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    Comparison of HYDRAN and laboratory DGA results for

    electric faults in ester transformer fluids

    Jie Dai, Imadullah Khan, Z. D. Wang and I. Cotton

    School of Electrical and Electronic Engineering,The University of Manchester,

    Manchester M60 1QD, UK

    Abstract- Due to the properties of biodegradability and high fire

    temperature, ester fluids are becoming potential substitutes to mineral oil

    for power transformers. Laboratory based DGA (Dissolved Gas Analysis)

    techniques and the online DGA devices have been widely used on mineral

    oil filled transformers to diagnose faults. It is therefore of importance to

    understand how these techniques and devices perform with ester fluids. In

    the paper high and low energy discharges were generated in mineral oil

    and esters and the on-line readings from HYDRAN 201R were recorded

    with time and compared with the laboratory DGA results. It is concluded

    that DGA fingerprints for electrical faults in esters are similar to those in

    mineral oil. However, in the present experimental configuration, a slower

    response of HYDRAN reading was found for esters than mineral oil due to

    both the higher viscosities of esters and the limited oil circulation.

    1 Introduction

    The ester fluids, with good dielectric strength, such as the syntheticester Midel7131 and the natural ester FR3 are available in the marketas alternatives to mineral oil. Ester fluids are biodegradable and henceenvironmentally friendly [1, 2]. Their high flash points and fire pointsalso make them suitable for the transformers located in underground,offshore or urban areas for safety reasons. Esters have already beensuccessfully used in a great number of distribution transformers, andhave great potentials to be applied in high voltage transformers in thefuture. However ester filled transformers face the challenge of beinglack of operating experience and especially the experience withcondition monitoring and assessment, which mineral oil filledtransformer has accumulated over years [3].

    Modern high voltage transformers work with relatively lowinsulation tolerance because of compact structure. A close monitoringis considered important to understand the behavior of transformers [4].DGA has been used for many years as an effective and reliable tool todetect incipient faults in mineral oil filled transformers. Theinformation provided by DGA analysis is extremely important to theasset managers in electricity supply companies. It is therefore essentialto ensure that traditional DGA analysis techniques can still workproperly if alternative fluids are used in power transformers. Table 1gives the types of dissolved gases evolved during faults in a mineraloil filled transformer and their indicative relationships with differenttypes of faults.

    Former studies suggested that the fault gases or the so called keygases were also found in esters and dissolved gas analysis istherefore still a feasible method to monitor ester oil filled transformers[6, 7]. However, little research covers the performance of on-line

    DGA devices in association with ester fluids. On-line DGAmonitoring has been accepted as an efficient means for early stagefault diagnoses, and the on-line DGA devices, such as HYDRAN,have been widely used in mineral oil filled transformers for years. TheHYDRAN sensor reads the ppm (part per million) value of thedissolved gas in oil through the membrane which only allows gases topass. The sensor mainly responds to hydrogen with 100% efficiencyand shows low sensitivity to other gases, which is approximately 15%to CO, 8% to C2H2 and only 1% to C2H4. Its accuracy is said as 10%from 20OC to 40OC [10]. For high voltage transformers, HYDRAN is

    normally installed between the cooling bank and the main tank to takethe full advantage of oil circulation. Sometimes a position on theupper part of the transformer tank is preferred to install the on-lineDGA monitoring devices. Although HYDRAN is unable to providethe concentrations of all fault gases, it works reliably as an early stagefault indicator since hydrogen is the gas which is normally evolved inmost faults.

    Table 1: Fault indicator gases [5, 6]Element Key indicator Secondary indicator

    H2 Corona Arcing, Overheated Oil

    CH4 Corona, Arcing, and Overheated Oil

    C2H6 Corona, Overheated Oil

    C2H4Overheated

    OilCorona, Arcing

    C2H2Arcing Severely Overheated Oil

    COOverheatedCellulose

    Arcing if the fault involves cellulose

    CO2Overheated Cellulose, Arcing ifthe fault involves cellulose

    O2Indicator of system leaks,over-pressurization, or changes inpressure or temperature.

