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VG519 The use of red mudgypsum to reduce water pollution from sandy soils used for vegetable production
Ian McPharlin Robert Jeffery et al Agriculture WA
VG519
This report is published by the Horticultural Research and Development Corporation to pass on information concerning horticultural research and development undertaken for the vegetable industry
The research contained in this report was funded by the Horticultural Research and Development Corporation with the financial support of Alcoa of Australia Ltd
All expressions of opinion are not to be regarded as expressing the opinion of the Horticultural Research and Development Corporation or any authority of the Australian Government
The Corporation and the Australian Government accept no responsibility for any of the opinions or the accuracy of the information contained in this report and readers should rely upon their own enquiries in making decisions concerning their own interests
Cover price $2000 HRDC ISBN 1 86423 756 2
Published and distributed by Horticultural Research amp Development Corporation Level 6 7 Merriwa Street Gordon NSW 2072 Telephone (02) 9418 2200 Fax (02) 9418 1352 E-Mail hrdchrdcgovau
copy Copyright 1998
of
HRDC
HORTICULTURAL RESEARCH amp DEVELOPMENT CORPORATION
Partnership in horticulture
CONTENTS
Page
1 Summary and recommendations 1
2 Project staff collaborators and acknowledgments 4
3 Publications arising out of work 5
4 Response of potatoes to freshly-applied and residual Red Mud (Alkaloamreg)gypsum 6 and phosphorus on a yellow Karrakatta sand
5 Response of cauliflowers to freshly-applied Red Mud (Alkaloamreg)gypsum and 30 phosphorus on a yellow Karrakatta sand
6 Response of cauliflowers to residual Red Mud (Alkaloamreg)gypsum and 59 phosphorus on a yellow Karrakatta sand
7 Retention leaching and recovery of P and other nutrients by carrots grown on 82 a Joel sand amended with residual Red Mud (Alkaloamreg)gypsum in large pots
CO
The use of Red Mudgypsum in vegetable production
1 SUMMARY AND RECOMMENDATIONS
11 Technical summary
Red Mud (Alkaloamreg)gypsum (AG) is seen as a useful amendment to increase the P retention of acid sandy soils low in this characteristic such as the Bassendean (Joel Gavin and Jandakot) and grey-phase Karrakatta sands P fertilisers applied to these soils from intensive horticultural production may leach and pollute associated water systems such as lakes rivers and estuaries Unfortunately because of strong demand for other land uses on soils better suited to vegetable production on the Swan Coastal Plain such as the Spearwood and yellow Karrakatta sands more of the less environmentally suitable Bassendean sands are being used for horticulture
In a previous project (HRDC VG0039) freshly-applied AG caused yield reduction in cauliflower and potatoes at low rates ie 60 tha on Karrakatta sands
In addition the effect of AG appeared to be specific and to vary with species For example levels of freshly-applied AG up to 240 tha had no effect on the yield of carrots on Joel sands and increased the yield of lettuce on Karrakatta sands
For this reason we approached Alcoa and HRDC for a subsequent project to further examine the response of cauliflower and potatoes to freshly-applied and residual AG
Addition of AG significantly increased the P retention (as measured by PRI total and Colwell P) pH Ec and exchangeable cations (NHU-N Ca K and Na) in the top 15 cm of the sands whilst concentrations of P and K in soil solution were reduced
With potatoes the effect of AG on yield varied depending of whether it was fresh or residual For example yield of potatoes were reduced with 601 of fresh AGha but only at 2401 of residual AGha In both cases the yield reduction could not be explained in terms of reduced P uptake by the plants as increased levels of applied P did not obviate the problem The yield reduction appeared to be due to K deficiency induced by high levels of Na (alkalinity) in the AG This was correlated with reduced K in soil solution With residual AG the alkalinity was lower as there had been more time for leaching and consequently the yield reduction was much less At levels of AG likely to be recommended for commercial use ie 60 to 120 tha no yield reduction would be anticipated with potatoes provided the AG was thoroughly leached with irrigation water for 1 or 2 months prior to planting In contrast to the previous project applications of fresh or residual AG up to 240 tha did not cause any reduction in yield of cauliflower even though concentrations of K decreased and Na increased in the YML at midgrowth
The optimum level of AG is that required to reduce leaching of fertiliser P substantially without reducing yield quality or increasing the level of P required for maximum crop yield significantly For example on unamended Joel sands leaching of fertiliser P was so high (ie 78 to 80 of applied P) that yield of carrots did not reach a maximum despite high levels of applied P (ie up to 400 kgha) By contrast 125 t AGha reduced leaching of fertiliser P to only 5 to 7 of applied P whilst yield maximised at 182 (95) and 314 (99) kg Pha At higher levels of AG (250 and 1000 tha) P required for maximum yield was significantly increased ie yield did not maximise at 400 kg Pha whilst leaching of P was not reduced much more than at 125 tha ie 1 to 3 of applied P However even at 125 tha the level of applied P required for maximum carrot yield (182 to 314 kgha) was higher than that required for maximum yield on higher P fixing sands such as the yellow Karrakatta sands ie 120 to 180 kgha suggesting that levels of AG less than 125 tha may be more agronomically suitable
In conclusion the benefits of amending acid sands with AG are increased retentionreduced leaching of P increased retentionreduced leaching of K Mg and NH4-N due to increased cation retention and an increase in pH (ie lime effect) The improved P retention of AG-amended sands enables the use of P soil testing as part of the P management of these soils whereas prior to amendment soil testing was not practical as leaching of P was too high
The use of Red Mudgypsum in vegetable production
An additional benefit which was not thoroughly investigated in this project but was obvious in the pot experiment was increased soil moisture holding capacity especially at high levels of application due to an increased in the fine fractions after amendment These benefits should be achieved at low to moderate levels of applied AG (ie 60 to 120 tha) without any negative effect on vegetable yield or quality
Some negative effects of amending acid sands with fresh AG include decreased yield due to increased conductivity and induced K deficiency in some vegetables such as potatoes However this does not appear to be a problem with carrots and cauliflower
This problem can be obviated by allowing sufficient time to leach the soluble alkalinity (Na2SCgt4) out of the root zone of the amended soil prior to cropping as it is less of a problem with residual AG Another disadvantage is the increase in fertiliser P requirements of vegetables after AG amendment in the short term due to increased P fixation This is particularly obvious at high levels of application However this disadvantage is offset as soil testing can be used on sands after amendment to reduce P fertiliser costs whereas it couldnt beforehand Also on unamended Joel sands leaching of P fertilisers (ie 80 of applied P) causes significant economic loss due to fertiliser losses and increased fertiliser P required for maximum yield
12 Industry summary
An important domestic and export vegetable industry is located on the sands of the Swan Coastal Plain (SCP) in Western Australia The total value of the vegetable industry on the SCP was estimated at $90M in 19967 or about 50 of the total value of the industry This vegetable production has been located on good quality sands such as the Spearwood and yellow Karrakatta sands close to the coast since the 1950s However in recent years competition for this land for urban and industrial use has forced vegetable production onto soils with poorer water and phosphorus retention capacity such as the more acidic Bassendean (Joel) and grey-phase Karrakatta sands This has lead leaching of fertiliser phosphorus into water systems of the SCP such as lakes rivers and estuaries with resulting pollution (algae blooms) Even though vegetable production is not the only or main source of this leached phosphorus the issue has resulted in negative publicity for the industry and increased scrutiny of industry practices by government agencies charged with responsibility for water the environment and health
As large quantities of Red Mud (Alkaloamreg)gypsum (AG) were produced from bauxite refining on the SCP it made sense to examine this as a soil amendment as it had been shown to improve the phosphorus retention capacity of coarse grey sands low in iron and aluminium oxides AG consistently increases the phosphorus retention capacity and the retention of cations such as potassium magnesium and ammonium-nitrogen and pH (lime effect) of grey and pale-yellow sands after amendment The reduction fertiliser P leaching is very high even at the lower rates of application such as 60 and 120 tha Fresh AG will increase the fertiliser phosphorus requirements of most vegetable crops compared with the unamended plots similar to the differences between low and high P fixing soils However this increase is not as much on residual or aged AG sites This increase in initial fertiliser P needs following AG application is offset by the use of soil testing to manage P fertiliser in subsequent crops on grey sands which was not practical prior to amendment Some initial problems with fresh AG causing yield reductions on potatoes was attributed to induced potassium deficiency due to high conductivity (ie high sodium) in amended soils However this problem can be overcome by leaching the soil of salts after amendment with high rates of irrigation so that EC of the amended soil doesnt exceed 6 mSm and the pH (water) 85 The potassium nutrition of the crop should be monitored to ensure it is adequate There is no problem on sites where AG has been applied for at least 12 months
2
The use of Red Mudgypsum in vegetable production
13 Recommendations It is recommended that AG be used as a soil amendment for vegetable crops on the grey and pale yellow sands of the SCP to reduce P fertiliser leaching However a number of guidelines should be adhered to ensure maximum benefits and minimum risks from the use of AG
bull Potatoes should not be grown on sites where fresh AG (ie 1 to 3 months after application) has been applied
bull Potatoes can be grown on sites where AG has be applied at levels up to 120 tha provided at least 12 months previously provided sufficient leaching of salts has occurred As a guide it is suggested that soil conductivity should not exceed 6 mSm and pH (water) 85 in the top 15 cm
bull Vegetable crops other than potatoes can be planted into sites where fresh AG has been applied at levels up to 120 tha without problems
bull Adjust level of P fertiliser application to account for increased P fertiliser requirements of vegetables due to higher P fixing on sites amended with AG
bull Use soil testing to manage P fertiliser applications on AG amended sites but follow recommendations for specific vegetable crops
The use of Red Mudgypsum in vegetable production
2 PROJECT STAFF
Ian McPharlin
Wendy Robertson
Bob Jeffery
Tony Shimmin
Jenny Harboard
Don Glenister
Patricia Aylmore
David Cooling
Gavin dAdhemar
Neil Lantzke
John Ferguson (Manager) and staff
Staff
COLLABORATORS AND ACKNOWLEDGMENTS
Project Manager and Principal Investigator
Research Officer
Project Collaborating Scientist (Chemistry Centre of WA)
Project Technical Officer
Project Laboratory Technician (Chemistry Centre of WA)
Residue Development Manager (Alcoa of Australia)
Environmental Scientist (Alcoa of Australia)
Senior Consultant Residue (Alcoa of Australia)
Technical Officer Medina Research Centre (for technical assistance and management of field and pot experiments)
Horticultural Extension Officer (for extension advice)
Medina Research Centre (for management of field experiments)
Chemistry Centre of WA (for advice of on soil plant and leachate chemistry)
4
The use of Red Mudgypsum in vegetable production
3 PUBLICATIONS ARISING OUT OF WORK Robertson WJ McPharlin IR and Jeffery RC (1997) The growth nutrition and
composition of potatoes (Solarium tuberosum L) cv Delaware grown on a yellow Karrakatta sand amended with freshly-applied and residual Alkaloamreggypsum Australian Journal of Experimental Agriculture (submitted)
McPharlin IR dAdhemar G and Shimmin TR (1997) The response of cauliflowers (Brassica oleraceae L) cv Plana to freshly-applied and residual Alkaloamreggypsum and phosphorus on a Karrakatta sand Australian Journal of Experimental Agriculture (in prep)
McPharlin IR Shimmin TR and dAdhemar G (1997) Leaching of P N and cations from carrots grown on Joel sands amended with residual Alkaloamreggypsum Communications in Soil Science and Plant Analysis (in prep)
The use of Red Mudgypsum in vegetable production
4 RESPONSE OF POTATOES TO FRESHLY-APPLIED AND RESIDUAL RED MUD (ALKALOAMreg)GYPSUM AND PHOSPHORUS ON A YELLOW KARRAKATTA SAND
Introduction
Previous work has shown that freshly-applied Alkaloamreggypsum (gypsum-amended red mud 10 ww) (AG) at 60 and 120 tha reduced the total yield of potatoes by 7 and 23 respectively compared with 01 AGha controls (Robertson et al 1994 Appendix 1 J) The reduction in marketable yield was almost identical to the reduction in total yield The exact cause of this reduction in yield could not be determined particularly the reduction at 120 tha It was unlikely to be a reduced availability of P Observations on commercial properties suggest that AG which has been in the soil for several seasons does not cause yield reductions in potatoes
Phosphorus was banded at planting in this experiment Subsequent work (Hegney and McPharlin unpublished data) showed that broadcasting P allowed a greater maximum yield of potatoes than banding P on Karrakatta sands of low P fertility
This experiment re-examines the response of potatoes to freshly-applied AG using broadcast P and also the effect of residual AG on growth of potatoes at unlimiting P
Materials and methods
Site characteristics
The experiment was conducted on a yellow Karrakatta sand (described by McArthur and Bettenay 1960) at Medina approximately 30 km south of Perth Two sites were used a site where pasture species had been grown several years earlier and to which no AG had ever been applied and a second (adjacent) site where AG had been applied approximately 2J2 years earlier A lettuce and a cauliflower crop had been grown previously on this site after AG amendment (Robertson et al 1994 Appendix 1H I)
Red Mud (Alkaloamreg)gypsum (AG)
Red Mud (Alkaloamreg)gypsum (10 ww) (AG) was produced by the dry mix process by ALCOA of Australia Ltd at their Kwinana Residue Treatment Plant It was spread manually on the previously unamended site on 22 December 1994 and was incorporated to a depth of approximately 30 cm using a rotary hoe The AG on the previously-amended site (residual AG) was applied using the same techniques on 24 November 1992 The freshly-applied AG was watered for 1 hour three times a week until planting
Experimental design
The freshly-applied and residual AG sites were used for separate experiments which were conducted simultaneously The experiment on the freshly-applied AG was a split-plot randomised complete block design with three replicates Main plots were levels of AG (0 60 90 and 120 tha) and sub-plots were levels of P application (0 25 50 100 300 and 600 kgha) Main plots measured 48 x 21 m and sub-plots measured 24 x 7 m (three rows of potatoes with 08 m between row centres) There was a 2 m buffer around each main plot The experiment on the residual AG site was a randomised complete block design with 4 levels of AG (0 60 120 and 240 tha) and three replicates The levels of AG were applied in November 1992 and had had several levels of P applied to them in the previous crops The AG plots measured 6 x 12 m but only an area of 34 x 8 m (4 rows of potatoes with 08 m between row centres) was cropped to allow a buffer of 1 to 2 m all around the planted area
6
The use of Red Mudgypsum in vegetable production
Crop management Both sites were initially sprayed with Roundupreg (3 Lha) to kill weeds and the sites were hoed with a rotary hoe Freshly-applied AG was applied at this stage The residual AG site was treated with metham sodium approximately two weeks before planting Potatoes cv Delaware were planted on both sites on 18 May 1995 using a single row mechanical planter Round seed was used and this was dusted with Rizolexreg (2 kgt) immediately before planting Sets were planted 15 cm apart The crops were irrigated using impact sprinklers once daily at 80 of Class A pan evaporation between planting and emergence and then at 100 of evaporation Afalonreg (15 kgha) was applied after planting and Sprayseedreg (2 Lha) was applied at 5 emergence both for weed control Nitofol (700 rnLha) was used for regular insect control Bravoreg (2 Lha) was applied every seven days from the time of 50 ground cover until blight symptoms appeared at which time it was then alternated with Rovralreg (2 Lha) at 7 day intervals Both crops were harvested on 15 November 1995
Fertilisers
Pre-planting fertilisers were broadcast by hand on 15 May 1995 on freshly-applied AG and on 16 May on residual AG These were 83 kg Kha as K2S04 10 kg Mgha as miso47H20 and a complete trace element mix containing (kgha) MnS04H20 (504) MgS047H20 (560) borax (336) FeS047H20 (336) CuS045H20 (336) ZnS04H20 (280) and Na2Mo042H20 (224) Single superphosphate (91 P) was broadcast by hand at 0 to 600 kg Pha on freshly-applied AG according to the treatment and at 600 kg Pha on all plots on residual AG Post-planting fertilisers were a total of 500 kg Nha as NH4NO2 and KN02 and 400 kg Kha as KN02 in equal amounts for 10 weeks via the irrigation system An extra 50 kgha MgS04 was applied in weeks 7 and 9
Measurements
(a) Plant
The petioles of the Youngest Mature Leaf (YML) often plants were collected at the S2 stage (longest tuber 10 mm long) (19 July 1995) on both freshly-applied and residual AG They were dried in a forced draught oven at 70degC and then analysed for P N K Na Ca Mg S B Cu Fe Mn and Zn On freshly-applied AG tubers were harvested from a 5 m length of the middle row of each plot On residual AG a 4 m length of the two middle rows of each plot was harvested Tubers were separated into the following size grades lt 30 g 30-80 g 80-250 g 250-450 g and gt 450 g Tubers between 30 g and 450 g were considered marketable except if they were green or damaged
Of the tubers in the 80-250 g category ten were sampled from each plot for P analysis They were washed in tap water and sliced thinly with a stainless steel knife Fresh and dry weights were measured before the tubers were analysed for total P
(b) Soil
All 0 kg Pha plots on freshly-applied AG were sampled to 15 cm depth (15 cores per plot) on 29 August (approximately 3 months after planting) They were analysed for Bicarbonate-extractable P (Bic-P) (Colwell 1963) total P EC pH (H20) pH (CaCl2) Phosphorus Retention Index (PRI) (Allen and Jeffery 1990) and P buffering capacity (Ozanne and Shaw 1968) Before fertilisers were applied to the residual AG site on 16 May 15 cores (0-15 cm) were sampled from each plot and analysed for Bic-P and PRI Residual AG plots were sampled again on 29 August (0-15 cm 15 cores per plot) and analysed for pH (H20) pH (CaCl2) EC and P buffering capacity All residual AG plots and 0 100 and 600 kg Pha freshly-applied AG plots were sampled to three depths (0-15 15-30 and 30-45 cm) (20 cores per plot) on 5 December (ie after harvest)
7
The use of Red Mudgypsum in vegetable production
Chemical analysis
Plant samples were ground to pass through a 1 mm screen after drying Concentrations of P N K and Na were measured by digesting the samples with sulphuric acid and hydrogen peroxide (Yuen and Pollard 1954) N and P were determined colorimetrically by indophenol blue and molybdo-vanadate methods respectively K and Na were determined by flame photometry All analysis was conducted on a 4-channel Auto-analyser system using modifications of Technicon procedures (Anon 1977) Samples for analysis of Ca Mg S Cu Fe B Mn and Zn concentrations were digested with nitricperchloric acids (McQuaker et al 1979) Concentrations were measured by inductively-coupled plasma atomic emission spectrometry (ICP-AES) Concentrations of heavy metals were determined using inductively-coupled plasma mass spectrometry (ICP-MS) with indium as an internal standard Samples were initially crushed in an agate mortar and digested using nitric and perchloric acids
All soil samples were dried at 40degC in a forced draught oven Lumps of AG and fertiliser in samples were crushed and the samples were thoroughly mixed and sieved to lt 2 mm before analysis The pH (H20) and the EC were determined on a 15 soilwater extract after shaking for 1 hour The pH (CaCl2) was determined on 15 soiksolution extract using 001 M CaCl2 after shaking for 1 hour Values for both are corrected to 25 degC Total P was determined on a Kjeldahl digest of a separate sub-sample of soil ground to less than 015 mm The concentration of phosphate was measured by the method of Murphy and Riley (1962)
Statistical analysis
All data were analysed by an Analysis of Variance (ANOVA) using Genstat v 50 Results from the two experiments were analysed separately Data from the freshly-applied AG site was analysed by a two-way ANOVA on level of Alkaloamreg and level of applied P while data from residual Alkaloamreg were analysed by a one-way ANOVA on level of AG Statistical differences were determined using a Least Significant Difference at 5 level of significance where the F value from the ANOVA was significant Mitscherlich curves were fitted to all relationships between level of applied P and yield petiole or tuber P concentration or total P uptake Maximum values of Mitscherlich equations were compared using a 5 t-test Linear relationships were fitted to the yield response on residual Alkaloam versus level of AG and also to the relationship between yield and petiole P concentration on freshly-applied AG
The amount of fertiliser P retained was calculated by subtracting total P at 0 kg Pha from the measured total P value Concentrations of P in ugg were converted to kilograms per hectare by multiplying by a factor of 225 This is based on the assumption that there are 2250 t soilha in the top 15 cm of soil
Results and discussion
Soil characteristics
The pH (H20) of the top 15 cm of soil at mid-growth when no P fertiliser was applied increased from 72 on unamended soil to 84 and 85 on amended soil (Table 41) EC also increased from 5 mSm on unamended soil to 8 and 9 mSm on amended soil (Table 41) Bic-P was approximately 10 ugg at all AG levels and total P ranged from 55 ugg on unamended soil to 76 ugg at 901 AGha (Table 41) PRI and P buffering capacity (Pbug) both increased between unamended and amended soil but there were no differences between levels of AG on amended soil PRI of amended soil was 26 to 30 and Pbuff was 24 to 30 (Table 41)
The Bic-P and PRI measurements taken two days before planting on residual AG were the same at all levels of AG Bic-P was 16 to 21 ugg and PRI was 37 to 53 (Table 42) On the other hand Pbuff measured mid-growth increased from 20 at 01 AGha to 30 and 40 at 120 and 2401 AGha The EC was 7-9 mSm on all treatments and pH (H20) increased between 0 and 120 t AGha from 73 to 84 (Table 42)
The use of Red Mudgypsum in vegetable production
Table 41 Characteristics of the top 15 cm of a Karrakatta sand amended with several levels of freshly-applied Alkaloamreggypsum (AG) when no fertiliser P was applied
AG (tha)
pH (H20)
pH (CaCl2)
EC (mSm)
Bic-P (ugg)
Total P (ugg)
PRI Pbuff
0 72 64 5 8 55 19 14
60 84 77 8 10 64 26 24
90 85 78 9 11 76 30 30
120 85 83 9 10 71 27 27
Signif NS NS $
Lsd 5 04 05 3 07 05
Table 42 Characteristics of the top 15 cm of a Karrakatta sand amended with several levels of residual Alkaloamreggypsum (AG) when 600 kg Pha was applied as superphosphate
AG (tha)
pH (H20)
pH (CaCl2)
EC (mSm)
Bic-Pa
(ugg) PRIa
Pbuff
0 73 67 7 16 37 20
60 78 71 5 17 40 23
120 84 77 9 20 44 30
240 88 80 9 21 53 40
Signif NS NS NS
Lsd 5 05 06 10
K Sampled and measured before application of fertiliser P
Total phosphorus in soil
Total P in the soil at harvest on freshly-applied AG increased significantly with level of AG averaged over all three depths sampled (P lt 005) It also increased with level of applied P on all levels of AG At 0-15 cm total P increased significantly between 0 and 601 AGha At 15-30 cm it increased significantly between 0 and 90 t AGha and at 30-45 cm there was no effect of level of AG at all (Fig 41) At all levels of AG and P which were sampled total P concentrations at 0-15 cm and 15-30 cm were not significantly different from each other and both were significantly greater than those at 30-45 cm (Fig 41)
In the top 15 cm of soil total P increased from 47 ugg on unamended soil to 62-67 ugg on amended soil when no fertiliser P was applied This increase represents the total P content of the AG itself When 100 kg Pha was applied total soil P (0-15 cm) increased from 63 ugg at 01 AGha to 83 ugg at 601 AGha and 95 and 103 ugg at 90 and 1201 AGha (Fig 41) When the increase due to the AG itself is considered this is an increase in fertiliser P retention of 6 ugg (26 kgha) between 0 and 601 AGha and a further 14 ugg (62 kgha) between 60 and 120 t AGha At 600 kg Pha the increase in fertiliser P retention was 35 ugg (15 kgha) between 0 and 601 AGha and 25 ugg (11 kgha) between 60 and 120 t AGha
Total P on residual AG increased with level of AG The increase was significant between 60 and 1201 AGha only It also decreased at increasing depth As observed on freshly-applied AG total P concentrations at 0-15 cm and 15-30 cm were not significantly different from each other and were both greater than that observed at 30-45 cm (Fig 43) At 0-15 cm total P increased by 20 ugg between 0 and 601 AGha and by a further 213 ugg between 60 and 1201 AGha when 600 kg Pha was applied These values cannot be corrected for the total content of AG itself as there was no 0 kg Pha treatment
9
The use of Red Mudgypsum in vegetable production
The addition of freshly-applied AG to the soil substantially increased the theoretical ability of the soil to sorb applied P as measured by the P buffering capacity in the top 15 cm of soil However it was reduced over time as 1201 AGha was required to increase Pbuff on residual AG compared with 601 AGha on freshly-applied AG Fertiliser P retention in the top 15 cm of soil when amended with 1201 AGha was increased by 9 at 100 kg Pha and by 4 at 600 kg Pha
The effects of residual and freshly-applied AG can be compared at 600 kgha of applied P The effect of residual AG on fertiliser P retention can be estimated from measurements made on the same site at the beginning of the first (lettuce) crop In that experiment total P before the application of P fertilisers increased from 69 and 62 ugg on 0 and 601 AGha to 91 ugg on 1201 AGha and 103 ugg on 2401 AGha (Robertson et al 1994 Appendix 1H) This makes the estimated increase in fertiliser P retention (0-15 cm) 27 ugg (12 kgha) between 0 and 601 AGha and 184 ugg (81 kgha) between 60 and 1201 AGha Therefore between 60 and 1201 AGha residual AG increased fertiliser retention by approximately 7 times as much as did freshly-applied AG
Bicarbonate-extractable P (soil-test P) in soil
On freshly-applied AG there was no overall response of Bic-P to level of AG although there was an upward trend Bic-P decreased with increasing depth averaged over all treatments following the same response as total P There was an interaction between the effects of depth and level of applied P At 0 kg Pha there was no difference in Bic-P between the three depths sampled but at 100 and 600 kg Pha Bic-P concentrations at 0-15 cm and 15-30 cm were both greater than those at 30-45 cm (Fig 42) The upward trend in Bic-P with increasing level of AG was weak on soil where no P fertiliser had been applied being from 9-10 ugg at 0 and 601 AGha to 11 and 14 ugg at 90 and 1201 AGha in the top 15 cm This suggests that the AG adds little if any plant available P to the soil The amount of fertiliser P retained as Bic-P in the top 15 cm of soil when 100 kg Pha was applied increased by 8 ugg between 0 and 601 AGha and by a further 4 ugg between 60 and 120 t AGha At 600 kg Pha Bic-P retained from fertiliser increased by 34 ugg between 0 and 601 AGha and by 16 ugg between 60 and 1201 AGha
The response of Bic-P to level of residual AG and to depth was the same as for total P (Fig 43) In the top 15 cm of soil Bic-P increased by 11 ugg between 0 and 601 AGha and by 82 ugg between 60 and 1201 AGha uncorrected for the Bic-P content of the AG itself
The increase in Bic-P retention observed on amended soil at 100 kg Pha was similar to that observed at 160 kg Pha on a crop of carrots grown on a Joel sand amended with AG (Robertson et al 1997) Using the soil-test standards published by Hegney et al (1997) these increases in Bic-P will reduce the P fertiliser requirement in the following potato crop by 10 at 601 AGha and 22 at 1201 AGha
Using the Bic-P concentrations observed on the residual site at the beginning of the lettuce crop (Robertson et al 1994 Appendix 1H) the increase in fertiliser P retained as Bic-P (0-15 cm) on residual AG was 15 ugg between 0 and 601 AGha and 79 ugg between 60 and 1201 AGha This is half the increase observed on freshly-applied AG between 0 and 60 t AGha and approximately 5 times that observed on freshly-applied AG between 60 and 1201 AGha
The reduced P retention at low levels of residual AG compared with freshly-applied AG was probably because of the higher initial Bic-P levels on residual AG For both total and Bic-P it is difficult to explain why the apparent retention of fertiliser P between 60 and 120 t AGha should have been so much greater on residual than on freshly-applied AG It may have been caused by changes to the chemical properties of the AG as it aged in the ground
10
The use of Red Mudgypsum in vegetable production
Yield
Total and marketable yields on freshly-applied AG both increased with level of applied P following a Mitscherlich response (Fig 44 (a) (b)) An ANOVA did not indicate any response to level of AG in either total or marketable yields However maximum total yield on unamended soil (61 tha) was significantly greater than that on AG-amended soil - 54 to 57 tha (Fig 44 (a)) On the other hand there were no differences in maximum marketable yields Maximum marketable yield values ranged from 52 to 55 tha (Fig 44 (b)) When marketable yield was calculated as a percentage of total yield an ANOVA indicated a significant interaction between level of AG and level of applied P At 400 kg Pha marketable yield was 88 of total yield on unamended soil compared with approximately 95 on amended soil (significant according to 5 Lsd) A similar trend was observed at 600 kg Pha where marketable yield was 90 of total yield on unamended soil and 93 to 96 on amended soil
The levels of applied P required for 99 of maximum total yield were 245 222 183 and 400 kg Pha on 0 60 90 and 1201 AGha and for 95 of maximum yield were 139 130 108 and 226 kg Pha (Fig 44 (a)) A similar trend can be seen for marketable yield where 99 of maximum yield required 178 206 208 and 356 kg Pha (Fig 44 (b))
Total yield on residual AG showed an almost significant response to level of AG (P = 0067) (Fig 45) Total yield was 68 to 72 tha on 0 60 and 120 t AGha and 62 tha on 2401 AGha Marketable yield was 65 to 68 tha on 0 to 1201 AGha and 58 tha on 2401 AGha Therefore 2401 AGha appears to reduce yields even when it has been in the ground for 2 years or more and even when 600 kg Pha is applied As only one level of P fertiliser was applied it is not possible to determine the effect of residual AG on the critical levels of P application required for 99 and 95 of maximum yield
Concentration of nutrients in petioles
Phosphorus
Phosphorus concentration in petioles of the YML sampled at the S2 stage on freshly-applied AG increased with level of applied P following a Mitscherlich response (Fig 46) Maximum petiole P concentrations were approximately 12 (dry basis) on all AG levels Values at 99 of maximum petiole P concentration were 116 122 117 and 116 at 0 60 90 and 1201 AGha There was a significant interaction between levels of AG and applied P (P lt 005) At low levels of applied P (25 50 and 100 kgha) P concentrations on amended soil were significantly less than those on unamended soil but there was no difference between them at 300 or 600 kg Pha This is reflected in the levels of applied P required for 99 of maximum petiole P concentration which were 209 499 581 and 508 kg Pha at 0 60 90 and 1201 AGha This is an increase of 138 on amended soil relative to unamended soil AG at levels of between 60 and 120 tha therefore reduces the availability of P to plants As there was no difference in the maximum P concentration in petioles between amended and unamended soil a reduction in P availability to plants cannot explain the reduced maximum yield on amended soil Another factor was therefore involved in reducing maximum yield on amended soil Despite this yield difference between amended and unamended soil which was not related to differences in P concentration total yield for all AG levels combined was linearly correlated with petiole P concentration at the S2 stage (y = 256 + 274x R2 = 087) (Fig 47)
The petiole P concentration at 99 of maximum total yield was 116 109 095 and 114o at 0 60 90 and 1201 AGha At 01 AGha this was the same as 99 of maximum petiole P concentration implying that the yield response on unamended soil was controlled principally by P availability On the other hand petiole P concentrations at 99 of maximum yield on amended soil especially 60 and 901 AGha were less than 99 of maximum petiole P concentration In other words yield stopped increasing even though P concentration in the plant kept increasing This supports the previous observation that some factor other than P was limiting yield in these treatments Petiole P concentration in YMLs sampled at S2 stage on residual AG did not change with level of AG Overall mean P concentration was 12 dry
11
The use of Red Mudgypsum in vegetable production
basis This is in keeping with the results observed on freshly-applied AG at 600 kg Pha It also means that the lower yield at 2401 AGha on residual AG could not be explained by a reduced P concentration in the plant As on freshly-applied AG another factor was involved which reduced yield on amended soil although at a higher level on residual than on freshly-applied AG
Hegney et al (1997) found that maximum petiole P concentration at S2 in potatoes grown on Karrakatta sand was 114 dry basis and that 109 was required for 99 of maximum yield in good agreement with the results observed here
Other nutrients
The responses of nutrients other than P were very similar on both freshly-applied and residual AG Concentrations of K (Tables 43 45) and Zn (Fig 48 (a) Table 45) decreased as level of AG increased and concentrations of Mg Fe and Ca increased with level of AG in both experiments (Tables 43 45 Fig 48 (b)) Zn concentrations also decreased with increasing level of applied P (Fig 49 (a)) while Ca concentrations increased with level of applied P (Fig 48 (b)) Concentrations of Na also showed an upward trend on both freshly-applied and residual AG (Tables 43 45) On freshly-applied AG K concentrations decreased significantly from 119 dry basis on unamended soil to 110 at 601 AGha and to 102 at 1201 AGha (Table 43) On residual AG it decreased from 11-12 at 0-1201 AGha to 103 at 2401 AGha (Table 45) No other nutrients showed any response to level of AG although concentrations of N Mn S and B increased with level of applied P on freshly-applied AG (Table 44)
Concentrations of all nutrients except K were adequate or more than adequate for maximum yield (Maier et al 1987) on both freshly-applied and residual AG Potatoes require concentrations of approximately 12 to 14 K (dry basis) in petioles of YML for maximum yield (Maier et al 1987) On freshly-apphed AG concentrations were adequate at 01 AGha but were less than adequate on amended soil On residual AG concentrations were adequate at 0 60 and 1201 AGha but less than adequate at 2401 AGha As less than adequate K concentrations correspond with those treatments which had low yield it is likely that K concentration was the limiting factor in yield on both freshly-applied and residual AG
Uptake of K may have been reduced at higher levels of AG due to an increased Cation Exchange Capacity (Barrow 1982 McPharlin et al 1994) or to the increased soil pH (Harris 1992) The reduction in Zn availability on amended soil is most likely to be a result of the increase in soil pH due to the AG (Harter 1983)
Table 43 Concentrations of several nutrients in the petioles of the Youngest Mature Leaf of potato plants sampled at the 10 mm tuber stage at several levels of freshly-applied Alkaloamreggypsum (AG) on a yellow Karrakatta sand
AG K Na Mg Fe (tha) () () () (ngg)
0 119 018 059 382
60 110 020 065 553
90 106 021 066 597
120 102 021 069 697
Signif NS
Lsd 5 04 004 119
12
The use of Red Mudgypsum in vegetable production
Table 44 Concentrations of several nutrients in the petioles of the Youngest Mature Leaf of potato plants sampled at the 10 mm tuber stage at two levels of applied P when grown on a yellow Karrakatta sand amended with freshly-applied Alkaloamreggypsum (AG)
Applied P N S Cu Mn B (kgha) () () (ngg) (ngg) (M-gg)
0 44 028 74 293 267
600 48 032 62 342 248
Signif NS NS
Table 45 Concentrations of several nutrients in the petioles of the Youngest Mature Leaf of potato plants sampled at the 10 mm tuber stage at several levels of residual Alkaloamreggypsum (AG) on a yellow Karrakatta sand
AG N K Na Ca S Mg Cu Fe Mn Zn B (tha) () () () () () () (l-igg) (ngg) (ngg) Ws) (^gg)
0 51 116 016 23 030 050 77 453 46 96 26
60 48 127 015 21 027 045 61 457 45 67 25
120 49 120 016 26 029 051 66 643 59 59 25
240 49 103 019 29 030 067 54 977 53 53 24
Signif NS NS NS NS NS NS
Lsd5 05 04 013 164 24
Tuber P and Crop P removal P concentration in tubers
The concentration of P in tubers on freshly-applied Alkaloamreg increased with level of applied P (P lt 0001) The response at each level of Alkaloamreg was best described by a Mitscherlich curve although none of the curves reached a maximum within the range of fertiliser P levels used (Fig 49 (a)) There was a trend for an overall response to level of AG (P = 0081) P concentrations were generally higher on unamended soil than on amended soil For example at 300 kg Pha P concentration was 033 on unamended soil and 026-028 on amended soil and at 600 kg Pha P concentrations were 036 and 032-033 on unamended and amended soil respectively At P levels corresponding to 99 of maximum yield tuber P concentration was 031 024 023 and 028 at 0 60 90 and 1201 AGha
On residual AG tuber P concentration did not change with level of AG The overall mean was 036 dry basis
Total P uptake
Total P uptake by tubers on freshly-applied AG showed a significant response to level of AG (P lt 005) and level of applied P (P lt 0001) The response to applied P at each level of AG was best described by a Mitscherlich curve although as for tuber P concentration none of the curves reached a maximum within the range of P levels applied P uptake by tubers on unamended soil was significantly greater than on amended soil regardless of AG level (Lsd 5) (Fig 49 (b)) At levels of applied P corresponding to 99 of maximum yield P uptake by tubers was 113 75 75 and 95 kgha at 0 60 90 and 1201 AGha These figures are lower than results reported by Hegney et al (1997) who found a P uptake by tubers grown on yellow Karrakatta sand of 204 kgha at 99 of maximum yield even though yields were similar to those observed on unamended soil in this experiment
13
The use of Red Mudgypsum in vegetable production
Total P uptake by tubers was not significantly different between AG levels on residual AG Overall mean P uptake was 110 kgha This is different from the situation observed at 600 kg Pha on freshly-applied AG As only one level of P was applied the response curve for tuber P concentration on residual AG cannot be compared with that on freshly-applied AG It is possible that less applied P is required on residual than on freshly-applied AG to reach maximum tuber P concentration
Metals in tubers
The concentration of As in tubers harvested from freshly-applied AG showed a trend to increase with level of AG from 5 x 104 mgkg (fresh weight) on unamended soil to 8 x 104 mgkg at 60 and 901 AGha (Fig 410) Concentrations of all other metals measured showed no response to level of AG either on residual or freshly-applied AG (Table 46 47) On freshly-applied AG concentrations of Ni and Cd increased and concentrations of Cu decreased with increasing level of applied P (Table 48)
Table 46 Mean concentrations (mgkg fresh weight) of metals in tubers of potato cv Delaware harvested from a yellow Karrakatta sand amended with freshly-applied Alkaloam^gypsum (AG)
Cr Co Sn Sb Hg
mean
se
0007
61 xlO5
60 x 104
50 x 106
15 x 103
10 x 104
90 x 105
10 xlO5
34 x 104
14 x 105
Table 47 Mean concentrations (mgkg fresh weight) of metals in tubers of potato cv Delaware harvested from a yellow Karrakatta sand amended with residual Alkaloamreggypsum (AG)
Cr Co Ni Cu As Cd Sn Sb Hg Pb
mean
se
001
68X104
72xl(f 29xia5
55xia3
17x1a4
010
35xia3
L2X103
0
58xia3
17X104
LOxlO3
29X104
30X1O4
43xl05
84X1G4
ii xia5
l ixia3
70xia5
Table 48 Mean concentrations (mgkg fresh weight) of metals in tubers of potato cv Delaware harvested from a yellow Karrakatta sand amended with freshly-applied Alkaloamreggypsum (AG) at various levels of applied P
Applied P (kgha)
Ni Cd Cu
0 0006 0002 018
100 0006 0002 016
300 0007 0004 015
600 0008 0006 013
Signif
Lsd (5) 00014 0001 002
The concentrations of As observed in tubers from freshly-applied AG regardless of the level of AG were less than 10 of the legal limit (10 mgkg fresh weight NFA 1992) The concentrations of all metals measured were between 3 and 33 of those measured in potato tubers in a previous experiment (Robertson et al 1994 Appendix 1 J) The concentrations on residual AG were also lower than the concentrations previously observed in lettuce and cauliflowers on the same site (Robertson et al 1994 Appendix IH I) As different batches of
14
The use of Red Mudgypsum in vegetable production
AG were used on the two sites they cannot be compared to determine the effect of time on metal availability and uptake Overall metal uptake by potato tubers grown on AG-amended yellow Karrakatta sand does not appear to pose any greater health risk than that on unamended yellow Karrakatta sand The observed increase in As concentration in potato tubers on freshly-applied AG was probably due to the increase in soil pH with level of AG (ONeill 1990)
Conclusions
Freshly-applied AG reduces the availability of fertiliser P so that approximately 25 times the level of applied P is required on 60 to 1201 AGha relative to unamended soil in order to attain maximum P concentration in plant tissues AG at 120 tha also increases the retention of fertiliser P sufficiently to reduce fertiliser requirements for a following potato crop by approximately 20 The effect of AG on the level of fertiliser P required for 99 of maximum yield was confounded in this experiment by the decrease in maximum yield between unamended and amended soil Total yield of potatoes will be reduced on 60 tha freshly-applied AG and by 240 tha residual AG probably by a limiting concentration of K There is potential for increased levels of K fertiliser to overcome this yield reduction AG increases the proportion of yield which is marketable so that even though total yield is reduced by 60 tha of freshly-applied AG the marketable yield is not There are no apparent problems with heavy metal contents of tubers due to amendment with AG
References Allen DG and Jeffery RC (1990) Methods for analysis of phosphorus in Western
Australian soils Chemistry Centre of WA Report of Investigation No 37
Anonymous (1977) Technicon Industrial Method 334-74WB+ Technicon Industrial Systems Tarrytown NY USA
Barrow NJ (1982) Possibility of using caustic residue from bauxite for improving the chemical and physical properties of sandy soils Australian Journal of Agricultural Research 275-285
Colwell JD (1963) The estimation of phosphorus fertiliser requirements of wheat in southern New South Wales by soil analysis Australian Journal of Experimental Agriculture and Animal Husbandry 3 190-197
Glenister DJ and Thoraber MR (1985) Alkalinity of red mud and its application for the management of acid wastes Chemeca 85 109-113
Harris PM (1992) Mineral Nutrition In The Potato Crop The scientific basis for improvement 2nd edition (ed P Harris) pp 162-213 (Chapman and Hall London UK)
Harter RD (1983) Effect of soil pH on adsorption of lead copper zinc and nickel Soil Science Society of America Journal 47 47-51
Hegney MA McPharlin IR and Jeffery RC (1997) Response of winter-grown potatoes (Solanum tuberosum L) to applied and residual phosphorus on a Karrakatta sand Australian Journal of Experimental Agriculture 37 (in press)
Maier NA Williams CMJ Potocky-Pacay K Moss D and Lomman GJ (1987) Interpretation standards for assessing the nutrient status of irrigated potato crops in South Australia Technote AGDEX 262533 September 1987 Department of Agriculture South Australia
15
The use of Red Mudgypsum in vegetable production
McArthur WM and Bettenay E (1960) The development and distribution of the soils of the Swan Coastal Plain Western Australia CSIRO Division of Soils Soils Publication No 16
McPharlin IR Jeffery RC Toussaint LF and Cooper M (1994) Phosphorus nitrogen and radionuclide retention and leaching from a Joel sand amended with red mudgypsum Communications in Soil Science and Plant Analysis 25 489-500
McQuaker NR Brown DF and Kluckner PD (1979) Digestion of environmental materials for analysis by inductively coupled plasma atomic emission spectrometry Analytica Chimica 51 1082-1084
Murphy J and Riley JP (1962) A modified single solution method for the determination of phosphate in natural waters Analytica Chimica Acta 27 31-36
NFA (National Food Authority) (1992) Australian Food Standards Code June 1992 (Australian Government Publishing Service Canberra)
ONeill P (1990) Arsenic In Heavy Metals in Soils(ed BJ Alloway) pp 83-99 (Blackie Glasgow)
Ozanne PG and Shaw TC (1967) Phosphate sorption by soils as a measure of the phosphate requirement for pasture growth Australian Journal of Agricultural Research 18 601-612
Robertson WJ McPharlin IR and Jeffery RC (1994) Final Report of investigation into the use of gypsum-amended red mud as a soil-amendment on horticultural properties on the Swan Coastal Plain Agriculture WA
Robertson WJ McPharlin IR and Jeffery RC (1997) Residues from bauxite-mining (red mud) increase phosphorus retention of a Joel sand without reducing yield of carrots Communications in Soil Science and Plant Analysis (in press)
Yuen SH and Pollard AG (1954) Determination of nitrogen in agricultural materials by the Nessler reagent II Micro-determination in plant tissue and in soil extracts Journal of Food in Agriculture 5 364-369
16
The use of Red Mudgypsum in vegetable production
300
250 -
I I
200
3
60 80
AG (tha)
140
Figure 41 Total phosphorus concentration in a yellow Karrakatta sand amended with freshly-applied Alkaloamreggypsum (AG) vs level of AG when 0 (bull) 100 (A) and 600 (bull) kg Pha was applied measured at 0-15 cm () 15-30 cm (mdash) and 30-45 cm (mdash) depth Bars are Lsds at 5 level of significance
17
The use of Red Mudgypsum in vegetable production
Z3
200
180 -
160
Q- 140
ro 120 bull 4 -
O CD X 100 CD i
3 80 CO c o
pound gt v_ CO
o CQ
AG Depth
I
0 20 40 60 80 100 120
AG (tha)
140
Figure 42 Bicarbonate-extractable phosphorus concentration in a yellow Karrakatta sand amended with freshly-applied Alkaloamreggypsum (AG) vs level of AG when 0 (bull) 100 (A) and 600 (bull) kg Pha was applied measured at 0-15 cm () 15-30 cm (mdash) and 30-45 cm (mdash) depth Bars are Lsds at 5 level of significance
18
The use of Red Mudgypsum in vegetable production
700
600
500
D)
3 400
CL
oil
300 CO
200
100
100 150
A G (tha)
250
Figure 43 Total (mdash) and Bicarbonate-extractable phosphorus () concentration in a yellow Karrakatta sand amended with residual Alkaloamreggypsum (AG) when 600 kg Pha was applied measured at 0-15 cm () 15-30 cm (A) and 30-45 cm (bull) depth Bars are Lsds at 5 level of significance
19
The use of Red Mudgypsum in vegetable production
CO
2 CD
gt-
200 300 400
Applied P (kgha)
Figure 44 (a) Total yield of potatoes cv Delaware grown on a yellow Karrakatta sand amended with freshly-applied AIkaIoamreggypsum (AG) at a level of 0 (bull) 60 (A) 90 (bull) and 120 (bull) tha vs level of applied P Lines represent the level of applied P required for 99 of maximum yield Bars are Lsds at 5 level of significance
Equations are
A
B
C
D
0 tha
60 tha
90 tha
120 tha
j - 614 - 255 x exp (-00152) (JR= 092)
y = 542 - 271 x exp (-00176) (R2= 090)
y = 552 - 274 x exp (-0021) (F= 094)
y = 566 - 229 x exp (-00092) (i^= 098)
20
The use of Red Mudgypsum in vegetable production
ro
JO
gt-
100 200 300 400
Applied P (kgha)
500 600
Figure 44 (b) Total yield of potatoes cv Delaware grown on a yellow Karrakatta sand amended with freshly-applied Alkaloamreggypsum (AG) at a level of 0 (bull) 60 (A) 90 (bull) and 120 (bull) tha vs level of applied P Lines represent the level of applied P required for 99 of maximum yield Bars are Lsds at 5 level of significance
Equations are
Otha A
B
C
D
60 tha
90 tha
120 tha
y = 547 - 216 x exp (-0021) (R2^ 088)
y = 517 - 278 x exp (-0019) (R2= 090)
y = 524 - 243 x exp (-001 to) (R2= 094)
y = 530 - 218 x exp (-001 Ox) (i^= 098)
21
The use of Red Mudgypsum in vegetable production
CO
32
gt-
80
70
60
50
40
30
20
10
0 0
Marketable yield
Marketable yield
Total yield
Total yield
_L 50 100 150 200
AG (tha)
250 300
Figure 45 Total (bull) and Marketable (bull) yield of potatoes cv Delaware grown on a yellow Karrakatta sand amended with residual AIkaloamreggypsum (AG) vs level of AG 600 kg Pha was applied Bars are Lsds at 5 level of significance
22
The use of Red Mudgypsum in vegetable production
w CO CO
a gtraquo i _
C
o 00
c CD O c o o
100 200 300 400
Applied P (kgha)
500
Figure 46 Concentration (dry basis) of phosphorus in petioles of the Youngest Mature Leaf of potatoes cv Delaware grown on a yellow Karrakatta sand amended with freshly-applied Alkaloamreggypsum (AG) at 0 (bull) 60 (A) 90 (bull) and 120 (bull) tha vs level of applied P Lines represent the level of applied P required for 99 of maximum yield Bars are Lsds at 5 level of significance
Equations are
A Otha y = 117- 079 x exp (-0020) (R2 = 096)
B 60 tha y=123- 096 x exp (-000874) (R2 - 099)
C 90 tha y = 118 - 0884 x exp (-000742) (R2 = 096)
D 120 tha y= 117 - 090 x exp (-00085) (R2 = 097)
23
The use of Red Mudgypsum in vegetable production
CO
c
53
CD
gt-
00 02 04 06 08 10
Petiole P ( dry basis)
12 14
Figure 47 Yield of potatoes cv Delaware grown on a yellow Karrakatta sand amended with freshly-applied AlkaIoamreggypsum (AG) at 0 (bull) 60 (A) 90 (bull) and 120 (bull) tha vs petiole P concentration
The equation is y = 256 + 274x (ft2 = 087)
24
The use of Red Mudgypsum in vegetable production
poundgt 3
0 100 200 300 400 500 600 700
Applied P (kgha)
Figure 48 (a) Concentration of Zinc and (B) Calcium ( dry weight) in petioles of the youngest mature leaf of potatoes cv Delaware harvested from a yellow Karrakatta sand amended with freshly-applied Alkaloamreggypsum (AG) at 0 (bull) 60 (A) 90 (bull) and 120 (bull) tha vs level of applied P Bars are Lsds at 5 level of significance
25
The use of Red Mudgypsum in vegetable production
100 200 300 400 500
Applied P (kgha)
700
Figure 48 (b) Concentration of Calcium ( dry weight) in petioles of the youngest mature leaf of potatoes cv Delaware harvested from a yellow Karrakatta sand amended with freshly-applied AlkaIoamreggypsum (AG) at 0 (bull) 60 (A) 90 (bull) and 120 (bull) tha vs level of applied P Bars are Lsds at 5 level of significance
The use of Red Mudgypsum in vegetable production
040
ogt 035 CD
gtgt bullo
w _CB O
H) CL
CO 1 _ -mdashraquo c CD O c o o Q
030 -
025 -
020
2 015
010 -
005
000 0 100 200 300 400
Applied P (kgha)
500 600
Figure 49 (a) The concentration of phosphorus in tubers ( dry weight) of potatoes cv Delaware harvested from a yellow Karrakatta sand amended with freshly-applied Alkaloamreggypsum (AG) at 0 (bull) 60 (A) 90 (bull) and 120 (bull) tha vs level of applied Pkgha Bars are Lsds at 5 level of significance
Equations are
A 0 tha
B 60 tha
C 90 tha
D 120 tha
y = 0372 - 0243 x exp (-00058) (R2 = 097)
y = 0378 - 0257 x exp (-00029x) (R2 = 098)
y = 0361 - 0216 x exp (-00029x) (i^= 095)
y = 0406 - 0279 x exp (-0002x) (R2 = 098)
27
The use of Red Mudgypsum in vegetable production
CO
3
ltD
CO Q Z5
ID
B
14
12 -^ ^
10
8 W
6
4
A G P
I
2
n I i i I I i
0 100 200 300 400
Applied P (kgha)
500 600
Figure 49 (b) Phosphorus uptake Gigha) by tubers of potatoes cv Delaware harvested from a yellow Karrakatta sand amended with freshly-applied Alkaloamreggypsum (AG) at 0 (bull) 60 (A) 90 (bull) and 120 (bull) tha vs level of applied P Bars are Lsds at 5 level of significance
Equations are
Otha A
B
C
D
60 tha
90 tha
120 tha
y = 140 - 1095 x exp (-00058r) (R2 = 096)
3= 111 - 882 x exp (-0004x) (R2 = 098)
y = 104 - 774 x exp (-00053) (R2 = 099)
3 = 127 -101 x exp (-00029x) (R2 = 0997)
28
The use of Red Mudgypsum in vegetable production
60 80
AG (tha)
Figure 410 Concentration of Arsenic (dry weight) in tubers of potatoes cv Delaware grown on a yellow Karrakatta sand amended with freshly-applied Alkaloamreggypsum (AG) Bar is Lsd at 5 level of significance
29
The use of Red Mudgypsum in vegetable production
5 RESPONSE OF CAULIFLOWERS TO FRESHLY-APPLIED RED MUD (ALKALOAMreg)GYPSUM AND PHOSPHORUS ON A YELLOW KARRAKATTA SAND
Introduction
It is important to reduce the leaching of phosphorus fertiliser from sandy soils used for vegetable production into the water systems of the Swan Coastal Plain Red Mud (AlkaloamR)gypsum (AG) a waste product from bauxite refining has been suggested as an amendment to reduce phosphorus leaching from sands of the Bassendean Association (Joel Gavin) used for agriculture and horticulture (Barrow 1982)
Experimental work in the field and pots showed amendment with AG significantly reduced P leaching from Joel and Gavin sands (Vlahos et al 1989 McPharlin ei al 1994) compared with the unamended (01 AGha) treatment
In previous work freshly-applied AG at 60 tha increased the amount of freshly-applied P required for maximum yield of cauliflowers 14 (autumn planted) but did not reduce maximum yield (20 tha) compared with the unamended (0 tha) treatment on a yellow Karrakatta sand (Robertson et al 1994) At the highest rate of applied AG (120 tha) P required for maximum yield was 32 higher than at 0 tha and maximum yield was reduced 23 (P lt 005)
Since more than 60 tha of AG may be required to significantly improve P retention by sands to enable sustainable horticultural production this yield reduction is re-examined with freshly-applied AG
Materials and methods
Site characteristics
The experiment was conducted on a yellow Karrakatta sand (McArthur and Bettenay 1960) of low P fertility at Medina Research Centre (32deg 13 S 115deg 49 E) 30 km South of Perth The site had no previous history of AG application and had been sown to pasture for several years Some relevant chemical characteristics of the topsoil (0-15 cm) and subsoil (15-30 cm) of the site after application of AG but prior to the application of fertiliser and transplanting are presented in Table 51
Red Mud (AlkaIoamreg)gypsum (AG)
Alkaloamreg (Red Mud) amended with 10 (ww) gypsum (AG) was produced by the dry mix process by ALCOA of Australia Ltd at their Kwinana Residue Treatment Plant The AG was spread manually on the site and incorporated using a rotary hoe to approximately 30 cm depth on 21 February 1996 The site was watered for 1 hour per day (8 mmday) using impact sprinklers until planting
Experimental design
The experimental design was a split-plot randomised block with 3 replicates The main plots were levels of AG (0 60 120 and 240 tha) and the sub-plots were levels of freshly-applied P (0 50 100 200 400 and 600 kgha) Main plots measured 6 x 12 m and sub-plots 12 x 6 m (excluding wheel tracks)
Crop management
The site was sprayed with Roundupreg (3 Lha) twice after application of AG and prior to planting to control weeds
The use of Red Mudgypsum in vegetable production
Six week old seedlings of cauliflowers (cv Plana) obtained from a commercial nursery were transplanted manually on 18 April 1996 in 2 rows per plot with 70 cm between rows and 50 cm between plants Seedlings were dipped in Rovralreg 1 mLL just prior to planting for control of fungi Treflanreg (14 Lha) and Dacthalreg (12 kgha) were applied immediately after transplanting to control broadleaved weeds and Sertinreg later on in the life of the crop for grass control Ambushreg (100 mLha) and Rogorreg (100 mLha) were used to control caterpillars and red legged earth-mite respectively Copper sprays were used for control of blackrot The crop was irrigated to a total application equivalent to 100 of the previous days pan evaporation using minisprinklers (Legoreg 6 x 6 m spacing 44 mmh) in 3 waterings of equal duration per day
Fertilisers
Pre-planting fertilisers were broadcast manually and rotary hoed on 17 April 1996
These were K2S04(244) Ca (N03)2 4H20 (387) MgS047H20 (504) MnS04H20 (504) FeS047H20 (18) Borax (27) CuS045H20 (36) ZnSOH20 (28) and Na2Mo042H20 (2) Single superphosphate (91 P)was applied at 0 to 600 kgha according to treatment and incorporated as before Post-planting K N and Ca were fertigated via the irrigation system as KN03 NH4NO3 and Ca (N03)2 in equal amounts per day for 12 weeks to a total of 600 kg K 423 kg N and 60 kg Caha Borax was fertigated at 20 kgha in week 3 and Mg was broadcast as MgS047H20 at 50 kgha in weeks 3 6 and 9
Measurements
Soil and soil solution
All zero P subplots were sampled 30 cores per plot just prior to planting and fertilising about 2 months after AG application to 2 depths (0-15 15-30 cm) These were oven dried at 40degC and analysed for Ec pH (CaCl2) P sorption (Ozanne and Shaw 1968) bicarbonate extractable P K (Colwell 1963) total P PRI P sorption K sorption (Allen and Jeffery 1990) and cation exchange capacity (Gillman and Sumpter 1986)
The soil water was obtained by centrifugation from soil samples (0-15 cm 30 per plot) and collected from the 0 100 200 and 600 kg Pha plots across all AG treatments on 16 May 1996 The supernatant was analysed for pH Ec Ca Mg K S and P The remaining soil was analysed for pH (H20) bicarbonate extractable P and K PRI and DTPA extractable Zn After harvest on 5 August 1996 soil samples were collected from 2 depths as for the preplanting treatment from all plots These were analysed for pH bicarbonate extractable P K total P PRI and exchangeable cations (Ca Mg K and N)
Plant
At buttoning on 13 June 1996 the younger mature leaves (YML) (4th from growing point) were collected from 16 plants in each plot (excluding 1 m buffer at each end) They were dried at 70degC in a force draught oven for 48 h and ground to pass through a 1 mm screen Sub-samples were digested with sulphuric acidhydrogen peroxide (Yuen and Pollard 1954) and the concentration of N P and K measured by an automated colorimetric process (Varley 1966) Concentration of other nutrients (B Ca Na Mg S Fe Mn Zn and Cu) were determined by inductively coupled plasma atomic emission spectroscopy (ICP-AES) after digestion with nitric-perchloric acids (McQuaker et al 1979)
Five whole plants were harvested from the middle of each plot (2 per row)at the end of the experiment on 4 July 1996 using shovels to recover as much of the root system as possible The plants were separated into four categories curds leaves stems and roots All soil was washed from the roots using tap water shaken and the excess water removed using paper towels The fresh weight of all four categories was recorded and the material was diced into small pieces (lt 8 cm3) using stainless steel knives sub-samples (300 g fresh weight) were collected at random from the diced pieces and the fresh weight recorded These were dried at
31
The use of Red Mudgypsum in vegetable production
70degC in a forced draught oven for 48 h and the dry weight recorded These samples were then analysed for P as for the youngest mature leaves Separate sub-samples (300 g fresh weight) of curds were collected and analysed for Ba Cd Cr Co Pb Mo Rb Sr Ti Th V and N using inductively coupled plasma mass spectrometry (ICP-MS) The fresh and dry weight of the curds leaves stems and roots at harvest were used to calculate P uptake in kgha)
Harvest
Harvest commenced when the leaves surrounding the head opened and exposed the curds 77-80 days after transplanting At this stage florets at the periphery of the curd had just begun to separate Sixteen curds (12 plus 4 from whole plant samples above) were collected from the central 4 m of both rows (1 m buffer) and all the leaves and stems removed according to requirements for export market Each fresh curd was weighed and rejects recorded if undersize (lt 500 g) oversize (gt 2000 g) discoloured (yellowing) overmature (separation of florets in centre of curd) diseased damaged or otherwise distorted The total marketable and reject yield were recorded for each plot
Analysis of data
Analysis of variance was carried out on level of applied AG or P versus (a) chemical characteristics of soil (bicarbonate extractable P total P etc) preplanting and harvest (b) concentrations of nutrients in soil solution at midgrowth (c) concentration of nutrients in YMLs at midgrowth (d) concentration of elements in curds at harvest (e) P uptake by plant parts and (f) total marketable and reject yield of curds at harvest Mitscherlich curves and inverse polynomials were fitted to the relationship between level of applied P and yield at each level of applied AG The level of applied P required for 95 99 and 100 (in case of inverse polynomials) of maximum yield was calculated Mitscherlich curves were fitted to the relationship between level of applied P and P in YMLs at midgrowth at all levels of AG The P in YMLs corresponding to the level of applied P required for 95 99 or 100 of maximum yield (as determined from yield versus applied P plots) was then determined
Mitscherlich curves were also fitted to the relationship between level of applied P and P uptake by curds leaves stems and roots and the P uptake corresponding to whole plants (additions of all 4) level of P required for 95-100 of maximum yield determined Phosphorus uptake by plant parts or whole plants on 0 P plots were detected from P uptake at other rates to account for non-fertiliser sources of P This was used to adjust P uptake When determining P fertiliser recovery efficiency (RE) by plant parts or whole plants (ie fertiliser P uptake by plant parts or whole plantsP applied both in kgha Novoa and Loomis 1981)
Results
Effects of fresh AG on chemical characteristics of soil and soil solution
There was a significant (P lt 005) increase in the Ec pH PRI and sorption capacity (topsoil only) of the topsoil and subsoil of a yellow Karrakatta sand with level of freshly-applied AG prior to fertiliser application and planting (Table 51) There was no significant effect of level of AG on Colwell K K sorption capacity and total P with level of freshly-applied AG (Table 51)
The use of Red Mudgypsum in vegetable production
Table 51 Some chemical characteristics of the topsoil (0-15 cm) and subsoil (15-30 cm) of a yellow Karrakatta sand after application of Alkaloam gypsum (AG)1 just prior to fertiliser application and transplanting
(a) Topsoil (0-15 cm)
AG (tha)
Ec (mSm)
pH (CaCl2)
BicP2
(Vigfe)
BicK2
(pgg) PRI3
(mLg) TP4
(Pgg) CEC5
(me ) Kads6 Pads7
0 37 74 107 153 097 507 2 0 41
60 67 82 93 197 167 473 2 043 66
120 80 82 100 277 243 607 2 044 78
240 103 84 97 290 38 637 2 058 129
Lsd8 202 037 38 136 046 1010 0 049 41
Sig9 ns ns ns ns ns
(b) Subsoil (15-30 cm)
AG Ec PH BicP2 BicK2 PRI3 TP4
(tha) (mSm) (CaCl2) (Pgg) (Pgg) (mLg) (Pgg)
0 30 72 83 227 07 507
60 63 81 73 190 15 453
120 80 81 87 220 18 540
240 107 83 83 240 27 563
Lsd8 202 037 38 136 046 101
Sig9 ns ns ns
Applied 7 weeks previously 2 After Colwell (1963) 3 Phosphorus retention index after Allen and Jeffery (1990) 4 Total phosphorus 5 Cation exchange capacity (Gillman and Sumpter 1986) 6 Slope of K adsorption isotherm from the Freundlich equation (Allen and Jeffery 1990) 7 Slope of P adsorption isotherm from the Freundlich equation (Allen and Jeffery 1990) 8 Least significant difference at P lt 005 9 Significance at lt 0001 () lt 001 () lt 005 () level or not significant (ns)
There was a significant (P lt 005) increase in the concentration of Na and a decrease in the concentration of K in the soil solution with level of freshly-applied AG one month after planting and fertilising (Table 52 (a) and Fig 51) At the same time Colwell K and PRI in the topsoil increased significantly with level of freshly-applied AG By contrast there was a significant decrease in extractable Zn with level of AG The concentration of Ca Mg S and P increased significantly with level of applied P in soil solution (Table 52 (a)) Colwell P in the topsoil increased significantly with level of P whilst Colwell K PRI and extractable Zn decreased at the same time (Table 52 (b))
33
The use of Red Mudgypsum in vegetable production
Table 52 (a) Ec (mSm) pH and concentration of nutrients (pgmL) in soil solution 1 month after planting with level of freshly-applied Alkaloamreggypsum (AG)1 and phosphorus
AG
AG (tha)
Ec (mSm)
pH Ca (pgmL)
Mg (pgmL)
Na (pgmL)
K (pgmL)
S (pgmL)
P (pgmL)
Psrp2
(VigmL)
0 112 70 175 18 110 77 101 57 56
60 132 74 164 17 137 58 92 34 31
120 172 75 166 17 152 54 97 44 34
240 166 81 130 16 198 34 75 24 11
Lsd3 19 025 33 4 16 11 26 27 32
Sig4 ns ns ns ns ns
p
AG (tha)
Ec (mSm) PH
Ca (pgmL)
Mg (pgmL)
Na (pgmL)
K (pgmL)
S (UgmL)
P (pgmL)
Psrp2
(pgmL)
0 137 78 99 15 150 46 26 10 01
100 142 76 112 15 153 54 52 23 14
200 170 74 179 19 150 62 114 39 30
600 133 72 244 19 144 60 174 89 87
Lsd3 43 022 31 24 17 15 29 25 30
Sig4 ns ns ns
Applied 11 weeks previously
Soluble reactive P 3 Least significant difference at P lt 005 4 Significance at lt 0001 () lt 001 () lt 005 () level or not significant (ns)
The use of Red Mudgypsum in vegetable production
220
200
E 180 O ) 3
^ 1fi0 _ o 3 140 O V)
oil
120 m c
100 C o CO 80 c flgt o B0 c o o 40
20
0 50 100 150 200
Freshly-applied AG(tha)
250 300
Fig51 Concentration (ugml) of Na(i ) and K ( bull ) in soil solution (0-15cm) under cauliflowers one month after planting with level of freshly-applied AlkaloamRgypsum(AG) Vertical bars indicates Lsd (Plt005) for differences in concentration betweeen levels of AG
35
The use of Red Mudgypsum in vegetable production
Table 52 (b) Extractable P K Zn and phosphorus retention index of the top soil (0-15 cm) of a yellow Karrakatta sand 1 month after transplanting with level of freshly-applied Alkaloamreggypsum (AG)1 and phosphorus (P)
AG
AG (tha)
P2
(ugg) K2
(Ugg) Zn3
(Pgg)
PRI4
(mLg)
0 47 32 67 -112
60 76 38 15 -090
120 94 42 26 -049
240 84 41 13 092
Lsd5 35 6 28 073
Sig6 ns
P P2 K2 Zn3 PRI4
(kgha) (ugg) (Hgg) (Ugg) (mLg)
0 8 42 31 201 100 35 37 45 043 200 80 39 18 -089 600 177 34 26 -313
Lsd5 39 6 27 082
Sig6 ns
Applied 11 weeks previously 2 After Colwell (1963) 3 Extracted in DTPA 4 Phosphorus retention index (Allen and Jeffery 1990) 5 Least significant difference at P lt 005 6 Significance at lt 0001 () lt 001 () lt 005 () level or not significant (ns)
Ec pH exchangeable Ca K Na in me and Colwell P K total P PRI and PRIP increased significantly (P lt 005) with level of freshly-applied AG in the topsoil and subsoil of a yellow Karrakatta sand (Table 53 (a) (b) and Fig 52) at harvest
The use of Red Mudgypsum in vegetable production
o CO
CD
E
o CO
co o
CD
X co CD ogt e co sz o X HI
50 100 150 200
Freshly-applied AG (tha)
250 300
Fig52 Exchangeable Ca() NaP) and K(A) cations (me dry soil) in topsoil (0-15cm) of Karrakatta sand amended with freshly-applied AlkaloamRgypsum(AG) after harvest of cauliflowers Vertical bars indicates Lsd (Plt005) for differences in concentration between levels of AG Lsd not shown when less than size of symbol
37
The use of Red Mudgypsum in vegetable production
Table 53 Ec (mSm) pH and exchangeable Ca Mg K and Na (me ) in the topsoil (0-15 cm) and subsoil (15-30 cm) of a yellow Karrakatta sand amended with AlkaIoamreggypsum (AG) at harvest of cauliflowers
(a) Topsoil
AG Ec PH Ca Mg K Na (tha) (mSm) (CaCl2) (me ) (me ) (me ) (me )
0 67 66 229 018 005 003
60 91 77 382 019 009 02
120 99 79 558 019 012 043
240 120 80 975 024 014 104
Lsd2 20 014 064 0033 0018 021
Sig3 ns
(b) Subsoil
AG Ec pH Ca Mg K1 Na (tha) (mSm) (CaCl2) (me ) (me ) (me ) (me )
0 44 67 225 017 005 003
60 59 74 269 019 005 008
120 66 77 300 018 005 017
240 99 79 397 02 005 029
Lsd2 075 01 029 0036 001 002
Sig3 n s ns
Extracted in 1 m NH4CI 2 Least significant difference at P lt 005 3 Significance at lt 0001 () lt 001 () lt 005 () level or not significant (ns)
However there was no effect of either level of AG or P on exchangeable Mg in the soil at harvest Colwell P total P and PRIP increased significantly whilst Colwell K and PRI decreased with level of freshly-applied P in the topsoil at harvest (Table 4 (a) (b) and Fig 53)
The use of Red Mudgypsum in vegetable production
Table 54 P (extractable P total P phosphorus retention index and P sorption) in the top soil (0-15 cm) and subsoil (15-30 cm) of a yellow Karrakatta sand at harvest of cauliflowers with level of freshly-applied Alkaloamreggypsum (AG) and phosphorus (P)
(a) Topsoil
AG
AG BicP1 BicK1 TotP2 PRI3 PRIP3
(tha) (ugg) (Pgg) (Hgg) (mLg) (mLg)
0 39 23 92 -07 28
60 50 38 110 02 50
120 59 51 135 16 75
240 58 62 157 35 99
Lsd4 5 11 15 03 06
Sig5
P BicP1 BicK1 TotP2 PRI3 PRIP3
(kgha) (ugg) (Hgg) (ngg) (mLg) (mLg)
0 10 53 57 29 40
50 15 40 66 22 38
100 25 41 78 17 44
200 53 41 128 14 71
400 87 44 186 -01 86
600 120 41 226 -12 102
Lsd4 11 8 20 09 13
Sig5
1 After Colwell (1963) 2 After Allen and Jeffery (1990) 3 After Allen and Jeffery (1990) 4 Least significant difference at P lt 005 5 Significance at lt 0001 () lt 001 () lt 005 () level or not significant (ns)
39
The use of Red Mudgypsum in vegetable production
Table 54 P (extractable P total P phosphorus retention index and P sorption) in the top soil (0-15 cm) and subsoil (15-30 cm) of a yellow Karrakatta sand at harvest of cauliflowers with level of freshly-applied Alkaloamreggypsum (AG) and phosphorus (P)
(b) Subsoil (15-30 cm)
AG
AG BicP1 BicK1 TotP2 PRI3 PRIP3
(tha) (ugg) (Ugg) (Ugg) (mLg) (mLg)
0 33 20 79 -05 26
60 30 21 73 -01 30
120 33 27 77 08 42
240 26 24 76 13 40
Lsd4 10 2 10 04 10
Sig5 ns ns
P BicP1 BicK1 TotP2 PRI3 PREP3
(kgha) (ugg) (Vigg) (Ugg) (mLg) (mLg)
0 7 25 48 15 22
50 11 22 52 09 19
100 15 24 59 10 27
200 32 23 81 06 39
400 51 22 100 -03 47
600 67 21 117 -11 52
Lsd4 8 5 8 05 09
Sig5 ns
1 After Colwell (1963) 2 After Allen and Jeffery (1990) 3 After Allen and Jeffery (1990) 4 Least significant difference at P lt 005 5 Significance at lt 0001 () lt 001 () lt 005 () level or not significant (ns)
The use of Red Mudgypsum in vegetable production
100 150 200
Freshly-applied AG (tha)
300
Fig53 Concentration of total P(A) Colwell P() or K(laquo) in topsoil (0-15cm) with level of freshly-applied AlkaloamRgypsum (AG) after harvest of cauliflowers Vertical bars indicates Lsd (Plt005) for differences in concentration between levels of AG Lsd not shown when less than size of symbol
41
The use of Red Mudgypsum in vegetable production
Nutrients in leaves at midgrowth and harvest
There was a significant decrease in concentration of K and an increase in concentration of Na S Mn and Cu in youngest mature leaves (YML) of cauliflowers at buttoning with level of freshly-applied AG (Table 55) The concentration of P in YML at 01 AGha (049) was significantly higher than at 2401 AGha (044) but not at other levels Currently-applied AG had no significant effect on concentration of N Ca Mg Fe Zn or B in YML There was a significant increase in YML in the concentration of K P and S in YML with level of applied P whilst concentration of N Mg Mn and B were variable (Fig 54 55) Level of applied P had no significant effect on the concentration of Ca and Na in the YML (Table 55)
Table 55 (a) Concentration of macro-nutrients (dry weight basis) in youngest mature leaves of cauliflowers at buttoning with level of freshly-applied Alkaloamreggypsum (AG) and phosphorus (P)
AG
AG N1 K1 Ca2 S2 P1 Na2 Mg2
(tha) () () () () () () ()
0 482 393 240 081 049 036 023
60 484 383 251 084 046 040 024
120 506 357 255 081 046 045 024
240 494 355 246 088 044 056 025
Lsd3 026 012 024 005 003 006 0013
Sig4 ns ns ns ns
p
p N1 K1 Ca2 S2 P1 Na2 Mg2
(kgha) () () () () () () ()
0 523 316 254 066 024 046 025
50 489 372 255 081 041 049 026
100 503 388 229 084 048 042 024
200 472 379 250 089 050 046 024
400 494 390 242 093 057 043 023
600 470 385 258 091 057 039 022
Lsd3 027 024 036 005 003 008 0017
Sig4 ns ns
1 After Varley (1966) 2 After McQuaker et al (1979) 3 Least significant difference at P lt 005 4 Significance at lt 0001 () lt 001 () lt 005 () level or not significant (ns)
The use of Red Mudgypsum in vegetable production
0 50 100 150 200 250 300
Freshly-applied AG (tha)
Rg54 Concentration of N() K(B) and Ca(A) in youngest mature leaf (YML) at buttoning
of cauliflowers with level of freshly-applied AlkaloamRgypsum(AG) Vertical bars
indicates Lsd (Plt005) for differences in concentration between levels of AG
10
bdquo 09 lt Q OR ^ D) 07 c
tto
06 3
X3
to 05 _ l
gtbull 04 C
i3 03 c agt bull c 02 3
-z 01 0 50 100 150 200 250 300
Freshly-applied AG (tha)
Rg55 Concentration of S() Na(B) Mg(4) and P(T) in youngest mature leaf (YML) at buttoning
of cauliflowers with level of freshly-applied AlkaloamRgypsum(AG) Vertical bars indicates Lsd (Plt005) for differences in concentration between levels of AG
43
The use of Red Mudgypsum in vegetable production
The relationship between P in YML at buttoning and level of freshly-applied P was best described by Mitscherlich relationships at all levels of applied AG (Fig 56)
en c o 3
X2
gt
06
^
bull A
05 ^ S
04
03
02
01
n n i i i
0 100 200 300 400 500 600 700
Applied P (kgha)
o
X I
5 gt
06
05
04
03
02
01
00
- bull B
- bull bull ^
o
I I I I
0 100 200 300 400 500 600 700
Applied P (kgha)
100 200 300 400 500 600 700
Applied P (kgha)
100 200 300 400 500 600 700
Applied P (kgha)
Fig56 P in YML of Cauliflowers at buttoning () corresponding to applied P required for either 95 (dashed line) or 99 (whole line) of maximum yield at 0(A) 60(B) 120(C) or240(D)t of freshly-applied AlkaloamRgypsumha
The equations for the fitted lines are
A
B
C
D
y = 056 - 030 x exp (-00182) (R2 = 097)
y = 057 - 032 x exp (-00103) (R2 = 088)
y = 055 - 031 x exp (-00126) (R2 = 099)
y = 056 - 032 x exp (-00092) (R2 = 098)
The P in YML corresponding to level of freshly-applied P required for 99 of maximum yield was 053 057 055 and 055 for 0 60 120 and 240 tha respectively
44
The use of Red Mudgypsum in vegetable production
Table 55 (b) Concentration of micro-nutrients (dry weight basis) in youngest mature leaves of cauliflowers at buttoning with freshly-applied Alkaloamreggypsum (AG) and phosphorus (P)
AG
AG (tha)
Fe (Pgg)
Zn (Ugg)
Mn (vigg)
B (Pgg)
Cu1
(Pgg)
0 1354 251 217 211 26
60 1274 248 237 213 28
120 1353 253 240 217 27
240 1394 263 260 214 29
Lsd2 153 24 15 082 02
Sig3 ns ns ns
P Fe Zn Mn B Cu (kgha) (ngg) (ugg) (Pgg) (Ugg) (Pgg)
0 1418 268 212 215 26
50 1388 253 263 220 27
100 1301 267 251 217 29
200 1336 249 250 217 28
400 1282 255 232 204 28
600 1341 233 224 210 28
Lsd2 197 29 19 08 02
Sig3 ns ns ns
1 Extracted in 1 m NH4CI 2 Least significant difference at P lt 005 3 Significance at lt 0001 () lt 001 () lt 005 () level or not significant (ns)
There was a significant (P lt 005) decrease in the concentration of P Zn and an increase in the concentration of Na in whole leaves (WL) of cauliflowers with rate of freshly-applied AG at harvest (Table 56) Level of freshly-applied AG had no significant effect on concentration of N K Ca S Mg Fe Mn B or Cu Concentration of Ca S P and Na in (WL) at harvest increased significantly (P lt 005) with level of freshly-applied P whereas Zn concentrations decreased and concentrations of Mg Mn and B were variable Level of freshly-applied P had no significant effect on concentration of N K Fe or Cu in WL at harvest
45
A O O ltyi
4x
r en 00
9 400 200 o o o copy
ns
O
kgt ON
kgt
4gt
kgt 4 4 4^
kgt
ns
O 4 4 ON 4 k)
o
i mdash t mdash raquo
4 00
4 ON
4 4^ NO Q O
o copy ON
i mdash gt
b b 1 mdash t
b o p Vcopy
O 00 ON
o ON
gtmdash 5 co 5J M
o o
O in
o 4 Ncopy
o 4 O
p 4
p kgt 1 mdash t
copy
ON
o b NO
O ON
o 00
o 00
o ON I mdash
O ON
O 3 Z 5 raquoM
o b 4
O
kgt o kgt -J
p kgt 00
O kgt 00
O
kgt NO
copy kgt ON
The use of Red Mudgypsum in vegetable production
Table 56 (b) Concentration of micro-nutrients (dry weight basis) in leaves of cauliflowers at harvest with level of freshly-applied Alkaloamreggypsum (AG) and phosphorus (P)
AG
AG (tha)
Fe1
(ugg) Zn1
(vgg) Mn1
(vgg) B1
(vgg) Cu1
(vigg)
0 762 224 214 263 42
60 700 197 227 265 38
120 811 196 216 254 38
240 842 193 236 256 37
Lsd2 132 099 21 16 06
Sig3 ns ns ns ns
P (kgha)
Fe1
(pgg) Zn1
(^gg) Mn1
(Vigg) B1
(lJgg) Cu1
(Pgg)
0 786 233 213 248 36
50 625 235 241 266 37
100 833 207 237 270 41
200 938 192 235 265 44
400 725 178 208 259 37
600 765 169 206 250 37
Lsd2 230 21 21 11 063
Sig3 ns ns
After McQuaker et al (1979)
Least significant difference at P lt 005
Significance at lt 0001 () lt 001 () lt 005 () level or not significant (ns)
47
The use of Red Mudgypsum in vegetable production
Nutrients and heavy metals in curds at harvest
There was a significant (P lt 005) decrease in the concentration of K and P and an increase in the concentration of Ca and Na in the curds at harvest with level of freshly-applied AG Concentration of N Mg Fe Zn Mn B and Cu in the curds were unaffected by level of freshly-applied AG (Table 57) As level of freshly-applied P increased there was a significant (P lt 005) decrease in concentration of N S Mg Fe Zn Mn and B and an increase in concentration of K Ca P and Na in curds at harvest Concentration of Cu in curds were unaffected by level of applied P (Table 57 (b))
Table 57 (a) Concentration of macro-nutrients (dry weight basis) in curds of cauliflowers at harvest with level of freshly-applied Alkaloamreggypsum (AG) and phosphorus (P)
AG
AG N1 K1 Ca S1 P2 Na1 Mg1
(tha) () () () () () () ()
0 392 515 040 066 047 023 018
60 384 500 040 067 045 023 017
120 404 474 043 071 043 024 018
240 402 458 041 071 041 028 018
Lsd3 022 016 001 004 002 002 0006
Sig4 ns + ns ns
P
p N1 K1 Ca1 S1 P2 Na1 Mg1
(kgha) () () () () () () ()
0 496 417 034 097 031 016 019
50 400 518 043 068 040 023 018
100 376 483 042 063 042 025 017
200 372 501 044 063 047 027 017
400 371 498 042 062 052 028 017
600 358 505 041 060 052 027 016
Lsd3 027 02 003 005 002 003 001
Sig4
1 After McQuaker et al (1979) 2 After Varley (1966) 3 Least significant difference at P lt 005 4 Significance at lt 0001 () lt 001 () lt 005 () level or not significant (ns)
The use of Red Mudgypsum in vegetable production
Table 57 (b) Concentration of micro-nutrients1 (dry weight basis) in curds Cauliflowers at harvest with level of freshly-applied Alkaloam gypsum (AG) and phosphorus (P)
AG
AG (tha)
Fe1
(Ugg)
Zn1
(vigg) Mn1
(Pgg) B1
(Pgg) Cu1
(Pgg)
0 611 279 124 188 26
60 587 247 134 191 25
120 706 299 139 192 29
240 592 268 145 186 25
Lsd2 329 57 14 08 06
Sig3 ns ns ns ns ns
p
p (kgha)
Fe1
(Ugg) Zn1
(Pgg) Mn1
(Ugg) B1
(ugg)
Cu1
(Pgg)
0 976 492 156 202 31
50 520 279 145 198 26
100 507 230 135 186 24
200 432 208 127 190 24
400 739 239 131 183 28
600 567 192 120 177 24
Lsd2 270 61 142 114 061
Sig3 a s
1 After McQuaker et al (1979) 2 Least significant difference at P lt 005 3 Significance at lt 0001 () lt 001 () lt 005 () level or not significant (ns)
49
The use of Red Mudgypsum in vegetable production
Concentration of Ba in curds at harvest decreased and concentration of Ti increased significantly in curds at harvest with level of freshly-applied P (Table 58) As level of freshly-applied P increased concentrations of Pb and Rb decreased and of Sr decreased Ba concentrations were variable with level of freshly-applied P (Table 58)
Table 58 Concentration of Ba plus heavy metals1 (fresh weight basis) in curds of cauliflowers at harvest with level of freshly-applied Alkaloamreggypsum (AG) and phosphorus (P)
AG Ba Cd Cr Co Pb Ni Rb Sr Ti Th V (tha) (ngg) (ngg) (ngg) (ngg) (ngg) (ngg) (ngg) (ngg) (ngg) (ngg) (ngg)
0 797 7 34 7 13 34 590 1219 34 39 7
60 482 7 34 7 15 34 610 1146 46 52 8
120 583 7 43 7 20 34 616 1246 45 50 8
240 355 7 34 7 15 34 637 1152 41 45 8
Lsd2 141 1 13 16 11 15 74 188 5 16 1
Sig3 ns ns ns ns ns ns ns ns ns
MRL4 50 2000
P (kgha)
Ba (ngg)
Cd (ngg)
Cr (ngg)
Co (ngg)
Pb (ngg)
Ni
(ngg)
Rb (ngg)
Sr (ngg)
Ti
(ngg)
Th
(ngg)
V (ngg)
0 556 7 34 7 25 34 650 998 39 45 9
50 670 7 34 7 18 34 657 1387 50 74 9
100 576 7 34 7 11 34 570 1206 45 50 8
200 529 7 34 7 12 34 616 1293 39 39 7
400 523 7 48 7 19 39 596 1126 39 36 7
600 476 7 34 7 11 34 603 1126 36 36 7
Lsd2 121 1 16 1 15 6 40 181 19 29 2
Sig3 ns ns ns ns ns ns ns ns
MRL4 50 2000
Inductively coupled plasma mass spectrometry 2 Least significant difference at P lt 005 3 Significance at lt 0001 () lt 001 () lt 005 () level or not significant (ns) 4 Maximum residue limit
The use of Red Mudgypsum in vegetable production
P uptake by plants P uptake by whole plants or plant parts was unaffected by level of freshly-applied AG by but increased significantly with level of freshly-applied P (Table 59)
P uptake by whole plants increased from 50 kg Pha to 19 to 21 kgha at 400 to 600 kg applied Pha respectively Curd root stem and leaf uptake was 33 5 6 and 50 respectively of total plant P uptake at the highest level of applied P (Table 59)
Table 59 P uptake (kgha) by curds roots stem leaf and whole cauliflower plants at harvest with level of freshly-applied Alkaloamreggypsum (AG) and phosphorus (P)
AG
AG Curds Roots Stem Leaf Total (tha) (kgha) (kgha) (kgha) (kgha) (kgha)
0 53 074 11 87 158
60 48 066 10 83 148
120 47 069 11 79 143
240 45 060 10 74 135
Lsd1 065 015 025 21 31
Sig-2 ns ns ns ns ns
p
p (kgha)
Curd (kgha)
Root (kgha)
Stem (kgha)
Leaf (kgha)
Total (kgha)
0 12 030 040 29 49
50 40 058 100 68 124
100 51 053 112 76 143
200 59 075 120 93 172
400 67 093 131 115 205
600 61 094 121 102 185
Ls-d1 055 017 020 18 25
Sig2
1 Least significant difference at P lt 005 2 Significance at lt 0001 () lt 001 () lt 005 () level or not significant (ns)
51
The use of Red Mudgypsum in vegetable production
Yield
There was a significant (P lt 005) increase in both total and marketable curd yield with level of freshly-applied P at all levels of freshly-applied AG (Table 510) There was no significant effect of level of freshly-applied AG on either total (Table 510 (a)) or marketable (Table 510 (b)) curd yield
Table 510 Curd yield (total marketable) of cauliflowers (tha) at harvest with level of freshly-applied Alkaloamreggypsum (AG) and phosphorus (P)
(a) Total
p (kgha)
AG (tha) p
(kgha) 0 60 120 240
0 755 468 483 177
50 1464 1675 1554 1516
100 2169 1706 1757 1985
200 2242 1737 1928 1862
400 1752 2102 2155 2136
600 1689 1764 1768 2023
Lsd1
Sig2
16 (AG)
ns 201 (P)
401 (AGP)
-
(b) Marketable
p (kgha)
AG (tha) p
(kgha) 0 60 120 240
0 274 060 000 000
50 1222 1463 1294 1152
100 2057 1416 1603 1820
200 2141 1377 1803 1752
400 1572 2020 2095 1996
600 1468 1534 1500 1974
Lsd1
Sig2
24 (AG)
ns
46 (P)
52(AGP)
ns
Least significant difference at P lt 005 2 Significance at lt 0001 () lt 001 () lt 005 () level or not significant (ns)
The relationship between total yield and level of freshly-applied P was best described by a quadratic relationship at all levels of freshly-applied AG (Fig 57) As level of AG increased the level of freshly-applied P required for 99 of maximum yield increase from 124 kg Pha at 0 t AGha to 339 kg Pha at 240 tha There was no significant effect of level of freshly-applied AG on maximum curd yield (Fig 57)
The use of Red Mudgypsum in vegetable production
26
24
22
(tha
) 20
18
Cur
d yi
eld 16
14
12
10
8
6 i ii
A=0
i i i i i
I I
0 100200300400500600700
Applied P (kgha)
24 22 20 18 16 14 12 10 8 6 4 2
- 7 I
_ bull
i i i n
mdash^ B=60
I I I
0 100200300400500600700
Applied P (kgha)
co
32 CD
gt 2 3
o
25
20
15
10
5
bull j
- bull
I I I I I
- - gt C=120
l l l
0 100200300400500600700
Applied P (kgha)
0 100200300400500600700
Applied P (kgha)
Fig57 Total curd yield (tha) of cauliflower with level of freshly-applied Alkaloam gypsum and
phosphorus (ABCD = 060120240 tha) Vertical lines represent applied P necessary
for either 95 (dashed) or 99 (whole) of maximum yield
The equations for the fitted lines are
A y = 1336 + (-577 + 01335x)(l-00088x +000007872) (Z2
B y = 89434 + 00705 - OOOOlx2 (R2 = 070)
C y = 84752 + 00810 - OOOOlx2 (B2 = 081)
D y = 733 +00871x - 00001 Ix2 (R2 = 099)
098)
53
The use of Red Mudgypsum in vegetable production
Discussion
The increase in pH Ec PRI and P sorption of Karrakatta sands with level of freshly-applied AG prior to fertiliser application is similar to that reported for the amendment of Joel (McPharlin et al 1994 and Robertson et al 1997a) and Karrakatta sands (Robertson et al 1994 and 1997b) with AG The increase in DH and Ec of the amended soil is explained by the high levels of both in the AG (ie pH (CaCr) = 94 and Ec = 623 mSm Appendix 1) The increased retentionsorption of P is explained by the addition of iron (974) and aluminium (551) in various oxides and hydroxides in the AG (Appendix 1 and Barrow 1982) to the soil After the application of P fertilisers levels of P in the soil at mid-growth and harvest as measured by total and Colwell P increased with a parallel decrease in PRI The increase in the levels of exchangeable Ca and Na in the soil at the same times with level of freshly-applied AG can be attributed to the AG itself However the increase in exchangeable and Colwell K appears to be due to improved K retention capacity of the soil due to physical properties of the AG rather any increased supply of K from the AG Whilst the overall K adsorption properties of the soil as measured by the Freundlich isotherm was not significantly increased with level of AG K sorption at 2401 AGha was significantly higher than at 01 AGha
There was no significant increase in cation exchange capacity (CEC) with level of freshly-applied AG on the Karrakatta sand in this experiment which remained about 2 me By contrast the CEC of virgin Joel sands increased from 1 to 2 me with level of freshly-applied AG (0 to 240 tha) in columns (McPharlin et al 1994) The application of AG would be expected to increase the CEC of coarse sands because (1) AG a fine textured material (10 clay 68 silt) (Ward 1983) would increase the fine fraction when applied to sands (2) AG has a much higher CEC ie 7 to 15 me depending on pH (Barrow 1982) than either Joel or Karrakatta sands ie 1 to 2 me (McPharlin et al 1994 and Table 51) and (3) application of AG to either Joel or Karrakatta sands increases the retentionreduces leaching of cations either not present in the AG such as NH4-N (McPharlin et al 1994) or only present in small quantities such as K (Tables 52 53 54 and Appendix 51)
The concentration of an element in the soil expressed as either extractable or total amounts represents the quantity or extensive factor in terms of plant nutrition as outlined by Holford and Mattingly (1976) The concentration of ions in soil solution or the intensive factor may better represent what is available to the plant A good example of this is the levels of K in the soil expressed as either Colwell or exchangeable K which increase significantly with level of applied AG However levels of K in the plant YML at buttoning and curds at harvest decrease significantly with level of AG K in soil solution 1 month after planting similarly decline significantly with level of applied AG and are therefore better correlated with K nutrition of the plant than measurements based on the dry soil Similarly P concentrations in the plant and soil solution decline whilst P retained by the soil increase in response to freshly-applied AG By contrast concentrations of Na in soil solution soil and plant all increase with levels of freshly-applied AG Similar relationships between concentrations of K Na and P in the soil soil solution and plant on a Karrakatta sand have been reported previously (Robertson et al 1997)
In previous work maximum yield (ie A value) of cauliflowers was reduced when freshly prepared AG was applied at levels gt 120 tha (Robertson et al 1994) This yield reduction was assumed not to be due to induced P deficiency resulting form high level of applied AG as it could not be alleviated by increased levels of applied P Although increased levels of applied P were needed to maximise yield as the level of freshly-applied AG increased Concentrations of K decreased and Na increased in the YML with level of applied AG and the yield reduction was assumed to be due either induced K deficiency or Na toxicity However neither the reduced concentrations of K or the increased concentrations of Na in the plant were at levels that would reduce yield according to published standards (Weir and Cresswell 1993) Antagonism between Na and K uptake by plants is common (Yeo 1983) For example increasing soil salinity resulted in increased concentrations of Na and decreased concentrations of K in the leaves of Zucchini grown in controlled greenhouses in Spain (Villora et al 1997)
The use of Red Mudgypsum in vegetable production
