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The elusive nature of minerality in white wine Wendy V. Parr, Ph. D. Lincoln University, Christchurch, New Zealand

The elusive nature of minerality in - Home | BCWGC elusive nature of minerality in white wine Wendy V. Parr, Ph. D. Lincoln University, Christchurch, New Zealand Minerality? Dominique

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Page 1: The elusive nature of minerality in - Home | BCWGC elusive nature of minerality in white wine Wendy V. Parr, Ph. D. Lincoln University, Christchurch, New Zealand Minerality? Dominique

The elusive nature of minerality in

white wine

Wendy V Parr Ph DLincoln University Christchurch New Zealand

Minerality

Dominique Valentin Jordi Ballester Dominique Peyron

Claire Grose

Jason Breitmeyer Rob Sherlock Brett Robinson

Philippe Darriet

Minerality ie what do we experience in wine that evokes

geological metaphors

bull Flinty silex

bull Smoky

bull Chalky calcareous

bull Matchstick gun flint struck match

bull Oyster shell iodine fossils

bull Earthy

bull Wet stones stony

bull Pencil lead graphite

Minerality in wine

bull Fashionable notion

ndash Increasingly reported as a wine descriptor

bull Positive concept

ndash Associated with cool climate wines

ndash Associated with higher-priced wines

bull Good for marketing

ndash Links with the concept of terroir or provenance

However geologists amp plant scientists tell us that it is unlikely that we are tasting directly the vineyard rocks amp soil (Maltman 2013)

So is perceived minerality all in the

mind

Have we been seduced by smart marketing

ldquoAll in the mindrdquo

bull Are we sensing specific characters in wine that evoke geological metaphors

ndash Data-driven perception based on the phenomenological properties of the wine

bull Or is minerality primarily a mental construction

ndash Top-down or knowledge-based perception

bull And is our experience of perceived minerality in wine shared by others

ndash Within a culture

ndash Across cultures

bull Influence of wine composition

Qs arising from industry media amp anecdotal reports

bull Can minerality be smelled or is it a palate sensation only

bull How is perceived minerality related to

ndash Acidity

ndash Relative absence of varietal flavour

ndash Reductive characteristics

bull What other wine characteristics associate with or drive perception of mineral character

How did we go about it(Parr et al FQAP 2015)

bull 32 French amp 31 NZ wine professionals evaluated 16 100 Sauvignon wines (8 French 8 NZ)ndash Via 3 modes of perception

bull Smelling only

bull Full lsquotastingrsquo

bull Palate only taste amp trigeminal (mouthfeel)

bull Wines were categorised amp describedndash Varietal characters

ndash Mineral characters (flinty smoky calcareous)

ndash Acidity freshness

ndash Reductive characters (graphite burnt rubber sulphide)

ndash Overall mineral intensity complexity familiarity liking

bull Physico-chemical analyses on the wines

What did we find

French and NZ wines were judged similarly in terms of overall intensity of mineral character

FBCBB

FBCLM

FLCH

FLPC

FSBAGA

FSBI

FSFCFSHB

NZAVFB

NZAVV

NZLWB

NZLWWH

NZRS

NZRSL

NZSVANZSVCH

Mineral NC

Mineral OMineral G

-2

-1

0

1

2

3

-4 -3 -2 -1 0 1 2 3

F2

(24

83

)

F1 (6944 )

Biplot (axes F1 et F2 9427 )

How were the wines characterised French Free SortingColours represent MDS clusters

pyrazine

good balance

acidic

varietal character

boxwood

fruit

tropical

mineral

asparagus

expressive aromatics

reductive

cat pee

citrusfloral

herbaceous

bitter

faulty

terroir expressioncreamy

oxidised

unripe

oak

smokey

NZRSL

FSHB

NZAVFB FSFC

FBCLMFSBI

NZRS

FSBAGA

FLCH

FLPCNZSVA

NZLWWH

FBCBB

NZLWB

NZAVV

NZSVCH

-15

-1

-05

0

05

1

-1 -05 0 05 1 15 2 25 3

F2 (

20

50

)

F1 (3900 )

FR axes F1 et F2 5950

How were the wines characterised NZ Free SortingColours represent MDS clusters

FSHB

FBCBB

NZSVCH

FLCH

NZLWBNZLWWH

NZRSNZAVFB

NZAVV

FSBI

FSBAGA

FSFC

FLPC

NZRSL

NZSVA

FBCLM

tropical

herbaceous

acidic reductive

pyrazine

boxwood

ripe

agedcitrus

faulty

complex

unripe

good balance

simplethin oak

varietal character

gooseberry

expressive aromatics

good weight

mineral lack of varietal character

oxidised

grapefruit

lack acidity

-15

-1

-05

0

05

1

-15 -1 -05 0 05 1 15 2

F2 (

15

33

)

F1 (4813 )

NZ_axes F1 et F2 6345

Can mineral be smelled

bull Both cultures reported perceiving minerality via each mode of perception ie

ndash Mineral can be smelled and

ndash Is a palate experience (taste amp mouthfeel)

bull French lsquotastersrsquo relied more on their noses than NZers in their full-tasting judgments of minerality NZers relying equally on olfaction (smelling) and palate phenomena

PCA Mineral intensity judgements in the 3 conditions

O = OrthonasalN = NoseclipG = Global

So which wine attributes predicted perceived mineralityin Sauvignon wine

And was there much consensus across cultures

Regression of Mineral by other descriptors Nose only Multiple Linear Regression alpha lt 005

Predictors

French

lsquotastersrsquo

t p Predictors

N Z lsquotastersrsquo

t p

Citrus 529 lt 00001 Citrus 378 lt 0001

Passionfruit -464 lt 00001 Passionfruit -337 lt 0001

Chalkycalc 675 lt 00001 Chalkycalc 594 lt 00001

Flintsmo 975 lt 00001 Flintsmo 723 lt 00001

Leadgraph 262 lt01 Leadgraph 451 lt 00001

Liking 310 lt 001 Liking 301 lt 001

Freshzingy 251 lt 005 Concentrat -205 lt 005

Iodioyster 209 lt 005

Regression of Mineral by other descriptors Full tasting Multiple Linear Regression alpha lt 005

Predictors

French

lsquotastersrsquo

t p Predictors

N Z lsquotastersrsquo

t p

Citrus 422 lt 00001 Citrus 209 lt 005

Passfruit -212 lt 005 Green -242 lt 005

Bitter 208 lt 005 Bitter 234 lt 005

Chalkycalc 205 lt 005 Chalkycalc 451 lt 00001

Flintsmo 461 lt 00001 Astringent -217 lt 005

Sweet -657 lt 00001 Freshzingy 220 lt 005

Leadgraphite 281 lt01 Herbaceous 223 lt 005

Liking 198 lt 005 ConcWght 248 lt 005

Regression of Mineral by other descriptors Palate only Multiple Linear Regression alpha lt 005

Predictors

French

lsquotastersrsquo

t p Predictors

N Z lsquotastersrsquo

t p

Freshzingy 522 lt 00001 Freshzingy 400 lt 00001

Flintsmo 853 lt 00001 Flintsmo 444 lt 00001

Chalkycalc 666 lt 00001 Chalkycalc 693 lt 00001

Souracid -226 lt 005 Souracid -226 lt 005

Sweet -433 lt 005 Leadgraph 202 lt 005

Bitter 397 lt 00001

PalateWght 537 lt 00001

Influence of wine composition(Parr et al FRIN 2016)

bull Standard parameters + an acidity index

bull pH TA ethanol RS total extract free amp bound SO2

bull Fermentation-derived volatile aroma compounds volatile

organic acids amp IBMP

bull Non-volatile organic acids

bull Tartaric lactic malic shikimic malonic

bull Wine elemental composition (ICP-OES)

bull Mg K Ca Na Rb Sr Al Fe Mn Si La P S Ba Cu Mo Ni Zn

bull Varietal thiols amp volatile sulphur compounds associated

with pungent aromas

Sulphur compounds

bull 3-mercaptohexan-1-ol (3MH) citrusgrapefruit

bull 3-mercaptohexyl acetate (3MHA) passion fruit

bull 4-mercapto-4-methylpentan-2-one (4MMP)

sweatyboxwood

bull Ethyl-2-sulfanylacetate (E2SA) ldquobaked beansrdquo note

bull Benzenemethanethiol (BMT) flinty note

bull Dimethyl sulfide (quince truffle)

bull Hydrogen sulfide (rotten eggs)

bull Meacutethanethiol (stagnant water halitosis)

bull Ethanethiol (onion rubber)

bull Dieacutethyl sulfide

bull Dimeacutethyl disulfide (quince asparagus)

PLSR plot projection of Y variables (M perceived minerality scores) on X variables (chemical compounds in red) and Wines (in green)

Figure 2

MeSH

DMSDMDS

BMTEthyl Acetate

Isoamyl Acetate

Octanoic Acid

Tartaric acid

DL-Lactic acid

Ba

MoZn

Titratable AcidityAcidityIndex

Density

Free SO2

Bound SO2

DMS(2)

BMT (2)Ethyl Acetate (2)

Isoamyl Acetate (2)Octanoic Acid (2)

Tartaric acid (2)

Malonic acid (2)

Ca (2)

S (2)

Ba (2)

Mo (2)Zn (2)

Titratable Acidity (2)AcidityIndex (2)

Density (2)

Free SO2 (2)

Bound SO2 (2)

3MH

Isobutanol

Isoamyl Alcohol

Diethyl succinate

Hexanoic Acid

L-Malic acid

Ca

Na

Mn

Isobutanol (2)

Isoamyl Alcohol (2)

Diethyl succinate (2)

Hexanoic Acid (2)

L-Malic acid (2)

DL-Lactic acid (2)

Na (2)

FR_Minerality

NZ_Minerality

FBCBB

FBCLM

FLCH

FLPC

FSBAGA

FSBI

FSFC

FSHB

NZAVFB

NZAVV

NZLWB

NZLWWHNZRS

NZRSL

NZSVA

NZSVCH

-1

-075

-05

-025

0

025

05

075

1

-1 -075 -05 -025 0 025 05 075 1

t2

t1

t1 amp t2

X

Y

Obs

Aspects of wine composition associated statistically with perception of mineral character in S blanc wines

(Parr et al FRIN 2016)

Positive predictors Negative predictors

French N Z French N Z

Free SO2 Bound SO2 Tartaric acid Isoamyl alcohol (fusel solvent)

Isoamyl

acetate(fruity)

Hexanoic acid (fatty waxy barnyard)

Titratable

acidity

Diethyl succinate (fruity wine-like)

Malic acid Isobutanol(fusel solvent)

Na

Ca

Implications

Not just smart marketingbull Perceived minerality in Sauvignon wine appears

based on data-driven input (wine attributes) bull Characters driving perceived minerality in Sauvignon

ndash Citrus notes and freshzingy character (acid)ndash Absence of passion fruit amp green characters

Caution needed in how the term mineral is usedbull Much between-judge variability in judging intensity

of mineral character in winebull Wine varietal differences may influence how

minerality is perceived in any particular wine bull Wine composition aspects appear complex amp

require further research

Acknowledgement

bull Our tasters in France amp NZ amp wine producers who provided their wines for the study

bull Funding

ndash Grape and Wine Research Programme PFR NZ

ndash New Zealand Winegrowers

ndash Pernod Ricard NZ amp Pernod Ricard Research Centre Paris France

ndash Regional Council of Burgundy

ndash Bureau Interprofessionnel des Vins de Bourgogne and Conseil Interprofessionel des Vins de Bordeaux

ndash Royal Society of New Zealand ISAT Linkages Fund

And thank you for your attention

Page 2: The elusive nature of minerality in - Home | BCWGC elusive nature of minerality in white wine Wendy V. Parr, Ph. D. Lincoln University, Christchurch, New Zealand Minerality? Dominique

Minerality

Dominique Valentin Jordi Ballester Dominique Peyron

Claire Grose

Jason Breitmeyer Rob Sherlock Brett Robinson

Philippe Darriet

Minerality ie what do we experience in wine that evokes

geological metaphors

bull Flinty silex

bull Smoky

bull Chalky calcareous

bull Matchstick gun flint struck match

bull Oyster shell iodine fossils

bull Earthy

bull Wet stones stony

bull Pencil lead graphite

Minerality in wine

bull Fashionable notion

ndash Increasingly reported as a wine descriptor

bull Positive concept

ndash Associated with cool climate wines

ndash Associated with higher-priced wines

bull Good for marketing

ndash Links with the concept of terroir or provenance

However geologists amp plant scientists tell us that it is unlikely that we are tasting directly the vineyard rocks amp soil (Maltman 2013)

So is perceived minerality all in the

mind

Have we been seduced by smart marketing

ldquoAll in the mindrdquo

bull Are we sensing specific characters in wine that evoke geological metaphors

ndash Data-driven perception based on the phenomenological properties of the wine

bull Or is minerality primarily a mental construction

ndash Top-down or knowledge-based perception

bull And is our experience of perceived minerality in wine shared by others

ndash Within a culture

ndash Across cultures

bull Influence of wine composition

Qs arising from industry media amp anecdotal reports

bull Can minerality be smelled or is it a palate sensation only

bull How is perceived minerality related to

ndash Acidity

ndash Relative absence of varietal flavour

ndash Reductive characteristics

bull What other wine characteristics associate with or drive perception of mineral character

How did we go about it(Parr et al FQAP 2015)

bull 32 French amp 31 NZ wine professionals evaluated 16 100 Sauvignon wines (8 French 8 NZ)ndash Via 3 modes of perception

bull Smelling only

bull Full lsquotastingrsquo

bull Palate only taste amp trigeminal (mouthfeel)

bull Wines were categorised amp describedndash Varietal characters

ndash Mineral characters (flinty smoky calcareous)

ndash Acidity freshness

ndash Reductive characters (graphite burnt rubber sulphide)

ndash Overall mineral intensity complexity familiarity liking

bull Physico-chemical analyses on the wines

What did we find

French and NZ wines were judged similarly in terms of overall intensity of mineral character

FBCBB

FBCLM

FLCH

FLPC

FSBAGA

FSBI

FSFCFSHB

NZAVFB

NZAVV

NZLWB

NZLWWH

NZRS

NZRSL

NZSVANZSVCH

Mineral NC

Mineral OMineral G

-2

-1

0

1

2

3

-4 -3 -2 -1 0 1 2 3

F2

(24

83

)

F1 (6944 )

Biplot (axes F1 et F2 9427 )

How were the wines characterised French Free SortingColours represent MDS clusters

pyrazine

good balance

acidic

varietal character

boxwood

fruit

tropical

mineral

asparagus

expressive aromatics

reductive

cat pee

citrusfloral

herbaceous

bitter

faulty

terroir expressioncreamy

oxidised

unripe

oak

smokey

NZRSL

FSHB

NZAVFB FSFC

FBCLMFSBI

NZRS

FSBAGA

FLCH

FLPCNZSVA

NZLWWH

FBCBB

NZLWB

NZAVV

NZSVCH

-15

-1

-05

0

05

1

-1 -05 0 05 1 15 2 25 3

F2 (

20

50

)

F1 (3900 )

FR axes F1 et F2 5950

How were the wines characterised NZ Free SortingColours represent MDS clusters

FSHB

FBCBB

NZSVCH

FLCH

NZLWBNZLWWH

NZRSNZAVFB

NZAVV

FSBI

FSBAGA

FSFC

FLPC

NZRSL

NZSVA

FBCLM

tropical

herbaceous

acidic reductive

pyrazine

boxwood

ripe

agedcitrus

faulty

complex

unripe

good balance

simplethin oak

varietal character

gooseberry

expressive aromatics

good weight

mineral lack of varietal character

oxidised

grapefruit

lack acidity

-15

-1

-05

0

05

1

-15 -1 -05 0 05 1 15 2

F2 (

15

33

)

F1 (4813 )

NZ_axes F1 et F2 6345

Can mineral be smelled

bull Both cultures reported perceiving minerality via each mode of perception ie

ndash Mineral can be smelled and

ndash Is a palate experience (taste amp mouthfeel)

bull French lsquotastersrsquo relied more on their noses than NZers in their full-tasting judgments of minerality NZers relying equally on olfaction (smelling) and palate phenomena

PCA Mineral intensity judgements in the 3 conditions

O = OrthonasalN = NoseclipG = Global

So which wine attributes predicted perceived mineralityin Sauvignon wine

And was there much consensus across cultures

Regression of Mineral by other descriptors Nose only Multiple Linear Regression alpha lt 005

Predictors

French

lsquotastersrsquo

t p Predictors

N Z lsquotastersrsquo

t p

Citrus 529 lt 00001 Citrus 378 lt 0001

Passionfruit -464 lt 00001 Passionfruit -337 lt 0001

Chalkycalc 675 lt 00001 Chalkycalc 594 lt 00001

Flintsmo 975 lt 00001 Flintsmo 723 lt 00001

Leadgraph 262 lt01 Leadgraph 451 lt 00001

Liking 310 lt 001 Liking 301 lt 001

Freshzingy 251 lt 005 Concentrat -205 lt 005

Iodioyster 209 lt 005

Regression of Mineral by other descriptors Full tasting Multiple Linear Regression alpha lt 005

Predictors

French

lsquotastersrsquo

t p Predictors

N Z lsquotastersrsquo

t p

Citrus 422 lt 00001 Citrus 209 lt 005

Passfruit -212 lt 005 Green -242 lt 005

Bitter 208 lt 005 Bitter 234 lt 005

Chalkycalc 205 lt 005 Chalkycalc 451 lt 00001

Flintsmo 461 lt 00001 Astringent -217 lt 005

Sweet -657 lt 00001 Freshzingy 220 lt 005

Leadgraphite 281 lt01 Herbaceous 223 lt 005

Liking 198 lt 005 ConcWght 248 lt 005

Regression of Mineral by other descriptors Palate only Multiple Linear Regression alpha lt 005

Predictors

French

lsquotastersrsquo

t p Predictors

N Z lsquotastersrsquo

t p

Freshzingy 522 lt 00001 Freshzingy 400 lt 00001

Flintsmo 853 lt 00001 Flintsmo 444 lt 00001

Chalkycalc 666 lt 00001 Chalkycalc 693 lt 00001

Souracid -226 lt 005 Souracid -226 lt 005

Sweet -433 lt 005 Leadgraph 202 lt 005

Bitter 397 lt 00001

PalateWght 537 lt 00001

Influence of wine composition(Parr et al FRIN 2016)

bull Standard parameters + an acidity index

bull pH TA ethanol RS total extract free amp bound SO2

bull Fermentation-derived volatile aroma compounds volatile

organic acids amp IBMP

bull Non-volatile organic acids

bull Tartaric lactic malic shikimic malonic

bull Wine elemental composition (ICP-OES)

bull Mg K Ca Na Rb Sr Al Fe Mn Si La P S Ba Cu Mo Ni Zn

bull Varietal thiols amp volatile sulphur compounds associated

with pungent aromas

Sulphur compounds

bull 3-mercaptohexan-1-ol (3MH) citrusgrapefruit

bull 3-mercaptohexyl acetate (3MHA) passion fruit

bull 4-mercapto-4-methylpentan-2-one (4MMP)

sweatyboxwood

bull Ethyl-2-sulfanylacetate (E2SA) ldquobaked beansrdquo note

bull Benzenemethanethiol (BMT) flinty note

bull Dimethyl sulfide (quince truffle)

bull Hydrogen sulfide (rotten eggs)

bull Meacutethanethiol (stagnant water halitosis)

bull Ethanethiol (onion rubber)

bull Dieacutethyl sulfide

bull Dimeacutethyl disulfide (quince asparagus)

PLSR plot projection of Y variables (M perceived minerality scores) on X variables (chemical compounds in red) and Wines (in green)

Figure 2

MeSH

DMSDMDS

BMTEthyl Acetate

Isoamyl Acetate

Octanoic Acid

Tartaric acid

DL-Lactic acid

Ba

MoZn

Titratable AcidityAcidityIndex

Density

Free SO2

Bound SO2

DMS(2)

BMT (2)Ethyl Acetate (2)

Isoamyl Acetate (2)Octanoic Acid (2)

Tartaric acid (2)

Malonic acid (2)

Ca (2)

S (2)

Ba (2)

Mo (2)Zn (2)

