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    Carob, S.A. Locust Bean Gum Palgum Page 1/6

    CAROB, S.A.Lbg Palgum

    Locust Bean Gum is one of thenoblest and well known foodstabilisers used by the industry.

    Lbg is obtained from the kernels of thecarob tree (Ceratonia Siliqua) which isfound in the Mediterranean area.

    Locust bean gum is a galactomannanpolysaccharide. Its structure isessentially a straight D-mannosepolymer linked C1-C4 with relativelyregular branching on every fourth orfifth mannose group on C6 by singleD-galactose units.

    This structure allows lbg to showsynergisms with k-carrageenan andxanthan gum.

    Carob, S.A. at his modern plant ofMallorca manufactures Palgum HighGrade a very high yield lbg

    Chemical and PhysicalProperties

    Solubility: lbg is only partially solublein cold water and is completelysoluble in hot.

    Viscosity: the ability of lbg to producehighly viscous aqueous solutions atrelatively low concentrations makes itvery interesting in food applications.

    Viscosity is affected by severalfactors:

    - Concentration: graph 1 shows howviscosity grows exponentially withthe concentration.

    - Temperature: in graph 2 is shownhow lbg viscosity decreases withtemperature.

    - pH: since lbg is a neutral polymer,its viscosity and stability is verylittle affected by pH within therange of pH 3-11 (graph 3).

    - Shear stress: lbg shows apseudoplastic (shear thinning)behaviour (graph 4), which isdesirable in any pumpingoperation with liquids.

    Graph 1Lbg Palgum HG

    Viscosity vs concentration

    % (w/w)

    0,0 0,2 0,4 0,6 0,8 1,0

    Viscosity(cp

    s)

    0

    500

    1000

    1500

    2000

    2500

    3000

    3500

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    Graph 2Lbg Palgum HG

    Viscosity vs temperature

    Temperature (C)

    30 40 50 60 70 80

    Viscosity1%(

    cps)

    0

    500

    1000

    1500

    2000

    2500

    3000

    Graph 3Lbg Palgum HGViscosity vs pH

    pH

    3 4 5 6 7 8

    Viscosity1%(

    cps)

    1800

    2000

    2200

    2400

    2600

    2800

    3000

    Graph 4Lbg Palgum HG

    Shear thinning behaviour

    rpm

    10 20 30 40 50 60

    Viscosity1%(

    cps)

    1500

    2000

    2500

    3000

    3500

    4000

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    Synergism

    Locust bean gum shows synergismswith k-carrageenan and xanthan gum.

    - With k-carrageenan, lbg forms inhot elastic gels increasing the gelstrength. The maximum yield isobtained at a 50:50 lbg:k-carrageenan ratio (graph 5). Lbgalso avoids the loss of water.

    - With xanthan gum, lbg in hot givesvery elastic gels with a remarkable

    water retention at a 60:40lbg:xanthan ratio.

    Graph 5Lbg Palgum HG

    Synergism with K-carrageenan

    Ratio Lbg:K-carrageenan

    0:100 10:90 30:70 50:50 70:30 90:10 100:0

    Gelstrength1,5

    %w

    /w(g/cm

    2)

    0

    100

    200

    300

    400

    500

    600

    700

    800

    Graph 6Lbg Palgum HG

    Sinergysm with xanthan gum

    Ratio Lbg:xanthan gum

    0:100 20:80 40:60 60:40 80:20 100:0

    Gelstrength1,5

    %w

    /w(g/cm

    2)

    0

    100

    200

    300

    400

    500

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    Lbg Applications

    Application Feature Combined with Lbg graderecommended

    Ice cream Avoids ice crystal formation

    Exceptionally high water absorption

    Gives excellent body, smooth fine texture,and chewiness

    High degree stabilisation

    High heat shock resistance

    Permits easy incorporation of air into themix

    Tasteless, no flavour masking properties

    Develops a basic viscosity that is notdestroyed by agitation

    Kappacarrageenan

    OrCMC-NaGuar gum

    Sodium Alginate

    PALGUM HG

    Sherbets Avoids ice crystal formation

    High degree stabilisation

    High heat shock resistance

    KappacarrageenanPectin

    PALGUM HG

    Cheeseproducts

    Speeds up coagulation

    Increases the yield of curd solids

    Makes curd separation and removal easier

    Gives excellent, smooth resilient body andtexture to the finished cheese

    Water exudation from fresh cheese isreduced

    Retains water and gives firm, spreadabletexture and homogeneous products incheese spreads and melted cheese

