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UV Technology For Corrosion Resistance Ben Curatolo [email protected] We Make It Exciting To Watch Paint Dry ™ Light Curable Coatings

UV Technology For Corrosion Resistance - … Technology for Corrosion... · UV Technology For Corrosion Resistance ... Portable UV Lamps For Field ... ASTM D 1654 ratings of scribed

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Page 1: UV Technology For Corrosion Resistance - … Technology for Corrosion... · UV Technology For Corrosion Resistance ... Portable UV Lamps For Field ... ASTM D 1654 ratings of scribed

UV Technology For Corrosion Resistance

Ben [email protected]

We Make It Exciting To Watch Paint Dry ™

Light Curable Coatings

Page 2: UV Technology For Corrosion Resistance - … Technology for Corrosion... · UV Technology For Corrosion Resistance ... Portable UV Lamps For Field ... ASTM D 1654 ratings of scribed

The Advantages Of Ultraviolet (UV) CoatingTechnology Are Well Documented

• Solvent-Free• Reduction Of VOCs• Reduction Of HAPs• Faster Cure• Improved Efficiency• Source Reduction• Sustainability

• Non-Flammable• Lower Insurance Costs• Healthier Work Environment• Reduced Regulatory Impact• Reduced Scrap And Waste• Lower Applied Cost• Reduced Overall Cost

Page 3: UV Technology For Corrosion Resistance - … Technology for Corrosion... · UV Technology For Corrosion Resistance ... Portable UV Lamps For Field ... ASTM D 1654 ratings of scribed

UV Coating Technology Is Widely Used For Decoration And Protection In Many Different Applications In A Wide Range Of Industries

Page 4: UV Technology For Corrosion Resistance - … Technology for Corrosion... · UV Technology For Corrosion Resistance ... Portable UV Lamps For Field ... ASTM D 1654 ratings of scribed

The Suitability Of UV Technology For High Performance Corrosion Resistant

Applications Has Now Been Demonstrated

• Industrial And Aerospace Applications

• Field Application And Cure Using Portable Lamps

• Protection Of Steel Surfaces And Large Structures

• Protection Of Aerospace Aluminum Alloys

Page 5: UV Technology For Corrosion Resistance - … Technology for Corrosion... · UV Technology For Corrosion Resistance ... Portable UV Lamps For Field ... ASTM D 1654 ratings of scribed

Corrosion Is A Tremendous Problem ForMany Segments Of The U.S. Economy

• Aircraft• Motor Vehicles• Ships• Railroad Cars• Bridges• Electrical Utilities• Petroleum Refining

• Gas Pipelines• Liquid Pipelines• Home Appliances• Food Processing• Water Systems• Sewer Systems• Pulp & Paper Processing

Page 6: UV Technology For Corrosion Resistance - … Technology for Corrosion... · UV Technology For Corrosion Resistance ... Portable UV Lamps For Field ... ASTM D 1654 ratings of scribed

Annual Corrosion Costs In The United States

• $276 Billion Annual Cost In 2001

• Office Of Infrastructure Research And Development

• U.S. Federal Highway Administration

• Report No. FHWA-RD-01-156*

• $400 Billion Annual Cost Presently

• U.S. Government Accountability Office (GAO)

*CC Technologies And NACE International, September 30, 2001

Page 7: UV Technology For Corrosion Resistance - … Technology for Corrosion... · UV Technology For Corrosion Resistance ... Portable UV Lamps For Field ... ASTM D 1654 ratings of scribed

Commercial Materials Typically Used For HighPerformance Corrosion-Resistant Applications

Are Epoxy And Polyurethane Paints

• Epoxy Paints As Primers And In Applications Where Maintaining Color And Appearance Are Not Critical

• Polyurethane Paints As Topcoats And In Applications Where Color And Appearance Must Be Maintained

Page 8: UV Technology For Corrosion Resistance - … Technology for Corrosion... · UV Technology For Corrosion Resistance ... Portable UV Lamps For Field ... ASTM D 1654 ratings of scribed

Disadvantages Of Epoxies And Polyurethanes

• Limited Application Conditions - Temperature And Humidity

• Two Part Systems With Corrosive Or Toxic Components

• Limited Pot Life - Viscosity Increases From Mixing Until Cure

• Extended Period Of Time Before Full Cure Is Achieved

• Components On The Toxics Release Inventory (TRI)