Titratable Acidity (2)AcidityIndex (2)

Density (2)

Free SO2 (2)

Bound SO2 (2)

3MH

Isobutanol

Isoamyl Alcohol

Diethyl succinate

Hexanoic Acid

L-Malic acid

Ca

Na

Mn

Isobutanol (2)

Isoamyl Alcohol (2)

Diethyl succinate (2)

Hexanoic Acid (2)

L-Malic acid (2)

DL-Lactic acid (2)

Na (2)

FR_Minerality

NZ_Minerality

FBCBB

FBCLM

FLCH

FLPC

FSBAGA

FSBI

FSFC

FSHB

NZAVFB

NZAVV

NZLWB

NZLWWHNZRS

NZRSL

NZSVA

NZSVCH

-1

-075

-05

-025

0

025

05

075

1

-1 -075 -05 -025 0 025 05 075 1

t2

t1

t1 amp t2

X

Y

Obs

Aspects of wine composition associated statistically with perception of mineral character in S blanc wines

(Parr et al FRIN 2016)

Positive predictors Negative predictors

French N Z French N Z

Free SO2 Bound SO2 Tartaric acid Isoamyl alcohol (fusel solvent)

Isoamyl

acetate(fruity)

Hexanoic acid (fatty waxy barnyard)

Titratable

acidity

Diethyl succinate (fruity wine-like)

Malic acid Isobutanol(fusel solvent)

Na

Ca

Implications

Not just smart marketingbull Perceived minerality in Sauvignon wine appears

based on data-driven input (wine attributes) bull Characters driving perceived minerality in Sauvignon

ndash Citrus notes and freshzingy character (acid)ndash Absence of passion fruit amp green characters

Caution needed in how the term mineral is usedbull Much between-judge variability in judging intensity

of mineral character in winebull Wine varietal differences may influence how

minerality is perceived in any particular wine bull Wine composition aspects appear complex amp

require further research

Acknowledgement

bull Our tasters in France amp NZ amp wine producers who provided their wines for the study

bull Funding

ndash Grape and Wine Research Programme PFR NZ

ndash New Zealand Winegrowers

ndash Pernod Ricard NZ amp Pernod Ricard Research Centre Paris France

ndash Regional Council of Burgundy

ndash Bureau Interprofessionnel des Vins de Bourgogne and Conseil Interprofessionel des Vins de Bordeaux

ndash Royal Society of New Zealand ISAT Linkages Fund

And thank you for your attention

Page 3: The elusive nature of minerality in - Home | BCWGC elusive nature of minerality in white wine Wendy V. Parr, Ph. D. Lincoln University, Christchurch, New Zealand Minerality? Dominique

Minerality ie what do we experience in wine that evokes

geological metaphors

bull Flinty silex

bull Smoky

bull Chalky calcareous

bull Matchstick gun flint struck match

bull Oyster shell iodine fossils

bull Earthy

bull Wet stones stony

bull Pencil lead graphite

Minerality in wine

bull Fashionable notion

ndash Increasingly reported as a wine descriptor

bull Positive concept

ndash Associated with cool climate wines

ndash Associated with higher-priced wines

bull Good for marketing

ndash Links with the concept of terroir or provenance

However geologists amp plant scientists tell us that it is unlikely that we are tasting directly the vineyard rocks amp soil (Maltman 2013)

So is perceived minerality all in the

mind

Have we been seduced by smart marketing

ldquoAll in the mindrdquo

bull Are we sensing specific characters in wine that evoke geological metaphors

ndash Data-driven perception based on the phenomenological properties of the wine

bull Or is minerality primarily a mental construction

ndash Top-down or knowledge-based perception

bull And is our experience of perceived minerality in wine shared by others

ndash Within a culture

ndash Across cultures

bull Influence of wine composition

Qs arising from industry media amp anecdotal reports

bull Can minerality be smelled or is it a palate sensation only

bull How is perceived minerality related to

ndash Acidity

ndash Relative absence of varietal flavour

ndash Reductive characteristics

bull What other wine characteristics associate with or drive perception of mineral character

How did we go about it(Parr et al FQAP 2015)

bull 32 French amp 31 NZ wine professionals evaluated 16 100 Sauvignon wines (8 French 8 NZ)ndash Via 3 modes of perception

bull Smelling only

bull Full lsquotastingrsquo

bull Palate only taste amp trigeminal (mouthfeel)

bull Wines were categorised amp describedndash Varietal characters

ndash Mineral characters (flinty smoky calcareous)

ndash Acidity freshness

ndash Reductive characters (graphite burnt rubber sulphide)

ndash Overall mineral intensity complexity familiarity liking

bull Physico-chemical analyses on the wines

What did we find

French and NZ wines were judged similarly in terms of overall intensity of mineral character

FBCBB

FBCLM

FLCH

FLPC

FSBAGA

FSBI

FSFCFSHB

NZAVFB

NZAVV

NZLWB

NZLWWH

NZRS

NZRSL

NZSVANZSVCH

Mineral NC

Mineral OMineral G

-2

-1

0

1

2

3

-4 -3 -2 -1 0 1 2 3

F2

(24

83

)

F1 (6944 )

Biplot (axes F1 et F2 9427 )

How were the wines characterised French Free SortingColours represent MDS clusters

pyrazine

good balance

acidic

varietal character

boxwood

fruit

tropical

mineral

asparagus

expressive aromatics

reductive

cat pee

citrusfloral

herbaceous

bitter

faulty

terroir expressioncreamy

oxidised

unripe

oak

smokey

NZRSL

FSHB

NZAVFB FSFC

FBCLMFSBI

NZRS

FSBAGA

FLCH

FLPCNZSVA

NZLWWH

FBCBB

NZLWB

NZAVV

NZSVCH

-15

-1

-05

0

05

1

-1 -05 0 05 1 15 2 25 3

F2 (

20

50

)

F1 (3900 )

FR axes F1 et F2 5950

How were the wines characterised NZ Free SortingColours represent MDS clusters

FSHB

FBCBB

NZSVCH

FLCH

NZLWBNZLWWH

NZRSNZAVFB

NZAVV

FSBI

FSBAGA

FSFC

FLPC

NZRSL

NZSVA

FBCLM

tropical

herbaceous

acidic reductive

pyrazine

boxwood

ripe

agedcitrus

faulty

complex

unripe

good balance

simplethin oak

varietal character

gooseberry

expressive aromatics

good weight

mineral lack of varietal character

oxidised

grapefruit

lack acidity

-15

-1

-05

0

05

1

-15 -1 -05 0 05 1 15 2

F2 (

15

33

)

F1 (4813 )

NZ_axes F1 et F2 6345

Can mineral be smelled

bull Both cultures reported perceiving minerality via each mode of perception ie

ndash Mineral can be smelled and

ndash Is a palate experience (taste amp mouthfeel)

bull French lsquotastersrsquo relied more on their noses than NZers in their full-tasting judgments of minerality NZers relying equally on olfaction (smelling) and palate phenomena

PCA Mineral intensity judgements in the 3 conditions

O = OrthonasalN = NoseclipG = Global

So which wine attributes predicted perceived mineralityin Sauvignon wine

And was there much consensus across cultures

Regression of Mineral by other descriptors Nose only Multiple Linear Regression alpha lt 005

Predictors

French

lsquotastersrsquo

t p Predictors

N Z lsquotastersrsquo

t p

Citrus 529 lt 00001 Citrus 378 lt 0001

Passionfruit -464 lt 00001 Passionfruit -337 lt 0001

Chalkycalc 675 lt 00001 Chalkycalc 594 lt 00001

Flintsmo 975 lt 00001 Flintsmo 723 lt 00001

Leadgraph 262 lt01 Leadgraph 451 lt 00001

Liking 310 lt 001 Liking 301 lt 001

Freshzingy 251 lt 005 Concentrat -205 lt 005

Iodioyster 209 lt 005

Regression of Mineral by other descriptors Full tasting Multiple Linear Regression alpha lt 005

Predictors

French

lsquotastersrsquo

t p Predictors

N Z lsquotastersrsquo

t p

Citrus 422 lt 00001 Citrus 209 lt 005

Passfruit -212 lt 005 Green -242 lt 005

Bitter 208 lt 005 Bitter 234 lt 005

Chalkycalc 205 lt 005 Chalkycalc 451 lt 00001

Flintsmo 461 lt 00001 Astringent -217 lt 005

Sweet -657 lt 00001 Freshzingy 220 lt 005

Leadgraphite 281 lt01 Herbaceous 223 lt 005

Liking 198 lt 005 ConcWght 248 lt 005

Regression of Mineral by other descriptors Palate only Multiple Linear Regression alpha lt 005

Predictors

French

lsquotastersrsquo

t p Predictors

N Z lsquotastersrsquo

t p

Freshzingy 522 lt 00001 Freshzingy 400 lt 00001

Flintsmo 853 lt 00001 Flintsmo 444 lt 00001

Chalkycalc 666 lt 00001 Chalkycalc 693 lt 00001

Souracid -226 lt 005 Souracid -226 lt 005

Sweet -433 lt 005 Leadgraph 202 lt 005

Bitter 397 lt 00001

PalateWght 537 lt 00001

Influence of wine composition(Parr et al FRIN 2016)

bull Standard parameters + an acidity index

bull pH TA ethanol RS total extract free amp bound SO2

bull Fermentation-derived volatile aroma compounds volatile

organic acids amp IBMP

bull Non-volatile organic acids

bull Tartaric lactic malic shikimic malonic

bull Wine elemental composition (ICP-OES)

bull Mg K Ca Na Rb Sr Al Fe Mn Si La P S Ba Cu Mo Ni Zn

bull Varietal thiols amp volatile sulphur compounds associated

with pungent aromas

Sulphur compounds

bull 3-mercaptohexan-1-ol (3MH) citrusgrapefruit

bull 3-mercaptohexyl acetate (3MHA) passion fruit

bull 4-mercapto-4-methylpentan-2-one (4MMP)

sweatyboxwood

bull Ethyl-2-sulfanylacetate (E2SA) ldquobaked beansrdquo note

bull Benzenemethanethiol (BMT) flinty note

bull Dimethyl sulfide (quince truffle)

bull Hydrogen sulfide (rotten eggs)

bull Meacutethanethiol (stagnant water halitosis)

bull Ethanethiol (onion rubber)

bull Dieacutethyl sulfide

bull Dimeacutethyl disulfide (quince asparagus)

PLSR plot projection of Y variables (M perceived minerality scores) on X variables (chemical compounds in red) and Wines (in green)

Figure 2

MeSH

DMSDMDS

BMTEthyl Acetate

Isoamyl Acetate

Octanoic Acid

Tartaric acid

DL-Lactic acid

Ba

MoZn

Titratable AcidityAcidityIndex

Density

Free SO2

Bound SO2

DMS(2)

BMT (2)Ethyl Acetate (2)

Isoamyl Acetate (2)Octanoic Acid (2)

Tartaric acid (2)

Malonic acid (2)

Ca (2)

S (2)

Ba (2)

Mo (2)Zn (2)

Titratable Acidity (2)AcidityIndex (2)

Density (2)

Free SO2 (2)

Bound SO2 (2)

3MH

Isobutanol

Isoamyl Alcohol

Diethyl succinate

Hexanoic Acid

L-Malic acid

Ca

Na

Mn

Isobutanol (2)

Isoamyl Alcohol (2)

Diethyl succinate (2)

Hexanoic Acid (2)

L-Malic acid (2)

DL-Lactic acid (2)

Na (2)

FR_Minerality

NZ_Minerality

FBCBB

FBCLM

FLCH

FLPC

FSBAGA

FSBI

FSFC

FSHB

NZAVFB

NZAVV

NZLWB

NZLWWHNZRS

NZRSL

NZSVA

NZSVCH

-1

-075

-05

-025

0

025

05

075

1

-1 -075 -05 -025 0 025 05 075 1

t2

t1

t1 amp t2

X

Y

Obs

Aspects of wine composition associated statistically with perception of mineral character in S blanc wines

(Parr et al FRIN 2016)

Positive predictors Negative predictors

French N Z French N Z

Free SO2 Bound SO2 Tartaric acid Isoamyl alcohol (fusel solvent)

Isoamyl

acetate(fruity)

Hexanoic acid (fatty waxy barnyard)

Titratable

acidity

Diethyl succinate (fruity wine-like)

Malic acid Isobutanol(fusel solvent)

Na

Ca

Implications

Not just smart marketingbull Perceived minerality in Sauvignon wine appears

based on data-driven input (wine attributes) bull Characters driving perceived minerality in Sauvignon

ndash Citrus notes and freshzingy character (acid)ndash Absence of passion fruit amp green characters

Caution needed in how the term mineral is usedbull Much between-judge variability in judging intensity

of mineral character in winebull Wine varietal differences may influence how

minerality is perceived in any particular wine bull Wine composition aspects appear complex amp

require further research

Acknowledgement

bull Our tasters in France amp NZ amp wine producers who provided their wines for the study

bull Funding

ndash Grape and Wine Research Programme PFR NZ

ndash New Zealand Winegrowers

ndash Pernod Ricard NZ amp Pernod Ricard Research Centre Paris France

ndash Regional Council of Burgundy

ndash Bureau Interprofessionnel des Vins de Bourgogne and Conseil Interprofessionel des Vins de Bordeaux

ndash Royal Society of New Zealand ISAT Linkages Fund

And thank you for your attention

Page 4: The elusive nature of minerality in - Home | BCWGC elusive nature of minerality in white wine Wendy V. Parr, Ph. D. Lincoln University, Christchurch, New Zealand Minerality? Dominique

Minerality in wine

bull Fashionable notion

ndash Increasingly reported as a wine descriptor

bull Positive concept

ndash Associated with cool climate wines

ndash Associated with higher-priced wines

bull Good for marketing

ndash Links with the concept of terroir or provenance

However geologists amp plant scientists tell us that it is unlikely that we are tasting directly the vineyard rocks amp soil (Maltman 2013)

So is perceived minerality all in the

mind

Have we been seduced by smart marketing

ldquoAll in the mindrdquo

bull Are we sensing specific characters in wine that evoke geological metaphors

ndash Data-driven perception based on the phenomenological properties of the wine

bull Or is minerality primarily a mental construction

ndash Top-down or knowledge-based perception

bull And is our experience of perceived minerality in wine shared by others

ndash Within a culture

ndash Across cultures

bull Influence of wine composition

Qs arising from industry media amp anecdotal reports

bull Can minerality be smelled or is it a palate sensation only

bull How is perceived minerality related to

ndash Acidity

ndash Relative absence of varietal flavour

ndash Reductive characteristics

bull What other wine characteristics associate with or drive perception of mineral character

How did we go about it(Parr et al FQAP 2015)

bull 32 French amp 31 NZ wine professionals evaluated 16 100 Sauvignon wines (8 French 8 NZ)ndash Via 3 modes of perception

bull Smelling only

bull Full lsquotastingrsquo

bull Palate only taste amp trigeminal (mouthfeel)

bull Wines were categorised amp describedndash Varietal characters

ndash Mineral characters (flinty smoky calcareous)

ndash Acidity freshness

ndash Reductive characters (graphite burnt rubber sulphide)

ndash Overall mineral intensity complexity familiarity liking

bull Physico-chemical analyses on the wines

What did we find

French and NZ wines were judged similarly in terms of overall intensity of mineral character

FBCBB

FBCLM

FLCH

FLPC

FSBAGA

FSBI

FSFCFSHB

NZAVFB

NZAVV

NZLWB

NZLWWH

NZRS

NZRSL

NZSVANZSVCH

Mineral NC

Mineral OMineral G

-2

-1

0

1

2

3

-4 -3 -2 -1 0 1 2 3

F2

(24

83

)

F1 (6944 )

Biplot (axes F1 et F2 9427 )

How were the wines characterised French Free SortingColours represent MDS clusters

pyrazine

good balance

acidic

varietal character

boxwood

fruit

tropical

mineral

asparagus

expressive aromatics

reductive

cat pee

citrusfloral

herbaceous

bitter

faulty

terroir expressioncreamy

oxidised

unripe

oak

smokey

NZRSL

FSHB

NZAVFB FSFC

FBCLMFSBI

NZRS

FSBAGA

FLCH

FLPCNZSVA

NZLWWH

FBCBB

NZLWB

NZAVV

NZSVCH

-15

-1

-05

0

05

1

-1 -05 0 05 1 15 2 25 3

F2 (

20

50

)

F1 (3900 )

FR axes F1 et F2 5950

How were the wines characterised NZ Free SortingColours represent MDS clusters

FSHB

FBCBB

NZSVCH

FLCH

NZLWBNZLWWH

NZRSNZAVFB

NZAVV

FSBI

FSBAGA

FSFC

FLPC

NZRSL

NZSVA

FBCLM

tropical

herbaceous

acidic reductive

pyrazine

boxwood

ripe

agedcitrus

faulty

complex

unripe

good balance

simplethin oak

varietal character

gooseberry

expressive aromatics

good weight

mineral lack of varietal character

oxidised

grapefruit

lack acidity

-15

-1

-05

0

05

1

-15 -1 -05 0 05 1 15 2

F2 (

15

33

)

F1 (4813 )

NZ_axes F1 et F2 6345

Can mineral be smelled

bull Both cultures reported perceiving minerality via each mode of perception ie

ndash Mineral can be smelled and

ndash Is a palate experience (taste amp mouthfeel)

bull French lsquotastersrsquo relied more on their noses than NZers in their full-tasting judgments of minerality NZers relying equally on olfaction (smelling) and palate phenomena

PCA Mineral intensity judgements in the 3 conditions

O = OrthonasalN = NoseclipG = Global

So which wine attributes predicted perceived mineralityin Sauvignon wine

And was there much consensus across cultures

Regression of Mineral by other descriptors Nose only Multiple Linear Regression alpha lt 005

Predictors

French

lsquotastersrsquo

t p Predictors

N Z lsquotastersrsquo

t p

Citrus 529 lt 00001 Citrus 378 lt 0001

Passionfruit -464 lt 00001 Passionfruit -337 lt 0001

Chalkycalc 675 lt 00001 Chalkycalc 594 lt 00001

Flintsmo 975 lt 00001 Flintsmo 723 lt 00001

Leadgraph 262 lt01 Leadgraph 451 lt 00001

Liking 310 lt 001 Liking 301 lt 001

Freshzingy 251 lt 005 Concentrat -205 lt 005

Iodioyster 209 lt 005

Regression of Mineral by other descriptors Full tasting Multiple Linear Regression alpha lt 005

Predictors

French

lsquotastersrsquo

t p Predictors

N Z lsquotastersrsquo

t p

Citrus 422 lt 00001 Citrus 209 lt 005

Passfruit -212 lt 005 Green -242 lt 005

Bitter 208 lt 005 Bitter 234 lt 005

Chalkycalc 205 lt 005 Chalkycalc 451 lt 00001

Flintsmo 461 lt 00001 Astringent -217 lt 005

Sweet -657 lt 00001 Freshzingy 220 lt 005

Leadgraphite 281 lt01 Herbaceous 223 lt 005

Liking 198 lt 005 ConcWght 248 lt 005

Regression of Mineral by other descriptors Palate only Multiple Linear Regression alpha lt 005

Predictors

French

lsquotastersrsquo

t p Predictors

N Z lsquotastersrsquo

t p

Freshzingy 522 lt 00001 Freshzingy 400 lt 00001

Flintsmo 853 lt 00001 Flintsmo 444 lt 00001

Chalkycalc 666 lt 00001 Chalkycalc 693 lt 00001

Souracid -226 lt 005 Souracid -226 lt 005

Sweet -433 lt 005 Leadgraph 202 lt 005

Bitter 397 lt 00001

PalateWght 537 lt 00001

Influence of wine composition(Parr et al FRIN 2016)

bull Standard parameters + an acidity index

bull pH TA ethanol RS total extract free amp bound SO2

bull Fermentation-derived volatile aroma compounds volatile

organic acids amp IBMP

bull Non-volatile organic acids

bull Tartaric lactic malic shikimic malonic

bull Wine elemental composition (ICP-OES)

bull Mg K Ca Na Rb Sr Al Fe Mn Si La P S Ba Cu Mo Ni Zn

bull Varietal thiols amp volatile sulphur compounds associated

with pungent aromas

Sulphur compounds

bull 3-mercaptohexan-1-ol (3MH) citrusgrapefruit

bull 3-mercaptohexyl acetate (3MHA) passion fruit

bull 4-mercapto-4-methylpentan-2-one (4MMP)

sweatyboxwood

bull Ethyl-2-sulfanylacetate (E2SA) ldquobaked beansrdquo note

bull Benzenemethanethiol (BMT) flinty note

bull Dimethyl sulfide (quince truffle)

bull Hydrogen sulfide (rotten eggs)

bull Meacutethanethiol (stagnant water halitosis)

bull Ethanethiol (onion rubber)

bull Dieacutethyl sulfide

bull Dimeacutethyl disulfide (quince asparagus)

