(m
g/L)
L/S (L/kg)
Ba concentration as function of L/S
0.001
0.01
0.1
1
10
100
2 4 6 8 10 12 14
Re
lea
se
(m
g/k
g)
pH
pH dependent release of Ba
0.001
0.01
0.1
1
10
100
1 10Cu
mu
lati
ve
re
lea
se
(m
g/k
g)
L/S (L/kg)
Cumulative release of Ba
0.0001
0.001
0.01
0.1
1
2 4 6 8 10 12 14
Co
nce
ntr
ati
on
(m
g/L)
pH
pH dependent concentration of As
0.0001
0.001
0.01
0.1
1
1 10 100
Co
nce
ntr
ati
on
(m
g/L)
L/S (L/kg)
As concentration as function of L/S
0.0001
0.001
0.01
0.1
1
10
2 4 6 8 10 12 14
Re
lea
se
(m
g/k
g)
pH
pH dependent release of As
0.0001
0.001
0.01
0.1
1
10
1 10 100
(Cu
mu
lati
ve
) re
lea
se
(m
g/k
g)
L/S (L/kg)
(Cumulative) release of As
Final Report Appendix 4: MixC&D Appendix Part 1: Leaching data
A possible methodology for setting pollutant limit values for aggregates in the EoW framework JRC-IPTS 45
0.0001
0.001
0.01
0.1
1
2 4 6 8 10 12 14
Co
nce
ntr
ati
on
(m
g/L)
pH
pH dependent concentration of Cd
0.0001
0.001
0.01
0.1
1
1 10
Co
nce
ntr
ati
on
(m
g/L)
L/S (L/kg)
Cd concentration as function of L/S
0.001
0.01
0.1
1
10
2 4 6 8 10 12 14
Re
lea
se
(m
g/k
g)
pH
pH dependent release of Cd
0.001
0.01
0.1
1
10
1 10
(Cu
mu
lati
ve
) re
lea
se
(m
g/k
g)
L/S (L/kg)
(Cumulative) release of Cd
0.001
0.01
0.1
1
2 4 6 8 10 12 14
Co
nce
ntr
ati
on
(m
g/L)
pH
pH dependent concentration of Cr
0.001
0.01
0.1
1
1 10 100
Co
nce
ntr
ati
on
(m
g/L)
L/S (L/kg)
Cr concentration as function of L/S
0.001
0.01
0.1
1
10
100
2 4 6 8 10 12 14
Re
lea
se
(m
g/k
g)
pH
pH dependent release of Cr
0.001
0.01
0.1
1
10
100
1 10 100
(Cu
mu
lati
ve
) re
lea
se
(m
g/k
g)
L/S (L/kg)
(Cumulative) release of Cr
Final Report Appendix 4: MixC&D Appendix Part 1: Leaching data
A possible methodology for setting pollutant limit values for aggregates in the EoW framework JRC-IPTS 46
0.001
0.01
0.1
1
10
2 4 6 8 10 12 14
Co
nce
ntr
ati
on
(m
g/L)
pH
pH dependent concentration of Cu
0.001
0.01
0.1
1
1 10 100
Co
nce
ntr
ati
on
(m
g/L)
L/S (L/kg)
Cu concentration as function of L/S
0.001
0.01
0.1
1
10
100
2 4 6 8 10 12 14
Re
lea
se
(m
g/k
g)
pH
pH dependent release of Cu
0.001
0.01
0.1
1
10
100
1 10 100
(Cu
mu
lati
ve
) re
lea
se
(m
g/k
g)
L/S (L/kg)
(Cumulative) release of Cu
0.001
0.01
0.1
1
2 4 6 8 10 12 14
Co
nce
ntr
ati
on
(m
g/L)
pH
pH dependent concentration of Mo
0.001
0.01
0.1
1
1 10
Co
nce
ntr
ati
on
(m
g/L)
L/S (L/kg)
Mo concentration as function of L/S
0.001
0.01
0.1
1
2 4 6 8 10 12 14
Re
lea
se
(m
g/k
g)
pH
pH dependent release of Mo
0.001
0.01
0.1
1
1 10Cu
mu
lati
ve
re
lea
se
(m
g/k
g)
L/S (L/kg)
Cumulative release of Mo
Final Report Appendix 4: MixC&D Appendix Part 1: Leaching data
A possible methodology for setting pollutant limit values for aggregates in the EoW framework JRC-IPTS 47
0.0001
0.001
0.01
0.1
1
2 4 6 8 10 12 14
Co
nce
ntr
ati
on
(m
g/L)
pH
pH dependent concentration of Ni
0.0001
0.001
0.01
0.1
1
1 10 100
Co
nce
ntr
ati
on
(m
g/L)
L/S (L/kg)
Ni concentration as function of L/S
0.001
0.01
0.1
1
10
2 4 6 8 10 12 14
Re
lea
se
(m
g/k
g)
pH
pH dependent release of Ni
0.001
0.01
0.1
1
10
1 10 100
(Cu
mu
lati
ve
) re
lea
se
(m
g/k
g)
L/S (L/kg)
(Cumulative) release of Ni
0.0001
0.001
0.01
0.1
1
10
2 4 6 8 10 12 14
Co
nce
ntr
ati
on
(m
g/L)
pH
pH dependent concentration of Pb
0.0001
0.001
0.01
0.1
1
1 10 100
Co
nce
ntr
ati
on
(m
g/L)
L/S (L/kg)
Pb concentration as function of L/S
0.0001
0.001
0.01
0.1
1
10
100
2 4 6 8 10 12 14
Re
lea
se
(m
g/k
g)
pH
pH dependent release of Pb
0.0001
0.001
0.01
0.1
1
10
100
1 10 100
(Cu
mu
lati
ve
) re
lea
se
(m
g/k
g)
L/S (L/kg)
(Cumulative) release of Pb
Final Report Appendix 4: MixC&D Appendix Part 1: Leaching data
A possible methodology for setting pollutant limit values for aggregates in the EoW framework JRC-IPTS 48
0.001
0.01
0.1
1
2 4 6 8 10 12 14
Co
nce
ntr
ati
on
(m
g/L)
pH
pH dependent concentration of Sb
0.0001
0.001
0.01
0.1
1
1 10
Co
nce
ntr
ati
on
(m
g/L)
L/S (L/kg)
Sb concentration as function of L/S
0.001
0.01
0.1
1
2 4 6 8 10 12 14
Re
lea
se
(m
g/k
g)
pH
pH dependent release of Sb
0.001
0.01
0.1
1
1 10Cu
mu
lati
ve
re
lea
se
(m
g/k
g)
L/S (L/kg)
Cumulative release of Sb
0.001
0.01
0.1
1
2 4 6 8 10 12 14
Co
nce
ntr
ati
on
(m
g/L)
pH
pH dependent concentration of Se
0.0001
0.001
0.01
0.1
1
1 10
Co
nce
ntr
ati
on
(m
g/L)
L/S (L/kg)
Se concentration as function of L/S
0.001
0.01
0.1
1
10
2 4 6 8 10 12 14
Re
lea
se
(m
g/k
g)
pH
pH dependent release of Se
0.001
0.01
0.1
1
10
1 10Cu
mu
lati
ve
re
lea
se
(m
g/k
g)
L/S (L/kg)
Cumulative release of Se
Final Report Appendix 4: MixC&D Appendix Part 1: Leaching data
A possible methodology for setting pollutant limit values for aggregates in the EoW framework JRC-IPTS 49
0.001
0.01
0.1
1
2 4 6 8 10 12 14
Co
nce
ntr
ati
on
(m
g/L)
pH
pH dependent concentration of Sn
0.001
0.01
0.1
1
1 10
Co
nce
ntr
ati
on
(m
g/L)
L/S (L/kg)
Sn concentration as function of L/S
0.001
0.01
0.1
1
2 4 6 8 10 12 14
Re
lea
se
(m
g/k
g)
pH
pH dependent release of Sn
0.001
0.01
0.1
1
1 10Cu
mu
lati
ve
re
lea
se
(m
g/k
g)
L/S (L/kg)
Cumulative release of Sn
0.0001
0.001
0.01
0.1
1
10
2 4 6 8 10 12 14
Co
nce
ntr
ati
on
(m
g/L)
pH
pH dependent concentration of V
0.001
0.01
0.1
1
1 10 100
Co
nce
ntr
ati
on
(m
g/L)
L/S (L/kg)
V concentration as function of L/S
0.001
0.01
0.1
1
10
100
2 4 6 8 10 12 14
Re
lea
se
(m
g/k
g)
pH
pH dependent release of V
0.001
0.01
0.1
1
10
100
1 10 100Cu
mu
lati
ve
re
lea
se
(m
g/k
g)
L/S (L/kg)
Cumulative release of V
Final Report Appendix 4: MixC&D Appendix Part 1: Leaching data
A possible methodology for setting pollutant limit values for aggregates in the EoW framework JRC-IPTS 50
0.0001
0.001
0.01
0.1
1
10
2 4 6 8 10 12 14
Co
nce
ntr
ati
on
(m
g/L)
pH
pH dependent concentration of Zn
0.0001
0.001
0.01
0.1
1
1 10 100
Co
nce
ntr
ati
on
(m
g/L)
L/S (L/kg)
Zn concentration as function of L/S
0.001
0.01
0.1
1
10
100
1000
2 4 6 8 10 12 14
Re
lea
se
(m
g/k
g)
pH
pH dependent release of Zn
0.001
0.01
0.1
1
10
100
1000
1 10 100
(Cu
mu
lati
ve
) re
lea
se
(m
g/k
g)
L/S (L/kg)
(Cumulative) release of Zn
0
2
4
6
8
10
12
14
1 10 100
pH
L/S (L/kg)
pH development as function of L/S
Final Report Appendix 5: RecAsph Appendix Part 1: Leaching data
A possible methodology for setting pollutant limit values for aggregates in the EoW framework JRC-IPTS 51
0.0001
0.001
0.01
0.1
1
10
100
2 4 6 8 10 12 14
Co
nce
ntr
ati
on
(m
g/L)
pH
pH dependent concentration of Al
0.001
0.01
0.1
1
10
100
1000
2 4 6 8 10 12 14
Re
lea
se
(m
g/k
g)
pH
pH dependent release of Al
0.1
1
10
100
1000
10000
100000
2 4 6 8 10 12 14
Co
nce
ntr
ati
on
(m
g/L)
pH
pH dependent concentration of Ca
1
10
100
1000
10000
100000
1000000
2 4 6 8 10 12 14
Re
lea
se
(m
g/k
g)
pH
pH dependent release of Ca
0.001
0.01
0.1
1
10
100
2 4 6 8 10 12 14
Co
nce
ntr
ati
on
(m
g/L)
pH
pH dependent concentration of Fe
0.01
0.1
1
10
100
1000
10000
2 4 6 8 10 12 14
Re
lea
se
(m
g/k
g)
pH
pH dependent release of Fe
0.01
0.1
1
10
100
1000
2 4 6 8 10 12 14
Re
lea
se
(m
g/k
g)
pH
pH dependent release of Mg
0.001
0.01
0.1
1
10
100
2 4 6 8 10 12 14
Co
nce
ntr
ati
on
(m
g/L)
pH
pH dependent concentration of Mg
Final Report Appendix 5: RecAsph Appendix Part 1: Leaching data
A possible methodology for setting pollutant limit values for aggregates in the EoW framework JRC-IPTS 52
1
10
100
2 4 6 8 10 12 14
Co
nce
ntr
ati
on
(m
g/L)
pH
pH dependent concentration of K
1
10
100
1000
2 4 6 8 10 12 14
Re
lea
se
(m
g/k
g)
pH
pH dependent release of K
0.1
1
1 10
Co
nce
ntr
ati
on
(m
g/L)
L/S (L/kg)
F concentration as function of L/S
1
10
1 10Cu
mu
lati
ve
re
lea
se
(m
g/k
g)
L/S (L/kg)
Cumulative release of F
0.01
0.1
1
10
100
2 4 6 8 10 12 14
Co
nce
ntr
ati
on
(m
g/L)
pH
pH dependent concentration of Cl
1
10
100
1 10
Co
nce
ntr
ati
on
(m
g/L)
L/S (L/kg)
Cl concentration as function of L/S
0.1
1
10
100
1000
2 4 6 8 10 12 14
Re
lea
se
(m
g/k
g)
pH
pH dependent release of Cl
0.1
1
10
100
1000
1 10Cu
mu
lati
ve
re
lea
se
(m
g/k
g)
L/S (L/kg)
Cumulative release of Cl
Final Report Appendix 5: RecAsph Appendix Part 1: Leaching data
A possible methodology for setting pollutant limit values for aggregates in the EoW framework JRC-IPTS 53
0.1
1
10
100
1000
10000
2 4 6 8 10 12 14
Co
nce
ntr
ati
on
(m
g/L)
pH
pH dependent concentration of Na
0.001
0.01
0.1
1
0.1 1 10
Co
nce
ntr
ati
on
(m
g/L)
L/S (L/kg)
Na concentration as function of L/S
0.01
0.1
1
10
100
1000
10000
100000
1000000
2 4 6 8 10 12 14
Re
lea
se
(m
g/k
g)
pH
pH dependent release of Na
0.01
0.1
1
10
100
1000
10000
100000
1000000
0.1 1 10Cu
mu
lati
ve
re
lea
se
(m
g/k
g)
L/S (L/kg)
Cumulative release of Na
0.0001
0.001
0.01
0.1
1
2 4 6 8 10 12 14
Co
nce
ntr
ati
on
(m
g/L)
pH
pH dependent concentration of As
0.0001
0.001
0.01
0.1
1
0.1 1 10 100
Co
nce
ntr
ati
on
(m
g/L)
L/S (L/kg)
As concentration as function of L/S
0.0001
0.001
0.01
0.1
1
10
100
2 4 6 8 10 12 14
Re
lea
se
(m
g/k
g)
pH
pH dependent release of As
0.0001
0.001
0.01
0.1
1
10
100
0.1 1 10 100
(Cu
mu
lati
ve
) re
lea
se
(m
g/k
g)
L/S (L/kg)
(Cumulative) release of As
Final Report Appendix 5: RecAsph Appendix Part 1: Leaching data
A possible methodology for setting pollutant limit values for aggregates in the EoW framework JRC-IPTS 54
0.001
0.01
0.1
1
2 4 6 8 10 12 14
Co
nce
ntr
ati
on
(m
g/L)
pH
pH dependent concentration of Ba
0.001
0.01
0.1
1
0.1 1 10 100
Co
nce
ntr
ati
on
(m
g/L)
L/S (L/kg)
Ba concentration as function of L/S
0.001
0.01
0.1
1
10
100
2 4 6 8 10 12 14
Re
lea
se
(m
g/k
g)
pH
pH dependent release of Ba
0.001
0.01
0.1
1
10
100
0.1 1 10 100Cu
mu
lati
ve
re
lea
se
(m
g/k
g)
L/S (L/kg)
Cumulative release of Ba
0.0001
0.001
0.01
0.1
1
2 4 6 8 10 12 14
Co
nce
ntr
ati
on
(m
g/L)
pH
pH dependent concentration of Cd
0.0001
0.001
0.01
0.1
1
0.1 1 10
Co
nce
ntr
ati
on
(m
g/L)
L/S (L/kg)
Cd concentration as function of L/S
0.00001
0.0001
0.001
0.01
0.1
1
2 4 6 8 10 12 14
Re
lea
se
(m
g/k
g)
pH
pH dependent release of Cd
0.00001
0.0001
0.001
0.01
0.1
1
0.1 1 10
(Cu
mu
lati
ve
) re
lea
se
(m
g/k
g)
L/S (L/kg)
(Cumulative) release of Cd
Final Report Appendix 5: RecAsph Appendix Part 1: Leaching data
A possible methodology for setting pollutant limit values for aggregates in the EoW framework JRC-IPTS 55
0.0001
0.001
0.01
0.1
1
2 4 6 8 10 12 14
Co
nce
ntr
ati
on
(m
g/L)
pH
pH dependent concentration of Cr
0.001
0.01
0.1
1
0.1 1 10
Co
nce
ntr
ati
on
(m
g/L)
L/S (L/kg)
Cr concentration as function of L/S
0.0001
0.001
0.01
0.1
1
10
2 4 6 8 10 12 14
Re
lea
se
(m
g/k
g)
pH
pH dependent release of Cr
0.0001
0.001
0.01
0.1
1
10
0.1 1 10
(Cu
mu
lati
ve
) re
lea
se
(m
g/k
g)
L/S (L/kg)
(Cumulative) release of Cr
0.0001
0.001
0.01
0.1
1
10
2 4 6 8 10 12 14
Co
nce
ntr
ati
on
(m
g/L)
pH
pH dependent concentration of Cu
0.001
0.01
0.1
1
0.1 1 10 100
Co
nce
ntr
ati
on
(m
g/L)
L/S (L/kg)
Cu concentration as function of L/S
0.0001
0.001
0.01
0.1
1
10
100
2 4 6 8 10 12 14
Re
lea
se
(m
g/k
g)
pH
pH dependent release of Cu
0.0001
0.001
0.01
0.1
1
10
100
0.1 1 10 100
(Cu
mu
lati
ve
) re
lea
se
(m
g/k
g)
L/S (L/kg)
(Cumulative) release of Cu
Final Report Appendix 5: RecAsph Appendix Part 1: Leaching data
A possible methodology for setting pollutant limit values for aggregates in the EoW framework JRC-IPTS 56
0.001
0.01
0.1
1
2 4 6 8 10 12 14
Co
nce
ntr
ati
on
(m
g/L)
pH
pH dependent concentration of Mo
0.001
0.01
0.1
1
0.1 1 10
Co
nce
ntr
ati
on
(m
g/L)
L/S (L/kg)
Mo concentration as function of L/S
0.001
0.01
0.1
1
2 4 6 8 10 12 14
Re
lea
se
(m
g/k
g)
pH
pH dependent release of Mo
0.001
0.01
0.1
1
0.1 1 10Cu
mu
lati
ve
re
lea
se
(m
g/k
g)
L/S (L/kg)
Cumulative release of Mo
0.0001
0.001
0.01
0.1
1
10
2 4 6 8 10 12 14
Co
nce
ntr
ati
on
(m
g/L)
pH
pH dependent concentration of Pb
0.001
0.01
0.1
1
0.1 1 10
Co
nce
ntr
ati
on
(m
g/L)
L/S (L/kg)
Pb concentration as function of L/S
0.0001
0.001
0.01
0.1
1
10
100
2 4 6 8 10 12 14
Re
lea
se
(m
g/k
g)
pH
pH dependent release of Pb
0.0001
0.001
0.01
0.1
1
10
100
0.1 1 10
(Cu
mu
lati
ve
) re
lea
se
(m
g/k
g)
L/S (L/kg)
(Cumulative) release of Pb
Final Report Appendix 5: RecAsph Appendix Part 1: Leaching data
A possible methodology for setting pollutant limit values for aggregates in the EoW framework JRC-IPTS 57
0.001
0.01
0.1
1
2 4 6 8 10 12 14
Co
nce
ntr
ati
on
(m
g/L)
pH
pH dependent concentration of Se
0.0001
0.001
0.01
0.1
1
0.1 1 10
Co
nce
ntr
ati
on
(m
g/L)
L/S (L/kg)
Se concentration as function of L/S
0.0001
0.001
0.01
0.1
1
2 4 6 8 10 12 14
Re
lea
se
(m
g/k
g)
pH
pH dependent release of Se
0.0001
0.001
0.01
0.1
1
0.1 1 10Cu
mu
lati
ve
re
lea
se
(m
g/k
g)
L/S (L/kg)
Cumulative release of Se
0.001
0.01
0.1
1
2 4 6 8 10 12 14
Co
nce
ntr
ati
on
(m
g/L)
pH
pH dependent concentration of Sn
0.01
0.1
1
1 10
Co
nce
ntr
ati
on
(m
g/L)
L/S (L/kg)
Sn concentration as function of L/S
0.01
0.1
1
2 4 6 8 10 12 14
Re
lea
se
(m
g/k
g)
pH
pH dependent release of Sn
0.01
0.1
1
1 10Cu
mu
lati
ve
re
lea
se
(m
g/k
g)
L/S (L/kg)
Cumulative release of Sn
Final Report Appendix 5: RecAsph Appendix Part 1: Leaching data
A possible methodology for setting pollutant limit values for aggregates in the EoW framework JRC-IPTS 58
0.0001
0.001
0.01
0.1
1
2 4 6 8 10 12 14
Co
nce
ntr
ati
on
(m
g/L)
pH
pH dependent concentration of V
0.001
0.01
0.1
1
0.1 1 10
Co
nce
ntr
ati
on
(m
g/L)
L/S (L/kg)
V concentration as function of L/S
0.001
0.01
0.1
1
2 4 6 8 10 12 14
Re
lea
se
(m
g/k
g)
pH
pH dependent release of V
0.001
0.01
0.1
1
0.1 1 10Cu
mu
lati
ve
re
lea
se
(m
g/k
g)
L/S (L/kg)
Cumulative release of V
0.0001
0.001
0.01
0.1
1
10
100
1000
2 4 6 8 10 12 14
Co
nce
ntr
ati
on
(m
g/L)
pH
pH dependent concentration of Zn
0.001
0.01
0.1
1
0.1 1 10
Co
nce
ntr
ati
on
(m
g/L)
L/S (L/kg)
Zn concentration as function of L/S
0.001
0.01
0.1
1
10
100
1000
2 4 6 8 10 12 14
Re
lea
se
(m
g/k
g)
pH
pH dependent release of Zn
0.001
0.01
0.1
1
10
100
1000
0.1 1 10
(Cu
mu
lati
ve
) re
lea
se
(m
g/k
g)
L/S (L/kg)
(Cumulative) release of Zn
Final Report Appendix 5: RecAsph Appendix Part 1: Leaching data
A possible methodology for setting pollutant limit values for aggregates in the EoW framework JRC-IPTS 59
0.1
1
10
2 4 6 8 10 12 14
Co
nce
ntr
ati
on
(m
g/L)
pH
pH dependent concentration of DOC
1
10
100
0.1 1 10 100
Co
nce
ntr
ati
on
(m
g/L)
L/S (L/kg)
DOC concentration as function of L/S
1
10
100
1000
10000
2 4 6 8 10 12 14
Re
lea
se
(m
g/k
g)
pH
pH dependent release of DOC
1
10
100
1000
10000
0.1 1 10 100Cu
mu
lati
ve
re
lea
se
(m
g/k
g)
L/S (L/kg)
Cumulative release of DOC
0
1
2
3
4
5
6
7
8
9
10
0.1 1 10
pH
L/S (L/kg)
pH development as function of L/S
Final Report Appendix 6: BFSlag Appendix Part 1: Leaching data
A possible methodology for setting pollutant limit values for aggregates in the EoW framework JRC-IPTS 60
0.01
0.1
1
10
100
1000
10000
2 4 6 8 10 12 14
Co
nce
ntr
ati
on
(m
g/L)
pH
pH dependent concentration of Al
0.1
1
10
100
1000
10000
0.01 0.1 1 10 100
Co
nce
ntr
ati
on
(m
g/L)
L/S (L/kg)
Al concentration as function of L/S
0.1
1
10
100
1000
10000
100000
2 4 6 8 10 12 14
Re
lea
se
(m
g/k
g)
pH
pH dependent release of Al
0.1
1
10
100
1000
10000
100000
0.01 0.1 1 10 100
(Cu
mu
lati
ve
) re
lea
se
(m
g/k
g)
L/S (L/kg)
(Cumulative) release of Al
1
10
100
1000
10000
2 4 6 8 10 12 14
Co
nce
ntr
ati
on
(m
g/L)
pH
pH dependent concentration of Ca
1
10
100
1000
0.01 0.1 1 10 100
Co
nce
ntr
ati
on
(m
g/L)
L/S (L/kg)
Ca concentration as function of L/S
0.01
0.1
1
10
100
1000
10000
100000
1000000
2 4 6 8 10 12 14
Re
lea
se
(m
g/k
g)
pH
pH dependent release of Ca
0.01
0.1
1
10
100
1000
10000
100000
1000000
0.01 0.1 1 10 100
(Cu
mu
lati
ve
) re
lea
se
(m
g/k
g)
L/S (L/kg)
(Cumulative) release of Ca
Final Report Appendix 6: BFSlag Appendix Part 1: Leaching data
A possible methodology for setting pollutant limit values for aggregates in the EoW framework JRC-IPTS 61
0.001
0.01
0.1
1
10
100
1000
2 4 6 8 10 12 14
Co
nce
ntr
ati
on
(m
g/L)
pH
pH dependent concentration of Fe
0.001
0.01
0.1
1
10
100
1000
0.01 0.1 1 10 100
Co
nce
ntr
ati
on
(m
g/L)
L/S (L/kg)
Fe concentration as function of L/S
0.0001
0.001
0.01
0.1
1
10
100
1000
10000
2 4 6 8 10 12 14
Re
lea
se
(m
g/k
g)
pH
pH dependent release of Fe
0.0001
0.001
0.01
0.1
1
10
100
1000
10000
0.01 0.1 1 10 100
(Cu
mu
lati
ve
) re
lea
se
(m
g/k
g)
L/S (L/kg)
(Cumulative) release of Fe
0.0001
0.001
0.01
0.1
1
10
100
1000
2 4 6 8 10 12 14
Co
nce
ntr
ati
on
(m
g/L)
pH
pH dependent concentration of Mn
0.0001
0.001
0.01
0.1
1
0.01 0.1 1 10 100
Co
nce
ntr
ati
on
(m
g/L)
L/S (L/kg)
Mn concentration as function of L/S
0.00001
0.0001
0.001
0.01
0.1
1
10
100
1000
10000
2 4 6 8 10 12 14
Re
lea
se
(m
g/k
g)
pH
pH dependent release of Mn
0.00001
0.0001
0.001
0.01
0.1
1
10
100
1000
10000
0.01 0.1 1 10 100
(Cu
mu
lati
ve
) re
lea
se
(m
g/k
g)
L/S (L/kg)
(Cumulative) release of Mn
Final Report Appendix 6: BFSlag Appendix Part 1: Leaching data
A possible methodology for setting pollutant limit values for aggregates in the EoW framework JRC-IPTS 62
0.1
1
10
100
1000
10000
2 4 6 8 10 12 14
Co
nce
ntr
ati
on
(m
g/L)
pH
pH dependent concentration of Si
0.1
1
10
100
0.01 0.1 1 10 100
Co
nce
ntr
ati
on
(m
g/L)
L/S (L/kg)
Si concentration as function of L/S
0.1
1
10
100
1000
10000
100000
2 4 6 8 10 12 14
Re
lea
se
(m
g/k
g)
pH
pH dependent release of Si
0.1
1
10
100
1000
10000
100000
0.01 0.1 1 10 100
(Cu
mu
lati
ve
) re
lea
se
(m
g/k
g)
L/S (L/kg)
(Cumulative) release of Si
0.0001
0.001
0.01
0.1
1
10
100
1000
2 4 6 8 10 12 14
Co
nce
ntr
ati
on
(m
g/L)
pH
pH dependent concentration of Mn
0.0001
0.001
0.01
0.1
1
0.01 0.1 1 10 100
Co
nce
ntr
ati
on
(m
g/L)
L/S (L/kg)
Mn concentration as function of L/S
0.00001
0.0001
0.001
0.01
0.1
1
10
100
1000
10000
2 4 6 8 10 12 14
Re
lea
se
(m
g/k
g)
pH
pH dependent release of Mn
0.00001
0.0001
0.001
0.01
0.1
1
10
100
1000
10000
0.01 0.1 1 10 100
(Cu
mu
lati
ve
) re
lea
se
(m
g/k
g)
L/S (L/kg)
(Cumulative) release of Mn