    N2Indicator of system leaks,over-pressurization, or changes inpressure or temperature.

    An experiment was carried out to investigate fault gas generation inesters with comparison to that in mineral oil and to test theperformance of HYDRAN 201R in ester fluids. A HYDRAN 201Rsensor was connected to an oil filled test vessel, in which partialdischarges (PD) and electric breakdown activities were generated. Theresponses of HYDRAN towards the electrical faults in differentinsulating fluids were recorded.

    It was found that after electric faults similar types of gases weredissolved in oil samples for mineral oil, Midel7131 and FR3according to the laboratory DGA results. HYDRAN 201Rsuccessfully performed as an on-line DGA indicator for ester fluidsunder electric faults, but a certain delay in the response of HYDRANreading was found for esters due to their relatively high viscosities

    which result in a slower oil circulation and consequently a slowerequilibrium of gases.

    2 Experimental setup

    2.1 Test vessel and HYDRAN connection

    The capacity of the glass test vessel is about 3 litres and a headspace about 50ml was left above the oil surface for safety reason. TheHYDRAN sensor was directly connected to one side of the glass

    2007 Annual Report Conference on Electrical Insulation and Dielectric Phenomena

    1-4244-1482-2/07/$25.00 2007 IEEE 731

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    vessel without any piping as shown in Fig. 1.

    Fig. 1 Test vessel and HYDRAN connection

    There was a distance of ~16 cm from the membrane of HYDRANsensor to the centre of body of oil, where the electrodes were located.Tests were done under room temperature. In order to create a thermalcirculation, a temperature approximately 10OC higher than theambient was maintained within the bottom oil by adding a heating

    jacket around the lower part of the test vessel.

    2.2 Electric test setup

    A 220V/40kV 8kVA 50Hz test transformer was used as the voltagesource throughout the experiment. Needle electrodes were used inboth oil gap breakdown and PD tests. The needle was pre-processedby introducing several arcing to melt the sharp tip so that the radius ofthe tip could remain relatively stable when used in the tests.

    a) Oil gap breakdown test: Oil gap breakdowns were achieved byusing the needle electrode connected to the HV source leaving an oilgap distance of 10mm above the grounded plate electrode. There wasan over-current relay set at 3A limit on the low voltage side of the testtransformer to control the energy during electric faults. Theover-current relay normally operates in 20ms after the formation of anarc.

    b) PD test: It was found that a stable PD source was difficult to

    obtain from the needle to plate electrode configuration, because thePD in oil would always propagate and cause a flashover of the oil gap.Therefore, the following electrode arrangement was developed toproduce a stable PD source as shown in Fig. 2.

    Fig. 2 Electrode configuration for PD test

    Upon the ground electrode, there was a 3mm thick pressboard

    with a cylindrical electrode of floating potential sitting above. The oilgap between the sharp needle and the floating object was remained as0.5mm. When an electric spark happened within this small oil gap, itwould automatically die out as the electric breakdown built a shortcircuit between the HV electrode and the floating object, whichthereby caused a temporary equal potential connection andsimultaneously cleared the spark in the oil gap. The duration of eachdischarge was so short that the current relay could react to function. Inorder to further reduce the current during PD tests, a 1.4 M waterresistor was connected between the test vessel and the HV source.

    The oil samples for the laboratory DGA were taken from the bottomsampling valve of the glass vessel using syringes. During sampling,the oil was naturally forced into glass syringes according to the BS EN60567 standard [8]. The DGA sampling point is different from theHYDRAN locating point, which to a certain extent inhibits the directcomparisons of the results. This drawback will be discussed further in

    session 3.

    3 Results and discussions

    3.1 Oil gap breakdown test

    Three breakdowns of the 10mm oil gap were made in each type offluid with 30 seconds standing time after each breakdown. The voltagewas manually controlled with a rising speed about 1 kV/s. The wholeprocess took about 5 minutes. The timing of the HYDRAN responsewas started immediately after the first breakdown. The breakdownvoltages for the 10 mm oil gap varied from 26kV to 32kV, and nosignificant difference was found among the breakdown voltage valuesof the three types of fluid. Therefore, comparable energy levels wereproduced in different fluids during breakdown tests.

