Title Cover

Author(s)

Citation The Review of Physical Chemistry of Japan (1974), 44(1)

Issue Date 1974-09-30

URL http://hdl.handle.net/2433/46992

Right

Type Others

Textversion publisher

Kyoto University

CORE Metadata, citation and similar papers at core.ac.uk

Provided by Kyoto University Research Information Repository

Vo(. 44, 1974

REI'IGN'o~

The Review of Physical Chemistry of Jap~l.}3i121o. 1~(1974J /~~

Nl.I.Gt/LCI

THE

ra~sicA~OF JAPAN

Fo.aded is 112f

Cp~~IISTRY

CONTENTS

Kaora Date : Evaluation of P-V-T Properties Data, The Most Probable Values of

Compressibility Factor of Propane and Propene ................................................... 1

lzumi lahihara, Kfmlhlko Hara and Jiro Oaugi : Pressure Effects on the

Complexes of Cobalt (II) Chlorideand Cobalt (II) Bromide in Acetone Solufion......,.....1 l

Tateo Arfmoto and Jiro Oengi : The Charge-Transfer Interaction and Successive

Thermal (2+2) Cycloaddition of a, S- Unsaturated Ethers with Tetracyanoethylene ......25

Takeshi Fulii :Kinetic Studies on the Rearrangement of N-Chloroacetanilide under

Pressure ......................................................................................................38

THB PHYSICO-CHEMICAL SOCIBTY OF JAPAN

The Review of Physical Chemistry of Japan Vol. 44 No. 1 (1974)

THE REVIEWOF PHYSICALCHEMISTRYOF JAPAN

(Butsuri-Kagaku no Fo¢ad.la 1926-

Shinpo)

President: Wasabuio Jo¢o

Members of Council Michio Okamoto (Chief)

Jiro Osugi Ryozo Goto

Renpei Goto Eiji Suito

Hiroyuki Hatano

Board of Bdltore:

J. Osugi (Cbief) Ryofo University R. Goto (Associate) Ryoto Santo University

E. Suito ( n ) Ryoto University

Secretors

S. Sbida

H. Tesaniski

%. Suzuki

%, %uwata

S. Seki

T. Imoto

R. Fujisbiro

T. Hayakawa

Y. Bubokawa

S. Tsuchibeshi

T. Makita

S. Hasegawa

%. Sbimizu

H. Toeawa

%. Hau

J. Nakaji

F akokama Uiriverisly

Kyoto Tetknital University

Rittomeikan Univurity

University of Osaka

University of Osaka

Osaka City University

Osaka Cily University

PreJutsral University of Osaka

PreJulwal University of Osaka

Univerrily of Kobe

University of Keba

Okay¢m¢ University

Daskiska University

Doskiska Univerzity

'M. Nakahara

The Review of Physical Chemistry of Japan Vol. 44 No. 1 (1974)

September 30 1974

Commmieationa to the PWiWr should be addressed to Board of Editors, The Phyaico•Chemical Society

of Japan, Faculty of Science, %yoto University, Syoto, Japan.

Boaineae Correapondeaeea should be addressed to: Secretary, The Phyaico~Chemieai Soeiety of Japaq

Faculty of &ieoce, %yoto Univcrsity, %yeto, Japan.

Pterchsao Order should be addressed to: Maruzm_ Co., Ltd,. Nihanbashi, Cbuoku, Tokyo, Japan

THB

Puhliabed by

PHYSICO•CHfiMICAL SC~GIBTY OF JAPAN

iNippon Buburi-%agaku %enkyu gai)

Faculty of Science, %yoto University, %yoto, Japm

Printed by %AWA%ITA PRINTING CO., LTD., %yom, Japan

The Review of Physical Chemistry of Japan Vol. 44 No 1 (1974)

'pei -el~ is a highly fluorinated elastomer. which can 6e easily •vulcanized by amines. peroxides. irradiation end etc., to produce the •cured prgduc[ with excellent thermal stability, resistance to oils, solvents, chemicals, ozone end weathering, high mechanical strength and rron-~nflemmability.

Majar user Packings. gaskets. diaphrams, expansion joints, 0-rings, sheets. hoses. gloves etc.

Enquuies io: Daikin Kogyo Co Ltd Chemical Division, Heed Ofhce. Shin Hankyu Bldg 8 Umeda Kitaku Osaka Japan.

Fluorochemicel amivities: Daikin is the biggest manufacturer of fluorochemi[als in Japan end produces on a commercial kale chemical products such ae hydrofluoric amd. fluorocarbon [efrigeranLS (Daiflon Gas). fluorocarbon polymers. Iluorotarbon agrculturai chemicals. 6enmmf.uonde and ds derivatives and many other Iluorochemicals.