Final Report Appendix 6: BFSlag Appendix Part 1: Leaching data
A possible methodology for setting pollutant limit values for aggregates in the EoW framework JRC-IPTS 63
1
10
100
1000
10000
2 4 6 8 10 12 14
Co
nce
ntr
ati
on
(m
g/L)
pH
pH dependent concentration of S
1
10
100
1000
0.01 0.1 1 10 100
Co
nce
ntr
ati
on
(m
g/L)
L/S (L/kg)
S concentration as function of L/S
1
10
100
1000
10000
100000
2 4 6 8 10 12 14
Re
lea
se
(m
g/k
g)
pH
pH dependent release of S
1
10
100
1000
10000
100000
0.01 0.1 1 10 100
(Cu
mu
lati
ve
) re
lea
se
(m
g/k
g)
L/S (L/kg)
(Cumulative) release of S
1
10
100
1000
2 4 6 8 10 12 14
Co
nce
ntr
ati
on
(m
g/L)
pH
pH dependent concentration of SO4
1
10
100
1000
0.01 0.1 1 10 100
Co
nce
ntr
ati
on
(m
g/L)
L/S (L/kg)
SO4 concentration as function of L/S
0.1
1
10
100
1000
10000
100000
2 4 6 8 10 12 14
Re
lea
se
(m
g/k
g)
pH
pH dependent release of SO4
0.1
1
10
100
1000
10000
100000
0.01 0.1 1 10 100
(Cu
mu
lati
ve
) re
lea
se
(m
g/k
g)
L/S (L/kg)
(Cumulative) release of SO4
Final Report Appendix 6: BFSlag Appendix Part 1: Leaching data
A possible methodology for setting pollutant limit values for aggregates in the EoW framework JRC-IPTS 64
0.1
1
10
100
1000
2 4 6 8 10 12 14
Co
nce
ntr
ati
on
(m
g/L)
pH
pH dependent concentration of Cl
0.1
1
10
100
1000
10000
0.01 0.1 1 10 100
Co
nce
ntr
ati
on
(m
g/L)
L/S (L/kg)
Cl concentration as function of L/S
0.1
1
10
100
1000
10000
2 4 6 8 10 12 14
Re
lea
se
(m
g/k
g)
pH
pH dependent release of Cl
0.1
1
10
100
1000
10000
0.01 0.1 1 10 100
(Cu
mu
lati
ve
) re
lea
se
(m
g/k
g)
L/S (L/kg)
(Cumulative) release of Cl
0.001
0.01
0.1
1
10
2 4 6 8 10 12 14
Co
nce
ntr
ati
on
(m
g/L)
pH
pH dependent concentration of P
0.001
0.01
0.1
1
10
0.01 0.1 1 10 100
Co
nce
ntr
ati
on
(m
g/L)
L/S (L/kg)
P concentration as function of L/S
0.001
0.01
0.1
1
10
100
2 4 6 8 10 12 14
Re
lea
se
(m
g/k
g)
pH
pH dependent release of P
0.001
0.01
0.1
1
10
100
0.01 0.1 1 10 100
(Cu
mu
lati
ve
) re
lea
se
(m
g/k
g)
L/S (L/kg)
(Cumulative) release of P
Final Report Appendix 6: BFSlag Appendix Part 1: Leaching data
A possible methodology for setting pollutant limit values for aggregates in the EoW framework JRC-IPTS 65
1
10
100
1000
2 4 6 8 10 12 14
Co
nce
ntr
ati
on
(m
g/L)
pH
pH dependent concentration of K
1
10
100
1000
0.01 0.1 1 10 100
Co
nce
ntr
ati
on
(m
g/L)
L/S (L/kg)
K concentration as function of L/S
1
10
100
1000
10000
100000
2 4 6 8 10 12 14
Re
lea
se
(m
g/k
g)
pH
pH dependent release of K
1
10
100
1000
10000
100000
0.01 0.1 1 10 100
(Cu
mu
lati
ve
) re
lea
se
(m
g/k
g)
L/S (L/kg)
(Cumulative) release of K
1
10
100
1000
10000
2 4 6 8 10 12 14
Co
nce
ntr
ati
on
(m
g/L)
pH
pH dependent concentration of Na
1
10
100
1000
10000
0.01 0.1 1 10 100
Co
nce
ntr
ati
on
(m
g/L)
L/S (L/kg)
Na concentration as function of L/S
10
100
1000
10000
100000
2 4 6 8 10 12 14
Re
lea
se
(m
g/k
g)
pH
pH dependent release of Na
10
100
1000
10000
100000
0.01 0.1 1 10 100 1000(Cu
mu
lati
ve
) re
lea
se
(m
g/k
g)
L/S (L/kg)
(Cumulative) release of Na
Final Report Appendix 6: BFSlag Appendix Part 1: Leaching data
A possible methodology for setting pollutant limit values for aggregates in the EoW framework JRC-IPTS 66
0.001
0.01
0.1
1
10
0.01 0.1 1 10 100
Co
nce
ntr
ati
on
(m
g/L)
L/S (L/kg)
Ba concentration as function of L/S
0.001
0.01
0.1
1
10
2 4 6 8 10 12 14
Co
nce
ntr
ati
on
(m
g/L)
pH
pH dependent concentration of Ba
0.001
0.01
0.1
1
10
100
2 4 6 8 10 12 14
Re
lea
se
(m
g/k
g)
pH
pH dependent release of Ba
0.001
0.01
0.1
1
10
100
0.01 0.1 1 10 100
(Cu
mu
lati
ve
) re
lea
se
(m
g/k
g)
L/S (L/kg)
(Cumulative) release of Ba
0.01
0.1
1
10
100
2 4 6 8 10 12 14
Co
nce
ntr
ati
on
(m
g/L)
pH
pH dependent concentration of Sr
0.01
0.1
1
0.01 0.1 1 10 100
Co
nce
ntr
ati
on
(m
g/L)
L/S (L/kg)
Sr concentration as function of L/S
0.01
0.1
1
10
100
1000
2 4 6 8 10 12 14
Re
lea
se
(m
g/k
g)
pH
pH dependent release of Sr
0.01
0.1
1
10
100
1000
0.01 0.1 1 10 100
(Cu
mu
lati
ve
) re
lea
se
(m
g/k
g)
L/S (L/kg)
(Cumulative) release of Sr
Final Report Appendix 6: BFSlag Appendix Part 1: Leaching data
A possible methodology for setting pollutant limit values for aggregates in the EoW framework JRC-IPTS 67
0.0001
0.001
0.01
0.1
1
0.01 0.1 1 10 100
Co
nce
ntr
ati
on
(m
g/L)
L/S (L/kg)
As concentration as function of L/S
0.00001
0.0001
0.001
0.01
0.1
1
10
0.01 0.1 1 10 100
(Cu
mu
lati
ve
) re
lea
se
(m
g/k
g)
L/S (L/kg)
(Cumulative) release of As
0.0001
0.001
0.01
0.1
1
2 4 6 8 10 12 14
Co
nce
ntr
ati
on
(m
g/L)
pH
pH dependent concentration of As
0.00001
0.0001
0.001
0.01
0.1
1
10
2 4 6 8 10 12 14
Re
lea
se
(m
g/k
g)
pH
pH dependent release of As
0.0001
0.001
0.01
0.1
2 4 6 8 10 12 14
Co
nce
ntr
ati
on
(m
g/L)
pH
pH dependent concentration of Cd
0.000001
0.00001
0.0001
0.001
0.01
0.1
1
2 4 6 8 10 12 14
Re
lea
se
(m
g/k
g)
pH
pH dependent release of Cd
0.0001
0.001
0.01
0.1
0.01 0.1 1 10 100
Co
nce
ntr
ati
on
(m
g/L)
L/S (L/kg)
Cd concentration as function of L/S
0.000001
0.00001
0.0001
0.001
0.01
0.1
1
0.01 0.1 1 10 100(Cu
mu
lati
ve
) re
lea
se
(m
g/k
g)
L/S (L/kg)
(Cumulative) release of Cd
Final Report Appendix 6: BFSlag Appendix Part 1: Leaching data
A possible methodology for setting pollutant limit values for aggregates in the EoW framework JRC-IPTS 68
0.0001
0.001
0.01
0.1
1
10
2 4 6 8 10 12 14
Co
nce
ntr
ati
on
(m
g/L)
pH
pH dependent concentration of Cr
0.0001
0.001
0.01
0.1
1
0.01 0.1 1 10 100
Co
nce
ntr
ati
on
(m
g/L)
L/S (L/kg)
Cr concentration as function of L/S
0.0001
0.001
0.01
0.1
1
10
100
2 4 6 8 10 12 14
Re
lea
se
(m
g/k
g)
pH
pH dependent release of Cr
0.0001
0.001
0.01
0.1
1
10
100
0.01 0.1 1 10 100
(Cu
mu
lati
ve
) re
lea
se
(m
g/k
g)
L/S (L/kg)
(Cumulative) release of Cr
0.0001
0.001
0.01
0.1
1
2 4 6 8 10 12 14
Co
nce
ntr
ati
on
(m
g/L)
pH
pH dependent concentration of Cu
0.0001
0.001
0.01
0.1
1
0.01 0.1 1 10 100
Co
nce
ntr
ati
on
(m
g/L)
L/S (L/kg)
Cu concentration as function of L/S
0.0001
0.001
0.01
0.1
1
10
2 4 6 8 10 12 14
Re
lea
se
(m
g/k
g)
pH
pH dependent release of Cu
0.0001
0.001
0.01
0.1
1
10
0.01 0.1 1 10 100
(Cu
mu
lati
ve
) re
lea
se
(m
g/k
g)
L/S (L/kg)
(Cumulative) release of Cu
Final Report Appendix 6: BFSlag Appendix Part 1: Leaching data
A possible methodology for setting pollutant limit values for aggregates in the EoW framework JRC-IPTS 69
0.0001
0.001
0.01
0.1
1
2 4 6 8 10 12 14
Co
nce
ntr
ati
on
(m
g/L)
pH
pH dependent concentration of Mo
0.0001
0.001
0.01
0.1
1
0.01 0.1 1 10 100
Co
nce
ntr
ati
on
(m
g/L)
L/S (L/kg)
Mo concentration as function of L/S
0.0001
0.001
0.01
0.1
1
10
2 4 6 8 10 12 14
Re
lea
se
(m
g/k
g)
pH
pH dependent release of Mo
0.0001
0.001
0.01
0.1
1
10
0.01 0.1 1 10 100
(Cu
mu
lati
ve
) re
lea
se
(m
g/k
g)
L/S (L/kg)
(Cumulative) release of Mo
0.0001
0.001
0.01
0.1
1
2 4 6 8 10 12 14
Co
nce
ntr
ati
on
(m
g/L)
pH
pH dependent concentration of Ni
0.0001
0.001
0.01
0.1
1
0.01 0.1 1 10 100
Co
nce
ntr
ati
on
(m
g/L)
L/S (L/kg)
Ni concentration as function of L/S
0.0001
0.001
0.01
0.1
1
10
2 4 6 8 10 12 14
Re
lea
se
(m
g/k
g)
pH
pH dependent release of Ni
0.0001
0.001
0.01
0.1
1
10
0.01 0.1 1 10 100
(Cu
mu
lati
ve
) re
lea
se
(m
g/k
g)
L/S (L/kg)
(Cumulative) release of Ni
Final Report Appendix 6: BFSlag Appendix Part 1: Leaching data
A possible methodology for setting pollutant limit values for aggregates in the EoW framework JRC-IPTS 70
0.0001
0.001
0.01
0.1
1
10
2 4 6 8 10 12 14
Co
nce
ntr
ati
on
(m
g/L)
pH
pH dependent concentration of Pb
0.00001
0.0001
0.001
0.01
0.1
1
10
100
1000
2 4 6 8 10 12 14
Re
lea
se
(m
g/k
g)
pH
pH dependent release of Pb
0.0001
0.001
0.01
0.1
1
10
0.01 0.1 1 10 100
Co
nce
ntr
ati
on
(m
g/L)
L/S (L/kg)
Pb concentration as function of L/S
0.00001
0.0001
0.001
0.01
0.1
1
10
100
1000
0.01 0.1 1 10 100(Cu
mu
lati
ve
) re
lea
se
(m
g/k
g)
L/S (L/kg)
(Cumulative) release of Pb
0.0001
0.001
0.01
0.1
1
2 4 6 8 10 12 14
Co
nce
ntr
ati
on
(m
g/L)
pH
pH dependent concentration of Sb
0.00001
0.0001
0.001
0.01
0.1
1
10
2 4 6 8 10 12 14
Re
lea
se
(m
g/k
g)
pH
pH dependent release of Sb
0.0001
0.001
0.01
0.1
1
0.01 0.1 1 10 100
Co
nce
ntr
ati
on
(m
g/L)
L/S (L/kg)
Sb concentration as function of L/S
0.00001
0.0001
0.001
0.01
0.1
1
10
0.01 0.1 1 10 100(Cu
mu
lati
ve
) re
lea
se
(m
g/k
g)
L/S (L/kg)
(Cumulative) release of Sb
Final Report Appendix 6: BFSlag Appendix Part 1: Leaching data
A possible methodology for setting pollutant limit values for aggregates in the EoW framework JRC-IPTS 71
0.0001
0.001
0.01
0.1
2 4 6 8 10 12 14
Co
nce
ntr
ati
on
(m
g/L)
pH
pH dependent concentration of Se
0.0001
0.001
0.01
0.1
1
2 4 6 8 10 12 14
Re
lea
se
(m
g/k
g)
pH
pH dependent release of Se
0.0001
0.001
0.01
0.1
0.01 0.1 1 10 100
Co
nce
ntr
ati
on
(m
g/L)
L/S (L/kg)
Se concentration as function of L/S
0.0001
0.001
0.01
0.1
1
0.01 0.1 1 10 100(Cu
mu
lati
ve
) re
lea
se
(m
g/k
g)
L/S (L/kg)
(Cumulative) release of Se
0.0001
0.001
0.01
0.1
1
2 4 6 8 10 12 14
Co
nce
ntr
ati
on
(m
g/L)
pH
pH dependent concentration of Sn
0.00001
0.0001
0.001
0.01
0.1
1
10
2 4 6 8 10 12 14
Re
lea
se
(m
g/k
g)
pH
pH dependent release of Sn
0.0001
0.001
0.01
0.1
1
0.01 0.1 1 10 100
Co
nce
ntr
ati
on
(m
g/L)
L/S (L/kg)
Sn concentration as function of L/S
0.00001
0.0001
0.001
0.01
0.1
1
10
0.01 0.1 1 10 100(Cu
mu
lati
ve
) re
lea
se
(m
g/k
g)
L/S (L/kg)
(Cumulative) release of Sn
Final Report Appendix 6: BFSlag Appendix Part 1: Leaching data
A possible methodology for setting pollutant limit values for aggregates in the EoW framework JRC-IPTS 72
0.0001
0.001
0.01
0.1
1
10
100
2 4 6 8 10 12 14
Co
nce
ntr
ati
on
(m
g/L)
pH
pH dependent concentration of V
0.001
0.01
0.1
1
0.01 0.1 1 10 100
Co
nce
ntr
ati
on
(m
g/L)
L/S (L/kg)
V concentration as function of L/S
0.001
0.01
0.1
1
10
100
1000
2 4 6 8 10 12 14
Re
lea
se
(m
g/k
g)
pH
pH dependent release of V
0.001
0.01
0.1
1
10
100
1000
0.01 0.1 1 10 100
(Cu
mu
lati
ve
) re
lea
se
(m
g/k
g)
L/S (L/kg)
(Cumulative) release of V
0.0001
0.001
0.01
0.1
1
2 4 6 8 10 12 14
Co
nce
ntr
ati
on
(m
g/L)
pH
pH dependent concentration of Zn
0.0001
0.001
0.01
0.1
1
0.01 0.1 1 10 100
Co
nce
ntr
ati
on
(m
g/L)
L/S (L/kg)
Zn concentration as function of L/S
0.0001
0.001
0.01
0.1
1
10
2 4 6 8 10 12 14
Re
lea
se
(m
g/k
g)
pH
pH dependent release of Zn
0.0001
0.001
0.01
0.1
1
10
0.01 0.1 1 10 100
(Cu
mu
lati
ve
) re
lea
se
(m
g/k
g)
L/S (L/kg)
(Cumulative) release of Zn
Final Report Appendix 6: BFSlag Appendix Part 1: Leaching data
A possible methodology for setting pollutant limit values for aggregates in the EoW framework JRC-IPTS 73
0
2
4
6
8
10
12
14
0.01 0.1 1 10 100
pH
L/S (L/kg)
pH development as function of L/S
Final Report Appendix 7: BOFSlag Appendix Part 1: Leaching data
A possible methodology for setting pollutant limit values for aggregates in the EoW framework JRC-IPTS 74
0.00001
0.0001
0.001
0.01
0.1
1
10
100
1000
2 4 6 8 10 12 14
Co
nce
ntr
ati
on
(m
g/L)
pH
pH dependent concentration of Al
0.01
0.1
1
10
0.01 0.1 1 10 100
Co
nce
ntr
ati
on
(m
g/L)
L/S (L/kg)
Al concentration as function of L/S
0.0001
0.001
0.01
0.1
1
10
100
1000
10000
2 4 6 8 10 12 14
Re
lea
se
(m
g/k
g)
pH
pH dependent release of Al
0.0001
0.001
0.01
0.1
1
10
100
1000
10000
0.01 0.1 1 10 100Cu
mu
lati
ve
re
lea
se
(m
g/k
g)
L/S (L/kg)
Cumulative release of Al
1
10
100
1000
10000
100000
2 4 6 8 10 12 14
Co
nce
ntr
ati
on
(m
g/L)
pH
pH dependent concentration of Ca
1
10
100
1000
10000
0.01 0.1 1 10 100
Co
nce
ntr
ati
on
(m
g/L)
L/S (L/kg)
Ca concentration as function of L/S
0.01
0.1
1
10
100
1000
10000
100000
1000000
2 4 6 8 10 12 14
Re
lea
se
(m
g/k
g)
pH
pH dependent release of Ca
0.01
0.1
1
10
100
1000
10000
100000
1000000
0.01 0.1 1 10 100
(Cu
mu
lati
ve
) re
lea
se
(m
g/k
g)
L/S (L/kg)
(Cumulative) release of Ca
Final Report Appendix 7: BOFSlag Appendix Part 1: Leaching data
A possible methodology for setting pollutant limit values for aggregates in the EoW framework JRC-IPTS 75
0.00001
0.0001
0.001
0.01
0.1
1
10
100
1000
10000
2 4 6 8 10 12 14
Co
nce
ntr
ati
on
(m
g/L)
pH
pH dependent concentration of Fe
0.00001
0.0001
0.001
0.01
0.1
1
10
100
1000
10000
0.01 0.1 1 10 100
Co
nce
ntr
ati
on
(m
g/L)
L/S (L/kg)
Fe concentration as function of L/S
0.00001
0.0001
0.001
0.01
0.1
1
10
100
1000
10000
100000
2 4 6 8 10 12 14
Re
lea
se
(m
g/k
g)
pH
pH dependent release of Fe
0.00001
0.0001
0.001
0.01
0.1
1
10
100
1000
10000
100000
0.01 0.1 1 10 100
(Cu
mu
lati
ve
) re
lea
se
(m
g/k
g)
L/S (L/kg)
(Cumulative) release of Fe
0.001
0.01
0.1
1
10
100
1000
10000
2 4 6 8 10 12 14
Co
nce
ntr
ati
on
(m
g/L)
pH
pH dependent concentration of Mg
0.0001
0.001
0.01
0.1
1
10
0.01 0.1 1 10 100
Co
nce
ntr
ati
on
(m
g/L)
L/S (L/kg)
Mg concentration as function of L/S
0.00001
0.0001
0.001
0.01
0.1
1
10
100
1000
10000
100000
2 4 6 8 10 12 14
Re
lea
se
(m
g/k
g)
pH
pH dependent release of Mg
0.00001
0.0001
0.001
0.01
0.1
1
10
100
1000
10000
100000
0.01 0.1 1 10 100
(Cu
mu
lati
ve
) re
lea
se
(m
g/k
g)
L/S (L/kg)
(Cumulative) release of Mg
Final Report Appendix 7: BOFSlag Appendix Part 1: Leaching data
A possible methodology for setting pollutant limit values for aggregates in the EoW framework JRC-IPTS 76
0.1
1
10
100
1000
2 4 6 8 10 12 14
Co
nce
ntr
ati
on
(m
g/L)
pH
pH dependent concentration of Si
0.1
1
10
100
0.01 0.1 1 10 100
Co
nce
ntr
ati
on
(m
g/L)
L/S (L/kg)
Si concentration as function of L/S
0.1
1
10
100
1000
10000
2 4 6 8 10 12 14
Re
lea
se
(m
g/k
g)
pH
pH dependent release of Si
0.1
1
10
100
1000
10000
0.01 0.1 1 10 100Cu
mu
lati
ve
re
lea
se
(m
g/k
g)
L/S (L/kg)
Cumulative release of Si
0.00001
0.0001
0.001
0.01
0.1
1
10
100
1000
2 4 6 8 10 12 14
Co
nce
ntr
ati
on
(m
g/L)
pH
pH dependent concentration of Mn
0.00001
0.0001
0.001
0.01
0.1
1
10
0.01 0.1 1 10 100
Co
nce
ntr
ati
on
(m
g/L)
L/S (L/kg)
Mn concentration as function of L/S
0.000001
0.00001
0.0001
0.001
0.01
0.1
1
10
100
1000
10000
2 4 6 8 10 12 14
Re
lea
se
(m
g/k
g)
pH
pH dependent release of Mn
0.000001
0.00001
0.0001
0.001
0.01
0.1
1
10
100
1000
10000
0.01 0.1 1 10 100
(Cu
mu
lati
ve
) re
lea
se
(m
g/k
g)
L/S (L/kg)
(Cumulative) release of Mn
Final Report Appendix 7: BOFSlag Appendix Part 1: Leaching data
A possible methodology for setting pollutant limit values for aggregates in the EoW framework JRC-IPTS 77
0.1
1
10
100
2 4 6 8 10 12 14
Co
nce
ntr
ati
on
(m
g/L)
pH
pH dependent concentration of S
0.1
1
10
100
0.01 0.1 1 10 100
Co
nce
ntr
ati
on
(m
g/L)
L/S (L/kg)
S concentration as function of L/S
0.01
0.1
1
10
100
1000
2 4 6 8 10 12 14
Re
lea
se
(m
g/k
g)
pH
pH dependent release of S
0.01
0.1
1
10
100
1000
0.01 0.1 1 10 100Cu
mu
lati
ve
re
lea
se
(m
g/k
g)
L/S (L/kg)
Cumulative release of S
0.01
0.1
1
10
100
2 4 6 8 10 12 14
Co
nce
ntr
ati
on
(m
g/L)
pH
pH dependent concentration of SO4
0.01
0.1
1
10
100
0.01 0.1 1 10 100
Co
nce
ntr
ati
on
(m
g/L)
L/S (L/kg)
SO4 concentration as function of L/S
0.01
0.1
1
10
100
1000
10000
2 4 6 8 10 12 14
Re
lea
se
(m
g/k
g)
pH
pH dependent release of SO4
0.01
0.1
1
10
100
1000
10000
0.01 0.1 1 10 100Cu
mu
lati
ve
re
lea
se
(m
g/k
g)
L/S (L/kg)
Cumulative release of SO4
Final Report Appendix 7: BOFSlag Appendix Part 1: Leaching data
A possible methodology for setting pollutant limit values for aggregates in the EoW framework JRC-IPTS 78
0.1
1
10
100
2 4 6 8 10 12 14
Co
nce
ntr
ati
on
(m
g/L)
pH
pH dependent concentration of Cl
0.01
0.1
1
10
100
0.01 0.1 1 10 100
Co
nce
ntr
ati
on
(m
g/L)
L/S (L/kg)
Cl concentration as function of L/S
0.01
0.1
1
10
100
1000
2 4 6 8 10 12 14
Re
lea
se
(m
g/k
g)
pH
pH dependent release of Cl
0.01
0.1
1
10
100
1000
0.01 0.1 1 10 100Cu
mu
lati
ve
re
lea
se
(m
g/k
g)
L/S (L/kg)
Cumulative release of Cl
0.0001
0.001
0.01
0.1
1
10
100
1000
2 4 6 8 10 12 14
Co
nce
ntr
ati
on
(m
g/L)
pH
pH dependent concentration of P
0.0001
0.001
0.01
0.1
1
0.01 0.1 1 10 100
Co
nce
ntr
ati
on
(m
g/L)
L/S (L/kg)
P concentration as function of L/S
0.0001
0.001
0.01
0.1
1
10
100
1000
10000
2 4 6 8 10 12 14
Re
lea
se
(m
g/k
g)
pH
pH dependent release of P
0.0001
0.001
0.01
0.1
1
10
100
1000
10000
0.01 0.1 1 10 100Cu
mu
lati
ve
re
lea
se
(m
g/k
g)
L/S (L/kg)
Cumulative release of P
Final Report Appendix 7: BOFSlag Appendix Part 1: Leaching data
A possible methodology for setting pollutant limit values for aggregates in the EoW framework JRC-IPTS 79
0.1
1
10
100
1000
10000
2 4 6 8 10 12 14
Co
nce
ntr
ati
on
(m
g/L)
pH
pH dependent concentration of Na
0.1
1
10
100
0.01 0.1 1 10 100
Co
nce
ntr
ati
on
(m
g/L)
L/S (L/kg)
Na concentration as function of L/S
0.01
0.1
1
10
100
1000
10000
100000
2 4 6 8 10 12 14
Re
lea
se
(m
g/k
g)
pH
pH dependent release of Na
0.01
0.1
1
10
100
1000
10000
100000
0.01 0.1 1 10 100Cu
mu
lati
ve
re
lea
se
(m
g/k
g)
L/S (L/kg)
Cumulative release of Na
0.01
0.1
1
10
100
2 4 6 8 10 12 14
Co
nce
ntr
ati
on
(m
g/L)
pH
pH dependent concentration of K
0.01
0.1
1
10
100
0.01 0.1 1 10 100
Co
nce
ntr
ati
on
(m
g/L)
L/S (L/kg)
K concentration as function of L/S
0.01
0.1
1
10
100
1000
2 4 6 8 10 12 14
Re
lea
se
(m
g/k
g)
pH
pH dependent release of K
0.01
0.1
1
10
100
1000
0.01 0.1 1 10 100Cu
mu
lati
ve
re
lea
se
(m
g/k
g)
L/S (L/kg)
Cumulative release of K
Final Report Appendix 7: BOFSlag Appendix Part 1: Leaching data
A possible methodology for setting pollutant limit values for aggregates in the EoW framework JRC-IPTS 80
0.0001
0.001
0.01
0.1
1
10
2 4 6 8 10 12 14
Co
nce
ntr
ati
on
(m
g/L)
pH
pH dependent concentration of Ba
0.001
0.01
0.1
1
10
0.01 0.1 1 10 100
Co
nce
ntr
ati
on
(m
g/L)
L/S (L/kg)
Ba concentration as function of L/S
0.0001
0.001
0.01
0.1
1
10
100
2 4 6 8 10 12 14
Re
lea
se
(m
g/k
g)
pH
pH dependent release of Ba
0.0001
0.001
0.01
0.1
1
10
100
0.01 0.1 1 10 100Cu
mu
lati
ve
re
lea
se
(m
g/k
g)
L/S (L/kg)
Cumulative release of Ba
0.001
0.01
0.1
1
10
2 4 6 8 10 12 14
Co
nce
ntr
