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TUBALL™ Single wall carbon nanotubesUSE LESS, DO MORE, PERFORM BETTERMPG Seminar 15th May 2017
Michael EnotiadesSALES MANAGER EMEAOFFICE: +352 2799 0373
MOBILE: +352 661 184 [email protected]
Diameter 1.6 nm
Length > 5 μm
Wall thickness 1 atom
SINGLE WALL CARBON NANOTUBESARE EXCEPTIONAL
SWCNT EXCEPTIONAL PROPERTIES
EXCELLENT CONDUCTOR5 times lighter than copper
STRONGER THAN STEEL100 times
THERMAL STABILITYup to 1000 °C
THE HIGHEST LENGTH TO DIAMETER RATIOup to 5000
LARGE SURFACE AREAUp to 1300 m2/g
1 G = 5,000,000 KMlength of line1 nanotube thick
CARBON NANOFIBERS
Concentration of particles ~0,1%
MICROPARTICLES
A B C
0,5 mm
0,5 mm
0,5 mm
1
1 0
00
1
SWCNT FORMS ITS OWN CONDUCTIVE 3D NETWORKAT ULTRA LOW CONCENTRATIONS
TUBALL™ SINGLE WALL CARBON NANOTUBES
SWCNTs DISPERSION POWER
MATERIAL’S PROPERTIESTHRESHOLD OF CHANGE
MWCNT1 - 6% SWCNT
0.01 - 0.1%
CARBON FIBERS 3 – 12%
CARBON BLACK 10 - 40%
DRASTIC CHANGE OF ELECTRICAL CONDUCTIVITY= 3D NETWORK
TUBALL™ OUTSTANDING QUALITY
TUBALL ™ Environment Health and Safety l OCSiAl November 2016
TUBALLtm CA n° IWTN/COA/W663/001
SPECIFICATIONS VALUE METHOD
Total Carbon ~85% W/W TGA
Nanotube Purity (T1%) ~74% ± 1.5% TGA
Raman G/D Ratio 86.5 ± 7.1Raman, 633 nm
Tube Diameter(approximate average)
~1,5 Nm TEM
SPECIFICATIONS VALUE METHOD
Carbon content > 85wt.% EDX, TGA
CNT content ≥75wt.% TGA, TEM
Number of walls CNT 1 TEM
Mean diameter CNT 1.6nm ± 0.4 Raman, TEM
Length of CNT >5μm AFM
TUBALLtm TDS
HISTORICAL CHANGE IN INDUSTRY - BY OCSIAL
HIGH QUALITY SINGLE WALL CNTS PRODUCED
LARGE VOLUMES AVAILABLE
ACCEPTABLE PRICE FOR INDUSTRY
FOR THE FIRST TIME
OCSiAl
ONE OF THE WORLD’S LEADING PHYSICISTS
Corresponding member of Russian Academy
of Science, professor. Inventor of the plasma-chemical
reactor and head of the technical division of the project.
Completed R&D projects for large international
corporations such as: Hewlett Packard, Samsung,
Air Products & Chemicals, etc.
MIKHAIL PREDTECHENSKIYInventor of OCSiAl Technology.
Senior vice-president and Chief Technology
Officer, OCSiAl
ABOUT OCSiAl
2009Founded to develop scalable synthesis of single wall carbon nanotubes (SWCNT)
2013
Awarded patent for scalable SWCNT production
Graphetron V1.0 reactor10 t/y capacity
2014Began large scale industrial sampling
TUBALL™ product
2017260+ peopleProduct lines: batteries, plastics, composites, coatings, elastomers
Graphetron V50 reactor50 t/y capacity
NovosibirskGRAPHETRON 1.0
OCSiAl WORLDWIDE
Columbus Berlin
Moscow
India
Seoul
Hong Kong
Singapore
Palo AltoChina
Manufacturing
Sales Office
Future Manufacturing
Malaysia
OCSiAl is the largest commercial manufacturer ofhigh quality SWCNTs. Our products are made possible by a breakthrough for industrial SWCNT synthesis.
