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VESPR • Valence Electron Shared Pair Repulsion • Atoms and non bonding pairs of electrons surrounding a central bond in such a way as to get as far away as possible from each other.

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VESPR. Valence Electron Shared Pair Repulsion Atoms and non bonding pairs of electrons surrounding a central bond in such a way as to get as far away as possible from each other. VESPR. Valence Electron Shared Pair Repulsion - PowerPoint PPT Presentation

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Page 1: VESPR

VESPR

• Valence Electron Shared Pair Repulsion

• Atoms and non bonding pairs of electrons surrounding a central bond in such a way as to get as far away as possible from each other.

Page 2: VESPR

VESPR

• Valence Electron Shared Pair Repulsion

• Atoms and non bonding pairs of electrons surrounding a central bond in such a way as to get as far away as possible from each other.

Page 3: VESPR

VESPR

• Valence Electron Shared Pair Repulsion

• Atoms and non bonding pairs of electrons surrounding a central bond in such a way as to get as far away as possible from each other.

Page 4: VESPR

VESPR

• Valence Electron Shared Pair Repulsion

• Atoms and non bonding pairs of electrons surrounding a central bond in such a way as to get as far away as possible from each other.

Page 5: VESPR

VESPR Rules

• Determine the number of valence electrons.• Single bond atoms to the central atom• Each bond accounts for two electrons• Double or triple bonds to the central atom if possible• If possible make the outer atoms octets by surrounding

them with the appropriate number of electrons.• If there are additional valence electrons available place

them on the central atom• Determine bond angles and bond shapes associated

with the central atoms

Page 6: VESPR

VESPR Rules

• Determine the number of valence electrons.• Single bond atoms to the central atom• Each bond accounts for two electrons• Double or triple bonds to the central atom if possible• If possible make the outer atoms octets by surrounding

them with the appropriate number of electrons.• If there are additional valence electrons available place

them on the central atom• Determine bond angles and bond shapes associated

with the central atoms

Page 7: VESPR

VESPR Rules

• Determine the number of valence electrons.• Single bond atoms to the central atom• Each bond accounts for two electrons• Double or triple bonds to the central atom if possible• If possible make the outer atoms octets by surrounding

them with the appropriate number of electrons.• If there are additional valence electrons available place

them on the central atom• Determine bond angles and bond shapes associated

with the central atoms

Page 8: VESPR

VESPR Rules

• Determine the number of valence electrons.• Single bond atoms to the central atom• Each bond accounts for two electrons• Double or triple bonds to the central atom if possible• If possible make the outer atoms octets by surrounding

them with the appropriate number of electrons.• If there are additional valence electrons available place

them on the central atom• Determine bond angles and bond shapes associated

with the central atoms

Page 9: VESPR

VESPR Rules

• Determine the number of valence electrons.• Single bond atoms to the central atom• Each bond accounts for two electrons• Double or triple bonds to the central atom if possible• If possible make the outer atoms octets by surrounding

them with the appropriate number of electrons.• If there are additional valence electrons available place

them on the central atom• Determine bond angles and bond shapes associated

with the central atoms

Page 10: VESPR

VESPR Rules

• Determine the number of valence electrons.• Single bond atoms to the central atom• Each bond accounts for two electrons• Double or triple bonds to the central atom if possible• If possible make the outer atoms octets by surrounding

them with the appropriate number of electrons.• If there are additional valence electrons available place

them on the central atom• Determine bond angles and bond shapes associated

with the central atoms

Page 11: VESPR

VESPR Rules

• Determine the number of valence electrons.• Single bond atoms to the central atom• Each bond accounts for two electrons• Double or triple bonds to the central atom if possible• If possible make the outer atoms octets by surrounding

them with the appropriate number of electrons.• If there are additional valence electrons available place

them on the central atom• Determine bond angles and bond shapes associated

with the central atoms

Page 12: VESPR

VESPR Rules

• Determine the number of valence electrons.• Single bond atoms to the central atom• Each bond accounts for two electrons• Double or triple bonds to the central atom if possible• If possible make the outer atoms octets by surrounding

them with the appropriate number of electrons.• If there are additional valence electrons available place

them on the central atom if possible• Determine bond angles and bond shapes associated

with the central atoms

Page 13: VESPR

VESPR Rules

• Determine the number of valence electrons.• Single bond atoms to the central atom• Each bond accounts for two electrons• Double or triple bonds to the central atom if possible• If possible make the outer atoms octets by surrounding

them with the appropriate number of electrons.• If there are additional valence electrons available place

them on the central atom if possible• Determine bond angles and bond shapes associated