ati
on
(m
g/L)
pH
pH dependent concentration of Sr
0.01
0.1
1
10
0.01 0.1 1 10 100
Co
nce
ntr
ati
on
(m
g/L)
L/S (L/kg)
Sr concentration as function of L/S
0.001
0.01
0.1
1
10
100
1000
2 4 6 8 10 12 14
Re
lea
se
(m
g/k
g)
pH
pH dependent release of Sr
0.001
0.01
0.1
1
10
100
1000
0.01 0.1 1 10 100Cu
mu
lati
ve
re
lea
se
(m
g/k
g)
L/S (L/kg)
Cumulative release of Sr
Final Report Appendix 7: BOFSlag Appendix Part 1: Leaching data
A possible methodology for setting pollutant limit values for aggregates in the EoW framework JRC-IPTS 81
0.00001
0.0001
0.001
0.01
0.1
1
2 4 6 8 10 12 14
Co
nce
ntr
ati
on
(m
g/L)
pH
pH dependent concentration of As
0.00001
0.0001
0.001
0.01
0.1
1
0.01 0.1 1 10 100
Co
nce
ntr
ati
on
(m
g/L)
L/S (L/kg)
As concentration as function of L/S
0.000001
0.00001
0.0001
0.001
0.01
0.1
1
10
2 4 6 8 10 12 14
Re
lea
se
(m
g/k
g)
pH
pH dependent release of As
0.000001
0.00001
0.0001
0.001
0.01
0.1
1
10
0.01 0.1 1 10 100
(Cu
mu
lati
ve
) re
lea
se
(m
g/k
g)
L/S (L/kg)
(Cumulative) release of As
0.00001
0.0001
0.001
0.01
0.1
1
2 4 6 8 10 12 14
Co
nce
ntr
ati
on
(m
g/L)
pH
pH dependent concentration of Cd
0.00001
0.0001
0.001
0.01
0.1
1
0.01 0.1 1 10 100
Co
nce
ntr
ati
on
(m
g/L)
L/S (L/kg)
Cd concentration as function of L/S
0.0000001
0.000001
0.00001
0.0001
0.001
0.01
0.1
1
2 4 6 8 10 12 14
Re
lea
se
(m
g/k
g)
pH
pH dependent release of Cd
0.0000001
0.000001
0.00001
0.0001
0.001
0.01
0.1
1
0.01 0.1 1 10 100
(Cu
mu
lati
ve
) re
lea
se
(m
g/k
g)
L/S (L/kg)
(Cumulative) release of Cd
Final Report Appendix 7: BOFSlag Appendix Part 1: Leaching data
A possible methodology for setting pollutant limit values for aggregates in the EoW framework JRC-IPTS 82
0.00001
0.0001
0.001
0.01
0.1
1
10
100
2 4 6 8 10 12 14
Co
nce
ntr
ati
on
(m
g/L)
pH
pH dependent concentration of Cr
0.00001
0.0001
0.001
0.01
0.1
1
10
0.01 0.1 1 10 100
Co
nce
ntr
ati
on
(m
g/L)
L/S (L/kg)
Cr concentration as function of L/S
0.00001
0.0001
0.001
0.01
0.1
1
10
100
1000
2 4 6 8 10 12 14
Re
lea
se
(m
g/k
g)
pH
pH dependent release of Cr
0.00001
0.0001
0.001
0.01
0.1
1
10
100
1000
0.01 0.1 1 10 100
(Cu
mu
lati
ve
) re
lea
se
(m
g/k
g)
L/S (L/kg)
(Cumulative) release of Cr
0.00001
0.0001
0.001
0.01
0.1
1
2 4 6 8 10 12 14
Co
nce
ntr
ati
on
(m
g/L)
pH
pH dependent concentration of Cu
0.00001
0.0001
0.001
0.01
0.1
1
0.01 0.1 1 10 100
Co
nce
ntr
ati
on
(m
g/L)
L/S (L/kg)
Cu concentration as function of L/S
0.00001
0.0001
0.001
0.01
0.1
1
10
2 4 6 8 10 12 14
Re
lea
se
(m
g/k
g)
pH
pH dependent release of Cu
0.00001
0.0001
0.001
0.01
0.1
1
10
0.01 0.1 1 10 100
(Cu
mu
lati
ve
) re
lea
se
(m
g/k
g)
L/S (L/kg)
(Cumulative) release of Cu
Final Report Appendix 7: BOFSlag Appendix Part 1: Leaching data
A possible methodology for setting pollutant limit values for aggregates in the EoW framework JRC-IPTS 83
0.00001
0.0001
0.001
0.01
0.1
1
2 4 6 8 10 12 14
Co
nce
ntr
ati
on
(m
g/L)
pH
pH dependent concentration of Mo
0.0001
0.001
0.01
0.1
1
0.01 0.1 1 10 100
Co
nce
ntr
ati
on
(m
g/L)
L/S (L/kg)
Mo concentration as function of L/S
0.00001
0.0001
0.001
0.01
0.1
1
10
2 4 6 8 10 12 14
Re
lea
se
(m
g/k
g)
pH
pH dependent release of Mo
0.00001
0.0001
0.001
0.01
0.1
1
10
0.01 0.1 1 10 100Cu
mu
lati
ve
re
lea
se
(m
g/k
g)
L/S (L/kg)
Cumulative release of Mo
0.00001
0.0001
0.001
0.01
0.1
1
10
2 4 6 8 10 12 14
Co
nce
ntr
ati
on
(m
g/L)
pH
pH dependent concentration of Ni
0.00001
0.0001
0.001
0.01
0.1
1
0.01 0.1 1 10 100
Co
nce
ntr
ati
on
(m
g/L)
L/S (L/kg)
Ni concentration as function of L/S
0.00001
0.0001
0.001
0.01
0.1
1
10
100
2 4 6 8 10 12 14
Re
lea
se
(m
g/k
g)
pH
pH dependent release of Ni
0.00001
0.0001
0.001
0.01
0.1
1
10
100
0.01 0.1 1 10 100
(Cu
mu
lati
ve
) re
lea
se
(m
g/k
g)
L/S (L/kg)
(Cumulative) release of Ni
Final Report Appendix 7: BOFSlag Appendix Part 1: Leaching data
A possible methodology for setting pollutant limit values for aggregates in the EoW framework JRC-IPTS 84
0.00001
0.0001
0.001
0.01
0.1
1
2 4 6 8 10 12 14
Co
nce
ntr
ati
on
(m
g/L)
pH
pH dependent concentration of Pb
0.00001
0.0001
0.001
0.01
0.1
1
0.01 0.1 1 10 100
Co
nce
ntr
ati
on
(m
g/L)
L/S (L/kg)
Pb concentration as function of L/S
0.00001
0.0001
0.001
0.01
0.1
1
10
100
2 4 6 8 10 12 14
Re
lea
se
(m
g/k
g)
pH
pH dependent release of Pb
0.00001
0.0001
0.001
0.01
0.1
1
10
100
0.01 0.1 1 10 100
(Cu
mu
lati
ve
) re
lea
se
(m
g/k
g)
L/S (L/kg)
(Cumulative) release of Pb
0.0001
0.001
0.01
0.1
1
2 4 6 8 10 12 14
Co
nce
ntr
ati
on
(m
g/L)
pH
pH dependent concentration of Sb
0.0001
0.001
0.01
0.1
1
0.01 0.1 1 10 100
Co
nce
ntr
ati
on
(m
g/L)
L/S (L/kg)
Sb concentration as function of L/S
0.00001
0.0001
0.001
0.01
0.1
1
2 4 6 8 10 12 14
Re
lea
se
(m
g/k
g)
pH
pH dependent release of Sb
0.00001
0.0001
0.001
0.01
0.1
1
0.01 0.1 1 10 100Cu
mu
lati
ve
re
lea
se
(m
g/k
g)
L/S (L/kg)
Cumulative release of Sb
Final Report Appendix 7: BOFSlag Appendix Part 1: Leaching data
A possible methodology for setting pollutant limit values for aggregates in the EoW framework JRC-IPTS 85
0.0001
0.001
0.01
0.1
1
2 4 6 8 10 12 14
Co
nce
ntr
ati
on
(m
g/L)
pH
pH dependent concentration of Se
0.00001
0.0001
0.001
0.01
0.1
1
0.01 0.1 1 10 100
Co
nce
ntr
ati
on
(m
g/L)
L/S (L/kg)
Se concentration as function of L/S
0.0001
0.001
0.01
0.1
1
10
2 4 6 8 10 12 14
Re
lea
se
(m
g/k
g)
pH
pH dependent release of Se
0.0001
0.001
0.01
0.1
1
10
0.01 0.1 1 10 100Cu
mu
lati
ve
re
lea
se
(m
g/k
g)
L/S (L/kg)
Cumulative release of Se
0.00001
0.0001
0.001
0.01
0.1
1
2 4 6 8 10 12 14
Co
nce
ntr
ati
on
(m
g/L)
pH
pH dependent concentration of Sn
0.00001
0.0001
0.001
0.01
0.1
1
0.01 0.1 1 10 100
Co
nce
ntr
ati
on
(m
g/L)
L/S (L/kg)
Sn concentration as function of L/S
0.000001
0.00001
0.0001
0.001
0.01
0.1
1
10
2 4 6 8 10 12 14
Re
lea
se
(m
g/k
g)
pH
pH dependent release of Sn
0.000001
0.00001
0.0001
0.001
0.01
0.1
1
10
0.01 0.1 1 10 100Cu
mu
lati
ve
re
lea
se
(m
g/k
g)
L/S (L/kg)
Cumulative release of Sn
Final Report Appendix 7: BOFSlag Appendix Part 1: Leaching data
A possible methodology for setting pollutant limit values for aggregates in the EoW framework JRC-IPTS 86
0.0001
0.001
0.01
0.1
1
10
100
2 4 6 8 10 12 14
Co
nce
ntr
ati
on
(m
g/L)
pH
pH dependent concentration of V
0.00001
0.0001
0.001
0.01
0.1
1
10
100
0.01 0.1 1 10 100
Co
nce
ntr
ati
on
(m
g/L)
L/S (L/kg)
V concentration as function of L/S
0.00001
0.0001
0.001
0.01
0.1
1
10
100
1000
10000
2 4 6 8 10 12 14
Re
lea
se
(m
g/k
g)
pH
pH dependent release of V
0.00001
0.0001
0.001
0.01
0.1
1
10
100
1000
10000
0.01 0.1 1 10 100Cu
mu
lati
ve
re
lea
se
(m
g/k
g)
L/S (L/kg)
Cumulative release of V
Carbonated
0.00001
0.0001
0.001
0.01
0.1
1
10
2 4 6 8 10 12 14
Co
nce
ntr
ati
on
(m
g/L)
pH
pH dependent concentration of Zn
0.0001
0.001
0.01
0.1
1
0.01 0.1 1 10 100
Co
nce
ntr
ati
on
(m
g/L)
L/S (L/kg)
Zn concentration as function of L/S
0.0001
0.001
0.01
0.1
1
10
100
2 4 6 8 10 12 14
Re
lea
se
(m
g/k
g)
pH
pH dependent release of Zn
0.0001
0.001
0.01
0.1
1
10
100
0.01 0.1 1 10 100
(Cu
mu
lati
ve
) re
lea
se
(m
g/k
g)
L/S (L/kg)
(Cumulative) release of Zn
Final Report Appendix 7: BOFSlag Appendix Part 1: Leaching data
A possible methodology for setting pollutant limit values for aggregates in the EoW framework JRC-IPTS 87
0
2
4
6
8
10
12
14
0.01 0.1 1 10 100
pH
L/S (L/kg)
pH development as function of L/S
Final Report Appendix 8: EAFSlag Appendix Part 1: Leaching data
A possible methodology for setting pollutant limit values for aggregates in the EoW framework JRC-IPTS 88
0.01
0.1
1
10
100
1000
10000
2 4 6 8 10 12 14
Co
nce
ntr
ati
on
(m
g/L)
pH
pH dependent concentration of Al
0.1
1
10
100
1000
0.1 1 10 100
Co
nce
ntr
ati
on
(m
g/L)
L/S (L/kg)
Al concentration as function of L/S
0.1
1
10
100
1000
10000
100000
2 4 6 8 10 12 14
Re
lea
se
(m
g/k
g)
pH
pH dependent release of Al
0.1
1
10
100
1000
10000
100000
0.1 1 10 100(Cu
mu
lati
ve
) re
lea
se
(m
g/k
g)
L/S (L/kg)
(Cumulative) release of Al
1
10
100
1000
10000
100000
2 4 6 8 10 12 14
Co
nce
ntr
ati
on
(m
g/L)
pH
pH dependent concentration of Ca
1
10
100
1000
0.1 1 10 100
Co
nce
ntr
ati
on
(m
g/L)
L/S (L/kg)
Ca concentration as function of L/S
1
10
100
1000
10000
100000
1000000
2 4 6 8 10 12 14
Re
lea
se
(m
g/k
g)
pH
pH dependent release of Ca
1
10
100
1000
10000
100000
1000000
0.1 1 10 100(Cu
mu
lati
ve
) re
lea
se
(m
g/k
g)
L/S (L/kg)
(Cumulative) release of Ca
Final Report Appendix 8: EAFSlag Appendix Part 1: Leaching data
A possible methodology for setting pollutant limit values for aggregates in the EoW framework JRC-IPTS 89
0.001
0.01
0.1
1
10
100
1000
10000
2 4 6 8 10 12 14
Co
nce
ntr
ati
on
(m
g/L)
pH
pH dependent concentration of Fe
0.001
0.01
0.1
1
0.1 1 10 100
Co
nce
ntr
ati
on
(m
g/L)
L/S (L/kg)
Fe concentration as function of L/S
0.01
0.1
1
10
100
1000
10000
100000
2 4 6 8 10 12 14
Re
lea
se
(m
g/k
g)
pH
pH dependent release of Fe
0.01
0.1
1
10
100
1000
10000
100000
0.1 1 10 100(Cu
mu
lati
ve
) re
lea
se
(m
g/k
g)
L/S (L/kg)
(Cumulative) release of Fe
0.01
0.1
1
10
100
1000
10000
2 4 6 8 10 12 14
Co
nce
ntr
ati
on
(m
g/L)
pH
pH dependent concentration of Mg
0.01
0.1
1
0.1 1 10 100
Co
nce
ntr
ati
on
(m
g/L)
L/S (L/kg)
Mg concentration as function of L/S
0.01
0.1
1
10
100
1000
10000
100000
2 4 6 8 10 12 14
Re
lea
se
(m
g/k
g)
pH
pH dependent release of Mg
0.01
0.1
1
10
100
1000
10000
100000
0.1 1 10 100(Cu
mu
lati
ve
) re
lea
se
(m
g/k
g)
L/S (L/kg)
(Cumulative) release of Mg
Final Report Appendix 8: EAFSlag Appendix Part 1: Leaching data
A possible methodology for setting pollutant limit values for aggregates in the EoW framework JRC-IPTS 90
0.0001
0.001
0.01
0.1
1
10
100
1000
10000
2 4 6 8 10 12 14
Co
nce
ntr
ati
on
(m
g/L)
pH
pH dependent concentration of Mn
0.0001
0.001
0.01
0.1
1
0.1 1 10 100
Co
nce
ntr
ati
on
(m
g/L)
L/S (L/kg)
Mn concentration as function of L/S
0.0001
0.001
0.01
0.1
1
10
100
1000
10000
100000
2 4 6 8 10 12 14
Re
lea
se
(m
g/k
g)
pH
pH dependent release of Mn
0.0001
0.001
0.01
0.1
1
10
100
1000
10000
100000
0.1 1 10 100(Cu
mu
lati
ve
) re
lea
se
(m
g/k
g)
L/S (L/kg)
(Cumulative) release of Mn
0.01
0.1
1
10
100
2 4 6 8 10 12 14
Co
nce
ntr
ati
on
(m
g/L)
pH
pH dependent concentration of Si
0.01
0.1
1
10
0.1 1 10 100
Co
nce
ntr
ati
on
(m
g/L)
L/S (L/kg)
Si concentration as function of L/S
0.1
1
10
100
1000
2 4 6 8 10 12 14
Re
lea
se
(m
g/k
g)
pH
pH dependent release of Si
0.1
1
10
100
1000
0.1 1 10 100(Cu
mu
lati
ve
) re
lea
se
(m
g/k
g)
L/S (L/kg)
(Cumulative) release of Si
Final Report Appendix 8: EAFSlag Appendix Part 1: Leaching data
A possible methodology for setting pollutant limit values for aggregates in the EoW framework JRC-IPTS 91
1
10
100
2 4 6 8 10 12 14
Co
nce
ntr
ati
on
(m
g/L)
pH
pH dependent concentration of SO4
1
10
100
1 10 100
Co
nce
ntr
ati
on
(m
g/L)
L/S (L/kg)
SO4 concentration as function of L/S
1
10
100
1000
10000
100000
2 4 6 8 10 12 14
Re
lea
se
(m
g/k
g)
pH
pH dependent release of SO4
1
10
100
1000
10000
100000
1 10 100
Re
lea
se
(m
g/k
g)
L/S (L/kg)
Release of SO4
0.001
0.01
0.1
1
10
100
2 4 6 8 10 12 14
Co
nce
ntr
ati
on
(m
g/L)
pH
pH dependent concentration of Ba
0.001
0.01
0.1
1
0.1 1 10 100
Co
nce
ntr
ati
on
(m
g/L)
L/S (L/kg)
Ba concentration as function of L/S
0.001
0.01
0.1
1
10
100
1000
2 4 6 8 10 12 14
Re
lea
se
(m
g/k
g)
pH
pH dependent release of Ba
0.001
0.01
0.1
1
10
100
1000
0.1 1 10 100(Cu
mu
lati
ve
) re
lea
se
(m
g/k
g)
L/S (L/kg)
(Cumulative) release of Ba
Final Report Appendix 8: EAFSlag Appendix Part 1: Leaching data
A possible methodology for setting pollutant limit values for aggregates in the EoW framework JRC-IPTS 92
0.1
1
10
2 4 6 8 10 12 14
Co
nce
ntr
ati
on
(m
g/L)
pH
pH dependent concentration of Cl
0.1
1
10
0.1 1 10 100
Co
nce
ntr
ati
on
(m
g/L)
L/S (L/kg)
Cl concentration as function of L/S
0.1
1
10
100
1000
10000
100000
2 4 6 8 10 12 14
Re
lea
se
(m
g/k
g)
pH
pH dependent release of Cl
0.1
1
10
100
1000
10000
0.1 1 10 100(Cu
mu
lati
ve
) re
lea
se
(m
g/k
g)
L/S (L/kg)
(Cumulative) release of Cl
1
10
100
2 4 6 8 10 12 14
Co
nce
ntr
ati
on
(m
g/L)
pH
pH dependent concentration of K
1
10
100
1 10
Co
nce
ntr
ati
on
(m
g/L)
L/S (L/kg)
K concentration as function of L/S
1
10
100
1000
2 4 6 8 10 12 14
Re
lea
se
(m
g/k
g)
pH
pH dependent release of K
1
10
100
1000
1 10
Re
lea
se
(m
g/k
g)
L/S (L/kg)
Release of K
Final Report Appendix 8: EAFSlag Appendix Part 1: Leaching data
A possible methodology for setting pollutant limit values for aggregates in the EoW framework JRC-IPTS 93
0.001
0.01
0.1
1
2 4 6 8 10 12 14
Co
nce
ntr
ati
on
(m
g/L)
pH
pH dependent concentration of As
0.001
0.01
0.1
1
1 10 100
Co
nce
ntr
ati
on
(m
g/L)
L/S (L/kg)
As concentration as function of L/S
0.001
0.01
0.1
1
10
100
1000
10000
100000
2 4 6 8 10 12 14
Re
lea
se
(m
g/k
g)
pH
pH dependent release of As
0.001
0.01
0.1
1
10
100
1000
10000
100000
0.1 1 10 100(Cu
mu
lati
ve
) re
lea
se
(m
g/k
g)
L/S (L/kg)
(Cumulative) release of As
0.001
0.01
0.1
1
2 4 6 8 10 12 14
Co
nce
ntr
ati
on
(m
g/L)
pH
pH dependent concentration of Cd
0.01
0.1
1
1 10 100
Co
nce
ntr
ati
on
(m
g/L)
L/S (L/kg)
Cd concentration as function of L/S
0.001
0.01
0.1
1
10
100
1000
10000
100000
2 4 6 8 10 12 14
Re
lea
se
(m
g/k
g)
pH
pH dependent release of Cd
0.001
0.01
0.1
1
10
100
1000
10000
100000
0.1 1 10 100(Cu
mu
lati
ve
) re
lea
se
(m
g/k
g)
L/S (L/kg)
(Cumulative) release of Cd
Final Report Appendix 8: EAFSlag Appendix Part 1: Leaching data
A possible methodology for setting pollutant limit values for aggregates in the EoW framework JRC-IPTS 94
0.001
0.01
0.1
1
10
100
2 4 6 8 10 12 14
Co
nce
ntr
ati
on
(m
g/L)
pH
pH dependent concentration of Cr
0.001
0.01
0.1
1
0.1 1 10 100
Co
nce
ntr
ati
on
(m
g/L)
L/S (L/kg)
Cr concentration as function of L/S
0.01
0.1
1
10
100
1000
2 4 6 8 10 12 14
Re
lea
se
(m
g/k
g)
pH
pH dependent release of Cr
0.01
0.1
1
10
100
1000
0.1 1 10 100(Cu
mu
lati
ve
) re
lea
se
(m
g/k
g)
L/S (L/kg)
(Cumulative) release of Cr
0.0001
0.001
0.01
0.1
1
2 4 6 8 10 12 14
Co
nce
ntr
ati
on
(m
g/L)
pH
pH dependent concentration of Cu
0.0001
0.001
0.01
0.1
1
0.1 1 10 100
Co
nce
ntr
ati
on
(m
g/L)
L/S (L/kg)
Cu concentration as function of L/S
0.0001
0.001
0.01
0.1
1
10
100
1000
10000
100000
2 4 6 8 10 12 14
Re
lea
se
(m
g/k
g)
pH
pH dependent release of Cu
0.0001
0.001
0.01
0.1
1
10
100
1000
10000
100000
0.1 1 10 100(Cu
mu
lati
ve
) re
lea
se
(m
g/k
g)
L/S (L/kg)
(Cumulative) release of Cu
Final Report Appendix 8: EAFSlag Appendix Part 1: Leaching data
A possible methodology for setting pollutant limit values for aggregates in the EoW framework JRC-IPTS 95
0.01
0.1
1
10
2 4 6 8 10 12 14
Co
nce
ntr
ati
on
(m
g/L)
pH
pH dependent concentration of Mo
0.01
0.1
1
0.1 1 10 100
Co
nce
ntr
ati
on
(m
g/L)
L/S (L/kg)
Mo concentration as function of L/S
0.01
0.1
1
10
100
2 4 6 8 10 12 14
Re
lea
se
(m
g/k
g)
pH
pH dependent release of Mo
0.01
0.1
1
10
100
0.1 1 10 100(Cu
mu
lati
ve
) re
lea
se
(m
g/k
g)
L/S (L/kg)
(Cumulative) release of Mo
0.0001
0.001
0.01
0.1
1
2 4 6 8 10 12 14
Co
nce
ntr
ati
on
(m
g/L)
pH
pH dependent concentration of Ni
0.0001
0.001
0.01
0.1
1
0.1 1 10 100
Co
nce
ntr
ati
on
(m
g/L)
L/S (L/kg)
Ni concentration as function of L/S
0.0001
0.001
0.01
0.1
1
10
100
1000
10000
100000
2 4 6 8 10 12 14
Re
lea
se
(m
g/k
g)
pH
pH dependent release of Ni
0.0001
0.001
0.01
0.1
1
10
100
1000
10000
100000
0.1 1 10 100(Cu
mu
lati
ve
) re
lea
se
(m
g/k
g)
L/S (L/kg)
(Cumulative) release of Ni
Final Report Appendix 8: EAFSlag Appendix Part 1: Leaching data
A possible methodology for setting pollutant limit values for aggregates in the EoW framework JRC-IPTS 96
0.001
0.01
0.1
1
2 4 6 8 10 12 14
Co
nce
ntr
ati
on
(m
g/L)
pH
pH dependent concentration of Pb
0.001
0.01
0.1
1
1 10 100
Co
nce
ntr
ati
on
(m
g/L)
L/S (L/kg)
Pb concentration as function of L/S
0.001
0.01
0.1
1
10
100
1000
10000
100000
2 4 6 8 10 12 14
Re
lea
se
(m
g/k
g)
pH
pH dependent release of Pb
0.001
0.01
0.1
1
10
100
1000
10000
100000
0.1 1 10 100(Cu
mu
lati
ve
) re
lea
se
(m
g/k
g)
L/S (L/kg)
(Cumulative) release of Pb
0.0001
0.001
0.01
0.1
1
2 4 6 8 10 12 14
Co
nce
ntr
ati
on
(m
g/L)
pH
pH dependent concentration of Sb
0.001
0.01
0.1
1
1 10
Co
nce
ntr
ati
on
(m
g/L)
L/S (L/kg)
Sb concentration as function of L/S
0.0001
0.001
0.01
0.1
1
10
100
1000
10000
100000
2 4 6 8 10 12 14
Re
lea
se
(m
g/k
g)
pH
pH dependent release of Sb
0.0001
0.001
0.01
0.1
1
10
100
1000
10000
100000
0.1 1 10 100(Cu
mu
lati
ve
) re
lea
se
(m
g/k
g)
L/S (L/kg)
(Cumulative) release of Sb
Final Report Appendix 8: EAFSlag Appendix Part 1: Leaching data
A possible methodology for setting pollutant limit values for aggregates in the EoW framework JRC-IPTS 97
0.001
0.01
0.1
1
2 4 6 8 10 12 14
Co
nce
ntr
ati
on
(m
g/L)
pH
pH dependent concentration of Se
0.001
0.01
0.1
1
1 10 100
Co
nce
ntr
ati
on
(m
g/L)
L/S (L/kg)
Se concentration as function of L/S
0.001
0.01
0.1
1
10
100
1000
10000
100000
2 4 6 8 10 12 14
Re
lea
se
(m
g/k
g)
pH
pH dependent release of Se
0.001
0.01
0.1
1
10
100
1000
10000
100000
0.1 1 10 100(Cu
mu
lati
ve
) re
lea
se
(m
g/k
g)
L/S (L/kg)
(Cumulative) release of Se
0.0001
0.001
0.01
0.1
1
10
2 4 6 8 10 12 14
Co
nce
ntr
ati
on
(m
g/L)
pH
pH dependent concentration of V
0.0001
0.001
0.01
0.1
1
0.1 1 10 100
Co
nce
ntr
ati
on
(m
g/L)
L/S (L/kg)
V concentration as function of L/S
0.001
0.01
0.1
1
10
100
2 4 6 8 10 12 14
Re
lea
se
(m
g/k
g)
pH
pH dependent release of V
0.001
0.01
0.1
1
10
100
0.1 1 10 100(Cu
mu
lati
ve
) re
lea
se
(m
g/k
g)
L/S (L/kg)
(Cumulative) release of V
Final Report Appendix 8: EAFSlag Appendix Part 1: Leaching data
A possible methodology for setting pollutant limit values for aggregates in the EoW framework JRC-IPTS 98
Note: percolation was not TS 14405, but a down flow test with daily additions of water (i.e much shorter contact time than in TS14405).