• Pollution From Solvents, VOCs, HAPs, Isocyanates, Chromates

• Performance Disadvantages When Used Individually

Page 9: UV Technology For Corrosion Resistance - … Technology for Corrosion... · UV Technology For Corrosion Resistance ... Portable UV Lamps For Field ... ASTM D 1654 ratings of scribed

Solvent-Free UV Coating Technology Has Demonstrated High Performance Corrosion

Protection For Industrial Applications

• Formulation With Urethane Acrylates

• Formulation With Chromium-Free Corrosion Inhibitors

• High Intensity UV Cure For OEM Applications

• Portable UV Lamps For Field Application And Cure

• Clean, Green, Pollution-Free Corrosion Protection

Page 10: UV Technology For Corrosion Resistance - … Technology for Corrosion... · UV Technology For Corrosion Resistance ... Portable UV Lamps For Field ... ASTM D 1654 ratings of scribed

Epoxy And Polyurethane Corrosion Resistance

Coating Layer Total Total CorrosionDescription Wet Mils Dry Mils Resistance*

Epoxy 22 16 1=Best

Epoxy 14 10 2

Polyurethane 10 6 3

Polyurethane 3 2 4=Worst

*Corrosion resistance ranking based on ASTM D 1654 ratings of scribed steel panels after 672 hours ASTM B 117 salt fog testing

Page 11: UV Technology For Corrosion Resistance - … Technology for Corrosion... · UV Technology For Corrosion Resistance ... Portable UV Lamps For Field ... ASTM D 1654 ratings of scribed

Epoxy And Polyurethane Corrosion Resistance

Coating Layer Layer Total Total CorrosionDescription Wet Mils Wet Mils Dry Mils Resistance*

Epoxy 22 22 16 1=Best

Polyurethane 5 15 10 2Epoxy 10

Epoxy 14 14 10 3

Polyurethane 10 10 6 4

Polyurethane 3 3 2 5=Worst

*Corrosion resistance ranking based on ASTM D 1654 ratings of scribed steel panels after 672 hours ASTM B 117 salt fog testing

Page 12: UV Technology For Corrosion Resistance - … Technology for Corrosion... · UV Technology For Corrosion Resistance ... Portable UV Lamps For Field ... ASTM D 1654 ratings of scribed

Corrosion Resistance With Zinc-Rich EpoxyCoating Layer Layer Total Total CorrosionDescription Wet Mils Wet Mils Dry Mils Resistance*

Polyurethane 7 13 8 1=BestZinc Epoxy Primer 6

Epoxy 16 22 15 2Zinc Epoxy Primer 6

Epoxy 22 22 16 3

Zinc Epoxy Primer 6 6 4 4

Epoxy 14 14 10 5

Polyurethane 10 10 6 6

Polyurethane 3 3 2 7=Worst*Corrosion resistance ranking based on ASTM D 1654 ratings of scribed steel panels after 672 hours ASTM B 117 salt fog testing

Page 13: UV Technology For Corrosion Resistance - … Technology for Corrosion... · UV Technology For Corrosion Resistance ... Portable UV Lamps For Field ... ASTM D 1654 ratings of scribed

Corrosion Resistance Ranking For UV CoatingCoating Layer Layer Total Total CorrosionDescription Wet Mils Wet Mils Dry Mils Resistance*

Epoxy 22 22 16 1=Best

UV Coating 2 2 2 2

Polyurethane 5 15 10 3Epoxy 10

Epoxy 14 14 10 4

Polyurethane 10 10 6 5

Polyurethane 3 3 2 6=Worst

*Corrosion resistance ranking based on ASTM D 1654 ratings of scribed steel panels after 672 hours ASTM B 117 salt fog testing

Page 14: UV Technology For Corrosion Resistance - … Technology for Corrosion... · UV Technology For Corrosion Resistance ... Portable UV Lamps For Field ... ASTM D 1654 ratings of scribed

Corrosion Resistance Rankings For UV CoatingsCoating Layer Layer Total Total CorrosionDescription Wet Mils Wet Mils Dry Mils Resistance*

UV Topcoat 2 4 4 1=BestUV Primer 2

Epoxy 22 22 16 2

UV Coating 2 2 2 3

Polyurethane 5 15 10 4Epoxy 10

Epoxy 14 14 10 5

Polyurethane 10 10 6 6

Polyurethane 3 3 2 7=Worst*Corrosion resistance ranking based on ASTM D 1654 ratings of scribed steel panels after 672 hours ASTM B 117 salt fog testing

