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Research funded through Defra’s Aggregates Levy Sustainability Fund
SUSTAINABLE UTILISATION OF QUARRY BY-PRODUCTS
THEME 2 - SUSTAINABLE PROVISION OF AGGREGATES
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SUSTAINABLE AGGREGATES
Written by: Evaggelia Petavratzi, Scott Wilson
Edited by: Abbie Drew, MIRO; Neil Roberts
Designed by: Sadie Ferriday, MIRO
Sustainable Aggregates:
Aggregate resources produced from sand and gravel deposits, crushed rock or dredged from the sea contribute to the
economic and social well being of the UK. Their production and supply has environmental effects.
The Aggregate Levy Sustainability Fund (ALSF) has provided funding to undertake work to minimise and mitigate these
effects. This report is part of a portfolio of work that reviews ALSF and other work undertaken between 2002-2007 on
‘promoting environmentally-friendly extraction and transport’ of land-won aggregates to provide a state of knowledge
account and to highlight the gaps in our understanding and practices.
This publication and references within it to any
methodology, process, service, manufacturer, or company
do not constitute its endorsement or recommendation
by the Minerals Industry Research Organisation, English
Heritage or The Department for Environment, Food and
Rural Affairs
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Executive Summary 5
1. Introduction 7
1.1 Scope of study 7
2 Quarry fines – definition and general description 9
2.1 Overview of Quarry Fines Production 9
2.2 Quarry scalpings 9
2.3 Quarry fines 10
2.4 The legislative framework Affecting quarry product 11
2.4.1 Minerals Planning 11
2.4.2 The Aggregates Levy 12
2.4.3 Mining Waste Directive 13
2.4.4 Interpretive Communication on waste and by-products 14
2.5 A fit-for-purpose Criteria For quarry fines (and dust) 15
2.5.1 Generation of quarry fines and dust – parameters of influence 16
2.5.2 European Standards 16
2.5.3 Highways Agency specifications 17
2.6 Summary 18
3 Production of quarry fines and mitigation practices 21
3.1 Production of quarry fines in the U.K. 21
3. 2 Minimising the generation of quarry Fines 27
4 Utilisation opportunities for quarry fines 31
4.1 The use of quarry fines in unbound applications 32
4.1.1 Bulk filling applications 32
4.1.2 Road pavement construction 33
4.1.3 Soil enhancement 34
4.1.4 Composting 35
4.1.5 Artificial soils 36
4.1.6 Filler applications 37
4.1.7 Other applications 37
4.2 The use of quarry fines in bound applications 38
CONTENTS
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4.2.1 Controlled low strength materials 38
4.2.2 Construction products – Manufactured Concrete 40
4.2.3 Construction products – Heavy ceramics 42
4.2.4 Construction products – Manufactured aggregates 44
4.2.5 Hydraulically Bound Mixtures 46
4.2.6 Asphalt applications 48
4.3 Summary of potential utilisation routes for quarry by-products 50
5 Barriers to utilisation 53
6 Conclusions 57
7 Recommendations for future work 59
References 61
Appendix 75
Appendix I: Past research MIST projects 75
Appendix ii: The interpretative communication on waste and by-products (com (2007) 59 final) 75
Appendix III: Fit- for- purpose requirements 78
Appendix iv: Technical specifications for manufactured concrete products 79
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Quarry dusts can include material from aggregate
washing or from filtration systems.
Quarry fines below 6 mm are an integral part
of many aggregate products, but are sometimes
produced in excess quantities that do not match
market demand. Where a production/market
imbalance exists, aggregate producers need to
identify alternative utilisation routes. Often the
inclusion of high quantities of dust (particles below
75 µm) requires further processing to remove the
unwanted fractions.
There is no consistent definition for quarry
fines used throughout the quarrying sector or
construction industry. This leads to confusion
of definitions in the published literature. The
phrases quarry fines, dusts and wastes are used
interchangeably, and are used to refer to materials
which are of different particle size ranges, may, or
may not be produced intentionally, and which may
not be waste materials at all. In order to clarify
future reporting, consistent definitions for quarry
fines (and dusts and scalpings) should be developed
and applied.
One of the major obstacles to utilisation is the
absence of specifications by the industry that
describe the different types of quarry fines
according to their physical properties (such
as composition, particle size) and potential
end uses. The current European standards for
aggregates provide some fit-for-use criteria
applicable to quarry fines, primarily related to
grading specifications. Fine aggregate is defined
as the fraction of material below 4 mm for use
in concrete, mortar, unbound and hydraulically
bound mixtures, and below 2 mm for inclusion in
asphalt products. Figures on available resources and
quantities of quarry fines are based on estimates
rather than real data and this is considered as a
substantial barrier towards utilisation.
This study investigated the potential use of quarry
fines in unbound and bound applications. Quarry
fines may find their most economically viable use
in quarry restoration. Certain types of quarry
fines may be suitable for a variety of end uses with
an associated profit for the aggregate producer.
Literature review has shown that quarry fines are
suitable for use in bulk fill applications (for example,
backfilling, infilling, general fill), in road pavement
construction, in remediation and for the production
of artificial soils and compost. To some extent,
quarry fines are currently supplied into these end
uses depending on the availability of aggregate
resources within geographical proximity in the
This report provides a desk study on the sustainable utilisation of quarry by-products, focussing on quarry fines. In this report, the term quarry fines refers namely material below 6 mm from aggregate and sand and gravel production, and includes quarry dusts (material below 75 µm). Quarry fines are considered to be deliberately produced to fulfil the grading requirements of specifications. That is, the definition of quarry fines in this report does not restrict itself to material below 6 mm which is excess to market requirements.
EXECUTIVE SUMMARY
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market. Other end uses such as fillers in paper
and paint or the use of quarry fines in Portland
cement have been trialled or have been used on
single occasions. The inclusion of quarry fines in
innovative products (such as, green roofs, cob
building) have not been implemented as yet. Bound
applications reviewed in this report include various
construction products such as concrete, heavy
ceramics, and manufactured aggregates, in flowable
fills, hydraulic mixtures and asphalt. Trials have been
undertaken for all these applications and some of
them are in use in individual cases.
Some of the barriers to utilisation identified
through this desk study are related to the location
of quarry fines, the limited awareness of potential
markets by aggregate producers, the limited
knowledge about quarry fines arisings and their
characteristics, and the absence of fully developed
fit-for-use specifications for a wide range of end
products. Future projects should investigate such
barriers, and this report proposes four possible
areas for future work:
n Mapping quarry fines: Quantities of excess
quarry fines should be determined in order
to promote sustainable utilisation. This project
proposes the classification of quarry fines arisings
into produced, stockpiled and marketed.
n Feasibility studies for quarry fines. Studies on
specific material streams will provide an insight to
the technical and economic viability of different
utilisation routes.
n Characterisation of quarry fines. To address
the principal characteristics of quarry fines such as
mineralogy, particle size, compositional consistency,
temporal variability and storage and handling
properties.
n Development of ‘good practice guides’ for
the utilisation of quarry fines into different
applications. These should include examples
from current utilisation practices and refer to
critical requirements that should be met for the
incorporation of quarry fines into different end
products.
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Quarry by-products include overburden, quarry fines, and dusts, and are produced during the extraction
and processing of aggregates. This report focuses on quarry fines, namely particles below 6 mm including
quarry dusts (below 75 µm). Quarry fines that are not being used in aggregate or other products commonly
find application in quarry restoration (Manning, 2004). However, this end use may not always be the most
desirable one as certain quarry fines may have potential higher value end uses than restoration, or quarry
space constraints may require the imminent identification of an end application, rather than long-term
planned use in quarry restoration. Past research funded through the Mineral Industry Sustainable Technology
Programme (MIST) has studied the utilisation of quarry by-products (listed in Table 19 in Appendix I), and
this report has been commissioned to summarise the findings from these previous projects and broader
literature sources into one report.
1.1 SCOPE OF STUDY
The scope of this study is to enhance the industry understanding of the sustainable utilisation of quarry fines,
and to identify any gaps in current knowledge. The term sustainable utilisation implies the use of quarry fines
to their full potential to meet the needs of the present, while at the same time conserving natural resources
and finding ways to minimise the environmental impacts associated both with quarry fines production and
use. The main issues addressed by this project are:
n Defining quarry fines. Over the years various definitions have been used to describe quarry fines. This
study reviews various definitions in use and seeks to clarify the terminology in use across the industry.
n Providing an overview of production figures for quarry fines and mitigation practices. The purpose
of this overview is to describe the availability of quarry fines in the UK and to report on steps that the
industry can follow to minimise the environmental impact associated with their production. Issues regarding
the generation of quarry by-products are addressed by sub-theme ‘Optimising the Efficiency of Aggregate
Production’ of the MIRO-ALSF Dissemination Project.
The work described in this report was carried out on behalf of the Mineral Industry Research Organisation (MIRO) by Scott Wilson; it was financially supported by the Aggregates Levy Sustainability Fund (ALSF). This project is part of Theme ‘Sustainable Provision of Aggregates’ of the MIRO-ALSF Dissemination Project 2007/8 and focuses in Planning for the sustainable provision of aggregates with a particular view at Sustainable utilisation of quarry by-products.
1 INTRODUCTION
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n Reviewing and reporting past and present research and development practices that demonstrate the
utilisation potential of quarry by-products, including quarry fines. Two generic application approaches are
discussed (a) unbound applications and (b) bound applications.
n Assessing the obstacles faced by the quarrying sector and the end users when utilising quarry fines. The
market, competition with other types of materials, and the end uses currently available are some of the areas
where barriers may arise.
n Identifying the steps necessary to increase the sustainable utilisation of quarry fines, outlining the gaps in
knowledge and providing recommendations for future work.
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2.1 OVERVIEW OF QUARRY FINES PRODUCTION
Quarry fines are produced from the full range of quarrying activities including:
n Extraction (overburden removal, drilling and blasting, loading and hauling).
n Rock preparation (such as pre-screening and primary crushing and screening).
n Further processing (secondary, tertiary comminution stages, screening and treatment).
Quarry fines comprise material less than (about) 6 mm generated from any of these activities. Quarry fines
may be used as specific products (for example, as fine aggregate below 4 mm) or within other aggregate
products (for example, as part of the overall grading for a Type 1 subbase). Quarry fines (that is material
less than 6 mm) are an essential part of many aggregate products and are intentionally produced by
quarrying activities in order to provide the required product
gradings. Quarry dusts are materials less than 75 µm and
are included within the scope of quarry fines. The flow of a
production process, and the need for quarry fines and dusts
to be produced in order to meet specific product gradings, is
exemplified in Figure 1, Figure 1 also shows schematically that
the fines from early production processes (such as primary
crushing and screening) may be useful in final aggregate
products and are not necessarily excess to requirements.
2.2 QUARRY SCALPINGS
Quarry scalpings are considered to be the coarse, clay
contaminated material produced from pre-screening extracted
rock before it is sent to the primary crusher (WRAP, 2006).
Anecdotal evidence suggests that the application of the
Aggregates Levy and the use of recycled and secondary
aggregates instead, has inhibited sales of scalpings in low grade
fill applications (WRAP, 2006). However, a model of sustainable
aggregate sourcing indicates that if recycled and secondary
aggregates are promoted to fulfil their potential (that is, instead
of being used as low specification fills), and if (where there is
regional demand) increased processing is applied to scalpings, a
balance between scalpings production and the market for low
grade fills can be achieved in most areas (WRAP, 2006)
2 QUARRY FINES - DEFINITION & GENERAL DESCRIPTION
<75
Production process Grading of aggregate product
m <6 mm
Quarry fines
Quarry dusts
Grading requirement for aggregate product
Primary crushing & screening
Secondary crushing & screening
Tertiary/Quaternary crushing & screening
Excess quarry fines, including quarry dusts
Figure 1: Schematic diagram showing the production and use of quarry fines to meet grading requirements
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2.3 QUARRY FINES
This report focuses on examining potential markets for excess quarry fines and dusts that may result from
an imbalance between the production process and market demand. This includes the production of excess
quarry dusts produced from crushing and screening and collected through filtering systems (such as bag
house filters). Dusts collected through filtering systems may currently be sent to landfill as waste.
Some aggregate producers use the term quarry dust when referring to quarry fines, or may only mean
material produced in excess of market demand when referring to quarry fines or dusts (WRAP, 2006). The
term ‘quarry wastes’ is also used by some authors to refer to quarry fines and dusts even when these may
not be wastes.
Different quarries, or activities within the same quarry, may generate a range of quarry fines in relation to
their particle size and composition. For instance, fines produced from primary screening may have higher or
lower clay content than those produced through tertiary crushing and screening. Quarry fines are composed
of the same mineral substances as the soil and solid rock from which they are derived, even though changes
to their physical and chemical characteristics may have occurred. Quarry fines by their nature, are usually
inert or non-hazardous. Disaggregation, mixing and moving to different locations, exposure to atmospheric
conditions and to surface or groundwater, as well as segregation and the increase of surface area due to
particle size reduction, may cause physical and chemical transformations with detrimental effects to the
environment (BGS, 2003).
According to past research, quarrying of limestone and dolomite typically produces 20-25% fines and
sandstone/gritstone up to 35% fines (University of Leeds, 2007a). A schematic diagram of the various steps
involved in the quarrying process, together with approximate estimates of quarry fines generated, is given
in Figure 2. Quarry fines are commonly used by consumers as fine aggregates, when they comply with
appropriate standards for the project. For instance, quarry fines below 4 mm may find application as fine
aggregate in concrete (BSI, 2002a). This is a common market for limestone fines, but the levels of dust (<75
µm) may limit usefulness, and in such cases, aggregate washing may be required (WRAP, 2006). Igneous rock
quarry fines may be unsuitable for use in concrete as they increase demand for cement and water demand
(impacting on the strength and cost of concrete) (WRAP, 2006).
The scope of the legislation in force does not provide a definition of quarry fines, but sets the boundaries on
when such materials comprise a product, a by-product or a waste. According to anecdotal evidence, the fact
that quarry fines attract the Aggregates Levy is believed to reduce their attractiveness and competitiveness in
the market place (Manning, 2004; University of Leeds, 2007d).
A simple classification scheme for quarry production residues based on the readiness of a material for
use has been proposed several authors (Harrison et al, 2001; Harrison et al, 2002; Mitchell, et al, 2004),
shown in Table 1. Quarry fines could be described as Type 1 materials (for example, limestone fines used
without further processing) and Type 2 materials (for example, quarry fines used following washing). Generic
classification systems, such as the one in Table 1, can be used to characterise mineral waste and identify
potential end uses.
This report focuses on quarry fines generated from the production of aggregates, although it is anticipated
that part of its content may be applicable to other quarry operations.
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Group Description Example Potential end usesType 1 Unprocessed waste: large volume, low value industrial
minerals; commonly used in construction applications; market would be located in close proximity
quarry scalpings; quarry blocks; colliery spoil
Fill, low grade road stone, armour stone, brick clay
Type 2 Processed waste – reclaimed minerals: only a small amount of processing is required; market largely local; a small amount of secondary waste will be produced
silica sand waste; limestone waste; building stone waste
Silica sand, kaolin, brick clay, mineral filler, aglime, aggregate
Type 3 Processed waste – added-value products: contain small amounts of valuable minerals; potentially complex processing is required; major capital investment; international market; large volumes of secondary waste
Lead/zinc waste; pegmatite waste; silica sand waste
Fluorite, barite, feldspar, rare earths, mica, heavy minerals
Type 4 Beneficiated wastes: contain small quantities of highly valuable minerals; complex processing requirements; large volumes of secondary waste; international market
Specific mine wastes Gemstones, other high value metals
As shown in Figure 2, excess materials from quarrying processes are produced either through the initial
stripping stages (overburden material) or during the extraction and processing phases (scalpings and quarry
fines). It is common practice for quarries to reuse overburden material in restoration, as well as other excess
materials (Manning, 2004). However, there is still an amount of material that remains unused, as a specified
market that could absorb it does not exist, or is unaware of the potential use of the excess, including quarry
fines (WRAP, 2006). Very often, dry quarry fines are stockpiled on site until a utilisation route has been
identified, whereas wet material is deposited in tailing lagoons.
2.4 THE LEGISLATIVE FRAMEWORK AFFECTING QUARRY PRODUCT
The various regulations discussed in this section may have an impact on potential utilisation approaches of
quarry waste and therefore should be taken under consideration when planning quarry operations.
2.4.1 MINERALS PLANNING
The UK Government has set specific objectives in England for Mineral Planning (DCLG, 2006a), referring also
to “quarry waste” and “utilisation practices”, with the aim for contributing to sustainable development. The
focal point of these objectives is summarised in the bullet points below (DCLG, 2006a):
n Sustainability: efficient and sustainable use of minerals and recycling of suitable materials; conservation of
mineral resources; sustainable transport; integration of mineral planning policy with legislation on sustainable
construction and waste management
n Environmental protection: prevention and minimisation of mineral waste production; nature conservation;
prevention and reduction of impacts on the environment and human health; environmental protection during
restoration and after extraction has ceased
n Production: securing adequate and steady supplies of minerals; maximising the benefits and minimising the
impacts of mineral operations over their full life cycle; fit-for purpose use of high quality materials
The Mineral Policy Statement (MPS1) sets also out Government planning policy on the provision of
aggregates in England. The scope of this policy is (DCLG, 2006a):
n To encourage the use of alternative aggregates where possible in preference to primary aggregates
Table 1: Mineral waste classification (Harrison et al, 2001; Harrison et al, 2002; Mitchell, et al, 2004)
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n To encourage the production of marine – dredged sand where environmentally acceptable sources are
available, adopting the principles of sustainability
n To ensure that the remainder of supply is provided by primary sources (that is, sand and gravel, crushed
rock)
In line with these national objectives (DCLG, 2006a), the full utilisation of quarry fines can contribute
to Government’s aim for sustainable development and environmental protection through the efficient
use of minerals, the conservation of mineral resources (by using all quarry products, including fines), the
minimisation of mineral waste production and also by ensuring that the supply of materials required for
specific end uses is satisfied.