Luxembourg
Tel-Aviv
10 T/YEAR 60 T/YEAR98% OF GLOBAL SWCNT PRODUCTION
OCSiAl PRODUCTION FACILITYGRAPHETRON 1.0 SWCNT REACTORGRAPHETRON 50 SWCNT REACTOR
TUBALL™ - PRODUCTION PLAN
Production capacity, t/y
50
10
1
800
3 000
1
10
60
800
3000
2015 2016 2017 years2020 2022
COAT COMP_M INK RUBBER BATT PLAST_M COMP_E
TUBALL™ - PRODUCTS AT INDUSTRIAL SCALE
TUBALL™ IS THE FIRST MASS PRODUCEDSWCNT PRODUCT ON THE MARKET
− 90% OF GLOBAL PRODUCTION CAPACITY− RANGE OF DEDICATED PRODUCTS
MATRIX
TUBALL™ - REACH REGISTERED
TUBALLTM is REACH-registered for sales up to 10 tonsRegistration n°01-2120130006-75-0000
TUBALLTM will be REACH-registered for sales up to 100 tons in Q1 2018
TUBALL™ FOR RUBBER
TUBALL™ IMPACT IN RUBBER
TENSILE STRENGTH
ABRASION
COMPRESSIONSET
HYSTERESIS LOSSES
ELECTRICAL CONDUCTIVITY
RESISTANCE TOCHEMICALS
STABILITY VSAGEING
WET GRIPFATIGUE
• Rubber polymer (NR, SBR, NBR,…)• Processing oil
TUBALL™ RUBBER SuspensionSuspensions based on:
TUBALL™ RUBBER MasterbatchTUBALL™ MATRIX Masterbatches based on:
• Solvents• H2O
HOW TO INTRODUCE?
During polymerisation During compound mixing
TYRE PERFORMANCES
TYRE PERFORMANCE: CURRENT SITUATION
Current technologies: Performance trade-offs
Reference compound
80859095
100105110115120
Electricalconductivity
Stiffness
Abrasionresistance
Wet grip
Energyefficiency
80859095
100105110115120
Electricalconductivity
Stiffness
Abrasionresistance
Wet grip
Energyefficiency
80859095
100105110115120
Electricalconductivity
Stiffness
Abrasionresistance
Wet grip
Energyefficiency
Better Rolling Resistance Higher Wet GripHigher Abrasion Resistance
TYRE PERFORMANCE: TUBALL™ FIRST RESULTS
Next slide: Results from the 3 first experiments run on Tyre Tread Compounds
- Addition of TUBALL™ - 0.1 to 0.2% weight
- No formulation optimization
- 3 different recipes and formulations – 3 different partners
- Sample testing in independent laboratories
TIRE PERFORMANCE: NEW SPACE
With TUBALL™ : Strong extension of performance space
Manufacturer recipe #10.2% TUBALLTM in compound
Manufacturer recipe #20.1% TUBALLTM in compound
Manufacturer recipe #30.1% TUBALLTM in compound
80859095
100105110115120
ElectricalConductivity
Stiffness
Abrasionresistance
Wet Grip(TanD 0°C)
Energyefficiency
(TanD 60°C)
80859095
100105110115120
ElectricalConductivity
Stiffness
Abrasionresistance
Wet Grip(TanD 0°C)
Energyefficiency
(TanD 60°C)
80859095
100105110115120
ElectricalConductivity
Stiffness
Abrasionresistance
Wet Grip(TanD 0°C)
Energyefficiency
(TanD 60°C)
Reference compound
OTHER RUBBER APPLICATIONS
Hoses and Seals for oil and gas industry
O-rings, Seals and Gasketsfor high temperature and high
pressure environments
Hoses and Flexible Partsfor automotive industry
Conveyor Belts for mining, food,
electronic industry
+20% reduced property loss after rapid gas decompression
+10% saving properties after heat aging
EXPERIMENTAL RESULTSHNBR RUBBER O-RING COMPOUND
+ 33°Ctemperature before degradation of material (thermal resistance )
-18%Compression set
+12% Shore A Hardness
x 103
Electrical conductivity
+29% Tensile strength
COMPANYEuropean producer
of Industrial and Off the Road Tyres