with the central atoms

Page 14: VESPR

Bond Angles Bond Shapes

Atoms NBPE Bond Angle Bond Shape

1 to 1 0 NA Linear

2 to 1 0 180 Linear

3 to 1 0 120 Trigonal planar

4 to 1 0 109.5 Tetrahedral

2 to 1 2 <109.5 Bent

3 to 1 1 <109.5 Pyrimidal

5 to 1 0 90/120 Trigonal Bipryimidal

6 to 1 0 90 Octahedral

Page 15: VESPR

Bond Angles Bond Shapes

Atoms NBPE Bond Angle Bond Shape

1 to 1 0 NA Linear

2 to 1 0 180 Linear

3 to 1 0 120 Trigonal planar

4 to 1 0 109.5 Tetrahedral

2 to 1 2 <109.5 Bent

3 to 1 1 <109.5 Pyrimidal

5 to 1 0 90/120 Trigonal Bipryimidal

6 to 1 0 90 Octahedral

Page 16: VESPR

Bond Angles Bond Shapes

Atoms NBPE Bond Angle Bond Shape

1 to 1 0 NA Linear

2 to 1 0 180 Linear

3 to 1 0 120 Trigonal planar

4 to 1 0 109.5 Tetrahedral

2 to 1 2 <109.5 Bent

3 to 1 1 <109.5 Pyrimidal

5 to 1 0 90/120 Trigonal Bipryimidal

6 to 1 0 90 Octahedral

Page 17: VESPR

Bond Angles Bond Shapes

Atoms NBPE Bond Angle Bond Shape

1 to 1 0 NA Linear

2 to 1 0 180 Linear

3 to 1 0 120 Trigonal planar

4 to 1 0 109.5 Tetrahedral

2 to 1 2 <109.5 Bent

3 to 1 1 <109.5 Pyrimidal

5 to 1 0 90/120 Trigonal Bipryimidal

6 to 1 0 90 Octahedral

Page 18: VESPR

Bond Angles Bond Shapes

Atoms NBPE Bond Angle Bond Shape

1 to 1 0 NA Linear

2 to 1 0 180 Linear

3 to 1 0 120 Trigonal planar

4 to 1 0 109.5 Tetrahedral

2 to 1 2 <109.5 Bent

3 to 1 1 <109.5 Pyrimidal

5 to 1 0 90/120 Trigonal Bipryimidal

6 to 1 0 90 Octahedral

Page 19: VESPR

Bond Angles Bond Shapes

Atoms NBPE Bond Angle Bond Shape

1 to 1 0 NA Linear

2 to 1 0 180 Linear

3 to 1 0 120 Trigonal planar

4 to 1 0 109.5 Tetrahedral

2 to 1 2 <109.5 Bent

3 to 1 1 <109.5 Pyrimidal

5 to 1 0 90/120 Trigonal Bipryimidal

6 to 1 0 90 Octahedral

Page 20: VESPR

Bond Angles Bond Shapes

Atoms NBPE Bond Angle Bond Shape

1 to 1 0 NA Linear

2 to 1 0 180 Linear

3 to 1 0 120 Trigonal planar

4 to 1 0 109.5 Tetrahedral

2 to 1 2 <109.5 Bent

3 to 1 1 <109.5 Pyrimidal

5 to 1 0 90/120 Trigonal Bipryimidal

6 to 1 0 90 Octahedral

Page 21: VESPR

Bond Angles Bond Shapes

Atoms NBPE Bond Angle Bond Shape

1 to 1 0 NA Linear

2 to 1 0 180 Linear

3 to 1 0 120 Trigonal planar

4 to 1 0 109.5 Tetrahedral

2 to 1 2 <109.5 Bent

3 to 1 1 <109.5 Pyrimidal

5 to 1 0 90/120 Trigonal Bipryimidal

6 to 1 0 90 Octahedral

Page 22: VESPR

Bond Angles Bond Shapes

Atoms NBPE Bond Angle Bond Shape

1 to 1 0 NA Linear

2 to 1 0 180 Linear

3 to 1 0 120 Trigonal planar

4 to 1 0 109.5 Tetrahedral

2 to 1 2 <109.5 Bent

3 to 1 1 <109.5 Pyrimidal

5 to 1 0 90/120 Trigonal Bipryimidal

6 to 1 0 90 Octahedral

Page 23: VESPR

Bond Angles Bond Shapes

Atoms NBPE Bond Angle Bond Shape

1 to 1 0 NA Linear

2 to 1 0 180 Linear

3 to 1 0 120 Trigonal planar

4 to 1 0 109.5 Tetrahedral

2 to 1 2 <109.5 Bent

3 to 1 1 <109.5 Pyrimidal

5 to 1 0 90/120 Trigonal Bipryimidal

6 to 1 0 90 Octahedral

Page 24: VESPR

Bond Angles Bond Shapes

Atoms NBPE Bond Angle Bond Shape

1 to 1 0 NA Linear

2 to 1 0 180 Linear

3 to 1 0 120 Trigonal planar

4 to 1 0 109.5 Tetrahedral

2 to 1 2 <109.5 Bent

3 to 1 1 <109.5 Pyrimidal

5 to 1 0 90/120 Trigonal Bipryimidal

6 to 1 0 90 Octahedral

Page 25: VESPR

Bond Angles Bond Shapes

Atoms NBPE Bond Angle Bond Shape

1 to 1 0 NA Linear

2 to 1 0 180 Linear

3 to 1 0 120 Trigonal planar

4 to 1 0 109.5 Tetrahedral

2 to 1 2 <109.5 Bent

3 to 1 1 <109.5 Pyrimidal

5 to 1 0 90/120 Trigonal Bipryimidal

6 to 1 0 90 Octahedral

Page 26: VESPR

Bond Angles Bond Shapes

Atoms NBPE Bond Angle Bond Shape

1 to 1 0 NA Linear

2 to 1 0 180 Linear

3 to 1 0 120 Trigonal planar

4 to 1 0 109.5 Tetrahedral

2 to 1 2 <109.5 Bent

3 to 1 1 <109.5 Pyrimidal

5 to 1 0 90/120 Trigonal Bipryimidal

6 to 1 0 90 Octahedral

Page 27: VESPR

Bond Angles Bond Shapes

Atoms NBPE Bond Angle Bond Shape

1 to 1 0 NA Linear

2 to 1 0 180 Linear

3 to 1 0 120 Trigonal planar

4 to 1 0 109.5 Tetrahedral

2 to 1 2 <109.5 Bent

3 to 1 1 <109.5 Pyrimidal

5 to 1 0 90/120 Trigonal Bipryimidal

6 to 1 0 90 Octahedral

Page 28: VESPR

Bond Angles Bond Shapes

Atoms NBPE Bond Angle Bond Shape

1 to 1 0 NA Linear

2 to 1 0 180 Linear

3 to 1 0 120 Trigonal planar

4 to 1 0 109.5 Tetrahedral

2 to 1 2 <109.5 Bent

3 to 1 1 <109.5 Pyrimidal

5 to 1 0 90/120 Trigonal Bipryimidal

6 to 1 0 90 Octahedral

Page 29: VESPR

Bond Angles Bond Shapes

Atoms NBPE Bond Angle Bond Shape