2.4.2 THE AGGREGATES LEVY
The Aggregates Levy is applied to primary sales of aggregates (Statutory Instrument, 2003). The purpose of
Aggregates Levy is to create a viable market for recycled and secondary aggregates by increasing the cost of
primary materials (DEFRA, 2007a). In addition to reducing the demand for primary aggregates, the Levy is
expected to:
Figure 2: Quarrying activities and estimates of fines generation per stage (source of data: (The University of Leeds, 2007c)
(Feed size)
(700-1000mm)
(700-1000mm)
(300-100mm)
(100-20mm)
(20-10mm)
Extraction
Pre-screening
* *Primary crushing &
Screening
* *Secondary crushing &
Screening
* *Tertiary/Quaternary
crushing & Screening
End products
Up to 20% fines (*1)
Up to 25% fines (*1)
Up to 40% fines (*1)
[Overburden removal] * *
[Drilling & blasting] *
[Loading & haauling] *
[Oversize rock]
[Scalpings]
* quarry fines (<6mm); consists of coarse, medium, fine particles (clay/silt <75µm)
* particulate matter (that is, collected from cyclones and bag house filters)
(*1 depending on rock type and comminution practices)
Figure 2: Quarrying activities and estimates of fines generation per stage (source of data: (The University of Leeds, 2007c)
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n promote environmentally friendly extraction and transport
n address the environmental impacts of past aggregates extraction
n compensate local communities for the impact of aggregates extraction
The Aggregates Levy also applies to quarry fines and is often seen as a barrier to utilisation, because recycled
and secondary aggregates do not attract the Levy (Manning, 2004; University of Leeds, 2007d). However, not
all natural aggregates (as defined in European Standards - see Table 3 are subject to the Aggregates Levy;
certain materials are exempt, as summarised in Table 2. The Aggregates Levy is currently set at £1.60 per
tonne. In the final Budget 2007 report, the Government announced that this will increase to £1.95 per tonne
from 1 April 2008 (HM Treasury, 2007). The Government also announced the introduction of an exemption
from the Levy for aggregate arising from the construction and maintenance of railways, tramways and
monorails.
The exemption of certain materials such as china clay waste and slate waste might be expected to promote
utilisation of these materials as aggregates. However, the distant geographical location of china clay and slate
quarries and the cost of haulage of waste material to appropriate markets are the principal barriers that
discourage their use (Smith et al, 2005 – see Figure 8).
The benefits seen from the implementation of the Levy have been the reduction in sales of primary
aggregates (by 8% between 2001 to 2005) and the reduction of pollution caused by noise, particulate matter
and other emissions to air, visual intrusion, loss of amenity and damage to wildlife habitats (HM Treasury,
2007). In addition, the Aggregates Levy Sustainability Fund (ALSF) has (and continues to) supported research
to assist the quarrying sector to move towards sustainability and improved environmental stewardship. In the
case of china clay waste, the exemption from the Levy initiated research, which looked at potential utilisation
routes and ways to overcome the barrier of transport through detailed feasibility studies (Smith et al, 2005).
The focus on sustainable utilisation of quarry fines is sufficiently recent that there are no statistical data that
provide a proof of progress made regarding quantities used, applications, substitution of primary materials
and sales figures.
2.4.3 MINING WASTE DIRECTIVE
The Mining Waste Directive (EU Directive 2006/21/EC) on the management of waste from the extractive
industries aims to prevent any adverse impacts associated with waste produced from mining activities as well
as promoting their minimisation, treatment, recovery and reuse (The European Parliament and the Council,
2006a). The Directive will require the implementation of a waste management plan and all non-inert waste
producers will require a permit to operate. Quarry operations will have to manage their waste in more
efficient ways, to investigate further mitigation practices where feasible (such as optimisation of processing
plans, greater levels of equipment maintenance), and to look at potential waste utilisation routes (The
European Parliament and the Council, 2006a). The Mining Waste Directive will be transposed into national
law by 1 May 2008 and mine waste facilities would be subject to the new provisions by 2012 (DEFRA, 2007b).
Table 2: Materials exempt from the Aggregates Levy (Finance Act, 2001)
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Materials exempt from the Aggregates Levy Commentsclay, soil, organic matter, vegetable that is, clay quarries currently utilised by brick manufacturers coal ligniteslate that is, slate waste, off-cuts Shalechina clay and ball clay waste that is, china clay sandcolliery spoil spoil from any process by which coal has been separated from
other rock after being extractedspoil or waste from any industrial combustion
process or the smelting or refining of metals
for example, industrial slag, pulverised fuel ash, foundry sand
drill cuttings from the seabed that is, beyond the water mark material arising from utility works for example from laying gas, water pipesaggregate arising from building sites material consisting wholly of aggregate arising from the site of any
building or proposed buildingaggregate extracted as a result of navigation
dredging
aggregate removed from inland waterways and harbours by
dredgingaggregate arising from highway construction,
construction and maintenance of railways,
tramways and monorails
excluding borrow pits; material that consists wholly of aggregate
arising from the ground in the course of excavation to improve,
maintain or construct highway or a proposed highway
2.4.4 INTERPRETIVE COMMUNICATION ON WASTE AND BY-PRODUCTS
The Waste Framework Directive (2006/12/EC) gives the definition of waste and accordingly materials can be
either waste or not (The European Parliament and the Council, 2006b). The terms by-product and secondary
materials, although commonly used by the quarrying and construction industry, do not have any legal
meaning. Quarry fines which have a defined end market are not a waste.
The Interpretative Communication on waste and by-products (COM (2007) 59 final) aims to clarify when a
material is waste or not in a production process context and to do so three new illustrative terms have been
introduced in addition to waste (Commission of the European Communities, 2007). These terms do not
represent a legal interpretation and they are used for clarification purposes only in this document.
n Product – the term is used to characterise materials that are deliberately created in the production
process (for example, aggregates and most quarry fines)
n Production residue - a material not deliberately produced, which may or may not be a waste (for
example, quarry dusts collected in bag house filters)
n By-product – a production residue that is not waste
The Interpretative Communication on waste and by-products (COM (2007) 59 final) facilitates the
distinction between product, by-products and waste by introducing a cumulative test comprised of three
primary criteria that set the definition of the material in question. Hence, a material is a by-product if
(Commission of the European Communities, 2007):
1. further use of the material is a certainty and not a mere possibility
2. no further processing prior to reuse is required
3. it is produced as part of a continues process of production
Table 2: Materials exempt from the Aggregates Levy (Finance Act, 2001)
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The decision tree in Figure 9 (Appendix II) displays all the different steps that have to be satisfied in order to
define a material as a by-product. Criteria 1, 2 and 3 are examined in greater detail in Figure 10 (Appendix
II) and Figure 11 (Appendix II), where three additional decision flow diagrams have been compiled for this
report, based on the information in the Communication document. The decision tree in Figure 9 (Appendix
II), suggests that if the material is deliberately produced, then this material should be considered a product,
not a production residue. Quarry fines may be considered to be deliberately produced to satisfy the
market’s demand for graded and fine aggregates; hence quarry fines represent a product. In other words,
the production of quarry fines cannot be eliminated from quarrying processes as the fines are a required
component of aggregate products. However, when excess quarry fines are generated and the market cannot
absorb them, or there is no planned use in restoration, then they may become a waste.
Similar arguments can be applied to quarry dusts. Dusts collected in bag houses, or removed by washing to
produce aggregates without dust, may currently be sent to landfill as waste but could be considered a by-
product if a satisfactory market can be found and the conditions of Criteria 1 to 3 are met. That is, the ideal
quarrying process would eliminate the production of these dusts if possible.
According to the Criteria 1 (Figure 10 – Appendix II) if a materials is not useable, does not meet the
technical specifications required for its use or there is no specified market for it, then it should continue
to comprise a waste until a useful output has been identified. When only a certain proportion of the
material can potentially be used then such a material should initially be characterised as waste until future
circumstances change its status (for example, long term contracts between waste producer and user). For
materials stored for an indefinite amount of time prior to potential reuse, they should be considered as
waste.
Often materials may undergo several processing stages prior to reuse, such as washing, drying, mixing
and comminution. Under these circumstances, additional clarification must be provided that explains
whether materials are made ready for use as an integral part of the continuing process of production. In
case that additional recovery processes are required prior to use, even if the subsequent use is a certainty,
then Criteria 2 suggests that the material is a waste until the completion of this process. The decision
flow diagram in Figure 11 (Appendix II) presents in more detail some of the sub-criteria that need to be
considered. The case of Avesta Polarit (AvestaPolarit Chrome Oy, 2003) also provides some evidence on the
application of Criteria 1-3 (Figure 12 – Appendix II).
Industry, legislative parties and research bodies often refer to quarry fines by giving different meanings to
this term. As discussed earlier in this section, quarry fines may represent a product, or a surplus material
when produced in excess quantities, and certain fractions such as the dust and filler material comprise a
production residue. It is considered essential that quarry fines will be defined properly in order to avoid
confusion and to enable their sustainable utilisation.
2.5 A FIT-FOR-PURPOSE CRITERIA FOR QUARRY FINES (AND DUST)
Quarry fines can comprise valuable alternative materials for use in a variety of end products and applications.
Commonly, the decision making criteria upon which the suitability of quarry fines is determined, are based
on technical specifications and standards or on characterisation procedures developed by end users, such as
construction product manufacturers. Therefore, it is end users that define whether quarry fines comprise a
valuable material.
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Technical specifications cover a large variety of end products, but commonly they correspond to
conventional primary aggregates. Quarry fines as well as other production residues do not necessarily behave
in a way similar to conventional primary aggregates. For instance, parameters such as the compositional
variability of quarry fines may be larger than that of conventional primary resources. Therefore, there is
a need to develop fit-for-purpose specifications that will be applicable not just for conventional primary
materials, but to other materials as well.
2.5.1 GENERATION OF QUARRY FINES AND DUST – PARAMETERS OF INFLUENCE
Parameters such as rock type, extraction technique and processing route, affect the generation of quarry
fines as well as their end properties, (for example, composition, particle size and shape). Although quarry
fines are expected to consist of similar minerals to the rocks they are derived from, the exact composition
by quantitative means may be different.
The fragmentation patterns will also vary for different rock types. Research work on assessing the dust
(fraction below 75 µm, particulate matter included) generation from various ores has found that different
rock types tested under specific mechanisms (such as abrasion), which simulate common processes such as
conveyor belts, produced different amounts of fines with different physical properties (Petavratzi, 2006). A
variety of parameters have been identified to influence the generation of fines and dust from different ores
(Petavratzi, 2006; Petavratzi et al, 2007):
n Feed: mass/bulk volume, particle size, grain/particle shape, concentration of fines in the feed (<75 µm),
mechanical properties (strength, elasticity, brittle behaviour), fragmentation.
n Mechanisms in involved industrial processes: Abrasion and impact represent the two primary mechanisms
associated with operations, such as conveyor belts, milling and mixing, haulage roads, stockpiling and tipping.
n Operational parameters: Blasting design, velocity of conveyor belts, mill type, haulage roads, time-scales of
operations, drop heights during tipping and stockpiling.
The properties of quarry fines and dust change in accordance with any of the above parameters. For
instance, fines produced during primary comminution stages may have a different particle size distribution
and composition (mineral weight %) to fines produced during secondary or tertiary crushing. Different types
of fines may find application in different end uses.
In order to facilitate the wider utilisation of quarry fines, the properties of these materials should be
determined to a level adequate to identify potential matches with end applications. Characterisation
requirements for quarry fines will vary for different end uses. For example, using X-ray diffraction analysis
(XRD) may not be the best method to determine the composition of quarry fines intended to be used in
cement because this technique does not characterise the material by quantitative means. In this instance,
the qualitative analysis (XRD) determines the mineralogy of cement and it needs to be combined with some
form of quantitative analysis, such as chemical testing.
2.5.2 EUROPEAN STANDARDS
The introduction of European Standards for aggregates during 2004 satisfied the need for specifications
for a broad variety of end applications and enabled the use of a wider range of aggregate resources. The
European Standards do not discriminate between different resources and they refer to natural, recycled and
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manufactured materials (WRAP, 2007b). Materials that could potential be used as aggregates fall within the
following categories (Quarry Products Association, 2007):
n Coarse and fine aggregates are now split at 2 mm for asphalt and 4 mm for all other uses
n Fines are defined as the inherent fraction of an aggregate passing 63 µm
n Filler is a material passing 63 µm that may be added to influence the properties of a mixture
The British Standards Institution developed a series of national guidance documents (referred to as Published
Document – PD) to support the European Standards and to provide further clarifications that fit the UK
market, and the production and nature of aggregates in the UK.
A summary of the different European Standards and Published Documents is given in Table 3. The European
Standards considered, are presented in more detail in following Sections of this report, where potential
utilisation practices are discussed. The inclusion of recycled and manufactured aggregates within the scope
of European Standards is considered a step forward. Nevertheless, specifications are still based on an ideal
grading. Research findings from an industry scoping exercise have shown that the industry finds current
specifications stringent, and that they do not specify fit-for-purpose aggregates (Mitchell, 2007a) (Project
code: MA 4/5/003).
Standard Category European Standard Number European Standard TitleProduct Standards BS EN 12620 Aggregates for concrete
BS EN 13043 Aggregates for bituminous mixtures and surface treatmentsBS EN 13139 Aggregates for mortar BS EN 13055 Part 1: Lightweight aggregate for concrete, mortar and grout
Part 2: Lightweight aggregate for bound and unbound materials
BS EN 13242 Aggregates for unbound and hydraulically bound mixtures BS EN 13383 ArmourstoneBS EN 13450 Railway ballast
National Guidance Documents
PD 6682-1 Aggregates for concretePD 6682-2 Aggregates for asphalt and chippingPD 6682-3 Aggregates for mortarPD 6682-4 Lightweight aggregates for concrete and mortarPD 6682-5 Lightweight aggregates for other usesPD 6682-6 Aggregates for unbound and hydraulically bound mixturesPD 6682-7 Aggregates for ArmourstonePD 6682-8 Aggregates for railway ballastPD 6682-9 Test method for aggregates
Test methods BS EN 932 part 1-6 General test methods (i.e sampling, petrography, repeatability –reproducibility etc)
BS EN 933 part 1-10 Test methods- geometrical propertiesBS EN 1097 part 1-9 Test methods – physical and mechanical properties BS EN 1367 part 1-5 Test methods – thermal and weathering properties BS EN 1744 Test methods – chemical properties
Table 3: European Standards for aggregates and associated documents
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2.5.3 HIGHWAYS AGENCY SPECIFICATIONS
The Highways Agency has developed a series of specifications for road pavement construction (Series 500
to 1000) that permit the use of a wide variety of natural, recycled and manufactured aggregates (Highways
Agency, 2004; Highways Agency, 2007a). Waste natural aggregates, such as china clay sand/stent and slate
waste, are included in the list of secondary and recycled materials and quarry fines may be considered for
use on a site specific basis (Highways Agency, 2004; Highways Agency, 2007a).
According to a recent DEFRA funded project, alternative materials should clearly demonstrate what their
contribution to an end use is. However, to do so, the principal elements and requirements of the end user
should be understood and presented in a way that will assist both parties (material producers and end users)
to identify potential matches of alternative materials DEFRA research states that characterisation should be
undertaken both for the alternative material (for example, mineralogy, chemistry, particle size), and the end
product (as set by technical standards).
Hence, producers of valuable materials such as quarry fines should be able to supply appropriate information
to end users which demonstrates that their materials are fit-for-purpose. One of the outcomes of this
previous research was the production of a characterisation framework that illustrates what the involvement
of various alternative materials will be, if used in five different construction products (Petavratzi and Barton,
2006; Petavratzi and Barton, 2007; Dunster, 2007). The characterisation framework covers the ceramic,
cement, concrete, insulation and manufactured aggregates sectors (shown in Table 20 in Appendix III).
Characterisation frameworks are able to promote the use of alternative materials and to assist during the
initial identification stages of identifying utilisation practices.
Relevant investigations undertaken for quarry fines have been extracted from the Waste – Products Pairings
(WPP) database developed through previous research (MIRO, 2007) and shown in Table 4. Several other
end uses for quarry fines are identified in following Sections of this report and relevant specifications are
presented there.
Development of specifications that combine the nature of different materials with the particular
requirements set by end users and technical standards is considered essential. Market trends (that is, demand,
product preferences, and product trends) and economic factors (such as cost savings associated with the use
of quarry fines, manufacturing costs) should also be considered in the development process of new fit-for-
purpose criteria. Work undertaken by the Highways Agency on the use of secondary and recycled materials
is a good example of fit-for-use specifications (Highways Agency, 2004).
2.6 SUMMARY
There is no consistent definition for quarry fines used throughout the quarrying sector or construction
industry. This leads to confusion of definitions in the published literature. The phrases quarry fines, dusts and
wastes are used interchangeably, and are used to refer to materials which are of different particle size ranges,
may, or may not be produced intentionally, and which may not be waste materials at all.
In order to clarify future reporting, consistent definitions for quarry fines (and dusts and scalpings) should be
developed and applied.
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Quarry production residues
End use Progress (1) Ingredient (2) AnalysisOf alternative Of manufacturing process
Quarry washings (fine grained silts and clay from sand and gravel operations; more rarely from crushed rock operations
Manufactured aggregates
Pilot scale trials Filler or base material
Mineralogy, chemistry, LOI(%), moisture content, particle size, cumulative % passing 300 µm-150 µm and 75 µm
According to BS EN 13055
Quarry washings Dense and lightweight concrete walling/ masonry blocks
Used in production
Coarse/ fine aggregate
Chemistry, bulk density, particle size, water absorption
Feedstock properties: grading, chloride content, sulfate content, effect on setting cement, Alkali/silica reactivity
Handling properties: particle size, moisture content, ease of flow, workability
End product properties: according to BS EN standards on various concrete products (for example, BS EN 206)
Quarry fines and dust (a wide variety of compositions)
Portland cement (CEM I)
Trials Source of silica, aluminium and iron
Particle size, mineralogy, chemistry, other constituents, total sulfur, chlorine content, heavy metals, loss on ignition
Testing on kiln feed: SiO2, Al2O3, Fe2O3, MgO
End product: according to BS EN 197
Quarry fines, and washings)
Facing brick
Work trials
Filler (primary contribution), clay substitute (secondary contribution), colourant (third contribution)
Mineralogy, chemistry, particle size, bulk density
According to BS EN 771-1:2003 for clay bricks(1) Progress made from the industry in using quarry production residues (2) The title Ingredient refers to the contribution of an alternative material to an end product
Table 4: Examples of utilisation of quarry production residues in various construction products as found in the Waste-Product Pairings (WPP) database (MIRO, 2007)
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Saleable aggregates in the UK mainly comprise sand and gravel and crushed rock and according to British
Geological Survey (BGS), there are currently 1723 active mines and quarries that produce primary aggregates
(Table 5) (BGS, 2003). The section of this report gives an overview of the information that is currently
available to describe production of quarry fines and mitigation practices. It is anticipated that sub-theme
‘Optimising the Efficiency of Aggregate Production’ of the ALSF Review Research Programme 2007-2008, will
refer to these areas in more detail.