    Small gas bubbles were observed after each breakdown, which

    travelled to the headspace. Therefore, it is suggested that a significantamount of the gases generated during an electric fault would bemaintained in the headspace. As the equilibrium between the headspace and the oil volume takes some time to reach, the HYDRANsensor actually reads the amount of gases already dissolved in the oilat that time other than the total amount of gases being generated.Since the mechanical impact produced by the arcing was relativelystrong, some of the small gas bubbles generated from the oilbreakdown were pushed 5 to 8 cm sideways from the centre. That is,the HYDRAN membrane had a relatively shorter distance to be incontact with the dissolved gases.

    HYDRAN readings:Normally, the HYDRAN monitor shows an initial reading around 10ppm. When an initial increase of 5 ppm was observed, it was recordedas the beginning of the response of HYDRAN sensor to the dissolved

    gas. The reading of HYDRAN was periodically recorded as shown inFig. 3. When the reading stopped increasing, two oil samples weretaken immediately from the bottom sampling valve of the test vesselfor laboratory DGA.

    0

    50

    100

    150

    200

    250

    1 10 100

    Time (minute)

    PPMv

    alue

    Mineral oil

    Midel7131

    FR3

    Fig.3 Response of HYDRAN after oil breakdown tests

    As shown in Fig.3 and Table 2, the HYDRAN sensor started tohave increasing readings immediately after the 3 breakdowns inmineral oil but a certain time delay was found in esters. Although thegas diffusion in a liquid is not dependent on the viscosity of liquidaccording to henrys law [9], this experiment indicates that HYDRANtends to respond slower in high viscosity fluids. As the speed of thekinetic movement of a fluid is highly dependent on its viscosity and a

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    relatively higher viscosity brings more resistance during thecirculation, the oil circulation in a viscous fluid tends to be relativelyslower, and the time for the dissolved gases in the high viscosity estersto be in contact with the membrane of HYDRAN is thereforeincreased.

    Table 2. Performance of HYDRAN after breakdown tests

    Fluid type Mineraloil Midel7131 FR3

    Response delay (minute) 5 9 14

    Time to reach maximumreading (minute)

    40 53 74

    Maximum reading (ppm) 207 129 208

    Consequently, there was a delay for the HYDRAN to pick up theppm value of dissolved gases in Midel7131 and FR3. On the otherhand the forced oil circulation can significantly accelerate theequilibrium of gases in the oil.

    The maximum readings from mineral oil and FR3 after thebreakdown test were similar, while the gases dissolved in Midel7131appeared about 50% less than the other two fluids as shown in table 2.

    DGA resultsTable 3 and Fig. 4 show the average concentrations of dissolved

    gases in two oil samples. The laboratory measurement error expectedduring the DGA measurements is 10% for the 50ml oil samplestaken in these tests.

    Table 3. DGA results from oil gap breakdown testGases(ppm)

    Mineral oil Midel 7131 FR3

    H2 96 49 105

    CH4 22 6 9

    C2H6 4 2 2

    C2H4 32 18 39

    C2H2 157 89 175

    CO 5 31 33

    0

    20

    40

    60

    80

    100

    120

    140

    160180

    200

    H2 CO CH4 C2H2 C2H4 C2H6

    Gasconcentration(ppm)

    Mineral oil

    Midel7131FR3

    Fig. 4 Comparison of dissolved gas concentrations between different fluids

    after breakdown tests

    Acetylene (C2H2) is the primary indicator for high energydischarges [5, 6] and it is supported by the DGA results that acetylenehad the highest concentration for all three types of fluid. DGA ofmineral oil and FR3 are in close agreement with each other, whereasMidel7131 has the lowest concentration of dissolved gases.

