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School of Chemical & Biochemical Engineering August 2014
Yoel Sasson Office: N1.2B22! "hone #$1% 0!#
S'lla(us: C)4220 *reen Chemistr' an+ Engineering.
% ,rontal hours -er ee/ first semester hurs+a's 1$:%01:%0
CBE
he course inclu+es # home assignments.
31 *eneral intro+uction: origin5 current status an+ future of
green chemistr' an+
engineering.Economic groth an+ natural resources +e-letion..
*lo(al foo+ an+ atershortage. "ollution an+ glo(al arming5 "ea/ Oil
an+ renea(le energ'. 6efinition of
sustaina(ilit'. Sustaina(le +e7elo-ment. 8enea(le resources.
9eta(olic societ'. ife c'cle
assessments5 Cra+le to Cra+le conce-t. Biorefiner' an+ (iofuels.
Shale gas an+ *-rocesses.
32 he tools of green chemistr'. he tel7e -rinci-les. *reen
chemistr' as a re+uction
-rocess: -ollution -re7ention an+ aste minimiation. ;aste
management )ierarch'
re+uction of energ' consum-tion5 re+uction of ris/ an+
haar+.
6esign of -rocess flochartfor a la(orator' s'nthetic -roce+ure.
9ass (alance ofla(orator' scale s'nthesis uation. Elementar' ste-.
he com-lete rate
e>uation. ?nstantaneous an+ o7erall 'iel+ an+ selecti7it' in
-arallel an+ consecuti7e multi-le
reactions. ?+eal reactors. Contacting -atterns an+ selecti7it'.
Acti7ation energ' an+
selecti7it'. @inetics of series-arallel reactions. 9iing effects
on selecti7it'.
34 *eneral mole (alance e>uation an+ +esign e>uations in
i+eal reactors: B85 CS85 ",8 "B8
an+ SB8. 9ole (alance for multi-le reactions. 6esign algorithm
for sol7ing multi-le reaction
mole (alances. 9aimiing selecti7it' in multi-le reactions using
+ifferent reactors.
9icroreactors5 mem(rane reactor5 semi(atch reactor. Com(ining
mole (alance5 rate la an+
stoichiometr' in multi-le reactions. 9o+eling an+ enhancement of
selecti7it' of +esire+
-ro+ucts in com-le reactions 7ia tem-erature control5 a+7ance+
catal'sis an+ reactor+esign. Sol7ing an+ anal'ing com-le reaction
netor/s using O6E softare.
3$ Energ' (alance. Energ' integration in the chemical -lant.
)eat echange netor/. "inch
anal'sis for energ' integration. Energ' an+ mole (alance in
nonisothermal reactors.
Algorithm for heat effects. Energ' (alance an+ selecti7it' for
multi-le reactions in non
isothermal stea+' state ",8"B8.
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3# 9ass integration in the chemical -lant. Sourcesin/ ma--ing
+iagram. 9aterial rec'cle
"inch 6iagram5 Sin/ an+ source com-osite cur7e. 6esign rules
from material reuse "inch
+iagram. ?n+ustrial eam-les of mass integration. he conce-t of
eerg' an+ lost or/.
Eerg' flo in chemical -roceses.
3! )ar+ an+ soft mo+els. Selecti7it' an+ 'iel+ im-ro7ements in
chemical -rocesses 7iastatistical metho+s: +esign of e-eriments
com-lete an+ -artial factorial +esign as an
o-timiation tools. Screening of e-erimental 7aria(les. 6esign
matri an+ mo+el matri.
Eam-les from s'nthetic organic chemistr'. Com-osite +esigns. 6OE
using Statgra-hics
softare.
3 En7ironmental fate of chemicals. Chemical an+ -h'sical
-ro-erties estimation. a-or
-ressure5 @O;5 ater solu(ilit'5 (ioconcentration factor5 )enr'Ds
constant5 soil sor-tion
coefficients5 estimating en7ironmental -ersistence5
(io+egra+a(ilit' an+ ris/. 6esigning
safer chemicals. 9etrics for en7ironmental ris/ e7aluation of
chemicals: *lo(al arming5oone +e-letion5 aci+ rain5 smog formation5
toicit'.
3 ,un+amentals of in+ustrial aste treatment: Characteristic of
aste streams. "h'sical5
(iological an+ chemical aste treatment. @inetics an+ mo+eling of
micro(ial groth an+
su(strate utiliation. Aeration an+ o'gen mass transfer.
Bioreactors. Aero(ic an+
anaero(ic fermentation an+ oi+ation. Biological nitrification
an+ +enitrification. reatment
of toic an+ refractor' organic astes. Chemical aste treatment.
,enton chemistr' an+
reacti7e o'gen s-ecies. ;et air oi+ation.
310 En7ironmental conse>uences of (urning fossil fuels for
generation of energ'.,lue gases treatment in -oer stations an+ in
motor 7ehicles. ,*6 flue gas +esulfuriation
ues an+ -rocess intensification: 9icroa7echemistr'5
su-ercritical sol7ents5 sonochemistr'5 ionic li>ui+s5 +omino
reactions5 mem(rane
reactors5 reacti7e +istillation5 microreactors.
Textbooks and References:
31 9. ancaster: *reen Chemistr'5 an ?ntro+uctor' et5 8SC5
Cam(ri+ge 200232 6.A. Allen5 6.8. Shonnar+: *reen Engineering5
"rentice )all 2002
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3% F.*. Conce-cion 6.F.C. Consta(le: *reen Chemistr' an+
Engineering: A "racticalA--roach. ;ile' 2011
3% ).C. ,ogler: Elements of Chemical 8eaction Engineering ? E+.
"rentice )all 200#34 F. +e Saan Arons et al.: Efficienc' &
Sustaina(ilit' in the Energ' an+ Chemical
?n+ustries5 9arcel 6e//er 2004
3$ 9. El)alagi: "rocess ?ntegration5 Aca+emic "ress 200#3# 8.
Carlson5 F.E. Carlson: 6esign & O-timiation in Organic
S'nthesis ?? E+.5 Else7ier
200$3! *. cho(anoglous et al.: 9etcalf & E++'5 ;asteater
Engineering5 9c*ra )ill 200%