Mineral worked Number of active sites England Wales Scotland Northern Ireland
Sand and Gravel 801 578 26 119 78Limestone 347 264 51 13 19Sandstone 305 200 29 41 35Igneous and metamorphic rock
205 50 12 97 46
Chalk 65 61 0 0 4
3.1 PRODUCTION OF QUARRY FINES IN THE U.K.
The 2004 UK survey of waste arisings by sector has revealed that 29% of total annual waste arisings are
generated by the mining and quarrying sector, which equal to approximately 100 million tonnes of mineral
residues - Figure 3 (DEFRA, 2007c). Waste from mining and quarrying does not fall within the scope of
controlled waste legislation therefore relevant regulations are not applicable.
3 PRODUCTION OF QUARRY FINES & MITIGATION PRACTICES
Table 5: Summary of active aggregate quarries in the UK (BGS, 2003)
Agriculture (inc. fishing)
Mining and Quarrying
Sewage sludge
Dredged materials
Household
Commercial
Industrial
Construction and Demolition
<1
21
<1
5
9
12
13
32
Total = 335 million tonnes
Source: Defra, ODPM, Environment Agency, Water UK
Figure 3: Estimated total UK annual waste arisings by sector: 2004, U.K (DEFRA, 2007c)
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Ratios of waste to product are used to estimate arisings of mineral waste by DEFRA. Quarry waste is
estimated using a waste to saleable product ratio equal to 1 to 9, that is one tonne of quarry waste is
generated for every nine tonnes of quarry products The overall trend shows a decrease in waste arisings,
which reflects the decline in production. There are many uncertainties associated with such published
statistics of mine and quarry waste, such as the consistency and reliability of the employed ratios.
According to the British Geological Survey research, the data in Table 6 and Figure 4, are only estimates
derived from an assumed ratio of waste to mineral that may be considerably different to the actual amounts.
The term ‘waste’ does not provide any indication of the nature of the material, any potential hazard to
the environment or appropriate utilisation routes, and whether part of this material is already in use.
Also, material generated at one site where it is regarded as waste, may be saleable at another because of
proximity to a potential market (BGS, 2003). Research undertaken by Arup on behalf of Office of the Deputy
Prime Minister (OPDM – now the Department for Communities and Local Government – DCLG) on land
for mineral workings in England, investigated the areas of land permitted for the disposal of mine waste.
However, this work makes no reference to the type or amount of waste permitted to disposed of in specific
areas (Arup, 2000).
Currently, the most definite source of information on mineral workings is considered to be the BGS BritPits
database, which holds information for the majority of mineral sites in the UK (active, inactive, closed, and
abandoned sites) (BGS, 2003; BGS, 2007). However, information on the quantities of mineral waste is limited
except for materials on which extended research has been undertaken, such as china clay and slate (BGS,
2003; BGS, 2007; Smith, 2005). The reasons behind the limited data are (BGS, 2003; Mitchell, 2007a; University
of Leeds, 2007c):
n The statistical and planning community has shown small interest due to no direct commercial value of
such materials
n Commercial sensitivity issues
n Having mine and quarry waste classed as non-controlled waste
160,000
140,000
120,000
100,000
80,000
60,000
40,000
20,000
0
1990 1991 1992 1993 1994 1995 1996 1997 1998 1999 2000 2001 2002 2003 2004
Source: UK Minerals Year Book, BGS
Tonn
es (
000s
)
Figure 4: Estimated total quantities of mining and quarrying by-products in the UK (1990 – 2004) (BGS, 2007)
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n Historically there has been no need to make estimates and the associated time and costs have meant data
were not collected
UK Category Waste arisings (Thousand tonnes) (1), (8)
1990 1991 1992 1993 1994 1995 1996 1997 1998 1999 2000 2001 2002 2003
2 Colliery(2) 36,450 36,679 32,900 25,229 15,927 17,575 16,112 15,141 12,543 10,444 8,594 8,674 8,196 7,818
3 Coal(3) 9,932 10,423 9,347 8,871 8,559 8,944 9,292 9,107 8,094 8,095 7,005 7,292 6,799 6,300
4 China Clay(4) 27,339 26,205 22,526 22,156 22,778 23,283 20,537 26,648 21,608 20,738 21,388 19,839 19,469 18,875
5 Clay5) 19,756 16,335 15,172 13,799 15,174 16,725 14,507 13,791 14,110 13,560 13,096 12,352 12,114 12,041
6 Slate(6) 7,180 7,200 6,520 9,240 8,040 5,500 8,180 6,940 9,000 7,220 9,580 11,020 14,840 18,000
7 Quarrying(7) 42,413 40,403 38,525 39,464 42,115 40,769 39,039 37,541 35,434 36,530 36,223 36,897 34,190 33,849
TOTAL 143,069 137,244 124,990 118,759 112,593 112,795 107,666 109,167 100,788 96,586 95,886 96,073 95,608 96,8821 Estimates are based on the production data in that year’s UK Minerals Year Book, published by British Geological Survey
2 Colliery waste estimate is based on deep-mined coal assuming a ratio of waste to saleable product of 1:2
Coal waste is based on opencast and other coal production and is also based on a 1:2 ratio.
China clay waste is estimated on the ratio of waste to saleable product of 9:1
Clay waste is estimated on the ratio of waste to saleable product of 9:1
Slate waste is estimated on the ratio of waste to saleable product of 20:1
Quarrying waste is estimated on the ratio of waste to saleable product of 1:9
Figures are provisional
In an industry scoping exercise relevant to quarry fines minimisation, responses collected from interviews
held with the quarry sector have showed that estimates on fines production at individual crushing stages
could be technically feasible (Mitchell, 2007a) (project code: MA 4/5/003). Research carried out to estimate
the generation of fines according to rock type indicated that (Manning, 2004) (project code MA 2/4/003):
n Limestone/ dolomite/ chalk quarrying generates around 20-25% fines
n Sandstone/gritstone quarries produce up to 35% fines
n Fines from sand and gravel pits vary enormously, but production percentages fall within 5 to 15%
n Igneous rocks produce between 10 to 30% fines
According to a survey on aggregate minerals for England and Wales, the total sales of primary aggregates
for 2005 was 172.7 Mt, the total sales of crushed rock for aggregate use was 100 Mt, and the total sand
and gravel sales was 72.6 Mt (DCLG, 2007). According to National Statistics figures for mineral extraction
in Great Britain, for 2006, the total extractor’s sales for the rock types shown in Table 7 are 222.5 Mt
(National Statistics Online, 2007). Taking into account the percentage estimates for quarry fines as reported
above, approximate figures for the fines production are presented in Table 7. Table 8 provides some further
information for the characteristics of quarry production residues and associated primary aggregates.
Table 6: Minerals waste arisings 1990-2003 (DEFRA, 2007e)
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Quarry operation Typical % of quarry fines (average values)
Total sales for aggregate use (Mt) Estimated fines production (Mt)*
(in England and Wales)
(in Great Britain) (in England and Wales)
(in Great Britain)
Sandstone 30% 10.8 11.8 3.2 3.54Limestone 20% 66.9 82.6 13.4 16.52Igneous and metamorphic rock
20% 22.4 47.9 4.5 9.58
Sand and gravel 10% 72.6 80.2 7.3 8.2Total - 172.7 222.5 28.4 37.84* This estimate is for total fines production, which includes material sustainably consumed in aggregate applications. It does not imply that all the fines are excess to market demand
Estimated tonnages of fines have declined due to the reduced production of primary aggregates between
2001 and 2005. Research work has reported an estimate of 41.3 Mt that corresponded to 238 Mt of
produced aggregates (based on the ‘Collation of the results of the 2001 Aggregate Minerals Survey of England
and Wales) (Manning, 2004) (project code MA 2/4/003). The data in Table 7 estimates the quantities of quarry
fines produced. Nevertheless, it should not be forgotten that this is estimated values and not actual data.
Real data may not match the calculated data, because parameters such as the composition and physical
characteristics of primary rocks and production residues, the processing routes and the end use potential of
quarry fines may vary for different sites.
Aggregate type Primary rock characteristics Production residues characteristics Comments Sand and gravel Composition: mainly quartz; other
types of co-existing rock such as quartzite, sandstone, flint, igneous (granitic) rock
Particle size:
0.0625 mm<sand<4 mm
4 mm<gravel<64 mm
Deposits: superficial, bedrock
Superficial deposits
Composition: mainly clay and silt;
inert or non-hazardous; considerable variation in production rates from a few percent up to 30% of total mined material; storage: in lagoons
Bedrock deposits
Composition: cobbles quartzites, igneous rocks, clay, silt
Possibility of radioactive minerals [low hazard] in fine tailings in some quarries (areas near granite)
Limestone Composition: limestoneà calcite (CaCO3); dolomite/dolomitic limestoneà 10-50% dolomite (CaMg(CO3)2, calcite
Particle size: various sizes following end product requirements, normally <10cm
Composition: similar to rock, but with higher quantities of chert and clay; some streams may also contain small amounts of vein materials such as galena, sphalerite, pyrite, barite;
variable quantities depending on the local topography and geology; non-hazardous
Possibility of included vein minerals
Igneous and metamorphic rock
Extrusive bodies are of variable quality; -Intrusive bodies are of variable size; Particle size: depending on end use, normally < 10cm
-rock types: granite, diorite, olivine dolerite and so on
Large variation in sizeà very large oversize blocks and very fine undersize particles; inert / non-hazardous
Possibility of radioactive [low hazard] and asbestiform minerals in fine tailings
Sandstone Wide range of sandstone types/ deposits; Particle size: depending on end use, normally < 10cm
inert material Potential host for uranium ore deposits
Table 7: Estimates of quarry fine production based on total sales figures for aggregate use in England and Wales (data for limestone also include data for dolomite and chalk)
Table 8: Characteristics of primary aggregates and associated (BGS, 2003)
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The lack of actual data for mineral waste is seen as an obstacle to utilisation. Taking as example recycled
aggregates (that is, from construction, demolition and excavation waste), extensive surveys have been
undertaken to determine exact arisings and availability. This is a very critical step towards their use, as
knowing the volume, nature, geographical proximity and availability of materials can assist the identification of
fit-for-use end markets and applications.
A detailed feasibility study modelling the sustainable use of resources for the production of aggregates was
undertaken for the West Midlands. This project investigated the supply of aggregates from primary, secondary
and recycled sources including fines from crushed rock and sand and gravel quarries. This work developed
an economic model that projects the potential sustainable resources for aggregate supply relative to
construction demand, market price and resource availability (WRAP, 2006). The outcomes of this study are
presented in more detail in Figure 5. Such feasibility studies are considered highly important for identifying
benefits and obstacles to utilisation in a local/regional level and promoting the sustainable use of aggregates
by balancing the use of recycled, secondary and primary materials. A similar study has been undertaken for
Scotland (WRAP, 2007).
Software tools and the principles of Mass Balance could assist to evaluate with greater accuracy the
generation of quarry fines. Earlier research work has developed software to assist the planning and evaluation
of aggregate resources according to fit-for purpose end uses. Such techniques could be employed even
during early stages (that is, during exploration). The techniques use the principles of resource management
and waste minimisation. Also software packages, such as the JK Simmet mineral processing simulator (JKTech,
2007), could assist to predict the generation of quarry fines. Mass balance has already found applications for
various resources (for example, tyres, packaging, glass etc), but has not been extensively used for the mineral
sector. A study undertaken on mineral resource availability and efficiency for the North-West region of
England found out that (4sight, 2007):
n There is a high demand for minerals in the North West. The North West is a major producer of minerals
and aggregates, but also the biggest net importer of aggregates in the UK
n Very little is known of the full environmental costs of mineral flows and information related to mineral
resources flows are not of sufficient detail and consistency
n Tracking minerals from exploitation through to end use and final disposal provides important information
about a system’s efficiency, resource availability and management at the regional level.
The use of any of the above tools would require the co-operation of the quarrying sector as the accuracy of
results from studies using such research techniques would be dependent on provided data.
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Feasibility case study – Sustainable resourcing of aggregate supply
Scope of project: Development of an economic model that projects the potential sustainable resourcing
of aggregate supply relative to construction demand, market price and resource availability
Case study location: West Midlands
Resource and product groupings: primary (crushed rock, sand and gravel, dust (residual), scalpings
(residual)); secondary (IBA, PFA, FBA, glass, used foundry sand); recycled (C&D waste, excavation waste)
Key variables identified: supply, costs, market price, and demand
Results – Shifts in resource use predicted for period 2004-2016
Crushed rock:
n Recycled aggregates will be used increasingly for subbase and higher value graded aggregates (including
concrete and asphalt) resulting to a significant market lose for crushed rock products.
n The production of low grade fills and scalpings will have to be increased to meet market demand and
this will require changes to the output profile of crushed rock quarries. This increase is due to the shift of
recycled aggregates to higher value products. The production of scalpings may remain uncompetitive due
to distance from market.
n Changes in production sales profile of crushed rock quarries will lead to a reduction in average selling
price and potentially increase the production of crushed rock fines above market demand.
Sand and gravel:
n Recycled aggregates use will shift to higher value graded aggregates therefore sand and gravel
producers will lose market share (market share falls from 19% to 15%)
Scalpings:
n These are used as fills to replace the demand previously met by recycled aggregates
Surplus fines:
n Stocks continue to rise. The costs of processing the material to a fine aggregate for concrete (according
to the model) are uneconomic.
Sensitivity analysis:
n Removal of the aggregate levy and equivalent reduction in the market place did not affect the market
of crushed rock products. This is due to the cost effectiveness of recycling in West Midlands and the
proximity of sources of recycled materials to sources of aggregate demand and the relative distance of
primary resources.
Other results:
n Investment in washing plants for the processing of crushed rock fines and scalping may be needed. Also
there is a need to develop processes that minimise the production of dust.
Figure 5: Feasibility case study on the sustainable use of resources for the production of aggregates in West Midlands (WRAP, 2006)
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3.2 MINIMISING THE GENERATION OF QUARRY FINES
The minimisation of quarry fines is perceived as essential in order to achieve resource efficiency,
environmental protection and optimisation of the quarrying process. There is a need to minimise quarry
fines for compliance with current legislation and the planning process. Environmental protection and social
responsibility is of vital importance to the quarrying sector to reduce any adverse consequences (for
example, in health and safety) and costs associated with the production of quarry fines (for example, storage,
dealing with arisings transport, and handling).
The minimisation of quarry fines could be achieved by carefully designing the quarrying process even
during the early stages of exploration. Research projects carried out at Leicester University focused on
minimising the inaccuracies associated with resource evaluation through statistical analysis and by exploring
drilling techniques (Jeffrey et al, 2004) (project code: MA 3/2/002). A second project looked at developing
a tool that could be used to identify the parts of a deposit that can produce good quality products with
least waste, and thus to optimise extraction. This tool used the techniques of image analysis together with
software development (Jeffrey et al, 2003a; Jeffrey et al, 2003b) (project code: MA 3/2/001; MA 4/02/002).
The generation of quarry fines is due to extraction and processing operations in a quarry. As discussed in
Section 2.2.1, there are several parameters that influence the production of fines, which are relevant to
the rock characteristics and the involved processes. However, careful design and optimisation of extraction
and processing could minimise fines production. A good practice guide mainly focusing on comminution is
presented in the “goodquarry” website and in Table 9 (The University of Leeds, 2007c).
Modelling tools can assist the quick performance evaluation of quarry operations. Research projects, part
of the MIST programme, have undertaken work using process flowsheet simulators, such as the JKSimMet
(JKtech, 2007) and Bruno (Metso minerals, 2007) and they have produced several case studies for sand and
gravel (Figure 6) and crushed rock quarries ( University of Nottingham, 2003; University of Nottingham,
2005; Mitchell, 2007a; University of Leeds, 2007) (project code: MA 2/3/007; MA 4/1/002; MA 4/5/003) . The
benefit in using such tools is that changes to equipment settings (crushers, screens), material flow rates or
alternative circuit configurations (such as replacing a cone crusher with an impact crusher) can take place
through the software, and the subsequent changes in the throughput tonnage figures and product grading
can be explored. The constructed model (depending on software package) can be calibrated to take into
account the physical and breakage characteristics of the rock and it may also be possible to understand and
monitor the performance of equipment. Modelling can be seen as an inexpensive way to achieve optimisation
in processing operations and models can be produced using either theoretical or real data. The reliability of
constructed models is closely related to the accuracy of data input. Therefore, process audits combined with
mass balance studies are considered essential in collecting appropriate data. The use of software tools could
assist to optimise plant processing routes with the scope to minimise the production of quarry fines, but in
order to validate such studies, results should be accompanied by pilot or full scale trials. Case studies (such
as the example given in Figure 6) demonstrate that it is possible to reduce the production of quarry fines,
nevertheless costs associated with modifications to flowsheets may not necessarily balance the benefits seen
from reduced quantities of fines. However, feasibility studies could provide the detailed information needed
to decide whether a modified processing route is viable.