In this work as level of freshly-apphed AG increased level of applied P necessary for maximum yield increased as in the previous work however maximum yield was not reduced by AG up to 240 tha This is despite concentrations of K in the YML decreasing and Na increasing in response to level of freshly-applied AG However as in the previous work neither concentrations of K or Na were at levels expected to cause yield reduction By contrast the reduction in maximum yield of potatoes at high levels of freshly-applied AG (ie gt 120 tha) was correlated with a reduced concentration of K in the petioles (Robertson et al 1997b)
The level of freshly-applied P required for 99 of maximum yield in this work increased from 124 kgha at 01 AGHa to 339 kgha at 2401 AGha These levels of applied P are similar to that reported necessary for maximum yield of cauliflowers on AG-amended (Robertson et al 1994) or unamended (McPharlin et al 1995) Karrakatta sands The P required for 99 of maximum yield in this work 053 to 057 was either slightly higher - 047 (McPharlin et al 1995) or within range - 05 to 07 (Piggott 1986) 03 toO7 (Weir and Cresswell 1993) of that reported as critical or adequate for maximum yield of cauliflowers
Increased levels of freshly-applied AG did not significantly change the concentrations of Cd Co Cr Pb Ni Rb Sr Th or V in the curds of cauliflowers By contrast concentrations of Ba were significantly reduced and Ti increased in the curds with levels of freshly-applied AG Similarly there was no reported change in concentration of Cd Cr Pb or Co with level of freshly-applied AG in curds of cauliflower grown on Karrakatta sands (Robertson et al 1994) in previous work Also there was no change in Ba concentration in curds with level of AG in contrast to the previous work
References
Barrow NJ (1982) Possibility of using caustic residue from bauxite for improving the chemical and physical properties of sandy soils Australian Journal of Soil Research 33 275-285
Holford ICR and Mattingly GEG (1976) Phosphate adsorption and plant availability of phosphate Plant and Soil 44 377-89
McArthur and Bettenay (1960) The development and distribution of the soils of the Swan Coastal Plain Western Australia Soils Publication No 16 CSIRO Division of Soils CSIRO Melbourne Australia
McPharlin IR JefFery RC Toussaint LF and Cooper M (1994) Phosphorus Nitrogen and Radionuclide Retention and Leaching from a Joel Sand amended with Red Mudgypsum Communications in Soil Science and Plant Analysis 25 (17 amp 18) 2925-2944
McPharlin IR Robertson WJ JefFery RC and Weissberg R (1995) Response of cauliflower to phosphate fertiliser placement and soil test phosphorus calibration on a Karrakatta sand Communications in Soil Science and Plant Analysis 26(3amp4) 607-620
McQuaker NR Brown DF and Kluckner PD (1979) Digestion of environmental materials for analysis by inductively coupled plasma-atomic emission spectrometry Analytical Chemistry 51 1082-1084
Piggott TJ (1986) Vegetable crops pp 148-187 In DJ Reuter and JB Robinson (eds) Plant Analysis an Interpretation manual Inkata Press Melbourne Australia
Robertson WJ McPharlin IR and JefFery RC (1994) Final report of investigation into the use of gypsum-amended Red Mud as a soil-amendment on horticultural properties on the Swan Coastal Plain Report to HRDC (Project No V0039RO) Department of Agriculture Western Australia
55
The use of Red Mudgypsum in vegetable production
Robertson WJ Jeffery RC and McPharlin IR (1997a) Residues from bauxite-mining (Red Mud) increase phosphorus retention of a Joel sand without reducing yield of carrots Communications in Soil Science and Plant Analysis 28 (in press)
Robertson WJ McPharlin IR and Jeffery RC (1997b) The growth nutrition and mineral composition of potatoes (Solanum tuberosum L) cv Delaware grown on an yellow Karrakatta sand amended with freshly-applied and residual Alkaloamreggypsum (Submitted to AJEA)
Varley J A (1966) Automatic methods for the determination of nitrogen phosphorus and potassium in plant material Analyst 91 119-126
Villora G Pulgar G Moreno DA and Romero L (1997) Effect of salinity treatments on nutrient concentration in Zucchini plants (Cucurbita pepo L var Moschatd) Australian Journal of Experimental Agriculture 37 605-608
Vlahos S Summers KJ Bell DT and Gilkes RJ (1989) Reducing phosphorus leaching from sandy soils with Red Mud bauxite processing residues Australian Journal of Soil Research 27 651-662
Weir RG and Cresswell GC (1993) Plant Nutrient Disorders 3 Vegetable crops p 93 Inkata Press Melbourne Australia
Yuen SH and Pollard AG (1954) Determination of nitrogen in agricultural material by the Nessler reagent II Micro determination in plant tissue and soil extracts Journal of the Science of Food and Agriculture 5 364-369
The use of Red Mudgypsum in vegetable production
Appendix 51 Chemical and physical characteristics of Alkaloam gypsum used in cauliflower experiment (freshly-applied Alkaloamreggypsum)
Parameter Units Value Kgt
Ec mSm 623 -
pH (H 20) mSm 99 -
pH (CaCl2) mSm 94 -
PRI mLg 610 - gt 1000 -
LOI 1973 -
C a C 0 3 1290 1290
Fe (Fe203) 974 974
Al (A1203) 551 551
Si (Si0 2 ) 797 797
Ca (CaO) 45 450
Na (Na 2 0) 228 228
Ti (Ti0 2 ) 174 174
K (K 2 0) 072 72
Mg (MgO) 028 28 sect 047 47
P (P2O5) 005 05
Mn (MnO) 002 02
Total P ngg 266 -
Extractable P M-gg 58 -
Extractable K M-gg 43 -
As ngg 35 -
Ba ^gg 413 -
Cu Ugg 29 -
Sr Hgg 287 -
Nb Hgg 99 -y Hgg 866 -
Zr fAgg 1477 -
Sand 232 -
Silt 473 -
Clay 295 -
After Allen and Jeffery (1990)
Based on X-ray fluorescence (XRF) spectrometry
After Colwell (1963)
The use of Red Mudgypsum in vegetable production
Appendix 52 Concentration of Ba plus heavy metals1 (dry weight basis) in curds of cauliflowers at harvest with level of freshly-applied Alkaloamreggypsum (AG) and phosphorus (P)
(a)
AG Ba Cd Cr Co Pb Ni Rb Sr Ti Th V (tha) (Pgg) (vigg) (ugg) (ugg) (Pgg) (Pgg) (Pgg) (ugg) (Pgg) (Pgg) (Pgg)
0 119 010 050 010 020 050 88 182 050 058 010
60 72 010 050 010 022 050 91 171 069 078 012
120 87 011 064 011 030 050 92 186 067 075 012
240 53 011 05 010 023 050 95 172 061 067 012
Lsd2 21 002 02 024 016 022 11 28 008 024 002
Sig3 ns ns ns ns ns ns ns ns ns
(b)
p (kgha)
Ba (vgg)
Cd (vigg)
Cr (Pgg)
Co (ngg)
Pb (vgg)
Ni (Pgg)
Rb (Pgg)
Sr (Pgg)
Ti
(Pgg)
Th (Pgg)
V
(Pgg)
0 83 010 050 010 038 050 97 149 058 067 013
50 100 011 050 010 027 050 98 207 075 110 013
100 86 010 050 010 017 050 85 180 067 075 012
200 79 010 050 010 018 050 92 193 058 058 010
400 78 011 071 011 028 058 89 168 058 054 011
600 71 010 050 010 016 050 90 168 054 054 010
Lsd2 18 002 024 0009 022 009 06 27 028 044 003
Sig3 ns ns ns ns ns ns ns ns
Inductively coupled plasma mass spectrometry
Least significant difference at P lt 005
Significance at lt 0001 () lt 001 () lt 005 () level or not significant (ns)
The use of Red Mudgypsum in vegetable production
6 RESPONSE OF CAULIFLOWERS TO RESIDUAL RED MUD (ALKALOAMreg)GYPSUM (AG) AND PHOSPHORUS ON A YELLOW KARRAKATTA SAND
Introduction
It is important to reduce the leaching of phosphorus fertiliser from sandy soils used for vegetable production into the water systems of the Swan Coastal Plain Red Mud (Alkaloam )gypsum (AG) (ie Red Mudgypsum RMG) a waste product from bauxite refining has been suggested as an amendment to reduce phosphorus leaching from sands of the Bassendean Association (Joel Gavin) used for agriculture and horticulture (Barrow 1982)
Experimental work in the field and pots showed amendment with AG significantly reduced P leaching from Joel and Gavin sands (Vlahos et al 1989 McPharlin et al 1994) compared with the unamended (01 RMGha) treatment
Previous work showed a significant reduction in maximum yield of cauliflowers with levels of residual AG of gt 60 tha compared with 01 AGha (Robertson et al 1994) This yield reduction was not due to P deficiency as increased levels of applied P did not obviate the problem Nor was it due to K deficiency as K concentrations in the youngest mature leaves (YML) although reduced by levels of residual AG did not decline to levels expected to reduce yield The converse was true for concentrations of Na in the YML which increased with levels of residual AG but not to concentrations expected to cause toxicity
Since more than 60 tha of AG may be required to significantly improve P retention by sands to enable sustainable horticultural production this yield reduction is re-examined with residual AG
Materials and methods
Site characteristics
The experiment was conducted on a yellow Karrakatta sand (McArthur and Bettenay 1960) at Medina Research Centre (32deg 13 S 115deg 49 E) 30 km south of Perth Both Alkaloamreggypsum (AG) and phosphorus had previously been applied to the site and a potato crop grown in 1995 Prior to that the site had been sown to pasture for several years Some relevant chemical characteristics of the topsoil (0-15 cm) and subsoil (15-30 cm) of the site after application of AG but prior to the application of fertiliser (except residual P) and transplanting are presented in Table 61
Red Mud (Alkaloamreg)gypsum
Alkaloamreg (Red Mud) amended with 10 (ww) gypsum (AG) was produced by the dry mix process by ALCOA of Australia Ltd at their Kwinana Residue Treatment Plant The AG had been spread manually on the site and incorporated using a rotary hoe to approximately 30 cm depth on 22 December 1994 Residual P had been applied just before planting of the previous potato crop on 17 May 1995 and incorporated with a rotary hoe The site was watered for 1 hour per day (8 mmday) using impact sprinklers until planting
Experimental design
The experimental design was a split-plot randomised block with 3 replicates The main plots were levels of AG (0 60 90 120 and 240 tha) and the sub-plots were levels of freshly-applied P (25 50 100 300 and 600 kgha) Main plots measured 7 x 12 m and sub-plots 12 x 7 m (excluding wheel tracks)
59
The use of Red Mudgypsum in vegetable production
Crop management
The site was sprayed with Roundupreg (3 Lha) twice after application of AG and prior to planting to control weeds Six week old seedlings of cauliflowers (cv Plana) obtained from a commercial nursery were transplanted manually on 18 April 1996 in 2 rows per plot with 70 cm between rows and 50 cm between plants Seedlings were dipped in Rovralreg (1 mLL) just prior to planting for control of fungi Treflanreg (14 Lha) and Dacthalreg (12 kgha) were applied immediately after transplanting to control broadleaved weeds and Sertinreg later on in the life of the crop for grass control Ambushreg (100 mLha) and Rogorreg (100 mLha) were used to control caterpillars and red legged earth-mite respectively Copper was applied for control of blackrot The crop was irrigated to a total application equivalent to 100 of the previous days pan evaporation using minisprinklers (Legoreg 6 x 6 m spacing 44 mmh) in 3 waterings of equal duration per day
Fertilisers
Pre-planting fertilisers were broadcast manually and rotary hoed on 17 April 1996
These were K2S04(244) Ca(N03)2(387) MgS047H20 (504) MnS04H20 (504) FeS047H20 (18) Borax (27) CuS045H20 (36) ZnSOH20 (28) and Na2Mo042H20 (2) P was applied as single superphosphate (91 P) at 0 to 600 kg Pha according to treatment and incorporated as before Post-planting K N and Ca were fertigated via the irrigation system as KN03 NHUNO3 and Ca (N03)2 in equal amounts per day for 12 weeks to a total of 600 kg Kha 423 kg Nha and 60 kg Caha Borax was fertigated at 20 kgha in week 3 and Mg was broadcast as MgS047H20 at 50 kgha in weeks 3 6 and 9
Measurements
Soil and soil solution
All zero P subplots were sampled 30 cores per plot just prior to planting and fertilising about 2 months after AG application to 2 depths (0-15 15-30 cm) These were oven dried at 40degC and analysed for Ec pH (CaCl2) P sorption (Ozane and Shaw 1968) bicarbonate extractable P K (Colwell 1963) total P PRI P sorption K sorption (Allen and Jeffery 1990) and cation exchange capacity (Gillman and Sumpter 1986)
The soil water was obtained by centrifugation from soil samples (0-15 cm 30 per plot) and collected from the 0 100 200 and 600 kg Pha plots across all AG treatments on the 16 May 1996 The supernatant was analysed for pH Ec Ca Mg K S and P The remaining soil was analysed for pH (H20) bicarbonate extractable P K PRI and DTPA extractable Zn After harvest 5 August 1997 soil samples were collected from 2 depths as for the preplanting treatment from all plots These were analysed for pH bicarbonate extractable P K total P PRI and exchangeable cations (Ca Mg K and N)
Plant
At buttoning on 13 June 1996 the younger mature leaves (YML) (4th from growing point) were collected from 16 plants (excluding 1 m buffer at each end of plot) in each plot They were dried at 70degC in a force draught oven for 48 h and ground to pass through a 1 mm screen Sub-samples were digested with sulphuric acidhydrogen peroxide (Yuen and Pollard 1954) and the concentration of N P and K measured by an automated colorimetric process (Varley 1966) Concentration of other nutrients (B Ca Na Mg S Fe Mn Zn and Cu) were determined by inductively coupled plasma atomic emission spectroscopy (ICP-AES) after digestion with nitric-perchloric acids (McQuaker et al 1979) Five whole plants were harvested from the middle of each plot (2 per row) at the end of the experiment on 4 July 1996 using shovels to remove as much of the roots as possible The plants were separated into four categories curds leaves stems and roots All soil was dried and digested as for ICP-AES as above and washed from the roots using tap water shaken and the excess water removed using paper towels The fresh weight of all four categories was recorded and the material was diced
60
The use of Red Mudgypsum in vegetable production
into small pieces (lt 8 cm3) using stainless steel knifes sub-samples (300 g fresh weight) were collected at random from the diced pieces and the fresh weight recorded These were dried at 70degC in a forced draught oven for 48 h and the dry weight recorded These samples were then analysed for P as for the youngest mature leaves Separate sub-samples (300 g fresh weight) of curds were collected and analysed for Ba Cd Cr Co Pb Mo Rb Sr Ti Th V and Ni using inductively coupled plasma mass spectrometry (ICP-MS) The fresh and dry weight of the curds leaves stems and roots at harvest were used to calculate P uptake in kgha)
Harvest
Harvest commenced when the leaves surrounding the head opened and exposed the curds 77-80 days after transplanting At this stage florets at the periphery of the curd had just begun to separate Sixteen curds (12 plus 4 from whole plant samples above) were collected from the central 4 m of both rows (1 m buffer) and then all the leaves and stems removed according to requirements for export market Each fresh curd was weighed and rejects recorded if undersize (lt 500 g) oversize (gt 2000 g) discoloured (yellowing) overmature (separation of florets in the centre of curd) diseased damaged or otherwise distorted The total marketable and reject yield were recorded for each plot
Analysis of data
Analysis of variance was carried out on level of applied AG or P versus (a) chemical characteristics of soil (bicarbonate extractable P total P etc) preplanting and harvest (b) concentrations of nutrients in soil solution at midgrowth (c) concentration of nutrients in YMLs at midgrowth (d) concentration of elements in curds at harvest (e) P uptake by plant parts and (f) total marketable and reject yield of curds at harvest Mitscherlich curves and inverse polynomials were fitted to the relationship between level of applied P and yield at each level of applied AG The level of applied P required for 95 99 and 100 (in case of inverse polynomials) of maximum yield was calculated Mitscherlich curves were fitted to the relationship between level of applied P and P in YMLs at midgrowth at all levels of AG The P in YMLs corresponding to the level of applied P required for 95 99 or 100 of maximum yield (as determined from yield versus applied P plots) was then determined
Mitscherlich curves were also fitted to the relationship between level of applied P and P uptake by curds leaves stems and roots and the P uptake corresponding to whole plants (additions of all 4) level of P required for 95-100 of maximum yield determined Phosphorus uptake by plant parts or whole plants on 0 P plots were deducted from P uptake at other rates to account for non-fertiliser sources of P This was used to adjust P uptake when determining P fertiliser recovery efficiency (RE) by plant parts or whole plants ie fertiliser P uptake by plant parts or whole plantsP applied both in kgha (Novoa and Loomis 1981)
The effect of residual AG andP on chemical characteristics of the soil
Increased levels of previously-applied (residual) AG resulted in a significant increase in Ec pH (CaCl2) Colwell P and PRI in the topsoil (0-15 cm) of a Karrakatta sand prior to current the application of fertilisers and planting (Table 61 Fig 61) There was no significant effect of level of residual AG on the levels of Colwell K in the topsoil Increasing levels of previously-applied (residual) P resulted in a significant increase in Colwell P and a decrease in PRI and pH at the same time but had no effect on the levels of Colwell K in the topsoil
61
The use of Red Mudgypsum in vegetable production
Table 61 Chemical characteristics of the topsoil (0-15 cm) of a yellow Karrakatta sand 12 months after application of Alkaloamreggypsum (AG) (residual AG) and phosphorus (P) just prior to fertiliser application and transplanting
AG Ec pH BicP1 BicK1 PRI2
(tha) (mSm) (CaCl2) (H8g) (Hgg) (mLg)
0 36 70 262 199 093
60 62 78 397 308 101
90 70 80 390 378 12
120 73 80 402 391 14
Lsd3 057 018 75 122 018
Sig4 ns
P (kgha)
Ec (mSm)
pH (CaCl2)
BicP1
(M-gg) BicK1
(figg) PRI2
(mLg)
0 59 78 117 323 17
25 58 78 147 338 15
50 58 78 160 322 16
100 58 78 255 327 13
300 62 76 554 309 06
600 66 75 944 296 005
Lsd3 063 01 58 60 02
Sig4 ns ns
1 After Colwell (1963) 2 After Allen and Jeffery (1990) 3 Least significant difference at P lt 005 4 Significance at lt 0001 () lt 001 () lt 005 () level or not significant (ns)
62
The use of Red Mudgypsum in vegetable production
mdash A
8 40 gt -o deggt 35 - en =gt mdash sect 30 _raquo CO
e 25 ltD O d
5 20
1 ^ I I I
T3
C
o
c CO o c o o
0 20 40 60 80 100120140
Residual AG (tha)
u u bull B
80 l
60
40
mdash n bull 20
n i i i i
I
i i i
100 200 300 400 500 600 700
Residual P (kgha)
Figure 61 (A B) Bicarbonate extractable P (bull) and K (bull) (figg dry soil after Colwell 1963) in the top soil (0-15 cm) of a yellow Karrakatta sand prior to fertilising and planting with level of residual Alkaloamreggypsum (t AGha) (A) and P (kgha) (B) Vertical bars refer to Lsd (P lt 005) for differences between levels of AG or P
5 E Q 0 -
20 40 60 80 100120 140
Residual AG (tha)
0 100 200 300 400 500 600 700
Residual P (kgha)
Figure 61 (C D) Phosphorus retention index (PRI) after Allen and Jeffery (1990) in the topsoil (0-15 cm) of a yellow Karrakatta sand prior to fertilising and planting with level of residual Alkaloamreggypsum (t AGha) (C) and P (kgha) (D) Vertical bars refer to Lsd (P lt 005) for differences between levels of AG or P
63
The use of Red Mudgypsum in vegetable production
One month after planting there was a significant increase in concentration of Ca Na and pH and a decrease in K concentration with level of residual AG in the soil solution at 15 cm depth There was no significant effect of level of residual AG on the Ec or concentration of Mg S and soluble reactive P (Psr) in the soil solution (Table 62 (a) Fig 62) There was a significant decrease in Ec pH and concentration of Mg Na and an increase in concentration of Ca S and Psr in soil solution with level of residual P
Table 62 (a) Ec (mSm) pH and concentration of nutrients (ugmL) in soil solution 1 month after planting cauliflowers with level of residual Alkaloamreggypsum (AG) and phosphorus (P)
AG
AG (tha)
Ec (mSm)
pH Ca (ngmL)
Mg (ugmL)
Na (jigmL)
K (UgmL)
S (jigmL)
Psrp1
(pgmL)
0 129 75 91 141 105 81 28 05
60 144 77 108 131 121 64 30 06
120 147 76 123 136 120 50 33 04
Lsd2 33 01 14 09 4 7 1 02
Sig3 ns ns ns ns
P
p (kgha)
Ec (mSm)
pH Ca (UgmL)
Mg (ligmL)
Na (jigmL)
K (UgmL)
S (UgmL)
Psrp1
(VigmL)
0 171 78 107 141 121 68 23 01
100 138 77 104 144 111 58 24 02
300 120 76 103 128 110 63 31 06
600 130 73 117 133 116 71 43 13
Lsd2 20 02 10 11 10 13 7 02
Sig3 ns
Soluble reactive P 2 Least significant difference at P ^ 005 3 Significance at lt 0001 () lt 001 () lt 005 () level or not significant (ns)
64
The use of Red Mudgypsum in vegetable production
3
C
o
o (gt
o in c c o
5 c CD O
o O
3
o
c o
c ltu o c o
o 0 20 40 60 80 100 120 140
Residual AG (tha)
0 100 200 300 400 500 600 700
Residual P (kgha)
Figure 62 (A B) Concentration (figmL) of Ca (bull) Mg (bull) Na (A) K (T) and S (bull) in soil solution (0-15 cm) under cauliflower one month after planting with level P residual Alkaloamreggypsum (AG) (A) and (B) Vertical bars refer to Lsd (P lt 005) for differences in concentration between levels of AG Where bars are not shown Lsd is less than size of symbol
There was a significant increase in Colwell P K and PRI in the topsoil (0-15 cm) and no change in DTPA extractable Zn with level of residual AG one month after planting (Table 62 (b)) As level of residual P increased there was a significant increase in Colwell P and decrease in PRI with no change in Colwell K or DTPA extractable Zn in the topsoil one month after planting
The use of Red Mudgypsum in vegetable production
Table 62 (b) Extractable P K Zn and phosphorus retention index of the TopsoU (0-15 cm) of a yellow Karrakatta sand 1 month after planting of cauliflowers with level of residual Alkaloamreggypsum (AG) and phosphorus (P)
AG
Ag BicP1 BicK1 Zn2 PRI3
(tha) (Pgg) (Pgg) (Pgg) (mLg)
0 27 41 25 05
60 45 43 26 03
120 50 59 23 07
Lsd4 8 6 05 01
Sig5 ns
p
p (kgha)
BicP1
(Pgg) BicK1
(Pgg)
Zn2
(l-igg) PRI3
(mLg)
0 9 46 19 12
100 21 47 22 09
300 42 46 25 03
600 90 52 31 -03
Lsd4 7 5 10 02
Sig5 ns ns
1 After Colwell (1963) 2 Extracted in DTPA 3 After Allen and Jeffery (1990) 4 Least significant difference at P ^ 005 5 Significance at lt 0001 () lt 001 () lt 005 () level or not significant (ns)
After harvest of cauliflowers there was a significant increase in Colwell P and K total P actual and predicted PRI (PRI and PRIp) with residual AG in the topsoil and subsoil of a Karrakatta sand (Table 63 (a) (b)) There was a significant increase in Colwell P and total P and decrease in Colwell K PRI and PRIp with level of residual P in both the topsoil and subsoil after harvest (Fig 63 (A B))
66
The use of Red Mudgypsum in vegetable production
Table 63 Extractable P K total P and phosphorus retention index of the topsoil (0-15 cm) and subsoil (15-30 cm) of a yellow Karrakatta sand after harvest of cauliflowers with level of residual AIkaloamreggypsum (AG) and phosphorus (P)
(a) Topsoil
AG
AG BicP1 BicK1 TotP2 PPJ3 PPJP4
(tha) (ngg) (Hgg) (Pgg) (mLg) (mLg)
0 16 28 68 10 26
60 25 42 86 15 41
90 25 46 91 16 43
120 26 54 96 18 46
Lsd5 3 9 8 005 03
Sig6
P (kgha)
BicP1
(Pgg) BicK1
(vigg) TotP2
(ngg) PPJ3
(mLg) PPJP4
(mLg)
0 7 46 58 19 27
25 8 45 63 19 28
50 9 44 64 20 30
100 15 43 72 17 33
300 37 40 103 09 48
600 63 36 152 03 67
Lsd5 3 6 8 03 05
Sig6
1 After Colwell (1963) 2 After Allen and Jeffery (1990) 3 Phosphorus retention index (Allen and Jeffery 1990) 4 Predicted phosphorus retention index (Allen and Jeffery 1990) 5 Least significant difference at P ^ 005 6 Significance at lt 0001 () lt 001 () lt 005 () level or not significant (ns)
The use of Red Mudgypsum in vegetable production
120
o lgt 100 bull gt
TJ
rn laquon D ) 3
mdash-
on
60
^^ m i _
c 40 ltigt o c o O 20
160 A (I 140
^ ^ ^ ^ 1 o (0 ^ ^ ^ ^ 1 gtraquo 120
^plusmn bull o
^ ^ ^ ^
66
100
^ 3 80
^ mdash ^ tra
tion
60
^ ^ - ^ ^ ^ cen 40
o 20 o 20
I I I I I I I
O
10
0
0 20 40 60 80 100 120 1lt
O
10
Residual AG (tha)
0 100 200 300 400 500 600 700
Residual P (kgha)
Figure 63 (A B) Bicarbonate extractable P (bull) K (bull) and total P (A) in the topsoil (0-15 cm) of a yellow Karrakatta sand after harvest of cauliflowers with level of residual AIkaloamreggypsum (t AGha) (A) and P (kgha) (B) Vertical bars refer to Lsd (P lt 005) for difference between level of AG or P Lsd not shown when less than size of symbol
68
The use of Red Mudgypsum in vegetable production
Table 63 Extractable P K total P and phosphorus retention index of the topsoil (0-15 cm) and subsoil (15-30 cm) of a yellow Karrakatta sand after harvest of cauliflowers with level of residual Alkaloamreggypsum (AG) and phosphorus (P)
(b) Subsoil
AG
AG BicP1 BicK1 TotP2 PRI3 PRJJP4
(tha) (Pgg) (ugg) (ngg) (mLg) (mLg)
0 15 23 69 08 24
60 23 31 82 12 36
90 24 37 91 14 39
120 25 40 90 17 43
Lsd5 4 6 7 01 03
Sig6
P (kgha)
BicP1
(ngg) BicK1
(ugg) TotP2
(ugg) PRI3
(mLg) PRIP4
(mLg)
0 6 36 57 18 25
25 8 36 63 17 26
50 8 34 63 17 26
100 13 31 71 15 29
300 33 29 102 08 43
600 61 30 141 03 64
Lsd5 5 5 8 02 05
Sig6
1 After Colwell (1963) 2 After Allen and Jeffery (1990) 3 Phosphorus retention index (Allen and Jeffery 1990) 4 Predicted phosphorus retention index (Allen and Jeffery 1990) 5 Least significant difference at P ^ 005 6 Significance at lt 0001 () lt 001 () lt 005 () level or not significant (ns)
The use of Red Mudgypsum in vegetable production
100
o CO
gtlaquo
C
o CO
bull-raquo
c o o o
20 40 60 80 100 120 140
Residual AG (tha) 0 100 200 300 400 500 600 700
Residual P (kgha)
Figure 63 (A B) Bicarbonate extractable P (bull) K (bull) and total P (A) in the subsoil (0-15 cm) of a yellow Karrakatta sand after harvest of cauliflowers with level of residual Alkaloamreggypsum (t AGha) (A) and P (kgha) (B) Vertical bars refer to Lsd (P lt 005) for difference between level of AG or P Lsd not shown when less than size of symbol
Ec pH (CaCl2) and exchangeable Ca and Na in the top and subsoil after harvest increased significantly with level of residual AG whilst there was no change in exchangeable Mg (Table 64 (a) (b)) Whilst there was no change in exchangeable K with level of residual AG in the topsoil there was a significant increase in exchangeable K in the subsoil (Table 64 (b))
70
The use of Red Mudgypsum in vegetable production
Table 64 Ec (mSm) pH (CaCl2) and exchangeable cations (me) in topsoil (0-15 cm) and subsoil (15-30 cm) of a yellow Karrakatta sand with level of residual AIkaloamreggypsum (AG) and phosphorus (P) after harvest of cauliflowers
(a) Topsoil (0-15 cm)
AG
AG Ec pH Ca1 Mg1 K1 Na1
(tha) (mSm) (CaCl2) (me) (me) (me) (me)
0 29 65 24 027 006 004
60 47 73 32 025 009 010
90 59 77 36 023 015 015
120 66 78 40 025 012 018
Lsd2 07 07 06 005 006 001
Sig3 as ns
P (kgha)
Ec (mSm)
PH (CaCl2)
Ca1
(me) Mg1
(me) K1
(me) Na1
(me)
0 43 73 30 025 001 011
25 46 73 33 026 010 011
50 46 73 32 025 010 011
100 52 74 32 025 010 011
300 56 74 34 024 009 011
600 58 73 37 025 014 012
Lsd2 05 05 03 002 007 -
Sig3 ns ns ns
Exchangeable in 1 m NILt-Cl 2 Least significant difference at P ^ 005 3 Significance at lt 0001 () lt 001 () lt 005 () level or not significant (ns)
The use of Red Mudgypsum in vegetable production
soil b
A soil
dry
4 _ I dry
I ^5 CD CD
b_ 3 - E c c o o CO at
i
U o CD CD
Xgt j a CO bull| mdash CO CD ogt
m- mdashM- mmdash JZ 0 - +~ -- mdash c CJ o X X LU
i 1 I i i i i LU
0 20 40 60 80 100 120 1^ W
Residual AG (tha)
100 200 300 400 500 600 700
Residual P (kgha)
Figure 64 (A B) Exchangeable Ca (bull) Mg (bull) K (A) and Na ( bull ) (me) in the topsoil (0-15 cm) of a yellow Karrakatta sand with level of residual Alkaloamreggypsum (t AGha) or P (kgha) Vertical bars refers to Lsd (P lt 005) for differences in concentration between levels of AG or P Lsd not shown when less than size of symbol
72
The use of Red Mudgypsum in vegetable production
Table 64 Ec (mSm) pH (CaCl2) and exchangeable cations (me) in topsoil (0-15 cm) and subsoil (15-30 cm) of a yellow Karrakatta sand with level of residual AlkaIoamreggypsum (AG) and phosphorus (P) after harvest of cauliflowers
(b) Subsoil (15-30 cm)
AG
AG Ec pH Ca1 Mg1 K1 Na1
(tha) (mSm) (CaCl2) (me) (me) (me) (me)
0 34 66 24 026 006 005
60 50 75 33 024 008 010
90 64 78 38 023 01 016
120 68 79 41 024 01 019
Lsd2 05 01 07 006 001 003
Sig3 ns
P (kgha)
Ec (mSm)
pH (CaCl2)
Ca1
(me) Mg1
(me) K1
(me) Na1
(me)
0 48 75 30 023 009 011
25 51 74 33 026 009 011
50 50 75 34 025 008 013
100 61 75 35 026 008 013
300 57 75 34 022 007 013
600 58 73 38 024 008 013
Lsd2 08 01 04 003 001 003
Sig3 ns
1 Exchangeable in 1 m NH4-CI 2 Least significant difference at P ^ 005 3 Significance at lt 0001 () lt 001 () lt 005 () level or not significant (ns)
The use of Red Mudgypsum in vegetable production
o 0 oi
4 CO c CO
gt T3 4 _ bull o
0s -5 3 agt CD
fc_ 3 - g
on
o 2 CO 2 CO
u 2
o CD CD 1 X I SI
1 CD 1 CD CD CU
O
n ^ 1 CO n X bull mdashXmdash mdash 1 1 CO U J= n bull - w 1 CO U
o o X X Lil
i i 1 1 i i 1 HI
0 20 40 60 80 100 120 140
Residual AG (tha)
100 200 300 400 500 600 700
Residual P (kgha)
Figure 64 (C D) Exchangeable Ca (bull) Mg (bull) K (A) and Na (T) (me) in the subsoil (0-15 cm) of a yellow Karrakatta sand with level of residual Alkaloamreggypsum (t AGha) or P (kgha) Vertical bars refers to Lsd (P lt 005) for differences in concentration between levels of AG or P Lsd not shown when less than size of symbol
As level of residual P increased there was a significant increase in exchangeable Ca in the tbpsoil and subsoil but no significant effect on exchangeable Mg K and Na in the topsoil and variable effects on exchangeable Mg and K in the subsoil Ec increased significantly with level of residual P in both the top and subsoil whilst pH in either was effected little by level of applied P
The effect of level of residual AG andP on the concentration of nutrients in cauliflower leaves
The level of residual AG had no effect on the concentrations of N Ca S P S Mg Fe Zn Mn B and Cu in the youngest mature leaves of cauliflowers at buttoning but increased levels significantly reduced the concentration of K (Fig 65 (A B)) As level of residual P increased there was a significant increase in the concentration of K P S Cu and Mn in the YMLs whilst concentrations of N decreased and B concentrations were variable with no clear trends
74
The use of Red Mudgypsum in vegetable production
Table 65 Concentration of nutrients (dry weight basis) in youngest mature leaves of cauliflowers at buttoning with level of applied residual Alkaloamreggypsum (AG) and phosphorus (P)
(a) Macronutrients
AG
AG N1 K1 Ca2 S2 P1 Na2 Mg2
(tha) () () () () () () ()
0 49 42 23 077 040 039 027
60 51 40 23 078 042 036 025
90 51 39 23 079 043 036 025
120 49 39 24 078 042 036 025
Lsd3 03 02 08 009 007 010 004
Sig4 ns ns ns ns ns ns
P N1 K1 Ca2 S2 P1 Na2 Mg2
(kgha) () () () () () () ()
0 53 36 22 069 027 033 024
25 51 38 24 071 030 038 026
50 52 40 24 075 034 040 027
100 51 41 24 079 043 041 027
300 48 43 24 087 055 039 026
600 47 42 20 086 060 031 023
Lsd3 02 02 04 003 004 006 003
Sig4 ns ns
1 After Varley (1966) 2 After McQuakerefl (1979) 3 Least significant difference at P lt 005 4 Significance at lt 0001 () lt 001 () lt 005 () level or not significant (ns)
The use of Red Mudgypsum in vegetable production
Table 65 Concentration of nutrients (dry weight basis) in youngest mature leaves of cauliflowers at buttoning with level of applied residual AlkaIoamreggypsum (AG) and phosphorus (P)
(b) Micronutrients
AG
AG (tha)
Fe (ugg)
Zn1
(Pgg) Mn1
(ugg) B1
(ugg) Cu1
(ugg)
0 122 31 19 21 28
60 121 32 22 22 30
90 119 36 25 22 32
120 120 29 23 22 29
Lsd2 21 8 6 1 05
sig3 ns ns ns ns ns
P (kgha)
Fe1
(Pgg)
Zn1
(ugg) Mn1
Gigg)
B1
(Fgg)
Cu1
(Pgg)
0 112 33 19 22 28
25 120 32 22 22 29
50 125 32 21 23 29
100 132 38 24 23 31
300 129 30 25 22 32
600 106 29 23 21 32
Lsd2 19 6 3 1 03
Sig-3 ns ns
After McQuaker et al (1979) 2 Least significant difference at P ^ 005 3 Significance at lt 0001 () lt 001 () lt 005 () level or not significant (ns)
The relationship between residual P ie Colwell P and P in YMLs at buttoning were best described by Mitscherlich relationships at all levels of residual AG (Fig 65)
The concentration of P in YMLs corresponding to levels of Colwell P necessary for 95 of maximum yield were 047 050 054 and 048 and for 99 of maximum yield were 053 055 058 and 054 for 0 60 90 and 1201 residual AGha respectively
76
The use of Red Mudgypsum in vegetable production
Q
en
3
gt-c 0
07
06
05
04
03
02
01 0
065
060
055
050
045
040
035
030
025
020
A
if 20 40 60 80 100
Colwell P (ugg dry soil)
_ 065
Q S 055
060
tz
ro _ i
gt
120
C bull - - - mdash bull
20 40 60 80 100
Colwell P (ugg dry soil)
120
050
045
040
035
030
025
020
065
060
055
050
045
040
035
030
025
020
-B
bull
- bull I
I I
bull
i i i
20 40 60 80 100
Colwell P (ugg dry soil)
120
-bull D
I I i i i
20 40 60 80 100
Colwell P (ugg dry soil)
120
Figure 65 P in youngest mature leaves at buttoning () corresponding to Colwell P necessary for 95 (dashed) or 99 (whole) of maximum yield at 0 (A) 60 (B) 90 (C) and 120 (D) t of residual Alkaloamreggypsumha Dashed and whole horizontal lines refers to P in YML corresponding to Colwell P required for 95 and 99 of maximum yield respectively
The equations for the fitted lines are
A y = 05964 - 0763 x exp (-0068) (B2 = 089)
B y = 05855 - 05144 x exp (-00465x) (R2 = 098)
C y = 006058 - 0549 x exp (-00435x) (B2 = 096)
D y = 06399 - 05208 x exp (-00291) (R2 = 097)
77
The use of Red Mudgypsum in vegetable production
The effect of level of residual AG andP on the yield of cauliflowers
There was no significant effect of levels of residual AG on the total or marketable yield of cauliflowers However yield responded significantly to levels of applied residual P and the interaction between residual P and AG was significant (Tables 66 (a) (b))
The relationship between Colwell P and total yield was best described by Mitscherlich relationships for all levels of residual AG (Fig 66) The Colwell P required for 95 of maximum total yield was 26 40 48 and 40 ugg dry soil and for 99 35 55 71 and 58 ugg dry soil for 0 60 90 and 1201 residual AGha respectively
Table 66 Curd yield (total and marketable) of cauliflowers (tha) at harvest with level of residual Alkaloamreggypsum (AG) and phosphorus (P)
(a) Total
AG p
(kgha) (tha) p
(kgha)
0 60 90 120
0 59 64 69 100
25 134 126 123 83
50 139 133 117 143
100 163 200 164 177
300 203 236 198 204
600 215 237 208 194
Ls-d1 36 (AG) 17 (P) 48(AGP) -
Sig2 ns
(b) Marketable
p (kgha)
AG (tha) p
(kgha)
0 60 90 120
0 14 14 18 56
25 83 74 84 13
50 90 99 67 99
100 138 188 125 160
300 187 232 182 190
600 206 234 191 185
Lsd1
Sig2
48 (AG)
ns 23 (P)
62(AGP)
-
Least significant difference at P lt 005 2 Significance at lt 0001 () lt 001 () lt 005 () level or not significant (ns)
The use of Red Mudgypsum in vegetable production
0 20 40 60 80 100120140160
Colwell P (ugg dry soil)
0 20 40 60 80 100120140160
Colwell P (ugg dry soil)
lt x
UJ gt-Q
o
lt X
Q _ l UJ gt-Q rr D O
24
22
20
18
16 14
12
10
8
6
4
-D
bull
I I
I I
I I
I
^~ bull
i i i i i
20 40 60 80 100120140160
Colwell P (ugg dry soil)
20 40 60 80 100120140160
Colwell P (ugg dry soil)
Figure 66 Colwell P in topsoil (0-15 cm) at planting versus yield of cauliflowers at 0 (A) 60 (B) 90 (C) and 120 (D) tha of residual Alkaloamreggypsum (AG) Dashed and whole vertical lines represent Colwell P required for 95 and 99 of maximum yield respectively
The equations for the fitted lines are
A y = 2088 - 818 x exp (-017x) (i2 = 089)
B y = 23731 - 4578 x exp (-00949) (i2 = 099)
C y = 2051 - 286 x exp (-00697) (R2 = 086)
D y = 2002 - 354 x exp (-0090) (B2 = 086)
79
The use of Red Mudgypsum in vegetable production
Discussion
There was no significant reduction in maximum yield (ie A values) of cauliflower (cv Plana) curds grown on Karrakatta sands amended with residual AG from 0 to 120 tha in this work This is in contrast to previous work (Robertson et al 1994) in which maximum curd yields of cauliflowers were significantly reduced with levels of residual AG at 120 tha compared with 0 and 60 tha In both studies concentrations of K were reduced and concentrations of Na were increased in the YML at buttoning with increasing levels of residual AG The increase in concentration of Na and the decrease in concentration of K in the YML with level of applied AG was related to similar changes in the concentrations of these elements in the soil solution with both freshly-applied (Section 5) and residual AG one month after planting As with freshly-applied AG increasing levels of residual AG resulted in increasing levels of Na in the soil (exchangeable) or soil solution however whilst K concentrations in soil solution decreased the K retained by the soil measured as either Colwell K or exchangeable K increased Increasing levels of residual AG resulted in increased pH in the topsoil as with fresh AG but this did not reduce the concentration of Mn Cu and Zn in the YML or increase the concentration of Mo These changes would be expected with increases in soil pH (Porter 1984) The level of Colwell P required for 95 to 99 of maximum yield increased from 26 and 35 ugg dry soil at 01 AGha to 48 and 71 ugg at 901 of residual AGha The level at 1201 AGha was slightly lower ie 40 and 58 ugg These levels are similar to those reported as necessary for 95 and 99 of maximum yield of Arfak cauliflowers 40 and 55 ugg Colwell P in planted in autumn and spring on unamended Karrakatta sands (McPharlin et al 1995) It therefore does not appear that AG amendment increases the residual P as measured by Colwell P requirement of cauliflower significantly This is in contrast to the significantly higher level of applied P necessary to maximise yield when AG is freshly-applied ie from 120-160 to gt 300 kg of Pha at 0 and 1201 AGha respectively (Robertson et al 1994 and Section 5) However requirements of residual (Colwell) P and freshly-applied P are not always correlated For example the Colwell P necessary for the maximum yield of spring and winter-planted lettuce was similar ie 80 to 120 ugg dry soil whereas the level of freshly-applied P required for maximum yield of winter-planted lettuce was 50 higher than in spring (McPharlin et al 1996 McPharlin and Robertson 1997)
References
Allen DG and Jeffery RC (1990) Methods for analysis of phosphorus in Western Australian soils Chemistry Centre of Western Australia Report of Investigation No 37
Barrow NJ (1982) Possibility of using caustic residue from bauxite for improving the chemical and physical properties of sandy soils Australian Journal of Experimental Agriculture Research 33 275-285
Colwell JD (1963) The estimation of phosphorus fertiliser requirements of wheat in southern New South Wales by soil analysis Australian Journal of Experimental Agriculture Animal Husbandry 3 190-197
Gillman GP and Sumpter EA (1986) Modification to the compulsive exchange method for measuring exchange characteristics of soils Australian Journal of Soil Research 24 616
McArthur WM and Bettenay E (1960) The development and distribution of the soils of the Swan Coastal Plain Western Australia CSIRO Division of Soils Soils Publication No 16
McPharlin IR Jeffery RC and Pitman DH (1996) Phosphorus requirements of winter planted lettuce (Lactuca sativa L) on a Karrakatta sand and the residual value of phosphate as determined by soil test Australian Journal Experimental Agriculture 36 887-903
80
The use of Red Mudgypsum in vegetable production
McPharlin IR Jeffery RC and Weissberg R (1994) Determination of the residual value of phosphate and soil test phosphorus calibration for carrots on a Karrakatta sand Communications in Soil Science Plant Analysis 25 (5-6) 489-500
McPharlin IR and Robertson WJ (1997) Response of spring-planted lettuce (Lactuca sativa L) to freshly-applied and residual phosphorus and to phosphate fertiliser placement on a Karrakatta sand Australian Journal of Experimental Agriculture (in press)
McPharlin IR Robertson WJ Jeffery RC and Weissberg R (1995) Response of cauliflower to phosphate fertiliser placement and soil test phosphorus calibration on a Karrakatta sand Communications in Soil Science and Plant Analysis 26(3-4) 607-620
McQuaker NR Brown DF and Kluckner PD (1979) Digestion of environmental materials for analysis by inductively coupled plasma-atomic emission spectrometry Analytical Chemistry 51 1082-1084
Novoa R and Loomis RS (1981) Nitrogen and plant production Plant and soil 58 177-204
Ozanne PG and Shaw TC (1968) Advantages of recently developed phosphate sorption test over the older extractant methods for soil phosphate (ed JW Holmes) pp 273-280 In Transactions of the 9th International Congress of Soil Science Volume 2 Angus and Robertson Sydney Australia
Porter WM (1984) Soil acidity Agriculture Western Australia Farmnote No 6884
Robertson WJ McPharlin IR and Jeffery RC (14) Final report of investigation into the use of gypsum-amended Red Mud as a soil-amendment on horticultural properties on the Swan Coastal Plain Report to HRDC (Project No V0039RO) Department of Agriculture Western Australia
Varley J A 1966 Automatic methods for the determination of nitrogen phosphorus and potassium in plant material Analyst 91 119-126
Vlahos S Summers KJ Bell DT and Gilkes RJ (1989) Reducing phosphorus leaching from sandy soils with Red Mud bauxite processing residues Australian Journal of Soil Research 27 651-662
Yuen SH and Pollard AG (1954) Determination of nitrogen in agricultural material by the Nessler reagent IL Microdetermination in plant tissue and soil extracts Journal of Science Food Agriculture 5 364-369
The use of Red Mudgypsum in vegetable production
7 RETENTION LEACHING AND RECOVERY OF P AND OTHER NUTRIENTS BY CARROTS GROWN ON A JOEL SAND AMENDED WITH RESIDUAL RED MUD (ALKALOAMreg)GYPSUM (AG) IN LARGE POTS
Introduction
It is difficult to quantify the retention of P by sands amended with Red Mud (Alkaloamreg)gypsum (AG) in the field because of native P in the soil and soluble P in the AG (Robertson et al 1994) It is easy to quantify leaching of P and other nutrients such as N and K from AG amended sands in pots or columns by collecting leachate and measuring concentration (McPharlin et al 1995) However plants were not grown in the columns used by McPharlin et al so there was no measurement of plant uptake of P and other nutrients to complete the nutrient budget Potatoes were grown successfully in Spearwood sands in large pots (70 L) and a complete N budget (N applied N retained by soil N leached and uptake by plant) determined (Hegney et al 1996)
Freshly-applied AG may not be in equilibrium with the soil to which it is applied ie the pH Ec and concentrations of elements such as Ca and Na may change rapidly with time The age of the AG may effect its capacity to retain P on amended soils AG may improve the retention of other nutrients such as ammonium N (McPharlin et al 1995) and K (Sections 5 and 6) by amended sands AG which has been applied to sands in the field for at least 2 to 5 years should be close to equilibrium with the soil as substantial leaching would have occurred AG of this age would give the best estimate of its long term capacity to reduce leaching of P and other nutrients from poor grey sands on the Swan Coastal Plain The purpose of this work was to quantify the leaching and retention of P and other nutrients (N Ca K etc) from Joel sands which had been amended with AG at different levels in the field for 14 years Carrots a major vegetable crop grown on the Swan Coastal Plain were used as the experimental crop and grown in these AG amended sands in large pots
Materials and methods
Pots
Fibreglass pots used for the experiment were 45 cm in diameter and 50 cm deep The area of soil surface was 016 m2 and the volume was 70 L The bottom of the pots tapered to a hole (diameter) to which was attached a polyethylene hose (length and diameter) and tap The pots were painted white to reduce heat The pots were placed on a metal table (with mesh tops) and the hose passed through a hole in the centre of a lid of a plastic (20 L) bucket
Experimental design
The experimental design was a 4 (levels of residual AG ie 0 125 250 and 1000 tha) times 5 (levels of applied P ie 0 50 100 200 and 400 kgha) factorial in a randomised block with 3 replicates The level of applied AG or Pha was calculated using the area of the soil surface The total number of pots was 60
Soil and Red Mud (Alkaloamreg)gypsum (AG)
Virgin Joel sand was obtained from a commercial garden supply site in Jandakot The top 20 cm of the soil was removed and the rest sieved (15 mm) to remove debris About 20 kg of Joel sand was added to each pot (10 cm depth) Another 60 kg (30 cm depth) of sand was added to the 0 AGha pots to which had been mixed lime and preplant fertilisers (see later) so the surface of the soil was about 10 cm below the top edge of the pot AG amended sand was obtained from a field site in Hope Valley Road Kwinana managed by ALCOA where it had been applied (and incorporated using a rotary hoe) to pastures growing on a Joel sand in 1983 at 0 250 500 and 1000 tha This AG amended sand was added to pots corresponding to 250 and 1000 tha in the field after the preplant fertiliser but not lime was added and was incorporated to a similar depth as in the 01 AGha pots The 125 t AGha treatment was
82
The use of Red Mudgypsum in vegetable production
obtained by mixing AG amended sand from the 250 tha field site with an equal weight of Joel sand in a cement mixer
Fertilisers and lime
The following fertilisers (in kgha) were thoroughly mixed (using a cement mixer) with the top 25-30 cm of the soil in each pot before planting Urea (108) K2SO4Q2I) MgS047H20 (100) MnS04H20 (100) Na2B4O710 H20 (50) FeS047H20 (50) CuS045H20 (50) ZnS04H20 (50) and NaMo042H20 (4) To this was added P at 0 50 100 200 and 400 kgha as single superphosphate at each level of residual AG Hydrated lime (Ca (OH)2) was mixed with the preplanting fertilisers on the 0 kg AGha treatment at 36 gpot
N K and Ca were fertigated via the drip irrigation system at 200 200 and 52 mgL using KNO3 NH4NO3 and Ca (N03)2 from immediately after sowing to 140 days after sowing (18 August 1996) MgS047H20 was broadcast at 100 kgha to each pot at weeks 6 and 12
Irrigation
The plants were irrigated using drippers (Netafim 2 Lh pressure compensated with 4 equalisers per pot) at 15 times the average monthly pan evaporation until 160 days after sowing (7 September 1996) Adjustments were made on a daily basis if evaporation was significantly higher or lower than the long term average (Table 71)
Table 71 Irrigation requirements of carrots in pot experiments
Month DAS Lpotday Minutesday
April 1- 27 10 33
May 28- 59 065 21
June 60- 90 044 14
July 91-122 044 14
August 123-154 056 19
September 155-160
Adjusted for 90 efficiency of irrigation system
Rain was excluded from the pots using a movable rain out shelter made of perspex and aluminium This was removed at all other times
Crop management
The soil in each pot was irrigated to field capacity ie so that free drainage occurred Carrot (cv Top Pak) seeds were sown on a 9 x 9 cm spacing and 1 cm deep with 5 seeds per site on 3 April 1996 These were thinned to 14 seedlingspot (88 plantsm2) after emergence (15 April 1996) No application of fungicides or insecticides were necessary
Soil and plant measurements
Soil
Immediately before fertilising and sowing 5 cores (22 diameter x 15 cm deep) were taken from each pot and dried in a force draught oven at 40degC Each sample was analysed for extractable P and K (Colwell 1963) pH (CaCl2 and H20) total P (Allen and Jeffery 1990) PRI (Allen and Jeffery 1990) total N extractable ammonium N (KC1) extractable nitrate N (KC1) organic carbon cation exchange capacity and exchangeable cations
83
The use of Red Mudgypsum in vegetable production
Leachate
Leachate from each pot was collected in 20 L plastic buckets under the pots each week from the 4 April 1996 to 22 July 1996 PMA (phenyl mercuric acetate) was added to the leachate to prevent contamination Total water volume was measured and sub-samples (200 mL) collected and submitted for analysis of P NH4-N NO3-N K Na Ca S Mg Ec and pH analysis of concentration The quantities leached of the above elements in kgha were calculated from concentration and volume of leachate collected and surface area of soil in pot
Harvest
The plants were harvested on 7 September 1997 and the total marketable and reject root yield determined for each plot
Analysis of data
Analysis of variance (Genstattrade for Windows version 32) was carried out on level of AG and P versus yield (total marketable reject) level of chemical factors in soil after harvest concentration of nutrients in youngest mature leaves at midgrowth tops and roots at harvest and leachate on 22 April 1996 5 May 1996 and 22 July 1996 and quantities of elements leached at each sampling time
Mitscherlich or linear relationships were fitted to level of P versus yield (total) at each level of residual AG P required for 95 and 99 of maximum yield was delivered at each level of residual AG P uptake by carrots was determined from the dry weight and P in tops and roots for each treatment Fertiliser P uptake was determined by deducting uptake on 0 kg Pha treatments at each level of applied AG Fertiliser P retained in the top-soil was determined from the concentration of total P and bulk density P leached was fertiliser leached below 15 cm The P in each plant fraction soil and leached was determine at each level of applied P and AG
Results
Effect of level of residual AG on chemical characteristics of Joel sand
Soil pH (CaCl2 H20) Ec Colwell P phosphorus retention index cation exchange capacity exchangeable Ca and Na and silt and clay all increased with level of residual AG in the top soil (0-15 cm) of a Joel sand before fertilising and sowing (Table 72)
The use of Red Mudgypsum in vegetable production
Table 72 Chemical and physical characteristics of Joel sand amended with residual Alkaloam gypsum (AG) in pots before fertilising and sowing of carrots
Level of residual AG
Parameter (tha)
Parameter
0 125 250 1000
pH (H20) 69 77 85 86
pH (CaCl2) 57 71 78 78
Ec (mSm) 4 9 9 11
Ext P (ngg)1 3 9 14 9
PRI2 -02 33 44 77
Total N ()3 - 0039 0044 0060
ExtNH4-N(ngg)4 - 2 2 2
ExtN03-N(ugg)5 - 3 2 5
CEC ()6 30 30 43 35
Exch Ca ()7 133 363 51 70
Exch Mg ()7 036 024 015 021
Exch Na ()7 005 015 015 032
Exch K ()7 007 004 0035 0035
OrgC()8 131 109 092 103
Sand () 977 967 960 910
Silt () 13 15 15 37
Clay () 10 23 25 53
1 Colwell (1963) 2 Phosphorus retention index (Allen and Jeffery 1990) 3 KjeldahlReardon et al 1966 4 Extracted in 1 m KC1 (Reardon et al 1966) 5 Extracted in 1 m KC1 (Best 1976) 6 Gillman and Sumpter (1986) 7 Exchangeable in 1 m NHU-Cl 8 Walkley and Black (1934)
Level of residual AG had no effect on levels of extractable NH4-N NO3-N exchangeable Mg and K or organic carbon After harvest levels of Colwell P K total P PRI Ec pH (CaCk) exchangeable Ca Mg K and Na in the topsoil (0-15 cm) all increase significantly (P lt 005) with level of residual AG (Tables 73 74)
85
The use of Red Mudgypsum in vegetable production
Table 73 Extractable P K NH4 total P (tot P) and phosphorus retention index (PRI) of the topsoil (0-15 cm) of a Joel sand after harvest of carrots with level of residual Alkaloamreggypsum (AG) and phosphorus (P)
AG
AG BicP1 BicK tot P2 PRI3 NIL (tha) (ngg) (Hgg) (ngg) (mLg) (Mfig)
0 33 119 234 -015 137
125 200 117 743 141 27
250 275 197 1258 231 19
1000 204 420 1853 154 30
Lsd5 4 34 129 45 26
Sig6
P
P (kgha)
BicP1
(ngg) BicK1
(Mgfe) totP2
(ugg) PRI3
(mLg) NIL
(ngg)
0 91 215 896 198 58
50 151 223 937 138 54
100 144 226 1005 126 62
200 182 193 1043 128 42
400 323 210 1231 116 52
Lsd5 48 39 144 50 29
Sig6 s | e ns ns
1 Colwell 1963 2 Allen and Jeffery 1990 3 Phosphorus retention index (Allen and Jeffery 1990) 4 Extracted in 1 m KC1 (Best 1976) 5 Least significant difference at P s 005 6 Significance at lt 0001 () lt 001 () lt 005 () level or not significant (ns)
By contrast levels of extractable NH4-N decreased significantly with level of residual AG Colwell P total P Colwell K all increased significantly (P lt 005) with level of applied P whilst PRI was decreased significantly Level of applied P had no significant effect on Ec pH or level of exchangeable Ca Mg K Na Colwell K or extractable NHu-N in the topsoil after harvest (Tables 73 74)
The use of Red Mudgypsum in vegetable production
Table 74 Ec (mSm) pH (CaCl2) and exchangeable cations (me) in topsoil (0-15 cm) of a Joel sand after harvest of carrots with level of residual Alkaloamreggypsum (AG) and phosphorus (P)
AG
AG Ec pH Ca1 Mg1 K1 Na1
(tha) (mSm) (CaCl2) (me) (me) (me) (me)
0 157 44 18 016 026 010
125 147 54 23 014 026 015
250 217 66 40 017 041 027
1000 308 76 135 027 096 094
Lsd2 32 01 07 002 005 005
sig3
p
p (kgha)
Ec (mSm)
pH (CaCl2)
Ca1
(me) Mg1
(me) K1
(me) Na1
(me)
0 202 59 52 019 048 035
50 195 60 53 018 050 036
100 203 60 57 019 048 039
200 202 60 57 018 045 040
400 236 59 51 017 046 034
Lsd2 35 01 08 002 006 005
Sig3 ns ns ns ns ns ns
Exchangeable in 1 m NH4CI 2 Least significant difference at P s 005 3 Significance at lt 0001 () lt 001 () lt 005 () level or not significant (ns)
Effect of level of residual AG and P on concentration of nutrients in leachate and quantities of nutrients leached
There was a significant (P lt 005) reduction in concentration of P in leachate with level of residual AG at three times of sampling (Fig 71) P concentration in leachate increased significantly with level of applied P at 01 AGha but not in presence of AG
P concentration in leachate at 01 AGha decreased with time from 80 mgL on 16 April 1996 at 400 kg Pha to 025 mgL on 22 July 1996 To reduce P concentration in leachate 125 t AGha was as effective as 250 or 1000 tha at all sampling times and levels of applied P Similar trends were shown in quantity of leached P as total or soluble reactive P in kgha (Appendix 71 (b) 72) Level of applied AG significantly (P lt 005) reduced the concentration of NH4-N in leachate from 40 mgL at 01 AGha to 15 mgL at 250 and 1000 tha (Fig 72 (a)) on 16 April 1996 Significant reductions in concentration were recorded on the other two sampling times as NH4-N concentration declined with increased plant uptake Similar trends were shown in the quantity of NH4-N leached with level of AG (Appendix 72 (b)) By contrast level of applied AG had no significant effect on concentration of NO3-N in leachate or quantity leached at any of the three sampling times (Fig 72 (b) and Appendix 73 (b)) There was a significant (P lt 005) reduction in concentration of K in leachate and quantity of K leached with level of residual AG although the reduction was less at the later sampling times (Fig 73 Appendix 73 (a)) Concentration of K in leachate increased
87
The use of Red Mudgypsum in vegetable production
with time at all levels of residual AG except 1000 tha By contrast both the concentration of Na in leachate and quantity of Na increased with level of residual AG to a maximum at the highest level (1000 tha) There was a reduction in Na concentration in leachate with time at level of residual AG lt 1000 tha The concentration of Ca in leachate increased significantly (P lt 005) as did quantity leached with level of residual AG and with time at all levels of AG (Fig 74 Appendix 74 (a)) By contrast concentration of Mg in leachate and quantity leached decreased significantly (P lt 005) with level of residual AG and with time at all levels of AG (Fig 78 and Appendix 78 (a)) There was a significant (P lt 005) increase in S concentration in leachate and quantity leached with level of residual AG at the first sampling time a decrease at the second and a increase up to 250 tha at the third sampling (Fig 79 Appendix 79 (a)) S concentration in leachate and quantity leached varied significantly with level of applied P at all sampling times and decreased with time from 16 April 1996 to 22 July 1996 (Fig 79 and Appendix 79 (a))
The use of Red Mudgypsum in vegetable production
deg E
c o
o O
c ltD
O
c o
I O
1 0 0 2 0 0 3 0 0 4 0 0
A p p l i e d P ( k g h a )
5 0 0
1 0 0 2 0 0
A p p l ie d P
3 0 0
k g h a )
4 0 0 5 0 0
1 0 0 2 0 0 3 0 0
A p p l i e d P ( k g h a
4 0 0 5 0 0
Figure 71 Concentration of P (mgL of total P) in leachate from Joel sands sown to carrots with level of applied P and Alkaloamreggypsum (AG) at 0 (bull) 125 (bull) 250 (A) and 1000 (T) tha on 16 April 1996 (A) 6 May 1996 (B) and 22 July 1996 (C) P was applied preplanting as superphosphate and carrots were sown on 3 April 1996 Vertical bars refer to Lsd (P lt 005) for differences in concentration between level of AG (at each level of P) or P (at each level of AG) or the interaction between AG and P Where bars arent shown Lsd is less than size of symbol
89
The use of Red Mudgypsum in vegetable production
2 0 0 4 0 0 6 0 0 8 0 0 1 0 0 0 1 2 0 0
L e v e l o f r e s i d u a A G ( t ha )
2 0 0 4 0 0 6 0 0 8 0 0 1 0 0 0 1 2 0 0
L e v e l o f r e s i d u a l A G ( t h a )
Figure 72 Concentration (mgL) of NBU-N (A) and NO3-N (B) in leachate from Joel sand sown to carrots amended with residual AlkaIoamreggypsum (AG) in pots on 16 April 1996 (bull) 6 May 1996 (bull) and 22 July 1996 (A) The carrots were sown on 3 April 1996 N was fertigated at a constant concentration of 300 mgL (250 mgL of NO3-N and 50 mgL NH4-N) from sowing to harvest Vertical bars refer to Lsd (P lt 005) for differences in concentration between level of AG at each sampling time Where bars arent shown Lsd is less than size of symbol
The use of Red Mudgypsum in vegetable production
200 400 600 800 1000 1200
Level of AG (tha)
200 400 600 800
Level of AG (tha)
1 0 0 0 1 2 0 0
Figure 73 Concentration (mgL) of K (A) and Na (B) in leachate from Joel sand sown to carrots amended with residual Alkaloamreggypsum (AG) in pots on 16 April 1996 (bull) 6 May 1996 (bull) and 22 July 1996 (A) The carrots were sown on 3 April 1996 K was fertigated at a constant concentration of 200 mgL from sowing to harvest Vertical bars refer to Lsd (P lt 005) for differences in concentration between level of AG at each time Where bars arent shown Lsd is less than size of symbol
91
The use of Red Mudgypsum in vegetable production
Effect of level of residual AG and P on concentration of nutrients in plants The concentration of K P Fe Cu Mn and Mo in the youngest mature leaves (YML) of carrots at midgrowth all increased significantly with level of residual AG (Tables 75 (a) (b)) The concentration of S in YML at midgrowth was significantly reduced as level of residual AG increased whilst concentrations of Ca Na Mg Zn and B were variable
Table 75 Concentration of nutrients ( dry basis) in youngest mature leaves of carrot at midgrowth with level of residual Alkaloamreggypsum (AG) and phosphorus (P)
(a) Macronutrients
AG
AG (tha)
K1 Ca2 S2 P1 Na2 Mg2
0 486 229 061 025 050 039
125 584 186 060 033 047 034
250 585 216 058 033 044 035
1000 531 215 056 031 052 037
Lsd3 03 02 004 0017 005 003
Sig4
p
P (kgha)
K1 Ca2 S2 P1 Na2 Mg2
0 538 198 062 029 037 036
50 523 222 061 028 043 037
100 562 208 056 030 049 035
200 548 216 057 032 058 037
400 563 214 056 035 054 036
Lsd3 033 022 004 002 006 003
Sig4 ns ns ns
1 After Varley (1966) 2 After McQuaker et al (1979) 3 Least significant difference at P s 005 4 Significance at lt 0001 () lt 001 () lt 005 () level or not significant (ns)
The use of Red Mudgypsum in vegetable production
Table 75 Concentration of nutrients ( dry basis) in youngest mature leaves of carrot at midgrowth with level of residual Alkaloam gypsum (AG) and phosphorus (P)
(b) Micronutrients
AG
AG (tha)
Fe Mn1 Zn B Cu Mo
0 111 386 280 345 95 21
125 127 279 367 348 107 25
250 126 173 269 349 108 24
1000 114 60 143 337 110 31
Lsd2 20 47 40 15 05 06
Sig3 ns ns
p
p (kgha) Fe Mn Zn B Cu Mo1
0 135 243 263 356 120 28
50 122 240 268 349 111 30
100 109 191 229 343 106 25
200 116 228 268 334 99 23
400 115 221 294 341 89 20
Lsd2 23 52 45 15 051 07
Sig3 ns ns ns ns
1 After McQuaker et al (1979) 2 Least significant difference at P s 005 3 Significance at lt 0001 () lt 001 () lt 005 () level or not significant (ns)
Concentration of P S and Na in YML increased significantly (P lt 005) with level of applied P whilst concentrations of Cu and Mo decreased (Tables 75 (a) (b)) By contrast concentrations of K Ca Mg Fe Mn Zn and B were not significantly changed by level of applied P
93
The use of Red Mudgypsum in vegetable production
At harvest the concentration of P N K and Fe in whole tops increased significantly (P lt 005) with level of residual AG whilst concentration of S Mn Zn and B decreased (Table 76) The concentrations of Ca Na and Mg were variable with level of residual AG whilst there was no significant effect on the concentration of Cu
Table 76 Concentration of nutrients ( dry basis) in whole carrot tops at harvest with level of residual Alkaloamreggypsum (AG) and phosphorus (P)
(a) Macronutrients
AG
AG (tha)
N1 K1 Ca2 S2 P1 Na2 Mg2
0 300 503 269 071 016 093 039
125 348 649 239 065 024 090 035
250 395 653 251 061 022 082 033
1000 351 566 262 066 024 099 037
Lsd3 010 036 011 002 001 009 002
Sig4
p
p (kgha)
N1 K1 Ca2 S2 P1 Na2 Mg2
0 355 589 240 073 019 074 035
50 343 597 258 068 020 082 036
100 339 587 257 068 021 098 038
200 339 580 259 063 022 108 037
400 332 608 263 057 024 095 036
Lsd3 011 041 012 002 001 010 002
Sig4 ns
1 After Varley (1966) 2 After McQuakere al (1979) 3 Least significant difference at P s 005 4 Significance at lt 0001 () lt 001 () lt 005 () level or not significant (ns)
The use of Red Mudgypsum in vegetable production
Table 76 Concentration of nutrients ( dry basis) in whole carrot tops at harvest with level of residual Alkaloamreggypsum (AG) and phosphorus (P)
(b) Micronutrients
AG
AG (tha)
Fe1 Mn1 Zn1 B1 Cu1
0 299 962 234 402 109
125 316 952 184 404 107
250 331 662 110 380 110
1000 374 673 77 383 115
Lsd2 90 106 20 002 05
Sig3 ns ns
p
p (kgha) Fe1 Mn1 Zn1 B1 Cu1
0 294 969 158 409 125
50 392 837 144 393 117
100 364 747 141 396 114
200 267 712 159 387 105
400 332 bull 796 154 377 89
Lsd2 101 118 23 13 05
Sig3 ns ns
1 After McQuaker et al (1979) 2 Least significant difference at P lt 005 3 Significance at lt 0001 () lt 001 () lt 005 () level or not significant (ns)
As level of applied P increased concentration of P Ca and Na in whole tops increased significantly (P lt 005) whilst concentrations of N S Mn B and Cu decreased There was no significant effect of level of applied P on concentrations of K Fe or Zn in whole tops whilst concentration of Mg was variable
Effect oflevel of residual AG and P on carrot yield
There was a significant (P lt 005) increase in total and marketable yield with level of applied P at all levels of applied AG (Table 77) The overall effect of AG was to reduce both total and marketable yield at the highest level (1000 cf 0 to 2501 AGha) especially at low levels of applied P (ie 0 to 50 kg Pha) At higher levels of applied P yield at 2501 AGha was not significantly (P lt 005) lower than at 125 tha
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The use of Red Mudgypsum in vegetable production
However at 10001 AGha total and marketable yield was significantly lower than 0 tha at all levels of applied P The relationship between level of applied P and total yield was described as linear at 0 250 and 10001 AGha and Mitscherlich at 125 AG tha (Fig 76) As yield did not maximise at 0 250 and 1000 t AGha no optimal level of applied P for 95 or 99 of maximum yield could be determined At 125 t AGha the level of applied P necessary for 95 and 99 of maximum yield was 182 and 314 kg Pha respectively
Effect of level of AG and P on efficiency of P recovery by plants and retention in soil
The proportion () of P recovered in the carrot roots and tops decreased with level of applied P increasing from 8 to 12 to 5 to 8 of depending on level of AG (Table 78) There was a reduction in P recovered in roots tops and whole plant as level of AG increased For example P recovered by whole plants at 01 AGha at 400 kg Pha was 8 but this had declined to 5 at 10001 AGha
Table 78 The of applied fertiliser P taken up by carrots grown in pots (tops roots) retained in the topsoil or leached with level of residual Alkaloamreggypsum (AG) and phosphorus (P) on a Joel sand
P in Fraction AG P ( of P applied )
(tha) (kgha) TopsA Roots2 Plant(A+B) Soil2 Leached3
0 50 2 9 11 3 86
0 100 2 8 10 13 77
0 200 2 6 8 2 90
0 400 2 6 8 3 89
125 50 4 8 12 73 15
125 100 2 8 10 18 72
125 200 2 6 8 30 62
125 400 1 4 5 18 77
250 50 3 7 10 0 90
250 100 2 4 6 0 94
250 200 1 4 5 0 95
250 400 1 4 5 12 83
1000 50 2 6 8 75 17
1000 100 2 5 7 67 26
1000 200 2 5 7 45 48
1000 400 1 4 5 41 55
P in fraction expressed as of P applied as fertiliser 2 P retained in topsoil (0-15 cm) 3 P leached below 15 cm
By contrast of applied P retained in topsoil varied with level of AG For example only 3 of P was retained in topsoil at 400 kg Pha and 01 AGha where as this had increased to 41 at 10001 AGha at the same level of applied P Consequently the of P leached decreased as level of AG increased For example at 01 AGha and 400 kg Pha nearly 90 of applied P leached below 15 cm This had been reduced to 55 at 10001 AGha and the same level of applied P
97
The use of Red Mudgypsum in vegetable production
Table 79 Fertiliser P leached (kgha) and P leached as a of P applied from a Joel sand sown to carrots with level of residual Alkaloam gypsum (AG) and P after harvest The P was then applied as superphosphate prior to planting The carrots were sown on 3 April 1996 P leached is expressed as a percentage of P applied
AG (tha)
P (kgha)
P leached1
(kgha) P leached
( P applied)
0 50 41 82
0 100 78 78
0 200 158 79 0 400 311 78
125 50 2 4
125 100 3 3
125 200 10 5 125 400 27 7
250 50 1 2
250 100 3 3 250 200 4 2
250 400 7 2 1000 50 02 lt1 1000 100 05 lt1
1000 200 1 lt1
1000 400 2 lt1
1 Fertiliser P leached = total P leaclied - P leached at 0 kg Pha (ie background P) 2 (Fertiliser P leachedP applied x 100)
The use of Red Mudgypsum in vegetable production
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pound CD
o TO
(D
o
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c
o c o o
pound
(0
o to
c o
TO tmdash
c 0) o c o o
0 2 0 0 4 0 0 6 0 0 8 0 0 1 0 0 0 1 2 0 0
L e v e l o f r e s i d u a l A G ( t h a )
0 2 0 0 4 0 0 6 0 0 8 0 0 1 0 0 0 1 2 0 0
L e v e l o f r e s i d u a l A G ( t h a )
Figure 74 Concentration (mgL) of Ca (A) and Mg (B) in leachate from Joel sand sown to carrots amended with residual Alkaloamreggypsum (AG) in pots on 16 April 1996 (bull) 6 May 1996 (bull) and 22 July 1996 (A) The carrots were sown on 3 April 1996 Ca was applied preplanting as superphosphate and fertigated at a constant concentration of SO mgL from sowing to harvest AG was applied preplanting and in weeks 6 (15 May 1996) and 12 (25 June 1996) Vertical bars refer to Lsd (P lt 005) for differences in concentration between level of AG at each time Where bars arent shown Lsd is less than size of symbol
99
The use of Red Mudgypsum in vegetable production
CD
CO
x o CO CD
c o
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CO
c CD O c o O
0 2 0 0 4 0 0 6 0 0 8 0 0 1 0 0 0 1 2 0 0
L e v e l of r e s i d u a l A G ( t ha )
0 100 2 0 0 3 0 0 4 0 0
L e v e l of r e s i d u a l P ( k g h a )
5 0 0
Figure 75 The concentration of S (mgL) in leachate from Joel sands sown to carrots with level of residual Alkaloamreggypsum (AG) (A) and P (B) on 16 April 1996 (bull) 6 May 1996 (bull) 22 July 1996 (A) The carrots were sown on 3 April 1996 S was applied preplanting as K2S04 and in superphosphate Vertical bars refer to Lsd (P lt 005) for differences in concentration between level of AG (A) or P (B) at each sampling time Where bars arent shown Lsd is less than size of symbol
100
The use of Red Mudgypsum in vegetable production
ID
0 100 200 300 400 500
Applied P (kgha)
lb 70
70 C
60 65 -
60
55 dt
ha 50
40
50
45 bull A
Yie
30
40 _ 20
35 i i i i 35 0 100 200 300 400 5( 50 10
Applied p (kgha)
0 100 200 300 400 500
Applied P (kgha)
0 100 200 300 400 500
Applied P (kgha)
Figure 76 Total yield of carrots with level of freshly-applied P at four levels of residual Alkaloamreggypsum (AG) (A B C D = 01252501000 tha) Vertical dashed and whole lines refer to applied P necessary to 95 (dashed) or 99 (whole) of maximum yield respectively
The equations of the fitted lines are
A y = 10943 - 9377 x exp (-00053) (R2 = 099)
B y = 6l7- 2848 x exp (-00122) (i2 = 099)
C y = 3842+ 0083x (J2 = 097)
D y = 238 + 0l07x(R2 = 096)
As level of applied P increased concentration of P Ca and Na in whole tops increased significantly (P lt 005) whilst concentrations of N S Mn B and Cu decreased There was no significant effect of level of applied P on concentrations of K Fe or Zn in whole tops whilst concentration of Mg was variable
101
The use of Red Mudgypsum in vegetable production
Discussion
The addition of residual Alkaloamreggypsum (AG) resulted in a significant reduction in the concentration of P NH4-N K and Mg in the leachate from Joel sands sown to carrots in large pots The reduction in P concentration is attributed to an increase in the level of iron and aluminium oxides when AG is applied to soils low in these minerals (Barrow 1982) Consequently all soil measurements of P status or retention such as total P Colwell P and phosphorus retention index as well as Ec and pH all increased with level of applied residual AG Similar reductions in phosphorus leaching or increases in P retention have been reported when Gavin (Vlahos et al 1989) or Joel (Sections 4 and 5 McPharlin et al 1994 Robertson et al 1997) sands were amended with fresh or residual AG (Sections 4 and 6 Robertson et al 1994)
The reduced leaching of cations such as NH4-N K and Mg is attributed to an increase in captain exchange capacity (CEC) when sands of low CEC are amended with AG (Barrow 1982 McPharlin et al 1994) Consequently NO3-N retention is not increased when soils are amended with residual (Fig 72) or freshly-applied AG (McPharlin et al 1994) The increased leaching of Na Ca and S from amended sands is attributed to the Alkaloamreg as a source of these elements either in the Alkaloamreg itself (Na2C03) or after amendment with gypsum (CaS042H20) which precipitates CaC03 and Na2S04 The Na2S04 is very soluble as is easily leached whereas Ca is only slightly soluble as gypsum and insoluble as lime Vlahos et al (1989) reported increased leaching of Na Ca and S from Gavin sands treated with copper as (FeS04) amended Alkaloamreg compared with unamended controls in the short term and a decrease in the longer term Concentrations of P in the YML at midgrowth or tops at harvest increased with level of applied P and also with level of residual AG from 025 at 0 t AGha to 031 at 10001 AGha By contrast freshly-applied AG reduced the concentration of P in the YML from 043 on unamended to 030 on amended Joel sands (Robertson et al 1997) Even at the highest level of applied P the concentration of P in the YML 035 was still lower than that shown to be necessary for maximum yield of carrots (ie 038 McPharlin et al 1992) This could explain why the yield wasnt maximised in three out of the four AG treatments On the treatment that yield was maximised 125 t AGha the highest concentration of P ie 038 was recorded The difference in trends of P in petioles with AG between the 2 studies could be explained in terms of the relative leaching of P or addition of P in the AG itself On the virgin Joel sand used in the pot study leaching of P was significant enough to reduce leaf P in the unamended versus amended treatments For example the P in YML was significantly lower in the 01 AGha than at all other levels of residual AG at all levels of applied P up to 200 kgha For example the P in YML at 01 AGha ranged from 020 to 027 at 0 and 200 kg Pha respectively whilst at 125 t AGha the P was 032 to 038 over the same levels of applied P (Appendix 71) This suggests that loss of P from the top soil is severely limiting the uptake of P by the plant in the absence of AG The phosphorus retention of virgin Joel sands is almost negligible with a PRI of close to 0 (Table 72 McPharlin et al 1994 Robertson et al 1997) By contrast the P retention of Joel sands appears to be increased following development possibly by the addition of iron in irrigation water and organic and inorganic fertilisers For example the estimate of PRI (PREM) ie PRI plus P as Colwell P measured in the developed Joel sands used by Robertson et al was 40 in the topsoil (0-15 cm) of the unamended treatment Thus in these soils P retention is high enough to reduce availability when AG is added and explains the reduced levels of P in the YML as level of AG is increased The contribution of AG to the P nutrition of the plant is an unlikely explanation as it didnt increase P levels in the plant when applied fresh (Robertson et al 1997)
Previous work showed that concentrations of K in the petioles of potatoes (Section 4 Robertson et al 1997) and youngest mature leaves in cauliflower (Robertson et al 1994 Sections 5 and 6) declined with level of freshly-applied and residual AG
With potatoes the decline in K concentrations was associated with a decrease in K concentration in the soil solution and an increase in Na concentrations in soil solution and petioles on fresh and residual AG treatments (Section 4 Robertson et al 1997) This was
102
The use of Red Mudgypsum in vegetable production
used to explain yield reductions on fresh AG sites at gt 60 tha or on residual sites at 240 tha With cauliflower the findings were variable Where yield was reduced (Robertson et al 1994) it could not be explained in terms of K nutrition as K concentrations in the YML did not decline to levels expected to result in deficiency In follow up work neither fresh or residual AG up to 240 tha resulted in yield reduction although there was a reduction in K concentrations in the YML but not below critical levels (Sections 5 and 6) By contrast concentrations of K in the YML of carrots increased with level of residual AG up to 1000 tha as did exchangeable K in the soil Similar increases in K concentration in YML of Chinese and Head cabbage with level of AG on Joel sands have been reported previously (Robertson et al 1994)
Yield response of carrots to applied P at various levels of residual AG was variable on Joel sands in this work For example yield with level of applied P reach a plateau at 125 t AGha (ie 182 and 314 kg Pha for 95 and 99 of maximum yield from the Mitscherlich regression) However at other levels of applied AG including 0 tha yield had not maximised at the highest level of applied P (400 kgha) This is surprising considering that on higher P retaining soils such as Karrakatta sands yield is maximised at much lower levels of applied P (ie 160 to 180 kgha) at a similar low P soil test (McPharlin et al 1992 1994) in the absence of AG Also on Joel sands yields of carrots at medium to low P soil test (16 to 20 ugg Colwell P) only 50 kg Pha was necessary for maximum yield (McPharlin et al Lantkze and McPharlin unpublished data) The only possible explanation is that leaching of P was significant enough in the absence of AG that increased levels of applied P were required to satisfy crop requirements The increase in P fertiliser requirement as level of applied AG increases as shown in this work above 125 tha is similar to that reported previously for Chinese and Head cabbage cauliflower lettuce onions (Robertson et al 1994) and potatoes (Robertson et al 1997) It is explained by increased P retention capacity of the soil when AG is applied and measured by PRI Colwell and Total P and similar measurements
References
Allen DG and Jeffery RC (1990) Methods for analysis of phosphorus in Western Australian soils Chemistry Centre of Western Australia Report of Investigation No 37
Barrow NJ (1982) Possibility of using caustic residue from bauxite for improving the chemical and physical properties of sandy soils Australian Journal of Agricultural Research 33 275-285
Best EK (1976) An automated method for the determination of nitrate-nitrogen in soil extracts Queensland Journal of Agriculture and Annual Science 33 161-166
Colwell JD (1963) The estimation of phosphorus fertiliser requirements of wheat in southern New South Wales by soil analysis Australian Journal of Experimental Agriculture and Animal Husbandry 3 190-197
Hegney M A McPharlin IR and Jeffery RC (1997) Response of winter-grown potatoes (Solanum tuberosum L) to freshly-applied and residual phosphorus on a Karrakatta sand Australian Journal of Experimental Agriculture 37 131-137
McPharlin IR Alymore PM and Jeffery RC (1992) Response of carrots (Daucus carota L) to applied P and P leaching on a Karrakatta sand under two irrigation regimes Australian Journal of Experimental Agriculture 32 225-232
McPharlin IR Jeffery RC and Weissberg R (1994) Determination of the residual value of phosphate and soil test phosphorus calibration for carrots on a Karrakatta sand Communications in Soil Science and Plant Analysis 25 (5-6) 489-500
103
The use of Red Mudgypsum in vegetable production
McPharlin IR Robertson WJ Jeffery RC and Weissberg R (1995) Response of cauliflower to phosphate fertiliser placement and soil test phosphorus calibration on a Karrakatta sand Communications in Soil Science and Plant Analysis 26(3amp4) 607-620
McQuaker NR Brown DF and Kluckner PD (1979) Digestion of environmental materials for analysis by inductively coupled plasma-atomic emission spectrometry Analytical Chemistry 51 1082-1084
Reardon J Foreman JA and Serai RL (1966) New reactants for the determination of ammonia Clinica Chemica Acta 14 403-405
Robertson WJ McPharlin IR and Jeffery RC (1994) Final report of investigation into the use of gypsum-amended Red Mud as a soil-amendment for horticultural properties on the Swan Coastal Plain Final Report of HRDC Project No V0039 RO
Robertson WJ Jeffery RC and McPharlin IR (1997) Residues from bauxite-mining (Red Mud) increase phosphorus retention of a Joel sand without reducing yield of carrots Communications in Soil Science and Plant Analysis 28 (13 amp 14) 1059-1079
Varley JA (1966) Automatic methods for the determination of nitrogen phosphorus and potassium in plant material Analyst 91 119-126
Vlahos S Summers KJ Bell DT and Gilkes RJ (1989) Reducing phosphorus leaching from sandy soils with Red Mud bauxite processing residues Australian Journal of Soil Research 27 651-662
Walkley A and Black I (1934) An examination of the Degtjareff method of determining soil organic matter and a proposed modification of the chromic acid titration method Soil Science 37 29-38
Yuen SH and Pollard AG (1954) Determination of nitrogen in agricultural material by the Nessler reagent II Micro determination in plant tissue and soil extracts Journal of the Science of Food and Agriculture 5 364-369
104
The use of Red Mudgypsum in vegetable production
CO JC
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0 200 400 600 800
Level of residual AG(tha)
1000 1200
Appendix 71 (b) P leached (kgha) from Joel sands sown to carrots amended with residual Alkaloanrgypsum (AG) in pots on 16 April 1996 (week 3) (bull) 6 May 1996 (week 6) (bull) and 22 July 1996 (week 16) ( bull ) P was applied preplanting as superphosphate and carrots were sown on 3 April 1996 Vertical bars refer to Lsd (P lt 005) for differences in quantities of P leached between level of AG (across all levels of applied P) at each sampling time Where bars arent shown Lsd is less than size of symbol Data from Appendix 71 (a)
105
The use of Red Mudgypsum in vegetable production
200 400 600 800
Level ofresidual AG(tha)
1 000 1 200
2 00
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copy
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1 2 0
100 -
80 200 400 600 800
Level of residual AG (tha)
1000 1200
Appendix 73 (b) 74 (b) Ammonium-N (A) and Nitrate-N (B) leached (kgha) from Joel sands sown to carrots amended with residual Alkaloamreggypsum (AG) in pots on 16 April 1996 (week 3) (bull) 6 May 1996 (week 6) (bull) and 22 July 1996 (week 16) (A) N was fertigated postplanting as NH4-N and NO3-N and carrots were sown on 3 April 1996 Vertical bars refer to differences in quantities of N leached between level of AG (across all levels of applied P) at each sampling time Where bars arent shown Lsd is less than size of symbol Data from Appendices 73 (a) 74 (a)
106
The use of Red Mudgypsum in vegetable production
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Appendix 75 76 K (A) and Na (B) in leachate from Joel sand sown to carrots amended with residual Alkaloamreggypsum (AG) in pots on 16 April 1996 (week 3) (bull) 6 May 1996 (week 6) (bull) and 22 July 1996 (week 16) (A) The carrots were sown on 3 April 1996 K was fertigated at a constant concentration of 200 mgL from sowing to harvest and Na was a constituent of AG Vertical bars refer to Lsd (P lt 005) for differences in quantities of K and Na leached between level of AG (across all levels of applied P) at each time Where bars arent shown Lsd is less than size of symbol
107
The use of Red Mudgypsum in vegetable production
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Appendix 77 78 Ca (A) and Mg (B) in leachate from Joel sand sown to carrots amended with residual Alkaloamreggypsum (AG) in pots on 16 April 1996 (bull) 6 May 1996 (bull) and 22 July 1996 (A) The carrots were sown on 3 April 1996 Ca was applied preplanting as superphosphate (and as a constituent of AG) and fertigated at a constant concentration of 50 mgL from sowing to harvest Mg was applied preplanting and in weeks 6 (15 May 1996) and 12 (25 June 1996) Vertical bars refer to Lsd (P lt 005) for differences in quantity of Ca and Mg leached between level of AG (across all levels of applied P) at each sampling time Where bars arent shown Lsd is less than size of symbol Data from Appendices 77 (a) and 78 (a)
108
The use of Red Mudgypsum in vegetable production
200 400 600 800
Level of residual AG(tha)
1000 1200
Appendix 79 S (mgL) in leachate from Joel sands sown to carrots with level of residual Alkaloamreggypsum (AG) 16 April 1996 (week 3) (bull) 6 May 1996 (week 6) (bull) 22 July 1996 (week 16) (A) The carrots were sown on 3 April 1996 S was applied preplanting as K2S04 in superphosphate and as a constituent of AG Vertical bars refer to Lsd (P lt 005) for differences in quantity of S leached between level of AG (A) or P (B) at each sampling time Where bars arent shown Lsd is less than size of symbol Data from Appendix 79 (a)
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This report is published by the Horticultural Research and Development Corporation to pass on information concerning horticultural research and development undertaken for the vegetable industry
The research contained in this report was funded by the Horticultural Research and Development Corporation with the financial support of Alcoa of Australia Ltd
All expressions of opinion are not to be regarded as expressing the opinion of the Horticultural Research and Development Corporation or any authority of the Australian Government
The Corporation and the Australian Government accept no responsibility for any of the opinions or the accuracy of the information contained in this report and readers should rely upon their own enquiries in making decisions concerning their own interests
Cover price $2000 HRDC ISBN 1 86423 756 2
Published and distributed by Horticultural Research amp Development Corporation Level 6 7 Merriwa Street Gordon NSW 2072 Telephone (02) 9418 2200 Fax (02) 9418 1352 E-Mail hrdchrdcgovau
copy Copyright 1998
of
HRDC
HORTICULTURAL RESEARCH amp DEVELOPMENT CORPORATION
Partnership in horticulture
CONTENTS
Page
1 Summary and recommendations 1
2 Project staff collaborators and acknowledgments 4
3 Publications arising out of work 5
4 Response of potatoes to freshly-applied and residual Red Mud (Alkaloamreg)gypsum 6 and phosphorus on a yellow Karrakatta sand
5 Response of cauliflowers to freshly-applied Red Mud (Alkaloamreg)gypsum and 30 phosphorus on a yellow Karrakatta sand
6 Response of cauliflowers to residual Red Mud (Alkaloamreg)gypsum and 59 phosphorus on a yellow Karrakatta sand
7 Retention leaching and recovery of P and other nutrients by carrots grown on 82 a Joel sand amended with residual Red Mud (Alkaloamreg)gypsum in large pots
CO
The use of Red Mudgypsum in vegetable production
1 SUMMARY AND RECOMMENDATIONS
11 Technical summary
Red Mud (Alkaloamreg)gypsum (AG) is seen as a useful amendment to increase the P retention of acid sandy soils low in this characteristic such as the Bassendean (Joel Gavin and Jandakot) and grey-phase Karrakatta sands P fertilisers applied to these soils from intensive horticultural production may leach and pollute associated water systems such as lakes rivers and estuaries Unfortunately because of strong demand for other land uses on soils better suited to vegetable production on the Swan Coastal Plain such as the Spearwood and yellow Karrakatta sands more of the less environmentally suitable Bassendean sands are being used for horticulture
In a previous project (HRDC VG0039) freshly-applied AG caused yield reduction in cauliflower and potatoes at low rates ie 60 tha on Karrakatta sands
In addition the effect of AG appeared to be specific and to vary with species For example levels of freshly-applied AG up to 240 tha had no effect on the yield of carrots on Joel sands and increased the yield of lettuce on Karrakatta sands
For this reason we approached Alcoa and HRDC for a subsequent project to further examine the response of cauliflower and potatoes to freshly-applied and residual AG
Addition of AG significantly increased the P retention (as measured by PRI total and Colwell P) pH Ec and exchangeable cations (NHU-N Ca K and Na) in the top 15 cm of the sands whilst concentrations of P and K in soil solution were reduced
With potatoes the effect of AG on yield varied depending of whether it was fresh or residual For example yield of potatoes were reduced with 601 of fresh AGha but only at 2401 of residual AGha In both cases the yield reduction could not be explained in terms of reduced P uptake by the plants as increased levels of applied P did not obviate the problem The yield reduction appeared to be due to K deficiency induced by high levels of Na (alkalinity) in the AG This was correlated with reduced K in soil solution With residual AG the alkalinity was lower as there had been more time for leaching and consequently the yield reduction was much less At levels of AG likely to be recommended for commercial use ie 60 to 120 tha no yield reduction would be anticipated with potatoes provided the AG was thoroughly leached with irrigation water for 1 or 2 months prior to planting In contrast to the previous project applications of fresh or residual AG up to 240 tha did not cause any reduction in yield of cauliflower even though concentrations of K decreased and Na increased in the YML at midgrowth
The optimum level of AG is that required to reduce leaching of fertiliser P substantially without reducing yield quality or increasing the level of P required for maximum crop yield significantly For example on unamended Joel sands leaching of fertiliser P was so high (ie 78 to 80 of applied P) that yield of carrots did not reach a maximum despite high levels of applied P (ie up to 400 kgha) By contrast 125 t AGha reduced leaching of fertiliser P to only 5 to 7 of applied P whilst yield maximised at 182 (95) and 314 (99) kg Pha At higher levels of AG (250 and 1000 tha) P required for maximum yield was significantly increased ie yield did not maximise at 400 kg Pha whilst leaching of P was not reduced much more than at 125 tha ie 1 to 3 of applied P However even at 125 tha the level of applied P required for maximum carrot yield (182 to 314 kgha) was higher than that required for maximum yield on higher P fixing sands such as the yellow Karrakatta sands ie 120 to 180 kgha suggesting that levels of AG less than 125 tha may be more agronomically suitable
In conclusion the benefits of amending acid sands with AG are increased retentionreduced leaching of P increased retentionreduced leaching of K Mg and NH4-N due to increased cation retention and an increase in pH (ie lime effect) The improved P retention of AG-amended sands enables the use of P soil testing as part of the P management of these soils whereas prior to amendment soil testing was not practical as leaching of P was too high
The use of Red Mudgypsum in vegetable production
An additional benefit which was not thoroughly investigated in this project but was obvious in the pot experiment was increased soil moisture holding capacity especially at high levels of application due to an increased in the fine fractions after amendment These benefits should be achieved at low to moderate levels of applied AG (ie 60 to 120 tha) without any negative effect on vegetable yield or quality
Some negative effects of amending acid sands with fresh AG include decreased yield due to increased conductivity and induced K deficiency in some vegetables such as potatoes However this does not appear to be a problem with carrots and cauliflower
This problem can be obviated by allowing sufficient time to leach the soluble alkalinity (Na2SCgt4) out of the root zone of the amended soil prior to cropping as it is less of a problem with residual AG Another disadvantage is the increase in fertiliser P requirements of vegetables after AG amendment in the short term due to increased P fixation This is particularly obvious at high levels of application However this disadvantage is offset as soil testing can be used on sands after amendment to reduce P fertiliser costs whereas it couldnt beforehand Also on unamended Joel sands leaching of P fertilisers (ie 80 of applied P) causes significant economic loss due to fertiliser losses and increased fertiliser P required for maximum yield
12 Industry summary
An important domestic and export vegetable industry is located on the sands of the Swan Coastal Plain (SCP) in Western Australia The total value of the vegetable industry on the SCP was estimated at $90M in 19967 or about 50 of the total value of the industry This vegetable production has been located on good quality sands such as the Spearwood and yellow Karrakatta sands close to the coast since the 1950s However in recent years competition for this land for urban and industrial use has forced vegetable production onto soils with poorer water and phosphorus retention capacity such as the more acidic Bassendean (Joel) and grey-phase Karrakatta sands This has lead leaching of fertiliser phosphorus into water systems of the SCP such as lakes rivers and estuaries with resulting pollution (algae blooms) Even though vegetable production is not the only or main source of this leached phosphorus the issue has resulted in negative publicity for the industry and increased scrutiny of industry practices by government agencies charged with responsibility for water the environment and health