PLSR plot projection of Y variables (M perceived minerality scores) on X variables (chemical compounds in red) and Wines (in green)

Figure 2

MeSH

DMSDMDS

BMTEthyl Acetate

Isoamyl Acetate

Octanoic Acid

Tartaric acid

DL-Lactic acid

Ba

MoZn

Titratable AcidityAcidityIndex

Density

Free SO2

Bound SO2

DMS(2)

BMT (2)Ethyl Acetate (2)

Isoamyl Acetate (2)Octanoic Acid (2)

Tartaric acid (2)

Malonic acid (2)

Ca (2)

S (2)

Ba (2)

Mo (2)Zn (2)

Titratable Acidity (2)AcidityIndex (2)

Density (2)

Free SO2 (2)

Bound SO2 (2)

3MH

Isobutanol

Isoamyl Alcohol

Diethyl succinate

Hexanoic Acid

L-Malic acid

Ca

Na

Mn

Isobutanol (2)

Isoamyl Alcohol (2)

Diethyl succinate (2)

Hexanoic Acid (2)

L-Malic acid (2)

DL-Lactic acid (2)

Na (2)

FR_Minerality

NZ_Minerality

FBCBB

FBCLM

FLCH

FLPC

FSBAGA

FSBI

FSFC

FSHB

NZAVFB

NZAVV

NZLWB

NZLWWHNZRS

NZRSL

NZSVA

NZSVCH

-1

-075

-05

-025

0

025

05

075

1

-1 -075 -05 -025 0 025 05 075 1

t2

t1

t1 amp t2

X

Y

Obs

Aspects of wine composition associated statistically with perception of mineral character in S blanc wines

(Parr et al FRIN 2016)

Positive predictors Negative predictors

French N Z French N Z

Free SO2 Bound SO2 Tartaric acid Isoamyl alcohol (fusel solvent)

Isoamyl

acetate(fruity)

Hexanoic acid (fatty waxy barnyard)

Titratable

acidity

Diethyl succinate (fruity wine-like)

Malic acid Isobutanol(fusel solvent)

Na

Ca

Implications

Not just smart marketingbull Perceived minerality in Sauvignon wine appears

based on data-driven input (wine attributes) bull Characters driving perceived minerality in Sauvignon

ndash Citrus notes and freshzingy character (acid)ndash Absence of passion fruit amp green characters

Caution needed in how the term mineral is usedbull Much between-judge variability in judging intensity

of mineral character in winebull Wine varietal differences may influence how

minerality is perceived in any particular wine bull Wine composition aspects appear complex amp

require further research

Acknowledgement

bull Our tasters in France amp NZ amp wine producers who provided their wines for the study

bull Funding

ndash Grape and Wine Research Programme PFR NZ

ndash New Zealand Winegrowers

ndash Pernod Ricard NZ amp Pernod Ricard Research Centre Paris France

ndash Regional Council of Burgundy

ndash Bureau Interprofessionnel des Vins de Bourgogne and Conseil Interprofessionel des Vins de Bordeaux

ndash Royal Society of New Zealand ISAT Linkages Fund

And thank you for your attention

Page 5: The elusive nature of minerality in - Home | BCWGC elusive nature of minerality in white wine Wendy V. Parr, Ph. D. Lincoln University, Christchurch, New Zealand Minerality? Dominique

So is perceived minerality all in the

mind

Have we been seduced by smart marketing

ldquoAll in the mindrdquo

bull Are we sensing specific characters in wine that evoke geological metaphors

ndash Data-driven perception based on the phenomenological properties of the wine

bull Or is minerality primarily a mental construction

ndash Top-down or knowledge-based perception

bull And is our experience of perceived minerality in wine shared by others

ndash Within a culture

ndash Across cultures

bull Influence of wine composition

Qs arising from industry media amp anecdotal reports

bull Can minerality be smelled or is it a palate sensation only

bull How is perceived minerality related to

ndash Acidity

ndash Relative absence of varietal flavour

ndash Reductive characteristics

bull What other wine characteristics associate with or drive perception of mineral character

How did we go about it(Parr et al FQAP 2015)

bull 32 French amp 31 NZ wine professionals evaluated 16 100 Sauvignon wines (8 French 8 NZ)ndash Via 3 modes of perception

bull Smelling only

bull Full lsquotastingrsquo

bull Palate only taste amp trigeminal (mouthfeel)

bull Wines were categorised amp describedndash Varietal characters

ndash Mineral characters (flinty smoky calcareous)

ndash Acidity freshness

ndash Reductive characters (graphite burnt rubber sulphide)

ndash Overall mineral intensity complexity familiarity liking

bull Physico-chemical analyses on the wines

What did we find

French and NZ wines were judged similarly in terms of overall intensity of mineral character

FBCBB

FBCLM

FLCH

FLPC

FSBAGA

FSBI

FSFCFSHB

NZAVFB

NZAVV

NZLWB

NZLWWH

NZRS

NZRSL

NZSVANZSVCH

Mineral NC

Mineral OMineral G

-2

-1

0

1

2

3

-4 -3 -2 -1 0 1 2 3

F2

(24

83

)

F1 (6944 )

Biplot (axes F1 et F2 9427 )

How were the wines characterised French Free SortingColours represent MDS clusters

pyrazine

good balance

acidic

varietal character

boxwood

fruit

tropical

mineral

asparagus

expressive aromatics

reductive

cat pee

citrusfloral

herbaceous

bitter

faulty

terroir expressioncreamy

oxidised

unripe

oak

smokey

NZRSL

FSHB

NZAVFB FSFC

FBCLMFSBI

NZRS

FSBAGA

FLCH

FLPCNZSVA

NZLWWH

FBCBB

NZLWB

NZAVV

NZSVCH

-15

-1

-05

0

05

1

-1 -05 0 05 1 15 2 25 3

F2 (

20

50

)

F1 (3900 )

FR axes F1 et F2 5950

How were the wines characterised NZ Free SortingColours represent MDS clusters

FSHB

FBCBB

NZSVCH

FLCH

NZLWBNZLWWH

NZRSNZAVFB

NZAVV

FSBI

FSBAGA

FSFC

FLPC

NZRSL

NZSVA

FBCLM

tropical

herbaceous

acidic reductive

pyrazine

boxwood

ripe

agedcitrus

faulty

complex

unripe

good balance

simplethin oak

varietal character

gooseberry

expressive aromatics

good weight

mineral lack of varietal character

oxidised

grapefruit

lack acidity

-15

-1

-05

0

05

1

-15 -1 -05 0 05 1 15 2

F2 (

15

33

)

F1 (4813 )

NZ_axes F1 et F2 6345

Can mineral be smelled

bull Both cultures reported perceiving minerality via each mode of perception ie

ndash Mineral can be smelled and

ndash Is a palate experience (taste amp mouthfeel)

bull French lsquotastersrsquo relied more on their noses than NZers in their full-tasting judgments of minerality NZers relying equally on olfaction (smelling) and palate phenomena

PCA Mineral intensity judgements in the 3 conditions

O = OrthonasalN = NoseclipG = Global

So which wine attributes predicted perceived mineralityin Sauvignon wine

And was there much consensus across cultures

Regression of Mineral by other descriptors Nose only Multiple Linear Regression alpha lt 005

Predictors

French

lsquotastersrsquo

t p Predictors

N Z lsquotastersrsquo

t p

Citrus 529 lt 00001 Citrus 378 lt 0001

Passionfruit -464 lt 00001 Passionfruit -337 lt 0001

Chalkycalc 675 lt 00001 Chalkycalc 594 lt 00001

Flintsmo 975 lt 00001 Flintsmo 723 lt 00001

Leadgraph 262 lt01 Leadgraph 451 lt 00001

Liking 310 lt 001 Liking 301 lt 001

Freshzingy 251 lt 005 Concentrat -205 lt 005

Iodioyster 209 lt 005

Regression of Mineral by other descriptors Full tasting Multiple Linear Regression alpha lt 005

Predictors

French

lsquotastersrsquo

t p Predictors

N Z lsquotastersrsquo

t p

Citrus 422 lt 00001 Citrus 209 lt 005

Passfruit -212 lt 005 Green -242 lt 005

Bitter 208 lt 005 Bitter 234 lt 005

Chalkycalc 205 lt 005 Chalkycalc 451 lt 00001

Flintsmo 461 lt 00001 Astringent -217 lt 005

Sweet -657 lt 00001 Freshzingy 220 lt 005

Leadgraphite 281 lt01 Herbaceous 223 lt 005

Liking 198 lt 005 ConcWght 248 lt 005

Regression of Mineral by other descriptors Palate only Multiple Linear Regression alpha lt 005

Predictors

French

lsquotastersrsquo

t p Predictors

N Z lsquotastersrsquo

t p

Freshzingy 522 lt 00001 Freshzingy 400 lt 00001

Flintsmo 853 lt 00001 Flintsmo 444 lt 00001

Chalkycalc 666 lt 00001 Chalkycalc 693 lt 00001

Souracid -226 lt 005 Souracid -226 lt 005

Sweet -433 lt 005 Leadgraph 202 lt 005

Bitter 397 lt 00001

PalateWght 537 lt 00001

Influence of wine composition(Parr et al FRIN 2016)

bull Standard parameters + an acidity index

bull pH TA ethanol RS total extract free amp bound SO2

bull Fermentation-derived volatile aroma compounds volatile

organic acids amp IBMP

bull Non-volatile organic acids

bull Tartaric lactic malic shikimic malonic

bull Wine elemental composition (ICP-OES)

bull Mg K Ca Na Rb Sr Al Fe Mn Si La P S Ba Cu Mo Ni Zn

bull Varietal thiols amp volatile sulphur compounds associated

with pungent aromas

Sulphur compounds

bull 3-mercaptohexan-1-ol (3MH) citrusgrapefruit

bull 3-mercaptohexyl acetate (3MHA) passion fruit

bull 4-mercapto-4-methylpentan-2-one (4MMP)

sweatyboxwood

bull Ethyl-2-sulfanylacetate (E2SA) ldquobaked beansrdquo note

bull Benzenemethanethiol (BMT) flinty note

bull Dimethyl sulfide (quince truffle)

bull Hydrogen sulfide (rotten eggs)

bull Meacutethanethiol (stagnant water halitosis)

bull Ethanethiol (onion rubber)

bull Dieacutethyl sulfide

bull Dimeacutethyl disulfide (quince asparagus)

PLSR plot projection of Y variables (M perceived minerality scores) on X variables (chemical compounds in red) and Wines (in green)

Figure 2

MeSH

DMSDMDS

BMTEthyl Acetate

Isoamyl Acetate

Octanoic Acid

Tartaric acid

DL-Lactic acid

Ba

MoZn

Titratable AcidityAcidityIndex

Density

Free SO2

Bound SO2

DMS(2)

BMT (2)Ethyl Acetate (2)

Isoamyl Acetate (2)Octanoic Acid (2)

Tartaric acid (2)

Malonic acid (2)

Ca (2)

S (2)

Ba (2)

Mo (2)Zn (2)

Titratable Acidity (2)AcidityIndex (2)

Density (2)

Free SO2 (2)

Bound SO2 (2)

3MH

Isobutanol

Isoamyl Alcohol

Diethyl succinate

Hexanoic Acid

L-Malic acid

Ca

Na

Mn

Isobutanol (2)

Isoamyl Alcohol (2)

Diethyl succinate (2)

Hexanoic Acid (2)

L-Malic acid (2)

DL-Lactic acid (2)

Na (2)

FR_Minerality

NZ_Minerality

FBCBB

FBCLM

FLCH

FLPC

FSBAGA

FSBI

FSFC

FSHB

NZAVFB

NZAVV

NZLWB

NZLWWHNZRS

NZRSL

NZSVA

NZSVCH

-1

-075

-05

-025

0

025

05

075

1

-1 -075 -05 -025 0 025 05 075 1

t2

t1

t1 amp t2

X

Y

Obs

Aspects of wine composition associated statistically with perception of mineral character in S blanc wines

(Parr et al FRIN 2016)

Positive predictors Negative predictors

French N Z French N Z

Free SO2 Bound SO2 Tartaric acid Isoamyl alcohol (fusel solvent)

Isoamyl

acetate(fruity)

Hexanoic acid (fatty waxy barnyard)

Titratable

acidity

Diethyl succinate (fruity wine-like)

Malic acid Isobutanol(fusel solvent)

Na

Ca

Implications

Not just smart marketingbull Perceived minerality in Sauvignon wine appears

based on data-driven input (wine attributes) bull Characters driving perceived minerality in Sauvignon

ndash Citrus notes and freshzingy character (acid)ndash Absence of passion fruit amp green characters

Caution needed in how the term mineral is usedbull Much between-judge variability in judging intensity

of mineral character in winebull Wine varietal differences may influence how

minerality is perceived in any particular wine bull Wine composition aspects appear complex amp

require further research

Acknowledgement

bull Our tasters in France amp NZ amp wine producers who provided their wines for the study

bull Funding

ndash Grape and Wine Research Programme PFR NZ

ndash New Zealand Winegrowers

ndash Pernod Ricard NZ amp Pernod Ricard Research Centre Paris France

ndash Regional Council of Burgundy

ndash Bureau Interprofessionnel des Vins de Bourgogne and Conseil Interprofessionel des Vins de Bordeaux

ndash Royal Society of New Zealand ISAT Linkages Fund

And thank you for your attention

Page 6: The elusive nature of minerality in - Home | BCWGC elusive nature of minerality in white wine Wendy V. Parr, Ph. D. Lincoln University, Christchurch, New Zealand Minerality? Dominique

ldquoAll in the mindrdquo

bull Are we sensing specific characters in wine that evoke geological metaphors

ndash Data-driven perception based on the phenomenological properties of the wine

bull Or is minerality primarily a mental construction

ndash Top-down or knowledge-based perception

bull And is our experience of perceived minerality in wine shared by others

ndash Within a culture

ndash Across cultures

bull Influence of wine composition

Qs arising from industry media amp anecdotal reports

bull Can minerality be smelled or is it a palate sensation only

bull How is perceived minerality related to

ndash Acidity

ndash Relative absence of varietal flavour

ndash Reductive characteristics

bull What other wine characteristics associate with or drive perception of mineral character

How did we go about it(Parr et al FQAP 2015)

bull 32 French amp 31 NZ wine professionals evaluated 16 100 Sauvignon wines (8 French 8 NZ)ndash Via 3 modes of perception

bull Smelling only

bull Full lsquotastingrsquo

bull Palate only taste amp trigeminal (mouthfeel)

bull Wines were categorised amp describedndash Varietal characters

ndash Mineral characters (flinty smoky calcareous)

ndash Acidity freshness

ndash Reductive characters (graphite burnt rubber sulphide)

ndash Overall mineral intensity complexity familiarity liking

bull Physico-chemical analyses on the wines

What did we find

French and NZ wines were judged similarly in terms of overall intensity of mineral character

FBCBB

FBCLM

FLCH

FLPC

FSBAGA

FSBI

FSFCFSHB

NZAVFB

NZAVV

NZLWB

NZLWWH

NZRS

NZRSL

NZSVANZSVCH

Mineral NC

Mineral OMineral G

-2

-1

0

1

2

3

-4 -3 -2 -1 0 1 2 3

F2

(24

83

)

F1 (6944 )

Biplot (axes F1 et F2 9427 )

How were the wines characterised French Free SortingColours represent MDS clusters

pyrazine

good balance

acidic

varietal character

boxwood

fruit

tropical

mineral

asparagus

expressive aromatics

reductive

cat pee

citrusfloral

herbaceous

bitter

faulty

terroir expressioncreamy

oxidised

unripe

oak

smokey

NZRSL

FSHB

NZAVFB FSFC

FBCLMFSBI

NZRS

FSBAGA

FLCH

FLPCNZSVA

NZLWWH

FBCBB

NZLWB

NZAVV

NZSVCH

-15

-1

-05

0

05

1

-1 -05 0 05 1 15 2 25 3

F2 (

20

50

)

F1 (3900 )

FR axes F1 et F2 5950

How were the wines characterised NZ Free SortingColours represent MDS clusters

FSHB

FBCBB

NZSVCH

FLCH

NZLWBNZLWWH

NZRSNZAVFB

NZAVV

FSBI

FSBAGA

FSFC

FLPC

NZRSL

NZSVA

FBCLM

tropical

herbaceous

acidic reductive

pyrazine

boxwood

ripe

agedcitrus

faulty

complex

unripe

good balance

simplethin oak

varietal character

gooseberry

expressive aromatics

good weight

mineral lack of varietal character

oxidised

grapefruit

lack acidity

-15

-1

-05

0

05

1

-15 -1 -05 0 05 1 15 2

F2 (

15

33

)

F1 (4813 )

NZ_axes F1 et F2 6345

Can mineral be smelled

bull Both cultures reported perceiving minerality via each mode of perception ie

ndash Mineral can be smelled and

ndash Is a palate experience (taste amp mouthfeel)

bull French lsquotastersrsquo relied more on their noses than NZers in their full-tasting judgments of minerality NZers relying equally on olfaction (smelling) and palate phenomena

PCA Mineral intensity judgements in the 3 conditions

O = OrthonasalN = NoseclipG = Global

So which wine attributes predicted perceived mineralityin Sauvignon wine

And was there much consensus across cultures

Regression of Mineral by other descriptors Nose only Multiple Linear Regression alpha lt 005

Predictors

French

lsquotastersrsquo

t p Predictors

N Z lsquotastersrsquo

t p

Citrus 529 lt 00001 Citrus 378 lt 0001

Passionfruit -464 lt 00001 Passionfruit -337 lt 0001

Chalkycalc 675 lt 00001 Chalkycalc 594 lt 00001

Flintsmo 975 lt 00001 Flintsmo 723 lt 00001

Leadgraph 262 lt01 Leadgraph 451 lt 00001

Liking 310 lt 001 Liking 301 lt 001

Freshzingy 251 lt 005 Concentrat -205 lt 005

Iodioyster 209 lt 005

Regression of Mineral by other descriptors Full tasting Multiple Linear Regression alpha lt 005

Predictors

French

lsquotastersrsquo

t p Predictors

N Z lsquotastersrsquo

t p

Citrus 422 lt 00001 Citrus 209 lt 005

Passfruit -212 lt 005 Green -242 lt 005

Bitter 208 lt 005 Bitter 234 lt 005

Chalkycalc 205 lt 005 Chalkycalc 451 lt 00001

Flintsmo 461 lt 00001 Astringent -217 lt 005

Sweet -657 lt 00001 Freshzingy 220 lt 005

Leadgraphite 281 lt01 Herbaceous 223 lt 005

Liking 198 lt 005 ConcWght 248 lt 005

Regression of Mineral by other descriptors Palate only Multiple Linear Regression alpha lt 005

Predictors

French

lsquotastersrsquo

t p Predictors

N Z lsquotastersrsquo

t p

Freshzingy 522 lt 00001 Freshzingy 400 lt 00001

Flintsmo 853 lt 00001 Flintsmo 444 lt 00001

Chalkycalc 666 lt 00001 Chalkycalc 693 lt 00001

Souracid -226 lt 005 Souracid -226 lt 005

Sweet -433 lt 005 Leadgraph 202 lt 005

Bitter 397 lt 00001

PalateWght 537 lt 00001

Influence of wine composition(Parr et al FRIN 2016)

bull Standard parameters + an acidity index

bull pH TA ethanol RS total extract free amp bound SO2

bull Fermentation-derived volatile aroma compounds volatile

organic acids amp IBMP

bull Non-volatile organic acids

bull Tartaric lactic malic shikimic malonic

bull Wine elemental composition (ICP-OES)

bull Mg K Ca Na Rb Sr Al Fe Mn Si La P S Ba Cu Mo Ni Zn

bull Varietal thiols amp volatile sulphur compounds associated

with pungent aromas

Sulphur compounds

bull 3-mercaptohexan-1-ol (3MH) citrusgrapefruit

bull 3-mercaptohexyl acetate (3MHA) passion fruit

bull 4-mercapto-4-methylpentan-2-one (4MMP)

sweatyboxwood

bull Ethyl-2-sulfanylacetate (E2SA) ldquobaked beansrdquo note

bull Benzenemethanethiol (BMT) flinty note

bull Dimethyl sulfide (quince truffle)

bull Hydrogen sulfide (rotten eggs)

bull Meacutethanethiol (stagnant water halitosis)

bull Ethanethiol (onion rubber)

bull Dieacutethyl sulfide

bull Dimeacutethyl disulfide (quince asparagus)