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Sandstone Quarry – Mid Wales – Three stage crushing circuit
Conclusions:n Process change: replacement of a horizontal shaft impact (HIS) crusher with a cone crushern Product: 0/20 aggregate has been increased from 250 to 300 tph from the same feed rateè 20% increase in productionn Fines: the proportion of fines has been decreased from 38% to 30% è 21% decrease in fines production
Cone CrushersSetting 14mmFeed / output 79 tph
Horizontal Shaft Imapct CrusherFeed / output 250 tphTip speed 45 m/s35mm setting
Jaw CrusherFeed 226 tphSetting 125mm
Screens 40 / 20 mmFeed / output 329 tphOutput12 tph +40mm67 tph +20mm250 tph -20mm
Screen 105mmFeed 400 tphUndersize174tph
Feed700mm medium Sandstone
Aggregate Product0/20 250tph 100%
0/20 Aggregate
Process FlowsheetOriginal process circuit
Cone CrushersSetting 14mmFeed / output 167 tph
Cone CrusherFeed / output 300 tph35mm setting
Jaw CrusherFeed 226 tphSetting 125mm
Screens 40 / 20 mmFeed / output 467 tphOutput45 tph +40mm122 tph +20mm300 tph -20mm
Screen 105mmFeed 400 tphUndersize174tph
Feed700mm medium Gritstone
Aggregate Product0/20 300tph 100%
0/20 Aggregate
Process FlowsheetModified process circuit
11
Figure 6: Case study example using the Bruno mineral processing simulator (Mitchell and Benn, 2007; The University of Leeds, 2007b; Metso minerals, 2007)
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Quarry fines are produced from various activities, but the stages of blasting and comminution are considered
the most liable to generate such fines. The amount of dust produced during blasting is estimated to be as high
as 20% (The University of Leeds, 2007c). Investigation into the quarry fines generated at various crushing
stages was carried out and some of the results are presented together with good practice suggestions,
in Table 9 (The University of Leeds, 2007c). Research undertaken by BGS identified that the quarrying
sector would consider using new technologies which reduce fines production if they were economically
viable and that further research work is required in identifying the capital and operational costs associated
with quarry fines (Mitchell, 2007a) (project cost: MA 4/5/003). When trying to optimise comminution
circuits, all parameters of influence should be taken into consideration including the physical properties
and characteristics of the rock, the mechanisms involved in various processes and operational parameters
(Petavratzi, 2006). Knowledge gained from comminution research (Evertsson, 2000; Bengtsson and Evertsson,
2006; Svedensten and Evertsson, 2005; Napier-Munn et al, 1996) should be used by quarry operators to
optimise the performance of their equipment and to achieve lower quantities of quarry fines.
The generation of quarry fines may cause adverse impacts on the environment (such as the local air, land,
water, flora and fauna) and human health, and the mitigation of potential impacts is mandatory. Commonly,
various dust control practices (conventional or alternative) are employed to minimise the impact of dust
generated by quarry activities (Petavratzi et al, 2005; Petavratzi, 2006; EIPPCB, 2006). Health issues and the
protection of fauna and flora are addressed through the management and protection of air quality. Fines
produced from sand and gravel operations are commonly separated from the wanted fraction in washing
plants and silt/clays are stored in lagoons. Although this process avoids the production of dust, it results in
water consumption. Research has investigated the waterless removal of fines (Mitchell, 2007b) (project code:
MA 4/5/002) as a different approach in reducing water consumption, and this is reviewed elsewhere (The
University of Leeds, 2007a). Quarry fines are often stored in stockpiles prior to use within the quarry or in
other end applications. A substantial quantity of quarry fines are replaced in the void created during aggregate
production, once activities in a specific quarry have been terminated.
In accordance with the Best Available Techniques document on the Management of tailings and waste
rock, good management of waste rock can be achieved by minimising its volume in the first place and by
maximising opportunities for the alternative use of production residues (EIPPCB, 2004). The generation
and minimisation of quarry fines is investigated in more detail by sub-theme ‘Optimising the Efficiency of
Aggregate Production’. The following Sections of this report focus on utilisation opportunities available for
quarry fines.
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Production stage
Rock type Proportion of fines in the crusher product (weight %)
Good practice
Primary crushing
Igneous and metamorphic
3 - 6% (j)1 to 10 - 15% (g) Changes at the closed side setting (CSS) of jaw crushers (optimising the CSS) or the feed system (such as replace choke system with non-choke system) may reduce fines.
Overall, small quantities are produced (<5%) and any changes may have little effect on the total arisings of quarry fines.
Limestone 6 - 7% (j) to 20% (hm)
Sandstone 1 - 2% (j) to 15 - 20% (j, g)
Secondary crushing
Igneous and metamorphic
0 - 23% (c) During secondary and tertiary crushing higher quantities of quarry fines are produced and minimisation of them will have an effect on overall fines production.
Pre-screening of the feed can remove a substantial proportion of fines, avoid packing of material in the chamber and introduce a more uniform feed distribution to the crusher.
Optimisation of the closed side settings of crushers may reduce fine material.
The rotor speed of impact crushers is directly proportional to the production of fines. Slower rotor speeds may reduce the amount of fines produced.
Limestone 15 - 25% (c) to 30% (hm)
Sandstone 10 - 15% (c)
Tertiary crushing
Igneous and metamorphic
5 - 30% (c) to 40% (hm)
Limestone < 20% to 40% (hm)4
Sandstone ~15% (c) to 40% (hm)
(j) refers to jaw crushers (g) refers to gyratory crushers(c) refers to cone crushers(hm) refers to hammermill/impact crusherTable 9: Estimation of quarry fines produced during crushing (The University of Leeds, 2007c)
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The utilisation of quarry fines is seen as a way to minimise the accumulation of unwanted material and at the
same time to maximise resource use and efficiency. As discussed in Section 2.2, utilisation opportunities for
quarry fines are identified by the end user, when fit-for-purpose criteria become available that allows their
use. Various utilisation prospects exist for quarry fines, which can broadly be classified into unbound and
bound applications. Both categories of end uses may require some degree of processing of the quarry fines
to be undertaken in order to comply with technical specifications. End uses falling within any of the above
categories are presented in detail in the following Sections. End applications may be of high or low value, or
may require a small or a large volume of quarry fines. Where applicable, the above issues are discussed. Figure
7 illustrates the applications reviewed in this report. Some quarry fines may already be used in some of the
discussed uses shown in Figure 7 or they may be future utilisation opportunities. Again, these parameters are
discussed where appropriate.
4 UTILISATION OPPORTUNITIES FOR QUARRY FINES
soil remineralisation, compost, artificial soils, remediation
site restoration, landscaping
road pavements
embankment construction
landfill capping
filler applications
manufactured sand
cement making
green roofs
straw and clay blocks
concrete
hydraulically bound mixtures
manufactured aggregates
ceramic products
asphalt pavement, bituminous blocks
synthetic rock
kerbs
fibre reinforced pre-cast units
grout products
Applications
Unbound Bound
Figure 7: Current and potential unbound and bound applications for quarry fines
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4.1 THE USE OF QUARRY FINES IN UNBOUND APPLICATIONS
Quarry fines may find use in several unbound applications as substitutes of primary aggregates, for example,
in unbound aggregate mixtures, such as subbases and cappings. Technical specifications for aggregates are set
by standards, for example BS EN 13242 for unbound mixtures (BSI, 2002b), with the supporting National
Guidance given in PD 6682-6 (BSI, 2003f). A summary of the content of the European standard and National
Guidance document is given by the Quarry Products Association (QPA, 2004).
Specifications for unbound mixtures products and the specifications describing unbound mixtures of
aggregates are found in European Standard BS EN 13285. In the UK BS EN 13285, applies to granular sub
bases and cappings. The aggregates in unbound mixtures must conform to the requirements of the BS EN
13242 for:
n Crushed, broken and totally rounded particlesn Resistance to fragmentation n Magnesium sulfate soundness
A summary of BS EN 13285 is found elsewhere (QPA, 2004).
4.1.1 BULK FILLING APPLICATIONS
Quarry fines are commonly used in reclamation of mineral workings, both alongside the development of
quarrying activities and during closure. Reclamation can be an economically viable use for quarry fines,
because the material is used on site instead of being transported to a different location/end user (Manning,
2004) (project code MA 2/4/003). Reclamation plans are controlled by the permission granted to a quarry
site. (DCLG, 2006b).
Backfilling or infilling of voids is applied in surface and underground mineral workings, although there are
cases where void filling is unnecessary (DCLG, 2006b). For instance, the extraction of sand and gravel
deposits frequently means that the workings extend beneath the water table. In these cases partial filling and
landscaping can convert such sites into recreational areas (Bell, 2007). Infilling voids may use various materials
such as quarry fines, overburden material, tailings, slurries from lagoons, and inert waste. The physical and
chemical properties, the bulking and settlement characteristics, and the compaction and stability of the fill are
of great importance in backfilling or infilling activities (DCLG, 2006b). The use of quarry residues in quarry
filling void applications is classified as high volume and low value. Often a flowable fill is required for irregular,
non-uniform voids and a case study demonstrating the use of quarry fines in infill grouts is given in Section
4.2 (bound applications). Sometimes quarry fines are used for landscaping purposes within the quarry, while
this is still in operation.
Quarry fines may also find use in general fill applications such as embankments, which are considered as
low value, but again they may require large quantities of materials. Currently several other alternative and
secondary materials are utilised in similar ways; therefore, quarry fines will have to compete in the same
markets as these materials, and with primary aggregates. Whether quarry fines are used in general fill
applications will be determined primarily by the cost of transport. Where demand for such uses exists in
close proximity to quarries, then quarry fines could easily satisfy this demand.
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Research work investigated the use of sandstone quarry sand in engineering fill applications and confirmed
its suitability. The research also identified that moisture susceptibility and frost heave would prevent its use in
unbound subbase applications, unless processing removed or diluted the filler fraction (Lamb, 2005).
The performance of recycled materials including building debris, crushed concrete, and quarry fines as
replacement for traditional materials (that is, primary aggregates), used as fine aggregate, was investigated
by researchers (Touahamia et al, 2002). The shear strength characteristics of recycled materials and quarry
fines were examined with, and without, reinforcement. Results suggested that recycled materials have lower
shear strength values, but the presence of geosynthetic reinforcement in recycled materials and quarry fines
increased the shearing resistance of materials (Touahamia et al, 2002).
Overall, unprocessed quarry fines (Type 1 group materials as classified in Table 1) can be used as bulk fill
in trenches, for backfilling underground caverns, in embankments, in landfill construction (that is, landfill
capping), in offshore “reef bag” construction and other general filling applications (Ghataora et al, 2004).
Several other examples from research papers are found in an earlier report on the Exploitation and Use of
Quarry Fines (Manning, 2004) (project code MA 2/4/003).
The geotechnical criteria that specify material suitable for use as fill are described in the European Standard
BS EN 1997-1 (BSI, 2004a) and a summary is shown in Table 10.
Principle requirements to be considered Applications
n good material handling properties
n adequate engineering properties
n transport/storage requirements
fills beneath foundation and ground slabs
backfill to excavations and retaining structures
general landfill including hydraulic fill, landscape mounds and spoil heaps
embankments for small dams and infrastructureCriteria Fill propertiesStrength; stiffness; durability; permeability Grading; resistance to crushing; compactibility; permeability; plasticity;
organic content; chemical aggression; pollution effects; solubility; susceptibility to volume changes (swelling clays and collapsible materials); low temperature and frost susceptibility; resistance to weathering; effect of excavation, transportation and placement; possibility of cementation occurring after placement (for example,. blast furnace slags).
4.1.2 ROAD PAVEMENT CONSTRUCTION
The Specification for Highway Works allows the use of a range of reclaimed materials including quarry fines
on a site (where construction occurs) specific basis (Highways Agency, 2007a). Series 600 on Earthworks set
the specifications for bulk fill materials which find application either as a general granular fill or/and general
cohesive fill (Highways Agency, 2007a). These specifications set detailed criteria for unacceptable materials,
which are determined by their potential hazardous nature and adverse physical properties (such as, grading,
moisture content, plasticity etc). Also Series 600 puts the requirements for materials used as capping on
their own or as part of a mixture. Table 11 provides a summary of material properties requirements as set in
Series 600. Series 800 sets the specifications for unbound mixtures for subbases, which have to conform to
BS EN 13285 (BSI, 2003a) and the properties of aggregates must comply with BS EN 13242 (BSI, 2002b). For
Type 1 Unbound mixtures only up to 10% by mass of fines below 4 mm is permitted.
Table 10: Geotechnical requirements for materials used in fill applications (BSI, 2004a)
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Previous research has investigated the use of quarry fines in road construction (Hills et al, 2001; Touahamia et
al, 2002; Lamb, 2005; Rockliff, 1996; Rezende et al, 2002). Research undertaken by TRL explored the suitability
of unbound sandstone quarry sand (SQS) in a 20 metres cycle path as well as the use of SQS underlain with
scalpings. The unbound section performed well and showed no signs of deteriorations during the research.
The section that combined the scalpings with the SQS performed well initially, but after a period a noticeable
channel appeared that highlighted the potential for a large volume of water to washout any unbound material
(Lamb, 2005). Other research investigated the use of alternative materials including quarry production
residues in road construction and bulk fill (Hill et al, 2001). This work stated that it is more appropriate to
simulate in situ loading (physical and environmental). Results suggested that the mechanical properties of
alternative materials using performance based specifications are equally good to conventional materials and
they could potentially be used as bulk fill (Hill et al, 2001).
Another project investigated the use of quarry waste for the construction of low-volume roads. The test
material consisted of 65.9% (by mass) of gravel, 12% (by mass) of sand and 22.1% (by mass) of silt and clay.
The material was considered suitable to replace natural primary aggregates without incurring significant
structural weakness. However, field studies suggested that the performance of this material is dependent of
its moisture content, which is affected significantly during rainy periods (Rezende, 2003).
Material description Critical material properties In accordance with (BSI, 1990)
Granular material as general fill • grading• uniformity coefficient• moisture content• moisture condition value
BS 1377-part 2
BS 1377-part 2Cohesive material as general fill • grading
• plastic limit• moisture content• moisture condition value• undrained shear strength of remoulded material
BS 1377-part 2
BS 1377-part 2
BS 1377-part 2
Granular material as capping (fine grained ) • grading• optimum moisture content• moisture content• Los Angeles coefficient
BS 1377-part 2
BS 1377-part 4
BS 1377-part 2Granular material as capping (fine grained) – Unbound mixtures
Complying with BS EN 13285 and BS EN 13242
4.1.3 SOIL ENHANCEMENT
Quarry fines are considered a valuable additive to soils which may help to improve its quality by providing
essential nutrients to plants (for example, iron, potassium, magnesium). Quarry production residues will tend
to vary according to the source they are derived from. A summary of the benefits that may be seen from the
use of quarry fines in soils is presented in Table 12 (Szmidt and Ferguson, 2004).
Table 11: A summary of Series 600 – Technical specifications for bulk fill materials in MCHW 1 (Highways Agency, 2007a)
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BenefitsEnhanced soil fertility and diverse soil biologyMulti-season effectsEnhanced plant establishment, growth and vigourEnhancement of flavour, aroma and shelf-life of produceHigh dry matter content, drought resistance, nutritional value and some plant disease resistance of plants
In compost, increases in process performance with integrated resource use andCarbon sequestration by calcium and magnesium carbonate formation, microfloral accumulation and C-accumulation as soil and crop biomass
The use of quarry fines for remediation and soil improvement has been addressed by previous research
(Madeley, 1999; Szmidt and Ferguson, 2004; Remineralize the Earth – online magazine, 2007). Quarry fines
and dust may be used to enhance plant growth. Several projects have been undertaken (UK and overseas),
which explored the use of a variety of crops with quarry fines containing soils such as brassicas with basalt/
glacial silt (Szmidt, 1998; Szmidt, 2004), soybean with sand and gravel fines (Angeles et al, 1997), acacia with
granite fines (Oldfield, 1998) and other (Szmidt and Ferguson, 2004). Results varied for different trials and
under some circumstances they were positive, whereas in other cases no significant changes were recorded
(Szmidt and Ferguson, 2004; Remineralize the Earth-online magazine, 2007). Overall however the use of a
suitable combination of crops with quarry fines can enhance plant growth.
There is evidence that the use of quarry fines in soils may enhance crop value as well as animal and
human nutrition. Plants grown in quarry dust – amended soils have higher levels of essential elements and
nutritional values when compared to those produced by conventional agriculture. Recent research has
identified that the nutrition content of fruits and vegetables has been dropping since initial records were
taken (Szmidt and Ferguson, 2004; Remineralize the Earth-online magazine, 2007). Hence, finding ways to
achieve soil remineralisation and nutrition content increase is considered critical. Another benefit seen from
incorporating quarry fines in soils is that this action may have a positive effect on carbon cycling, but further
research is required however to demonstrate this (Szmidt and Ferguson, 2004; Remineralize the Earth-online
magazine, 2007).
4.1.4 COMPOSTING
Quarry fines may also find application in composting. Research in this area has been less active and only
a few trials have been undertaken. Results from some trials have not shown any clear benefits from the
incorporation of quarry fines in compost. In another occasion, work at Glasgow University (Graham, 2001)
and the Scottish Agricultural College (SAC) (Szmidt, 2004) has determined small but significant increases
in compost temperature at relatively high rates of quarry fines (20 kg/m3). Also ammonia production from
compost was lower in the presence of quarry fines suggesting a lower odour potential (Szmidt and Ferguson,
2004).
Table 12: Benefits seen from the use of quarry fines in soil (Szmidt and Ferguson, 2004)
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In the UK, some extensive work, funded through the MIST project investigated the use of basaltic quarry
fines with organic process residues for the development of growing media. Various combinations of quarry
fines and compost were trialled and grass and tomato plant pot experiments were set up to assess the
performance of different blends. Field trials, at a local quarry were also set up. The main parameters
investigated were plants’ growth, the leachability of nutrients and potential contaminants, and physical
properties (such as, infiltration, water holding capacity, and shear strength) of blends tested in lysimeters.
Results suggested that most quarry fines interact positively with compost and vice-versa to allow
development of novel growing media suitable for horticultural and land restoration uses. However, further
research work is required to understand and assess the influence of quarry production residues on compost
(Guillou and Davies, 2004) (project code MA 1/3/003).