As large quantities of Red Mud (Alkaloamreg)gypsum (AG) were produced from bauxite refining on the SCP it made sense to examine this as a soil amendment as it had been shown to improve the phosphorus retention capacity of coarse grey sands low in iron and aluminium oxides AG consistently increases the phosphorus retention capacity and the retention of cations such as potassium magnesium and ammonium-nitrogen and pH (lime effect) of grey and pale-yellow sands after amendment The reduction fertiliser P leaching is very high even at the lower rates of application such as 60 and 120 tha Fresh AG will increase the fertiliser phosphorus requirements of most vegetable crops compared with the unamended plots similar to the differences between low and high P fixing soils However this increase is not as much on residual or aged AG sites This increase in initial fertiliser P needs following AG application is offset by the use of soil testing to manage P fertiliser in subsequent crops on grey sands which was not practical prior to amendment Some initial problems with fresh AG causing yield reductions on potatoes was attributed to induced potassium deficiency due to high conductivity (ie high sodium) in amended soils However this problem can be overcome by leaching the soil of salts after amendment with high rates of irrigation so that EC of the amended soil doesnt exceed 6 mSm and the pH (water) 85 The potassium nutrition of the crop should be monitored to ensure it is adequate There is no problem on sites where AG has been applied for at least 12 months
2
The use of Red Mudgypsum in vegetable production
13 Recommendations It is recommended that AG be used as a soil amendment for vegetable crops on the grey and pale yellow sands of the SCP to reduce P fertiliser leaching However a number of guidelines should be adhered to ensure maximum benefits and minimum risks from the use of AG
bull Potatoes should not be grown on sites where fresh AG (ie 1 to 3 months after application) has been applied
bull Potatoes can be grown on sites where AG has be applied at levels up to 120 tha provided at least 12 months previously provided sufficient leaching of salts has occurred As a guide it is suggested that soil conductivity should not exceed 6 mSm and pH (water) 85 in the top 15 cm
bull Vegetable crops other than potatoes can be planted into sites where fresh AG has been applied at levels up to 120 tha without problems
bull Adjust level of P fertiliser application to account for increased P fertiliser requirements of vegetables due to higher P fixing on sites amended with AG
bull Use soil testing to manage P fertiliser applications on AG amended sites but follow recommendations for specific vegetable crops
The use of Red Mudgypsum in vegetable production
2 PROJECT STAFF
Ian McPharlin
Wendy Robertson
Bob Jeffery
Tony Shimmin
Jenny Harboard
Don Glenister
Patricia Aylmore
David Cooling
Gavin dAdhemar
Neil Lantzke
John Ferguson (Manager) and staff
Staff
COLLABORATORS AND ACKNOWLEDGMENTS
Project Manager and Principal Investigator
Research Officer
Project Collaborating Scientist (Chemistry Centre of WA)
Project Technical Officer
Project Laboratory Technician (Chemistry Centre of WA)
Residue Development Manager (Alcoa of Australia)
Environmental Scientist (Alcoa of Australia)
Senior Consultant Residue (Alcoa of Australia)
Technical Officer Medina Research Centre (for technical assistance and management of field and pot experiments)
Horticultural Extension Officer (for extension advice)
Medina Research Centre (for management of field experiments)
Chemistry Centre of WA (for advice of on soil plant and leachate chemistry)
4
The use of Red Mudgypsum in vegetable production
3 PUBLICATIONS ARISING OUT OF WORK Robertson WJ McPharlin IR and Jeffery RC (1997) The growth nutrition and
composition of potatoes (Solarium tuberosum L) cv Delaware grown on a yellow Karrakatta sand amended with freshly-applied and residual Alkaloamreggypsum Australian Journal of Experimental Agriculture (submitted)
McPharlin IR dAdhemar G and Shimmin TR (1997) The response of cauliflowers (Brassica oleraceae L) cv Plana to freshly-applied and residual Alkaloamreggypsum and phosphorus on a Karrakatta sand Australian Journal of Experimental Agriculture (in prep)
McPharlin IR Shimmin TR and dAdhemar G (1997) Leaching of P N and cations from carrots grown on Joel sands amended with residual Alkaloamreggypsum Communications in Soil Science and Plant Analysis (in prep)
The use of Red Mudgypsum in vegetable production
4 RESPONSE OF POTATOES TO FRESHLY-APPLIED AND RESIDUAL RED MUD (ALKALOAMreg)GYPSUM AND PHOSPHORUS ON A YELLOW KARRAKATTA SAND
Introduction
Previous work has shown that freshly-applied Alkaloamreggypsum (gypsum-amended red mud 10 ww) (AG) at 60 and 120 tha reduced the total yield of potatoes by 7 and 23 respectively compared with 01 AGha controls (Robertson et al 1994 Appendix 1 J) The reduction in marketable yield was almost identical to the reduction in total yield The exact cause of this reduction in yield could not be determined particularly the reduction at 120 tha It was unlikely to be a reduced availability of P Observations on commercial properties suggest that AG which has been in the soil for several seasons does not cause yield reductions in potatoes
Phosphorus was banded at planting in this experiment Subsequent work (Hegney and McPharlin unpublished data) showed that broadcasting P allowed a greater maximum yield of potatoes than banding P on Karrakatta sands of low P fertility
This experiment re-examines the response of potatoes to freshly-applied AG using broadcast P and also the effect of residual AG on growth of potatoes at unlimiting P
Materials and methods
Site characteristics
The experiment was conducted on a yellow Karrakatta sand (described by McArthur and Bettenay 1960) at Medina approximately 30 km south of Perth Two sites were used a site where pasture species had been grown several years earlier and to which no AG had ever been applied and a second (adjacent) site where AG had been applied approximately 2J2 years earlier A lettuce and a cauliflower crop had been grown previously on this site after AG amendment (Robertson et al 1994 Appendix 1H I)
Red Mud (Alkaloamreg)gypsum (AG)
Red Mud (Alkaloamreg)gypsum (10 ww) (AG) was produced by the dry mix process by ALCOA of Australia Ltd at their Kwinana Residue Treatment Plant It was spread manually on the previously unamended site on 22 December 1994 and was incorporated to a depth of approximately 30 cm using a rotary hoe The AG on the previously-amended site (residual AG) was applied using the same techniques on 24 November 1992 The freshly-applied AG was watered for 1 hour three times a week until planting
Experimental design
The freshly-applied and residual AG sites were used for separate experiments which were conducted simultaneously The experiment on the freshly-applied AG was a split-plot randomised complete block design with three replicates Main plots were levels of AG (0 60 90 and 120 tha) and sub-plots were levels of P application (0 25 50 100 300 and 600 kgha) Main plots measured 48 x 21 m and sub-plots measured 24 x 7 m (three rows of potatoes with 08 m between row centres) There was a 2 m buffer around each main plot The experiment on the residual AG site was a randomised complete block design with 4 levels of AG (0 60 120 and 240 tha) and three replicates The levels of AG were applied in November 1992 and had had several levels of P applied to them in the previous crops The AG plots measured 6 x 12 m but only an area of 34 x 8 m (4 rows of potatoes with 08 m between row centres) was cropped to allow a buffer of 1 to 2 m all around the planted area
6
The use of Red Mudgypsum in vegetable production
Crop management Both sites were initially sprayed with Roundupreg (3 Lha) to kill weeds and the sites were hoed with a rotary hoe Freshly-applied AG was applied at this stage The residual AG site was treated with metham sodium approximately two weeks before planting Potatoes cv Delaware were planted on both sites on 18 May 1995 using a single row mechanical planter Round seed was used and this was dusted with Rizolexreg (2 kgt) immediately before planting Sets were planted 15 cm apart The crops were irrigated using impact sprinklers once daily at 80 of Class A pan evaporation between planting and emergence and then at 100 of evaporation Afalonreg (15 kgha) was applied after planting and Sprayseedreg (2 Lha) was applied at 5 emergence both for weed control Nitofol (700 rnLha) was used for regular insect control Bravoreg (2 Lha) was applied every seven days from the time of 50 ground cover until blight symptoms appeared at which time it was then alternated with Rovralreg (2 Lha) at 7 day intervals Both crops were harvested on 15 November 1995
Fertilisers
Pre-planting fertilisers were broadcast by hand on 15 May 1995 on freshly-applied AG and on 16 May on residual AG These were 83 kg Kha as K2S04 10 kg Mgha as miso47H20 and a complete trace element mix containing (kgha) MnS04H20 (504) MgS047H20 (560) borax (336) FeS047H20 (336) CuS045H20 (336) ZnS04H20 (280) and Na2Mo042H20 (224) Single superphosphate (91 P) was broadcast by hand at 0 to 600 kg Pha on freshly-applied AG according to the treatment and at 600 kg Pha on all plots on residual AG Post-planting fertilisers were a total of 500 kg Nha as NH4NO2 and KN02 and 400 kg Kha as KN02 in equal amounts for 10 weeks via the irrigation system An extra 50 kgha MgS04 was applied in weeks 7 and 9
Measurements
(a) Plant
The petioles of the Youngest Mature Leaf (YML) often plants were collected at the S2 stage (longest tuber 10 mm long) (19 July 1995) on both freshly-applied and residual AG They were dried in a forced draught oven at 70degC and then analysed for P N K Na Ca Mg S B Cu Fe Mn and Zn On freshly-applied AG tubers were harvested from a 5 m length of the middle row of each plot On residual AG a 4 m length of the two middle rows of each plot was harvested Tubers were separated into the following size grades lt 30 g 30-80 g 80-250 g 250-450 g and gt 450 g Tubers between 30 g and 450 g were considered marketable except if they were green or damaged
Of the tubers in the 80-250 g category ten were sampled from each plot for P analysis They were washed in tap water and sliced thinly with a stainless steel knife Fresh and dry weights were measured before the tubers were analysed for total P
(b) Soil
All 0 kg Pha plots on freshly-applied AG were sampled to 15 cm depth (15 cores per plot) on 29 August (approximately 3 months after planting) They were analysed for Bicarbonate-extractable P (Bic-P) (Colwell 1963) total P EC pH (H20) pH (CaCl2) Phosphorus Retention Index (PRI) (Allen and Jeffery 1990) and P buffering capacity (Ozanne and Shaw 1968) Before fertilisers were applied to the residual AG site on 16 May 15 cores (0-15 cm) were sampled from each plot and analysed for Bic-P and PRI Residual AG plots were sampled again on 29 August (0-15 cm 15 cores per plot) and analysed for pH (H20) pH (CaCl2) EC and P buffering capacity All residual AG plots and 0 100 and 600 kg Pha freshly-applied AG plots were sampled to three depths (0-15 15-30 and 30-45 cm) (20 cores per plot) on 5 December (ie after harvest)
7
The use of Red Mudgypsum in vegetable production
Chemical analysis
Plant samples were ground to pass through a 1 mm screen after drying Concentrations of P N K and Na were measured by digesting the samples with sulphuric acid and hydrogen peroxide (Yuen and Pollard 1954) N and P were determined colorimetrically by indophenol blue and molybdo-vanadate methods respectively K and Na were determined by flame photometry All analysis was conducted on a 4-channel Auto-analyser system using modifications of Technicon procedures (Anon 1977) Samples for analysis of Ca Mg S Cu Fe B Mn and Zn concentrations were digested with nitricperchloric acids (McQuaker et al 1979) Concentrations were measured by inductively-coupled plasma atomic emission spectrometry (ICP-AES) Concentrations of heavy metals were determined using inductively-coupled plasma mass spectrometry (ICP-MS) with indium as an internal standard Samples were initially crushed in an agate mortar and digested using nitric and perchloric acids
All soil samples were dried at 40degC in a forced draught oven Lumps of AG and fertiliser in samples were crushed and the samples were thoroughly mixed and sieved to lt 2 mm before analysis The pH (H20) and the EC were determined on a 15 soilwater extract after shaking for 1 hour The pH (CaCl2) was determined on 15 soiksolution extract using 001 M CaCl2 after shaking for 1 hour Values for both are corrected to 25 degC Total P was determined on a Kjeldahl digest of a separate sub-sample of soil ground to less than 015 mm The concentration of phosphate was measured by the method of Murphy and Riley (1962)
Statistical analysis
All data were analysed by an Analysis of Variance (ANOVA) using Genstat v 50 Results from the two experiments were analysed separately Data from the freshly-applied AG site was analysed by a two-way ANOVA on level of Alkaloamreg and level of applied P while data from residual Alkaloamreg were analysed by a one-way ANOVA on level of AG Statistical differences were determined using a Least Significant Difference at 5 level of significance where the F value from the ANOVA was significant Mitscherlich curves were fitted to all relationships between level of applied P and yield petiole or tuber P concentration or total P uptake Maximum values of Mitscherlich equations were compared using a 5 t-test Linear relationships were fitted to the yield response on residual Alkaloam versus level of AG and also to the relationship between yield and petiole P concentration on freshly-applied AG
The amount of fertiliser P retained was calculated by subtracting total P at 0 kg Pha from the measured total P value Concentrations of P in ugg were converted to kilograms per hectare by multiplying by a factor of 225 This is based on the assumption that there are 2250 t soilha in the top 15 cm of soil
Results and discussion
Soil characteristics
The pH (H20) of the top 15 cm of soil at mid-growth when no P fertiliser was applied increased from 72 on unamended soil to 84 and 85 on amended soil (Table 41) EC also increased from 5 mSm on unamended soil to 8 and 9 mSm on amended soil (Table 41) Bic-P was approximately 10 ugg at all AG levels and total P ranged from 55 ugg on unamended soil to 76 ugg at 901 AGha (Table 41) PRI and P buffering capacity (Pbug) both increased between unamended and amended soil but there were no differences between levels of AG on amended soil PRI of amended soil was 26 to 30 and Pbuff was 24 to 30 (Table 41)
The Bic-P and PRI measurements taken two days before planting on residual AG were the same at all levels of AG Bic-P was 16 to 21 ugg and PRI was 37 to 53 (Table 42) On the other hand Pbuff measured mid-growth increased from 20 at 01 AGha to 30 and 40 at 120 and 2401 AGha The EC was 7-9 mSm on all treatments and pH (H20) increased between 0 and 120 t AGha from 73 to 84 (Table 42)
The use of Red Mudgypsum in vegetable production
Table 41 Characteristics of the top 15 cm of a Karrakatta sand amended with several levels of freshly-applied Alkaloamreggypsum (AG) when no fertiliser P was applied
AG (tha)
pH (H20)
pH (CaCl2)
EC (mSm)
Bic-P (ugg)
Total P (ugg)
PRI Pbuff
0 72 64 5 8 55 19 14
60 84 77 8 10 64 26 24
90 85 78 9 11 76 30 30
120 85 83 9 10 71 27 27
Signif NS NS $
Lsd 5 04 05 3 07 05
Table 42 Characteristics of the top 15 cm of a Karrakatta sand amended with several levels of residual Alkaloamreggypsum (AG) when 600 kg Pha was applied as superphosphate
AG (tha)
pH (H20)
pH (CaCl2)
EC (mSm)
Bic-Pa
(ugg) PRIa
Pbuff
0 73 67 7 16 37 20
60 78 71 5 17 40 23
120 84 77 9 20 44 30
240 88 80 9 21 53 40
Signif NS NS NS
Lsd 5 05 06 10
K Sampled and measured before application of fertiliser P
Total phosphorus in soil
Total P in the soil at harvest on freshly-applied AG increased significantly with level of AG averaged over all three depths sampled (P lt 005) It also increased with level of applied P on all levels of AG At 0-15 cm total P increased significantly between 0 and 601 AGha At 15-30 cm it increased significantly between 0 and 90 t AGha and at 30-45 cm there was no effect of level of AG at all (Fig 41) At all levels of AG and P which were sampled total P concentrations at 0-15 cm and 15-30 cm were not significantly different from each other and both were significantly greater than those at 30-45 cm (Fig 41)
In the top 15 cm of soil total P increased from 47 ugg on unamended soil to 62-67 ugg on amended soil when no fertiliser P was applied This increase represents the total P content of the AG itself When 100 kg Pha was applied total soil P (0-15 cm) increased from 63 ugg at 01 AGha to 83 ugg at 601 AGha and 95 and 103 ugg at 90 and 1201 AGha (Fig 41) When the increase due to the AG itself is considered this is an increase in fertiliser P retention of 6 ugg (26 kgha) between 0 and 601 AGha and a further 14 ugg (62 kgha) between 60 and 120 t AGha At 600 kg Pha the increase in fertiliser P retention was 35 ugg (15 kgha) between 0 and 601 AGha and 25 ugg (11 kgha) between 60 and 120 t AGha
Total P on residual AG increased with level of AG The increase was significant between 60 and 1201 AGha only It also decreased at increasing depth As observed on freshly-applied AG total P concentrations at 0-15 cm and 15-30 cm were not significantly different from each other and were both greater than that observed at 30-45 cm (Fig 43) At 0-15 cm total P increased by 20 ugg between 0 and 601 AGha and by a further 213 ugg between 60 and 1201 AGha when 600 kg Pha was applied These values cannot be corrected for the total content of AG itself as there was no 0 kg Pha treatment
9
The use of Red Mudgypsum in vegetable production
The addition of freshly-applied AG to the soil substantially increased the theoretical ability of the soil to sorb applied P as measured by the P buffering capacity in the top 15 cm of soil However it was reduced over time as 1201 AGha was required to increase Pbuff on residual AG compared with 601 AGha on freshly-applied AG Fertiliser P retention in the top 15 cm of soil when amended with 1201 AGha was increased by 9 at 100 kg Pha and by 4 at 600 kg Pha
The effects of residual and freshly-applied AG can be compared at 600 kgha of applied P The effect of residual AG on fertiliser P retention can be estimated from measurements made on the same site at the beginning of the first (lettuce) crop In that experiment total P before the application of P fertilisers increased from 69 and 62 ugg on 0 and 601 AGha to 91 ugg on 1201 AGha and 103 ugg on 2401 AGha (Robertson et al 1994 Appendix 1H) This makes the estimated increase in fertiliser P retention (0-15 cm) 27 ugg (12 kgha) between 0 and 601 AGha and 184 ugg (81 kgha) between 60 and 1201 AGha Therefore between 60 and 1201 AGha residual AG increased fertiliser retention by approximately 7 times as much as did freshly-applied AG
Bicarbonate-extractable P (soil-test P) in soil
On freshly-applied AG there was no overall response of Bic-P to level of AG although there was an upward trend Bic-P decreased with increasing depth averaged over all treatments following the same response as total P There was an interaction between the effects of depth and level of applied P At 0 kg Pha there was no difference in Bic-P between the three depths sampled but at 100 and 600 kg Pha Bic-P concentrations at 0-15 cm and 15-30 cm were both greater than those at 30-45 cm (Fig 42) The upward trend in Bic-P with increasing level of AG was weak on soil where no P fertiliser had been applied being from 9-10 ugg at 0 and 601 AGha to 11 and 14 ugg at 90 and 1201 AGha in the top 15 cm This suggests that the AG adds little if any plant available P to the soil The amount of fertiliser P retained as Bic-P in the top 15 cm of soil when 100 kg Pha was applied increased by 8 ugg between 0 and 601 AGha and by a further 4 ugg between 60 and 120 t AGha At 600 kg Pha Bic-P retained from fertiliser increased by 34 ugg between 0 and 601 AGha and by 16 ugg between 60 and 1201 AGha
The response of Bic-P to level of residual AG and to depth was the same as for total P (Fig 43) In the top 15 cm of soil Bic-P increased by 11 ugg between 0 and 601 AGha and by 82 ugg between 60 and 1201 AGha uncorrected for the Bic-P content of the AG itself
The increase in Bic-P retention observed on amended soil at 100 kg Pha was similar to that observed at 160 kg Pha on a crop of carrots grown on a Joel sand amended with AG (Robertson et al 1997) Using the soil-test standards published by Hegney et al (1997) these increases in Bic-P will reduce the P fertiliser requirement in the following potato crop by 10 at 601 AGha and 22 at 1201 AGha
Using the Bic-P concentrations observed on the residual site at the beginning of the lettuce crop (Robertson et al 1994 Appendix 1H) the increase in fertiliser P retained as Bic-P (0-15 cm) on residual AG was 15 ugg between 0 and 601 AGha and 79 ugg between 60 and 1201 AGha This is half the increase observed on freshly-applied AG between 0 and 60 t AGha and approximately 5 times that observed on freshly-applied AG between 60 and 1201 AGha
The reduced P retention at low levels of residual AG compared with freshly-applied AG was probably because of the higher initial Bic-P levels on residual AG For both total and Bic-P it is difficult to explain why the apparent retention of fertiliser P between 60 and 120 t AGha should have been so much greater on residual than on freshly-applied AG It may have been caused by changes to the chemical properties of the AG as it aged in the ground
10
The use of Red Mudgypsum in vegetable production
Yield
Total and marketable yields on freshly-applied AG both increased with level of applied P following a Mitscherlich response (Fig 44 (a) (b)) An ANOVA did not indicate any response to level of AG in either total or marketable yields However maximum total yield on unamended soil (61 tha) was significantly greater than that on AG-amended soil - 54 to 57 tha (Fig 44 (a)) On the other hand there were no differences in maximum marketable yields Maximum marketable yield values ranged from 52 to 55 tha (Fig 44 (b)) When marketable yield was calculated as a percentage of total yield an ANOVA indicated a significant interaction between level of AG and level of applied P At 400 kg Pha marketable yield was 88 of total yield on unamended soil compared with approximately 95 on amended soil (significant according to 5 Lsd) A similar trend was observed at 600 kg Pha where marketable yield was 90 of total yield on unamended soil and 93 to 96 on amended soil
The levels of applied P required for 99 of maximum total yield were 245 222 183 and 400 kg Pha on 0 60 90 and 1201 AGha and for 95 of maximum yield were 139 130 108 and 226 kg Pha (Fig 44 (a)) A similar trend can be seen for marketable yield where 99 of maximum yield required 178 206 208 and 356 kg Pha (Fig 44 (b))
Total yield on residual AG showed an almost significant response to level of AG (P = 0067) (Fig 45) Total yield was 68 to 72 tha on 0 60 and 120 t AGha and 62 tha on 2401 AGha Marketable yield was 65 to 68 tha on 0 to 1201 AGha and 58 tha on 2401 AGha Therefore 2401 AGha appears to reduce yields even when it has been in the ground for 2 years or more and even when 600 kg Pha is applied As only one level of P fertiliser was applied it is not possible to determine the effect of residual AG on the critical levels of P application required for 99 and 95 of maximum yield
Concentration of nutrients in petioles
Phosphorus
Phosphorus concentration in petioles of the YML sampled at the S2 stage on freshly-applied AG increased with level of applied P following a Mitscherlich response (Fig 46) Maximum petiole P concentrations were approximately 12 (dry basis) on all AG levels Values at 99 of maximum petiole P concentration were 116 122 117 and 116 at 0 60 90 and 1201 AGha There was a significant interaction between levels of AG and applied P (P lt 005) At low levels of applied P (25 50 and 100 kgha) P concentrations on amended soil were significantly less than those on unamended soil but there was no difference between them at 300 or 600 kg Pha This is reflected in the levels of applied P required for 99 of maximum petiole P concentration which were 209 499 581 and 508 kg Pha at 0 60 90 and 1201 AGha This is an increase of 138 on amended soil relative to unamended soil AG at levels of between 60 and 120 tha therefore reduces the availability of P to plants As there was no difference in the maximum P concentration in petioles between amended and unamended soil a reduction in P availability to plants cannot explain the reduced maximum yield on amended soil Another factor was therefore involved in reducing maximum yield on amended soil Despite this yield difference between amended and unamended soil which was not related to differences in P concentration total yield for all AG levels combined was linearly correlated with petiole P concentration at the S2 stage (y = 256 + 274x R2 = 087) (Fig 47)
The petiole P concentration at 99 of maximum total yield was 116 109 095 and 114o at 0 60 90 and 1201 AGha At 01 AGha this was the same as 99 of maximum petiole P concentration implying that the yield response on unamended soil was controlled principally by P availability On the other hand petiole P concentrations at 99 of maximum yield on amended soil especially 60 and 901 AGha were less than 99 of maximum petiole P concentration In other words yield stopped increasing even though P concentration in the plant kept increasing This supports the previous observation that some factor other than P was limiting yield in these treatments Petiole P concentration in YMLs sampled at S2 stage on residual AG did not change with level of AG Overall mean P concentration was 12 dry
11
The use of Red Mudgypsum in vegetable production
basis This is in keeping with the results observed on freshly-applied AG at 600 kg Pha It also means that the lower yield at 2401 AGha on residual AG could not be explained by a reduced P concentration in the plant As on freshly-applied AG another factor was involved which reduced yield on amended soil although at a higher level on residual than on freshly-applied AG
Hegney et al (1997) found that maximum petiole P concentration at S2 in potatoes grown on Karrakatta sand was 114 dry basis and that 109 was required for 99 of maximum yield in good agreement with the results observed here
Other nutrients
The responses of nutrients other than P were very similar on both freshly-applied and residual AG Concentrations of K (Tables 43 45) and Zn (Fig 48 (a) Table 45) decreased as level of AG increased and concentrations of Mg Fe and Ca increased with level of AG in both experiments (Tables 43 45 Fig 48 (b)) Zn concentrations also decreased with increasing level of applied P (Fig 49 (a)) while Ca concentrations increased with level of applied P (Fig 48 (b)) Concentrations of Na also showed an upward trend on both freshly-applied and residual AG (Tables 43 45) On freshly-applied AG K concentrations decreased significantly from 119 dry basis on unamended soil to 110 at 601 AGha and to 102 at 1201 AGha (Table 43) On residual AG it decreased from 11-12 at 0-1201 AGha to 103 at 2401 AGha (Table 45) No other nutrients showed any response to level of AG although concentrations of N Mn S and B increased with level of applied P on freshly-applied AG (Table 44)
Concentrations of all nutrients except K were adequate or more than adequate for maximum yield (Maier et al 1987) on both freshly-applied and residual AG Potatoes require concentrations of approximately 12 to 14 K (dry basis) in petioles of YML for maximum yield (Maier et al 1987) On freshly-apphed AG concentrations were adequate at 01 AGha but were less than adequate on amended soil On residual AG concentrations were adequate at 0 60 and 1201 AGha but less than adequate at 2401 AGha As less than adequate K concentrations correspond with those treatments which had low yield it is likely that K concentration was the limiting factor in yield on both freshly-applied and residual AG
Uptake of K may have been reduced at higher levels of AG due to an increased Cation Exchange Capacity (Barrow 1982 McPharlin et al 1994) or to the increased soil pH (Harris 1992) The reduction in Zn availability on amended soil is most likely to be a result of the increase in soil pH due to the AG (Harter 1983)
Table 43 Concentrations of several nutrients in the petioles of the Youngest Mature Leaf of potato plants sampled at the 10 mm tuber stage at several levels of freshly-applied Alkaloamreggypsum (AG) on a yellow Karrakatta sand
AG K Na Mg Fe (tha) () () () (ngg)
0 119 018 059 382
60 110 020 065 553
90 106 021 066 597
120 102 021 069 697
Signif NS
Lsd 5 04 004 119
12
The use of Red Mudgypsum in vegetable production
Table 44 Concentrations of several nutrients in the petioles of the Youngest Mature Leaf of potato plants sampled at the 10 mm tuber stage at two levels of applied P when grown on a yellow Karrakatta sand amended with freshly-applied Alkaloamreggypsum (AG)
Applied P N S Cu Mn B (kgha) () () (ngg) (ngg) (M-gg)
0 44 028 74 293 267
600 48 032 62 342 248
Signif NS NS
Table 45 Concentrations of several nutrients in the petioles of the Youngest Mature Leaf of potato plants sampled at the 10 mm tuber stage at several levels of residual Alkaloamreggypsum (AG) on a yellow Karrakatta sand
AG N K Na Ca S Mg Cu Fe Mn Zn B (tha) () () () () () () (l-igg) (ngg) (ngg) Ws) (^gg)
0 51 116 016 23 030 050 77 453 46 96 26
60 48 127 015 21 027 045 61 457 45 67 25
120 49 120 016 26 029 051 66 643 59 59 25
240 49 103 019 29 030 067 54 977 53 53 24
Signif NS NS NS NS NS NS
Lsd5 05 04 013 164 24
Tuber P and Crop P removal P concentration in tubers
The concentration of P in tubers on freshly-applied Alkaloamreg increased with level of applied P (P lt 0001) The response at each level of Alkaloamreg was best described by a Mitscherlich curve although none of the curves reached a maximum within the range of fertiliser P levels used (Fig 49 (a)) There was a trend for an overall response to level of AG (P = 0081) P concentrations were generally higher on unamended soil than on amended soil For example at 300 kg Pha P concentration was 033 on unamended soil and 026-028 on amended soil and at 600 kg Pha P concentrations were 036 and 032-033 on unamended and amended soil respectively At P levels corresponding to 99 of maximum yield tuber P concentration was 031 024 023 and 028 at 0 60 90 and 1201 AGha
On residual AG tuber P concentration did not change with level of AG The overall mean was 036 dry basis
Total P uptake
Total P uptake by tubers on freshly-applied AG showed a significant response to level of AG (P lt 005) and level of applied P (P lt 0001) The response to applied P at each level of AG was best described by a Mitscherlich curve although as for tuber P concentration none of the curves reached a maximum within the range of P levels applied P uptake by tubers on unamended soil was significantly greater than on amended soil regardless of AG level (Lsd 5) (Fig 49 (b)) At levels of applied P corresponding to 99 of maximum yield P uptake by tubers was 113 75 75 and 95 kgha at 0 60 90 and 1201 AGha These figures are lower than results reported by Hegney et al (1997) who found a P uptake by tubers grown on yellow Karrakatta sand of 204 kgha at 99 of maximum yield even though yields were similar to those observed on unamended soil in this experiment
13
The use of Red Mudgypsum in vegetable production
Total P uptake by tubers was not significantly different between AG levels on residual AG Overall mean P uptake was 110 kgha This is different from the situation observed at 600 kg Pha on freshly-applied AG As only one level of P was applied the response curve for tuber P concentration on residual AG cannot be compared with that on freshly-applied AG It is possible that less applied P is required on residual than on freshly-applied AG to reach maximum tuber P concentration
Metals in tubers
The concentration of As in tubers harvested from freshly-applied AG showed a trend to increase with level of AG from 5 x 104 mgkg (fresh weight) on unamended soil to 8 x 104 mgkg at 60 and 901 AGha (Fig 410) Concentrations of all other metals measured showed no response to level of AG either on residual or freshly-applied AG (Table 46 47) On freshly-applied AG concentrations of Ni and Cd increased and concentrations of Cu decreased with increasing level of applied P (Table 48)
Table 46 Mean concentrations (mgkg fresh weight) of metals in tubers of potato cv Delaware harvested from a yellow Karrakatta sand amended with freshly-applied Alkaloam^gypsum (AG)
Cr Co Sn Sb Hg
mean
se
0007
61 xlO5
60 x 104
50 x 106
15 x 103
10 x 104
90 x 105
10 xlO5
34 x 104
14 x 105
Table 47 Mean concentrations (mgkg fresh weight) of metals in tubers of potato cv Delaware harvested from a yellow Karrakatta sand amended with residual Alkaloamreggypsum (AG)
Cr Co Ni Cu As Cd Sn Sb Hg Pb
mean
se
001
68X104
72xl(f 29xia5
55xia3
17x1a4
010
35xia3
L2X103
0
58xia3
17X104
LOxlO3
29X104
30X1O4
43xl05
84X1G4
ii xia5
l ixia3
70xia5
Table 48 Mean concentrations (mgkg fresh weight) of metals in tubers of potato cv Delaware harvested from a yellow Karrakatta sand amended with freshly-applied Alkaloamreggypsum (AG) at various levels of applied P
Applied P (kgha)
Ni Cd Cu
0 0006 0002 018
100 0006 0002 016
300 0007 0004 015
600 0008 0006 013
Signif
Lsd (5) 00014 0001 002
The concentrations of As observed in tubers from freshly-applied AG regardless of the level of AG were less than 10 of the legal limit (10 mgkg fresh weight NFA 1992) The concentrations of all metals measured were between 3 and 33 of those measured in potato tubers in a previous experiment (Robertson et al 1994 Appendix 1 J) The concentrations on residual AG were also lower than the concentrations previously observed in lettuce and cauliflowers on the same site (Robertson et al 1994 Appendix IH I) As different batches of
14
The use of Red Mudgypsum in vegetable production
AG were used on the two sites they cannot be compared to determine the effect of time on metal availability and uptake Overall metal uptake by potato tubers grown on AG-amended yellow Karrakatta sand does not appear to pose any greater health risk than that on unamended yellow Karrakatta sand The observed increase in As concentration in potato tubers on freshly-applied AG was probably due to the increase in soil pH with level of AG (ONeill 1990)
Conclusions
Freshly-applied AG reduces the availability of fertiliser P so that approximately 25 times the level of applied P is required on 60 to 1201 AGha relative to unamended soil in order to attain maximum P concentration in plant tissues AG at 120 tha also increases the retention of fertiliser P sufficiently to reduce fertiliser requirements for a following potato crop by approximately 20 The effect of AG on the level of fertiliser P required for 99 of maximum yield was confounded in this experiment by the decrease in maximum yield between unamended and amended soil Total yield of potatoes will be reduced on 60 tha freshly-applied AG and by 240 tha residual AG probably by a limiting concentration of K There is potential for increased levels of K fertiliser to overcome this yield reduction AG increases the proportion of yield which is marketable so that even though total yield is reduced by 60 tha of freshly-applied AG the marketable yield is not There are no apparent problems with heavy metal contents of tubers due to amendment with AG
References Allen DG and Jeffery RC (1990) Methods for analysis of phosphorus in Western
Australian soils Chemistry Centre of WA Report of Investigation No 37
Anonymous (1977) Technicon Industrial Method 334-74WB+ Technicon Industrial Systems Tarrytown NY USA
Barrow NJ (1982) Possibility of using caustic residue from bauxite for improving the chemical and physical properties of sandy soils Australian Journal of Agricultural Research 275-285
Colwell JD (1963) The estimation of phosphorus fertiliser requirements of wheat in southern New South Wales by soil analysis Australian Journal of Experimental Agriculture and Animal Husbandry 3 190-197
Glenister DJ and Thoraber MR (1985) Alkalinity of red mud and its application for the management of acid wastes Chemeca 85 109-113
Harris PM (1992) Mineral Nutrition In The Potato Crop The scientific basis for improvement 2nd edition (ed P Harris) pp 162-213 (Chapman and Hall London UK)
Harter RD (1983) Effect of soil pH on adsorption of lead copper zinc and nickel Soil Science Society of America Journal 47 47-51
Hegney MA McPharlin IR and Jeffery RC (1997) Response of winter-grown potatoes (Solanum tuberosum L) to applied and residual phosphorus on a Karrakatta sand Australian Journal of Experimental Agriculture 37 (in press)
Maier NA Williams CMJ Potocky-Pacay K Moss D and Lomman GJ (1987) Interpretation standards for assessing the nutrient status of irrigated potato crops in South Australia Technote AGDEX 262533 September 1987 Department of Agriculture South Australia
15
The use of Red Mudgypsum in vegetable production
McArthur WM and Bettenay E (1960) The development and distribution of the soils of the Swan Coastal Plain Western Australia CSIRO Division of Soils Soils Publication No 16
McPharlin IR Jeffery RC Toussaint LF and Cooper M (1994) Phosphorus nitrogen and radionuclide retention and leaching from a Joel sand amended with red mudgypsum Communications in Soil Science and Plant Analysis 25 489-500
McQuaker NR Brown DF and Kluckner PD (1979) Digestion of environmental materials for analysis by inductively coupled plasma atomic emission spectrometry Analytica Chimica 51 1082-1084
Murphy J and Riley JP (1962) A modified single solution method for the determination of phosphate in natural waters Analytica Chimica Acta 27 31-36
NFA (National Food Authority) (1992) Australian Food Standards Code June 1992 (Australian Government Publishing Service Canberra)
ONeill P (1990) Arsenic In Heavy Metals in Soils(ed BJ Alloway) pp 83-99 (Blackie Glasgow)
Ozanne PG and Shaw TC (1967) Phosphate sorption by soils as a measure of the phosphate requirement for pasture growth Australian Journal of Agricultural Research 18 601-612
Robertson WJ McPharlin IR and Jeffery RC (1994) Final Report of investigation into the use of gypsum-amended red mud as a soil-amendment on horticultural properties on the Swan Coastal Plain Agriculture WA
Robertson WJ McPharlin IR and Jeffery RC (1997) Residues from bauxite-mining (red mud) increase phosphorus retention of a Joel sand without reducing yield of carrots Communications in Soil Science and Plant Analysis (in press)
Yuen SH and Pollard AG (1954) Determination of nitrogen in agricultural materials by the Nessler reagent II Micro-determination in plant tissue and in soil extracts Journal of Food in Agriculture 5 364-369
16
The use of Red Mudgypsum in vegetable production
300
250 -
I I
200
3
60 80
AG (tha)
140
Figure 41 Total phosphorus concentration in a yellow Karrakatta sand amended with freshly-applied Alkaloamreggypsum (AG) vs level of AG when 0 (bull) 100 (A) and 600 (bull) kg Pha was applied measured at 0-15 cm () 15-30 cm (mdash) and 30-45 cm (mdash) depth Bars are Lsds at 5 level of significance
17
The use of Red Mudgypsum in vegetable production
Z3
200
180 -
160
Q- 140
ro 120 bull 4 -
O CD X 100 CD i
3 80 CO c o
pound gt v_ CO
o CQ
AG Depth
I
0 20 40 60 80 100 120
AG (tha)
140
Figure 42 Bicarbonate-extractable phosphorus concentration in a yellow Karrakatta sand amended with freshly-applied Alkaloamreggypsum (AG) vs level of AG when 0 (bull) 100 (A) and 600 (bull) kg Pha was applied measured at 0-15 cm () 15-30 cm (mdash) and 30-45 cm (mdash) depth Bars are Lsds at 5 level of significance
18
The use of Red Mudgypsum in vegetable production
700
600
500
D)
3 400
CL
oil
300 CO
200
100
100 150
A G (tha)
250
Figure 43 Total (mdash) and Bicarbonate-extractable phosphorus () concentration in a yellow Karrakatta sand amended with residual Alkaloamreggypsum (AG) when 600 kg Pha was applied measured at 0-15 cm () 15-30 cm (A) and 30-45 cm (bull) depth Bars are Lsds at 5 level of significance
19
The use of Red Mudgypsum in vegetable production
CO
2 CD
gt-
200 300 400
Applied P (kgha)
Figure 44 (a) Total yield of potatoes cv Delaware grown on a yellow Karrakatta sand amended with freshly-applied AIkaIoamreggypsum (AG) at a level of 0 (bull) 60 (A) 90 (bull) and 120 (bull) tha vs level of applied P Lines represent the level of applied P required for 99 of maximum yield Bars are Lsds at 5 level of significance
Equations are
A
B
C
D
0 tha
60 tha
90 tha
120 tha
j - 614 - 255 x exp (-00152) (JR= 092)
y = 542 - 271 x exp (-00176) (R2= 090)
y = 552 - 274 x exp (-0021) (F= 094)
y = 566 - 229 x exp (-00092) (i^= 098)
20
The use of Red Mudgypsum in vegetable production
ro
JO
gt-
100 200 300 400
Applied P (kgha)
500 600
Figure 44 (b) Total yield of potatoes cv Delaware grown on a yellow Karrakatta sand amended with freshly-applied Alkaloamreggypsum (AG) at a level of 0 (bull) 60 (A) 90 (bull) and 120 (bull) tha vs level of applied P Lines represent the level of applied P required for 99 of maximum yield Bars are Lsds at 5 level of significance
Equations are
Otha A
B
C
D
60 tha
90 tha
120 tha
y = 547 - 216 x exp (-0021) (R2^ 088)
y = 517 - 278 x exp (-0019) (R2= 090)
y = 524 - 243 x exp (-001 to) (R2= 094)
y = 530 - 218 x exp (-001 Ox) (i^= 098)
21
The use of Red Mudgypsum in vegetable production
CO
32
gt-
80
70
60
50
40
30
20
10
0 0
Marketable yield
Marketable yield
Total yield
Total yield
_L 50 100 150 200
AG (tha)
250 300
Figure 45 Total (bull) and Marketable (bull) yield of potatoes cv Delaware grown on a yellow Karrakatta sand amended with residual AIkaloamreggypsum (AG) vs level of AG 600 kg Pha was applied Bars are Lsds at 5 level of significance
22
The use of Red Mudgypsum in vegetable production
w CO CO
a gtraquo i _
C
o 00
c CD O c o o
100 200 300 400
Applied P (kgha)
500
Figure 46 Concentration (dry basis) of phosphorus in petioles of the Youngest Mature Leaf of potatoes cv Delaware grown on a yellow Karrakatta sand amended with freshly-applied Alkaloamreggypsum (AG) at 0 (bull) 60 (A) 90 (bull) and 120 (bull) tha vs level of applied P Lines represent the level of applied P required for 99 of maximum yield Bars are Lsds at 5 level of significance
Equations are
A Otha y = 117- 079 x exp (-0020) (R2 = 096)
B 60 tha y=123- 096 x exp (-000874) (R2 - 099)
C 90 tha y = 118 - 0884 x exp (-000742) (R2 = 096)
D 120 tha y= 117 - 090 x exp (-00085) (R2 = 097)
23
The use of Red Mudgypsum in vegetable production
CO
c
53
CD
gt-
00 02 04 06 08 10
Petiole P ( dry basis)
12 14
Figure 47 Yield of potatoes cv Delaware grown on a yellow Karrakatta sand amended with freshly-applied AlkaIoamreggypsum (AG) at 0 (bull) 60 (A) 90 (bull) and 120 (bull) tha vs petiole P concentration
The equation is y = 256 + 274x (ft2 = 087)
24
The use of Red Mudgypsum in vegetable production
poundgt 3
0 100 200 300 400 500 600 700
Applied P (kgha)
Figure 48 (a) Concentration of Zinc and (B) Calcium ( dry weight) in petioles of the youngest mature leaf of potatoes cv Delaware harvested from a yellow Karrakatta sand amended with freshly-applied Alkaloamreggypsum (AG) at 0 (bull) 60 (A) 90 (bull) and 120 (bull) tha vs level of applied P Bars are Lsds at 5 level of significance
25
The use of Red Mudgypsum in vegetable production
100 200 300 400 500
Applied P (kgha)
700
Figure 48 (b) Concentration of Calcium ( dry weight) in petioles of the youngest mature leaf of potatoes cv Delaware harvested from a yellow Karrakatta sand amended with freshly-applied AlkaIoamreggypsum (AG) at 0 (bull) 60 (A) 90 (bull) and 120 (bull) tha vs level of applied P Bars are Lsds at 5 level of significance
The use of Red Mudgypsum in vegetable production
040
ogt 035 CD
gtgt bullo
w _CB O
H) CL
CO 1 _ -mdashraquo c CD O c o o Q
030 -
025 -
020
2 015
010 -
005
000 0 100 200 300 400
Applied P (kgha)
500 600
Figure 49 (a) The concentration of phosphorus in tubers ( dry weight) of potatoes cv Delaware harvested from a yellow Karrakatta sand amended with freshly-applied Alkaloamreggypsum (AG) at 0 (bull) 60 (A) 90 (bull) and 120 (bull) tha vs level of applied Pkgha Bars are Lsds at 5 level of significance
Equations are
A 0 tha
B 60 tha
C 90 tha
D 120 tha
y = 0372 - 0243 x exp (-00058) (R2 = 097)
y = 0378 - 0257 x exp (-00029x) (R2 = 098)
y = 0361 - 0216 x exp (-00029x) (i^= 095)
y = 0406 - 0279 x exp (-0002x) (R2 = 098)
27
The use of Red Mudgypsum in vegetable production
CO
3
ltD
CO Q Z5
ID
B
14
12 -^ ^
10
8 W
6
4
A G P
I
2
n I i i I I i
0 100 200 300 400
Applied P (kgha)
500 600
Figure 49 (b) Phosphorus uptake Gigha) by tubers of potatoes cv Delaware harvested from a yellow Karrakatta sand amended with freshly-applied Alkaloamreggypsum (AG) at 0 (bull) 60 (A) 90 (bull) and 120 (bull) tha vs level of applied P Bars are Lsds at 5 level of significance
Equations are
Otha A
B
C
D
60 tha
90 tha
120 tha
y = 140 - 1095 x exp (-00058r) (R2 = 096)
3= 111 - 882 x exp (-0004x) (R2 = 098)
y = 104 - 774 x exp (-00053) (R2 = 099)
3 = 127 -101 x exp (-00029x) (R2 = 0997)
28
The use of Red Mudgypsum in vegetable production
60 80
AG (tha)
Figure 410 Concentration of Arsenic (dry weight) in tubers of potatoes cv Delaware grown on a yellow Karrakatta sand amended with freshly-applied Alkaloamreggypsum (AG) Bar is Lsd at 5 level of significance
29
The use of Red Mudgypsum in vegetable production
5 RESPONSE OF CAULIFLOWERS TO FRESHLY-APPLIED RED MUD (ALKALOAMreg)GYPSUM AND PHOSPHORUS ON A YELLOW KARRAKATTA SAND
Introduction
It is important to reduce the leaching of phosphorus fertiliser from sandy soils used for vegetable production into the water systems of the Swan Coastal Plain Red Mud (AlkaloamR)gypsum (AG) a waste product from bauxite refining has been suggested as an amendment to reduce phosphorus leaching from sands of the Bassendean Association (Joel Gavin) used for agriculture and horticulture (Barrow 1982)
Experimental work in the field and pots showed amendment with AG significantly reduced P leaching from Joel and Gavin sands (Vlahos et al 1989 McPharlin ei al 1994) compared with the unamended (01 AGha) treatment
In previous work freshly-applied AG at 60 tha increased the amount of freshly-applied P required for maximum yield of cauliflowers 14 (autumn planted) but did not reduce maximum yield (20 tha) compared with the unamended (0 tha) treatment on a yellow Karrakatta sand (Robertson et al 1994) At the highest rate of applied AG (120 tha) P required for maximum yield was 32 higher than at 0 tha and maximum yield was reduced 23 (P lt 005)
Since more than 60 tha of AG may be required to significantly improve P retention by sands to enable sustainable horticultural production this yield reduction is re-examined with freshly-applied AG
Materials and methods
Site characteristics
The experiment was conducted on a yellow Karrakatta sand (McArthur and Bettenay 1960) of low P fertility at Medina Research Centre (32deg 13 S 115deg 49 E) 30 km South of Perth The site had no previous history of AG application and had been sown to pasture for several years Some relevant chemical characteristics of the topsoil (0-15 cm) and subsoil (15-30 cm) of the site after application of AG but prior to the application of fertiliser and transplanting are presented in Table 51
Red Mud (AlkaIoamreg)gypsum (AG)
Alkaloamreg (Red Mud) amended with 10 (ww) gypsum (AG) was produced by the dry mix process by ALCOA of Australia Ltd at their Kwinana Residue Treatment Plant The AG was spread manually on the site and incorporated using a rotary hoe to approximately 30 cm depth on 21 February 1996 The site was watered for 1 hour per day (8 mmday) using impact sprinklers until planting
Experimental design
The experimental design was a split-plot randomised block with 3 replicates The main plots were levels of AG (0 60 120 and 240 tha) and the sub-plots were levels of freshly-applied P (0 50 100 200 400 and 600 kgha) Main plots measured 6 x 12 m and sub-plots 12 x 6 m (excluding wheel tracks)
Crop management
The site was sprayed with Roundupreg (3 Lha) twice after application of AG and prior to planting to control weeds
The use of Red Mudgypsum in vegetable production
Six week old seedlings of cauliflowers (cv Plana) obtained from a commercial nursery were transplanted manually on 18 April 1996 in 2 rows per plot with 70 cm between rows and 50 cm between plants Seedlings were dipped in Rovralreg 1 mLL just prior to planting for control of fungi Treflanreg (14 Lha) and Dacthalreg (12 kgha) were applied immediately after transplanting to control broadleaved weeds and Sertinreg later on in the life of the crop for grass control Ambushreg (100 mLha) and Rogorreg (100 mLha) were used to control caterpillars and red legged earth-mite respectively Copper sprays were used for control of blackrot The crop was irrigated to a total application equivalent to 100 of the previous days pan evaporation using minisprinklers (Legoreg 6 x 6 m spacing 44 mmh) in 3 waterings of equal duration per day
Fertilisers
Pre-planting fertilisers were broadcast manually and rotary hoed on 17 April 1996
These were K2S04(244) Ca (N03)2 4H20 (387) MgS047H20 (504) MnS04H20 (504) FeS047H20 (18) Borax (27) CuS045H20 (36) ZnSOH20 (28) and Na2Mo042H20 (2) Single superphosphate (91 P)was applied at 0 to 600 kgha according to treatment and incorporated as before Post-planting K N and Ca were fertigated via the irrigation system as KN03 NH4NO3 and Ca (N03)2 in equal amounts per day for 12 weeks to a total of 600 kg K 423 kg N and 60 kg Caha Borax was fertigated at 20 kgha in week 3 and Mg was broadcast as MgS047H20 at 50 kgha in weeks 3 6 and 9
Measurements
Soil and soil solution
All zero P subplots were sampled 30 cores per plot just prior to planting and fertilising about 2 months after AG application to 2 depths (0-15 15-30 cm) These were oven dried at 40degC and analysed for Ec pH (CaCl2) P sorption (Ozanne and Shaw 1968) bicarbonate extractable P K (Colwell 1963) total P PRI P sorption K sorption (Allen and Jeffery 1990) and cation exchange capacity (Gillman and Sumpter 1986)
The soil water was obtained by centrifugation from soil samples (0-15 cm 30 per plot) and collected from the 0 100 200 and 600 kg Pha plots across all AG treatments on 16 May 1996 The supernatant was analysed for pH Ec Ca Mg K S and P The remaining soil was analysed for pH (H20) bicarbonate extractable P and K PRI and DTPA extractable Zn After harvest on 5 August 1996 soil samples were collected from 2 depths as for the preplanting treatment from all plots These were analysed for pH bicarbonate extractable P K total P PRI and exchangeable cations (Ca Mg K and N)
Plant
At buttoning on 13 June 1996 the younger mature leaves (YML) (4th from growing point) were collected from 16 plants in each plot (excluding 1 m buffer at each end) They were dried at 70degC in a force draught oven for 48 h and ground to pass through a 1 mm screen Sub-samples were digested with sulphuric acidhydrogen peroxide (Yuen and Pollard 1954) and the concentration of N P and K measured by an automated colorimetric process (Varley 1966) Concentration of other nutrients (B Ca Na Mg S Fe Mn Zn and Cu) were determined by inductively coupled plasma atomic emission spectroscopy (ICP-AES) after digestion with nitric-perchloric acids (McQuaker et al 1979)
Five whole plants were harvested from the middle of each plot (2 per row)at the end of the experiment on 4 July 1996 using shovels to recover as much of the root system as possible The plants were separated into four categories curds leaves stems and roots All soil was washed from the roots using tap water shaken and the excess water removed using paper towels The fresh weight of all four categories was recorded and the material was diced into small pieces (lt 8 cm3) using stainless steel knives sub-samples (300 g fresh weight) were collected at random from the diced pieces and the fresh weight recorded These were dried at
31
The use of Red Mudgypsum in vegetable production
70degC in a forced draught oven for 48 h and the dry weight recorded These samples were then analysed for P as for the youngest mature leaves Separate sub-samples (300 g fresh weight) of curds were collected and analysed for Ba Cd Cr Co Pb Mo Rb Sr Ti Th V and N using inductively coupled plasma mass spectrometry (ICP-MS) The fresh and dry weight of the curds leaves stems and roots at harvest were used to calculate P uptake in kgha)
Harvest
Harvest commenced when the leaves surrounding the head opened and exposed the curds 77-80 days after transplanting At this stage florets at the periphery of the curd had just begun to separate Sixteen curds (12 plus 4 from whole plant samples above) were collected from the central 4 m of both rows (1 m buffer) and all the leaves and stems removed according to requirements for export market Each fresh curd was weighed and rejects recorded if undersize (lt 500 g) oversize (gt 2000 g) discoloured (yellowing) overmature (separation of florets in centre of curd) diseased damaged or otherwise distorted The total marketable and reject yield were recorded for each plot
Analysis of data
Analysis of variance was carried out on level of applied AG or P versus (a) chemical characteristics of soil (bicarbonate extractable P total P etc) preplanting and harvest (b) concentrations of nutrients in soil solution at midgrowth (c) concentration of nutrients in YMLs at midgrowth (d) concentration of elements in curds at harvest (e) P uptake by plant parts and (f) total marketable and reject yield of curds at harvest Mitscherlich curves and inverse polynomials were fitted to the relationship between level of applied P and yield at each level of applied AG The level of applied P required for 95 99 and 100 (in case of inverse polynomials) of maximum yield was calculated Mitscherlich curves were fitted to the relationship between level of applied P and P in YMLs at midgrowth at all levels of AG The P in YMLs corresponding to the level of applied P required for 95 99 or 100 of maximum yield (as determined from yield versus applied P plots) was then determined
Mitscherlich curves were also fitted to the relationship between level of applied P and P uptake by curds leaves stems and roots and the P uptake corresponding to whole plants (additions of all 4) level of P required for 95-100 of maximum yield determined Phosphorus uptake by plant parts or whole plants on 0 P plots were detected from P uptake at other rates to account for non-fertiliser sources of P This was used to adjust P uptake When determining P fertiliser recovery efficiency (RE) by plant parts or whole plants (ie fertiliser P uptake by plant parts or whole plantsP applied both in kgha Novoa and Loomis 1981)
Results
Effects of fresh AG on chemical characteristics of soil and soil solution
There was a significant (P lt 005) increase in the Ec pH PRI and sorption capacity (topsoil only) of the topsoil and subsoil of a yellow Karrakatta sand with level of freshly-applied AG prior to fertiliser application and planting (Table 51) There was no significant effect of level of AG on Colwell K K sorption capacity and total P with level of freshly-applied AG (Table 51)
The use of Red Mudgypsum in vegetable production
Table 51 Some chemical characteristics of the topsoil (0-15 cm) and subsoil (15-30 cm) of a yellow Karrakatta sand after application of Alkaloam gypsum (AG)1 just prior to fertiliser application and transplanting
(a) Topsoil (0-15 cm)
AG (tha)
Ec (mSm)
pH (CaCl2)
BicP2
(Vigfe)
BicK2
(pgg) PRI3
(mLg) TP4
(Pgg) CEC5
(me ) Kads6 Pads7
0 37 74 107 153 097 507 2 0 41
60 67 82 93 197 167 473 2 043 66
120 80 82 100 277 243 607 2 044 78
240 103 84 97 290 38 637 2 058 129
Lsd8 202 037 38 136 046 1010 0 049 41
Sig9 ns ns ns ns ns
(b) Subsoil (15-30 cm)
AG Ec PH BicP2 BicK2 PRI3 TP4
(tha) (mSm) (CaCl2) (Pgg) (Pgg) (mLg) (Pgg)
0 30 72 83 227 07 507
60 63 81 73 190 15 453
120 80 81 87 220 18 540
240 107 83 83 240 27 563
Lsd8 202 037 38 136 046 101
Sig9 ns ns ns
Applied 7 weeks previously 2 After Colwell (1963) 3 Phosphorus retention index after Allen and Jeffery (1990) 4 Total phosphorus 5 Cation exchange capacity (Gillman and Sumpter 1986) 6 Slope of K adsorption isotherm from the Freundlich equation (Allen and Jeffery 1990) 7 Slope of P adsorption isotherm from the Freundlich equation (Allen and Jeffery 1990) 8 Least significant difference at P lt 005 9 Significance at lt 0001 () lt 001 () lt 005 () level or not significant (ns)
There was a significant (P lt 005) increase in the concentration of Na and a decrease in the concentration of K in the soil solution with level of freshly-applied AG one month after planting and fertilising (Table 52 (a) and Fig 51) At the same time Colwell K and PRI in the topsoil increased significantly with level of freshly-applied AG By contrast there was a significant decrease in extractable Zn with level of AG The concentration of Ca Mg S and P increased significantly with level of applied P in soil solution (Table 52 (a)) Colwell P in the topsoil increased significantly with level of P whilst Colwell K PRI and extractable Zn decreased at the same time (Table 52 (b))
33
The use of Red Mudgypsum in vegetable production
Table 52 (a) Ec (mSm) pH and concentration of nutrients (pgmL) in soil solution 1 month after planting with level of freshly-applied Alkaloamreggypsum (AG)1 and phosphorus
AG
AG (tha)
Ec (mSm)
pH Ca (pgmL)
Mg (pgmL)
Na (pgmL)
K (pgmL)
S (pgmL)
P (pgmL)
Psrp2
(VigmL)
0 112 70 175 18 110 77 101 57 56
60 132 74 164 17 137 58 92 34 31
120 172 75 166 17 152 54 97 44 34
240 166 81 130 16 198 34 75 24 11
Lsd3 19 025 33 4 16 11 26 27 32
Sig4 ns ns ns ns ns
p
AG (tha)
Ec (mSm) PH
Ca (pgmL)
Mg (pgmL)
Na (pgmL)
K (pgmL)
S (UgmL)
P (pgmL)
Psrp2
(pgmL)
0 137 78 99 15 150 46 26 10 01
100 142 76 112 15 153 54 52 23 14
200 170 74 179 19 150 62 114 39 30
600 133 72 244 19 144 60 174 89 87
Lsd3 43 022 31 24 17 15 29 25 30
Sig4 ns ns ns
Applied 11 weeks previously
Soluble reactive P 3 Least significant difference at P lt 005 4 Significance at lt 0001 () lt 001 () lt 005 () level or not significant (ns)
The use of Red Mudgypsum in vegetable production
220
200
E 180 O ) 3
^ 1fi0 _ o 3 140 O V)
oil
120 m c
100 C o CO 80 c flgt o B0 c o o 40
20
0 50 100 150 200
Freshly-applied AG(tha)
250 300
Fig51 Concentration (ugml) of Na(i ) and K ( bull ) in soil solution (0-15cm) under cauliflowers one month after planting with level of freshly-applied AlkaloamRgypsum(AG) Vertical bars indicates Lsd (Plt005) for differences in concentration betweeen levels of AG
35
The use of Red Mudgypsum in vegetable production
Table 52 (b) Extractable P K Zn and phosphorus retention index of the top soil (0-15 cm) of a yellow Karrakatta sand 1 month after transplanting with level of freshly-applied Alkaloamreggypsum (AG)1 and phosphorus (P)
AG
AG (tha)
P2
(ugg) K2
(Ugg) Zn3
(Pgg)
PRI4
(mLg)
0 47 32 67 -112
60 76 38 15 -090
120 94 42 26 -049
240 84 41 13 092
Lsd5 35 6 28 073
Sig6 ns
P P2 K2 Zn3 PRI4
(kgha) (ugg) (Hgg) (Ugg) (mLg)
0 8 42 31 201 100 35 37 45 043 200 80 39 18 -089 600 177 34 26 -313
Lsd5 39 6 27 082
Sig6 ns
Applied 11 weeks previously 2 After Colwell (1963) 3 Extracted in DTPA 4 Phosphorus retention index (Allen and Jeffery 1990) 5 Least significant difference at P lt 005 6 Significance at lt 0001 () lt 001 () lt 005 () level or not significant (ns)
Ec pH exchangeable Ca K Na in me and Colwell P K total P PRI and PRIP increased significantly (P lt 005) with level of freshly-applied AG in the topsoil and subsoil of a yellow Karrakatta sand (Table 53 (a) (b) and Fig 52) at harvest
The use of Red Mudgypsum in vegetable production
o CO
CD
E
o CO
co o
CD
X co CD ogt e co sz o X HI
50 100 150 200
Freshly-applied AG (tha)
250 300
Fig52 Exchangeable Ca() NaP) and K(A) cations (me dry soil) in topsoil (0-15cm) of Karrakatta sand amended with freshly-applied AlkaloamRgypsum(AG) after harvest of cauliflowers Vertical bars indicates Lsd (Plt005) for differences in concentration between levels of AG Lsd not shown when less than size of symbol
37
The use of Red Mudgypsum in vegetable production
Table 53 Ec (mSm) pH and exchangeable Ca Mg K and Na (me ) in the topsoil (0-15 cm) and subsoil (15-30 cm) of a yellow Karrakatta sand amended with AlkaIoamreggypsum (AG) at harvest of cauliflowers
(a) Topsoil
AG Ec PH Ca Mg K Na (tha) (mSm) (CaCl2) (me ) (me ) (me ) (me )
0 67 66 229 018 005 003
60 91 77 382 019 009 02
120 99 79 558 019 012 043
240 120 80 975 024 014 104
Lsd2 20 014 064 0033 0018 021
Sig3 ns
(b) Subsoil
AG Ec pH Ca Mg K1 Na (tha) (mSm) (CaCl2) (me ) (me ) (me ) (me )
0 44 67 225 017 005 003
60 59 74 269 019 005 008
120 66 77 300 018 005 017
240 99 79 397 02 005 029
Lsd2 075 01 029 0036 001 002
Sig3 n s ns
Extracted in 1 m NH4CI 2 Least significant difference at P lt 005 3 Significance at lt 0001 () lt 001 () lt 005 () level or not significant (ns)
However there was no effect of either level of AG or P on exchangeable Mg in the soil at harvest Colwell P total P and PRIP increased significantly whilst Colwell K and PRI decreased with level of freshly-applied P in the topsoil at harvest (Table 4 (a) (b) and Fig 53)
The use of Red Mudgypsum in vegetable production
Table 54 P (extractable P total P phosphorus retention index and P sorption) in the top soil (0-15 cm) and subsoil (15-30 cm) of a yellow Karrakatta sand at harvest of cauliflowers with level of freshly-applied Alkaloamreggypsum (AG) and phosphorus (P)
(a) Topsoil
AG
AG BicP1 BicK1 TotP2 PRI3 PRIP3
(tha) (ugg) (Pgg) (Hgg) (mLg) (mLg)
0 39 23 92 -07 28
60 50 38 110 02 50
120 59 51 135 16 75
240 58 62 157 35 99
Lsd4 5 11 15 03 06
Sig5
P BicP1 BicK1 TotP2 PRI3 PRIP3
(kgha) (ugg) (Hgg) (ngg) (mLg) (mLg)
0 10 53 57 29 40
50 15 40 66 22 38
100 25 41 78 17 44
200 53 41 128 14 71
400 87 44 186 -01 86
600 120 41 226 -12 102
Lsd4 11 8 20 09 13
Sig5
1 After Colwell (1963) 2 After Allen and Jeffery (1990) 3 After Allen and Jeffery (1990) 4 Least significant difference at P lt 005 5 Significance at lt 0001 () lt 001 () lt 005 () level or not significant (ns)
39
The use of Red Mudgypsum in vegetable production
Table 54 P (extractable P total P phosphorus retention index and P sorption) in the top soil (0-15 cm) and subsoil (15-30 cm) of a yellow Karrakatta sand at harvest of cauliflowers with level of freshly-applied Alkaloamreggypsum (AG) and phosphorus (P)
(b) Subsoil (15-30 cm)
AG
AG BicP1 BicK1 TotP2 PRI3 PRIP3
(tha) (ugg) (Ugg) (Ugg) (mLg) (mLg)
0 33 20 79 -05 26
60 30 21 73 -01 30
120 33 27 77 08 42
240 26 24 76 13 40
Lsd4 10 2 10 04 10
Sig5 ns ns
P BicP1 BicK1 TotP2 PRI3 PREP3
(kgha) (ugg) (Vigg) (Ugg) (mLg) (mLg)
0 7 25 48 15 22
50 11 22 52 09 19
100 15 24 59 10 27
200 32 23 81 06 39
400 51 22 100 -03 47
600 67 21 117 -11 52
Lsd4 8 5 8 05 09
Sig5 ns
1 After Colwell (1963) 2 After Allen and Jeffery (1990) 3 After Allen and Jeffery (1990) 4 Least significant difference at P lt 005 5 Significance at lt 0001 () lt 001 () lt 005 () level or not significant (ns)
The use of Red Mudgypsum in vegetable production
100 150 200
Freshly-applied AG (tha)
300
Fig53 Concentration of total P(A) Colwell P() or K(laquo) in topsoil (0-15cm) with level of freshly-applied AlkaloamRgypsum (AG) after harvest of cauliflowers Vertical bars indicates Lsd (Plt005) for differences in concentration between levels of AG Lsd not shown when less than size of symbol
41
The use of Red Mudgypsum in vegetable production
Nutrients in leaves at midgrowth and harvest
There was a significant decrease in concentration of K and an increase in concentration of Na S Mn and Cu in youngest mature leaves (YML) of cauliflowers at buttoning with level of freshly-applied AG (Table 55) The concentration of P in YML at 01 AGha (049) was significantly higher than at 2401 AGha (044) but not at other levels Currently-applied AG had no significant effect on concentration of N Ca Mg Fe Zn or B in YML There was a significant increase in YML in the concentration of K P and S in YML with level of applied P whilst concentration of N Mg Mn and B were variable (Fig 54 55) Level of applied P had no significant effect on the concentration of Ca and Na in the YML (Table 55)
Table 55 (a) Concentration of macro-nutrients (dry weight basis) in youngest mature leaves of cauliflowers at buttoning with level of freshly-applied Alkaloamreggypsum (AG) and phosphorus (P)
AG
AG N1 K1 Ca2 S2 P1 Na2 Mg2
(tha) () () () () () () ()
0 482 393 240 081 049 036 023
60 484 383 251 084 046 040 024
120 506 357 255 081 046 045 024
240 494 355 246 088 044 056 025
Lsd3 026 012 024 005 003 006 0013
Sig4 ns ns ns ns
p
p N1 K1 Ca2 S2 P1 Na2 Mg2
(kgha) () () () () () () ()
0 523 316 254 066 024 046 025
50 489 372 255 081 041 049 026
100 503 388 229 084 048 042 024
200 472 379 250 089 050 046 024
400 494 390 242 093 057 043 023
600 470 385 258 091 057 039 022
Lsd3 027 024 036 005 003 008 0017
Sig4 ns ns
1 After Varley (1966) 2 After McQuaker et al (1979) 3 Least significant difference at P lt 005 4 Significance at lt 0001 () lt 001 () lt 005 () level or not significant (ns)
The use of Red Mudgypsum in vegetable production
0 50 100 150 200 250 300
Freshly-applied AG (tha)
Rg54 Concentration of N() K(B) and Ca(A) in youngest mature leaf (YML) at buttoning
of cauliflowers with level of freshly-applied AlkaloamRgypsum(AG) Vertical bars
indicates Lsd (Plt005) for differences in concentration between levels of AG
10
bdquo 09 lt Q OR ^ D) 07 c
tto
06 3
X3
to 05 _ l
gtbull 04 C
i3 03 c agt bull c 02 3
-z 01 0 50 100 150 200 250 300
Freshly-applied AG (tha)
Rg55 Concentration of S() Na(B) Mg(4) and P(T) in youngest mature leaf (YML) at buttoning
of cauliflowers with level of freshly-applied AlkaloamRgypsum(AG) Vertical bars indicates Lsd (Plt005) for differences in concentration between levels of AG
43
The use of Red Mudgypsum in vegetable production
The relationship between P in YML at buttoning and level of freshly-applied P was best described by Mitscherlich relationships at all levels of applied AG (Fig 56)
en c o 3
X2
gt
06
^
bull A
05 ^ S
04
03
02
01
n n i i i
0 100 200 300 400 500 600 700
Applied P (kgha)
o
X I
5 gt
06
05
04
03
02
01
00
- bull B
- bull bull ^
o
I I I I
0 100 200 300 400 500 600 700
Applied P (kgha)
100 200 300 400 500 600 700
Applied P (kgha)
100 200 300 400 500 600 700
Applied P (kgha)
Fig56 P in YML of Cauliflowers at buttoning () corresponding to applied P required for either 95 (dashed line) or 99 (whole line) of maximum yield at 0(A) 60(B) 120(C) or240(D)t of freshly-applied AlkaloamRgypsumha
The equations for the fitted lines are
A
B
C
D
y = 056 - 030 x exp (-00182) (R2 = 097)
y = 057 - 032 x exp (-00103) (R2 = 088)
y = 055 - 031 x exp (-00126) (R2 = 099)
y = 056 - 032 x exp (-00092) (R2 = 098)
The P in YML corresponding to level of freshly-applied P required for 99 of maximum yield was 053 057 055 and 055 for 0 60 120 and 240 tha respectively
44
The use of Red Mudgypsum in vegetable production
Table 55 (b) Concentration of micro-nutrients (dry weight basis) in youngest mature leaves of cauliflowers at buttoning with freshly-applied Alkaloamreggypsum (AG) and phosphorus (P)
AG
AG (tha)
Fe (Pgg)
Zn (Ugg)
Mn (vigg)
B (Pgg)
Cu1
(Pgg)
0 1354 251 217 211 26
60 1274 248 237 213 28
120 1353 253 240 217 27
240 1394 263 260 214 29
Lsd2 153 24 15 082 02
Sig3 ns ns ns
P Fe Zn Mn B Cu (kgha) (ngg) (ugg) (Pgg) (Ugg) (Pgg)
0 1418 268 212 215 26
50 1388 253 263 220 27
100 1301 267 251 217 29
200 1336 249 250 217 28
400 1282 255 232 204 28
600 1341 233 224 210 28
Lsd2 197 29 19 08 02
Sig3 ns ns ns
1 Extracted in 1 m NH4CI 2 Least significant difference at P lt 005 3 Significance at lt 0001 () lt 001 () lt 005 () level or not significant (ns)
There was a significant (P lt 005) decrease in the concentration of P Zn and an increase in the concentration of Na in whole leaves (WL) of cauliflowers with rate of freshly-applied AG at harvest (Table 56) Level of freshly-applied AG had no significant effect on concentration of N K Ca S Mg Fe Mn B or Cu Concentration of Ca S P and Na in (WL) at harvest increased significantly (P lt 005) with level of freshly-applied P whereas Zn concentrations decreased and concentrations of Mg Mn and B were variable Level of freshly-applied P had no significant effect on concentration of N K Fe or Cu in WL at harvest
45
A O O ltyi
4x
r en 00
9 400 200 o o o copy
ns
O
kgt ON
kgt
4gt
kgt 4 4 4^
kgt
ns
O 4 4 ON 4 k)
o
i mdash t mdash raquo
4 00
4 ON
4 4^ NO Q O
o copy ON
i mdash gt
b b 1 mdash t
b o p Vcopy
O 00 ON
o ON
gtmdash 5 co 5J M
o o
O in
o 4 Ncopy
o 4 O
p 4
p kgt 1 mdash t
copy
ON
o b NO
O ON
o 00
o 00
o ON I mdash
O ON
O 3 Z 5 raquoM
o b 4
O
kgt o kgt -J
p kgt 00
O kgt 00
O
kgt NO
copy kgt ON
The use of Red Mudgypsum in vegetable production
Table 56 (b) Concentration of micro-nutrients (dry weight basis) in leaves of cauliflowers at harvest with level of freshly-applied Alkaloamreggypsum (AG) and phosphorus (P)
AG
AG (tha)
Fe1
(ugg) Zn1
(vgg) Mn1
(vgg) B1
(vgg) Cu1
(vigg)
0 762 224 214 263 42
60 700 197 227 265 38
120 811 196 216 254 38
240 842 193 236 256 37
Lsd2 132 099 21 16 06
Sig3 ns ns ns ns
P (kgha)
Fe1
(pgg) Zn1
(^gg) Mn1
(Vigg) B1
(lJgg) Cu1
(Pgg)
0 786 233 213 248 36
50 625 235 241 266 37
100 833 207 237 270 41
200 938 192 235 265 44
400 725 178 208 259 37
600 765 169 206 250 37
Lsd2 230 21 21 11 063
Sig3 ns ns
After McQuaker et al (1979)
Least significant difference at P lt 005
Significance at lt 0001 () lt 001 () lt 005 () level or not significant (ns)
47
The use of Red Mudgypsum in vegetable production
Nutrients and heavy metals in curds at harvest
There was a significant (P lt 005) decrease in the concentration of K and P and an increase in the concentration of Ca and Na in the curds at harvest with level of freshly-applied AG Concentration of N Mg Fe Zn Mn B and Cu in the curds were unaffected by level of freshly-applied AG (Table 57) As level of freshly-applied P increased there was a significant (P lt 005) decrease in concentration of N S Mg Fe Zn Mn and B and an increase in concentration of K Ca P and Na in curds at harvest Concentration of Cu in curds were unaffected by level of applied P (Table 57 (b))
Table 57 (a) Concentration of macro-nutrients (dry weight basis) in curds of cauliflowers at harvest with level of freshly-applied Alkaloamreggypsum (AG) and phosphorus (P)
AG
AG N1 K1 Ca S1 P2 Na1 Mg1
(tha) () () () () () () ()
0 392 515 040 066 047 023 018
60 384 500 040 067 045 023 017
120 404 474 043 071 043 024 018
240 402 458 041 071 041 028 018
Lsd3 022 016 001 004 002 002 0006
Sig4 ns + ns ns
P
p N1 K1 Ca1 S1 P2 Na1 Mg1
(kgha) () () () () () () ()
0 496 417 034 097 031 016 019
50 400 518 043 068 040 023 018
100 376 483 042 063 042 025 017
200 372 501 044 063 047 027 017
400 371 498 042 062 052 028 017
600 358 505 041 060 052 027 016
Lsd3 027 02 003 005 002 003 001
Sig4
1 After McQuaker et al (1979) 2 After Varley (1966) 3 Least significant difference at P lt 005 4 Significance at lt 0001 () lt 001 () lt 005 () level or not significant (ns)
The use of Red Mudgypsum in vegetable production
Table 57 (b) Concentration of micro-nutrients1 (dry weight basis) in curds Cauliflowers at harvest with level of freshly-applied Alkaloam gypsum (AG) and phosphorus (P)
AG
AG (tha)
Fe1
(Ugg)
Zn1
(vigg) Mn1
(Pgg) B1
(Pgg) Cu1
(Pgg)
0 611 279 124 188 26
60 587 247 134 191 25
120 706 299 139 192 29
240 592 268 145 186 25
Lsd2 329 57 14 08 06
Sig3 ns ns ns ns ns
p
p (kgha)
Fe1
(Ugg) Zn1
(Pgg) Mn1
(Ugg) B1
(ugg)
Cu1
(Pgg)
0 976 492 156 202 31
50 520 279 145 198 26
100 507 230 135 186 24
200 432 208 127 190 24
400 739 239 131 183 28
600 567 192 120 177 24
Lsd2 270 61 142 114 061
Sig3 a s
1 After McQuaker et al (1979) 2 Least significant difference at P lt 005 3 Significance at lt 0001 () lt 001 () lt 005 () level or not significant (ns)
49
The use of Red Mudgypsum in vegetable production
Concentration of Ba in curds at harvest decreased and concentration of Ti increased significantly in curds at harvest with level of freshly-applied P (Table 58) As level of freshly-applied P increased concentrations of Pb and Rb decreased and of Sr decreased Ba concentrations were variable with level of freshly-applied P (Table 58)
Table 58 Concentration of Ba plus heavy metals1 (fresh weight basis) in curds of cauliflowers at harvest with level of freshly-applied Alkaloamreggypsum (AG) and phosphorus (P)
AG Ba Cd Cr Co Pb Ni Rb Sr Ti Th V (tha) (ngg) (ngg) (ngg) (ngg) (ngg) (ngg) (ngg) (ngg) (ngg) (ngg) (ngg)
0 797 7 34 7 13 34 590 1219 34 39 7
60 482 7 34 7 15 34 610 1146 46 52 8
120 583 7 43 7 20 34 616 1246 45 50 8
240 355 7 34 7 15 34 637 1152 41 45 8
Lsd2 141 1 13 16 11 15 74 188 5 16 1
Sig3 ns ns ns ns ns ns ns ns ns
MRL4 50 2000
P (kgha)
Ba (ngg)
Cd (ngg)
Cr (ngg)
Co (ngg)
Pb (ngg)
Ni
(ngg)
Rb (ngg)
Sr (ngg)
Ti
(ngg)
Th
(ngg)
V (ngg)
0 556 7 34 7 25 34 650 998 39 45 9
50 670 7 34 7 18 34 657 1387 50 74 9
100 576 7 34 7 11 34 570 1206 45 50 8
200 529 7 34 7 12 34 616 1293 39 39 7
400 523 7 48 7 19 39 596 1126 39 36 7
600 476 7 34 7 11 34 603 1126 36 36 7
Lsd2 121 1 16 1 15 6 40 181 19 29 2
Sig3 ns ns ns ns ns ns ns ns
MRL4 50 2000
Inductively coupled plasma mass spectrometry 2 Least significant difference at P lt 005 3 Significance at lt 0001 () lt 001 () lt 005 () level or not significant (ns) 4 Maximum residue limit
The use of Red Mudgypsum in vegetable production
P uptake by plants P uptake by whole plants or plant parts was unaffected by level of freshly-applied AG by but increased significantly with level of freshly-applied P (Table 59)
P uptake by whole plants increased from 50 kg Pha to 19 to 21 kgha at 400 to 600 kg applied Pha respectively Curd root stem and leaf uptake was 33 5 6 and 50 respectively of total plant P uptake at the highest level of applied P (Table 59)
Table 59 P uptake (kgha) by curds roots stem leaf and whole cauliflower plants at harvest with level of freshly-applied Alkaloamreggypsum (AG) and phosphorus (P)
AG
AG Curds Roots Stem Leaf Total (tha) (kgha) (kgha) (kgha) (kgha) (kgha)
0 53 074 11 87 158
60 48 066 10 83 148
120 47 069 11 79 143
240 45 060 10 74 135
Lsd1 065 015 025 21 31
Sig-2 ns ns ns ns ns
p
p (kgha)
Curd (kgha)
Root (kgha)
Stem (kgha)
Leaf (kgha)
Total (kgha)
0 12 030 040 29 49
50 40 058 100 68 124
100 51 053 112 76 143
200 59 075 120 93 172
400 67 093 131 115 205
600 61 094 121 102 185
Ls-d1 055 017 020 18 25
Sig2
1 Least significant difference at P lt 005 2 Significance at lt 0001 () lt 001 () lt 005 () level or not significant (ns)
51
The use of Red Mudgypsum in vegetable production
Yield
There was a significant (P lt 005) increase in both total and marketable curd yield with level of freshly-applied P at all levels of freshly-applied AG (Table 510) There was no significant effect of level of freshly-applied AG on either total (Table 510 (a)) or marketable (Table 510 (b)) curd yield
Table 510 Curd yield (total marketable) of cauliflowers (tha) at harvest with level of freshly-applied Alkaloamreggypsum (AG) and phosphorus (P)
(a) Total
p (kgha)
AG (tha) p
(kgha) 0 60 120 240
0 755 468 483 177
50 1464 1675 1554 1516
100 2169 1706 1757 1985
200 2242 1737 1928 1862
400 1752 2102 2155 2136
600 1689 1764 1768 2023
Lsd1
Sig2
16 (AG)
ns 201 (P)
401 (AGP)
-
(b) Marketable
p (kgha)
AG (tha) p
(kgha) 0 60 120 240
0 274 060 000 000
50 1222 1463 1294 1152
100 2057 1416 1603 1820
200 2141 1377 1803 1752
400 1572 2020 2095 1996
600 1468 1534 1500 1974
Lsd1
Sig2
24 (AG)
ns
46 (P)
52(AGP)
ns
Least significant difference at P lt 005 2 Significance at lt 0001 () lt 001 () lt 005 () level or not significant (ns)
The relationship between total yield and level of freshly-applied P was best described by a quadratic relationship at all levels of freshly-applied AG (Fig 57) As level of AG increased the level of freshly-applied P required for 99 of maximum yield increase from 124 kg Pha at 0 t AGha to 339 kg Pha at 240 tha There was no significant effect of level of freshly-applied AG on maximum curd yield (Fig 57)
The use of Red Mudgypsum in vegetable production
26
24
22
(tha
) 20
18
Cur
d yi
eld 16
14
12
10
8
6 i ii
A=0
i i i i i
I I
0 100200300400500600700
Applied P (kgha)
24 22 20 18 16 14 12 10 8 6 4 2
- 7 I
_ bull
i i i n
mdash^ B=60
I I I
0 100200300400500600700
Applied P (kgha)
co
32 CD
gt 2 3
o
25
20
15
10
5
bull j
- bull
I I I I I
- - gt C=120
l l l
0 100200300400500600700
Applied P (kgha)
0 100200300400500600700
Applied P (kgha)
Fig57 Total curd yield (tha) of cauliflower with level of freshly-applied Alkaloam gypsum and
phosphorus (ABCD = 060120240 tha) Vertical lines represent applied P necessary
for either 95 (dashed) or 99 (whole) of maximum yield
The equations for the fitted lines are
A y = 1336 + (-577 + 01335x)(l-00088x +000007872) (Z2
B y = 89434 + 00705 - OOOOlx2 (R2 = 070)
C y = 84752 + 00810 - OOOOlx2 (B2 = 081)
D y = 733 +00871x - 00001 Ix2 (R2 = 099)
098)
53
The use of Red Mudgypsum in vegetable production
Discussion
The increase in pH Ec PRI and P sorption of Karrakatta sands with level of freshly-applied AG prior to fertiliser application is similar to that reported for the amendment of Joel (McPharlin et al 1994 and Robertson et al 1997a) and Karrakatta sands (Robertson et al 1994 and 1997b) with AG The increase in DH and Ec of the amended soil is explained by the high levels of both in the AG (ie pH (CaCr) = 94 and Ec = 623 mSm Appendix 1) The increased retentionsorption of P is explained by the addition of iron (974) and aluminium (551) in various oxides and hydroxides in the AG (Appendix 1 and Barrow 1982) to the soil After the application of P fertilisers levels of P in the soil at mid-growth and harvest as measured by total and Colwell P increased with a parallel decrease in PRI The increase in the levels of exchangeable Ca and Na in the soil at the same times with level of freshly-applied AG can be attributed to the AG itself However the increase in exchangeable and Colwell K appears to be due to improved K retention capacity of the soil due to physical properties of the AG rather any increased supply of K from the AG Whilst the overall K adsorption properties of the soil as measured by the Freundlich isotherm was not significantly increased with level of AG K sorption at 2401 AGha was significantly higher than at 01 AGha
There was no significant increase in cation exchange capacity (CEC) with level of freshly-applied AG on the Karrakatta sand in this experiment which remained about 2 me By contrast the CEC of virgin Joel sands increased from 1 to 2 me with level of freshly-applied AG (0 to 240 tha) in columns (McPharlin et al 1994) The application of AG would be expected to increase the CEC of coarse sands because (1) AG a fine textured material (10 clay 68 silt) (Ward 1983) would increase the fine fraction when applied to sands (2) AG has a much higher CEC ie 7 to 15 me depending on pH (Barrow 1982) than either Joel or Karrakatta sands ie 1 to 2 me (McPharlin et al 1994 and Table 51) and (3) application of AG to either Joel or Karrakatta sands increases the retentionreduces leaching of cations either not present in the AG such as NH4-N (McPharlin et al 1994) or only present in small quantities such as K (Tables 52 53 54 and Appendix 51)
The concentration of an element in the soil expressed as either extractable or total amounts represents the quantity or extensive factor in terms of plant nutrition as outlined by Holford and Mattingly (1976) The concentration of ions in soil solution or the intensive factor may better represent what is available to the plant A good example of this is the levels of K in the soil expressed as either Colwell or exchangeable K which increase significantly with level of applied AG However levels of K in the plant YML at buttoning and curds at harvest decrease significantly with level of AG K in soil solution 1 month after planting similarly decline significantly with level of applied AG and are therefore better correlated with K nutrition of the plant than measurements based on the dry soil Similarly P concentrations in the plant and soil solution decline whilst P retained by the soil increase in response to freshly-applied AG By contrast concentrations of Na in soil solution soil and plant all increase with levels of freshly-applied AG Similar relationships between concentrations of K Na and P in the soil soil solution and plant on a Karrakatta sand have been reported previously (Robertson et al 1997)
In previous work maximum yield (ie A value) of cauliflowers was reduced when freshly prepared AG was applied at levels gt 120 tha (Robertson et al 1994) This yield reduction was assumed not to be due to induced P deficiency resulting form high level of applied AG as it could not be alleviated by increased levels of applied P Although increased levels of applied P were needed to maximise yield as the level of freshly-applied AG increased Concentrations of K decreased and Na increased in the YML with level of applied AG and the yield reduction was assumed to be due either induced K deficiency or Na toxicity However neither the reduced concentrations of K or the increased concentrations of Na in the plant were at levels that would reduce yield according to published standards (Weir and Cresswell 1993) Antagonism between Na and K uptake by plants is common (Yeo 1983) For example increasing soil salinity resulted in increased concentrations of Na and decreased concentrations of K in the leaves of Zucchini grown in controlled greenhouses in Spain (Villora et al 1997)
The use of Red Mudgypsum in vegetable production
In this work as level of freshly-apphed AG increased level of applied P necessary for maximum yield increased as in the previous work however maximum yield was not reduced by AG up to 240 tha This is despite concentrations of K in the YML decreasing and Na increasing in response to level of freshly-applied AG However as in the previous work neither concentrations of K or Na were at levels expected to cause yield reduction By contrast the reduction in maximum yield of potatoes at high levels of freshly-applied AG (ie gt 120 tha) was correlated with a reduced concentration of K in the petioles (Robertson et al 1997b)
The level of freshly-applied P required for 99 of maximum yield in this work increased from 124 kgha at 01 AGHa to 339 kgha at 2401 AGha These levels of applied P are similar to that reported necessary for maximum yield of cauliflowers on AG-amended (Robertson et al 1994) or unamended (McPharlin et al 1995) Karrakatta sands The P required for 99 of maximum yield in this work 053 to 057 was either slightly higher - 047 (McPharlin et al 1995) or within range - 05 to 07 (Piggott 1986) 03 toO7 (Weir and Cresswell 1993) of that reported as critical or adequate for maximum yield of cauliflowers
Increased levels of freshly-applied AG did not significantly change the concentrations of Cd Co Cr Pb Ni Rb Sr Th or V in the curds of cauliflowers By contrast concentrations of Ba were significantly reduced and Ti increased in the curds with levels of freshly-applied AG Similarly there was no reported change in concentration of Cd Cr Pb or Co with level of freshly-applied AG in curds of cauliflower grown on Karrakatta sands (Robertson et al 1994) in previous work Also there was no change in Ba concentration in curds with level of AG in contrast to the previous work
References
Barrow NJ (1982) Possibility of using caustic residue from bauxite for improving the chemical and physical properties of sandy soils Australian Journal of Soil Research 33 275-285
Holford ICR and Mattingly GEG (1976) Phosphate adsorption and plant availability of phosphate Plant and Soil 44 377-89
McArthur and Bettenay (1960) The development and distribution of the soils of the Swan Coastal Plain Western Australia Soils Publication No 16 CSIRO Division of Soils CSIRO Melbourne Australia
McPharlin IR JefFery RC Toussaint LF and Cooper M (1994) Phosphorus Nitrogen and Radionuclide Retention and Leaching from a Joel Sand amended with Red Mudgypsum Communications in Soil Science and Plant Analysis 25 (17 amp 18) 2925-2944
McPharlin IR Robertson WJ JefFery RC and Weissberg R (1995) Response of cauliflower to phosphate fertiliser placement and soil test phosphorus calibration on a Karrakatta sand Communications in Soil Science and Plant Analysis 26(3amp4) 607-620
McQuaker NR Brown DF and Kluckner PD (1979) Digestion of environmental materials for analysis by inductively coupled plasma-atomic emission spectrometry Analytical Chemistry 51 1082-1084
Piggott TJ (1986) Vegetable crops pp 148-187 In DJ Reuter and JB Robinson (eds) Plant Analysis an Interpretation manual Inkata Press Melbourne Australia
Robertson WJ McPharlin IR and JefFery RC (1994) Final report of investigation into the use of gypsum-amended Red Mud as a soil-amendment on horticultural properties on the Swan Coastal Plain Report to HRDC (Project No V0039RO) Department of Agriculture Western Australia
55
The use of Red Mudgypsum in vegetable production
Robertson WJ Jeffery RC and McPharlin IR (1997a) Residues from bauxite-mining (Red Mud) increase phosphorus retention of a Joel sand without reducing yield of carrots Communications in Soil Science and Plant Analysis 28 (in press)
Robertson WJ McPharlin IR and Jeffery RC (1997b) The growth nutrition and mineral composition of potatoes (Solanum tuberosum L) cv Delaware grown on an yellow Karrakatta sand amended with freshly-applied and residual Alkaloamreggypsum (Submitted to AJEA)
Varley J A (1966) Automatic methods for the determination of nitrogen phosphorus and potassium in plant material Analyst 91 119-126
Villora G Pulgar G Moreno DA and Romero L (1997) Effect of salinity treatments on nutrient concentration in Zucchini plants (Cucurbita pepo L var Moschatd) Australian Journal of Experimental Agriculture 37 605-608
Vlahos S Summers KJ Bell DT and Gilkes RJ (1989) Reducing phosphorus leaching from sandy soils with Red Mud bauxite processing residues Australian Journal of Soil Research 27 651-662
Weir RG and Cresswell GC (1993) Plant Nutrient Disorders 3 Vegetable crops p 93 Inkata Press Melbourne Australia
Yuen SH and Pollard AG (1954) Determination of nitrogen in agricultural material by the Nessler reagent II Micro determination in plant tissue and soil extracts Journal of the Science of Food and Agriculture 5 364-369
The use of Red Mudgypsum in vegetable production
Appendix 51 Chemical and physical characteristics of Alkaloam gypsum used in cauliflower experiment (freshly-applied Alkaloamreggypsum)
Parameter Units Value Kgt
Ec mSm 623 -
pH (H 20) mSm 99 -
pH (CaCl2) mSm 94 -
PRI mLg 610 - gt 1000 -
LOI 1973 -
C a C 0 3 1290 1290
Fe (Fe203) 974 974
Al (A1203) 551 551
Si (Si0 2 ) 797 797
Ca (CaO) 45 450
Na (Na 2 0) 228 228
Ti (Ti0 2 ) 174 174
K (K 2 0) 072 72
Mg (MgO) 028 28 sect 047 47
P (P2O5) 005 05
Mn (MnO) 002 02
Total P ngg 266 -
Extractable P M-gg 58 -
Extractable K M-gg 43 -
As ngg 35 -
Ba ^gg 413 -
Cu Ugg 29 -
Sr Hgg 287 -
Nb Hgg 99 -y Hgg 866 -
Zr fAgg 1477 -
Sand 232 -
Silt 473 -
Clay 295 -
After Allen and Jeffery (1990)
Based on X-ray fluorescence (XRF) spectrometry
After Colwell (1963)
The use of Red Mudgypsum in vegetable production
Appendix 52 Concentration of Ba plus heavy metals1 (dry weight basis) in curds of cauliflowers at harvest with level of freshly-applied Alkaloamreggypsum (AG) and phosphorus (P)
(a)
AG Ba Cd Cr Co Pb Ni Rb Sr Ti Th V (tha) (Pgg) (vigg) (ugg) (ugg) (Pgg) (Pgg) (Pgg) (ugg) (Pgg) (Pgg) (Pgg)
0 119 010 050 010 020 050 88 182 050 058 010
60 72 010 050 010 022 050 91 171 069 078 012
120 87 011 064 011 030 050 92 186 067 075 012
240 53 011 05 010 023 050 95 172 061 067 012
Lsd2 21 002 02 024 016 022 11 28 008 024 002
Sig3 ns ns ns ns ns ns ns ns ns
(b)
p (kgha)
Ba (vgg)
Cd (vigg)
Cr (Pgg)
Co (ngg)
Pb (vgg)
Ni (Pgg)
Rb (Pgg)
Sr (Pgg)
Ti
(Pgg)
Th (Pgg)
V
(Pgg)
0 83 010 050 010 038 050 97 149 058 067 013
50 100 011 050 010 027 050 98 207 075 110 013
100 86 010 050 010 017 050 85 180 067 075 012
200 79 010 050 010 018 050 92 193 058 058 010
400 78 011 071 011 028 058 89 168 058 054 011
600 71 010 050 010 016 050 90 168 054 054 010
Lsd2 18 002 024 0009 022 009 06 27 028 044 003
Sig3 ns ns ns ns ns ns ns ns
Inductively coupled plasma mass spectrometry
Least significant difference at P lt 005
Significance at lt 0001 () lt 001 () lt 005 () level or not significant (ns)
The use of Red Mudgypsum in vegetable production
6 RESPONSE OF CAULIFLOWERS TO RESIDUAL RED MUD (ALKALOAMreg)GYPSUM (AG) AND PHOSPHORUS ON A YELLOW KARRAKATTA SAND
Introduction
It is important to reduce the leaching of phosphorus fertiliser from sandy soils used for vegetable production into the water systems of the Swan Coastal Plain Red Mud (Alkaloam )gypsum (AG) (ie Red Mudgypsum RMG) a waste product from bauxite refining has been suggested as an amendment to reduce phosphorus leaching from sands of the Bassendean Association (Joel Gavin) used for agriculture and horticulture (Barrow 1982)
Experimental work in the field and pots showed amendment with AG significantly reduced P leaching from Joel and Gavin sands (Vlahos et al 1989 McPharlin et al 1994) compared with the unamended (01 RMGha) treatment
Previous work showed a significant reduction in maximum yield of cauliflowers with levels of residual AG of gt 60 tha compared with 01 AGha (Robertson et al 1994) This yield reduction was not due to P deficiency as increased levels of applied P did not obviate the problem Nor was it due to K deficiency as K concentrations in the youngest mature leaves (YML) although reduced by levels of residual AG did not decline to levels expected to reduce yield The converse was true for concentrations of Na in the YML which increased with levels of residual AG but not to concentrations expected to cause toxicity
Since more than 60 tha of AG may be required to significantly improve P retention by sands to enable sustainable horticultural production this yield reduction is re-examined with residual AG
Materials and methods
Site characteristics
The experiment was conducted on a yellow Karrakatta sand (McArthur and Bettenay 1960) at Medina Research Centre (32deg 13 S 115deg 49 E) 30 km south of Perth Both Alkaloamreggypsum (AG) and phosphorus had previously been applied to the site and a potato crop grown in 1995 Prior to that the site had been sown to pasture for several years Some relevant chemical characteristics of the topsoil (0-15 cm) and subsoil (15-30 cm) of the site after application of AG but prior to the application of fertiliser (except residual P) and transplanting are presented in Table 61
Red Mud (Alkaloamreg)gypsum