Page 15: UV Technology For Corrosion Resistance - … Technology for Corrosion... · UV Technology For Corrosion Resistance ... Portable UV Lamps For Field ... ASTM D 1654 ratings of scribed

Corrosion Resistance Rankings For UV CoatingsCoating Layer Layer Total Total CorrosionDescription Wet Mils Wet Mils Dry Mils Resistance*

UV Topcoat 2 5 4 1=BestZinc Epoxy Primer 3

Polyurethane 7 13 8 2Zinc Epoxy Primer 6

UV Topcoat 2 4 4 3UV Primer 2

Epoxy 16 22 15 4Zinc Epoxy Primer 6

Epoxy 22 22 16 5

*Corrosion resistance ranking based on ASTM D 1654 ratings of scribed steel panels after 672 hours ASTM B 117 salt fog testing

Page 16: UV Technology For Corrosion Resistance - … Technology for Corrosion... · UV Technology For Corrosion Resistance ... Portable UV Lamps For Field ... ASTM D 1654 ratings of scribed

Corrosion Resistance Rankings SummaryCoating Layer Layer Total Total CorrosionDescription Wet Mils Wet Mils Dry Mils Resistance*

UV Topcoat 2 5 4 1=BestZinc Epoxy Primer 3

Polyurethane 7 13 8 2Zinc Epoxy Primer 6

UV Topcoat 2 4 4 3UV Primer 2

Epoxy 16 22 15 4Zinc Epoxy Primer 6

Epoxy 22 22 16 5

*Corrosion resistance ranking based on ASTM D 1654 ratings of scribed steel panels after 672 hours ASTM B 117 salt fog testing

Page 17: UV Technology For Corrosion Resistance - … Technology for Corrosion... · UV Technology For Corrosion Resistance ... Portable UV Lamps For Field ... ASTM D 1654 ratings of scribed

Corrosion Resistance Rankings SummaryCoating Layer Layer Total Total CorrosionDescription Wet Mils Wet Mils Dry Mils Resistance*

UV Coating 2 2 2 6

Zinc Epoxy Primer 6 6 4 7

Polyurethane 5 15 10 8Epoxy 10

Epoxy 14 14 10 9

Polyurethane 10 10 6 10

Polyurethane 3 3 2 11=Worst

*Corrosion resistance ranking based on ASTM D 1654 ratings of scribed steel panels after 672 hours ASTM B 117 salt fog testing

Page 18: UV Technology For Corrosion Resistance - … Technology for Corrosion... · UV Technology For Corrosion Resistance ... Portable UV Lamps For Field ... ASTM D 1654 ratings of scribed

UV Coating Technology Is Suitable For High Performance Industrial Applications

Requiring Corrosion Protection

• Improved Protection Of Steel Compared To Standard Coatings

• Dramatically Faster Cure With Lower Material Usage

• Can Be Multifunctional Coating Or Primer/Topcoat System

• Elimination Of Solvents, VOCs, HAPs, Isocyanates, Chromates

• Reduced Pollution And Improved Health Considerations

• Safer And More Efficient Alternative For Corrosion Protection

Page 19: UV Technology For Corrosion Resistance - … Technology for Corrosion... · UV Technology For Corrosion Resistance ... Portable UV Lamps For Field ... ASTM D 1654 ratings of scribed

UV Coating Technology Is Suitable For Corrosion Protection Of Large Structures

• Just As Any Surface Can Be Painted By A Few Individuals Spraying Or Rolling, A UV Coating Can Be Applied And Cured By Painting And Then Following With A UV Lamp

• Cure Is Achieved With A Motion That Can Be Described As "Painting" The Surface With A Handheld UV Lamp

• Movement Of The UV Lamp Is Similar To That Of A Roller Or Spray Gun - At The Same Speed As Paint Application

Page 20: UV Technology For Corrosion Resistance - … Technology for Corrosion... · UV Technology For Corrosion Resistance ... Portable UV Lamps For Field ... ASTM D 1654 ratings of scribed

UV Coating Technology Is Suitable For Corrosion Protection Of Large Structures

Page 21: UV Technology For Corrosion Resistance - … Technology for Corrosion... · UV Technology For Corrosion Resistance ... Portable UV Lamps For Field ... ASTM D 1654 ratings of scribed