Specifications for composted materials are set by the Publicly Available Specifications for Composted
Materials (PAS 100, 2005). The BSI PAS 100 covers various key elements related to composting such
as process control, input materials, sanitation, stabilisation, quality requirements, sampling frequency,
classification and others (PAS 100, 2005). However, according to PAS 100 and the compost quality protocol,
quarry production residues are not included in the list of permitted materials (PAS 100, 2005; Environment
Agency et al, 2007). The latter is limited to biodegradable materials only. The deliberate addition of non-
biodegradable materials (for example, basaltic fines) is not allowed. The provision of data that justify the
suitability of quarry fines in the composting process could permit incorporation. This however will have to be
classified on a case by case basis (Szmidt and Ferguson, 2004).
4.1.5 ARTIFICIAL SOILS
Quarry fines may also be used to produce artificial soils. The British Standard BS 3882 (BSI, 1994) specifies
topsoil requirements. According to BS 3882, three grades of topsoil are established, premium, the general
purpose, and economy grade (BSI, 1994). Topsoil is classified to any of the above grades after review of the
following characteristics (BSI, 1994):
n Textural classification
n Maximum stone content
n pH value
n Nutrients content
n Loss on ignition
n Exchangeable sodium percentage
Past research into artificial soils suggests that blending quarry production residues (such as sandstone quarry
sand) with organic material (i.e compost, agricultural waste) might produce an artificial soil (Lamb, 2005;
Keeling et al, 2001; Mitchell et al, 2004). Results determined that the textural classification of premium grade
topsoil can be achieved by using a 70:30 (v/v) blend of the filler fraction (<75 µm) of sandstone quarry sand
or as produced sandstone quarry sand and a suitable organic material. The grading requirements for premium
topsoil are met by the filler fraction, but not from the as produced sandstone quarry sand (Lamb, 2005).
Specific types of quarry fines, such as from limestone quarrying activities may be used to remediate acidic
soils. In a project funded through the MIST programme, limestone quarry fines were used in combination
with steel slag fines and compost to remediate acidic colliery spoil sites. Grass growing trials were
undertaken at various compositions of colliery spoil, limestone dust and steel slag. Results confirmed that
the most appropriate mix will contain 5% of each limestone and compost and 4% of steel slag (Tarmac Ltd
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and Associates, 2007) (project code: MA 4/2/019). Further research is currently undertaken from Birmingham
University in remediated acidic sites using quarry wastes (project code MA 6/4/02) (Birmingham University,
2007).
4.1.6 FILLER APPLICATIONS
Quarry fines may substitute primary materials which are used as fillers in paper, paint, plastics, rubber and
elsewhere. Mineral fillers are used in a wide range of commodities and commonly comprise fine grained
materials (<2 mm). Fillers used in certain end uses must fulfil specific requirements. For instance the
production of photocopier paper and household paints must use fillers with high brightness levels and good
rheological properties. In order to satisfy such demand, primary materials like kaolin, calcium carbonate
or talc are used and sold at a relatively high cost in order to recover total production costs (extraction
and processing). Quarry fines could not comply with the requirements for high value filler applications.
Nevertheless they could be used as general fillers in papermaking (for example, packaging paper), pigments
(for example, marine paint), plastics (for example, glass reinforced plastics), membranes and rubber (tyres,
cable) (MIRO, 2001a; Bonney et al, 2000).
Research investigated the use of mineral residues of calcareous and siliceous composition from aggregate
quarries in end uses such as elastomeric membranes, paints, paper and plastic. The aim of this research was
to develop low cost by-product fillers where product specifications and end use do not demand high-
grade fillers. Siliceous and calcareous quarry fines have been shown to be suitable for use in elastomeric
membranes and a large scale trial was carried out for the calcareous materials.
Trials were undertaken to establish the compatibility of these materials with paints, but results were not
positive. However it was found out that micronised calcareous quarry fines could partially substitute
extenders and produce a reasonable quality of paints. The use of calcareous micronised quarry fines in the
production of glass reinforced plastics was also examined and it was found out that partial substitution of
extenders does not impair the quality of the panels produced. Finally, micronised calcareous quarry fines
could substitute up to 5% wood pulp in paper pulp without influencing the production procedure (MIRO,
2001a; MIRO, 2001b; Bonney et al, 2000).
4.1.7 OTHER APPLICATIONS
Quarry fines could also find use in the production of Portland cement. The cement sector has been active
in trying to utilise such material for the preparation of kiln meal (Petavratzi and Barton, 2007). The cement
making process requires four major constituent oxides to be present, namely CaO, SiO2, Al2O3 and Fe2O3.
Therefore, quarry fines with the above constituents may be applicable for use. Materials used in clinker’s
recipe are blended to specification prior to use and it is anticipated that various other alternative materials
may be found suitable. The production of meals suitable for cement is often undertaken by a secondary
industry sector specialised in blending. Quarry production residues, which present some of the essential
ingredients and low compositional variability, could be used in cement manufacture (Petavratzi and Barton,
2007). Current cement standards (BS EN 197-1) only refer to well established alternative materials (i.e
pulverized fuel ash) commonly used for the production of blended cements (BSI, 2000a). The use of
quarry fines and other alternative materials pre-kiln is relatively new and further research work should be
undertaken to determine its full potential.
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Finally quarry fines might find application in new, innovative products such as green roofs, eco-friendly slates,
cob building, light earth or straw clay, earth bags and earth plasters.
In green roofs, clay, silt and quarry fines could be used in the soil and aggregate mixtures, and scalpings
in the aggregate mixture. The particle size distribution and particle shape of quarry production residues
are considered critical parameters that will determine their utilisation potential. Currently there are no
specifications on green roofs in the UK and the market is limited, although it is anticipated that changes will
be seen in the near future due to active research and development. Further information can be found in
GreenSpec website (GreenSpec, 2007a) and the Green Roof Centre (The Green Roof Centre, 2007).
Eco-friendy slates for roofing are produced by one manufacturer in the UK by resin-bonded recycled plastic
and dolomite/limestone fines. Dolomite or limestone comprises a filler material in this application. By-
product fillers derived from quarry fines might be suitable to this product, but further research should be
undertaken to determine this. (E-C-B-UK, 2007; GreenSpec, 2007b).
Quarry production residues could also be used in earth construction applications. For example, clay, silt and
quarry fines could be used in cob building and straw clay end uses. Again more research work is required to
determine the applicability of quarry fines in earth construction. More information on earth construction can
be found elsewhere (Sustainable Build, 2007).
4.2 THE USE OF QUARRY FINES IN BOUND APPLICATIONS
Quarry fines could be diverted and utilised in various bound applications such as controlled low strength
materials, masonry products, asphalt and asphalt surface treatments, hydraulic bound mixtures and mortar.
Technical standards (British and European) specify the requirements for aggregate materials used in bound
applications. The BS EN 12620 sets the criteria for aggregates to be used in concrete (BSI, 2002a). The
accompanying National Guidance Document PD6682-1 provides information on the application of the
standard to the UK (BSI, 2003g). The product standard BS EN 13043 (BSI, 2002e) and the PD 6682-2 (BSI,
2003e) corresponds to aggregates used for asphalt and surface treatment. The BS EN 13242 (BSI, 2002b)
and the supporting PD 6682-6 sets the specifications for aggregates used in hydraulic bound uses (BSI,
2003f). Finally the BS EN 13139 (BSI, 2002c) and the National Guidance PD 6682-3 (BSI, 2003h) set the
requirements for aggregates used in mortar. The content and relevance of the above technical standards
with quarry production residues is discussed in the following sections together with findings from relevant
research that demonstrate the potential utilisation of quarry fines in bound applications.
4.2.1 CONTROLLED LOW STRENGTH MATERIALS
Controlled low strength materials (CLSM) are defined as self-compacting, low strength, cementitious
materials used primarily as backfill in lieu of compacted fill (ACI, 1999).Controlled low strength material is
characterised by high workability, low density and low strength, which allows for self-compaction. Fly ash,
ground granulated blast furnace slag (GGBS), and waste foundry sand, are commonly found in flowable fill
mixtures (Naik et al., 2003), but non-standard materials such as quarry fines may also be used to produce
CLSM as far as they satisfy the requirements for intended applications.
According to the Federal Highway Administration’s (FHWA’s) Office of Research, Development, and
Technology, quarry residues such as screenings, pond fines and baghouse fines can be used as a filler
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aggregate or as a partial or possibly a complete replacement for the pozzolan component in flowable fill
mixes (TFHRC, 2007). Screenings may substitute sand, whereas pond and baghouse fines could partially or
completely used instead of conventional aggregates. It is anticipated that fines produced from comminution
and screening will not require any additional processing except from some minimal sizing or drying if they
exhibit high moisture content. Pond fines will require some type of dewatering prior to use. Engineering
properties of quarry residues that are of particular importance to quarry fines are gradation, moisture
content and unit weight, whereas properties such as the mix strength, the flowability, the time of set and the
bleeding and shrinkage determine the performance of the controlled low strength material (CLSM) (TFHRC,
2007).
Research investigated the use of fly ash, rice husk ash and quarry dust as potential by-products in controlled
low strength materials. Quarry fines were obtained from a granite quarry and comprised material below 4.75
mm. Trials explored different mixtures such as cement-fly ash-quarry fines, cement-quarry fines and cement-
rice husk-quarry fines (Nataraja and Nalanda, 2007). Engineering properties such as flowability, density,
uniaxial compressive strength, stress-strain behaviour, water absorption and volume change were investigated.
Results suggested that the engineering properties of CLSM can be achieved satisfactorily using a very
small amount of cement and a large amount of quarry fines. When the by-product content was increased,
the water-cement ratio also increased linearly to get a specific flow. Quarry fines could substitute sand in
CLSM. Quarry dust content (<75 µm) as high as 96% by weight, could be mixed with flowable fill without
noticeable segregation and bleeding. The uniaxial compressive strength test results were acceptable and the
stress- strain behaviour results suggested that quarry fines could be used for soil-like material applications in
producing CLSM (Nataraja and Nalanda, 2007).
In another project quarry fines were used as the main constituent of a pumpable infill grout (Tarmac Ltd and
Associates, 2007; Ghataora et al, 2004) (project code: MA 4/2/019). Laboratory trials and modelling studies
were carried out to establish the constituents of potential mixes, and were followed by field trials that
verified the pumping qualities of a selection of mixes (Ghataora et al, 2004). Limestone quarry fines below
4 mm were used in field trials and several mixtures were prepared with different ratios of water-cement-
quarry fines and in one of the trials foaming agent, whereas the effect of pumping aid was also investigated.
Two different field trials were undertaken and both explored the ‘pumpability’ of different mixtures and
the compaction properties. The objective of these trials was to examine the suitability of flowable fills in
underground void filling and back-filling applications. The product expected to be utilised in underground void
filling was required to have free flowing properties, to be able to be pumped long distances, to have a low
strength and to contain a high content of quarry fines. The properties investigated for the material used as
a backfill were the pumpability, 3-day strength, bleed and segregation after placement. Results suggested the
following: (Tarmac Ltd and Associates, 2007) (project code: MA 4/2/019):
n Quarry fines could be pumped by hydro-transport techniques using water only
n Quarry fines could be developed into cementitious pastes and pumped over long distances
n Pastes based on quarry fines can be pumped over long distances without segregating thus providing an
alternative material to pulverized-fuel ash
n Overall the pumpable grouts would be suitable for low value, bulk infill products such as void infill or
reinstatement of utility excavations.
Limestone quarry fines were used in one project as a substitute for natural sand (approximately to 50% by
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mass) for the production of self–compacting concrete (SCC). Fines content (<75 µm) of 10% (by mass) was
included in the limestone quarry fines, which was absent in the natural sand. The substitution reduced the
requirement for chemical admixtures, without affecting the strength of the self-compacting concrete (Naik
et al, 2005). In one research, three types of limestone quarry fines were tested as substitutes for cement.
Results suggested that a 10% replacement of cement with quarry fines produce a self-compacting concrete
with good rheological properties in its fresh state and compressive strengths and drying shrinkage at
hardened state (Felekoglu, 2006). The use of granite quarry fines in self-compacting concrete was investigated
against limestone fines. Granite fines had a finer particle size distribution and higher flakiness index than its
limestone equivalent. Research demonstrated that granite fines could be successfully incorporated into SCC.
When granite fines were compared with limestone particles, then it was concluded that they required a
higher dosage of superplasticiser for similar yield stresses and rheological properties for routine use in SCC.
The consistency of quarry fines overtime may be an issue, and durability issues such as alkali-silica reaction
should be investigated in detail (Ho et al, 2002). Other examples are reviewed by other authors (Manning,
2004) (project code MA 2/4/003).
Geotechnical design and properties are determined by European standards (Eurocode 7) (BSI, 2004a),
whereas the properties of the aggregates used in controlled low strength materials should comply with BS
EN 12620 (BSI, 2002a).
4.2.2 CONSTRUCTION PRODUCTS – MANUFACTURED CONCRETE
The use of quarry fines in concrete is well established, in particular where arisings become available from
local sources (Manning, 2004) (project code MA 2/4/003).
Technical specifications for concrete are given in BS EN 206-1 (BSI, 2000f)( and the complementary British
Standard, BS 8500 (BSI, 2006a; BSI, 2006b) (part 1 and part 2). Other standards which relate to specific end
products exist and some of them are summarised in Table 21 in Appendix IV (Price, 2002; WRAP, 2007c).
Specifications for aggregates used are given in BS EN 12620 (BSI, 2002a). The production of concrete requires
the use of coarse aggregate (>4 mm) and fine aggregate (<4 mm) and in some cases also filler aggregate (<
63 µm). Filler aggregates are obtained by processing natural, recycled or manufactured aggregates. In some
European countries it is common practice to set a minimum fines content and to use fine filler aggregate, as
it may be beneficial in minimizing voids and bleeding in concrete (BSI, 2003g) The “aggregates for concrete”
standard specifies the geometrical, physical and chemical requirements for aggregates and a summary of them
is given in Table 13.
BS EN standard requirement Properties Applicable to/MethodologyGeometrical Aggregate sizes (Sieve apertures)
Grading Coarse and fine aggregateAggregate shape Coarse aggregate (flakiness index)Shell content Coarse aggregateFines content Coarse, fine, filler aggregate (up to 11% for all-in aggregate)
Fines quality Fine/Filler aggregate (Harmfulness that is, clay content) Physical Resistance to fragmentation Los Angeles method
Resistance to wear Coarse aggregatesPolished stone value Coarse aggregateAggregate abrasion value (for highways surfaces uses)Durability Magnesium sulfate soundness test
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Chemical Chlorides Water soluble ion chlorideSulphur rich compounds Acid soluble sulfates and total sulfur Other constituents Constituents that alter setting and hardening of concrete Carbonate content Fine aggregates – concrete pavement surface sources
Technical specifications on the use of aggregates for mortar are set by BS EN 13139 (BSI, 2002c), with the
supporting National Guidance given in PD 6682-3 (BSI, 2003b). Grading requirements place greater emphasis
on ‘consistency of products’ based on ‘typical grading’ figures with controlling tolerances and overall
requirements on designated sieves (QPA, 2007).
Quarry fines may be produced to comply with standards for concrete or mortar, specification. There are
cases when the fines cannot meet the technical requirements, or the local concrete or/and mortar market
cannot absorb the quantities produced, or that even a suitable local market may be absent. Under such
circumstances, quarry fines remain unused. Unfortunately there is little data on the technical suitability
and market availability for quarry fines to be used in concrete or mortar, and the only existing information
comprises anecdotal evidence provided from interviews with the industry (Mitchell, 2007a) (project code:
MA 4/5/003). According to such anecdotal evidence, hard rock and sandstone quarries produce fines as
a result of high demand for 10 mm aggregate. At some hard rock quarries, demand exceeds supply and
aggregate producers re-crush single-size aggregate to create more fines. Sandstone quarry fines produced
from some sites are consumed locally, whereas some other sites have no sales and stockpiles are increasing,
often matching a critical level, which constrains the continuity of quarrying activities (The University of Leeds,
2007a).
Research has investigated the use of quarry fines in various concrete applications. The International Center
for Aggregates Research (ICAR) explored the use of microfines (particles below 75 µm) in concrete.
According to American Standards (ASTM C33) a maximum of 7% (by mass) microfines is allowed in some
applications, when adverse constituents such as clay or shale are absent. Trials were undertaken using 63
samples of fine aggregate from seven different rock types and characterisation included standard tests such
as specific gravity, gradation, absorption, uncompacted void content, as well as less commonly used tests, like
laser diffraction, particle sizing, chemical analysis and the methylene blue method. Tests were conducted on
mortar mixes containing fine aggregate. Findings suggested that manufactured fine aggregate mortars with
high fines content generally had higher flexural strength, improved abrasion resistance, higher unit weight and
lower permeability due to filling of pores with microfines. Compression strength and shrinkage were within
generally acceptable ranges. Manufactured fine aggregate can be produced from a variety of rock types such
as limestone, granite, quartzite, diabase and dolomite. Hence concrete can be manufactured using all of the
aggregate, including microfines from 7 to 18% without the use of admixtures (Ahn and Fowler, 2001).
The use of limestone fines (90% of material passing 300 µm), cumulated from limestone quarrying activities,
was examined by one research project. This work looked at the use of limestone fines combined with
Portland cement (with or without the use of waste glass powder) (Turgut, 2006). Other research looked
at the use of limestone fines with a small quantity of Portland cement was explored for the production
of artificial stone. Cement to limestone dust ratio and compaction pressure, were considered as the two
independent process variables and compressive strength represented the dependent variable (Galetakis
and Raka, 2004a; Galetakis and Raka, 2004b). Experimental work from both projects showed that quarry
dust cement combination can be utilised for the production of moulded masonry blocks with acceptable
Table 13: Requirements for aggregates for concrete according to BS EN 12620 (BSI, 2002a)
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mechanical and physical properties (Turgut, 2006; Galetakis and Raka, 2004a; Galetakis and Raka, 2004b).