Alkaloamreg (Red Mud) amended with 10 (ww) gypsum (AG) was produced by the dry mix process by ALCOA of Australia Ltd at their Kwinana Residue Treatment Plant The AG had been spread manually on the site and incorporated using a rotary hoe to approximately 30 cm depth on 22 December 1994 Residual P had been applied just before planting of the previous potato crop on 17 May 1995 and incorporated with a rotary hoe The site was watered for 1 hour per day (8 mmday) using impact sprinklers until planting
Experimental design
The experimental design was a split-plot randomised block with 3 replicates The main plots were levels of AG (0 60 90 120 and 240 tha) and the sub-plots were levels of freshly-applied P (25 50 100 300 and 600 kgha) Main plots measured 7 x 12 m and sub-plots 12 x 7 m (excluding wheel tracks)
59
The use of Red Mudgypsum in vegetable production
Crop management
The site was sprayed with Roundupreg (3 Lha) twice after application of AG and prior to planting to control weeds Six week old seedlings of cauliflowers (cv Plana) obtained from a commercial nursery were transplanted manually on 18 April 1996 in 2 rows per plot with 70 cm between rows and 50 cm between plants Seedlings were dipped in Rovralreg (1 mLL) just prior to planting for control of fungi Treflanreg (14 Lha) and Dacthalreg (12 kgha) were applied immediately after transplanting to control broadleaved weeds and Sertinreg later on in the life of the crop for grass control Ambushreg (100 mLha) and Rogorreg (100 mLha) were used to control caterpillars and red legged earth-mite respectively Copper was applied for control of blackrot The crop was irrigated to a total application equivalent to 100 of the previous days pan evaporation using minisprinklers (Legoreg 6 x 6 m spacing 44 mmh) in 3 waterings of equal duration per day
Fertilisers
Pre-planting fertilisers were broadcast manually and rotary hoed on 17 April 1996
These were K2S04(244) Ca(N03)2(387) MgS047H20 (504) MnS04H20 (504) FeS047H20 (18) Borax (27) CuS045H20 (36) ZnSOH20 (28) and Na2Mo042H20 (2) P was applied as single superphosphate (91 P) at 0 to 600 kg Pha according to treatment and incorporated as before Post-planting K N and Ca were fertigated via the irrigation system as KN03 NHUNO3 and Ca (N03)2 in equal amounts per day for 12 weeks to a total of 600 kg Kha 423 kg Nha and 60 kg Caha Borax was fertigated at 20 kgha in week 3 and Mg was broadcast as MgS047H20 at 50 kgha in weeks 3 6 and 9
Measurements
Soil and soil solution
All zero P subplots were sampled 30 cores per plot just prior to planting and fertilising about 2 months after AG application to 2 depths (0-15 15-30 cm) These were oven dried at 40degC and analysed for Ec pH (CaCl2) P sorption (Ozane and Shaw 1968) bicarbonate extractable P K (Colwell 1963) total P PRI P sorption K sorption (Allen and Jeffery 1990) and cation exchange capacity (Gillman and Sumpter 1986)
The soil water was obtained by centrifugation from soil samples (0-15 cm 30 per plot) and collected from the 0 100 200 and 600 kg Pha plots across all AG treatments on the 16 May 1996 The supernatant was analysed for pH Ec Ca Mg K S and P The remaining soil was analysed for pH (H20) bicarbonate extractable P K PRI and DTPA extractable Zn After harvest 5 August 1997 soil samples were collected from 2 depths as for the preplanting treatment from all plots These were analysed for pH bicarbonate extractable P K total P PRI and exchangeable cations (Ca Mg K and N)
Plant
At buttoning on 13 June 1996 the younger mature leaves (YML) (4th from growing point) were collected from 16 plants (excluding 1 m buffer at each end of plot) in each plot They were dried at 70degC in a force draught oven for 48 h and ground to pass through a 1 mm screen Sub-samples were digested with sulphuric acidhydrogen peroxide (Yuen and Pollard 1954) and the concentration of N P and K measured by an automated colorimetric process (Varley 1966) Concentration of other nutrients (B Ca Na Mg S Fe Mn Zn and Cu) were determined by inductively coupled plasma atomic emission spectroscopy (ICP-AES) after digestion with nitric-perchloric acids (McQuaker et al 1979) Five whole plants were harvested from the middle of each plot (2 per row) at the end of the experiment on 4 July 1996 using shovels to remove as much of the roots as possible The plants were separated into four categories curds leaves stems and roots All soil was dried and digested as for ICP-AES as above and washed from the roots using tap water shaken and the excess water removed using paper towels The fresh weight of all four categories was recorded and the material was diced
60
The use of Red Mudgypsum in vegetable production
into small pieces (lt 8 cm3) using stainless steel knifes sub-samples (300 g fresh weight) were collected at random from the diced pieces and the fresh weight recorded These were dried at 70degC in a forced draught oven for 48 h and the dry weight recorded These samples were then analysed for P as for the youngest mature leaves Separate sub-samples (300 g fresh weight) of curds were collected and analysed for Ba Cd Cr Co Pb Mo Rb Sr Ti Th V and Ni using inductively coupled plasma mass spectrometry (ICP-MS) The fresh and dry weight of the curds leaves stems and roots at harvest were used to calculate P uptake in kgha)
Harvest
Harvest commenced when the leaves surrounding the head opened and exposed the curds 77-80 days after transplanting At this stage florets at the periphery of the curd had just begun to separate Sixteen curds (12 plus 4 from whole plant samples above) were collected from the central 4 m of both rows (1 m buffer) and then all the leaves and stems removed according to requirements for export market Each fresh curd was weighed and rejects recorded if undersize (lt 500 g) oversize (gt 2000 g) discoloured (yellowing) overmature (separation of florets in the centre of curd) diseased damaged or otherwise distorted The total marketable and reject yield were recorded for each plot
Analysis of data
Analysis of variance was carried out on level of applied AG or P versus (a) chemical characteristics of soil (bicarbonate extractable P total P etc) preplanting and harvest (b) concentrations of nutrients in soil solution at midgrowth (c) concentration of nutrients in YMLs at midgrowth (d) concentration of elements in curds at harvest (e) P uptake by plant parts and (f) total marketable and reject yield of curds at harvest Mitscherlich curves and inverse polynomials were fitted to the relationship between level of applied P and yield at each level of applied AG The level of applied P required for 95 99 and 100 (in case of inverse polynomials) of maximum yield was calculated Mitscherlich curves were fitted to the relationship between level of applied P and P in YMLs at midgrowth at all levels of AG The P in YMLs corresponding to the level of applied P required for 95 99 or 100 of maximum yield (as determined from yield versus applied P plots) was then determined
Mitscherlich curves were also fitted to the relationship between level of applied P and P uptake by curds leaves stems and roots and the P uptake corresponding to whole plants (additions of all 4) level of P required for 95-100 of maximum yield determined Phosphorus uptake by plant parts or whole plants on 0 P plots were deducted from P uptake at other rates to account for non-fertiliser sources of P This was used to adjust P uptake when determining P fertiliser recovery efficiency (RE) by plant parts or whole plants ie fertiliser P uptake by plant parts or whole plantsP applied both in kgha (Novoa and Loomis 1981)
The effect of residual AG andP on chemical characteristics of the soil
Increased levels of previously-applied (residual) AG resulted in a significant increase in Ec pH (CaCl2) Colwell P and PRI in the topsoil (0-15 cm) of a Karrakatta sand prior to current the application of fertilisers and planting (Table 61 Fig 61) There was no significant effect of level of residual AG on the levels of Colwell K in the topsoil Increasing levels of previously-applied (residual) P resulted in a significant increase in Colwell P and a decrease in PRI and pH at the same time but had no effect on the levels of Colwell K in the topsoil
61
The use of Red Mudgypsum in vegetable production
Table 61 Chemical characteristics of the topsoil (0-15 cm) of a yellow Karrakatta sand 12 months after application of Alkaloamreggypsum (AG) (residual AG) and phosphorus (P) just prior to fertiliser application and transplanting
AG Ec pH BicP1 BicK1 PRI2
(tha) (mSm) (CaCl2) (H8g) (Hgg) (mLg)
0 36 70 262 199 093
60 62 78 397 308 101
90 70 80 390 378 12
120 73 80 402 391 14
Lsd3 057 018 75 122 018
Sig4 ns
P (kgha)
Ec (mSm)
pH (CaCl2)
BicP1
(M-gg) BicK1
(figg) PRI2
(mLg)
0 59 78 117 323 17
25 58 78 147 338 15
50 58 78 160 322 16
100 58 78 255 327 13
300 62 76 554 309 06
600 66 75 944 296 005
Lsd3 063 01 58 60 02
Sig4 ns ns
1 After Colwell (1963) 2 After Allen and Jeffery (1990) 3 Least significant difference at P lt 005 4 Significance at lt 0001 () lt 001 () lt 005 () level or not significant (ns)
62
The use of Red Mudgypsum in vegetable production
mdash A
8 40 gt -o deggt 35 - en =gt mdash sect 30 _raquo CO
e 25 ltD O d
5 20
1 ^ I I I
T3
C
o
c CO o c o o
0 20 40 60 80 100120140
Residual AG (tha)
u u bull B
80 l
60
40
mdash n bull 20
n i i i i
I
i i i
100 200 300 400 500 600 700
Residual P (kgha)
Figure 61 (A B) Bicarbonate extractable P (bull) and K (bull) (figg dry soil after Colwell 1963) in the top soil (0-15 cm) of a yellow Karrakatta sand prior to fertilising and planting with level of residual Alkaloamreggypsum (t AGha) (A) and P (kgha) (B) Vertical bars refer to Lsd (P lt 005) for differences between levels of AG or P
5 E Q 0 -
20 40 60 80 100120 140
Residual AG (tha)
0 100 200 300 400 500 600 700
Residual P (kgha)
Figure 61 (C D) Phosphorus retention index (PRI) after Allen and Jeffery (1990) in the topsoil (0-15 cm) of a yellow Karrakatta sand prior to fertilising and planting with level of residual Alkaloamreggypsum (t AGha) (C) and P (kgha) (D) Vertical bars refer to Lsd (P lt 005) for differences between levels of AG or P
63
The use of Red Mudgypsum in vegetable production
One month after planting there was a significant increase in concentration of Ca Na and pH and a decrease in K concentration with level of residual AG in the soil solution at 15 cm depth There was no significant effect of level of residual AG on the Ec or concentration of Mg S and soluble reactive P (Psr) in the soil solution (Table 62 (a) Fig 62) There was a significant decrease in Ec pH and concentration of Mg Na and an increase in concentration of Ca S and Psr in soil solution with level of residual P
Table 62 (a) Ec (mSm) pH and concentration of nutrients (ugmL) in soil solution 1 month after planting cauliflowers with level of residual Alkaloamreggypsum (AG) and phosphorus (P)
AG
AG (tha)
Ec (mSm)
pH Ca (ngmL)
Mg (ugmL)
Na (jigmL)
K (UgmL)
S (jigmL)
Psrp1
(pgmL)
0 129 75 91 141 105 81 28 05
60 144 77 108 131 121 64 30 06
120 147 76 123 136 120 50 33 04
Lsd2 33 01 14 09 4 7 1 02
Sig3 ns ns ns ns
P
p (kgha)
Ec (mSm)
pH Ca (UgmL)
Mg (ligmL)
Na (jigmL)
K (UgmL)
S (UgmL)
Psrp1
(VigmL)
0 171 78 107 141 121 68 23 01
100 138 77 104 144 111 58 24 02
300 120 76 103 128 110 63 31 06
600 130 73 117 133 116 71 43 13
Lsd2 20 02 10 11 10 13 7 02
Sig3 ns
Soluble reactive P 2 Least significant difference at P ^ 005 3 Significance at lt 0001 () lt 001 () lt 005 () level or not significant (ns)
64
The use of Red Mudgypsum in vegetable production
3
C
o
o (gt
o in c c o
5 c CD O
o O
3
o
c o
c ltu o c o
o 0 20 40 60 80 100 120 140
Residual AG (tha)
0 100 200 300 400 500 600 700
Residual P (kgha)
Figure 62 (A B) Concentration (figmL) of Ca (bull) Mg (bull) Na (A) K (T) and S (bull) in soil solution (0-15 cm) under cauliflower one month after planting with level P residual Alkaloamreggypsum (AG) (A) and (B) Vertical bars refer to Lsd (P lt 005) for differences in concentration between levels of AG Where bars are not shown Lsd is less than size of symbol
There was a significant increase in Colwell P K and PRI in the topsoil (0-15 cm) and no change in DTPA extractable Zn with level of residual AG one month after planting (Table 62 (b)) As level of residual P increased there was a significant increase in Colwell P and decrease in PRI with no change in Colwell K or DTPA extractable Zn in the topsoil one month after planting
The use of Red Mudgypsum in vegetable production
Table 62 (b) Extractable P K Zn and phosphorus retention index of the TopsoU (0-15 cm) of a yellow Karrakatta sand 1 month after planting of cauliflowers with level of residual Alkaloamreggypsum (AG) and phosphorus (P)
AG
Ag BicP1 BicK1 Zn2 PRI3
(tha) (Pgg) (Pgg) (Pgg) (mLg)
0 27 41 25 05
60 45 43 26 03
120 50 59 23 07
Lsd4 8 6 05 01
Sig5 ns
p
p (kgha)
BicP1
(Pgg) BicK1
(Pgg)
Zn2
(l-igg) PRI3
(mLg)
0 9 46 19 12
100 21 47 22 09
300 42 46 25 03
600 90 52 31 -03
Lsd4 7 5 10 02
Sig5 ns ns
1 After Colwell (1963) 2 Extracted in DTPA 3 After Allen and Jeffery (1990) 4 Least significant difference at P ^ 005 5 Significance at lt 0001 () lt 001 () lt 005 () level or not significant (ns)
After harvest of cauliflowers there was a significant increase in Colwell P and K total P actual and predicted PRI (PRI and PRIp) with residual AG in the topsoil and subsoil of a Karrakatta sand (Table 63 (a) (b)) There was a significant increase in Colwell P and total P and decrease in Colwell K PRI and PRIp with level of residual P in both the topsoil and subsoil after harvest (Fig 63 (A B))
66
The use of Red Mudgypsum in vegetable production
Table 63 Extractable P K total P and phosphorus retention index of the topsoil (0-15 cm) and subsoil (15-30 cm) of a yellow Karrakatta sand after harvest of cauliflowers with level of residual AIkaloamreggypsum (AG) and phosphorus (P)
(a) Topsoil
AG
AG BicP1 BicK1 TotP2 PPJ3 PPJP4
(tha) (ngg) (Hgg) (Pgg) (mLg) (mLg)
0 16 28 68 10 26
60 25 42 86 15 41
90 25 46 91 16 43
120 26 54 96 18 46
Lsd5 3 9 8 005 03
Sig6
P (kgha)
BicP1
(Pgg) BicK1
(vigg) TotP2
(ngg) PPJ3
(mLg) PPJP4
(mLg)
0 7 46 58 19 27
25 8 45 63 19 28
50 9 44 64 20 30
100 15 43 72 17 33
300 37 40 103 09 48
600 63 36 152 03 67
Lsd5 3 6 8 03 05
Sig6
1 After Colwell (1963) 2 After Allen and Jeffery (1990) 3 Phosphorus retention index (Allen and Jeffery 1990) 4 Predicted phosphorus retention index (Allen and Jeffery 1990) 5 Least significant difference at P ^ 005 6 Significance at lt 0001 () lt 001 () lt 005 () level or not significant (ns)
The use of Red Mudgypsum in vegetable production
120
o lgt 100 bull gt
TJ
rn laquon D ) 3
mdash-
on
60
^^ m i _
c 40 ltigt o c o O 20
160 A (I 140
^ ^ ^ ^ 1 o (0 ^ ^ ^ ^ 1 gtraquo 120
^plusmn bull o
^ ^ ^ ^
66
100
^ 3 80
^ mdash ^ tra
tion
60
^ ^ - ^ ^ ^ cen 40
o 20 o 20
I I I I I I I
O
10
0
0 20 40 60 80 100 120 1lt
O
10
Residual AG (tha)
0 100 200 300 400 500 600 700
Residual P (kgha)
Figure 63 (A B) Bicarbonate extractable P (bull) K (bull) and total P (A) in the topsoil (0-15 cm) of a yellow Karrakatta sand after harvest of cauliflowers with level of residual AIkaloamreggypsum (t AGha) (A) and P (kgha) (B) Vertical bars refer to Lsd (P lt 005) for difference between level of AG or P Lsd not shown when less than size of symbol
68
The use of Red Mudgypsum in vegetable production
Table 63 Extractable P K total P and phosphorus retention index of the topsoil (0-15 cm) and subsoil (15-30 cm) of a yellow Karrakatta sand after harvest of cauliflowers with level of residual Alkaloamreggypsum (AG) and phosphorus (P)
(b) Subsoil
AG
AG BicP1 BicK1 TotP2 PRI3 PRJJP4
(tha) (Pgg) (ugg) (ngg) (mLg) (mLg)
0 15 23 69 08 24
60 23 31 82 12 36
90 24 37 91 14 39
120 25 40 90 17 43
Lsd5 4 6 7 01 03
Sig6
P (kgha)
BicP1
(ngg) BicK1
(ugg) TotP2
(ugg) PRI3
(mLg) PRIP4
(mLg)
0 6 36 57 18 25
25 8 36 63 17 26
50 8 34 63 17 26
100 13 31 71 15 29
300 33 29 102 08 43
600 61 30 141 03 64
Lsd5 5 5 8 02 05
Sig6
1 After Colwell (1963) 2 After Allen and Jeffery (1990) 3 Phosphorus retention index (Allen and Jeffery 1990) 4 Predicted phosphorus retention index (Allen and Jeffery 1990) 5 Least significant difference at P ^ 005 6 Significance at lt 0001 () lt 001 () lt 005 () level or not significant (ns)
The use of Red Mudgypsum in vegetable production
100
o CO
gtlaquo
C
o CO
bull-raquo
c o o o
20 40 60 80 100 120 140
Residual AG (tha) 0 100 200 300 400 500 600 700
Residual P (kgha)
Figure 63 (A B) Bicarbonate extractable P (bull) K (bull) and total P (A) in the subsoil (0-15 cm) of a yellow Karrakatta sand after harvest of cauliflowers with level of residual Alkaloamreggypsum (t AGha) (A) and P (kgha) (B) Vertical bars refer to Lsd (P lt 005) for difference between level of AG or P Lsd not shown when less than size of symbol
Ec pH (CaCl2) and exchangeable Ca and Na in the top and subsoil after harvest increased significantly with level of residual AG whilst there was no change in exchangeable Mg (Table 64 (a) (b)) Whilst there was no change in exchangeable K with level of residual AG in the topsoil there was a significant increase in exchangeable K in the subsoil (Table 64 (b))
70
The use of Red Mudgypsum in vegetable production
Table 64 Ec (mSm) pH (CaCl2) and exchangeable cations (me) in topsoil (0-15 cm) and subsoil (15-30 cm) of a yellow Karrakatta sand with level of residual AIkaloamreggypsum (AG) and phosphorus (P) after harvest of cauliflowers
(a) Topsoil (0-15 cm)
AG
AG Ec pH Ca1 Mg1 K1 Na1
(tha) (mSm) (CaCl2) (me) (me) (me) (me)
0 29 65 24 027 006 004
60 47 73 32 025 009 010
90 59 77 36 023 015 015
120 66 78 40 025 012 018
Lsd2 07 07 06 005 006 001
Sig3 as ns
P (kgha)
Ec (mSm)
PH (CaCl2)
Ca1
(me) Mg1
(me) K1
(me) Na1
(me)
0 43 73 30 025 001 011
25 46 73 33 026 010 011
50 46 73 32 025 010 011
100 52 74 32 025 010 011
300 56 74 34 024 009 011
600 58 73 37 025 014 012
Lsd2 05 05 03 002 007 -
Sig3 ns ns ns
Exchangeable in 1 m NILt-Cl 2 Least significant difference at P ^ 005 3 Significance at lt 0001 () lt 001 () lt 005 () level or not significant (ns)
The use of Red Mudgypsum in vegetable production
soil b
A soil
dry
4 _ I dry
I ^5 CD CD
b_ 3 - E c c o o CO at
i
U o CD CD
Xgt j a CO bull| mdash CO CD ogt
m- mdashM- mmdash JZ 0 - +~ -- mdash c CJ o X X LU
i 1 I i i i i LU
0 20 40 60 80 100 120 1^ W
Residual AG (tha)
100 200 300 400 500 600 700
Residual P (kgha)
Figure 64 (A B) Exchangeable Ca (bull) Mg (bull) K (A) and Na ( bull ) (me) in the topsoil (0-15 cm) of a yellow Karrakatta sand with level of residual Alkaloamreggypsum (t AGha) or P (kgha) Vertical bars refers to Lsd (P lt 005) for differences in concentration between levels of AG or P Lsd not shown when less than size of symbol
72
The use of Red Mudgypsum in vegetable production
Table 64 Ec (mSm) pH (CaCl2) and exchangeable cations (me) in topsoil (0-15 cm) and subsoil (15-30 cm) of a yellow Karrakatta sand with level of residual AlkaIoamreggypsum (AG) and phosphorus (P) after harvest of cauliflowers
(b) Subsoil (15-30 cm)
AG
AG Ec pH Ca1 Mg1 K1 Na1
(tha) (mSm) (CaCl2) (me) (me) (me) (me)
0 34 66 24 026 006 005
60 50 75 33 024 008 010
90 64 78 38 023 01 016
120 68 79 41 024 01 019
Lsd2 05 01 07 006 001 003
Sig3 ns
P (kgha)
Ec (mSm)
pH (CaCl2)
Ca1
(me) Mg1
(me) K1
(me) Na1
(me)
0 48 75 30 023 009 011
25 51 74 33 026 009 011
50 50 75 34 025 008 013
100 61 75 35 026 008 013
300 57 75 34 022 007 013
600 58 73 38 024 008 013
Lsd2 08 01 04 003 001 003
Sig3 ns
1 Exchangeable in 1 m NH4-CI 2 Least significant difference at P ^ 005 3 Significance at lt 0001 () lt 001 () lt 005 () level or not significant (ns)
The use of Red Mudgypsum in vegetable production
o 0 oi
4 CO c CO
gt T3 4 _ bull o
0s -5 3 agt CD
fc_ 3 - g
on
o 2 CO 2 CO
u 2
o CD CD 1 X I SI
1 CD 1 CD CD CU
O
n ^ 1 CO n X bull mdashXmdash mdash 1 1 CO U J= n bull - w 1 CO U
o o X X Lil
i i 1 1 i i 1 HI
0 20 40 60 80 100 120 140
Residual AG (tha)
100 200 300 400 500 600 700
Residual P (kgha)
Figure 64 (C D) Exchangeable Ca (bull) Mg (bull) K (A) and Na (T) (me) in the subsoil (0-15 cm) of a yellow Karrakatta sand with level of residual Alkaloamreggypsum (t AGha) or P (kgha) Vertical bars refers to Lsd (P lt 005) for differences in concentration between levels of AG or P Lsd not shown when less than size of symbol
As level of residual P increased there was a significant increase in exchangeable Ca in the tbpsoil and subsoil but no significant effect on exchangeable Mg K and Na in the topsoil and variable effects on exchangeable Mg and K in the subsoil Ec increased significantly with level of residual P in both the top and subsoil whilst pH in either was effected little by level of applied P
The effect of level of residual AG andP on the concentration of nutrients in cauliflower leaves
The level of residual AG had no effect on the concentrations of N Ca S P S Mg Fe Zn Mn B and Cu in the youngest mature leaves of cauliflowers at buttoning but increased levels significantly reduced the concentration of K (Fig 65 (A B)) As level of residual P increased there was a significant increase in the concentration of K P S Cu and Mn in the YMLs whilst concentrations of N decreased and B concentrations were variable with no clear trends
74
The use of Red Mudgypsum in vegetable production
Table 65 Concentration of nutrients (dry weight basis) in youngest mature leaves of cauliflowers at buttoning with level of applied residual Alkaloamreggypsum (AG) and phosphorus (P)
(a) Macronutrients
AG
AG N1 K1 Ca2 S2 P1 Na2 Mg2
(tha) () () () () () () ()
0 49 42 23 077 040 039 027
60 51 40 23 078 042 036 025
90 51 39 23 079 043 036 025
120 49 39 24 078 042 036 025
Lsd3 03 02 08 009 007 010 004
Sig4 ns ns ns ns ns ns
P N1 K1 Ca2 S2 P1 Na2 Mg2
(kgha) () () () () () () ()
0 53 36 22 069 027 033 024
25 51 38 24 071 030 038 026
50 52 40 24 075 034 040 027
100 51 41 24 079 043 041 027
300 48 43 24 087 055 039 026
600 47 42 20 086 060 031 023
Lsd3 02 02 04 003 004 006 003
Sig4 ns ns
1 After Varley (1966) 2 After McQuakerefl (1979) 3 Least significant difference at P lt 005 4 Significance at lt 0001 () lt 001 () lt 005 () level or not significant (ns)
The use of Red Mudgypsum in vegetable production
Table 65 Concentration of nutrients (dry weight basis) in youngest mature leaves of cauliflowers at buttoning with level of applied residual AlkaIoamreggypsum (AG) and phosphorus (P)
(b) Micronutrients
AG
AG (tha)
Fe (ugg)
Zn1
(Pgg) Mn1
(ugg) B1
(ugg) Cu1
(ugg)
0 122 31 19 21 28
60 121 32 22 22 30
90 119 36 25 22 32
120 120 29 23 22 29
Lsd2 21 8 6 1 05
sig3 ns ns ns ns ns
P (kgha)
Fe1
(Pgg)
Zn1
(ugg) Mn1
Gigg)
B1
(Fgg)
Cu1
(Pgg)
0 112 33 19 22 28
25 120 32 22 22 29
50 125 32 21 23 29
100 132 38 24 23 31
300 129 30 25 22 32
600 106 29 23 21 32
Lsd2 19 6 3 1 03
Sig-3 ns ns
After McQuaker et al (1979) 2 Least significant difference at P ^ 005 3 Significance at lt 0001 () lt 001 () lt 005 () level or not significant (ns)
The relationship between residual P ie Colwell P and P in YMLs at buttoning were best described by Mitscherlich relationships at all levels of residual AG (Fig 65)
The concentration of P in YMLs corresponding to levels of Colwell P necessary for 95 of maximum yield were 047 050 054 and 048 and for 99 of maximum yield were 053 055 058 and 054 for 0 60 90 and 1201 residual AGha respectively
76
The use of Red Mudgypsum in vegetable production
Q
en
3
gt-c 0
07
06
05
04
03
02
01 0
065
060
055
050
045
040
035
030
025
020
A
if 20 40 60 80 100
Colwell P (ugg dry soil)
_ 065
Q S 055
060
tz
ro _ i
gt
120
C bull - - - mdash bull
20 40 60 80 100
Colwell P (ugg dry soil)
120
050
045
040
035
030
025
020
065
060
055
050
045
040
035
030
025
020
-B
bull
- bull I
I I
bull
i i i
20 40 60 80 100
Colwell P (ugg dry soil)
120
-bull D
I I i i i
20 40 60 80 100
Colwell P (ugg dry soil)
120
Figure 65 P in youngest mature leaves at buttoning () corresponding to Colwell P necessary for 95 (dashed) or 99 (whole) of maximum yield at 0 (A) 60 (B) 90 (C) and 120 (D) t of residual Alkaloamreggypsumha Dashed and whole horizontal lines refers to P in YML corresponding to Colwell P required for 95 and 99 of maximum yield respectively
The equations for the fitted lines are
A y = 05964 - 0763 x exp (-0068) (B2 = 089)
B y = 05855 - 05144 x exp (-00465x) (R2 = 098)
C y = 006058 - 0549 x exp (-00435x) (B2 = 096)
D y = 06399 - 05208 x exp (-00291) (R2 = 097)
77
The use of Red Mudgypsum in vegetable production
The effect of level of residual AG andP on the yield of cauliflowers
There was no significant effect of levels of residual AG on the total or marketable yield of cauliflowers However yield responded significantly to levels of applied residual P and the interaction between residual P and AG was significant (Tables 66 (a) (b))
The relationship between Colwell P and total yield was best described by Mitscherlich relationships for all levels of residual AG (Fig 66) The Colwell P required for 95 of maximum total yield was 26 40 48 and 40 ugg dry soil and for 99 35 55 71 and 58 ugg dry soil for 0 60 90 and 1201 residual AGha respectively
Table 66 Curd yield (total and marketable) of cauliflowers (tha) at harvest with level of residual Alkaloamreggypsum (AG) and phosphorus (P)
(a) Total
AG p
(kgha) (tha) p
(kgha)
0 60 90 120
0 59 64 69 100
25 134 126 123 83
50 139 133 117 143
100 163 200 164 177
300 203 236 198 204
600 215 237 208 194
Ls-d1 36 (AG) 17 (P) 48(AGP) -
Sig2 ns
(b) Marketable
p (kgha)
AG (tha) p
(kgha)
0 60 90 120
0 14 14 18 56
25 83 74 84 13
50 90 99 67 99
100 138 188 125 160
300 187 232 182 190
600 206 234 191 185
Lsd1
Sig2
48 (AG)
ns 23 (P)
62(AGP)
-
Least significant difference at P lt 005 2 Significance at lt 0001 () lt 001 () lt 005 () level or not significant (ns)
The use of Red Mudgypsum in vegetable production
0 20 40 60 80 100120140160
Colwell P (ugg dry soil)
0 20 40 60 80 100120140160
Colwell P (ugg dry soil)
lt x
UJ gt-Q
o
lt X
Q _ l UJ gt-Q rr D O
24
22
20
18
16 14
12
10
8
6
4
-D
bull
I I
I I
I I
I
^~ bull
i i i i i
20 40 60 80 100120140160
Colwell P (ugg dry soil)
20 40 60 80 100120140160
Colwell P (ugg dry soil)
Figure 66 Colwell P in topsoil (0-15 cm) at planting versus yield of cauliflowers at 0 (A) 60 (B) 90 (C) and 120 (D) tha of residual Alkaloamreggypsum (AG) Dashed and whole vertical lines represent Colwell P required for 95 and 99 of maximum yield respectively
The equations for the fitted lines are
A y = 2088 - 818 x exp (-017x) (i2 = 089)
B y = 23731 - 4578 x exp (-00949) (i2 = 099)
C y = 2051 - 286 x exp (-00697) (R2 = 086)
D y = 2002 - 354 x exp (-0090) (B2 = 086)
79
The use of Red Mudgypsum in vegetable production
Discussion
There was no significant reduction in maximum yield (ie A values) of cauliflower (cv Plana) curds grown on Karrakatta sands amended with residual AG from 0 to 120 tha in this work This is in contrast to previous work (Robertson et al 1994) in which maximum curd yields of cauliflowers were significantly reduced with levels of residual AG at 120 tha compared with 0 and 60 tha In both studies concentrations of K were reduced and concentrations of Na were increased in the YML at buttoning with increasing levels of residual AG The increase in concentration of Na and the decrease in concentration of K in the YML with level of applied AG was related to similar changes in the concentrations of these elements in the soil solution with both freshly-applied (Section 5) and residual AG one month after planting As with freshly-applied AG increasing levels of residual AG resulted in increasing levels of Na in the soil (exchangeable) or soil solution however whilst K concentrations in soil solution decreased the K retained by the soil measured as either Colwell K or exchangeable K increased Increasing levels of residual AG resulted in increased pH in the topsoil as with fresh AG but this did not reduce the concentration of Mn Cu and Zn in the YML or increase the concentration of Mo These changes would be expected with increases in soil pH (Porter 1984) The level of Colwell P required for 95 to 99 of maximum yield increased from 26 and 35 ugg dry soil at 01 AGha to 48 and 71 ugg at 901 of residual AGha The level at 1201 AGha was slightly lower ie 40 and 58 ugg These levels are similar to those reported as necessary for 95 and 99 of maximum yield of Arfak cauliflowers 40 and 55 ugg Colwell P in planted in autumn and spring on unamended Karrakatta sands (McPharlin et al 1995) It therefore does not appear that AG amendment increases the residual P as measured by Colwell P requirement of cauliflower significantly This is in contrast to the significantly higher level of applied P necessary to maximise yield when AG is freshly-applied ie from 120-160 to gt 300 kg of Pha at 0 and 1201 AGha respectively (Robertson et al 1994 and Section 5) However requirements of residual (Colwell) P and freshly-applied P are not always correlated For example the Colwell P necessary for the maximum yield of spring and winter-planted lettuce was similar ie 80 to 120 ugg dry soil whereas the level of freshly-applied P required for maximum yield of winter-planted lettuce was 50 higher than in spring (McPharlin et al 1996 McPharlin and Robertson 1997)
References
Allen DG and Jeffery RC (1990) Methods for analysis of phosphorus in Western Australian soils Chemistry Centre of Western Australia Report of Investigation No 37
Barrow NJ (1982) Possibility of using caustic residue from bauxite for improving the chemical and physical properties of sandy soils Australian Journal of Experimental Agriculture Research 33 275-285
Colwell JD (1963) The estimation of phosphorus fertiliser requirements of wheat in southern New South Wales by soil analysis Australian Journal of Experimental Agriculture Animal Husbandry 3 190-197
Gillman GP and Sumpter EA (1986) Modification to the compulsive exchange method for measuring exchange characteristics of soils Australian Journal of Soil Research 24 616
McArthur WM and Bettenay E (1960) The development and distribution of the soils of the Swan Coastal Plain Western Australia CSIRO Division of Soils Soils Publication No 16
McPharlin IR Jeffery RC and Pitman DH (1996) Phosphorus requirements of winter planted lettuce (Lactuca sativa L) on a Karrakatta sand and the residual value of phosphate as determined by soil test Australian Journal Experimental Agriculture 36 887-903
80
The use of Red Mudgypsum in vegetable production
McPharlin IR Jeffery RC and Weissberg R (1994) Determination of the residual value of phosphate and soil test phosphorus calibration for carrots on a Karrakatta sand Communications in Soil Science Plant Analysis 25 (5-6) 489-500
McPharlin IR and Robertson WJ (1997) Response of spring-planted lettuce (Lactuca sativa L) to freshly-applied and residual phosphorus and to phosphate fertiliser placement on a Karrakatta sand Australian Journal of Experimental Agriculture (in press)
McPharlin IR Robertson WJ Jeffery RC and Weissberg R (1995) Response of cauliflower to phosphate fertiliser placement and soil test phosphorus calibration on a Karrakatta sand Communications in Soil Science and Plant Analysis 26(3-4) 607-620
McQuaker NR Brown DF and Kluckner PD (1979) Digestion of environmental materials for analysis by inductively coupled plasma-atomic emission spectrometry Analytical Chemistry 51 1082-1084
Novoa R and Loomis RS (1981) Nitrogen and plant production Plant and soil 58 177-204
Ozanne PG and Shaw TC (1968) Advantages of recently developed phosphate sorption test over the older extractant methods for soil phosphate (ed JW Holmes) pp 273-280 In Transactions of the 9th International Congress of Soil Science Volume 2 Angus and Robertson Sydney Australia
Porter WM (1984) Soil acidity Agriculture Western Australia Farmnote No 6884
Robertson WJ McPharlin IR and Jeffery RC (14) Final report of investigation into the use of gypsum-amended Red Mud as a soil-amendment on horticultural properties on the Swan Coastal Plain Report to HRDC (Project No V0039RO) Department of Agriculture Western Australia
Varley J A 1966 Automatic methods for the determination of nitrogen phosphorus and potassium in plant material Analyst 91 119-126
Vlahos S Summers KJ Bell DT and Gilkes RJ (1989) Reducing phosphorus leaching from sandy soils with Red Mud bauxite processing residues Australian Journal of Soil Research 27 651-662
Yuen SH and Pollard AG (1954) Determination of nitrogen in agricultural material by the Nessler reagent IL Microdetermination in plant tissue and soil extracts Journal of Science Food Agriculture 5 364-369
The use of Red Mudgypsum in vegetable production
7 RETENTION LEACHING AND RECOVERY OF P AND OTHER NUTRIENTS BY CARROTS GROWN ON A JOEL SAND AMENDED WITH RESIDUAL RED MUD (ALKALOAMreg)GYPSUM (AG) IN LARGE POTS
Introduction
It is difficult to quantify the retention of P by sands amended with Red Mud (Alkaloamreg)gypsum (AG) in the field because of native P in the soil and soluble P in the AG (Robertson et al 1994) It is easy to quantify leaching of P and other nutrients such as N and K from AG amended sands in pots or columns by collecting leachate and measuring concentration (McPharlin et al 1995) However plants were not grown in the columns used by McPharlin et al so there was no measurement of plant uptake of P and other nutrients to complete the nutrient budget Potatoes were grown successfully in Spearwood sands in large pots (70 L) and a complete N budget (N applied N retained by soil N leached and uptake by plant) determined (Hegney et al 1996)
Freshly-applied AG may not be in equilibrium with the soil to which it is applied ie the pH Ec and concentrations of elements such as Ca and Na may change rapidly with time The age of the AG may effect its capacity to retain P on amended soils AG may improve the retention of other nutrients such as ammonium N (McPharlin et al 1995) and K (Sections 5 and 6) by amended sands AG which has been applied to sands in the field for at least 2 to 5 years should be close to equilibrium with the soil as substantial leaching would have occurred AG of this age would give the best estimate of its long term capacity to reduce leaching of P and other nutrients from poor grey sands on the Swan Coastal Plain The purpose of this work was to quantify the leaching and retention of P and other nutrients (N Ca K etc) from Joel sands which had been amended with AG at different levels in the field for 14 years Carrots a major vegetable crop grown on the Swan Coastal Plain were used as the experimental crop and grown in these AG amended sands in large pots
Materials and methods
Pots
Fibreglass pots used for the experiment were 45 cm in diameter and 50 cm deep The area of soil surface was 016 m2 and the volume was 70 L The bottom of the pots tapered to a hole (diameter) to which was attached a polyethylene hose (length and diameter) and tap The pots were painted white to reduce heat The pots were placed on a metal table (with mesh tops) and the hose passed through a hole in the centre of a lid of a plastic (20 L) bucket
Experimental design
The experimental design was a 4 (levels of residual AG ie 0 125 250 and 1000 tha) times 5 (levels of applied P ie 0 50 100 200 and 400 kgha) factorial in a randomised block with 3 replicates The level of applied AG or Pha was calculated using the area of the soil surface The total number of pots was 60
Soil and Red Mud (Alkaloamreg)gypsum (AG)
Virgin Joel sand was obtained from a commercial garden supply site in Jandakot The top 20 cm of the soil was removed and the rest sieved (15 mm) to remove debris About 20 kg of Joel sand was added to each pot (10 cm depth) Another 60 kg (30 cm depth) of sand was added to the 0 AGha pots to which had been mixed lime and preplant fertilisers (see later) so the surface of the soil was about 10 cm below the top edge of the pot AG amended sand was obtained from a field site in Hope Valley Road Kwinana managed by ALCOA where it had been applied (and incorporated using a rotary hoe) to pastures growing on a Joel sand in 1983 at 0 250 500 and 1000 tha This AG amended sand was added to pots corresponding to 250 and 1000 tha in the field after the preplant fertiliser but not lime was added and was incorporated to a similar depth as in the 01 AGha pots The 125 t AGha treatment was
82
The use of Red Mudgypsum in vegetable production
obtained by mixing AG amended sand from the 250 tha field site with an equal weight of Joel sand in a cement mixer
Fertilisers and lime
The following fertilisers (in kgha) were thoroughly mixed (using a cement mixer) with the top 25-30 cm of the soil in each pot before planting Urea (108) K2SO4Q2I) MgS047H20 (100) MnS04H20 (100) Na2B4O710 H20 (50) FeS047H20 (50) CuS045H20 (50) ZnS04H20 (50) and NaMo042H20 (4) To this was added P at 0 50 100 200 and 400 kgha as single superphosphate at each level of residual AG Hydrated lime (Ca (OH)2) was mixed with the preplanting fertilisers on the 0 kg AGha treatment at 36 gpot
N K and Ca were fertigated via the drip irrigation system at 200 200 and 52 mgL using KNO3 NH4NO3 and Ca (N03)2 from immediately after sowing to 140 days after sowing (18 August 1996) MgS047H20 was broadcast at 100 kgha to each pot at weeks 6 and 12
Irrigation
The plants were irrigated using drippers (Netafim 2 Lh pressure compensated with 4 equalisers per pot) at 15 times the average monthly pan evaporation until 160 days after sowing (7 September 1996) Adjustments were made on a daily basis if evaporation was significantly higher or lower than the long term average (Table 71)
Table 71 Irrigation requirements of carrots in pot experiments
Month DAS Lpotday Minutesday
April 1- 27 10 33
May 28- 59 065 21
June 60- 90 044 14
July 91-122 044 14
August 123-154 056 19
September 155-160
Adjusted for 90 efficiency of irrigation system
Rain was excluded from the pots using a movable rain out shelter made of perspex and aluminium This was removed at all other times
Crop management
The soil in each pot was irrigated to field capacity ie so that free drainage occurred Carrot (cv Top Pak) seeds were sown on a 9 x 9 cm spacing and 1 cm deep with 5 seeds per site on 3 April 1996 These were thinned to 14 seedlingspot (88 plantsm2) after emergence (15 April 1996) No application of fungicides or insecticides were necessary
Soil and plant measurements
Soil
Immediately before fertilising and sowing 5 cores (22 diameter x 15 cm deep) were taken from each pot and dried in a force draught oven at 40degC Each sample was analysed for extractable P and K (Colwell 1963) pH (CaCl2 and H20) total P (Allen and Jeffery 1990) PRI (Allen and Jeffery 1990) total N extractable ammonium N (KC1) extractable nitrate N (KC1) organic carbon cation exchange capacity and exchangeable cations
83
The use of Red Mudgypsum in vegetable production
Leachate
Leachate from each pot was collected in 20 L plastic buckets under the pots each week from the 4 April 1996 to 22 July 1996 PMA (phenyl mercuric acetate) was added to the leachate to prevent contamination Total water volume was measured and sub-samples (200 mL) collected and submitted for analysis of P NH4-N NO3-N K Na Ca S Mg Ec and pH analysis of concentration The quantities leached of the above elements in kgha were calculated from concentration and volume of leachate collected and surface area of soil in pot
Harvest
The plants were harvested on 7 September 1997 and the total marketable and reject root yield determined for each plot
Analysis of data
Analysis of variance (Genstattrade for Windows version 32) was carried out on level of AG and P versus yield (total marketable reject) level of chemical factors in soil after harvest concentration of nutrients in youngest mature leaves at midgrowth tops and roots at harvest and leachate on 22 April 1996 5 May 1996 and 22 July 1996 and quantities of elements leached at each sampling time
Mitscherlich or linear relationships were fitted to level of P versus yield (total) at each level of residual AG P required for 95 and 99 of maximum yield was delivered at each level of residual AG P uptake by carrots was determined from the dry weight and P in tops and roots for each treatment Fertiliser P uptake was determined by deducting uptake on 0 kg Pha treatments at each level of applied AG Fertiliser P retained in the top-soil was determined from the concentration of total P and bulk density P leached was fertiliser leached below 15 cm The P in each plant fraction soil and leached was determine at each level of applied P and AG
Results
Effect of level of residual AG on chemical characteristics of Joel sand
Soil pH (CaCl2 H20) Ec Colwell P phosphorus retention index cation exchange capacity exchangeable Ca and Na and silt and clay all increased with level of residual AG in the top soil (0-15 cm) of a Joel sand before fertilising and sowing (Table 72)
The use of Red Mudgypsum in vegetable production
Table 72 Chemical and physical characteristics of Joel sand amended with residual Alkaloam gypsum (AG) in pots before fertilising and sowing of carrots
Level of residual AG
Parameter (tha)
Parameter
0 125 250 1000
pH (H20) 69 77 85 86
pH (CaCl2) 57 71 78 78
Ec (mSm) 4 9 9 11
Ext P (ngg)1 3 9 14 9
PRI2 -02 33 44 77
Total N ()3 - 0039 0044 0060
ExtNH4-N(ngg)4 - 2 2 2
ExtN03-N(ugg)5 - 3 2 5
CEC ()6 30 30 43 35
Exch Ca ()7 133 363 51 70
Exch Mg ()7 036 024 015 021
Exch Na ()7 005 015 015 032
Exch K ()7 007 004 0035 0035
OrgC()8 131 109 092 103
Sand () 977 967 960 910
Silt () 13 15 15 37
Clay () 10 23 25 53
1 Colwell (1963) 2 Phosphorus retention index (Allen and Jeffery 1990) 3 KjeldahlReardon et al 1966 4 Extracted in 1 m KC1 (Reardon et al 1966) 5 Extracted in 1 m KC1 (Best 1976) 6 Gillman and Sumpter (1986) 7 Exchangeable in 1 m NHU-Cl 8 Walkley and Black (1934)
Level of residual AG had no effect on levels of extractable NH4-N NO3-N exchangeable Mg and K or organic carbon After harvest levels of Colwell P K total P PRI Ec pH (CaCk) exchangeable Ca Mg K and Na in the topsoil (0-15 cm) all increase significantly (P lt 005) with level of residual AG (Tables 73 74)
85
The use of Red Mudgypsum in vegetable production
Table 73 Extractable P K NH4 total P (tot P) and phosphorus retention index (PRI) of the topsoil (0-15 cm) of a Joel sand after harvest of carrots with level of residual Alkaloamreggypsum (AG) and phosphorus (P)
AG
AG BicP1 BicK tot P2 PRI3 NIL (tha) (ngg) (Hgg) (ngg) (mLg) (Mfig)
0 33 119 234 -015 137
125 200 117 743 141 27
250 275 197 1258 231 19
1000 204 420 1853 154 30
Lsd5 4 34 129 45 26
Sig6
P
P (kgha)
BicP1
(ngg) BicK1
(Mgfe) totP2
(ugg) PRI3
(mLg) NIL
(ngg)
0 91 215 896 198 58
50 151 223 937 138 54
100 144 226 1005 126 62
200 182 193 1043 128 42
400 323 210 1231 116 52
Lsd5 48 39 144 50 29
Sig6 s | e ns ns
1 Colwell 1963 2 Allen and Jeffery 1990 3 Phosphorus retention index (Allen and Jeffery 1990) 4 Extracted in 1 m KC1 (Best 1976) 5 Least significant difference at P s 005 6 Significance at lt 0001 () lt 001 () lt 005 () level or not significant (ns)
By contrast levels of extractable NH4-N decreased significantly with level of residual AG Colwell P total P Colwell K all increased significantly (P lt 005) with level of applied P whilst PRI was decreased significantly Level of applied P had no significant effect on Ec pH or level of exchangeable Ca Mg K Na Colwell K or extractable NHu-N in the topsoil after harvest (Tables 73 74)
The use of Red Mudgypsum in vegetable production
Table 74 Ec (mSm) pH (CaCl2) and exchangeable cations (me) in topsoil (0-15 cm) of a Joel sand after harvest of carrots with level of residual Alkaloamreggypsum (AG) and phosphorus (P)
AG
AG Ec pH Ca1 Mg1 K1 Na1
(tha) (mSm) (CaCl2) (me) (me) (me) (me)
0 157 44 18 016 026 010
125 147 54 23 014 026 015
250 217 66 40 017 041 027
1000 308 76 135 027 096 094
Lsd2 32 01 07 002 005 005
sig3
p
p (kgha)
Ec (mSm)
pH (CaCl2)
Ca1
(me) Mg1
(me) K1
(me) Na1
(me)
0 202 59 52 019 048 035
50 195 60 53 018 050 036
100 203 60 57 019 048 039
200 202 60 57 018 045 040
400 236 59 51 017 046 034
Lsd2 35 01 08 002 006 005
Sig3 ns ns ns ns ns ns
Exchangeable in 1 m NH4CI 2 Least significant difference at P s 005 3 Significance at lt 0001 () lt 001 () lt 005 () level or not significant (ns)
Effect of level of residual AG and P on concentration of nutrients in leachate and quantities of nutrients leached
There was a significant (P lt 005) reduction in concentration of P in leachate with level of residual AG at three times of sampling (Fig 71) P concentration in leachate increased significantly with level of applied P at 01 AGha but not in presence of AG
P concentration in leachate at 01 AGha decreased with time from 80 mgL on 16 April 1996 at 400 kg Pha to 025 mgL on 22 July 1996 To reduce P concentration in leachate 125 t AGha was as effective as 250 or 1000 tha at all sampling times and levels of applied P Similar trends were shown in quantity of leached P as total or soluble reactive P in kgha (Appendix 71 (b) 72) Level of applied AG significantly (P lt 005) reduced the concentration of NH4-N in leachate from 40 mgL at 01 AGha to 15 mgL at 250 and 1000 tha (Fig 72 (a)) on 16 April 1996 Significant reductions in concentration were recorded on the other two sampling times as NH4-N concentration declined with increased plant uptake Similar trends were shown in the quantity of NH4-N leached with level of AG (Appendix 72 (b)) By contrast level of applied AG had no significant effect on concentration of NO3-N in leachate or quantity leached at any of the three sampling times (Fig 72 (b) and Appendix 73 (b)) There was a significant (P lt 005) reduction in concentration of K in leachate and quantity of K leached with level of residual AG although the reduction was less at the later sampling times (Fig 73 Appendix 73 (a)) Concentration of K in leachate increased
87
The use of Red Mudgypsum in vegetable production
with time at all levels of residual AG except 1000 tha By contrast both the concentration of Na in leachate and quantity of Na increased with level of residual AG to a maximum at the highest level (1000 tha) There was a reduction in Na concentration in leachate with time at level of residual AG lt 1000 tha The concentration of Ca in leachate increased significantly (P lt 005) as did quantity leached with level of residual AG and with time at all levels of AG (Fig 74 Appendix 74 (a)) By contrast concentration of Mg in leachate and quantity leached decreased significantly (P lt 005) with level of residual AG and with time at all levels of AG (Fig 78 and Appendix 78 (a)) There was a significant (P lt 005) increase in S concentration in leachate and quantity leached with level of residual AG at the first sampling time a decrease at the second and a increase up to 250 tha at the third sampling (Fig 79 Appendix 79 (a)) S concentration in leachate and quantity leached varied significantly with level of applied P at all sampling times and decreased with time from 16 April 1996 to 22 July 1996 (Fig 79 and Appendix 79 (a))
The use of Red Mudgypsum in vegetable production
deg E
c o
o O
c ltD
O
c o
I O
1 0 0 2 0 0 3 0 0 4 0 0
A p p l i e d P ( k g h a )
5 0 0
1 0 0 2 0 0
A p p l ie d P
3 0 0
k g h a )
4 0 0 5 0 0
1 0 0 2 0 0 3 0 0
A p p l i e d P ( k g h a
4 0 0 5 0 0
Figure 71 Concentration of P (mgL of total P) in leachate from Joel sands sown to carrots with level of applied P and Alkaloamreggypsum (AG) at 0 (bull) 125 (bull) 250 (A) and 1000 (T) tha on 16 April 1996 (A) 6 May 1996 (B) and 22 July 1996 (C) P was applied preplanting as superphosphate and carrots were sown on 3 April 1996 Vertical bars refer to Lsd (P lt 005) for differences in concentration between level of AG (at each level of P) or P (at each level of AG) or the interaction between AG and P Where bars arent shown Lsd is less than size of symbol
89
The use of Red Mudgypsum in vegetable production
2 0 0 4 0 0 6 0 0 8 0 0 1 0 0 0 1 2 0 0
L e v e l o f r e s i d u a A G ( t ha )
2 0 0 4 0 0 6 0 0 8 0 0 1 0 0 0 1 2 0 0
L e v e l o f r e s i d u a l A G ( t h a )
Figure 72 Concentration (mgL) of NBU-N (A) and NO3-N (B) in leachate from Joel sand sown to carrots amended with residual AlkaIoamreggypsum (AG) in pots on 16 April 1996 (bull) 6 May 1996 (bull) and 22 July 1996 (A) The carrots were sown on 3 April 1996 N was fertigated at a constant concentration of 300 mgL (250 mgL of NO3-N and 50 mgL NH4-N) from sowing to harvest Vertical bars refer to Lsd (P lt 005) for differences in concentration between level of AG at each sampling time Where bars arent shown Lsd is less than size of symbol
The use of Red Mudgypsum in vegetable production
200 400 600 800 1000 1200
Level of AG (tha)
200 400 600 800
Level of AG (tha)
1 0 0 0 1 2 0 0
Figure 73 Concentration (mgL) of K (A) and Na (B) in leachate from Joel sand sown to carrots amended with residual Alkaloamreggypsum (AG) in pots on 16 April 1996 (bull) 6 May 1996 (bull) and 22 July 1996 (A) The carrots were sown on 3 April 1996 K was fertigated at a constant concentration of 200 mgL from sowing to harvest Vertical bars refer to Lsd (P lt 005) for differences in concentration between level of AG at each time Where bars arent shown Lsd is less than size of symbol
91
The use of Red Mudgypsum in vegetable production
Effect of level of residual AG and P on concentration of nutrients in plants The concentration of K P Fe Cu Mn and Mo in the youngest mature leaves (YML) of carrots at midgrowth all increased significantly with level of residual AG (Tables 75 (a) (b)) The concentration of S in YML at midgrowth was significantly reduced as level of residual AG increased whilst concentrations of Ca Na Mg Zn and B were variable
Table 75 Concentration of nutrients ( dry basis) in youngest mature leaves of carrot at midgrowth with level of residual Alkaloamreggypsum (AG) and phosphorus (P)
(a) Macronutrients
AG
AG (tha)
K1 Ca2 S2 P1 Na2 Mg2
0 486 229 061 025 050 039
125 584 186 060 033 047 034
250 585 216 058 033 044 035
1000 531 215 056 031 052 037
Lsd3 03 02 004 0017 005 003
Sig4
p
P (kgha)
K1 Ca2 S2 P1 Na2 Mg2
0 538 198 062 029 037 036
50 523 222 061 028 043 037
100 562 208 056 030 049 035
200 548 216 057 032 058 037
400 563 214 056 035 054 036
Lsd3 033 022 004 002 006 003
Sig4 ns ns ns
1 After Varley (1966) 2 After McQuaker et al (1979) 3 Least significant difference at P s 005 4 Significance at lt 0001 () lt 001 () lt 005 () level or not significant (ns)
The use of Red Mudgypsum in vegetable production
Table 75 Concentration of nutrients ( dry basis) in youngest mature leaves of carrot at midgrowth with level of residual Alkaloam gypsum (AG) and phosphorus (P)
(b) Micronutrients
AG
AG (tha)
Fe Mn1 Zn B Cu Mo
0 111 386 280 345 95 21
125 127 279 367 348 107 25
250 126 173 269 349 108 24
1000 114 60 143 337 110 31
Lsd2 20 47 40 15 05 06
Sig3 ns ns
p
p (kgha) Fe Mn Zn B Cu Mo1
0 135 243 263 356 120 28
50 122 240 268 349 111 30
100 109 191 229 343 106 25
200 116 228 268 334 99 23
400 115 221 294 341 89 20
Lsd2 23 52 45 15 051 07
Sig3 ns ns ns ns
1 After McQuaker et al (1979) 2 Least significant difference at P s 005 3 Significance at lt 0001 () lt 001 () lt 005 () level or not significant (ns)
Concentration of P S and Na in YML increased significantly (P lt 005) with level of applied P whilst concentrations of Cu and Mo decreased (Tables 75 (a) (b)) By contrast concentrations of K Ca Mg Fe Mn Zn and B were not significantly changed by level of applied P
93
The use of Red Mudgypsum in vegetable production
At harvest the concentration of P N K and Fe in whole tops increased significantly (P lt 005) with level of residual AG whilst concentration of S Mn Zn and B decreased (Table 76) The concentrations of Ca Na and Mg were variable with level of residual AG whilst there was no significant effect on the concentration of Cu
Table 76 Concentration of nutrients ( dry basis) in whole carrot tops at harvest with level of residual Alkaloamreggypsum (AG) and phosphorus (P)
(a) Macronutrients
AG
AG (tha)
N1 K1 Ca2 S2 P1 Na2 Mg2
0 300 503 269 071 016 093 039
125 348 649 239 065 024 090 035
250 395 653 251 061 022 082 033
1000 351 566 262 066 024 099 037
Lsd3 010 036 011 002 001 009 002
Sig4
p
p (kgha)
N1 K1 Ca2 S2 P1 Na2 Mg2
0 355 589 240 073 019 074 035
50 343 597 258 068 020 082 036
100 339 587 257 068 021 098 038
200 339 580 259 063 022 108 037
400 332 608 263 057 024 095 036
Lsd3 011 041 012 002 001 010 002
Sig4 ns
1 After Varley (1966) 2 After McQuakere al (1979) 3 Least significant difference at P s 005 4 Significance at lt 0001 () lt 001 () lt 005 () level or not significant (ns)
The use of Red Mudgypsum in vegetable production
Table 76 Concentration of nutrients ( dry basis) in whole carrot tops at harvest with level of residual Alkaloamreggypsum (AG) and phosphorus (P)
(b) Micronutrients
AG
AG (tha)
Fe1 Mn1 Zn1 B1 Cu1
0 299 962 234 402 109
125 316 952 184 404 107
250 331 662 110 380 110
1000 374 673 77 383 115
Lsd2 90 106 20 002 05
Sig3 ns ns
p
p (kgha) Fe1 Mn1 Zn1 B1 Cu1
0 294 969 158 409 125
50 392 837 144 393 117
100 364 747 141 396 114
200 267 712 159 387 105
400 332 bull 796 154 377 89
Lsd2 101 118 23 13 05
Sig3 ns ns
1 After McQuaker et al (1979) 2 Least significant difference at P lt 005 3 Significance at lt 0001 () lt 001 () lt 005 () level or not significant (ns)
As level of applied P increased concentration of P Ca and Na in whole tops increased significantly (P lt 005) whilst concentrations of N S Mn B and Cu decreased There was no significant effect of level of applied P on concentrations of K Fe or Zn in whole tops whilst concentration of Mg was variable
Effect oflevel of residual AG and P on carrot yield
There was a significant (P lt 005) increase in total and marketable yield with level of applied P at all levels of applied AG (Table 77) The overall effect of AG was to reduce both total and marketable yield at the highest level (1000 cf 0 to 2501 AGha) especially at low levels of applied P (ie 0 to 50 kg Pha) At higher levels of applied P yield at 2501 AGha was not significantly (P lt 005) lower than at 125 tha
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The use of Red Mudgypsum in vegetable production
However at 10001 AGha total and marketable yield was significantly lower than 0 tha at all levels of applied P The relationship between level of applied P and total yield was described as linear at 0 250 and 10001 AGha and Mitscherlich at 125 AG tha (Fig 76) As yield did not maximise at 0 250 and 1000 t AGha no optimal level of applied P for 95 or 99 of maximum yield could be determined At 125 t AGha the level of applied P necessary for 95 and 99 of maximum yield was 182 and 314 kg Pha respectively
Effect of level of AG and P on efficiency of P recovery by plants and retention in soil
The proportion () of P recovered in the carrot roots and tops decreased with level of applied P increasing from 8 to 12 to 5 to 8 of depending on level of AG (Table 78) There was a reduction in P recovered in roots tops and whole plant as level of AG increased For example P recovered by whole plants at 01 AGha at 400 kg Pha was 8 but this had declined to 5 at 10001 AGha
Table 78 The of applied fertiliser P taken up by carrots grown in pots (tops roots) retained in the topsoil or leached with level of residual Alkaloamreggypsum (AG) and phosphorus (P) on a Joel sand
P in Fraction AG P ( of P applied )
(tha) (kgha) TopsA Roots2 Plant(A+B) Soil2 Leached3
0 50 2 9 11 3 86
0 100 2 8 10 13 77
0 200 2 6 8 2 90
0 400 2 6 8 3 89
125 50 4 8 12 73 15
125 100 2 8 10 18 72
125 200 2 6 8 30 62
125 400 1 4 5 18 77
250 50 3 7 10 0 90
250 100 2 4 6 0 94
250 200 1 4 5 0 95
250 400 1 4 5 12 83
1000 50 2 6 8 75 17
1000 100 2 5 7 67 26
1000 200 2 5 7 45 48
1000 400 1 4 5 41 55
P in fraction expressed as of P applied as fertiliser 2 P retained in topsoil (0-15 cm) 3 P leached below 15 cm
By contrast of applied P retained in topsoil varied with level of AG For example only 3 of P was retained in topsoil at 400 kg Pha and 01 AGha where as this had increased to 41 at 10001 AGha at the same level of applied P Consequently the of P leached decreased as level of AG increased For example at 01 AGha and 400 kg Pha nearly 90 of applied P leached below 15 cm This had been reduced to 55 at 10001 AGha and the same level of applied P
97
The use of Red Mudgypsum in vegetable production
Table 79 Fertiliser P leached (kgha) and P leached as a of P applied from a Joel sand sown to carrots with level of residual Alkaloam gypsum (AG) and P after harvest The P was then applied as superphosphate prior to planting The carrots were sown on 3 April 1996 P leached is expressed as a percentage of P applied
AG (tha)
P (kgha)
P leached1
(kgha) P leached
( P applied)
0 50 41 82
0 100 78 78
0 200 158 79 0 400 311 78
125 50 2 4
125 100 3 3
125 200 10 5 125 400 27 7
250 50 1 2
250 100 3 3 250 200 4 2
250 400 7 2 1000 50 02 lt1 1000 100 05 lt1
1000 200 1 lt1
1000 400 2 lt1
1 Fertiliser P leached = total P leaclied - P leached at 0 kg Pha (ie background P) 2 (Fertiliser P leachedP applied x 100)
The use of Red Mudgypsum in vegetable production
O)
pound CD
o TO
(D
o
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c
o c o o
pound
(0
o to
c o
TO tmdash
c 0) o c o o
0 2 0 0 4 0 0 6 0 0 8 0 0 1 0 0 0 1 2 0 0
L e v e l o f r e s i d u a l A G ( t h a )
0 2 0 0 4 0 0 6 0 0 8 0 0 1 0 0 0 1 2 0 0
L e v e l o f r e s i d u a l A G ( t h a )
Figure 74 Concentration (mgL) of Ca (A) and Mg (B) in leachate from Joel sand sown to carrots amended with residual Alkaloamreggypsum (AG) in pots on 16 April 1996 (bull) 6 May 1996 (bull) and 22 July 1996 (A) The carrots were sown on 3 April 1996 Ca was applied preplanting as superphosphate and fertigated at a constant concentration of SO mgL from sowing to harvest AG was applied preplanting and in weeks 6 (15 May 1996) and 12 (25 June 1996) Vertical bars refer to Lsd (P lt 005) for differences in concentration between level of AG at each time Where bars arent shown Lsd is less than size of symbol
99
The use of Red Mudgypsum in vegetable production
CD
CO
x o CO CD
c o
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CO
c CD O c o O
0 2 0 0 4 0 0 6 0 0 8 0 0 1 0 0 0 1 2 0 0
L e v e l of r e s i d u a l A G ( t ha )
0 100 2 0 0 3 0 0 4 0 0
L e v e l of r e s i d u a l P ( k g h a )
5 0 0
Figure 75 The concentration of S (mgL) in leachate from Joel sands sown to carrots with level of residual Alkaloamreggypsum (AG) (A) and P (B) on 16 April 1996 (bull) 6 May 1996 (bull) 22 July 1996 (A) The carrots were sown on 3 April 1996 S was applied preplanting as K2S04 and in superphosphate Vertical bars refer to Lsd (P lt 005) for differences in concentration between level of AG (A) or P (B) at each sampling time Where bars arent shown Lsd is less than size of symbol
100
The use of Red Mudgypsum in vegetable production
ID
0 100 200 300 400 500
Applied P (kgha)
lb 70
70 C
60 65 -
60
55 dt
ha 50
40
50
45 bull A
Yie
30
40 _ 20
35 i i i i 35 0 100 200 300 400 5( 50 10
Applied p (kgha)
0 100 200 300 400 500
Applied P (kgha)
0 100 200 300 400 500
Applied P (kgha)
Figure 76 Total yield of carrots with level of freshly-applied P at four levels of residual Alkaloamreggypsum (AG) (A B C D = 01252501000 tha) Vertical dashed and whole lines refer to applied P necessary to 95 (dashed) or 99 (whole) of maximum yield respectively
The equations of the fitted lines are
A y = 10943 - 9377 x exp (-00053) (R2 = 099)
B y = 6l7- 2848 x exp (-00122) (i2 = 099)
C y = 3842+ 0083x (J2 = 097)
D y = 238 + 0l07x(R2 = 096)
As level of applied P increased concentration of P Ca and Na in whole tops increased significantly (P lt 005) whilst concentrations of N S Mn B and Cu decreased There was no significant effect of level of applied P on concentrations of K Fe or Zn in whole tops whilst concentration of Mg was variable
101
The use of Red Mudgypsum in vegetable production
Discussion
The addition of residual Alkaloamreggypsum (AG) resulted in a significant reduction in the concentration of P NH4-N K and Mg in the leachate from Joel sands sown to carrots in large pots The reduction in P concentration is attributed to an increase in the level of iron and aluminium oxides when AG is applied to soils low in these minerals (Barrow 1982) Consequently all soil measurements of P status or retention such as total P Colwell P and phosphorus retention index as well as Ec and pH all increased with level of applied residual AG Similar reductions in phosphorus leaching or increases in P retention have been reported when Gavin (Vlahos et al 1989) or Joel (Sections 4 and 5 McPharlin et al 1994 Robertson et al 1997) sands were amended with fresh or residual AG (Sections 4 and 6 Robertson et al 1994)
The reduced leaching of cations such as NH4-N K and Mg is attributed to an increase in captain exchange capacity (CEC) when sands of low CEC are amended with AG (Barrow 1982 McPharlin et al 1994) Consequently NO3-N retention is not increased when soils are amended with residual (Fig 72) or freshly-applied AG (McPharlin et al 1994) The increased leaching of Na Ca and S from amended sands is attributed to the Alkaloamreg as a source of these elements either in the Alkaloamreg itself (Na2C03) or after amendment with gypsum (CaS042H20) which precipitates CaC03 and Na2S04 The Na2S04 is very soluble as is easily leached whereas Ca is only slightly soluble as gypsum and insoluble as lime Vlahos et al (1989) reported increased leaching of Na Ca and S from Gavin sands treated with copper as (FeS04) amended Alkaloamreg compared with unamended controls in the short term and a decrease in the longer term Concentrations of P in the YML at midgrowth or tops at harvest increased with level of applied P and also with level of residual AG from 025 at 0 t AGha to 031 at 10001 AGha By contrast freshly-applied AG reduced the concentration of P in the YML from 043 on unamended to 030 on amended Joel sands (Robertson et al 1997) Even at the highest level of applied P the concentration of P in the YML 035 was still lower than that shown to be necessary for maximum yield of carrots (ie 038 McPharlin et al 1992) This could explain why the yield wasnt maximised in three out of the four AG treatments On the treatment that yield was maximised 125 t AGha the highest concentration of P ie 038 was recorded The difference in trends of P in petioles with AG between the 2 studies could be explained in terms of the relative leaching of P or addition of P in the AG itself On the virgin Joel sand used in the pot study leaching of P was significant enough to reduce leaf P in the unamended versus amended treatments For example the P in YML was significantly lower in the 01 AGha than at all other levels of residual AG at all levels of applied P up to 200 kgha For example the P in YML at 01 AGha ranged from 020 to 027 at 0 and 200 kg Pha respectively whilst at 125 t AGha the P was 032 to 038 over the same levels of applied P (Appendix 71) This suggests that loss of P from the top soil is severely limiting the uptake of P by the plant in the absence of AG The phosphorus retention of virgin Joel sands is almost negligible with a PRI of close to 0 (Table 72 McPharlin et al 1994 Robertson et al 1997) By contrast the P retention of Joel sands appears to be increased following development possibly by the addition of iron in irrigation water and organic and inorganic fertilisers For example the estimate of PRI (PREM) ie PRI plus P as Colwell P measured in the developed Joel sands used by Robertson et al was 40 in the topsoil (0-15 cm) of the unamended treatment Thus in these soils P retention is high enough to reduce availability when AG is added and explains the reduced levels of P in the YML as level of AG is increased The contribution of AG to the P nutrition of the plant is an unlikely explanation as it didnt increase P levels in the plant when applied fresh (Robertson et al 1997)
Previous work showed that concentrations of K in the petioles of potatoes (Section 4 Robertson et al 1997) and youngest mature leaves in cauliflower (Robertson et al 1994 Sections 5 and 6) declined with level of freshly-applied and residual AG
With potatoes the decline in K concentrations was associated with a decrease in K concentration in the soil solution and an increase in Na concentrations in soil solution and petioles on fresh and residual AG treatments (Section 4 Robertson et al 1997) This was
102
The use of Red Mudgypsum in vegetable production
used to explain yield reductions on fresh AG sites at gt 60 tha or on residual sites at 240 tha With cauliflower the findings were variable Where yield was reduced (Robertson et al 1994) it could not be explained in terms of K nutrition as K concentrations in the YML did not decline to levels expected to result in deficiency In follow up work neither fresh or residual AG up to 240 tha resulted in yield reduction although there was a reduction in K concentrations in the YML but not below critical levels (Sections 5 and 6) By contrast concentrations of K in the YML of carrots increased with level of residual AG up to 1000 tha as did exchangeable K in the soil Similar increases in K concentration in YML of Chinese and Head cabbage with level of AG on Joel sands have been reported previously (Robertson et al 1994)
Yield response of carrots to applied P at various levels of residual AG was variable on Joel sands in this work For example yield with level of applied P reach a plateau at 125 t AGha (ie 182 and 314 kg Pha for 95 and 99 of maximum yield from the Mitscherlich regression) However at other levels of applied AG including 0 tha yield had not maximised at the highest level of applied P (400 kgha) This is surprising considering that on higher P retaining soils such as Karrakatta sands yield is maximised at much lower levels of applied P (ie 160 to 180 kgha) at a similar low P soil test (McPharlin et al 1992 1994) in the absence of AG Also on Joel sands yields of carrots at medium to low P soil test (16 to 20 ugg Colwell P) only 50 kg Pha was necessary for maximum yield (McPharlin et al Lantkze and McPharlin unpublished data) The only possible explanation is that leaching of P was significant enough in the absence of AG that increased levels of applied P were required to satisfy crop requirements The increase in P fertiliser requirement as level of applied AG increases as shown in this work above 125 tha is similar to that reported previously for Chinese and Head cabbage cauliflower lettuce onions (Robertson et al 1994) and potatoes (Robertson et al 1997) It is explained by increased P retention capacity of the soil when AG is applied and measured by PRI Colwell and Total P and similar measurements
References
Allen DG and Jeffery RC (1990) Methods for analysis of phosphorus in Western Australian soils Chemistry Centre of Western Australia Report of Investigation No 37
Barrow NJ (1982) Possibility of using caustic residue from bauxite for improving the chemical and physical properties of sandy soils Australian Journal of Agricultural Research 33 275-285
Best EK (1976) An automated method for the determination of nitrate-nitrogen in soil extracts Queensland Journal of Agriculture and Annual Science 33 161-166
Colwell JD (1963) The estimation of phosphorus fertiliser requirements of wheat in southern New South Wales by soil analysis Australian Journal of Experimental Agriculture and Animal Husbandry 3 190-197
Hegney M A McPharlin IR and Jeffery RC (1997) Response of winter-grown potatoes (Solanum tuberosum L) to freshly-applied and residual phosphorus on a Karrakatta sand Australian Journal of Experimental Agriculture 37 131-137
McPharlin IR Alymore PM and Jeffery RC (1992) Response of carrots (Daucus carota L) to applied P and P leaching on a Karrakatta sand under two irrigation regimes Australian Journal of Experimental Agriculture 32 225-232
McPharlin IR Jeffery RC and Weissberg R (1994) Determination of the residual value of phosphate and soil test phosphorus calibration for carrots on a Karrakatta sand Communications in Soil Science and Plant Analysis 25 (5-6) 489-500
103
The use of Red Mudgypsum in vegetable production
McPharlin IR Robertson WJ Jeffery RC and Weissberg R (1995) Response of cauliflower to phosphate fertiliser placement and soil test phosphorus calibration on a Karrakatta sand Communications in Soil Science and Plant Analysis 26(3amp4) 607-620
McQuaker NR Brown DF and Kluckner PD (1979) Digestion of environmental materials for analysis by inductively coupled plasma-atomic emission spectrometry Analytical Chemistry 51 1082-1084
Reardon J Foreman JA and Serai RL (1966) New reactants for the determination of ammonia Clinica Chemica Acta 14 403-405
Robertson WJ McPharlin IR and Jeffery RC (1994) Final report of investigation into the use of gypsum-amended Red Mud as a soil-amendment for horticultural properties on the Swan Coastal Plain Final Report of HRDC Project No V0039 RO
Robertson WJ Jeffery RC and McPharlin IR (1997) Residues from bauxite-mining (Red Mud) increase phosphorus retention of a Joel sand without reducing yield of carrots Communications in Soil Science and Plant Analysis 28 (13 amp 14) 1059-1079
Varley JA (1966) Automatic methods for the determination of nitrogen phosphorus and potassium in plant material Analyst 91 119-126
Vlahos S Summers KJ Bell DT and Gilkes RJ (1989) Reducing phosphorus leaching from sandy soils with Red Mud bauxite processing residues Australian Journal of Soil Research 27 651-662
Walkley A and Black I (1934) An examination of the Degtjareff method of determining soil organic matter and a proposed modification of the chromic acid titration method Soil Science 37 29-38
Yuen SH and Pollard AG (1954) Determination of nitrogen in agricultural material by the Nessler reagent II Micro determination in plant tissue and soil extracts Journal of the Science of Food and Agriculture 5 364-369
104
The use of Red Mudgypsum in vegetable production
CO JC
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0 200 400 600 800
Level of residual AG(tha)
1000 1200
Appendix 71 (b) P leached (kgha) from Joel sands sown to carrots amended with residual Alkaloanrgypsum (AG) in pots on 16 April 1996 (week 3) (bull) 6 May 1996 (week 6) (bull) and 22 July 1996 (week 16) ( bull ) P was applied preplanting as superphosphate and carrots were sown on 3 April 1996 Vertical bars refer to Lsd (P lt 005) for differences in quantities of P leached between level of AG (across all levels of applied P) at each sampling time Where bars arent shown Lsd is less than size of symbol Data from Appendix 71 (a)
105
The use of Red Mudgypsum in vegetable production
200 400 600 800
Level ofresidual AG(tha)
1 000 1 200
2 00
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copy
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1 2 0
100 -
80 200 400 600 800
Level of residual AG (tha)
1000 1200
Appendix 73 (b) 74 (b) Ammonium-N (A) and Nitrate-N (B) leached (kgha) from Joel sands sown to carrots amended with residual Alkaloamreggypsum (AG) in pots on 16 April 1996 (week 3) (bull) 6 May 1996 (week 6) (bull) and 22 July 1996 (week 16) (A) N was fertigated postplanting as NH4-N and NO3-N and carrots were sown on 3 April 1996 Vertical bars refer to differences in quantities of N leached between level of AG (across all levels of applied P) at each sampling time Where bars arent shown Lsd is less than size of symbol Data from Appendices 73 (a) 74 (a)
106
The use of Red Mudgypsum in vegetable production
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Appendix 75 76 K (A) and Na (B) in leachate from Joel sand sown to carrots amended with residual Alkaloamreggypsum (AG) in pots on 16 April 1996 (week 3) (bull) 6 May 1996 (week 6) (bull) and 22 July 1996 (week 16) (A) The carrots were sown on 3 April 1996 K was fertigated at a constant concentration of 200 mgL from sowing to harvest and Na was a constituent of AG Vertical bars refer to Lsd (P lt 005) for differences in quantities of K and Na leached between level of AG (across all levels of applied P) at each time Where bars arent shown Lsd is less than size of symbol
107
The use of Red Mudgypsum in vegetable production
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Appendix 77 78 Ca (A) and Mg (B) in leachate from Joel sand sown to carrots amended with residual Alkaloamreggypsum (AG) in pots on 16 April 1996 (bull) 6 May 1996 (bull) and 22 July 1996 (A) The carrots were sown on 3 April 1996 Ca was applied preplanting as superphosphate (and as a constituent of AG) and fertigated at a constant concentration of 50 mgL from sowing to harvest Mg was applied preplanting and in weeks 6 (15 May 1996) and 12 (25 June 1996) Vertical bars refer to Lsd (P lt 005) for differences in quantity of Ca and Mg leached between level of AG (across all levels of applied P) at each sampling time Where bars arent shown Lsd is less than size of symbol Data from Appendices 77 (a) and 78 (a)
108
The use of Red Mudgypsum in vegetable production
200 400 600 800
Level of residual AG(tha)
1000 1200
Appendix 79 S (mgL) in leachate from Joel sands sown to carrots with level of residual Alkaloamreggypsum (AG) 16 April 1996 (week 3) (bull) 6 May 1996 (week 6) (bull) 22 July 1996 (week 16) (A) The carrots were sown on 3 April 1996 S was applied preplanting as K2S04 in superphosphate and as a constituent of AG Vertical bars refer to Lsd (P lt 005) for differences in quantity of S leached between level of AG (A) or P (B) at each sampling time Where bars arent shown Lsd is less than size of symbol Data from Appendix 79 (a)
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CONTENTS
Page
1 Summary and recommendations 1
2 Project staff collaborators and acknowledgments 4
3 Publications arising out of work 5
4 Response of potatoes to freshly-applied and residual Red Mud (Alkaloamreg)gypsum 6 and phosphorus on a yellow Karrakatta sand
5 Response of cauliflowers to freshly-applied Red Mud (Alkaloamreg)gypsum and 30 phosphorus on a yellow Karrakatta sand
6 Response of cauliflowers to residual Red Mud (Alkaloamreg)gypsum and 59 phosphorus on a yellow Karrakatta sand
7 Retention leaching and recovery of P and other nutrients by carrots grown on 82 a Joel sand amended with residual Red Mud (Alkaloamreg)gypsum in large pots
CO
The use of Red Mudgypsum in vegetable production
1 SUMMARY AND RECOMMENDATIONS
11 Technical summary
Red Mud (Alkaloamreg)gypsum (AG) is seen as a useful amendment to increase the P retention of acid sandy soils low in this characteristic such as the Bassendean (Joel Gavin and Jandakot) and grey-phase Karrakatta sands P fertilisers applied to these soils from intensive horticultural production may leach and pollute associated water systems such as lakes rivers and estuaries Unfortunately because of strong demand for other land uses on soils better suited to vegetable production on the Swan Coastal Plain such as the Spearwood and yellow Karrakatta sands more of the less environmentally suitable Bassendean sands are being used for horticulture
In a previous project (HRDC VG0039) freshly-applied AG caused yield reduction in cauliflower and potatoes at low rates ie 60 tha on Karrakatta sands
In addition the effect of AG appeared to be specific and to vary with species For example levels of freshly-applied AG up to 240 tha had no effect on the yield of carrots on Joel sands and increased the yield of lettuce on Karrakatta sands
For this reason we approached Alcoa and HRDC for a subsequent project to further examine the response of cauliflower and potatoes to freshly-applied and residual AG
Addition of AG significantly increased the P retention (as measured by PRI total and Colwell P) pH Ec and exchangeable cations (NHU-N Ca K and Na) in the top 15 cm of the sands whilst concentrations of P and K in soil solution were reduced
With potatoes the effect of AG on yield varied depending of whether it was fresh or residual For example yield of potatoes were reduced with 601 of fresh AGha but only at 2401 of residual AGha In both cases the yield reduction could not be explained in terms of reduced P uptake by the plants as increased levels of applied P did not obviate the problem The yield reduction appeared to be due to K deficiency induced by high levels of Na (alkalinity) in the AG This was correlated with reduced K in soil solution With residual AG the alkalinity was lower as there had been more time for leaching and consequently the yield reduction was much less At levels of AG likely to be recommended for commercial use ie 60 to 120 tha no yield reduction would be anticipated with potatoes provided the AG was thoroughly leached with irrigation water for 1 or 2 months prior to planting In contrast to the previous project applications of fresh or residual AG up to 240 tha did not cause any reduction in yield of cauliflower even though concentrations of K decreased and Na increased in the YML at midgrowth
The optimum level of AG is that required to reduce leaching of fertiliser P substantially without reducing yield quality or increasing the level of P required for maximum crop yield significantly For example on unamended Joel sands leaching of fertiliser P was so high (ie 78 to 80 of applied P) that yield of carrots did not reach a maximum despite high levels of applied P (ie up to 400 kgha) By contrast 125 t AGha reduced leaching of fertiliser P to only 5 to 7 of applied P whilst yield maximised at 182 (95) and 314 (99) kg Pha At higher levels of AG (250 and 1000 tha) P required for maximum yield was significantly increased ie yield did not maximise at 400 kg Pha whilst leaching of P was not reduced much more than at 125 tha ie 1 to 3 of applied P However even at 125 tha the level of applied P required for maximum carrot yield (182 to 314 kgha) was higher than that required for maximum yield on higher P fixing sands such as the yellow Karrakatta sands ie 120 to 180 kgha suggesting that levels of AG less than 125 tha may be more agronomically suitable
In conclusion the benefits of amending acid sands with AG are increased retentionreduced leaching of P increased retentionreduced leaching of K Mg and NH4-N due to increased cation retention and an increase in pH (ie lime effect) The improved P retention of AG-amended sands enables the use of P soil testing as part of the P management of these soils whereas prior to amendment soil testing was not practical as leaching of P was too high
The use of Red Mudgypsum in vegetable production
An additional benefit which was not thoroughly investigated in this project but was obvious in the pot experiment was increased soil moisture holding capacity especially at high levels of application due to an increased in the fine fractions after amendment These benefits should be achieved at low to moderate levels of applied AG (ie 60 to 120 tha) without any negative effect on vegetable yield or quality
Some negative effects of amending acid sands with fresh AG include decreased yield due to increased conductivity and induced K deficiency in some vegetables such as potatoes However this does not appear to be a problem with carrots and cauliflower
This problem can be obviated by allowing sufficient time to leach the soluble alkalinity (Na2SCgt4) out of the root zone of the amended soil prior to cropping as it is less of a problem with residual AG Another disadvantage is the increase in fertiliser P requirements of vegetables after AG amendment in the short term due to increased P fixation This is particularly obvious at high levels of application However this disadvantage is offset as soil testing can be used on sands after amendment to reduce P fertiliser costs whereas it couldnt beforehand Also on unamended Joel sands leaching of P fertilisers (ie 80 of applied P) causes significant economic loss due to fertiliser losses and increased fertiliser P required for maximum yield
12 Industry summary
An important domestic and export vegetable industry is located on the sands of the Swan Coastal Plain (SCP) in Western Australia The total value of the vegetable industry on the SCP was estimated at $90M in 19967 or about 50 of the total value of the industry This vegetable production has been located on good quality sands such as the Spearwood and yellow Karrakatta sands close to the coast since the 1950s However in recent years competition for this land for urban and industrial use has forced vegetable production onto soils with poorer water and phosphorus retention capacity such as the more acidic Bassendean (Joel) and grey-phase Karrakatta sands This has lead leaching of fertiliser phosphorus into water systems of the SCP such as lakes rivers and estuaries with resulting pollution (algae blooms) Even though vegetable production is not the only or main source of this leached phosphorus the issue has resulted in negative publicity for the industry and increased scrutiny of industry practices by government agencies charged with responsibility for water the environment and health
As large quantities of Red Mud (Alkaloamreg)gypsum (AG) were produced from bauxite refining on the SCP it made sense to examine this as a soil amendment as it had been shown to improve the phosphorus retention capacity of coarse grey sands low in iron and aluminium oxides AG consistently increases the phosphorus retention capacity and the retention of cations such as potassium magnesium and ammonium-nitrogen and pH (lime effect) of grey and pale-yellow sands after amendment The reduction fertiliser P leaching is very high even at the lower rates of application such as 60 and 120 tha Fresh AG will increase the fertiliser phosphorus requirements of most vegetable crops compared with the unamended plots similar to the differences between low and high P fixing soils However this increase is not as much on residual or aged AG sites This increase in initial fertiliser P needs following AG application is offset by the use of soil testing to manage P fertiliser in subsequent crops on grey sands which was not practical prior to amendment Some initial problems with fresh AG causing yield reductions on potatoes was attributed to induced potassium deficiency due to high conductivity (ie high sodium) in amended soils However this problem can be overcome by leaching the soil of salts after amendment with high rates of irrigation so that EC of the amended soil doesnt exceed 6 mSm and the pH (water) 85 The potassium nutrition of the crop should be monitored to ensure it is adequate There is no problem on sites where AG has been applied for at least 12 months
2
The use of Red Mudgypsum in vegetable production
13 Recommendations It is recommended that AG be used as a soil amendment for vegetable crops on the grey and pale yellow sands of the SCP to reduce P fertiliser leaching However a number of guidelines should be adhered to ensure maximum benefits and minimum risks from the use of AG
bull Potatoes should not be grown on sites where fresh AG (ie 1 to 3 months after application) has been applied
bull Potatoes can be grown on sites where AG has be applied at levels up to 120 tha provided at least 12 months previously provided sufficient leaching of salts has occurred As a guide it is suggested that soil conductivity should not exceed 6 mSm and pH (water) 85 in the top 15 cm
bull Vegetable crops other than potatoes can be planted into sites where fresh AG has been applied at levels up to 120 tha without problems
bull Adjust level of P fertiliser application to account for increased P fertiliser requirements of vegetables due to higher P fixing on sites amended with AG
bull Use soil testing to manage P fertiliser applications on AG amended sites but follow recommendations for specific vegetable crops
The use of Red Mudgypsum in vegetable production
2 PROJECT STAFF
Ian McPharlin
Wendy Robertson
Bob Jeffery
Tony Shimmin
Jenny Harboard
Don Glenister
Patricia Aylmore
David Cooling
Gavin dAdhemar
Neil Lantzke
John Ferguson (Manager) and staff
Staff
COLLABORATORS AND ACKNOWLEDGMENTS
Project Manager and Principal Investigator
Research Officer
Project Collaborating Scientist (Chemistry Centre of WA)
Project Technical Officer
Project Laboratory Technician (Chemistry Centre of WA)
Residue Development Manager (Alcoa of Australia)
Environmental Scientist (Alcoa of Australia)
Senior Consultant Residue (Alcoa of Australia)
Technical Officer Medina Research Centre (for technical assistance and management of field and pot experiments)
Horticultural Extension Officer (for extension advice)
Medina Research Centre (for management of field experiments)
Chemistry Centre of WA (for advice of on soil plant and leachate chemistry)
4
The use of Red Mudgypsum in vegetable production
3 PUBLICATIONS ARISING OUT OF WORK Robertson WJ McPharlin IR and Jeffery RC (1997) The growth nutrition and
composition of potatoes (Solarium tuberosum L) cv Delaware grown on a yellow Karrakatta sand amended with freshly-applied and residual Alkaloamreggypsum Australian Journal of Experimental Agriculture (submitted)
McPharlin IR dAdhemar G and Shimmin TR (1997) The response of cauliflowers (Brassica oleraceae L) cv Plana to freshly-applied and residual Alkaloamreggypsum and phosphorus on a Karrakatta sand Australian Journal of Experimental Agriculture (in prep)
McPharlin IR Shimmin TR and dAdhemar G (1997) Leaching of P N and cations from carrots grown on Joel sands amended with residual Alkaloamreggypsum Communications in Soil Science and Plant Analysis (in prep)
The use of Red Mudgypsum in vegetable production
4 RESPONSE OF POTATOES TO FRESHLY-APPLIED AND RESIDUAL RED MUD (ALKALOAMreg)GYPSUM AND PHOSPHORUS ON A YELLOW KARRAKATTA SAND
Introduction
Previous work has shown that freshly-applied Alkaloamreggypsum (gypsum-amended red mud 10 ww) (AG) at 60 and 120 tha reduced the total yield of potatoes by 7 and 23 respectively compared with 01 AGha controls (Robertson et al 1994 Appendix 1 J) The reduction in marketable yield was almost identical to the reduction in total yield The exact cause of this reduction in yield could not be determined particularly the reduction at 120 tha It was unlikely to be a reduced availability of P Observations on commercial properties suggest that AG which has been in the soil for several seasons does not cause yield reductions in potatoes
Phosphorus was banded at planting in this experiment Subsequent work (Hegney and McPharlin unpublished data) showed that broadcasting P allowed a greater maximum yield of potatoes than banding P on Karrakatta sands of low P fertility
This experiment re-examines the response of potatoes to freshly-applied AG using broadcast P and also the effect of residual AG on growth of potatoes at unlimiting P
Materials and methods
Site characteristics
The experiment was conducted on a yellow Karrakatta sand (described by McArthur and Bettenay 1960) at Medina approximately 30 km south of Perth Two sites were used a site where pasture species had been grown several years earlier and to which no AG had ever been applied and a second (adjacent) site where AG had been applied approximately 2J2 years earlier A lettuce and a cauliflower crop had been grown previously on this site after AG amendment (Robertson et al 1994 Appendix 1H I)
Red Mud (Alkaloamreg)gypsum (AG)
Red Mud (Alkaloamreg)gypsum (10 ww) (AG) was produced by the dry mix process by ALCOA of Australia Ltd at their Kwinana Residue Treatment Plant It was spread manually on the previously unamended site on 22 December 1994 and was incorporated to a depth of approximately 30 cm using a rotary hoe The AG on the previously-amended site (residual AG) was applied using the same techniques on 24 November 1992 The freshly-applied AG was watered for 1 hour three times a week until planting
Experimental design
The freshly-applied and residual AG sites were used for separate experiments which were conducted simultaneously The experiment on the freshly-applied AG was a split-plot randomised complete block design with three replicates Main plots were levels of AG (0 60 90 and 120 tha) and sub-plots were levels of P application (0 25 50 100 300 and 600 kgha) Main plots measured 48 x 21 m and sub-plots measured 24 x 7 m (three rows of potatoes with 08 m between row centres) There was a 2 m buffer around each main plot The experiment on the residual AG site was a randomised complete block design with 4 levels of AG (0 60 120 and 240 tha) and three replicates The levels of AG were applied in November 1992 and had had several levels of P applied to them in the previous crops The AG plots measured 6 x 12 m but only an area of 34 x 8 m (4 rows of potatoes with 08 m between row centres) was cropped to allow a buffer of 1 to 2 m all around the planted area
6
The use of Red Mudgypsum in vegetable production
Crop management Both sites were initially sprayed with Roundupreg (3 Lha) to kill weeds and the sites were hoed with a rotary hoe Freshly-applied AG was applied at this stage The residual AG site was treated with metham sodium approximately two weeks before planting Potatoes cv Delaware were planted on both sites on 18 May 1995 using a single row mechanical planter Round seed was used and this was dusted with Rizolexreg (2 kgt) immediately before planting Sets were planted 15 cm apart The crops were irrigated using impact sprinklers once daily at 80 of Class A pan evaporation between planting and emergence and then at 100 of evaporation Afalonreg (15 kgha) was applied after planting and Sprayseedreg (2 Lha) was applied at 5 emergence both for weed control Nitofol (700 rnLha) was used for regular insect control Bravoreg (2 Lha) was applied every seven days from the time of 50 ground cover until blight symptoms appeared at which time it was then alternated with Rovralreg (2 Lha) at 7 day intervals Both crops were harvested on 15 November 1995
Fertilisers
Pre-planting fertilisers were broadcast by hand on 15 May 1995 on freshly-applied AG and on 16 May on residual AG These were 83 kg Kha as K2S04 10 kg Mgha as miso47H20 and a complete trace element mix containing (kgha) MnS04H20 (504) MgS047H20 (560) borax (336) FeS047H20 (336) CuS045H20 (336) ZnS04H20 (280) and Na2Mo042H20 (224) Single superphosphate (91 P) was broadcast by hand at 0 to 600 kg Pha on freshly-applied AG according to the treatment and at 600 kg Pha on all plots on residual AG Post-planting fertilisers were a total of 500 kg Nha as NH4NO2 and KN02 and 400 kg Kha as KN02 in equal amounts for 10 weeks via the irrigation system An extra 50 kgha MgS04 was applied in weeks 7 and 9
Measurements
(a) Plant
The petioles of the Youngest Mature Leaf (YML) often plants were collected at the S2 stage (longest tuber 10 mm long) (19 July 1995) on both freshly-applied and residual AG They were dried in a forced draught oven at 70degC and then analysed for P N K Na Ca Mg S B Cu Fe Mn and Zn On freshly-applied AG tubers were harvested from a 5 m length of the middle row of each plot On residual AG a 4 m length of the two middle rows of each plot was harvested Tubers were separated into the following size grades lt 30 g 30-80 g 80-250 g 250-450 g and gt 450 g Tubers between 30 g and 450 g were considered marketable except if they were green or damaged