1 to 1 0 NA Linear

2 to 1 0 180 Linear

3 to 1 0 120 Trigonal planar

4 to 1 0 109.5 Tetrahedral

2 to 1 2 <109.5 Bent

3 to 1 1 <109.5 Pyrimidal

5 to 1 0 90/120 Trigonal Bipryimidal

6 to 1 0 90 Octahedral

Page 30: VESPR

Bond Angles Bond Shapes

Atoms NBPE Bond Angle Bond Shape

1 to 1 0 NA Linear

2 to 1 0 180 Linear

3 to 1 0 120 Trigonal planar

4 to 1 0 109.5 Tetrahedral

2 to 1 2 <109.5 Bent

3 to 1 1 <109.5 Pyrimidal

5 to 1 0 90/120 Trigonal Bipryimidal

6 to 1 0 90 Octahedral

Page 31: VESPR

HF

• H = 1 valence electron

• F = 7 valence electron

• H – F

• Linear

Page 32: VESPR

HF

• H = 1 valence electron

• F = 7 valence electron

• H – F

• Linear

Page 33: VESPR

HF

• H = 1 valence electron

• F = 7 valence electron

• H – F

• Linear

Page 34: VESPR

HF

• H = 1 valence electron

• F = 7 valence electron

• H – F

• Linear

Page 35: VESPR

HF

• H = 1 valence electron

• F = 7 valence electron

• H – F

• Linear

Page 36: VESPR

HF

• H = 1 valence electron

• F = 7 valence electron

• H – F

• Linear

Page 37: VESPR

CO2

• C=4 valence electrons = 4• O= 2 (6) valence electrons = 12• O-C-O 16 electrons• O=C=O• O=C=O 16 electrons• 8 surrounding central atom, octet• 0 Nonbonding Pairs Electrons• 2 to 1, 0 NBPE, 180o, Linear

Page 38: VESPR

CO2

• C=4 valence electrons = 4• O= 2 (6) valence electrons = 12• O-C-O 16 electrons• O=C=O• O=C=O 16 electrons• 8 surrounding central atom, octet• 0 Nonbonding Pairs Electrons• 2 to 1, 0 NBPE, 180o, Linear

Page 39: VESPR

CO2

• C=4 valence electrons = 4• O= 2 (6) valence electrons = 12• O-C-O 16 electrons• O=C=O• O=C=O 16 electrons• 8 surrounding central atom, octet• 0 Nonbonding Pairs Electrons• 2 to 1, 0 NBPE, 180o, Linear

Page 40: VESPR

CO2

• C=4 valence electrons = 4• O= 2 (6) valence electrons = 12• O-C-O 16 electrons• O=C=O• O=C=O 16 electrons• 8 surrounding central atom, octet• 0 Nonbonding Pairs Electrons• 2 to 1, 0 NBPE, 180o, Linear

Page 41: VESPR

CO2

• C=4 valence electrons = 4• O= 2 (6) valence electrons = 12• O-C-O 16 electrons• O=C=O• O=C=O 16 electrons• 8 surrounding central atom, octet• 0 Nonbonding Pairs Electrons• 2 to 1, 0 NBPE, 180o, Linear

Page 42: VESPR

CO2

• C=4 valence electrons = 4• O= 2 (6) valence electrons = 12• O-C-O 16 electrons• O=C=O• O=C=O 16 electrons• 8 surrounding central atom, octet• 0 Nonbonding Pairs Electrons• 2 to 1, 0 NBPE, 180o, Linear

Page 43: VESPR

CO2

• C=4 valence electrons = 4• O= 2 (6) valence electrons = 12• O-C-O 16 electrons• O=C=O• O=C=O 16 electrons• 8 surrounding central atom, octet• 0 Nonbonding Pairs Electrons• 2 to 1, 0 NBPE, 180o, Linear

Page 44: VESPR

CO2

• C=4 valence electrons = 4• O= 2 (6) valence electrons = 12• O-C-O 16 electrons• O=C=O• O=C=O 16 electrons• 8 surrounding central atom, octet• 0 Nonbonding Pairs Electrons• 2 to 1, 0 NBPE, 180o, Linear

Page 45: VESPR

CO2

• C=4 valence electrons = 4• O= 2 (6) valence electrons = 12• O-C-O 16 electrons• O=C=O• O=C=O 16 electrons• 8 surrounding central atom, octet• 0 Nonbonding Pairs Electrons• 2 to 1, 0 NBPE, 180o, Linear

Page 46: VESPR

CO2

• C=4 valence electrons = 4• O= 2 (6) valence electrons = 12• O-C-O 16 electrons• O=C=O• O=C=O 16 electrons• 8 surrounding central atom, octet• 0 Nonbonding Pairs Electrons• 2 to 1, 0 NBPE, 180o, Linear

Page 47: VESPR

CO2

• C=4 valence electrons = 4• O= 2 (6) valence electrons = 12• O-C-O 16 electrons• O=C=O• O=C=O 16 electrons• 8 surrounding central atom, octet• 0 Nonbonding Pairs Electrons• 2 to 1, 0 NBPE, 180o, Linear

Page 48: VESPR

CO2

• C=4 valence electrons = 4• O= 2 (6) valence electrons = 12• O-C-O 16 electrons• O=C=O• O=C=O 16 electrons• 8 surrounding central atom, octet• 0 Nonbonding Pairs Electrons• 2 to 1, 0 NBPE, 180o, Linear

Page 49: VESPR

CO2

• C=4 valence electrons = 4• O= 2 (6) valence electrons = 12• O-C-O 16 electrons• O=C=O• O=C=O 16 electrons• 8 surrounding central atom, octet• 0 Nonbonding Pairs Electrons• 2 to 1, 0 NBPE, 180o, Linear

Page 50: VESPR

CO2

• C=4 valence electrons = 4• O= 2 (6) valence electrons = 12• O-C-O 16 electrons• O=C=O• O=C=O 16 electrons• 8 surrounding central atom, octet• 0 Nonbonding Pairs Electrons• 2 to 1, 0 NBPE, 180o, Linear

Page 51: VESPR

BF3

• B= 3 valence electrons = 3• F= 3 (7) valence electrons = 21• F B F 24 electrons• F• No Double Bonds Possible• F B F 24 electrons• F