Hanson Aggregates manufactures structural concrete in Wales (Craig-yr-Hesg) using 12% unseparated
sandstone quarry fines. The product is being sold as standard C35 strength concrete (35 N/mm2). However
measurements identified that the strength of the final product would be considerably higher than 35 N/mm2
after 28 days. Therefore, it was proposed that, if the filler was to be removed, then much greater proportions
of the coarser grained material could be incorporated into the mix, while retaining the desirable strength
value (Lamb, 2005). Also sandstone quarry sand (SQS)is used in block manufacture, in a mass percentage up
to 10% of 6 mm aggregate to prevent balling and voids. This is common practice for a number of companies
in South Wales (Lamb, 2005).
The filler fraction of the sandstone quarry sand (SQS) was tested as a cement replacement material. Physical
and chemical analysis results determined that this material could be used as a cement substitute, subject to
the end user requirements and material’s availability. The leachate results showed a significant increase in lime,
when SQS was added to mortar, which may cause efflorescence on concrete products. The pozzolanicity
results were positive, but it was found out that this material contains a very high insoluble residue, which
limits its use in cement only as filler. Although overall results were considered positive, it was thought that
further work would be required to determine if additional routine testing requirements were essential for
using SQS in cement. It was also unclear if it would be practical for the quarry to separate the filler from the
SQS and also dry the material prior to inclusion with the cement mix (Lamb, 2005).
The use of silt and clays (SiO2 composition) obtained from crushed granite stone (<150 µm and between
75 and 150 µm) was tested as cement substitutes and it was found out that up to 25% of cement
replacement could be achieved without affecting the durability of concrete, namely parameters such as
strength, workability and impermeability. Silt and clays expressed reactive properties and they could be
used as reactive minerals. Although the inclusion of silt and clay increased the water / cement ratio, it was
thought that the problem could be solved by using high specific surface area material with a superplasticizer
admixture (Chan and Wu, 2000).
The production of concrete for sea defence structures using limestone quarry fines was investigated by
laboratory experimentation undertaken by the University of Birmingham. The aim was to produce concrete
structures for erosion control. The strength of concrete at 28 days was higher than the specified, but the
project did not move forward as economic evaluation showed that this application was not cost effective
(Ghataora et al, 2004).
An analytical literature review is presented in the report “Exploitation and use of quarry fines” and further
literature findings can be reviewed there (Manning, 2004) (project code MA 2/4/003).
4.2.3 CONSTRUCTION PRODUCTS – HEAVY CERAMICS
Heavy ceramics such as bricks, tiles and pipes could absorb some quantities of quarry fines from local
sources, but it is expected that utilisation rates will be much lower than in concrete and controlled low
strength applications. The market for bricks has changed significantly after the introduction of concrete
blocks, as the latter replaced common bricks. This resulted to a shift to producing facing bricks used for
aesthetic purposes (BGS, 2007). Brickworks commonly own clay quarries, which provide the primary raw
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materials. However, other constituents derived from primary, secondary and waste sources are also utilised
in order to satisfy market competition, which requires from companies to produce large portfolios with
different product.
Technical specifications on masonry products, as described in BS EN 771-1, (BSI, 2003i) apply to ceramic
products such as bricks and they set the requirements for a variety of physical properties such as density,
dimensions, thermal properties, compression strength, water absorption and others. ’Fit-for-use‘ criteria
for raw materials are not currently available, because historically brick manufacturers utilised only primary
materials from their own clay quarries and the use of alternative materials has not progressed sufficiently to
require the development of a new set of specifications.
A recent research project looked at the utilisation of various alternative materials in brick making. A
characterisation framework was developed based on end user requirements. The framework aimed to
characterise constituent materials according to their contribution to the end product (Petavratzi and Barton,
2006). The approach and findings of this research is presented in Section 2.2.2 and
Table 4. Depending on the physical (that is, composition) and chemical characteristics (for example, soluble
salts content) of quarry fines, they may be used as filler, clay substitute, colourant, fluxing agent or even
body fuels (Petavratzi and Barton, 2006). Examples of quarry fines that could potentially be suitable for use
in bricks categories are given in Table 20, in Appendix III. According to responses from brick manufacturers,
the inclusion of quarry fines in bricks, in a percentage of 3 to 5% by mass, is possible without affecting the
appearance and properties of end product. Nevertheless the brick sector will only choose to introduce
materials to the process that will provide some clear benefits to the appearance of the end product (for
example, desirable colour) or the manufacturing process (for example, fluxing) (Petavratzi and Barton, 2006).
The incorporation of quarry fines in ceramic products has been explored by several other research projects
and a summary of findings is shown in Table 14. A review of other literature sources can be found elsewhere
(Manning, 2004) (project code MA 2/4/003).
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Project Findings ReferenceAcid resisting bricks from kaolin fine quarry residues, granulated blastfurnace slag (GBFS) and granite-basalt fine quarry residues
The performance and characteristics of these bricks were compared with conventional ones made of clay, feldspar and sand. The study suggested that it is possible to produce acid resistant bricks, which satisfied the technical specifications in place, by using (by mass) 50% kaolin fines, 20% granite-basalt fines and 30% granulated blastfurnace slag at a firing temperature of 1125 oC.
(El-Mahllawy, 2007)
Recovered slate waste in sintered structural tiles manufactured by powder technology
This study examined the characteristics of the raw materials (slate waste), the sintering process, the suitability for processing by powder technology and the final properties of the end product. The obtained results showed that recovered slate waste is a suitable material for use in ceramic tiles, since their properties are within the range of those of conventional ceramic tiles
(Campos et al, 2004)
Slate powder waste in ceramics using the slip casting process
‘Green’ ceramic pieces from slate powder waste have a potential use in the manufacturing of ceramic pieces by the slip casting process.
(Mansur et al, 2006)
Unfired earth bricks (that is, compressed unfired bricks, light unfired bricks, unfired clay bricks)
Although currently there is no clear evidence that demonstrate the use of quarry fines, it is believed that clays and manufactured sand produced as by-products from the extraction of aggregates could find application in unfired bricks.
(GreenSpec, 2007c)
Marble and granite reject to enhance the processing of clay products
Addition of up to 30% (by weight) of non-beneficiated, fine grained and low iron marble and granite reject in red clay based mixture did not alter the properties of the end product and reduced the firing temperature.
(Segadaes et al, 2005)
Granite sawing wastes in ceramic bricks and tiles
Granite wastes have physical and mineralogical characteristics similar to those of conventional ceramic raw materials. The technological characteristics are in agreement with standards for ceramic bricks and tiles. Additions up to 35% (by weight) can be achieved at firing temperatures up to 1200oC.
(Menezes et al, 2005)
4.2.4 CONSTRUCTION PRODUCTS – MANUFACTURED AGGREGATES
The production and use of manufactured aggregates, although limited currently in the UK is expected to
increase in the future due to changes in legislation and government initiatives, such as the work undertaken
by WRAP (The Waste and Resources Action Programme) that promote the specification of good practice
recycled content products (WRAP, 2007d). Manufactured aggregates produced using only quarry fines will
result to dense products and their end applications is considered limited as primary aggregate sources are
readily available at lower cost. However the production of lightweight aggregates is beneficial, because it
could assist to the development of lightweight products and at the same time ‘consume’ waste materials and
by-products that are currently being landfilled.
Technical specifications for lightweight aggregates for concrete are set by BS EN 13055. Part 1 (BSI, 2002d)
together with the National Guidance Document PD 6682-4 (BSI, 2003c). Part 2 of BS EN 13055 specifies
lightweight aggregates for bound and unbound materials (BSI, 2004b) and it is accompanied by the National
Guidance Document PD 6682-5 (BSI, 2005).
Research in this area has been active and several trials and projects have been developed that investigated the
use of quarry fines in the production of manufactured aggregates. The quarrying of ragstone in Kent produces
in excess approximately 200,000 tonnes of poor quality fine grained material and research was conducted
to identify the suitability of this material in the production of manufactured aggregates. In the South-East of
Table 14: Literature findings on the use of quarry fines in heavy ceramic products
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England, only 40% of the aggregate required for construction can be supplied by local sources, which is seen
as a driver towards the use of manufacture aggregates. Quarry fines comprises poorly cemented sandstone
with high fines content (16.5%) and it has not been found to be suitable for use as an engineering material
or as fine aggregate in concrete. Washing the fines could remove the excess fines content and provide
an appropriate concrete aggregate, but the installation of a washing plant is expensive. Quarry fines were
blended with other solid waste products (namely cement kiln dust, ground granulated blastfurnace slag and
pulverized-fuel ash) and were pelletised in a CO2-rich atmosphere. The final products may find potential
use as secondary lightweight aggregates, for structural concrete, concrete block manufacture or highways
application, if proved suitable through compliance with BS EN 13055 (Padfield et al, 2004).
The potential use of quarry fines (<4 mm) combined with recycled plastics for the production of
manufactured aggregates was investigated by research. The ‘Plasmega’ process involved the mixing of
shredded plastic waste and quarry fines at controlled temperatures to produce lightweight aggregates. A
range of different plastics to fines ratios, which varied from 60 to 80% for quarry fines and 20 to 40% for
general plastic waste, were used in these trials. Plastic waste was delivered in bales and consisted primarily of
general waste (variety of plastic). Contaminants such as wood and metals were separated before and during
shredding. Quarry fines consisted of gritstone and limestone, but trial batches were also produced using
steel slag, lagoon silt, sand and china clay waste. Fines were added to the mixer first followed by the shredded
plastics and combined together at a temperature between 250 to 260oC for 6 to 8 minutes. The mix was
fed directly into a briquette plant that produced a 40 mm diameter ovoid, which were subsequently crushed
using a hammer mill. Laboratory tests were carried out to determine the properties of the finished product
and small scale trials were undertaken of the use of ‘Plasmega’ in asphalt, concrete and block manufacture.
Results suggested that from a technical point of view, the process technology appears to be viable and
aggregates of consistent quality can be produced for the 50:50 and 60:40 fines/plastic blends of materials.
Based on the aggregate abrasion value and the magnesium sulphate soundness value, the produced aggregate
is considered a hard and durable material. The polished stone value results especially for the limestone mixes
suggested that the manufactured aggregate may not be suitable for surface course material. Asphalt materials
containing the lightweight aggregate required an extra binder to achieve full coating and to ensure durability
of the material. Overall it was concluded that the ‘Plasmega’ aggregate could potentially be used in asphalt
and unbound applications, but further work should be carried out through full scale trials to determine this.
The fundamental obstacle to the process was considered to be the ready supply of usable waste plastic at
cost appropriate to make the product competitive (Tarmac Ltd and Associates, 2007) (project code: MA
4/2/019).
Lightweight aggregates were produced using marine clay and a CaF2-rich semiconductor industry sludge
using a bench-scale rotary kiln. The scope of this study was to produce an aggregate source in the area of
Singapore, utilising marine clay produced during excavation in construction sites, which is currently treated
as waste. Different clay to sludge ratios were trialled (90/10, 70/30, 50/50 (mass %)). All three mixtures
showed good bloating behaviour during firing and the ceramic pellets (1 – 1.5 cm diameter) had densities
below that required for lightweight aggregates. The water absorption of the aggregates was high due to
large pore size, which could be altered by changing the clay to sludge ratio or the firing conditions. Also
the composition of the aggregate showed a significant loss of fluorine (40-60%) during processing, but
leach testing suggested that aggregates would not pose a human or environmental hazard due to fluorine
mobilization. The aggregates were considered suitable for the manufacture of low strength building blocks
(Laursen et al, 2006). Clay produced from aggregate quarries could also comprise the binder rather than the
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base material in manufactured aggregates. In other work lightweight aggregates were produced using a rotary
kiln by mixing combustion ashes such as pulverized-fuel ash, incinerated sewage sludge ash, municipal solid
waste incinerator bottom ash with a binder such as clay (Wainwright and Cresswell, 2000; Wainwright and
Cresswell, 2001).
Unless energy consumption associated with the production of lightweight aggregates is reduced, the wide use
of such materials is expected to be limited as the competition from alternatives such as primary, secondary
and recycled aggregates is high. A project currently carried out within the Fifth call of the MIST programme
investigates the use of microwave technology to produce lightweight aggregate from quarry wastes, which
may result in energy savings. This project is currently underway and it is expected to establish the technical
and economical feasibility of microwave processing in the manufacture of sustainable construction materials
(The University of Nottingham, 2007) (project code: MA 6/4/006).
4.2.5 HYDRAULICALLY BOUND MIXTURES
Hydraulically bound mixtures (HBMs) comprise a combination of aggregates with binder mixtures that set
and harden in the presence of water. Hydraulically bound mixtures can employ different types of hydraulic
binders and they are therefore classified as Cement Bound Granular Mixtures (CBGM), Slag Bound Mixtures
(SBM) and Fly Ash Bound Mixtures (FABM). Cement bound mixtures commonly use Portland cement,
whereas slag bound mixtures and fly ash bound mixtures utilise granulated blast furnace slag (and depending
on mixture type also include partially ground granulated blast furnace slag and ground granulated blast
furnace slag) and fly ash respectively as the binder phase. Hydraulically bound mixtures find application
in road (major, minor roads) and paving construction (paved areas, heavy duty paving), in shore and slope
protection, flood protection, dams, liners, container embankment structures, river/canal bank protection and
backfill. In pavement construction, HBMs can find application in base, subbase and capping layers. Quarry
fines could be utilised as an aggregate or in the production of alternative binders (for example, in composite
cement), material below 4 mm could find application as fine aggregate in HBMs.
Technical specifications on aggregates for hydraulically bound mixtures are given by BS EN 13242 (BSI,
2002b) and the accompanying National Guidance document PD 6682-6 (BSI, 2003b). The European Standard
sets specific requirements for the geometry, physical, chemical and durability properties of aggregates, a
summary of which is shown in Table 15. The Manual of Contract for Highways Work, Volume 1 and Series 800
(Highways Agency, 2007a) sets the requirements for hydraulically bound materials used in road pavement.
According to Specification for Highway Works, china clay and slate waste is included in the list of alternative
materials that could be used as aggregates, whereas the use of quarry fines may be considered by the
Overseeing Organisation on a site specific basis. Also the Interim Advice Note 73/06 (Highways Agency,
2006) provides guidance on the construction of road pavement foundations and has to be applied during
all road construction, implementation, improvement and maintenance works. The European Standards for
HBMs are divided into two main series, the BS EN 14227 series (BSI, 2004c), which covers specifications for
hydraulically bound mixtures and the BS EN 13286 series which cover test methods for HBM (BSI, 2003d).
The use of sandstone quarry sand (SQS) in cement bound road subbase was investigated. Physical data
suggested that the material would form a good subbase in terms of strength and compaction. The sandstone
quarry sand could comfortably meet the specification for a cement bound subbase (CBM 1). Four different
mixes utilising 50, 75, 100 and 125 kg/m3 cement contents based on a density of 2,200 kg/m3 were prepared
and test cubes were compacted at moisture content of 9% by mass of aggregate. Results suggested that
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blocks displayed a steady increase in compressive strength with cement content. The 4.5 N/mm2 requirement
for CBM1 was satisfied for materials with cement content falling between 75 and 100 kg/m3. Also, the 7 day
compressive strength of 4.5 N/mm2 would be achieved by materials with 100 kg/m3 cement content and by
adding approximately 4% of cement to SQS (Lamb, 2005).
The utilisation of recycled and secondary materials in hydraulically bound mixtures has been studied in the
past (Dunster et al, 2005a; Dunster et al, 2005b). Alternative materials such as silt dredging, pulverized-fuel
ash, clay and steel slag fines were trialled in applications that involved stabilisation for erosion protection and
in road construction and paving (Dunster et al, 2005b). The advantages seen from using alternative materials
in HBM were end product related (such as, higher strength was achieved), economic (for example, avoid
disposal cost or transport of primary aggregates), environmental (such as, reduced pollution associated with
transport) and operational (such as, easy to handle and use). Technical guidance on the use of alternative
materials in HBMs for different applications such as in major road or minor road construction, erosion
protection, liners and heavy pavement was produced within this project (Dunster et al, 2005c; Dunster et
al, 2005d; Dunster et al, 2005e). The referenced case studies provide some good examples of utilisation of
alternative materials in HBM and it is anticipated that similar benefits could be achieved by using quarry fines.
Research is currently being undertaken within the MIST programme (sixth call – Thematic Value: Optimising
Resource Value) on the use of quarry dust in hydraulically bound mixtures for construction applications. The
scope of this project is to carry out a detailed literature review of existing studies, to develop specifications
for HBMs with quarry fines in their structure, to undertake laboratory investigation and to produce a
guidance document and technical report which will include all project findings. It is anticipated that this
project will be completed during 2008 (Scott Wilson, 2007) (project code: MA 6/4/003).
BS/EN standard requirement
Properties Applicable to/ methodology
Geometrical Grading Coarse, fine and all in aggregates (determines sieve apertures; break point between coarse and fine aggregates = 4 mm)
Crushed and broken surfaces
Coarse aggregates (assesses the potential for mechanical interlock between the coarse aggregate particles; in accordance with BS EN 933-5:1998 (BSI, 1998)
Fines content Coarse, fine and all-in aggregates (percentage passing a 63 µm sieve; the Specification for Highway Works however specifies a 75 µm sieve; adopted category will be determined from end use)
Physical Resistance to fragmentation
Los Angeles test
Resistance to wear Coarse aggregate (Micro-Deval test)
Particle density In accordance with BS EN 1097-6 (BSI, 2000b)
Chemical Acid-soluble sulfate Applicable to blast furnace slag aggregate only
Total sulfur Low content in aggregate sources in the UK, so unless stated this is not applicable
Constituents which alter the rate of setting and hardening of hydraulically bound mixtures
Commonly not applicable in the UK
Durability Based on water absorption value
In the UK, aggregates are considered satisfactory without further testing if they conform to water absorption WA242. Aggregates with water absorption above 2% should satisfy general purposes uses if they conform to the magnesium sulfate soundness category MS35Table 15: Requirements for aggregates for hydraulically bound mixtures in accordance with BS EN 13242 (BSI, 2002b)
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The use of quarry fines is under investigation by Scott Wilson and Transport Research Laboratory. This
project is due to be completed in 2008 (Scott Wilson and TRL, 2007). The objective of this project is to
characterise a range of different quarry fines, with and without hydraulic binders, and to develop procedures
for the use in pavement engineering. (Scott Wilson and TRL, 2007).