Of the tubers in the 80-250 g category ten were sampled from each plot for P analysis They were washed in tap water and sliced thinly with a stainless steel knife Fresh and dry weights were measured before the tubers were analysed for total P
(b) Soil
All 0 kg Pha plots on freshly-applied AG were sampled to 15 cm depth (15 cores per plot) on 29 August (approximately 3 months after planting) They were analysed for Bicarbonate-extractable P (Bic-P) (Colwell 1963) total P EC pH (H20) pH (CaCl2) Phosphorus Retention Index (PRI) (Allen and Jeffery 1990) and P buffering capacity (Ozanne and Shaw 1968) Before fertilisers were applied to the residual AG site on 16 May 15 cores (0-15 cm) were sampled from each plot and analysed for Bic-P and PRI Residual AG plots were sampled again on 29 August (0-15 cm 15 cores per plot) and analysed for pH (H20) pH (CaCl2) EC and P buffering capacity All residual AG plots and 0 100 and 600 kg Pha freshly-applied AG plots were sampled to three depths (0-15 15-30 and 30-45 cm) (20 cores per plot) on 5 December (ie after harvest)
7
The use of Red Mudgypsum in vegetable production
Chemical analysis
Plant samples were ground to pass through a 1 mm screen after drying Concentrations of P N K and Na were measured by digesting the samples with sulphuric acid and hydrogen peroxide (Yuen and Pollard 1954) N and P were determined colorimetrically by indophenol blue and molybdo-vanadate methods respectively K and Na were determined by flame photometry All analysis was conducted on a 4-channel Auto-analyser system using modifications of Technicon procedures (Anon 1977) Samples for analysis of Ca Mg S Cu Fe B Mn and Zn concentrations were digested with nitricperchloric acids (McQuaker et al 1979) Concentrations were measured by inductively-coupled plasma atomic emission spectrometry (ICP-AES) Concentrations of heavy metals were determined using inductively-coupled plasma mass spectrometry (ICP-MS) with indium as an internal standard Samples were initially crushed in an agate mortar and digested using nitric and perchloric acids
All soil samples were dried at 40degC in a forced draught oven Lumps of AG and fertiliser in samples were crushed and the samples were thoroughly mixed and sieved to lt 2 mm before analysis The pH (H20) and the EC were determined on a 15 soilwater extract after shaking for 1 hour The pH (CaCl2) was determined on 15 soiksolution extract using 001 M CaCl2 after shaking for 1 hour Values for both are corrected to 25 degC Total P was determined on a Kjeldahl digest of a separate sub-sample of soil ground to less than 015 mm The concentration of phosphate was measured by the method of Murphy and Riley (1962)
Statistical analysis
All data were analysed by an Analysis of Variance (ANOVA) using Genstat v 50 Results from the two experiments were analysed separately Data from the freshly-applied AG site was analysed by a two-way ANOVA on level of Alkaloamreg and level of applied P while data from residual Alkaloamreg were analysed by a one-way ANOVA on level of AG Statistical differences were determined using a Least Significant Difference at 5 level of significance where the F value from the ANOVA was significant Mitscherlich curves were fitted to all relationships between level of applied P and yield petiole or tuber P concentration or total P uptake Maximum values of Mitscherlich equations were compared using a 5 t-test Linear relationships were fitted to the yield response on residual Alkaloam versus level of AG and also to the relationship between yield and petiole P concentration on freshly-applied AG
The amount of fertiliser P retained was calculated by subtracting total P at 0 kg Pha from the measured total P value Concentrations of P in ugg were converted to kilograms per hectare by multiplying by a factor of 225 This is based on the assumption that there are 2250 t soilha in the top 15 cm of soil
Results and discussion
Soil characteristics
The pH (H20) of the top 15 cm of soil at mid-growth when no P fertiliser was applied increased from 72 on unamended soil to 84 and 85 on amended soil (Table 41) EC also increased from 5 mSm on unamended soil to 8 and 9 mSm on amended soil (Table 41) Bic-P was approximately 10 ugg at all AG levels and total P ranged from 55 ugg on unamended soil to 76 ugg at 901 AGha (Table 41) PRI and P buffering capacity (Pbug) both increased between unamended and amended soil but there were no differences between levels of AG on amended soil PRI of amended soil was 26 to 30 and Pbuff was 24 to 30 (Table 41)
The Bic-P and PRI measurements taken two days before planting on residual AG were the same at all levels of AG Bic-P was 16 to 21 ugg and PRI was 37 to 53 (Table 42) On the other hand Pbuff measured mid-growth increased from 20 at 01 AGha to 30 and 40 at 120 and 2401 AGha The EC was 7-9 mSm on all treatments and pH (H20) increased between 0 and 120 t AGha from 73 to 84 (Table 42)
The use of Red Mudgypsum in vegetable production
Table 41 Characteristics of the top 15 cm of a Karrakatta sand amended with several levels of freshly-applied Alkaloamreggypsum (AG) when no fertiliser P was applied
AG (tha)
pH (H20)
pH (CaCl2)
EC (mSm)
Bic-P (ugg)
Total P (ugg)
PRI Pbuff
0 72 64 5 8 55 19 14
60 84 77 8 10 64 26 24
90 85 78 9 11 76 30 30
120 85 83 9 10 71 27 27
Signif NS NS $
Lsd 5 04 05 3 07 05
Table 42 Characteristics of the top 15 cm of a Karrakatta sand amended with several levels of residual Alkaloamreggypsum (AG) when 600 kg Pha was applied as superphosphate
AG (tha)
pH (H20)
pH (CaCl2)
EC (mSm)
Bic-Pa
(ugg) PRIa
Pbuff
0 73 67 7 16 37 20
60 78 71 5 17 40 23
120 84 77 9 20 44 30
240 88 80 9 21 53 40
Signif NS NS NS
Lsd 5 05 06 10
K Sampled and measured before application of fertiliser P
Total phosphorus in soil
Total P in the soil at harvest on freshly-applied AG increased significantly with level of AG averaged over all three depths sampled (P lt 005) It also increased with level of applied P on all levels of AG At 0-15 cm total P increased significantly between 0 and 601 AGha At 15-30 cm it increased significantly between 0 and 90 t AGha and at 30-45 cm there was no effect of level of AG at all (Fig 41) At all levels of AG and P which were sampled total P concentrations at 0-15 cm and 15-30 cm were not significantly different from each other and both were significantly greater than those at 30-45 cm (Fig 41)
In the top 15 cm of soil total P increased from 47 ugg on unamended soil to 62-67 ugg on amended soil when no fertiliser P was applied This increase represents the total P content of the AG itself When 100 kg Pha was applied total soil P (0-15 cm) increased from 63 ugg at 01 AGha to 83 ugg at 601 AGha and 95 and 103 ugg at 90 and 1201 AGha (Fig 41) When the increase due to the AG itself is considered this is an increase in fertiliser P retention of 6 ugg (26 kgha) between 0 and 601 AGha and a further 14 ugg (62 kgha) between 60 and 120 t AGha At 600 kg Pha the increase in fertiliser P retention was 35 ugg (15 kgha) between 0 and 601 AGha and 25 ugg (11 kgha) between 60 and 120 t AGha
Total P on residual AG increased with level of AG The increase was significant between 60 and 1201 AGha only It also decreased at increasing depth As observed on freshly-applied AG total P concentrations at 0-15 cm and 15-30 cm were not significantly different from each other and were both greater than that observed at 30-45 cm (Fig 43) At 0-15 cm total P increased by 20 ugg between 0 and 601 AGha and by a further 213 ugg between 60 and 1201 AGha when 600 kg Pha was applied These values cannot be corrected for the total content of AG itself as there was no 0 kg Pha treatment
9
The use of Red Mudgypsum in vegetable production
The addition of freshly-applied AG to the soil substantially increased the theoretical ability of the soil to sorb applied P as measured by the P buffering capacity in the top 15 cm of soil However it was reduced over time as 1201 AGha was required to increase Pbuff on residual AG compared with 601 AGha on freshly-applied AG Fertiliser P retention in the top 15 cm of soil when amended with 1201 AGha was increased by 9 at 100 kg Pha and by 4 at 600 kg Pha
The effects of residual and freshly-applied AG can be compared at 600 kgha of applied P The effect of residual AG on fertiliser P retention can be estimated from measurements made on the same site at the beginning of the first (lettuce) crop In that experiment total P before the application of P fertilisers increased from 69 and 62 ugg on 0 and 601 AGha to 91 ugg on 1201 AGha and 103 ugg on 2401 AGha (Robertson et al 1994 Appendix 1H) This makes the estimated increase in fertiliser P retention (0-15 cm) 27 ugg (12 kgha) between 0 and 601 AGha and 184 ugg (81 kgha) between 60 and 1201 AGha Therefore between 60 and 1201 AGha residual AG increased fertiliser retention by approximately 7 times as much as did freshly-applied AG
Bicarbonate-extractable P (soil-test P) in soil
On freshly-applied AG there was no overall response of Bic-P to level of AG although there was an upward trend Bic-P decreased with increasing depth averaged over all treatments following the same response as total P There was an interaction between the effects of depth and level of applied P At 0 kg Pha there was no difference in Bic-P between the three depths sampled but at 100 and 600 kg Pha Bic-P concentrations at 0-15 cm and 15-30 cm were both greater than those at 30-45 cm (Fig 42) The upward trend in Bic-P with increasing level of AG was weak on soil where no P fertiliser had been applied being from 9-10 ugg at 0 and 601 AGha to 11 and 14 ugg at 90 and 1201 AGha in the top 15 cm This suggests that the AG adds little if any plant available P to the soil The amount of fertiliser P retained as Bic-P in the top 15 cm of soil when 100 kg Pha was applied increased by 8 ugg between 0 and 601 AGha and by a further 4 ugg between 60 and 120 t AGha At 600 kg Pha Bic-P retained from fertiliser increased by 34 ugg between 0 and 601 AGha and by 16 ugg between 60 and 1201 AGha
The response of Bic-P to level of residual AG and to depth was the same as for total P (Fig 43) In the top 15 cm of soil Bic-P increased by 11 ugg between 0 and 601 AGha and by 82 ugg between 60 and 1201 AGha uncorrected for the Bic-P content of the AG itself
The increase in Bic-P retention observed on amended soil at 100 kg Pha was similar to that observed at 160 kg Pha on a crop of carrots grown on a Joel sand amended with AG (Robertson et al 1997) Using the soil-test standards published by Hegney et al (1997) these increases in Bic-P will reduce the P fertiliser requirement in the following potato crop by 10 at 601 AGha and 22 at 1201 AGha
Using the Bic-P concentrations observed on the residual site at the beginning of the lettuce crop (Robertson et al 1994 Appendix 1H) the increase in fertiliser P retained as Bic-P (0-15 cm) on residual AG was 15 ugg between 0 and 601 AGha and 79 ugg between 60 and 1201 AGha This is half the increase observed on freshly-applied AG between 0 and 60 t AGha and approximately 5 times that observed on freshly-applied AG between 60 and 1201 AGha
The reduced P retention at low levels of residual AG compared with freshly-applied AG was probably because of the higher initial Bic-P levels on residual AG For both total and Bic-P it is difficult to explain why the apparent retention of fertiliser P between 60 and 120 t AGha should have been so much greater on residual than on freshly-applied AG It may have been caused by changes to the chemical properties of the AG as it aged in the ground
10
The use of Red Mudgypsum in vegetable production
Yield
Total and marketable yields on freshly-applied AG both increased with level of applied P following a Mitscherlich response (Fig 44 (a) (b)) An ANOVA did not indicate any response to level of AG in either total or marketable yields However maximum total yield on unamended soil (61 tha) was significantly greater than that on AG-amended soil - 54 to 57 tha (Fig 44 (a)) On the other hand there were no differences in maximum marketable yields Maximum marketable yield values ranged from 52 to 55 tha (Fig 44 (b)) When marketable yield was calculated as a percentage of total yield an ANOVA indicated a significant interaction between level of AG and level of applied P At 400 kg Pha marketable yield was 88 of total yield on unamended soil compared with approximately 95 on amended soil (significant according to 5 Lsd) A similar trend was observed at 600 kg Pha where marketable yield was 90 of total yield on unamended soil and 93 to 96 on amended soil
The levels of applied P required for 99 of maximum total yield were 245 222 183 and 400 kg Pha on 0 60 90 and 1201 AGha and for 95 of maximum yield were 139 130 108 and 226 kg Pha (Fig 44 (a)) A similar trend can be seen for marketable yield where 99 of maximum yield required 178 206 208 and 356 kg Pha (Fig 44 (b))
Total yield on residual AG showed an almost significant response to level of AG (P = 0067) (Fig 45) Total yield was 68 to 72 tha on 0 60 and 120 t AGha and 62 tha on 2401 AGha Marketable yield was 65 to 68 tha on 0 to 1201 AGha and 58 tha on 2401 AGha Therefore 2401 AGha appears to reduce yields even when it has been in the ground for 2 years or more and even when 600 kg Pha is applied As only one level of P fertiliser was applied it is not possible to determine the effect of residual AG on the critical levels of P application required for 99 and 95 of maximum yield
Concentration of nutrients in petioles
Phosphorus
Phosphorus concentration in petioles of the YML sampled at the S2 stage on freshly-applied AG increased with level of applied P following a Mitscherlich response (Fig 46) Maximum petiole P concentrations were approximately 12 (dry basis) on all AG levels Values at 99 of maximum petiole P concentration were 116 122 117 and 116 at 0 60 90 and 1201 AGha There was a significant interaction between levels of AG and applied P (P lt 005) At low levels of applied P (25 50 and 100 kgha) P concentrations on amended soil were significantly less than those on unamended soil but there was no difference between them at 300 or 600 kg Pha This is reflected in the levels of applied P required for 99 of maximum petiole P concentration which were 209 499 581 and 508 kg Pha at 0 60 90 and 1201 AGha This is an increase of 138 on amended soil relative to unamended soil AG at levels of between 60 and 120 tha therefore reduces the availability of P to plants As there was no difference in the maximum P concentration in petioles between amended and unamended soil a reduction in P availability to plants cannot explain the reduced maximum yield on amended soil Another factor was therefore involved in reducing maximum yield on amended soil Despite this yield difference between amended and unamended soil which was not related to differences in P concentration total yield for all AG levels combined was linearly correlated with petiole P concentration at the S2 stage (y = 256 + 274x R2 = 087) (Fig 47)
The petiole P concentration at 99 of maximum total yield was 116 109 095 and 114o at 0 60 90 and 1201 AGha At 01 AGha this was the same as 99 of maximum petiole P concentration implying that the yield response on unamended soil was controlled principally by P availability On the other hand petiole P concentrations at 99 of maximum yield on amended soil especially 60 and 901 AGha were less than 99 of maximum petiole P concentration In other words yield stopped increasing even though P concentration in the plant kept increasing This supports the previous observation that some factor other than P was limiting yield in these treatments Petiole P concentration in YMLs sampled at S2 stage on residual AG did not change with level of AG Overall mean P concentration was 12 dry
11
The use of Red Mudgypsum in vegetable production
basis This is in keeping with the results observed on freshly-applied AG at 600 kg Pha It also means that the lower yield at 2401 AGha on residual AG could not be explained by a reduced P concentration in the plant As on freshly-applied AG another factor was involved which reduced yield on amended soil although at a higher level on residual than on freshly-applied AG
Hegney et al (1997) found that maximum petiole P concentration at S2 in potatoes grown on Karrakatta sand was 114 dry basis and that 109 was required for 99 of maximum yield in good agreement with the results observed here
Other nutrients
The responses of nutrients other than P were very similar on both freshly-applied and residual AG Concentrations of K (Tables 43 45) and Zn (Fig 48 (a) Table 45) decreased as level of AG increased and concentrations of Mg Fe and Ca increased with level of AG in both experiments (Tables 43 45 Fig 48 (b)) Zn concentrations also decreased with increasing level of applied P (Fig 49 (a)) while Ca concentrations increased with level of applied P (Fig 48 (b)) Concentrations of Na also showed an upward trend on both freshly-applied and residual AG (Tables 43 45) On freshly-applied AG K concentrations decreased significantly from 119 dry basis on unamended soil to 110 at 601 AGha and to 102 at 1201 AGha (Table 43) On residual AG it decreased from 11-12 at 0-1201 AGha to 103 at 2401 AGha (Table 45) No other nutrients showed any response to level of AG although concentrations of N Mn S and B increased with level of applied P on freshly-applied AG (Table 44)
Concentrations of all nutrients except K were adequate or more than adequate for maximum yield (Maier et al 1987) on both freshly-applied and residual AG Potatoes require concentrations of approximately 12 to 14 K (dry basis) in petioles of YML for maximum yield (Maier et al 1987) On freshly-apphed AG concentrations were adequate at 01 AGha but were less than adequate on amended soil On residual AG concentrations were adequate at 0 60 and 1201 AGha but less than adequate at 2401 AGha As less than adequate K concentrations correspond with those treatments which had low yield it is likely that K concentration was the limiting factor in yield on both freshly-applied and residual AG
Uptake of K may have been reduced at higher levels of AG due to an increased Cation Exchange Capacity (Barrow 1982 McPharlin et al 1994) or to the increased soil pH (Harris 1992) The reduction in Zn availability on amended soil is most likely to be a result of the increase in soil pH due to the AG (Harter 1983)
Table 43 Concentrations of several nutrients in the petioles of the Youngest Mature Leaf of potato plants sampled at the 10 mm tuber stage at several levels of freshly-applied Alkaloamreggypsum (AG) on a yellow Karrakatta sand
AG K Na Mg Fe (tha) () () () (ngg)
0 119 018 059 382
60 110 020 065 553
90 106 021 066 597
120 102 021 069 697
Signif NS
Lsd 5 04 004 119
12
The use of Red Mudgypsum in vegetable production
Table 44 Concentrations of several nutrients in the petioles of the Youngest Mature Leaf of potato plants sampled at the 10 mm tuber stage at two levels of applied P when grown on a yellow Karrakatta sand amended with freshly-applied Alkaloamreggypsum (AG)
Applied P N S Cu Mn B (kgha) () () (ngg) (ngg) (M-gg)
0 44 028 74 293 267
600 48 032 62 342 248
Signif NS NS
Table 45 Concentrations of several nutrients in the petioles of the Youngest Mature Leaf of potato plants sampled at the 10 mm tuber stage at several levels of residual Alkaloamreggypsum (AG) on a yellow Karrakatta sand
AG N K Na Ca S Mg Cu Fe Mn Zn B (tha) () () () () () () (l-igg) (ngg) (ngg) Ws) (^gg)
0 51 116 016 23 030 050 77 453 46 96 26
60 48 127 015 21 027 045 61 457 45 67 25
120 49 120 016 26 029 051 66 643 59 59 25
240 49 103 019 29 030 067 54 977 53 53 24
Signif NS NS NS NS NS NS
Lsd5 05 04 013 164 24
Tuber P and Crop P removal P concentration in tubers
The concentration of P in tubers on freshly-applied Alkaloamreg increased with level of applied P (P lt 0001) The response at each level of Alkaloamreg was best described by a Mitscherlich curve although none of the curves reached a maximum within the range of fertiliser P levels used (Fig 49 (a)) There was a trend for an overall response to level of AG (P = 0081) P concentrations were generally higher on unamended soil than on amended soil For example at 300 kg Pha P concentration was 033 on unamended soil and 026-028 on amended soil and at 600 kg Pha P concentrations were 036 and 032-033 on unamended and amended soil respectively At P levels corresponding to 99 of maximum yield tuber P concentration was 031 024 023 and 028 at 0 60 90 and 1201 AGha
On residual AG tuber P concentration did not change with level of AG The overall mean was 036 dry basis
Total P uptake
Total P uptake by tubers on freshly-applied AG showed a significant response to level of AG (P lt 005) and level of applied P (P lt 0001) The response to applied P at each level of AG was best described by a Mitscherlich curve although as for tuber P concentration none of the curves reached a maximum within the range of P levels applied P uptake by tubers on unamended soil was significantly greater than on amended soil regardless of AG level (Lsd 5) (Fig 49 (b)) At levels of applied P corresponding to 99 of maximum yield P uptake by tubers was 113 75 75 and 95 kgha at 0 60 90 and 1201 AGha These figures are lower than results reported by Hegney et al (1997) who found a P uptake by tubers grown on yellow Karrakatta sand of 204 kgha at 99 of maximum yield even though yields were similar to those observed on unamended soil in this experiment
13
The use of Red Mudgypsum in vegetable production
Total P uptake by tubers was not significantly different between AG levels on residual AG Overall mean P uptake was 110 kgha This is different from the situation observed at 600 kg Pha on freshly-applied AG As only one level of P was applied the response curve for tuber P concentration on residual AG cannot be compared with that on freshly-applied AG It is possible that less applied P is required on residual than on freshly-applied AG to reach maximum tuber P concentration
Metals in tubers
The concentration of As in tubers harvested from freshly-applied AG showed a trend to increase with level of AG from 5 x 104 mgkg (fresh weight) on unamended soil to 8 x 104 mgkg at 60 and 901 AGha (Fig 410) Concentrations of all other metals measured showed no response to level of AG either on residual or freshly-applied AG (Table 46 47) On freshly-applied AG concentrations of Ni and Cd increased and concentrations of Cu decreased with increasing level of applied P (Table 48)
Table 46 Mean concentrations (mgkg fresh weight) of metals in tubers of potato cv Delaware harvested from a yellow Karrakatta sand amended with freshly-applied Alkaloam^gypsum (AG)
Cr Co Sn Sb Hg
mean
se
0007
61 xlO5
60 x 104
50 x 106
15 x 103
10 x 104
90 x 105
10 xlO5
34 x 104
14 x 105
Table 47 Mean concentrations (mgkg fresh weight) of metals in tubers of potato cv Delaware harvested from a yellow Karrakatta sand amended with residual Alkaloamreggypsum (AG)
Cr Co Ni Cu As Cd Sn Sb Hg Pb
mean
se
001
68X104
72xl(f 29xia5
55xia3
17x1a4
010
35xia3
L2X103
0
58xia3
17X104
LOxlO3
29X104
30X1O4
43xl05
84X1G4
ii xia5
l ixia3
70xia5
Table 48 Mean concentrations (mgkg fresh weight) of metals in tubers of potato cv Delaware harvested from a yellow Karrakatta sand amended with freshly-applied Alkaloamreggypsum (AG) at various levels of applied P
Applied P (kgha)
Ni Cd Cu
0 0006 0002 018
100 0006 0002 016
300 0007 0004 015
600 0008 0006 013
Signif
Lsd (5) 00014 0001 002
The concentrations of As observed in tubers from freshly-applied AG regardless of the level of AG were less than 10 of the legal limit (10 mgkg fresh weight NFA 1992) The concentrations of all metals measured were between 3 and 33 of those measured in potato tubers in a previous experiment (Robertson et al 1994 Appendix 1 J) The concentrations on residual AG were also lower than the concentrations previously observed in lettuce and cauliflowers on the same site (Robertson et al 1994 Appendix IH I) As different batches of
14
The use of Red Mudgypsum in vegetable production
AG were used on the two sites they cannot be compared to determine the effect of time on metal availability and uptake Overall metal uptake by potato tubers grown on AG-amended yellow Karrakatta sand does not appear to pose any greater health risk than that on unamended yellow Karrakatta sand The observed increase in As concentration in potato tubers on freshly-applied AG was probably due to the increase in soil pH with level of AG (ONeill 1990)
Conclusions
Freshly-applied AG reduces the availability of fertiliser P so that approximately 25 times the level of applied P is required on 60 to 1201 AGha relative to unamended soil in order to attain maximum P concentration in plant tissues AG at 120 tha also increases the retention of fertiliser P sufficiently to reduce fertiliser requirements for a following potato crop by approximately 20 The effect of AG on the level of fertiliser P required for 99 of maximum yield was confounded in this experiment by the decrease in maximum yield between unamended and amended soil Total yield of potatoes will be reduced on 60 tha freshly-applied AG and by 240 tha residual AG probably by a limiting concentration of K There is potential for increased levels of K fertiliser to overcome this yield reduction AG increases the proportion of yield which is marketable so that even though total yield is reduced by 60 tha of freshly-applied AG the marketable yield is not There are no apparent problems with heavy metal contents of tubers due to amendment with AG
References Allen DG and Jeffery RC (1990) Methods for analysis of phosphorus in Western
Australian soils Chemistry Centre of WA Report of Investigation No 37
Anonymous (1977) Technicon Industrial Method 334-74WB+ Technicon Industrial Systems Tarrytown NY USA
Barrow NJ (1982) Possibility of using caustic residue from bauxite for improving the chemical and physical properties of sandy soils Australian Journal of Agricultural Research 275-285
Colwell JD (1963) The estimation of phosphorus fertiliser requirements of wheat in southern New South Wales by soil analysis Australian Journal of Experimental Agriculture and Animal Husbandry 3 190-197
Glenister DJ and Thoraber MR (1985) Alkalinity of red mud and its application for the management of acid wastes Chemeca 85 109-113
Harris PM (1992) Mineral Nutrition In The Potato Crop The scientific basis for improvement 2nd edition (ed P Harris) pp 162-213 (Chapman and Hall London UK)
Harter RD (1983) Effect of soil pH on adsorption of lead copper zinc and nickel Soil Science Society of America Journal 47 47-51
Hegney MA McPharlin IR and Jeffery RC (1997) Response of winter-grown potatoes (Solanum tuberosum L) to applied and residual phosphorus on a Karrakatta sand Australian Journal of Experimental Agriculture 37 (in press)
Maier NA Williams CMJ Potocky-Pacay K Moss D and Lomman GJ (1987) Interpretation standards for assessing the nutrient status of irrigated potato crops in South Australia Technote AGDEX 262533 September 1987 Department of Agriculture South Australia
15
The use of Red Mudgypsum in vegetable production
McArthur WM and Bettenay E (1960) The development and distribution of the soils of the Swan Coastal Plain Western Australia CSIRO Division of Soils Soils Publication No 16
McPharlin IR Jeffery RC Toussaint LF and Cooper M (1994) Phosphorus nitrogen and radionuclide retention and leaching from a Joel sand amended with red mudgypsum Communications in Soil Science and Plant Analysis 25 489-500
McQuaker NR Brown DF and Kluckner PD (1979) Digestion of environmental materials for analysis by inductively coupled plasma atomic emission spectrometry Analytica Chimica 51 1082-1084
Murphy J and Riley JP (1962) A modified single solution method for the determination of phosphate in natural waters Analytica Chimica Acta 27 31-36
NFA (National Food Authority) (1992) Australian Food Standards Code June 1992 (Australian Government Publishing Service Canberra)
ONeill P (1990) Arsenic In Heavy Metals in Soils(ed BJ Alloway) pp 83-99 (Blackie Glasgow)
Ozanne PG and Shaw TC (1967) Phosphate sorption by soils as a measure of the phosphate requirement for pasture growth Australian Journal of Agricultural Research 18 601-612
Robertson WJ McPharlin IR and Jeffery RC (1994) Final Report of investigation into the use of gypsum-amended red mud as a soil-amendment on horticultural properties on the Swan Coastal Plain Agriculture WA
Robertson WJ McPharlin IR and Jeffery RC (1997) Residues from bauxite-mining (red mud) increase phosphorus retention of a Joel sand without reducing yield of carrots Communications in Soil Science and Plant Analysis (in press)
Yuen SH and Pollard AG (1954) Determination of nitrogen in agricultural materials by the Nessler reagent II Micro-determination in plant tissue and in soil extracts Journal of Food in Agriculture 5 364-369
16
The use of Red Mudgypsum in vegetable production
300
250 -
I I
200
3
60 80
AG (tha)
140
Figure 41 Total phosphorus concentration in a yellow Karrakatta sand amended with freshly-applied Alkaloamreggypsum (AG) vs level of AG when 0 (bull) 100 (A) and 600 (bull) kg Pha was applied measured at 0-15 cm () 15-30 cm (mdash) and 30-45 cm (mdash) depth Bars are Lsds at 5 level of significance
17
The use of Red Mudgypsum in vegetable production
Z3
200
180 -
160
Q- 140
ro 120 bull 4 -
O CD X 100 CD i
3 80 CO c o
pound gt v_ CO
o CQ
AG Depth
I
0 20 40 60 80 100 120
AG (tha)
140
Figure 42 Bicarbonate-extractable phosphorus concentration in a yellow Karrakatta sand amended with freshly-applied Alkaloamreggypsum (AG) vs level of AG when 0 (bull) 100 (A) and 600 (bull) kg Pha was applied measured at 0-15 cm () 15-30 cm (mdash) and 30-45 cm (mdash) depth Bars are Lsds at 5 level of significance
18
The use of Red Mudgypsum in vegetable production
700
600
500
D)
3 400
CL
oil
300 CO
200
100
100 150
A G (tha)
250
Figure 43 Total (mdash) and Bicarbonate-extractable phosphorus () concentration in a yellow Karrakatta sand amended with residual Alkaloamreggypsum (AG) when 600 kg Pha was applied measured at 0-15 cm () 15-30 cm (A) and 30-45 cm (bull) depth Bars are Lsds at 5 level of significance
19
The use of Red Mudgypsum in vegetable production
CO
2 CD
gt-
200 300 400
Applied P (kgha)
Figure 44 (a) Total yield of potatoes cv Delaware grown on a yellow Karrakatta sand amended with freshly-applied AIkaIoamreggypsum (AG) at a level of 0 (bull) 60 (A) 90 (bull) and 120 (bull) tha vs level of applied P Lines represent the level of applied P required for 99 of maximum yield Bars are Lsds at 5 level of significance
Equations are
A
B
C
D
0 tha
60 tha
90 tha
120 tha
j - 614 - 255 x exp (-00152) (JR= 092)
y = 542 - 271 x exp (-00176) (R2= 090)
y = 552 - 274 x exp (-0021) (F= 094)
y = 566 - 229 x exp (-00092) (i^= 098)
20
The use of Red Mudgypsum in vegetable production
ro
JO
gt-
100 200 300 400
Applied P (kgha)
500 600
Figure 44 (b) Total yield of potatoes cv Delaware grown on a yellow Karrakatta sand amended with freshly-applied Alkaloamreggypsum (AG) at a level of 0 (bull) 60 (A) 90 (bull) and 120 (bull) tha vs level of applied P Lines represent the level of applied P required for 99 of maximum yield Bars are Lsds at 5 level of significance
Equations are
Otha A
B
C
D
60 tha
90 tha
120 tha
y = 547 - 216 x exp (-0021) (R2^ 088)
y = 517 - 278 x exp (-0019) (R2= 090)
y = 524 - 243 x exp (-001 to) (R2= 094)
y = 530 - 218 x exp (-001 Ox) (i^= 098)
21
The use of Red Mudgypsum in vegetable production
CO
32
gt-
80
70
60
50
40
30
20
10
0 0
Marketable yield
Marketable yield
Total yield
Total yield
_L 50 100 150 200
AG (tha)
250 300
Figure 45 Total (bull) and Marketable (bull) yield of potatoes cv Delaware grown on a yellow Karrakatta sand amended with residual AIkaloamreggypsum (AG) vs level of AG 600 kg Pha was applied Bars are Lsds at 5 level of significance
22
The use of Red Mudgypsum in vegetable production
w CO CO
a gtraquo i _
C
o 00
c CD O c o o
100 200 300 400
Applied P (kgha)
500
Figure 46 Concentration (dry basis) of phosphorus in petioles of the Youngest Mature Leaf of potatoes cv Delaware grown on a yellow Karrakatta sand amended with freshly-applied Alkaloamreggypsum (AG) at 0 (bull) 60 (A) 90 (bull) and 120 (bull) tha vs level of applied P Lines represent the level of applied P required for 99 of maximum yield Bars are Lsds at 5 level of significance
Equations are
A Otha y = 117- 079 x exp (-0020) (R2 = 096)
B 60 tha y=123- 096 x exp (-000874) (R2 - 099)
C 90 tha y = 118 - 0884 x exp (-000742) (R2 = 096)
D 120 tha y= 117 - 090 x exp (-00085) (R2 = 097)
23
The use of Red Mudgypsum in vegetable production
CO
c
53
CD
gt-
00 02 04 06 08 10
Petiole P ( dry basis)
12 14
Figure 47 Yield of potatoes cv Delaware grown on a yellow Karrakatta sand amended with freshly-applied AlkaIoamreggypsum (AG) at 0 (bull) 60 (A) 90 (bull) and 120 (bull) tha vs petiole P concentration
The equation is y = 256 + 274x (ft2 = 087)
24
The use of Red Mudgypsum in vegetable production
poundgt 3
0 100 200 300 400 500 600 700
Applied P (kgha)
Figure 48 (a) Concentration of Zinc and (B) Calcium ( dry weight) in petioles of the youngest mature leaf of potatoes cv Delaware harvested from a yellow Karrakatta sand amended with freshly-applied Alkaloamreggypsum (AG) at 0 (bull) 60 (A) 90 (bull) and 120 (bull) tha vs level of applied P Bars are Lsds at 5 level of significance
25
The use of Red Mudgypsum in vegetable production
100 200 300 400 500
Applied P (kgha)
700
Figure 48 (b) Concentration of Calcium ( dry weight) in petioles of the youngest mature leaf of potatoes cv Delaware harvested from a yellow Karrakatta sand amended with freshly-applied AlkaIoamreggypsum (AG) at 0 (bull) 60 (A) 90 (bull) and 120 (bull) tha vs level of applied P Bars are Lsds at 5 level of significance
The use of Red Mudgypsum in vegetable production
040
ogt 035 CD
gtgt bullo
w _CB O
H) CL
CO 1 _ -mdashraquo c CD O c o o Q
030 -
025 -
020
2 015
010 -
005
000 0 100 200 300 400
Applied P (kgha)
500 600
Figure 49 (a) The concentration of phosphorus in tubers ( dry weight) of potatoes cv Delaware harvested from a yellow Karrakatta sand amended with freshly-applied Alkaloamreggypsum (AG) at 0 (bull) 60 (A) 90 (bull) and 120 (bull) tha vs level of applied Pkgha Bars are Lsds at 5 level of significance
Equations are
A 0 tha
B 60 tha
C 90 tha
D 120 tha
y = 0372 - 0243 x exp (-00058) (R2 = 097)
y = 0378 - 0257 x exp (-00029x) (R2 = 098)
y = 0361 - 0216 x exp (-00029x) (i^= 095)
y = 0406 - 0279 x exp (-0002x) (R2 = 098)
27
The use of Red Mudgypsum in vegetable production
CO
3
ltD
CO Q Z5
ID
B
14
12 -^ ^
10
8 W
6
4
A G P
I
2
n I i i I I i
0 100 200 300 400
Applied P (kgha)
500 600
Figure 49 (b) Phosphorus uptake Gigha) by tubers of potatoes cv Delaware harvested from a yellow Karrakatta sand amended with freshly-applied Alkaloamreggypsum (AG) at 0 (bull) 60 (A) 90 (bull) and 120 (bull) tha vs level of applied P Bars are Lsds at 5 level of significance
Equations are
Otha A
B
C
D
60 tha
90 tha
120 tha
y = 140 - 1095 x exp (-00058r) (R2 = 096)
3= 111 - 882 x exp (-0004x) (R2 = 098)
y = 104 - 774 x exp (-00053) (R2 = 099)
3 = 127 -101 x exp (-00029x) (R2 = 0997)
28
The use of Red Mudgypsum in vegetable production
60 80
AG (tha)
Figure 410 Concentration of Arsenic (dry weight) in tubers of potatoes cv Delaware grown on a yellow Karrakatta sand amended with freshly-applied Alkaloamreggypsum (AG) Bar is Lsd at 5 level of significance
29
The use of Red Mudgypsum in vegetable production
5 RESPONSE OF CAULIFLOWERS TO FRESHLY-APPLIED RED MUD (ALKALOAMreg)GYPSUM AND PHOSPHORUS ON A YELLOW KARRAKATTA SAND
Introduction
It is important to reduce the leaching of phosphorus fertiliser from sandy soils used for vegetable production into the water systems of the Swan Coastal Plain Red Mud (AlkaloamR)gypsum (AG) a waste product from bauxite refining has been suggested as an amendment to reduce phosphorus leaching from sands of the Bassendean Association (Joel Gavin) used for agriculture and horticulture (Barrow 1982)
Experimental work in the field and pots showed amendment with AG significantly reduced P leaching from Joel and Gavin sands (Vlahos et al 1989 McPharlin ei al 1994) compared with the unamended (01 AGha) treatment
In previous work freshly-applied AG at 60 tha increased the amount of freshly-applied P required for maximum yield of cauliflowers 14 (autumn planted) but did not reduce maximum yield (20 tha) compared with the unamended (0 tha) treatment on a yellow Karrakatta sand (Robertson et al 1994) At the highest rate of applied AG (120 tha) P required for maximum yield was 32 higher than at 0 tha and maximum yield was reduced 23 (P lt 005)
Since more than 60 tha of AG may be required to significantly improve P retention by sands to enable sustainable horticultural production this yield reduction is re-examined with freshly-applied AG
Materials and methods
Site characteristics
The experiment was conducted on a yellow Karrakatta sand (McArthur and Bettenay 1960) of low P fertility at Medina Research Centre (32deg 13 S 115deg 49 E) 30 km South of Perth The site had no previous history of AG application and had been sown to pasture for several years Some relevant chemical characteristics of the topsoil (0-15 cm) and subsoil (15-30 cm) of the site after application of AG but prior to the application of fertiliser and transplanting are presented in Table 51
Red Mud (AlkaIoamreg)gypsum (AG)
Alkaloamreg (Red Mud) amended with 10 (ww) gypsum (AG) was produced by the dry mix process by ALCOA of Australia Ltd at their Kwinana Residue Treatment Plant The AG was spread manually on the site and incorporated using a rotary hoe to approximately 30 cm depth on 21 February 1996 The site was watered for 1 hour per day (8 mmday) using impact sprinklers until planting
Experimental design
The experimental design was a split-plot randomised block with 3 replicates The main plots were levels of AG (0 60 120 and 240 tha) and the sub-plots were levels of freshly-applied P (0 50 100 200 400 and 600 kgha) Main plots measured 6 x 12 m and sub-plots 12 x 6 m (excluding wheel tracks)
Crop management
The site was sprayed with Roundupreg (3 Lha) twice after application of AG and prior to planting to control weeds
The use of Red Mudgypsum in vegetable production
Six week old seedlings of cauliflowers (cv Plana) obtained from a commercial nursery were transplanted manually on 18 April 1996 in 2 rows per plot with 70 cm between rows and 50 cm between plants Seedlings were dipped in Rovralreg 1 mLL just prior to planting for control of fungi Treflanreg (14 Lha) and Dacthalreg (12 kgha) were applied immediately after transplanting to control broadleaved weeds and Sertinreg later on in the life of the crop for grass control Ambushreg (100 mLha) and Rogorreg (100 mLha) were used to control caterpillars and red legged earth-mite respectively Copper sprays were used for control of blackrot The crop was irrigated to a total application equivalent to 100 of the previous days pan evaporation using minisprinklers (Legoreg 6 x 6 m spacing 44 mmh) in 3 waterings of equal duration per day
Fertilisers
Pre-planting fertilisers were broadcast manually and rotary hoed on 17 April 1996
These were K2S04(244) Ca (N03)2 4H20 (387) MgS047H20 (504) MnS04H20 (504) FeS047H20 (18) Borax (27) CuS045H20 (36) ZnSOH20 (28) and Na2Mo042H20 (2) Single superphosphate (91 P)was applied at 0 to 600 kgha according to treatment and incorporated as before Post-planting K N and Ca were fertigated via the irrigation system as KN03 NH4NO3 and Ca (N03)2 in equal amounts per day for 12 weeks to a total of 600 kg K 423 kg N and 60 kg Caha Borax was fertigated at 20 kgha in week 3 and Mg was broadcast as MgS047H20 at 50 kgha in weeks 3 6 and 9
Measurements
Soil and soil solution
All zero P subplots were sampled 30 cores per plot just prior to planting and fertilising about 2 months after AG application to 2 depths (0-15 15-30 cm) These were oven dried at 40degC and analysed for Ec pH (CaCl2) P sorption (Ozanne and Shaw 1968) bicarbonate extractable P K (Colwell 1963) total P PRI P sorption K sorption (Allen and Jeffery 1990) and cation exchange capacity (Gillman and Sumpter 1986)
The soil water was obtained by centrifugation from soil samples (0-15 cm 30 per plot) and collected from the 0 100 200 and 600 kg Pha plots across all AG treatments on 16 May 1996 The supernatant was analysed for pH Ec Ca Mg K S and P The remaining soil was analysed for pH (H20) bicarbonate extractable P and K PRI and DTPA extractable Zn After harvest on 5 August 1996 soil samples were collected from 2 depths as for the preplanting treatment from all plots These were analysed for pH bicarbonate extractable P K total P PRI and exchangeable cations (Ca Mg K and N)
Plant
At buttoning on 13 June 1996 the younger mature leaves (YML) (4th from growing point) were collected from 16 plants in each plot (excluding 1 m buffer at each end) They were dried at 70degC in a force draught oven for 48 h and ground to pass through a 1 mm screen Sub-samples were digested with sulphuric acidhydrogen peroxide (Yuen and Pollard 1954) and the concentration of N P and K measured by an automated colorimetric process (Varley 1966) Concentration of other nutrients (B Ca Na Mg S Fe Mn Zn and Cu) were determined by inductively coupled plasma atomic emission spectroscopy (ICP-AES) after digestion with nitric-perchloric acids (McQuaker et al 1979)
Five whole plants were harvested from the middle of each plot (2 per row)at the end of the experiment on 4 July 1996 using shovels to recover as much of the root system as possible The plants were separated into four categories curds leaves stems and roots All soil was washed from the roots using tap water shaken and the excess water removed using paper towels The fresh weight of all four categories was recorded and the material was diced into small pieces (lt 8 cm3) using stainless steel knives sub-samples (300 g fresh weight) were collected at random from the diced pieces and the fresh weight recorded These were dried at
31
The use of Red Mudgypsum in vegetable production
70degC in a forced draught oven for 48 h and the dry weight recorded These samples were then analysed for P as for the youngest mature leaves Separate sub-samples (300 g fresh weight) of curds were collected and analysed for Ba Cd Cr Co Pb Mo Rb Sr Ti Th V and N using inductively coupled plasma mass spectrometry (ICP-MS) The fresh and dry weight of the curds leaves stems and roots at harvest were used to calculate P uptake in kgha)
Harvest
Harvest commenced when the leaves surrounding the head opened and exposed the curds 77-80 days after transplanting At this stage florets at the periphery of the curd had just begun to separate Sixteen curds (12 plus 4 from whole plant samples above) were collected from the central 4 m of both rows (1 m buffer) and all the leaves and stems removed according to requirements for export market Each fresh curd was weighed and rejects recorded if undersize (lt 500 g) oversize (gt 2000 g) discoloured (yellowing) overmature (separation of florets in centre of curd) diseased damaged or otherwise distorted The total marketable and reject yield were recorded for each plot
Analysis of data
Analysis of variance was carried out on level of applied AG or P versus (a) chemical characteristics of soil (bicarbonate extractable P total P etc) preplanting and harvest (b) concentrations of nutrients in soil solution at midgrowth (c) concentration of nutrients in YMLs at midgrowth (d) concentration of elements in curds at harvest (e) P uptake by plant parts and (f) total marketable and reject yield of curds at harvest Mitscherlich curves and inverse polynomials were fitted to the relationship between level of applied P and yield at each level of applied AG The level of applied P required for 95 99 and 100 (in case of inverse polynomials) of maximum yield was calculated Mitscherlich curves were fitted to the relationship between level of applied P and P in YMLs at midgrowth at all levels of AG The P in YMLs corresponding to the level of applied P required for 95 99 or 100 of maximum yield (as determined from yield versus applied P plots) was then determined
Mitscherlich curves were also fitted to the relationship between level of applied P and P uptake by curds leaves stems and roots and the P uptake corresponding to whole plants (additions of all 4) level of P required for 95-100 of maximum yield determined Phosphorus uptake by plant parts or whole plants on 0 P plots were detected from P uptake at other rates to account for non-fertiliser sources of P This was used to adjust P uptake When determining P fertiliser recovery efficiency (RE) by plant parts or whole plants (ie fertiliser P uptake by plant parts or whole plantsP applied both in kgha Novoa and Loomis 1981)
Results
Effects of fresh AG on chemical characteristics of soil and soil solution
There was a significant (P lt 005) increase in the Ec pH PRI and sorption capacity (topsoil only) of the topsoil and subsoil of a yellow Karrakatta sand with level of freshly-applied AG prior to fertiliser application and planting (Table 51) There was no significant effect of level of AG on Colwell K K sorption capacity and total P with level of freshly-applied AG (Table 51)
The use of Red Mudgypsum in vegetable production
Table 51 Some chemical characteristics of the topsoil (0-15 cm) and subsoil (15-30 cm) of a yellow Karrakatta sand after application of Alkaloam gypsum (AG)1 just prior to fertiliser application and transplanting
(a) Topsoil (0-15 cm)
AG (tha)
Ec (mSm)
pH (CaCl2)
BicP2
(Vigfe)
BicK2
(pgg) PRI3
(mLg) TP4
(Pgg) CEC5
(me ) Kads6 Pads7
0 37 74 107 153 097 507 2 0 41
60 67 82 93 197 167 473 2 043 66
120 80 82 100 277 243 607 2 044 78
240 103 84 97 290 38 637 2 058 129
Lsd8 202 037 38 136 046 1010 0 049 41
Sig9 ns ns ns ns ns
(b) Subsoil (15-30 cm)
AG Ec PH BicP2 BicK2 PRI3 TP4
(tha) (mSm) (CaCl2) (Pgg) (Pgg) (mLg) (Pgg)
0 30 72 83 227 07 507
60 63 81 73 190 15 453
120 80 81 87 220 18 540
240 107 83 83 240 27 563
Lsd8 202 037 38 136 046 101
Sig9 ns ns ns
Applied 7 weeks previously 2 After Colwell (1963) 3 Phosphorus retention index after Allen and Jeffery (1990) 4 Total phosphorus 5 Cation exchange capacity (Gillman and Sumpter 1986) 6 Slope of K adsorption isotherm from the Freundlich equation (Allen and Jeffery 1990) 7 Slope of P adsorption isotherm from the Freundlich equation (Allen and Jeffery 1990) 8 Least significant difference at P lt 005 9 Significance at lt 0001 () lt 001 () lt 005 () level or not significant (ns)
There was a significant (P lt 005) increase in the concentration of Na and a decrease in the concentration of K in the soil solution with level of freshly-applied AG one month after planting and fertilising (Table 52 (a) and Fig 51) At the same time Colwell K and PRI in the topsoil increased significantly with level of freshly-applied AG By contrast there was a significant decrease in extractable Zn with level of AG The concentration of Ca Mg S and P increased significantly with level of applied P in soil solution (Table 52 (a)) Colwell P in the topsoil increased significantly with level of P whilst Colwell K PRI and extractable Zn decreased at the same time (Table 52 (b))
33
The use of Red Mudgypsum in vegetable production
Table 52 (a) Ec (mSm) pH and concentration of nutrients (pgmL) in soil solution 1 month after planting with level of freshly-applied Alkaloamreggypsum (AG)1 and phosphorus
AG
AG (tha)
Ec (mSm)
pH Ca (pgmL)
Mg (pgmL)
Na (pgmL)
K (pgmL)
S (pgmL)
P (pgmL)
Psrp2
(VigmL)
0 112 70 175 18 110 77 101 57 56
60 132 74 164 17 137 58 92 34 31
120 172 75 166 17 152 54 97 44 34
240 166 81 130 16 198 34 75 24 11
Lsd3 19 025 33 4 16 11 26 27 32
Sig4 ns ns ns ns ns
p
AG (tha)
Ec (mSm) PH
Ca (pgmL)
Mg (pgmL)
Na (pgmL)
K (pgmL)
S (UgmL)
P (pgmL)
Psrp2
(pgmL)
0 137 78 99 15 150 46 26 10 01
100 142 76 112 15 153 54 52 23 14
200 170 74 179 19 150 62 114 39 30
600 133 72 244 19 144 60 174 89 87
Lsd3 43 022 31 24 17 15 29 25 30
Sig4 ns ns ns
Applied 11 weeks previously
Soluble reactive P 3 Least significant difference at P lt 005 4 Significance at lt 0001 () lt 001 () lt 005 () level or not significant (ns)
The use of Red Mudgypsum in vegetable production
220
200
E 180 O ) 3
^ 1fi0 _ o 3 140 O V)
oil
120 m c
100 C o CO 80 c flgt o B0 c o o 40
20
0 50 100 150 200
Freshly-applied AG(tha)
250 300
Fig51 Concentration (ugml) of Na(i ) and K ( bull ) in soil solution (0-15cm) under cauliflowers one month after planting with level of freshly-applied AlkaloamRgypsum(AG) Vertical bars indicates Lsd (Plt005) for differences in concentration betweeen levels of AG
35
The use of Red Mudgypsum in vegetable production
Table 52 (b) Extractable P K Zn and phosphorus retention index of the top soil (0-15 cm) of a yellow Karrakatta sand 1 month after transplanting with level of freshly-applied Alkaloamreggypsum (AG)1 and phosphorus (P)
AG
AG (tha)
P2
(ugg) K2
(Ugg) Zn3
(Pgg)
PRI4
(mLg)
0 47 32 67 -112
60 76 38 15 -090
120 94 42 26 -049
240 84 41 13 092
Lsd5 35 6 28 073
Sig6 ns
P P2 K2 Zn3 PRI4
(kgha) (ugg) (Hgg) (Ugg) (mLg)
0 8 42 31 201 100 35 37 45 043 200 80 39 18 -089 600 177 34 26 -313
Lsd5 39 6 27 082
Sig6 ns
Applied 11 weeks previously 2 After Colwell (1963) 3 Extracted in DTPA 4 Phosphorus retention index (Allen and Jeffery 1990) 5 Least significant difference at P lt 005 6 Significance at lt 0001 () lt 001 () lt 005 () level or not significant (ns)
Ec pH exchangeable Ca K Na in me and Colwell P K total P PRI and PRIP increased significantly (P lt 005) with level of freshly-applied AG in the topsoil and subsoil of a yellow Karrakatta sand (Table 53 (a) (b) and Fig 52) at harvest
The use of Red Mudgypsum in vegetable production
o CO
CD
E
o CO
co o
CD
X co CD ogt e co sz o X HI
50 100 150 200
Freshly-applied AG (tha)
250 300
Fig52 Exchangeable Ca() NaP) and K(A) cations (me dry soil) in topsoil (0-15cm) of Karrakatta sand amended with freshly-applied AlkaloamRgypsum(AG) after harvest of cauliflowers Vertical bars indicates Lsd (Plt005) for differences in concentration between levels of AG Lsd not shown when less than size of symbol
37
The use of Red Mudgypsum in vegetable production
Table 53 Ec (mSm) pH and exchangeable Ca Mg K and Na (me ) in the topsoil (0-15 cm) and subsoil (15-30 cm) of a yellow Karrakatta sand amended with AlkaIoamreggypsum (AG) at harvest of cauliflowers
(a) Topsoil
AG Ec PH Ca Mg K Na (tha) (mSm) (CaCl2) (me ) (me ) (me ) (me )
0 67 66 229 018 005 003
60 91 77 382 019 009 02
120 99 79 558 019 012 043
240 120 80 975 024 014 104
Lsd2 20 014 064 0033 0018 021
Sig3 ns
(b) Subsoil
AG Ec pH Ca Mg K1 Na (tha) (mSm) (CaCl2) (me ) (me ) (me ) (me )
0 44 67 225 017 005 003
60 59 74 269 019 005 008
120 66 77 300 018 005 017
240 99 79 397 02 005 029
Lsd2 075 01 029 0036 001 002
Sig3 n s ns
Extracted in 1 m NH4CI 2 Least significant difference at P lt 005 3 Significance at lt 0001 () lt 001 () lt 005 () level or not significant (ns)
However there was no effect of either level of AG or P on exchangeable Mg in the soil at harvest Colwell P total P and PRIP increased significantly whilst Colwell K and PRI decreased with level of freshly-applied P in the topsoil at harvest (Table 4 (a) (b) and Fig 53)
The use of Red Mudgypsum in vegetable production
Table 54 P (extractable P total P phosphorus retention index and P sorption) in the top soil (0-15 cm) and subsoil (15-30 cm) of a yellow Karrakatta sand at harvest of cauliflowers with level of freshly-applied Alkaloamreggypsum (AG) and phosphorus (P)
(a) Topsoil
AG
AG BicP1 BicK1 TotP2 PRI3 PRIP3
(tha) (ugg) (Pgg) (Hgg) (mLg) (mLg)
0 39 23 92 -07 28
60 50 38 110 02 50
120 59 51 135 16 75
240 58 62 157 35 99
Lsd4 5 11 15 03 06
Sig5
P BicP1 BicK1 TotP2 PRI3 PRIP3
(kgha) (ugg) (Hgg) (ngg) (mLg) (mLg)
0 10 53 57 29 40
50 15 40 66 22 38
100 25 41 78 17 44
200 53 41 128 14 71
400 87 44 186 -01 86
600 120 41 226 -12 102
Lsd4 11 8 20 09 13
Sig5
1 After Colwell (1963) 2 After Allen and Jeffery (1990) 3 After Allen and Jeffery (1990) 4 Least significant difference at P lt 005 5 Significance at lt 0001 () lt 001 () lt 005 () level or not significant (ns)
39
The use of Red Mudgypsum in vegetable production
Table 54 P (extractable P total P phosphorus retention index and P sorption) in the top soil (0-15 cm) and subsoil (15-30 cm) of a yellow Karrakatta sand at harvest of cauliflowers with level of freshly-applied Alkaloamreggypsum (AG) and phosphorus (P)
(b) Subsoil (15-30 cm)
AG
AG BicP1 BicK1 TotP2 PRI3 PRIP3
(tha) (ugg) (Ugg) (Ugg) (mLg) (mLg)
0 33 20 79 -05 26
60 30 21 73 -01 30
120 33 27 77 08 42
240 26 24 76 13 40
Lsd4 10 2 10 04 10
Sig5 ns ns
P BicP1 BicK1 TotP2 PRI3 PREP3
(kgha) (ugg) (Vigg) (Ugg) (mLg) (mLg)
0 7 25 48 15 22
50 11 22 52 09 19
100 15 24 59 10 27
200 32 23 81 06 39
400 51 22 100 -03 47
600 67 21 117 -11 52
Lsd4 8 5 8 05 09
Sig5 ns
1 After Colwell (1963) 2 After Allen and Jeffery (1990) 3 After Allen and Jeffery (1990) 4 Least significant difference at P lt 005 5 Significance at lt 0001 () lt 001 () lt 005 () level or not significant (ns)
The use of Red Mudgypsum in vegetable production
100 150 200
Freshly-applied AG (tha)
300
Fig53 Concentration of total P(A) Colwell P() or K(laquo) in topsoil (0-15cm) with level of freshly-applied AlkaloamRgypsum (AG) after harvest of cauliflowers Vertical bars indicates Lsd (Plt005) for differences in concentration between levels of AG Lsd not shown when less than size of symbol
41
The use of Red Mudgypsum in vegetable production
Nutrients in leaves at midgrowth and harvest
There was a significant decrease in concentration of K and an increase in concentration of Na S Mn and Cu in youngest mature leaves (YML) of cauliflowers at buttoning with level of freshly-applied AG (Table 55) The concentration of P in YML at 01 AGha (049) was significantly higher than at 2401 AGha (044) but not at other levels Currently-applied AG had no significant effect on concentration of N Ca Mg Fe Zn or B in YML There was a significant increase in YML in the concentration of K P and S in YML with level of applied P whilst concentration of N Mg Mn and B were variable (Fig 54 55) Level of applied P had no significant effect on the concentration of Ca and Na in the YML (Table 55)
Table 55 (a) Concentration of macro-nutrients (dry weight basis) in youngest mature leaves of cauliflowers at buttoning with level of freshly-applied Alkaloamreggypsum (AG) and phosphorus (P)
AG
AG N1 K1 Ca2 S2 P1 Na2 Mg2
(tha) () () () () () () ()
0 482 393 240 081 049 036 023
60 484 383 251 084 046 040 024
120 506 357 255 081 046 045 024
240 494 355 246 088 044 056 025
Lsd3 026 012 024 005 003 006 0013
Sig4 ns ns ns ns
p
p N1 K1 Ca2 S2 P1 Na2 Mg2
(kgha) () () () () () () ()
0 523 316 254 066 024 046 025
50 489 372 255 081 041 049 026
100 503 388 229 084 048 042 024
200 472 379 250 089 050 046 024
400 494 390 242 093 057 043 023
600 470 385 258 091 057 039 022
Lsd3 027 024 036 005 003 008 0017
Sig4 ns ns
1 After Varley (1966) 2 After McQuaker et al (1979) 3 Least significant difference at P lt 005 4 Significance at lt 0001 () lt 001 () lt 005 () level or not significant (ns)
The use of Red Mudgypsum in vegetable production
0 50 100 150 200 250 300
Freshly-applied AG (tha)
Rg54 Concentration of N() K(B) and Ca(A) in youngest mature leaf (YML) at buttoning
of cauliflowers with level of freshly-applied AlkaloamRgypsum(AG) Vertical bars
indicates Lsd (Plt005) for differences in concentration between levels of AG
10
bdquo 09 lt Q OR ^ D) 07 c
tto
06 3
X3
to 05 _ l
gtbull 04 C
i3 03 c agt bull c 02 3
-z 01 0 50 100 150 200 250 300
Freshly-applied AG (tha)
Rg55 Concentration of S() Na(B) Mg(4) and P(T) in youngest mature leaf (YML) at buttoning
of cauliflowers with level of freshly-applied AlkaloamRgypsum(AG) Vertical bars indicates Lsd (Plt005) for differences in concentration between levels of AG
43
The use of Red Mudgypsum in vegetable production
The relationship between P in YML at buttoning and level of freshly-applied P was best described by Mitscherlich relationships at all levels of applied AG (Fig 56)
en c o 3
X2
gt
06
^
bull A
05 ^ S
04
03
02
01
n n i i i
0 100 200 300 400 500 600 700
Applied P (kgha)
o
X I
5 gt
06
05
04
03
02
01
00
- bull B
- bull bull ^
o
I I I I
0 100 200 300 400 500 600 700
Applied P (kgha)
100 200 300 400 500 600 700
Applied P (kgha)
100 200 300 400 500 600 700
Applied P (kgha)
Fig56 P in YML of Cauliflowers at buttoning () corresponding to applied P required for either 95 (dashed line) or 99 (whole line) of maximum yield at 0(A) 60(B) 120(C) or240(D)t of freshly-applied AlkaloamRgypsumha
The equations for the fitted lines are
A
B
C
D
y = 056 - 030 x exp (-00182) (R2 = 097)
y = 057 - 032 x exp (-00103) (R2 = 088)
y = 055 - 031 x exp (-00126) (R2 = 099)
y = 056 - 032 x exp (-00092) (R2 = 098)
The P in YML corresponding to level of freshly-applied P required for 99 of maximum yield was 053 057 055 and 055 for 0 60 120 and 240 tha respectively
44
The use of Red Mudgypsum in vegetable production
Table 55 (b) Concentration of micro-nutrients (dry weight basis) in youngest mature leaves of cauliflowers at buttoning with freshly-applied Alkaloamreggypsum (AG) and phosphorus (P)
AG
AG (tha)
Fe (Pgg)
Zn (Ugg)
Mn (vigg)
B (Pgg)
Cu1
(Pgg)
0 1354 251 217 211 26
60 1274 248 237 213 28
120 1353 253 240 217 27
240 1394 263 260 214 29
Lsd2 153 24 15 082 02
Sig3 ns ns ns
P Fe Zn Mn B Cu (kgha) (ngg) (ugg) (Pgg) (Ugg) (Pgg)
0 1418 268 212 215 26
50 1388 253 263 220 27
100 1301 267 251 217 29
200 1336 249 250 217 28
400 1282 255 232 204 28
600 1341 233 224 210 28
Lsd2 197 29 19 08 02
Sig3 ns ns ns
1 Extracted in 1 m NH4CI 2 Least significant difference at P lt 005 3 Significance at lt 0001 () lt 001 () lt 005 () level or not significant (ns)
There was a significant (P lt 005) decrease in the concentration of P Zn and an increase in the concentration of Na in whole leaves (WL) of cauliflowers with rate of freshly-applied AG at harvest (Table 56) Level of freshly-applied AG had no significant effect on concentration of N K Ca S Mg Fe Mn B or Cu Concentration of Ca S P and Na in (WL) at harvest increased significantly (P lt 005) with level of freshly-applied P whereas Zn concentrations decreased and concentrations of Mg Mn and B were variable Level of freshly-applied P had no significant effect on concentration of N K Fe or Cu in WL at harvest
45
A O O ltyi
4x
r en 00
9 400 200 o o o copy
ns
O
kgt ON
kgt
4gt
kgt 4 4 4^
kgt
ns
O 4 4 ON 4 k)
o
i mdash t mdash raquo
4 00
4 ON
4 4^ NO Q O
o copy ON
i mdash gt
b b 1 mdash t
b o p Vcopy
O 00 ON
o ON
gtmdash 5 co 5J M
o o
O in
o 4 Ncopy
o 4 O
p 4
p kgt 1 mdash t
copy
ON
o b NO
O ON
o 00
o 00
o ON I mdash
O ON
O 3 Z 5 raquoM
o b 4
O
kgt o kgt -J
p kgt 00
O kgt 00
O
kgt NO
copy kgt ON
The use of Red Mudgypsum in vegetable production
Table 56 (b) Concentration of micro-nutrients (dry weight basis) in leaves of cauliflowers at harvest with level of freshly-applied Alkaloamreggypsum (AG) and phosphorus (P)
AG
AG (tha)
Fe1
(ugg) Zn1
(vgg) Mn1
(vgg) B1
(vgg) Cu1
(vigg)
0 762 224 214 263 42
60 700 197 227 265 38
120 811 196 216 254 38
240 842 193 236 256 37
Lsd2 132 099 21 16 06
Sig3 ns ns ns ns
P (kgha)
Fe1
(pgg) Zn1
(^gg) Mn1
(Vigg) B1
(lJgg) Cu1
(Pgg)
0 786 233 213 248 36
50 625 235 241 266 37
100 833 207 237 270 41
200 938 192 235 265 44
400 725 178 208 259 37
600 765 169 206 250 37
Lsd2 230 21 21 11 063
Sig3 ns ns
After McQuaker et al (1979)
Least significant difference at P lt 005
Significance at lt 0001 () lt 001 () lt 005 () level or not significant (ns)
47
The use of Red Mudgypsum in vegetable production
Nutrients and heavy metals in curds at harvest
There was a significant (P lt 005) decrease in the concentration of K and P and an increase in the concentration of Ca and Na in the curds at harvest with level of freshly-applied AG Concentration of N Mg Fe Zn Mn B and Cu in the curds were unaffected by level of freshly-applied AG (Table 57) As level of freshly-applied P increased there was a significant (P lt 005) decrease in concentration of N S Mg Fe Zn Mn and B and an increase in concentration of K Ca P and Na in curds at harvest Concentration of Cu in curds were unaffected by level of applied P (Table 57 (b))
Table 57 (a) Concentration of macro-nutrients (dry weight basis) in curds of cauliflowers at harvest with level of freshly-applied Alkaloamreggypsum (AG) and phosphorus (P)
AG
AG N1 K1 Ca S1 P2 Na1 Mg1
(tha) () () () () () () ()
0 392 515 040 066 047 023 018
60 384 500 040 067 045 023 017
120 404 474 043 071 043 024 018
240 402 458 041 071 041 028 018
Lsd3 022 016 001 004 002 002 0006
Sig4 ns + ns ns
P
p N1 K1 Ca1 S1 P2 Na1 Mg1
(kgha) () () () () () () ()
0 496 417 034 097 031 016 019
50 400 518 043 068 040 023 018
100 376 483 042 063 042 025 017
200 372 501 044 063 047 027 017
400 371 498 042 062 052 028 017
600 358 505 041 060 052 027 016
Lsd3 027 02 003 005 002 003 001
Sig4
1 After McQuaker et al (1979) 2 After Varley (1966) 3 Least significant difference at P lt 005 4 Significance at lt 0001 () lt 001 () lt 005 () level or not significant (ns)
The use of Red Mudgypsum in vegetable production
Table 57 (b) Concentration of micro-nutrients1 (dry weight basis) in curds Cauliflowers at harvest with level of freshly-applied Alkaloam gypsum (AG) and phosphorus (P)
AG
AG (tha)
Fe1
(Ugg)
Zn1
(vigg) Mn1
(Pgg) B1
(Pgg) Cu1
(Pgg)
0 611 279 124 188 26
60 587 247 134 191 25
120 706 299 139 192 29
240 592 268 145 186 25
Lsd2 329 57 14 08 06
Sig3 ns ns ns ns ns
p
p (kgha)
Fe1
(Ugg) Zn1
(Pgg) Mn1
(Ugg) B1
(ugg)
Cu1
(Pgg)
0 976 492 156 202 31
50 520 279 145 198 26
100 507 230 135 186 24
200 432 208 127 190 24
400 739 239 131 183 28
600 567 192 120 177 24
Lsd2 270 61 142 114 061
Sig3 a s
1 After McQuaker et al (1979) 2 Least significant difference at P lt 005 3 Significance at lt 0001 () lt 001 () lt 005 () level or not significant (ns)
49
The use of Red Mudgypsum in vegetable production
Concentration of Ba in curds at harvest decreased and concentration of Ti increased significantly in curds at harvest with level of freshly-applied P (Table 58) As level of freshly-applied P increased concentrations of Pb and Rb decreased and of Sr decreased Ba concentrations were variable with level of freshly-applied P (Table 58)
Table 58 Concentration of Ba plus heavy metals1 (fresh weight basis) in curds of cauliflowers at harvest with level of freshly-applied Alkaloamreggypsum (AG) and phosphorus (P)
AG Ba Cd Cr Co Pb Ni Rb Sr Ti Th V (tha) (ngg) (ngg) (ngg) (ngg) (ngg) (ngg) (ngg) (ngg) (ngg) (ngg) (ngg)
0 797 7 34 7 13 34 590 1219 34 39 7
60 482 7 34 7 15 34 610 1146 46 52 8
120 583 7 43 7 20 34 616 1246 45 50 8
240 355 7 34 7 15 34 637 1152 41 45 8
Lsd2 141 1 13 16 11 15 74 188 5 16 1
Sig3 ns ns ns ns ns ns ns ns ns
MRL4 50 2000
P (kgha)
Ba (ngg)
Cd (ngg)
Cr (ngg)
Co (ngg)
Pb (ngg)
Ni
(ngg)
Rb (ngg)
Sr (ngg)
Ti
(ngg)
Th
(ngg)
V (ngg)
0 556 7 34 7 25 34 650 998 39 45 9
50 670 7 34 7 18 34 657 1387 50 74 9
100 576 7 34 7 11 34 570 1206 45 50 8
200 529 7 34 7 12 34 616 1293 39 39 7
400 523 7 48 7 19 39 596 1126 39 36 7
600 476 7 34 7 11 34 603 1126 36 36 7
Lsd2 121 1 16 1 15 6 40 181 19 29 2
Sig3 ns ns ns ns ns ns ns ns
MRL4 50 2000
Inductively coupled plasma mass spectrometry 2 Least significant difference at P lt 005 3 Significance at lt 0001 () lt 001 () lt 005 () level or not significant (ns) 4 Maximum residue limit
The use of Red Mudgypsum in vegetable production
P uptake by plants P uptake by whole plants or plant parts was unaffected by level of freshly-applied AG by but increased significantly with level of freshly-applied P (Table 59)
P uptake by whole plants increased from 50 kg Pha to 19 to 21 kgha at 400 to 600 kg applied Pha respectively Curd root stem and leaf uptake was 33 5 6 and 50 respectively of total plant P uptake at the highest level of applied P (Table 59)
Table 59 P uptake (kgha) by curds roots stem leaf and whole cauliflower plants at harvest with level of freshly-applied Alkaloamreggypsum (AG) and phosphorus (P)
AG
AG Curds Roots Stem Leaf Total (tha) (kgha) (kgha) (kgha) (kgha) (kgha)
0 53 074 11 87 158
60 48 066 10 83 148
120 47 069 11 79 143
240 45 060 10 74 135
Lsd1 065 015 025 21 31
Sig-2 ns ns ns ns ns
p
p (kgha)
Curd (kgha)
Root (kgha)
Stem (kgha)
Leaf (kgha)
Total (kgha)
0 12 030 040 29 49
50 40 058 100 68 124
100 51 053 112 76 143
200 59 075 120 93 172
400 67 093 131 115 205
600 61 094 121 102 185
Ls-d1 055 017 020 18 25
Sig2
1 Least significant difference at P lt 005 2 Significance at lt 0001 () lt 001 () lt 005 () level or not significant (ns)
51
The use of Red Mudgypsum in vegetable production
Yield
There was a significant (P lt 005) increase in both total and marketable curd yield with level of freshly-applied P at all levels of freshly-applied AG (Table 510) There was no significant effect of level of freshly-applied AG on either total (Table 510 (a)) or marketable (Table 510 (b)) curd yield
Table 510 Curd yield (total marketable) of cauliflowers (tha) at harvest with level of freshly-applied Alkaloamreggypsum (AG) and phosphorus (P)
(a) Total
p (kgha)
AG (tha) p
(kgha) 0 60 120 240
0 755 468 483 177
50 1464 1675 1554 1516
100 2169 1706 1757 1985
200 2242 1737 1928 1862
400 1752 2102 2155 2136
600 1689 1764 1768 2023
Lsd1
Sig2
16 (AG)
ns 201 (P)
401 (AGP)
-
(b) Marketable
p (kgha)
AG (tha) p
(kgha) 0 60 120 240
0 274 060 000 000
50 1222 1463 1294 1152
100 2057 1416 1603 1820
200 2141 1377 1803 1752
400 1572 2020 2095 1996
600 1468 1534 1500 1974
Lsd1
Sig2
24 (AG)
ns
46 (P)
52(AGP)
ns
Least significant difference at P lt 005 2 Significance at lt 0001 () lt 001 () lt 005 () level or not significant (ns)
The relationship between total yield and level of freshly-applied P was best described by a quadratic relationship at all levels of freshly-applied AG (Fig 57) As level of AG increased the level of freshly-applied P required for 99 of maximum yield increase from 124 kg Pha at 0 t AGha to 339 kg Pha at 240 tha There was no significant effect of level of freshly-applied AG on maximum curd yield (Fig 57)
The use of Red Mudgypsum in vegetable production
26
24
22
(tha
) 20
18
Cur
d yi
eld 16
14
12
10
8
6 i ii
A=0
i i i i i
I I
0 100200300400500600700
Applied P (kgha)
24 22 20 18 16 14 12 10 8 6 4 2
- 7 I
_ bull
i i i n
mdash^ B=60
I I I
0 100200300400500600700
Applied P (kgha)
co
32 CD
gt 2 3
o
25
20
15
10
5
bull j
- bull
I I I I I
- - gt C=120
l l l
0 100200300400500600700
Applied P (kgha)
0 100200300400500600700
Applied P (kgha)
Fig57 Total curd yield (tha) of cauliflower with level of freshly-applied Alkaloam gypsum and
phosphorus (ABCD = 060120240 tha) Vertical lines represent applied P necessary
for either 95 (dashed) or 99 (whole) of maximum yield
The equations for the fitted lines are
A y = 1336 + (-577 + 01335x)(l-00088x +000007872) (Z2
B y = 89434 + 00705 - OOOOlx2 (R2 = 070)
C y = 84752 + 00810 - OOOOlx2 (B2 = 081)
D y = 733 +00871x - 00001 Ix2 (R2 = 099)
098)
53
The use of Red Mudgypsum in vegetable production
Discussion
The increase in pH Ec PRI and P sorption of Karrakatta sands with level of freshly-applied AG prior to fertiliser application is similar to that reported for the amendment of Joel (McPharlin et al 1994 and Robertson et al 1997a) and Karrakatta sands (Robertson et al 1994 and 1997b) with AG The increase in DH and Ec of the amended soil is explained by the high levels of both in the AG (ie pH (CaCr) = 94 and Ec = 623 mSm Appendix 1) The increased retentionsorption of P is explained by the addition of iron (974) and aluminium (551) in various oxides and hydroxides in the AG (Appendix 1 and Barrow 1982) to the soil After the application of P fertilisers levels of P in the soil at mid-growth and harvest as measured by total and Colwell P increased with a parallel decrease in PRI The increase in the levels of exchangeable Ca and Na in the soil at the same times with level of freshly-applied AG can be attributed to the AG itself However the increase in exchangeable and Colwell K appears to be due to improved K retention capacity of the soil due to physical properties of the AG rather any increased supply of K from the AG Whilst the overall K adsorption properties of the soil as measured by the Freundlich isotherm was not significantly increased with level of AG K sorption at 2401 AGha was significantly higher than at 01 AGha
There was no significant increase in cation exchange capacity (CEC) with level of freshly-applied AG on the Karrakatta sand in this experiment which remained about 2 me By contrast the CEC of virgin Joel sands increased from 1 to 2 me with level of freshly-applied AG (0 to 240 tha) in columns (McPharlin et al 1994) The application of AG would be expected to increase the CEC of coarse sands because (1) AG a fine textured material (10 clay 68 silt) (Ward 1983) would increase the fine fraction when applied to sands (2) AG has a much higher CEC ie 7 to 15 me depending on pH (Barrow 1982) than either Joel or Karrakatta sands ie 1 to 2 me (McPharlin et al 1994 and Table 51) and (3) application of AG to either Joel or Karrakatta sands increases the retentionreduces leaching of cations either not present in the AG such as NH4-N (McPharlin et al 1994) or only present in small quantities such as K (Tables 52 53 54 and Appendix 51)
The concentration of an element in the soil expressed as either extractable or total amounts represents the quantity or extensive factor in terms of plant nutrition as outlined by Holford and Mattingly (1976) The concentration of ions in soil solution or the intensive factor may better represent what is available to the plant A good example of this is the levels of K in the soil expressed as either Colwell or exchangeable K which increase significantly with level of applied AG However levels of K in the plant YML at buttoning and curds at harvest decrease significantly with level of AG K in soil solution 1 month after planting similarly decline significantly with level of applied AG and are therefore better correlated with K nutrition of the plant than measurements based on the dry soil Similarly P concentrations in the plant and soil solution decline whilst P retained by the soil increase in response to freshly-applied AG By contrast concentrations of Na in soil solution soil and plant all increase with levels of freshly-applied AG Similar relationships between concentrations of K Na and P in the soil soil solution and plant on a Karrakatta sand have been reported previously (Robertson et al 1997)
In previous work maximum yield (ie A value) of cauliflowers was reduced when freshly prepared AG was applied at levels gt 120 tha (Robertson et al 1994) This yield reduction was assumed not to be due to induced P deficiency resulting form high level of applied AG as it could not be alleviated by increased levels of applied P Although increased levels of applied P were needed to maximise yield as the level of freshly-applied AG increased Concentrations of K decreased and Na increased in the YML with level of applied AG and the yield reduction was assumed to be due either induced K deficiency or Na toxicity However neither the reduced concentrations of K or the increased concentrations of Na in the plant were at levels that would reduce yield according to published standards (Weir and Cresswell 1993) Antagonism between Na and K uptake by plants is common (Yeo 1983) For example increasing soil salinity resulted in increased concentrations of Na and decreased concentrations of K in the leaves of Zucchini grown in controlled greenhouses in Spain (Villora et al 1997)
The use of Red Mudgypsum in vegetable production
In this work as level of freshly-apphed AG increased level of applied P necessary for maximum yield increased as in the previous work however maximum yield was not reduced by AG up to 240 tha This is despite concentrations of K in the YML decreasing and Na increasing in response to level of freshly-applied AG However as in the previous work neither concentrations of K or Na were at levels expected to cause yield reduction By contrast the reduction in maximum yield of potatoes at high levels of freshly-applied AG (ie gt 120 tha) was correlated with a reduced concentration of K in the petioles (Robertson et al 1997b)
The level of freshly-applied P required for 99 of maximum yield in this work increased from 124 kgha at 01 AGHa to 339 kgha at 2401 AGha These levels of applied P are similar to that reported necessary for maximum yield of cauliflowers on AG-amended (Robertson et al 1994) or unamended (McPharlin et al 1995) Karrakatta sands The P required for 99 of maximum yield in this work 053 to 057 was either slightly higher - 047 (McPharlin et al 1995) or within range - 05 to 07 (Piggott 1986) 03 toO7 (Weir and Cresswell 1993) of that reported as critical or adequate for maximum yield of cauliflowers
Increased levels of freshly-applied AG did not significantly change the concentrations of Cd Co Cr Pb Ni Rb Sr Th or V in the curds of cauliflowers By contrast concentrations of Ba were significantly reduced and Ti increased in the curds with levels of freshly-applied AG Similarly there was no reported change in concentration of Cd Cr Pb or Co with level of freshly-applied AG in curds of cauliflower grown on Karrakatta sands (Robertson et al 1994) in previous work Also there was no change in Ba concentration in curds with level of AG in contrast to the previous work
References
Barrow NJ (1982) Possibility of using caustic residue from bauxite for improving the chemical and physical properties of sandy soils Australian Journal of Soil Research 33 275-285
Holford ICR and Mattingly GEG (1976) Phosphate adsorption and plant availability of phosphate Plant and Soil 44 377-89
McArthur and Bettenay (1960) The development and distribution of the soils of the Swan Coastal Plain Western Australia Soils Publication No 16 CSIRO Division of Soils CSIRO Melbourne Australia
McPharlin IR JefFery RC Toussaint LF and Cooper M (1994) Phosphorus Nitrogen and Radionuclide Retention and Leaching from a Joel Sand amended with Red Mudgypsum Communications in Soil Science and Plant Analysis 25 (17 amp 18) 2925-2944
McPharlin IR Robertson WJ JefFery RC and Weissberg R (1995) Response of cauliflower to phosphate fertiliser placement and soil test phosphorus calibration on a Karrakatta sand Communications in Soil Science and Plant Analysis 26(3amp4) 607-620
McQuaker NR Brown DF and Kluckner PD (1979) Digestion of environmental materials for analysis by inductively coupled plasma-atomic emission spectrometry Analytical Chemistry 51 1082-1084
Piggott TJ (1986) Vegetable crops pp 148-187 In DJ Reuter and JB Robinson (eds) Plant Analysis an Interpretation manual Inkata Press Melbourne Australia
Robertson WJ McPharlin IR and JefFery RC (1994) Final report of investigation into the use of gypsum-amended Red Mud as a soil-amendment on horticultural properties on the Swan Coastal Plain Report to HRDC (Project No V0039RO) Department of Agriculture Western Australia
55
The use of Red Mudgypsum in vegetable production
Robertson WJ Jeffery RC and McPharlin IR (1997a) Residues from bauxite-mining (Red Mud) increase phosphorus retention of a Joel sand without reducing yield of carrots Communications in Soil Science and Plant Analysis 28 (in press)
Robertson WJ McPharlin IR and Jeffery RC (1997b) The growth nutrition and mineral composition of potatoes (Solanum tuberosum L) cv Delaware grown on an yellow Karrakatta sand amended with freshly-applied and residual Alkaloamreggypsum (Submitted to AJEA)
Varley J A (1966) Automatic methods for the determination of nitrogen phosphorus and potassium in plant material Analyst 91 119-126
Villora G Pulgar G Moreno DA and Romero L (1997) Effect of salinity treatments on nutrient concentration in Zucchini plants (Cucurbita pepo L var Moschatd) Australian Journal of Experimental Agriculture 37 605-608
Vlahos S Summers KJ Bell DT and Gilkes RJ (1989) Reducing phosphorus leaching from sandy soils with Red Mud bauxite processing residues Australian Journal of Soil Research 27 651-662
Weir RG and Cresswell GC (1993) Plant Nutrient Disorders 3 Vegetable crops p 93 Inkata Press Melbourne Australia
Yuen SH and Pollard AG (1954) Determination of nitrogen in agricultural material by the Nessler reagent II Micro determination in plant tissue and soil extracts Journal of the Science of Food and Agriculture 5 364-369
The use of Red Mudgypsum in vegetable production
Appendix 51 Chemical and physical characteristics of Alkaloam gypsum used in cauliflower experiment (freshly-applied Alkaloamreggypsum)
Parameter Units Value Kgt
Ec mSm 623 -
pH (H 20) mSm 99 -
pH (CaCl2) mSm 94 -
PRI mLg 610 - gt 1000 -
LOI 1973 -
C a C 0 3 1290 1290
Fe (Fe203) 974 974
Al (A1203) 551 551
Si (Si0 2 ) 797 797
Ca (CaO) 45 450
Na (Na 2 0) 228 228
Ti (Ti0 2 ) 174 174
K (K 2 0) 072 72
Mg (MgO) 028 28 sect 047 47
P (P2O5) 005 05
Mn (MnO) 002 02
Total P ngg 266 -
Extractable P M-gg 58 -
Extractable K M-gg 43 -
As ngg 35 -
Ba ^gg 413 -
Cu Ugg 29 -
Sr Hgg 287 -
Nb Hgg 99 -y Hgg 866 -
Zr fAgg 1477 -
Sand 232 -
Silt 473 -
Clay 295 -
After Allen and Jeffery (1990)
Based on X-ray fluorescence (XRF) spectrometry
After Colwell (1963)
The use of Red Mudgypsum in vegetable production
Appendix 52 Concentration of Ba plus heavy metals1 (dry weight basis) in curds of cauliflowers at harvest with level of freshly-applied Alkaloamreggypsum (AG) and phosphorus (P)
(a)
AG Ba Cd Cr Co Pb Ni Rb Sr Ti Th V (tha) (Pgg) (vigg) (ugg) (ugg) (Pgg) (Pgg) (Pgg) (ugg) (Pgg) (Pgg) (Pgg)
0 119 010 050 010 020 050 88 182 050 058 010
60 72 010 050 010 022 050 91 171 069 078 012
120 87 011 064 011 030 050 92 186 067 075 012
240 53 011 05 010 023 050 95 172 061 067 012
Lsd2 21 002 02 024 016 022 11 28 008 024 002
Sig3 ns ns ns ns ns ns ns ns ns
(b)
p (kgha)
Ba (vgg)
Cd (vigg)
Cr (Pgg)
Co (ngg)
Pb (vgg)
Ni (Pgg)
Rb (Pgg)
Sr (Pgg)
Ti
(Pgg)
Th (Pgg)
V
(Pgg)
0 83 010 050 010 038 050 97 149 058 067 013
50 100 011 050 010 027 050 98 207 075 110 013
100 86 010 050 010 017 050 85 180 067 075 012
200 79 010 050 010 018 050 92 193 058 058 010
400 78 011 071 011 028 058 89 168 058 054 011
600 71 010 050 010 016 050 90 168 054 054 010
Lsd2 18 002 024 0009 022 009 06 27 028 044 003
Sig3 ns ns ns ns ns ns ns ns
Inductively coupled plasma mass spectrometry
Least significant difference at P lt 005
Significance at lt 0001 () lt 001 () lt 005 () level or not significant (ns)
The use of Red Mudgypsum in vegetable production
6 RESPONSE OF CAULIFLOWERS TO RESIDUAL RED MUD (ALKALOAMreg)GYPSUM (AG) AND PHOSPHORUS ON A YELLOW KARRAKATTA SAND
Introduction
It is important to reduce the leaching of phosphorus fertiliser from sandy soils used for vegetable production into the water systems of the Swan Coastal Plain Red Mud (Alkaloam )gypsum (AG) (ie Red Mudgypsum RMG) a waste product from bauxite refining has been suggested as an amendment to reduce phosphorus leaching from sands of the Bassendean Association (Joel Gavin) used for agriculture and horticulture (Barrow 1982)
Experimental work in the field and pots showed amendment with AG significantly reduced P leaching from Joel and Gavin sands (Vlahos et al 1989 McPharlin et al 1994) compared with the unamended (01 RMGha) treatment
Previous work showed a significant reduction in maximum yield of cauliflowers with levels of residual AG of gt 60 tha compared with 01 AGha (Robertson et al 1994) This yield reduction was not due to P deficiency as increased levels of applied P did not obviate the problem Nor was it due to K deficiency as K concentrations in the youngest mature leaves (YML) although reduced by levels of residual AG did not decline to levels expected to reduce yield The converse was true for concentrations of Na in the YML which increased with levels of residual AG but not to concentrations expected to cause toxicity
Since more than 60 tha of AG may be required to significantly improve P retention by sands to enable sustainable horticultural production this yield reduction is re-examined with residual AG
Materials and methods
Site characteristics
The experiment was conducted on a yellow Karrakatta sand (McArthur and Bettenay 1960) at Medina Research Centre (32deg 13 S 115deg 49 E) 30 km south of Perth Both Alkaloamreggypsum (AG) and phosphorus had previously been applied to the site and a potato crop grown in 1995 Prior to that the site had been sown to pasture for several years Some relevant chemical characteristics of the topsoil (0-15 cm) and subsoil (15-30 cm) of the site after application of AG but prior to the application of fertiliser (except residual P) and transplanting are presented in Table 61
Red Mud (Alkaloamreg)gypsum
Alkaloamreg (Red Mud) amended with 10 (ww) gypsum (AG) was produced by the dry mix process by ALCOA of Australia Ltd at their Kwinana Residue Treatment Plant The AG had been spread manually on the site and incorporated using a rotary hoe to approximately 30 cm depth on 22 December 1994 Residual P had been applied just before planting of the previous potato crop on 17 May 1995 and incorporated with a rotary hoe The site was watered for 1 hour per day (8 mmday) using impact sprinklers until planting
Experimental design
The experimental design was a split-plot randomised block with 3 replicates The main plots were levels of AG (0 60 90 120 and 240 tha) and the sub-plots were levels of freshly-applied P (25 50 100 300 and 600 kgha) Main plots measured 7 x 12 m and sub-plots 12 x 7 m (excluding wheel tracks)
59
The use of Red Mudgypsum in vegetable production
Crop management
The site was sprayed with Roundupreg (3 Lha) twice after application of AG and prior to planting to control weeds Six week old seedlings of cauliflowers (cv Plana) obtained from a commercial nursery were transplanted manually on 18 April 1996 in 2 rows per plot with 70 cm between rows and 50 cm between plants Seedlings were dipped in Rovralreg (1 mLL) just prior to planting for control of fungi Treflanreg (14 Lha) and Dacthalreg (12 kgha) were applied immediately after transplanting to control broadleaved weeds and Sertinreg later on in the life of the crop for grass control Ambushreg (100 mLha) and Rogorreg (100 mLha) were used to control caterpillars and red legged earth-mite respectively Copper was applied for control of blackrot The crop was irrigated to a total application equivalent to 100 of the previous days pan evaporation using minisprinklers (Legoreg 6 x 6 m spacing 44 mmh) in 3 waterings of equal duration per day
Fertilisers
Pre-planting fertilisers were broadcast manually and rotary hoed on 17 April 1996
These were K2S04(244) Ca(N03)2(387) MgS047H20 (504) MnS04H20 (504) FeS047H20 (18) Borax (27) CuS045H20 (36) ZnSOH20 (28) and Na2Mo042H20 (2) P was applied as single superphosphate (91 P) at 0 to 600 kg Pha according to treatment and incorporated as before Post-planting K N and Ca were fertigated via the irrigation system as KN03 NHUNO3 and Ca (N03)2 in equal amounts per day for 12 weeks to a total of 600 kg Kha 423 kg Nha and 60 kg Caha Borax was fertigated at 20 kgha in week 3 and Mg was broadcast as MgS047H20 at 50 kgha in weeks 3 6 and 9
Measurements
Soil and soil solution
All zero P subplots were sampled 30 cores per plot just prior to planting and fertilising about 2 months after AG application to 2 depths (0-15 15-30 cm) These were oven dried at 40degC and analysed for Ec pH (CaCl2) P sorption (Ozane and Shaw 1968) bicarbonate extractable P K (Colwell 1963) total P PRI P sorption K sorption (Allen and Jeffery 1990) and cation exchange capacity (Gillman and Sumpter 1986)
The soil water was obtained by centrifugation from soil samples (0-15 cm 30 per plot) and collected from the 0 100 200 and 600 kg Pha plots across all AG treatments on the 16 May 1996 The supernatant was analysed for pH Ec Ca Mg K S and P The remaining soil was analysed for pH (H20) bicarbonate extractable P K PRI and DTPA extractable Zn After harvest 5 August 1997 soil samples were collected from 2 depths as for the preplanting treatment from all plots These were analysed for pH bicarbonate extractable P K total P PRI and exchangeable cations (Ca Mg K and N)
Plant
At buttoning on 13 June 1996 the younger mature leaves (YML) (4th from growing point) were collected from 16 plants (excluding 1 m buffer at each end of plot) in each plot They were dried at 70degC in a force draught oven for 48 h and ground to pass through a 1 mm screen Sub-samples were digested with sulphuric acidhydrogen peroxide (Yuen and Pollard 1954) and the concentration of N P and K measured by an automated colorimetric process (Varley 1966) Concentration of other nutrients (B Ca Na Mg S Fe Mn Zn and Cu) were determined by inductively coupled plasma atomic emission spectroscopy (ICP-AES) after digestion with nitric-perchloric acids (McQuaker et al 1979) Five whole plants were harvested from the middle of each plot (2 per row) at the end of the experiment on 4 July 1996 using shovels to remove as much of the roots as possible The plants were separated into four categories curds leaves stems and roots All soil was dried and digested as for ICP-AES as above and washed from the roots using tap water shaken and the excess water removed using paper towels The fresh weight of all four categories was recorded and the material was diced
60
The use of Red Mudgypsum in vegetable production
into small pieces (lt 8 cm3) using stainless steel knifes sub-samples (300 g fresh weight) were collected at random from the diced pieces and the fresh weight recorded These were dried at 70degC in a forced draught oven for 48 h and the dry weight recorded These samples were then analysed for P as for the youngest mature leaves Separate sub-samples (300 g fresh weight) of curds were collected and analysed for Ba Cd Cr Co Pb Mo Rb Sr Ti Th V and Ni using inductively coupled plasma mass spectrometry (ICP-MS) The fresh and dry weight of the curds leaves stems and roots at harvest were used to calculate P uptake in kgha)
Harvest
Harvest commenced when the leaves surrounding the head opened and exposed the curds 77-80 days after transplanting At this stage florets at the periphery of the curd had just begun to separate Sixteen curds (12 plus 4 from whole plant samples above) were collected from the central 4 m of both rows (1 m buffer) and then all the leaves and stems removed according to requirements for export market Each fresh curd was weighed and rejects recorded if undersize (lt 500 g) oversize (gt 2000 g) discoloured (yellowing) overmature (separation of florets in the centre of curd) diseased damaged or otherwise distorted The total marketable and reject yield were recorded for each plot
Analysis of data
Analysis of variance was carried out on level of applied AG or P versus (a) chemical characteristics of soil (bicarbonate extractable P total P etc) preplanting and harvest (b) concentrations of nutrients in soil solution at midgrowth (c) concentration of nutrients in YMLs at midgrowth (d) concentration of elements in curds at harvest (e) P uptake by plant parts and (f) total marketable and reject yield of curds at harvest Mitscherlich curves and inverse polynomials were fitted to the relationship between level of applied P and yield at each level of applied AG The level of applied P required for 95 99 and 100 (in case of inverse polynomials) of maximum yield was calculated Mitscherlich curves were fitted to the relationship between level of applied P and P in YMLs at midgrowth at all levels of AG The P in YMLs corresponding to the level of applied P required for 95 99 or 100 of maximum yield (as determined from yield versus applied P plots) was then determined
Mitscherlich curves were also fitted to the relationship between level of applied P and P uptake by curds leaves stems and roots and the P uptake corresponding to whole plants (additions of all 4) level of P required for 95-100 of maximum yield determined Phosphorus uptake by plant parts or whole plants on 0 P plots were deducted from P uptake at other rates to account for non-fertiliser sources of P This was used to adjust P uptake when determining P fertiliser recovery efficiency (RE) by plant parts or whole plants ie fertiliser P uptake by plant parts or whole plantsP applied both in kgha (Novoa and Loomis 1981)
The effect of residual AG andP on chemical characteristics of the soil
Increased levels of previously-applied (residual) AG resulted in a significant increase in Ec pH (CaCl2) Colwell P and PRI in the topsoil (0-15 cm) of a Karrakatta sand prior to current the application of fertilisers and planting (Table 61 Fig 61) There was no significant effect of level of residual AG on the levels of Colwell K in the topsoil Increasing levels of previously-applied (residual) P resulted in a significant increase in Colwell P and a decrease in PRI and pH at the same time but had no effect on the levels of Colwell K in the topsoil
61
The use of Red Mudgypsum in vegetable production
Table 61 Chemical characteristics of the topsoil (0-15 cm) of a yellow Karrakatta sand 12 months after application of Alkaloamreggypsum (AG) (residual AG) and phosphorus (P) just prior to fertiliser application and transplanting
AG Ec pH BicP1 BicK1 PRI2
(tha) (mSm) (CaCl2) (H8g) (Hgg) (mLg)
0 36 70 262 199 093
60 62 78 397 308 101
90 70 80 390 378 12
120 73 80 402 391 14
Lsd3 057 018 75 122 018
Sig4 ns
P (kgha)
Ec (mSm)
pH (CaCl2)
BicP1
(M-gg) BicK1
(figg) PRI2
(mLg)
0 59 78 117 323 17
25 58 78 147 338 15
50 58 78 160 322 16
100 58 78 255 327 13
300 62 76 554 309 06
600 66 75 944 296 005
Lsd3 063 01 58 60 02
Sig4 ns ns
1 After Colwell (1963) 2 After Allen and Jeffery (1990) 3 Least significant difference at P lt 005 4 Significance at lt 0001 () lt 001 () lt 005 () level or not significant (ns)
62
The use of Red Mudgypsum in vegetable production
mdash A
8 40 gt -o deggt 35 - en =gt mdash sect 30 _raquo CO
e 25 ltD O d
5 20
1 ^ I I I
T3
C
o
c CO o c o o
0 20 40 60 80 100120140
Residual AG (tha)
u u bull B
80 l
60
40
mdash n bull 20
n i i i i
I
i i i
100 200 300 400 500 600 700
Residual P (kgha)
Figure 61 (A B) Bicarbonate extractable P (bull) and K (bull) (figg dry soil after Colwell 1963) in the top soil (0-15 cm) of a yellow Karrakatta sand prior to fertilising and planting with level of residual Alkaloamreggypsum (t AGha) (A) and P (kgha) (B) Vertical bars refer to Lsd (P lt 005) for differences between levels of AG or P
5 E Q 0 -
20 40 60 80 100120 140
Residual AG (tha)
0 100 200 300 400 500 600 700
Residual P (kgha)
