12
2006 WINTER The Tufts University Department of Chemistry continues its dual mission of education and research. RESEARCH Charles Sykes In 1983 Heinrich Rohrer and Gerd Binning became the first to image individual atoms. Using a home-built apparatus floating on a superconducting magnet and partially held together with scotch tape they resolved the atoms of a silicon surface. They had just built the first Scanning Tunneling Microscope (STM). This instrument operates by scanning a very sharp metal tip biased at around 1 Volt over a conducting surface. With a separation between the tip and sample of around 1 nm one would expect classically that no current should flow, but quantum mechanics tells us that electrons can tunnel from one place to another when the gap is small enough. The magnitude of this tunneling current is exponentially dependent on the distance between the tip and sample, and this phenomenon is the origin of the incredible resolution of the technique. Over the last 25 years the design of STMs has been refined and the scanning probe field has reached the point where one can move single atoms and molecules, measure the vibrational spectrum of a single bond, and even controllably alter the charge and conformation of individual molecules. The geometry of the microscope tip is crucial for high resolution imaging. Figure 1 shows some scanning electron microscope images of Education and Research Continued on page 2 Chair’s Corner MARY SHULTZ Hello alums and friends of the department. It has been another great year for Chemistry at Tufts University and we have even more planned for the coming year. Actually, part of the plans involves you, our alums. A Chemistry Alumni Organizing Committee is being formed with the initial contacts being Lynn Batchelder, Roy Desrochers, Cedric D'Hue and Mark Latina. The Faculty liaison for the group is Professor Albert Robbat. The Organizing Committee will be run by alumni for alumni. The primary purpose of the Committee is to organize events involving our graduates at various venues beginning with an event around reunion weekend on campus this spring. Professor Robbat is looking for volunteers to join the four initial contacts, so please email him at [email protected] and let him know of your interest and suggestions. Our major news this year is moving into the newly renovated east wing and the hiring of Professor Charles Sykes. Professor Sykes received his Masters degree in Chemistry at Oxford University in England and his Ph.D. in Chemistry at Cambridge University also in England. He is a physical chemist working on some very fundamental problems in the field. Here at Tufts, Professor Sykes is setting up experiments at 4 K and will scan surfaces with Charles Sykes Chem Notes { TUFTS UNIVERSITY CHEMISTRY DEPARTMENT } DUAL MISSION Continued on page 9

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Page 1: TUFTS UNIVERSITY CHEMISTRY DEPARTMENT

2 0 0 6 • W I N T E R

The Tufts University Department of Chemistry continues its dual mission of education and research.

RESEARCHCharles Sykes

In 1983 Heinrich Rohrer and Gerd Binningbecame the first to image individual atoms.Using a home-built apparatus floating on asuperconducting magnet and partially heldtogether with scotch tape they resolved theatoms of a silicon surface. They had just builtthe first Scanning Tunneling Microscope(STM). This instrument operates by scanning a very sharp metal tip biased at around 1 Voltover a conducting surface. With a separationbetween the tip and sample of around 1 nm one would expect classically that no current

should flow, but quantum mechanics tells us that electrons can tunnel from one place to another when the gap is small enough.The magnitude of this tunneling current is exponentially dependent on the distancebetween the tip and sample, and this phenomenon is the origin of the incredible resolution of the technique.

Over the last 25 years the design of STMs has been refined and the scanning probe field has reached the point where one can move single atoms and molecules,measure the vibrational spectrum of a singlebond, and even controllably alter the charge and conformation of individual molecules.The geometry of the microscope tip is crucial for high resolution imaging. Figure 1 showssome scanning electron microscope images of

Education and Research

Continued on page 2

Chair’s CornerM A R Y S H U LT Z

Hello alums and friends of the

department. It has been another

great year for Chemistry at Tufts

University and we have even more

planned for the coming year.

