TRADEASIA INTERNATIONAL PTE LTD 133 Cecil Street # 12 …aluminium-sulphate.com/wp-content/...SulfateMSDS.pdf133 Cecil Street # 12-03 Keck Seng Tower, Singapore 069535, Republic Of

TRADEASIA INTERNATIONAL PTE LTD 133 Cecil Street # 12-03 Keck Seng Tower, Singapore 069535, Republic Of Singapore Tel. +65 6227 6365 - Fax. +65 6225 6286 www.chemtradeasia.com

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Material Safety Data Sheet Aluminium Sulfate

Section 1: Chemical Product and Company Identification Product Name : Aluminium Sulfate Chemical Formula : Al2(SO4)3 Company Identification : Tradeasia International Pte Ltd Email : [email protected] Section 2: Composition and Information on Ingredients Composition:

Name CAS# Aluminium Sulfate 10043-01-3

Section 3: Hazards Identification 3.1 GHS Classification Corrosive to metals (Category 1), H290 Serious eye damage/eye irritation (Category 1), H318 3.2 GHS Label elements Signal word: Danger Hazard statement(s):

• H290 May be corrosive to metals. • H318 Causes serious eye damage.

Precautionary statement(s) Prevention

• P234 Keep only in original container. • P280 Wear eye protection/ face protection.

Response • P305 + P351 + P338 + P310 IF IN EYES: Rinse cautiously with water for several minutes.

Remove contact lenses, if present and easy to do. Continue rinsing. Immediately call a POISON CENTER/doctor.

• P390 Absorb spillage to prevent material damage. Storage

• P406 Store in corrosive resistant container with a resistant inner liner. 3.3 Other hazards - none Section 4: First Aid Measures


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4.1 Description of first aid measures General advice: Consult a physician. Show this safety data sheet to the doctor in attendance. If inhaled: If breathed in, move person into fresh air. If not breathing, give artificial respiration. Consult a physician. In case of skin contact: Wash off with soap and plenty of water. Consult a physician. In case of eye contact Rinse thoroughly with plenty of water for at least 15 minutes and consult a physician. If swallowed: Never give anything by mouth to an unconscious person. Rinse mouth with water. Consult a physician. 4.2 Indication of any immediate medical attention and special treatment needed: No data available Section 5: Fire and Explosion Data 5.1 Extinguishing media Suitable extinguishing media: Use water spray, alcohol-resistant foam, dry chemical or carbon dioxide. 5.2 Special hazards arising from the substance or mixture: Sulphur oxides, Aluminum oxide 5.3 Advice for firefighters: Wear self-contained breathing apparatus for firefighting if necessary. 5.4 Further information: No data available Section 6: Accidental Release Measures 6.1 Personal precautions, protective equipment and emergency procedures Wear respiratory protection. Avoid dust formation. Avoid breathing vapours, mist or gas. Ensure adequate ventilation. Evacuate personnel to safe areas. Avoid breathing dust. 6.2 Environmental precautions: Do not let product enter drains. 6.3 Methods and materials for containment and cleaning up Pick up and arrange disposal without creating dust. Sweep up and shovel. Keep in suitable, closed containers for disposal. Section 7: Handling and Storage 7.1 Precautions for safe handling Avoid formation of dust and aerosols. Provide appropriate exhaust ventilation at places where dust is formed.


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7.2 Conditions for safe storage, including any incompatibilities Store in cool place. Keep container tightly closed in a dry and well-ventilated place. Hygroscopic. Store under inert gas. Section 8: Exposure Controls/Personal Protection 8.1 Control parameters Value: PEL (long term) Control parameters: 2 mg/m3 Basis: Singapore. Workplace Safety and Health Act - First Schedule Permissible Exposure Limits of Toxic Substances 8.2 Exposure controls Appropriate engineering controls: Handle in accordance with good industrial hygiene and safety practice. Wash hands before breaks and at the end of workday. Personal protective equipment: Eye/face protection: Face shield and safety glasses Use equipment for eye protection tested and approved under appropriate government standards such as NIOSH (US) or EN 166(EU). Skin protection: Handle with gloves. Gloves must be inspected prior to use. Use proper glove removal technique (without touching glove's outer surface) to avoid skin contact with this product. Dispose of contaminated gloves after use in accordance with applicable laws and good laboratory practices. Wash and dry hands. The selected protective gloves have to satisfy the specifications of EU Directive 89/686/EEC and the standard EN 374 derived from it. Full contact Material: Nitrile rubber Minimum layer thickness: 0,11 mm Break through time: 480 min Material tested:Dermatril® (KCL 740 / Aldrich Z677272, Size M) Splash contact Material: Nitrile rubber Minimum layer thickness: 0,11 mm Break through time: 480 min Material tested:Dermatril® (KCL 740 / Aldrich Z677272, Size M) data source: KCL GmbH, D-36124 Eichenzell, phone +49 (0)6659 87300, e-mail [email protected], test method: EN374 If used in solution, or mixed with other substances, and under conditions which differ from EN 374, contact the supplier of the CE approved gloves. This recommendation is advisory only and must be evaluated by an industria situation of anticipated use by our customers. It should not be construed as offering an approval for any specific use scenario. Body Protection: Complete suit protecting against chemicals, The type of protective equipment must be selected according to the concentration and amount of the dangerous substance at the specific workplace. Respiratory protection:


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Where risk assessment shows air-purifying respirators are appropriate use (EN 143) respirator cartridges as a backup to engineering controls. If th full-face supplied air respirator. Use respirators and components tested and approved under appropriate government standards such as NIOSH (US) or CEN (EU). Control of environmental exposure: Do not let product enter drains. Section 9: Physical and Chemical Properties a) Appearance: Form: powder Colour: white b) Odour No data available c) Odour Threshold No data available d) pH No data available e) Melting point/freezing point Melting point/range: 770 °C - dec. f) Initial boiling point and boiling range No data available g) Flash point Not applicable, No data available h) Evaporation rate No data available i) Flammability (solid, gas) The product is not flammable. - Flammability (solids) j) Upper/lower flammability or explosive limits No data available k) Vapour pressure No data available l) Vapour density No data available m) Relative density 2,71 g/mL at 25 °C n) Water solubility 1.000 g/l at 20 °C - OECD Test Guideline 105 - completely miscible o) Partition coefficient: noctanol/water No data available p) Auto-ignition temperature No data available q) Decomposition temperature No data available r) Viscosity No data available s) Explosive properties Not explosive t) Oxidizing properties The product has been shown not to be oxidizing in a test following Directive 67/548/EEC (Method A17, Oxidizing properties). u) Surface tension 73 mN/m at 20 °C Section 10: Stability and Reactivity Data 10.1 Reactivity: No data available 10.2 Chemical stability: Stable under recommended storage conditions. 10.3 Possibility of hazardous reactions: No data available 10.4 Conditions to avoid: Air Exposure to moisture 10.5 Incompatible materials: Incompatible with strong bases and oxidizing agents., Ammonia, Water, Amines 10.6 Hazardous decomposition products: Hazardous decomposition products formed under fire conditions. - Sulphur oxides, Aluminum oxide Other decomposition products - No data available


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Section 11: Toxicological Information 11.1 Information on toxicological effects Acute toxicity: LD50 Oral - Rat - male and female - > 5.000 mg/kg(Aluminium sulphate) (OECD Test Guideline 401) Skin corrosion/irritation: Skin - Rabbit(Aluminium sulphate) Result: No skin irritation - 4 h (OECD Test Guideline 404) Serious eye damage/eye irritation: Eyes - Rabbit(Aluminium sulphate) Result: Irritating to eyes. (OECD Test Guideline 405) Respiratory or skin sensitization: No data available(Aluminium sulphate) Germ cell mutagenicity Ames test(Aluminium sulphate) S. typhimurium Result: negative (Aluminium sulphate) Rat Cytogenetic analysis Carcinogenicity: IARC: No component of this product present at levels greater than or equal to 0.1% is identified as probable, possible or confirmed human carcinogen by IARC. Reproductive toxicity: Specific target organ toxicity - single exposure: No data available(Aluminium sulphate) Specific target organ toxicity - repeated exposure: No data available Aspiration hazard: No data available(Aluminium sulphate) Additional Information: RTECS: BD1700000 To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated. To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated.(Aluminium sulphate) Section 12: Ecological Information 12.1 Toxicity: Toxicity to daphnia and other aquatic invertebrates LC50 - Daphnia magna (Water flea) - 38,2 mg/l - 48 h(Aluminium sulphate) 12.2 Persistence and degradability: No data available 12.3 Bioaccumulative potential No data available 12.4 Mobility in soil: No data available(Aluminium sulphate) 12.5 Results of PBT and vPvB assessment: PBT/vPvB assessment not available as chemical safety assessment not required/not conducted Section 13: Disposal Considerations 13.1 Waste treatment methods Product: Offer surplus and non-recyclable solutions to a licensed disposal company. Dissolve or mix the material with a combustible solvent and burn in a chem scrubber. Contaminated packaging: Dispose of as unused product


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Section 14: Transport Information 14.1 UN number: ADR/RID: 3260 IMDG: 3260 IATA-DGR: 3260 14.2 UN proper shipping name: ADR/RID: CORROSIVE SOLID, ACIDIC, INORGANIC, N.O.S. (Aluminium sulphate) IMDG: CORROSIVE SOLID, ACIDIC, INORGANIC, N.O.S. (Aluminium sulphate) IATADGR: Corrosive solid, acidic, inorganic, n.o.s. (Aluminium sulphate) 14.3 Transport hazard class(es) ADR/RID: 8 IMDG: 8 IATA-DGR: 8 14.4 Packaging group: ADR/RID: III IMDG: III IATA-DGR: III 14.5 Environmental hazards: ADR/RID: no IMDG Marine pollutant: no IATA-DGR: no 14.6 Special precautions for user: No data available Section 15: Other Regulatory Information 15.1 Safety, health and environmental regulations/legislation specific for the substance or mixture: No data available

Section 16: Other Information References: Not available. Other Special Considerations: Not available. The information above is believed to be accurate and represents the best information currently available to us. However, we make no warranty of merchantability or any other warranty, express or implied, with respect to such information, and we assume no liability resulting from its use. Users should make their own investigations to determine the suitability of the information for their particular purposes. In no way shall Tradeasia International Pte. Ltd. Be liable for any claims, losses, or damages of any third party or for lost profits or any special, indirect, incidental, consequential or exemplary damages, howsoever arising, even if Tradeasia International Pte. Ltd. has been advised of the possibility of such damages.

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TRADEASIA INTERNATIONAL PTE LTD 133 Cecil Street # 12 …aluminium-sulphate.com/wp-content/...SulfateMSDS.pdf133 Cecil Street # 12-03 Keck Seng Tower, Singapore 069535, Republic Of