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The Globally Accepted Industry Standard for Gasoline Testing
Ac RefoRmulyzeR® m3
WORLDWIDE ACCEPTED INDUSTRY STANDARD FOR gASOLINE & gASOLINE BLENDS TESTINg
• Group Type Analysis per Carbon Number for O-PIONA Samples• Complete Solution with Calculation Reporting, Diagnostic Tool,
Certified QC Samples and Trend Recording • Fully Compliant with ASTM D6839, D5443, EN 14517 and ISO 22854
ThE WORLDWIDE ACCEPTED INDUSTRY STANDARD IN gASOLINE & gASOLINE BLENDS TESTINgAC Analytical Controls pioneered, developed and optimized the AC Reformulyzer® Mark 3 (M3) application, which is used globally by nearly all refineries. The Reformulyzer® M3 analysis is based on a multi-dimensional column switching technique. After sample introduction, a set of columns and traps separates the sample into different hydrocarbon groups. The multi-dimensional technique determines carbon number distribution for (Iso-)Paraffins, Olefins, Naphthenes, Aromatics and Oxygenates. The Reformulyzer® M3 complies with accepted international standard test methods, including: • ASTM D5443, (D6293), D6839• IP 382, (526), 566• UOP 870• ISO 22854
AC Reformulyzer® M3 analysis of gasoline in 75 minutes
AC
Ref
orm
ulyz
er® M
3
WIDE RANgE OF REPORT OPTIONS• Hydrocarbon type concentrations by carbon number in
weight% and liquid volume%
• Oxygenated component concentrations in weight% and liquid volume% as specified by EN 228
• Benzene, Total Aromatics, Total Olefins and Total Saturates in liquid volume%; Oxygen in weight%, Oxygenates in liquid volume%
• Density in g/ml, kg/m3 and lb/gal• Average molecular weight• RON/MON calculation for the PIONA mode• C:H:O ratio and Calorific Value• Excellent LIMS connectivity: upload the results directly to
your LIMS or manually after approval
AC Reformulyzer® M3 report options
Report of a Winterspec analysis
reformulyzer 048 Winterspec AC
Data FileName Operator Acquired On Processed On Sample Name
Sample Type Instrument Method
C:\Chem32\1\DATA\D1002\048 Winterspec4.dAdmin2/17/2010 1:30:25 PM2/17/2010 1:30:29 PM048 Winterspec
Winter02Winterspec ETBE
104Vial Inj Volume 0,1 μ
:::::::
:
:l:
SampleGroup:
Winterspec EtOH/ETBE
00.02.048C048 Gasoline N lot 004
Reference Number:Reference Name
:
Analysis ConditionsA 3.4 EthAlcSep 110B 5.3 OlefinSep1 100E 2.5 OlefinSep2 150
Normalized weight percent resultsC-nr Naph. Paraf. Cycl Ol. Olef. Arom . Oxyg. Total
12 0.95 0.95 34 0.99 0.48 1.47 5 0.24 10.44 0.14 3.53 14.35 6 1.77 9.47 0.45 2.76 0.96 9.96 25.37 7 1.42 6.93 0.38 1.72 9.96 20.41 8 0.98 8.75 0.13 0.87 14.67 25.40 9 0.39 1.01 0.29 8.42 10.12 10 0.04 0.90 0.94
11+ 0.69 0.29 0.98 PolyTotal 4.80 38.28 1.10 9.70 35.21 10.90 100.00
Normalized volume percent resultsC-nr Naph. Paraf. Cycl Ol. Olef. Arom . Oxyg. Total
12 0.89 0.89 34 1.27 0.59 1.86 5 0.24 12.61 0.13 4.04 17.02 6 1.72 10.66 0.42 3.01 0.81 9.96 26.57 7 1.38 7.47 0.36 1.81 8.50 19.52 8 0.93 9.13 0.12 0.89 12.50 23.58 9 0.37 1.03 0.30 7.16 8.85 10 0.04 0.76 0.80
11+ 0.67 0.25 0.92 PolyTotal 4.63 42.83 1.04 10.67 29.98 10.84 100.00
Oxygenate Wt% LV% O2%
Oxygenates results
ETBE 9.96 9.96 1.56Ethanol 0.95 0.89 0.33Total 10.90 10.84 1.89
EN 14517 / ASTM D 6839
Benzene 0.81 LV%Total Aromatics 29.98 LV%Total Olefins 11.71 LV%Total Oxygenates 10.84 LV%Total Saturates 47.47 LV%Total Oxygen 1.89 Wt%
Reports Fuel Specifications EN228 includes the EN ISO 22854 (Multidimensional GC, Reformulyzer) as Referee Method for Hydrocarbon content (Olefins & Aromatics), Benzene, Oxygenates and Oxygen content. It therefore replaces FIA (EN15553) for Hydrocarbon content, EN12177 for Benzene and EN1601 for Oxygenates.