Actually, part of the plans

involves you, our alums. A

Chemistry Alumni Organizing

Committee is being formed with

the initial contacts being Lynn

Batchelder, Roy Desrochers,

Cedric D'Hue and Mark Latina.

The Faculty liaison for the group

is Professor Albert Robbat. The

Organizing Committee will be run

by alumni for alumni.The primary

purpose of the Committee is to

organize events involving our

graduates at various venues

beginning with an event around

reunion weekend on campus this

spring. Professor Robbat is looking

for volunteers to join the four

initial contacts, so please email

him at [email protected]

and let him know of your interest

and suggestions.

Our major news this year is

moving into the newly renovated

east wing and the hiring of

Professor Charles Sykes. Professor

Sykes received his Masters

degree in Chemistry at Oxford

University in England and his

Ph.D. in Chemistry at Cambridge

University also in England. He is

a physical chemist working on

some very fundamental problems

in the field. Here at Tufts, Professor

Sykes is setting up experiments

at 4 K and will scan surfaces with

Charles Sykes

ChemNotes{ T U F T S U N I V E R S I T Y C H E M I S T R Y D E PA R T M E N T }

DUAL MISSION

Continued on page 9

Page 2: TUFTS UNIVERSITY CHEMISTRY DEPARTMENT

2 t u f t s c h e m n o t e s w i n t e r 2 0 0 6

STM tips we prepared by electrochemicallyetching tungsten wire in concentrated potassiumhydroxide solution. Most of these tips yieldatomically resolved images, which means thatthe tips have a single atom protruding a fractionof a nanometer further than all the other atoms.

My interest in this technique arose during myPh.D. at Cambridge when I had the opportunityto use an STM, and I realized the incredibleopportunities this microscope offered in theunderstanding of chemistry at the single moleculelevel. My group is now focused on using STMto study catalytically relevant systems in anattempt to understand reaction mechanisms byrelating atomic-scale structure to reactivity. Weare also interested in the intrinsic properties ofmetals such as copper, silver and gold and howwe can exploit them in order to position, order,and move molecules with nanometer precision.

We can create regular surface features called“Quantum Corrals” which are single atom highterraces containing between 50-3000 atoms.Electrons are trapped inside these structures and

they form patterns as they bounce off the sidesof the corrals. Quantum mechanics allows us tocalculate the wavefunctions of the electronstrapped in these structures using simple particlein a box equations. The goals of this project areto understand how molecules interact with theelectron density in these systems and to investi-gate how we can tailor these interactions inorder to spontaneously self-assemble moleculesinto new surface architectures.

To date, my most interesting research involvedour discovery at Penn State that individualhydrogen atoms could be moved and positionedjust below a metal surface using the microscopetip. Figure 2 shows an STM image of the word“Sykes” I wrote by placing individual hydrogenatoms in subsurface sites in palladium metal.This type of work has important implications for the chemical and catalysis industries, as manyimportant hydrogenation reactions are thoughtto be driven by this subsurface hydrogen.

Professor Charles Sykes obtained a combinedB.S./M.S. in Chemistry from Oxford University(UK) in 1998 before moving to Cambridge University to start a Ph.D. with ProfessorRichard Lambert in Surface Chemistry. Aftergraduating from Cambridge in 2002 he movedto the US as a postdoctoral fellow in ProfessorPaul Weiss’s group at The Pennsylvania StateUniversity to work on low-temperature scanningtunneling microscopy. After two years at PSU he moved to The University of North Carolinaat Charlotte to work in the OptoelectronicsCenter and specialized in atomic forcemicroscopy research.

The goals of this project are to understand how moleculesinteract with the electron density in these systems

and to investigate how we can tailor these interactions in order to spontaneously

self-assemble molecules into new surface architectures.

Manipulation of hydrogen atoms beneath the

surface of palladium using low-temperature

STM produces features that are only 0.03 nm

high and 4 nm wide. These arise from the out-

ward distortion of the surface metal atoms to

accommodate the hydrogen atoms placed in

chemically and technologically important sites

immediately below the surface.