UV Technology Is Suitable For Cold Temperatures

• UV Cure Is Tolerant Of Adverse Conditions (34°F)

• Maintains Fast Cure In Seconds

Page 22: UV Technology For Corrosion Resistance - … Technology for Corrosion... · UV Technology For Corrosion Resistance ... Portable UV Lamps For Field ... ASTM D 1654 ratings of scribed

UV Technology Is Suitable For A Wider Range Of Application Conditions Than Standard Coatings

• When Compared To Conventional Paints, UV Cure Is Relatively Independent Of Temperature And Humidity

• UV Coatings Cured Completely In Seconds With Good Performance In A Field Application At 34°F - No Standard Paint Would Have Cured Under Those Conditions

• Good Cure Performance Has Also Been Demonstrated Under Typical Ambient Summertime Conditions

Page 23: UV Technology For Corrosion Resistance - … Technology for Corrosion... · UV Technology For Corrosion Resistance ... Portable UV Lamps For Field ... ASTM D 1654 ratings of scribed

UV Technology Is Suitable For Aerospace Applications Requiring Corrosion Resistance

• Multifunctional UV Coating Can Replace Both The Strontium Chromate Epoxy Primer Layer And The Polyurethane Topcoat Layer Of Current Systems

• Solvent-Free UV Technology With A Chromate-Free Corrosion Inhibitor Eliminates All Toxic Components

• Immediate Cure Increases Efficiency And Dramatically Reduces Dry-To-Fly Time For Painting Operations

Page 24: UV Technology For Corrosion Resistance - … Technology for Corrosion... · UV Technology For Corrosion Resistance ... Portable UV Lamps For Field ... ASTM D 1654 ratings of scribed

Chromate-Free Multifunctional UV Coatings Provide ASTM B-117 Corrosion Resistance

0 Hrs 500 Hrs 1000 Hrs 1500 Hrs 2000 Hrs 2500 Hrs 3000 Hrs

Coated 2024-T3 Aerospace Aluminum Alloy Panels After ASTM B-117 Salt Fog Testing

Page 25: UV Technology For Corrosion Resistance - … Technology for Corrosion... · UV Technology For Corrosion Resistance ... Portable UV Lamps For Field ... ASTM D 1654 ratings of scribed

Chromate-Free Corrosion Resistance Is Maintained With Different Pigments

0 Hrs 500 Hrs 1000 Hrs 1500 Hrs 2000 Hrs 2500 Hrs 3000 Hrs

UV Coated 2024-T3 Aluminum Alloy Panels After ASTM B-117 Salt Fog Testing

Page 26: UV Technology For Corrosion Resistance - … Technology for Corrosion... · UV Technology For Corrosion Resistance ... Portable UV Lamps For Field ... ASTM D 1654 ratings of scribed

Chromate-Free Corrosion Resistance Is Maintained With Different Oligomers

0 Hrs 500 Hrs 1000 Hrs 1500 Hrs 2000 Hrs 2500 Hrs 3000 Hrs

UV Coated 2024-T3 Aluminum Alloy Panels After ASTM B-117 Salt Fog Testing

Page 27: UV Technology For Corrosion Resistance - … Technology for Corrosion... · UV Technology For Corrosion Resistance ... Portable UV Lamps For Field ... ASTM D 1654 ratings of scribed

Chromate-Free Corrosion Resistance Is Maintained With Lower Inhibitor Level

0 Hrs 500 Hrs 1000 Hrs 1500 Hrs 2000 Hrs 2500 Hrs 3000 Hrs

UV Coated 2024-T3 Aluminum Alloy Panels After ASTM B-117 Salt Fog Testing

Page 28: UV Technology For Corrosion Resistance - … Technology for Corrosion... · UV Technology For Corrosion Resistance ... Portable UV Lamps For Field ... ASTM D 1654 ratings of scribed

Chromate-Free Corrosion Resistance Is Maintained With Different Surface Treatment

0 Hrs 500 Hrs 1000 Hrs 1500 Hrs 2000 Hrs 2500 Hrs 3000 Hrs

UV Coated Anodized 2024-T3 Panels After ASTM B-117 Salt Fog Testing

Page 29: UV Technology For Corrosion Resistance - … Technology for Corrosion... · UV Technology For Corrosion Resistance ... Portable UV Lamps For Field ... ASTM D 1654 ratings of scribed