PLSR plot projection of Y variables (M perceived minerality scores) on X variables (chemical compounds in red) and Wines (in green)

Figure 2

MeSH

DMSDMDS

BMTEthyl Acetate

Isoamyl Acetate

Octanoic Acid

Tartaric acid

DL-Lactic acid

Ba

MoZn

Titratable AcidityAcidityIndex

Density

Free SO2

Bound SO2

DMS(2)

BMT (2)Ethyl Acetate (2)

Isoamyl Acetate (2)Octanoic Acid (2)

Tartaric acid (2)

Malonic acid (2)

Ca (2)

S (2)

Ba (2)

Mo (2)Zn (2)

Titratable Acidity (2)AcidityIndex (2)

Density (2)

Free SO2 (2)

Bound SO2 (2)

3MH

Isobutanol

Isoamyl Alcohol

Diethyl succinate

Hexanoic Acid

L-Malic acid

Ca

Na

Mn

Isobutanol (2)

Isoamyl Alcohol (2)

Diethyl succinate (2)

Hexanoic Acid (2)

L-Malic acid (2)

DL-Lactic acid (2)

Na (2)

FR_Minerality

NZ_Minerality

FBCBB

FBCLM

FLCH

FLPC

FSBAGA

FSBI

FSFC

FSHB

NZAVFB

NZAVV

NZLWB

NZLWWHNZRS

NZRSL

NZSVA

NZSVCH

-1

-075

-05

-025

0

025

05

075

1

-1 -075 -05 -025 0 025 05 075 1

t2

t1

t1 amp t2

X

Y

Obs

Aspects of wine composition associated statistically with perception of mineral character in S blanc wines

(Parr et al FRIN 2016)

Positive predictors Negative predictors

French N Z French N Z

Free SO2 Bound SO2 Tartaric acid Isoamyl alcohol (fusel solvent)

Isoamyl

acetate(fruity)

Hexanoic acid (fatty waxy barnyard)

Titratable

acidity

Diethyl succinate (fruity wine-like)

Malic acid Isobutanol(fusel solvent)

Na

Ca

Implications

Not just smart marketingbull Perceived minerality in Sauvignon wine appears

based on data-driven input (wine attributes) bull Characters driving perceived minerality in Sauvignon

ndash Citrus notes and freshzingy character (acid)ndash Absence of passion fruit amp green characters

Caution needed in how the term mineral is usedbull Much between-judge variability in judging intensity

of mineral character in winebull Wine varietal differences may influence how

minerality is perceived in any particular wine bull Wine composition aspects appear complex amp

require further research

Acknowledgement

bull Our tasters in France amp NZ amp wine producers who provided their wines for the study

bull Funding

ndash Grape and Wine Research Programme PFR NZ

ndash New Zealand Winegrowers

ndash Pernod Ricard NZ amp Pernod Ricard Research Centre Paris France

ndash Regional Council of Burgundy

ndash Bureau Interprofessionnel des Vins de Bourgogne and Conseil Interprofessionel des Vins de Bordeaux

ndash Royal Society of New Zealand ISAT Linkages Fund

And thank you for your attention

Page 7: The elusive nature of minerality in - Home | BCWGC elusive nature of minerality in white wine Wendy V. Parr, Ph. D. Lincoln University, Christchurch, New Zealand Minerality? Dominique

Qs arising from industry media amp anecdotal reports

bull Can minerality be smelled or is it a palate sensation only

bull How is perceived minerality related to

ndash Acidity

ndash Relative absence of varietal flavour

ndash Reductive characteristics

bull What other wine characteristics associate with or drive perception of mineral character

How did we go about it(Parr et al FQAP 2015)

bull 32 French amp 31 NZ wine professionals evaluated 16 100 Sauvignon wines (8 French 8 NZ)ndash Via 3 modes of perception

bull Smelling only

bull Full lsquotastingrsquo

bull Palate only taste amp trigeminal (mouthfeel)

bull Wines were categorised amp describedndash Varietal characters

ndash Mineral characters (flinty smoky calcareous)

ndash Acidity freshness

ndash Reductive characters (graphite burnt rubber sulphide)

ndash Overall mineral intensity complexity familiarity liking

bull Physico-chemical analyses on the wines

What did we find

French and NZ wines were judged similarly in terms of overall intensity of mineral character

FBCBB

FBCLM

FLCH

FLPC

FSBAGA

FSBI

FSFCFSHB

NZAVFB

NZAVV

NZLWB

NZLWWH

NZRS

NZRSL

NZSVANZSVCH

Mineral NC

Mineral OMineral G

-2

-1

0

1

2

3

-4 -3 -2 -1 0 1 2 3

F2

(24

83

)

F1 (6944 )

Biplot (axes F1 et F2 9427 )

How were the wines characterised French Free SortingColours represent MDS clusters

pyrazine

good balance

acidic

varietal character

boxwood

fruit

tropical

mineral

asparagus

expressive aromatics

reductive

cat pee

citrusfloral

herbaceous

bitter

faulty

terroir expressioncreamy

oxidised

unripe

oak

smokey

NZRSL

FSHB

NZAVFB FSFC

FBCLMFSBI

NZRS

FSBAGA

FLCH

FLPCNZSVA

NZLWWH

FBCBB

NZLWB

NZAVV

NZSVCH

-15

-1

-05

0

05

1

-1 -05 0 05 1 15 2 25 3

F2 (

20

50

)

F1 (3900 )

FR axes F1 et F2 5950

How were the wines characterised NZ Free SortingColours represent MDS clusters

FSHB

FBCBB

NZSVCH

FLCH

NZLWBNZLWWH

NZRSNZAVFB

NZAVV

FSBI

FSBAGA

FSFC

FLPC

NZRSL

NZSVA

FBCLM

tropical

herbaceous

acidic reductive

pyrazine

boxwood

ripe

agedcitrus

faulty

complex

unripe

good balance

simplethin oak

varietal character

gooseberry

expressive aromatics

good weight

mineral lack of varietal character

oxidised

grapefruit

lack acidity

-15

-1

-05

0

05

1

-15 -1 -05 0 05 1 15 2

F2 (

15

33

)

F1 (4813 )

NZ_axes F1 et F2 6345

Can mineral be smelled

bull Both cultures reported perceiving minerality via each mode of perception ie

ndash Mineral can be smelled and

ndash Is a palate experience (taste amp mouthfeel)

bull French lsquotastersrsquo relied more on their noses than NZers in their full-tasting judgments of minerality NZers relying equally on olfaction (smelling) and palate phenomena

PCA Mineral intensity judgements in the 3 conditions

O = OrthonasalN = NoseclipG = Global

So which wine attributes predicted perceived mineralityin Sauvignon wine

And was there much consensus across cultures

Regression of Mineral by other descriptors Nose only Multiple Linear Regression alpha lt 005

Predictors

French

lsquotastersrsquo

t p Predictors

N Z lsquotastersrsquo

t p

Citrus 529 lt 00001 Citrus 378 lt 0001

Passionfruit -464 lt 00001 Passionfruit -337 lt 0001

Chalkycalc 675 lt 00001 Chalkycalc 594 lt 00001

Flintsmo 975 lt 00001 Flintsmo 723 lt 00001

Leadgraph 262 lt01 Leadgraph 451 lt 00001

Liking 310 lt 001 Liking 301 lt 001

Freshzingy 251 lt 005 Concentrat -205 lt 005

Iodioyster 209 lt 005

Regression of Mineral by other descriptors Full tasting Multiple Linear Regression alpha lt 005

Predictors

French

lsquotastersrsquo

t p Predictors

N Z lsquotastersrsquo

t p

Citrus 422 lt 00001 Citrus 209 lt 005

Passfruit -212 lt 005 Green -242 lt 005

Bitter 208 lt 005 Bitter 234 lt 005

Chalkycalc 205 lt 005 Chalkycalc 451 lt 00001

Flintsmo 461 lt 00001 Astringent -217 lt 005

Sweet -657 lt 00001 Freshzingy 220 lt 005

Leadgraphite 281 lt01 Herbaceous 223 lt 005

Liking 198 lt 005 ConcWght 248 lt 005

Regression of Mineral by other descriptors Palate only Multiple Linear Regression alpha lt 005

Predictors

French

lsquotastersrsquo

t p Predictors

N Z lsquotastersrsquo

t p

Freshzingy 522 lt 00001 Freshzingy 400 lt 00001

Flintsmo 853 lt 00001 Flintsmo 444 lt 00001

Chalkycalc 666 lt 00001 Chalkycalc 693 lt 00001

Souracid -226 lt 005 Souracid -226 lt 005

Sweet -433 lt 005 Leadgraph 202 lt 005

Bitter 397 lt 00001

PalateWght 537 lt 00001

Influence of wine composition(Parr et al FRIN 2016)

bull Standard parameters + an acidity index

bull pH TA ethanol RS total extract free amp bound SO2

bull Fermentation-derived volatile aroma compounds volatile

organic acids amp IBMP

bull Non-volatile organic acids

bull Tartaric lactic malic shikimic malonic

bull Wine elemental composition (ICP-OES)

bull Mg K Ca Na Rb Sr Al Fe Mn Si La P S Ba Cu Mo Ni Zn

bull Varietal thiols amp volatile sulphur compounds associated

with pungent aromas

Sulphur compounds

bull 3-mercaptohexan-1-ol (3MH) citrusgrapefruit

bull 3-mercaptohexyl acetate (3MHA) passion fruit

bull 4-mercapto-4-methylpentan-2-one (4MMP)

sweatyboxwood

bull Ethyl-2-sulfanylacetate (E2SA) ldquobaked beansrdquo note

bull Benzenemethanethiol (BMT) flinty note

bull Dimethyl sulfide (quince truffle)

bull Hydrogen sulfide (rotten eggs)

bull Meacutethanethiol (stagnant water halitosis)

bull Ethanethiol (onion rubber)

bull Dieacutethyl sulfide

bull Dimeacutethyl disulfide (quince asparagus)

PLSR plot projection of Y variables (M perceived minerality scores) on X variables (chemical compounds in red) and Wines (in green)

Figure 2

MeSH

DMSDMDS

BMTEthyl Acetate

Isoamyl Acetate

Octanoic Acid

Tartaric acid

DL-Lactic acid

Ba

MoZn

Titratable AcidityAcidityIndex

Density

Free SO2

Bound SO2

DMS(2)

BMT (2)Ethyl Acetate (2)

Isoamyl Acetate (2)Octanoic Acid (2)

Tartaric acid (2)

Malonic acid (2)

Ca (2)

S (2)

Ba (2)

Mo (2)Zn (2)

Titratable Acidity (2)AcidityIndex (2)

Density (2)

Free SO2 (2)

Bound SO2 (2)

3MH

Isobutanol

Isoamyl Alcohol

Diethyl succinate

Hexanoic Acid

L-Malic acid

Ca

Na

Mn

Isobutanol (2)

Isoamyl Alcohol (2)

Diethyl succinate (2)

Hexanoic Acid (2)

L-Malic acid (2)

DL-Lactic acid (2)

Na (2)

FR_Minerality

NZ_Minerality

FBCBB

FBCLM

FLCH

FLPC

FSBAGA

FSBI

FSFC

FSHB

NZAVFB

NZAVV

NZLWB

NZLWWHNZRS

NZRSL

NZSVA

NZSVCH

-1

-075

-05

-025

0

025

05

075

1

-1 -075 -05 -025 0 025 05 075 1

t2

t1

t1 amp t2

X

Y

Obs

Aspects of wine composition associated statistically with perception of mineral character in S blanc wines

(Parr et al FRIN 2016)

Positive predictors Negative predictors

French N Z French N Z

Free SO2 Bound SO2 Tartaric acid Isoamyl alcohol (fusel solvent)

Isoamyl

acetate(fruity)

Hexanoic acid (fatty waxy barnyard)

Titratable

acidity

Diethyl succinate (fruity wine-like)

Malic acid Isobutanol(fusel solvent)

Na

Ca

Implications

Not just smart marketingbull Perceived minerality in Sauvignon wine appears

based on data-driven input (wine attributes) bull Characters driving perceived minerality in Sauvignon

ndash Citrus notes and freshzingy character (acid)ndash Absence of passion fruit amp green characters

Caution needed in how the term mineral is usedbull Much between-judge variability in judging intensity

of mineral character in winebull Wine varietal differences may influence how

minerality is perceived in any particular wine bull Wine composition aspects appear complex amp

require further research

Acknowledgement

bull Our tasters in France amp NZ amp wine producers who provided their wines for the study

bull Funding

ndash Grape and Wine Research Programme PFR NZ

ndash New Zealand Winegrowers

ndash Pernod Ricard NZ amp Pernod Ricard Research Centre Paris France

ndash Regional Council of Burgundy

ndash Bureau Interprofessionnel des Vins de Bourgogne and Conseil Interprofessionel des Vins de Bordeaux

ndash Royal Society of New Zealand ISAT Linkages Fund

And thank you for your attention

Page 8: The elusive nature of minerality in - Home | BCWGC elusive nature of minerality in white wine Wendy V. Parr, Ph. D. Lincoln University, Christchurch, New Zealand Minerality? Dominique

How did we go about it(Parr et al FQAP 2015)

bull 32 French amp 31 NZ wine professionals evaluated 16 100 Sauvignon wines (8 French 8 NZ)ndash Via 3 modes of perception

bull Smelling only

bull Full lsquotastingrsquo

bull Palate only taste amp trigeminal (mouthfeel)

bull Wines were categorised amp describedndash Varietal characters

ndash Mineral characters (flinty smoky calcareous)

ndash Acidity freshness

ndash Reductive characters (graphite burnt rubber sulphide)

ndash Overall mineral intensity complexity familiarity liking

bull Physico-chemical analyses on the wines

What did we find

French and NZ wines were judged similarly in terms of overall intensity of mineral character

FBCBB

FBCLM

FLCH

FLPC

FSBAGA

FSBI

FSFCFSHB

NZAVFB

NZAVV

NZLWB

NZLWWH

NZRS

NZRSL

NZSVANZSVCH

Mineral NC

Mineral OMineral G

-2

-1

0

1

2

3

-4 -3 -2 -1 0 1 2 3

F2

(24

83

)

F1 (6944 )

Biplot (axes F1 et F2 9427 )

How were the wines characterised French Free SortingColours represent MDS clusters

pyrazine

good balance

acidic

varietal character

boxwood

fruit

tropical

mineral

asparagus

expressive aromatics

reductive

cat pee

citrusfloral

herbaceous

bitter

faulty

terroir expressioncreamy

oxidised

unripe

oak

smokey

NZRSL

FSHB

NZAVFB FSFC

FBCLMFSBI

NZRS

FSBAGA

FLCH

FLPCNZSVA

NZLWWH

FBCBB

NZLWB

NZAVV

NZSVCH

-15

-1

-05

0

05

1

-1 -05 0 05 1 15 2 25 3

F2 (

20

50

)

F1 (3900 )

FR axes F1 et F2 5950

How were the wines characterised NZ Free SortingColours represent MDS clusters

FSHB

FBCBB

NZSVCH

FLCH

NZLWBNZLWWH

NZRSNZAVFB

NZAVV

FSBI

FSBAGA

FSFC

FLPC

NZRSL

NZSVA

FBCLM

tropical

herbaceous

acidic reductive

pyrazine

boxwood

ripe

agedcitrus

faulty

complex

unripe

good balance

simplethin oak

varietal character

gooseberry

expressive aromatics

good weight

mineral lack of varietal character

oxidised

grapefruit

lack acidity

-15

-1

-05

0

05

1

-15 -1 -05 0 05 1 15 2

F2 (

15

33

)

F1 (4813 )

NZ_axes F1 et F2 6345

Can mineral be smelled

bull Both cultures reported perceiving minerality via each mode of perception ie

ndash Mineral can be smelled and

ndash Is a palate experience (taste amp mouthfeel)

bull French lsquotastersrsquo relied more on their noses than NZers in their full-tasting judgments of minerality NZers relying equally on olfaction (smelling) and palate phenomena

PCA Mineral intensity judgements in the 3 conditions

O = OrthonasalN = NoseclipG = Global

So which wine attributes predicted perceived mineralityin Sauvignon wine

And was there much consensus across cultures

Regression of Mineral by other descriptors Nose only Multiple Linear Regression alpha lt 005

Predictors

French

lsquotastersrsquo

t p Predictors

N Z lsquotastersrsquo

t p

Citrus 529 lt 00001 Citrus 378 lt 0001

Passionfruit -464 lt 00001 Passionfruit -337 lt 0001

Chalkycalc 675 lt 00001 Chalkycalc 594 lt 00001

Flintsmo 975 lt 00001 Flintsmo 723 lt 00001

Leadgraph 262 lt01 Leadgraph 451 lt 00001

Liking 310 lt 001 Liking 301 lt 001

Freshzingy 251 lt 005 Concentrat -205 lt 005

Iodioyster 209 lt 005

Regression of Mineral by other descriptors Full tasting Multiple Linear Regression alpha lt 005

Predictors

French

lsquotastersrsquo

t p Predictors

N Z lsquotastersrsquo

t p

Citrus 422 lt 00001 Citrus 209 lt 005

Passfruit -212 lt 005 Green -242 lt 005

Bitter 208 lt 005 Bitter 234 lt 005

Chalkycalc 205 lt 005 Chalkycalc 451 lt 00001

Flintsmo 461 lt 00001 Astringent -217 lt 005

Sweet -657 lt 00001 Freshzingy 220 lt 005

Leadgraphite 281 lt01 Herbaceous 223 lt 005

Liking 198 lt 005 ConcWght 248 lt 005

Regression of Mineral by other descriptors Palate only Multiple Linear Regression alpha lt 005

Predictors

French

lsquotastersrsquo

t p Predictors

N Z lsquotastersrsquo

t p

Freshzingy 522 lt 00001 Freshzingy 400 lt 00001

Flintsmo 853 lt 00001 Flintsmo 444 lt 00001

Chalkycalc 666 lt 00001 Chalkycalc 693 lt 00001

Souracid -226 lt 005 Souracid -226 lt 005

Sweet -433 lt 005 Leadgraph 202 lt 005

Bitter 397 lt 00001

PalateWght 537 lt 00001

Influence of wine composition(Parr et al FRIN 2016)

bull Standard parameters + an acidity index

bull pH TA ethanol RS total extract free amp bound SO2

bull Fermentation-derived volatile aroma compounds volatile

organic acids amp IBMP

bull Non-volatile organic acids

bull Tartaric lactic malic shikimic malonic

bull Wine elemental composition (ICP-OES)

bull Mg K Ca Na Rb Sr Al Fe Mn Si La P S Ba Cu Mo Ni Zn

bull Varietal thiols amp volatile sulphur compounds associated

with pungent aromas

Sulphur compounds

bull 3-mercaptohexan-1-ol (3MH) citrusgrapefruit

bull 3-mercaptohexyl acetate (3MHA) passion fruit

bull 4-mercapto-4-methylpentan-2-one (4MMP)

sweatyboxwood

bull Ethyl-2-sulfanylacetate (E2SA) ldquobaked beansrdquo note

bull Benzenemethanethiol (BMT) flinty note

bull Dimethyl sulfide (quince truffle)

bull Hydrogen sulfide (rotten eggs)

bull Meacutethanethiol (stagnant water halitosis)

bull Ethanethiol (onion rubber)

bull Dieacutethyl sulfide

bull Dimeacutethyl disulfide (quince asparagus)