Figure 1

Figure 2

Scanning electron microscopy images

of a STM tip made by electrochemically etching

tungsten wire. From the inset one can see that

the tip is very sharp at both micrometer and

nanometer scales.

Page 3: TUFTS UNIVERSITY CHEMISTRY DEPARTMENT

w i n t e r 2 0 0 6 c h e m n o t e s 3

The Chemistry Department recently purchased a new gas chromatography/massspectrometry (GC/MS) instrument fromShimadzu Corporation. The GC hasstate-of-the-art temperature and pressurecontrol technology, while the MS providesunmatched detection sensitivity. The dataanalysis software uses automated searchablelibraries to identify sample unknowns. TheGC/MS will be used to support problem-based lab learning experiments in Chemistry42 (quantitative analysis), Chemistry 141(instrumental analysis), and in a universitysponsored freshman course, Windows onResearch, Environmental Forensics.

Coupling mass spectrometers to gas andliquid chromatography systems, the purposeof the latter is to separate componentspresent in complex mixtures into individualconstituents prior to detection, has madethis instrument the most often used analytical tool in industry. Sophisticated algorithms are used to match each samplecomponent’s mass spectrum against a knowncompound’s mass spectral fingerprint inthe library. When no spectral interferencesexist from other constituents in the sample,compound identification is unambiguous.

Experiments will be developed to teach students how to use GC/MS and LC/MS instruments, apply them to real-worldproblems and, at the same time, learn aboutthe science behind each of the techniques.In one experiment, students are given a soilsample contaminated with fuel and askedto determine the type (e.g., gasoline, dieselfuel, bunker oil, and/or coal tar) and age of contamination. A list of indicator compounds (biomarkers) is provided thatcan be used to differentiate fuel type andrelease age. Since these compounds rangefrom highly volatile (gasoline) to extremelylow volatility organics (coal tar), studentsneed to develop GC separation methodspractical to the boiling range of these compounds. To accomplish this task efficiently, students learn how to use a software tool that calculates optimum GC separation performance based on running extremely slow, faster, and fastestexperiments. From this data, studentslearn about the field of separation scienceby answering questions related to theoryand practice as they relate to why separation

efficiencies change with column temperatureand pressure conditions. Once each tech-nique has been optimized, students learnhow to use the MS library search tools toidentify sample unknowns. They learn, atthe same time, how mass spectrometers work and how to interpret MS data.

Students will have success, but will fail to identify some of the important indicator compounds because they existin low concentrations and are masked byinterferents in the sample. Fresh gasoline,for example, consists of more than 250 different organic compounds.

Failure to identify key constituents is an important problem in the chemicalindustry. The ability to identify unknownsin complex mixtures is equally important in the food, beverage, fragrance, and phar-maceutical industries, where unanticipatedodors, poor taste, or toxic compounds mayresult in unanticipated health problemsand/or damage to the brand. Concentratedoil extracts of lemons and oranges, for example, contain more than one-hundred different organic compounds as do petroleum products. How is it possible to identify low level unknowns in suchcomplicated mixtures? Students will learn

how to use new deconvolution softwaredeveloped at Tufts (Robbat) that is capable of untangling complicated mass spectra so that low-level target compounds and unknowns can be identified. In the process, students will learn about chemometrics (statistical analysis) and the emergence of these tools to solve complex analytical problems.

Problem-based lab learning employsstrategies that mix academic rigor withpractical, hands-on training. It offers students an opportunity to spend more time learning instruments and, at the same time, understanding the strengths and weaknesses of each technique in a particular application. Problem-based labexperiments are not “cook-book” as werelaboratory experiments done in the past.Roy Desrochers, a Tufts graduate and consultant in the beverage industry, hasalready offered to help with the design of a lab that will employ the MS as an electronic nose to “sniff ” differences in the aroma of beer. I welcome your involvement in helping to develop another problem-based lab experiment based on your experiences.