Figure 61 (C D) Phosphorus retention index (PRI) after Allen and Jeffery (1990) in the topsoil (0-15 cm) of a yellow Karrakatta sand prior to fertilising and planting with level of residual Alkaloamreggypsum (t AGha) (C) and P (kgha) (D) Vertical bars refer to Lsd (P lt 005) for differences between levels of AG or P
63
The use of Red Mudgypsum in vegetable production
One month after planting there was a significant increase in concentration of Ca Na and pH and a decrease in K concentration with level of residual AG in the soil solution at 15 cm depth There was no significant effect of level of residual AG on the Ec or concentration of Mg S and soluble reactive P (Psr) in the soil solution (Table 62 (a) Fig 62) There was a significant decrease in Ec pH and concentration of Mg Na and an increase in concentration of Ca S and Psr in soil solution with level of residual P
Table 62 (a) Ec (mSm) pH and concentration of nutrients (ugmL) in soil solution 1 month after planting cauliflowers with level of residual Alkaloamreggypsum (AG) and phosphorus (P)
AG
AG (tha)
Ec (mSm)
pH Ca (ngmL)
Mg (ugmL)
Na (jigmL)
K (UgmL)
S (jigmL)
Psrp1
(pgmL)
0 129 75 91 141 105 81 28 05
60 144 77 108 131 121 64 30 06
120 147 76 123 136 120 50 33 04
Lsd2 33 01 14 09 4 7 1 02
Sig3 ns ns ns ns
P
p (kgha)
Ec (mSm)
pH Ca (UgmL)
Mg (ligmL)
Na (jigmL)
K (UgmL)
S (UgmL)
Psrp1
(VigmL)
0 171 78 107 141 121 68 23 01
100 138 77 104 144 111 58 24 02
300 120 76 103 128 110 63 31 06
600 130 73 117 133 116 71 43 13
Lsd2 20 02 10 11 10 13 7 02
Sig3 ns
Soluble reactive P 2 Least significant difference at P ^ 005 3 Significance at lt 0001 () lt 001 () lt 005 () level or not significant (ns)
64
The use of Red Mudgypsum in vegetable production
3
C
o
o (gt
o in c c o
5 c CD O
o O
3
o
c o
c ltu o c o
o 0 20 40 60 80 100 120 140
Residual AG (tha)
0 100 200 300 400 500 600 700
Residual P (kgha)
Figure 62 (A B) Concentration (figmL) of Ca (bull) Mg (bull) Na (A) K (T) and S (bull) in soil solution (0-15 cm) under cauliflower one month after planting with level P residual Alkaloamreggypsum (AG) (A) and (B) Vertical bars refer to Lsd (P lt 005) for differences in concentration between levels of AG Where bars are not shown Lsd is less than size of symbol
There was a significant increase in Colwell P K and PRI in the topsoil (0-15 cm) and no change in DTPA extractable Zn with level of residual AG one month after planting (Table 62 (b)) As level of residual P increased there was a significant increase in Colwell P and decrease in PRI with no change in Colwell K or DTPA extractable Zn in the topsoil one month after planting
The use of Red Mudgypsum in vegetable production
Table 62 (b) Extractable P K Zn and phosphorus retention index of the TopsoU (0-15 cm) of a yellow Karrakatta sand 1 month after planting of cauliflowers with level of residual Alkaloamreggypsum (AG) and phosphorus (P)
AG
Ag BicP1 BicK1 Zn2 PRI3
(tha) (Pgg) (Pgg) (Pgg) (mLg)
0 27 41 25 05
60 45 43 26 03
120 50 59 23 07
Lsd4 8 6 05 01
Sig5 ns
p
p (kgha)
BicP1
(Pgg) BicK1
(Pgg)
Zn2
(l-igg) PRI3
(mLg)
0 9 46 19 12
100 21 47 22 09
300 42 46 25 03
600 90 52 31 -03
Lsd4 7 5 10 02
Sig5 ns ns
1 After Colwell (1963) 2 Extracted in DTPA 3 After Allen and Jeffery (1990) 4 Least significant difference at P ^ 005 5 Significance at lt 0001 () lt 001 () lt 005 () level or not significant (ns)
After harvest of cauliflowers there was a significant increase in Colwell P and K total P actual and predicted PRI (PRI and PRIp) with residual AG in the topsoil and subsoil of a Karrakatta sand (Table 63 (a) (b)) There was a significant increase in Colwell P and total P and decrease in Colwell K PRI and PRIp with level of residual P in both the topsoil and subsoil after harvest (Fig 63 (A B))
66
The use of Red Mudgypsum in vegetable production
Table 63 Extractable P K total P and phosphorus retention index of the topsoil (0-15 cm) and subsoil (15-30 cm) of a yellow Karrakatta sand after harvest of cauliflowers with level of residual AIkaloamreggypsum (AG) and phosphorus (P)
(a) Topsoil
AG
AG BicP1 BicK1 TotP2 PPJ3 PPJP4
(tha) (ngg) (Hgg) (Pgg) (mLg) (mLg)
0 16 28 68 10 26
60 25 42 86 15 41
90 25 46 91 16 43
120 26 54 96 18 46
Lsd5 3 9 8 005 03
Sig6
P (kgha)
BicP1
(Pgg) BicK1
(vigg) TotP2
(ngg) PPJ3
(mLg) PPJP4
(mLg)
0 7 46 58 19 27
25 8 45 63 19 28
50 9 44 64 20 30
100 15 43 72 17 33
300 37 40 103 09 48
600 63 36 152 03 67
Lsd5 3 6 8 03 05
Sig6
1 After Colwell (1963) 2 After Allen and Jeffery (1990) 3 Phosphorus retention index (Allen and Jeffery 1990) 4 Predicted phosphorus retention index (Allen and Jeffery 1990) 5 Least significant difference at P ^ 005 6 Significance at lt 0001 () lt 001 () lt 005 () level or not significant (ns)
The use of Red Mudgypsum in vegetable production
120
o lgt 100 bull gt
TJ
rn laquon D ) 3
mdash-
on
60
^^ m i _
c 40 ltigt o c o O 20
160 A (I 140
^ ^ ^ ^ 1 o (0 ^ ^ ^ ^ 1 gtraquo 120
^plusmn bull o
^ ^ ^ ^
66
100
^ 3 80
^ mdash ^ tra
tion
60
^ ^ - ^ ^ ^ cen 40
o 20 o 20
I I I I I I I
O
10
0
0 20 40 60 80 100 120 1lt
O
10
Residual AG (tha)
0 100 200 300 400 500 600 700
Residual P (kgha)
Figure 63 (A B) Bicarbonate extractable P (bull) K (bull) and total P (A) in the topsoil (0-15 cm) of a yellow Karrakatta sand after harvest of cauliflowers with level of residual AIkaloamreggypsum (t AGha) (A) and P (kgha) (B) Vertical bars refer to Lsd (P lt 005) for difference between level of AG or P Lsd not shown when less than size of symbol
68
The use of Red Mudgypsum in vegetable production
Table 63 Extractable P K total P and phosphorus retention index of the topsoil (0-15 cm) and subsoil (15-30 cm) of a yellow Karrakatta sand after harvest of cauliflowers with level of residual Alkaloamreggypsum (AG) and phosphorus (P)
(b) Subsoil
AG
AG BicP1 BicK1 TotP2 PRI3 PRJJP4
(tha) (Pgg) (ugg) (ngg) (mLg) (mLg)
0 15 23 69 08 24
60 23 31 82 12 36
90 24 37 91 14 39
120 25 40 90 17 43
Lsd5 4 6 7 01 03
Sig6
P (kgha)
BicP1
(ngg) BicK1
(ugg) TotP2
(ugg) PRI3
(mLg) PRIP4
(mLg)
0 6 36 57 18 25
25 8 36 63 17 26
50 8 34 63 17 26
100 13 31 71 15 29
300 33 29 102 08 43
600 61 30 141 03 64
Lsd5 5 5 8 02 05
Sig6
1 After Colwell (1963) 2 After Allen and Jeffery (1990) 3 Phosphorus retention index (Allen and Jeffery 1990) 4 Predicted phosphorus retention index (Allen and Jeffery 1990) 5 Least significant difference at P ^ 005 6 Significance at lt 0001 () lt 001 () lt 005 () level or not significant (ns)
The use of Red Mudgypsum in vegetable production
100
o CO
gtlaquo
C
o CO
bull-raquo
c o o o
20 40 60 80 100 120 140
Residual AG (tha) 0 100 200 300 400 500 600 700
Residual P (kgha)
Figure 63 (A B) Bicarbonate extractable P (bull) K (bull) and total P (A) in the subsoil (0-15 cm) of a yellow Karrakatta sand after harvest of cauliflowers with level of residual Alkaloamreggypsum (t AGha) (A) and P (kgha) (B) Vertical bars refer to Lsd (P lt 005) for difference between level of AG or P Lsd not shown when less than size of symbol
Ec pH (CaCl2) and exchangeable Ca and Na in the top and subsoil after harvest increased significantly with level of residual AG whilst there was no change in exchangeable Mg (Table 64 (a) (b)) Whilst there was no change in exchangeable K with level of residual AG in the topsoil there was a significant increase in exchangeable K in the subsoil (Table 64 (b))
70
The use of Red Mudgypsum in vegetable production
Table 64 Ec (mSm) pH (CaCl2) and exchangeable cations (me) in topsoil (0-15 cm) and subsoil (15-30 cm) of a yellow Karrakatta sand with level of residual AIkaloamreggypsum (AG) and phosphorus (P) after harvest of cauliflowers
(a) Topsoil (0-15 cm)
AG
AG Ec pH Ca1 Mg1 K1 Na1
(tha) (mSm) (CaCl2) (me) (me) (me) (me)
0 29 65 24 027 006 004
60 47 73 32 025 009 010
90 59 77 36 023 015 015
120 66 78 40 025 012 018
Lsd2 07 07 06 005 006 001
Sig3 as ns
P (kgha)
Ec (mSm)
PH (CaCl2)
Ca1
(me) Mg1
(me) K1
(me) Na1
(me)
0 43 73 30 025 001 011
25 46 73 33 026 010 011
50 46 73 32 025 010 011
100 52 74 32 025 010 011
300 56 74 34 024 009 011
600 58 73 37 025 014 012
Lsd2 05 05 03 002 007 -
Sig3 ns ns ns
Exchangeable in 1 m NILt-Cl 2 Least significant difference at P ^ 005 3 Significance at lt 0001 () lt 001 () lt 005 () level or not significant (ns)
The use of Red Mudgypsum in vegetable production
soil b
A soil
dry
4 _ I dry
I ^5 CD CD
b_ 3 - E c c o o CO at
i
U o CD CD
Xgt j a CO bull| mdash CO CD ogt
m- mdashM- mmdash JZ 0 - +~ -- mdash c CJ o X X LU
i 1 I i i i i LU
0 20 40 60 80 100 120 1^ W
Residual AG (tha)
100 200 300 400 500 600 700
Residual P (kgha)
Figure 64 (A B) Exchangeable Ca (bull) Mg (bull) K (A) and Na ( bull ) (me) in the topsoil (0-15 cm) of a yellow Karrakatta sand with level of residual Alkaloamreggypsum (t AGha) or P (kgha) Vertical bars refers to Lsd (P lt 005) for differences in concentration between levels of AG or P Lsd not shown when less than size of symbol
72
The use of Red Mudgypsum in vegetable production
Table 64 Ec (mSm) pH (CaCl2) and exchangeable cations (me) in topsoil (0-15 cm) and subsoil (15-30 cm) of a yellow Karrakatta sand with level of residual AlkaIoamreggypsum (AG) and phosphorus (P) after harvest of cauliflowers
(b) Subsoil (15-30 cm)
AG
AG Ec pH Ca1 Mg1 K1 Na1
(tha) (mSm) (CaCl2) (me) (me) (me) (me)
0 34 66 24 026 006 005
60 50 75 33 024 008 010
90 64 78 38 023 01 016
120 68 79 41 024 01 019
Lsd2 05 01 07 006 001 003
Sig3 ns
P (kgha)
Ec (mSm)
pH (CaCl2)
Ca1
(me) Mg1
(me) K1
(me) Na1
(me)
0 48 75 30 023 009 011
25 51 74 33 026 009 011
50 50 75 34 025 008 013
100 61 75 35 026 008 013
300 57 75 34 022 007 013
600 58 73 38 024 008 013
Lsd2 08 01 04 003 001 003
Sig3 ns
1 Exchangeable in 1 m NH4-CI 2 Least significant difference at P ^ 005 3 Significance at lt 0001 () lt 001 () lt 005 () level or not significant (ns)
The use of Red Mudgypsum in vegetable production
o 0 oi
4 CO c CO
gt T3 4 _ bull o
0s -5 3 agt CD
fc_ 3 - g
on
o 2 CO 2 CO
u 2
o CD CD 1 X I SI
1 CD 1 CD CD CU
O
n ^ 1 CO n X bull mdashXmdash mdash 1 1 CO U J= n bull - w 1 CO U
o o X X Lil
i i 1 1 i i 1 HI
0 20 40 60 80 100 120 140
Residual AG (tha)
100 200 300 400 500 600 700
Residual P (kgha)
Figure 64 (C D) Exchangeable Ca (bull) Mg (bull) K (A) and Na (T) (me) in the subsoil (0-15 cm) of a yellow Karrakatta sand with level of residual Alkaloamreggypsum (t AGha) or P (kgha) Vertical bars refers to Lsd (P lt 005) for differences in concentration between levels of AG or P Lsd not shown when less than size of symbol
As level of residual P increased there was a significant increase in exchangeable Ca in the tbpsoil and subsoil but no significant effect on exchangeable Mg K and Na in the topsoil and variable effects on exchangeable Mg and K in the subsoil Ec increased significantly with level of residual P in both the top and subsoil whilst pH in either was effected little by level of applied P
The effect of level of residual AG andP on the concentration of nutrients in cauliflower leaves
The level of residual AG had no effect on the concentrations of N Ca S P S Mg Fe Zn Mn B and Cu in the youngest mature leaves of cauliflowers at buttoning but increased levels significantly reduced the concentration of K (Fig 65 (A B)) As level of residual P increased there was a significant increase in the concentration of K P S Cu and Mn in the YMLs whilst concentrations of N decreased and B concentrations were variable with no clear trends
74
The use of Red Mudgypsum in vegetable production
Table 65 Concentration of nutrients (dry weight basis) in youngest mature leaves of cauliflowers at buttoning with level of applied residual Alkaloamreggypsum (AG) and phosphorus (P)
(a) Macronutrients
AG
AG N1 K1 Ca2 S2 P1 Na2 Mg2
(tha) () () () () () () ()
0 49 42 23 077 040 039 027
60 51 40 23 078 042 036 025
90 51 39 23 079 043 036 025
120 49 39 24 078 042 036 025
Lsd3 03 02 08 009 007 010 004
Sig4 ns ns ns ns ns ns
P N1 K1 Ca2 S2 P1 Na2 Mg2
(kgha) () () () () () () ()
0 53 36 22 069 027 033 024
25 51 38 24 071 030 038 026
50 52 40 24 075 034 040 027
100 51 41 24 079 043 041 027
300 48 43 24 087 055 039 026
600 47 42 20 086 060 031 023
Lsd3 02 02 04 003 004 006 003
Sig4 ns ns
1 After Varley (1966) 2 After McQuakerefl (1979) 3 Least significant difference at P lt 005 4 Significance at lt 0001 () lt 001 () lt 005 () level or not significant (ns)
The use of Red Mudgypsum in vegetable production
Table 65 Concentration of nutrients (dry weight basis) in youngest mature leaves of cauliflowers at buttoning with level of applied residual AlkaIoamreggypsum (AG) and phosphorus (P)
(b) Micronutrients
AG
AG (tha)
Fe (ugg)
Zn1
(Pgg) Mn1
(ugg) B1
(ugg) Cu1
(ugg)
0 122 31 19 21 28
60 121 32 22 22 30
90 119 36 25 22 32
120 120 29 23 22 29
Lsd2 21 8 6 1 05
sig3 ns ns ns ns ns
P (kgha)
Fe1
(Pgg)
Zn1
(ugg) Mn1
Gigg)
B1
(Fgg)
Cu1
(Pgg)
0 112 33 19 22 28
25 120 32 22 22 29
50 125 32 21 23 29
100 132 38 24 23 31
300 129 30 25 22 32
600 106 29 23 21 32
Lsd2 19 6 3 1 03
Sig-3 ns ns
After McQuaker et al (1979) 2 Least significant difference at P ^ 005 3 Significance at lt 0001 () lt 001 () lt 005 () level or not significant (ns)
The relationship between residual P ie Colwell P and P in YMLs at buttoning were best described by Mitscherlich relationships at all levels of residual AG (Fig 65)
The concentration of P in YMLs corresponding to levels of Colwell P necessary for 95 of maximum yield were 047 050 054 and 048 and for 99 of maximum yield were 053 055 058 and 054 for 0 60 90 and 1201 residual AGha respectively
76
The use of Red Mudgypsum in vegetable production
Q
en
3
gt-c 0
07
06
05
04
03
02
01 0
065
060
055
050
045
040
035
030
025
020
A
if 20 40 60 80 100
Colwell P (ugg dry soil)
_ 065
Q S 055
060
tz
ro _ i
gt
120
C bull - - - mdash bull
20 40 60 80 100
Colwell P (ugg dry soil)
120
050
045
040
035
030
025
020
065
060
055
050
045
040
035
030
025
020
-B
bull
- bull I
I I
bull
i i i
20 40 60 80 100
Colwell P (ugg dry soil)
120
-bull D
I I i i i
20 40 60 80 100
Colwell P (ugg dry soil)
120
Figure 65 P in youngest mature leaves at buttoning () corresponding to Colwell P necessary for 95 (dashed) or 99 (whole) of maximum yield at 0 (A) 60 (B) 90 (C) and 120 (D) t of residual Alkaloamreggypsumha Dashed and whole horizontal lines refers to P in YML corresponding to Colwell P required for 95 and 99 of maximum yield respectively
The equations for the fitted lines are
A y = 05964 - 0763 x exp (-0068) (B2 = 089)
B y = 05855 - 05144 x exp (-00465x) (R2 = 098)
C y = 006058 - 0549 x exp (-00435x) (B2 = 096)
D y = 06399 - 05208 x exp (-00291) (R2 = 097)
77
The use of Red Mudgypsum in vegetable production
The effect of level of residual AG andP on the yield of cauliflowers
There was no significant effect of levels of residual AG on the total or marketable yield of cauliflowers However yield responded significantly to levels of applied residual P and the interaction between residual P and AG was significant (Tables 66 (a) (b))
The relationship between Colwell P and total yield was best described by Mitscherlich relationships for all levels of residual AG (Fig 66) The Colwell P required for 95 of maximum total yield was 26 40 48 and 40 ugg dry soil and for 99 35 55 71 and 58 ugg dry soil for 0 60 90 and 1201 residual AGha respectively
Table 66 Curd yield (total and marketable) of cauliflowers (tha) at harvest with level of residual Alkaloamreggypsum (AG) and phosphorus (P)
(a) Total
AG p
(kgha) (tha) p
(kgha)
0 60 90 120
0 59 64 69 100
25 134 126 123 83
50 139 133 117 143
100 163 200 164 177
300 203 236 198 204
600 215 237 208 194
Ls-d1 36 (AG) 17 (P) 48(AGP) -
Sig2 ns
(b) Marketable
p (kgha)
AG (tha) p
(kgha)
0 60 90 120
0 14 14 18 56
25 83 74 84 13
50 90 99 67 99
100 138 188 125 160
300 187 232 182 190
600 206 234 191 185
Lsd1
Sig2
48 (AG)
ns 23 (P)
62(AGP)
-
Least significant difference at P lt 005 2 Significance at lt 0001 () lt 001 () lt 005 () level or not significant (ns)
The use of Red Mudgypsum in vegetable production
0 20 40 60 80 100120140160
Colwell P (ugg dry soil)
0 20 40 60 80 100120140160
Colwell P (ugg dry soil)
lt x
UJ gt-Q
o
lt X
Q _ l UJ gt-Q rr D O
24
22
20
18
16 14
12
10
8
6
4
-D
bull
I I
I I
I I
I
^~ bull
i i i i i
20 40 60 80 100120140160
Colwell P (ugg dry soil)
20 40 60 80 100120140160
Colwell P (ugg dry soil)
Figure 66 Colwell P in topsoil (0-15 cm) at planting versus yield of cauliflowers at 0 (A) 60 (B) 90 (C) and 120 (D) tha of residual Alkaloamreggypsum (AG) Dashed and whole vertical lines represent Colwell P required for 95 and 99 of maximum yield respectively
The equations for the fitted lines are
A y = 2088 - 818 x exp (-017x) (i2 = 089)
B y = 23731 - 4578 x exp (-00949) (i2 = 099)
C y = 2051 - 286 x exp (-00697) (R2 = 086)
D y = 2002 - 354 x exp (-0090) (B2 = 086)
79
The use of Red Mudgypsum in vegetable production
Discussion
There was no significant reduction in maximum yield (ie A values) of cauliflower (cv Plana) curds grown on Karrakatta sands amended with residual AG from 0 to 120 tha in this work This is in contrast to previous work (Robertson et al 1994) in which maximum curd yields of cauliflowers were significantly reduced with levels of residual AG at 120 tha compared with 0 and 60 tha In both studies concentrations of K were reduced and concentrations of Na were increased in the YML at buttoning with increasing levels of residual AG The increase in concentration of Na and the decrease in concentration of K in the YML with level of applied AG was related to similar changes in the concentrations of these elements in the soil solution with both freshly-applied (Section 5) and residual AG one month after planting As with freshly-applied AG increasing levels of residual AG resulted in increasing levels of Na in the soil (exchangeable) or soil solution however whilst K concentrations in soil solution decreased the K retained by the soil measured as either Colwell K or exchangeable K increased Increasing levels of residual AG resulted in increased pH in the topsoil as with fresh AG but this did not reduce the concentration of Mn Cu and Zn in the YML or increase the concentration of Mo These changes would be expected with increases in soil pH (Porter 1984) The level of Colwell P required for 95 to 99 of maximum yield increased from 26 and 35 ugg dry soil at 01 AGha to 48 and 71 ugg at 901 of residual AGha The level at 1201 AGha was slightly lower ie 40 and 58 ugg These levels are similar to those reported as necessary for 95 and 99 of maximum yield of Arfak cauliflowers 40 and 55 ugg Colwell P in planted in autumn and spring on unamended Karrakatta sands (McPharlin et al 1995) It therefore does not appear that AG amendment increases the residual P as measured by Colwell P requirement of cauliflower significantly This is in contrast to the significantly higher level of applied P necessary to maximise yield when AG is freshly-applied ie from 120-160 to gt 300 kg of Pha at 0 and 1201 AGha respectively (Robertson et al 1994 and Section 5) However requirements of residual (Colwell) P and freshly-applied P are not always correlated For example the Colwell P necessary for the maximum yield of spring and winter-planted lettuce was similar ie 80 to 120 ugg dry soil whereas the level of freshly-applied P required for maximum yield of winter-planted lettuce was 50 higher than in spring (McPharlin et al 1996 McPharlin and Robertson 1997)
References
Allen DG and Jeffery RC (1990) Methods for analysis of phosphorus in Western Australian soils Chemistry Centre of Western Australia Report of Investigation No 37
Barrow NJ (1982) Possibility of using caustic residue from bauxite for improving the chemical and physical properties of sandy soils Australian Journal of Experimental Agriculture Research 33 275-285
Colwell JD (1963) The estimation of phosphorus fertiliser requirements of wheat in southern New South Wales by soil analysis Australian Journal of Experimental Agriculture Animal Husbandry 3 190-197
Gillman GP and Sumpter EA (1986) Modification to the compulsive exchange method for measuring exchange characteristics of soils Australian Journal of Soil Research 24 616
McArthur WM and Bettenay E (1960) The development and distribution of the soils of the Swan Coastal Plain Western Australia CSIRO Division of Soils Soils Publication No 16
McPharlin IR Jeffery RC and Pitman DH (1996) Phosphorus requirements of winter planted lettuce (Lactuca sativa L) on a Karrakatta sand and the residual value of phosphate as determined by soil test Australian Journal Experimental Agriculture 36 887-903
80
The use of Red Mudgypsum in vegetable production
McPharlin IR Jeffery RC and Weissberg R (1994) Determination of the residual value of phosphate and soil test phosphorus calibration for carrots on a Karrakatta sand Communications in Soil Science Plant Analysis 25 (5-6) 489-500
McPharlin IR and Robertson WJ (1997) Response of spring-planted lettuce (Lactuca sativa L) to freshly-applied and residual phosphorus and to phosphate fertiliser placement on a Karrakatta sand Australian Journal of Experimental Agriculture (in press)
McPharlin IR Robertson WJ Jeffery RC and Weissberg R (1995) Response of cauliflower to phosphate fertiliser placement and soil test phosphorus calibration on a Karrakatta sand Communications in Soil Science and Plant Analysis 26(3-4) 607-620
McQuaker NR Brown DF and Kluckner PD (1979) Digestion of environmental materials for analysis by inductively coupled plasma-atomic emission spectrometry Analytical Chemistry 51 1082-1084
Novoa R and Loomis RS (1981) Nitrogen and plant production Plant and soil 58 177-204
Ozanne PG and Shaw TC (1968) Advantages of recently developed phosphate sorption test over the older extractant methods for soil phosphate (ed JW Holmes) pp 273-280 In Transactions of the 9th International Congress of Soil Science Volume 2 Angus and Robertson Sydney Australia
Porter WM (1984) Soil acidity Agriculture Western Australia Farmnote No 6884
Robertson WJ McPharlin IR and Jeffery RC (14) Final report of investigation into the use of gypsum-amended Red Mud as a soil-amendment on horticultural properties on the Swan Coastal Plain Report to HRDC (Project No V0039RO) Department of Agriculture Western Australia
Varley J A 1966 Automatic methods for the determination of nitrogen phosphorus and potassium in plant material Analyst 91 119-126
Vlahos S Summers KJ Bell DT and Gilkes RJ (1989) Reducing phosphorus leaching from sandy soils with Red Mud bauxite processing residues Australian Journal of Soil Research 27 651-662
Yuen SH and Pollard AG (1954) Determination of nitrogen in agricultural material by the Nessler reagent IL Microdetermination in plant tissue and soil extracts Journal of Science Food Agriculture 5 364-369
The use of Red Mudgypsum in vegetable production
7 RETENTION LEACHING AND RECOVERY OF P AND OTHER NUTRIENTS BY CARROTS GROWN ON A JOEL SAND AMENDED WITH RESIDUAL RED MUD (ALKALOAMreg)GYPSUM (AG) IN LARGE POTS
Introduction
It is difficult to quantify the retention of P by sands amended with Red Mud (Alkaloamreg)gypsum (AG) in the field because of native P in the soil and soluble P in the AG (Robertson et al 1994) It is easy to quantify leaching of P and other nutrients such as N and K from AG amended sands in pots or columns by collecting leachate and measuring concentration (McPharlin et al 1995) However plants were not grown in the columns used by McPharlin et al so there was no measurement of plant uptake of P and other nutrients to complete the nutrient budget Potatoes were grown successfully in Spearwood sands in large pots (70 L) and a complete N budget (N applied N retained by soil N leached and uptake by plant) determined (Hegney et al 1996)
Freshly-applied AG may not be in equilibrium with the soil to which it is applied ie the pH Ec and concentrations of elements such as Ca and Na may change rapidly with time The age of the AG may effect its capacity to retain P on amended soils AG may improve the retention of other nutrients such as ammonium N (McPharlin et al 1995) and K (Sections 5 and 6) by amended sands AG which has been applied to sands in the field for at least 2 to 5 years should be close to equilibrium with the soil as substantial leaching would have occurred AG of this age would give the best estimate of its long term capacity to reduce leaching of P and other nutrients from poor grey sands on the Swan Coastal Plain The purpose of this work was to quantify the leaching and retention of P and other nutrients (N Ca K etc) from Joel sands which had been amended with AG at different levels in the field for 14 years Carrots a major vegetable crop grown on the Swan Coastal Plain were used as the experimental crop and grown in these AG amended sands in large pots
Materials and methods
Pots
Fibreglass pots used for the experiment were 45 cm in diameter and 50 cm deep The area of soil surface was 016 m2 and the volume was 70 L The bottom of the pots tapered to a hole (diameter) to which was attached a polyethylene hose (length and diameter) and tap The pots were painted white to reduce heat The pots were placed on a metal table (with mesh tops) and the hose passed through a hole in the centre of a lid of a plastic (20 L) bucket
Experimental design
The experimental design was a 4 (levels of residual AG ie 0 125 250 and 1000 tha) times 5 (levels of applied P ie 0 50 100 200 and 400 kgha) factorial in a randomised block with 3 replicates The level of applied AG or Pha was calculated using the area of the soil surface The total number of pots was 60
Soil and Red Mud (Alkaloamreg)gypsum (AG)
Virgin Joel sand was obtained from a commercial garden supply site in Jandakot The top 20 cm of the soil was removed and the rest sieved (15 mm) to remove debris About 20 kg of Joel sand was added to each pot (10 cm depth) Another 60 kg (30 cm depth) of sand was added to the 0 AGha pots to which had been mixed lime and preplant fertilisers (see later) so the surface of the soil was about 10 cm below the top edge of the pot AG amended sand was obtained from a field site in Hope Valley Road Kwinana managed by ALCOA where it had been applied (and incorporated using a rotary hoe) to pastures growing on a Joel sand in 1983 at 0 250 500 and 1000 tha This AG amended sand was added to pots corresponding to 250 and 1000 tha in the field after the preplant fertiliser but not lime was added and was incorporated to a similar depth as in the 01 AGha pots The 125 t AGha treatment was
82
The use of Red Mudgypsum in vegetable production
obtained by mixing AG amended sand from the 250 tha field site with an equal weight of Joel sand in a cement mixer
Fertilisers and lime
The following fertilisers (in kgha) were thoroughly mixed (using a cement mixer) with the top 25-30 cm of the soil in each pot before planting Urea (108) K2SO4Q2I) MgS047H20 (100) MnS04H20 (100) Na2B4O710 H20 (50) FeS047H20 (50) CuS045H20 (50) ZnS04H20 (50) and NaMo042H20 (4) To this was added P at 0 50 100 200 and 400 kgha as single superphosphate at each level of residual AG Hydrated lime (Ca (OH)2) was mixed with the preplanting fertilisers on the 0 kg AGha treatment at 36 gpot
N K and Ca were fertigated via the drip irrigation system at 200 200 and 52 mgL using KNO3 NH4NO3 and Ca (N03)2 from immediately after sowing to 140 days after sowing (18 August 1996) MgS047H20 was broadcast at 100 kgha to each pot at weeks 6 and 12
Irrigation
The plants were irrigated using drippers (Netafim 2 Lh pressure compensated with 4 equalisers per pot) at 15 times the average monthly pan evaporation until 160 days after sowing (7 September 1996) Adjustments were made on a daily basis if evaporation was significantly higher or lower than the long term average (Table 71)
Table 71 Irrigation requirements of carrots in pot experiments
Month DAS Lpotday Minutesday
April 1- 27 10 33
May 28- 59 065 21
June 60- 90 044 14
July 91-122 044 14
August 123-154 056 19
September 155-160
Adjusted for 90 efficiency of irrigation system
Rain was excluded from the pots using a movable rain out shelter made of perspex and aluminium This was removed at all other times
Crop management
The soil in each pot was irrigated to field capacity ie so that free drainage occurred Carrot (cv Top Pak) seeds were sown on a 9 x 9 cm spacing and 1 cm deep with 5 seeds per site on 3 April 1996 These were thinned to 14 seedlingspot (88 plantsm2) after emergence (15 April 1996) No application of fungicides or insecticides were necessary
Soil and plant measurements
Soil
Immediately before fertilising and sowing 5 cores (22 diameter x 15 cm deep) were taken from each pot and dried in a force draught oven at 40degC Each sample was analysed for extractable P and K (Colwell 1963) pH (CaCl2 and H20) total P (Allen and Jeffery 1990) PRI (Allen and Jeffery 1990) total N extractable ammonium N (KC1) extractable nitrate N (KC1) organic carbon cation exchange capacity and exchangeable cations
83
The use of Red Mudgypsum in vegetable production
Leachate
Leachate from each pot was collected in 20 L plastic buckets under the pots each week from the 4 April 1996 to 22 July 1996 PMA (phenyl mercuric acetate) was added to the leachate to prevent contamination Total water volume was measured and sub-samples (200 mL) collected and submitted for analysis of P NH4-N NO3-N K Na Ca S Mg Ec and pH analysis of concentration The quantities leached of the above elements in kgha were calculated from concentration and volume of leachate collected and surface area of soil in pot
Harvest
The plants were harvested on 7 September 1997 and the total marketable and reject root yield determined for each plot
Analysis of data
Analysis of variance (Genstattrade for Windows version 32) was carried out on level of AG and P versus yield (total marketable reject) level of chemical factors in soil after harvest concentration of nutrients in youngest mature leaves at midgrowth tops and roots at harvest and leachate on 22 April 1996 5 May 1996 and 22 July 1996 and quantities of elements leached at each sampling time
Mitscherlich or linear relationships were fitted to level of P versus yield (total) at each level of residual AG P required for 95 and 99 of maximum yield was delivered at each level of residual AG P uptake by carrots was determined from the dry weight and P in tops and roots for each treatment Fertiliser P uptake was determined by deducting uptake on 0 kg Pha treatments at each level of applied AG Fertiliser P retained in the top-soil was determined from the concentration of total P and bulk density P leached was fertiliser leached below 15 cm The P in each plant fraction soil and leached was determine at each level of applied P and AG
Results
Effect of level of residual AG on chemical characteristics of Joel sand
Soil pH (CaCl2 H20) Ec Colwell P phosphorus retention index cation exchange capacity exchangeable Ca and Na and silt and clay all increased with level of residual AG in the top soil (0-15 cm) of a Joel sand before fertilising and sowing (Table 72)
The use of Red Mudgypsum in vegetable production
Table 72 Chemical and physical characteristics of Joel sand amended with residual Alkaloam gypsum (AG) in pots before fertilising and sowing of carrots
Level of residual AG
Parameter (tha)
Parameter
0 125 250 1000
pH (H20) 69 77 85 86
pH (CaCl2) 57 71 78 78
Ec (mSm) 4 9 9 11
Ext P (ngg)1 3 9 14 9
PRI2 -02 33 44 77
Total N ()3 - 0039 0044 0060
ExtNH4-N(ngg)4 - 2 2 2
ExtN03-N(ugg)5 - 3 2 5
CEC ()6 30 30 43 35
Exch Ca ()7 133 363 51 70
Exch Mg ()7 036 024 015 021
Exch Na ()7 005 015 015 032
Exch K ()7 007 004 0035 0035
OrgC()8 131 109 092 103
Sand () 977 967 960 910
Silt () 13 15 15 37
Clay () 10 23 25 53
1 Colwell (1963) 2 Phosphorus retention index (Allen and Jeffery 1990) 3 KjeldahlReardon et al 1966 4 Extracted in 1 m KC1 (Reardon et al 1966) 5 Extracted in 1 m KC1 (Best 1976) 6 Gillman and Sumpter (1986) 7 Exchangeable in 1 m NHU-Cl 8 Walkley and Black (1934)
Level of residual AG had no effect on levels of extractable NH4-N NO3-N exchangeable Mg and K or organic carbon After harvest levels of Colwell P K total P PRI Ec pH (CaCk) exchangeable Ca Mg K and Na in the topsoil (0-15 cm) all increase significantly (P lt 005) with level of residual AG (Tables 73 74)
85
The use of Red Mudgypsum in vegetable production
Table 73 Extractable P K NH4 total P (tot P) and phosphorus retention index (PRI) of the topsoil (0-15 cm) of a Joel sand after harvest of carrots with level of residual Alkaloamreggypsum (AG) and phosphorus (P)
AG
AG BicP1 BicK tot P2 PRI3 NIL (tha) (ngg) (Hgg) (ngg) (mLg) (Mfig)
0 33 119 234 -015 137
125 200 117 743 141 27
250 275 197 1258 231 19
1000 204 420 1853 154 30
Lsd5 4 34 129 45 26
Sig6
P
P (kgha)
BicP1
(ngg) BicK1
(Mgfe) totP2
(ugg) PRI3
(mLg) NIL
(ngg)
0 91 215 896 198 58
50 151 223 937 138 54
100 144 226 1005 126 62
200 182 193 1043 128 42
400 323 210 1231 116 52
Lsd5 48 39 144 50 29
Sig6 s | e ns ns
1 Colwell 1963 2 Allen and Jeffery 1990 3 Phosphorus retention index (Allen and Jeffery 1990) 4 Extracted in 1 m KC1 (Best 1976) 5 Least significant difference at P s 005 6 Significance at lt 0001 () lt 001 () lt 005 () level or not significant (ns)
By contrast levels of extractable NH4-N decreased significantly with level of residual AG Colwell P total P Colwell K all increased significantly (P lt 005) with level of applied P whilst PRI was decreased significantly Level of applied P had no significant effect on Ec pH or level of exchangeable Ca Mg K Na Colwell K or extractable NHu-N in the topsoil after harvest (Tables 73 74)
The use of Red Mudgypsum in vegetable production
Table 74 Ec (mSm) pH (CaCl2) and exchangeable cations (me) in topsoil (0-15 cm) of a Joel sand after harvest of carrots with level of residual Alkaloamreggypsum (AG) and phosphorus (P)
AG
AG Ec pH Ca1 Mg1 K1 Na1
(tha) (mSm) (CaCl2) (me) (me) (me) (me)
0 157 44 18 016 026 010
125 147 54 23 014 026 015
250 217 66 40 017 041 027
1000 308 76 135 027 096 094
Lsd2 32 01 07 002 005 005
sig3
p
p (kgha)
Ec (mSm)
pH (CaCl2)
Ca1
(me) Mg1
(me) K1
(me) Na1
(me)
0 202 59 52 019 048 035
50 195 60 53 018 050 036
100 203 60 57 019 048 039
200 202 60 57 018 045 040
400 236 59 51 017 046 034
Lsd2 35 01 08 002 006 005
Sig3 ns ns ns ns ns ns
Exchangeable in 1 m NH4CI 2 Least significant difference at P s 005 3 Significance at lt 0001 () lt 001 () lt 005 () level or not significant (ns)
Effect of level of residual AG and P on concentration of nutrients in leachate and quantities of nutrients leached
There was a significant (P lt 005) reduction in concentration of P in leachate with level of residual AG at three times of sampling (Fig 71) P concentration in leachate increased significantly with level of applied P at 01 AGha but not in presence of AG
P concentration in leachate at 01 AGha decreased with time from 80 mgL on 16 April 1996 at 400 kg Pha to 025 mgL on 22 July 1996 To reduce P concentration in leachate 125 t AGha was as effective as 250 or 1000 tha at all sampling times and levels of applied P Similar trends were shown in quantity of leached P as total or soluble reactive P in kgha (Appendix 71 (b) 72) Level of applied AG significantly (P lt 005) reduced the concentration of NH4-N in leachate from 40 mgL at 01 AGha to 15 mgL at 250 and 1000 tha (Fig 72 (a)) on 16 April 1996 Significant reductions in concentration were recorded on the other two sampling times as NH4-N concentration declined with increased plant uptake Similar trends were shown in the quantity of NH4-N leached with level of AG (Appendix 72 (b)) By contrast level of applied AG had no significant effect on concentration of NO3-N in leachate or quantity leached at any of the three sampling times (Fig 72 (b) and Appendix 73 (b)) There was a significant (P lt 005) reduction in concentration of K in leachate and quantity of K leached with level of residual AG although the reduction was less at the later sampling times (Fig 73 Appendix 73 (a)) Concentration of K in leachate increased
87
The use of Red Mudgypsum in vegetable production
with time at all levels of residual AG except 1000 tha By contrast both the concentration of Na in leachate and quantity of Na increased with level of residual AG to a maximum at the highest level (1000 tha) There was a reduction in Na concentration in leachate with time at level of residual AG lt 1000 tha The concentration of Ca in leachate increased significantly (P lt 005) as did quantity leached with level of residual AG and with time at all levels of AG (Fig 74 Appendix 74 (a)) By contrast concentration of Mg in leachate and quantity leached decreased significantly (P lt 005) with level of residual AG and with time at all levels of AG (Fig 78 and Appendix 78 (a)) There was a significant (P lt 005) increase in S concentration in leachate and quantity leached with level of residual AG at the first sampling time a decrease at the second and a increase up to 250 tha at the third sampling (Fig 79 Appendix 79 (a)) S concentration in leachate and quantity leached varied significantly with level of applied P at all sampling times and decreased with time from 16 April 1996 to 22 July 1996 (Fig 79 and Appendix 79 (a))
The use of Red Mudgypsum in vegetable production
deg E
c o
o O
c ltD
O
c o
I O
1 0 0 2 0 0 3 0 0 4 0 0
A p p l i e d P ( k g h a )
5 0 0
1 0 0 2 0 0
A p p l ie d P
3 0 0
k g h a )
4 0 0 5 0 0
1 0 0 2 0 0 3 0 0
A p p l i e d P ( k g h a
4 0 0 5 0 0
Figure 71 Concentration of P (mgL of total P) in leachate from Joel sands sown to carrots with level of applied P and Alkaloamreggypsum (AG) at 0 (bull) 125 (bull) 250 (A) and 1000 (T) tha on 16 April 1996 (A) 6 May 1996 (B) and 22 July 1996 (C) P was applied preplanting as superphosphate and carrots were sown on 3 April 1996 Vertical bars refer to Lsd (P lt 005) for differences in concentration between level of AG (at each level of P) or P (at each level of AG) or the interaction between AG and P Where bars arent shown Lsd is less than size of symbol
89
The use of Red Mudgypsum in vegetable production
2 0 0 4 0 0 6 0 0 8 0 0 1 0 0 0 1 2 0 0
L e v e l o f r e s i d u a A G ( t ha )
2 0 0 4 0 0 6 0 0 8 0 0 1 0 0 0 1 2 0 0
L e v e l o f r e s i d u a l A G ( t h a )
Figure 72 Concentration (mgL) of NBU-N (A) and NO3-N (B) in leachate from Joel sand sown to carrots amended with residual AlkaIoamreggypsum (AG) in pots on 16 April 1996 (bull) 6 May 1996 (bull) and 22 July 1996 (A) The carrots were sown on 3 April 1996 N was fertigated at a constant concentration of 300 mgL (250 mgL of NO3-N and 50 mgL NH4-N) from sowing to harvest Vertical bars refer to Lsd (P lt 005) for differences in concentration between level of AG at each sampling time Where bars arent shown Lsd is less than size of symbol
The use of Red Mudgypsum in vegetable production
200 400 600 800 1000 1200
Level of AG (tha)
200 400 600 800
Level of AG (tha)
1 0 0 0 1 2 0 0
Figure 73 Concentration (mgL) of K (A) and Na (B) in leachate from Joel sand sown to carrots amended with residual Alkaloamreggypsum (AG) in pots on 16 April 1996 (bull) 6 May 1996 (bull) and 22 July 1996 (A) The carrots were sown on 3 April 1996 K was fertigated at a constant concentration of 200 mgL from sowing to harvest Vertical bars refer to Lsd (P lt 005) for differences in concentration between level of AG at each time Where bars arent shown Lsd is less than size of symbol
91
The use of Red Mudgypsum in vegetable production
Effect of level of residual AG and P on concentration of nutrients in plants The concentration of K P Fe Cu Mn and Mo in the youngest mature leaves (YML) of carrots at midgrowth all increased significantly with level of residual AG (Tables 75 (a) (b)) The concentration of S in YML at midgrowth was significantly reduced as level of residual AG increased whilst concentrations of Ca Na Mg Zn and B were variable
Table 75 Concentration of nutrients ( dry basis) in youngest mature leaves of carrot at midgrowth with level of residual Alkaloamreggypsum (AG) and phosphorus (P)
(a) Macronutrients
AG
AG (tha)
K1 Ca2 S2 P1 Na2 Mg2
0 486 229 061 025 050 039
125 584 186 060 033 047 034
250 585 216 058 033 044 035
1000 531 215 056 031 052 037
Lsd3 03 02 004 0017 005 003
Sig4
p
P (kgha)
K1 Ca2 S2 P1 Na2 Mg2
0 538 198 062 029 037 036
50 523 222 061 028 043 037
100 562 208 056 030 049 035
200 548 216 057 032 058 037
400 563 214 056 035 054 036
Lsd3 033 022 004 002 006 003
Sig4 ns ns ns
1 After Varley (1966) 2 After McQuaker et al (1979) 3 Least significant difference at P s 005 4 Significance at lt 0001 () lt 001 () lt 005 () level or not significant (ns)
The use of Red Mudgypsum in vegetable production
Table 75 Concentration of nutrients ( dry basis) in youngest mature leaves of carrot at midgrowth with level of residual Alkaloam gypsum (AG) and phosphorus (P)
(b) Micronutrients
AG
AG (tha)
Fe Mn1 Zn B Cu Mo
0 111 386 280 345 95 21
125 127 279 367 348 107 25
250 126 173 269 349 108 24
1000 114 60 143 337 110 31
Lsd2 20 47 40 15 05 06
Sig3 ns ns
p
p (kgha) Fe Mn Zn B Cu Mo1
0 135 243 263 356 120 28
50 122 240 268 349 111 30
100 109 191 229 343 106 25
200 116 228 268 334 99 23
400 115 221 294 341 89 20
Lsd2 23 52 45 15 051 07
Sig3 ns ns ns ns
1 After McQuaker et al (1979) 2 Least significant difference at P s 005 3 Significance at lt 0001 () lt 001 () lt 005 () level or not significant (ns)
Concentration of P S and Na in YML increased significantly (P lt 005) with level of applied P whilst concentrations of Cu and Mo decreased (Tables 75 (a) (b)) By contrast concentrations of K Ca Mg Fe Mn Zn and B were not significantly changed by level of applied P
93
The use of Red Mudgypsum in vegetable production
At harvest the concentration of P N K and Fe in whole tops increased significantly (P lt 005) with level of residual AG whilst concentration of S Mn Zn and B decreased (Table 76) The concentrations of Ca Na and Mg were variable with level of residual AG whilst there was no significant effect on the concentration of Cu
Table 76 Concentration of nutrients ( dry basis) in whole carrot tops at harvest with level of residual Alkaloamreggypsum (AG) and phosphorus (P)
(a) Macronutrients
AG
AG (tha)
N1 K1 Ca2 S2 P1 Na2 Mg2
0 300 503 269 071 016 093 039
125 348 649 239 065 024 090 035
250 395 653 251 061 022 082 033
1000 351 566 262 066 024 099 037
Lsd3 010 036 011 002 001 009 002
Sig4
p
p (kgha)
N1 K1 Ca2 S2 P1 Na2 Mg2
0 355 589 240 073 019 074 035
50 343 597 258 068 020 082 036
100 339 587 257 068 021 098 038
200 339 580 259 063 022 108 037
400 332 608 263 057 024 095 036
Lsd3 011 041 012 002 001 010 002
Sig4 ns
1 After Varley (1966) 2 After McQuakere al (1979) 3 Least significant difference at P s 005 4 Significance at lt 0001 () lt 001 () lt 005 () level or not significant (ns)
The use of Red Mudgypsum in vegetable production
Table 76 Concentration of nutrients ( dry basis) in whole carrot tops at harvest with level of residual Alkaloamreggypsum (AG) and phosphorus (P)
(b) Micronutrients
AG
AG (tha)
Fe1 Mn1 Zn1 B1 Cu1
0 299 962 234 402 109
125 316 952 184 404 107
250 331 662 110 380 110
1000 374 673 77 383 115
Lsd2 90 106 20 002 05
Sig3 ns ns
p
p (kgha) Fe1 Mn1 Zn1 B1 Cu1
0 294 969 158 409 125
50 392 837 144 393 117
100 364 747 141 396 114
200 267 712 159 387 105
400 332 bull 796 154 377 89
Lsd2 101 118 23 13 05
Sig3 ns ns
1 After McQuaker et al (1979) 2 Least significant difference at P lt 005 3 Significance at lt 0001 () lt 001 () lt 005 () level or not significant (ns)
As level of applied P increased concentration of P Ca and Na in whole tops increased significantly (P lt 005) whilst concentrations of N S Mn B and Cu decreased There was no significant effect of level of applied P on concentrations of K Fe or Zn in whole tops whilst concentration of Mg was variable
Effect oflevel of residual AG and P on carrot yield
There was a significant (P lt 005) increase in total and marketable yield with level of applied P at all levels of applied AG (Table 77) The overall effect of AG was to reduce both total and marketable yield at the highest level (1000 cf 0 to 2501 AGha) especially at low levels of applied P (ie 0 to 50 kg Pha) At higher levels of applied P yield at 2501 AGha was not significantly (P lt 005) lower than at 125 tha
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The use of Red Mudgypsum in vegetable production
However at 10001 AGha total and marketable yield was significantly lower than 0 tha at all levels of applied P The relationship between level of applied P and total yield was described as linear at 0 250 and 10001 AGha and Mitscherlich at 125 AG tha (Fig 76) As yield did not maximise at 0 250 and 1000 t AGha no optimal level of applied P for 95 or 99 of maximum yield could be determined At 125 t AGha the level of applied P necessary for 95 and 99 of maximum yield was 182 and 314 kg Pha respectively
Effect of level of AG and P on efficiency of P recovery by plants and retention in soil
The proportion () of P recovered in the carrot roots and tops decreased with level of applied P increasing from 8 to 12 to 5 to 8 of depending on level of AG (Table 78) There was a reduction in P recovered in roots tops and whole plant as level of AG increased For example P recovered by whole plants at 01 AGha at 400 kg Pha was 8 but this had declined to 5 at 10001 AGha
Table 78 The of applied fertiliser P taken up by carrots grown in pots (tops roots) retained in the topsoil or leached with level of residual Alkaloamreggypsum (AG) and phosphorus (P) on a Joel sand
P in Fraction AG P ( of P applied )
(tha) (kgha) TopsA Roots2 Plant(A+B) Soil2 Leached3
0 50 2 9 11 3 86
0 100 2 8 10 13 77
0 200 2 6 8 2 90
0 400 2 6 8 3 89
125 50 4 8 12 73 15
125 100 2 8 10 18 72
125 200 2 6 8 30 62
125 400 1 4 5 18 77
250 50 3 7 10 0 90
250 100 2 4 6 0 94
250 200 1 4 5 0 95
250 400 1 4 5 12 83
1000 50 2 6 8 75 17
1000 100 2 5 7 67 26
1000 200 2 5 7 45 48
1000 400 1 4 5 41 55
P in fraction expressed as of P applied as fertiliser 2 P retained in topsoil (0-15 cm) 3 P leached below 15 cm
By contrast of applied P retained in topsoil varied with level of AG For example only 3 of P was retained in topsoil at 400 kg Pha and 01 AGha where as this had increased to 41 at 10001 AGha at the same level of applied P Consequently the of P leached decreased as level of AG increased For example at 01 AGha and 400 kg Pha nearly 90 of applied P leached below 15 cm This had been reduced to 55 at 10001 AGha and the same level of applied P
97
The use of Red Mudgypsum in vegetable production
Table 79 Fertiliser P leached (kgha) and P leached as a of P applied from a Joel sand sown to carrots with level of residual Alkaloam gypsum (AG) and P after harvest The P was then applied as superphosphate prior to planting The carrots were sown on 3 April 1996 P leached is expressed as a percentage of P applied
AG (tha)
P (kgha)
P leached1
(kgha) P leached
( P applied)
0 50 41 82
0 100 78 78
0 200 158 79 0 400 311 78
125 50 2 4
125 100 3 3
125 200 10 5 125 400 27 7
250 50 1 2
250 100 3 3 250 200 4 2
250 400 7 2 1000 50 02 lt1 1000 100 05 lt1
1000 200 1 lt1
1000 400 2 lt1
1 Fertiliser P leached = total P leaclied - P leached at 0 kg Pha (ie background P) 2 (Fertiliser P leachedP applied x 100)
The use of Red Mudgypsum in vegetable production
O)
pound CD
o TO
(D
o
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c
o c o o
pound
(0
o to
c o
TO tmdash
c 0) o c o o
0 2 0 0 4 0 0 6 0 0 8 0 0 1 0 0 0 1 2 0 0
L e v e l o f r e s i d u a l A G ( t h a )
0 2 0 0 4 0 0 6 0 0 8 0 0 1 0 0 0 1 2 0 0
L e v e l o f r e s i d u a l A G ( t h a )
Figure 74 Concentration (mgL) of Ca (A) and Mg (B) in leachate from Joel sand sown to carrots amended with residual Alkaloamreggypsum (AG) in pots on 16 April 1996 (bull) 6 May 1996 (bull) and 22 July 1996 (A) The carrots were sown on 3 April 1996 Ca was applied preplanting as superphosphate and fertigated at a constant concentration of SO mgL from sowing to harvest AG was applied preplanting and in weeks 6 (15 May 1996) and 12 (25 June 1996) Vertical bars refer to Lsd (P lt 005) for differences in concentration between level of AG at each time Where bars arent shown Lsd is less than size of symbol
99
The use of Red Mudgypsum in vegetable production
CD
CO
x o CO CD
c o
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CO
c CD O c o O
0 2 0 0 4 0 0 6 0 0 8 0 0 1 0 0 0 1 2 0 0
L e v e l of r e s i d u a l A G ( t ha )
0 100 2 0 0 3 0 0 4 0 0
L e v e l of r e s i d u a l P ( k g h a )
5 0 0
Figure 75 The concentration of S (mgL) in leachate from Joel sands sown to carrots with level of residual Alkaloamreggypsum (AG) (A) and P (B) on 16 April 1996 (bull) 6 May 1996 (bull) 22 July 1996 (A) The carrots were sown on 3 April 1996 S was applied preplanting as K2S04 and in superphosphate Vertical bars refer to Lsd (P lt 005) for differences in concentration between level of AG (A) or P (B) at each sampling time Where bars arent shown Lsd is less than size of symbol
100
The use of Red Mudgypsum in vegetable production
ID
0 100 200 300 400 500
Applied P (kgha)
lb 70
70 C
60 65 -
60
55 dt
ha 50
40
50
45 bull A
Yie
30
40 _ 20
35 i i i i 35 0 100 200 300 400 5( 50 10
Applied p (kgha)
0 100 200 300 400 500
Applied P (kgha)
0 100 200 300 400 500
Applied P (kgha)
Figure 76 Total yield of carrots with level of freshly-applied P at four levels of residual Alkaloamreggypsum (AG) (A B C D = 01252501000 tha) Vertical dashed and whole lines refer to applied P necessary to 95 (dashed) or 99 (whole) of maximum yield respectively
The equations of the fitted lines are
A y = 10943 - 9377 x exp (-00053) (R2 = 099)
B y = 6l7- 2848 x exp (-00122) (i2 = 099)
C y = 3842+ 0083x (J2 = 097)
D y = 238 + 0l07x(R2 = 096)
As level of applied P increased concentration of P Ca and Na in whole tops increased significantly (P lt 005) whilst concentrations of N S Mn B and Cu decreased There was no significant effect of level of applied P on concentrations of K Fe or Zn in whole tops whilst concentration of Mg was variable
101
The use of Red Mudgypsum in vegetable production
Discussion
The addition of residual Alkaloamreggypsum (AG) resulted in a significant reduction in the concentration of P NH4-N K and Mg in the leachate from Joel sands sown to carrots in large pots The reduction in P concentration is attributed to an increase in the level of iron and aluminium oxides when AG is applied to soils low in these minerals (Barrow 1982) Consequently all soil measurements of P status or retention such as total P Colwell P and phosphorus retention index as well as Ec and pH all increased with level of applied residual AG Similar reductions in phosphorus leaching or increases in P retention have been reported when Gavin (Vlahos et al 1989) or Joel (Sections 4 and 5 McPharlin et al 1994 Robertson et al 1997) sands were amended with fresh or residual AG (Sections 4 and 6 Robertson et al 1994)
The reduced leaching of cations such as NH4-N K and Mg is attributed to an increase in captain exchange capacity (CEC) when sands of low CEC are amended with AG (Barrow 1982 McPharlin et al 1994) Consequently NO3-N retention is not increased when soils are amended with residual (Fig 72) or freshly-applied AG (McPharlin et al 1994) The increased leaching of Na Ca and S from amended sands is attributed to the Alkaloamreg as a source of these elements either in the Alkaloamreg itself (Na2C03) or after amendment with gypsum (CaS042H20) which precipitates CaC03 and Na2S04 The Na2S04 is very soluble as is easily leached whereas Ca is only slightly soluble as gypsum and insoluble as lime Vlahos et al (1989) reported increased leaching of Na Ca and S from Gavin sands treated with copper as (FeS04) amended Alkaloamreg compared with unamended controls in the short term and a decrease in the longer term Concentrations of P in the YML at midgrowth or tops at harvest increased with level of applied P and also with level of residual AG from 025 at 0 t AGha to 031 at 10001 AGha By contrast freshly-applied AG reduced the concentration of P in the YML from 043 on unamended to 030 on amended Joel sands (Robertson et al 1997) Even at the highest level of applied P the concentration of P in the YML 035 was still lower than that shown to be necessary for maximum yield of carrots (ie 038 McPharlin et al 1992) This could explain why the yield wasnt maximised in three out of the four AG treatments On the treatment that yield was maximised 125 t AGha the highest concentration of P ie 038 was recorded The difference in trends of P in petioles with AG between the 2 studies could be explained in terms of the relative leaching of P or addition of P in the AG itself On the virgin Joel sand used in the pot study leaching of P was significant enough to reduce leaf P in the unamended versus amended treatments For example the P in YML was significantly lower in the 01 AGha than at all other levels of residual AG at all levels of applied P up to 200 kgha For example the P in YML at 01 AGha ranged from 020 to 027 at 0 and 200 kg Pha respectively whilst at 125 t AGha the P was 032 to 038 over the same levels of applied P (Appendix 71) This suggests that loss of P from the top soil is severely limiting the uptake of P by the plant in the absence of AG The phosphorus retention of virgin Joel sands is almost negligible with a PRI of close to 0 (Table 72 McPharlin et al 1994 Robertson et al 1997) By contrast the P retention of Joel sands appears to be increased following development possibly by the addition of iron in irrigation water and organic and inorganic fertilisers For example the estimate of PRI (PREM) ie PRI plus P as Colwell P measured in the developed Joel sands used by Robertson et al was 40 in the topsoil (0-15 cm) of the unamended treatment Thus in these soils P retention is high enough to reduce availability when AG is added and explains the reduced levels of P in the YML as level of AG is increased The contribution of AG to the P nutrition of the plant is an unlikely explanation as it didnt increase P levels in the plant when applied fresh (Robertson et al 1997)
Previous work showed that concentrations of K in the petioles of potatoes (Section 4 Robertson et al 1997) and youngest mature leaves in cauliflower (Robertson et al 1994 Sections 5 and 6) declined with level of freshly-applied and residual AG
With potatoes the decline in K concentrations was associated with a decrease in K concentration in the soil solution and an increase in Na concentrations in soil solution and petioles on fresh and residual AG treatments (Section 4 Robertson et al 1997) This was
102
The use of Red Mudgypsum in vegetable production
used to explain yield reductions on fresh AG sites at gt 60 tha or on residual sites at 240 tha With cauliflower the findings were variable Where yield was reduced (Robertson et al 1994) it could not be explained in terms of K nutrition as K concentrations in the YML did not decline to levels expected to result in deficiency In follow up work neither fresh or residual AG up to 240 tha resulted in yield reduction although there was a reduction in K concentrations in the YML but not below critical levels (Sections 5 and 6) By contrast concentrations of K in the YML of carrots increased with level of residual AG up to 1000 tha as did exchangeable K in the soil Similar increases in K concentration in YML of Chinese and Head cabbage with level of AG on Joel sands have been reported previously (Robertson et al 1994)
Yield response of carrots to applied P at various levels of residual AG was variable on Joel sands in this work For example yield with level of applied P reach a plateau at 125 t AGha (ie 182 and 314 kg Pha for 95 and 99 of maximum yield from the Mitscherlich regression) However at other levels of applied AG including 0 tha yield had not maximised at the highest level of applied P (400 kgha) This is surprising considering that on higher P retaining soils such as Karrakatta sands yield is maximised at much lower levels of applied P (ie 160 to 180 kgha) at a similar low P soil test (McPharlin et al 1992 1994) in the absence of AG Also on Joel sands yields of carrots at medium to low P soil test (16 to 20 ugg Colwell P) only 50 kg Pha was necessary for maximum yield (McPharlin et al Lantkze and McPharlin unpublished data) The only possible explanation is that leaching of P was significant enough in the absence of AG that increased levels of applied P were required to satisfy crop requirements The increase in P fertiliser requirement as level of applied AG increases as shown in this work above 125 tha is similar to that reported previously for Chinese and Head cabbage cauliflower lettuce onions (Robertson et al 1994) and potatoes (Robertson et al 1997) It is explained by increased P retention capacity of the soil when AG is applied and measured by PRI Colwell and Total P and similar measurements
References
Allen DG and Jeffery RC (1990) Methods for analysis of phosphorus in Western Australian soils Chemistry Centre of Western Australia Report of Investigation No 37
Barrow NJ (1982) Possibility of using caustic residue from bauxite for improving the chemical and physical properties of sandy soils Australian Journal of Agricultural Research 33 275-285
Best EK (1976) An automated method for the determination of nitrate-nitrogen in soil extracts Queensland Journal of Agriculture and Annual Science 33 161-166
Colwell JD (1963) The estimation of phosphorus fertiliser requirements of wheat in southern New South Wales by soil analysis Australian Journal of Experimental Agriculture and Animal Husbandry 3 190-197
Hegney M A McPharlin IR and Jeffery RC (1997) Response of winter-grown potatoes (Solanum tuberosum L) to freshly-applied and residual phosphorus on a Karrakatta sand Australian Journal of Experimental Agriculture 37 131-137
McPharlin IR Alymore PM and Jeffery RC (1992) Response of carrots (Daucus carota L) to applied P and P leaching on a Karrakatta sand under two irrigation regimes Australian Journal of Experimental Agriculture 32 225-232
McPharlin IR Jeffery RC and Weissberg R (1994) Determination of the residual value of phosphate and soil test phosphorus calibration for carrots on a Karrakatta sand Communications in Soil Science and Plant Analysis 25 (5-6) 489-500
103
The use of Red Mudgypsum in vegetable production
McPharlin IR Robertson WJ Jeffery RC and Weissberg R (1995) Response of cauliflower to phosphate fertiliser placement and soil test phosphorus calibration on a Karrakatta sand Communications in Soil Science and Plant Analysis 26(3amp4) 607-620
McQuaker NR Brown DF and Kluckner PD (1979) Digestion of environmental materials for analysis by inductively coupled plasma-atomic emission spectrometry Analytical Chemistry 51 1082-1084
Reardon J Foreman JA and Serai RL (1966) New reactants for the determination of ammonia Clinica Chemica Acta 14 403-405
Robertson WJ McPharlin IR and Jeffery RC (1994) Final report of investigation into the use of gypsum-amended Red Mud as a soil-amendment for horticultural properties on the Swan Coastal Plain Final Report of HRDC Project No V0039 RO
Robertson WJ Jeffery RC and McPharlin IR (1997) Residues from bauxite-mining (Red Mud) increase phosphorus retention of a Joel sand without reducing yield of carrots Communications in Soil Science and Plant Analysis 28 (13 amp 14) 1059-1079
Varley JA (1966) Automatic methods for the determination of nitrogen phosphorus and potassium in plant material Analyst 91 119-126
Vlahos S Summers KJ Bell DT and Gilkes RJ (1989) Reducing phosphorus leaching from sandy soils with Red Mud bauxite processing residues Australian Journal of Soil Research 27 651-662
Walkley A and Black I (1934) An examination of the Degtjareff method of determining soil organic matter and a proposed modification of the chromic acid titration method Soil Science 37 29-38
Yuen SH and Pollard AG (1954) Determination of nitrogen in agricultural material by the Nessler reagent II Micro determination in plant tissue and soil extracts Journal of the Science of Food and Agriculture 5 364-369
104
The use of Red Mudgypsum in vegetable production
CO JC
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0 200 400 600 800
Level of residual AG(tha)
1000 1200
Appendix 71 (b) P leached (kgha) from Joel sands sown to carrots amended with residual Alkaloanrgypsum (AG) in pots on 16 April 1996 (week 3) (bull) 6 May 1996 (week 6) (bull) and 22 July 1996 (week 16) ( bull ) P was applied preplanting as superphosphate and carrots were sown on 3 April 1996 Vertical bars refer to Lsd (P lt 005) for differences in quantities of P leached between level of AG (across all levels of applied P) at each sampling time Where bars arent shown Lsd is less than size of symbol Data from Appendix 71 (a)
105
The use of Red Mudgypsum in vegetable production
200 400 600 800
Level ofresidual AG(tha)
1 000 1 200
2 00
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copy
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1 2 0
100 -
80 200 400 600 800
Level of residual AG (tha)
1000 1200
Appendix 73 (b) 74 (b) Ammonium-N (A) and Nitrate-N (B) leached (kgha) from Joel sands sown to carrots amended with residual Alkaloamreggypsum (AG) in pots on 16 April 1996 (week 3) (bull) 6 May 1996 (week 6) (bull) and 22 July 1996 (week 16) (A) N was fertigated postplanting as NH4-N and NO3-N and carrots were sown on 3 April 1996 Vertical bars refer to differences in quantities of N leached between level of AG (across all levels of applied P) at each sampling time Where bars arent shown Lsd is less than size of symbol Data from Appendices 73 (a) 74 (a)
106
The use of Red Mudgypsum in vegetable production
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Appendix 75 76 K (A) and Na (B) in leachate from Joel sand sown to carrots amended with residual Alkaloamreggypsum (AG) in pots on 16 April 1996 (week 3) (bull) 6 May 1996 (week 6) (bull) and 22 July 1996 (week 16) (A) The carrots were sown on 3 April 1996 K was fertigated at a constant concentration of 200 mgL from sowing to harvest and Na was a constituent of AG Vertical bars refer to Lsd (P lt 005) for differences in quantities of K and Na leached between level of AG (across all levels of applied P) at each time Where bars arent shown Lsd is less than size of symbol
107
The use of Red Mudgypsum in vegetable production
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Appendix 77 78 Ca (A) and Mg (B) in leachate from Joel sand sown to carrots amended with residual Alkaloamreggypsum (AG) in pots on 16 April 1996 (bull) 6 May 1996 (bull) and 22 July 1996 (A) The carrots were sown on 3 April 1996 Ca was applied preplanting as superphosphate (and as a constituent of AG) and fertigated at a constant concentration of 50 mgL from sowing to harvest Mg was applied preplanting and in weeks 6 (15 May 1996) and 12 (25 June 1996) Vertical bars refer to Lsd (P lt 005) for differences in quantity of Ca and Mg leached between level of AG (across all levels of applied P) at each sampling time Where bars arent shown Lsd is less than size of symbol Data from Appendices 77 (a) and 78 (a)
108
The use of Red Mudgypsum in vegetable production
200 400 600 800
Level of residual AG(tha)
1000 1200
Appendix 79 S (mgL) in leachate from Joel sands sown to carrots with level of residual Alkaloamreggypsum (AG) 16 April 1996 (week 3) (bull) 6 May 1996 (week 6) (bull) 22 July 1996 (week 16) (A) The carrots were sown on 3 April 1996 S was applied preplanting as K2S04 in superphosphate and as a constituent of AG Vertical bars refer to Lsd (P lt 005) for differences in quantity of S leached between level of AG (A) or P (B) at each sampling time Where bars arent shown Lsd is less than size of symbol Data from Appendix 79 (a)
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The use of Red Mudgypsum in vegetable production
1 SUMMARY AND RECOMMENDATIONS
11 Technical summary
Red Mud (Alkaloamreg)gypsum (AG) is seen as a useful amendment to increase the P retention of acid sandy soils low in this characteristic such as the Bassendean (Joel Gavin and Jandakot) and grey-phase Karrakatta sands P fertilisers applied to these soils from intensive horticultural production may leach and pollute associated water systems such as lakes rivers and estuaries Unfortunately because of strong demand for other land uses on soils better suited to vegetable production on the Swan Coastal Plain such as the Spearwood and yellow Karrakatta sands more of the less environmentally suitable Bassendean sands are being used for horticulture
In a previous project (HRDC VG0039) freshly-applied AG caused yield reduction in cauliflower and potatoes at low rates ie 60 tha on Karrakatta sands
In addition the effect of AG appeared to be specific and to vary with species For example levels of freshly-applied AG up to 240 tha had no effect on the yield of carrots on Joel sands and increased the yield of lettuce on Karrakatta sands
For this reason we approached Alcoa and HRDC for a subsequent project to further examine the response of cauliflower and potatoes to freshly-applied and residual AG
Addition of AG significantly increased the P retention (as measured by PRI total and Colwell P) pH Ec and exchangeable cations (NHU-N Ca K and Na) in the top 15 cm of the sands whilst concentrations of P and K in soil solution were reduced
With potatoes the effect of AG on yield varied depending of whether it was fresh or residual For example yield of potatoes were reduced with 601 of fresh AGha but only at 2401 of residual AGha In both cases the yield reduction could not be explained in terms of reduced P uptake by the plants as increased levels of applied P did not obviate the problem The yield reduction appeared to be due to K deficiency induced by high levels of Na (alkalinity) in the AG This was correlated with reduced K in soil solution With residual AG the alkalinity was lower as there had been more time for leaching and consequently the yield reduction was much less At levels of AG likely to be recommended for commercial use ie 60 to 120 tha no yield reduction would be anticipated with potatoes provided the AG was thoroughly leached with irrigation water for 1 or 2 months prior to planting In contrast to the previous project applications of fresh or residual AG up to 240 tha did not cause any reduction in yield of cauliflower even though concentrations of K decreased and Na increased in the YML at midgrowth
The optimum level of AG is that required to reduce leaching of fertiliser P substantially without reducing yield quality or increasing the level of P required for maximum crop yield significantly For example on unamended Joel sands leaching of fertiliser P was so high (ie 78 to 80 of applied P) that yield of carrots did not reach a maximum despite high levels of applied P (ie up to 400 kgha) By contrast 125 t AGha reduced leaching of fertiliser P to only 5 to 7 of applied P whilst yield maximised at 182 (95) and 314 (99) kg Pha At higher levels of AG (250 and 1000 tha) P required for maximum yield was significantly increased ie yield did not maximise at 400 kg Pha whilst leaching of P was not reduced much more than at 125 tha ie 1 to 3 of applied P However even at 125 tha the level of applied P required for maximum carrot yield (182 to 314 kgha) was higher than that required for maximum yield on higher P fixing sands such as the yellow Karrakatta sands ie 120 to 180 kgha suggesting that levels of AG less than 125 tha may be more agronomically suitable
In conclusion the benefits of amending acid sands with AG are increased retentionreduced leaching of P increased retentionreduced leaching of K Mg and NH4-N due to increased cation retention and an increase in pH (ie lime effect) The improved P retention of AG-amended sands enables the use of P soil testing as part of the P management of these soils whereas prior to amendment soil testing was not practical as leaching of P was too high
The use of Red Mudgypsum in vegetable production
An additional benefit which was not thoroughly investigated in this project but was obvious in the pot experiment was increased soil moisture holding capacity especially at high levels of application due to an increased in the fine fractions after amendment These benefits should be achieved at low to moderate levels of applied AG (ie 60 to 120 tha) without any negative effect on vegetable yield or quality
Some negative effects of amending acid sands with fresh AG include decreased yield due to increased conductivity and induced K deficiency in some vegetables such as potatoes However this does not appear to be a problem with carrots and cauliflower
This problem can be obviated by allowing sufficient time to leach the soluble alkalinity (Na2SCgt4) out of the root zone of the amended soil prior to cropping as it is less of a problem with residual AG Another disadvantage is the increase in fertiliser P requirements of vegetables after AG amendment in the short term due to increased P fixation This is particularly obvious at high levels of application However this disadvantage is offset as soil testing can be used on sands after amendment to reduce P fertiliser costs whereas it couldnt beforehand Also on unamended Joel sands leaching of P fertilisers (ie 80 of applied P) causes significant economic loss due to fertiliser losses and increased fertiliser P required for maximum yield
12 Industry summary
An important domestic and export vegetable industry is located on the sands of the Swan Coastal Plain (SCP) in Western Australia The total value of the vegetable industry on the SCP was estimated at $90M in 19967 or about 50 of the total value of the industry This vegetable production has been located on good quality sands such as the Spearwood and yellow Karrakatta sands close to the coast since the 1950s However in recent years competition for this land for urban and industrial use has forced vegetable production onto soils with poorer water and phosphorus retention capacity such as the more acidic Bassendean (Joel) and grey-phase Karrakatta sands This has lead leaching of fertiliser phosphorus into water systems of the SCP such as lakes rivers and estuaries with resulting pollution (algae blooms) Even though vegetable production is not the only or main source of this leached phosphorus the issue has resulted in negative publicity for the industry and increased scrutiny of industry practices by government agencies charged with responsibility for water the environment and health
As large quantities of Red Mud (Alkaloamreg)gypsum (AG) were produced from bauxite refining on the SCP it made sense to examine this as a soil amendment as it had been shown to improve the phosphorus retention capacity of coarse grey sands low in iron and aluminium oxides AG consistently increases the phosphorus retention capacity and the retention of cations such as potassium magnesium and ammonium-nitrogen and pH (lime effect) of grey and pale-yellow sands after amendment The reduction fertiliser P leaching is very high even at the lower rates of application such as 60 and 120 tha Fresh AG will increase the fertiliser phosphorus requirements of most vegetable crops compared with the unamended plots similar to the differences between low and high P fixing soils However this increase is not as much on residual or aged AG sites This increase in initial fertiliser P needs following AG application is offset by the use of soil testing to manage P fertiliser in subsequent crops on grey sands which was not practical prior to amendment Some initial problems with fresh AG causing yield reductions on potatoes was attributed to induced potassium deficiency due to high conductivity (ie high sodium) in amended soils However this problem can be overcome by leaching the soil of salts after amendment with high rates of irrigation so that EC of the amended soil doesnt exceed 6 mSm and the pH (water) 85 The potassium nutrition of the crop should be monitored to ensure it is adequate There is no problem on sites where AG has been applied for at least 12 months
2
The use of Red Mudgypsum in vegetable production
13 Recommendations It is recommended that AG be used as a soil amendment for vegetable crops on the grey and pale yellow sands of the SCP to reduce P fertiliser leaching However a number of guidelines should be adhered to ensure maximum benefits and minimum risks from the use of AG
bull Potatoes should not be grown on sites where fresh AG (ie 1 to 3 months after application) has been applied
bull Potatoes can be grown on sites where AG has be applied at levels up to 120 tha provided at least 12 months previously provided sufficient leaching of salts has occurred As a guide it is suggested that soil conductivity should not exceed 6 mSm and pH (water) 85 in the top 15 cm
bull Vegetable crops other than potatoes can be planted into sites where fresh AG has been applied at levels up to 120 tha without problems
bull Adjust level of P fertiliser application to account for increased P fertiliser requirements of vegetables due to higher P fixing on sites amended with AG
bull Use soil testing to manage P fertiliser applications on AG amended sites but follow recommendations for specific vegetable crops
The use of Red Mudgypsum in vegetable production
2 PROJECT STAFF
Ian McPharlin
Wendy Robertson
Bob Jeffery
Tony Shimmin
Jenny Harboard
Don Glenister
Patricia Aylmore
David Cooling
Gavin dAdhemar
Neil Lantzke
John Ferguson (Manager) and staff
Staff
COLLABORATORS AND ACKNOWLEDGMENTS
Project Manager and Principal Investigator
Research Officer
Project Collaborating Scientist (Chemistry Centre of WA)
Project Technical Officer
Project Laboratory Technician (Chemistry Centre of WA)
Residue Development Manager (Alcoa of Australia)
Environmental Scientist (Alcoa of Australia)
Senior Consultant Residue (Alcoa of Australia)
Technical Officer Medina Research Centre (for technical assistance and management of field and pot experiments)
Horticultural Extension Officer (for extension advice)
Medina Research Centre (for management of field experiments)
Chemistry Centre of WA (for advice of on soil plant and leachate chemistry)
4
The use of Red Mudgypsum in vegetable production
3 PUBLICATIONS ARISING OUT OF WORK Robertson WJ McPharlin IR and Jeffery RC (1997) The growth nutrition and
composition of potatoes (Solarium tuberosum L) cv Delaware grown on a yellow Karrakatta sand amended with freshly-applied and residual Alkaloamreggypsum Australian Journal of Experimental Agriculture (submitted)
McPharlin IR dAdhemar G and Shimmin TR (1997) The response of cauliflowers (Brassica oleraceae L) cv Plana to freshly-applied and residual Alkaloamreggypsum and phosphorus on a Karrakatta sand Australian Journal of Experimental Agriculture (in prep)
McPharlin IR Shimmin TR and dAdhemar G (1997) Leaching of P N and cations from carrots grown on Joel sands amended with residual Alkaloamreggypsum Communications in Soil Science and Plant Analysis (in prep)
The use of Red Mudgypsum in vegetable production
4 RESPONSE OF POTATOES TO FRESHLY-APPLIED AND RESIDUAL RED MUD (ALKALOAMreg)GYPSUM AND PHOSPHORUS ON A YELLOW KARRAKATTA SAND
Introduction
Previous work has shown that freshly-applied Alkaloamreggypsum (gypsum-amended red mud 10 ww) (AG) at 60 and 120 tha reduced the total yield of potatoes by 7 and 23 respectively compared with 01 AGha controls (Robertson et al 1994 Appendix 1 J) The reduction in marketable yield was almost identical to the reduction in total yield The exact cause of this reduction in yield could not be determined particularly the reduction at 120 tha It was unlikely to be a reduced availability of P Observations on commercial properties suggest that AG which has been in the soil for several seasons does not cause yield reductions in potatoes
Phosphorus was banded at planting in this experiment Subsequent work (Hegney and McPharlin unpublished data) showed that broadcasting P allowed a greater maximum yield of potatoes than banding P on Karrakatta sands of low P fertility
This experiment re-examines the response of potatoes to freshly-applied AG using broadcast P and also the effect of residual AG on growth of potatoes at unlimiting P
Materials and methods
Site characteristics
The experiment was conducted on a yellow Karrakatta sand (described by McArthur and Bettenay 1960) at Medina approximately 30 km south of Perth Two sites were used a site where pasture species had been grown several years earlier and to which no AG had ever been applied and a second (adjacent) site where AG had been applied approximately 2J2 years earlier A lettuce and a cauliflower crop had been grown previously on this site after AG amendment (Robertson et al 1994 Appendix 1H I)
Red Mud (Alkaloamreg)gypsum (AG)
Red Mud (Alkaloamreg)gypsum (10 ww) (AG) was produced by the dry mix process by ALCOA of Australia Ltd at their Kwinana Residue Treatment Plant It was spread manually on the previously unamended site on 22 December 1994 and was incorporated to a depth of approximately 30 cm using a rotary hoe The AG on the previously-amended site (residual AG) was applied using the same techniques on 24 November 1992 The freshly-applied AG was watered for 1 hour three times a week until planting
Experimental design
The freshly-applied and residual AG sites were used for separate experiments which were conducted simultaneously The experiment on the freshly-applied AG was a split-plot randomised complete block design with three replicates Main plots were levels of AG (0 60 90 and 120 tha) and sub-plots were levels of P application (0 25 50 100 300 and 600 kgha) Main plots measured 48 x 21 m and sub-plots measured 24 x 7 m (three rows of potatoes with 08 m between row centres) There was a 2 m buffer around each main plot The experiment on the residual AG site was a randomised complete block design with 4 levels of AG (0 60 120 and 240 tha) and three replicates The levels of AG were applied in November 1992 and had had several levels of P applied to them in the previous crops The AG plots measured 6 x 12 m but only an area of 34 x 8 m (4 rows of potatoes with 08 m between row centres) was cropped to allow a buffer of 1 to 2 m all around the planted area
6
The use of Red Mudgypsum in vegetable production
Crop management Both sites were initially sprayed with Roundupreg (3 Lha) to kill weeds and the sites were hoed with a rotary hoe Freshly-applied AG was applied at this stage The residual AG site was treated with metham sodium approximately two weeks before planting Potatoes cv Delaware were planted on both sites on 18 May 1995 using a single row mechanical planter Round seed was used and this was dusted with Rizolexreg (2 kgt) immediately before planting Sets were planted 15 cm apart The crops were irrigated using impact sprinklers once daily at 80 of Class A pan evaporation between planting and emergence and then at 100 of evaporation Afalonreg (15 kgha) was applied after planting and Sprayseedreg (2 Lha) was applied at 5 emergence both for weed control Nitofol (700 rnLha) was used for regular insect control Bravoreg (2 Lha) was applied every seven days from the time of 50 ground cover until blight symptoms appeared at which time it was then alternated with Rovralreg (2 Lha) at 7 day intervals Both crops were harvested on 15 November 1995
Fertilisers
Pre-planting fertilisers were broadcast by hand on 15 May 1995 on freshly-applied AG and on 16 May on residual AG These were 83 kg Kha as K2S04 10 kg Mgha as miso47H20 and a complete trace element mix containing (kgha) MnS04H20 (504) MgS047H20 (560) borax (336) FeS047H20 (336) CuS045H20 (336) ZnS04H20 (280) and Na2Mo042H20 (224) Single superphosphate (91 P) was broadcast by hand at 0 to 600 kg Pha on freshly-applied AG according to the treatment and at 600 kg Pha on all plots on residual AG Post-planting fertilisers were a total of 500 kg Nha as NH4NO2 and KN02 and 400 kg Kha as KN02 in equal amounts for 10 weeks via the irrigation system An extra 50 kgha MgS04 was applied in weeks 7 and 9
Measurements
(a) Plant
The petioles of the Youngest Mature Leaf (YML) often plants were collected at the S2 stage (longest tuber 10 mm long) (19 July 1995) on both freshly-applied and residual AG They were dried in a forced draught oven at 70degC and then analysed for P N K Na Ca Mg S B Cu Fe Mn and Zn On freshly-applied AG tubers were harvested from a 5 m length of the middle row of each plot On residual AG a 4 m length of the two middle rows of each plot was harvested Tubers were separated into the following size grades lt 30 g 30-80 g 80-250 g 250-450 g and gt 450 g Tubers between 30 g and 450 g were considered marketable except if they were green or damaged
Of the tubers in the 80-250 g category ten were sampled from each plot for P analysis They were washed in tap water and sliced thinly with a stainless steel knife Fresh and dry weights were measured before the tubers were analysed for total P
(b) Soil
All 0 kg Pha plots on freshly-applied AG were sampled to 15 cm depth (15 cores per plot) on 29 August (approximately 3 months after planting) They were analysed for Bicarbonate-extractable P (Bic-P) (Colwell 1963) total P EC pH (H20) pH (CaCl2) Phosphorus Retention Index (PRI) (Allen and Jeffery 1990) and P buffering capacity (Ozanne and Shaw 1968) Before fertilisers were applied to the residual AG site on 16 May 15 cores (0-15 cm) were sampled from each plot and analysed for Bic-P and PRI Residual AG plots were sampled again on 29 August (0-15 cm 15 cores per plot) and analysed for pH (H20) pH (CaCl2) EC and P buffering capacity All residual AG plots and 0 100 and 600 kg Pha freshly-applied AG plots were sampled to three depths (0-15 15-30 and 30-45 cm) (20 cores per plot) on 5 December (ie after harvest)
7
The use of Red Mudgypsum in vegetable production
Chemical analysis
Plant samples were ground to pass through a 1 mm screen after drying Concentrations of P N K and Na were measured by digesting the samples with sulphuric acid and hydrogen peroxide (Yuen and Pollard 1954) N and P were determined colorimetrically by indophenol blue and molybdo-vanadate methods respectively K and Na were determined by flame photometry All analysis was conducted on a 4-channel Auto-analyser system using modifications of Technicon procedures (Anon 1977) Samples for analysis of Ca Mg S Cu Fe B Mn and Zn concentrations were digested with nitricperchloric acids (McQuaker et al 1979) Concentrations were measured by inductively-coupled plasma atomic emission spectrometry (ICP-AES) Concentrations of heavy metals were determined using inductively-coupled plasma mass spectrometry (ICP-MS) with indium as an internal standard Samples were initially crushed in an agate mortar and digested using nitric and perchloric acids
All soil samples were dried at 40degC in a forced draught oven Lumps of AG and fertiliser in samples were crushed and the samples were thoroughly mixed and sieved to lt 2 mm before analysis The pH (H20) and the EC were determined on a 15 soilwater extract after shaking for 1 hour The pH (CaCl2) was determined on 15 soiksolution extract using 001 M CaCl2 after shaking for 1 hour Values for both are corrected to 25 degC Total P was determined on a Kjeldahl digest of a separate sub-sample of soil ground to less than 015 mm The concentration of phosphate was measured by the method of Murphy and Riley (1962)
Statistical analysis
All data were analysed by an Analysis of Variance (ANOVA) using Genstat v 50 Results from the two experiments were analysed separately Data from the freshly-applied AG site was analysed by a two-way ANOVA on level of Alkaloamreg and level of applied P while data from residual Alkaloamreg were analysed by a one-way ANOVA on level of AG Statistical differences were determined using a Least Significant Difference at 5 level of significance where the F value from the ANOVA was significant Mitscherlich curves were fitted to all relationships between level of applied P and yield petiole or tuber P concentration or total P uptake Maximum values of Mitscherlich equations were compared using a 5 t-test Linear relationships were fitted to the yield response on residual Alkaloam versus level of AG and also to the relationship between yield and petiole P concentration on freshly-applied AG
The amount of fertiliser P retained was calculated by subtracting total P at 0 kg Pha from the measured total P value Concentrations of P in ugg were converted to kilograms per hectare by multiplying by a factor of 225 This is based on the assumption that there are 2250 t soilha in the top 15 cm of soil
Results and discussion
Soil characteristics
The pH (H20) of the top 15 cm of soil at mid-growth when no P fertiliser was applied increased from 72 on unamended soil to 84 and 85 on amended soil (Table 41) EC also increased from 5 mSm on unamended soil to 8 and 9 mSm on amended soil (Table 41) Bic-P was approximately 10 ugg at all AG levels and total P ranged from 55 ugg on unamended soil to 76 ugg at 901 AGha (Table 41) PRI and P buffering capacity (Pbug) both increased between unamended and amended soil but there were no differences between levels of AG on amended soil PRI of amended soil was 26 to 30 and Pbuff was 24 to 30 (Table 41)
The Bic-P and PRI measurements taken two days before planting on residual AG were the same at all levels of AG Bic-P was 16 to 21 ugg and PRI was 37 to 53 (Table 42) On the other hand Pbuff measured mid-growth increased from 20 at 01 AGha to 30 and 40 at 120 and 2401 AGha The EC was 7-9 mSm on all treatments and pH (H20) increased between 0 and 120 t AGha from 73 to 84 (Table 42)
The use of Red Mudgypsum in vegetable production
Table 41 Characteristics of the top 15 cm of a Karrakatta sand amended with several levels of freshly-applied Alkaloamreggypsum (AG) when no fertiliser P was applied
AG (tha)
pH (H20)
pH (CaCl2)
EC (mSm)
Bic-P (ugg)
Total P (ugg)
PRI Pbuff
0 72 64 5 8 55 19 14
60 84 77 8 10 64 26 24
90 85 78 9 11 76 30 30
120 85 83 9 10 71 27 27
Signif NS NS $
Lsd 5 04 05 3 07 05
Table 42 Characteristics of the top 15 cm of a Karrakatta sand amended with several levels of residual Alkaloamreggypsum (AG) when 600 kg Pha was applied as superphosphate
AG (tha)
pH (H20)
pH (CaCl2)
EC (mSm)
Bic-Pa
(ugg) PRIa
Pbuff
0 73 67 7 16 37 20
60 78 71 5 17 40 23
120 84 77 9 20 44 30
240 88 80 9 21 53 40
Signif NS NS NS
Lsd 5 05 06 10
K Sampled and measured before application of fertiliser P
Total phosphorus in soil
Total P in the soil at harvest on freshly-applied AG increased significantly with level of AG averaged over all three depths sampled (P lt 005) It also increased with level of applied P on all levels of AG At 0-15 cm total P increased significantly between 0 and 601 AGha At 15-30 cm it increased significantly between 0 and 90 t AGha and at 30-45 cm there was no effect of level of AG at all (Fig 41) At all levels of AG and P which were sampled total P concentrations at 0-15 cm and 15-30 cm were not significantly different from each other and both were significantly greater than those at 30-45 cm (Fig 41)
In the top 15 cm of soil total P increased from 47 ugg on unamended soil to 62-67 ugg on amended soil when no fertiliser P was applied This increase represents the total P content of the AG itself When 100 kg Pha was applied total soil P (0-15 cm) increased from 63 ugg at 01 AGha to 83 ugg at 601 AGha and 95 and 103 ugg at 90 and 1201 AGha (Fig 41) When the increase due to the AG itself is considered this is an increase in fertiliser P retention of 6 ugg (26 kgha) between 0 and 601 AGha and a further 14 ugg (62 kgha) between 60 and 120 t AGha At 600 kg Pha the increase in fertiliser P retention was 35 ugg (15 kgha) between 0 and 601 AGha and 25 ugg (11 kgha) between 60 and 120 t AGha
Total P on residual AG increased with level of AG The increase was significant between 60 and 1201 AGha only It also decreased at increasing depth As observed on freshly-applied AG total P concentrations at 0-15 cm and 15-30 cm were not significantly different from each other and were both greater than that observed at 30-45 cm (Fig 43) At 0-15 cm total P increased by 20 ugg between 0 and 601 AGha and by a further 213 ugg between 60 and 1201 AGha when 600 kg Pha was applied These values cannot be corrected for the total content of AG itself as there was no 0 kg Pha treatment
9
The use of Red Mudgypsum in vegetable production
The addition of freshly-applied AG to the soil substantially increased the theoretical ability of the soil to sorb applied P as measured by the P buffering capacity in the top 15 cm of soil However it was reduced over time as 1201 AGha was required to increase Pbuff on residual AG compared with 601 AGha on freshly-applied AG Fertiliser P retention in the top 15 cm of soil when amended with 1201 AGha was increased by 9 at 100 kg Pha and by 4 at 600 kg Pha
The effects of residual and freshly-applied AG can be compared at 600 kgha of applied P The effect of residual AG on fertiliser P retention can be estimated from measurements made on the same site at the beginning of the first (lettuce) crop In that experiment total P before the application of P fertilisers increased from 69 and 62 ugg on 0 and 601 AGha to 91 ugg on 1201 AGha and 103 ugg on 2401 AGha (Robertson et al 1994 Appendix 1H) This makes the estimated increase in fertiliser P retention (0-15 cm) 27 ugg (12 kgha) between 0 and 601 AGha and 184 ugg (81 kgha) between 60 and 1201 AGha Therefore between 60 and 1201 AGha residual AG increased fertiliser retention by approximately 7 times as much as did freshly-applied AG
Bicarbonate-extractable P (soil-test P) in soil
On freshly-applied AG there was no overall response of Bic-P to level of AG although there was an upward trend Bic-P decreased with increasing depth averaged over all treatments following the same response as total P There was an interaction between the effects of depth and level of applied P At 0 kg Pha there was no difference in Bic-P between the three depths sampled but at 100 and 600 kg Pha Bic-P concentrations at 0-15 cm and 15-30 cm were both greater than those at 30-45 cm (Fig 42) The upward trend in Bic-P with increasing level of AG was weak on soil where no P fertiliser had been applied being from 9-10 ugg at 0 and 601 AGha to 11 and 14 ugg at 90 and 1201 AGha in the top 15 cm This suggests that the AG adds little if any plant available P to the soil The amount of fertiliser P retained as Bic-P in the top 15 cm of soil when 100 kg Pha was applied increased by 8 ugg between 0 and 601 AGha and by a further 4 ugg between 60 and 120 t AGha At 600 kg Pha Bic-P retained from fertiliser increased by 34 ugg between 0 and 601 AGha and by 16 ugg between 60 and 1201 AGha
The response of Bic-P to level of residual AG and to depth was the same as for total P (Fig 43) In the top 15 cm of soil Bic-P increased by 11 ugg between 0 and 601 AGha and by 82 ugg between 60 and 1201 AGha uncorrected for the Bic-P content of the AG itself