Further information and case studies on the use of quarry fines in hydraulically bound mixtures can be found
elsewhere (Manning, 2004; Zoorob et al, 2002).
4.2.6 ASPHALT APPLICATIONS
Quarry fines may be used in asphalt paving and surface treatment as fine aggregate or/and filler. Technical
requirements for aggregates used in asphalt are covered by BS EN 13043 (BSI, 2002e) with the supporting
document PD 6682-2 (BSI, 2003e). According to BS EN 13043, fine aggregate suitable for asphalt comprise
the particle size fraction below 2 mm and as filler, the aggregate most of which passes the 63 µm sieve,
which can be added to construction materials to provide certain properties. A summary of requirements
for aggregates used in asphalt according to BS EN 13043 is shown in Table 16. The Specification for
Highway Works, Series 900 sets the requirements for bituminous bound materials used in road pavement
construction (Highways Agency, 2007). Also technical standards such as the BS EN 12697 (part 11) (BSI,
2000c) specifies the compatibility between aggregate and bitumen and the BS EN 13179 (BSI, 2000d)
describes testing for filler aggregate used in bituminous mixtures. By the beginning of 2008, new European
Specifications for asphalt, its constituents, and methods of testing will be introduced (QPA, 2007b).
BS/ EN standard requirement
Properties Applicable to/ methodology
Geometry Grading Coarse, fine and all in aggregates; break point between coarse and fine aggregates = 2 mm
Fines content Fine aggregate (percentage passing a 63 µm sieve; the methylene blue test is not considered sufficiently precise in the UK; compliance with the fines content limit or evidence of satisfactory use is required instead; in British Standards a 75 µm sieve is specified)
Physical Resistance to fragmentation
Los Angeles test
Resistance to polishing of coarse aggregate for surface courses
Coarse aggregates (In accordance with BS EN 1097-8 (BSI, 2000e); guidance on minimum polished stone values is given in the Highways Agency Design Manual For Roads and Bridges (Highways Agency, 2004)
Resistance to surface abrasion
Measurement of the aggregate abrasion value (in accordance with BS EN 1097-8) (BSI, 2000e)
Durability Soundness The magnesium – sulfate soundness test is recommendedChemical Coarse lightweight
contaminants Testing is recommended for recycled aggregates only
Requirements for filler aggregate
Recommended tests: particle size distribution and loose bulk density in kerosene in accordance with BS EN 13043 (BSI, 2002e)
The use of quarry fines as aggregate or filler for asphalt has been investigated by research, and where
possible, such materials are utilised. A good example is the use of china clay waste in the A30 Bodmin to
Indian Queens dual carriageway, where approximately 800,000 tonnes of material have been utilised for
the new road and asphalt layers. The use of china clay waste reduced the demand for primary materials,
minimised the pollution from long distance transport of quarried stone, as well as reduced the associated
Table 16: Requirements for aggregates for asphalt and surface treatment (BSI, 2002e)
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costs, and provided social benefits such as less nuisance to local communities from transport, and
employment opportunities (Highways Agency, 2007b).
The REFILL project, funded by the EU BriteEURam programme, investigated the use of quarry fines from the
sandstone Leadhill Quarry (Scott Wilson Ireland) in various end uses including asphalt. Assessment work was
focused on incorporating 0-2 mm fines in typical surface (wearing) course asphalt mixtures and subsequently
examined impact durability. Results suggested that the mixtures are not suitable due to the high filler content
(~23%). Additional testing with blends of fines with 3 mm single size aggregates provided satisfactory results
due to the lower filler content of these mixtures (Mitchell et al, 2004).
According to the International Center for Aggregates Research, the physical and chemical properties of
fine material are critical when utilised in applications such as hot-mix asphalt. In particular properties such
as surface free energy, chemical interaction potential, surface area and aggregate shape characteristics
(angularity and texture) can impact the adhesive bond between the aggregate and binder. Testing trials were
undertaken with a variety of combinations of bitumen and aggregates for determining mixtures’ performance,
whereas the influence of aggregate shape was evaluated by modelling techniques (Bhasin and Little, 2006;
Masad et al, 2004).
Several other research projects examined the use of quarry fines as well as recycled and secondary
aggregates in asphalt and bituminous mixtures. A summary of the outcomes of these projects is shown in
Table 17.
Project Findings ReferenceEvaluation of marble waste dust in the mixture of asphaltic concrete
Use of marble dust as filler material. Optimum filler/ bitumen content was obtained and results suggested that marble dust can be used (unprocessed in asphalt mixtures)
(Karasahin and Terzi, 2007)
Use of aggregates produced from marble quarry waste in asphalt pavement
Marble and andesite quarry wastes were compared with conventional materials for use as aggregates in asphalt pavement. The physical properties of the aggregate were found to be within specified limits and they could potentially be used in light to medium asphalt pavement binder layers
(Akbulut and Gurer, 2007)
Case Study – A316 resurfacing project
Use of recycled aggregates such as glass and incinerator bottom ash (IBA) in a resurfacing pilot project. Recycled aggregates replaced the fine aggregate in asphalt. The recycled glass and IBA performed well. Materials were found to be highly consistent and comparison with primary materials gave good results
(Transport for London, 2005)
Development of bitumen-bound waste aggregate building blocks
Use of pulverized-fuel ash, incinerated sewage sludge ash and steel slag for the development of bitumen–bound blocks (Bitu-blocks), which are made by 100% recycled aggregates. Compressive strength results were at least equal to concrete blocks and appeared to be more stable than conventional masonry blocks.
(Forth et al., 2006; Van Dao, 2006; Zoorob et al, 2002))
Exploitation and use of quarry fines
Literature review report presenting several other examples (Manning, 2004) (project code MA 2/4/003)
Table 17: Literature findings on the use of quarry fines and alternative aggregates in asphalt applications
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4.3 SUMMARY OF POTENTIAL UTILISATION ROUTES FOR QUARRY BY-PRODUCTS
In Section 4, several end uses, which could potentially be applicable to quarry fines, have been discussed.
These include the use of quarry fines in unbound and bound applications. As mentioned earlier in this report,
quarry fines are most often economically used for restoration purposes, but a fraction of these materials
remain unused and the objective of this report is to identify potential end uses for these materials. A
summary of the trends identified in Section 4 is given in Table 18 (a and b).
End Use SpecificationsType of quarry by-products *1
Current level of exploitation *2
Utilisation potential *3 Benefits
Quarry restoration
Type 1 and Type 2 (and often inert waste from secondary sources)
In use – predominant end use
High volume – low value
Re-use of overburden material and production residues
Backfill/infill of voids
BS EN 13242 (BSI, 2002b)
Type 1 and Type 2 In use (in a few projects)
High volume – low value
Use of large volumes of quarry finesMinimisation of exploitation of primary aggregatesLess pollution produced from the production and transport of primary aggregates
General fill (i.e embankments)
BS EN 13242 (BSI, 2002b)
Type 1 and Type 2 In use if found locally / Trials
High volume – low value
Road pavement construction (i.e sub-base, capping)
Specifications for Highway Works–Series 600 and 800 (Highways agency, 2007a)
Mainly Type 2–Type 1 in certain circumstances (such as high consistency material)
In use if found locally / Trials
High volume – low value
Remediation; artificial soils; compost
BSI PAS 100BS 3882
Type 1 and Type 2 In use in some areas
High volume – low value
Enhance plant growth; soil fertility; added nutritional valueMinimisation of quarry residuesEnvironmental and social benefits seen from enhanced health of soils and plants
Filler applications (for example, paper, paint, plastics, rubber)
European Standards on fillers’ critical properties
Type 2 Trials with mineral residues of calcareous and siliceous composition
Low volume – high value
Low cost fillers
Portland cement – kiln meal
BS EN 197 (BSI, 2000a)
Type 2 and Type 1 (in certain circumstances (for example, high consistency material)
Trials/In use Medium to high volume - medium value
Substitution of primary materials
Innovative products (for example, green roofs, eco-slates, cob building )
Green specifications design guides
Type 2 and Type 1 (in certain circumstances (for example, high consistency material, composition)
Not in use Low volume – high value
Low cost primary materials
(*1)à Mineral by-products classification as determined by REFILL research project – check Table 1 for further information(*2)à Based on literature review findings (*3)à Term Volume refers to quarry fines volumes potentially utilised; term Value corresponds to end use
Table 18a: Summary of potential end uses for quarry fines
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End Use Specifications Type of quarry by-products *1
Current level of exploitation *2
Utilisation potential *3
Benefits
Controlled low strength materials – self compacting concrete
BS EN 12620 (BSI, 2002a)
Type 1 and Type 2 Trials High volume – low value
Substitute of natural sand/ aggregate
Minimisation of quarry residues
Reduced exploitation of primary aggregates
If sourced locally, reduced emissions/ pollution from transport
Manufactured concrete
BS EN 12620 (BSI, 2002a); BS EN 206 – 1 (BSI, 2000f); BS 8500 (BSI, 2006a; BSI, 2006b)
Type 1 and Type 2 In use (if found locally)/trials
Low volume – low to medium value (depending on end product)
Heavy ceramics BS EN 771–1 (BSI, 2003i)
Type 1 and Type 2 In use/trials Low volume – low to medium value
Manufactured aggregates
BS EN 13055 (BSI, 2002d; BSI, 2004b)
Type 2 and Type 1 in certain circumstances (such as material consistency)
Trials/In use Low volume – medium to high value
Hydraulically bound mixtures
BS EN 13242 (BSI, 2002b)
Type 2 and Type 1 in certain circumstances (such as high consistency material)
Trials/In use Low volume – low to medium value
Asphalt BS EN 13043 (BSI, 2002e); Specifications for Highway Works - Series 900 (Highways Agency, 2007a)
Type 2 Trials/In use (in certain cases)
Low volume – medium value
(*1)à Mineral by-products classification as determined by REFILL research project – check Table 1 for further information
(*2)à Based on literature review findings
(*3)à term Volume refers to quarry by-products volumes potentially utilised; term Value corresponds to end use
Table 18b: Summary of potential end uses for quarry by-products
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Quarry fines can be suitable materials for a variety of end applications; however, currently their utilisation is
not widespread to the level it would have been expected mainly due to reasons related to the geographical
position of quarries.
Very often quarries operate in remote location from potential end users and the cost of material to them
includes high transport costs, which discourages their use. A good example of the effect of transport cost
to utilisation is the china clay by-products in Cornwall, which although they represent a suitable material for
various end product, their use has been limited to local markets only. A case study of china clay sand is given
in Figure 8, which presents in detail the drivers and constraints associated with the sustainable use of these
materials.
There are occasions where producers of aggregates are not aware of potential utilisation routes for their
quarry fines in the local area, and these materials remain unused. The principles of industrial ecology and
industrial symbiosis could prove beneficial in such cases for identifying markets in close geographical
proximity that can absorb these materials. Government initiatives like the National Industrial Symbiosis
Programme (NISP), aim to assist the industry to develop linkages and synergies between businesses in a local/
regional level and this way to turn unutilised material into a resource.
Another obstacle, reported by research, is the application of the Aggregates Levy to quarry fines (Manning,
2004; The University of Leeds, 2007d) (project code MA 2/4/003). End users decide what materials will be
incorporated into their manufacturing process primarily upon economic criteria. If a secondary material
offers essential elements to the end product or manufacturing route and at the same time provides a
profit to the end user by reducing the cost of the feedstock or contributing other benefits, for instance
environmental (reduced emissions) or technical (desirable performance), then this material will be
considered as a valuable substitute for primary materials. Quarry fines are found in competition at the same
time with primary and alternative materials.
Certain advantages can be seen however in quarry fines compared to other secondary materials. Quarry
fines are considered more consistent materials in relation to their composition and particle size, also over
time (temporal variability), they are commonly inert or non-hazardous which means that their impact to the
environment and human health is very low, and they could provide some degree of security to the end user
in terms of stable material supply.
Often quarry fines require some degree of processing before they can be used, which may increase their cost
and at the same time requires suitable infrastructure and equipment to become readily available.
Quarry fines from aggregate and sand and gravel production are not exempt from the Aggregates Levy and
therefore the use of such materials in construction products does not count towards recycled content.
Current legislation such as the Waste Framework Directive and sustainability strategies (for example
Strategy for Sustainable Construction (BERR, 2007)) aim to promote resource efficiency and the use of
recycled/reclaimed materials (for example, set minimum requirements for recycled content in construction),
which drive construction product manufacturers to utilise secondary materials in their products. This driver
5 BARRIERS TO UTILISATION
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to supply on products containing increased recycled content supports the use of recycled and secondary
aggregates, and investment and technical inventions to enable these uses. This driver does not apply to quarry
fines.
Another important obstacle to utilisation is the limited knowledge of exact quantities of quarry fines.
Currently only estimated quantities are available, which are calculated using a waste to mineral ratio.
According to DEFRA, during 2003 approximately 34 million tonnes of quarry waste were generated, based
on a waste to product ratio equal to 1 to 9. DEFRA does not provide an accurate definition of quarry waste
hence it is not clear what proportion of the reported figures corresponds to quarry fines, or whether it
includes other materials such as overburden. Past research estimated the percentages of fines generated
from different rock types and following this methodology the total production of fines from quarrying
using the 2005 Aggregates Mineral Survey was 28.4 million tonnes (Table 7). The estimation of quarry fines
production given in Table 7 is considered more relevant in this report, as it is an estimate of overall fines
production, but it is not possible to quantify the fraction of these quarry fines that may be excess to market
demand. Taking as example the utilisation of alternative materials used as aggregates, it can be seen that they
have progressed considerably, in part due to the availability of information on sources, tonnages, temporal
variability and consistency. It is recommended that figures on quantities of fines produced, marketed and
stockpiled should be calculated in order to properly evaluate the quantities of quarry fines currently available,
and information that present the geographical distribution of quarry fines, should be compiled to enable the
identification of potential end markets.
Information on the characteristics of quarry fines (such as, particle size, mineralogy) from different quarry
operations is not available and this is seen to affect the marketability of these materials. A past European
project (REFILL) carried out research which identified the characteristics of quarry fines. However, this
information is difficult to locate, which prevents this project from the assessing the quality and consistency of
those data, and makes it impossible to decide if they should become publicly available.
Very often barriers to the use of quarry fines are due to the absence of fit-for-purpose specifications.
Although technical standards, such as the European Standards on aggregates have broadened their scope
to include secondary and recycled materials, they are not always considered as fit-for-use by the industry.
For instance, the use of grading specifications to determine aggregates for concrete will exclude very fine
material (below 63 µm), because it is not common practice in the UK to use filler aggregate in concrete and
more importantly it is not required to determine the composition of fine and filler aggregate. Compositional
characterisation and suitable classification tests can easily identify adverse constituents such as clay or shale
into quarry fines and thus determine whether their incorporation into the final product is feasible. Grading
specifications cannot provide this kind of knowledge and currently in the UK only compliance with the fines
content limit is required. Another example is the use of quarry fines and dust in soil remineralisation and
composting. Uncertainty over the acceptability of compost containing rock dust in respect with the BSI PAS
100 has become apparent as the deliberate addition of non-biodegradable feedstock (for example, sand and
gravel) is not allowed unless sufficient evidence to demonstrate an enhancement of the process is presented
(Szmidt and Ferguson, 2004).
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Case study: Promoting the use of china clay waste China clay waste is produced from the extraction of kaolin from decomposed granite. The waste to product ratio is 9:1 in china clay quarries
Locations of china clay quarries: Cornwall (St Austell), Devon (Lee Moor, South Devon)Composition of china clay waste (in relation to 9:1 waste to product ratio): n sand (4 tonnes)n stent (2.5 tonnes)n overburden (1.5 tonnes)n fines (1 tonne)
Arisingsn Overall arisings: 19.6 Mtn Potentially available (estimated aggregate resources from ‘live feed’ operations): 7 Mt/yearn Potentially available (estimated aggregate resources from existing stockpiles): 156 Mt/yearn Aggregate resources in use: 2.6 Mt/year
Current usePredominantly in the South-West, which has a finite requirement for such aggregates. Several other end uses have been investigated and found suitable (such as, aggregates for concrete, bulk fill uses etc)
Drivers to utilisationn Legislation and government initiatives support the use of secondary aggregates: for example, exemption of china clay waste from Aggregates Levy; landfill tax; sustainability issues (such as, sustainable construction strategy and the promotion of use of materials with recycled content, sustainable use of natural resources); EU Mining Waste directive; EU Communication on waste and by-products n Existing standards and specifications are in place: for example Specifications for Highway Works Series 800, 900 and 1000 permit the use of china clay sand; BS13242 on aggregates for unbound and hydraulically bound materials, BS EN 12620 on aggregates for concrete and so onn There is a significant supply of china clay waste and a high potential for aggregate usen There is a significant market for sand and gravel, which china clay aggregate could meet n Shipping or pumping seems as economically viable solution for transporting china clay wasten Landscape, habitat and environmental benefits to be seen from removing this waste
Barriers to utilisationn Transport of china clay waste remains a significant obstacle to utilisation n If pumping of china clay becomes the preferred route for transport, then additional installations and infrastructure requirements will have to be developed with additional economical cost.
Future work requirementsn Resolve the problem associated with the transport of china clay waste. Pumping and shipping both look as potential solutionsn Further research is required in establishing the suitability of china clay waste for certain end uses (for example, in concrete)n Developing a Quality Protocol for china clay waste is expected to promote utilisationn Developing a marketing plan for china clay wasten Conducting detailed feasibility studies on the true capital and operational costs associated with aggregate pumping
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This report focused on quarry fines produced from aggregates and sand and gravel production. Quarry fines
and dust are generated from various activities such as extraction (for example drilling and blasting) and rock
preparation / beneficiation.