EDUCATIONAlbert Robbat, Jr.

Problem-based lab learning employs strategies that mix academic rigor with practical,

hands-on training.

Page 4: TUFTS UNIVERSITY CHEMISTRY DEPARTMENT

4 t u f t s c h e m n o t e s w i n t e r 2 0 0 6

The R.M. Karapetoff Cobb Chemistry FundMimi ChoMina Fung

The M.D. Angell & H.B. Durkee Scholarship FundKarolina Mizeracka

The Durkee ScholarshipsShinji SuzukiScott West

The Max Tishler Prize ScholarshipTimothy BassellMimi Cho

The Amos Emerson Dolbear ScholarshipsAlex R. Caplan

The Anna Quincy Churchill Prizes in General BiologyKatherine DunnCory Rillahan

The Benjamin G. Brown ScholarshipKarolina Mizeracka

The Howard Sample Prize Scholarship in PhysicsMimi Cho

The Thomas Harrison Carmichael and Emily Leonard Carmichael Prize ScholarshipKarolina Mizeracka

Summa Cum Laude GraduatesKarolina MizerackaMatthew CableJason Vladimer

Magna Cum Laude GraduatesAlex CaplanLewis RieleyShinji SuzukiJennifer Wind

Outstanding Academic Performance AwardZihni Basar Bilgicer

Graduate Student Research AwardIvan Korendovych

Gladys Anderson Emerson ScholarshipMimo Cho

Research Travel Excellence AwardYina KuangNicholas Yoder

Doctoral Degrees Awarded 2004-2005

Zihni Basar Bilgicer (Kumar)“Protein Design Using Unnatural Amino Acidswith Fluorinated Side Chains”

John Paul Birtles (Kounaves) “Solution Based Studies of Tetranuclear ( ~ 4-oxo) – Cu (II) Complexes”

Alfio Fichera (Kumar) “Syntheses of Trifluoromethyl-Containing AminoAcids and Development of Catalysts Capable ofHydrolyzing the D-Ala-D-Lac Depsipeptide”

David Ives Turner (d’Alarcao)“Design and Synthesis of Inositol Phosphate Glycan Conjugates”

Master’s Degrees Awarded 2004-2005

Brandon Jerome KitchelMichael Ramos

Bachelor’s Degrees Awarded

Clifford Jeffrey BergMatthew Gregory CableAngela D. Caldera-SiuAlex R. CaplanCelia Cristina EscamillaRobert Howard GoldsteinJason GoutisAlison Jane HolmesNarmadan KumarasamyElizabeth Rose MacariKarolina MizerackaLewis Thomas RieleyJessica F. RobertsPeter John SambatakosNina Marie SoaresAbbey D. StatesShinji SuzukiJason Samuel VladimerJennifer Kathleen Wind

Chemistry Major AwardsPresented 2004-2005

Page 5: TUFTS UNIVERSITY CHEMISTRY DEPARTMENT

w i n t e r 2 0 0 6 c h e m n o t e s 5

Faculty and Staff NewsStudent AwardsLaila Dafik selected to present a talk at the Younger Chemists Committees of the ACS Northeastern Section (NESACS) and the German Chemical Society 6th annual student exchange program in Konstanz, Germany

Ginevra Clark selected to present a poster at the Younger Chemists Committees of the ACS Northeastern Section (NESACS) and the GermanChemical Society 6th annual student exchange program in Konstanz,Germany

Faculty AwardsKrishna Kumar received the Massachusetts Technology Investigation Award.

David Walt received the Herman Block Award, University of Chicago,Department of Chemistry.

David Walt – Willard Lecturer, University of Michigan, Department of Chemistry.

David Walt – Francis Clifford Phillips Lectures,University of Pittsburgh, Department of Chemistry.

The awards for Outstanding Achievement are

given semi-annually to a teaching assistant,

staff member and faculty member for extra-

ordinary contributions to the department.