• 6 surrounding central atom, incomplete octet• 0 Nonbonding Pairs Electrons• 3 to 1, 0 NBPE, 120o, trigonal planar

Page 52: VESPR

BF3

• B= 3 valence electrons = 3• F= 3 (7) valence electrons = 21• F B F 24 electrons• F• No Double Bonds Possible• F B F 24 electrons• F

• 6 surrounding central atom, incomplete octet• 0 Nonbonding Pairs Electrons• 3 to 1, 0 NBPE, 120o, trigonal planar

Page 53: VESPR

BF3

• B= 3 valence electrons = 3• F= 3 (7) valence electrons = 21• F B F 24 electrons• F• No Double Bonds Possible• F B F 24 electrons• F

• 6 surrounding central atom, incomplete octet• 0 Nonbonding Pairs Electrons• 3 to 1, 0 NBPE, 120o, trigonal planar

Page 54: VESPR

BF3

• B= 3 valence electrons = 3• F= 3 (7) valence electrons = 21• F B F 24 electrons• F• No Double Bonds Possible• F B F 24 electrons• F

• 6 surrounding central atom, incomplete octet• 0 Nonbonding Pairs Electrons• 3 to 1, 0 NBPE, 120o, trigonal planar

Page 55: VESPR

BF3

• B= 3 valence electrons = 3• F= 3 (7) valence electrons = 21• F B F 24 electrons• F• No Double Bonds Possible• F B F 24 electrons• F

• 6 surrounding central atom, incomplete octet• 0 Nonbonding Pairs Electrons• 3 to 1, 0 NBPE, 120o, trigonal planar

Page 56: VESPR

BF3

• B= 3 valence electrons = 3• F= 3 (7) valence electrons = 21• F B F 24 electrons• F• No Double Bonds Possible• F B F 24 electrons• F

• 6 surrounding central atom, incomplete octet• 0 Nonbonding Pairs Electrons• 3 to 1, 0 NBPE, 120o, trigonal planar

Page 57: VESPR

BF3

• B= 3 valence electrons = 3• F= 3 (7) valence electrons = 21• F B F 24 electrons• F• No Double Bonds Possible• F B F 24 electrons• F

• 6 surrounding central atom, incomplete octet• 0 Nonbonding Pairs Electrons• 3 to 1, 0 NBPE, 120o, trigonal planar

Page 58: VESPR

BF3

• B= 3 valence electrons = 3• F= 3 (7) valence electrons = 21• F B F 24 electrons• F• No Double Bonds Possible• F B F 24 electrons• F

• 6 surrounding central atom, incomplete 0 Nonbonding Pairs Electrons

• 3 to 1, 0 NBPE, 120o, trigonal planar

Page 59: VESPR

BF3

• B= 3 valence electrons = 3• F= 3 (7) valence electrons = 21• F B F 24 electrons• F• No Double Bonds Possible• F B F 24 electrons• F

• 6 surrounding central atom, incomplete • 0 Nonbonding Pairs Electrons• 3 to 1, 0 NBPE, 120o, trigonal planar

Page 60: VESPR

BF3

• B= 3 valence electrons = 3• F= 3 (7) valence electrons = 21• F B F 24 electrons• F• No Double Bonds Possible• F B F 24 electrons• F

• 6 surrounding central atom, incomplete• 0 Nonbonding Pairs Electrons• 3 to 1, 0 NBPE, 120o, trigonal planar

Page 61: VESPR

BF3

• B= 3 valence electrons = 3• F= 3 (7) valence electrons = 21• F B F 24 electrons• F• No Double Bonds Possible• F B F 24 electrons• F

• 6 surrounding central atom, incomplete • 0 Nonbonding Pairs Electrons• 3 to 1, 0 NBPE, 120o, trigonal planar

Page 62: VESPR

CCl4• C= 4 valence electrons = 4• Cl= 4 (7) valence electrons = 28• Cl 32 electrons• Cl C Cl • Cl No Double Bonds Possible• • Cl• Cl C Cl 32 electrons• Cl

• 8 surrounding central atom, octet• 0 Nonbonding Pairs Electrons• 4 to 1, 0 NBPE, 109.5o, tetrahedral

Page 63: VESPR

CCl4• C= 4 valence electrons = 4• Cl= 4 (7) valence electrons = 28• Cl 32 electrons• Cl C Cl • Cl No Double Bonds Possible• • Cl• Cl C Cl 32 electrons• Cl

• 8 surrounding central atom, octet• 0 Nonbonding Pairs Electrons• 4 to 1, 0 NBPE, 109.5o, tetrahedral

Page 64: VESPR

CCl4• C= 4 valence electrons = 4• Cl= 4 (7) valence electrons = 28• Cl 32 electrons• Cl C Cl • Cl No Double Bonds Possible• • Cl• Cl C Cl 32 electrons• Cl

• 8 surrounding central atom, octet• 0 Nonbonding Pairs Electrons• 4 to 1, 0 NBPE, 109.5o, tetrahedral

Page 65: VESPR

CCl4• C= 4 valence electrons = 4• Cl= 4 (7) valence electrons = 28• Cl 32 electrons• Cl C Cl • Cl No Double Bonds Possible• • Cl• Cl C Cl 32 electrons• Cl

• 8 surrounding central atom, octet• 0 Nonbonding Pairs Electrons• 4 to 1, 0 NBPE, 109.5o, tetrahedral

Page 66: VESPR

CCl4• C= 4 valence electrons = 4• Cl= 4 (7) valence electrons = 28• Cl 32 electrons• Cl C Cl • Cl No Double Bonds Possible• • Cl• Cl C Cl 32 electrons• Cl

• 8 surrounding central atom, octet• 0 Nonbonding Pairs Electrons• 4 to 1, 0 NBPE, 109.5o, tetrahedral

Page 67: VESPR

CCl4• C= 4 valence electrons = 4• Cl= 4 (7) valence electrons = 28• Cl 32 electrons• Cl C Cl • Cl No Double Bonds Possible• • Cl• Cl C Cl 32 electrons• Cl