QUALITY CONTROL SAMPLESBesides the gravimetric PIONA standards, AC offers a set of quality control samples that covers most light petroleum streams:
• Reformer feed• Reformate• FCC naphtha• Gasoline containing MTBE
• Oxygenates free gasoline • Gasoline containing Ethanol • Gasoline containing ETBE &
Ethanol
www.paclp.comANALYSIS SIMULATION PROGRAMTRAINING TOOL FOR SELF-ExPLANATORY OPERATION
AC developed the Reformulyzer® M3 Analysis Simulation Program to train users in the multi-dimensional technique, by showing the analysis sequence step-by-step. The program demonstrates sample separation through various columns and traps integrated into the software. Simultaneously the elution pattern can be observed in the chromatogram.
INTEgRATED DIAgNOSTIC TOOL AUTOMATES vALIDATIONAC has developed an integrated diagnostic tool to validate the Reformulyzer® M3’s performance.
After analysis of the QC samples, the diagnostic tool reports validation and statistical data for:• a specific analysis• a series of analyses over a longer
period
The diagnostic tool will automatically mark results outside specification limits. You will find these marked results in the on-screen report. The diagnostic tool also advices on possible causes for components exceeding the limits and reviews data for trend recording.
AC Reformulyzer® M3 Diagnostic Tool
AC Reformulyzer® M3 on-screen report
AC REFORMULYzER® M3 USER gROUPReformulyzer® users can join the AC User Group. AC organizes interactive meetings periodically that allow users to share and exchange technical knowledge.An important part of the user group is the Performance Monitoring Program (PMP), a regular round robin anonymous testing program that helps labs verify their analyzer’s precision.Results are processed anonymously; AC reports the statistical values and offers suggestions for improving precision.The 2010 PMP test consisted of 4 samples: three gasolines, one high olefinic FCC naphtha. One gasoline contained a relative high ethanol concentration, exceeding the current Fuel specifications limits to prepare the analyzer for possible future market developments.
solidpartnersproven solutions
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PAC Authorized Representatives are also located in most countries worldwide. For more information visit www.paclp.com
Ordering Information
CCG6652A M3 REFORMULYZER ON 120V 7890 GC
CCG6652B M3 REFORMULYZER ON 200V 7890 GC
CCG6652C M3 REFORMULYZER ON 230V 7890 GC
CCG6652.100 KIT, SPARE PARTS M3 REFORMULYZER ON 120V 7890 GC
CCG6652.200 KIT, CONSUMABLE PARTS M3 REFORMULYZER ON 120V 7890 GC
Analysis Information
Sample Matrix Gasoline and Gasoline Blending Feedstocks • Reformate• C4 streams• Straight naphtha• FCC naphtha• Alkylate• Isomerate• Oxygenates.
Analysis Modes PNAExtended PNAPIPNAPONAPHONAPIONA PIANOPIHONAOPNAWinterspec
Separation range: (varies per method)
Paraffins C4-C11Olefins C4-C10Naphthenes C5-C11Aromatics C6-C12Oxygenates C1-C6
Standard Method Compliance
ASTM D5443, D6839EN 14517IP 526, IP 566 EN ISO 22854
Utilities Requirements
Carrier gas Helium (99.999%)FID fuel Hydrogen (99.999%) and AirCooling Compressed dry AirSystem Power 110 - 230 Volts
Accessories Included
Testing DocumentationOperating manualCalibration saamplesReference samplesStartup KitCarrier Gas FiltersOven Exhaust deflectorFactory plumbing for quick installation
SPECIFICATIONS
AC Analytical Controls® by PAC,has been the recognized leader in chromatography analyzers for gas, naphtha and gasoline streams in crude oil refining since 1981. AC also provides technology for residuals analysis for the hydrocarbon processing industry. Applications cover the entire spectrum of petroleum, petrochemical and refinery, gas and natural gas analysis; ACs Turn-Key Application solutions include the AC Reformulyzer, SimDis, HiSpeed RGA and DHA instruments.
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