FA L L 2 0 0 4FACULTY

Christopher Morse

STAFF

Geni Magliano

TEACHING

ASSISTANT

Deno Del Sesto

S P R I N G 2 0 0 5FACULTY

Marc d’Alarcao

STAFF

Larry Aulenback

TEACHING

ASSISTANT

Subbu Tarakkad

Krishnaji

Semester Achievement Awards

In Memoriam

It is with great sadness that we report on the passing of Grant Urry.Professor Urry was chairman of the department from 1968-1973 and was named the Robinson Professor of Chemistry in 1971,a chair he held until his retirement in 1992. Those of you who remember Professor Urry will appreciate the following:At his passing he requested no service, but rather to remember him by voting democratic.

Dr. Charles Sykes recentlyjoined the faculty as a physicalchemist. Charlie received hisMaster’s Degree in Chemistry at Oxford University in Englandand his Ph.D. in Chemistry atCambridge University in England. Prior to Tufts, Charlieworked as a research associateat University of North Carolina at Charlotte.

Justin Cronin is the most recentaddition to the office staff. Justinpreviously worked as a buyer atJoseph’s Gourmet Pasta & SaucesCompany. Justin majored ineconomics at the University ofMassachusetts.

Page 6: TUFTS UNIVERSITY CHEMISTRY DEPARTMENT

6 t u f t s c h e m n o t e s w i n t e r 2 0 0 6

Tufts Chemistry Journal ClubNick Yoder

For the past few years, a newarena for communicating anddiscussing scientific ideas hasbeen quietly growing in theChemistry Department. SinceSpring Semester of 2003, a fewgrad students have been organizing biweekly JournalClub meetings. Students, faculty,and postdocs gather to hearexciting, freshly publishedresults from the chemical literature presented by one oftheir own number. Althoughattendance was sometimeserratic in the beginning, thegroup is now firmly established in Department culture andattracts 15-20 attendees permeeting. An even surer sign ofthe original group’s success isthe establishment of a secondJournal Club with a different scientific focus in Spring 2005.(see accompanying article on the Physical/Analytical Journal Club)

The older group, known as theTufts Chemistry Journal Club,began as a group dedicated to discussing biologically oriented literature. The decisionto narrow the scientific topicswas not easy, but was intendedto keep the nascent groupgoing. Comments grad studentNick Yoder, one of the original organizers:“Our goal was to onlymeet every few weeks, but toattract a core group that attendsevery meeting. We felt that if thescience was too general, wemight not get that core.”Theplan has worked out well, and

the scientific focus has evenbroadened somewhat. Recentpresentations have addressedthe characterization of themolybdenum-iron cofactor of anitrogen-fixing enzyme, theacceleration of organic reactionsin combinations of immisciblesolvents and, in a guest lecturefrom Chemical Engineering’s Professor Blaine Pfeifer, the large-scale production of organic chemicals by bacteria.One particularly memorable discussion considered basic scientific philosophy and howbest to study complex biologicalsystems.

Each meeting focuses on a particular paper, which is distributed electronically theweek before the meeting.The presenter makes an informal presentation duringwhich audience questions areencouraged, and more discus-sion follows the end of the talk. Refreshments are provided,thanks to the kind support ofthe Department, the GraduateStudent Council, and the Graduate School of Arts and Sciences.

The Club provides many bene-fits. For starters, students getsome help keeping up with thefast pace of scientific researchand also benefit from havingfaculty to provide backgroundand insight.“The journal club isvery useful to follow currenttrends in science and, mostimportantly, talk about themwith people who are interestedin it” comments graduate student Ivan Korendovych.Beyond that, students get

some insight into how to keep up with literature andwhat constitutes an interestingpaper. They can also hone theirpresenting skills, a significantand under-emphasized part ofboth academic and industrial science. Many more studentshave realized this chance, as the number of volunteers ready to present has grownsteadily.