• 8 surrounding central atom, octet• 0 Nonbonding Pairs Electrons• 4 to 1, 0 NBPE, 109.5o, tetrahedral

Page 68: VESPR

CCl4• C= 4 valence electrons = 4• Cl= 4 (7) valence electrons = 28• Cl 32 electrons• Cl C Cl • Cl No Double Bonds Possible• • Cl• Cl C Cl 32 electrons• Cl

• 8 surrounding central atom, octet• 0 Nonbonding Pairs Electrons• 4 to 1, 0 NBPE, 109.5o, tetrahedral

Page 69: VESPR

CCl4• C= 4 valence electrons = 4• Cl= 4 (7) valence electrons = 28• Cl 32 electrons• Cl C Cl • Cl No Double Bonds Possible• • Cl• Cl C Cl 32 electrons• Cl

• 8 surrounding central atom, octet• 0 Nonbonding Pairs Electrons• 4 to 1, 0 NBPE, 109.5o, tetrahedral

Page 70: VESPR

CCl4• C= 4 valence electrons = 4• Cl= 4 (7) valence electrons = 28• Cl 32 electrons• Cl C Cl • Cl No Double Bonds Possible• • Cl• Cl C Cl 32 electrons• Cl

• 8 surrounding central atom, octet• 0 Nonbonding Pairs Electrons• 4 to 1, 0 NBPE, 109.5o, tetrahedral

Page 71: VESPR

CCl4• C= 4 valence electrons = 4• Cl= 4 (7) valence electrons = 28• Cl 32 electrons• Cl C Cl • Cl No Double Bonds Possible• • Cl• Cl C Cl 32 electrons• Cl

• 8 surrounding central atom, octet• 0 Nonbonding Pairs Electrons• 4 to 1, 0 NBPE, 109.5o, tetrahedral

Page 72: VESPR

CCl4• C= 4 valence electrons = 4• Cl= 4 (7) valence electrons = 28• Cl 32 electrons• Cl C Cl • Cl No Double Bonds Possible• • Cl• Cl C Cl 32 electrons• Cl

• 8 surrounding central atom, octet• 0 Nonbonding Pairs Electrons• 4 to 1, 0 NBPE, 109.5o, tetrahedral

Page 73: VESPR

NH3

• N= 5 valence electrons = 5• H= 3 (1) valence electrons = 3• H N H 8 electrons• H• No Double Bonds Possible• H N H 8 electrons• H

• 8 surrounding central atom, octet• 1 Nonbonding Pairs Electrons• 3 to 1, 1 NBPE, <109.5o, pyrimidal

Page 74: VESPR

NH3

• N= 5 valence electrons = 5• H= 3 (1) valence electrons = 3• H N H 8 electrons• H• No Double Bonds Possible• H N H 8 electrons• H

• 8 surrounding central atom, octet• 1 Nonbonding Pairs Electrons• 3 to 1, 1 NBPE, <109.5o, pyrimidal

Page 75: VESPR

NH3

• N= 5 valence electrons = 5• H= 3 (1) valence electrons = 3• H N H 8 electrons• H• No Double Bonds Possible• H N H 8 electrons• H

• 8 surrounding central atom, octet• 1 Nonbonding Pairs Electrons• 3 to 1, 1 NBPE, <109.5o, pyrimidal

Page 76: VESPR

NH3

• N= 5 valence electrons = 5• H= 3 (1) valence electrons = 3• H N H 8 electrons• H• No Double Bonds Possible• H N H 8 electrons• H

• 8 surrounding central atom, octet• 1 Nonbonding Pairs Electrons• 3 to 1, 1 NBPE, <109.5o, pyrimidal

Page 77: VESPR

NH3

• N= 5 valence electrons = 5• H= 3 (1) valence electrons = 3• H N H 8 electrons• H• No Double Bonds Possible• H N H 8 electrons• H

• 8 surrounding central atom, octet• 1 Nonbonding Pairs Electrons• 3 to 1, 1 NBPE, <109.5o, pyrimidal

Page 78: VESPR

NH3

• N= 5 valence electrons = 5• H= 3 (1) valence electrons = 3• H N H 8 electrons• H• No Double Bonds Possible• H N H 8 electrons• H

• 8 surrounding central atom, octet• 1 Nonbonding Pairs Electrons• 3 to 1, 1 NBPE, <109.5o, pyrimidal

Page 79: VESPR

NH3

• N= 5 valence electrons = 5• H= 3 (1) valence electrons = 3• H N H 8 electrons• H• No Double Bonds Possible• H N H 8 electrons• H

• 8 surrounding central atom, octet• 1 Nonbonding Pairs Electrons• 3 to 1, 1 NBPE, <109.5o, pyrimidal

Page 80: VESPR

NH3

• N= 5 valence electrons = 5• H= 3 (1) valence electrons = 3• H N H 8 electrons• H• No Double Bonds Possible• H N H 8 electrons• H

• 8 surrounding central atom, octet• 1 Nonbonding Pairs Electrons• 3 to 1, 1 NBPE, <109.5o, pyrimidal

Page 81: VESPR

NH3

• N= 5 valence electrons = 5• H= 3 (1) valence electrons = 3• H N H 8 electrons• H• No Double Bonds Possible• H N H 8 electrons• H

• 8 surrounding central atom, octet• 1 Nonbonding Pairs Electrons• 3 to 1, 1 NBPE, <109.5o, pyrimidal

Page 82: VESPR

NH3

• N= 5 valence electrons = 5• H= 3 (1) valence electrons = 3• H N H 8 electrons• H• No Double Bonds Possible• H N H 8 electrons• H

• 8 surrounding central atom, octet• 1 Nonbonding Pairs Electrons• 3 to 1, 1 NBPE, <109.5o, pyrimidal

Page 83: VESPR

NH3

• N= 5 valence electrons = 5• H= 3 (1) valence electrons = 3• H N H 8 electrons• H• No Double Bonds Possible• H N H 8 electrons• H