    Based on the sensitivities of the HYDRAN sensor to different gases,the expected readings from HYDRAN 201R could be calculated usingthe laboratory DGA results:- Expected HYDRAN reading = 100% H2+ 15% CO + 8% C2H2 +1% C2H4 (1).

    A comparison was made between the HYDRAN readings and thelaboratory DGA results as shown in Fig. 5. The HYDRAN sensorreadings are approximately two times higher than the expected values,

    and this trend was found in three types of fluids.

    0

    25

    50

    75

    100

    125

    150

    175

    200

    225

    250

    Mineral o il Mide l7131 FR3

    Gasconce

    ntration(ppm)

    Calculated valueHYDRAN reading

    Fig.5. HYDRAN readings versus calculated ppm values from laboratory DGA

    results for breakdown tests

    HYDRAN is normally calibrated to illustrate the realconcentration of the gases in the fluid so that the reading and thecalculated value by (1) would be expected the same. The differenceshown in Fig. 5 may be due to the different gas concentration betweenthe side of the vessel where the HYDRAN sensor was mounted to thebottom where the oil samples were taken. The produced gas bubblesrise upwards and while travelling they dissolved into the oil in the

    upper part of oil body.

    3.2 Partial discharge test

    In order to produce a comparable energy level of partial dischargeactivity in three types of fluids, 15kV voltage was applied on the sharpelectrode in each PD test for 5 minutes. Small sparks in the 0.5mm oilgap were constantly observed. The oscilloscope monitoring thevoltage and discharge activities showed that there were one to fourdischarges in every power cycle.

    HYDRAN readingsTiny gas bubbles were stably and smoothly generated during the

    continuous partial discharges, which means the dissolved gases had alonger distance, i.e. 16 cm to reach the membrane of HYDRANcompared to the breakdown test. Fig. 5 shows the increased readings

    of HYDRAN with time after the PD test.

    0

    50

    100

    150

    200

    1 10 100 1000

    Time (minute)

    PPMv

    alue

    Mineral oil

    Midel7131FR3

    Fig. 5 Response of HYDRAN after PD tests

    Table 4. Performance of HYDRAN after PD tests

    Fluid typeMineral

    oilMidel7131

    FR3

    Response delay (minute) 5 14 30Time to reach maximum

    reading (minute)30 126 420

    Maximum reading (ppm) 147 71 72

    Table 4 shows that the HYDRAN sensor responds considerablyslower for esters, especially for FR3, as compared to mineral oil. Alonger delay of response by HYDRAN reading in the PD test than in

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    the breakdown test may be caused by the longer distance for the oilwith dissolved gas to circulate. The low energy discharge has littlemechanical impact to push gas bubbles horizontally closer to theHYDRAN membrane.

    DGA resultsTable 5 and Fig. 6 show the dissolved gas concentrations in the oil

    samples tested by the laboratory DGA.

    Table 5. DGA results for partial discharge testsGases(ppm)

    Mineral oil MIDEL 7131 FR3

    H2 88 28 70

    CH4 15 4 7

    C2H6 1 1 1

    C2H4 15 7 15

    C2H2 75 20 60

    CO 7 24 22

    0

    10

    20

    30

    40

    50

    60

    70

    80

    90

    100

    H2 CO CH4 C2H2 C2H4 C2H6

    Gasconcentration(ppm)

    Mineral oil

    Midel7131

    FR3

    Fig. 6 Comparison of dissolved gas concentrations between different fluids

    after PD tests

    Because the partial discharges generated in the experimental setupwere not the cold corona type discharge, a large amount of acetylenewas still produced. However, different from the breakdown tests, thistype of low energy discharge generates relatively more hydrogen in

    proportion to acetylene. In the PD test, Midel7131 was found withmuch lower dissolved gas concentrations, and FR3 showedcomparable results to mineral oil.