The increase in Bic-P retention observed on amended soil at 100 kg Pha was similar to that observed at 160 kg Pha on a crop of carrots grown on a Joel sand amended with AG (Robertson et al 1997) Using the soil-test standards published by Hegney et al (1997) these increases in Bic-P will reduce the P fertiliser requirement in the following potato crop by 10 at 601 AGha and 22 at 1201 AGha
Using the Bic-P concentrations observed on the residual site at the beginning of the lettuce crop (Robertson et al 1994 Appendix 1H) the increase in fertiliser P retained as Bic-P (0-15 cm) on residual AG was 15 ugg between 0 and 601 AGha and 79 ugg between 60 and 1201 AGha This is half the increase observed on freshly-applied AG between 0 and 60 t AGha and approximately 5 times that observed on freshly-applied AG between 60 and 1201 AGha
The reduced P retention at low levels of residual AG compared with freshly-applied AG was probably because of the higher initial Bic-P levels on residual AG For both total and Bic-P it is difficult to explain why the apparent retention of fertiliser P between 60 and 120 t AGha should have been so much greater on residual than on freshly-applied AG It may have been caused by changes to the chemical properties of the AG as it aged in the ground
10
The use of Red Mudgypsum in vegetable production
Yield
Total and marketable yields on freshly-applied AG both increased with level of applied P following a Mitscherlich response (Fig 44 (a) (b)) An ANOVA did not indicate any response to level of AG in either total or marketable yields However maximum total yield on unamended soil (61 tha) was significantly greater than that on AG-amended soil - 54 to 57 tha (Fig 44 (a)) On the other hand there were no differences in maximum marketable yields Maximum marketable yield values ranged from 52 to 55 tha (Fig 44 (b)) When marketable yield was calculated as a percentage of total yield an ANOVA indicated a significant interaction between level of AG and level of applied P At 400 kg Pha marketable yield was 88 of total yield on unamended soil compared with approximately 95 on amended soil (significant according to 5 Lsd) A similar trend was observed at 600 kg Pha where marketable yield was 90 of total yield on unamended soil and 93 to 96 on amended soil
The levels of applied P required for 99 of maximum total yield were 245 222 183 and 400 kg Pha on 0 60 90 and 1201 AGha and for 95 of maximum yield were 139 130 108 and 226 kg Pha (Fig 44 (a)) A similar trend can be seen for marketable yield where 99 of maximum yield required 178 206 208 and 356 kg Pha (Fig 44 (b))
Total yield on residual AG showed an almost significant response to level of AG (P = 0067) (Fig 45) Total yield was 68 to 72 tha on 0 60 and 120 t AGha and 62 tha on 2401 AGha Marketable yield was 65 to 68 tha on 0 to 1201 AGha and 58 tha on 2401 AGha Therefore 2401 AGha appears to reduce yields even when it has been in the ground for 2 years or more and even when 600 kg Pha is applied As only one level of P fertiliser was applied it is not possible to determine the effect of residual AG on the critical levels of P application required for 99 and 95 of maximum yield
Concentration of nutrients in petioles
Phosphorus
Phosphorus concentration in petioles of the YML sampled at the S2 stage on freshly-applied AG increased with level of applied P following a Mitscherlich response (Fig 46) Maximum petiole P concentrations were approximately 12 (dry basis) on all AG levels Values at 99 of maximum petiole P concentration were 116 122 117 and 116 at 0 60 90 and 1201 AGha There was a significant interaction between levels of AG and applied P (P lt 005) At low levels of applied P (25 50 and 100 kgha) P concentrations on amended soil were significantly less than those on unamended soil but there was no difference between them at 300 or 600 kg Pha This is reflected in the levels of applied P required for 99 of maximum petiole P concentration which were 209 499 581 and 508 kg Pha at 0 60 90 and 1201 AGha This is an increase of 138 on amended soil relative to unamended soil AG at levels of between 60 and 120 tha therefore reduces the availability of P to plants As there was no difference in the maximum P concentration in petioles between amended and unamended soil a reduction in P availability to plants cannot explain the reduced maximum yield on amended soil Another factor was therefore involved in reducing maximum yield on amended soil Despite this yield difference between amended and unamended soil which was not related to differences in P concentration total yield for all AG levels combined was linearly correlated with petiole P concentration at the S2 stage (y = 256 + 274x R2 = 087) (Fig 47)
The petiole P concentration at 99 of maximum total yield was 116 109 095 and 114o at 0 60 90 and 1201 AGha At 01 AGha this was the same as 99 of maximum petiole P concentration implying that the yield response on unamended soil was controlled principally by P availability On the other hand petiole P concentrations at 99 of maximum yield on amended soil especially 60 and 901 AGha were less than 99 of maximum petiole P concentration In other words yield stopped increasing even though P concentration in the plant kept increasing This supports the previous observation that some factor other than P was limiting yield in these treatments Petiole P concentration in YMLs sampled at S2 stage on residual AG did not change with level of AG Overall mean P concentration was 12 dry
11
The use of Red Mudgypsum in vegetable production
basis This is in keeping with the results observed on freshly-applied AG at 600 kg Pha It also means that the lower yield at 2401 AGha on residual AG could not be explained by a reduced P concentration in the plant As on freshly-applied AG another factor was involved which reduced yield on amended soil although at a higher level on residual than on freshly-applied AG
Hegney et al (1997) found that maximum petiole P concentration at S2 in potatoes grown on Karrakatta sand was 114 dry basis and that 109 was required for 99 of maximum yield in good agreement with the results observed here
Other nutrients
The responses of nutrients other than P were very similar on both freshly-applied and residual AG Concentrations of K (Tables 43 45) and Zn (Fig 48 (a) Table 45) decreased as level of AG increased and concentrations of Mg Fe and Ca increased with level of AG in both experiments (Tables 43 45 Fig 48 (b)) Zn concentrations also decreased with increasing level of applied P (Fig 49 (a)) while Ca concentrations increased with level of applied P (Fig 48 (b)) Concentrations of Na also showed an upward trend on both freshly-applied and residual AG (Tables 43 45) On freshly-applied AG K concentrations decreased significantly from 119 dry basis on unamended soil to 110 at 601 AGha and to 102 at 1201 AGha (Table 43) On residual AG it decreased from 11-12 at 0-1201 AGha to 103 at 2401 AGha (Table 45) No other nutrients showed any response to level of AG although concentrations of N Mn S and B increased with level of applied P on freshly-applied AG (Table 44)
Concentrations of all nutrients except K were adequate or more than adequate for maximum yield (Maier et al 1987) on both freshly-applied and residual AG Potatoes require concentrations of approximately 12 to 14 K (dry basis) in petioles of YML for maximum yield (Maier et al 1987) On freshly-apphed AG concentrations were adequate at 01 AGha but were less than adequate on amended soil On residual AG concentrations were adequate at 0 60 and 1201 AGha but less than adequate at 2401 AGha As less than adequate K concentrations correspond with those treatments which had low yield it is likely that K concentration was the limiting factor in yield on both freshly-applied and residual AG
Uptake of K may have been reduced at higher levels of AG due to an increased Cation Exchange Capacity (Barrow 1982 McPharlin et al 1994) or to the increased soil pH (Harris 1992) The reduction in Zn availability on amended soil is most likely to be a result of the increase in soil pH due to the AG (Harter 1983)
Table 43 Concentrations of several nutrients in the petioles of the Youngest Mature Leaf of potato plants sampled at the 10 mm tuber stage at several levels of freshly-applied Alkaloamreggypsum (AG) on a yellow Karrakatta sand
AG K Na Mg Fe (tha) () () () (ngg)
0 119 018 059 382
60 110 020 065 553
90 106 021 066 597
120 102 021 069 697
Signif NS
Lsd 5 04 004 119
12
The use of Red Mudgypsum in vegetable production
Table 44 Concentrations of several nutrients in the petioles of the Youngest Mature Leaf of potato plants sampled at the 10 mm tuber stage at two levels of applied P when grown on a yellow Karrakatta sand amended with freshly-applied Alkaloamreggypsum (AG)
Applied P N S Cu Mn B (kgha) () () (ngg) (ngg) (M-gg)
0 44 028 74 293 267
600 48 032 62 342 248
Signif NS NS
Table 45 Concentrations of several nutrients in the petioles of the Youngest Mature Leaf of potato plants sampled at the 10 mm tuber stage at several levels of residual Alkaloamreggypsum (AG) on a yellow Karrakatta sand
AG N K Na Ca S Mg Cu Fe Mn Zn B (tha) () () () () () () (l-igg) (ngg) (ngg) Ws) (^gg)
0 51 116 016 23 030 050 77 453 46 96 26
60 48 127 015 21 027 045 61 457 45 67 25
120 49 120 016 26 029 051 66 643 59 59 25
240 49 103 019 29 030 067 54 977 53 53 24
Signif NS NS NS NS NS NS
Lsd5 05 04 013 164 24
Tuber P and Crop P removal P concentration in tubers
The concentration of P in tubers on freshly-applied Alkaloamreg increased with level of applied P (P lt 0001) The response at each level of Alkaloamreg was best described by a Mitscherlich curve although none of the curves reached a maximum within the range of fertiliser P levels used (Fig 49 (a)) There was a trend for an overall response to level of AG (P = 0081) P concentrations were generally higher on unamended soil than on amended soil For example at 300 kg Pha P concentration was 033 on unamended soil and 026-028 on amended soil and at 600 kg Pha P concentrations were 036 and 032-033 on unamended and amended soil respectively At P levels corresponding to 99 of maximum yield tuber P concentration was 031 024 023 and 028 at 0 60 90 and 1201 AGha
On residual AG tuber P concentration did not change with level of AG The overall mean was 036 dry basis
Total P uptake
Total P uptake by tubers on freshly-applied AG showed a significant response to level of AG (P lt 005) and level of applied P (P lt 0001) The response to applied P at each level of AG was best described by a Mitscherlich curve although as for tuber P concentration none of the curves reached a maximum within the range of P levels applied P uptake by tubers on unamended soil was significantly greater than on amended soil regardless of AG level (Lsd 5) (Fig 49 (b)) At levels of applied P corresponding to 99 of maximum yield P uptake by tubers was 113 75 75 and 95 kgha at 0 60 90 and 1201 AGha These figures are lower than results reported by Hegney et al (1997) who found a P uptake by tubers grown on yellow Karrakatta sand of 204 kgha at 99 of maximum yield even though yields were similar to those observed on unamended soil in this experiment
13
The use of Red Mudgypsum in vegetable production
Total P uptake by tubers was not significantly different between AG levels on residual AG Overall mean P uptake was 110 kgha This is different from the situation observed at 600 kg Pha on freshly-applied AG As only one level of P was applied the response curve for tuber P concentration on residual AG cannot be compared with that on freshly-applied AG It is possible that less applied P is required on residual than on freshly-applied AG to reach maximum tuber P concentration
Metals in tubers
The concentration of As in tubers harvested from freshly-applied AG showed a trend to increase with level of AG from 5 x 104 mgkg (fresh weight) on unamended soil to 8 x 104 mgkg at 60 and 901 AGha (Fig 410) Concentrations of all other metals measured showed no response to level of AG either on residual or freshly-applied AG (Table 46 47) On freshly-applied AG concentrations of Ni and Cd increased and concentrations of Cu decreased with increasing level of applied P (Table 48)
Table 46 Mean concentrations (mgkg fresh weight) of metals in tubers of potato cv Delaware harvested from a yellow Karrakatta sand amended with freshly-applied Alkaloam^gypsum (AG)
Cr Co Sn Sb Hg
mean
se
0007
61 xlO5
60 x 104
50 x 106
15 x 103
10 x 104
90 x 105
10 xlO5
34 x 104
14 x 105
Table 47 Mean concentrations (mgkg fresh weight) of metals in tubers of potato cv Delaware harvested from a yellow Karrakatta sand amended with residual Alkaloamreggypsum (AG)
Cr Co Ni Cu As Cd Sn Sb Hg Pb
mean
se
001
68X104
72xl(f 29xia5
55xia3
17x1a4
010
35xia3
L2X103
0
58xia3
17X104
LOxlO3
29X104
30X1O4
43xl05
84X1G4
ii xia5
l ixia3
70xia5
Table 48 Mean concentrations (mgkg fresh weight) of metals in tubers of potato cv Delaware harvested from a yellow Karrakatta sand amended with freshly-applied Alkaloamreggypsum (AG) at various levels of applied P
Applied P (kgha)
Ni Cd Cu
0 0006 0002 018
100 0006 0002 016
300 0007 0004 015
600 0008 0006 013
Signif
Lsd (5) 00014 0001 002
The concentrations of As observed in tubers from freshly-applied AG regardless of the level of AG were less than 10 of the legal limit (10 mgkg fresh weight NFA 1992) The concentrations of all metals measured were between 3 and 33 of those measured in potato tubers in a previous experiment (Robertson et al 1994 Appendix 1 J) The concentrations on residual AG were also lower than the concentrations previously observed in lettuce and cauliflowers on the same site (Robertson et al 1994 Appendix IH I) As different batches of
14
The use of Red Mudgypsum in vegetable production
AG were used on the two sites they cannot be compared to determine the effect of time on metal availability and uptake Overall metal uptake by potato tubers grown on AG-amended yellow Karrakatta sand does not appear to pose any greater health risk than that on unamended yellow Karrakatta sand The observed increase in As concentration in potato tubers on freshly-applied AG was probably due to the increase in soil pH with level of AG (ONeill 1990)
Conclusions
Freshly-applied AG reduces the availability of fertiliser P so that approximately 25 times the level of applied P is required on 60 to 1201 AGha relative to unamended soil in order to attain maximum P concentration in plant tissues AG at 120 tha also increases the retention of fertiliser P sufficiently to reduce fertiliser requirements for a following potato crop by approximately 20 The effect of AG on the level of fertiliser P required for 99 of maximum yield was confounded in this experiment by the decrease in maximum yield between unamended and amended soil Total yield of potatoes will be reduced on 60 tha freshly-applied AG and by 240 tha residual AG probably by a limiting concentration of K There is potential for increased levels of K fertiliser to overcome this yield reduction AG increases the proportion of yield which is marketable so that even though total yield is reduced by 60 tha of freshly-applied AG the marketable yield is not There are no apparent problems with heavy metal contents of tubers due to amendment with AG
References Allen DG and Jeffery RC (1990) Methods for analysis of phosphorus in Western
Australian soils Chemistry Centre of WA Report of Investigation No 37
Anonymous (1977) Technicon Industrial Method 334-74WB+ Technicon Industrial Systems Tarrytown NY USA
Barrow NJ (1982) Possibility of using caustic residue from bauxite for improving the chemical and physical properties of sandy soils Australian Journal of Agricultural Research 275-285
Colwell JD (1963) The estimation of phosphorus fertiliser requirements of wheat in southern New South Wales by soil analysis Australian Journal of Experimental Agriculture and Animal Husbandry 3 190-197
Glenister DJ and Thoraber MR (1985) Alkalinity of red mud and its application for the management of acid wastes Chemeca 85 109-113
Harris PM (1992) Mineral Nutrition In The Potato Crop The scientific basis for improvement 2nd edition (ed P Harris) pp 162-213 (Chapman and Hall London UK)
Harter RD (1983) Effect of soil pH on adsorption of lead copper zinc and nickel Soil Science Society of America Journal 47 47-51
Hegney MA McPharlin IR and Jeffery RC (1997) Response of winter-grown potatoes (Solanum tuberosum L) to applied and residual phosphorus on a Karrakatta sand Australian Journal of Experimental Agriculture 37 (in press)
Maier NA Williams CMJ Potocky-Pacay K Moss D and Lomman GJ (1987) Interpretation standards for assessing the nutrient status of irrigated potato crops in South Australia Technote AGDEX 262533 September 1987 Department of Agriculture South Australia
15
The use of Red Mudgypsum in vegetable production
McArthur WM and Bettenay E (1960) The development and distribution of the soils of the Swan Coastal Plain Western Australia CSIRO Division of Soils Soils Publication No 16
McPharlin IR Jeffery RC Toussaint LF and Cooper M (1994) Phosphorus nitrogen and radionuclide retention and leaching from a Joel sand amended with red mudgypsum Communications in Soil Science and Plant Analysis 25 489-500
McQuaker NR Brown DF and Kluckner PD (1979) Digestion of environmental materials for analysis by inductively coupled plasma atomic emission spectrometry Analytica Chimica 51 1082-1084
Murphy J and Riley JP (1962) A modified single solution method for the determination of phosphate in natural waters Analytica Chimica Acta 27 31-36
NFA (National Food Authority) (1992) Australian Food Standards Code June 1992 (Australian Government Publishing Service Canberra)
ONeill P (1990) Arsenic In Heavy Metals in Soils(ed BJ Alloway) pp 83-99 (Blackie Glasgow)
Ozanne PG and Shaw TC (1967) Phosphate sorption by soils as a measure of the phosphate requirement for pasture growth Australian Journal of Agricultural Research 18 601-612
Robertson WJ McPharlin IR and Jeffery RC (1994) Final Report of investigation into the use of gypsum-amended red mud as a soil-amendment on horticultural properties on the Swan Coastal Plain Agriculture WA
Robertson WJ McPharlin IR and Jeffery RC (1997) Residues from bauxite-mining (red mud) increase phosphorus retention of a Joel sand without reducing yield of carrots Communications in Soil Science and Plant Analysis (in press)
Yuen SH and Pollard AG (1954) Determination of nitrogen in agricultural materials by the Nessler reagent II Micro-determination in plant tissue and in soil extracts Journal of Food in Agriculture 5 364-369
16
The use of Red Mudgypsum in vegetable production
300
250 -
I I
200
3
60 80
AG (tha)
140
Figure 41 Total phosphorus concentration in a yellow Karrakatta sand amended with freshly-applied Alkaloamreggypsum (AG) vs level of AG when 0 (bull) 100 (A) and 600 (bull) kg Pha was applied measured at 0-15 cm () 15-30 cm (mdash) and 30-45 cm (mdash) depth Bars are Lsds at 5 level of significance
17
The use of Red Mudgypsum in vegetable production
Z3
200
180 -
160
Q- 140
ro 120 bull 4 -
O CD X 100 CD i
3 80 CO c o
pound gt v_ CO
o CQ
AG Depth
I
0 20 40 60 80 100 120
AG (tha)
140
Figure 42 Bicarbonate-extractable phosphorus concentration in a yellow Karrakatta sand amended with freshly-applied Alkaloamreggypsum (AG) vs level of AG when 0 (bull) 100 (A) and 600 (bull) kg Pha was applied measured at 0-15 cm () 15-30 cm (mdash) and 30-45 cm (mdash) depth Bars are Lsds at 5 level of significance
18
The use of Red Mudgypsum in vegetable production
700
600
500
D)
3 400
CL
oil
300 CO
200
100
100 150
A G (tha)
250
Figure 43 Total (mdash) and Bicarbonate-extractable phosphorus () concentration in a yellow Karrakatta sand amended with residual Alkaloamreggypsum (AG) when 600 kg Pha was applied measured at 0-15 cm () 15-30 cm (A) and 30-45 cm (bull) depth Bars are Lsds at 5 level of significance
19
The use of Red Mudgypsum in vegetable production
CO
2 CD
gt-
200 300 400
Applied P (kgha)
Figure 44 (a) Total yield of potatoes cv Delaware grown on a yellow Karrakatta sand amended with freshly-applied AIkaIoamreggypsum (AG) at a level of 0 (bull) 60 (A) 90 (bull) and 120 (bull) tha vs level of applied P Lines represent the level of applied P required for 99 of maximum yield Bars are Lsds at 5 level of significance
Equations are
A
B
C
D
0 tha
60 tha
90 tha
120 tha
j - 614 - 255 x exp (-00152) (JR= 092)
y = 542 - 271 x exp (-00176) (R2= 090)
y = 552 - 274 x exp (-0021) (F= 094)
y = 566 - 229 x exp (-00092) (i^= 098)
20
The use of Red Mudgypsum in vegetable production
ro
JO
gt-
100 200 300 400
Applied P (kgha)
500 600
Figure 44 (b) Total yield of potatoes cv Delaware grown on a yellow Karrakatta sand amended with freshly-applied Alkaloamreggypsum (AG) at a level of 0 (bull) 60 (A) 90 (bull) and 120 (bull) tha vs level of applied P Lines represent the level of applied P required for 99 of maximum yield Bars are Lsds at 5 level of significance
Equations are
Otha A
B
C
D
60 tha
90 tha
120 tha
y = 547 - 216 x exp (-0021) (R2^ 088)
y = 517 - 278 x exp (-0019) (R2= 090)
y = 524 - 243 x exp (-001 to) (R2= 094)
y = 530 - 218 x exp (-001 Ox) (i^= 098)
21
The use of Red Mudgypsum in vegetable production
CO
32
gt-
80
70
60
50
40
30
20
10
0 0
Marketable yield
Marketable yield
Total yield
Total yield
_L 50 100 150 200
AG (tha)
250 300
Figure 45 Total (bull) and Marketable (bull) yield of potatoes cv Delaware grown on a yellow Karrakatta sand amended with residual AIkaloamreggypsum (AG) vs level of AG 600 kg Pha was applied Bars are Lsds at 5 level of significance
22
The use of Red Mudgypsum in vegetable production
w CO CO
a gtraquo i _
C
o 00
c CD O c o o
100 200 300 400
Applied P (kgha)
500
Figure 46 Concentration (dry basis) of phosphorus in petioles of the Youngest Mature Leaf of potatoes cv Delaware grown on a yellow Karrakatta sand amended with freshly-applied Alkaloamreggypsum (AG) at 0 (bull) 60 (A) 90 (bull) and 120 (bull) tha vs level of applied P Lines represent the level of applied P required for 99 of maximum yield Bars are Lsds at 5 level of significance
Equations are
A Otha y = 117- 079 x exp (-0020) (R2 = 096)
B 60 tha y=123- 096 x exp (-000874) (R2 - 099)
C 90 tha y = 118 - 0884 x exp (-000742) (R2 = 096)
D 120 tha y= 117 - 090 x exp (-00085) (R2 = 097)
23
The use of Red Mudgypsum in vegetable production
CO
c
53
CD
gt-
00 02 04 06 08 10
Petiole P ( dry basis)
12 14
Figure 47 Yield of potatoes cv Delaware grown on a yellow Karrakatta sand amended with freshly-applied AlkaIoamreggypsum (AG) at 0 (bull) 60 (A) 90 (bull) and 120 (bull) tha vs petiole P concentration
The equation is y = 256 + 274x (ft2 = 087)
24
The use of Red Mudgypsum in vegetable production
poundgt 3
0 100 200 300 400 500 600 700
Applied P (kgha)
Figure 48 (a) Concentration of Zinc and (B) Calcium ( dry weight) in petioles of the youngest mature leaf of potatoes cv Delaware harvested from a yellow Karrakatta sand amended with freshly-applied Alkaloamreggypsum (AG) at 0 (bull) 60 (A) 90 (bull) and 120 (bull) tha vs level of applied P Bars are Lsds at 5 level of significance
25
The use of Red Mudgypsum in vegetable production
100 200 300 400 500
Applied P (kgha)
700
Figure 48 (b) Concentration of Calcium ( dry weight) in petioles of the youngest mature leaf of potatoes cv Delaware harvested from a yellow Karrakatta sand amended with freshly-applied AlkaIoamreggypsum (AG) at 0 (bull) 60 (A) 90 (bull) and 120 (bull) tha vs level of applied P Bars are Lsds at 5 level of significance
The use of Red Mudgypsum in vegetable production
040
ogt 035 CD
gtgt bullo
w _CB O
H) CL
CO 1 _ -mdashraquo c CD O c o o Q
030 -
025 -
020
2 015
010 -
005
000 0 100 200 300 400
Applied P (kgha)
500 600
Figure 49 (a) The concentration of phosphorus in tubers ( dry weight) of potatoes cv Delaware harvested from a yellow Karrakatta sand amended with freshly-applied Alkaloamreggypsum (AG) at 0 (bull) 60 (A) 90 (bull) and 120 (bull) tha vs level of applied Pkgha Bars are Lsds at 5 level of significance
Equations are
A 0 tha
B 60 tha
C 90 tha
D 120 tha
y = 0372 - 0243 x exp (-00058) (R2 = 097)
y = 0378 - 0257 x exp (-00029x) (R2 = 098)
y = 0361 - 0216 x exp (-00029x) (i^= 095)
y = 0406 - 0279 x exp (-0002x) (R2 = 098)
27
The use of Red Mudgypsum in vegetable production
CO
3
ltD
CO Q Z5
ID
B
14
12 -^ ^
10
8 W
6
4
A G P
I
2
n I i i I I i
0 100 200 300 400
Applied P (kgha)
500 600
Figure 49 (b) Phosphorus uptake Gigha) by tubers of potatoes cv Delaware harvested from a yellow Karrakatta sand amended with freshly-applied Alkaloamreggypsum (AG) at 0 (bull) 60 (A) 90 (bull) and 120 (bull) tha vs level of applied P Bars are Lsds at 5 level of significance
Equations are
Otha A
B
C
D
60 tha
90 tha
120 tha
y = 140 - 1095 x exp (-00058r) (R2 = 096)
3= 111 - 882 x exp (-0004x) (R2 = 098)
y = 104 - 774 x exp (-00053) (R2 = 099)
3 = 127 -101 x exp (-00029x) (R2 = 0997)
28
The use of Red Mudgypsum in vegetable production
60 80
AG (tha)
Figure 410 Concentration of Arsenic (dry weight) in tubers of potatoes cv Delaware grown on a yellow Karrakatta sand amended with freshly-applied Alkaloamreggypsum (AG) Bar is Lsd at 5 level of significance
29
The use of Red Mudgypsum in vegetable production
5 RESPONSE OF CAULIFLOWERS TO FRESHLY-APPLIED RED MUD (ALKALOAMreg)GYPSUM AND PHOSPHORUS ON A YELLOW KARRAKATTA SAND
Introduction
It is important to reduce the leaching of phosphorus fertiliser from sandy soils used for vegetable production into the water systems of the Swan Coastal Plain Red Mud (AlkaloamR)gypsum (AG) a waste product from bauxite refining has been suggested as an amendment to reduce phosphorus leaching from sands of the Bassendean Association (Joel Gavin) used for agriculture and horticulture (Barrow 1982)
Experimental work in the field and pots showed amendment with AG significantly reduced P leaching from Joel and Gavin sands (Vlahos et al 1989 McPharlin ei al 1994) compared with the unamended (01 AGha) treatment
In previous work freshly-applied AG at 60 tha increased the amount of freshly-applied P required for maximum yield of cauliflowers 14 (autumn planted) but did not reduce maximum yield (20 tha) compared with the unamended (0 tha) treatment on a yellow Karrakatta sand (Robertson et al 1994) At the highest rate of applied AG (120 tha) P required for maximum yield was 32 higher than at 0 tha and maximum yield was reduced 23 (P lt 005)
Since more than 60 tha of AG may be required to significantly improve P retention by sands to enable sustainable horticultural production this yield reduction is re-examined with freshly-applied AG
Materials and methods
Site characteristics
The experiment was conducted on a yellow Karrakatta sand (McArthur and Bettenay 1960) of low P fertility at Medina Research Centre (32deg 13 S 115deg 49 E) 30 km South of Perth The site had no previous history of AG application and had been sown to pasture for several years Some relevant chemical characteristics of the topsoil (0-15 cm) and subsoil (15-30 cm) of the site after application of AG but prior to the application of fertiliser and transplanting are presented in Table 51
Red Mud (AlkaIoamreg)gypsum (AG)
Alkaloamreg (Red Mud) amended with 10 (ww) gypsum (AG) was produced by the dry mix process by ALCOA of Australia Ltd at their Kwinana Residue Treatment Plant The AG was spread manually on the site and incorporated using a rotary hoe to approximately 30 cm depth on 21 February 1996 The site was watered for 1 hour per day (8 mmday) using impact sprinklers until planting
Experimental design
The experimental design was a split-plot randomised block with 3 replicates The main plots were levels of AG (0 60 120 and 240 tha) and the sub-plots were levels of freshly-applied P (0 50 100 200 400 and 600 kgha) Main plots measured 6 x 12 m and sub-plots 12 x 6 m (excluding wheel tracks)
Crop management
The site was sprayed with Roundupreg (3 Lha) twice after application of AG and prior to planting to control weeds
The use of Red Mudgypsum in vegetable production
Six week old seedlings of cauliflowers (cv Plana) obtained from a commercial nursery were transplanted manually on 18 April 1996 in 2 rows per plot with 70 cm between rows and 50 cm between plants Seedlings were dipped in Rovralreg 1 mLL just prior to planting for control of fungi Treflanreg (14 Lha) and Dacthalreg (12 kgha) were applied immediately after transplanting to control broadleaved weeds and Sertinreg later on in the life of the crop for grass control Ambushreg (100 mLha) and Rogorreg (100 mLha) were used to control caterpillars and red legged earth-mite respectively Copper sprays were used for control of blackrot The crop was irrigated to a total application equivalent to 100 of the previous days pan evaporation using minisprinklers (Legoreg 6 x 6 m spacing 44 mmh) in 3 waterings of equal duration per day
Fertilisers
Pre-planting fertilisers were broadcast manually and rotary hoed on 17 April 1996
These were K2S04(244) Ca (N03)2 4H20 (387) MgS047H20 (504) MnS04H20 (504) FeS047H20 (18) Borax (27) CuS045H20 (36) ZnSOH20 (28) and Na2Mo042H20 (2) Single superphosphate (91 P)was applied at 0 to 600 kgha according to treatment and incorporated as before Post-planting K N and Ca were fertigated via the irrigation system as KN03 NH4NO3 and Ca (N03)2 in equal amounts per day for 12 weeks to a total of 600 kg K 423 kg N and 60 kg Caha Borax was fertigated at 20 kgha in week 3 and Mg was broadcast as MgS047H20 at 50 kgha in weeks 3 6 and 9
Measurements
Soil and soil solution
All zero P subplots were sampled 30 cores per plot just prior to planting and fertilising about 2 months after AG application to 2 depths (0-15 15-30 cm) These were oven dried at 40degC and analysed for Ec pH (CaCl2) P sorption (Ozanne and Shaw 1968) bicarbonate extractable P K (Colwell 1963) total P PRI P sorption K sorption (Allen and Jeffery 1990) and cation exchange capacity (Gillman and Sumpter 1986)
The soil water was obtained by centrifugation from soil samples (0-15 cm 30 per plot) and collected from the 0 100 200 and 600 kg Pha plots across all AG treatments on 16 May 1996 The supernatant was analysed for pH Ec Ca Mg K S and P The remaining soil was analysed for pH (H20) bicarbonate extractable P and K PRI and DTPA extractable Zn After harvest on 5 August 1996 soil samples were collected from 2 depths as for the preplanting treatment from all plots These were analysed for pH bicarbonate extractable P K total P PRI and exchangeable cations (Ca Mg K and N)
Plant
At buttoning on 13 June 1996 the younger mature leaves (YML) (4th from growing point) were collected from 16 plants in each plot (excluding 1 m buffer at each end) They were dried at 70degC in a force draught oven for 48 h and ground to pass through a 1 mm screen Sub-samples were digested with sulphuric acidhydrogen peroxide (Yuen and Pollard 1954) and the concentration of N P and K measured by an automated colorimetric process (Varley 1966) Concentration of other nutrients (B Ca Na Mg S Fe Mn Zn and Cu) were determined by inductively coupled plasma atomic emission spectroscopy (ICP-AES) after digestion with nitric-perchloric acids (McQuaker et al 1979)
Five whole plants were harvested from the middle of each plot (2 per row)at the end of the experiment on 4 July 1996 using shovels to recover as much of the root system as possible The plants were separated into four categories curds leaves stems and roots All soil was washed from the roots using tap water shaken and the excess water removed using paper towels The fresh weight of all four categories was recorded and the material was diced into small pieces (lt 8 cm3) using stainless steel knives sub-samples (300 g fresh weight) were collected at random from the diced pieces and the fresh weight recorded These were dried at
31
The use of Red Mudgypsum in vegetable production
70degC in a forced draught oven for 48 h and the dry weight recorded These samples were then analysed for P as for the youngest mature leaves Separate sub-samples (300 g fresh weight) of curds were collected and analysed for Ba Cd Cr Co Pb Mo Rb Sr Ti Th V and N using inductively coupled plasma mass spectrometry (ICP-MS) The fresh and dry weight of the curds leaves stems and roots at harvest were used to calculate P uptake in kgha)
Harvest
Harvest commenced when the leaves surrounding the head opened and exposed the curds 77-80 days after transplanting At this stage florets at the periphery of the curd had just begun to separate Sixteen curds (12 plus 4 from whole plant samples above) were collected from the central 4 m of both rows (1 m buffer) and all the leaves and stems removed according to requirements for export market Each fresh curd was weighed and rejects recorded if undersize (lt 500 g) oversize (gt 2000 g) discoloured (yellowing) overmature (separation of florets in centre of curd) diseased damaged or otherwise distorted The total marketable and reject yield were recorded for each plot
Analysis of data
Analysis of variance was carried out on level of applied AG or P versus (a) chemical characteristics of soil (bicarbonate extractable P total P etc) preplanting and harvest (b) concentrations of nutrients in soil solution at midgrowth (c) concentration of nutrients in YMLs at midgrowth (d) concentration of elements in curds at harvest (e) P uptake by plant parts and (f) total marketable and reject yield of curds at harvest Mitscherlich curves and inverse polynomials were fitted to the relationship between level of applied P and yield at each level of applied AG The level of applied P required for 95 99 and 100 (in case of inverse polynomials) of maximum yield was calculated Mitscherlich curves were fitted to the relationship between level of applied P and P in YMLs at midgrowth at all levels of AG The P in YMLs corresponding to the level of applied P required for 95 99 or 100 of maximum yield (as determined from yield versus applied P plots) was then determined
Mitscherlich curves were also fitted to the relationship between level of applied P and P uptake by curds leaves stems and roots and the P uptake corresponding to whole plants (additions of all 4) level of P required for 95-100 of maximum yield determined Phosphorus uptake by plant parts or whole plants on 0 P plots were detected from P uptake at other rates to account for non-fertiliser sources of P This was used to adjust P uptake When determining P fertiliser recovery efficiency (RE) by plant parts or whole plants (ie fertiliser P uptake by plant parts or whole plantsP applied both in kgha Novoa and Loomis 1981)
Results
Effects of fresh AG on chemical characteristics of soil and soil solution
There was a significant (P lt 005) increase in the Ec pH PRI and sorption capacity (topsoil only) of the topsoil and subsoil of a yellow Karrakatta sand with level of freshly-applied AG prior to fertiliser application and planting (Table 51) There was no significant effect of level of AG on Colwell K K sorption capacity and total P with level of freshly-applied AG (Table 51)
The use of Red Mudgypsum in vegetable production
Table 51 Some chemical characteristics of the topsoil (0-15 cm) and subsoil (15-30 cm) of a yellow Karrakatta sand after application of Alkaloam gypsum (AG)1 just prior to fertiliser application and transplanting
(a) Topsoil (0-15 cm)
AG (tha)
Ec (mSm)
pH (CaCl2)
BicP2
(Vigfe)
BicK2
(pgg) PRI3
(mLg) TP4
(Pgg) CEC5
(me ) Kads6 Pads7
0 37 74 107 153 097 507 2 0 41
60 67 82 93 197 167 473 2 043 66
120 80 82 100 277 243 607 2 044 78
240 103 84 97 290 38 637 2 058 129
Lsd8 202 037 38 136 046 1010 0 049 41
Sig9 ns ns ns ns ns
(b) Subsoil (15-30 cm)
AG Ec PH BicP2 BicK2 PRI3 TP4
(tha) (mSm) (CaCl2) (Pgg) (Pgg) (mLg) (Pgg)
0 30 72 83 227 07 507
60 63 81 73 190 15 453
120 80 81 87 220 18 540
240 107 83 83 240 27 563
Lsd8 202 037 38 136 046 101
Sig9 ns ns ns
Applied 7 weeks previously 2 After Colwell (1963) 3 Phosphorus retention index after Allen and Jeffery (1990) 4 Total phosphorus 5 Cation exchange capacity (Gillman and Sumpter 1986) 6 Slope of K adsorption isotherm from the Freundlich equation (Allen and Jeffery 1990) 7 Slope of P adsorption isotherm from the Freundlich equation (Allen and Jeffery 1990) 8 Least significant difference at P lt 005 9 Significance at lt 0001 () lt 001 () lt 005 () level or not significant (ns)
There was a significant (P lt 005) increase in the concentration of Na and a decrease in the concentration of K in the soil solution with level of freshly-applied AG one month after planting and fertilising (Table 52 (a) and Fig 51) At the same time Colwell K and PRI in the topsoil increased significantly with level of freshly-applied AG By contrast there was a significant decrease in extractable Zn with level of AG The concentration of Ca Mg S and P increased significantly with level of applied P in soil solution (Table 52 (a)) Colwell P in the topsoil increased significantly with level of P whilst Colwell K PRI and extractable Zn decreased at the same time (Table 52 (b))
33
The use of Red Mudgypsum in vegetable production
Table 52 (a) Ec (mSm) pH and concentration of nutrients (pgmL) in soil solution 1 month after planting with level of freshly-applied Alkaloamreggypsum (AG)1 and phosphorus
AG
AG (tha)
Ec (mSm)
pH Ca (pgmL)
Mg (pgmL)
Na (pgmL)
K (pgmL)
S (pgmL)
P (pgmL)
Psrp2
(VigmL)
0 112 70 175 18 110 77 101 57 56
60 132 74 164 17 137 58 92 34 31
120 172 75 166 17 152 54 97 44 34
240 166 81 130 16 198 34 75 24 11
Lsd3 19 025 33 4 16 11 26 27 32
Sig4 ns ns ns ns ns
p
AG (tha)
Ec (mSm) PH
Ca (pgmL)
Mg (pgmL)
Na (pgmL)
K (pgmL)
S (UgmL)
P (pgmL)
Psrp2
(pgmL)
0 137 78 99 15 150 46 26 10 01
100 142 76 112 15 153 54 52 23 14
200 170 74 179 19 150 62 114 39 30
600 133 72 244 19 144 60 174 89 87
Lsd3 43 022 31 24 17 15 29 25 30
Sig4 ns ns ns
Applied 11 weeks previously
Soluble reactive P 3 Least significant difference at P lt 005 4 Significance at lt 0001 () lt 001 () lt 005 () level or not significant (ns)
The use of Red Mudgypsum in vegetable production
220
200
E 180 O ) 3
^ 1fi0 _ o 3 140 O V)
oil
120 m c
100 C o CO 80 c flgt o B0 c o o 40
20
0 50 100 150 200
Freshly-applied AG(tha)
250 300
Fig51 Concentration (ugml) of Na(i ) and K ( bull ) in soil solution (0-15cm) under cauliflowers one month after planting with level of freshly-applied AlkaloamRgypsum(AG) Vertical bars indicates Lsd (Plt005) for differences in concentration betweeen levels of AG
35
The use of Red Mudgypsum in vegetable production
Table 52 (b) Extractable P K Zn and phosphorus retention index of the top soil (0-15 cm) of a yellow Karrakatta sand 1 month after transplanting with level of freshly-applied Alkaloamreggypsum (AG)1 and phosphorus (P)
AG
AG (tha)
P2
(ugg) K2
(Ugg) Zn3
(Pgg)
PRI4
(mLg)
0 47 32 67 -112
60 76 38 15 -090
120 94 42 26 -049
240 84 41 13 092
Lsd5 35 6 28 073
Sig6 ns
P P2 K2 Zn3 PRI4
(kgha) (ugg) (Hgg) (Ugg) (mLg)
0 8 42 31 201 100 35 37 45 043 200 80 39 18 -089 600 177 34 26 -313
Lsd5 39 6 27 082
Sig6 ns
Applied 11 weeks previously 2 After Colwell (1963) 3 Extracted in DTPA 4 Phosphorus retention index (Allen and Jeffery 1990) 5 Least significant difference at P lt 005 6 Significance at lt 0001 () lt 001 () lt 005 () level or not significant (ns)
Ec pH exchangeable Ca K Na in me and Colwell P K total P PRI and PRIP increased significantly (P lt 005) with level of freshly-applied AG in the topsoil and subsoil of a yellow Karrakatta sand (Table 53 (a) (b) and Fig 52) at harvest
The use of Red Mudgypsum in vegetable production
o CO
CD
E
o CO
co o
CD
X co CD ogt e co sz o X HI
50 100 150 200
Freshly-applied AG (tha)
250 300
Fig52 Exchangeable Ca() NaP) and K(A) cations (me dry soil) in topsoil (0-15cm) of Karrakatta sand amended with freshly-applied AlkaloamRgypsum(AG) after harvest of cauliflowers Vertical bars indicates Lsd (Plt005) for differences in concentration between levels of AG Lsd not shown when less than size of symbol
37
The use of Red Mudgypsum in vegetable production
Table 53 Ec (mSm) pH and exchangeable Ca Mg K and Na (me ) in the topsoil (0-15 cm) and subsoil (15-30 cm) of a yellow Karrakatta sand amended with AlkaIoamreggypsum (AG) at harvest of cauliflowers
(a) Topsoil
AG Ec PH Ca Mg K Na (tha) (mSm) (CaCl2) (me ) (me ) (me ) (me )
0 67 66 229 018 005 003
60 91 77 382 019 009 02
120 99 79 558 019 012 043
240 120 80 975 024 014 104
Lsd2 20 014 064 0033 0018 021
Sig3 ns
(b) Subsoil
AG Ec pH Ca Mg K1 Na (tha) (mSm) (CaCl2) (me ) (me ) (me ) (me )
0 44 67 225 017 005 003
60 59 74 269 019 005 008
120 66 77 300 018 005 017
240 99 79 397 02 005 029
Lsd2 075 01 029 0036 001 002
Sig3 n s ns
Extracted in 1 m NH4CI 2 Least significant difference at P lt 005 3 Significance at lt 0001 () lt 001 () lt 005 () level or not significant (ns)
However there was no effect of either level of AG or P on exchangeable Mg in the soil at harvest Colwell P total P and PRIP increased significantly whilst Colwell K and PRI decreased with level of freshly-applied P in the topsoil at harvest (Table 4 (a) (b) and Fig 53)
The use of Red Mudgypsum in vegetable production
Table 54 P (extractable P total P phosphorus retention index and P sorption) in the top soil (0-15 cm) and subsoil (15-30 cm) of a yellow Karrakatta sand at harvest of cauliflowers with level of freshly-applied Alkaloamreggypsum (AG) and phosphorus (P)
(a) Topsoil
AG
AG BicP1 BicK1 TotP2 PRI3 PRIP3
(tha) (ugg) (Pgg) (Hgg) (mLg) (mLg)
0 39 23 92 -07 28
60 50 38 110 02 50
120 59 51 135 16 75
240 58 62 157 35 99
Lsd4 5 11 15 03 06
Sig5
P BicP1 BicK1 TotP2 PRI3 PRIP3
(kgha) (ugg) (Hgg) (ngg) (mLg) (mLg)
0 10 53 57 29 40
50 15 40 66 22 38
100 25 41 78 17 44
200 53 41 128 14 71
400 87 44 186 -01 86
600 120 41 226 -12 102
Lsd4 11 8 20 09 13
Sig5
1 After Colwell (1963) 2 After Allen and Jeffery (1990) 3 After Allen and Jeffery (1990) 4 Least significant difference at P lt 005 5 Significance at lt 0001 () lt 001 () lt 005 () level or not significant (ns)
39
The use of Red Mudgypsum in vegetable production
Table 54 P (extractable P total P phosphorus retention index and P sorption) in the top soil (0-15 cm) and subsoil (15-30 cm) of a yellow Karrakatta sand at harvest of cauliflowers with level of freshly-applied Alkaloamreggypsum (AG) and phosphorus (P)
(b) Subsoil (15-30 cm)
AG
AG BicP1 BicK1 TotP2 PRI3 PRIP3
(tha) (ugg) (Ugg) (Ugg) (mLg) (mLg)
0 33 20 79 -05 26
60 30 21 73 -01 30
120 33 27 77 08 42
240 26 24 76 13 40
Lsd4 10 2 10 04 10
Sig5 ns ns
P BicP1 BicK1 TotP2 PRI3 PREP3
(kgha) (ugg) (Vigg) (Ugg) (mLg) (mLg)
0 7 25 48 15 22
50 11 22 52 09 19
100 15 24 59 10 27
200 32 23 81 06 39
400 51 22 100 -03 47
600 67 21 117 -11 52
Lsd4 8 5 8 05 09
Sig5 ns
1 After Colwell (1963) 2 After Allen and Jeffery (1990) 3 After Allen and Jeffery (1990) 4 Least significant difference at P lt 005 5 Significance at lt 0001 () lt 001 () lt 005 () level or not significant (ns)
The use of Red Mudgypsum in vegetable production
100 150 200
Freshly-applied AG (tha)
300
Fig53 Concentration of total P(A) Colwell P() or K(laquo) in topsoil (0-15cm) with level of freshly-applied AlkaloamRgypsum (AG) after harvest of cauliflowers Vertical bars indicates Lsd (Plt005) for differences in concentration between levels of AG Lsd not shown when less than size of symbol
41
The use of Red Mudgypsum in vegetable production
Nutrients in leaves at midgrowth and harvest
There was a significant decrease in concentration of K and an increase in concentration of Na S Mn and Cu in youngest mature leaves (YML) of cauliflowers at buttoning with level of freshly-applied AG (Table 55) The concentration of P in YML at 01 AGha (049) was significantly higher than at 2401 AGha (044) but not at other levels Currently-applied AG had no significant effect on concentration of N Ca Mg Fe Zn or B in YML There was a significant increase in YML in the concentration of K P and S in YML with level of applied P whilst concentration of N Mg Mn and B were variable (Fig 54 55) Level of applied P had no significant effect on the concentration of Ca and Na in the YML (Table 55)
Table 55 (a) Concentration of macro-nutrients (dry weight basis) in youngest mature leaves of cauliflowers at buttoning with level of freshly-applied Alkaloamreggypsum (AG) and phosphorus (P)
AG
AG N1 K1 Ca2 S2 P1 Na2 Mg2
(tha) () () () () () () ()
0 482 393 240 081 049 036 023
60 484 383 251 084 046 040 024
120 506 357 255 081 046 045 024
240 494 355 246 088 044 056 025
Lsd3 026 012 024 005 003 006 0013
Sig4 ns ns ns ns
p
p N1 K1 Ca2 S2 P1 Na2 Mg2
(kgha) () () () () () () ()
0 523 316 254 066 024 046 025
50 489 372 255 081 041 049 026
100 503 388 229 084 048 042 024
200 472 379 250 089 050 046 024
400 494 390 242 093 057 043 023
600 470 385 258 091 057 039 022
Lsd3 027 024 036 005 003 008 0017
Sig4 ns ns
1 After Varley (1966) 2 After McQuaker et al (1979) 3 Least significant difference at P lt 005 4 Significance at lt 0001 () lt 001 () lt 005 () level or not significant (ns)
The use of Red Mudgypsum in vegetable production
0 50 100 150 200 250 300
Freshly-applied AG (tha)
Rg54 Concentration of N() K(B) and Ca(A) in youngest mature leaf (YML) at buttoning
of cauliflowers with level of freshly-applied AlkaloamRgypsum(AG) Vertical bars
indicates Lsd (Plt005) for differences in concentration between levels of AG
10
bdquo 09 lt Q OR ^ D) 07 c
tto
06 3
X3
to 05 _ l
gtbull 04 C
i3 03 c agt bull c 02 3
-z 01 0 50 100 150 200 250 300
Freshly-applied AG (tha)
Rg55 Concentration of S() Na(B) Mg(4) and P(T) in youngest mature leaf (YML) at buttoning
of cauliflowers with level of freshly-applied AlkaloamRgypsum(AG) Vertical bars indicates Lsd (Plt005) for differences in concentration between levels of AG
43
The use of Red Mudgypsum in vegetable production
The relationship between P in YML at buttoning and level of freshly-applied P was best described by Mitscherlich relationships at all levels of applied AG (Fig 56)
en c o 3
X2
gt
06
^
bull A
05 ^ S
04
03
02
01
n n i i i
0 100 200 300 400 500 600 700
Applied P (kgha)
o
X I
5 gt
06
05
04
03
02
01
00
- bull B
- bull bull ^
o
I I I I
0 100 200 300 400 500 600 700
Applied P (kgha)
100 200 300 400 500 600 700
Applied P (kgha)
100 200 300 400 500 600 700
Applied P (kgha)
Fig56 P in YML of Cauliflowers at buttoning () corresponding to applied P required for either 95 (dashed line) or 99 (whole line) of maximum yield at 0(A) 60(B) 120(C) or240(D)t of freshly-applied AlkaloamRgypsumha
The equations for the fitted lines are
A
B
C
D
y = 056 - 030 x exp (-00182) (R2 = 097)
y = 057 - 032 x exp (-00103) (R2 = 088)
y = 055 - 031 x exp (-00126) (R2 = 099)
y = 056 - 032 x exp (-00092) (R2 = 098)
The P in YML corresponding to level of freshly-applied P required for 99 of maximum yield was 053 057 055 and 055 for 0 60 120 and 240 tha respectively
44
The use of Red Mudgypsum in vegetable production
Table 55 (b) Concentration of micro-nutrients (dry weight basis) in youngest mature leaves of cauliflowers at buttoning with freshly-applied Alkaloamreggypsum (AG) and phosphorus (P)
AG
AG (tha)
Fe (Pgg)
Zn (Ugg)
Mn (vigg)
B (Pgg)
Cu1
(Pgg)
0 1354 251 217 211 26
60 1274 248 237 213 28
120 1353 253 240 217 27
240 1394 263 260 214 29
Lsd2 153 24 15 082 02
Sig3 ns ns ns
P Fe Zn Mn B Cu (kgha) (ngg) (ugg) (Pgg) (Ugg) (Pgg)
0 1418 268 212 215 26
50 1388 253 263 220 27
100 1301 267 251 217 29
200 1336 249 250 217 28
400 1282 255 232 204 28
600 1341 233 224 210 28
Lsd2 197 29 19 08 02
Sig3 ns ns ns
1 Extracted in 1 m NH4CI 2 Least significant difference at P lt 005 3 Significance at lt 0001 () lt 001 () lt 005 () level or not significant (ns)
There was a significant (P lt 005) decrease in the concentration of P Zn and an increase in the concentration of Na in whole leaves (WL) of cauliflowers with rate of freshly-applied AG at harvest (Table 56) Level of freshly-applied AG had no significant effect on concentration of N K Ca S Mg Fe Mn B or Cu Concentration of Ca S P and Na in (WL) at harvest increased significantly (P lt 005) with level of freshly-applied P whereas Zn concentrations decreased and concentrations of Mg Mn and B were variable Level of freshly-applied P had no significant effect on concentration of N K Fe or Cu in WL at harvest
45
A O O ltyi
4x
r en 00
9 400 200 o o o copy
ns
O
kgt ON
kgt
4gt
kgt 4 4 4^
kgt
ns
O 4 4 ON 4 k)
o
i mdash t mdash raquo
4 00
4 ON
4 4^ NO Q O
o copy ON
i mdash gt
b b 1 mdash t
b o p Vcopy
O 00 ON
o ON
gtmdash 5 co 5J M
o o
O in
o 4 Ncopy
o 4 O
p 4
p kgt 1 mdash t
copy
ON
o b NO
O ON
o 00
o 00
o ON I mdash
O ON
O 3 Z 5 raquoM
o b 4
O
kgt o kgt -J
p kgt 00
O kgt 00
O
kgt NO
copy kgt ON
The use of Red Mudgypsum in vegetable production
Table 56 (b) Concentration of micro-nutrients (dry weight basis) in leaves of cauliflowers at harvest with level of freshly-applied Alkaloamreggypsum (AG) and phosphorus (P)
AG
AG (tha)
Fe1
(ugg) Zn1
(vgg) Mn1
(vgg) B1
(vgg) Cu1
(vigg)
0 762 224 214 263 42
60 700 197 227 265 38
120 811 196 216 254 38
240 842 193 236 256 37
Lsd2 132 099 21 16 06
Sig3 ns ns ns ns
P (kgha)
Fe1
(pgg) Zn1
(^gg) Mn1
(Vigg) B1
(lJgg) Cu1
(Pgg)
0 786 233 213 248 36
50 625 235 241 266 37
100 833 207 237 270 41
200 938 192 235 265 44
400 725 178 208 259 37
600 765 169 206 250 37
Lsd2 230 21 21 11 063
Sig3 ns ns
After McQuaker et al (1979)
Least significant difference at P lt 005
Significance at lt 0001 () lt 001 () lt 005 () level or not significant (ns)
47
The use of Red Mudgypsum in vegetable production
Nutrients and heavy metals in curds at harvest
There was a significant (P lt 005) decrease in the concentration of K and P and an increase in the concentration of Ca and Na in the curds at harvest with level of freshly-applied AG Concentration of N Mg Fe Zn Mn B and Cu in the curds were unaffected by level of freshly-applied AG (Table 57) As level of freshly-applied P increased there was a significant (P lt 005) decrease in concentration of N S Mg Fe Zn Mn and B and an increase in concentration of K Ca P and Na in curds at harvest Concentration of Cu in curds were unaffected by level of applied P (Table 57 (b))
Table 57 (a) Concentration of macro-nutrients (dry weight basis) in curds of cauliflowers at harvest with level of freshly-applied Alkaloamreggypsum (AG) and phosphorus (P)
AG
AG N1 K1 Ca S1 P2 Na1 Mg1
(tha) () () () () () () ()
0 392 515 040 066 047 023 018
60 384 500 040 067 045 023 017
120 404 474 043 071 043 024 018
240 402 458 041 071 041 028 018
Lsd3 022 016 001 004 002 002 0006
Sig4 ns + ns ns
P
p N1 K1 Ca1 S1 P2 Na1 Mg1
(kgha) () () () () () () ()
0 496 417 034 097 031 016 019
50 400 518 043 068 040 023 018
100 376 483 042 063 042 025 017
200 372 501 044 063 047 027 017
400 371 498 042 062 052 028 017
600 358 505 041 060 052 027 016
Lsd3 027 02 003 005 002 003 001
Sig4
1 After McQuaker et al (1979) 2 After Varley (1966) 3 Least significant difference at P lt 005 4 Significance at lt 0001 () lt 001 () lt 005 () level or not significant (ns)
The use of Red Mudgypsum in vegetable production
Table 57 (b) Concentration of micro-nutrients1 (dry weight basis) in curds Cauliflowers at harvest with level of freshly-applied Alkaloam gypsum (AG) and phosphorus (P)
AG
AG (tha)
Fe1
(Ugg)
Zn1
(vigg) Mn1
(Pgg) B1
(Pgg) Cu1
(Pgg)
0 611 279 124 188 26
60 587 247 134 191 25
120 706 299 139 192 29
240 592 268 145 186 25
Lsd2 329 57 14 08 06
Sig3 ns ns ns ns ns
p
p (kgha)
Fe1
(Ugg) Zn1
(Pgg) Mn1
(Ugg) B1
(ugg)
Cu1
(Pgg)
0 976 492 156 202 31
50 520 279 145 198 26
100 507 230 135 186 24
200 432 208 127 190 24
400 739 239 131 183 28
600 567 192 120 177 24
Lsd2 270 61 142 114 061
Sig3 a s
1 After McQuaker et al (1979) 2 Least significant difference at P lt 005 3 Significance at lt 0001 () lt 001 () lt 005 () level or not significant (ns)
49
The use of Red Mudgypsum in vegetable production
Concentration of Ba in curds at harvest decreased and concentration of Ti increased significantly in curds at harvest with level of freshly-applied P (Table 58) As level of freshly-applied P increased concentrations of Pb and Rb decreased and of Sr decreased Ba concentrations were variable with level of freshly-applied P (Table 58)
Table 58 Concentration of Ba plus heavy metals1 (fresh weight basis) in curds of cauliflowers at harvest with level of freshly-applied Alkaloamreggypsum (AG) and phosphorus (P)
AG Ba Cd Cr Co Pb Ni Rb Sr Ti Th V (tha) (ngg) (ngg) (ngg) (ngg) (ngg) (ngg) (ngg) (ngg) (ngg) (ngg) (ngg)
0 797 7 34 7 13 34 590 1219 34 39 7
60 482 7 34 7 15 34 610 1146 46 52 8
120 583 7 43 7 20 34 616 1246 45 50 8
240 355 7 34 7 15 34 637 1152 41 45 8
Lsd2 141 1 13 16 11 15 74 188 5 16 1
Sig3 ns ns ns ns ns ns ns ns ns
MRL4 50 2000
P (kgha)
Ba (ngg)
Cd (ngg)
Cr (ngg)
Co (ngg)
Pb (ngg)
Ni
(ngg)
Rb (ngg)
Sr (ngg)
Ti
(ngg)
Th
(ngg)
V (ngg)
0 556 7 34 7 25 34 650 998 39 45 9
50 670 7 34 7 18 34 657 1387 50 74 9
100 576 7 34 7 11 34 570 1206 45 50 8
200 529 7 34 7 12 34 616 1293 39 39 7
400 523 7 48 7 19 39 596 1126 39 36 7
600 476 7 34 7 11 34 603 1126 36 36 7
Lsd2 121 1 16 1 15 6 40 181 19 29 2
Sig3 ns ns ns ns ns ns ns ns
MRL4 50 2000
Inductively coupled plasma mass spectrometry 2 Least significant difference at P lt 005 3 Significance at lt 0001 () lt 001 () lt 005 () level or not significant (ns) 4 Maximum residue limit
The use of Red Mudgypsum in vegetable production
P uptake by plants P uptake by whole plants or plant parts was unaffected by level of freshly-applied AG by but increased significantly with level of freshly-applied P (Table 59)
P uptake by whole plants increased from 50 kg Pha to 19 to 21 kgha at 400 to 600 kg applied Pha respectively Curd root stem and leaf uptake was 33 5 6 and 50 respectively of total plant P uptake at the highest level of applied P (Table 59)
Table 59 P uptake (kgha) by curds roots stem leaf and whole cauliflower plants at harvest with level of freshly-applied Alkaloamreggypsum (AG) and phosphorus (P)
AG
AG Curds Roots Stem Leaf Total (tha) (kgha) (kgha) (kgha) (kgha) (kgha)
0 53 074 11 87 158
60 48 066 10 83 148
120 47 069 11 79 143
240 45 060 10 74 135
Lsd1 065 015 025 21 31
Sig-2 ns ns ns ns ns
p
p (kgha)
Curd (kgha)
Root (kgha)
Stem (kgha)
Leaf (kgha)
Total (kgha)
0 12 030 040 29 49
50 40 058 100 68 124
100 51 053 112 76 143
200 59 075 120 93 172
400 67 093 131 115 205
600 61 094 121 102 185
Ls-d1 055 017 020 18 25
Sig2
1 Least significant difference at P lt 005 2 Significance at lt 0001 () lt 001 () lt 005 () level or not significant (ns)
51
The use of Red Mudgypsum in vegetable production
Yield
There was a significant (P lt 005) increase in both total and marketable curd yield with level of freshly-applied P at all levels of freshly-applied AG (Table 510) There was no significant effect of level of freshly-applied AG on either total (Table 510 (a)) or marketable (Table 510 (b)) curd yield
Table 510 Curd yield (total marketable) of cauliflowers (tha) at harvest with level of freshly-applied Alkaloamreggypsum (AG) and phosphorus (P)
(a) Total
p (kgha)
AG (tha) p
(kgha) 0 60 120 240
0 755 468 483 177
50 1464 1675 1554 1516
100 2169 1706 1757 1985
200 2242 1737 1928 1862
400 1752 2102 2155 2136
600 1689 1764 1768 2023
Lsd1
Sig2
16 (AG)
ns 201 (P)
401 (AGP)
-
(b) Marketable
p (kgha)
AG (tha) p
(kgha) 0 60 120 240
0 274 060 000 000
50 1222 1463 1294 1152
100 2057 1416 1603 1820
200 2141 1377 1803 1752
400 1572 2020 2095 1996
600 1468 1534 1500 1974
Lsd1
Sig2
24 (AG)
ns
46 (P)
52(AGP)
ns
Least significant difference at P lt 005 2 Significance at lt 0001 () lt 001 () lt 005 () level or not significant (ns)
The relationship between total yield and level of freshly-applied P was best described by a quadratic relationship at all levels of freshly-applied AG (Fig 57) As level of AG increased the level of freshly-applied P required for 99 of maximum yield increase from 124 kg Pha at 0 t AGha to 339 kg Pha at 240 tha There was no significant effect of level of freshly-applied AG on maximum curd yield (Fig 57)
The use of Red Mudgypsum in vegetable production
26
24
22
(tha
) 20
18
Cur
d yi
eld 16
14
12
10
8
6 i ii
A=0
i i i i i
I I
0 100200300400500600700
Applied P (kgha)
24 22 20 18 16 14 12 10 8 6 4 2
- 7 I
_ bull
i i i n
mdash^ B=60
I I I
0 100200300400500600700
Applied P (kgha)
co
32 CD
gt 2 3
o
25
20
15
10
5
bull j
- bull
I I I I I
- - gt C=120
l l l
0 100200300400500600700
Applied P (kgha)
0 100200300400500600700
Applied P (kgha)
Fig57 Total curd yield (tha) of cauliflower with level of freshly-applied Alkaloam gypsum and
phosphorus (ABCD = 060120240 tha) Vertical lines represent applied P necessary
for either 95 (dashed) or 99 (whole) of maximum yield
The equations for the fitted lines are
A y = 1336 + (-577 + 01335x)(l-00088x +000007872) (Z2
B y = 89434 + 00705 - OOOOlx2 (R2 = 070)
C y = 84752 + 00810 - OOOOlx2 (B2 = 081)
D y = 733 +00871x - 00001 Ix2 (R2 = 099)
098)
53
The use of Red Mudgypsum in vegetable production
Discussion
The increase in pH Ec PRI and P sorption of Karrakatta sands with level of freshly-applied AG prior to fertiliser application is similar to that reported for the amendment of Joel (McPharlin et al 1994 and Robertson et al 1997a) and Karrakatta sands (Robertson et al 1994 and 1997b) with AG The increase in DH and Ec of the amended soil is explained by the high levels of both in the AG (ie pH (CaCr) = 94 and Ec = 623 mSm Appendix 1) The increased retentionsorption of P is explained by the addition of iron (974) and aluminium (551) in various oxides and hydroxides in the AG (Appendix 1 and Barrow 1982) to the soil After the application of P fertilisers levels of P in the soil at mid-growth and harvest as measured by total and Colwell P increased with a parallel decrease in PRI The increase in the levels of exchangeable Ca and Na in the soil at the same times with level of freshly-applied AG can be attributed to the AG itself However the increase in exchangeable and Colwell K appears to be due to improved K retention capacity of the soil due to physical properties of the AG rather any increased supply of K from the AG Whilst the overall K adsorption properties of the soil as measured by the Freundlich isotherm was not significantly increased with level of AG K sorption at 2401 AGha was significantly higher than at 01 AGha
There was no significant increase in cation exchange capacity (CEC) with level of freshly-applied AG on the Karrakatta sand in this experiment which remained about 2 me By contrast the CEC of virgin Joel sands increased from 1 to 2 me with level of freshly-applied AG (0 to 240 tha) in columns (McPharlin et al 1994) The application of AG would be expected to increase the CEC of coarse sands because (1) AG a fine textured material (10 clay 68 silt) (Ward 1983) would increase the fine fraction when applied to sands (2) AG has a much higher CEC ie 7 to 15 me depending on pH (Barrow 1982) than either Joel or Karrakatta sands ie 1 to 2 me (McPharlin et al 1994 and Table 51) and (3) application of AG to either Joel or Karrakatta sands increases the retentionreduces leaching of cations either not present in the AG such as NH4-N (McPharlin et al 1994) or only present in small quantities such as K (Tables 52 53 54 and Appendix 51)
The concentration of an element in the soil expressed as either extractable or total amounts represents the quantity or extensive factor in terms of plant nutrition as outlined by Holford and Mattingly (1976) The concentration of ions in soil solution or the intensive factor may better represent what is available to the plant A good example of this is the levels of K in the soil expressed as either Colwell or exchangeable K which increase significantly with level of applied AG However levels of K in the plant YML at buttoning and curds at harvest decrease significantly with level of AG K in soil solution 1 month after planting similarly decline significantly with level of applied AG and are therefore better correlated with K nutrition of the plant than measurements based on the dry soil Similarly P concentrations in the plant and soil solution decline whilst P retained by the soil increase in response to freshly-applied AG By contrast concentrations of Na in soil solution soil and plant all increase with levels of freshly-applied AG Similar relationships between concentrations of K Na and P in the soil soil solution and plant on a Karrakatta sand have been reported previously (Robertson et al 1997)
In previous work maximum yield (ie A value) of cauliflowers was reduced when freshly prepared AG was applied at levels gt 120 tha (Robertson et al 1994) This yield reduction was assumed not to be due to induced P deficiency resulting form high level of applied AG as it could not be alleviated by increased levels of applied P Although increased levels of applied P were needed to maximise yield as the level of freshly-applied AG increased Concentrations of K decreased and Na increased in the YML with level of applied AG and the yield reduction was assumed to be due either induced K deficiency or Na toxicity However neither the reduced concentrations of K or the increased concentrations of Na in the plant were at levels that would reduce yield according to published standards (Weir and Cresswell 1993) Antagonism between Na and K uptake by plants is common (Yeo 1983) For example increasing soil salinity resulted in increased concentrations of Na and decreased concentrations of K in the leaves of Zucchini grown in controlled greenhouses in Spain (Villora et al 1997)
The use of Red Mudgypsum in vegetable production
In this work as level of freshly-apphed AG increased level of applied P necessary for maximum yield increased as in the previous work however maximum yield was not reduced by AG up to 240 tha This is despite concentrations of K in the YML decreasing and Na increasing in response to level of freshly-applied AG However as in the previous work neither concentrations of K or Na were at levels expected to cause yield reduction By contrast the reduction in maximum yield of potatoes at high levels of freshly-applied AG (ie gt 120 tha) was correlated with a reduced concentration of K in the petioles (Robertson et al 1997b)
The level of freshly-applied P required for 99 of maximum yield in this work increased from 124 kgha at 01 AGHa to 339 kgha at 2401 AGha These levels of applied P are similar to that reported necessary for maximum yield of cauliflowers on AG-amended (Robertson et al 1994) or unamended (McPharlin et al 1995) Karrakatta sands The P required for 99 of maximum yield in this work 053 to 057 was either slightly higher - 047 (McPharlin et al 1995) or within range - 05 to 07 (Piggott 1986) 03 toO7 (Weir and Cresswell 1993) of that reported as critical or adequate for maximum yield of cauliflowers
Increased levels of freshly-applied AG did not significantly change the concentrations of Cd Co Cr Pb Ni Rb Sr Th or V in the curds of cauliflowers By contrast concentrations of Ba were significantly reduced and Ti increased in the curds with levels of freshly-applied AG Similarly there was no reported change in concentration of Cd Cr Pb or Co with level of freshly-applied AG in curds of cauliflower grown on Karrakatta sands (Robertson et al 1994) in previous work Also there was no change in Ba concentration in curds with level of AG in contrast to the previous work
References
Barrow NJ (1982) Possibility of using caustic residue from bauxite for improving the chemical and physical properties of sandy soils Australian Journal of Soil Research 33 275-285
Holford ICR and Mattingly GEG (1976) Phosphate adsorption and plant availability of phosphate Plant and Soil 44 377-89
McArthur and Bettenay (1960) The development and distribution of the soils of the Swan Coastal Plain Western Australia Soils Publication No 16 CSIRO Division of Soils CSIRO Melbourne Australia
McPharlin IR JefFery RC Toussaint LF and Cooper M (1994) Phosphorus Nitrogen and Radionuclide Retention and Leaching from a Joel Sand amended with Red Mudgypsum Communications in Soil Science and Plant Analysis 25 (17 amp 18) 2925-2944
McPharlin IR Robertson WJ JefFery RC and Weissberg R (1995) Response of cauliflower to phosphate fertiliser placement and soil test phosphorus calibration on a Karrakatta sand Communications in Soil Science and Plant Analysis 26(3amp4) 607-620
McQuaker NR Brown DF and Kluckner PD (1979) Digestion of environmental materials for analysis by inductively coupled plasma-atomic emission spectrometry Analytical Chemistry 51 1082-1084
Piggott TJ (1986) Vegetable crops pp 148-187 In DJ Reuter and JB Robinson (eds) Plant Analysis an Interpretation manual Inkata Press Melbourne Australia
Robertson WJ McPharlin IR and JefFery RC (1994) Final report of investigation into the use of gypsum-amended Red Mud as a soil-amendment on horticultural properties on the Swan Coastal Plain Report to HRDC (Project No V0039RO) Department of Agriculture Western Australia
55
The use of Red Mudgypsum in vegetable production
Robertson WJ Jeffery RC and McPharlin IR (1997a) Residues from bauxite-mining (Red Mud) increase phosphorus retention of a Joel sand without reducing yield of carrots Communications in Soil Science and Plant Analysis 28 (in press)
Robertson WJ McPharlin IR and Jeffery RC (1997b) The growth nutrition and mineral composition of potatoes (Solanum tuberosum L) cv Delaware grown on an yellow Karrakatta sand amended with freshly-applied and residual Alkaloamreggypsum (Submitted to AJEA)
Varley J A (1966) Automatic methods for the determination of nitrogen phosphorus and potassium in plant material Analyst 91 119-126
Villora G Pulgar G Moreno DA and Romero L (1997) Effect of salinity treatments on nutrient concentration in Zucchini plants (Cucurbita pepo L var Moschatd) Australian Journal of Experimental Agriculture 37 605-608
Vlahos S Summers KJ Bell DT and Gilkes RJ (1989) Reducing phosphorus leaching from sandy soils with Red Mud bauxite processing residues Australian Journal of Soil Research 27 651-662
Weir RG and Cresswell GC (1993) Plant Nutrient Disorders 3 Vegetable crops p 93 Inkata Press Melbourne Australia
Yuen SH and Pollard AG (1954) Determination of nitrogen in agricultural material by the Nessler reagent II Micro determination in plant tissue and soil extracts Journal of the Science of Food and Agriculture 5 364-369
The use of Red Mudgypsum in vegetable production
Appendix 51 Chemical and physical characteristics of Alkaloam gypsum used in cauliflower experiment (freshly-applied Alkaloamreggypsum)
Parameter Units Value Kgt
Ec mSm 623 -
pH (H 20) mSm 99 -
pH (CaCl2) mSm 94 -
PRI mLg 610 - gt 1000 -
LOI 1973 -
C a C 0 3 1290 1290
Fe (Fe203) 974 974
Al (A1203) 551 551
Si (Si0 2 ) 797 797
Ca (CaO) 45 450
Na (Na 2 0) 228 228
Ti (Ti0 2 ) 174 174
K (K 2 0) 072 72
Mg (MgO) 028 28 sect 047 47
P (P2O5) 005 05
Mn (MnO) 002 02
Total P ngg 266 -
Extractable P M-gg 58 -
Extractable K M-gg 43 -
As ngg 35 -
Ba ^gg 413 -
Cu Ugg 29 -
Sr Hgg 287 -
Nb Hgg 99 -y Hgg 866 -
Zr fAgg 1477 -
Sand 232 -
Silt 473 -
Clay 295 -
After Allen and Jeffery (1990)
Based on X-ray fluorescence (XRF) spectrometry
After Colwell (1963)
The use of Red Mudgypsum in vegetable production
Appendix 52 Concentration of Ba plus heavy metals1 (dry weight basis) in curds of cauliflowers at harvest with level of freshly-applied Alkaloamreggypsum (AG) and phosphorus (P)
(a)
AG Ba Cd Cr Co Pb Ni Rb Sr Ti Th V (tha) (Pgg) (vigg) (ugg) (ugg) (Pgg) (Pgg) (Pgg) (ugg) (Pgg) (Pgg) (Pgg)
0 119 010 050 010 020 050 88 182 050 058 010
60 72 010 050 010 022 050 91 171 069 078 012
120 87 011 064 011 030 050 92 186 067 075 012
240 53 011 05 010 023 050 95 172 061 067 012
Lsd2 21 002 02 024 016 022 11 28 008 024 002
Sig3 ns ns ns ns ns ns ns ns ns
(b)
p (kgha)
Ba (vgg)
Cd (vigg)
Cr (Pgg)
Co (ngg)
Pb (vgg)
Ni (Pgg)
Rb (Pgg)
Sr (Pgg)
Ti
(Pgg)
Th (Pgg)
V
(Pgg)
0 83 010 050 010 038 050 97 149 058 067 013
50 100 011 050 010 027 050 98 207 075 110 013
100 86 010 050 010 017 050 85 180 067 075 012
200 79 010 050 010 018 050 92 193 058 058 010
400 78 011 071 011 028 058 89 168 058 054 011
600 71 010 050 010 016 050 90 168 054 054 010
Lsd2 18 002 024 0009 022 009 06 27 028 044 003
Sig3 ns ns ns ns ns ns ns ns
Inductively coupled plasma mass spectrometry
Least significant difference at P lt 005
Significance at lt 0001 () lt 001 () lt 005 () level or not significant (ns)
The use of Red Mudgypsum in vegetable production
6 RESPONSE OF CAULIFLOWERS TO RESIDUAL RED MUD (ALKALOAMreg)GYPSUM (AG) AND PHOSPHORUS ON A YELLOW KARRAKATTA SAND
Introduction
It is important to reduce the leaching of phosphorus fertiliser from sandy soils used for vegetable production into the water systems of the Swan Coastal Plain Red Mud (Alkaloam )gypsum (AG) (ie Red Mudgypsum RMG) a waste product from bauxite refining has been suggested as an amendment to reduce phosphorus leaching from sands of the Bassendean Association (Joel Gavin) used for agriculture and horticulture (Barrow 1982)
Experimental work in the field and pots showed amendment with AG significantly reduced P leaching from Joel and Gavin sands (Vlahos et al 1989 McPharlin et al 1994) compared with the unamended (01 RMGha) treatment
Previous work showed a significant reduction in maximum yield of cauliflowers with levels of residual AG of gt 60 tha compared with 01 AGha (Robertson et al 1994) This yield reduction was not due to P deficiency as increased levels of applied P did not obviate the problem Nor was it due to K deficiency as K concentrations in the youngest mature leaves (YML) although reduced by levels of residual AG did not decline to levels expected to reduce yield The converse was true for concentrations of Na in the YML which increased with levels of residual AG but not to concentrations expected to cause toxicity
Since more than 60 tha of AG may be required to significantly improve P retention by sands to enable sustainable horticultural production this yield reduction is re-examined with residual AG
Materials and methods
Site characteristics
The experiment was conducted on a yellow Karrakatta sand (McArthur and Bettenay 1960) at Medina Research Centre (32deg 13 S 115deg 49 E) 30 km south of Perth Both Alkaloamreggypsum (AG) and phosphorus had previously been applied to the site and a potato crop grown in 1995 Prior to that the site had been sown to pasture for several years Some relevant chemical characteristics of the topsoil (0-15 cm) and subsoil (15-30 cm) of the site after application of AG but prior to the application of fertiliser (except residual P) and transplanting are presented in Table 61
Red Mud (Alkaloamreg)gypsum
Alkaloamreg (Red Mud) amended with 10 (ww) gypsum (AG) was produced by the dry mix process by ALCOA of Australia Ltd at their Kwinana Residue Treatment Plant The AG had been spread manually on the site and incorporated using a rotary hoe to approximately 30 cm depth on 22 December 1994 Residual P had been applied just before planting of the previous potato crop on 17 May 1995 and incorporated with a rotary hoe The site was watered for 1 hour per day (8 mmday) using impact sprinklers until planting
Experimental design
The experimental design was a split-plot randomised block with 3 replicates The main plots were levels of AG (0 60 90 120 and 240 tha) and the sub-plots were levels of freshly-applied P (25 50 100 300 and 600 kgha) Main plots measured 7 x 12 m and sub-plots 12 x 7 m (excluding wheel tracks)
59
The use of Red Mudgypsum in vegetable production
Crop management
The site was sprayed with Roundupreg (3 Lha) twice after application of AG and prior to planting to control weeds Six week old seedlings of cauliflowers (cv Plana) obtained from a commercial nursery were transplanted manually on 18 April 1996 in 2 rows per plot with 70 cm between rows and 50 cm between plants Seedlings were dipped in Rovralreg (1 mLL) just prior to planting for control of fungi Treflanreg (14 Lha) and Dacthalreg (12 kgha) were applied immediately after transplanting to control broadleaved weeds and Sertinreg later on in the life of the crop for grass control Ambushreg (100 mLha) and Rogorreg (100 mLha) were used to control caterpillars and red legged earth-mite respectively Copper was applied for control of blackrot The crop was irrigated to a total application equivalent to 100 of the previous days pan evaporation using minisprinklers (Legoreg 6 x 6 m spacing 44 mmh) in 3 waterings of equal duration per day
Fertilisers
Pre-planting fertilisers were broadcast manually and rotary hoed on 17 April 1996
These were K2S04(244) Ca(N03)2(387) MgS047H20 (504) MnS04H20 (504) FeS047H20 (18) Borax (27) CuS045H20 (36) ZnSOH20 (28) and Na2Mo042H20 (2) P was applied as single superphosphate (91 P) at 0 to 600 kg Pha according to treatment and incorporated as before Post-planting K N and Ca were fertigated via the irrigation system as KN03 NHUNO3 and Ca (N03)2 in equal amounts per day for 12 weeks to a total of 600 kg Kha 423 kg Nha and 60 kg Caha Borax was fertigated at 20 kgha in week 3 and Mg was broadcast as MgS047H20 at 50 kgha in weeks 3 6 and 9
Measurements
Soil and soil solution
All zero P subplots were sampled 30 cores per plot just prior to planting and fertilising about 2 months after AG application to 2 depths (0-15 15-30 cm) These were oven dried at 40degC and analysed for Ec pH (CaCl2) P sorption (Ozane and Shaw 1968) bicarbonate extractable P K (Colwell 1963) total P PRI P sorption K sorption (Allen and Jeffery 1990) and cation exchange capacity (Gillman and Sumpter 1986)
The soil water was obtained by centrifugation from soil samples (0-15 cm 30 per plot) and collected from the 0 100 200 and 600 kg Pha plots across all AG treatments on the 16 May 1996 The supernatant was analysed for pH Ec Ca Mg K S and P The remaining soil was analysed for pH (H20) bicarbonate extractable P K PRI and DTPA extractable Zn After harvest 5 August 1997 soil samples were collected from 2 depths as for the preplanting treatment from all plots These were analysed for pH bicarbonate extractable P K total P PRI and exchangeable cations (Ca Mg K and N)
Plant
At buttoning on 13 June 1996 the younger mature leaves (YML) (4th from growing point) were collected from 16 plants (excluding 1 m buffer at each end of plot) in each plot They were dried at 70degC in a force draught oven for 48 h and ground to pass through a 1 mm screen Sub-samples were digested with sulphuric acidhydrogen peroxide (Yuen and Pollard 1954) and the concentration of N P and K measured by an automated colorimetric process (Varley 1966) Concentration of other nutrients (B Ca Na Mg S Fe Mn Zn and Cu) were determined by inductively coupled plasma atomic emission spectroscopy (ICP-AES) after digestion with nitric-perchloric acids (McQuaker et al 1979) Five whole plants were harvested from the middle of each plot (2 per row) at the end of the experiment on 4 July 1996 using shovels to remove as much of the roots as possible The plants were separated into four categories curds leaves stems and roots All soil was dried and digested as for ICP-AES as above and washed from the roots using tap water shaken and the excess water removed using paper towels The fresh weight of all four categories was recorded and the material was diced
60
The use of Red Mudgypsum in vegetable production
into small pieces (lt 8 cm3) using stainless steel knifes sub-samples (300 g fresh weight) were collected at random from the diced pieces and the fresh weight recorded These were dried at 70degC in a forced draught oven for 48 h and the dry weight recorded These samples were then analysed for P as for the youngest mature leaves Separate sub-samples (300 g fresh weight) of curds were collected and analysed for Ba Cd Cr Co Pb Mo Rb Sr Ti Th V and Ni using inductively coupled plasma mass spectrometry (ICP-MS) The fresh and dry weight of the curds leaves stems and roots at harvest were used to calculate P uptake in kgha)
Harvest
Harvest commenced when the leaves surrounding the head opened and exposed the curds 77-80 days after transplanting At this stage florets at the periphery of the curd had just begun to separate Sixteen curds (12 plus 4 from whole plant samples above) were collected from the central 4 m of both rows (1 m buffer) and then all the leaves and stems removed according to requirements for export market Each fresh curd was weighed and rejects recorded if undersize (lt 500 g) oversize (gt 2000 g) discoloured (yellowing) overmature (separation of florets in the centre of curd) diseased damaged or otherwise distorted The total marketable and reject yield were recorded for each plot
Analysis of data
Analysis of variance was carried out on level of applied AG or P versus (a) chemical characteristics of soil (bicarbonate extractable P total P etc) preplanting and harvest (b) concentrations of nutrients in soil solution at midgrowth (c) concentration of nutrients in YMLs at midgrowth (d) concentration of elements in curds at harvest (e) P uptake by plant parts and (f) total marketable and reject yield of curds at harvest Mitscherlich curves and inverse polynomials were fitted to the relationship between level of applied P and yield at each level of applied AG The level of applied P required for 95 99 and 100 (in case of inverse polynomials) of maximum yield was calculated Mitscherlich curves were fitted to the relationship between level of applied P and P in YMLs at midgrowth at all levels of AG The P in YMLs corresponding to the level of applied P required for 95 99 or 100 of maximum yield (as determined from yield versus applied P plots) was then determined
Mitscherlich curves were also fitted to the relationship between level of applied P and P uptake by curds leaves stems and roots and the P uptake corresponding to whole plants (additions of all 4) level of P required for 95-100 of maximum yield determined Phosphorus uptake by plant parts or whole plants on 0 P plots were deducted from P uptake at other rates to account for non-fertiliser sources of P This was used to adjust P uptake when determining P fertiliser recovery efficiency (RE) by plant parts or whole plants ie fertiliser P uptake by plant parts or whole plantsP applied both in kgha (Novoa and Loomis 1981)
The effect of residual AG andP on chemical characteristics of the soil
Increased levels of previously-applied (residual) AG resulted in a significant increase in Ec pH (CaCl2) Colwell P and PRI in the topsoil (0-15 cm) of a Karrakatta sand prior to current the application of fertilisers and planting (Table 61 Fig 61) There was no significant effect of level of residual AG on the levels of Colwell K in the topsoil Increasing levels of previously-applied (residual) P resulted in a significant increase in Colwell P and a decrease in PRI and pH at the same time but had no effect on the levels of Colwell K in the topsoil
61
The use of Red Mudgypsum in vegetable production
Table 61 Chemical characteristics of the topsoil (0-15 cm) of a yellow Karrakatta sand 12 months after application of Alkaloamreggypsum (AG) (residual AG) and phosphorus (P) just prior to fertiliser application and transplanting
AG Ec pH BicP1 BicK1 PRI2
(tha) (mSm) (CaCl2) (H8g) (Hgg) (mLg)
0 36 70 262 199 093
60 62 78 397 308 101
90 70 80 390 378 12
120 73 80 402 391 14
Lsd3 057 018 75 122 018
Sig4 ns
P (kgha)
Ec (mSm)
pH (CaCl2)
BicP1
(M-gg) BicK1
(figg) PRI2
(mLg)
0 59 78 117 323 17
25 58 78 147 338 15
50 58 78 160 322 16
100 58 78 255 327 13
300 62 76 554 309 06
600 66 75 944 296 005
Lsd3 063 01 58 60 02
Sig4 ns ns
1 After Colwell (1963) 2 After Allen and Jeffery (1990) 3 Least significant difference at P lt 005 4 Significance at lt 0001 () lt 001 () lt 005 () level or not significant (ns)
62
The use of Red Mudgypsum in vegetable production
mdash A
8 40 gt -o deggt 35 - en =gt mdash sect 30 _raquo CO
e 25 ltD O d
5 20
1 ^ I I I
T3
C
o
c CO o c o o
0 20 40 60 80 100120140
Residual AG (tha)
u u bull B
80 l
60
40
mdash n bull 20
n i i i i
I
i i i
100 200 300 400 500 600 700
Residual P (kgha)
Figure 61 (A B) Bicarbonate extractable P (bull) and K (bull) (figg dry soil after Colwell 1963) in the top soil (0-15 cm) of a yellow Karrakatta sand prior to fertilising and planting with level of residual Alkaloamreggypsum (t AGha) (A) and P (kgha) (B) Vertical bars refer to Lsd (P lt 005) for differences between levels of AG or P
5 E Q 0 -
20 40 60 80 100120 140
Residual AG (tha)
0 100 200 300 400 500 600 700
Residual P (kgha)
Figure 61 (C D) Phosphorus retention index (PRI) after Allen and Jeffery (1990) in the topsoil (0-15 cm) of a yellow Karrakatta sand prior to fertilising and planting with level of residual Alkaloamreggypsum (t AGha) (C) and P (kgha) (D) Vertical bars refer to Lsd (P lt 005) for differences between levels of AG or P
63
The use of Red Mudgypsum in vegetable production
One month after planting there was a significant increase in concentration of Ca Na and pH and a decrease in K concentration with level of residual AG in the soil solution at 15 cm depth There was no significant effect of level of residual AG on the Ec or concentration of Mg S and soluble reactive P (Psr) in the soil solution (Table 62 (a) Fig 62) There was a significant decrease in Ec pH and concentration of Mg Na and an increase in concentration of Ca S and Psr in soil solution with level of residual P
Table 62 (a) Ec (mSm) pH and concentration of nutrients (ugmL) in soil solution 1 month after planting cauliflowers with level of residual Alkaloamreggypsum (AG) and phosphorus (P)
AG
AG (tha)
Ec (mSm)
pH Ca (ngmL)
Mg (ugmL)
Na (jigmL)
K (UgmL)
S (jigmL)
Psrp1
(pgmL)
0 129 75 91 141 105 81 28 05
60 144 77 108 131 121 64 30 06
120 147 76 123 136 120 50 33 04
Lsd2 33 01 14 09 4 7 1 02
Sig3 ns ns ns ns
P
p (kgha)
Ec (mSm)
pH Ca (UgmL)
Mg (ligmL)
Na (jigmL)
K (UgmL)
S (UgmL)
Psrp1
(VigmL)
0 171 78 107 141 121 68 23 01
100 138 77 104 144 111 58 24 02
300 120 76 103 128 110 63 31 06
600 130 73 117 133 116 71 43 13
Lsd2 20 02 10 11 10 13 7 02
Sig3 ns
Soluble reactive P 2 Least significant difference at P ^ 005 3 Significance at lt 0001 () lt 001 () lt 005 () level or not significant (ns)
64
The use of Red Mudgypsum in vegetable production
3
C
o
o (gt
o in c c o
5 c CD O
o O
3
o
c o
c ltu o c o
o 0 20 40 60 80 100 120 140
Residual AG (tha)
0 100 200 300 400 500 600 700
Residual P (kgha)
Figure 62 (A B) Concentration (figmL) of Ca (bull) Mg (bull) Na (A) K (T) and S (bull) in soil solution (0-15 cm) under cauliflower one month after planting with level P residual Alkaloamreggypsum (AG) (A) and (B) Vertical bars refer to Lsd (P lt 005) for differences in concentration between levels of AG Where bars are not shown Lsd is less than size of symbol
There was a significant increase in Colwell P K and PRI in the topsoil (0-15 cm) and no change in DTPA extractable Zn with level of residual AG one month after planting (Table 62 (b)) As level of residual P increased there was a significant increase in Colwell P and decrease in PRI with no change in Colwell K or DTPA extractable Zn in the topsoil one month after planting
The use of Red Mudgypsum in vegetable production
Table 62 (b) Extractable P K Zn and phosphorus retention index of the TopsoU (0-15 cm) of a yellow Karrakatta sand 1 month after planting of cauliflowers with level of residual Alkaloamreggypsum (AG) and phosphorus (P)
AG
Ag BicP1 BicK1 Zn2 PRI3
(tha) (Pgg) (Pgg) (Pgg) (mLg)
0 27 41 25 05
60 45 43 26 03
120 50 59 23 07
Lsd4 8 6 05 01
Sig5 ns
p
p (kgha)
BicP1
(Pgg) BicK1
(Pgg)
Zn2
(l-igg) PRI3
(mLg)
0 9 46 19 12
100 21 47 22 09
300 42 46 25 03
600 90 52 31 -03
Lsd4 7 5 10 02
Sig5 ns ns
1 After Colwell (1963) 2 Extracted in DTPA 3 After Allen and Jeffery (1990) 4 Least significant difference at P ^ 005 5 Significance at lt 0001 () lt 001 () lt 005 () level or not significant (ns)
After harvest of cauliflowers there was a significant increase in Colwell P and K total P actual and predicted PRI (PRI and PRIp) with residual AG in the topsoil and subsoil of a Karrakatta sand (Table 63 (a) (b)) There was a significant increase in Colwell P and total P and decrease in Colwell K PRI and PRIp with level of residual P in both the topsoil and subsoil after harvest (Fig 63 (A B))
66
The use of Red Mudgypsum in vegetable production
Table 63 Extractable P K total P and phosphorus retention index of the topsoil (0-15 cm) and subsoil (15-30 cm) of a yellow Karrakatta sand after harvest of cauliflowers with level of residual AIkaloamreggypsum (AG) and phosphorus (P)
(a) Topsoil
AG
AG BicP1 BicK1 TotP2 PPJ3 PPJP4
(tha) (ngg) (Hgg) (Pgg) (mLg) (mLg)
0 16 28 68 10 26
60 25 42 86 15 41
90 25 46 91 16 43
120 26 54 96 18 46
Lsd5 3 9 8 005 03
Sig6
P (kgha)
BicP1
(Pgg) BicK1
(vigg) TotP2
(ngg) PPJ3
(mLg) PPJP4
(mLg)
0 7 46 58 19 27
25 8 45 63 19 28
50 9 44 64 20 30
100 15 43 72 17 33
300 37 40 103 09 48
600 63 36 152 03 67
Lsd5 3 6 8 03 05
Sig6
1 After Colwell (1963) 2 After Allen and Jeffery (1990) 3 Phosphorus retention index (Allen and Jeffery 1990) 4 Predicted phosphorus retention index (Allen and Jeffery 1990) 5 Least significant difference at P ^ 005 6 Significance at lt 0001 () lt 001 () lt 005 () level or not significant (ns)
The use of Red Mudgypsum in vegetable production
120
o lgt 100 bull gt
TJ
rn laquon D ) 3
mdash-
on
60
^^ m i _
c 40 ltigt o c o O 20
160 A (I 140
^ ^ ^ ^ 1 o (0 ^ ^ ^ ^ 1 gtraquo 120
^plusmn bull o
^ ^ ^ ^
66
100
^ 3 80
^ mdash ^ tra
tion
60
^ ^ - ^ ^ ^ cen 40
o 20 o 20
I I I I I I I
O
10
0
0 20 40 60 80 100 120 1lt
O
10
Residual AG (tha)
0 100 200 300 400 500 600 700
Residual P (kgha)
Figure 63 (A B) Bicarbonate extractable P (bull) K (bull) and total P (A) in the topsoil (0-15 cm) of a yellow Karrakatta sand after harvest of cauliflowers with level of residual AIkaloamreggypsum (t AGha) (A) and P (kgha) (B) Vertical bars refer to Lsd (P lt 005) for difference between level of AG or P Lsd not shown when less than size of symbol
68
The use of Red Mudgypsum in vegetable production
Table 63 Extractable P K total P and phosphorus retention index of the topsoil (0-15 cm) and subsoil (15-30 cm) of a yellow Karrakatta sand after harvest of cauliflowers with level of residual Alkaloamreggypsum (AG) and phosphorus (P)
(b) Subsoil
AG
AG BicP1 BicK1 TotP2 PRI3 PRJJP4
(tha) (Pgg) (ugg) (ngg) (mLg) (mLg)
0 15 23 69 08 24
60 23 31 82 12 36
90 24 37 91 14 39
120 25 40 90 17 43
Lsd5 4 6 7 01 03
Sig6
P (kgha)
BicP1
(ngg) BicK1
(ugg) TotP2
(ugg) PRI3
(mLg) PRIP4
(mLg)
0 6 36 57 18 25
25 8 36 63 17 26
50 8 34 63 17 26
100 13 31 71 15 29
300 33 29 102 08 43
600 61 30 141 03 64
Lsd5 5 5 8 02 05
Sig6
1 After Colwell (1963) 2 After Allen and Jeffery (1990) 3 Phosphorus retention index (Allen and Jeffery 1990) 4 Predicted phosphorus retention index (Allen and Jeffery 1990) 5 Least significant difference at P ^ 005 6 Significance at lt 0001 () lt 001 () lt 005 () level or not significant (ns)
The use of Red Mudgypsum in vegetable production
100
o CO
gtlaquo
C
o CO
bull-raquo
c o o o
20 40 60 80 100 120 140
Residual AG (tha) 0 100 200 300 400 500 600 700
Residual P (kgha)
Figure 63 (A B) Bicarbonate extractable P (bull) K (bull) and total P (A) in the subsoil (0-15 cm) of a yellow Karrakatta sand after harvest of cauliflowers with level of residual Alkaloamreggypsum (t AGha) (A) and P (kgha) (B) Vertical bars refer to Lsd (P lt 005) for difference between level of AG or P Lsd not shown when less than size of symbol
Ec pH (CaCl2) and exchangeable Ca and Na in the top and subsoil after harvest increased significantly with level of residual AG whilst there was no change in exchangeable Mg (Table 64 (a) (b)) Whilst there was no change in exchangeable K with level of residual AG in the topsoil there was a significant increase in exchangeable K in the subsoil (Table 64 (b))
70
The use of Red Mudgypsum in vegetable production
Table 64 Ec (mSm) pH (CaCl2) and exchangeable cations (me) in topsoil (0-15 cm) and subsoil (15-30 cm) of a yellow Karrakatta sand with level of residual AIkaloamreggypsum (AG) and phosphorus (P) after harvest of cauliflowers
(a) Topsoil (0-15 cm)
AG
AG Ec pH Ca1 Mg1 K1 Na1
(tha) (mSm) (CaCl2) (me) (me) (me) (me)
0 29 65 24 027 006 004
60 47 73 32 025 009 010
90 59 77 36 023 015 015
120 66 78 40 025 012 018
Lsd2 07 07 06 005 006 001
Sig3 as ns
P (kgha)
Ec (mSm)
PH (CaCl2)
Ca1
(me) Mg1
(me) K1
(me) Na1
(me)
0 43 73 30 025 001 011
25 46 73 33 026 010 011
50 46 73 32 025 010 011
100 52 74 32 025 010 011
300 56 74 34 024 009 011
600 58 73 37 025 014 012
Lsd2 05 05 03 002 007 -
Sig3 ns ns ns
Exchangeable in 1 m NILt-Cl 2 Least significant difference at P ^ 005 3 Significance at lt 0001 () lt 001 () lt 005 () level or not significant (ns)
The use of Red Mudgypsum in vegetable production
soil b
A soil
dry
4 _ I dry
I ^5 CD CD
b_ 3 - E c c o o CO at
i
U o CD CD
Xgt j a CO bull| mdash CO CD ogt
m- mdashM- mmdash JZ 0 - +~ -- mdash c CJ o X X LU
i 1 I i i i i LU
0 20 40 60 80 100 120 1^ W
Residual AG (tha)
100 200 300 400 500 600 700
Residual P (kgha)
Figure 64 (A B) Exchangeable Ca (bull) Mg (bull) K (A) and Na ( bull ) (me) in the topsoil (0-15 cm) of a yellow Karrakatta sand with level of residual Alkaloamreggypsum (t AGha) or P (kgha) Vertical bars refers to Lsd (P lt 005) for differences in concentration between levels of AG or P Lsd not shown when less than size of symbol
72
The use of Red Mudgypsum in vegetable production
Table 64 Ec (mSm) pH (CaCl2) and exchangeable cations (me) in topsoil (0-15 cm) and subsoil (15-30 cm) of a yellow Karrakatta sand with level of residual AlkaIoamreggypsum (AG) and phosphorus (P) after harvest of cauliflowers
(b) Subsoil (15-30 cm)
AG
AG Ec pH Ca1 Mg1 K1 Na1
(tha) (mSm) (CaCl2) (me) (me) (me) (me)
0 34 66 24 026 006 005
60 50 75 33 024 008 010
90 64 78 38 023 01 016
120 68 79 41 024 01 019
Lsd2 05 01 07 006 001 003
Sig3 ns
P (kgha)
Ec (mSm)
pH (CaCl2)
Ca1
(me) Mg1
(me) K1
(me) Na1
(me)
0 48 75 30 023 009 011
25 51 74 33 026 009 011
50 50 75 34 025 008 013
100 61 75 35 026 008 013
300 57 75 34 022 007 013
600 58 73 38 024 008 013
Lsd2 08 01 04 003 001 003
Sig3 ns
1 Exchangeable in 1 m NH4-CI 2 Least significant difference at P ^ 005 3 Significance at lt 0001 () lt 001 () lt 005 () level or not significant (ns)
The use of Red Mudgypsum in vegetable production
o 0 oi
4 CO c CO
gt T3 4 _ bull o
0s -5 3 agt CD
fc_ 3 - g
on
o 2 CO 2 CO
u 2
o CD CD 1 X I SI
1 CD 1 CD CD CU
O
n ^ 1 CO n X bull mdashXmdash mdash 1 1 CO U J= n bull - w 1 CO U
o o X X Lil
i i 1 1 i i 1 HI
0 20 40 60 80 100 120 140
Residual AG (tha)
100 200 300 400 500 600 700
Residual P (kgha)
Figure 64 (C D) Exchangeable Ca (bull) Mg (bull) K (A) and Na (T) (me) in the subsoil (0-15 cm) of a yellow Karrakatta sand with level of residual Alkaloamreggypsum (t AGha) or P (kgha) Vertical bars refers to Lsd (P lt 005) for differences in concentration between levels of AG or P Lsd not shown when less than size of symbol
As level of residual P increased there was a significant increase in exchangeable Ca in the tbpsoil and subsoil but no significant effect on exchangeable Mg K and Na in the topsoil and variable effects on exchangeable Mg and K in the subsoil Ec increased significantly with level of residual P in both the top and subsoil whilst pH in either was effected little by level of applied P