0.001
0.01
0.1
1
10
2 4 6 8 10 12 14
Co
nce
ntr
ati
on
(m
g/L)
pH
pH dependent concentration of Zn
0.001
0.01
0.1
1
1 10 100
Co
nce
ntr
ati
on
(m
g/L)
L/S (L/kg)
Zn concentration as function of L/S
0.001
0.01
0.1
1
10
100
2 4 6 8 10 12 14
Re
lea
se
(m
g/k
g)
pH
pH dependent release of Zn
0.001
0.01
0.1
1
10
100
0.1 1 10 100(Cu
mu
lati
ve
) re
lea
se
(m
g/k
g)
L/S (L/kg)
(Cumulative) release of Zn
0
2
4
6
8
10
12
14
0.1 1 10 100
pH
L/S (L/kg)
pH development as function of L/S
Final Report Appendix 9: PSlag Appendix Part 1: Leaching data
A possible methodology for setting pollutant limit values for aggregates in the EoW framework JRC-IPTS 99
0.0001
0.001
0.01
0.1
1
10
100
2 4 6 8 10 12 14
Co
nce
ntr
ati
on
(m
g/L)
pH
pH dependent concentration of Al
0.001
0.01
0.1
1
10
100
1000
0.01 0.1 1 10 100
Co
nce
ntr
ati
on
(m
g/L)
L/S (L/kg)
Al concentration as function of L/S
0.0001
0.001
0.01
0.1
1
10
100
1000
10000
2 4 6 8 10 12 14
Re
lea
se
(m
g/k
g)
pH
pH dependent release of Al
0.0001
0.001
0.01
0.1
1
10
100
1000
10000
0.01 0.1 1 10 100Cu
mu
lati
ve
re
lea
se
(m
g/k
g)
L/S (L/kg)
Cumulative release of Al
1
10
100
1000
10000
2 4 6 8 10 12 14
Co
nce
ntr
ati
on
(m
g/L)
pH
pH dependent concentration of Ca
0.001
0.01
0.1
1
10
100
1000
10000
0.01 0.1 1 10 100
Co
nce
ntr
ati
on
(m
g/L)
L/S (L/kg)
Ca concentration as function of L/S
0.001
0.01
0.1
1
10
100
1000
10000
100000
1000000
2 4 6 8 10 12 14
Re
lea
se
(m
g/k
g)
pH
pH dependent release of Ca
0.001
0.01
0.1
1
10
100
1000
10000
100000
1000000
0.01 0.1 1 10 100Cu
mu
lati
ve
re
lea
se
(m
g/k
g)
L/S (L/kg)
Cumulative release of Ca
Final Report Appendix 9: PSlag Appendix Part 1: Leaching data
A possible methodology for setting pollutant limit values for aggregates in the EoW framework JRC-IPTS 100
0.0001
0.001
0.01
0.1
1
10
2 4 6 8 10 12 14
Co
nce
ntr
ati
on
(m
g/L)
pH
pH dependent concentration of Fe
0.0001
0.001
0.01
0.1
1
0.01 0.1 1 10 100
Co
nce
ntr
ati
on
(m
g/L)
L/S (L/kg)
Fe concentration as function of L/S
0.0001
0.001
0.01
0.1
1
10
100
2 4 6 8 10 12 14
Re
lea
se
(m
g/k
g)
pH
pH dependent release of Fe
0.0001
0.001
0.01
0.1
1
10
100
0.01 0.1 1 10 100Cu
mu
lati
ve
re
lea
se
(m
g/k
g)
L/S (L/kg)
Cumulative release of Fe
0.0001
0.001
0.01
0.1
1
10
100
2 4 6 8 10 12 14
Co
nce
ntr
ati
on
(m
g/L)
pH
pH dependent concentration of Mg
0.001
0.01
0.1
1
10
100
0.01 0.1 1 10 100
Co
nce
ntr
ati
on
(m
g/L)
L/S (L/kg)
Mg concentration as function of L/S
0.001
0.01
0.1
1
10
100
1000
10000
2 4 6 8 10 12 14
Re
lea
se
(m
g/k
g)
pH
pH dependent release of Mg
0.001
0.01
0.1
1
10
100
1000
10000
0.01 0.1 1 10 100Cu
mu
lati
ve
re
lea
se
(m
g/k
g)
L/S (L/kg)
Cumulative release of Mg
Final Report Appendix 9: PSlag Appendix Part 1: Leaching data
A possible methodology for setting pollutant limit values for aggregates in the EoW framework JRC-IPTS 101
0.1
1
10
100
1000
10000
100000
2 4 6 8 10 12 14
Re
lea
se
(m
g/k
g)
pH
pH dependent release of Si
0.1
1
10
100
1000
10000
100000
0.1 1 10Cu
mu
lati
ve
re
lea
se
(m
g/k
g)
L/S (L/kg)
Cumulative release of Si
0.0001
0.001
0.01
0.1
1
10
2 4 6 8 10 12 14
Co
nce
ntr
ati
on
(m
g/L)
pH
pH dependent concentration of Mn
0.0001
0.001
0.01
0.1
1
0.01 0.1 1 10 100
Co
nce
ntr
ati
on
(m
g/L)
L/S (L/kg)
Mn concentration as function of L/S
0.00001
0.0001
0.001
0.01
0.1
1
10
100
2 4 6 8 10 12 14
Re
lea
se
(m
g/k
g)
pH
pH dependent release of Mn
0.00001
0.0001
0.001
0.01
0.1
1
10
100
0.01 0.1 1 10 100Cu
mu
lati
ve
re
lea
se
(m
g/k
g)
L/S (L/kg)
Cumulative release of Mn
1
10
100
1000
10000
2 4 6 8 10 12 14
Co
nce
ntr
ati
on
(m
g/L)
pH
pH dependent concentration of Si
1
10
100
0.1 1 10
Co
nce
ntr
ati
on
(m
g/L)
L/S (L/kg)
Si concentration as function of L/S
Final Report Appendix 9: PSlag Appendix Part 1: Leaching data
A possible methodology for setting pollutant limit values for aggregates in the EoW framework JRC-IPTS 102
1
10
100
1000
10000
2 4 6 8 10 12 14
Co
nce
ntr
ati
on
(m
g/L)
pH
pH dependent concentration of S
1
10
100
1000
10000
0.1 1 10 100
Co
nce
ntr
ati
on
(m
g/L)
L/S (L/kg)
S concentration as function of L/S
1
10
100
1000
10000
100000
2 4 6 8 10 12 14
Re
lea
se
(m
g/k
g)
pH
pH dependent release of S
1
10
100
1000
10000
100000
0.1 1 10 100Cu
mu
lati
ve
re
lea
se
(m
g/k
g)
L/S (L/kg)
Cumulative release of S
0.01
0.1
1
10
100
1000
10000
0.1 1 10 100
Co
nce
ntr
ati
on
(m
g/L)
L/S (L/kg)
SO4 concentration as function of L/S
0.01
0.1
1
10
100
1000
10000
100000
1000000
0.1 1 10 100Cu
mu
lati
ve
re
lea
se
(m
g/k
g)
L/S (L/kg)
Cumulative release of SO4
0.001
0.01
0.1
1
10
100
0.1 1 10 100
Co
nce
ntr
ati
on
(m
g/L)
L/S (L/kg)
F concentration as function of L/S
0.001
0.01
0.1
1
10
100
1000
10000
0.1 1 10 100Cu
mu
lati
ve
re
lea
se
(m
g/k
g)
L/S (L/kg)
Cumulative release of F
Final Report Appendix 9: PSlag Appendix Part 1: Leaching data
A possible methodology for setting pollutant limit values for aggregates in the EoW framework JRC-IPTS 103
0.001
0.01
0.1
1
10
100
1000
10000
100000
0.1 1 10 100
Co
nce
ntr
ati
on
(m
g/L)
L/S (L/kg)
Cl concentration as function of L/S
0.1
1
10
100
1000
10000
100000
1000000
10000000
0.1 1 10 100Cu
mu
lati
ve
re
lea
se
(m
g/k
g)
L/S (L/kg)
Cumulative release of Cl
0.01
0.1
1
10
2 4 6 8 10 12 14
Co
nce
ntr
ati
on
(m
g/L)
pH
pH dependent concentration of P
0.01
0.1
1
10
100
0.1 1 10
Co
nce
ntr
ati
on
(m
g/L)
L/S (L/kg)
P concentration as function of L/S
0.1
1
10
100
2 4 6 8 10 12 14
Re
lea
se
(m
g/k
g)
pH
pH dependent release of P
0.1
1
10
100
0.1 1 10Cu
mu
lati
ve
re
lea
se
(m
g/k
g)
L/S (L/kg)
Cumulative release of P
1
10
100
1000
2 4 6 8 10 12 14
Co
nce
ntr
ati
on
(m
g/L)
pH
pH dependent concentration of Na
0.1
1
10
100
1000
10000
0.01 0.1 1 10 100
Co
nce
ntr
ati
on
(m
g/L)
L/S (L/kg)
Na concentration as function of L/S
Final Report Appendix 9: PSlag Appendix Part 1: Leaching data
A possible methodology for setting pollutant limit values for aggregates in the EoW framework JRC-IPTS 104
0.1
1
10
100
2 4 6 8 10 12 14
Co
nce
ntr
ati
on
(m
g/L)
pH
pH dependent concentration of K
0.1
1
10
100
1000
0.01 0.1 1 10 100
Co
nce
ntr
ati
on
(m
g/L)
L/S (L/kg)
K concentration as function of L/S
0.1
1
10
100
1000
10000
100000
2 4 6 8 10 12 14
Re
lea
se
(m
g/k
g)
pH
pH dependent release of K
0.1
1
10
100
1000
10000
100000
0.01 0.1 1 10 100Cu
mu
lati
ve
re
lea
se
(m
g/k
g)
L/S (L/kg)
Cumulative release of K
0.01
0.1
1
10
2 4 6 8 10 12 14
Co
nce
ntr
ati
on
(m
g/L)
pH
pH dependent concentration of Ba
0.001
0.01
0.1
1
10
100
0.01 0.1 1 10 100
Co
nce
ntr
ati
on
(m
g/L)
L/S (L/kg)
Ba concentration as function of L/S
0.001
0.01
0.1
1
10
100
1000
2 4 6 8 10 12 14
Re
lea
se
(m
g/k
g)
pH
pH dependent release of Ba
0.001
0.01
0.1
1
10
100
1000
0.01 0.1 1 10 100Cu
mu
lati
ve
re
lea
se
(m
g/k
g)
L/S (L/kg)
Cumulative release of Ba
Final Report Appendix 9: PSlag Appendix Part 1: Leaching data
A possible methodology for setting pollutant limit values for aggregates in the EoW framework JRC-IPTS 105
0.1
1
10
100
2 4 6 8 10 12 14
Co
nce
ntr
ati
on
(m
g/L)
pH
pH dependent concentration of Sr
0.01
0.1
1
10
100
0.01 0.1 1 10 100
Co
nce
ntr
ati
on
(m
g/L)
L/S (L/kg)
Sr concentration as function of L/S
0.01
0.1
1
10
100
1000
2 4 6 8 10 12 14
Re
lea
se
(m
g/k
g)
pH
pH dependent release of Sr
0.01
0.1
1
10
100
1000
0.01 0.1 1 10 100Cu
mu
lati
ve
re
lea
se
(m
g/k
g)
L/S (L/kg)
Cumulative release of Sr
0.001
0.01
0.1
1
2 4 6 8 10 12 14
Co
nce
ntr
ati
on
(m
g/L)
pH
pH dependent concentration of As
0.0001
0.001
0.01
0.1
1
0.01 0.1 1 10 100
Co
nce
ntr
ati
on
(m
g/L)
L/S (L/kg)
As concentration as function of L/S
0.00001
0.0001
0.001
0.01
0.1
1
10
100
2 4 6 8 10 12 14
Re
lea
se
(m
g/k
g)
pH
pH dependent release of As
0.00001
0.0001
0.001
0.01
0.1
1
10
100
0.01 0.1 1 10 100Cu
mu
lati
ve
re
lea
se
(m
g/k
g)
L/S (L/kg)
Cumulative release of As
Final Report Appendix 9: PSlag Appendix Part 1: Leaching data
A possible methodology for setting pollutant limit values for aggregates in the EoW framework JRC-IPTS 106
0.0001
0.001
0.01
0.1
1
2 4 6 8 10 12 14
Co
nce
ntr
ati
on
(m
g/L)
pH
pH dependent concentration of Cr
0.0001
0.001
0.01
0.1
1
0.01 0.1 1 10 100
Co
nce
ntr
ati
on
(m
g/L)
L/S (L/kg)
Cr concentration as function of L/S
0.00001
0.0001
0.001
0.01
0.1
1
10
2 4 6 8 10 12 14
Re
lea
se
(m
g/k
g)
pH
pH dependent release of Cr
0.00001
0.0001
0.001
0.01
0.1
1
10
0.01 0.1 1 10 100Cu
mu
lati
ve
re
lea
se
(m
g/k
g)
L/S (L/kg)
Cumulative release of Cr
0.00001
0.0001
0.001
0.01
0.1
2 4 6 8 10 12 14
Co
nce
ntr
ati
on
(m
g/L)
pH
pH dependent concentration of Cd
0.000001
0.00001
0.0001
0.001
0.01
0.1
1
2 4 6 8 10 12 14
Re
lea
se
(m
g/k
g)
pH
pH dependent release of Cd
0.00001
0.0001
0.001
0.01
0.1
0.01 0.1 1 10 100
Co
nce
ntr
ati
on
(m
g/L)
L/S (L/kg)
Cd concentration as function of L/S
0.000001
0.00001
0.0001
0.001
0.01
0.1
1
0.01 0.1 1 10 100
Cu
mu
lati
ve
re
lea
se
(m
g/k
g)
L/S (L/kg)
Cumulative release of Cd
Final Report Appendix 9: PSlag Appendix Part 1: Leaching data
A possible methodology for setting pollutant limit values for aggregates in the EoW framework JRC-IPTS 107
0.0001
0.001
0.01
0.1
1
2 4 6 8 10 12 14
Co
nce
ntr
ati
on
(m
g/L)
pH
pH dependent concentration of Mo
0.0001
0.001
0.01
0.1
1
10
0.01 0.1 1 10 100
Co
nce
ntr
ati
on
(m
g/L)
L/S (L/kg)
Mo concentration as function of L/S
0.00001
0.0001
0.001
0.01
0.1
1
10
100
1000
2 4 6 8 10 12 14
Re
lea
se
(m
g/k
g)
pH
pH dependent release of Mo
0.00001
0.0001
0.001
0.01
0.1
1
10
100
1000
0.01 0.1 1 10 100Cu
mu
lati
ve
re
lea
se
(m
g/k
g)
L/S (L/kg)
Cumulative release of Mo
0.00001
0.0001
0.001
0.01
0.1
1
10
2 4 6 8 10 12 14
Re
lea
se
(m
g/k
g)
pH
pH dependent release of Cu
0.0001
0.001
0.01
0.1
1
0.01 0.1 1 10 100
Co
nce
ntr
ati
on
(m
g/L)
L/S (L/kg)
Cu concentration as function of L/S
0.00001
0.0001
0.001
0.01
0.1
1
10
0.01 0.1 1 10 100
Cu
mu
lati
ve
re
lea
se
(m
g/k
g)
L/S (L/kg)
Cumulative release of Cu
0.0001
0.001
0.01
0.1
1
2 4 6 8 10 12 14
Co
nce
ntr
ati
on
(m
g/L)
pH
pH dependent concentration of Cu
Final Report Appendix 9: PSlag Appendix Part 1: Leaching data
A possible methodology for setting pollutant limit values for aggregates in the EoW framework JRC-IPTS 108
0.001
0.01
0.1
1
2 4 6 8 10 12 14
Co
nce
ntr
ati
on
(m
g/L)
pH
pH dependent concentration of Ni
0.0001
0.001
0.01
0.1
1
0.01 0.1 1 10 100
Co
nce
ntr
ati
on
(m
g/L)
L/S (L/kg)
Ni concentration as function of L/S
0.0001
0.001
0.01
0.1
1
10
100
2 4 6 8 10 12 14
Re
lea
se
(m
g/k
g)
pH
pH dependent release of Ni
0.0001
0.001
0.01
0.1
1
10
100
0.01 0.1 1 10 100Cu
mu
lati
ve
re
lea
se
(m
g/k
g)
L/S (L/kg)
Cumulative release of Ni
0.001
0.01
0.1
1
2 4 6 8 10 12 14
Co
nce
ntr
ati
on
(m
g/L)
pH
pH dependent concentration of Pb
0.0001
0.001
0.01
0.1
1
10
2 4 6 8 10 12 14
Re
lea
se
(m
g/k
g)
pH
pH dependent release of Pb
0.0001
0.001
0.01
0.1
1
0.01 0.1 1 10 100
Co
nce
ntr
ati
on
(m
g/L)
L/S (L/kg)
Pb concentration as function of L/S
0.0001
0.001
0.01
0.1
1
10
0.01 0.1 1 10 100
Cu
mu
lati
ve
re
lea
se
(m
g/k
g)
L/S (L/kg)
Cumulative release of Pb
Final Report Appendix 9: PSlag Appendix Part 1: Leaching data
A possible methodology for setting pollutant limit values for aggregates in the EoW framework JRC-IPTS 109
0.0001
0.001
0.01
0.1
1
2 4 6 8 10 12 14
Co
nce
ntr
ati
on
(m
g/L)
pH
pH dependent concentration of Sb
0.00001
0.0001
0.001
0.01
0.1
1
10
2 4 6 8 10 12 14
Re
lea
se
(m
g/k
g)
pH
pH dependent release of Sb
0.0001
0.001
0.01
0.1
1
0.01 0.1 1 10 100
Co
nce
ntr
ati
on
(m
g/L)
L/S (L/kg)
Sb concentration as function of L/S
0.00001
0.0001
0.001
0.01
0.1
1
10
0.01 0.1 1 10 100
Cu
mu
lati
ve
re
lea
se
(m
g/k
g)
L/S (L/kg)
Cumulative release of Sb
0.0001
0.001
0.01
0.1
1
2 4 6 8 10 12 14
Co
nce
ntr
ati
on
(m
g/L)
pH
pH dependent concentration of Se
0.00001
0.0001
0.001
0.01
0.1
1
2 4 6 8 10 12 14
Re
lea
se
(m
g/k
g)
pH
pH dependent release of Se
0.0001
0.001
0.01
0.1
1
0.01 0.1 1 10 100
Co
nce
ntr
ati
on
(m
g/L)
L/S (L/kg)
Se concentration as function of L/S
0.00001
0.0001
0.001
0.01
0.1
1
0.01 0.1 1 10 100
Cu
mu
lati
ve
re
lea
se
(m
g/k
g)
L/S (L/kg)
Cumulative release of Se
Final Report Appendix 9: PSlag Appendix Part 1: Leaching data
A possible methodology for setting pollutant limit values for aggregates in the EoW framework JRC-IPTS 110
0.001
0.01
0.1
1
2 4 6 8 10 12 14
Co
nce
ntr
ati
on
(m
g/L)
pH
pH dependent concentration of Sn
0.0001
0.001
0.01
0.1
1
0.01 0.1 1 10 100
Co
nce
ntr
ati
on
(m
g/L)
L/S (L/kg)
Sn concentration as function of L/S
0.00001
0.0001
0.001
0.01
0.1
1
10
2 4 6 8 10 12 14
Re
lea
se
(m
g/k
g)
pH
pH dependent release of Sn
0.00001
0.0001
0.001
0.01
0.1
1
10
0.01 0.1 1 10 100Cu
mu
lati
ve
re
lea
se
(m
g/k
g)
L/S (L/kg)
Cumulative release of Sn
0.001
0.01
0.1
1
2 4 6 8 10 12 14
Co
nce
ntr
ati
on
(m
g/L)
pH
pH dependent concentration of V
0.0001
0.001
0.01
0.1
1
0.01 0.1 1 10 100
Co
nce
ntr
ati
on
(m
g/L)
L/S (L/kg)
V concentration as function of L/S
0.00001
0.0001
0.001
0.01
0.1
1
10
100
2 4 6 8 10 12 14
Re
lea
se
(m
g/k
g)
pH
pH dependent release of V
0.00001
0.0001
0.001
0.01
0.1
1
10
100
0.01 0.1 1 10 100Cu
mu
lati
ve
re
lea
se
(m
g/k
g)
L/S (L/kg)
Cumulative release of V
Final Report Appendix 9: PSlag Appendix Part 1: Leaching data
A possible methodology for setting pollutant limit values for aggregates in the EoW framework JRC-IPTS 111
0.0001
0.001
0.01
0.1
1
2 4 6 8 10 12 14
Co
nce
ntr
ati
on
(m
g/L)
pH
pH dependent concentration of Zn
0.001
0.01
0.1
1
0.01 0.1 1 10 100
Co
nce
ntr
ati
on
(m
g/L)
L/S (L/kg)
Zn concentration as function of L/S
0.0001
0.001
0.01
0.1
1
10
100
2 4 6 8 10 12 14
Re
lea
se
(m
g/k
g)
pH
pH dependent release of Zn
0.0001
0.001
0.01
0.1
1
10
100
0.01 0.1 1 10 100Cu
mu
lati
ve
re
lea
se
(m
g/k
g)
L/S (L/kg)
Cumulative release of Zn
0
2
4
6
8
10
12
14
0.01 0.1 1 10 100
pH
L/S (L/kg)
pH development as function of L/S
Final Report Appendix 10: CFA Appendix Part 1: Leaching data
A possible methodology for setting pollutant limit values for aggregates in the EoW framework JRC-IPTS 112
0.001
0.01
0.1
1
10
100
1000
10000
2 4 6 8 10 12 14
Co
nce
ntr
ati
on
(m
g/L)
pH
pH dependent concentration of Al
0.01
0.1
1
10
100
0.01 0.1 1 10 100 1000
Co
nce
ntr
ati
on
(m
g/L)
L/S (L/kg)
Al concentration as function of L/S
0.01
0.1
1
10
100
1000
10000
100000
2 4 6 8 10 12 14
Re
lea
se
(m
g/k
g)
pH
pH dependent release of Al
0.01
0.1
1
10
100
1000
10000
100000
0.01 0.1 1 10 100 1000
(Cu
mu
lati
ve
) re
lea
se
(m
g/k
g)
L/S (L/kg)
(Cumulative) release of Al
1
10
100
1000
10000
2 4 6 8 10 12 14
Co
nce
ntr
ati
on
(m
g/L)
pH
pH dependent concentration of Ca
1
10
100
1000
10000
0.01 0.1 1 10 100 1000
Co
nce
ntr
ati
on
(m
g/L)
L/S (L/kg)
Ca concentration as function of L/S
0.1
1
10
100
1000
10000
100000
2 4 6 8 10 12 14
Re
lea
se
(m
g/k
g)
pH
pH dependent release of Ca
0.1
1
10
100
1000
10000
100000
0.01 0.1 1 10 100 1000
(Cu
mu
lati
ve
) re
lea
se
(m
g/k
g)
L/S (L/kg)
(Cumulative) release of Ca
Final Report Appendix 10: CFA Appendix Part 1: Leaching data
A possible methodology for setting pollutant limit values for aggregates in the EoW framework JRC-IPTS 113
0.000001
0.00001
0.0001
0.001
0.01
0.1
1
10
100
1000
2 4 6 8 10 12 14
Co
nce
ntr
ati
on
(m
g/L)
pH
pH dependent concentration of Fe
0.00001
0.0001
0.001
0.01
0.1
1
0.01 0.1 1 10 100
Co
nce
ntr
ati
on
(m
g/L)
L/S (L/kg)
Fe concentration as function of L/S
0.00001
0.0001
0.001
0.01
0.1
1
10
100
1000
10000
2 4 6 8 10 12 14
Re
lea
se
(m
g/k
g)
pH
pH dependent release of Fe
0.00001
0.0001
0.001
0.01
0.1
1
10
100
1000
10000
0.01 0.1 1 10 100
(Cu
mu
lati
ve
) re
lea
se
(m
g/k
g)
L/S (L/kg)
(Cumulative) release of Fe
0.01
0.1
1
10
100
1000
2 4 6 8 10 12 14
Co
nce
ntr
ati
on
(m
g/L)
pH
pH dependent concentration of Mg
0.001
0.01
0.1
1
10
100
0.01 0.1 1 10 100 1000
Co
nce
ntr
ati
on
(m
g/L)
L/S (L/kg)
Mg concentration as function of L/S
0.001
0.01
0.1
1
10
100
1000
10000
100000
2 4 6 8 10 12 14
Re
lea
se
(m
g/k
g)
pH
pH dependent release of Mg
0.001
0.01
0.1
1
10
100
1000
10000
100000
0.01 0.1 1 10 100 1000
(Cu
mu
lati
ve
) re
lea
se
(m
g/k
g)
L/S (L/kg)
(Cumulative) release of Mg
Final Report Appendix 10: CFA Appendix Part 1: Leaching data
A possible methodology for setting pollutant limit values for aggregates in the EoW framework JRC-IPTS 114
0.01
0.1
1
10
100
1000
10000
2 4 6 8 10 12 14
Co
nce
ntr
ati
on
(m
g/L)
pH
pH dependent concentration of Si
0.1
1
10
0.01 0.1 1 10 100
Co
nce
ntr
ati
on
(m
g/L)
L/S (L/kg)
Si concentration as function of L/S
0.1
1
10
100
1000
10000
100000
2 4 6 8 10 12 14
Re
lea
se
(m
g/k
g)
pH
pH dependent release of Si
0.1
1
10
100
1000
10000
100000
0.01 0.1 1 10 100
(Cu
mu
lati
ve
) re
lea
se
(m
g/k
g)
L/S (L/kg)
(Cumulative) release of Si
0.0000001
0.000001
0.00001
0.0001
0.001
0.01
0.1
1
10
100
2 4 6 8 10 12 14
Co
nce
ntr
ati
on
(m
g/L)
pH
pH dependent concentration of Mn
0.0000001
0.000001
0.00001
0.0001
0.001
0.01
0.1
1
10
0.01 0.1 1 10 100 1000
Co
nce
ntr
ati
on
(m
g/L)
L/S (L/kg)
Mn concentration as function of L/S
0.000001
0.00001
0.0001
0.001
0.01
0.1
1
10
100
1000
10000
2 4 6 8 10 12 14
Re
lea
se
(m
g/k
g)
pH
pH dependent release of Mn
0.000001
0.00001
0.0001
0.001
0.01
0.1
1
10
100
1000
10000
0.01 0.1 1 10 100 1000
(Cu
mu
lati
ve
) re
lea
se
(m
g/k
g)
L/S (L/kg)
(Cumulative) release of Mn
Final Report Appendix 10: CFA Appendix Part 1: Leaching data
A possible methodology for setting pollutant limit values for aggregates in the EoW framework JRC-IPTS 115
1
10
100
1000
2 4 6 8 10 12 14
Co
nce
ntr
ati
on
(m
g/L)
pH
pH dependent concentration of S
0.1
1
10
100
1000
10000
0.01 0.1 1 10 100
Co
nce
ntr
ati
on
(m
g/L)
L/S (L/kg)
S concentration as function of L/S
0.1
1
10
100
1000
10000
100000
2 4 6 8 10 12 14
Re
lea
se
(m
g/k
g)
pH
pH dependent release of S
0.1
1
10
100
1000
10000
100000
0.01 0.1 1 10 100
(Cu
mu
lati
ve
) re
lea
se
(m
g/k
g)
L/S (L/kg)
(Cumulative) release of S
1
10
100
1000
10000
2 4 6 8 10 12 14
Co
nce
ntr
ati
on
(m
g/L)
pH
pH dependent concentration of SO4
0.1
1
10
100
1000
10000
0.01 0.1 1 10 100 1000
Co
nce
ntr
ati
on
(m
g/L)
L/S (L/kg)
SO4 concentration as function of L/S
10
100
1000
10000
100000
2 4 6 8 10 12 14
Re
lea
se
(m
g/k
g)
pH
pH dependent release of SO4
10
100
1000
10000
100000
0.01 0.1 1 10 100 1000
(Cu
mu
lati
ve
) re
lea
se
(m
g/k
g)
L/S (L/kg)
(Cumulative) release of SO4
Final Report Appendix 10: CFA Appendix Part 1: Leaching data
A possible methodology for setting pollutant limit values for aggregates in the EoW framework JRC-IPTS 116
0.01
0.1
1
10
100
1000
10000
2 4 6 8 10 12 14
Co
nce
ntr
ati
on
(m
g/L)
pH
pH dependent concentration of Cl
0.01
0.1
1
10
100
1000
10000
0.01 0.1 1 10 100 1000
Co
nce
ntr
ati
on
(m
g/L)
L/S (L/kg)
Cl concentration as function of L/S
0.1
1
10
100
1000
10000
100000
1000000
10000000
2 4 6 8 10 12 14
Re
lea
se
(m
g/k
g)
pH
pH dependent release of Cl
0.1
1
10
100
1000
10000
100000
1000000
10000000
0.01 0.1 1 10 100 1000
(Cu
mu
lati
ve
) re
lea
se
(m
g/k
g)
L/S (L/kg)
(Cumulative) release of Cl
0.0001
0.001
0.01
0.1
1
10
100
1000
2 4 6 8 10 12 14
Co
nce
ntr
ati
on
(m
g/L)
pH
pH dependent concentration of P
0.001
0.01
0.1
1
0.01 0.1 1 10 100
Co
nce
ntr
ati
on
(m
g/L)
L/S (L/kg)
P concentration as function of L/S
0.001
0.01
0.1
1
10
100
1000
10000
2 4 6 8 10 12 14
Re
lea
se
(m
g/k
g)
pH
pH dependent release of P
0.001
0.01
0.1
1
10
100
1000
10000
0.01 0.1 1 10 100
(Cu
mu
lati
ve
) re
lea
se
(m
g/k
g)
L/S (L/kg)
(Cumulative) release of P
Final Report Appendix 10: CFA Appendix Part 1: Leaching data
A possible methodology for setting pollutant limit values for aggregates in the EoW framework JRC-IPTS 117
0.1
1
10
100
1000
2 4 6 8 10 12 14
Co
nce
ntr
ati
on
(m
g/L)
pH
pH dependent concentration of Na
0.01
0.1
1
10
100
1000
10000
0.01 0.1 1 10 100 1000
Co
nce
ntr
ati
on
(m
g/L)
L/S (L/kg)
Na concentration as function of L/S
0.1
1
10
100
1000
10000
2 4 6 8 10 12 14
Re
lea
se
(m
g/k
g)
pH
pH dependent release of Na
0.1
1
10
100
1000
10000
0.01 0.1 1 10 100 1000
(Cu
mu
lati
ve
) re
lea
se
(m
g/k
g)
L/S (L/kg)
(Cumulative) release of Na
0.1
1
10
100
1000
10000
2 4 6 8 10 12 14
Co
nce
ntr
ati
on
(m
g/L)
pH
pH dependent concentration of K
0.1
1
10
100
1000
10000
0.01 0.1 1 10 100 1000
Co
nce
ntr
ati
on
(m
g/L)
L/S (L/kg)
K concentration as function of L/S
0.1
1
10
100
1000
10000
2 4 6 8 10 12 14
Re
lea
se
(m
g/k
g)
pH
pH dependent release of K
0.1
1
10
100
1000
10000
0.01 0.1 1 10 100 1000
(Cu
mu
lati
ve
) re
lea
se
(m
g/k
g)
L/S (L/kg)
(Cumulative) release of K
Final Report Appendix 10: CFA Appendix Part 1: Leaching data
A possible methodology for setting pollutant limit values for aggregates in the EoW framework JRC-IPTS 118
0.001
0.01
0.1
1
10
2 4 6 8 10 12 14
Co
nce
ntr
ati
on
(m
g/L)
pH
pH dependent concentration of Ba
0.01
0.1
1
10
100
0.01 0.1 1 10 100 1000
Co
nce
ntr
ati
on
(m
g/L)
L/S (L/kg)
Ba concentration as function of L/S
0.001
0.01
0.1
1
10
100
1000
2 4 6 8 10 12 14
Re
lea
se
(m
g/k
g)
pH
pH dependent release of Ba
0.001
0.01
0.1
1
10
100
1000
0.01 0.1 1 10 100 1000
(Cu
mu
lati
ve
) re
lea
se
(m
g/k
g)
L/S (L/kg)
(Cumulative) release of Ba
0.1
1
10
100
1000
2 4 6 8 10 12 14
Co
nce
ntr
ati
on
(m
g/L)
pH
pH dependent concentration of Sr
0.1
1
10
100
1000
0.01 0.1 1 10 100
Co
nce
ntr
ati
on
(m
g/L)
L/S (L/kg)
Sr concentration as function of L/S
1
10
100
1000
10000
100000
2 4 6 8 10 12 14
Re
lea
se
(m
g/k
g)
pH
pH dependent release of Sr
1
10
100
1000
10000
100000
0.01 0.1 1 10 100
(Cu
mu
lati
ve
) re
lea
se
(m
g/k
g)
L/S (L/kg)
(Cumulative) release of Sr
Final Report Appendix 10: CFA Appendix Part 1: Leaching data
A possible methodology for setting pollutant limit values for aggregates in the EoW framework JRC-IPTS 119
0.000001
0.00001
0.0001
0.001
0.01
0.1
1
10
2 4 6 8 10 12 14
Co
nce
ntr
ati
on
(m
g/L)
pH
pH dependent concentration of As
0.0001
0.001
0.01
0.1
1
0.01 0.1 1 10 100 1000
Co
nce
ntr
ati
on
(m
g/L)
L/S (L/kg)
As concentration as function of L/S
0.00001
0.0001
0.001
0.01
0.1
1
10
100
1000
2 4 6 8 10 12 14
Re
lea
se
(m
g/k
g)
pH
pH dependent release of As
0.00001
0.0001
0.001
0.01
0.1
1
10
100
1000
0.01 0.1 1 10 100 1000
(Cu
mu
lati
ve
) re
lea
se
(m
g/k
g)
L/S (L/kg)
(Cumulative) release of As
0.0000001
0.000001
0.00001
0.0001
0.001
0.01
0.1
1
10
2 4 6 8 10 12 14
Co
nce
ntr
ati
on
(m
g/L)
pH
pH dependent concentration of Cd
0.0000001
0.000001
0.00001
0.0001
0.001
0.01
0.1
1
10
0.01 0.1 1 10 100
Co
nce
ntr
ati
on
(m
g/L)
L/S (L/kg)
Cd concentration as function of L/S
0.000001
0.00001
0.0001
0.001
0.01
0.1
1
10
100
1000
2 4 6 8 10 12 14
Re
lea
se
(m
g/k
g)
pH
pH dependent release of Cd
0.000001
0.00001
0.0001
0.001
0.01
0.1
1
10
100
1000
0.01 0.1 1 10 100
(Cu
mu