    0

    20

    40

    60

    80

    100

    120

    140

    160

    Mineral oil Midel7131 FR3

    Gasconcentration(ppm) Calculated value

    HYDRAN reading

    Fig.7 HYDRAN readings versus calculated values from laboratory DGAresults for PD tests

    The comparison between the maximum HYDRAN readings and theexpected values calculated from the laboratory DGA results by (1) forthe three types of fluid was shown in Fig. 7.

    For mineral oil and Midel7131, the maximum readings obtainedfrom the HYDRAN sensor were about two times higher than theexpected values, which was similar to the situation of breakdown tests.However the maximum reading from HYDRAN in FR3 is in thesimilar range as the calculated value. It took 7 hours for the HYDRAN

    reading to reach the maximum in FR3 and this long waiting timeallows the dissolved gases in FR3 to reach a better equilibrium in thebody of oil and a relatively higher gas concentration was achieved inthe bottom area.

    4 Conclusions

    Esters have similar DGA characteristics to mineral oil for electricfaults, and the DGA diagnosis continues to act as a feasible means toindicate the health of ester oil filled transformer, since key gases werefound in mineral oil as well as ester oils after electric faults throughthe laboratory based DGA.

    The dissolved gas concentrations in FR3 after breakdown andpartial discharges was found similar to mineral oil, while Midel7131having lower gas concentrations for both tests.

    Although HYDRAN successfully read the dissolved gases, thequantitative comparison between the HYDRAN reading and the DGAresults show the difference and this difference could be caused by thedifferent sampling positions. A time delay of HYDRANs reading wasobserved with esters due to the high viscosity of ester and the limitedoil circulation in the experiment setup. In real situation, ester filledtransformers operate under a relatively higher temperature with load,

    which helps to reduce the viscosity of ester and achieve a better oilcirculation through either natural or forced oil flow. Neverthelessfurther study on the HYDRANs sensitivities to dissolved gases inesters is required.

    Acknowledgement

    The authors wish to thank AREVA T & D, EdF Energy, M & IMaterials, National Grid, Scottish Power, TJ|H2b analytical servicesand United Utilities for their financial support to form the researchconsortium on Alternative fluids for large power transformers at TheUniversity of Manchester. The authors are grateful to the help givenby Michael Webb from MW Test Equipment for supplying theHYDRAN 201R.

    Reference[1] T.V Oommen, C. C. Claiborne, C.T. Mullen, Biodegradable electrical

    insulation fluids, Electrical Insulation Conference Proceedings, Illinois,USA, pp 465 468, IEEE, 1997.

    [2] T.V.Oommen, C.C.Claiborne and E.J.Walsh. A new vegetable oil basedtransformer fluid:Development and verification Conference on IEEEElectrical Insulation and Dielectric phenomena 2000, pp 308-312.

    [3] D.Martin, I Khan, J.Dai, Z.D.Wang, An Overview of the Suitability ofVegetable Oil Dielectrics for use in Large Power Transformers, Eurotechconference 2005, November 2005, Chester, UK

    [4] Duval, M., Dissolved gas analysis: It can save your transformer, ElectricalInsulation Magazine, IEEE Volume 5, Issue 6, Nov.-Dec. 1989 Page(s):22 27, Digital Object Identifier 10.1109/57.44605

    [5] IEEE.Std.C57.104-1991, "IEEE Guide for the Interpretation of GasesGenerated in Oil-Immersed Transformers, June/July 1991.

    [6] I. Khan, Z.D Wang, I. Cotton,S. Northcote, Dissolved Gas Analysis (DGA)of Alternative Fluids for Power Transformers, submitted to IEEE ElectricalInsulation Magazine in 2007.

    [7] Envirotemp FR3 Fluid Dissolved Gas Guid, Section R900-20-19, August,2006[8] BS EN60567 Oil-filled electrical equipment Sampling of gases and of oil

    for analysis of free and dissolved gases Guidance pp 19-39 December2005.

    [9] Moore, J.H.; Spencer, N.D, Encyclopedia of Chemical Physics andPhysical Chemistry, Volumes 1-3. Institute of Physics, 2001

    [10] Instruction manual for HYDRAN 201R, version 3.0

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