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Unit 5: Ionic Bonding & Nomenclature

Unit 5: Ionic Bonding & Nomenclature. Section 1: Ions Pyrite (FeS 2 ) is a common mineral that is often mistaken for gold—hence its nickname, “fool’s

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Page 1: Unit 5: Ionic Bonding & Nomenclature. Section 1: Ions Pyrite (FeS 2 ) is a common mineral that is often mistaken for gold—hence its nickname, “fool’s

Unit 5: Ionic Bonding & Nomenclature

Page 2: Unit 5: Ionic Bonding & Nomenclature. Section 1: Ions Pyrite (FeS 2 ) is a common mineral that is often mistaken for gold—hence its nickname, “fool’s

Section 1: Ions

Pyrite (FeS2) is a common mineral that is often mistaken for gold—hence its nickname, “fool’s gold.” Pyrite is an example of a crystalline solid. In this chapter, you will learn about crystalline solids composed of ions that are bonded together. But first you need to understand how ions form from neutral atoms.

Page 3: Unit 5: Ionic Bonding & Nomenclature. Section 1: Ions Pyrite (FeS 2 ) is a common mineral that is often mistaken for gold—hence its nickname, “fool’s

Valence Electrons:electrons in the highest

occupied energy level

- determines chemical properties

- only e- involved in chemical reactions

9-Fluorine (F) 11-Sodium (Na)10-Neon (Ne)

Group # =

Valence #

Page 4: Unit 5: Ionic Bonding & Nomenclature. Section 1: Ions Pyrite (FeS 2 ) is a common mineral that is often mistaken for gold—hence its nickname, “fool’s

Electron dot structures:diagrams showing valence e- as dots

Page 5: Unit 5: Ionic Bonding & Nomenclature. Section 1: Ions Pyrite (FeS 2 ) is a common mineral that is often mistaken for gold—hence its nickname, “fool’s

Electron dot structures:diagrams showing valence e- as dots

Page 6: Unit 5: Ionic Bonding & Nomenclature. Section 1: Ions Pyrite (FeS 2 ) is a common mineral that is often mistaken for gold—hence its nickname, “fool’s

Electron dot structures:diagrams showing valence e- as dots

Page 7: Unit 5: Ionic Bonding & Nomenclature. Section 1: Ions Pyrite (FeS 2 ) is a common mineral that is often mistaken for gold—hence its nickname, “fool’s

Electron dot structures:diagrams showing valence e- as dots

Page 8: Unit 5: Ionic Bonding & Nomenclature. Section 1: Ions Pyrite (FeS 2 ) is a common mineral that is often mistaken for gold—hence its nickname, “fool’s

Electron dot structures:diagrams showing valence e- as dots

Page 9: Unit 5: Ionic Bonding & Nomenclature. Section 1: Ions Pyrite (FeS 2 ) is a common mineral that is often mistaken for gold—hence its nickname, “fool’s

Electron dot structures:diagrams showing valence e- as dots

Page 10: Unit 5: Ionic Bonding & Nomenclature. Section 1: Ions Pyrite (FeS 2 ) is a common mineral that is often mistaken for gold—hence its nickname, “fool’s

Electron dot structures:diagrams showing valence e- as dots

Page 11: Unit 5: Ionic Bonding & Nomenclature. Section 1: Ions Pyrite (FeS 2 ) is a common mineral that is often mistaken for gold—hence its nickname, “fool’s

Electron dot structures:diagrams showing valence e- as dots

Page 12: Unit 5: Ionic Bonding & Nomenclature. Section 1: Ions Pyrite (FeS 2 ) is a common mineral that is often mistaken for gold—hence its nickname, “fool’s

Electron dot structures:diagrams showing valence e- as dots

Page 13: Unit 5: Ionic Bonding & Nomenclature. Section 1: Ions Pyrite (FeS 2 ) is a common mineral that is often mistaken for gold—hence its nickname, “fool’s

The Octet Rule• most atoms form bonds to have

8 valence e-

• full outer energy level

• like the Noble Gases

Ne

Lewis dot structure

Page 14: Unit 5: Ionic Bonding & Nomenclature. Section 1: Ions Pyrite (FeS 2 ) is a common mineral that is often mistaken for gold—hence its nickname, “fool’s

nonmetals gain electrons to form negative ionsto achieve a complete octet in its valence level.

Anions

metals lose electrons to form positive ionsleaving a complete octet in the next-lowest energy level.