PLSR plot projection of Y variables (M perceived minerality scores) on X variables (chemical compounds in red) and Wines (in green)

Figure 2

MeSH

DMSDMDS

BMTEthyl Acetate

Isoamyl Acetate

Octanoic Acid

Tartaric acid

DL-Lactic acid

Ba

MoZn

Titratable AcidityAcidityIndex

Density

Free SO2

Bound SO2

DMS(2)

BMT (2)Ethyl Acetate (2)

Isoamyl Acetate (2)Octanoic Acid (2)

Tartaric acid (2)

Malonic acid (2)

Ca (2)

S (2)

Ba (2)

Mo (2)Zn (2)

Titratable Acidity (2)AcidityIndex (2)

Density (2)

Free SO2 (2)

Bound SO2 (2)

3MH

Isobutanol

Isoamyl Alcohol

Diethyl succinate

Hexanoic Acid

L-Malic acid

Ca

Na

Mn

Isobutanol (2)

Isoamyl Alcohol (2)

Diethyl succinate (2)

Hexanoic Acid (2)

L-Malic acid (2)

DL-Lactic acid (2)

Na (2)

FR_Minerality

NZ_Minerality

FBCBB

FBCLM

FLCH

FLPC

FSBAGA

FSBI

FSFC

FSHB

NZAVFB

NZAVV

NZLWB

NZLWWHNZRS

NZRSL

NZSVA

NZSVCH

-1

-075

-05

-025

0

025

05

075

1

-1 -075 -05 -025 0 025 05 075 1

t2

t1

t1 amp t2

X

Y

Obs

Aspects of wine composition associated statistically with perception of mineral character in S blanc wines

(Parr et al FRIN 2016)

Positive predictors Negative predictors

French N Z French N Z

Free SO2 Bound SO2 Tartaric acid Isoamyl alcohol (fusel solvent)

Isoamyl

acetate(fruity)

Hexanoic acid (fatty waxy barnyard)

Titratable

acidity

Diethyl succinate (fruity wine-like)

Malic acid Isobutanol(fusel solvent)

Na

Ca

Implications

Not just smart marketingbull Perceived minerality in Sauvignon wine appears

based on data-driven input (wine attributes) bull Characters driving perceived minerality in Sauvignon

ndash Citrus notes and freshzingy character (acid)ndash Absence of passion fruit amp green characters

Caution needed in how the term mineral is usedbull Much between-judge variability in judging intensity

of mineral character in winebull Wine varietal differences may influence how

minerality is perceived in any particular wine bull Wine composition aspects appear complex amp

require further research

Acknowledgement

bull Our tasters in France amp NZ amp wine producers who provided their wines for the study

bull Funding

ndash Grape and Wine Research Programme PFR NZ

ndash New Zealand Winegrowers

ndash Pernod Ricard NZ amp Pernod Ricard Research Centre Paris France

ndash Regional Council of Burgundy

ndash Bureau Interprofessionnel des Vins de Bourgogne and Conseil Interprofessionel des Vins de Bordeaux

ndash Royal Society of New Zealand ISAT Linkages Fund

And thank you for your attention

Page 9: The elusive nature of minerality in - Home | BCWGC elusive nature of minerality in white wine Wendy V. Parr, Ph. D. Lincoln University, Christchurch, New Zealand Minerality? Dominique

What did we find

French and NZ wines were judged similarly in terms of overall intensity of mineral character

FBCBB

FBCLM

FLCH

FLPC

FSBAGA

FSBI

FSFCFSHB

NZAVFB

NZAVV

NZLWB

NZLWWH

NZRS

NZRSL

NZSVANZSVCH

Mineral NC

Mineral OMineral G

-2

-1

0

1

2

3

-4 -3 -2 -1 0 1 2 3

F2

(24

83

)

F1 (6944 )

Biplot (axes F1 et F2 9427 )

How were the wines characterised French Free SortingColours represent MDS clusters

pyrazine

good balance

acidic

varietal character

boxwood

fruit

tropical

mineral

asparagus

expressive aromatics

reductive

cat pee

citrusfloral

herbaceous

bitter

faulty

terroir expressioncreamy

oxidised

unripe

oak

smokey

NZRSL

FSHB

NZAVFB FSFC

FBCLMFSBI

NZRS

FSBAGA

FLCH

FLPCNZSVA

NZLWWH

FBCBB

NZLWB

NZAVV

NZSVCH

-15

-1

-05

0

05

1

-1 -05 0 05 1 15 2 25 3

F2 (

20

50

)

F1 (3900 )

FR axes F1 et F2 5950

How were the wines characterised NZ Free SortingColours represent MDS clusters

FSHB

FBCBB

NZSVCH

FLCH

NZLWBNZLWWH

NZRSNZAVFB

NZAVV

FSBI

FSBAGA

FSFC

FLPC

NZRSL

NZSVA

FBCLM

tropical

herbaceous

acidic reductive

pyrazine

boxwood

ripe

agedcitrus

faulty

complex

unripe

good balance

simplethin oak

varietal character

gooseberry

expressive aromatics

good weight

mineral lack of varietal character

oxidised

grapefruit

lack acidity

-15

-1

-05

0

05

1

-15 -1 -05 0 05 1 15 2

F2 (

15

33

)

F1 (4813 )

NZ_axes F1 et F2 6345

Can mineral be smelled

bull Both cultures reported perceiving minerality via each mode of perception ie

ndash Mineral can be smelled and

ndash Is a palate experience (taste amp mouthfeel)

bull French lsquotastersrsquo relied more on their noses than NZers in their full-tasting judgments of minerality NZers relying equally on olfaction (smelling) and palate phenomena

PCA Mineral intensity judgements in the 3 conditions

O = OrthonasalN = NoseclipG = Global

So which wine attributes predicted perceived mineralityin Sauvignon wine

And was there much consensus across cultures

Regression of Mineral by other descriptors Nose only Multiple Linear Regression alpha lt 005

Predictors

French

lsquotastersrsquo

t p Predictors

N Z lsquotastersrsquo

t p

Citrus 529 lt 00001 Citrus 378 lt 0001

Passionfruit -464 lt 00001 Passionfruit -337 lt 0001

Chalkycalc 675 lt 00001 Chalkycalc 594 lt 00001

Flintsmo 975 lt 00001 Flintsmo 723 lt 00001

Leadgraph 262 lt01 Leadgraph 451 lt 00001

Liking 310 lt 001 Liking 301 lt 001

Freshzingy 251 lt 005 Concentrat -205 lt 005

Iodioyster 209 lt 005

Regression of Mineral by other descriptors Full tasting Multiple Linear Regression alpha lt 005

Predictors

French

lsquotastersrsquo

t p Predictors

N Z lsquotastersrsquo

t p

Citrus 422 lt 00001 Citrus 209 lt 005

Passfruit -212 lt 005 Green -242 lt 005

Bitter 208 lt 005 Bitter 234 lt 005

Chalkycalc 205 lt 005 Chalkycalc 451 lt 00001

Flintsmo 461 lt 00001 Astringent -217 lt 005

Sweet -657 lt 00001 Freshzingy 220 lt 005

Leadgraphite 281 lt01 Herbaceous 223 lt 005

Liking 198 lt 005 ConcWght 248 lt 005

Regression of Mineral by other descriptors Palate only Multiple Linear Regression alpha lt 005

Predictors

French

lsquotastersrsquo

t p Predictors

N Z lsquotastersrsquo

t p

Freshzingy 522 lt 00001 Freshzingy 400 lt 00001

Flintsmo 853 lt 00001 Flintsmo 444 lt 00001

Chalkycalc 666 lt 00001 Chalkycalc 693 lt 00001

Souracid -226 lt 005 Souracid -226 lt 005

Sweet -433 lt 005 Leadgraph 202 lt 005

Bitter 397 lt 00001

PalateWght 537 lt 00001

Influence of wine composition(Parr et al FRIN 2016)

bull Standard parameters + an acidity index

bull pH TA ethanol RS total extract free amp bound SO2

bull Fermentation-derived volatile aroma compounds volatile

organic acids amp IBMP

bull Non-volatile organic acids

bull Tartaric lactic malic shikimic malonic

bull Wine elemental composition (ICP-OES)

bull Mg K Ca Na Rb Sr Al Fe Mn Si La P S Ba Cu Mo Ni Zn

bull Varietal thiols amp volatile sulphur compounds associated

with pungent aromas

Sulphur compounds

bull 3-mercaptohexan-1-ol (3MH) citrusgrapefruit

bull 3-mercaptohexyl acetate (3MHA) passion fruit

bull 4-mercapto-4-methylpentan-2-one (4MMP)

sweatyboxwood

bull Ethyl-2-sulfanylacetate (E2SA) ldquobaked beansrdquo note

bull Benzenemethanethiol (BMT) flinty note

bull Dimethyl sulfide (quince truffle)

bull Hydrogen sulfide (rotten eggs)

bull Meacutethanethiol (stagnant water halitosis)

bull Ethanethiol (onion rubber)

bull Dieacutethyl sulfide

bull Dimeacutethyl disulfide (quince asparagus)

PLSR plot projection of Y variables (M perceived minerality scores) on X variables (chemical compounds in red) and Wines (in green)

Figure 2

MeSH

DMSDMDS

BMTEthyl Acetate

Isoamyl Acetate

Octanoic Acid

Tartaric acid

DL-Lactic acid

Ba

MoZn

Titratable AcidityAcidityIndex

Density

Free SO2

Bound SO2

DMS(2)

BMT (2)Ethyl Acetate (2)

Isoamyl Acetate (2)Octanoic Acid (2)

Tartaric acid (2)

Malonic acid (2)

Ca (2)

S (2)

Ba (2)

Mo (2)Zn (2)

Titratable Acidity (2)AcidityIndex (2)

Density (2)

Free SO2 (2)

Bound SO2 (2)

3MH

Isobutanol

Isoamyl Alcohol

Diethyl succinate

Hexanoic Acid

L-Malic acid

Ca

Na

Mn

Isobutanol (2)

Isoamyl Alcohol (2)

Diethyl succinate (2)

Hexanoic Acid (2)

L-Malic acid (2)

DL-Lactic acid (2)

Na (2)

FR_Minerality

NZ_Minerality

FBCBB

FBCLM

FLCH

FLPC

FSBAGA

FSBI

FSFC

FSHB

NZAVFB

NZAVV

NZLWB

NZLWWHNZRS

NZRSL

NZSVA

NZSVCH

-1

-075

-05

-025

0

025

05

075

1

-1 -075 -05 -025 0 025 05 075 1

t2

t1

t1 amp t2

X

Y

Obs

Aspects of wine composition associated statistically with perception of mineral character in S blanc wines

(Parr et al FRIN 2016)

Positive predictors Negative predictors

French N Z French N Z

Free SO2 Bound SO2 Tartaric acid Isoamyl alcohol (fusel solvent)

Isoamyl

acetate(fruity)

Hexanoic acid (fatty waxy barnyard)

Titratable

acidity

Diethyl succinate (fruity wine-like)

Malic acid Isobutanol(fusel solvent)

Na

Ca

Implications

Not just smart marketingbull Perceived minerality in Sauvignon wine appears

based on data-driven input (wine attributes) bull Characters driving perceived minerality in Sauvignon

ndash Citrus notes and freshzingy character (acid)ndash Absence of passion fruit amp green characters

Caution needed in how the term mineral is usedbull Much between-judge variability in judging intensity

of mineral character in winebull Wine varietal differences may influence how

minerality is perceived in any particular wine bull Wine composition aspects appear complex amp

require further research

Acknowledgement

bull Our tasters in France amp NZ amp wine producers who provided their wines for the study

bull Funding

ndash Grape and Wine Research Programme PFR NZ

ndash New Zealand Winegrowers

ndash Pernod Ricard NZ amp Pernod Ricard Research Centre Paris France

ndash Regional Council of Burgundy

ndash Bureau Interprofessionnel des Vins de Bourgogne and Conseil Interprofessionel des Vins de Bordeaux

ndash Royal Society of New Zealand ISAT Linkages Fund

And thank you for your attention

Page 10: The elusive nature of minerality in - Home | BCWGC elusive nature of minerality in white wine Wendy V. Parr, Ph. D. Lincoln University, Christchurch, New Zealand Minerality? Dominique

How were the wines characterised French Free SortingColours represent MDS clusters

pyrazine

good balance

acidic

varietal character

boxwood

fruit

tropical

mineral

asparagus

expressive aromatics

reductive

cat pee

citrusfloral

herbaceous

bitter

faulty

terroir expressioncreamy

oxidised

unripe

oak

smokey

NZRSL

FSHB

NZAVFB FSFC

FBCLMFSBI

NZRS

FSBAGA

FLCH

FLPCNZSVA

NZLWWH

FBCBB

NZLWB

NZAVV

NZSVCH

-15

-1

-05

0

05

1

-1 -05 0 05 1 15 2 25 3

F2 (

20

50

)

F1 (3900 )

FR axes F1 et F2 5950

How were the wines characterised NZ Free SortingColours represent MDS clusters

FSHB

FBCBB

NZSVCH

FLCH

NZLWBNZLWWH

NZRSNZAVFB

NZAVV

FSBI

FSBAGA

FSFC

FLPC

NZRSL

NZSVA

FBCLM

tropical

herbaceous

acidic reductive

pyrazine

boxwood

ripe

agedcitrus

faulty

complex

unripe

good balance

simplethin oak

varietal character

gooseberry

expressive aromatics

good weight

mineral lack of varietal character

oxidised

grapefruit

lack acidity

-15

-1

-05

0

05

1

-15 -1 -05 0 05 1 15 2

F2 (

15

33

)

F1 (4813 )

NZ_axes F1 et F2 6345

Can mineral be smelled

bull Both cultures reported perceiving minerality via each mode of perception ie

ndash Mineral can be smelled and

ndash Is a palate experience (taste amp mouthfeel)

bull French lsquotastersrsquo relied more on their noses than NZers in their full-tasting judgments of minerality NZers relying equally on olfaction (smelling) and palate phenomena

PCA Mineral intensity judgements in the 3 conditions

O = OrthonasalN = NoseclipG = Global

So which wine attributes predicted perceived mineralityin Sauvignon wine

And was there much consensus across cultures

Regression of Mineral by other descriptors Nose only Multiple Linear Regression alpha lt 005

Predictors

French

lsquotastersrsquo

t p Predictors

N Z lsquotastersrsquo

t p

Citrus 529 lt 00001 Citrus 378 lt 0001

Passionfruit -464 lt 00001 Passionfruit -337 lt 0001

Chalkycalc 675 lt 00001 Chalkycalc 594 lt 00001

Flintsmo 975 lt 00001 Flintsmo 723 lt 00001

Leadgraph 262 lt01 Leadgraph 451 lt 00001

Liking 310 lt 001 Liking 301 lt 001

Freshzingy 251 lt 005 Concentrat -205 lt 005

Iodioyster 209 lt 005

Regression of Mineral by other descriptors Full tasting Multiple Linear Regression alpha lt 005

Predictors

French

lsquotastersrsquo

t p Predictors

N Z lsquotastersrsquo

t p

Citrus 422 lt 00001 Citrus 209 lt 005

Passfruit -212 lt 005 Green -242 lt 005

Bitter 208 lt 005 Bitter 234 lt 005

Chalkycalc 205 lt 005 Chalkycalc 451 lt 00001

Flintsmo 461 lt 00001 Astringent -217 lt 005

Sweet -657 lt 00001 Freshzingy 220 lt 005

Leadgraphite 281 lt01 Herbaceous 223 lt 005

Liking 198 lt 005 ConcWght 248 lt 005

Regression of Mineral by other descriptors Palate only Multiple Linear Regression alpha lt 005

Predictors

French

lsquotastersrsquo

t p Predictors

N Z lsquotastersrsquo

t p

Freshzingy 522 lt 00001 Freshzingy 400 lt 00001

Flintsmo 853 lt 00001 Flintsmo 444 lt 00001

Chalkycalc 666 lt 00001 Chalkycalc 693 lt 00001

Souracid -226 lt 005 Souracid -226 lt 005

Sweet -433 lt 005 Leadgraph 202 lt 005

Bitter 397 lt 00001

PalateWght 537 lt 00001

Influence of wine composition(Parr et al FRIN 2016)

bull Standard parameters + an acidity index

bull pH TA ethanol RS total extract free amp bound SO2

bull Fermentation-derived volatile aroma compounds volatile

organic acids amp IBMP

bull Non-volatile organic acids

bull Tartaric lactic malic shikimic malonic

bull Wine elemental composition (ICP-OES)

bull Mg K Ca Na Rb Sr Al Fe Mn Si La P S Ba Cu Mo Ni Zn

bull Varietal thiols amp volatile sulphur compounds associated

with pungent aromas

Sulphur compounds

bull 3-mercaptohexan-1-ol (3MH) citrusgrapefruit

bull 3-mercaptohexyl acetate (3MHA) passion fruit

bull 4-mercapto-4-methylpentan-2-one (4MMP)

sweatyboxwood

bull Ethyl-2-sulfanylacetate (E2SA) ldquobaked beansrdquo note

bull Benzenemethanethiol (BMT) flinty note

bull Dimethyl sulfide (quince truffle)

bull Hydrogen sulfide (rotten eggs)

bull Meacutethanethiol (stagnant water halitosis)

bull Ethanethiol (onion rubber)

bull Dieacutethyl sulfide

bull Dimeacutethyl disulfide (quince asparagus)

PLSR plot projection of Y variables (M perceived minerality scores) on X variables (chemical compounds in red) and Wines (in green)

Figure 2

MeSH

DMSDMDS

BMTEthyl Acetate

Isoamyl Acetate

Octanoic Acid

Tartaric acid

DL-Lactic acid

Ba

MoZn

Titratable AcidityAcidityIndex

Density

Free SO2

Bound SO2

DMS(2)

BMT (2)Ethyl Acetate (2)

Isoamyl Acetate (2)Octanoic Acid (2)

Tartaric acid (2)

Malonic acid (2)

Ca (2)

S (2)

Ba (2)

Mo (2)Zn (2)

Titratable Acidity (2)AcidityIndex (2)

Density (2)

Free SO2 (2)

Bound SO2 (2)

3MH

Isobutanol

Isoamyl Alcohol

Diethyl succinate

Hexanoic Acid

L-Malic acid

Ca

Na

Mn

Isobutanol (2)

Isoamyl Alcohol (2)

Diethyl succinate (2)

Hexanoic Acid (2)

L-Malic acid (2)

DL-Lactic acid (2)

Na (2)

FR_Minerality

NZ_Minerality

FBCBB

FBCLM

FLCH

FLPC

FSBAGA

FSBI

FSFC

FSHB

NZAVFB

NZAVV

NZLWB

NZLWWHNZRS

NZRSL

NZSVA

NZSVCH

-1

-075

-05

-025

0

025

05

075

1

-1 -075 -05 -025 0 025 05 075 1

t2

t1

t1 amp t2

X

Y

Obs

Aspects of wine composition associated statistically with perception of mineral character in S blanc wines

(Parr et al FRIN 2016)

Positive predictors Negative predictors

French N Z French N Z

Free SO2 Bound SO2 Tartaric acid Isoamyl alcohol (fusel solvent)

Isoamyl

acetate(fruity)

Hexanoic acid (fatty waxy barnyard)

Titratable

acidity

Diethyl succinate (fruity wine-like)

Malic acid Isobutanol(fusel solvent)

Na

Ca

Implications

Not just smart marketingbull Perceived minerality in Sauvignon wine appears

based on data-driven input (wine attributes) bull Characters driving perceived minerality in Sauvignon

ndash Citrus notes and freshzingy character (acid)ndash Absence of passion fruit amp green characters

Caution needed in how the term mineral is usedbull Much between-judge variability in judging intensity

of mineral character in winebull Wine varietal differences may influence how

minerality is perceived in any particular wine bull Wine composition aspects appear complex amp

require further research

Acknowledgement

bull Our tasters in France amp NZ amp wine producers who provided their wines for the study

bull Funding

ndash Grape and Wine Research Programme PFR NZ

ndash New Zealand Winegrowers

ndash Pernod Ricard NZ amp Pernod Ricard Research Centre Paris France

ndash Regional Council of Burgundy

ndash Bureau Interprofessionnel des Vins de Bourgogne and Conseil Interprofessionel des Vins de Bordeaux

ndash Royal Society of New Zealand ISAT Linkages Fund

And thank you for your attention

Page 11: The elusive nature of minerality in - Home | BCWGC elusive nature of minerality in white wine Wendy V. Parr, Ph. D. Lincoln University, Christchurch, New Zealand Minerality? Dominique

