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TRANSFORMING A PAINT FACTORY TO PLAYING FIELDS
A CASE STUDY
Presented By: Thomas HoldenHaley & Aldrich, San Diego, CA
Coauthors: Deborah GevaltMark HaleyHaley & Aldrich, Boston, MABarry MonahanWellesley College, Wellesley, MA
Outline
■ Project vision
■ Site history
■ Nature and extent of contamination
■ Remediation activities
■ Completed athletic complex
■ Remediation and construction costs
■ Lessons learned and conclusions
■ Questions
Project Vision
■ Reclaim and reuse land consistent with Master Plan
■ Construct an NCAA-caliber athletic complex to attract students
■ Create additional educational opportunities
■ Mitigate existing liability and risks
Physical 3-D modelFencing and warning signs
Historical Site UsageHenry Wood’s Sons Paint Factory 1848 to 1928
Paint factory engraving
Dam and remnant foundation, prior to remediation
On-Site Paint Pigment Manufacturing
Numerous other colors and shades were discovered at the former paint factory
Yellow Building
Lead Melting
Manufacturing Building
Storage Building
Residential Buildings
1920 Sanborn map
Marseilles Green
Color Common
Name Chemical Formula
YellowChrome Yellow
(Lead Chromate)
PbCrO4
Red Red Lead(Minium)
Pb3O4
BluePrussian
Blue(Ferric
Ferrocyanide)
Fe4[Fe(CN)6]3
Red Bldg
Characterization Elements
■ Multiple sources of contamination
■ Primary contaminants of concern:● Heavy metals and cyanide in soil
● Hexavalent chromium in groundwater
■ Innovative approaches to:● Develop alternative exploration and
analytical techniques
● Differentiate leachability potentials
● Develop conceptual site model
Innovative Approaches
■ Negotiation and use of Synthetic Precipitation Leaching Procedure (SPLP)
■ Application of Scanning Electron Microscope coupled with Energy Dispersive X-Ray (SEM/EDX) to differentiate chromium compounds
● Leachable (calcium/potassium chromate)
● Non-Leachable (lead chromate)
■ Calcium chromate is ~3 million times more soluble than lead chromate
Scanning electron microscope
Magnified image of soil particles
Typical calcium chromate EDX
Calcium
Chromium
Typical lead chromate EDX
Chromium
Lead
Lead
Innovative Approaches (Cont.)
■ Detailed groundwater profiling program to define the location and limits of source material
■ Bench-scale treatability studies to evaluate chemical reduction of CrVI
● Calcium polysulfide
● Ferrous sulfate
● others
Groundwater profiling to define plume and sources
Primary Contaminants of Concern and Remediation Goals
Cyanide
Chromium, Total
Chromium, Hexavalent
Lead
1,300200
110,0008,635
31,700200
220,000400
Max Soil/Sed. Conc. (mg/kg)
Soil Remedial Goal (mg/kg)
Treatment Goal:
Chromium, Hexavalent 200 mg/kg
1.0 mg/l SPLP
Remedial Solution
Surface water diversion (10 sq. mile watershed)
Cofferdam installationConsolidation area construction
Remove contaminated sediment from Paintshop Pond in the dry
Excavate and consolidate 200,000 cy of contaminated soils
Remediation of additional impact areas discovered
Dredge 6,500 cy from Lake Waban Treat 30,000 cy of leachable CrVI contaminated soils (15% of total volume)
Five-Acre engineered barrier (cap) over contaminated soils
Cost Summary
Generalized Scope Est. Cost (Millions)
Pre-construction Services 3.6
Remediation
1. Treatment (30,000 cy) ~ $75/cy2. Earthmoving (450,000 cy), Dam, Wetlands3. Engineered Barrier Cap (5 ac.) ~ $132K/ac.
Subtotal:
2.212.50.7
15.4
Construction Administration 4.4
Athletic Fields 7.3
Total: 30.7
Excludes Legal, Remedial Investigation, Risk Assessment, and Wellesley College Internal Management Costs.
Project Benefits■ Reclaimed 30 acres of the campus that was
restricted from use due to exposure to contaminants
■ Developed athletic fields, open space, and wetland habitat for use by the College and surrounding community
■ Irrigation of fields from on-site surface water source
■ Restoration of historic mill dam
■ Created 7.35 acres of wetland replacement including a boardwalk within the area being utilized today as a learning environment by the College
Restored wetland habitat, October 2003
Restored mill dam structure
Lessons Learned and Conclusions
■ On-site remedy combined with suitable land use and control resulted in cost effective solution
■ Successful dust control
■ Treatment rates impacted more by physical than chemical constraints
■ Contingency planning for discovery of additional contaminated material necessary
Lessons Learned and Conclusions(Cont.)
■ Combination of SEM-EDX, SPLP, and CrVI analyses were useful tools for conceptual site model development and delineating leachable CrVI
■ Field XRF and other on-site mobile lab analyses useful in guiding remediation
■ Groundwater has dramatically improved
■ Beware of the snapping turtles!