Cations

Page 15: Unit 5: Ionic Bonding & Nomenclature. Section 1: Ions Pyrite (FeS 2 ) is a common mineral that is often mistaken for gold—hence its nickname, “fool’s

The electron configuration of the sodium ion is the same as that of a neon atom.

Page 16: Unit 5: Ionic Bonding & Nomenclature. Section 1: Ions Pyrite (FeS 2 ) is a common mineral that is often mistaken for gold—hence its nickname, “fool’s

Group 1 always 1+ charge

7.1

MgNa

Mg2+Na+

Group 2always 2+ charge

Page 17: Unit 5: Ionic Bonding & Nomenclature. Section 1: Ions Pyrite (FeS 2 ) is a common mineral that is often mistaken for gold—hence its nickname, “fool’s

1+

2+ 3+

Ionic Compounds

Charges of Ions

Page 18: Unit 5: Ionic Bonding & Nomenclature. Section 1: Ions Pyrite (FeS 2 ) is a common mineral that is often mistaken for gold—hence its nickname, “fool’s

Formation of Anions7.1

The electron configuration of the chloride ion is the same as that of argon.

Page 19: Unit 5: Ionic Bonding & Nomenclature. Section 1: Ions Pyrite (FeS 2 ) is a common mineral that is often mistaken for gold—hence its nickname, “fool’s

Formation of Anions

Oxygen is in Group 6A.

7.1

Page 20: Unit 5: Ionic Bonding & Nomenclature. Section 1: Ions Pyrite (FeS 2 ) is a common mineral that is often mistaken for gold—hence its nickname, “fool’s

7.1

Group 16 (6A) always 2- charge

Group 15 (5A) always 3- charge

Group 17 (7A) always 1- charge

F F

O O

N N

-

2-

3-

Page 21: Unit 5: Ionic Bonding & Nomenclature. Section 1: Ions Pyrite (FeS 2 ) is a common mineral that is often mistaken for gold—hence its nickname, “fool’s

7.1Anions names typically end in -ide

Page 22: Unit 5: Ionic Bonding & Nomenclature. Section 1: Ions Pyrite (FeS 2 ) is a common mineral that is often mistaken for gold—hence its nickname, “fool’s

1+

2+ 3+ 3- 2- 1-

0

charges vary but always +

Charges of Ions

Page 23: Unit 5: Ionic Bonding & Nomenclature. Section 1: Ions Pyrite (FeS 2 ) is a common mineral that is often mistaken for gold—hence its nickname, “fool’s

Conceptual Problem 7.1

7.1

Fill in the blanks.

1.Iodine gains __ e- to form ___

2.Magnesium loses __ e- to form ___

3.Sulfur _____ __ e- to form ___

4.Aluminum _____ __ e- to form ___

1 I-

2 Mg2+

gains 2 S2-

loses 3 Al3+

Page 24: Unit 5: Ionic Bonding & Nomenclature. Section 1: Ions Pyrite (FeS 2 ) is a common mineral that is often mistaken for gold—hence its nickname, “fool’s

Quick Quiz!

1. How many valence electrons are in an atom of oxygen?

A. 2

B. 4

C. 6

D. 8

Page 25: Unit 5: Ionic Bonding & Nomenclature. Section 1: Ions Pyrite (FeS 2 ) is a common mineral that is often mistaken for gold—hence its nickname, “fool’s

Quick Quiz.

2. Atoms that tend to gain a noble gas electron configuration by losing valence electrons are

A. metals.

B. nonmetals.

C. halogens.

D. anions.

Page 26: Unit 5: Ionic Bonding & Nomenclature. Section 1: Ions Pyrite (FeS 2 ) is a common mineral that is often mistaken for gold—hence its nickname, “fool’s

3. When a magnesium atom forms a cation, it does so by

A. losing two electrons.

B. gaining two electrons.

C. losing one electron.

D. gaining one electron.

Quick Quiz.

Page 27: Unit 5: Ionic Bonding & Nomenclature. Section 1: Ions Pyrite (FeS 2 ) is a common mineral that is often mistaken for gold—hence its nickname, “fool’s

Quick Quiz.

4. When a bromine atom forms an anion, it does so by

A. losing two electrons.

B. gaining two electrons.

C. losing one electron.

D. gaining one electron

Page 28: Unit 5: Ionic Bonding & Nomenclature. Section 1: Ions Pyrite (FeS 2 ) is a common mineral that is often mistaken for gold—hence its nickname, “fool’s

Quick Quiz.

5. Write the name and the symbol of the ion formed from a nitrogen atom.

A. nitrogen ion, N3+

B. nitride, N-

C. nitride, N3-

D. nitrogen ion, N2-