How were the wines characterised NZ Free SortingColours represent MDS clusters

FSHB

FBCBB

NZSVCH

FLCH

NZLWBNZLWWH

NZRSNZAVFB

NZAVV

FSBI

FSBAGA

FSFC

FLPC

NZRSL

NZSVA

FBCLM

tropical

herbaceous

acidic reductive

pyrazine

boxwood

ripe

agedcitrus

faulty

complex

unripe

good balance

simplethin oak

varietal character

gooseberry

expressive aromatics

good weight

mineral lack of varietal character

oxidised

grapefruit

lack acidity

-15

-1

-05

0

05

1

-15 -1 -05 0 05 1 15 2

F2 (

15

33

)

F1 (4813 )

NZ_axes F1 et F2 6345

Can mineral be smelled

bull Both cultures reported perceiving minerality via each mode of perception ie

ndash Mineral can be smelled and

ndash Is a palate experience (taste amp mouthfeel)

bull French lsquotastersrsquo relied more on their noses than NZers in their full-tasting judgments of minerality NZers relying equally on olfaction (smelling) and palate phenomena

PCA Mineral intensity judgements in the 3 conditions

O = OrthonasalN = NoseclipG = Global

So which wine attributes predicted perceived mineralityin Sauvignon wine

And was there much consensus across cultures

Regression of Mineral by other descriptors Nose only Multiple Linear Regression alpha lt 005

Predictors

French

lsquotastersrsquo

t p Predictors

N Z lsquotastersrsquo

t p

Citrus 529 lt 00001 Citrus 378 lt 0001

Passionfruit -464 lt 00001 Passionfruit -337 lt 0001

Chalkycalc 675 lt 00001 Chalkycalc 594 lt 00001

Flintsmo 975 lt 00001 Flintsmo 723 lt 00001

Leadgraph 262 lt01 Leadgraph 451 lt 00001

Liking 310 lt 001 Liking 301 lt 001

Freshzingy 251 lt 005 Concentrat -205 lt 005

Iodioyster 209 lt 005

Regression of Mineral by other descriptors Full tasting Multiple Linear Regression alpha lt 005

Predictors

French

lsquotastersrsquo

t p Predictors

N Z lsquotastersrsquo

t p

Citrus 422 lt 00001 Citrus 209 lt 005

Passfruit -212 lt 005 Green -242 lt 005

Bitter 208 lt 005 Bitter 234 lt 005

Chalkycalc 205 lt 005 Chalkycalc 451 lt 00001

Flintsmo 461 lt 00001 Astringent -217 lt 005

Sweet -657 lt 00001 Freshzingy 220 lt 005

Leadgraphite 281 lt01 Herbaceous 223 lt 005

Liking 198 lt 005 ConcWght 248 lt 005

Regression of Mineral by other descriptors Palate only Multiple Linear Regression alpha lt 005

Predictors

French

lsquotastersrsquo

t p Predictors

N Z lsquotastersrsquo

t p

Freshzingy 522 lt 00001 Freshzingy 400 lt 00001

Flintsmo 853 lt 00001 Flintsmo 444 lt 00001

Chalkycalc 666 lt 00001 Chalkycalc 693 lt 00001

Souracid -226 lt 005 Souracid -226 lt 005

Sweet -433 lt 005 Leadgraph 202 lt 005

Bitter 397 lt 00001

PalateWght 537 lt 00001

Influence of wine composition(Parr et al FRIN 2016)

bull Standard parameters + an acidity index

bull pH TA ethanol RS total extract free amp bound SO2

bull Fermentation-derived volatile aroma compounds volatile

organic acids amp IBMP

bull Non-volatile organic acids

bull Tartaric lactic malic shikimic malonic

bull Wine elemental composition (ICP-OES)

bull Mg K Ca Na Rb Sr Al Fe Mn Si La P S Ba Cu Mo Ni Zn

bull Varietal thiols amp volatile sulphur compounds associated

with pungent aromas

Sulphur compounds

bull 3-mercaptohexan-1-ol (3MH) citrusgrapefruit

bull 3-mercaptohexyl acetate (3MHA) passion fruit

bull 4-mercapto-4-methylpentan-2-one (4MMP)

sweatyboxwood

bull Ethyl-2-sulfanylacetate (E2SA) ldquobaked beansrdquo note

bull Benzenemethanethiol (BMT) flinty note

bull Dimethyl sulfide (quince truffle)

bull Hydrogen sulfide (rotten eggs)

bull Meacutethanethiol (stagnant water halitosis)

bull Ethanethiol (onion rubber)

bull Dieacutethyl sulfide

bull Dimeacutethyl disulfide (quince asparagus)

PLSR plot projection of Y variables (M perceived minerality scores) on X variables (chemical compounds in red) and Wines (in green)

Figure 2

MeSH

DMSDMDS

BMTEthyl Acetate

Isoamyl Acetate

Octanoic Acid

Tartaric acid

DL-Lactic acid

Ba

MoZn

Titratable AcidityAcidityIndex

Density

Free SO2

Bound SO2

DMS(2)

BMT (2)Ethyl Acetate (2)

Isoamyl Acetate (2)Octanoic Acid (2)

Tartaric acid (2)

Malonic acid (2)

Ca (2)

S (2)

Ba (2)

Mo (2)Zn (2)

Titratable Acidity (2)AcidityIndex (2)

Density (2)

Free SO2 (2)

Bound SO2 (2)

3MH

Isobutanol

Isoamyl Alcohol

Diethyl succinate

Hexanoic Acid

L-Malic acid

Ca

Na

Mn

Isobutanol (2)

Isoamyl Alcohol (2)

Diethyl succinate (2)

Hexanoic Acid (2)

L-Malic acid (2)

DL-Lactic acid (2)

Na (2)

FR_Minerality

NZ_Minerality

FBCBB

FBCLM

FLCH

FLPC

FSBAGA

FSBI

FSFC

FSHB

NZAVFB

NZAVV

NZLWB

NZLWWHNZRS

NZRSL

NZSVA

NZSVCH

-1

-075

-05

-025

0

025

05

075

1

-1 -075 -05 -025 0 025 05 075 1

t2

t1

t1 amp t2

X

Y

Obs

Aspects of wine composition associated statistically with perception of mineral character in S blanc wines

(Parr et al FRIN 2016)

Positive predictors Negative predictors

French N Z French N Z

Free SO2 Bound SO2 Tartaric acid Isoamyl alcohol (fusel solvent)

Isoamyl

acetate(fruity)

Hexanoic acid (fatty waxy barnyard)

Titratable

acidity

Diethyl succinate (fruity wine-like)

Malic acid Isobutanol(fusel solvent)

Na

Ca

Implications

Not just smart marketingbull Perceived minerality in Sauvignon wine appears

based on data-driven input (wine attributes) bull Characters driving perceived minerality in Sauvignon

ndash Citrus notes and freshzingy character (acid)ndash Absence of passion fruit amp green characters

Caution needed in how the term mineral is usedbull Much between-judge variability in judging intensity

of mineral character in winebull Wine varietal differences may influence how

minerality is perceived in any particular wine bull Wine composition aspects appear complex amp

require further research

Acknowledgement

bull Our tasters in France amp NZ amp wine producers who provided their wines for the study

bull Funding

ndash Grape and Wine Research Programme PFR NZ

ndash New Zealand Winegrowers

ndash Pernod Ricard NZ amp Pernod Ricard Research Centre Paris France

ndash Regional Council of Burgundy

ndash Bureau Interprofessionnel des Vins de Bourgogne and Conseil Interprofessionel des Vins de Bordeaux

ndash Royal Society of New Zealand ISAT Linkages Fund

And thank you for your attention

Page 12: The elusive nature of minerality in - Home | BCWGC elusive nature of minerality in white wine Wendy V. Parr, Ph. D. Lincoln University, Christchurch, New Zealand Minerality? Dominique

Can mineral be smelled

bull Both cultures reported perceiving minerality via each mode of perception ie

ndash Mineral can be smelled and

ndash Is a palate experience (taste amp mouthfeel)

bull French lsquotastersrsquo relied more on their noses than NZers in their full-tasting judgments of minerality NZers relying equally on olfaction (smelling) and palate phenomena

PCA Mineral intensity judgements in the 3 conditions

O = OrthonasalN = NoseclipG = Global

So which wine attributes predicted perceived mineralityin Sauvignon wine

And was there much consensus across cultures

Regression of Mineral by other descriptors Nose only Multiple Linear Regression alpha lt 005

Predictors

French

lsquotastersrsquo

t p Predictors

N Z lsquotastersrsquo

t p

Citrus 529 lt 00001 Citrus 378 lt 0001

Passionfruit -464 lt 00001 Passionfruit -337 lt 0001

Chalkycalc 675 lt 00001 Chalkycalc 594 lt 00001

Flintsmo 975 lt 00001 Flintsmo 723 lt 00001

Leadgraph 262 lt01 Leadgraph 451 lt 00001

Liking 310 lt 001 Liking 301 lt 001

Freshzingy 251 lt 005 Concentrat -205 lt 005

Iodioyster 209 lt 005

Regression of Mineral by other descriptors Full tasting Multiple Linear Regression alpha lt 005

Predictors

French

lsquotastersrsquo

t p Predictors

N Z lsquotastersrsquo

t p

Citrus 422 lt 00001 Citrus 209 lt 005

Passfruit -212 lt 005 Green -242 lt 005

Bitter 208 lt 005 Bitter 234 lt 005

Chalkycalc 205 lt 005 Chalkycalc 451 lt 00001

Flintsmo 461 lt 00001 Astringent -217 lt 005

Sweet -657 lt 00001 Freshzingy 220 lt 005

Leadgraphite 281 lt01 Herbaceous 223 lt 005

Liking 198 lt 005 ConcWght 248 lt 005

Regression of Mineral by other descriptors Palate only Multiple Linear Regression alpha lt 005

Predictors

French

lsquotastersrsquo

t p Predictors

N Z lsquotastersrsquo

t p

Freshzingy 522 lt 00001 Freshzingy 400 lt 00001

Flintsmo 853 lt 00001 Flintsmo 444 lt 00001

Chalkycalc 666 lt 00001 Chalkycalc 693 lt 00001

Souracid -226 lt 005 Souracid -226 lt 005

Sweet -433 lt 005 Leadgraph 202 lt 005

Bitter 397 lt 00001

PalateWght 537 lt 00001

Influence of wine composition(Parr et al FRIN 2016)

bull Standard parameters + an acidity index

bull pH TA ethanol RS total extract free amp bound SO2

bull Fermentation-derived volatile aroma compounds volatile

organic acids amp IBMP

bull Non-volatile organic acids

bull Tartaric lactic malic shikimic malonic

bull Wine elemental composition (ICP-OES)

bull Mg K Ca Na Rb Sr Al Fe Mn Si La P S Ba Cu Mo Ni Zn

bull Varietal thiols amp volatile sulphur compounds associated

with pungent aromas

Sulphur compounds

bull 3-mercaptohexan-1-ol (3MH) citrusgrapefruit

bull 3-mercaptohexyl acetate (3MHA) passion fruit

bull 4-mercapto-4-methylpentan-2-one (4MMP)

sweatyboxwood

bull Ethyl-2-sulfanylacetate (E2SA) ldquobaked beansrdquo note

bull Benzenemethanethiol (BMT) flinty note

bull Dimethyl sulfide (quince truffle)

bull Hydrogen sulfide (rotten eggs)

bull Meacutethanethiol (stagnant water halitosis)

bull Ethanethiol (onion rubber)

bull Dieacutethyl sulfide

bull Dimeacutethyl disulfide (quince asparagus)

PLSR plot projection of Y variables (M perceived minerality scores) on X variables (chemical compounds in red) and Wines (in green)

Figure 2

MeSH

DMSDMDS

BMTEthyl Acetate

Isoamyl Acetate

Octanoic Acid

Tartaric acid

DL-Lactic acid

Ba

MoZn

Titratable AcidityAcidityIndex

Density

Free SO2

Bound SO2

DMS(2)

BMT (2)Ethyl Acetate (2)

Isoamyl Acetate (2)Octanoic Acid (2)

Tartaric acid (2)

Malonic acid (2)

Ca (2)

S (2)

Ba (2)

Mo (2)Zn (2)

Titratable Acidity (2)AcidityIndex (2)

Density (2)

Free SO2 (2)

Bound SO2 (2)

3MH

Isobutanol

Isoamyl Alcohol

Diethyl succinate

Hexanoic Acid

L-Malic acid

Ca

Na

Mn

Isobutanol (2)

Isoamyl Alcohol (2)

Diethyl succinate (2)

Hexanoic Acid (2)

L-Malic acid (2)

DL-Lactic acid (2)

Na (2)

FR_Minerality

NZ_Minerality

FBCBB

FBCLM

FLCH

FLPC

FSBAGA

FSBI

FSFC

FSHB

NZAVFB

NZAVV

NZLWB

NZLWWHNZRS

NZRSL

NZSVA

NZSVCH

-1

-075

-05

-025

0

025

05

075

1

-1 -075 -05 -025 0 025 05 075 1

t2

t1

t1 amp t2

X

Y

Obs

Aspects of wine composition associated statistically with perception of mineral character in S blanc wines

(Parr et al FRIN 2016)

Positive predictors Negative predictors

French N Z French N Z

Free SO2 Bound SO2 Tartaric acid Isoamyl alcohol (fusel solvent)

Isoamyl

acetate(fruity)

Hexanoic acid (fatty waxy barnyard)

Titratable

acidity

Diethyl succinate (fruity wine-like)

Malic acid Isobutanol(fusel solvent)

Na

Ca

Implications

Not just smart marketingbull Perceived minerality in Sauvignon wine appears

based on data-driven input (wine attributes) bull Characters driving perceived minerality in Sauvignon

ndash Citrus notes and freshzingy character (acid)ndash Absence of passion fruit amp green characters

Caution needed in how the term mineral is usedbull Much between-judge variability in judging intensity

of mineral character in winebull Wine varietal differences may influence how

minerality is perceived in any particular wine bull Wine composition aspects appear complex amp

require further research

Acknowledgement

bull Our tasters in France amp NZ amp wine producers who provided their wines for the study

bull Funding

ndash Grape and Wine Research Programme PFR NZ

ndash New Zealand Winegrowers

ndash Pernod Ricard NZ amp Pernod Ricard Research Centre Paris France

ndash Regional Council of Burgundy

ndash Bureau Interprofessionnel des Vins de Bourgogne and Conseil Interprofessionel des Vins de Bordeaux

ndash Royal Society of New Zealand ISAT Linkages Fund

And thank you for your attention

Page 13: The elusive nature of minerality in - Home | BCWGC elusive nature of minerality in white wine Wendy V. Parr, Ph. D. Lincoln University, Christchurch, New Zealand Minerality? Dominique

PCA Mineral intensity judgements in the 3 conditions

O = OrthonasalN = NoseclipG = Global

So which wine attributes predicted perceived mineralityin Sauvignon wine

And was there much consensus across cultures

Regression of Mineral by other descriptors Nose only Multiple Linear Regression alpha lt 005

Predictors

French

lsquotastersrsquo

t p Predictors

N Z lsquotastersrsquo

t p

Citrus 529 lt 00001 Citrus 378 lt 0001

Passionfruit -464 lt 00001 Passionfruit -337 lt 0001

Chalkycalc 675 lt 00001 Chalkycalc 594 lt 00001

Flintsmo 975 lt 00001 Flintsmo 723 lt 00001

Leadgraph 262 lt01 Leadgraph 451 lt 00001

Liking 310 lt 001 Liking 301 lt 001

Freshzingy 251 lt 005 Concentrat -205 lt 005

Iodioyster 209 lt 005

Regression of Mineral by other descriptors Full tasting Multiple Linear Regression alpha lt 005

Predictors

French

lsquotastersrsquo

t p Predictors

N Z lsquotastersrsquo

t p

Citrus 422 lt 00001 Citrus 209 lt 005

Passfruit -212 lt 005 Green -242 lt 005

Bitter 208 lt 005 Bitter 234 lt 005

Chalkycalc 205 lt 005 Chalkycalc 451 lt 00001

Flintsmo 461 lt 00001 Astringent -217 lt 005

Sweet -657 lt 00001 Freshzingy 220 lt 005

Leadgraphite 281 lt01 Herbaceous 223 lt 005

Liking 198 lt 005 ConcWght 248 lt 005

Regression of Mineral by other descriptors Palate only Multiple Linear Regression alpha lt 005

Predictors

French

lsquotastersrsquo

t p Predictors

N Z lsquotastersrsquo

t p

Freshzingy 522 lt 00001 Freshzingy 400 lt 00001

Flintsmo 853 lt 00001 Flintsmo 444 lt 00001

Chalkycalc 666 lt 00001 Chalkycalc 693 lt 00001

Souracid -226 lt 005 Souracid -226 lt 005

Sweet -433 lt 005 Leadgraph 202 lt 005

Bitter 397 lt 00001

PalateWght 537 lt 00001

Influence of wine composition(Parr et al FRIN 2016)

bull Standard parameters + an acidity index

bull pH TA ethanol RS total extract free amp bound SO2

bull Fermentation-derived volatile aroma compounds volatile

organic acids amp IBMP

bull Non-volatile organic acids

bull Tartaric lactic malic shikimic malonic

bull Wine elemental composition (ICP-OES)

bull Mg K Ca Na Rb Sr Al Fe Mn Si La P S Ba Cu Mo Ni Zn

bull Varietal thiols amp volatile sulphur compounds associated

with pungent aromas

Sulphur compounds

bull 3-mercaptohexan-1-ol (3MH) citrusgrapefruit

bull 3-mercaptohexyl acetate (3MHA) passion fruit

bull 4-mercapto-4-methylpentan-2-one (4MMP)

sweatyboxwood

bull Ethyl-2-sulfanylacetate (E2SA) ldquobaked beansrdquo note

bull Benzenemethanethiol (BMT) flinty note

bull Dimethyl sulfide (quince truffle)

bull Hydrogen sulfide (rotten eggs)

bull Meacutethanethiol (stagnant water halitosis)

bull Ethanethiol (onion rubber)

bull Dieacutethyl sulfide

bull Dimeacutethyl disulfide (quince asparagus)

PLSR plot projection of Y variables (M perceived minerality scores) on X variables (chemical compounds in red) and Wines (in green)

Figure 2

MeSH

DMSDMDS

BMTEthyl Acetate

Isoamyl Acetate

Octanoic Acid

Tartaric acid

DL-Lactic acid

Ba

MoZn

Titratable AcidityAcidityIndex

Density

Free SO2

Bound SO2

DMS(2)

BMT (2)Ethyl Acetate (2)

Isoamyl Acetate (2)Octanoic Acid (2)

Tartaric acid (2)

Malonic acid (2)

Ca (2)

S (2)

Ba (2)

Mo (2)Zn (2)

Titratable Acidity (2)AcidityIndex (2)

Density (2)

Free SO2 (2)

Bound SO2 (2)

3MH

Isobutanol

Isoamyl Alcohol

Diethyl succinate

Hexanoic Acid

L-Malic acid

Ca

Na

Mn

Isobutanol (2)

Isoamyl Alcohol (2)

Diethyl succinate (2)

Hexanoic Acid (2)

L-Malic acid (2)

DL-Lactic acid (2)

Na (2)

FR_Minerality

NZ_Minerality

FBCBB

FBCLM

FLCH

FLPC

FSBAGA

FSBI

FSFC

FSHB

NZAVFB

NZAVV

NZLWB

NZLWWHNZRS

NZRSL

NZSVA

NZSVCH

-1

-075

-05

-025

0

025

05

075

1

-1 -075 -05 -025 0 025 05 075 1

t2

t1

t1 amp t2

X

Y

Obs

Aspects of wine composition associated statistically with perception of mineral character in S blanc wines

(Parr et al FRIN 2016)

Positive predictors Negative predictors

French N Z French N Z

Free SO2 Bound SO2 Tartaric acid Isoamyl alcohol (fusel solvent)