Beyond these, however, theJournal Club provides an

opportunity to get away from the daily grind of theirexperiments and consider exciting new research. As Professor Marc d’Alarcao says:“The intellectual environment of our department dependsheavily on events outside theclassroom and lab, includingseminars, journal clubs, and even the ‘problem of the day’posted in the graduate studentlounge. These extracurricularactivities provide a forum for all of us to take a break from

Physical Chemistry Journal ClubDan Killelea

Public speaking is one of the most important skills a chemist canpossess. No matter what aspect of chemistry a student enters afterleaving Tufts, it will be of utmost importance that graduates be able to communicate clearly to an audience. Public speaking skills are emphasized by the degree requirements; however, theopportunities to present are among the most stressful aspects ofthe graduate program!

The success of the biochemistry journal club inspired a group of students in the physical chemistry groups to start a comple-mentary journal club, the Physical Chemistry Journal Club (PCJC).Dan Killelea typically recruits speakers and with help from Irene Li and Tory Campbell gets refreshments, and sets up for the meetings. The meetings are held alternating Friday afternoons and are intended to be an informal forum for discussion of current research.

The PCJC gives the department a chance to step out of their specialty and look at a different problem.Topics covered over thepast year have included multiple quantum coherences of nuclearspins in a nanometer-scale device, sequence-specific molecularlithography on single DNA molecules and single-molecule optoelectronics. The PCJC looks forward to our second year, and a new slate of presentations from both faculty and students!

A list of past and future presenters can be found athttp://chem.tufts.edu/PhysChem.html. If you are interested in attending or presenting, please email Dan Killelea at [email protected].

Student News

Page 7: TUFTS UNIVERSITY CHEMISTRY DEPARTMENT

w i n t e r 2 0 0 6 c h e m n o t e s 7

our daily problems and remem-ber why we love science”.

For more information about theTufts Chemistry Journal Club

or to contact the organizers,

please visit http: //ase.tufts.edu

/chemistry/kumar/jc/.

Younger Chemists CommitteeIvan Korendovych

This year three of Tufts Chemistry graduate students,Ginevra Clark, Laila Dafik andDan Killelea were selected for a weeklong German ExchangeProgram. This program is anexchange program betweenthe German Chemical Society(GDCh-JCF) and the Northeast-ern Section of the AmericanChemical Society (NESACS)Younger Chemists Committee(YCC). Each year since the program's conception, a groupof twelve younger chemists has traveled across the AtlanticOcean to participate in a weeklong program.The programusually consists of visits to local laboratories, tours of local companies, presentationsat a regional student research conference, networking eventsand, of course, sightseeing.Foreign career and educationalopportunities are especiallyemphasized throughout theweek. The students that partici-pated in the program wereselected by a selection commit-tee in a highly competitive two-step process that consisted ofapplication screening followedby an interview.

CGSC News

The 2005-2006 members of

the CGSC (Timothy Blicharz,

Tory Campbell, Ryan

Hayman, Subrahmanian

Tarakkad Krishnaji, and

Deniz Yuksel) have been

busy organizing fun and

stimulating social events for

the department this year.

With the conclusion of the

Tufts Intramural Summer

Softball League, a cookout

was held to celebrate another playoff con-

tending Chemistry Department ‘Isotopes.’

The annual September rafting trip saw its

biggest turnout yet, with 16 people partici-

pating, including several from the incoming

first year graduate student class. Many first

year graduate students also took advantage

of the Q&A session sponsored by the CGSC

in October, where they could bring forth

questions regarding classes, choosing a

research group, or any other aspect of

graduate student life at Tufts. Plans for

the winter months include movie night

and other popular New England activities,

such as ice skating and skiing trips. Once

spring and summer roll around, there will

surely be more interesting and exciting

activities in store for the department, too!