lati
ve
) re
lea
se
(m
g/k
g)
L/S (L/kg)
(Cumulative) release of Cd
Final Report Appendix 10: CFA Appendix Part 1: Leaching data
A possible methodology for setting pollutant limit values for aggregates in the EoW framework JRC-IPTS 120
0.001
0.01
0.1
1
10
2 4 6 8 10 12 14
Co
nce
ntr
ati
on
(m
g/L)
pH
pH dependent concentration of Cr
0.001
0.01
0.1
1
10
100
0.01 0.1 1 10 100 1000
Co
nce
ntr
ati
on
(m
g/L)
L/S (L/kg)
Cr concentration as function of L/S
0.0001
0.001
0.01
0.1
1
10
100
1000
10000
100000
2 4 6 8 10 12 14
Re
lea
se
(m
g/k
g)
pH
pH dependent release of Cr
0.0001
0.001
0.01
0.1
1
10
100
1000
10000
100000
0.0001 0.01 1 100
(Cu
mu
lati
ve
) re
lea
se
(m
g/k
g)
L/S (L/kg)
(Cumulative) release of Cr
0.0000001
0.000001
0.00001
0.0001
0.001
0.01
0.1
1
10
2 4 6 8 10 12 14
Co
nce
ntr
ati
on
(m
g/L)
pH
pH dependent concentration of Cu
0.0000001
0.000001
0.00001
0.0001
0.001
0.01
0.1
1
0.01 0.1 1 10 100
Co
nce
ntr
ati
on
(m
g/L)
L/S (L/kg)
Cu concentration as function of L/S
0.000001
0.00001
0.0001
0.001
0.01
0.1
1
10
100
2 4 6 8 10 12 14
Re
lea
se
(m
g/k
g)
pH
pH dependent release of Cu
0.000001
0.00001
0.0001
0.001
0.01
0.1
1
10
100
0.01 0.1 1 10 100
(Cu
mu
lati
ve
) re
lea
se
(m
g/k
g)
L/S (L/kg)
(Cumulative) release of Cu
Final Report Appendix 10: CFA Appendix Part 1: Leaching data
A possible methodology for setting pollutant limit values for aggregates in the EoW framework JRC-IPTS 121
0.01
0.1
1
10
100
2 4 6 8 10 12 14
Co
nce
ntr
ati
on
(m
g/L)
pH
pH dependent concentration of Mo
0.001
0.01
0.1
1
10
100
0.01 0.1 1 10 100 1000
Co
nce
ntr
ati
on
(m
g/L)
L/S (L/kg)
Mo concentration as function of L/S
0.01
0.1
1
10
100
1000
2 4 6 8 10 12 14
Re
lea
se
(m
g/k
g)
pH
pH dependent release of Mo
0.01
0.1
1
10
100
1000
0.01 0.1 1 10 100 1000
(Cu
mu
lati
ve
) re
lea
se
(m
g/k
g)
L/S (L/kg)
(Cumulative) release of Mo
0.000001
0.00001
0.0001
0.001
0.01
0.1
1
10
2 4 6 8 10 12 14
Co
nce
ntr
ati
on
(m
g/L)
pH
pH dependent concentration of Ni
0.000001
0.00001
0.0001
0.001
0.01
0.1
1
0.01 0.1 1 10 100
Co
nce
ntr
ati
on
(m
g/L)
L/S (L/kg)
Ni concentration as function of L/S
0.00001
0.0001
0.001
0.01
0.1
1
10
100
2 4 6 8 10 12 14
Re
lea
se
(m
g/k
g)
pH
pH dependent release of Ni
0.00001
0.0001
0.001
0.01
0.1
1
10
100
0.01 0.1 1 10 100
(Cu
mu
lati
ve
) re
lea
se
(m
g/k
g)
L/S (L/kg)
(Cumulative) release of Ni
Final Report Appendix 10: CFA Appendix Part 1: Leaching data
A possible methodology for setting pollutant limit values for aggregates in the EoW framework JRC-IPTS 122
0.00001
0.0001
0.001
0.01
0.1
1
10
100
2 4 6 8 10 12 14
Co
nce
ntr
ati
on
(m
g/L)
pH
pH dependent concentration of Pb
0.00001
0.0001
0.001
0.01
0.1
1
10
100
0.01 0.1 1 10 100
Co
nce
ntr
ati
on
(m
g/L)
L/S (L/kg)
Pb concentration as function of L/S
0.0001
0.001
0.01
0.1
1
10
100
1000
10000
2 4 6 8 10 12 14
Re
lea
se
(m
g/k
g)
pH
pH dependent release of Pb
0.0001
0.001
0.01
0.1
1
10
100
1000
10000
0.01 0.1 1 10 100
(Cu
mu
lati
ve
) re
lea
se
(m
g/k
g)
L/S (L/kg)
(Cumulative) release of Pb
0.00001
0.0001
0.001
0.01
0.1
1
10
100
2 4 6 8 10 12 14
Co
nce
ntr
ati
on
(m
g/L)
pH
pH dependent concentration of Sb
0.0001
0.001
0.01
0.1
1
10
100
0.01 0.1 1 10 100 1000
Co
nce
ntr
ati
on
(m
g/L)
L/S (L/kg)
Sb concentration as function of L/S
0.0001
0.001
0.01
0.1
1
10
100
1000
2 4 6 8 10 12 14
Re
lea
se
(m
g/k
g)
pH
pH dependent release of Sb
0.0001
0.001
0.01
0.1
1
10
100
1000
0.01 0.1 1 10 100 1000
(Cu
mu
lati
ve
) re
lea
se
(m
g/k
g)
L/S (L/kg)
(Cumulative) release of Sb
Final Report Appendix 10: CFA Appendix Part 1: Leaching data
A possible methodology for setting pollutant limit values for aggregates in the EoW framework JRC-IPTS 123
0.001
0.01
0.1
1
10
2 4 6 8 10 12 14
Co
nce
ntr
ati
on
(m
g/L)
pH
pH dependent concentration of Se
0.001
0.01
0.1
1
0.01 0.1 1 10 100 1000
Co
nce
ntr
ati
on
(m
g/L)
L/S (L/kg)
Se concentration as function of L/S
0.00001
0.0001
0.001
0.01
0.1
1
10
100
1000
2 4 6 8 10 12 14
Re
lea
se
(m
g/k
g)
pH
pH dependent release of Se
0.00001
0.0001
0.001
0.01
0.1
1
10
100
1000
0.01 0.1 1 10 100 1000
(Cu
mu
lati
ve
) re
lea
se
(m
g/k
g)
L/S (L/kg)
(Cumulative) release of Se
0.000001
0.00001
0.0001
0.001
0.01
0.1
1
2 4 6 8 10 12 14
Co
nce
ntr
ati
on
(m
g/L)
pH
pH dependent concentration of Sn
0.000001
0.00001
0.0001
0.001
0.01
0.1
1
0.01 0.1 1 10 100
Co
nce
ntr
ati
on
(m
g/L)
L/S (L/kg)
Sn concentration as function of L/S
0.00001
0.0001
0.001
0.01
0.1
1
10
2 4 6 8 10 12 14
Re
lea
se
(m
g/k
g)
pH
pH dependent release of Sn
0.00001
0.0001
0.001
0.01
0.1
1
10
0.01 0.1 1 10 100
(Cu
mu
lati
ve
) re
lea
se
(m
g/k
g)
L/S (L/kg)
(Cumulative) release of Sn
Final Report Appendix 10: CFA Appendix Part 1: Leaching data
A possible methodology for setting pollutant limit values for aggregates in the EoW framework JRC-IPTS 124
0.001
0.01
0.1
1
10
2 4 6 8 10 12 14
Co
nce
ntr
ati
on
(m
g/L)
pH
pH dependent concentration of V
0.0001
0.001
0.01
0.1
1
10
0.01 0.1 1 10 100 1000
Co
nce
ntr
ati
on
(m
g/L)
L/S (L/kg)
V concentration as function of L/S
0.00001
0.0001
0.001
0.01
0.1
1
10
100
1000
10000
2 4 6 8 10 12 14
Re
lea
se
(m
g/k
g)
pH
pH dependent release of V
0.00001
0.0001
0.001
0.01
0.1
1
10
100
1000
10000
0.01 0.1 1 10 100 1000
(Cu
mu
lati
ve
) re
lea
se
(m
g/k
g)
L/S (L/kg)
(Cumulative) release of V
0.000001
0.00001
0.0001
0.001
0.01
0.1
1
10
2 4 6 8 10 12 14
Co
nce
ntr
ati
on
(m
g/L)
pH
pH dependent concentration of Zn
0.00001
0.0001
0.001
0.01
0.1
1
10
0.01 0.1 1 10 100 1000
Co
nce
ntr
ati
on
(m
g/L)
L/S (L/kg)
Zn concentration as function of L/S
0.00001
0.0001
0.001
0.01
0.1
1
10
100
1000
10000
2 4 6 8 10 12 14
Re
lea
se
(m
g/k
g)
pH
pH dependent release of Zn
0.000001
0.00001
0.0001
0.001
0.01
0.1
1
10
100
1000
10000
0.01 0.1 1 10 100 1000
(Cu
mu
lati
ve
) re
lea
se
(m
g/k
g)
L/S (L/kg)
(Cumulative) release of Zn
Final Report Appendix 10: CFA Appendix Part 1: Leaching data
A possible methodology for setting pollutant limit values for aggregates in the EoW framework JRC-IPTS 125
0
2
4
6
8
10
12
14
0.01 0.1 1 10 100 1000
pH
L/S (L/kg)
pH development as function of L/S
Final Report Appendix 11: CBA Appendix Part 1: Leaching data
A possible methodology for setting pollutant limit values for aggregates in the EoW framework JRC-IPTS 126
1
10
100
1000
10000
2 4 6 8 10 12 14
Co
nce
ntr
ati
on
(m
g/L)
pH
pH dependent concentration of SO4
1
10
100
1000
10000
0.1 1 10 100
Co
nce
ntr
ati
on
(m
g/L)
L/S (L/kg)
SO4 concentration as function of L/S
1
10
100
1000
10000
100000
2 4 6 8 10 12 14
Re
lea
se
(m
g/k
g)
pH
pH dependent release of SO4
1
10
100
1000
10000
100000
0.1 1 10 100
(Cu
mu
lati
ve
) re
lea
se
(m
g/k
g)
L/S (L/kg)
(Cumulative) release of SO4
0.01
0.1
1
2 4 6 8 10 12 14
Co
nce
ntr
ati
on
(m
g/L)
pH
pH dependent concentration of F
0.01
0.1
1
10
0.1 1 10 100
Co
nce
ntr
ati
on
(m
g/L)
L/S (L/kg)
F concentration as function of L/S
0.1
1
10
100
2 4 6 8 10 12 14
Re
lea
se
(m
g/k
g)
pH
pH dependent release of F
0.1
1
10
100
0.1 1 10 100
(Cu
mu
lati
ve
) re
lea
se
(m
g/k
g)
L/S (L/kg)
(Cumulative) release of F
Final Report Appendix 11: CBA Appendix Part 1: Leaching data
A possible methodology for setting pollutant limit values for aggregates in the EoW framework JRC-IPTS 127
0.1
1
10
100
0.1 1 10 100
Co
nce
ntr
ati
on
(m
g/L)
L/S (L/kg)
Na concentration as function of L/S
1
10
100
1000
10000
0.1 1 10 100Cu
mu
lati
ve
re
lea
se
(m
g/k
g)
L/S (L/kg)
Cumulative release of Na
0.1
1
10
100
0.1 1 10 100
Co
nce
ntr
ati
on
(m
g/L)
L/S (L/kg)
K concentration as function of L/S
1
10
100
1000
0.1 1 10 100Cu
mu
lati
ve
re
lea
se
(m
g/k
g)
L/S (L/kg)
Cumulative release of K
0.1
1
10
100
0.1 1 10 100
Co
nce
ntr
ati
on
(m
g/L)
L/S (L/kg)
Mg concentration as function of L/S
1
10
100
1000
0.1 1 10 100Cu
mu
lati
ve
re
lea
se
(m
g/k
g)
L/S (L/kg)
Cumulative release of Mg
0.1
1
2 4 6 8 10 12 14
Re
lea
se
(m
g/k
g)
pH
pH dependent release of Sr
0.1
1
1 10
Re
lea
se
(m
g/k
g)
L/S (L/kg)
Release of Sr
Final Report Appendix 11: CBA Appendix Part 1: Leaching data
A possible methodology for setting pollutant limit values for aggregates in the EoW framework JRC-IPTS 128
1
10
100
1000
10000
2 4 6 8 10 12 14
Co
nce
ntr
ati
on
(m
g/L)
pH
pH dependent concentration of Cl
0.1
1
10
100
1000
10000
0.1 1 10 100
Co
nce
ntr
ati
on
(m
g/L)
L/S (L/kg)
Cl concentration as function of L/S
1
10
100
1000
10000
100000
2 4 6 8 10 12 14
Re
lea
se
(m
g/k
g)
pH
pH dependent release of Cl
1
10
100
1000
10000
100000
0.1 1 10 100
(Cu
mu
lati
ve
) re
lea
se
(m
g/k
g)
L/S (L/kg)
(Cumulative) release of Cl
0.001
0.01
0.1
1
2 4 6 8 10 12 14
Co
nce
ntr
ati
on
(m
g/L)
pH
pH dependent concentration of As
0.001
0.01
0.1
1
0.1 1 10 100
Co
nce
ntr
ati
on
(m
g/L)
L/S (L/kg)
As concentration as function of L/S
0.001
0.01
0.1
1
10
2 4 6 8 10 12 14
Re
lea
se
(m
g/k
g)
pH
pH dependent release of As
0.001
0.01
0.1
1
10
0.1 1 10 100
(Cu
mu
lati
ve
) re
lea
se
(m
g/k
g)
L/S (L/kg)
(Cumulative) release of As
Final Report Appendix 11: CBA Appendix Part 1: Leaching data
A possible methodology for setting pollutant limit values for aggregates in the EoW framework JRC-IPTS 129
0.01
0.1
1
2 4 6 8 10 12 14
Co
nce
ntr
ati
on
(m
g/L)
pH
pH dependent concentration of Ba
0.01
0.1
1
1 10
Co
nce
ntr
ati
on
(m
g/L)
L/S (L/kg)
Ba concentration as function of L/S
0.1
1
10
100
2 4 6 8 10 12 14
Re
lea
se
(m
g/k
g)
pH
pH dependent release of Ba
0.1
1
10
100
1 10
(Cu
mu
lati
ve
) re
lea
se
(m
g/k
g)
L/S (L/kg)
(Cumulative) release of Ba
0.001
0.01
0.1
1
2 4 6 8 10 12 14
Co
nce
ntr
ati
on
(m
g/L)
pH
pH dependent concentration of Cd
0.0001
0.001
0.01
0.1
1
0.1 1 10 100
Co
nce
ntr
ati
on
(m
g/L)
L/S (L/kg)
Cd concentration as function of L/S
0.0001
0.001
0.01
0.1
1
2 4 6 8 10 12 14
Re
lea
se
(m
g/k
g)
pH
pH dependent release of Cd
0.0001
0.001
0.01
0.1
1
0.1 1 10 100
(Cu
mu
lati
ve
) re
lea
se
(m
g/k
g)
L/S (L/kg)
(Cumulative) release of Cd
Final Report Appendix 11: CBA Appendix Part 1: Leaching data
A possible methodology for setting pollutant limit values for aggregates in the EoW framework JRC-IPTS 130
0.001
0.01
0.1
1
2 4 6 8 10 12 14
Co
nce
ntr
ati
on
(m
g/L)
pH
pH dependent concentration of Cr
0.001
0.01
0.1
1
0.1 1 10 100
Co
nce
ntr
ati
on
(m
g/L)
L/S (L/kg)
Cr concentration as function of L/S
0.001
0.01
0.1
1
10
2 4 6 8 10 12 14
Re
lea
se
(m
g/k
g)
pH
pH dependent release of Cr
0.001
0.01
0.1
1
10
0.1 1 10 100
(Cu
mu
lati
ve
) re
lea
se
(m
g/k
g)
L/S (L/kg)
(Cumulative) release of Cr
0.001
0.01
0.1
1
2 4 6 8 10 12 14
Co
nce
ntr
ati
on
(m
g/L)
pH
pH dependent concentration of Cu
0.001
0.01
0.1
1
0.1 1 10 100
Co
nce
ntr
ati
on
(m
g/L)
L/S (L/kg)
Cu concentration as function of L/S
0.001
0.01
0.1
1
10
2 4 6 8 10 12 14
Re
lea
se
(m
g/k
g)
pH
pH dependent release of Cu
0.001
0.01
0.1
1
10
0.1 1 10 100
(Cu
mu
lati
ve
) re
lea
se
(m
g/k
g)
L/S (L/kg)
(Cumulative) release of Cu
Final Report Appendix 11: CBA Appendix Part 1: Leaching data
A possible methodology for setting pollutant limit values for aggregates in the EoW framework JRC-IPTS 131
0.01
0.1
1
10
0.1 1 10 100Cu
mu
lati
ve
re
lea
se
(m
g/k
g)
L/S (L/kg)
Cumulative release of Mo
0.001
0.01
0.1
1
0.1 1 10 100
Co
nce
ntr
ati
on
(m
g/L)
L/S (L/kg)
Mo concentration as function of L/S
0.001
0.01
0.1
1
2 4 6 8 10 12 14
Co
nce
ntr
ati
on
(m
g/L)
pH
pH dependent concentration of Ni
0.001
0.01
0.1
1
0.1 1 10 100
Co
nce
ntr
ati
on
(m
g/L)
L/S (L/kg)
Ni concentration as function of L/S
0.001
0.01
0.1
1
10
2 4 6 8 10 12 14
Re
lea
se
(m
g/k
g)
pH
pH dependent release of Ni
0.001
0.01
0.1
1
10
0.1 1 10 100
(Cu
mu
lati
ve
) re
lea
se
(m
g/k
g)
L/S (L/kg)
(Cumulative) release of Ni
0.0001
0.001
0.01
0.1
1
1 10
Co
nce
ntr
ati
on
(m
g/L)
L/S (L/kg)
Sb concentration as function of L/S
0.001
0.01
0.1
1
1 10Cu
mu
lati
ve
re
lea
se
(m
g/k
g)
L/S (L/kg)
Cumulative release of Sb
Final Report Appendix 11: CBA Appendix Part 1: Leaching data
A possible methodology for setting pollutant limit values for aggregates in the EoW framework JRC-IPTS 132
0.0001
0.001
0.01
0.1
1
1 10
Co
nce
ntr
ati
on
(m
g/L)
L/S (L/kg)
Se concentration as function of L/S
0.001
0.01
0.1
1
1 10Cu
mu
lati
ve
re
lea
se
(m
g/k
g)
L/S (L/kg)
Cumulative release of Se
0.001
0.01
0.1
1
1 10
Co
nce
ntr
ati
on
(m
g/L)
L/S (L/kg)
Sn concentration as function of L/S
0.01
0.1
1
1 10Cu
mu
lati
ve
re
lea
se
(m
g/k
g)
L/S (L/kg)
Cumulative release of Sn
0.01
0.1
2 4 6 8 10 12 14
Co
nce
ntr
ati
on
(m
g/L)
pH
pH dependent concentration of V
0.001
0.01
0.1
1
0.1 1 10 100
Co
nce
ntr
ati
on
(m
g/L)
L/S (L/kg)
V concentration as function of L/S
0.001
0.01
0.1
1
2 4 6 8 10 12 14
Re
lea
se
(m
g/k
g)
pH
pH dependent release of V
0.001
0.01
0.1
1
0.1 1 10 100
(Cu
mu
lati
ve
) re
lea
se
(m
g/k
g)
L/S (L/kg)
(Cumulative) release of V
Final Report Appendix 11: CBA Appendix Part 1: Leaching data
A possible methodology for setting pollutant limit values for aggregates in the EoW framework JRC-IPTS 133
0.001
0.01
0.1
1
10
2 4 6 8 10 12 14
Co
nce
ntr
ati
on
(m
g/L)
pH
pH dependent concentration of Zn
0.001
0.01
0.1
1
10
0.1 1 10 100
Co
nce
ntr
ati
on
(m
g/L)
L/S (L/kg)
Zn concentration as function of L/S
0.01
0.1
1
10
100
2 4 6 8 10 12 14
Re
lea
se
(m
g/k
g)
pH
pH dependent release of Zn
0.01
0.1
1
10
100
0.1 1 10 100
(Cu
mu
lati
ve
) re
lea
se
(m
g/k
g)
L/S (L/kg)
(Cumulative) release of Zn
0
2
4
6
8
10
12
14
0.1 1 10 100
pH
L/S (L/kg)
pH development as function of L/S
Final Report Appendix 12: MSWIFA Appendix Part 1: Leaching data
A possible methodology for setting pollutant limit values for aggregates in the EoW framework JRC-IPTS 134
0.001
0.01
0.1
1
10
100
1000
2 4 6 8 10 12 14
Co
nce
ntr
ati
on
(m
g/L)
pH
pH dependent concentration of Al
0.01
0.1
1
10
100
1000
0.01 0.1 1 10 100
Co
nce
ntr
ati
on
(m
g/L)
L/S (L/kg)
Al concentration as function of L/S
0.01
0.1
1
10
100
1000
10000
2 4 6 8 10 12 14
Re
lea
se
(m
g/k
g)
pH
pH dependent release of Al
0.01
0.1
1
10
100
1000
10000
0.01 0.1 1 10 100
(Cu
mu
lati
ve
) re
lea
se
(m
g/k
g)
L/S (L/kg)
(Cumulative) release of Al
1
10
100
1000
10000
100000
1000000
2 4 6 8 10 12 14
Co
nce
ntr
ati
on
(m
g/L)
pH
pH dependent concentration of Ca
1
10
100
1000
10000
100000
1000000
0.01 0.1 1 10 100
Co
nce
ntr
ati
on
(m
g/L)
L/S (L/kg)
Ca concentration as function of L/S
100
1000
10000
100000
1000000
2 4 6 8 10 12 14
Re
lea
se
(m
g/k
g)
pH
pH dependent release of Ca
100
1000
10000
100000
1000000
0.01 0.1 1 10 100
(Cu
mu
lati
ve
) re
lea
se
(m
g/k
g)
L/S (L/kg)
(Cumulative) release of Ca
Final Report Appendix 12: MSWIFA Appendix Part 1: Leaching data
A possible methodology for setting pollutant limit values for aggregates in the EoW framework JRC-IPTS 135
0.001
0.01
0.1
1
10
100
1000
2 4 6 8 10 12 14
Co
nce
ntr
ati
on
(m
g/L)
pH
pH dependent concentration of Fe
0.001
0.01
0.1
1
10
100
1000
0.01 0.1 1 10 100
Co
nce
ntr
ati
on
(m
g/L)
L/S (L/kg)
Fe concentration as function of L/S
0.001
0.01
0.1
1
10
100
1000
10000
2 4 6 8 10 12 14
Re
lea
se
(m
g/k
g)
pH
pH dependent release of Fe
0.001
0.01
0.1
1
10
100
1000
10000
0.01 0.1 1 10 100
(Cu
mu
lati
ve
) re
lea
se
(m
g/k
g)
L/S (L/kg)
(Cumulative) release of Fe
0.1
1
10
100
1000
10000
2 4 6 8 10 12 14
Co
nce
ntr
ati
on
(m
g/L)
pH
pH dependent concentration of Si
0.1
1
10
100
1000
10000
0.01 0.1 1 10 100
Co
nce
ntr
ati
on
(m
g/L)
L/S (L/kg)
Si concentration as function of L/S
0.01
0.1
1
10
100
1000
10000
2 4 6 8 10 12 14
Re
lea
se
(m
g/k
g)
pH
pH dependent release of Si
0.01
0.1
1
10
100
1000
10000
0.01 0.1 1 10 100
(Cu
mu
lati
ve
) re
lea
se
(m
g/k
g)
L/S (L/kg)
(Cumulative) release of Si
Final Report Appendix 12: MSWIFA Appendix Part 1: Leaching data
A possible methodology for setting pollutant limit values for aggregates in the EoW framework JRC-IPTS 136
0.01
0.1
1
10
100
1000
2 4 6 8 10 12 14
Co
nce
ntr
ati
on
(m
g/L)
pH
pH dependent concentration of Mg
0.1
1
10
100
1000
0.01 0.1 1 10 100
Co
nce
ntr
ati
on
(m
g/L)
L/S (L/kg)
Mg concentration as function of L/S
0.01
0.1
1
10
100
1000
10000
2 4 6 8 10 12 14
Re
lea
se
(m
g/k
g)
pH
pH dependent release of Mg
0.01
0.1
1
10
100
1000
10000
0.01 0.1 1 10 100
(Cu
mu
lati
ve
) re
lea
se
(m
g/k
g)
L/S (L/kg)
(Cumulative) release of Mg
1
10
100
1000
10000
100000
1000000
10000000
2 4 6 8 10 12 14
Co
nce
ntr
ati
on
(m
g/L)
pH
pH dependent concentration of Cl
1
10
100
1000
10000
100000
1000000
10000000
0.01 0.1 1 10 100
Co
nce
ntr
ati
on
(m
g/L)
L/S (L/kg)
Cl concentration as function of L/S
1
10
100
1000
10000
100000
1000000
10000000
2 4 6 8 10 12 14
Re
lea
se
(m
g/k
g)
pH
pH dependent release of Cl
1
10
100
1000
10000
100000
1000000
10000000
0.01 0.1 1 10 100
(Cu
mu
lati
ve
) re
lea
se
(m
g/k
g)
L/S (L/kg)
(Cumulative) release of Cl
Final Report Appendix 12: MSWIFA Appendix Part 1: Leaching data
A possible methodology for setting pollutant limit values for aggregates in the EoW framework JRC-IPTS 137
1
10
100
1000
10000
100000
2 4 6 8 10 12 14
Co
nce
ntr
ati
on
(m
g/L)
pH
pH dependent concentration of S
1
10
100
1000
10000
100000
0.01 0.1 1 10 100
Co
nce
ntr
ati
on
(m
g/L)
L/S (L/kg)
S concentration as function of L/S
100
1000
10000
100000
1000000
2 4 6 8 10 12 14
Re
lea
se
(m
g/k
g)
pH
pH dependent release of S
100
1000
10000
100000
1000000
0.01 0.1 1 10 100
(Cu
mu
lati
ve
) re
lea
se
(m
g/k
g)
L/S (L/kg)
(Cumulative) release of S
1
10
100
1000
10000
100000
2 4 6 8 10 12 14
Co
nce
ntr
ati
on
(m
g/L)
pH
pH dependent concentration of SO4
1
10
100
1000
10000
100000
0.1 1 10 100
Co
nce
ntr
ati
on
(m
g/L)
L/S (L/kg)
SO4 concentration as function of L/S
10
100
1000
10000
100000
1000000
2 4 6 8 10 12 14
Re
lea
se
(m
g/k
g)
pH
pH dependent release of SO4
10
100
1000
10000
100000
1000000
0.1 1 10 100
(Cu
mu
lati
ve
) re
lea
se
(m
g/k
g)
L/S (L/kg)
(Cumulative) release of SO4
Final Report Appendix 12: MSWIFA Appendix Part 1: Leaching data
A possible methodology for setting pollutant limit values for aggregates in the EoW framework JRC-IPTS 138
1
10
100
1000
10000
100000
2 4 6 8 10 12 14
Co
nce
ntr
ati
on
(m
g/L)
pH
pH dependent concentration of K
1
10
100
1000
10000
100000
0.01 0.1 1 10 100
Co
nce
ntr
ati
on
(m
g/L)
L/S (L/kg)
K concentration as function of L/S
10
100
1000
10000
100000
2 4 6 8 10 12 14
Re
lea
se
(m
g/k
g)
pH
pH dependent release of K
10
100
1000
10000
100000
0.01 0.1 1 10 100
(Cu
mu
lati
ve
) re
lea
se
(m
g/k
g)
L/S (L/kg)
(Cumulative) release of K
1
10
100
1000
10000
100000
2 4 6 8 10 12 14
Co
nce
ntr
ati
on
(m
g/L)
pH
pH dependent concentration of Na
1
10
100
1000
10000
100000
0.01 0.1 1 10 100
Co
nce
ntr
ati
on
(m
g/L)
L/S (L/kg)
Na concentration as function of L/S
100
1000
10000
100000
1000000
2 4 6 8 10 12 14
Re
lea
se
(m
g/k
g)
pH
pH dependent release of Na
100
1000
10000
100000
1000000
0.01 0.1 1 10 100
(Cu
mu
lati
ve
) re
lea
se
(m
g/k
g)
L/S (L/kg)
(Cumulative) release of Na
Final Report Appendix 12: MSWIFA Appendix Part 1: Leaching data
A possible methodology for setting pollutant limit values for aggregates in the EoW framework JRC-IPTS 139
0.0001
0.001
0.01
0.1
1
10
2 4 6 8 10 12 14
Co
nce
ntr
ati
on
(m
g/L)
pH
pH dependent concentration of As
0.0001
0.001
0.01
0.1
1
10
0.01 0.1 1 10 100
Co
nce
ntr
ati
on
(m
g/L)
L/S (L/kg)
As concentration as function of L/S
0.0001
0.001
0.01
0.1
1
10
100
2 4 6 8 10 12 14
Re
lea
se
(m
g/k
g)
pH
pH dependent release of As
0.0001
0.001
0.01
0.1
1
10
100
0.01 0.1 1 10 100
(Cu
mu
lati
ve
) re
lea
se
(m
g/k
g)
L/S (L/kg)
(Cumulative) release of As
0.001
0.01
0.1
1
10
100
2 4 6 8 10 12 14
Co
nce
ntr
ati
on
(m
g/L)
pH
pH dependent concentration of Ba
0.001
0.01
0.1
1
10
100
0.01 0.1 1 10 100
Co
nce
ntr
ati
on
(m
g/L)
L/S (L/kg)
Ba concentration as function of L/S
0.01
0.1
1
10
100
1000
2 4 6 8 10 12 14
Re
lea
se
(m
g/k
g)
pH
pH dependent release of Ba
0.01
0.1
1
10
100
1000
0.01 0.1 1 10 100
(Cu
mu
lati
ve
) re
lea
se
(m
g/k
g)
L/S (L/kg)
(Cumulative) release of Ba
Final Report Appendix 12: MSWIFA Appendix Part 1: Leaching data
A possible methodology for setting pollutant limit values for aggregates in the EoW framework JRC-IPTS 140
0.0001
0.001
0.01
0.1
1
10
100
1000
10000
2 4 6 8 10 12 14
Co
nce
ntr
ati
on
(m
g/L)
pH
pH dependent concentration of Cd
0.00001
0.0001
0.001
0.01
0.1
1
10
100
1000
10000
0.01 0.1 1 10 100
Co
nce
ntr
ati
on
(m
g/L)
L/S (L/kg)
Cd concentration as function of L/S
0.001
0.01
0.1
1
10
100
1000
2 4 6 8 10 12 14
Re
lea
se
(m
g/k
g)
pH
pH dependent release of Cd
0.001
0.01
0.1
1
10
100
1000
0.01 0.1 1 10 100
(Cu
mu
lati
ve
) re
lea
se
(m
g/k
g)
L/S (L/kg)
(Cumulative) release of Cd
0.01
0.1
1
10
2 4 6 8 10 12 14
Co
nce
ntr
ati
on
(m
g/L)
pH
pH dependent concentration of Cr
0.001
0.01
0.1
1
10
0.01 0.1 1 10 100
Co
nce
ntr
ati
on
(m
g/L)
L/S (L/kg)
Cr concentration as function of L/S
0.0001
0.001
0.01
0.1
1
10
100
1000
2 4 6 8 10 12 14
Re
lea
se
(m
g/k
g)
pH
pH dependent release of Cr
0.0001
0.001
0.01
0.1
1
10
100
1000
0.01 0.1 1 10 100
(Cu
mu
lati
ve
) re
lea
se
(m
g/k
g)
L/S (L/kg)
(Cumulative) release of Cr
Final Report Appendix 12: MSWIFA Appendix Part 1: Leaching data
A possible methodology for setting pollutant limit values for aggregates in the EoW framework JRC-IPTS 141
0.001
0.01
0.1
1
10
100
2 4 6 8 10 12 14
Co
nce
ntr
ati
on
(m
g/L)
pH
pH dependent concentration of Cu
0.0001
0.001
0.01
0.1
1
10
100
0.01 0.1 1 10 100
Co
nce
ntr
ati
on
(m
g/L)
L/S (L/kg)
Cu concentration as function of L/S
0.0001
0.001
0.01
0.1
1
10
100
1000
2 4 6 8 10 12 14
Re
lea
se
(m
g/k
g)
pH
pH dependent release of Cu
0.0001
0.001
0.01
0.1
1
10
100
1000
0.01 0.1 1 10 100
(Cu
mu
lati
ve
) re
lea
se
(m
g/k
g)
L/S (L/kg)
(Cumulative) release of Cu
0.0001
0.001
0.01
0.1
1
10
100
2 4 6 8 10 12 14
Co
nce
ntr
ati
on
(m
g/L)
pH
pH dependent concentration of Mn
0.0001
0.001
0.01
0.1
1
10
100
0.01 0.1 1 10 100
Co
nce
ntr
ati
on
(m
g/L)
L/S (L/kg)
Mn concentration as function of L/S
0.00001
0.0001
0.001
0.01
0.1
1
10
100
1000
2 4 6 8 10 12 14
Re
lea
se
(m
g/k
g)
pH
pH dependent release of Mn
0.00001
0.0001
0.001
0.01
0.1
1
10
100
1000
0.01 0.1 1 10 100
(Cu
mu
lati
ve
) re
lea
se
(m
g/k
g)
L/S (L/kg)
(Cumulative) release of Mn
Final Report Appendix 12: MSWIFA Appendix Part 1: Leaching data
A possible methodology for setting pollutant limit values for aggregates in the EoW framework JRC-IPTS 142
0.01
0.1
1
10
100
2 4 6 8 10 12 14
Co
nce
ntr
ati
on
(m
g/L)
pH
pH dependent concentration of Mo
0.001
0.01
0.1
1
10
100
0.01 0.1 1 10 100
Co
nce
ntr
ati
on
(m
g/L)
L/S (L/kg)
Mo concentration as function of L/S
0.01
0.1
1
10
100
1000
2 4 6 8 10 12 14
Re
lea
se
(m
g/k
g)
pH
pH dependent release of Mo
0.01
0.1
1
10
100
1000
0.01 0.1 1 10 100
(Cu
mu
lati
ve
) re
lea
se
(m
g/k
g)
L/S (L/kg)
(Cumulative) release of Mo