Isoamyl

acetate(fruity)

Hexanoic acid (fatty waxy barnyard)

Titratable

acidity

Diethyl succinate (fruity wine-like)

Malic acid Isobutanol(fusel solvent)

Na

Ca

Implications

Not just smart marketingbull Perceived minerality in Sauvignon wine appears

based on data-driven input (wine attributes) bull Characters driving perceived minerality in Sauvignon

ndash Citrus notes and freshzingy character (acid)ndash Absence of passion fruit amp green characters

Caution needed in how the term mineral is usedbull Much between-judge variability in judging intensity

of mineral character in winebull Wine varietal differences may influence how

minerality is perceived in any particular wine bull Wine composition aspects appear complex amp

require further research

Acknowledgement

bull Our tasters in France amp NZ amp wine producers who provided their wines for the study

bull Funding

ndash Grape and Wine Research Programme PFR NZ

ndash New Zealand Winegrowers

ndash Pernod Ricard NZ amp Pernod Ricard Research Centre Paris France

ndash Regional Council of Burgundy

ndash Bureau Interprofessionnel des Vins de Bourgogne and Conseil Interprofessionel des Vins de Bordeaux

ndash Royal Society of New Zealand ISAT Linkages Fund

And thank you for your attention

Page 14: The elusive nature of minerality in - Home | BCWGC elusive nature of minerality in white wine Wendy V. Parr, Ph. D. Lincoln University, Christchurch, New Zealand Minerality? Dominique

So which wine attributes predicted perceived mineralityin Sauvignon wine

And was there much consensus across cultures

Regression of Mineral by other descriptors Nose only Multiple Linear Regression alpha lt 005

Predictors

French

lsquotastersrsquo

t p Predictors

N Z lsquotastersrsquo

t p

Citrus 529 lt 00001 Citrus 378 lt 0001

Passionfruit -464 lt 00001 Passionfruit -337 lt 0001

Chalkycalc 675 lt 00001 Chalkycalc 594 lt 00001

Flintsmo 975 lt 00001 Flintsmo 723 lt 00001

Leadgraph 262 lt01 Leadgraph 451 lt 00001

Liking 310 lt 001 Liking 301 lt 001

Freshzingy 251 lt 005 Concentrat -205 lt 005

Iodioyster 209 lt 005

Regression of Mineral by other descriptors Full tasting Multiple Linear Regression alpha lt 005

Predictors

French

lsquotastersrsquo

t p Predictors

N Z lsquotastersrsquo

t p

Citrus 422 lt 00001 Citrus 209 lt 005

Passfruit -212 lt 005 Green -242 lt 005

Bitter 208 lt 005 Bitter 234 lt 005

Chalkycalc 205 lt 005 Chalkycalc 451 lt 00001

Flintsmo 461 lt 00001 Astringent -217 lt 005

Sweet -657 lt 00001 Freshzingy 220 lt 005

Leadgraphite 281 lt01 Herbaceous 223 lt 005

Liking 198 lt 005 ConcWght 248 lt 005

Regression of Mineral by other descriptors Palate only Multiple Linear Regression alpha lt 005

Predictors

French

lsquotastersrsquo

t p Predictors

N Z lsquotastersrsquo

t p

Freshzingy 522 lt 00001 Freshzingy 400 lt 00001

Flintsmo 853 lt 00001 Flintsmo 444 lt 00001

Chalkycalc 666 lt 00001 Chalkycalc 693 lt 00001

Souracid -226 lt 005 Souracid -226 lt 005

Sweet -433 lt 005 Leadgraph 202 lt 005

Bitter 397 lt 00001

PalateWght 537 lt 00001

Influence of wine composition(Parr et al FRIN 2016)

bull Standard parameters + an acidity index

bull pH TA ethanol RS total extract free amp bound SO2

bull Fermentation-derived volatile aroma compounds volatile

organic acids amp IBMP

bull Non-volatile organic acids

bull Tartaric lactic malic shikimic malonic

bull Wine elemental composition (ICP-OES)

bull Mg K Ca Na Rb Sr Al Fe Mn Si La P S Ba Cu Mo Ni Zn

bull Varietal thiols amp volatile sulphur compounds associated

with pungent aromas

Sulphur compounds

bull 3-mercaptohexan-1-ol (3MH) citrusgrapefruit

bull 3-mercaptohexyl acetate (3MHA) passion fruit

bull 4-mercapto-4-methylpentan-2-one (4MMP)

sweatyboxwood

bull Ethyl-2-sulfanylacetate (E2SA) ldquobaked beansrdquo note

bull Benzenemethanethiol (BMT) flinty note

bull Dimethyl sulfide (quince truffle)

bull Hydrogen sulfide (rotten eggs)

bull Meacutethanethiol (stagnant water halitosis)

bull Ethanethiol (onion rubber)

bull Dieacutethyl sulfide

bull Dimeacutethyl disulfide (quince asparagus)

PLSR plot projection of Y variables (M perceived minerality scores) on X variables (chemical compounds in red) and Wines (in green)

Figure 2

MeSH

DMSDMDS

BMTEthyl Acetate

Isoamyl Acetate

Octanoic Acid

Tartaric acid

DL-Lactic acid

Ba

MoZn

Titratable AcidityAcidityIndex

Density

Free SO2

Bound SO2

DMS(2)

BMT (2)Ethyl Acetate (2)

Isoamyl Acetate (2)Octanoic Acid (2)

Tartaric acid (2)

Malonic acid (2)

Ca (2)

S (2)

Ba (2)

Mo (2)Zn (2)

Titratable Acidity (2)AcidityIndex (2)

Density (2)

Free SO2 (2)

Bound SO2 (2)

3MH

Isobutanol

Isoamyl Alcohol

Diethyl succinate

Hexanoic Acid

L-Malic acid

Ca

Na

Mn

Isobutanol (2)

Isoamyl Alcohol (2)

Diethyl succinate (2)

Hexanoic Acid (2)

L-Malic acid (2)

DL-Lactic acid (2)

Na (2)

FR_Minerality

NZ_Minerality

FBCBB

FBCLM

FLCH

FLPC

FSBAGA

FSBI

FSFC

FSHB

NZAVFB

NZAVV

NZLWB

NZLWWHNZRS

NZRSL

NZSVA

NZSVCH

-1

-075

-05

-025

0

025

05

075

1

-1 -075 -05 -025 0 025 05 075 1

t2

t1

t1 amp t2

X

Y

Obs

Aspects of wine composition associated statistically with perception of mineral character in S blanc wines

(Parr et al FRIN 2016)

Positive predictors Negative predictors

French N Z French N Z

Free SO2 Bound SO2 Tartaric acid Isoamyl alcohol (fusel solvent)

Isoamyl

acetate(fruity)

Hexanoic acid (fatty waxy barnyard)

Titratable

acidity

Diethyl succinate (fruity wine-like)

Malic acid Isobutanol(fusel solvent)

Na

Ca

Implications

Not just smart marketingbull Perceived minerality in Sauvignon wine appears

based on data-driven input (wine attributes) bull Characters driving perceived minerality in Sauvignon

ndash Citrus notes and freshzingy character (acid)ndash Absence of passion fruit amp green characters

Caution needed in how the term mineral is usedbull Much between-judge variability in judging intensity

of mineral character in winebull Wine varietal differences may influence how

minerality is perceived in any particular wine bull Wine composition aspects appear complex amp

require further research

Acknowledgement

bull Our tasters in France amp NZ amp wine producers who provided their wines for the study

bull Funding

ndash Grape and Wine Research Programme PFR NZ

ndash New Zealand Winegrowers

ndash Pernod Ricard NZ amp Pernod Ricard Research Centre Paris France

ndash Regional Council of Burgundy

ndash Bureau Interprofessionnel des Vins de Bourgogne and Conseil Interprofessionel des Vins de Bordeaux

ndash Royal Society of New Zealand ISAT Linkages Fund

And thank you for your attention

Page 15: The elusive nature of minerality in - Home | BCWGC elusive nature of minerality in white wine Wendy V. Parr, Ph. D. Lincoln University, Christchurch, New Zealand Minerality? Dominique

Regression of Mineral by other descriptors Nose only Multiple Linear Regression alpha lt 005

Predictors

French

lsquotastersrsquo

t p Predictors

N Z lsquotastersrsquo

t p

Citrus 529 lt 00001 Citrus 378 lt 0001

Passionfruit -464 lt 00001 Passionfruit -337 lt 0001

Chalkycalc 675 lt 00001 Chalkycalc 594 lt 00001

Flintsmo 975 lt 00001 Flintsmo 723 lt 00001

Leadgraph 262 lt01 Leadgraph 451 lt 00001

Liking 310 lt 001 Liking 301 lt 001

Freshzingy 251 lt 005 Concentrat -205 lt 005

Iodioyster 209 lt 005

Regression of Mineral by other descriptors Full tasting Multiple Linear Regression alpha lt 005

Predictors

French

lsquotastersrsquo

t p Predictors

N Z lsquotastersrsquo

t p

Citrus 422 lt 00001 Citrus 209 lt 005

Passfruit -212 lt 005 Green -242 lt 005

Bitter 208 lt 005 Bitter 234 lt 005

Chalkycalc 205 lt 005 Chalkycalc 451 lt 00001

Flintsmo 461 lt 00001 Astringent -217 lt 005

Sweet -657 lt 00001 Freshzingy 220 lt 005

Leadgraphite 281 lt01 Herbaceous 223 lt 005

Liking 198 lt 005 ConcWght 248 lt 005

Regression of Mineral by other descriptors Palate only Multiple Linear Regression alpha lt 005

Predictors

French

lsquotastersrsquo

t p Predictors

N Z lsquotastersrsquo

t p

Freshzingy 522 lt 00001 Freshzingy 400 lt 00001

Flintsmo 853 lt 00001 Flintsmo 444 lt 00001

Chalkycalc 666 lt 00001 Chalkycalc 693 lt 00001

Souracid -226 lt 005 Souracid -226 lt 005

Sweet -433 lt 005 Leadgraph 202 lt 005

Bitter 397 lt 00001

PalateWght 537 lt 00001

Influence of wine composition(Parr et al FRIN 2016)

bull Standard parameters + an acidity index

bull pH TA ethanol RS total extract free amp bound SO2

bull Fermentation-derived volatile aroma compounds volatile

organic acids amp IBMP

bull Non-volatile organic acids

bull Tartaric lactic malic shikimic malonic

bull Wine elemental composition (ICP-OES)

bull Mg K Ca Na Rb Sr Al Fe Mn Si La P S Ba Cu Mo Ni Zn

bull Varietal thiols amp volatile sulphur compounds associated

with pungent aromas

Sulphur compounds

bull 3-mercaptohexan-1-ol (3MH) citrusgrapefruit

bull 3-mercaptohexyl acetate (3MHA) passion fruit

bull 4-mercapto-4-methylpentan-2-one (4MMP)

sweatyboxwood

bull Ethyl-2-sulfanylacetate (E2SA) ldquobaked beansrdquo note

bull Benzenemethanethiol (BMT) flinty note

bull Dimethyl sulfide (quince truffle)

bull Hydrogen sulfide (rotten eggs)

bull Meacutethanethiol (stagnant water halitosis)

bull Ethanethiol (onion rubber)

bull Dieacutethyl sulfide

bull Dimeacutethyl disulfide (quince asparagus)

PLSR plot projection of Y variables (M perceived minerality scores) on X variables (chemical compounds in red) and Wines (in green)

Figure 2

MeSH

DMSDMDS

BMTEthyl Acetate

Isoamyl Acetate

Octanoic Acid

Tartaric acid

DL-Lactic acid

Ba

MoZn

Titratable AcidityAcidityIndex

Density

Free SO2

Bound SO2

DMS(2)

BMT (2)Ethyl Acetate (2)

Isoamyl Acetate (2)Octanoic Acid (2)

Tartaric acid (2)

Malonic acid (2)

Ca (2)

S (2)

Ba (2)

Mo (2)Zn (2)

Titratable Acidity (2)AcidityIndex (2)

Density (2)

Free SO2 (2)

Bound SO2 (2)

3MH

Isobutanol

Isoamyl Alcohol

Diethyl succinate

Hexanoic Acid

L-Malic acid

Ca

Na

Mn

Isobutanol (2)

Isoamyl Alcohol (2)

Diethyl succinate (2)

Hexanoic Acid (2)

L-Malic acid (2)

DL-Lactic acid (2)

Na (2)

FR_Minerality

NZ_Minerality

FBCBB

FBCLM

FLCH

FLPC

FSBAGA

FSBI

FSFC

FSHB

NZAVFB

NZAVV

NZLWB

NZLWWHNZRS

NZRSL

NZSVA

NZSVCH

-1

-075

-05

-025

0

025

05

075

1

-1 -075 -05 -025 0 025 05 075 1

t2

t1

t1 amp t2

X

Y

Obs

Aspects of wine composition associated statistically with perception of mineral character in S blanc wines

(Parr et al FRIN 2016)

Positive predictors Negative predictors

French N Z French N Z

Free SO2 Bound SO2 Tartaric acid Isoamyl alcohol (fusel solvent)

Isoamyl

acetate(fruity)

Hexanoic acid (fatty waxy barnyard)

Titratable

acidity

Diethyl succinate (fruity wine-like)

Malic acid Isobutanol(fusel solvent)

Na

Ca

Implications

Not just smart marketingbull Perceived minerality in Sauvignon wine appears

based on data-driven input (wine attributes) bull Characters driving perceived minerality in Sauvignon

ndash Citrus notes and freshzingy character (acid)ndash Absence of passion fruit amp green characters

Caution needed in how the term mineral is usedbull Much between-judge variability in judging intensity

of mineral character in winebull Wine varietal differences may influence how

minerality is perceived in any particular wine bull Wine composition aspects appear complex amp

require further research

Acknowledgement

bull Our tasters in France amp NZ amp wine producers who provided their wines for the study

bull Funding

ndash Grape and Wine Research Programme PFR NZ

ndash New Zealand Winegrowers

ndash Pernod Ricard NZ amp Pernod Ricard Research Centre Paris France

ndash Regional Council of Burgundy

ndash Bureau Interprofessionnel des Vins de Bourgogne and Conseil Interprofessionel des Vins de Bordeaux

ndash Royal Society of New Zealand ISAT Linkages Fund

And thank you for your attention

Page 16: The elusive nature of minerality in - Home | BCWGC elusive nature of minerality in white wine Wendy V. Parr, Ph. D. Lincoln University, Christchurch, New Zealand Minerality? Dominique

Regression of Mineral by other descriptors Full tasting Multiple Linear Regression alpha lt 005

Predictors

French

lsquotastersrsquo

t p Predictors

N Z lsquotastersrsquo

t p

Citrus 422 lt 00001 Citrus 209 lt 005

Passfruit -212 lt 005 Green -242 lt 005

Bitter 208 lt 005 Bitter 234 lt 005

Chalkycalc 205 lt 005 Chalkycalc 451 lt 00001

Flintsmo 461 lt 00001 Astringent -217 lt 005

Sweet -657 lt 00001 Freshzingy 220 lt 005

Leadgraphite 281 lt01 Herbaceous 223 lt 005

Liking 198 lt 005 ConcWght 248 lt 005

Regression of Mineral by other descriptors Palate only Multiple Linear Regression alpha lt 005

Predictors

French

lsquotastersrsquo

t p Predictors

N Z lsquotastersrsquo

t p

Freshzingy 522 lt 00001 Freshzingy 400 lt 00001

Flintsmo 853 lt 00001 Flintsmo 444 lt 00001

Chalkycalc 666 lt 00001 Chalkycalc 693 lt 00001

Souracid -226 lt 005 Souracid -226 lt 005

Sweet -433 lt 005 Leadgraph 202 lt 005

Bitter 397 lt 00001

PalateWght 537 lt 00001

Influence of wine composition(Parr et al FRIN 2016)

bull Standard parameters + an acidity index

bull pH TA ethanol RS total extract free amp bound SO2

bull Fermentation-derived volatile aroma compounds volatile

organic acids amp IBMP

bull Non-volatile organic acids

bull Tartaric lactic malic shikimic malonic

bull Wine elemental composition (ICP-OES)

bull Mg K Ca Na Rb Sr Al Fe Mn Si La P S Ba Cu Mo Ni Zn

bull Varietal thiols amp volatile sulphur compounds associated

with pungent aromas

Sulphur compounds

bull 3-mercaptohexan-1-ol (3MH) citrusgrapefruit

bull 3-mercaptohexyl acetate (3MHA) passion fruit

bull 4-mercapto-4-methylpentan-2-one (4MMP)

sweatyboxwood

bull Ethyl-2-sulfanylacetate (E2SA) ldquobaked beansrdquo note

bull Benzenemethanethiol (BMT) flinty note

bull Dimethyl sulfide (quince truffle)

bull Hydrogen sulfide (rotten eggs)

bull Meacutethanethiol (stagnant water halitosis)

bull Ethanethiol (onion rubber)

bull Dieacutethyl sulfide

bull Dimeacutethyl disulfide (quince asparagus)

PLSR plot projection of Y variables (M perceived minerality scores) on X variables (chemical compounds in red) and Wines (in green)

Figure 2

MeSH

DMSDMDS

BMTEthyl Acetate

Isoamyl Acetate

Octanoic Acid

Tartaric acid

DL-Lactic acid

Ba

MoZn

Titratable AcidityAcidityIndex

Density

Free SO2

Bound SO2

DMS(2)

BMT (2)Ethyl Acetate (2)

Isoamyl Acetate (2)Octanoic Acid (2)

Tartaric acid (2)

Malonic acid (2)

Ca (2)

S (2)

Ba (2)

Mo (2)Zn (2)

Titratable Acidity (2)AcidityIndex (2)

Density (2)

Free SO2 (2)

Bound SO2 (2)

3MH

Isobutanol

Isoamyl Alcohol

Diethyl succinate

Hexanoic Acid

L-Malic acid

Ca

Na

Mn

Isobutanol (2)

Isoamyl Alcohol (2)

Diethyl succinate (2)

Hexanoic Acid (2)

L-Malic acid (2)

DL-Lactic acid (2)

Na (2)

FR_Minerality

NZ_Minerality

FBCBB

FBCLM

FLCH

FLPC

FSBAGA

FSBI

FSFC

FSHB

NZAVFB

NZAVV

NZLWB

NZLWWHNZRS

NZRSL

NZSVA

NZSVCH

-1

-075

-05

-025

0

025

05

075

1

-1 -075 -05 -025 0 025 05 075 1

t2

t1

t1 amp t2

X

Y

Obs

Aspects of wine composition associated statistically with perception of mineral character in S blanc wines

(Parr et al FRIN 2016)

Positive predictors Negative predictors

French N Z French N Z

Free SO2 Bound SO2 Tartaric acid Isoamyl alcohol (fusel solvent)

Isoamyl

acetate(fruity)

Hexanoic acid (fatty waxy barnyard)

Titratable

acidity

Diethyl succinate (fruity wine-like)

Malic acid Isobutanol(fusel solvent)

Na

Ca

Implications

Not just smart marketingbull Perceived minerality in Sauvignon wine appears

based on data-driven input (wine attributes) bull Characters driving perceived minerality in Sauvignon

ndash Citrus notes and freshzingy character (acid)ndash Absence of passion fruit amp green characters

Caution needed in how the term mineral is usedbull Much between-judge variability in judging intensity

of mineral character in winebull Wine varietal differences may influence how

minerality is perceived in any particular wine bull Wine composition aspects appear complex amp

require further research

Acknowledgement

bull Our tasters in France amp NZ amp wine producers who provided their wines for the study

bull Funding

ndash Grape and Wine Research Programme PFR NZ

ndash New Zealand Winegrowers

ndash Pernod Ricard NZ amp Pernod Ricard Research Centre Paris France

ndash Regional Council of Burgundy

ndash Bureau Interprofessionnel des Vins de Bourgogne and Conseil Interprofessionel des Vins de Bordeaux

ndash Royal Society of New Zealand ISAT Linkages Fund

And thank you for your attention

Page 17: The elusive nature of minerality in - Home | BCWGC elusive nature of minerality in white wine Wendy V. Parr, Ph. D. Lincoln University, Christchurch, New Zealand Minerality? Dominique