• 8 surrounding central atom, octet• 1 Nonbonding Pairs Electrons• 3 to 1, 1 NBPE, <109.5o, pyrimidal

Page 84: VESPR

NH3

• N= 5 valence electrons = 5• H= 3 (1) valence electrons = 3• H N H 8 electrons• H• No Double Bonds Possible• H N H 8 electrons• H

• 8 surrounding central atom, octet• 1 Nonbonding Pairs Electrons• 3 to 1, 1 NBPE, <109.5o, pyrimidal

Page 85: VESPR

NH3

• N= 5 valence electrons = 5• H= 3 (1) valence electrons = 3• H N H 8 electrons• H• No Double Bonds Possible• H N H 8 electrons• H

• 8 surrounding central atom, octet• 1 Nonbonding Pairs Electrons• 3 to 1, 1 NBPE, <109.5o, pyrimidal

Page 86: VESPR

NH3

• N= 5 valence electrons = 5• H= 3 (1) valence electrons = 3• H N H 8 electrons• H• No Double Bonds Possible• H N H 8 electrons• H

• 8 surrounding central atom, octet• 1 Nonbonding Pairs Electrons• 3 to 1, 1 NBPE, <109.5o, pyrimidal

Page 87: VESPR

NH3

• N= 5 valence electrons = 5• H= 3 (1) valence electrons = 3• H N H 8 electrons• H• No Double Bonds Possible• H N H 8 electrons• H

• 8 surrounding central atom, octet• 1 Nonbonding Pairs Electrons• 3 to 1, 1 NBPE, <109.5o, pyrimidal

Page 88: VESPR

NH3

• N= 5 valence electrons = 5• H= 3 (1) valence electrons = 3• H N H 8 electrons• H• No Double Bonds Possible• H N H 8 electrons• H

• 8 surrounding central atom, octet• 1 Nonbonding Pairs Electrons• 3 to 1, 1 NBPE, <109.5o, pyrimidal

Page 89: VESPR

H2O

• O= 6 valence electrons = 6• H= 2 (1) valence electrons = 2• H O H 8 electrons• • No Double Bonds Possible• H O 8 electrons• H

• 8 surrounding central atom, octet• 2 Nonbonding Pairs Electrons• 2 to 1, 2 NBPE, <109.5o, bent

Page 90: VESPR

H2O

• O= 6 valence electrons = 6• H= 2 (1) valence electrons = 2• H O H 8 electrons• • No Double Bonds Possible• H O 8 electrons• H

• 8 surrounding central atom, octet• 2 Nonbonding Pairs Electrons• 2 to 1, 2 NBPE, <109.5o, bent

Page 91: VESPR

H2O

• O= 6 valence electrons = 6• H= 2 (1) valence electrons = 2• H O H 8 electrons• • No Double Bonds Possible• H O 8 electrons• H

• 8 surrounding central atom, octet• 2 Nonbonding Pairs Electrons• 2 to 1, 2 NBPE, <109.5o, bent

Page 92: VESPR

H2O

• O= 6 valence electrons = 6• H= 2 (1) valence electrons = 2• H O H 8 electrons• • No Double Bonds Possible• H O 8 electrons• H

• 8 surrounding central atom, octet• 2 Nonbonding Pairs Electrons• 2 to 1, 2 NBPE, <109.5o, bent

Page 93: VESPR

H2O

• O= 6 valence electrons = 6• H= 2 (1) valence electrons = 2• H O H 8 electrons• • No Double Bonds Possible• H O 8 electrons• H

• 8 surrounding central atom, octet• 2 Nonbonding Pairs Electrons• 2 to 1, 2 NBPE, <109.5o, bent

Page 94: VESPR

H2O

• O= 6 valence electrons = 6• H= 2 (1) valence electrons = 2• H O H 8 electrons• • No Double Bonds Possible• H O 8 electrons• H

• 8 surrounding central atom, octet• 2 Nonbonding Pairs Electrons• 2 to 1, 2 NBPE, <109.5o, bent

Page 95: VESPR

H2O

• O= 6 valence electrons = 6• H= 2 (1) valence electrons = 2• H O H 8 electrons• • No Double Bonds Possible• H O 8 electrons• H

• 8 surrounding central atom, octet• 2 Nonbonding Pairs Electrons• 2 to 1, 2 NBPE, <109.5o, bent

Page 96: VESPR

H2O

• O= 6 valence electrons = 6• H= 2 (1) valence electrons = 2• H O H 8 electrons• • No Double Bonds Possible• H O 8 electrons• H

• 8 surrounding central atom, octet• 2 Nonbonding Pairs Electrons• 2 to 1, 2 NBPE, <109.5o, bent

Page 97: VESPR

H2O

• O= 6 valence electrons = 6• H= 2 (1) valence electrons = 2• H O H 8 electrons• • No Double Bonds Possible• H O 8 electrons• H

• 8 surrounding central atom, octet• 2 Nonbonding Pairs Electrons• 2 to 1, 2 NBPE, <109.5o, bent

Page 98: VESPR

H2O

• O= 6 valence electrons = 6• H= 2 (1) valence electrons = 2• H O H 8 electrons• • No Double Bonds Possible• H O 8 electrons• H

• 8 surrounding central atom, octet• 2 Nonbonding Pairs Electrons• 2 to 1, 2 NBPE, <109.5o, bent

Page 99: VESPR

PF5

• P= 5 valence electrons = 5• F= 5 (7) valence electrons = 35• F F 40 electrons• C F • F F No Double Bonds Possible• F F C F electrons F F

• 8 surrounding central atom, octet• 0 Nonbonding Pairs Electrons• 4 to 1, 0 NBPE, 109.5o, tetrahedral

Page 100: VESPR

PF5

• P= 5 valence electrons = 5• F= 5 (7) valence electrons = 35• F F 40 electrons• C F • F F No Double Bonds Possible• F F C F electrons F F

• 8 surrounding central atom, octet• 0 Nonbonding Pairs Electrons• 4 to 1, 0 NBPE, 109.5o, tetrahedral