0.0001
0.001
0.01
0.1
1
10
100
2 4 6 8 10 12 14
Co
nce
ntr
ati
on
(m
g/L)
pH
pH dependent concentration of Ni
0.0001
0.001
0.01
0.1
1
10
100
0.01 0.1 1 10 100
Co
nce
ntr
ati
on
(m
g/L)
L/S (L/kg)
Ni concentration as function of L/S
0.00001
0.0001
0.001
0.01
0.1
1
10
100
2 4 6 8 10 12 14
Re
lea
se
(m
g/k
g)
pH
pH dependent release of Ni
0.00001
0.0001
0.001
0.01
0.1
1
10
100
0.01 0.1 1 10 100
(Cu
mu
lati
ve
) re
lea
se
(m
g/k
g)
L/S (L/kg)
(Cumulative) release of Ni
Final Report Appendix 12: MSWIFA Appendix Part 1: Leaching data
A possible methodology for setting pollutant limit values for aggregates in the EoW framework JRC-IPTS 143
0.01
0.1
1
10
100
1000
10000
2 4 6 8 10 12 14
Co
nce
ntr
ati
on
(m
g/L)
pH
pH dependent concentration of Pb
0.0001
0.001
0.01
0.1
1
10
100
1000
10000
0.01 0.1 1 10 100
Co
nce
ntr
ati
on
(m
g/L)
L/S (L/kg)
Pb concentration as function of L/S
0.01
0.1
1
10
100
1000
10000
100000
2 4 6 8 10 12 14
Re
lea
se
(m
g/k
g)
pH
pH dependent release of Pb
0.01
0.1
1
10
100
1000
10000
100000
0.01 0.1 1 10 100
(Cu
mu
lati
ve
) re
lea
se
(m
g/k
g)
L/S (L/kg)
(Cumulative) release of Pb
0.0001
0.001
0.01
0.1
1
10
2 4 6 8 10 12 14
Co
nce
ntr
ati
on
(m
g/L)
pH
pH dependent concentration of Sb
0.00001
0.0001
0.001
0.01
0.1
1
10
0.01 0.1 1 10 100
Co
nce
ntr
ati
on
(m
g/L)
L/S (L/kg)
Sb concentration as function of L/S
0.00001
0.0001
0.001
0.01
0.1
1
10
100
2 4 6 8 10 12 14
Re
lea
se
(m
g/k
g)
pH
pH dependent release of Sb
0.00001
0.0001
0.001
0.01
0.1
1
10
100
0.01 0.1 1 10 100
(Cu
mu
lati
ve
) re
lea
se
(m
g/k
g)
L/S (L/kg)
(Cumulative) release of Sb
Final Report Appendix 12: MSWIFA Appendix Part 1: Leaching data
A possible methodology for setting pollutant limit values for aggregates in the EoW framework JRC-IPTS 144
0.01
0.1
1
10
100
2 4 6 8 10 12 14
Co
nce
ntr
ati
on
(m
g/L)
pH
pH dependent concentration of Se
0.0001
0.001
0.01
0.1
1
10
100
0.01 0.1 1 10 100
Co
nce
ntr
ati
on
(m
g/L)
L/S (L/kg)
Se concentration as function of L/S
0.001
0.01
0.1
1
10
100
2 4 6 8 10 12 14
Re
lea
se
(m
g/k
g)
pH
pH dependent release of Se
0.001
0.01
0.1
1
10
100
0.01 0.1 1 10 100
(Cu
mu
lati
ve
) re
lea
se
(m
g/k
g)
L/S (L/kg)
(Cumulative) release of Se
1
10
100
2 4 6 8 10 12 14
Co
nce
ntr
ati
on
(m
g/L)
pH
pH dependent concentration of Sr
0.1
1
10
100
0.01 0.1 1 10 100
Co
nce
ntr
ati
on
(m
g/L)
L/S (L/kg)
Sr concentration as function of L/S
0.1
1
10
100
1000
2 4 6 8 10 12 14
Re
lea
se
(m
g/k
g)
pH
pH dependent release of Sr
0.1
1
10
100
1000
0.01 0.1 1 10 100
(Cu
mu
lati
ve
) re
lea
se
(m
g/k
g)
L/S (L/kg)
(Cumulative) release of Sr
Final Report Appendix 12: MSWIFA Appendix Part 1: Leaching data
A possible methodology for setting pollutant limit values for aggregates in the EoW framework JRC-IPTS 145
0.0001
0.001
0.01
0.1
1
2 4 6 8 10 12 14
Co
nce
ntr
ati
on
(m
g/L)
pH
pH dependent concentration of V
0.0001
0.001
0.01
0.1
1
0.01 0.1 1 10 100
Co
nce
ntr
ati
on
(m
g/L)
L/S (L/kg)
V concentration as function of L/S
0.00001
0.0001
0.001
0.01
0.1
1
10
2 4 6 8 10 12 14
Re
lea
se
(m
g/k
g)
pH
pH dependent release of V
0.00001
0.0001
0.001
0.01
0.1
1
10
0.01 0.1 1 10 100
(Cu
mu
lati
ve
) re
lea
se
(m
g/k
g)
L/S (L/kg)
(Cumulative) release of V
0.01
0.1
1
10
100
1000
10000
2 4 6 8 10 12 14
Co
nce
ntr
ati
on
(m
g/L)
pH
pH dependent concentration of Zn
0.001
0.01
0.1
1
10
100
1000
10000
0.01 0.1 1 10 100
Co
nce
ntr
ati
on
(m
g/L)
L/S (L/kg)
Zn concentration as function of L/S
0.01
0.1
1
10
100
1000
10000
100000
2 4 6 8 10 12 14
Re
lea
se
(m
g/k
g)
pH
pH dependent release of Zn
0.01
0.1
1
10
100
1000
10000
100000
0.01 0.1 1 10 100
(Cu
mu
lati
ve
) re
lea
se
(m
g/k
g)
L/S (L/kg)
(Cumulative) release of Zn
Final Report Appendix 12: MSWIFA Appendix Part 1: Leaching data
A possible methodology for setting pollutant limit values for aggregates in the EoW framework JRC-IPTS 146
0.0110000
2 4 6 8 10 12 14
Co
nce
ntr
ati
on
(m
g/L) pH
pH dependent concentration of ZnMSWI Fly ash A NL MSWI Fly ash A2 NL MSWI Fly ash H NL
MSWI Fly ash H2 NL MSWI Fly ash R NL MSWI Fly ash R2 NL
MSWI Fly ash 1 DK MSWI Fly ash 2 DK MSWI fly ash 2 DK
MSWI fly ash R4 NL MSWI fly ash R3 NL
0.001
1
1000
0.01 0.1 1 10 100
Co
nce
ntr
ati
on
(m
g/L)
L/S (L/kg)
Zn concentration as function of L/SMSWI FA 6 BLS10 DK MSWI FA 3 BLS10 DK
MSWI FA B LS10 DK MSWI FA 2 BLS10 DK
MSWI FA CLS10 DK MSWI FA 5 LS2 DK
MSWI FA 4 CLS5 DK MSWI FA 3 CLS5 DK
MSWI fly ash LS170 DK MSWI Fly ash 6 NL
MSWI Fly ash 10 NL MSWI Fly ash 07 NL
MSWI Fly ash 08 NL MSWI Fly ash 09 NL
MSWI Fly ash 310 NL MSWI Fly ash 11 NL
MSWI Fly ash 12 NL MSWI Fly ash 21 NL
MSWI Fly ash 60 NL
7
8
9
10
11
12
13
0.01 0.1 1 10 100
pH
L/S (L/kg)
pH development as function of L/S
Final Report Appendix 13: MSWIBA Appendix Part 1: Leaching data
A possible methodology for setting pollutant limit values for aggregates in the EoW framework JRC-IPTS 147
0.0001
0.001
0.01
0.1
1
10
100
1000
10000
2 4 6 8 10 12 14
Co
nce
ntr
ati
on
(m
g/L)
pH
pH dependent concentration of Al
0.01
0.1
1
10
100
1000
0.01 0.1 1 10 100
Co
nce
ntr
ati
on
(m
g/L)
L/S (L/kg)
Al concentration as function of L/S
0.001
0.01
0.1
1
10
100
1000
10000
100000
2 4 6 8 10 12 14
Re
lea
se
(m
g/k
g)
pH
pH dependent release of Al
0.001
0.01
0.1
1
10
100
1000
10000
100000
0.01 0.1 1 10 100Cu
mu
lati
ve
re
lea
se
(m
g/k
g)
L/S (L/kg)
Cumulative release of Al
1
10
100
1000
10000
100000
2 4 6 8 10 12 14
Co
nce
ntr
ati
on
(m
g/L)
pH
pH dependent concentration of Ca
1
10
100
1000
10000
0.01 0.1 1 10 100
Co
nce
ntr
ati
on
(m
g/L)
L/S (L/kg)
Ca concentration as function of L/S
1
10
100
1000
10000
100000
1000000
2 4 6 8 10 12 14
Re
lea
se
(m
g/k
g)
pH
pH dependent release of Ca
1
10
100
1000
10000
100000
1000000
0.01 0.1 1 10 100Cu
mu
lati
ve
re
lea
se
(m
g/k
g)
L/S (L/kg)
Cumulative release of Ca
Final Report Appendix 13: MSWIBA Appendix Part 1: Leaching data
A possible methodology for setting pollutant limit values for aggregates in the EoW framework JRC-IPTS 148
0.0001
0.001
0.01
0.1
1
10
100
1000
10000
2 4 6 8 10 12 14
Co
nce
ntr
ati
on
(m
g/L)
pH
pH dependent concentration of Fe
0.00001
0.0001
0.001
0.01
0.1
1
10
0.01 0.1 1 10 100
Co
nce
ntr
ati
on
(m
g/L)
L/S (L/kg)
Fe concentration as function of L/S
0.0001
0.001
0.01
0.1
1
10
100
1000
10000
100000
2 4 6 8 10 12 14
Re
lea
se
(m
g/k
g)
pH
pH dependent release of Fe
0.0001
0.001
0.01
0.1
1
10
100
1000
10000
100000
0.01 0.1 1 10 100Cu
mu
lati
ve
re
lea
se
(m
g/k
g)
L/S (L/kg)
Cumulative release of Fe
0.001
0.01
0.1
1
10
100
1000
2 4 6 8 10 12 14
Co
nce
ntr
ati
on
(m
g/L)
pH
pH dependent concentration of Mg
0.001
0.01
0.1
1
10
100
0.01 0.1 1 10 100
Co
nce
ntr
ati
on
(m
g/L)
L/S (L/kg)
Mg concentration as function of L/S
0.001
0.01
0.1
1
10
100
1000
10000
2 4 6 8 10 12 14
Re
lea
se
(m
g/k
g)
pH
pH dependent release of Mg
0.001
0.01
0.1
1
10
100
1000
10000
0.01 0.1 1 10 100Cu
mu
lati
ve
re
lea
se
(m
g/k
g)
L/S (L/kg)
Cumulative release of Mg
Final Report Appendix 13: MSWIBA Appendix Part 1: Leaching data
A possible methodology for setting pollutant limit values for aggregates in the EoW framework JRC-IPTS 149
0.01
0.1
1
10
100
1000
10000
2 4 6 8 10 12 14
Co
nce
ntr
ati
on
(m
g/L)
pH
pH dependent concentration of Si
0.01
0.1
1
10
100
1000
0.01 0.1 1 10 100
Co
nce
ntr
ati
on
(m
g/L)
L/S (L/kg)
Si concentration as function of L/S
0.1
1
10
100
1000
10000
100000
2 4 6 8 10 12 14
Re
lea
se
(m
g/k
g)
pH
pH dependent release of Si
0.1
1
10
100
1000
10000
100000
0.01 0.1 1 10 100Cu
mu
lati
ve
re
lea
se
(m
g/k
g)
L/S (L/kg)
Cumulative release of Si
0.0001
0.001
0.01
0.1
1
10
100
1000
2 4 6 8 10 12 14
Co
nce
ntr
ati
on
(m
g/L)
pH
pH dependent concentration of Mn
0.00001
0.0001
0.001
0.01
0.1
1
10
0.01 0.1 1 10 100
Co
nce
ntr
ati
on
(m
g/L)
L/S (L/kg)
Mn concentration as function of L/S
0.00001
0.0001
0.001
0.01
0.1
1
10
100
1000
10000
2 4 6 8 10 12 14
Re
lea
se
(m
g/k
g)
pH
pH dependent release of Mn
0.00001
0.0001
0.001
0.01
0.1
1
10
100
1000
10000
0.01 0.1 1 10 100Cu
mu
lati
ve
re
lea
se
(m
g/k
g)
L/S (L/kg)
Cumulative release of Mn
Final Report Appendix 13: MSWIBA Appendix Part 1: Leaching data
A possible methodology for setting pollutant limit values for aggregates in the EoW framework JRC-IPTS 150
1
10
100
1000
2 4 6 8 10 12 14
Co
nce
ntr
ati
on
(m
g/L)
pH
pH dependent concentration of S
0.1
1
10
100
1000
0.01 0.1 1 10 100
Co
nce
ntr
ati
on
(m
g/L)
L/S (L/kg)
S concentration as function of L/S
1
10
100
1000
10000
100000
2 4 6 8 10 12 14
Re
lea
se
(m
g/k
g)
pH
pH dependent release of S
1
10
100
1000
10000
100000
0.01 0.1 1 10 100Cu
mu
lati
ve
re
lea
se
(m
g/k
g)
L/S (L/kg)
Cumulative release of S
0.1
1
10
100
1000
10000
2 4 6 8 10 12 14
Co
nce
ntr
ati
on
(m
g/L)
pH
pH dependent concentration of SO4
1
10
100
1000
10000
0.01 0.1 1 10 100
Co
nce
ntr
ati
on
(m
g/L)
L/S (L/kg)
SO4 concentration as function of L/S
0.1
1
10
100
1000
10000
100000
2 4 6 8 10 12 14
Re
lea
se
(m
g/k
g)
pH
pH dependent release of SO4
0.1
1
10
100
1000
10000
100000
0.01 0.1 1 10 100Cu
mu
lati
ve
re
lea
se
(m
g/k
g)
L/S (L/kg)
Cumulative release of SO4
Final Report Appendix 13: MSWIBA Appendix Part 1: Leaching data
A possible methodology for setting pollutant limit values for aggregates in the EoW framework JRC-IPTS 151
1
10
100
1000
2 4 6 8 10 12 14
Co
nce
ntr
ati
on
(m
g/L)
pH
pH dependent concentration of Cl
0.1
1
10
100
1000
10000
100000
0.01 0.1 1 10 100
Co
nce
ntr
ati
on
(m
g/L)
L/S (L/kg)
Cl concentration as function of L/S
0.1
1
10
100
1000
10000
100000
1000000
2 4 6 8 10 12 14
Re
lea
se
(m
g/k
g)
pH
pH dependent release of Cl
0.1
1
10
100
1000
10000
100000
1000000
0.01 0.1 1 10 100Cu
mu
lati
ve
re
lea
se
(m
g/k
g)
L/S (L/kg)
Cumulative release of Cl
0.001
0.01
0.1
1
10
100
1000
10000
2 4 6 8 10 12 14
Co
nce
ntr
ati
on
(m
g/L)
pH
pH dependent concentration of P
0.001
0.01
0.1
1
10
0.01 0.1 1 10 100
Co
nce
ntr
ati
on
(m
g/L)
L/S (L/kg)
P concentration as function of L/S
0.01
0.1
1
10
100
1000
10000
100000
2 4 6 8 10 12 14
Re
lea
se
(m
g/k
g)
pH
pH dependent release of P
0.01
0.1
1
10
100
1000
10000
100000
0.01 0.1 1 10 100Cu
mu
lati
ve
re
lea
se
(m
g/k
g)
L/S (L/kg)
Cumulative release of P
Final Report Appendix 13: MSWIBA Appendix Part 1: Leaching data
A possible methodology for setting pollutant limit values for aggregates in the EoW framework JRC-IPTS 152
1
10
100
1000
10000
2 4 6 8 10 12 14
Co
nce
ntr
ati
on
(m
g/L)
pH
pH dependent concentration of Na
1
10
100
1000
10000
100000
0.01 0.1 1 10 100
Co
nce
ntr
ati
on
(m
g/L)
L/S (L/kg)
Na concentration as function of L/S
1
10
100
1000
10000
100000
1000000
2 4 6 8 10 12 14
Re
lea
se
(m
g/k
g)
pH
pH dependent release of Na
1
10
100
1000
10000
100000
1000000
0.01 0.1 1 10 100Cu
mu
lati
ve
re
lea
se
(m
g/k
g)
L/S (L/kg)
Cumulative release of Na
1
10
100
1000
2 4 6 8 10 12 14
Co
nce
ntr
ati
on
(m
g/L)
pH
pH dependent concentration of K
1
10
100
1000
10000
0.01 0.1 1 10 100
Co
nce
ntr
ati
on
(m
g/L)
L/S (L/kg)
K concentration as function of L/S
1
10
100
1000
10000
100000
2 4 6 8 10 12 14
Re
lea
se
(m
g/k
g)
pH
pH dependent release of K
1
10
100
1000
10000
100000
0.01 0.1 1 10 100Cu
mu
lati
ve
re
lea
se
(m
g/k
g)
L/S (L/kg)
Cumulative release of K
Final Report Appendix 13: MSWIBA Appendix Part 1: Leaching data
A possible methodology for setting pollutant limit values for aggregates in the EoW framework JRC-IPTS 153
0.00001
0.0001
0.001
0.01
0.1
1
10
2 4 6 8 10 12 14
Co
nce
ntr
ati
on
(m
g/L)
pH
pH dependent concentration of Ba
0.01
0.1
1
10
100
0.01 0.1 1 10 100
Co
nce
ntr
ati
on
(m
g/L)
L/S (L/kg)
Ba concentration as function of L/S
0.0001
0.001
0.01
0.1
1
10
100
1000
2 4 6 8 10 12 14
Re
lea
se
(m
g/k
g)
pH
pH dependent release of Ba
0.0001
0.001
0.01
0.1
1
10
100
1000
0.01 0.1 1 10 100Cu
mu
lati
ve
re
lea
se
(m
g/k
g)
L/S (L/kg)
Cumulative release of Ba
0.01
0.1
1
10
100
2 4 6 8 10 12 14
Co
nce
ntr
ati
on
(m
g/L)
pH
pH dependent concentration of Sr
0.1
1
10
100
1000
10000
0.01 0.1 1 10 100
Co
nce
ntr
ati
on
(m
g/L)
L/S (L/kg)
Sr concentration as function of L/S
0.01
0.1
1
10
100
1000
10000
100000
2 4 6 8 10 12 14
Re
lea
se
(m
g/k
g)
pH
pH dependent release of Sr
0.01
0.1
1
10
100
1000
10000
100000
0.01 0.1 1 10 100Cu
mu
lati
ve
re
lea
se
(m
g/k
g)
L/S (L/kg)
Cumulative release of Sr
Final Report Appendix 13: MSWIBA Appendix Part 1: Leaching data
A possible methodology for setting pollutant limit values for aggregates in the EoW framework JRC-IPTS 154
0.00001
0.0001
0.001
0.01
0.1
1
2 4 6 8 10 12 14
Co
nce
ntr
ati
on
(m
g/L)
pH
pH dependent concentration of As
0.0001
0.001
0.01
0.1
1
0.01 0.1 1 10 100
Co
nce
ntr
ati
on
(m
g/L)
L/S (L/kg)
As concentration as function of L/S
0.0001
0.001
0.01
0.1
1
10
2 4 6 8 10 12 14
Re
lea
se
(m
g/k
g)
pH
pH dependent release of As
0.0001
0.001
0.01
0.1
1
10
0.01 0.1 1 10 100Cu
mu
lati
ve
re
lea
se
(m
g/k
g)
L/S (L/kg)
Cumulative release of As
0.00001
0.0001
0.001
0.01
0.1
1
10
2 4 6 8 10 12 14
Co
nce
ntr
ati
on
(m
g/L)
pH
pH dependent concentration of Cd
0.000001
0.00001
0.0001
0.001
0.01
0.1
1
0.01 0.1 1 10 100
Co
nce
ntr
ati
on
(m
g/L)
L/S (L/kg)
Cd concentration as function of L/S
0.000001
0.00001
0.0001
0.001
0.01
0.1
1
10
100
2 4 6 8 10 12 14
Re
lea
se
(m
g/k
g)
pH
pH dependent release of Cd
0.000001
0.00001
0.0001
0.001
0.01
0.1
1
10
100
0.01 0.1 1 10 100Cu
mu
lati
ve
re
lea
se
(m
g/k
g)
L/S (L/kg)
Cumulative release of Cd
Final Report Appendix 13: MSWIBA Appendix Part 1: Leaching data
A possible methodology for setting pollutant limit values for aggregates in the EoW framework JRC-IPTS 155
0.00001
0.0001
0.001
0.01
0.1
1
10
2 4 6 8 10 12 14
Co
nce
ntr
ati
on
(m
g/L)
pH
pH dependent concentration of Cr
1E-08
0.0000001
0.000001
0.00001
0.0001
0.001
0.01
0.1
1
10
0.01 0.1 1 10 100
Co
nce
ntr
ati
on
(m
g/L)
L/S (L/kg)
Cr concentration as function of L/S
0.0001
0.001
0.01
0.1
1
10
100
1000
2 4 6 8 10 12 14
Re
lea
se
(m
g/k
g)
pH
pH dependent release of Cr
0.0001
0.001
0.01
0.1
1
10
100
1000
0.01 0.1 1 10 100Cu
mu
lati
ve
re
lea
se
(m
g/k
g)
L/S (L/kg)
Cumulative release of Cr
0.001
0.01
0.1
1
10
100
1000
2 4 6 8 10 12 14
Co
nce
ntr
ati
on
(m
g/L)
pH
pH dependent concentration of Cu
0.01
0.1
1
10
100
0.01 0.1 1 10 100
Co
nce
ntr
ati
on
(m
g/L)
L/S (L/kg)
Cu concentration as function of L/S
0.0001
0.001
0.01
0.1
1
10
100
1000
10000
2 4 6 8 10 12 14
Re
lea
se
(m
g/k
g)
pH
pH dependent release of Cu
0.0001
0.001
0.01
0.1
1
10
100
1000
10000
0.01 0.1 1 10 100Cu
mu
lati
ve
re
lea
se
(m
g/k
g)
L/S (L/kg)
Cumulative release of Cu
Final Report Appendix 13: MSWIBA Appendix Part 1: Leaching data
A possible methodology for setting pollutant limit values for aggregates in the EoW framework JRC-IPTS 156
0.0001
0.001
0.01
0.1
1
2 4 6 8 10 12 14
Co
nce
ntr
ati
on
(m
g/L)
pH
pH dependent concentration of Mo
0.001
0.01
0.1
1
10
0.01 0.1 1 10 100
Co
nce
ntr
ati
on
(m
g/L)
L/S (L/kg)
Mo concentration as function of L/S
0.001
0.01
0.1
1
10
100
2 4 6 8 10 12 14
Re
lea
se
(m
g/k
g)
pH
pH dependent release of Mo
0.001
0.01
0.1
1
10
100
0.01 0.1 1 10 100Cu
mu
lati
ve
re
lea
se
(m
g/k
g)
L/S (L/kg)
Cumulative release of Mo
0.0001
0.001
0.01
0.1
1
10
100
1000
2 4 6 8 10 12 14
Co
nce
ntr
ati
on
(m
g/L)
pH
pH dependent concentration of Ni
0.0001
0.001
0.01
0.1
1
10
0.01 0.1 1 10 100
Co
nce
ntr
ati
on
(m
g/L)
L/S (L/kg)
Ni concentration as function of L/S
0.001
0.01
0.1
1
10
100
1000
10000
2 4 6 8 10 12 14
Re
lea
se
(m
g/k
g)
pH
pH dependent release of Ni
0.001
0.01
0.1
1
10
100
1000
10000
0.01 0.1 1 10 100Cu
mu
lati
ve
re
lea
se
(m
g/k
g)
L/S (L/kg)
Cumulative release of Ni
Final Report Appendix 13: MSWIBA Appendix Part 1: Leaching data
A possible methodology for setting pollutant limit values for aggregates in the EoW framework JRC-IPTS 157
0.0001
0.001
0.01
0.1
1
10
100
1000
2 4 6 8 10 12 14
Co
nce
ntr
ati
on
(m
g/L)
pH
pH dependent concentration of Pb
0.0000001
0.000001
0.00001
0.0001
0.001
0.01
0.1
1
10
0.01 0.1 1 10 100
Co
nce
ntr
ati
on
(m
g/L)
L/S (L/kg)
Pb concentration as function of L/S
0.00001
0.0001
0.001
0.01
0.1
1
10
100
1000
10000
2 4 6 8 10 12 14
Re
lea
se
(m
g/k
g)
pH
pH dependent release of Pb
0.00001
0.0001
0.001
0.01
0.1
1
10
100
1000
10000
0.01 0.1 1 10 100Cu
mu
lati
ve
re
lea
se
(m
g/k
g)
L/S (L/kg)
Cumulative release of Pb
0.001
0.01
0.1
1
10
2 4 6 8 10 12 14
Co
nce
ntr
ati
on
(m
g/L)
pH
pH dependent concentration of Sb
0.001
0.01
0.1
1
0.01 0.1 1 10 100
Co
nce
ntr
ati
on
(m
g/L)
L/S (L/kg)
Sb concentration as function of L/S
0.0001
0.001
0.01
0.1
1
10
100
2 4 6 8 10 12 14
Re
lea
se
(m
g/k
g)
pH
pH dependent release of Sb
0.0001
0.001
0.01
0.1
1
10
100
0.01 0.1 1 10 100Cu
mu
lati
ve
re
lea
se
(m
g/k
g)
L/S (L/kg)
Cumulative release of Sb
Final Report Appendix 13: MSWIBA Appendix Part 1: Leaching data
A possible methodology for setting pollutant limit values for aggregates in the EoW framework JRC-IPTS 158
0.0001
0.001
0.01
0.1
1
2 4 6 8 10 12 14
Co
nce
ntr
ati
on
(m
g/L)
pH
pH dependent concentration of Se
0.0001
0.001
0.01
0.1
1
0.01 0.1 1 10 100
Co
nce
ntr
ati
on
(m
g/L)
L/S (L/kg)
Se concentration as function of L/S
0.0001
0.001
0.01
0.1
1
10
2 4 6 8 10 12 14
Re
lea
se
(m
g/k
g)
pH
pH dependent release of Se
0.0001
0.001
0.01
0.1
1
10
0.01 0.1 1 10 100Cu
mu
lati
ve
re
lea
se
(m
g/k
g)
L/S (L/kg)
Cumulative release of Se
0.0001
0.001
0.01
0.1
1
10
2 4 6 8 10 12 14
Co
nce
ntr
ati
on
(m
g/L)
pH
pH dependent concentration of Sn
0.00001
0.0001
0.001
0.01
0.1
1
0.01 0.1 1 10 100
Co
nce
ntr
ati
on
(m
g/L)
L/S (L/kg)
Sn concentration as function of L/S
0.0001
0.001
0.01
0.1
1
10
100
2 4 6 8 10 12 14
Re
lea
se
(m
g/k
g)
pH
pH dependent release of Sn
0.0001
0.001
0.01
0.1
1
10
100
0.01 0.1 1 10 100Cu
mu
lati
ve
re
lea
se
(m
g/k
g)
L/S (L/kg)
Cumulative release of Sn
Final Report Appendix 13: MSWIBA Appendix Part 1: Leaching data
A possible methodology for setting pollutant limit values for aggregates in the EoW framework JRC-IPTS 159
0.000001
0.00001
0.0001
0.001
0.01
0.1
1
10
2 4 6 8 10 12 14
Co
nce
ntr
ati
on
(m
g/L)
pH
pH dependent concentration of V
0.00001
0.0001
0.001
0.01
0.1
1
0.01 0.1 1 10 100
Co
nce
ntr
ati
on
(m
g/L)
L/S (L/kg)
V concentration as function of L/S
0.00001
0.0001
0.001
0.01
0.1
1
10
100
2 4 6 8 10 12 14
Re
lea
se
(m
g/k
g)
pH
pH dependent release of V
0.00001
0.0001
0.001
0.01
0.1
1
10
100
0.01 0.1 1 10 100Cu
mu
lati
ve
re
lea
se
(m
g/k
g)
L/S (L/kg)
Cumulative release of V
0.0001
0.001
0.01
0.1
1
10
100
1000
2 4 6 8 10 12 14
Co
nce
ntr
ati
on
(m
g/L)
pH
pH dependent concentration of Zn
0.00001
0.0001
0.001
0.01
0.1
1
10
0.01 0.1 1 10 100
Co
nce
ntr
ati
on
(m
g/L)
L/S (L/kg)
Zn concentration as function of L/S
0.00001
0.0001
0.001
0.01
0.1
1
10
100
1000
10000
2 4 6 8 10 12 14
Re
lea
se
(m
g/k
g)
pH
pH dependent release of Zn
0.00001
0.0001
0.001
0.01
0.1
1
10
100
1000
10000
0.01 0.1 1 10 100Cu
mu
lati
ve
re
lea
se
(m
g/k
g)
L/S (L/kg)
Cumulative release of Zn
Final Report Appendix 13: MSWIBA Appendix Part 1: Leaching data
A possible methodology for setting pollutant limit values for aggregates in the EoW framework JRC-IPTS 160
0
2
4
6
8
10
12
14
0.01 0.1 1 10 100
pH
L/S (L/kg)
pH development as function of L/S
Final Report Appendix 14: ArtAggr Appendix Part 1: Leaching data
A possible methodology for setting pollutant limit values for aggregates in the EoW framework JRC-IPTS 161
0.001
0.01
0.1
1
10
100
2 4 6 8 10 12 14
Co
nce
ntr
ati
on
(m
g/L)
pH
pH dependent concentration of Al
0.01
0.1
1
10
100
0.01 0.1 1 10 100
Co
nce
ntr
ati
on
(m
g/L)
L/S (L/kg)
Al concentration as function of L/S
0.01
0.1
1
10
100
1000
10000
2 4 6 8 10 12 14
Re
lea
se
(m
g/k
g)
pH
pH dependent release of Al
0.01
0.1
1
10
100
1000
10000
0.01 0.1 1 10 100Cu
mu
lati
ve
re
lea
se
(m
g/k
g)
L/S (L/kg)
Cumulative release of Al
0.1
1
10
100
1000
10000
100000
2 4 6 8 10 12 14
Co
nce
ntr
ati
on
(m
g/L)
pH
pH dependent concentration of Ca
0.1
1
10
100
1000
10000
100000
0.01 0.1 1 10 100
Co
nce
ntr
ati
on
(m
g/L)
L/S (L/kg)
Ca concentration as function of L/S
1
10
100
1000
10000
100000
1000000
2 4 6 8 10 12 14
Re
lea
se
(m
g/k
g)
pH
pH dependent release of Ca
1
10
100
1000
10000
100000
1000000
0.01 0.1 1 10 100Cu
mu
lati
ve
re
lea
se
(m
g/k
g)
L/S (L/kg)
Cumulative release of Ca
Final Report Appendix 14: ArtAggr Appendix Part 1: Leaching data
A possible methodology for setting pollutant limit values for aggregates in the EoW framework JRC-IPTS 162
0.0001
0.001
0.01
0.1
1
10
100
1000
2 4 6 8 10 12 14
Co
nce
ntr
ati
on
(m
g/L)
pH
pH dependent concentration of Fe
0.0001
0.001
0.01
0.1
1
10
100
1000
0.01 0.1 1 10 100
Co
nce
ntr
ati
on
(m
g/L)
L/S (L/kg)
Fe concentration as function of L/S
0.0001
0.001
0.01
0.1
1
10
100
1000
10000
100000
2 4 6 8 10 12 14
Re
lea
se
(m
g/k
g)
pH
pH dependent release of Fe
0.0001
0.001
0.01
0.1
1
10
100
1000
10000
100000
0.01 0.1 1 10 100Cu
mu
lati
ve
re
lea
se
(m
g/k
g)
L/S (L/kg)
Cumulative release of Fe
0.001
0.01
0.1
1
10
100
1000
2 4 6 8 10 12 14
Co
nce
ntr
ati
on
(m
g/L)
pH
pH dependent concentration of Mg
0.001
0.01
0.1
1
10
100
1000
0.01 0.1 1 10 100
Co
nce
ntr
ati
on
(m
g/L)
L/S (L/kg)
Mg concentration as function of L/S
0.01
0.1
1
10
100
1000
10000
100000
2 4 6 8 10 12 14
Re
lea
se
(m
g/k
g)
pH
pH dependent release of Mg
0.01
0.1
1
10
100
1000
10000
100000
0.01 0.1 1 10 100Cu
mu
lati
ve
re
lea
se
(m
g/k
g)
L/S (L/kg)
Cumulative release of Mg
Final Report Appendix 14: ArtAggr Appendix Part 1: Leaching data
A possible methodology for setting pollutant limit values for aggregates in the EoW framework JRC-IPTS 163
0.1
1
10
100
1000
10000
2 4 6 8 10 12 14
Co
nce
ntr
ati
on
(m
g/L)
pH
pH dependent concentration of S
0.1
1
10
100
1000
10000
0.01 0.1 1 10 100
Co
nce
ntr
ati
on
(m
g/L)
L/S (L/kg)
S concentration as function of L/S
0.1
1
10
100
1000
10000
100000
1000000
2 4 6 8 10 12 14
Re
lea
se
(m
g/k
g)
pH
pH dependent release of S
0.1
1
10
100
1000
10000
100000
1000000
0.01 0.1 1 10 100Cu
mu
lati
ve
re
lea
se
(m
g/k
g)
L/S (L/kg)
Cumulative release of S
1
10
100
0.1 1 10 100
Co
nce
ntr
ati
on
(m
g/L)
L/S (L/kg)
SO4 concentration as function of L/S
1
10
100
1000
10000
100000
0.1 1 10 100Cu
mu
lati
ve
re
lea
se
(m
g/k
g)
L/S (L/kg)
Cumulative release of SO4
0.01
0.1
1
10
100
0.1 1 10 100
Co
nce
ntr
ati
on
(m
g/L)
L/S (L/kg)
Cl concentration as function of L/S
0.01
0.1
1
10
100
1000
10000
0.1 1 10 100Cu
mu
lati
ve
re
lea
se
(m
g/k
g)
L/S (L/kg)
Cumulative release of Cl
Final Report Appendix 14: ArtAggr Appendix Part 1: Leaching data
A possible methodology for setting pollutant limit values for aggregates in the EoW framework JRC-IPTS 164
0.1
1
10
100
1000
10000
100000
2 4 6 8 10 12 14
Co
nce
ntr
ati
on
(m
g/L)
pH