PRODUCTTruck tyre for mining and earth moving
REQUIREMENTS• Abrasion resistance 15% higher than existing compounds
• Rubber running temperature reduced by 10 to 20oC
TURNING POINT0.3% of TUBALL
single wall carbon nanotubes
added to existing formulation
KEY BENEFITS• Higher mileage than existing tyres in ssame
category
• Longer tyre carcass life
• More robustness versus speed and hot
qweather
Application case
TUBALL single wall carbon nanotubes
for EARTHMOVER TYRES
COMPANYEuropean producer
of Motorcycle Tyres
PRODUCTOriginal Equipment tyre for
electrical 2 wheeled vehicle
REQUIREMENTS• Resistivity to earth <106 Ohm
• Weight < 1650g
• Wear resistance and wet grip 15% better than existing tyre in the same category
TURNING POINT0.1% of TUBALL single wall
carbon nanotubes added to
existing formulation
KEY BENEFITS• Protection of user and electronic ccomponents
against electrostatic discharge
• Energy saving
• Higher mileage and better grip than
cconventional tyres in the same category
Application case
TUBALL single wall carbon nanotubes
for MOTORCYCLE TYRES
TUBALL™ FORCONDUCTIVE SILICONE
Gaskets, profiles for electronics
Cable elements Adhesive/encapsulantfor solar cells
High voltageresistor packs
MARKET REQUIREMENTS FORCONDUCTIVE SILICONE
High consistency silicone (HCR)
10–108 Ω•сm
Liquid silicone rubber (LSR)
101–105 Ω•сm
TUBALL™ MATRIX FOR SILICONES
TUBALL™ MATRIX 601Carrier: polydimethylsiloxane oil LSR (liquid silicone rubber), and RTV (room temperature vulcanized) silicones
TUBALL™ MATRIX 602Carrier: vinyl-terminated polydimethylsiloxane LSR (liquid silicone rubber), and RTV (room temperature vulcanized) and HCR (high consistency rubber) silicones
TUBALL™ MATRIX 605Carrier: silicone gumHCR (high consistency rubber) silicones
STANDARD COMPOUNDING PROCESS
Same technique as other masterbatch introduction (pigments, etc.)
TUBALL™ MATRIX 605HCR ELECTRICAL RESISTANCE 10-1011 Ω•cm*
* Tested in HCR (Shore 60). Measurements conducted according to ASTM D991 standard.
Vo
lum
e r
esi
stiv
ity,
Ω∙c
m
TUBALLTM MATRIX 605 content, wt.%
PHYSICAL PROPERTIES OF HCR (50-60 SHORE)WITH 3% TUBALL™MATRIX 103 - 104 Ω•cm
HCR (Base) 50% of Carbon Black based masterbatch
Ultimate elongation, %
11
Tensile strength, Mpa
580
Hardness Shore A, pts.
61
0.3% TUBALLTM
5
9
576
150
5667
THANK YOU
OCSiAl ASIA PACIFIC
Hong Kong: Suite 1207100, Queen’s Road CentralHong Kong+852 3180-9388
China: #2004, 20th Floor , Block B, Dachong Business Centre, No. 9678, Shennan Road , Nanshan District, Shenzhen, Guangdong, China+86 135 9012 [email protected]
Korea: 406-840 Republic of Korea, Incheon, Incheon Technopark 12, Gaetbeol-ro, Yeonsu-gu, Pilot Plant Bldg., Office 208.+82 32 260 [email protected]
OCSiAl LLC
500 S Front St, Suite 860, Columbus, OH 43215+1 415 9065271
640 W California Ave, Suite 210, Sunnyvale, CA 94086+1 415 906 5271
OCSiAl.ru LLC
107078, Russia, MoscowKalanchevskaya str., 2 bld.+7 499 653 5152
630090, Russia, Novosibirsk,Inzhenernaya str., 24+7 383 201 8387
OCSiAl Europe Sarl
Luxembourg: 1, rue de la Poudrerie,L-3364, LeudelangeGrand Duchy of Luxembourg+352 27990373
OCSiAl CONTACTS