Quarry fines below 6 mm may be included in an end product (for example, Type 1 aggregate), be a product
in their own right (for example, fine aggregate) or be surplus to market demand, namely excess fines
which remain unused. The fines may include a high proportion of ultra fine (dust) particles (below 75 µm),
which may also be part of an aggregate product, or be produced in excess, or be produced as a by-product.
Definitions that properly describe all these different fractions do not currently exist; it is considered essential
that the industry establish robust definitions in order to provide a clear language with which to discuss and
communicate the issues relevant to quarry fines.
The current European standards on aggregates provide some fit-for-purpose criteria for aggregate materials,
which are primarily based on grading but are applied to all aggregates, wither recycled, secondary or primary.
Therefore, as fine aggregate is determined the fraction of material below 4 mm for use in concrete, mortar,
unbound and hydraulic bound applications and below 2 mm for inclusion in asphalt products. There is still a
need to develop better fit-for-purpose specifications that take into account the nature of different materials,
market trends and economics in conjunction with criteria currently used by end user and available technical
standards.
Figures on available resources and quantities of quarry fines are based on estimates rather than real data and
this is considered as a substantial barrier towards utilisation.
This report investigated the potential use of quarry fines in both unbound and bound applications. The
primary utilisation route for quarry fines is in restoration work. However, not all of quarry fines are used
for restoration, and in certain cases they may exhibit suitable properties for a variety of other end uses with
an associated profit for the aggregate producer. Literature findings have shown that quarry fines are suitable
materials for use in bulk fill applications (for example, backfilling, infilling, general fill), in road pavement
construction, in remediation and for the production of artificial soils and compost. All the above end uses are
partially in use, depending on availability of resources in geographical proximity. Other end uses such as fillers
in paper and paint or the use of quarry fines in Portland cement have been trialled or have been used on
single occasions. Also, the inclusion of quarry fines in innovative products (such as, green roofs, cob building)
has not been implemented as yet. Bound applications reviewed in this report include various construction
products (such as, concrete, heavy ceramics, manufactured aggregates), in flowable fills, in hydraulic mixtures
and asphalt. Trials have been undertaken for all these different applications and some of them are in use in
individual cases.
6 CONCLUSIONS
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The location of quarry fines, the limited awareness of aggregate producers for potential markets, the
competition with primary and alternative materials, the limited knowledge about quarry fines arisings and the
characteristics of these materials, and the absence of properly developed fit–for–use specifications are some
of the barriers to utilisation identified through this project.
Future research work should address and try to find solutions to constraints identified. Further information
for future research work is presented in Section 7.
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This project has addressed the sustainable utilisation of quarry by-products in a variety of applications. The
review process has identified certain gaps of knowledge that should be covered by future research work.
These are highlighted in the bullet points following:
n Mapping quarry fines: It is considered essential to determine the quantities of quarry fines, in order
to promote sustainable utilisation. The classification of quarry fines arisings into produced, stockpiled and
marketed would enhance current knowledge regarding the percentage of such materials which remains
unused. Also it would be useful to develop a ‘live’ system, such as a GIS database, which will display the
geographical distribution of quarry fines across the UK.
n Feasibility studies for quarry fines. The development of detailed feasibility studies for specific material
streams will provide an insight to the technical and economic viability of different utilisation routes. Although
feasibility studies tend to be case specific, they assist to increase awareness for issues specifically relevant to
different rock types (such as, sand and gravel, hard rock).
n Characterisation of quarry fines. Critical characteristics of quarry fines such as mineralogy, particle size,
compositional consistency, temporal variability and storage and handling properties should be addressed
for a variety of different products. The availability of such information is expected to assist the match
making process between quarry fines and utilisation routes and to assist the initiation of synergies between
aggregate producers and end users.
n Development of ‘good practice guides’ for the utilisation of quarry fines into different applications. These
should include examples from current utilisation practices and refer to critical requirements that should be
met for the incorporation of quarry fines and dust into different end products.
7 RECOMMENDATIONS FOR FUTURE WORK
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ALSF FUNDED REFERENCES
MA 6/4/012. Birmingham University (2007). Monitoring of remediated acidic sites using quarry wastes.
URL<http://www.mi-st.org.uk/research_projects/summeries/proj_sum_ma_6_4_012.pdf>. Access
date:[15/12/2007].
MA 1/3/003. Guillou, G. and Davies, R. (2004). Combination of basaltic quarry fines with organic process
residues for the development of novel growing media. URL< http://www.mi-st.org.uk/research_projects/
final_reports/final_report_ma_1_3_003.pdf>. Access date: [15/12/2007]. Mineral Solutions Ltd.
MA 4/2/002. Jeffrey, C.A, Hill, I.A and Fitch, P.J. (2003b). Waste minimisation by the application of integrated
technology. URL< http://www.mi-st.org.uk/research_projects/final_reports/final_report_ma_4_2_002.pdf>.
Access date: [15/12/2007]. Department of Geology. University of Leicester.
MA 3/2/001. Jeffrey, K., Eddleston, M. and Bailey, E. (2003a). Aggregate deposits and processing simulation to
optimise waste utilisation (AGSIM). URL< http://www.mi-st.org.uk/research_projects/final_reports/final_
report_ma_3_2_001.pdf>. Access date:[15/12/2007]. Department of Geology. University of Leicester.
MA 3/2/002. Jeffrey, K., McKee, G. and Bailey, E. (2004). Sand and gravel aggregate deposits-improved
characterisation technology (ADICT). URL< http://www.mi-st.org.uk/research_projects/final_reports/final_
report_ma_3_2_002.pdf>. Access date:[15/12/2007]. Leicester University and Tarmac Southern.
MA 2/4/003. Manning, D. (2004). Exploitation and Use of Quarry Fines. Manchester: Mineral Solutions. Report
No. 087/MIST2/DACM/01. URL< http://www.mi-st.org.uk/research_projects/final_reports/final_report_ma_
2_4_003.pdf>. Access date: [15/12/2007].
MA 4/5/003. Mitchell, C. (2007). Quarry Fines Minimisation. URL< http://www.mi-st.org.uk/research_
projects/final_reports/final_report_ma_4_5_003.pdf>. Access date: [18/12/2007]. British Geological Survey,
Nottingham.
MA 4/5/002. Mitchell, C. (2007b). Waterless fines removal. URL<: http://www.mi-st.org.uk/research_projects/
final_reports/final_report_ma_4_5_002.pdf>. Access date:[18/12/2007]. British Geological Survey.
MA 6/4/003. Scott Wilson (2007). The use of quarry dusts in hydraulically bound mixtures for construction
applications - Summary. URL< http://www.mi-st.org.uk/research_projects/summeries/proj_sum_ma_6_4_
003.pdf>. Access date:[17.10.2007].
MA 4/5/009. Smith, R.A., Sowerby, C., Knapman, D., Myall, D., May, J., Lewis, R., Bamfield, B. and Fox-Davies, T.
(2005). Feasibility of china clay secondary aggregate use. URLhttp://www.mi-st.org.uk/research_projects/final_
reports/final_report_ma_4_5_009.pdf. Access date:[17/10/2007]. TRL Limited.
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MA 4/2/019. Tarmac Ltd and Associates (2007). Management and Re-use of Quarry Assets. URL< http://www.
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University of Leeds (2007a). Goodquarry. URL<http://www.goodquarry.com/article.aspx?id=31&navid=11>,
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MA 2/3/007. University of Nottingham (2003). Cleaner Quarries: optimising environmental performance..
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MA 4/1/002. University of Nottingham (2005). Cleaner Quarries: Methods to reduce the environmental
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Access date:[17/12/2007].
MA 6/4/006. University of Nottingham (2007). Using microwave technology to produce lightweight aggregate
from quarry waste. URL<http://www.mi-st.org.uk/section_e.htm>; Access date:[12/10/2007].
OTHER REFERENCES
4sight (2007). Rocks to Rubble.: URL<http://www.4sight.org.uk/>. Access date:[12-09-2007].
Ahn, N. and Fowler, D.W (2001). An Experimental Study on the Guidelines for Using Higher Contents of
Aggregate Microfines in Portland Cement Concrete. ICAR-102-1S. International Center for Aggregates
Research (ICAR).
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Szmidt, R.A.K and Ferguson, J. (2004a). Co-utilization of rockdust, mineral fines and compost - Working
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the Council of 5 April 2006 on waste.
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Touahamia, M., Sivakumar, V. and McKelvey, D. (2002). Shear strength of reinforced-recycled material.
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APPENDIX I: PAST RESEARCH MIST PROJECTS
Project title Project holder Project programme
Project code
China Clay Secondary Aggregates Feasibility and Demonstration Programme Imerys Minerals MIST MA/4/5/009Combination of basaltic quarry fines with organic process residues for the development of novel growing media Mineral Solutions Ltd MIST MA/1/3/003Development of an interactive database to enhance the exploitation of quarry fines. Mineral Solutions Ltd MIST MA/2/4/003A Generic Model for the Formulation of Growing Media from Composts and Quarry Fines Mineral Solutions Ltd MIST MA/3/1/003
APPENDIX II: THE INTERPRETATIVE COMMUNICATION ON WASTE AND BY-PRODUCTS (COM (2007) 59 FINAL)
APPENDIX
Is the intended use of the material lawful?
Material is a waste
Material is a waste
Material is a waste
Material is a waste
Was the material deliberatelyproduced? (Was the production process modified in order to produce the material?)
Is the material ready for use without further processing (other than normal processing as an integral part of the production process?
Is the material produced as an integral part of the production process?
Then the material is a non-waste by-product
Then material is a product, not a production residue
Material is a production residue - tests below apply
Is use of the material certain?
Yes
Yes
Yes
Yes
Yes
No
No
No
No
No
Criteria 3
Criteria 2
Criteria 1
Figure 9: A decision tree for waste versus by product decision (Commission of the European Communities, 2007)
Table 19: Past research projects undertaken within the Mineral Industry Sustainable Technology Programme
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Is the material not useable? OR
Does it not meet technical specifications? OR
Is there no market present for this material?
Only a proportion of the material has a guaranteed use
Material is going to be stored for indefinite time prior to potential (not certain) reuse
NoNo
No
Yes
Yes
Yes
Criteria 1
Waste
Waste
Waste (*)
Go to Criteria 2
*until further changes are identified (i.e long term contracts)additional parameters to be taken under consideration
Figure 10: Decision tree for criteria 1 (in accordance with the Interpretative Communication on waste and by-products (COM (2007) 59 final (Commission of the European Communities, 2007))
Criteria 2&3
Yes
No
Yes
Yes
Material is a by-product after investigating the following: n Degree of readiness of material for further use n The investigation of processing/ recovery tasks into the main production process n Whether tasks are carried out by someone other than the manufacturer
Are tasks performed as integral part of the continuing process of production?
An additional recovery process is required
Can the material be used without any further processing?
Go to Criteria 3
Material is a waste until this process is complete
Figure 11: Decision tree for Criteria 2 and 3 (in accordance with the Interpretative Communication on waste and by-products (COM (2007) 59 final (Commission of the European Communities, 2007))
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Case Study – Leftover rocks from mining and quarrying – The AvestaPolaris case (I)
Facts on the operation
n The activities of AvestaPolarit Chrome Oy consist in extracting chromium-rich ore and producing
chromium concentrate.
n Within one year of extraction 8 million tonnes of leftover rock is generated.
n About 100 million tonnes of leftover rock are already stored around the mine
Potential end uses of leftover rock
n Backfilling parts of the mine – stacks will be landscaped prior to use
n A small proportion, about 20% will be processed into aggregates
n Stacks already stored may be used as filling material in constructing breakwaters and embankments
Diary of actions
n AvestaPolarit applied for an environmental licence to enable the continuity of mining and processing
activities on site (gradual changes took place from open-cast activities to underground mining)
n Environment centre granted licence, but classified leftover rock and ore-dressing sand as waste,
because production residues are not immediately reused or consumed.
n AvestaPolarit appealed against that decision
Questions set to the Court
Are production residues (leftover rock and ore-dressing sand) from mining operations to be regarded
as waste in accordance with Directive 75/442/EEC on waste (The European Parliament and the Council,
1975) and having recard to points:
n Place production residues are stored (i.e mining site, ancillary site, other)
n Composition of production residues (i.e leftover rock is of similar composition to primary ore)
n Health and safety impacts (i.e leftover rock is harmless to human health and the environment)
n Potential reuse and no intention to discard such materials
Court’s reply
Answers to question 1:
n Leftover rock stored for an indefinite length of time to await possible use/discard is classified as waste
(Palin Granit Oy, 2002)
n The place of storage, composition or proof that residues do not pose a threat to human health or the
environment, are not relevant criteria for determining whether leftover stone is to be regarded as waste
(Palin Granit Oy, 2002)
n Foreseeable reuses, such as in the construction of harbours, in embankment work or for inclusion in
construction products do not represent a certainty and leftover rock should be regarded as waste
n Leftover rock processed into aggregates, even if such use is probable, it requires an operation for
recovery of the desirable fraction, which does not comprise part of the production process and residues
therefore should be classified as waste
n Stacks of materials that remain on site will also constitute a waste, as no certain use without requiring
processing exists. Landscaping of such materials represents an environmental friendly manner of dealing
with them, not a stage in the production process
n Where leftover rock is intended to be used for filling in the galleries of the mine and sufficient evidence is
in place as to the identification and actual use of the substances, then they would not be waste.
n The term by-product should be confined to situations in which the reuse of the goods, materials is not
a mere possibility, but a certainty, without further processing prior to reuse and as an integral part of the
production process
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APPENDIX III: FIT- FOR- PURPOSE REQUIREMENTS
Product sector Role of alternative material (source/ ingredient)
Critical properties on alternative materials Examples of materials
Ceramic products
Clay substitute Particle size, plasticity, firing temperature, colour after firing
Common clay, fireclay
Body fuel Calorific content Colliery spoil, coal finesFillerParticle sizesand
Colourant Aesthetic properties (colour, texture), scumming, efflorescence
Water-ochre colliery waste
Fluxing agent Reactivity temperature, particle size Fine silica sandCement For use in kiln meal
Ca-rich source Chemistry, particle size, loss on ignition Limestone finesSi-rich source Chemistry, particle size, loss on ignition SandAl-rich source Chemistry, particle size, loss on ignition Residues from bauxite miningFe-rich source Chemistry, particle size, loss on ignition Water colliery wasteSi+Al+Fe source Chemistry, particle size, loss on ignition Quarry fines (various)Ca+Si+Al+Fe source Chemistry, particle size, loss on ignition Quarry finesFor the production of blended cements Pozzolanas Chemistry, specific surface area Natural pozzolanas, silica fourHydraulic materials Chemistry, particle size Ground granulated blast
furnace blastReactive phase Chemistry Limestone, gypsum
Concrete Coarse aggregate Particle size aggregatesFiller aggregate Particle size Quarry finesCement Portland cement, blended
cementpigments Iron oxides
Insulation Fuel Chemistry, particle size cokeFormstone Chemistry, particle size Waste material from mineral
wool productionFlux Chemistry, particle size Blast furnace slagPrimary rock Chemistry, particle size Basalt, gabbro
Manufactured aggregates
Base filler Mineralogy, chemistry, particle size, moisture content, loss on ignition (%)
Quarry washings
Binder Mineralogy, chemistry, particle size, moisture content, loss on ignition (%)
Cement
Fuel Mineralogy, chemistry, particle size, moisture content, loss on ignition (%)
Colliery spoil
Bloating agent Mineralogy, chemistry, particle size, moisture content, loss on ignition (%)
Municipal solid waste fly ash
Fluxing agent Mineralogy, chemistry, particle size, moisture content, loss on ignition (%)
Fine glass, fine silica sand
Coating Mineralogy, chemistry, particle size, moisture content, loss on ignition (%)
Table 20: Characterisation framework and fit-for-purpose requirements for the use of alternative materials in ceramics, cement, concrete, insulation and manufactured aggregates products (MIRO, 2007)
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APPENDIX IV: TECHNICAL SPECIFICATIONS FOR MANUFACTURED CONCRETE PRODUCTS
Concrete application Product Technical specificationPrecast concrete drainage units Channel BS EN 1340:2003
Manholes and inspection chambers BS EN 1917:2002Pipes BS EN 1916:2002
Precast concrete floor elements Ribbed floor; ribbed floor elements BS EN 13224:2004Precast concrete landscaping and hard surfacing units
Block paving BS EN 1338:2003Edging BS EN 1340:2003Flags BS EN 1339:2003Street furniture BS EN 1340: 2003
Precast masonry units Autoclaved aerated concrete BS EN 771-4:2003Block BS EN 771-3:2003Brick BS EN 771-3:2003Cast stone and reconstructed stone masonry BS 1217:1997Capping BS 5642-2:1983Edging BS EN 1340:2003Lintel BS EN 845-2:2003Manufactured stone masonry unit BS EN 771-5:2003sills BS 5642-1:1978
Precast concrete linear units Beam BS EN 13225:2004BS EN 206-1:2000
Column BS EN 13225:2004BS EN 206-1:2000
Frame unit BS EN 13225:2004BS EN 206-1:2000
Staircase unit BS EN 206-1:2000Precast flooring units Beam and block BS EN 206-1:2000
Composite lattice girder BS EN 206-1:2000Composite solid slabs BS EN 206-1:2000Floor plates for flooring systems BS EN 13747:2005Hollow core BS EN 1168:2005Hollowcore BS EN 206-1:2000Staircase unit BS EN 206-1:2000
Precast concrete road and hard surfacing unit
Block paving BS EN 1338:2003Channel BS EN 1340:2003Kerbs BS EN 1340:2003Quadrant BS EN 1340:2003
Precast concrete roofing system units
Floor plates for flooring systems BS EN 13747:2005Roof tiles and fittings BS EN 490:2004
Precast structural units Beam BS EN 206-1:2000Beam and block BS EN 206-1:2000Column BS EN 13225:2004
BS EN 206-1:2000Composite solid slab BS EN 206-1:2000Foundation unit BS EN 206-1:2000Frame unit BS EN 13225:2004
BS EN 206-1:2000Hollow core BS EN 206-1:2000Precast concrete pile unit BS EN 206-1:2000Staircase unit BS EN 206-1:2000
Table 21: Manufactured concrete products and relevant technical specifications