Page 8: TUFTS UNIVERSITY CHEMISTRY DEPARTMENT

Workhard,Play hard

8 t u f t s c h e m n o t e s w i n t e r 2 0 0 6

From left to right:

Dan Killelea, Ivan Korendovych,

Deno Del Sesto, Irene Li, Kyle Bake,

Ryan Hayman, Ginevra Clark and

Christian Ziegler laying in the mud.

From left to right:

Dan Killelea, Ginevra Clark, Erin Iski, Deno Del Sesto,

Ryan Hayman, Ashleigh Baber, Chris Thomas

and Dr. Blaine PfeiferIt seems that a good portion of the graduate students in

the chemistry department have been leading double lives.

Aside from their work in chemistry, they also seem to be

football players. A group of about 20 students meets on

Saturday mornings for a game of tag-football. The weather

does not stop the game. So far, they have played in bitter

cold, almost a foot of snow, and the infamous mud bowl on

an unseasonably warm January morning. Despite the rumors,

Bill Belichick and Rodney Harrison have not agreed to play,

at least not yet!

Page 9: TUFTS UNIVERSITY CHEMISTRY DEPARTMENT

Continued from page 1 STM. The combination of STM

and low temperature produces

some stunning and compelling

images of electron waves and

molecules assembled on surfaces.

He is currently setting up his lab

on the ground floor of the newly

renovated east wing. The space

has certainly transformed with this

cutting edge instrumentation.

We also welcomed one of our

largest classes of graduate students

this fall – a full seventeen strong.

Graduate students are, in many

ways, the lifeblood of the depart-

ment and we welcome these new

recruits to our professional ranks.

Two graduate students: Nicholas

Yoder and Yina Kuang, received the

graduate student excellence award.

The award carries with it an expense

paid trip back to the graduate

student’s undergraduate school

where they present a seminar

about their research at Tufts.

This year we had our first winner

in the Gladys Anderson Emerson

Scholarship competition. Mimi Cho

received this award in recognition

of her outstanding performance,

including research, in chemistry.

The scholarship is sponsored by

Iota Sigma Pi (ISP).

On the faculty front, this year

we are searching for a lecturer in

chemistry. The lecturer will take

major responsibility for the main-

stream introductory program and

is expected to play an integral role

in ongoing efforts to ensure that

all students achieve their potential

in chemistry.

With the completion of the East

Wing renovation, only the center

of the building remains to complete

the phased renovation plan. The

center of the building houses the

organic chemistry teaching labora-

tory that many of you remember

well. We are looking to our alums

to help us renovate this space.

w i n t e r 2 0 0 6 c h e m n o t e s 9

Chair’s Corner

Mary Shultz

The Tufts Chemistry WEB Site!http://chem.tufts.edu

OUR SITE PROVIDES INFORMATION such as course listings, current course material, degree requirements, faculty/staff/student

info, the graduate program, special events, links to other chemistry resources, an on-line historical archive, back issues of ChemNotes,

and more detailed information about the exciting and ongoing research being carried out by our faculty. The hope is that this

resource will provide information for prospective graduate students and alumni and will eventually contain links to many valuable

chemistry resources within the department and throughout the world. Check us out and see what is currently going on in the

department.You can access our site at: http://chem.tufts.edu.

We are still collecting information for several new areas including “Alumni Page” where we would like to list as many of you as

possible.We would like to include not only names and e-mail addresses but items of interest and WWW links to alumni pages and

your areas of current employment or involvement. So please write or e-mail us if you would like to be included. Let us know where

you are and what you are doing!

The web site was created and is maintained by Professor Samuel Kounaves. (Samuel. [email protected])

Page 10: TUFTS UNIVERSITY CHEMISTRY DEPARTMENT

10 t u f t s c h e m n o t e s w i n t e r 2 0 0 6

Seminar Series JANUARY 24

Prof. Annabella Selloni

Princeton University

The Surface Science of TiO2:

Insights from First Principles

Simulations

JANUARY 31

Dr. Timothy Clackson

Ariad Pharmaceuticals, Inc.