DA/K/N KOOYO CO ITO

KANEKA's

products and technologies shall be at your service

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KANEKA has now firmly secured Its leading

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. only for its capability of offering unique, high-quality products in quick succession but also for its establishment of technical know-how in various field of technology. KANEKA's unique, high-quality products are

as follows .." Kanekalon; ' a self-extinguish-ing modacrylic fiber and is booming for its suitability and nonflammability for carpets;

curtains and wig's. "Kane-Ace B;'~PVC modifier, isnow in bnskworld-wide demand "PVC Dispersion Resin;' "Heat Resistant PVC," "Expandable Polystyrene," and so on. A vanety of epochal projects are now under way at our 10 laboratories far ahead in the same field both at home and abroad.

p

tamurms m me wonD, manxs m our very mgn productivity.

* KANEKA's products have . for the most pan, originated in Its own laboratones.

* 55p/o of-KANEKA's products have been devel- oped on Its hands for the'first time in Japan

KA1V'E=fA Por Portlier deLik. pleas wrNe tp

KANEfiAFUCNI CHEMICAL IND. CO., LTD. Need OBin (AmM Bhinbun 6ldp)3, 3-elwnu, NekeMah~me,

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Phone Tokyo (03/218 1011 New York OBicc PANAM a1d8.37th Floor, 200 Park Ayenua,

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EYfOM ONice 4DWat/orf BerllMrAWa 26, West GemuM Phena 1P38

HORIBA Ltd. has established a steady pradumicn line for large size crystals of greater than 12 inches by diameter m addrtian to conventional size crystals. The photograph at right shows an Nal (TQScintilla[or for use with scintillation camera. The large diameter Nal R4 scintillator en-abled scintillation survey of an ex-tensivearea to be done in a drasti~ tally shorter time. HOfl180.Ltd-is ready to respond fo your re-

quirementsforany purpose as for as the scintillators are concerned.

Infrared ray optical crystal is

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ingot Its uncontested high purity.

exact crystal lattice and trans-

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The crystal is available iniarmsof

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Materials : liF. NaCL KCL KBr.

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HOflIBA.Ltd. is the first in Japan

to have developed electro~oDtic

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hydrogen in KDP crystal by ns

isotope, deuterium (maximum

deuterium replacement :99.7%)

Electro-Optical Crystals

r.y,bx,A-Stiu ne.rwpA-fu ruuran

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HORIBA, Ltd, Miyanohigashi. Kisshoin

Minamiku, Kyoto. Japan Phone: (075)-3138721

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The Review of Physical Chemistry of Japan Vol . 44 No. 1 (1974)

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ALE Heat Exchangers Now Available with Super-Large Cores for LNG, SNG and NG Plants.

But still at half the with one tenth the

cost,

size.

LNG, SNG and chemical plant builders, rejoice. ALEX heat exchangers from Kobe Steel, Ltd. cost about half as much and cake up about one tenth the space of conventional multi-tube types, but et no loss in heat transfer efficiency. The secret isn't so secret-heat transfer area per cubic foot of equipment volume is around 1,500 square fee[ or eight to ten times larger than in multi-tube models.

Now available with super-large cores up to 47.2'(f ,200mm)X47.2' (1,200mm) x 263.6"(6,700mm), our ALEX exchangers have fewer core connections and cause much lass pressure drop. Compact size means that your plant needs a much smaller cold box.

We make them from our own special aluminum alloy to guarantee start~to finish quality control. Brazed aluminum Construction explains the excellent behavior at low temperatures, the high pressure resistance and the '"so what" attitude toward quick temperature changes .

Plus: you get the priceless extra of Koba Steel's ezpettise gained by having quite a few ALEX heat exchangers in operation at our own steel works. In other words, we won't sell you a heat exchanger that we wouldn't use ourselves. Write to the nearest agent listed below for our new ALEX catalog and our prompt delivery times.

~~

KOBE STEEL, LTD. MACNINlRY DIVISION

Tokyo Office: Tekko Building, 8.2,1-chome, Marunouchi, Chiyoda•ku, Tokyo , Japan Cabl

e Address: "KOBESTEEL TOKYO" Phone: Tokyo f03) 218-7117 Telex: 222.3601 (KOBESTEEL TOK)

The Review of Physical Chemistry of Japan Vol. 44 No. 1 (1974)

It's a long road from here

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to here For example, the field of oil resource development. We began drilling for oil in the olf-shore area of Nigeria and our very auccesstul strike has already yielded lors-sulphur crude. We have also begun exploratory drilling in Iran's l,orestan district.

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or here ~ , In the Malagasy Republic Teijin is ~l engaged in joint vnntures for the raising of cattle end production r

or here In jepan. Teijin parlicipales in a join)venture for the

processing oI EVR video cassette rePes.

of beef and beef extract. The latter is used es a basic ingredient in many packs Red food products.

Dul T<!/in keeps going. Other nrens indicntiv¢ of our growing versatility: glass fiber, agricultural chemicals. eye medicines, ophthalmic instruments, eosmetin, computer software.

For a company known to most peoP/e es a leading maoufacturcr of floe fashion fihem end tehries, [heso eetivltiea may seem like quite a depermre. Bu[ the proeeu of divorsificalion promises to grow.

Because it [s T¢I/bi s husiness

philosophy to engage in business that promotes human welfare and socialprogrcas. We will continue to expand into new fields wherever [hero fs a favorable business and social dfinete.

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