pH dependent concentration of Na
0.1
1
10
100
1000
10000
100000
0.01 0.1 1 10 100
Co
nce
ntr
ati
on
(m
g/L)
L/S (L/kg)
Na concentration as function of L/S
0.1
1
10
100
1000
10000
100000
1000000
10000000
2 4 6 8 10 12 14
Re
lea
se
(m
g/k
g)
pH
pH dependent release of Na
0.1
1
10
100
1000
10000
100000
1000000
10000000
0.01 0.1 1 10 100Cu
mu
lati
ve
re
lea
se
(m
g/k
g)
L/S (L/kg)
Cumulative release of Na
0.1
1
10
100
1000
10000
2 4 6 8 10 12 14
Co
nce
ntr
ati
on
(m
g/L)
pH
pH dependent concentration of K
0.1
1
10
100
1000
10000
0.01 0.1 1 10 100
Co
nce
ntr
ati
on
(m
g/L)
L/S (L/kg)
K concentration as function of L/S
0.1
1
10
100
1000
10000
100000
1000000
2 4 6 8 10 12 14
Re
lea
se
(m
g/k
g)
pH
pH dependent release of K
0.1
1
10
100
1000
10000
100000
1000000
0.01 0.1 1 10 100Cu
mu
lati
ve
re
lea
se
(m
g/k
g)
L/S (L/kg)
Cumulative release of K
Final Report Appendix 14: ArtAggr Appendix Part 1: Leaching data
A possible methodology for setting pollutant limit values for aggregates in the EoW framework JRC-IPTS 165
0.001
0.01
0.1
1
10
2 4 6 8 10 12 14
Co
nce
ntr
ati
on
(m
g/L)
pH
pH dependent concentration of Ba
0.001
0.01
0.1
1
10
0.01 0.1 1 10 100
Co
nce
ntr
ati
on
(m
g/L)
L/S (L/kg)
Ba concentration as function of L/S
0.001
0.01
0.1
1
10
100
2 4 6 8 10 12 14
Re
lea
se
(m
g/k
g)
pH
pH dependent release of Ba
0.001
0.01
0.1
1
10
100
0.01 0.1 1 10 100Cu
mu
lati
ve
re
lea
se
(m
g/k
g)
L/S (L/kg)
Cumulative release of Ba
0.0001
0.001
0.01
0.1
1
2 4 6 8 10 12 14
Co
nce
ntr
ati
on
(m
g/L)
pH
pH dependent concentration of As
0.0000001
0.000001
0.00001
0.0001
0.001
0.01
0.1
1
0.01 0.1 1 10 100
Co
nce
ntr
ati
on
(m
g/L)
L/S (L/kg)
As concentration as function of L/S
0.0001
0.001
0.01
0.1
1
10
100
2 4 6 8 10 12 14
Re
lea
se
(m
g/k
g)
pH
pH dependent release of As
0.0000001
0.000001
0.00001
0.0001
0.001
0.01
0.1
1
10
100
0.01 0.1 1 10 100Cu
mu
lati
ve
re
lea
se
(m
g/k
g)
L/S (L/kg)
Cumulative release of As
Final Report Appendix 14: ArtAggr Appendix Part 1: Leaching data
A possible methodology for setting pollutant limit values for aggregates in the EoW framework JRC-IPTS 166
0.00001
0.0001
0.001
0.01
0.1
1
10
100
2 4 6 8 10 12 14
Co
nce
ntr
ati
on
(m
g/L)
pH
pH dependent concentration of Cd
0.0001
0.001
0.01
0.1
1
10
100
0.01 0.1 1 10 100
Co
nce
ntr
ati
on
(m
g/L)
L/S (L/kg)
Cd concentration as function of L/S
0.00001
0.0001
0.001
0.01
0.1
1
10
100
1000
2 4 6 8 10 12 14
Re
lea
se
(m
g/k
g)
pH
pH dependent release of Cd
0.00001
0.0001
0.001
0.01
0.1
1
10
100
1000
0.01 0.1 1 10 100Cu
mu
lati
ve
re
lea
se
(m
g/k
g)
L/S (L/kg)
Cumulative release of Cd
0.0001
0.001
0.01
0.1
1
10
2 4 6 8 10 12 14
Co
nce
ntr
ati
on
(m
g/L)
pH
pH dependent concentration of Cr
0.0001
0.001
0.01
0.1
1
10
0.01 0.1 1 10 100
Co
nce
ntr
ati
on
(m
g/L)
L/S (L/kg)
Cr concentration as function of L/S
0.0001
0.001
0.01
0.1
1
10
100
1000
2 4 6 8 10 12 14
Re
lea
se
(m
g/k
g)
pH
pH dependent release of Cr
0.0001
0.001
0.01
0.1
1
10
100
1000
0.01 0.1 1 10 100Cu
mu
lati
ve
re
lea
se
(m
g/k
g)
L/S (L/kg)
Cumulative release of Cr
Final Report Appendix 14: ArtAggr Appendix Part 1: Leaching data
A possible methodology for setting pollutant limit values for aggregates in the EoW framework JRC-IPTS 167
0.00001
0.0001
0.001
0.01
0.1
1
10
2 4 6 8 10 12 14
Co
nce
ntr
ati
on
(m
g/L)
pH
pH dependent concentration of Cu
0.000001
0.00001
0.0001
0.001
0.01
0.1
1
10
0.01 0.1 1 10 100
Co
nce
ntr
ati
on
(m
g/L)
L/S (L/kg)
Cu concentration as function of L/S
0.00001
0.0001
0.001
0.01
0.1
1
10
100
2 4 6 8 10 12 14
Re
lea
se
(m
g/k
g)
pH
pH dependent release of Cu
0.00001
0.0001
0.001
0.01
0.1
1
10
100
0.01 0.1 1 10 100Cu
mu
lati
ve
re
lea
se
(m
g/k
g)
L/S (L/kg)
Cumulative release of Cu
0.0001
0.001
0.01
0.1
1
2 4 6 8 10 12 14
Co
nce
ntr
ati
on
(m
g/L)
pH
pH dependent concentration of Mo
0.000001
0.00001
0.0001
0.001
0.01
0.1
1
0.01 0.1 1 10 100
Co
nce
ntr
ati
on
(m
g/L)
L/S (L/kg)
Mo concentration as function of L/S
0.000001
0.00001
0.0001
0.001
0.01
0.1
1
10
100
2 4 6 8 10 12 14
Re
lea
se
(m
g/k
g)
pH
pH dependent release of Mo
0.000001
0.00001
0.0001
0.001
0.01
0.1
1
10
100
0.01 0.1 1 10 100Cu
mu
lati
ve
re
lea
se
(m
g/k
g)
L/S (L/kg)
Cumulative release of Mo
Final Report Appendix 14: ArtAggr Appendix Part 1: Leaching data
A possible methodology for setting pollutant limit values for aggregates in the EoW framework JRC-IPTS 168
0.0001
0.001
0.01
0.1
1
10
100
2 4 6 8 10 12 14
Co
nce
ntr
ati
on
(m
g/L)
pH
pH dependent concentration of Pb
0.0001
0.001
0.01
0.1
1
10
100
0.01 0.1 1 10 100
Co
nce
ntr
ati
on
(m
g/L)
L/S (L/kg)
Pb concentration as function of L/S
0.0001
0.001
0.01
0.1
1
10
100
1000
2 4 6 8 10 12 14
Re
lea
se
(m
g/k
g)
pH
pH dependent release of Pb
0.0001
0.001
0.01
0.1
1
10
100
1000
0.01 0.1 1 10 100Cu
mu
lati
ve
re
lea
se
(m
g/k
g)
L/S (L/kg)
Cumulative release of Pb
0.0001
0.001
0.01
0.1
1
2 4 6 8 10 12 14
Co
nce
ntr
ati
on
(m
g/L)
pH
pH dependent concentration of Se
0.00001
0.0001
0.001
0.01
0.1
1
0.01 0.1 1 10 100
Co
nce
ntr
ati
on
(m
g/L)
L/S (L/kg)
Se concentration as function of L/S
0.00001
0.0001
0.001
0.01
0.1
1
10
2 4 6 8 10 12 14
Re
lea
se
(m
g/k
g)
pH
pH dependent release of Se
0.00001
0.0001
0.001
0.01
0.1
1
10
0.01 0.1 1 10 100Cu
mu
lati
ve
re
lea
se
(m
g/k
g)
L/S (L/kg)
Cumulative release of Se
Final Report Appendix 14: ArtAggr Appendix Part 1: Leaching data
A possible methodology for setting pollutant limit values for aggregates in the EoW framework JRC-IPTS 169
0.0001
0.001
0.01
0.1
1
10
2 4 6 8 10 12 14
Co
nce
ntr
ati
on
(m
g/L)
pH
pH dependent concentration of V
0.00001
0.0001
0.001
0.01
0.1
1
10
0.01 0.1 1 10 100
Co
nce
ntr
ati
on
(m
g/L)
L/S (L/kg)
V concentration as function of L/S
0.00001
0.0001
0.001
0.01
0.1
1
10
100
1000
2 4 6 8 10 12 14
Re
lea
se
(m
g/k
g)
pH
pH dependent release of V
0.00001
0.0001
0.001
0.01
0.1
1
10
100
1000
0.01 0.1 1 10 100Cu
mu
lati
ve
re
lea
se
(m
g/k
g)
L/S (L/kg)
Cumulative release of V
0.0001
0.001
0.01
0.1
1
10
100
1000
2 4 6 8 10 12 14
Co
nce
ntr
ati
on
(m
g/L)
pH
pH dependent concentration of Zn
0.0001
0.001
0.01
0.1
1
10
100
1000
0.01 0.1 1 10 100
Co
nce
ntr
ati
on
(m
g/L)
L/S (L/kg)
Zn concentration as function of L/S
0.0001
0.001
0.01
0.1
1
10
100
1000
10000
100000
2 4 6 8 10 12 14
Re
lea
se
(m
g/k
g)
pH
pH dependent release of Zn
0.0001
0.001
0.01
0.1
1
10
100
1000
10000
100000
0.01 0.1 1 10 100Cu
mu
lati
ve
re
lea
se
(m
g/k
g)
L/S (L/kg)
Cumulative release of Zn
Final Report Appendix 14: ArtAggr Appendix Part 1: Leaching data
A possible methodology for setting pollutant limit values for aggregates in the EoW framework JRC-IPTS 170
0
2
4
6
8
10
12
14
0.01 0.1 1 10 100
pH
L/S (L/kg)
pH development as function of L/S
Final Report Appendix 15: NatAggr Appendix Part 1: Leaching data
A possible methodology for setting pollutant limit values for aggregates in the EoW framework JRC-IPTS 171
0.00001
0.0001
0.001
0.01
0.1
1
10
100
2 4 6 8 10 12 14
Co
nce
ntr
ati
on
(m
g/L)
pH
pH dependent concentration of Al
0.01
0.1
1
10
0.1 1 10
Co
nce
ntr
ati
on
(m
g/L)
L/S (L/kg)
Al concentration as function of L/S
0.0001
0.001
0.01
0.1
1
10
100
1000
2 4 6 8 10 12 14
Re
lea
se
(m
g/k
g)
pH
pH dependent release of Al
0.0001
0.001
0.01
0.1
1
10
100
1000
0.1 1 10
(Cu
mu
lati
ve
) re
lea
se
(m
g/k
g)
L/S (L/kg)
(Cumulative) release of Al
0.01
0.1
1
10
100
1000
10000
100000
2 4 6 8 10 12 14
Co
nce
ntr
ati
on
(m
g/L)
pH
pH dependent concentration of Ca
0.0001
0.001
0.01
0.1
1
10
100
1000
0.1 1 10 100
Co
nce
ntr
ati
on
(m
g/L)
L/S (L/kg)
Ca concentration as function of L/S
0.001
0.01
0.1
1
10
100
1000
10000
100000
1000000
2 4 6 8 10 12 14
Re
lea
se
(m
g/k
g)
pH
pH dependent release of Ca
0.001
0.01
0.1
1
10
100
1000
10000
100000
1000000
0.1 1 10 100
(Cu
mu
lati
ve
) re
lea
se
(m
g/k
g)
L/S (L/kg)
(Cumulative) release of Ca
Final Report Appendix 15: NatAggr Appendix Part 1: Leaching data
A possible methodology for setting pollutant limit values for aggregates in the EoW framework JRC-IPTS 172
0.00001
0.0001
0.001
0.01
0.1
1
10
100
1000
10000
2 4 6 8 10 12 14
Co
nce
ntr
ati
on
(m
g/L)
pH
pH dependent concentration of Fe
0.0001
0.001
0.01
0.1
1
0.1 1 10
Co
nce
ntr
ati
on
(m
g/L)
L/S (L/kg)
Fe concentration as function of L/S
0.0001
0.001
0.01
0.1
1
10
100
1000
10000
100000
2 4 6 8 10 12 14
Re
lea
se
(m
g/k
g)
pH
pH dependent release of Fe
0.0001
0.001
0.01
0.1
1
10
100
1000
10000
100000
0.1 1 10
(Cu
mu
lati
ve
) re
lea
se
(m
g/k
g)
L/S (L/kg)
(Cumulative) release of Fe
0.00001
0.0001
0.001
0.01
0.1
1
10
100
1000
2 4 6 8 10 12 14
Co
nce
ntr
ati
on
(m
g/L)
pH
pH dependent concentration of Mg
0.00001
0.0001
0.001
0.01
0.1
1
10
100
0.1 1 10 100
Co
nce
ntr
ati
on
(m
g/L)
L/S (L/kg)
Mg concentration as function of L/S
0.0001
0.001
0.01
0.1
1
10
100
1000
10000
2 4 6 8 10 12 14
Re
lea
se
(m
g/k
g)
pH
pH dependent release of Mg
0.0001
0.001
0.01
0.1
1
10
100
1000
10000
0.1 1 10 100
(Cu
mu
lati
ve
) re
lea
se
(m
g/k
g)
L/S (L/kg)
(Cumulative) release of Mg
Final Report Appendix 15: NatAggr Appendix Part 1: Leaching data
A possible methodology for setting pollutant limit values for aggregates in the EoW framework JRC-IPTS 173
1
10
100
1000
10000
2 4 6 8 10 12 14
Co
nce
ntr
ati
on
(m
g/L)
pH
pH dependent concentration of Si
1
10
100
1000
10000
100000
2 4 6 8 10 12 14
Re
lea
se
(m
g/k
g)
pH
pH dependent release of Si
0.00001
0.0001
0.001
0.01
0.1
1
10
100
1000
2 4 6 8 10 12 14
Co
nce
ntr
ati
on
(m
g/L)
pH
pH dependent concentration of Mn
0.0001
0.001
0.01
0.1
1
10
100
1000
10000
2 4 6 8 10 12 14
Re
lea
se
(m
g/k
g)
pH
pH dependent release of Mn
0.1
1
10
100
2 4 6 8 10 12 14
Co
nce
ntr
ati
on
(m
g/L)
pH
pH dependent concentration of Cl
0.01
0.1
1
10
100
0.1 1 10 100
Co
nce
ntr
ati
on
(m
g/L)
L/S (L/kg)
Cl concentration as function of L/S
0.1
1
10
100
1000
2 4 6 8 10 12 14
Re
lea
se
(m
g/k
g)
pH
pH dependent release of Cl
0.1
1
10
100
1000
0.1 1 10 100
(Cu
mu
lati
ve
) re
lea
se
(m
g/k
g)
L/S (L/kg)
(Cumulative) release of Cl
Final Report Appendix 15: NatAggr Appendix Part 1: Leaching data
A possible methodology for setting pollutant limit values for aggregates in the EoW framework JRC-IPTS 174
0.1
1
10
100
1000
2 4 6 8 10 12 14
Co
nce
ntr
ati
on
(m
g/L)
pH
pH dependent concentration of S
0.1
1
10
100
1000
0.1 1 10
Co
nce
ntr
ati
on
(m
g/L)
L/S (L/kg)
S concentration as function of L/S
1
10
100
1000
10000
2 4 6 8 10 12 14
Re
lea
se
(m
g/k
g)
pH
pH dependent release of S
1
10
100
1000
10000
0.1 1 10Cu
mu
lati
ve
re
lea
se
(m
g/k
g)
L/S (L/kg)
Cumulative release of S
0.1
1
10
100
1000
2 4 6 8 10 12 14
Co
nce
ntr
ati
on
(m
g/L)
pH
pH dependent concentration of SO4
1
10
100
1000
0.1 1 10 100
Co
nce
ntr
ati
on
(m
g/L)
L/S (L/kg)
SO4 concentration as function of L/S
0.1
1
10
100
1000
10000
2 4 6 8 10 12 14
Re
lea
se
(m
g/k
g)
pH
pH dependent release of SO4
0.1
1
10
100
1000
10000
0.1 1 10 100Cu
mu
lati
ve
re
lea
se
(m
g/k
g)
L/S (L/kg)
Cumulative release of SO4
Final Report Appendix 15: NatAggr Appendix Part 1: Leaching data
A possible methodology for setting pollutant limit values for aggregates in the EoW framework JRC-IPTS 175
0.00001
0.0001
0.001
0.01
0.1
1
10
100
2 4 6 8 10 12 14
Co
nce
ntr
ati
on
(m
g/L)
pH
pH dependent concentration of P
0.1
1
10
0.1 1 10 100
Co
nce
ntr
ati
on
(m
g/L)
L/S (L/kg)
P concentration as function of L/S
0.0001
0.001
0.01
0.1
1
10
100
1000
2 4 6 8 10 12 14
Re
lea
se
(m
g/k
g)
pH
pH dependent release of P
0.0001
0.001
0.01
0.1
1
10
100
1000
0.1 1 10 100Cu
mu
lati
ve
re
lea
se
(m
g/k
g)
L/S (L/kg)
Cumulative release of P
0.0001
0.001
0.01
0.1
1
10
100
1000
10000
2 4 6 8 10 12 14
Co
nce
ntr
ati
on
(m
g/L)
pH
pH dependent concentration of Na
0.0001
0.001
0.01
0.1
1
10
100
0.1 1 10 100
Co
nce
ntr
ati
on
(m
g/L)
L/S (L/kg)
Na concentration as function of L/S
0.001
0.01
0.1
1
10
100
1000
10000
100000
2 4 6 8 10 12 14
Re
lea
se
(m
g/k
g)
pH
pH dependent release of Na
0.001
0.01
0.1
1
10
100
1000
10000
100000
0.1 1 10 100
(Cu
mu
lati
ve
) re
lea
se
(m
g/k
g)
L/S (L/kg)
(Cumulative) release of Na
Final Report Appendix 15: NatAggr Appendix Part 1: Leaching data
A possible methodology for setting pollutant limit values for aggregates in the EoW framework JRC-IPTS 176
0.0001
0.001
0.01
0.1
1
10
100
2 4 6 8 10 12 14
Co
nce
ntr
ati
on
(m
g/L)
pH
pH dependent concentration of K
0.00001
0.0001
0.001
0.01
0.1
1
10
100
0.1 1 10 100
Co
nce
ntr
ati
on
(m
g/L)
L/S (L/kg)
K concentration as function of L/S
0.0001
0.001
0.01
0.1
1
10
100
1000
2 4 6 8 10 12 14
Re
lea
se
(m
g/k
g)
pH
pH dependent release of K
0.0001
0.001
0.01
0.1
1
10
100
1000
0.1 1 10 100
(Cu
mu
lati
ve
) re
lea
se
(m
g/k
g)
L/S (L/kg)
(Cumulative) release of K
0.0001
0.001
0.01
0.1
1
10
100
2 4 6 8 10 12 14
Co
nce
ntr
ati
on
(m
g/L)
pH
pH dependent concentration of Ba
0.001
0.01
0.1
1
0.1 1 10
Co
nce
ntr
ati
on
(m
g/L)
L/S (L/kg)
Ba concentration as function of L/S
0.00001
0.0001
0.001
0.01
0.1
1
10
100
1000
2 4 6 8 10 12 14
Re
lea
se
(m
g/k
g)
pH
pH dependent release of Ba
0.00001
0.0001
0.001
0.01
0.1
1
10
100
1000
0.1 1 10Cu
mu
lati
ve
re
lea
se
(m
g/k
g)
L/S (L/kg)
Cumulative release of Ba
Final Report Appendix 15: NatAggr Appendix Part 1: Leaching data
A possible methodology for setting pollutant limit values for aggregates in the EoW framework JRC-IPTS 177
0.0001
0.001
0.01
0.1
1
10
2 4 6 8 10 12 14
Co
nce
ntr
ati
on
(m
g/L)
pH
pH dependent concentration of Sr
0.0001
0.001
0.01
0.1
1
1 10
Co
nce
ntr
ati
on
(m
g/L)
L/S (L/kg)
Sr concentration as function of L/S
0.001
0.01
0.1
1
10
100
2 4 6 8 10 12 14
Re
lea
se
(m
g/k
g)
pH
pH dependent release of Sr
0.001
0.01
0.1
1
10
100
1 10
(Cu
mu
lati
ve
) re
lea
se
(m
g/k
g)
L/S (L/kg)
(Cumulative) release of Sr
0.0001
0.001
0.01
0.1
1
2 4 6 8 10 12 14
Co
nce
ntr
ati
on
(m
g/L)
pH
pH dependent concentration of As
0.0000001
0.000001
0.00001
0.0001
0.001
0.01
0.1
1
0.1 1 10 100
Co
nce
ntr
ati
on
(m
g/L)
L/S (L/kg)
As concentration as function of L/S
0.0000001
0.000001
0.00001
0.0001
0.001
0.01
0.1
1
10
2 4 6 8 10 12 14
Re
lea
se
(m
g/k
g)
pH
pH dependent release of As
0.0000001
0.000001
0.00001
0.0001
0.001
0.01
0.1
1
10
0.1 1 10 100
(Cu
mu
lati
ve
) re
lea
se
(m
g/k
g)
L/S (L/kg)
(Cumulative) release of As
Final Report Appendix 15: NatAggr Appendix Part 1: Leaching data
A possible methodology for setting pollutant limit values for aggregates in the EoW framework JRC-IPTS 178
0.000001
0.00001
0.0001
0.001
0.01
0.1
1
2 4 6 8 10 12 14
Co
nce
ntr
ati
on
(m
g/L)
pH
pH dependent concentration of Cd
0.00001
0.0001
0.001
0.01
0.1
1
0.1 1 10 100
Co
nce
ntr
ati
on
(m
g/L)
L/S (L/kg)
Cd concentration as function of L/S
0.00001
0.0001
0.001
0.01
0.1
1
10
2 4 6 8 10 12 14
Re
lea
se
(m
g/k
g)
pH
pH dependent release of Cd
0.00001
0.0001
0.001
0.01
0.1
1
10
0.1 1 10 100
(Cu
mu
lati
ve
) re
lea
se
(m
g/k
g)
L/S (L/kg)
(Cumulative) release of Cd
0.000001
0.00001
0.0001
0.001
0.01
0.1
1
2 4 6 8 10 12 14
Co
nce
ntr
ati
on
(m
g/L)
pH
pH dependent concentration of Cr
0.000001
0.00001
0.0001
0.001
0.01
0.1
1
0.1 1 10 100
Co
nce
ntr
ati
on
(m
g/L)
L/S (L/kg)
Cr concentration as function of L/S
0.000001
0.00001
0.0001
0.001
0.01
0.1
1
10
2 4 6 8 10 12 14
Re
lea
se
(m
g/k
g)
pH
pH dependent release of Cr
0.000001
0.00001
0.0001
0.001
0.01
0.1
1
10
0.1 1 10 100
(Cu
mu
lati
ve
) re
lea
se
(m
g/k
g)
L/S (L/kg)
(Cumulative) release of Cr
Final Report Appendix 15: NatAggr Appendix Part 1: Leaching data
A possible methodology for setting pollutant limit values for aggregates in the EoW framework JRC-IPTS 179
0.000001
0.00001
0.0001
0.001
0.01
0.1
1
2 4 6 8 10 12 14
Co
nce
ntr
ati
on
(m
g/L)
pH
pH dependent concentration of Cu
0.000001
0.00001
0.0001
0.001
0.01
0.1
1
0.1 1 10 100
Co
nce
ntr
ati
on
(m
g/L)
L/S (L/kg)
Cu concentration as function of L/S
0.000001
0.00001
0.0001
0.001
0.01
0.1
1
10
2 4 6 8 10 12 14
Re
lea
se
(m
g/k
g)
pH
pH dependent release of Cu
0.000001
0.00001
0.0001
0.001
0.01
0.1
1
10
0.1 1 10 100
(Cu
mu
lati
ve
) re
lea
se
(m
g/k
g)
L/S (L/kg)
(Cumulative) release of Cu
0.00001
0.0001
0.001
0.01
0.1
1
2 4 6 8 10 12 14
Co
nce
ntr
ati
on
(m
g/L)
pH
pH dependent concentration of Mo
0.000001
0.00001
0.0001
0.001
0.01
0.1
1
0.1 1 10 100
Co
nce
ntr
ati
on
(m
g/L)
L/S (L/kg)
Mo concentration as function of L/S
0.000001
0.00001
0.0001
0.001
0.01
0.1
1
2 4 6 8 10 12 14
Re
lea
se
(m
g/k
g)
pH
pH dependent release of Mo
0.000001
0.00001
0.0001
0.001
0.01
0.1
1
0.1 1 10 100Cu
mu
lati
ve
re
lea
se
(m
g/k
g)
L/S (L/kg)
Cumulative release of Mo
Final Report Appendix 15: NatAggr Appendix Part 1: Leaching data
A possible methodology for setting pollutant limit values for aggregates in the EoW framework JRC-IPTS 180
0.000001
0.00001
0.0001
0.001
0.01
0.1
1
10
2 4 6 8 10 12 14
Co
nce
ntr
ati
on
(m
g/L)
pH
pH dependent concentration of Ni
0.000001
0.00001
0.0001
0.001
0.01
0.1
1
0.1 1 10 100
Co
nce
ntr
ati
on
(m
g/L)
L/S (L/kg)
Ni concentration as function of L/S
0.000001
0.00001
0.0001
0.001
0.01
0.1
1
10
100
2 4 6 8 10 12 14
Re
lea
se
(m
g/k
g)
pH
pH dependent release of Ni
0.000001
0.00001
0.0001
0.001
0.01
0.1
1
10
100
0.1 1 10 100
(Cu
mu
lati
ve
) re
lea
se
(m
g/k
g)
L/S (L/kg)
(Cumulative) release of Ni
0.000001
0.00001
0.0001
0.001
0.01
0.1
1
2 4 6 8 10 12 14
Co
nce
ntr
ati
on
(m
g/L)
pH
pH dependent concentration of Pb
0.001
0.01
0.1
1
0.1 1 10 100
Co
nce
ntr
ati
on
(m
g/L)
L/S (L/kg)
Pb concentration as function of L/S
0.00001
0.0001
0.001
0.01
0.1
1
10
2 4 6 8 10 12 14
Re
lea
se
(m
g/k
g)
pH
pH dependent release of Pb
0.00001
0.0001
0.001
0.01
0.1
1
10
0.1 1 10 100
(Cu
mu
lati
ve
) re
lea
se
(m
g/k
g)
L/S (L/kg)
(Cumulative) release of Pb
Final Report Appendix 15: NatAggr Appendix Part 1: Leaching data
A possible methodology for setting pollutant limit values for aggregates in the EoW framework JRC-IPTS 181
0.00001
0.0001
0.001
0.01
0.1
1
2 4 6 8 10 12 14
Co
nce
ntr
ati
on
(m
g/L)
pH
pH dependent concentration of Sb
0.000001
0.00001
0.0001
0.001
0.01
0.1
1
0.1 1 10 100
Co
nce
ntr
ati
on
(m
g/L)
L/S (L/kg)
Sb concentration as function of L/S
0.0000001
0.000001
0.00001
0.0001
0.001
0.01
0.1
1
2 4 6 8 10 12 14
Re
lea
se
(m
g/k
g)
pH
pH dependent release of Sb
0.0000001
0.000001
0.00001
0.0001
0.001
0.01
0.1
1
0.1 1 10 100Cu
mu
lati
ve
re
lea
se
(m
g/k
g)
L/S (L/kg)
Cumulative release of Sb
0.0001
0.001
0.01
0.1
1
2 4 6 8 10 12 14
Co
nce
ntr
ati
on
(m
g/L)
pH
pH dependent concentration of Se
0.0001
0.001
0.01
0.1
1
0.1 1 10 100
Co
nce
ntr
ati
on
(m
g/L)
L/S (L/kg)
Se concentration as function of L/S
0.0001
0.001
0.01
0.1
1
2 4 6 8 10 12 14
Re
lea
se
(m
g/k
g)
pH
pH dependent release of Se
0.0001
0.001
0.01
0.1
1
0.1 1 10 100Cu
mu
lati
ve
re
lea
se
(m
g/k
g)
L/S (L/kg)
Cumulative release of Se
Final Report Appendix 15: NatAggr Appendix Part 1: Leaching data
A possible methodology for setting pollutant limit values for aggregates in the EoW framework JRC-IPTS 182
0.00001
0.0001
0.001
0.01
0.1
1
2 4 6 8 10 12 14
Co
nce
ntr
ati
on
(m
g/L)
pH
pH dependent concentration of Sn
0.00001
0.0001
0.001
0.01
0.1
1
0.1 1 10 100
Co
nce
ntr
ati
on
(m
g/L)
L/S (L/kg)
Sn concentration as function of L/S
0.00001
0.0001
0.001
0.01
0.1
1
2 4 6 8 10 12 14
Re
lea
se
(m
g/k
g)
pH
pH dependent release of Sn
0.00001
0.0001
0.001
0.01
0.1
1
0.1 1 10 100Cu
mu
lati
ve
re
lea
se
(m
g/k
g)
L/S (L/kg)
Cumulative release of Sn
0.0000001
0.000001
0.00001
0.0001
0.001
0.01
0.1
1
2 4 6 8 10 12 14
Co
nce
ntr
ati
on
(m
g/L)
pH
pH dependent concentration of V
0.00001
0.0001
0.001
0.01
0.1
1
0.1 1 10 100
Co
nce
ntr
ati
on
(m
g/L)
L/S (L/kg)
V concentration as function of L/S
0.000001
0.00001
0.0001
0.001
0.01
0.1
1
10
2 4 6 8 10 12 14
Re
lea
se
(m
g/k
g)
pH
pH dependent release of V
0.000001
0.00001
0.0001
0.001
0.01
0.1
1
10
0.1 1 10 100Cu
mu
lati
ve
re
lea
se
(m
g/k
g)
L/S (L/kg)
Cumulative release of V
Final Report Appendix 15: NatAggr Appendix Part 1: Leaching data
A possible methodology for setting pollutant limit values for aggregates in the EoW framework JRC-IPTS 183
0.000001
0.00001
0.0001
0.001
0.01
0.1
1
10
2 4 6 8 10 12 14
Co
nce
ntr
ati
on
(m
g/L)
pH
pH dependent concentration of Zn
0.000001
0.00001
0.0001
0.001
0.01
0.1
1
0.1 1 10 100
Co
nce
ntr
ati
on
(m
g/L)
L/S (L/kg)
Zn concentration as function of L/S
0.00001
0.0001
0.001
0.01
0.1
1
10
100
2 4 6 8 10 12 14
Re
lea
se
(m
g/k
g)
pH
pH dependent release of Zn
0.00001
0.0001
0.001
0.01
0.1
1
10
100
0.1 1 10 100
(Cu
mu
lati
ve
) re
lea
se
(m
g/k
g)
L/S (L/kg)
(Cumulative) release of Zn
0
2
4
6
8
10
12
0.1 1 10 100
pH
L/S (L/kg)
pH development as function of L/S
Final Report Appendix 16: LimeStone Appendix Part 1: Leaching data
A possible methodology for setting pollutant limit values for aggregates in the EoW framework JRC-IPTS 184
0.001
0.01
0.1
1
10
2 4 6 8 10 12 14
Re
lea
se
(m
g/k
g)
pH
pH dependent release of Al
0.001
0.01
0.1
1
1 10
Co
nce
ntr
ati
on
(m
g/L)
L/S (L/kg)
Al concentration as function of L/S
1
10
100
1000
2 4 6 8 10 12 14
Re
lea
se
(m
g/k
g)
pH
pH dependent release of Ca
1
10
100
1 10
Co
nce
ntr
ati
on
(m
g/L)
L/S (L/kg)
Ca concentration as function of L/S
0.01
0.1
1
2 4 6 8 10 12 14
Re
lea
se
(m
g/k
g)
pH
pH dependent release of Fe
0.001
0.01
0.1
1
1 10
Co
nce
ntr
ati
on
(m
g/L)
L/S (L/kg)
Fe concentration as function of L/S
1
10
100
1000
10000
100000
2 4 6 8 10 12 14
Re
lea
se
(m
g/k
g)
pH
pH dependent release of SO4
1
10
1 10
Co
nce
ntr
ati
on
(m
g/L)
L/S (L/kg)
SO4 concentration as function of L/S
Final Report Appendix 16: LimeStone Appendix Part 1: Leaching data
A possible methodology for setting pollutant limit values for aggregates in the EoW framework JRC-IPTS 185
1
10
100
1000
10000
100000
2 4 6 8 10 12 14
Re
lea
se
(m
g/k
g)
pH
pH dependent release of Cl
1
10
1 10
Co
nce
ntr
ati
on
(m
g/L)
L/S (L/kg)
Cl concentration as function of L/S
0.1
1
10
100
2 4 6 8 10 12 14
Re
lea
se
(m
g/k
g)
pH
pH dependent release of K
0.1
1
10
1 10
Co
nce
ntr
ati
on
(m
g/L)
L/S (L/kg)
K concentration as function of L/S
1
10
100
1000
2 4 6 8 10 12 14
Re
lea
se
(m
g/k
g)
pH
pH dependent release of Mg
0.1
1
10
100
1 10
Co
nce
ntr
ati
on
(m
g/L)
L/S (L/kg)
Mg concentration as function of L/S
1
10
100
2 4 6 8 10 12 14
Re
lea
se
(m
g/k
g)
pH
pH dependent release of Na
0.1
1
10
1 10
Co
nce
ntr
ati
on
(m
g/L)
L/S (L/kg)
Na concentration as function of L/S
Final Report Appendix 16: LimeStone Appendix Part 1: Leaching data
A possible methodology for setting pollutant limit values for aggregates in the EoW framework JRC-IPTS 186
0.1
1
10
100
1000
10000
100000
2 4 6 8 10 12 14
Re
lea
se
(m
g/k
g)
pH
pH dependent release of As
0.01
0.1
1
1 10
Co
nce
ntr
ati
on
(m
g/L)
L/S (L/kg)
As concentration as function of L/S