Page 101: VESPR

PF5

• P= 5 valence electrons = 5• F= 5 (7) valence electrons = 35• F F 40 electrons• C F • F F No Double Bonds Possible• F F C F electrons F F

• 8 surrounding central atom, octet• 0 Nonbonding Pairs Electrons• 4 to 1, 0 NBPE, 109.5o, tetrahedral

Page 102: VESPR

PF5

• P= 5 valence electrons = 5• F= 5 (7) valence electrons = 35• F F 40 electrons• C F • F F No Double Bonds Possible• F F C F electrons F F

• 8 surrounding central atom, octet• 0 Nonbonding Pairs Electrons• 4 to 1, 0 NBPE, 109.5o, tetrahedral

Page 103: VESPR

PF5

• P= 5 valence electrons = 5• F= 5 (7) valence electrons = 35• F F 40 electrons• C F • F F No Double Bonds Possible• F F C F 40 electrons F F

• 8 surrounding central atom, octet• 0 Nonbonding Pairs Electrons• 4 to 1, 0 NBPE, 109.5o, tetrahedral

Page 104: VESPR

PF5

• P= 5 valence electrons = 5• F= 5 (7) valence electrons = 35• F F 40 electrons• C F • F F No Double Bonds Possible• F F C F 40 electrons F F

• 8 surrounding central atom, octet• 0 Nonbonding Pairs Electrons• 4 to 1, 0 NBPE, 109.5o, tetrahedral

Page 105: VESPR

PF5

• P= 5 valence electrons = 5• F= 5 (7) valence electrons = 35• F F 40 electrons• C F • F F No Double Bonds Possible• F F C F 40 electrons F F

• 10 surrounding central atom, expanded 0 Nonbonding Pairs Electrons

• 4 to 1, 0 NBPE, 109.5o, tetrahedral

Page 106: VESPR

PF5

• P= 5 valence electrons = 5• F= 5 (7) valence electrons = 35• F F 40 electrons• C F • F F No Double Bonds Possible• F F C F 40 electrons F F

• 10 surrounding central atom, expanded • 0 Nonbonding Pairs Electrons• 4 to 1, 0 NBPE, 109.5o, tetrahedral

Page 107: VESPR

PF5

• P= 5 valence electrons = 5• F= 5 (7) valence electrons = 35• F F 40 electrons• C F • F F No Double Bonds Possible• F F C F 40 electrons F F

• 10 surrounding central atom, expanded • 0 Nonbonding Pairs Electrons• 5 to 1, 0 NBPE, 900/1200 , trigonal bipyrimidal

Page 108: VESPR

PF5

• P= 5 valence electrons = 5• F= 5 (7) valence electrons = 35• F F 40 electrons• C F • F F No Double Bonds Possible• F F C F 40 electrons F F

• 10 surrounding central atom, expanded • 0 Nonbonding Pairs Electrons• 5 to 1, 0 NBPE, 900/1200 , trigonal bipyrimidal

Page 109: VESPR

PF5

• P= 5 valence electrons = 5• F= 5 (7) valence electrons = 35• F F 40 electrons• C F • F F No Double Bonds Possible• F F C F 40 electrons F F

• 10 surrounding central atom, expanded • 0 Nonbonding Pairs Electrons• 5 to 1, 0 NBPE, 900/1200 , trigonal bipyrimidal

Page 110: VESPR

SCl6• S= 6 valence electrons = 6• Cl= 6 (7) valence electrons = 42• Cl Cl 48 electrons• Cl S Cl • Cl Cl No Double Bonds Possible• Cl• Cl • Cl S Cl 32 electrons• Cl• Cl

• 12 surrounding central atom, expanded octet• 0 Nonbonding Pairs Electrons• 6 to 1, 0 NBPE, 90o, octahedral

Page 111: VESPR

SCl6• S= 6 valence electrons = 6• Cl= 6 (7) valence electrons = 42• Cl Cl 48 electrons• Cl S Cl • Cl Cl No Double Bonds Possible• Cl• Cl • Cl S Cl 32 electrons• Cl• Cl

• 12 surrounding central atom, expanded octet• 0 Nonbonding Pairs Electrons• 6 to 1, 0 NBPE, 90o, octahedral

Page 112: VESPR

SCl6• S= 6 valence electrons = 6• Cl= 6 (7) valence electrons = 42• Cl Cl 48 electrons• Cl S Cl • Cl Cl No Double Bonds Possible• Cl• Cl • Cl S Cl 32 electrons• Cl• Cl

• 12 surrounding central atom, expanded octet• 0 Nonbonding Pairs Electrons• 6 to 1, 0 NBPE, 90o, octahedral

Page 113: VESPR

SCl6• S= 6 valence electrons = 6• Cl= 6 (7) valence electrons = 42• Cl Cl 48 electrons• Cl S Cl • Cl Cl No Double Bonds Possible• Cl• Cl • Cl S Cl 32 electrons• Cl• Cl

• 12 surrounding central atom, expanded octet• 0 Nonbonding Pairs Electrons• 6 to 1, 0 NBPE, 90o, octahedral

Page 114: VESPR

SCl6• S= 6 valence electrons = 6• Cl= 6 (7) valence electrons = 42• Cl Cl 48 electrons• Cl S Cl • Cl Cl No Double Bonds Possible• Cl• Cl • Cl S Cl 32 electrons• Cl• Cl

• 12 surrounding central atom, expanded octet• 0 Nonbonding Pairs Electrons• 6 to 1, 0 NBPE, 90o, octahedral

Page 115: VESPR

SCl6• S= 6 valence electrons = 6• Cl= 6 (7) valence electrons = 42• Cl Cl 48 electrons• Cl S Cl • Cl Cl No Double Bonds Possible• Cl• Cl • Cl S Cl 48 electrons• Cl• Cl

• 12 surrounding central atom, expanded octet• 0 Nonbonding Pairs Electrons• 6 to 1, 0 NBPE, 90o, octahedral

