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Magnesium Research Joe Robson University of Manchester joseph.robson@manchester. ac.uk

Titanium Research Activity in Manchester

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Magnesium Research

Joe RobsonUniversity of Manchester

[email protected]

Key Application Areas• Increased future role for Mg in

transport (33% lighter than Al) • Future vehicle concepts assume

greatly increased application of Mg as part of multi-material structure

• Challenges• Making complex shapes using Mg• Reducing anisotropy/asymmetry of properties • Joining Mg to Al and steel, joining cast Mg alloys• Corrosion control (coatings/protection systems)

SuperLight CarMagnesium

Mg Research – Current Hot Topics• Based on a survey of recent conference

proceedings, top research areas for Mg are– Improving low temperature formability (texture

control, rare-earth additions etc.)– Alternative production routes (e.g. twin roll

casting, advanced casting processes)– Bio-resorbable magnesium alloys for implants– Corrosion control (alloy design and coatings)– Improving strengthening response (improving

precipitation hardening...)

International Picture• China, Germany, Canada, Australia and

US all have major Mg research activities• China

– National Engineering Research Centre for Magnesium Alloys, Chongqing ~80 academics

• Germany– Magnesium Innovation Centre (MagIC)

~50 scientists• Canada

– MagNET. 20 academics from 5 partner universities

UK Picture• UK Mg research activity is comparatively small

(handful of academics “part time” on Mg) but maintains wide coverage and internationally recognized position

• Mg research in UK receives ~ 5% of light metals funding

• Significant Mg activity within:– LATEST2 programme– Towards Affordable, Closed-Loop Recyclable Future

Low Carbon Vehicle Structures (TARF-LCV)– Centre for Innovative Manufacture in Liquid Metal

Engineering (LiME)– Doctoral Training Centre in Advanced Metallic

Systems (DTC)• Most UK Mg research involves collaboration with

industry - Magnesium Elektron

Reducing Temperature for Forming• Unlike steel/Al magnesium cannot be

formed at room temperature (hcp crystal structure)

• Reducing temperature required to form Mg is critical to economics for automotive sheet– Alloy design, e.g. dilute rare-earth

additions– Fundamental understanding of formability

in Mg– Alternative processes, e.g. superplastic

forming• Relevant UK research

– Alloy design and fundamentals [Manchester]

– Forming trials and alternative processes [Imperial/Warwick]

Improved formability with dilute rare-earth additions

Alternative Process Routes• Reducing cost of Mg requires using lower cost production route• Twin roll casting (TRC) attractive option

– Avoids need for large rolling reduction (difficult with Mg)– Potential to maintain randomized (cast) texture in sheet product– Potential to directly form TRC sheet (e.g. with superplastic forming)

• Research needed to improve consistency, microstructure and properties of TRC-Mg

• UK active through TRC optimization LiME [Brunel], microstructure and corrosion performance [Manchester]

TRC sheet Light further warm rolling

Warm forming

Direct superplastic forming of TRC sheet

Bio-resorbable Mg Alloys• Potential of Mg for bio-resorbable

implants has attracted massive new research interest in past ~10 years

• Magnesium Elektron developed Synermag – first commercial Mg alloy designed for biological applications

• UK research– Mg alloy optimization and biological

performance [Manchester]– Magnesium Elektron in-house

activities

Magnesium alloy stent

Corrosion Control and Coatings• Corrosion control is critical for Mg use• Mg corrosion is highly sensitive to impurities

(e.g. Fe)– Key concern for recyclability

• Mg corrodes rapidly in contact with other metals – must be electrically isolated

• UK research– Fundamentals of corrosion in Mg alloys

[Manchester]– Coating and protection systems for dissimilar

joints [Manchester]– Effect of recycling/impurities on corrosion

[Brunel, Manchester]Corrosion of ZE41 with PEO coating

[Manchester]

time

Improving Strengthening Response of Mg• Highest strength Mg alloys only ~ ½

strength of strongest Al alloy• Strongest Mg alloys are precipitation

hardened (as with Al)• Requires improving effectiveness of

precipitates in Mg to provide strength– Fundamentals of strengthening in

alloy systems that twin [Manchester]– New alloy systems– Micro-alloying to promote

precipitation (as in Al)– Computer based alloy design (ICME)

[Manchester]

Other Research Topics• Recent/ongoing UK research in

– Dissimilar metal joining of Mg to steel, Al structures [Manchester, Warwick]

– Magnesium based carbon reinforced composites [Manchester]

– Friction stir welding of magnesium [Manchester/Sheffield]