Multifunctional UV Coating Corrosion Resistance Compared To Unprotected Al 2024-T3 Surface

3000 Hrs 24 Hrs

Unprotected:

2024-T3 Panels After ASTM B-117 Salt Fog Testing

UV Coated:

Page 30: UV Technology For Corrosion Resistance - … Technology for Corrosion... · UV Technology For Corrosion Resistance ... Portable UV Lamps For Field ... ASTM D 1654 ratings of scribed

UV Technology Is Suitable For Aerospace Applications Requiring:

Multifunctional Coating - Replaces Primer/TopcoatFast Cure - Seconds To MinutesLong Pot Life - UnlimitedLow VOCs - Solvent-Free, Zero VOC Low Gloss - 20°= 0.4, 60°= 3.0, 85°= 7.0 Flexibility - 10%-20% ElongationCorrosion Resistance - 3000 Hrs ASTM B-117Solvent Resistance - > 200 MEK Double Rubs Skydrol Resistance - Pass

Page 31: UV Technology For Corrosion Resistance - … Technology for Corrosion... · UV Technology For Corrosion Resistance ... Portable UV Lamps For Field ... ASTM D 1654 ratings of scribed

UV Coating Technology Is Also Suitable For High Performance Applications That Do Not

Require Corrosion Resistance

Automobile Headlamps

After Refurbishing Before Refurbishing

Page 32: UV Technology For Corrosion Resistance - … Technology for Corrosion... · UV Technology For Corrosion Resistance ... Portable UV Lamps For Field ... ASTM D 1654 ratings of scribed

UV Coating Technology Is Suitable For High Performance Applications That

Require Excellent Weatherability

Clear UV Coating ∆ E Values After QUV Accelerated Weathering

∆ E = 0.35 0.23 0.25 0.60 0.35 0.47

1000 Hrs 2000 Hrs 3000 Hrs 4000 Hrs 5000 Hrs 6000 Hrs

Page 33: UV Technology For Corrosion Resistance - … Technology for Corrosion... · UV Technology For Corrosion Resistance ... Portable UV Lamps For Field ... ASTM D 1654 ratings of scribed

UV Coating Technology Is Suitable For High Performance Applications That

Require Excellent Weatherability

Clear UV Coating ∆ E Values After QUV Accelerated Weathering

∆ E

Hours

Page 34: UV Technology For Corrosion Resistance - … Technology for Corrosion... · UV Technology For Corrosion Resistance ... Portable UV Lamps For Field ... ASTM D 1654 ratings of scribed

UV Coating Technology Is Also Suitable For High Performance Applications That Do Not

Require Corrosion Resistance

Fast Cure Flooring Applications

Page 35: UV Technology For Corrosion Resistance - … Technology for Corrosion... · UV Technology For Corrosion Resistance ... Portable UV Lamps For Field ... ASTM D 1654 ratings of scribed

UV Coating Technology Is Also Suitable For High Performance Applications That Do Not

Require Corrosion Resistance

Fast Cure Flooring Applications

Page 36: UV Technology For Corrosion Resistance - … Technology for Corrosion... · UV Technology For Corrosion Resistance ... Portable UV Lamps For Field ... ASTM D 1654 ratings of scribed

Summary – UV Technology Is Suitable ForApplications Requiring Corrosion Resistance

And Other High Performance Properties

• Improved Performance Compared To Current Systems

• Dramatically Faster Cure With Lower Material Usage

• Excellent Cure At Temperatures Too Low For Standard Paints

Page 37: UV Technology For Corrosion Resistance - … Technology for Corrosion... · UV Technology For Corrosion Resistance ... Portable UV Lamps For Field ... ASTM D 1654 ratings of scribed

Summary – UV Technology Is Suitable ForApplications Requiring Corrosion Resistance

And Other High Performance Properties

• Reduced Pollution And Improved Health Considerations

• Safer And More Efficient Alternative For Corrosion Protection

• Markets Include Major Infrastructure Of The United States

Page 38: UV Technology For Corrosion Resistance - … Technology for Corrosion... · UV Technology For Corrosion Resistance ... Portable UV Lamps For Field ... ASTM D 1654 ratings of scribed

Summary – UV Technology Is Suitable ForApplications Requiring Corrosion Resistance

And Other High Performance Properties

• From Weatherability To Corrosion Resistance

• From The Ground To The Sky