    Improves the baking characteristics ofspray-dried cheese

    Alone PALGUM M/200

    Application Feature Combined with Lbg graderecommended

    Meat products Binding and stabiliser agent

    Lubricating effects on the meat mix,facilitating extrusion and stuffing

    High water retention

    Reduces loss of weight during storage

    Improves sliceability of the meat blend with

    k-carrageenan Enhances the suspension capacity of

    xanthan gum in brine

    KappacarrageenanXanthan gum

    PALGUM HG orSTANDARD

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    Bakery Doughs with good water-holdingcharacteristics

    Doughs with constant functional properties

    Improves texture and softness

    Gives longer shelf-life, retarding staling andreducing crumbliness

    Give higher yield and saving eggs in cakesand biscuit doughs

    Gives firmer texture

    Improves the sliceability

    The cakes are easily removed from thecake pans

    Alone PALGUM HG

    Butter Effective antioxidant for butterfat Alone PALGUM M-200

    Juices Maintains the natural cloudiness of fruit

    beberages Stabilizing agent

    Alone PALGUM HG

    Baby milks Treatment of diarrhoea and digestiveproblems

    There is not description of allergic effects

    Alone PALGUM M-200

    Dietetics Gives a higher degree of satiety withoutincreasing caloric content

    Replacement of gluten

    Xanthan gumCMC-Na

    PALGUM HG

    Water jellies Improves the elasticity of carrageenan

    Avoids the loss of moisture Improves sliceability

    Kappa

    carrageenan

    PALGUM M-200

    Ketchup Increase viscosity

    Eliminate syneresis

    Xanthan gumGuar gumTara gum

    PALGUM HG

    Dressings Thickener GuarXanthan gum

    PALGUM HG

    Sterilised soupsand sauces

    Reduces sterilisation times and thermalload on the product

    Guar gumXanthan gum

    PALGUM HG

    Application Feature Combined with Lbg graderecommended

    Restructuredfoods

    Binding agent

    High water retention

    Improves sliceability

    K-carrageenanXanthan gum

    PALGUM HG

    Noodles Makes more slippery the pasta

    Binding agent

    Guar PALGUM HG

    Fish fillet blocks Binding agent

    Phosphate replacer

    Alone PALGUM HG

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    Batter mixes Viscosity control in adhesive batters Starch PALGUM HG

    Jams Avoids syneresis

    Makes spreadable the jams

    Alone or with :PectinXanthan

    PALGUM HG

    Sugar free jams Avoids syneresis Improves the spreadability

    KappacarrageenanAgar

    PALGUM HG

    Milkshakes Improves the mouthfeel

    Improves cocoa particles suspension

    Xanthan gum PALGUM HG

    Flan, pudding Prevent syneresis

    Improves sliceability

    Improves texture

    Gives elasticity

    KappacarrageenanAgar

    PALGUM HG

    Cream toppings Imparts creamier and fuller mouthfeel Kappa-carrageenan

    Gelatine

    PALGUM HGGRADE or

    M-200

    Mayonnaise Avoids syneresis

    Emulsifies

    Guar gumTara gumXanthan gum

    PALGUM HG

    Milkshakes Improves the mouthfeel

    Improves cocoa particles suspension

    Xanthan gum PALGUM HG

    Flan, pudding Prevent syneresis

    Improves sliceability

    Improves texture

    Gives elasticity

    KappacarrageenanAgar

    PALGUM HG

    Cream toppings Imparts creamier and fuller mouthfeel KappacarrageenanGelatine

    PALGUM HG

    Legal Status

    Locust bean gum is approved as food additive as E-410 by the European UnionNormative EC/95/2.