Regression of Mineral by other descriptors Palate only Multiple Linear Regression alpha lt 005

Predictors

French

lsquotastersrsquo

t p Predictors

N Z lsquotastersrsquo

t p

Freshzingy 522 lt 00001 Freshzingy 400 lt 00001

Flintsmo 853 lt 00001 Flintsmo 444 lt 00001

Chalkycalc 666 lt 00001 Chalkycalc 693 lt 00001

Souracid -226 lt 005 Souracid -226 lt 005

Sweet -433 lt 005 Leadgraph 202 lt 005

Bitter 397 lt 00001

PalateWght 537 lt 00001

Influence of wine composition(Parr et al FRIN 2016)

bull Standard parameters + an acidity index

bull pH TA ethanol RS total extract free amp bound SO2

bull Fermentation-derived volatile aroma compounds volatile

organic acids amp IBMP

bull Non-volatile organic acids

bull Tartaric lactic malic shikimic malonic

bull Wine elemental composition (ICP-OES)

bull Mg K Ca Na Rb Sr Al Fe Mn Si La P S Ba Cu Mo Ni Zn

bull Varietal thiols amp volatile sulphur compounds associated

with pungent aromas

Sulphur compounds

bull 3-mercaptohexan-1-ol (3MH) citrusgrapefruit

bull 3-mercaptohexyl acetate (3MHA) passion fruit

bull 4-mercapto-4-methylpentan-2-one (4MMP)

sweatyboxwood

bull Ethyl-2-sulfanylacetate (E2SA) ldquobaked beansrdquo note

bull Benzenemethanethiol (BMT) flinty note

bull Dimethyl sulfide (quince truffle)

bull Hydrogen sulfide (rotten eggs)

bull Meacutethanethiol (stagnant water halitosis)

bull Ethanethiol (onion rubber)

bull Dieacutethyl sulfide

bull Dimeacutethyl disulfide (quince asparagus)

PLSR plot projection of Y variables (M perceived minerality scores) on X variables (chemical compounds in red) and Wines (in green)

Figure 2

MeSH

DMSDMDS

BMTEthyl Acetate

Isoamyl Acetate

Octanoic Acid

Tartaric acid

DL-Lactic acid

Ba

MoZn

Titratable AcidityAcidityIndex

Density

Free SO2

Bound SO2

DMS(2)

BMT (2)Ethyl Acetate (2)

Isoamyl Acetate (2)Octanoic Acid (2)

Tartaric acid (2)

Malonic acid (2)

Ca (2)

S (2)

Ba (2)

Mo (2)Zn (2)

Titratable Acidity (2)AcidityIndex (2)

Density (2)

Free SO2 (2)

Bound SO2 (2)

3MH

Isobutanol

Isoamyl Alcohol

Diethyl succinate

Hexanoic Acid

L-Malic acid

Ca

Na

Mn

Isobutanol (2)

Isoamyl Alcohol (2)

Diethyl succinate (2)

Hexanoic Acid (2)

L-Malic acid (2)

DL-Lactic acid (2)

Na (2)

FR_Minerality

NZ_Minerality

FBCBB

FBCLM

FLCH

FLPC

FSBAGA

FSBI

FSFC

FSHB

NZAVFB

NZAVV

NZLWB

NZLWWHNZRS

NZRSL

NZSVA

NZSVCH

-1

-075

-05

-025

0

025

05

075

1

-1 -075 -05 -025 0 025 05 075 1

t2

t1

t1 amp t2

X

Y

Obs

Aspects of wine composition associated statistically with perception of mineral character in S blanc wines

(Parr et al FRIN 2016)

Positive predictors Negative predictors

French N Z French N Z

Free SO2 Bound SO2 Tartaric acid Isoamyl alcohol (fusel solvent)

Isoamyl

acetate(fruity)

Hexanoic acid (fatty waxy barnyard)

Titratable

acidity

Diethyl succinate (fruity wine-like)

Malic acid Isobutanol(fusel solvent)

Na

Ca

Implications

Not just smart marketingbull Perceived minerality in Sauvignon wine appears

based on data-driven input (wine attributes) bull Characters driving perceived minerality in Sauvignon

ndash Citrus notes and freshzingy character (acid)ndash Absence of passion fruit amp green characters

Caution needed in how the term mineral is usedbull Much between-judge variability in judging intensity

of mineral character in winebull Wine varietal differences may influence how

minerality is perceived in any particular wine bull Wine composition aspects appear complex amp

require further research

Acknowledgement

bull Our tasters in France amp NZ amp wine producers who provided their wines for the study

bull Funding

ndash Grape and Wine Research Programme PFR NZ

ndash New Zealand Winegrowers

ndash Pernod Ricard NZ amp Pernod Ricard Research Centre Paris France

ndash Regional Council of Burgundy

ndash Bureau Interprofessionnel des Vins de Bourgogne and Conseil Interprofessionel des Vins de Bordeaux

ndash Royal Society of New Zealand ISAT Linkages Fund

And thank you for your attention

Page 18: The elusive nature of minerality in - Home | BCWGC elusive nature of minerality in white wine Wendy V. Parr, Ph. D. Lincoln University, Christchurch, New Zealand Minerality? Dominique

Influence of wine composition(Parr et al FRIN 2016)

bull Standard parameters + an acidity index

bull pH TA ethanol RS total extract free amp bound SO2

bull Fermentation-derived volatile aroma compounds volatile

organic acids amp IBMP

bull Non-volatile organic acids

bull Tartaric lactic malic shikimic malonic

bull Wine elemental composition (ICP-OES)

bull Mg K Ca Na Rb Sr Al Fe Mn Si La P S Ba Cu Mo Ni Zn

bull Varietal thiols amp volatile sulphur compounds associated

with pungent aromas

Sulphur compounds

bull 3-mercaptohexan-1-ol (3MH) citrusgrapefruit

bull 3-mercaptohexyl acetate (3MHA) passion fruit

bull 4-mercapto-4-methylpentan-2-one (4MMP)

sweatyboxwood

bull Ethyl-2-sulfanylacetate (E2SA) ldquobaked beansrdquo note

bull Benzenemethanethiol (BMT) flinty note

bull Dimethyl sulfide (quince truffle)

bull Hydrogen sulfide (rotten eggs)

bull Meacutethanethiol (stagnant water halitosis)

bull Ethanethiol (onion rubber)

bull Dieacutethyl sulfide

bull Dimeacutethyl disulfide (quince asparagus)

PLSR plot projection of Y variables (M perceived minerality scores) on X variables (chemical compounds in red) and Wines (in green)

Figure 2

MeSH

DMSDMDS

BMTEthyl Acetate

Isoamyl Acetate

Octanoic Acid

Tartaric acid

DL-Lactic acid

Ba

MoZn

Titratable AcidityAcidityIndex

Density

Free SO2

Bound SO2

DMS(2)

BMT (2)Ethyl Acetate (2)

Isoamyl Acetate (2)Octanoic Acid (2)

Tartaric acid (2)

Malonic acid (2)

Ca (2)

S (2)

Ba (2)

Mo (2)Zn (2)

Titratable Acidity (2)AcidityIndex (2)

Density (2)

Free SO2 (2)

Bound SO2 (2)

3MH

Isobutanol

Isoamyl Alcohol

Diethyl succinate

Hexanoic Acid

L-Malic acid

Ca

Na

Mn

Isobutanol (2)

Isoamyl Alcohol (2)

Diethyl succinate (2)

Hexanoic Acid (2)

L-Malic acid (2)

DL-Lactic acid (2)

Na (2)

FR_Minerality

NZ_Minerality

FBCBB

FBCLM

FLCH

FLPC

FSBAGA

FSBI

FSFC

FSHB

NZAVFB

NZAVV

NZLWB

NZLWWHNZRS

NZRSL

NZSVA

NZSVCH

-1

-075

-05

-025

0

025

05

075

1

-1 -075 -05 -025 0 025 05 075 1

t2

t1

t1 amp t2

X

Y

Obs

Aspects of wine composition associated statistically with perception of mineral character in S blanc wines

(Parr et al FRIN 2016)

Positive predictors Negative predictors

French N Z French N Z

Free SO2 Bound SO2 Tartaric acid Isoamyl alcohol (fusel solvent)

Isoamyl

acetate(fruity)

Hexanoic acid (fatty waxy barnyard)

Titratable

acidity

Diethyl succinate (fruity wine-like)

Malic acid Isobutanol(fusel solvent)

Na

Ca

Implications

Not just smart marketingbull Perceived minerality in Sauvignon wine appears

based on data-driven input (wine attributes) bull Characters driving perceived minerality in Sauvignon

ndash Citrus notes and freshzingy character (acid)ndash Absence of passion fruit amp green characters

Caution needed in how the term mineral is usedbull Much between-judge variability in judging intensity

of mineral character in winebull Wine varietal differences may influence how

minerality is perceived in any particular wine bull Wine composition aspects appear complex amp

require further research

Acknowledgement

bull Our tasters in France amp NZ amp wine producers who provided their wines for the study

bull Funding

ndash Grape and Wine Research Programme PFR NZ

ndash New Zealand Winegrowers

ndash Pernod Ricard NZ amp Pernod Ricard Research Centre Paris France

ndash Regional Council of Burgundy

ndash Bureau Interprofessionnel des Vins de Bourgogne and Conseil Interprofessionel des Vins de Bordeaux

ndash Royal Society of New Zealand ISAT Linkages Fund

And thank you for your attention

Page 19: The elusive nature of minerality in - Home | BCWGC elusive nature of minerality in white wine Wendy V. Parr, Ph. D. Lincoln University, Christchurch, New Zealand Minerality? Dominique

Sulphur compounds

bull 3-mercaptohexan-1-ol (3MH) citrusgrapefruit

bull 3-mercaptohexyl acetate (3MHA) passion fruit

bull 4-mercapto-4-methylpentan-2-one (4MMP)

sweatyboxwood

bull Ethyl-2-sulfanylacetate (E2SA) ldquobaked beansrdquo note

bull Benzenemethanethiol (BMT) flinty note

bull Dimethyl sulfide (quince truffle)

bull Hydrogen sulfide (rotten eggs)

bull Meacutethanethiol (stagnant water halitosis)

bull Ethanethiol (onion rubber)

bull Dieacutethyl sulfide

bull Dimeacutethyl disulfide (quince asparagus)

PLSR plot projection of Y variables (M perceived minerality scores) on X variables (chemical compounds in red) and Wines (in green)

Figure 2

MeSH

DMSDMDS

BMTEthyl Acetate

Isoamyl Acetate

Octanoic Acid

Tartaric acid

DL-Lactic acid

Ba

MoZn

Titratable AcidityAcidityIndex

Density

Free SO2

Bound SO2

DMS(2)

BMT (2)Ethyl Acetate (2)

Isoamyl Acetate (2)Octanoic Acid (2)

Tartaric acid (2)

Malonic acid (2)

Ca (2)

S (2)

Ba (2)

Mo (2)Zn (2)

Titratable Acidity (2)AcidityIndex (2)

Density (2)

Free SO2 (2)

Bound SO2 (2)

3MH

Isobutanol

Isoamyl Alcohol

Diethyl succinate

Hexanoic Acid

L-Malic acid

Ca

Na

Mn

Isobutanol (2)

Isoamyl Alcohol (2)

Diethyl succinate (2)

Hexanoic Acid (2)

L-Malic acid (2)

DL-Lactic acid (2)

Na (2)

FR_Minerality

NZ_Minerality

FBCBB

FBCLM

FLCH

FLPC

FSBAGA

FSBI

FSFC

FSHB

NZAVFB

NZAVV

NZLWB

NZLWWHNZRS

NZRSL

NZSVA

NZSVCH

-1

-075

-05

-025

0

025

05

075

1

-1 -075 -05 -025 0 025 05 075 1

t2

t1

t1 amp t2

X

Y

Obs

Aspects of wine composition associated statistically with perception of mineral character in S blanc wines

(Parr et al FRIN 2016)

Positive predictors Negative predictors

French N Z French N Z

Free SO2 Bound SO2 Tartaric acid Isoamyl alcohol (fusel solvent)

Isoamyl

acetate(fruity)

Hexanoic acid (fatty waxy barnyard)

Titratable

acidity

Diethyl succinate (fruity wine-like)

Malic acid Isobutanol(fusel solvent)

Na

Ca

Implications

Not just smart marketingbull Perceived minerality in Sauvignon wine appears

based on data-driven input (wine attributes) bull Characters driving perceived minerality in Sauvignon

ndash Citrus notes and freshzingy character (acid)ndash Absence of passion fruit amp green characters

Caution needed in how the term mineral is usedbull Much between-judge variability in judging intensity

of mineral character in winebull Wine varietal differences may influence how

minerality is perceived in any particular wine bull Wine composition aspects appear complex amp

require further research

Acknowledgement

bull Our tasters in France amp NZ amp wine producers who provided their wines for the study

bull Funding

ndash Grape and Wine Research Programme PFR NZ

ndash New Zealand Winegrowers

ndash Pernod Ricard NZ amp Pernod Ricard Research Centre Paris France

ndash Regional Council of Burgundy

ndash Bureau Interprofessionnel des Vins de Bourgogne and Conseil Interprofessionel des Vins de Bordeaux

ndash Royal Society of New Zealand ISAT Linkages Fund

And thank you for your attention

Page 20: The elusive nature of minerality in - Home | BCWGC elusive nature of minerality in white wine Wendy V. Parr, Ph. D. Lincoln University, Christchurch, New Zealand Minerality? Dominique

PLSR plot projection of Y variables (M perceived minerality scores) on X variables (chemical compounds in red) and Wines (in green)

Figure 2

MeSH

DMSDMDS

BMTEthyl Acetate

Isoamyl Acetate

Octanoic Acid

Tartaric acid

DL-Lactic acid

Ba

MoZn

Titratable AcidityAcidityIndex

Density

Free SO2

Bound SO2

DMS(2)

BMT (2)Ethyl Acetate (2)

Isoamyl Acetate (2)Octanoic Acid (2)

Tartaric acid (2)

Malonic acid (2)

Ca (2)

S (2)

Ba (2)

Mo (2)Zn (2)

Titratable Acidity (2)AcidityIndex (2)

Density (2)

Free SO2 (2)

Bound SO2 (2)

3MH

Isobutanol

Isoamyl Alcohol

Diethyl succinate

Hexanoic Acid

L-Malic acid

Ca

Na

Mn

Isobutanol (2)

Isoamyl Alcohol (2)

Diethyl succinate (2)

Hexanoic Acid (2)

L-Malic acid (2)

DL-Lactic acid (2)

Na (2)

FR_Minerality

NZ_Minerality

FBCBB

FBCLM

FLCH

FLPC

FSBAGA

FSBI

FSFC

FSHB

NZAVFB

NZAVV

NZLWB

NZLWWHNZRS

NZRSL

NZSVA

NZSVCH

-1

-075

-05

-025

0

025

05

075

1

-1 -075 -05 -025 0 025 05 075 1

t2

t1

t1 amp t2

X

Y

Obs

Aspects of wine composition associated statistically with perception of mineral character in S blanc wines

(Parr et al FRIN 2016)

Positive predictors Negative predictors

French N Z French N Z

Free SO2 Bound SO2 Tartaric acid Isoamyl alcohol (fusel solvent)

Isoamyl

acetate(fruity)

Hexanoic acid (fatty waxy barnyard)

Titratable

acidity

Diethyl succinate (fruity wine-like)

Malic acid Isobutanol(fusel solvent)

Na

Ca

Implications

Not just smart marketingbull Perceived minerality in Sauvignon wine appears

based on data-driven input (wine attributes) bull Characters driving perceived minerality in Sauvignon

ndash Citrus notes and freshzingy character (acid)ndash Absence of passion fruit amp green characters

Caution needed in how the term mineral is usedbull Much between-judge variability in judging intensity

of mineral character in winebull Wine varietal differences may influence how

minerality is perceived in any particular wine bull Wine composition aspects appear complex amp

require further research

Acknowledgement

bull Our tasters in France amp NZ amp wine producers who provided their wines for the study

bull Funding

ndash Grape and Wine Research Programme PFR NZ

ndash New Zealand Winegrowers

ndash Pernod Ricard NZ amp Pernod Ricard Research Centre Paris France

ndash Regional Council of Burgundy

ndash Bureau Interprofessionnel des Vins de Bourgogne and Conseil Interprofessionel des Vins de Bordeaux

ndash Royal Society of New Zealand ISAT Linkages Fund

And thank you for your attention

Page 21: The elusive nature of minerality in - Home | BCWGC elusive nature of minerality in white wine Wendy V. Parr, Ph. D. Lincoln University, Christchurch, New Zealand Minerality? Dominique

Aspects of wine composition associated statistically with perception of mineral character in S blanc wines

(Parr et al FRIN 2016)

Positive predictors Negative predictors

French N Z French N Z

Free SO2 Bound SO2 Tartaric acid Isoamyl alcohol (fusel solvent)

Isoamyl

acetate(fruity)

Hexanoic acid (fatty waxy barnyard)

Titratable

acidity

Diethyl succinate (fruity wine-like)

Malic acid Isobutanol(fusel solvent)

Na

Ca

Implications

Not just smart marketingbull Perceived minerality in Sauvignon wine appears

based on data-driven input (wine attributes) bull Characters driving perceived minerality in Sauvignon

ndash Citrus notes and freshzingy character (acid)ndash Absence of passion fruit amp green characters

Caution needed in how the term mineral is usedbull Much between-judge variability in judging intensity

of mineral character in winebull Wine varietal differences may influence how

minerality is perceived in any particular wine bull Wine composition aspects appear complex amp

require further research

Acknowledgement

bull Our tasters in France amp NZ amp wine producers who provided their wines for the study

bull Funding

ndash Grape and Wine Research Programme PFR NZ

ndash New Zealand Winegrowers

ndash Pernod Ricard NZ amp Pernod Ricard Research Centre Paris France

ndash Regional Council of Burgundy

ndash Bureau Interprofessionnel des Vins de Bourgogne and Conseil Interprofessionel des Vins de Bordeaux

ndash Royal Society of New Zealand ISAT Linkages Fund

And thank you for your attention

Page 22: The elusive nature of minerality in - Home | BCWGC elusive nature of minerality in white wine Wendy V. Parr, Ph. D. Lincoln University, Christchurch, New Zealand Minerality? Dominique

Implications

Not just smart marketingbull Perceived minerality in Sauvignon wine appears

based on data-driven input (wine attributes) bull Characters driving perceived minerality in Sauvignon

ndash Citrus notes and freshzingy character (acid)ndash Absence of passion fruit amp green characters

Caution needed in how the term mineral is usedbull Much between-judge variability in judging intensity

of mineral character in winebull Wine varietal differences may influence how

minerality is perceived in any particular wine bull Wine composition aspects appear complex amp

require further research

Acknowledgement

bull Our tasters in France amp NZ amp wine producers who provided their wines for the study

bull Funding

ndash Grape and Wine Research Programme PFR NZ

ndash New Zealand Winegrowers

ndash Pernod Ricard NZ amp Pernod Ricard Research Centre Paris France

ndash Regional Council of Burgundy

ndash Bureau Interprofessionnel des Vins de Bourgogne and Conseil Interprofessionel des Vins de Bordeaux

ndash Royal Society of New Zealand ISAT Linkages Fund

And thank you for your attention

Page 23: The elusive nature of minerality in - Home | BCWGC elusive nature of minerality in white wine Wendy V. Parr, Ph. D. Lincoln University, Christchurch, New Zealand Minerality? Dominique

Acknowledgement

bull Our tasters in France amp NZ amp wine producers who provided their wines for the study

bull Funding

ndash Grape and Wine Research Programme PFR NZ

ndash New Zealand Winegrowers

ndash Pernod Ricard NZ amp Pernod Ricard Research Centre Paris France

ndash Regional Council of Burgundy

ndash Bureau Interprofessionnel des Vins de Bourgogne and Conseil Interprofessionel des Vins de Bordeaux

ndash Royal Society of New Zealand ISAT Linkages Fund

And thank you for your attention

Page 24: The elusive nature of minerality in - Home | BCWGC elusive nature of minerality in white wine Wendy V. Parr, Ph. D. Lincoln University, Christchurch, New Zealand Minerality? Dominique

And thank you for your attention