0.01
0.1
1
10
100
1000
10000
100000
2 4 6 8 10 12 14
Re
lea
se
(m
g/k
g)
pH
pH dependent release of Cu
0.001
0.01
0.1
1
1 10
Co
nce
ntr
ati
on
(m
g/L)
L/S (L/kg)
Cu concentration as function of L/S
0.01
0.1
1
10
100
1000
10000
100000
2 4 6 8 10 12 14
Re
lea
se
(m
g/k
g)
pH
pH dependent release of Zn
0.001
0.01
0.1
1
1 10
Co
nce
ntr
ati
on
(m
g/L)
L/S (L/kg)
Zn concentration as function of L/S
0
1
2
3
4
5
6
7
8
9
10
1 10
pH
L/S (L/kg)
pH development as function of L/S
Final Report Appendix 17: GranTyr Append. Part 1: Leaching data
A possible methodology for setting pollutant limit values for aggregates in the EoW framework JRC-IPTS 187
Leaching results for scrap tyre (Column test NEN 7383 - Cumulative release at L/S=10 )
Product 1 Product 2 Product 3 BSB SQD
Element mg/kg mg/kg mg/kg mg/kg mg/kg
Antimony < 0.02 < 0.02 < 0.02 0.31 0.16
Arsenic < 0.25 < 0.25 < 0.25 1.1 0.9
Barium 0.4 0.3 0.26 50 22
Cadmium < 0.005 < 0.005 < 0.005 0.059 0.04
Chromium < 0.05 < 0.05 < 0.05 4.1 0.63
Cobalt 0.06 0.06 0.15 1 0.54
Copper < 0.05 < 0.05 < 0.05 1.9 0.9
Mercury < 0.0015 < 0.0015 < 0.0015 0.022 0.02
Lead < 0.1 < 0.1 < 0.1 4.6 2.3
Molybdenum < 0.05 < 0.025 < 0.025 1.9 1
Nickel < 0.05 < 0.05 < 0.05 2.2 0.63
Selenium < 0.02 < 0.02 < 0.02 0.23 0.15
Tin < 0.075 < 0.075 < 0.075 0.85 0.4
Vanadium < 0.1 < 0.1 < 0.1 10 1.8
Zinc 4.6 4 12 8.4 4.5
Fluoride < 1 < 1 < 1 125 55
Chloride 9.8 14.6 6.4 710 616
Sulfate 21 29 41 3760 1730
Bromide 4 < 0.5 < 0.5 3.6 20
Leaching of scrap tyre (data recalculated to mg/kg leached)
Origin Minnesota-1990 Wisconsin-1992 RMA-1991 Virginia-1992 Main Westerberg Haoya
Condition pH7,LS? pH 7 pH7,LS20 pH7,LS20 LS20 LS10,pH7 LS10,pH7
Zinc 2.3-7 0.44-13 121 13 1.9
Barium 5.3-2.1 1.9-2.1 0.4-12 3.0-7.1 0.11
Cadmium 0.14 0.03 0.3-2.3 0.0008 0.005
Chromium 0.04 0.2-0.96 0.06 0.7-1.7 0.03 0.06
Lead 0.04-0.32 0.7-4.3 0.08
Copper 1.7 0.06
Nickel 0.97 0.04
Final Report Appendix 17: GranTyr Append. Part 1: Leaching data
A possible methodology for setting pollutant limit values for aggregates in the EoW framework JRC-IPTS 188
Summary of leaching test data (L/S=10, concentrations in μg/l)
Average Median Stdev Min Max
Ca 1905 367 2913 10 7200 Fe 887 480 1493 1.39 5500 K 2685 1535 3428 50 9140
Mg 3149 125 6629 29 15000 Na 5945 2815 8439 70 22200 S 3421 1327 4430 5 10100 Al 455 454.745 631 8.49 901 As 1.0 1 0.6 0.005 2.27 Ba 9.3 9.34 2 8.08 10.6 Cd 0.4 0.5 0 0.0001 0.72 Co 5.1 5 2.4 0.005 10 Cr 3 5 2 0.001 5.96 Cu 36 5.0 109 0.005 383 Hg 33 0.15 71 0.0386 160 Mn 484 72 1143 0.03 3895 Ni 4.1 5 3.6 0.015 13 Pb 10 10 13 0.001 48.8 Zn 878 192 1986 0.03 7050
Leaching results for field samples (Column test - NEN 7383 expressed in mg/kg)
Component Field 1 Field 2 Field 3 Field 4 Field 5 BSB SQD
mg/kg mg/kg mg/kg mg/kg mg/kg mg/kg mg/kg
Antimony < 0.02 < 0.02 < 0.02 < 0.02 < 0.02 0.31 0.16
Arsenic < 0.25 < 0.25 < 0.25 < 0.25 < 0.25 1.1 0.9
Barium 7.5 0.18 0.36 0.24 0.17 50 22
Cadmium < 0.005 < 0.005 < 0.005 < 0.005 < 0.005 0.059 0.04
Chromium < 0.05 < 0.05 < 0.05 < 0.5 < 0.5 4.1 0.63
Cobalt 0.06 0.076 < 0.05 0.11 0.06 1 0.54
Copper < 0.05 < 0.05 < 0.05 0.076 < 0.05 1.9 0.9
Mercury < 0.0015 < 0.015 < 0.0015 < 0.0015 < 0.0015 0.022 0.02
Lead < 0.1 < 0.1 < 0.1 < 0.1 < 0.1 4.6 2.3
Molybdenum < 0.05 < 0.05 < 0.05 < 0.05 < 0.05 1.9 1
Nickel < 0.05 < 0.05 < 0.05 < 0.05 < 0.05 2.2 0.63
Selenium < 0.02 < 0.02 < 0.02 < 0.02 < 0.02 0.23 0.15
Tin < 0.075 < 0.075 < 0.075 < 0.075 < 0.075 0.85 0.4
Vanadium < 0.1 < 0.1 < 0.1 < 0.1 < 0.1 10 1.8
Zinc 12 41 19 53 33 8.4 4.5
Fluoride < 1 < 1 < 1 < 1 < 1 125 55
Chloride 7.6 4.9 7.4 7.5 4.8 710 616
Sulfate 41 18 30 16 8.3 3760 1730
Bromide 2.5 0.8 1.8 1.3 0.9 3.6 20
Final Report Appendix 17: GranTyr Append. Part 1: Leaching data
A possible methodology for setting pollutant limit values for aggregates in the EoW framework JRC-IPTS 189
Note: Data in several cases lack pH information, which is crucial as concentrations may vary over orders of magnitude as a function of pH. The table gives min and max values as this is the basis of reporting in some of the documents. Such ranges are not very meaningful as the information on what concentration corresponds with what experimental condition is lost. It is obvious that at low pH Zn leachability increases. Providing a number of 1000 mg/l for Zn without the corresponding pH is misleading. In the graph below the ranges as reported are specified as a box, which makes clear that the high value for Zn must match with a low pH condition. This also illustrates that 1000 mg/l is unlikely to occur at pH 6. More attention needs to be given to reporting leaching test results in a meaningful manner. The pH ranges reported by Ademe (1995) and by Kjeldsen et al (2002) seem unlikely in view of Zn chemistry and its solubility controlling phases. Plotting individual measurements at their corresponding pH is most relevant. Data on tyre shreds and tyre granulates have been merged, as the leachability of most substances is not affected by the presence or absence of iron. It should be realized that content has no relation with leaching. From a leaching perspective the differ-ence between tyre shreds and granulates is not as big as the difference in leaching as a function of pH. For the same material the difference in leaching can be 3 orders of magni-tude going from pH 4 to 8 (case of Zn). The difference as given in Edeskar’s Thesis between tyre shreds and granulates is much smaller than this difference. An aspect that can have a more significant influence on the leaching result is the particle size. Coarse granular material is likely to leach less than rather finer grained tyre granulates. This aspect is now covered for several materials in the robustness work under CEN/TC351and will be of relevance for parti-cle size distribution aspects in tyre shreds and granulates. Another aspect of leaching that is not yet covered concerns the role of dissolved organic carbon (DOC) in leaching from tyre shreds and granulates.
Figure 17.1 Zn leachability from Tyre granulate as a function of pH illustrating the relevance of a full pH range for evaluation of a material’s leachability.
0.01
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2 3 4 5 6 7 8 9 10 11 12 13 14
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Zn leaching as a function of pHMCPA 1990
Down et al, 1996
LU Test 2 L/S=10
LU Test 2: L/S=2
LU Test 1; L/S=10
Ademe 1995
Kjeldsen et al, 2002
Edeskär, 2006
Aggregate
Final Report Appendix 17: GranTyr Append. Part 1: Leaching data
A possible methodology for setting pollutant limit values for aggregates in the EoW framework JRC-IPTS 190
In figure 17.2 the leachability of PAH as a function of pH is given. The kind of increase ob-served here is consistent with matrices releasing dissolved organic matter (DOC), which is known to bind PAH and thus increase its mobility.
Figure 17.2 Leachability of PAH as a function of pH illustrating the effect of mobility increase due to binding to DOC (dissolved organic matter).
0.0
1.0
2.0
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Le
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(m
icro
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m/
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DS
)
pH
PAH leaching as a function of pH
PAH carcinogenic
PAH non carcinogenic
16 EPA PAH
Final Report Appendix 18: Comparison of BOF data with FEHS data A1: Leach. data
A possible methodology for setting pollutant limit values for aggregates in the EoW framework JRC-IPTS 191
0.00001
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pH dependent concentration of Al
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0.0001
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pH dependent concentration of Ba
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pH dependent concentration of Ca
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pH dependent concentration of Cd
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pH dependent concentration of Cr
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0.0001
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pH dependent concentration of Cu
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pH dependent concentration of Fe
Final Report Appendix 18: Comparison of BOF data with FEHS data A1: Leach. data
A possible methodology for setting pollutant limit values for aggregates in the EoW framework JRC-IPTS 192
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pH dependent concentration of K
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pH dependent concentration of Mg
0.00001
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pH dependent concentration of Mn
0.00001
0.0001
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pH dependent concentration of Mo
0.00001
0.0001
0.001
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pH dependent concentration of Ni
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0.0001
0.001
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g/L)
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pH dependent concentration of Pb
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0.001
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(m
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pH
pH dependent concentration of Sb
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0.001
0.01
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Co
nce
ntr
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on
(m
g/L)
pH
pH dependent concentration of Se
Final Report Appendix 18: Comparison of BOF data with FEHS data A1: Leach. data
A possible methodology for setting pollutant limit values for aggregates in the EoW framework JRC-IPTS 193
The red squares give the pH dependence test data for a representative BOF sample from FEHS. Apart from situations where measurements are reported as detection limits (data re-ported in this work have lower detection limits), the agreement is very good. The difference for V at high pH, for example, is the result of carbonation of the slag sample.
0.1
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2 4 6 8 10 12 14
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pH dependent concentration of Si
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pH dependent concentration of Sn
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0.001
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pH dependent concentration of V
0.00001
0.0001
0.001
0.01
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Co
nce
ntr
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(m
g/L)
pH
pH dependent concentration of Zn
Final Report Appendix 19: Comparison INTRON data with this work App.1: Leaching data
A possible methodology for setting pollutant limit values for aggregates in the EoW framework JRC-IPTS 194
In the context of the CEN/TC351 work INTRON has reported on data ranges for several con-struction products (INTRON 2003-2004 and 2005). Such data ranges can be misleading, as it masks crucial factors affecting leachability, such as pH influences, particle size, redox state and organic matter content. It is possible to derive from the more elaborate data presented here ranges as well to demonstrate that the populations are very similar for the respective material types. Obviously, the ranges for the pH dependence test can be wider for specific substances than for the percolation test only, as pH influences are included (Zn, Ni, Cd). For three materials the comparison has been made. In general, the agreement is good. Table 19.1 Comparison of leachability ranges for BOF slag from the INTRON studies and from this work.
INTRON 2003-2004 INTRON 2005 This work Percolation This work pH dep
Component Gem. 90% Gem. 90% Gem. 90% Gem. 90% pH
antimony 0.0063 0.0063 0.0089 0.012 0.0138 0.018 0.0097 0.025 10
arsenic 0.014 0.014 0.068 0.14 0.0725 0.19 0.016 0.032 10
barium 3.1 6.1 2.2 2.9 3.23 7.15 2.094 5.25 7
cadmium 0.0011 0.0011 0.0016 0.0029 0.0026 0.005 0.001 0.003 7
chromium 0.033 0.071 0.044 0.077 0.0337 0.076 0.042 0.131 10
cobalt 0.024 0.024 0.026 0.032
cupper 0.02 0.02 0.021 0.031 0.0288 0.058 0.004 0.018 7
mercury 0.0017 0.0035 0.00049 0.00088
lead 0.057 0.093 0.047 0.063 0.0639 0.108 0.018 0.062 7
molybdenum 0.016 0.035 0.019 0.031 0.0243 0.045 0.039 0.178 10
nickel 0.061 0.14 0.035 0.035 0.0371 0.072 0.043 0.227 7
selenium 0.0063 0.0063 0.0089 0.012 0.0145 0.020 0.036 0.071 10
tin 0.017 0.021 0.021 0.031 0.0690 0.172 0.006 0.012 7
vanadium 0.059 0.21 0.057 0.094 0.2716 0.961 0.686 2.164 10
zinc 0.09 0.15 0.082 0.12 0.0379 0.112 0.028 0.071 7
fluoride 0.5 0.7 0.61 0.7
chloride 33 44 19 25 16.96 40.25 163.8 298.0 10
sulphate 46 83 8.1 21 8.02 15.4 31.9 133.9 10Number of
observations 10-21 3-15 39-96 7-30
Final Report Appendix 19: Comparison INTRON data with this work App.1: Leaching data
A possible methodology for setting pollutant limit values for aggregates in the EoW framework JRC-IPTS 195
Table 19.2 Comparison of leachability ranges for P slag from the INTRON studies and from this work.
INTRON 2003-2004 INTRON 2005 This work Percolation
Component Gem. 90% Gem. 90% Gem. 90%
antimony 0.014 0.014 0.014 0.014 0.095 0.454
arsenic 0.18 0.18 0.035 0.035 0.065 0.191
barium 1.01 1.2 1.12 1.6 1.4 3.4
cadmium 0.0035 0.0035 0.0035 0.0035 0.014 0.026
chromium 0.042 0.056 0.035 0.035 0.045 0.101
cobalt 0.035 0.035 0.035 0.035
cupper 0.042 0.056 0.035 0.035 0.12 0.21
mercury 0.0011 0.0011 0.0011 0.0011
lead 0.07 0.07 0.07 0.07 0.22 0.69
molybdenum 0.028 0.05 0.018 0.018 0.18 0.54
nickel 0.035 0.035 0.035 0.035 0.18 0.64
selenium 0.016 0.025 0.0083 0.014 0.11 0.39
tin 0.26 0.64 0.043 0.053 0.14 0.34
vanadium 0.33 0.47 0.34 0.62 0.47 2.07
zinc 0.14 0.14 0.14 0.14 0.22 0.55Number of
observations 5-10 1-9 6-8
Final Report Appendix 19: Comparison INTRON data with this work App.1: Leaching data
A possible methodology for setting pollutant limit values for aggregates in the EoW framework JRC-IPTS 196
Table 19.3 Comparison of leachability ranges for MSWI BA from the INTRON studies and from this work.
Figure 19.1 Graph of the comparison of INTRON data with data from this work.
INTRON 2003-2004 INTRON 2005 This work Percolation This work pH dep
Component Gem. 90% Gem. 90% Gem. 90% Gem. 90% pH
antimony 0.28 0.48 0.23 0.43 0.18 0.30 0.77 1.50 10
arsenic 0.14 0.18 0.14 0.18 0.052 0.134 0.018 0.060 10
barium 4 9.7 0.72 1.16 1.3 3.2 1.0 4.2 7
cadmium 0.0067 0.007 0.0048 0.007 0.003 0.008 0.112 0.282 7
chromium 0.11 0.3 0.054 0.11 0.057 0.184 0.106 0.319 10
cobalt 0.042 0.05 0.04 0.05
cupper 4.6 8.6 4.3 8.2 3.3 5.6 5.0 13.4 7
mercury 0.0015 0.002 0.0014 0.002
lead 0.66 1.03 0.08 0.1 0.24 0.69 0.11 0.41 7
molybdenum 1.31 2.1 1.17 2.2 0.9 1.3 0.9 1.7 10
nickel 0.12 0.2 0.085 0.14 0.101 0.192 1.201 2.445 7
selenium 0.0089 0.014 0.0076 0.014 0.024 0.038 0.060 0.124 10
tin 0.066 0.14 0.035 0.053 0.047 0.108 0.007 0.015 7
vanadium 0.096 0.1 0.14 0.3 0.085 0.219 0.015 0.049 10
zinc 0.36 0.89 0.21 0.2 0.30 0.69 20.1 49.1 7
fluoride 2.7 4.8 2.1 3
chloride 3747 5.8 3656 6.12 2726 3975 2966 6286 10
sulphate 2128 6.085 3143 5.573 648 1629 1720 2343 10Number of
observations 82-514 4-150 46-171 20-36
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INTRON 2003-2004
INTRON 2005
This work - percolation
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Final Report Appendix 20: MSWIBA - Organic Appendix Part 1: Leaching data
A possible methodology for setting pollutant limit values for aggregates in the EoW framework JRC-IPTS 197
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pH dependent release of PAH-EPA
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PAH-EPA concentration as function of L/S
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L/S (L/kg)
(Cumulative) release of PAH-EPA
6
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L/S (L/kg)
pH development as function of L/S
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ACE concentration as function of L/S
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mu
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Cumulative release of ACE
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ACY concentration as function of L/S
0.0000001
0.000001
0.00001
0.0001
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L/S (L/kg)
Cumulative release of ACY
Final Report Appendix 20: MSWIBA - Organic Appendix Part 1: Leaching data
A possible methodology for setting pollutant limit values for aggregates in the EoW framework JRC-IPTS 198
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ANT concentration as function of L/S
0.0000001
0.000001
0.00001
0.0001
0.001
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mu
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L/S (L/kg)
Cumulative release of ANT
0.000001
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0.0001
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Co
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BAA concentration as function of L/S
0.0000001
0.000001
0.00001
0.0001
0.001
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mu
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L/S (L/kg)
Cumulative release of BAA
0.000001
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0.0001
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Co
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BAP concentration as function of L/S
1E-08
0.0000001
0.000001
0.00001
0.0001
0.001
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mu
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Cumulative release of BAP
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0.0001
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Co
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CHR concentration as function of L/S
1E-08
0.0000001
0.000001
0.00001
0.0001
0.001
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Final Report Appendix 20: MSWIBA - Organic Appendix Part 1: Leaching data
A possible methodology for setting pollutant limit values for aggregates in the EoW framework JRC-IPTS 199
0.000001
0.00001
0.0001
0.001
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Co
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L/S (L/kg)
FLA concentration as function of L/S
0.0000001
0.000001
0.00001
0.0001
0.001
0.01
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0.01 0.1 1 10 100 1000Cu
mu
lati
ve
re
lea
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g/k
g)
L/S (L/kg)
Cumulative release of FLA
0.000001
0.00001
0.0001
0.001
0.01
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Co
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L/S (L/kg)
FLU concentration as function of L/S
0.000001
0.00001
0.0001
0.001
0.01
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0.01 0.1 1 10 100 1000Cu
mu
lati
ve
re
lea
se
(m
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g)
L/S (L/kg)
Cumulative release of FLU
0.000001
0.00001
0.0001
0.001
0.01
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0.01 0.1 1 10 100 1000
Co
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L/S (L/kg)
NAP concentration as function of L/S
0.000001
0.00001
0.0001
0.001
0.01
0.1
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0.01 0.1 1 10 100 1000Cu
mu
lati
ve
re
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se
(m
g/k
g)
L/S (L/kg)
Cumulative release of NAP
0.000001
0.00001
0.0001
0.001
0.01
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0.01 0.1 1 10 100 1000
Co
nce
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L/S (L/kg)
PHE concentration as function of L/S
0.000001
0.00001
0.0001
0.001
0.01
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0.01 0.1 1 10 100 1000Cu
mu
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g/k
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L/S (L/kg)
Cumulative release of PHE
Final Report Appendix 20: MSWIBA - Organic Appendix Part 1: Leaching data
A possible methodology for setting pollutant limit values for aggregates in the EoW framework JRC-IPTS 200
0.000001
0.00001
0.0001
0.001
0.01
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Co
nce
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L/S (L/kg)
PYR concentration as function of L/S
0.0000001
0.000001
0.00001
0.0001
0.001
0.01
0.1
1
0.01 0.1 1 10 100 1000Cu
mu
lati
ve
re
lea
se
(m
g/k
g)
L/S (L/kg)
Cumulative release of PYR
Final Report Appendix 20: MSWIBA - Organic Appendix Part 1: Leaching data
A possible methodology for setting pollutant limit values for aggregates in the EoW framework JRC-IPTS 201
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European Commission
EUR 26769 – Joint Research Centre – Institute for Prospective Technological Studies
Title: Study on methodological aspects regarding limit values for pollutants in aggregates in the context of the possible
development of end-of-waste criteria under the EU Waste Framework Directive
Author(s): Hans Saveyn, Peter Eder, Elena Garbarino, Lenka Muchova, Ole Hjelmar, Hans van der Sloot, Rob Comans, André van
Zomeren, Jiri Hyks, Anke Oberender
Luxembourg: Publications Office of the European Union
2014 – 197 pp. – 21.0 x 29.7 cm
EUR – Scientific and Technical Research series –ISSN 1831-9424 (online)
ISBN 978-92-79-39781-3 (PDF)
doi:10.2791/11763
Abstract
This report provides a methodology proposal for establishing limit values for pollutants in waste-derived aggregates with a view
of using such aggregates in a wide variety of construction projects, as part of possible end-of-waste criteria for aggregates in
accordance with Article 6 of the Waste Framework Directive (2008/98/EC). More specifically, the study centres on aggregate
substances that are subject to leaching and/or release through wear. The report focuses on identifying and assessing the
pollution risks of using aggregates derived from waste, on reviewing how the use of aggregates is regulated today in the EU
with respect to avoiding pollution, on assessing the need for including limit values for pollutants in end-of-waste criteria, on
assessing the suitability of different types of pollutant limit values, on identifying and assessing the different methodological
approaches for deriving pollutant limit values and on identifying the most suitable testing approaches and methods, including
simplified modes of compliance.
doi:10.2791/11763 ISBN 978-92-79-39781-3
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