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8/13/2019 Technical+Information+Lbg
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Carob, S.A. Locust Bean Gum Palgum Page 1/6
CAROB, S.A.Lbg Palgum
Locust Bean Gum is one of thenoblest and well known foodstabilisers used by the industry.
Lbg is obtained from the kernels of thecarob tree (Ceratonia Siliqua) which isfound in the Mediterranean area.
Locust bean gum is a galactomannanpolysaccharide. Its structure isessentially a straight D-mannosepolymer linked C1-C4 with relativelyregular branching on every fourth orfifth mannose group on C6 by singleD-galactose units.
This structure allows lbg to showsynergisms with k-carrageenan andxanthan gum.
Carob, S.A. at his modern plant ofMallorca manufactures Palgum HighGrade a very high yield lbg
Chemical and PhysicalProperties
Solubility: lbg is only partially solublein cold water and is completelysoluble in hot.
Viscosity: the ability of lbg to producehighly viscous aqueous solutions atrelatively low concentrations makes itvery interesting in food applications.
Viscosity is affected by severalfactors:
- Concentration: graph 1 shows howviscosity grows exponentially withthe concentration.
- Temperature: in graph 2 is shownhow lbg viscosity decreases withtemperature.
- pH: since lbg is a neutral polymer,its viscosity and stability is verylittle affected by pH within therange of pH 3-11 (graph 3).
- Shear stress: lbg shows apseudoplastic (shear thinning)behaviour (graph 4), which isdesirable in any pumpingoperation with liquids.
Graph 1Lbg Palgum HG
Viscosity vs concentration
% (w/w)
0,0 0,2 0,4 0,6 0,8 1,0
Viscosity(cp
s)
0
500
1000
1500
2000
2500
3000
3500
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Graph 2Lbg Palgum HG
Viscosity vs temperature
Temperature (C)
30 40 50 60 70 80
Viscosity1%(
cps)
0
500
1000
1500
2000
2500
3000
Graph 3Lbg Palgum HGViscosity vs pH
pH
3 4 5 6 7 8
Viscosity1%(
cps)
1800
2000
2200
2400
2600
2800
3000
Graph 4Lbg Palgum HG
Shear thinning behaviour
rpm
10 20 30 40 50 60
Viscosity1%(
cps)
1500
2000
2500
3000
3500
4000
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Synergism
Locust bean gum shows synergismswith k-carrageenan and xanthan gum.
- With k-carrageenan, lbg forms inhot elastic gels increasing the gelstrength. The maximum yield isobtained at a 50:50 lbg:k-carrageenan ratio (graph 5). Lbgalso avoids the loss of water.
- With xanthan gum, lbg in hot givesvery elastic gels with a remarkable
water retention at a 60:40lbg:xanthan ratio.
Graph 5Lbg Palgum HG
Synergism with K-carrageenan
Ratio Lbg:K-carrageenan
0:100 10:90 30:70 50:50 70:30 90:10 100:0
Gelstrength1,5
%w
/w(g/cm
2)
0
100
200
300
400
500
600
700
800
Graph 6Lbg Palgum HG
Sinergysm with xanthan gum
Ratio Lbg:xanthan gum
0:100 20:80 40:60 60:40 80:20 100:0
Gelstrength1,5
%w
/w(g/cm
2)
0
100
200
300
400
500
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Lbg Applications
Application Feature Combined with Lbg graderecommended
Ice cream Avoids ice crystal formation
Exceptionally high water absorption
Gives excellent body, smooth fine texture,and chewiness
High degree stabilisation
High heat shock resistance
Permits easy incorporation of air into themix
Tasteless, no flavour masking properties
Develops a basic viscosity that is notdestroyed by agitation
Kappacarrageenan
OrCMC-NaGuar gum
Sodium Alginate
PALGUM HG
Sherbets Avoids ice crystal formation
High degree stabilisation
High heat shock resistance
KappacarrageenanPectin
PALGUM HG
Cheeseproducts
Speeds up coagulation
Increases the yield of curd solids
Makes curd separation and removal easier
Gives excellent, smooth resilient body andtexture to the finished cheese
Water exudation from fresh cheese isreduced
Retains water and gives firm, spreadabletexture and homogeneous products incheese spreads and melted cheese
Improves the baking characteristics ofspray-dried cheese
Alone PALGUM M/200
Application Feature Combined with Lbg graderecommended
Meat products Binding and stabiliser agent
Lubricating effects on the meat mix,facilitating extrusion and stuffing
High water retention
Reduces loss of weight during storage
Improves sliceability of the meat blend with
k-carrageenan Enhances the suspension capacity of
xanthan gum in brine
KappacarrageenanXanthan gum
PALGUM HG orSTANDARD
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Bakery Doughs with good water-holdingcharacteristics
Doughs with constant functional properties
Improves texture and softness
Gives longer shelf-life, retarding staling andreducing crumbliness
Give higher yield and saving eggs in cakesand biscuit doughs
Gives firmer texture
Improves the sliceability
The cakes are easily removed from thecake pans
Alone PALGUM HG
Butter Effective antioxidant for butterfat Alone PALGUM M-200
Juices Maintains the natural cloudiness of fruit
beberages Stabilizing agent
Alone PALGUM HG
Baby milks Treatment of diarrhoea and digestiveproblems
There is not description of allergic effects
Alone PALGUM M-200
Dietetics Gives a higher degree of satiety withoutincreasing caloric content
Replacement of gluten
Xanthan gumCMC-Na
PALGUM HG
Water jellies Improves the elasticity of carrageenan
Avoids the loss of moisture Improves sliceability
Kappa
carrageenan
PALGUM M-200
Ketchup Increase viscosity
Eliminate syneresis
Xanthan gumGuar gumTara gum
PALGUM HG
Dressings Thickener GuarXanthan gum
PALGUM HG
Sterilised soupsand sauces
Reduces sterilisation times and thermalload on the product
Guar gumXanthan gum
PALGUM HG
Application Feature Combined with Lbg graderecommended
Restructuredfoods
Binding agent
High water retention
Improves sliceability
K-carrageenanXanthan gum
PALGUM HG
Noodles Makes more slippery the pasta
Binding agent
Guar PALGUM HG
Fish fillet blocks Binding agent
Phosphate replacer
Alone PALGUM HG
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Batter mixes Viscosity control in adhesive batters Starch PALGUM HG
Jams Avoids syneresis
Makes spreadable the jams
Alone or with :PectinXanthan
PALGUM HG
Sugar free jams Avoids syneresis Improves the spreadability
KappacarrageenanAgar
PALGUM HG
Milkshakes Improves the mouthfeel
Improves cocoa particles suspension
Xanthan gum PALGUM HG
Flan, pudding Prevent syneresis
Improves sliceability
Improves texture
Gives elasticity
KappacarrageenanAgar
PALGUM HG
Cream toppings Imparts creamier and fuller mouthfeel Kappa-carrageenan
Gelatine
PALGUM HGGRADE or
M-200
Mayonnaise Avoids syneresis
Emulsifies
Guar gumTara gumXanthan gum
PALGUM HG
Milkshakes Improves the mouthfeel
Improves cocoa particles suspension
Xanthan gum PALGUM HG
Flan, pudding Prevent syneresis
Improves sliceability
Improves texture
Gives elasticity
KappacarrageenanAgar
PALGUM HG
Cream toppings Imparts creamier and fuller mouthfeel KappacarrageenanGelatine
PALGUM HG
Legal Status
Locust bean gum is approved as food additive as E-410 by the European UnionNormative EC/95/2.