Page 116: VESPR

SCl6• S= 6 valence electrons = 6• Cl= 6 (7) valence electrons = 42• Cl Cl 48 electrons• Cl S Cl • Cl Cl No Double Bonds Possible• Cl• Cl • Cl S Cl 48 electrons• Cl• Cl

• 12 surrounding central atom, expanded octet• 0 Nonbonding Pairs Electrons• 6 to 1, 0 NBPE, 90o, octahedral

Page 117: VESPR

SCl6• S= 6 valence electrons = 6• Cl= 6 (7) valence electrons = 42• Cl Cl 48 electrons• Cl S Cl • Cl Cl No Double Bonds Possible• Cl• Cl • Cl S Cl 48 electrons• Cl• Cl

• 12 surrounding central atom, expanded octet• 0 Nonbonding Pairs Electrons• 6 to 1, 0 NBPE, 90o, octahedral

Page 118: VESPR

SCl6• S= 6 valence electrons = 6• Cl= 6 (7) valence electrons = 42• Cl Cl 48 electrons• Cl S Cl • Cl Cl No Double Bonds Possible• Cl• Cl • Cl S Cl 48 electrons• Cl• Cl

• 12 surrounding central atom, expanded octet• 0 Nonbonding Pairs Electrons• 6 to 1, 0 NBPE, 90o, octahedral

Page 119: VESPR

SCl6• S= 6 valence electrons = 6• Cl= 6 (7) valence electrons = 42• Cl Cl 48 electrons• Cl S Cl • Cl Cl No Double Bonds Possible• Cl• Cl • Cl S Cl 48 electrons• Cl• Cl

• 12 surrounding central atom, expanded octet• 0 Nonbonding Pairs Electrons• 6 to 1, 0 NBPE, 90o, octahedral

Page 120: VESPR

SCl6• S= 6 valence electrons = 6• Cl= 6 (7) valence electrons = 42• Cl Cl 48 electrons• Cl S Cl • Cl Cl No Double Bonds Possible• Cl• Cl • Cl S Cl 48 electrons• Cl• Cl

• 12 surrounding central atom, expanded octet• 0 Nonbonding Pairs Electrons• 6 to 1, 0 NBPE, 90o, octahedral

Page 121: VESPR

H2NCH2COOH

• Hydrogen (1)5 = 5 electrons• Nitrogen (5) 1 = 5 electrons• Oxygen (6) 2 = 12 electrons• Carbon (4) 2 =8 electrons• 30 electrons

• H H O• N C C O H• H H

Page 122: VESPR

H2NCH2COOH

• Hydrogen (1)5 = 5 electrons• Nitrogen (5) 1 = 5 electrons• Oxygen (6) 2 = 12 electrons• Carbon (4) 2 =8 electrons• 30 electrons

• H H O• N C C O H• H H

Page 123: VESPR

H2NCH2COOH

• Hydrogen (1)5 = 5 electrons• Nitrogen (5) 1 = 5 electrons• Oxygen (6) 2 = 12 electrons• Carbon (4) 2 =8 electrons• 30 electrons

• H H O• N C C O H• H H

Page 124: VESPR

H2NCH2COOH

• Hydrogen (1)5 = 5 electrons• Nitrogen (5) 1 = 5 electrons• Oxygen (6) 2 = 12 electrons• Carbon (4) 2 =8 electrons• 30 electrons

• H H O• N C C O H• H H

Page 125: VESPR

H2NCH2COOH

• Hydrogen (1)5 = 5 electrons• Nitrogen (5) 1 = 5 electrons• Oxygen (6) 2 = 12 electrons• Carbon (4) 2 =8 electrons• 30 electrons

• H H O• N C C O H• H H

Page 126: VESPR

H2NCH2COOH

• Hydrogen (1)5 = 5 electrons• Nitrogen (5) 1 = 5 electrons• Oxygen (6) 2 = 12 electrons• Carbon (4) 2 =8 electrons• 30 electrons

• H H O• N C C O H• H H• 3 to 1

Page 127: VESPR

H2NCH2COOH

• Hydrogen (1)5 = 5 electrons• Nitrogen (5) 1 = 5 electrons• Oxygen (6) 2 = 12 electrons• Carbon (4) 2 =8 electrons• 30 electrons

• H H O• N C C O H• H H• 3 to 1 1 NBPE

Page 128: VESPR

H2NCH2COOH

• Hydrogen (1)5 = 5 electrons• Nitrogen (5) 1 = 5 electrons• Oxygen (6) 2 = 12 electrons• Carbon (4) 2 =8 electrons• 30 electrons

• H H O• N C C O H• H H• 3 to 1 1 NBPE <109.5

Page 129: VESPR

H2NCH2COOH

• Hydrogen (1)5 = 5 electrons• Nitrogen (5) 1 = 5 electrons• Oxygen (6) 2 = 12 electrons• Carbon (4) 2 =8 electrons• 30 electrons

• H H O• N C C O H• H H• 3 to 1 1 NBPE <109.5 pyrimidal

Page 130: VESPR

H2NCH2COOH

• Hydrogen (1)5 = 5 electrons• Nitrogen (5) 1 = 5 electrons• Oxygen (6) 2 = 12 electrons• Carbon (4) 2 =8 electrons• 30 electrons

• H H O• N C C O H• H H• 4 to 1 0 NBPE 109.5 tetrahedral

Page 131: VESPR

H2NCH2COOH

• Hydrogen (1)5 = 5 electrons• Nitrogen (5) 1 = 5 electrons• Oxygen (6) 2 = 12 electrons• Carbon (4) 2 =8 electrons• 30 electrons

• H H O• N C C O H• H H• 3 to 1 0 NBPE 120o trigonal planar

Page 132: VESPR

H2NCH2COOH

• Hydrogen (1)5 = 5 electrons• Nitrogen (5) 1 = 5 electrons• Oxygen (6) 2 = 12 electrons• Carbon (4) 2 =8 electrons• 30 electrons

• H H O• N C C O H• H H• 2 to 1 2 NBPE <109.5o bent