Controlling Cellular Events

using Dimerizer Drugs

FEBRUARY 7

Prof. Steven Sibener

University of Chicago

Interfacial Dynamics of Polymers and

SAMs: Glassy Dynamics, Hierarchical

Assembly, and the Quest for Perfection

FEBRUARY 23

Prof. Donald Hilvert

ETH Zürich, Switzerland

Molecular Diversity and Catalysis

FEBRUARY 28

Prof. Héctor Abruña

Cornell University

Nanometric Building Blocks

and Devices

MARCH 7

Prof. Andrew Gellman

Carnegie Mellon University

Enantioselectivity on Naturally

Chiral Surfaces

MARCH 16

Max Tishler Lecture

Prof. George Whitesides,

Harvard University

TBA

The Max Tishler lecture will be held

in P104, Pearson Chem on Thursday,

March 16th

MARCH 30

Dr. Andrea Cochran

Genentech, Inc.

TBA

APRIL 4

Prof. Mark Hersam

Northwestern University

Characterization and Manipulation

of Individual Molecules

on Semiconductor Surfaces

APRIL 11

Prof. Paul Canfield

Iowa State University

The Design, Growth, Discovery

and Characterization of Novel

Intermetallic Compounds

APRIL 18

Prof. Jon Clardy

Harvard Medical School

Discovering New Compounds

in Nature

APRIL 25

Graduate Student

Hosted Colloquium

Prof. Harry Gray

California Institute of Technology

The Currents of Life: Electron Flow

Through Iron and Copper Proteins

SPRI

NG

2006

Visitors are welcomeAll seminars are held in the Pearson

Chemistry Building, 62 Talbot

Avenue in Medford, Room P-106

at 4:30 pm unless otherwise noted.

Refreshments are served thirty

minutes prior to the seminar. For

further information please contact

Ruth Ayers at (617) 627-6491.

Page 11: TUFTS UNIVERSITY CHEMISTRY DEPARTMENT

BUSINESS REPLY MAILFIRST CLASS MAIL PERMIT NO.3696 BOSTON,MA

NewsletterDepartment of ChemistryTufts University62 Talbot AvenueMedford,MA 02155

NO POSTAGE NECESSARY IF MAILED

IN THE UNITED STATES

Postage will be paid by addressee

3 PRINTED ON RECYCLED PAPER

TUFTS UNIVERSIT Y OFFICE OF PUBLICATIONS 6833 01/04

ChemNotesCREDITS:

Contributors: M. J. Shultz, C. Sykes, A. Robbat, N.Yoder,

I. Korendovych, D. Killelea, T. Blicharz, K. Kumar, D. D'Andrea

SENIOR EDITOR:

E. Coombes

Page 12: TUFTS UNIVERSITY CHEMISTRY DEPARTMENT

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NONPROFIT ORGANIZATION U.S. POSTAGE PA I D BOSTON, MA PERMIT NO. 1161

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Calling all alums!In this edition of the newsletter, we are seeking information from you,our alumni. Looking ahead a couple of years, we plan to have a reunionof chemistry graduates, likely in connection with alumni weekend.To plan this event, it would be helpful if you could take a few minutesand let us know what you would like to see.

What are your interests? ______________________________________________________________________________________

What events would you like to see planned for this celebration? ______________________________________________________________________________________

How has your chemistry education helped in development of your career? ______________________________________________________________________________________

What advice might you have for our newly minted grads? ____________________________________________________________________________________________________________________________________________________________________________

We are also seeking to expand our advisory group. The advisory groupconsists of chemistry alums who have gone on to assume leadershippositions. While we have been in touch with a few of you to be part ofour advisory group, we would be very pleased to have more of you joinin this endeavor.

You may jot your responses on this form, fold it and pop it back in themail. Or you can send your thoughts to me by email:[email protected]—no c in Shultz!

Thank you in advance for being in touch with us!

Mary Shultz

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