The effect of level of residual AG andP on the concentration of nutrients in cauliflower leaves
The level of residual AG had no effect on the concentrations of N Ca S P S Mg Fe Zn Mn B and Cu in the youngest mature leaves of cauliflowers at buttoning but increased levels significantly reduced the concentration of K (Fig 65 (A B)) As level of residual P increased there was a significant increase in the concentration of K P S Cu and Mn in the YMLs whilst concentrations of N decreased and B concentrations were variable with no clear trends
74
The use of Red Mudgypsum in vegetable production
Table 65 Concentration of nutrients (dry weight basis) in youngest mature leaves of cauliflowers at buttoning with level of applied residual Alkaloamreggypsum (AG) and phosphorus (P)
(a) Macronutrients
AG
AG N1 K1 Ca2 S2 P1 Na2 Mg2
(tha) () () () () () () ()
0 49 42 23 077 040 039 027
60 51 40 23 078 042 036 025
90 51 39 23 079 043 036 025
120 49 39 24 078 042 036 025
Lsd3 03 02 08 009 007 010 004
Sig4 ns ns ns ns ns ns
P N1 K1 Ca2 S2 P1 Na2 Mg2
(kgha) () () () () () () ()
0 53 36 22 069 027 033 024
25 51 38 24 071 030 038 026
50 52 40 24 075 034 040 027
100 51 41 24 079 043 041 027
300 48 43 24 087 055 039 026
600 47 42 20 086 060 031 023
Lsd3 02 02 04 003 004 006 003
Sig4 ns ns
1 After Varley (1966) 2 After McQuakerefl (1979) 3 Least significant difference at P lt 005 4 Significance at lt 0001 () lt 001 () lt 005 () level or not significant (ns)
The use of Red Mudgypsum in vegetable production
Table 65 Concentration of nutrients (dry weight basis) in youngest mature leaves of cauliflowers at buttoning with level of applied residual AlkaIoamreggypsum (AG) and phosphorus (P)
(b) Micronutrients
AG
AG (tha)
Fe (ugg)
Zn1
(Pgg) Mn1
(ugg) B1
(ugg) Cu1
(ugg)
0 122 31 19 21 28
60 121 32 22 22 30
90 119 36 25 22 32
120 120 29 23 22 29
Lsd2 21 8 6 1 05
sig3 ns ns ns ns ns
P (kgha)
Fe1
(Pgg)
Zn1
(ugg) Mn1
Gigg)
B1
(Fgg)
Cu1
(Pgg)
0 112 33 19 22 28
25 120 32 22 22 29
50 125 32 21 23 29
100 132 38 24 23 31
300 129 30 25 22 32
600 106 29 23 21 32
Lsd2 19 6 3 1 03
Sig-3 ns ns
After McQuaker et al (1979) 2 Least significant difference at P ^ 005 3 Significance at lt 0001 () lt 001 () lt 005 () level or not significant (ns)
The relationship between residual P ie Colwell P and P in YMLs at buttoning were best described by Mitscherlich relationships at all levels of residual AG (Fig 65)
The concentration of P in YMLs corresponding to levels of Colwell P necessary for 95 of maximum yield were 047 050 054 and 048 and for 99 of maximum yield were 053 055 058 and 054 for 0 60 90 and 1201 residual AGha respectively
76
The use of Red Mudgypsum in vegetable production
Q
en
3
gt-c 0
07
06
05
04
03
02
01 0
065
060
055
050
045
040
035
030
025
020
A
if 20 40 60 80 100
Colwell P (ugg dry soil)
_ 065
Q S 055
060
tz
ro _ i
gt
120
C bull - - - mdash bull
20 40 60 80 100
Colwell P (ugg dry soil)
120
050
045
040
035
030
025
020
065
060
055
050
045
040
035
030
025
020
-B
bull
- bull I
I I
bull
i i i
20 40 60 80 100
Colwell P (ugg dry soil)
120
-bull D
I I i i i
20 40 60 80 100
Colwell P (ugg dry soil)
120
Figure 65 P in youngest mature leaves at buttoning () corresponding to Colwell P necessary for 95 (dashed) or 99 (whole) of maximum yield at 0 (A) 60 (B) 90 (C) and 120 (D) t of residual Alkaloamreggypsumha Dashed and whole horizontal lines refers to P in YML corresponding to Colwell P required for 95 and 99 of maximum yield respectively
The equations for the fitted lines are
A y = 05964 - 0763 x exp (-0068) (B2 = 089)
B y = 05855 - 05144 x exp (-00465x) (R2 = 098)
C y = 006058 - 0549 x exp (-00435x) (B2 = 096)
D y = 06399 - 05208 x exp (-00291) (R2 = 097)
77
The use of Red Mudgypsum in vegetable production
The effect of level of residual AG andP on the yield of cauliflowers
There was no significant effect of levels of residual AG on the total or marketable yield of cauliflowers However yield responded significantly to levels of applied residual P and the interaction between residual P and AG was significant (Tables 66 (a) (b))
The relationship between Colwell P and total yield was best described by Mitscherlich relationships for all levels of residual AG (Fig 66) The Colwell P required for 95 of maximum total yield was 26 40 48 and 40 ugg dry soil and for 99 35 55 71 and 58 ugg dry soil for 0 60 90 and 1201 residual AGha respectively
Table 66 Curd yield (total and marketable) of cauliflowers (tha) at harvest with level of residual Alkaloamreggypsum (AG) and phosphorus (P)
(a) Total
AG p
(kgha) (tha) p
(kgha)
0 60 90 120
0 59 64 69 100
25 134 126 123 83
50 139 133 117 143
100 163 200 164 177
300 203 236 198 204
600 215 237 208 194
Ls-d1 36 (AG) 17 (P) 48(AGP) -
Sig2 ns
(b) Marketable
p (kgha)
AG (tha) p
(kgha)
0 60 90 120
0 14 14 18 56
25 83 74 84 13
50 90 99 67 99
100 138 188 125 160
300 187 232 182 190
600 206 234 191 185
Lsd1
Sig2
48 (AG)
ns 23 (P)
62(AGP)
-
Least significant difference at P lt 005 2 Significance at lt 0001 () lt 001 () lt 005 () level or not significant (ns)
The use of Red Mudgypsum in vegetable production
0 20 40 60 80 100120140160
Colwell P (ugg dry soil)
0 20 40 60 80 100120140160
Colwell P (ugg dry soil)
lt x
UJ gt-Q
o
lt X
Q _ l UJ gt-Q rr D O
24
22
20
18
16 14
12
10
8
6
4
-D
bull
I I
I I
I I
I
^~ bull
i i i i i
20 40 60 80 100120140160
Colwell P (ugg dry soil)
20 40 60 80 100120140160
Colwell P (ugg dry soil)
Figure 66 Colwell P in topsoil (0-15 cm) at planting versus yield of cauliflowers at 0 (A) 60 (B) 90 (C) and 120 (D) tha of residual Alkaloamreggypsum (AG) Dashed and whole vertical lines represent Colwell P required for 95 and 99 of maximum yield respectively
The equations for the fitted lines are
A y = 2088 - 818 x exp (-017x) (i2 = 089)
B y = 23731 - 4578 x exp (-00949) (i2 = 099)
C y = 2051 - 286 x exp (-00697) (R2 = 086)
D y = 2002 - 354 x exp (-0090) (B2 = 086)
79
The use of Red Mudgypsum in vegetable production
Discussion
There was no significant reduction in maximum yield (ie A values) of cauliflower (cv Plana) curds grown on Karrakatta sands amended with residual AG from 0 to 120 tha in this work This is in contrast to previous work (Robertson et al 1994) in which maximum curd yields of cauliflowers were significantly reduced with levels of residual AG at 120 tha compared with 0 and 60 tha In both studies concentrations of K were reduced and concentrations of Na were increased in the YML at buttoning with increasing levels of residual AG The increase in concentration of Na and the decrease in concentration of K in the YML with level of applied AG was related to similar changes in the concentrations of these elements in the soil solution with both freshly-applied (Section 5) and residual AG one month after planting As with freshly-applied AG increasing levels of residual AG resulted in increasing levels of Na in the soil (exchangeable) or soil solution however whilst K concentrations in soil solution decreased the K retained by the soil measured as either Colwell K or exchangeable K increased Increasing levels of residual AG resulted in increased pH in the topsoil as with fresh AG but this did not reduce the concentration of Mn Cu and Zn in the YML or increase the concentration of Mo These changes would be expected with increases in soil pH (Porter 1984) The level of Colwell P required for 95 to 99 of maximum yield increased from 26 and 35 ugg dry soil at 01 AGha to 48 and 71 ugg at 901 of residual AGha The level at 1201 AGha was slightly lower ie 40 and 58 ugg These levels are similar to those reported as necessary for 95 and 99 of maximum yield of Arfak cauliflowers 40 and 55 ugg Colwell P in planted in autumn and spring on unamended Karrakatta sands (McPharlin et al 1995) It therefore does not appear that AG amendment increases the residual P as measured by Colwell P requirement of cauliflower significantly This is in contrast to the significantly higher level of applied P necessary to maximise yield when AG is freshly-applied ie from 120-160 to gt 300 kg of Pha at 0 and 1201 AGha respectively (Robertson et al 1994 and Section 5) However requirements of residual (Colwell) P and freshly-applied P are not always correlated For example the Colwell P necessary for the maximum yield of spring and winter-planted lettuce was similar ie 80 to 120 ugg dry soil whereas the level of freshly-applied P required for maximum yield of winter-planted lettuce was 50 higher than in spring (McPharlin et al 1996 McPharlin and Robertson 1997)
References
Allen DG and Jeffery RC (1990) Methods for analysis of phosphorus in Western Australian soils Chemistry Centre of Western Australia Report of Investigation No 37
Barrow NJ (1982) Possibility of using caustic residue from bauxite for improving the chemical and physical properties of sandy soils Australian Journal of Experimental Agriculture Research 33 275-285
Colwell JD (1963) The estimation of phosphorus fertiliser requirements of wheat in southern New South Wales by soil analysis Australian Journal of Experimental Agriculture Animal Husbandry 3 190-197
Gillman GP and Sumpter EA (1986) Modification to the compulsive exchange method for measuring exchange characteristics of soils Australian Journal of Soil Research 24 616
McArthur WM and Bettenay E (1960) The development and distribution of the soils of the Swan Coastal Plain Western Australia CSIRO Division of Soils Soils Publication No 16
McPharlin IR Jeffery RC and Pitman DH (1996) Phosphorus requirements of winter planted lettuce (Lactuca sativa L) on a Karrakatta sand and the residual value of phosphate as determined by soil test Australian Journal Experimental Agriculture 36 887-903
80
The use of Red Mudgypsum in vegetable production
McPharlin IR Jeffery RC and Weissberg R (1994) Determination of the residual value of phosphate and soil test phosphorus calibration for carrots on a Karrakatta sand Communications in Soil Science Plant Analysis 25 (5-6) 489-500
McPharlin IR and Robertson WJ (1997) Response of spring-planted lettuce (Lactuca sativa L) to freshly-applied and residual phosphorus and to phosphate fertiliser placement on a Karrakatta sand Australian Journal of Experimental Agriculture (in press)
McPharlin IR Robertson WJ Jeffery RC and Weissberg R (1995) Response of cauliflower to phosphate fertiliser placement and soil test phosphorus calibration on a Karrakatta sand Communications in Soil Science and Plant Analysis 26(3-4) 607-620
McQuaker NR Brown DF and Kluckner PD (1979) Digestion of environmental materials for analysis by inductively coupled plasma-atomic emission spectrometry Analytical Chemistry 51 1082-1084
Novoa R and Loomis RS (1981) Nitrogen and plant production Plant and soil 58 177-204
Ozanne PG and Shaw TC (1968) Advantages of recently developed phosphate sorption test over the older extractant methods for soil phosphate (ed JW Holmes) pp 273-280 In Transactions of the 9th International Congress of Soil Science Volume 2 Angus and Robertson Sydney Australia
Porter WM (1984) Soil acidity Agriculture Western Australia Farmnote No 6884
Robertson WJ McPharlin IR and Jeffery RC (14) Final report of investigation into the use of gypsum-amended Red Mud as a soil-amendment on horticultural properties on the Swan Coastal Plain Report to HRDC (Project No V0039RO) Department of Agriculture Western Australia
Varley J A 1966 Automatic methods for the determination of nitrogen phosphorus and potassium in plant material Analyst 91 119-126
Vlahos S Summers KJ Bell DT and Gilkes RJ (1989) Reducing phosphorus leaching from sandy soils with Red Mud bauxite processing residues Australian Journal of Soil Research 27 651-662
Yuen SH and Pollard AG (1954) Determination of nitrogen in agricultural material by the Nessler reagent IL Microdetermination in plant tissue and soil extracts Journal of Science Food Agriculture 5 364-369
The use of Red Mudgypsum in vegetable production
7 RETENTION LEACHING AND RECOVERY OF P AND OTHER NUTRIENTS BY CARROTS GROWN ON A JOEL SAND AMENDED WITH RESIDUAL RED MUD (ALKALOAMreg)GYPSUM (AG) IN LARGE POTS
Introduction
It is difficult to quantify the retention of P by sands amended with Red Mud (Alkaloamreg)gypsum (AG) in the field because of native P in the soil and soluble P in the AG (Robertson et al 1994) It is easy to quantify leaching of P and other nutrients such as N and K from AG amended sands in pots or columns by collecting leachate and measuring concentration (McPharlin et al 1995) However plants were not grown in the columns used by McPharlin et al so there was no measurement of plant uptake of P and other nutrients to complete the nutrient budget Potatoes were grown successfully in Spearwood sands in large pots (70 L) and a complete N budget (N applied N retained by soil N leached and uptake by plant) determined (Hegney et al 1996)
Freshly-applied AG may not be in equilibrium with the soil to which it is applied ie the pH Ec and concentrations of elements such as Ca and Na may change rapidly with time The age of the AG may effect its capacity to retain P on amended soils AG may improve the retention of other nutrients such as ammonium N (McPharlin et al 1995) and K (Sections 5 and 6) by amended sands AG which has been applied to sands in the field for at least 2 to 5 years should be close to equilibrium with the soil as substantial leaching would have occurred AG of this age would give the best estimate of its long term capacity to reduce leaching of P and other nutrients from poor grey sands on the Swan Coastal Plain The purpose of this work was to quantify the leaching and retention of P and other nutrients (N Ca K etc) from Joel sands which had been amended with AG at different levels in the field for 14 years Carrots a major vegetable crop grown on the Swan Coastal Plain were used as the experimental crop and grown in these AG amended sands in large pots
Materials and methods
Pots
Fibreglass pots used for the experiment were 45 cm in diameter and 50 cm deep The area of soil surface was 016 m2 and the volume was 70 L The bottom of the pots tapered to a hole (diameter) to which was attached a polyethylene hose (length and diameter) and tap The pots were painted white to reduce heat The pots were placed on a metal table (with mesh tops) and the hose passed through a hole in the centre of a lid of a plastic (20 L) bucket
Experimental design
The experimental design was a 4 (levels of residual AG ie 0 125 250 and 1000 tha) times 5 (levels of applied P ie 0 50 100 200 and 400 kgha) factorial in a randomised block with 3 replicates The level of applied AG or Pha was calculated using the area of the soil surface The total number of pots was 60
Soil and Red Mud (Alkaloamreg)gypsum (AG)
Virgin Joel sand was obtained from a commercial garden supply site in Jandakot The top 20 cm of the soil was removed and the rest sieved (15 mm) to remove debris About 20 kg of Joel sand was added to each pot (10 cm depth) Another 60 kg (30 cm depth) of sand was added to the 0 AGha pots to which had been mixed lime and preplant fertilisers (see later) so the surface of the soil was about 10 cm below the top edge of the pot AG amended sand was obtained from a field site in Hope Valley Road Kwinana managed by ALCOA where it had been applied (and incorporated using a rotary hoe) to pastures growing on a Joel sand in 1983 at 0 250 500 and 1000 tha This AG amended sand was added to pots corresponding to 250 and 1000 tha in the field after the preplant fertiliser but not lime was added and was incorporated to a similar depth as in the 01 AGha pots The 125 t AGha treatment was
82
The use of Red Mudgypsum in vegetable production
obtained by mixing AG amended sand from the 250 tha field site with an equal weight of Joel sand in a cement mixer
Fertilisers and lime
The following fertilisers (in kgha) were thoroughly mixed (using a cement mixer) with the top 25-30 cm of the soil in each pot before planting Urea (108) K2SO4Q2I) MgS047H20 (100) MnS04H20 (100) Na2B4O710 H20 (50) FeS047H20 (50) CuS045H20 (50) ZnS04H20 (50) and NaMo042H20 (4) To this was added P at 0 50 100 200 and 400 kgha as single superphosphate at each level of residual AG Hydrated lime (Ca (OH)2) was mixed with the preplanting fertilisers on the 0 kg AGha treatment at 36 gpot
N K and Ca were fertigated via the drip irrigation system at 200 200 and 52 mgL using KNO3 NH4NO3 and Ca (N03)2 from immediately after sowing to 140 days after sowing (18 August 1996) MgS047H20 was broadcast at 100 kgha to each pot at weeks 6 and 12
Irrigation
The plants were irrigated using drippers (Netafim 2 Lh pressure compensated with 4 equalisers per pot) at 15 times the average monthly pan evaporation until 160 days after sowing (7 September 1996) Adjustments were made on a daily basis if evaporation was significantly higher or lower than the long term average (Table 71)
Table 71 Irrigation requirements of carrots in pot experiments
Month DAS Lpotday Minutesday
April 1- 27 10 33
May 28- 59 065 21
June 60- 90 044 14
July 91-122 044 14
August 123-154 056 19
September 155-160
Adjusted for 90 efficiency of irrigation system
Rain was excluded from the pots using a movable rain out shelter made of perspex and aluminium This was removed at all other times
Crop management
The soil in each pot was irrigated to field capacity ie so that free drainage occurred Carrot (cv Top Pak) seeds were sown on a 9 x 9 cm spacing and 1 cm deep with 5 seeds per site on 3 April 1996 These were thinned to 14 seedlingspot (88 plantsm2) after emergence (15 April 1996) No application of fungicides or insecticides were necessary
Soil and plant measurements
Soil
Immediately before fertilising and sowing 5 cores (22 diameter x 15 cm deep) were taken from each pot and dried in a force draught oven at 40degC Each sample was analysed for extractable P and K (Colwell 1963) pH (CaCl2 and H20) total P (Allen and Jeffery 1990) PRI (Allen and Jeffery 1990) total N extractable ammonium N (KC1) extractable nitrate N (KC1) organic carbon cation exchange capacity and exchangeable cations
83
The use of Red Mudgypsum in vegetable production
Leachate
Leachate from each pot was collected in 20 L plastic buckets under the pots each week from the 4 April 1996 to 22 July 1996 PMA (phenyl mercuric acetate) was added to the leachate to prevent contamination Total water volume was measured and sub-samples (200 mL) collected and submitted for analysis of P NH4-N NO3-N K Na Ca S Mg Ec and pH analysis of concentration The quantities leached of the above elements in kgha were calculated from concentration and volume of leachate collected and surface area of soil in pot
Harvest
The plants were harvested on 7 September 1997 and the total marketable and reject root yield determined for each plot
Analysis of data
Analysis of variance (Genstattrade for Windows version 32) was carried out on level of AG and P versus yield (total marketable reject) level of chemical factors in soil after harvest concentration of nutrients in youngest mature leaves at midgrowth tops and roots at harvest and leachate on 22 April 1996 5 May 1996 and 22 July 1996 and quantities of elements leached at each sampling time
Mitscherlich or linear relationships were fitted to level of P versus yield (total) at each level of residual AG P required for 95 and 99 of maximum yield was delivered at each level of residual AG P uptake by carrots was determined from the dry weight and P in tops and roots for each treatment Fertiliser P uptake was determined by deducting uptake on 0 kg Pha treatments at each level of applied AG Fertiliser P retained in the top-soil was determined from the concentration of total P and bulk density P leached was fertiliser leached below 15 cm The P in each plant fraction soil and leached was determine at each level of applied P and AG
Results
Effect of level of residual AG on chemical characteristics of Joel sand
Soil pH (CaCl2 H20) Ec Colwell P phosphorus retention index cation exchange capacity exchangeable Ca and Na and silt and clay all increased with level of residual AG in the top soil (0-15 cm) of a Joel sand before fertilising and sowing (Table 72)
The use of Red Mudgypsum in vegetable production
Table 72 Chemical and physical characteristics of Joel sand amended with residual Alkaloam gypsum (AG) in pots before fertilising and sowing of carrots
Level of residual AG
Parameter (tha)
Parameter
0 125 250 1000
pH (H20) 69 77 85 86
pH (CaCl2) 57 71 78 78
Ec (mSm) 4 9 9 11
Ext P (ngg)1 3 9 14 9
PRI2 -02 33 44 77
Total N ()3 - 0039 0044 0060
ExtNH4-N(ngg)4 - 2 2 2
ExtN03-N(ugg)5 - 3 2 5
CEC ()6 30 30 43 35
Exch Ca ()7 133 363 51 70
Exch Mg ()7 036 024 015 021
Exch Na ()7 005 015 015 032
Exch K ()7 007 004 0035 0035
OrgC()8 131 109 092 103
Sand () 977 967 960 910
Silt () 13 15 15 37
Clay () 10 23 25 53
1 Colwell (1963) 2 Phosphorus retention index (Allen and Jeffery 1990) 3 KjeldahlReardon et al 1966 4 Extracted in 1 m KC1 (Reardon et al 1966) 5 Extracted in 1 m KC1 (Best 1976) 6 Gillman and Sumpter (1986) 7 Exchangeable in 1 m NHU-Cl 8 Walkley and Black (1934)
Level of residual AG had no effect on levels of extractable NH4-N NO3-N exchangeable Mg and K or organic carbon After harvest levels of Colwell P K total P PRI Ec pH (CaCk) exchangeable Ca Mg K and Na in the topsoil (0-15 cm) all increase significantly (P lt 005) with level of residual AG (Tables 73 74)
85
The use of Red Mudgypsum in vegetable production
Table 73 Extractable P K NH4 total P (tot P) and phosphorus retention index (PRI) of the topsoil (0-15 cm) of a Joel sand after harvest of carrots with level of residual Alkaloamreggypsum (AG) and phosphorus (P)
AG
AG BicP1 BicK tot P2 PRI3 NIL (tha) (ngg) (Hgg) (ngg) (mLg) (Mfig)
0 33 119 234 -015 137
125 200 117 743 141 27
250 275 197 1258 231 19
1000 204 420 1853 154 30
Lsd5 4 34 129 45 26
Sig6
P
P (kgha)
BicP1
(ngg) BicK1
(Mgfe) totP2
(ugg) PRI3
(mLg) NIL
(ngg)
0 91 215 896 198 58
50 151 223 937 138 54
100 144 226 1005 126 62
200 182 193 1043 128 42
400 323 210 1231 116 52
Lsd5 48 39 144 50 29
Sig6 s | e ns ns
1 Colwell 1963 2 Allen and Jeffery 1990 3 Phosphorus retention index (Allen and Jeffery 1990) 4 Extracted in 1 m KC1 (Best 1976) 5 Least significant difference at P s 005 6 Significance at lt 0001 () lt 001 () lt 005 () level or not significant (ns)
By contrast levels of extractable NH4-N decreased significantly with level of residual AG Colwell P total P Colwell K all increased significantly (P lt 005) with level of applied P whilst PRI was decreased significantly Level of applied P had no significant effect on Ec pH or level of exchangeable Ca Mg K Na Colwell K or extractable NHu-N in the topsoil after harvest (Tables 73 74)
The use of Red Mudgypsum in vegetable production
Table 74 Ec (mSm) pH (CaCl2) and exchangeable cations (me) in topsoil (0-15 cm) of a Joel sand after harvest of carrots with level of residual Alkaloamreggypsum (AG) and phosphorus (P)
AG
AG Ec pH Ca1 Mg1 K1 Na1
(tha) (mSm) (CaCl2) (me) (me) (me) (me)
0 157 44 18 016 026 010
125 147 54 23 014 026 015
250 217 66 40 017 041 027
1000 308 76 135 027 096 094
Lsd2 32 01 07 002 005 005
sig3
p
p (kgha)
Ec (mSm)
pH (CaCl2)
Ca1
(me) Mg1
(me) K1
(me) Na1
(me)
0 202 59 52 019 048 035
50 195 60 53 018 050 036
100 203 60 57 019 048 039
200 202 60 57 018 045 040
400 236 59 51 017 046 034
Lsd2 35 01 08 002 006 005
Sig3 ns ns ns ns ns ns
Exchangeable in 1 m NH4CI 2 Least significant difference at P s 005 3 Significance at lt 0001 () lt 001 () lt 005 () level or not significant (ns)
Effect of level of residual AG and P on concentration of nutrients in leachate and quantities of nutrients leached
There was a significant (P lt 005) reduction in concentration of P in leachate with level of residual AG at three times of sampling (Fig 71) P concentration in leachate increased significantly with level of applied P at 01 AGha but not in presence of AG
P concentration in leachate at 01 AGha decreased with time from 80 mgL on 16 April 1996 at 400 kg Pha to 025 mgL on 22 July 1996 To reduce P concentration in leachate 125 t AGha was as effective as 250 or 1000 tha at all sampling times and levels of applied P Similar trends were shown in quantity of leached P as total or soluble reactive P in kgha (Appendix 71 (b) 72) Level of applied AG significantly (P lt 005) reduced the concentration of NH4-N in leachate from 40 mgL at 01 AGha to 15 mgL at 250 and 1000 tha (Fig 72 (a)) on 16 April 1996 Significant reductions in concentration were recorded on the other two sampling times as NH4-N concentration declined with increased plant uptake Similar trends were shown in the quantity of NH4-N leached with level of AG (Appendix 72 (b)) By contrast level of applied AG had no significant effect on concentration of NO3-N in leachate or quantity leached at any of the three sampling times (Fig 72 (b) and Appendix 73 (b)) There was a significant (P lt 005) reduction in concentration of K in leachate and quantity of K leached with level of residual AG although the reduction was less at the later sampling times (Fig 73 Appendix 73 (a)) Concentration of K in leachate increased
87
The use of Red Mudgypsum in vegetable production
with time at all levels of residual AG except 1000 tha By contrast both the concentration of Na in leachate and quantity of Na increased with level of residual AG to a maximum at the highest level (1000 tha) There was a reduction in Na concentration in leachate with time at level of residual AG lt 1000 tha The concentration of Ca in leachate increased significantly (P lt 005) as did quantity leached with level of residual AG and with time at all levels of AG (Fig 74 Appendix 74 (a)) By contrast concentration of Mg in leachate and quantity leached decreased significantly (P lt 005) with level of residual AG and with time at all levels of AG (Fig 78 and Appendix 78 (a)) There was a significant (P lt 005) increase in S concentration in leachate and quantity leached with level of residual AG at the first sampling time a decrease at the second and a increase up to 250 tha at the third sampling (Fig 79 Appendix 79 (a)) S concentration in leachate and quantity leached varied significantly with level of applied P at all sampling times and decreased with time from 16 April 1996 to 22 July 1996 (Fig 79 and Appendix 79 (a))
The use of Red Mudgypsum in vegetable production
deg E
c o
o O
c ltD
O
c o
I O
1 0 0 2 0 0 3 0 0 4 0 0
A p p l i e d P ( k g h a )
5 0 0
1 0 0 2 0 0
A p p l ie d P
3 0 0
k g h a )
4 0 0 5 0 0
1 0 0 2 0 0 3 0 0
A p p l i e d P ( k g h a
4 0 0 5 0 0
Figure 71 Concentration of P (mgL of total P) in leachate from Joel sands sown to carrots with level of applied P and Alkaloamreggypsum (AG) at 0 (bull) 125 (bull) 250 (A) and 1000 (T) tha on 16 April 1996 (A) 6 May 1996 (B) and 22 July 1996 (C) P was applied preplanting as superphosphate and carrots were sown on 3 April 1996 Vertical bars refer to Lsd (P lt 005) for differences in concentration between level of AG (at each level of P) or P (at each level of AG) or the interaction between AG and P Where bars arent shown Lsd is less than size of symbol
89
The use of Red Mudgypsum in vegetable production
2 0 0 4 0 0 6 0 0 8 0 0 1 0 0 0 1 2 0 0
L e v e l o f r e s i d u a A G ( t ha )
2 0 0 4 0 0 6 0 0 8 0 0 1 0 0 0 1 2 0 0
L e v e l o f r e s i d u a l A G ( t h a )
Figure 72 Concentration (mgL) of NBU-N (A) and NO3-N (B) in leachate from Joel sand sown to carrots amended with residual AlkaIoamreggypsum (AG) in pots on 16 April 1996 (bull) 6 May 1996 (bull) and 22 July 1996 (A) The carrots were sown on 3 April 1996 N was fertigated at a constant concentration of 300 mgL (250 mgL of NO3-N and 50 mgL NH4-N) from sowing to harvest Vertical bars refer to Lsd (P lt 005) for differences in concentration between level of AG at each sampling time Where bars arent shown Lsd is less than size of symbol
The use of Red Mudgypsum in vegetable production
200 400 600 800 1000 1200
Level of AG (tha)
200 400 600 800
Level of AG (tha)
1 0 0 0 1 2 0 0
Figure 73 Concentration (mgL) of K (A) and Na (B) in leachate from Joel sand sown to carrots amended with residual Alkaloamreggypsum (AG) in pots on 16 April 1996 (bull) 6 May 1996 (bull) and 22 July 1996 (A) The carrots were sown on 3 April 1996 K was fertigated at a constant concentration of 200 mgL from sowing to harvest Vertical bars refer to Lsd (P lt 005) for differences in concentration between level of AG at each time Where bars arent shown Lsd is less than size of symbol
91
The use of Red Mudgypsum in vegetable production
Effect of level of residual AG and P on concentration of nutrients in plants The concentration of K P Fe Cu Mn and Mo in the youngest mature leaves (YML) of carrots at midgrowth all increased significantly with level of residual AG (Tables 75 (a) (b)) The concentration of S in YML at midgrowth was significantly reduced as level of residual AG increased whilst concentrations of Ca Na Mg Zn and B were variable
Table 75 Concentration of nutrients ( dry basis) in youngest mature leaves of carrot at midgrowth with level of residual Alkaloamreggypsum (AG) and phosphorus (P)
(a) Macronutrients
AG
AG (tha)
K1 Ca2 S2 P1 Na2 Mg2
0 486 229 061 025 050 039
125 584 186 060 033 047 034
250 585 216 058 033 044 035
1000 531 215 056 031 052 037
Lsd3 03 02 004 0017 005 003
Sig4
p
P (kgha)
K1 Ca2 S2 P1 Na2 Mg2
0 538 198 062 029 037 036
50 523 222 061 028 043 037
100 562 208 056 030 049 035
200 548 216 057 032 058 037
400 563 214 056 035 054 036
Lsd3 033 022 004 002 006 003
Sig4 ns ns ns
1 After Varley (1966) 2 After McQuaker et al (1979) 3 Least significant difference at P s 005 4 Significance at lt 0001 () lt 001 () lt 005 () level or not significant (ns)
The use of Red Mudgypsum in vegetable production
Table 75 Concentration of nutrients ( dry basis) in youngest mature leaves of carrot at midgrowth with level of residual Alkaloam gypsum (AG) and phosphorus (P)
(b) Micronutrients
AG
AG (tha)
Fe Mn1 Zn B Cu Mo
0 111 386 280 345 95 21
125 127 279 367 348 107 25
250 126 173 269 349 108 24
1000 114 60 143 337 110 31
Lsd2 20 47 40 15 05 06
Sig3 ns ns
p
p (kgha) Fe Mn Zn B Cu Mo1
0 135 243 263 356 120 28
50 122 240 268 349 111 30
100 109 191 229 343 106 25
200 116 228 268 334 99 23
400 115 221 294 341 89 20
Lsd2 23 52 45 15 051 07
Sig3 ns ns ns ns
1 After McQuaker et al (1979) 2 Least significant difference at P s 005 3 Significance at lt 0001 () lt 001 () lt 005 () level or not significant (ns)
Concentration of P S and Na in YML increased significantly (P lt 005) with level of applied P whilst concentrations of Cu and Mo decreased (Tables 75 (a) (b)) By contrast concentrations of K Ca Mg Fe Mn Zn and B were not significantly changed by level of applied P
93
The use of Red Mudgypsum in vegetable production
At harvest the concentration of P N K and Fe in whole tops increased significantly (P lt 005) with level of residual AG whilst concentration of S Mn Zn and B decreased (Table 76) The concentrations of Ca Na and Mg were variable with level of residual AG whilst there was no significant effect on the concentration of Cu
Table 76 Concentration of nutrients ( dry basis) in whole carrot tops at harvest with level of residual Alkaloamreggypsum (AG) and phosphorus (P)
(a) Macronutrients
AG
AG (tha)
N1 K1 Ca2 S2 P1 Na2 Mg2
0 300 503 269 071 016 093 039
125 348 649 239 065 024 090 035
250 395 653 251 061 022 082 033
1000 351 566 262 066 024 099 037
Lsd3 010 036 011 002 001 009 002
Sig4
p
p (kgha)
N1 K1 Ca2 S2 P1 Na2 Mg2
0 355 589 240 073 019 074 035
50 343 597 258 068 020 082 036
100 339 587 257 068 021 098 038
200 339 580 259 063 022 108 037
400 332 608 263 057 024 095 036
Lsd3 011 041 012 002 001 010 002
Sig4 ns
1 After Varley (1966) 2 After McQuakere al (1979) 3 Least significant difference at P s 005 4 Significance at lt 0001 () lt 001 () lt 005 () level or not significant (ns)
The use of Red Mudgypsum in vegetable production
Table 76 Concentration of nutrients ( dry basis) in whole carrot tops at harvest with level of residual Alkaloamreggypsum (AG) and phosphorus (P)
(b) Micronutrients
AG
AG (tha)
Fe1 Mn1 Zn1 B1 Cu1
0 299 962 234 402 109
125 316 952 184 404 107
250 331 662 110 380 110
1000 374 673 77 383 115
Lsd2 90 106 20 002 05
Sig3 ns ns
p
p (kgha) Fe1 Mn1 Zn1 B1 Cu1
0 294 969 158 409 125
50 392 837 144 393 117
100 364 747 141 396 114
200 267 712 159 387 105
400 332 bull 796 154 377 89
Lsd2 101 118 23 13 05
Sig3 ns ns
1 After McQuaker et al (1979) 2 Least significant difference at P lt 005 3 Significance at lt 0001 () lt 001 () lt 005 () level or not significant (ns)
As level of applied P increased concentration of P Ca and Na in whole tops increased significantly (P lt 005) whilst concentrations of N S Mn B and Cu decreased There was no significant effect of level of applied P on concentrations of K Fe or Zn in whole tops whilst concentration of Mg was variable
Effect oflevel of residual AG and P on carrot yield
There was a significant (P lt 005) increase in total and marketable yield with level of applied P at all levels of applied AG (Table 77) The overall effect of AG was to reduce both total and marketable yield at the highest level (1000 cf 0 to 2501 AGha) especially at low levels of applied P (ie 0 to 50 kg Pha) At higher levels of applied P yield at 2501 AGha was not significantly (P lt 005) lower than at 125 tha
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The use of Red Mudgypsum in vegetable production
However at 10001 AGha total and marketable yield was significantly lower than 0 tha at all levels of applied P The relationship between level of applied P and total yield was described as linear at 0 250 and 10001 AGha and Mitscherlich at 125 AG tha (Fig 76) As yield did not maximise at 0 250 and 1000 t AGha no optimal level of applied P for 95 or 99 of maximum yield could be determined At 125 t AGha the level of applied P necessary for 95 and 99 of maximum yield was 182 and 314 kg Pha respectively
Effect of level of AG and P on efficiency of P recovery by plants and retention in soil
The proportion () of P recovered in the carrot roots and tops decreased with level of applied P increasing from 8 to 12 to 5 to 8 of depending on level of AG (Table 78) There was a reduction in P recovered in roots tops and whole plant as level of AG increased For example P recovered by whole plants at 01 AGha at 400 kg Pha was 8 but this had declined to 5 at 10001 AGha
Table 78 The of applied fertiliser P taken up by carrots grown in pots (tops roots) retained in the topsoil or leached with level of residual Alkaloamreggypsum (AG) and phosphorus (P) on a Joel sand
P in Fraction AG P ( of P applied )
(tha) (kgha) TopsA Roots2 Plant(A+B) Soil2 Leached3
0 50 2 9 11 3 86
0 100 2 8 10 13 77
0 200 2 6 8 2 90
0 400 2 6 8 3 89
125 50 4 8 12 73 15
125 100 2 8 10 18 72
125 200 2 6 8 30 62
125 400 1 4 5 18 77
250 50 3 7 10 0 90
250 100 2 4 6 0 94
250 200 1 4 5 0 95
250 400 1 4 5 12 83
1000 50 2 6 8 75 17
1000 100 2 5 7 67 26
1000 200 2 5 7 45 48
1000 400 1 4 5 41 55
P in fraction expressed as of P applied as fertiliser 2 P retained in topsoil (0-15 cm) 3 P leached below 15 cm
By contrast of applied P retained in topsoil varied with level of AG For example only 3 of P was retained in topsoil at 400 kg Pha and 01 AGha where as this had increased to 41 at 10001 AGha at the same level of applied P Consequently the of P leached decreased as level of AG increased For example at 01 AGha and 400 kg Pha nearly 90 of applied P leached below 15 cm This had been reduced to 55 at 10001 AGha and the same level of applied P
97
The use of Red Mudgypsum in vegetable production
Table 79 Fertiliser P leached (kgha) and P leached as a of P applied from a Joel sand sown to carrots with level of residual Alkaloam gypsum (AG) and P after harvest The P was then applied as superphosphate prior to planting The carrots were sown on 3 April 1996 P leached is expressed as a percentage of P applied
AG (tha)
P (kgha)
P leached1
(kgha) P leached
( P applied)
0 50 41 82
0 100 78 78
0 200 158 79 0 400 311 78
125 50 2 4
125 100 3 3
125 200 10 5 125 400 27 7
250 50 1 2
250 100 3 3 250 200 4 2
250 400 7 2 1000 50 02 lt1 1000 100 05 lt1
1000 200 1 lt1
1000 400 2 lt1
1 Fertiliser P leached = total P leaclied - P leached at 0 kg Pha (ie background P) 2 (Fertiliser P leachedP applied x 100)
The use of Red Mudgypsum in vegetable production
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pound CD
o TO
(D
o
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c
o c o o
pound
(0
o to
c o
TO tmdash
c 0) o c o o
0 2 0 0 4 0 0 6 0 0 8 0 0 1 0 0 0 1 2 0 0
L e v e l o f r e s i d u a l A G ( t h a )
0 2 0 0 4 0 0 6 0 0 8 0 0 1 0 0 0 1 2 0 0
L e v e l o f r e s i d u a l A G ( t h a )
Figure 74 Concentration (mgL) of Ca (A) and Mg (B) in leachate from Joel sand sown to carrots amended with residual Alkaloamreggypsum (AG) in pots on 16 April 1996 (bull) 6 May 1996 (bull) and 22 July 1996 (A) The carrots were sown on 3 April 1996 Ca was applied preplanting as superphosphate and fertigated at a constant concentration of SO mgL from sowing to harvest AG was applied preplanting and in weeks 6 (15 May 1996) and 12 (25 June 1996) Vertical bars refer to Lsd (P lt 005) for differences in concentration between level of AG at each time Where bars arent shown Lsd is less than size of symbol
99
The use of Red Mudgypsum in vegetable production
CD
CO
x o CO CD
c o
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CO
c CD O c o O
0 2 0 0 4 0 0 6 0 0 8 0 0 1 0 0 0 1 2 0 0
L e v e l of r e s i d u a l A G ( t ha )
0 100 2 0 0 3 0 0 4 0 0
L e v e l of r e s i d u a l P ( k g h a )
5 0 0
Figure 75 The concentration of S (mgL) in leachate from Joel sands sown to carrots with level of residual Alkaloamreggypsum (AG) (A) and P (B) on 16 April 1996 (bull) 6 May 1996 (bull) 22 July 1996 (A) The carrots were sown on 3 April 1996 S was applied preplanting as K2S04 and in superphosphate Vertical bars refer to Lsd (P lt 005) for differences in concentration between level of AG (A) or P (B) at each sampling time Where bars arent shown Lsd is less than size of symbol
100
The use of Red Mudgypsum in vegetable production
ID
0 100 200 300 400 500
Applied P (kgha)
lb 70
70 C
60 65 -
60
55 dt
ha 50
40
50
45 bull A
Yie
30
40 _ 20
35 i i i i 35 0 100 200 300 400 5( 50 10
Applied p (kgha)
0 100 200 300 400 500
Applied P (kgha)
0 100 200 300 400 500
Applied P (kgha)
Figure 76 Total yield of carrots with level of freshly-applied P at four levels of residual Alkaloamreggypsum (AG) (A B C D = 01252501000 tha) Vertical dashed and whole lines refer to applied P necessary to 95 (dashed) or 99 (whole) of maximum yield respectively
The equations of the fitted lines are
A y = 10943 - 9377 x exp (-00053) (R2 = 099)
B y = 6l7- 2848 x exp (-00122) (i2 = 099)
C y = 3842+ 0083x (J2 = 097)
D y = 238 + 0l07x(R2 = 096)
As level of applied P increased concentration of P Ca and Na in whole tops increased significantly (P lt 005) whilst concentrations of N S Mn B and Cu decreased There was no significant effect of level of applied P on concentrations of K Fe or Zn in whole tops whilst concentration of Mg was variable
101
The use of Red Mudgypsum in vegetable production
Discussion
The addition of residual Alkaloamreggypsum (AG) resulted in a significant reduction in the concentration of P NH4-N K and Mg in the leachate from Joel sands sown to carrots in large pots The reduction in P concentration is attributed to an increase in the level of iron and aluminium oxides when AG is applied to soils low in these minerals (Barrow 1982) Consequently all soil measurements of P status or retention such as total P Colwell P and phosphorus retention index as well as Ec and pH all increased with level of applied residual AG Similar reductions in phosphorus leaching or increases in P retention have been reported when Gavin (Vlahos et al 1989) or Joel (Sections 4 and 5 McPharlin et al 1994 Robertson et al 1997) sands were amended with fresh or residual AG (Sections 4 and 6 Robertson et al 1994)
The reduced leaching of cations such as NH4-N K and Mg is attributed to an increase in captain exchange capacity (CEC) when sands of low CEC are amended with AG (Barrow 1982 McPharlin et al 1994) Consequently NO3-N retention is not increased when soils are amended with residual (Fig 72) or freshly-applied AG (McPharlin et al 1994) The increased leaching of Na Ca and S from amended sands is attributed to the Alkaloamreg as a source of these elements either in the Alkaloamreg itself (Na2C03) or after amendment with gypsum (CaS042H20) which precipitates CaC03 and Na2S04 The Na2S04 is very soluble as is easily leached whereas Ca is only slightly soluble as gypsum and insoluble as lime Vlahos et al (1989) reported increased leaching of Na Ca and S from Gavin sands treated with copper as (FeS04) amended Alkaloamreg compared with unamended controls in the short term and a decrease in the longer term Concentrations of P in the YML at midgrowth or tops at harvest increased with level of applied P and also with level of residual AG from 025 at 0 t AGha to 031 at 10001 AGha By contrast freshly-applied AG reduced the concentration of P in the YML from 043 on unamended to 030 on amended Joel sands (Robertson et al 1997) Even at the highest level of applied P the concentration of P in the YML 035 was still lower than that shown to be necessary for maximum yield of carrots (ie 038 McPharlin et al 1992) This could explain why the yield wasnt maximised in three out of the four AG treatments On the treatment that yield was maximised 125 t AGha the highest concentration of P ie 038 was recorded The difference in trends of P in petioles with AG between the 2 studies could be explained in terms of the relative leaching of P or addition of P in the AG itself On the virgin Joel sand used in the pot study leaching of P was significant enough to reduce leaf P in the unamended versus amended treatments For example the P in YML was significantly lower in the 01 AGha than at all other levels of residual AG at all levels of applied P up to 200 kgha For example the P in YML at 01 AGha ranged from 020 to 027 at 0 and 200 kg Pha respectively whilst at 125 t AGha the P was 032 to 038 over the same levels of applied P (Appendix 71) This suggests that loss of P from the top soil is severely limiting the uptake of P by the plant in the absence of AG The phosphorus retention of virgin Joel sands is almost negligible with a PRI of close to 0 (Table 72 McPharlin et al 1994 Robertson et al 1997) By contrast the P retention of Joel sands appears to be increased following development possibly by the addition of iron in irrigation water and organic and inorganic fertilisers For example the estimate of PRI (PREM) ie PRI plus P as Colwell P measured in the developed Joel sands used by Robertson et al was 40 in the topsoil (0-15 cm) of the unamended treatment Thus in these soils P retention is high enough to reduce availability when AG is added and explains the reduced levels of P in the YML as level of AG is increased The contribution of AG to the P nutrition of the plant is an unlikely explanation as it didnt increase P levels in the plant when applied fresh (Robertson et al 1997)
Previous work showed that concentrations of K in the petioles of potatoes (Section 4 Robertson et al 1997) and youngest mature leaves in cauliflower (Robertson et al 1994 Sections 5 and 6) declined with level of freshly-applied and residual AG
With potatoes the decline in K concentrations was associated with a decrease in K concentration in the soil solution and an increase in Na concentrations in soil solution and petioles on fresh and residual AG treatments (Section 4 Robertson et al 1997) This was
102
The use of Red Mudgypsum in vegetable production
used to explain yield reductions on fresh AG sites at gt 60 tha or on residual sites at 240 tha With cauliflower the findings were variable Where yield was reduced (Robertson et al 1994) it could not be explained in terms of K nutrition as K concentrations in the YML did not decline to levels expected to result in deficiency In follow up work neither fresh or residual AG up to 240 tha resulted in yield reduction although there was a reduction in K concentrations in the YML but not below critical levels (Sections 5 and 6) By contrast concentrations of K in the YML of carrots increased with level of residual AG up to 1000 tha as did exchangeable K in the soil Similar increases in K concentration in YML of Chinese and Head cabbage with level of AG on Joel sands have been reported previously (Robertson et al 1994)
Yield response of carrots to applied P at various levels of residual AG was variable on Joel sands in this work For example yield with level of applied P reach a plateau at 125 t AGha (ie 182 and 314 kg Pha for 95 and 99 of maximum yield from the Mitscherlich regression) However at other levels of applied AG including 0 tha yield had not maximised at the highest level of applied P (400 kgha) This is surprising considering that on higher P retaining soils such as Karrakatta sands yield is maximised at much lower levels of applied P (ie 160 to 180 kgha) at a similar low P soil test (McPharlin et al 1992 1994) in the absence of AG Also on Joel sands yields of carrots at medium to low P soil test (16 to 20 ugg Colwell P) only 50 kg Pha was necessary for maximum yield (McPharlin et al Lantkze and McPharlin unpublished data) The only possible explanation is that leaching of P was significant enough in the absence of AG that increased levels of applied P were required to satisfy crop requirements The increase in P fertiliser requirement as level of applied AG increases as shown in this work above 125 tha is similar to that reported previously for Chinese and Head cabbage cauliflower lettuce onions (Robertson et al 1994) and potatoes (Robertson et al 1997) It is explained by increased P retention capacity of the soil when AG is applied and measured by PRI Colwell and Total P and similar measurements
References
Allen DG and Jeffery RC (1990) Methods for analysis of phosphorus in Western Australian soils Chemistry Centre of Western Australia Report of Investigation No 37
Barrow NJ (1982) Possibility of using caustic residue from bauxite for improving the chemical and physical properties of sandy soils Australian Journal of Agricultural Research 33 275-285
Best EK (1976) An automated method for the determination of nitrate-nitrogen in soil extracts Queensland Journal of Agriculture and Annual Science 33 161-166
Colwell JD (1963) The estimation of phosphorus fertiliser requirements of wheat in southern New South Wales by soil analysis Australian Journal of Experimental Agriculture and Animal Husbandry 3 190-197
Hegney M A McPharlin IR and Jeffery RC (1997) Response of winter-grown potatoes (Solanum tuberosum L) to freshly-applied and residual phosphorus on a Karrakatta sand Australian Journal of Experimental Agriculture 37 131-137
McPharlin IR Alymore PM and Jeffery RC (1992) Response of carrots (Daucus carota L) to applied P and P leaching on a Karrakatta sand under two irrigation regimes Australian Journal of Experimental Agriculture 32 225-232
McPharlin IR Jeffery RC and Weissberg R (1994) Determination of the residual value of phosphate and soil test phosphorus calibration for carrots on a Karrakatta sand Communications in Soil Science and Plant Analysis 25 (5-6) 489-500
103
The use of Red Mudgypsum in vegetable production
McPharlin IR Robertson WJ Jeffery RC and Weissberg R (1995) Response of cauliflower to phosphate fertiliser placement and soil test phosphorus calibration on a Karrakatta sand Communications in Soil Science and Plant Analysis 26(3amp4) 607-620
McQuaker NR Brown DF and Kluckner PD (1979) Digestion of environmental materials for analysis by inductively coupled plasma-atomic emission spectrometry Analytical Chemistry 51 1082-1084
Reardon J Foreman JA and Serai RL (1966) New reactants for the determination of ammonia Clinica Chemica Acta 14 403-405
Robertson WJ McPharlin IR and Jeffery RC (1994) Final report of investigation into the use of gypsum-amended Red Mud as a soil-amendment for horticultural properties on the Swan Coastal Plain Final Report of HRDC Project No V0039 RO
Robertson WJ Jeffery RC and McPharlin IR (1997) Residues from bauxite-mining (Red Mud) increase phosphorus retention of a Joel sand without reducing yield of carrots Communications in Soil Science and Plant Analysis 28 (13 amp 14) 1059-1079
Varley JA (1966) Automatic methods for the determination of nitrogen phosphorus and potassium in plant material Analyst 91 119-126
Vlahos S Summers KJ Bell DT and Gilkes RJ (1989) Reducing phosphorus leaching from sandy soils with Red Mud bauxite processing residues Australian Journal of Soil Research 27 651-662
Walkley A and Black I (1934) An examination of the Degtjareff method of determining soil organic matter and a proposed modification of the chromic acid titration method Soil Science 37 29-38
Yuen SH and Pollard AG (1954) Determination of nitrogen in agricultural material by the Nessler reagent II Micro determination in plant tissue and soil extracts Journal of the Science of Food and Agriculture 5 364-369
104
The use of Red Mudgypsum in vegetable production
CO JC
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0 200 400 600 800
Level of residual AG(tha)
1000 1200
Appendix 71 (b) P leached (kgha) from Joel sands sown to carrots amended with residual Alkaloanrgypsum (AG) in pots on 16 April 1996 (week 3) (bull) 6 May 1996 (week 6) (bull) and 22 July 1996 (week 16) ( bull ) P was applied preplanting as superphosphate and carrots were sown on 3 April 1996 Vertical bars refer to Lsd (P lt 005) for differences in quantities of P leached between level of AG (across all levels of applied P) at each sampling time Where bars arent shown Lsd is less than size of symbol Data from Appendix 71 (a)
105
The use of Red Mudgypsum in vegetable production
200 400 600 800
Level ofresidual AG(tha)
1 000 1 200
2 00
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copy
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1 2 0
100 -
80 200 400 600 800
Level of residual AG (tha)
1000 1200
Appendix 73 (b) 74 (b) Ammonium-N (A) and Nitrate-N (B) leached (kgha) from Joel sands sown to carrots amended with residual Alkaloamreggypsum (AG) in pots on 16 April 1996 (week 3) (bull) 6 May 1996 (week 6) (bull) and 22 July 1996 (week 16) (A) N was fertigated postplanting as NH4-N and NO3-N and carrots were sown on 3 April 1996 Vertical bars refer to differences in quantities of N leached between level of AG (across all levels of applied P) at each sampling time Where bars arent shown Lsd is less than size of symbol Data from Appendices 73 (a) 74 (a)
106
The use of Red Mudgypsum in vegetable production
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Appendix 75 76 K (A) and Na (B) in leachate from Joel sand sown to carrots amended with residual Alkaloamreggypsum (AG) in pots on 16 April 1996 (week 3) (bull) 6 May 1996 (week 6) (bull) and 22 July 1996 (week 16) (A) The carrots were sown on 3 April 1996 K was fertigated at a constant concentration of 200 mgL from sowing to harvest and Na was a constituent of AG Vertical bars refer to Lsd (P lt 005) for differences in quantities of K and Na leached between level of AG (across all levels of applied P) at each time Where bars arent shown Lsd is less than size of symbol
107
The use of Red Mudgypsum in vegetable production
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Appendix 77 78 Ca (A) and Mg (B) in leachate from Joel sand sown to carrots amended with residual Alkaloamreggypsum (AG) in pots on 16 April 1996 (bull) 6 May 1996 (bull) and 22 July 1996 (A) The carrots were sown on 3 April 1996 Ca was applied preplanting as superphosphate (and as a constituent of AG) and fertigated at a constant concentration of 50 mgL from sowing to harvest Mg was applied preplanting and in weeks 6 (15 May 1996) and 12 (25 June 1996) Vertical bars refer to Lsd (P lt 005) for differences in quantity of Ca and Mg leached between level of AG (across all levels of applied P) at each sampling time Where bars arent shown Lsd is less than size of symbol Data from Appendices 77 (a) and 78 (a)
108
The use of Red Mudgypsum in vegetable production
200 400 600 800
Level of residual AG(tha)
1000 1200
Appendix 79 S (mgL) in leachate from Joel sands sown to carrots with level of residual Alkaloamreggypsum (AG) 16 April 1996 (week 3) (bull) 6 May 1996 (week 6) (bull) 22 July 1996 (week 16) (A) The carrots were sown on 3 April 1996 S was applied preplanting as K2S04 in superphosphate and as a constituent of AG Vertical bars refer to Lsd (P lt 005) for differences in quantity of S leached between level of AG (A) or P (B) at each sampling time Where bars arent shown Lsd is less than size of symbol Data from Appendix 79 (a)
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The use of Red Mudgypsum in vegetable production
An additional benefit which was not thoroughly investigated in this project but was obvious in the pot experiment was increased soil moisture holding capacity especially at high levels of application due to an increased in the fine fractions after amendment These benefits should be achieved at low to moderate levels of applied AG (ie 60 to 120 tha) without any negative effect on vegetable yield or quality
Some negative effects of amending acid sands with fresh AG include decreased yield due to increased conductivity and induced K deficiency in some vegetables such as potatoes However this does not appear to be a problem with carrots and cauliflower
This problem can be obviated by allowing sufficient time to leach the soluble alkalinity (Na2SCgt4) out of the root zone of the amended soil prior to cropping as it is less of a problem with residual AG Another disadvantage is the increase in fertiliser P requirements of vegetables after AG amendment in the short term due to increased P fixation This is particularly obvious at high levels of application However this disadvantage is offset as soil testing can be used on sands after amendment to reduce P fertiliser costs whereas it couldnt beforehand Also on unamended Joel sands leaching of P fertilisers (ie 80 of applied P) causes significant economic loss due to fertiliser losses and increased fertiliser P required for maximum yield
12 Industry summary
An important domestic and export vegetable industry is located on the sands of the Swan Coastal Plain (SCP) in Western Australia The total value of the vegetable industry on the SCP was estimated at $90M in 19967 or about 50 of the total value of the industry This vegetable production has been located on good quality sands such as the Spearwood and yellow Karrakatta sands close to the coast since the 1950s However in recent years competition for this land for urban and industrial use has forced vegetable production onto soils with poorer water and phosphorus retention capacity such as the more acidic Bassendean (Joel) and grey-phase Karrakatta sands This has lead leaching of fertiliser phosphorus into water systems of the SCP such as lakes rivers and estuaries with resulting pollution (algae blooms) Even though vegetable production is not the only or main source of this leached phosphorus the issue has resulted in negative publicity for the industry and increased scrutiny of industry practices by government agencies charged with responsibility for water the environment and health
As large quantities of Red Mud (Alkaloamreg)gypsum (AG) were produced from bauxite refining on the SCP it made sense to examine this as a soil amendment as it had been shown to improve the phosphorus retention capacity of coarse grey sands low in iron and aluminium oxides AG consistently increases the phosphorus retention capacity and the retention of cations such as potassium magnesium and ammonium-nitrogen and pH (lime effect) of grey and pale-yellow sands after amendment The reduction fertiliser P leaching is very high even at the lower rates of application such as 60 and 120 tha Fresh AG will increase the fertiliser phosphorus requirements of most vegetable crops compared with the unamended plots similar to the differences between low and high P fixing soils However this increase is not as much on residual or aged AG sites This increase in initial fertiliser P needs following AG application is offset by the use of soil testing to manage P fertiliser in subsequent crops on grey sands which was not practical prior to amendment Some initial problems with fresh AG causing yield reductions on potatoes was attributed to induced potassium deficiency due to high conductivity (ie high sodium) in amended soils However this problem can be overcome by leaching the soil of salts after amendment with high rates of irrigation so that EC of the amended soil doesnt exceed 6 mSm and the pH (water) 85 The potassium nutrition of the crop should be monitored to ensure it is adequate There is no problem on sites where AG has been applied for at least 12 months
2
The use of Red Mudgypsum in vegetable production
13 Recommendations It is recommended that AG be used as a soil amendment for vegetable crops on the grey and pale yellow sands of the SCP to reduce P fertiliser leaching However a number of guidelines should be adhered to ensure maximum benefits and minimum risks from the use of AG
bull Potatoes should not be grown on sites where fresh AG (ie 1 to 3 months after application) has been applied
bull Potatoes can be grown on sites where AG has be applied at levels up to 120 tha provided at least 12 months previously provided sufficient leaching of salts has occurred As a guide it is suggested that soil conductivity should not exceed 6 mSm and pH (water) 85 in the top 15 cm
bull Vegetable crops other than potatoes can be planted into sites where fresh AG has been applied at levels up to 120 tha without problems
bull Adjust level of P fertiliser application to account for increased P fertiliser requirements of vegetables due to higher P fixing on sites amended with AG
bull Use soil testing to manage P fertiliser applications on AG amended sites but follow recommendations for specific vegetable crops
The use of Red Mudgypsum in vegetable production
2 PROJECT STAFF
Ian McPharlin
Wendy Robertson
Bob Jeffery
Tony Shimmin
Jenny Harboard
Don Glenister
Patricia Aylmore
David Cooling
Gavin dAdhemar
Neil Lantzke
John Ferguson (Manager) and staff
Staff
COLLABORATORS AND ACKNOWLEDGMENTS
Project Manager and Principal Investigator
Research Officer
Project Collaborating Scientist (Chemistry Centre of WA)
Project Technical Officer
Project Laboratory Technician (Chemistry Centre of WA)
Residue Development Manager (Alcoa of Australia)
Environmental Scientist (Alcoa of Australia)
Senior Consultant Residue (Alcoa of Australia)
Technical Officer Medina Research Centre (for technical assistance and management of field and pot experiments)
Horticultural Extension Officer (for extension advice)
Medina Research Centre (for management of field experiments)
Chemistry Centre of WA (for advice of on soil plant and leachate chemistry)
4
The use of Red Mudgypsum in vegetable production
3 PUBLICATIONS ARISING OUT OF WORK Robertson WJ McPharlin IR and Jeffery RC (1997) The growth nutrition and
composition of potatoes (Solarium tuberosum L) cv Delaware grown on a yellow Karrakatta sand amended with freshly-applied and residual Alkaloamreggypsum Australian Journal of Experimental Agriculture (submitted)
McPharlin IR dAdhemar G and Shimmin TR (1997) The response of cauliflowers (Brassica oleraceae L) cv Plana to freshly-applied and residual Alkaloamreggypsum and phosphorus on a Karrakatta sand Australian Journal of Experimental Agriculture (in prep)
McPharlin IR Shimmin TR and dAdhemar G (1997) Leaching of P N and cations from carrots grown on Joel sands amended with residual Alkaloamreggypsum Communications in Soil Science and Plant Analysis (in prep)
The use of Red Mudgypsum in vegetable production
4 RESPONSE OF POTATOES TO FRESHLY-APPLIED AND RESIDUAL RED MUD (ALKALOAMreg)GYPSUM AND PHOSPHORUS ON A YELLOW KARRAKATTA SAND
Introduction
Previous work has shown that freshly-applied Alkaloamreggypsum (gypsum-amended red mud 10 ww) (AG) at 60 and 120 tha reduced the total yield of potatoes by 7 and 23 respectively compared with 01 AGha controls (Robertson et al 1994 Appendix 1 J) The reduction in marketable yield was almost identical to the reduction in total yield The exact cause of this reduction in yield could not be determined particularly the reduction at 120 tha It was unlikely to be a reduced availability of P Observations on commercial properties suggest that AG which has been in the soil for several seasons does not cause yield reductions in potatoes
Phosphorus was banded at planting in this experiment Subsequent work (Hegney and McPharlin unpublished data) showed that broadcasting P allowed a greater maximum yield of potatoes than banding P on Karrakatta sands of low P fertility
This experiment re-examines the response of potatoes to freshly-applied AG using broadcast P and also the effect of residual AG on growth of potatoes at unlimiting P
Materials and methods
Site characteristics
The experiment was conducted on a yellow Karrakatta sand (described by McArthur and Bettenay 1960) at Medina approximately 30 km south of Perth Two sites were used a site where pasture species had been grown several years earlier and to which no AG had ever been applied and a second (adjacent) site where AG had been applied approximately 2J2 years earlier A lettuce and a cauliflower crop had been grown previously on this site after AG amendment (Robertson et al 1994 Appendix 1H I)
Red Mud (Alkaloamreg)gypsum (AG)
Red Mud (Alkaloamreg)gypsum (10 ww) (AG) was produced by the dry mix process by ALCOA of Australia Ltd at their Kwinana Residue Treatment Plant It was spread manually on the previously unamended site on 22 December 1994 and was incorporated to a depth of approximately 30 cm using a rotary hoe The AG on the previously-amended site (residual AG) was applied using the same techniques on 24 November 1992 The freshly-applied AG was watered for 1 hour three times a week until planting
Experimental design
The freshly-applied and residual AG sites were used for separate experiments which were conducted simultaneously The experiment on the freshly-applied AG was a split-plot randomised complete block design with three replicates Main plots were levels of AG (0 60 90 and 120 tha) and sub-plots were levels of P application (0 25 50 100 300 and 600 kgha) Main plots measured 48 x 21 m and sub-plots measured 24 x 7 m (three rows of potatoes with 08 m between row centres) There was a 2 m buffer around each main plot The experiment on the residual AG site was a randomised complete block design with 4 levels of AG (0 60 120 and 240 tha) and three replicates The levels of AG were applied in November 1992 and had had several levels of P applied to them in the previous crops The AG plots measured 6 x 12 m but only an area of 34 x 8 m (4 rows of potatoes with 08 m between row centres) was cropped to allow a buffer of 1 to 2 m all around the planted area
6
The use of Red Mudgypsum in vegetable production
Crop management Both sites were initially sprayed with Roundupreg (3 Lha) to kill weeds and the sites were hoed with a rotary hoe Freshly-applied AG was applied at this stage The residual AG site was treated with metham sodium approximately two weeks before planting Potatoes cv Delaware were planted on both sites on 18 May 1995 using a single row mechanical planter Round seed was used and this was dusted with Rizolexreg (2 kgt) immediately before planting Sets were planted 15 cm apart The crops were irrigated using impact sprinklers once daily at 80 of Class A pan evaporation between planting and emergence and then at 100 of evaporation Afalonreg (15 kgha) was applied after planting and Sprayseedreg (2 Lha) was applied at 5 emergence both for weed control Nitofol (700 rnLha) was used for regular insect control Bravoreg (2 Lha) was applied every seven days from the time of 50 ground cover until blight symptoms appeared at which time it was then alternated with Rovralreg (2 Lha) at 7 day intervals Both crops were harvested on 15 November 1995
Fertilisers
Pre-planting fertilisers were broadcast by hand on 15 May 1995 on freshly-applied AG and on 16 May on residual AG These were 83 kg Kha as K2S04 10 kg Mgha as miso47H20 and a complete trace element mix containing (kgha) MnS04H20 (504) MgS047H20 (560) borax (336) FeS047H20 (336) CuS045H20 (336) ZnS04H20 (280) and Na2Mo042H20 (224) Single superphosphate (91 P) was broadcast by hand at 0 to 600 kg Pha on freshly-applied AG according to the treatment and at 600 kg Pha on all plots on residual AG Post-planting fertilisers were a total of 500 kg Nha as NH4NO2 and KN02 and 400 kg Kha as KN02 in equal amounts for 10 weeks via the irrigation system An extra 50 kgha MgS04 was applied in weeks 7 and 9
Measurements
(a) Plant
The petioles of the Youngest Mature Leaf (YML) often plants were collected at the S2 stage (longest tuber 10 mm long) (19 July 1995) on both freshly-applied and residual AG They were dried in a forced draught oven at 70degC and then analysed for P N K Na Ca Mg S B Cu Fe Mn and Zn On freshly-applied AG tubers were harvested from a 5 m length of the middle row of each plot On residual AG a 4 m length of the two middle rows of each plot was harvested Tubers were separated into the following size grades lt 30 g 30-80 g 80-250 g 250-450 g and gt 450 g Tubers between 30 g and 450 g were considered marketable except if they were green or damaged
Of the tubers in the 80-250 g category ten were sampled from each plot for P analysis They were washed in tap water and sliced thinly with a stainless steel knife Fresh and dry weights were measured before the tubers were analysed for total P
(b) Soil
All 0 kg Pha plots on freshly-applied AG were sampled to 15 cm depth (15 cores per plot) on 29 August (approximately 3 months after planting) They were analysed for Bicarbonate-extractable P (Bic-P) (Colwell 1963) total P EC pH (H20) pH (CaCl2) Phosphorus Retention Index (PRI) (Allen and Jeffery 1990) and P buffering capacity (Ozanne and Shaw 1968) Before fertilisers were applied to the residual AG site on 16 May 15 cores (0-15 cm) were sampled from each plot and analysed for Bic-P and PRI Residual AG plots were sampled again on 29 August (0-15 cm 15 cores per plot) and analysed for pH (H20) pH (CaCl2) EC and P buffering capacity All residual AG plots and 0 100 and 600 kg Pha freshly-applied AG plots were sampled to three depths (0-15 15-30 and 30-45 cm) (20 cores per plot) on 5 December (ie after harvest)
7
The use of Red Mudgypsum in vegetable production
Chemical analysis
Plant samples were ground to pass through a 1 mm screen after drying Concentrations of P N K and Na were measured by digesting the samples with sulphuric acid and hydrogen peroxide (Yuen and Pollard 1954) N and P were determined colorimetrically by indophenol blue and molybdo-vanadate methods respectively K and Na were determined by flame photometry All analysis was conducted on a 4-channel Auto-analyser system using modifications of Technicon procedures (Anon 1977) Samples for analysis of Ca Mg S Cu Fe B Mn and Zn concentrations were digested with nitricperchloric acids (McQuaker et al 1979) Concentrations were measured by inductively-coupled plasma atomic emission spectrometry (ICP-AES) Concentrations of heavy metals were determined using inductively-coupled plasma mass spectrometry (ICP-MS) with indium as an internal standard Samples were initially crushed in an agate mortar and digested using nitric and perchloric acids
All soil samples were dried at 40degC in a forced draught oven Lumps of AG and fertiliser in samples were crushed and the samples were thoroughly mixed and sieved to lt 2 mm before analysis The pH (H20) and the EC were determined on a 15 soilwater extract after shaking for 1 hour The pH (CaCl2) was determined on 15 soiksolution extract using 001 M CaCl2 after shaking for 1 hour Values for both are corrected to 25 degC Total P was determined on a Kjeldahl digest of a separate sub-sample of soil ground to less than 015 mm The concentration of phosphate was measured by the method of Murphy and Riley (1962)
Statistical analysis
All data were analysed by an Analysis of Variance (ANOVA) using Genstat v 50 Results from the two experiments were analysed separately Data from the freshly-applied AG site was analysed by a two-way ANOVA on level of Alkaloamreg and level of applied P while data from residual Alkaloamreg were analysed by a one-way ANOVA on level of AG Statistical differences were determined using a Least Significant Difference at 5 level of significance where the F value from the ANOVA was significant Mitscherlich curves were fitted to all relationships between level of applied P and yield petiole or tuber P concentration or total P uptake Maximum values of Mitscherlich equations were compared using a 5 t-test Linear relationships were fitted to the yield response on residual Alkaloam versus level of AG and also to the relationship between yield and petiole P concentration on freshly-applied AG
The amount of fertiliser P retained was calculated by subtracting total P at 0 kg Pha from the measured total P value Concentrations of P in ugg were converted to kilograms per hectare by multiplying by a factor of 225 This is based on the assumption that there are 2250 t soilha in the top 15 cm of soil
Results and discussion
Soil characteristics
The pH (H20) of the top 15 cm of soil at mid-growth when no P fertiliser was applied increased from 72 on unamended soil to 84 and 85 on amended soil (Table 41) EC also increased from 5 mSm on unamended soil to 8 and 9 mSm on amended soil (Table 41) Bic-P was approximately 10 ugg at all AG levels and total P ranged from 55 ugg on unamended soil to 76 ugg at 901 AGha (Table 41) PRI and P buffering capacity (Pbug) both increased between unamended and amended soil but there were no differences between levels of AG on amended soil PRI of amended soil was 26 to 30 and Pbuff was 24 to 30 (Table 41)
The Bic-P and PRI measurements taken two days before planting on residual AG were the same at all levels of AG Bic-P was 16 to 21 ugg and PRI was 37 to 53 (Table 42) On the other hand Pbuff measured mid-growth increased from 20 at 01 AGha to 30 and 40 at 120 and 2401 AGha The EC was 7-9 mSm on all treatments and pH (H20) increased between 0 and 120 t AGha from 73 to 84 (Table 42)
The use of Red Mudgypsum in vegetable production
Table 41 Characteristics of the top 15 cm of a Karrakatta sand amended with several levels of freshly-applied Alkaloamreggypsum (AG) when no fertiliser P was applied
AG (tha)
pH (H20)
pH (CaCl2)
EC (mSm)
Bic-P (ugg)
Total P (ugg)
PRI Pbuff
0 72 64 5 8 55 19 14
60 84 77 8 10 64 26 24
90 85 78 9 11 76 30 30
120 85 83 9 10 71 27 27
Signif NS NS $
Lsd 5 04 05 3 07 05
Table 42 Characteristics of the top 15 cm of a Karrakatta sand amended with several levels of residual Alkaloamreggypsum (AG) when 600 kg Pha was applied as superphosphate
AG (tha)
pH (H20)
pH (CaCl2)
EC (mSm)
Bic-Pa
(ugg) PRIa
Pbuff
0 73 67 7 16 37 20
60 78 71 5 17 40 23
120 84 77 9 20 44 30
240 88 80 9 21 53 40
Signif NS NS NS
Lsd 5 05 06 10
K Sampled and measured before application of fertiliser P
Total phosphorus in soil
Total P in the soil at harvest on freshly-applied AG increased significantly with level of AG averaged over all three depths sampled (P lt 005) It also increased with level of applied P on all levels of AG At 0-15 cm total P increased significantly between 0 and 601 AGha At 15-30 cm it increased significantly between 0 and 90 t AGha and at 30-45 cm there was no effect of level of AG at all (Fig 41) At all levels of AG and P which were sampled total P concentrations at 0-15 cm and 15-30 cm were not significantly different from each other and both were significantly greater than those at 30-45 cm (Fig 41)
In the top 15 cm of soil total P increased from 47 ugg on unamended soil to 62-67 ugg on amended soil when no fertiliser P was applied This increase represents the total P content of the AG itself When 100 kg Pha was applied total soil P (0-15 cm) increased from 63 ugg at 01 AGha to 83 ugg at 601 AGha and 95 and 103 ugg at 90 and 1201 AGha (Fig 41) When the increase due to the AG itself is considered this is an increase in fertiliser P retention of 6 ugg (26 kgha) between 0 and 601 AGha and a further 14 ugg (62 kgha) between 60 and 120 t AGha At 600 kg Pha the increase in fertiliser P retention was 35 ugg (15 kgha) between 0 and 601 AGha and 25 ugg (11 kgha) between 60 and 120 t AGha
Total P on residual AG increased with level of AG The increase was significant between 60 and 1201 AGha only It also decreased at increasing depth As observed on freshly-applied AG total P concentrations at 0-15 cm and 15-30 cm were not significantly different from each other and were both greater than that observed at 30-45 cm (Fig 43) At 0-15 cm total P increased by 20 ugg between 0 and 601 AGha and by a further 213 ugg between 60 and 1201 AGha when 600 kg Pha was applied These values cannot be corrected for the total content of AG itself as there was no 0 kg Pha treatment
9
The use of Red Mudgypsum in vegetable production
The addition of freshly-applied AG to the soil substantially increased the theoretical ability of the soil to sorb applied P as measured by the P buffering capacity in the top 15 cm of soil However it was reduced over time as 1201 AGha was required to increase Pbuff on residual AG compared with 601 AGha on freshly-applied AG Fertiliser P retention in the top 15 cm of soil when amended with 1201 AGha was increased by 9 at 100 kg Pha and by 4 at 600 kg Pha
The effects of residual and freshly-applied AG can be compared at 600 kgha of applied P The effect of residual AG on fertiliser P retention can be estimated from measurements made on the same site at the beginning of the first (lettuce) crop In that experiment total P before the application of P fertilisers increased from 69 and 62 ugg on 0 and 601 AGha to 91 ugg on 1201 AGha and 103 ugg on 2401 AGha (Robertson et al 1994 Appendix 1H) This makes the estimated increase in fertiliser P retention (0-15 cm) 27 ugg (12 kgha) between 0 and 601 AGha and 184 ugg (81 kgha) between 60 and 1201 AGha Therefore between 60 and 1201 AGha residual AG increased fertiliser retention by approximately 7 times as much as did freshly-applied AG
Bicarbonate-extractable P (soil-test P) in soil
On freshly-applied AG there was no overall response of Bic-P to level of AG although there was an upward trend Bic-P decreased with increasing depth averaged over all treatments following the same response as total P There was an interaction between the effects of depth and level of applied P At 0 kg Pha there was no difference in Bic-P between the three depths sampled but at 100 and 600 kg Pha Bic-P concentrations at 0-15 cm and 15-30 cm were both greater than those at 30-45 cm (Fig 42) The upward trend in Bic-P with increasing level of AG was weak on soil where no P fertiliser had been applied being from 9-10 ugg at 0 and 601 AGha to 11 and 14 ugg at 90 and 1201 AGha in the top 15 cm This suggests that the AG adds little if any plant available P to the soil The amount of fertiliser P retained as Bic-P in the top 15 cm of soil when 100 kg Pha was applied increased by 8 ugg between 0 and 601 AGha and by a further 4 ugg between 60 and 120 t AGha At 600 kg Pha Bic-P retained from fertiliser increased by 34 ugg between 0 and 601 AGha and by 16 ugg between 60 and 1201 AGha
The response of Bic-P to level of residual AG and to depth was the same as for total P (Fig 43) In the top 15 cm of soil Bic-P increased by 11 ugg between 0 and 601 AGha and by 82 ugg between 60 and 1201 AGha uncorrected for the Bic-P content of the AG itself
The increase in Bic-P retention observed on amended soil at 100 kg Pha was similar to that observed at 160 kg Pha on a crop of carrots grown on a Joel sand amended with AG (Robertson et al 1997) Using the soil-test standards published by Hegney et al (1997) these increases in Bic-P will reduce the P fertiliser requirement in the following potato crop by 10 at 601 AGha and 22 at 1201 AGha
Using the Bic-P concentrations observed on the residual site at the beginning of the lettuce crop (Robertson et al 1994 Appendix 1H) the increase in fertiliser P retained as Bic-P (0-15 cm) on residual AG was 15 ugg between 0 and 601 AGha and 79 ugg between 60 and 1201 AGha This is half the increase observed on freshly-applied AG between 0 and 60 t AGha and approximately 5 times that observed on freshly-applied AG between 60 and 1201 AGha
The reduced P retention at low levels of residual AG compared with freshly-applied AG was probably because of the higher initial Bic-P levels on residual AG For both total and Bic-P it is difficult to explain why the apparent retention of fertiliser P between 60 and 120 t AGha should have been so much greater on residual than on freshly-applied AG It may have been caused by changes to the chemical properties of the AG as it aged in the ground
10
The use of Red Mudgypsum in vegetable production
Yield
Total and marketable yields on freshly-applied AG both increased with level of applied P following a Mitscherlich response (Fig 44 (a) (b)) An ANOVA did not indicate any response to level of AG in either total or marketable yields However maximum total yield on unamended soil (61 tha) was significantly greater than that on AG-amended soil - 54 to 57 tha (Fig 44 (a)) On the other hand there were no differences in maximum marketable yields Maximum marketable yield values ranged from 52 to 55 tha (Fig 44 (b)) When marketable yield was calculated as a percentage of total yield an ANOVA indicated a significant interaction between level of AG and level of applied P At 400 kg Pha marketable yield was 88 of total yield on unamended soil compared with approximately 95 on amended soil (significant according to 5 Lsd) A similar trend was observed at 600 kg Pha where marketable yield was 90 of total yield on unamended soil and 93 to 96 on amended soil
The levels of applied P required for 99 of maximum total yield were 245 222 183 and 400 kg Pha on 0 60 90 and 1201 AGha and for 95 of maximum yield were 139 130 108 and 226 kg Pha (Fig 44 (a)) A similar trend can be seen for marketable yield where 99 of maximum yield required 178 206 208 and 356 kg Pha (Fig 44 (b))
Total yield on residual AG showed an almost significant response to level of AG (P = 0067) (Fig 45) Total yield was 68 to 72 tha on 0 60 and 120 t AGha and 62 tha on 2401 AGha Marketable yield was 65 to 68 tha on 0 to 1201 AGha and 58 tha on 2401 AGha Therefore 2401 AGha appears to reduce yields even when it has been in the ground for 2 years or more and even when 600 kg Pha is applied As only one level of P fertiliser was applied it is not possible to determine the effect of residual AG on the critical levels of P application required for 99 and 95 of maximum yield
Concentration of nutrients in petioles
Phosphorus
Phosphorus concentration in petioles of the YML sampled at the S2 stage on freshly-applied AG increased with level of applied P following a Mitscherlich response (Fig 46) Maximum petiole P concentrations were approximately 12 (dry basis) on all AG levels Values at 99 of maximum petiole P concentration were 116 122 117 and 116 at 0 60 90 and 1201 AGha There was a significant interaction between levels of AG and applied P (P lt 005) At low levels of applied P (25 50 and 100 kgha) P concentrations on amended soil were significantly less than those on unamended soil but there was no difference between them at 300 or 600 kg Pha This is reflected in the levels of applied P required for 99 of maximum petiole P concentration which were 209 499 581 and 508 kg Pha at 0 60 90 and 1201 AGha This is an increase of 138 on amended soil relative to unamended soil AG at levels of between 60 and 120 tha therefore reduces the availability of P to plants As there was no difference in the maximum P concentration in petioles between amended and unamended soil a reduction in P availability to plants cannot explain the reduced maximum yield on amended soil Another factor was therefore involved in reducing maximum yield on amended soil Despite this yield difference between amended and unamended soil which was not related to differences in P concentration total yield for all AG levels combined was linearly correlated with petiole P concentration at the S2 stage (y = 256 + 274x R2 = 087) (Fig 47)
The petiole P concentration at 99 of maximum total yield was 116 109 095 and 114o at 0 60 90 and 1201 AGha At 01 AGha this was the same as 99 of maximum petiole P concentration implying that the yield response on unamended soil was controlled principally by P availability On the other hand petiole P concentrations at 99 of maximum yield on amended soil especially 60 and 901 AGha were less than 99 of maximum petiole P concentration In other words yield stopped increasing even though P concentration in the plant kept increasing This supports the previous observation that some factor other than P was limiting yield in these treatments Petiole P concentration in YMLs sampled at S2 stage on residual AG did not change with level of AG Overall mean P concentration was 12 dry
11
The use of Red Mudgypsum in vegetable production
basis This is in keeping with the results observed on freshly-applied AG at 600 kg Pha It also means that the lower yield at 2401 AGha on residual AG could not be explained by a reduced P concentration in the plant As on freshly-applied AG another factor was involved which reduced yield on amended soil although at a higher level on residual than on freshly-applied AG
Hegney et al (1997) found that maximum petiole P concentration at S2 in potatoes grown on Karrakatta sand was 114 dry basis and that 109 was required for 99 of maximum yield in good agreement with the results observed here
Other nutrients
The responses of nutrients other than P were very similar on both freshly-applied and residual AG Concentrations of K (Tables 43 45) and Zn (Fig 48 (a) Table 45) decreased as level of AG increased and concentrations of Mg Fe and Ca increased with level of AG in both experiments (Tables 43 45 Fig 48 (b)) Zn concentrations also decreased with increasing level of applied P (Fig 49 (a)) while Ca concentrations increased with level of applied P (Fig 48 (b)) Concentrations of Na also showed an upward trend on both freshly-applied and residual AG (Tables 43 45) On freshly-applied AG K concentrations decreased significantly from 119 dry basis on unamended soil to 110 at 601 AGha and to 102 at 1201 AGha (Table 43) On residual AG it decreased from 11-12 at 0-1201 AGha to 103 at 2401 AGha (Table 45) No other nutrients showed any response to level of AG although concentrations of N Mn S and B increased with level of applied P on freshly-applied AG (Table 44)
Concentrations of all nutrients except K were adequate or more than adequate for maximum yield (Maier et al 1987) on both freshly-applied and residual AG Potatoes require concentrations of approximately 12 to 14 K (dry basis) in petioles of YML for maximum yield (Maier et al 1987) On freshly-apphed AG concentrations were adequate at 01 AGha but were less than adequate on amended soil On residual AG concentrations were adequate at 0 60 and 1201 AGha but less than adequate at 2401 AGha As less than adequate K concentrations correspond with those treatments which had low yield it is likely that K concentration was the limiting factor in yield on both freshly-applied and residual AG
Uptake of K may have been reduced at higher levels of AG due to an increased Cation Exchange Capacity (Barrow 1982 McPharlin et al 1994) or to the increased soil pH (Harris 1992) The reduction in Zn availability on amended soil is most likely to be a result of the increase in soil pH due to the AG (Harter 1983)
Table 43 Concentrations of several nutrients in the petioles of the Youngest Mature Leaf of potato plants sampled at the 10 mm tuber stage at several levels of freshly-applied Alkaloamreggypsum (AG) on a yellow Karrakatta sand
AG K Na Mg Fe (tha) () () () (ngg)
0 119 018 059 382
60 110 020 065 553
90 106 021 066 597
120 102 021 069 697
Signif NS
Lsd 5 04 004 119
12
The use of Red Mudgypsum in vegetable production
Table 44 Concentrations of several nutrients in the petioles of the Youngest Mature Leaf of potato plants sampled at the 10 mm tuber stage at two levels of applied P when grown on a yellow Karrakatta sand amended with freshly-applied Alkaloamreggypsum (AG)
Applied P N S Cu Mn B (kgha) () () (ngg) (ngg) (M-gg)
0 44 028 74 293 267
600 48 032 62 342 248
Signif NS NS
Table 45 Concentrations of several nutrients in the petioles of the Youngest Mature Leaf of potato plants sampled at the 10 mm tuber stage at several levels of residual Alkaloamreggypsum (AG) on a yellow Karrakatta sand
AG N K Na Ca S Mg Cu Fe Mn Zn B (tha) () () () () () () (l-igg) (ngg) (ngg) Ws) (^gg)
0 51 116 016 23 030 050 77 453 46 96 26
60 48 127 015 21 027 045 61 457 45 67 25
120 49 120 016 26 029 051 66 643 59 59 25
240 49 103 019 29 030 067 54 977 53 53 24
Signif NS NS NS NS NS NS
Lsd5 05 04 013 164 24
Tuber P and Crop P removal P concentration in tubers
The concentration of P in tubers on freshly-applied Alkaloamreg increased with level of applied P (P lt 0001) The response at each level of Alkaloamreg was best described by a Mitscherlich curve although none of the curves reached a maximum within the range of fertiliser P levels used (Fig 49 (a)) There was a trend for an overall response to level of AG (P = 0081) P concentrations were generally higher on unamended soil than on amended soil For example at 300 kg Pha P concentration was 033 on unamended soil and 026-028 on amended soil and at 600 kg Pha P concentrations were 036 and 032-033 on unamended and amended soil respectively At P levels corresponding to 99 of maximum yield tuber P concentration was 031 024 023 and 028 at 0 60 90 and 1201 AGha
On residual AG tuber P concentration did not change with level of AG The overall mean was 036 dry basis
Total P uptake
Total P uptake by tubers on freshly-applied AG showed a significant response to level of AG (P lt 005) and level of applied P (P lt 0001) The response to applied P at each level of AG was best described by a Mitscherlich curve although as for tuber P concentration none of the curves reached a maximum within the range of P levels applied P uptake by tubers on unamended soil was significantly greater than on amended soil regardless of AG level (Lsd 5) (Fig 49 (b)) At levels of applied P corresponding to 99 of maximum yield P uptake by tubers was 113 75 75 and 95 kgha at 0 60 90 and 1201 AGha These figures are lower than results reported by Hegney et al (1997) who found a P uptake by tubers grown on yellow Karrakatta sand of 204 kgha at 99 of maximum yield even though yields were similar to those observed on unamended soil in this experiment
13
The use of Red Mudgypsum in vegetable production
Total P uptake by tubers was not significantly different between AG levels on residual AG Overall mean P uptake was 110 kgha This is different from the situation observed at 600 kg Pha on freshly-applied AG As only one level of P was applied the response curve for tuber P concentration on residual AG cannot be compared with that on freshly-applied AG It is possible that less applied P is required on residual than on freshly-applied AG to reach maximum tuber P concentration
Metals in tubers
The concentration of As in tubers harvested from freshly-applied AG showed a trend to increase with level of AG from 5 x 104 mgkg (fresh weight) on unamended soil to 8 x 104 mgkg at 60 and 901 AGha (Fig 410) Concentrations of all other metals measured showed no response to level of AG either on residual or freshly-applied AG (Table 46 47) On freshly-applied AG concentrations of Ni and Cd increased and concentrations of Cu decreased with increasing level of applied P (Table 48)
Table 46 Mean concentrations (mgkg fresh weight) of metals in tubers of potato cv Delaware harvested from a yellow Karrakatta sand amended with freshly-applied Alkaloam^gypsum (AG)
Cr Co Sn Sb Hg
mean
se
0007
61 xlO5
60 x 104
50 x 106
15 x 103
10 x 104
90 x 105
10 xlO5
34 x 104
14 x 105
Table 47 Mean concentrations (mgkg fresh weight) of metals in tubers of potato cv Delaware harvested from a yellow Karrakatta sand amended with residual Alkaloamreggypsum (AG)
Cr Co Ni Cu As Cd Sn Sb Hg Pb
mean
se
001
68X104
72xl(f 29xia5
55xia3
17x1a4
010
35xia3
L2X103
0
58xia3
17X104
LOxlO3
29X104
30X1O4
43xl05
84X1G4
ii xia5
l ixia3
70xia5
Table 48 Mean concentrations (mgkg fresh weight) of metals in tubers of potato cv Delaware harvested from a yellow Karrakatta sand amended with freshly-applied Alkaloamreggypsum (AG) at various levels of applied P
Applied P (kgha)
Ni Cd Cu
0 0006 0002 018
100 0006 0002 016
300 0007 0004 015
600 0008 0006 013
Signif
Lsd (5) 00014 0001 002
The concentrations of As observed in tubers from freshly-applied AG regardless of the level of AG were less than 10 of the legal limit (10 mgkg fresh weight NFA 1992) The concentrations of all metals measured were between 3 and 33 of those measured in potato tubers in a previous experiment (Robertson et al 1994 Appendix 1 J) The concentrations on residual AG were also lower than the concentrations previously observed in lettuce and cauliflowers on the same site (Robertson et al 1994 Appendix IH I) As different batches of
14
The use of Red Mudgypsum in vegetable production
AG were used on the two sites they cannot be compared to determine the effect of time on metal availability and uptake Overall metal uptake by potato tubers grown on AG-amended yellow Karrakatta sand does not appear to pose any greater health risk than that on unamended yellow Karrakatta sand The observed increase in As concentration in potato tubers on freshly-applied AG was probably due to the increase in soil pH with level of AG (ONeill 1990)
Conclusions
Freshly-applied AG reduces the availability of fertiliser P so that approximately 25 times the level of applied P is required on 60 to 1201 AGha relative to unamended soil in order to attain maximum P concentration in plant tissues AG at 120 tha also increases the retention of fertiliser P sufficiently to reduce fertiliser requirements for a following potato crop by approximately 20 The effect of AG on the level of fertiliser P required for 99 of maximum yield was confounded in this experiment by the decrease in maximum yield between unamended and amended soil Total yield of potatoes will be reduced on 60 tha freshly-applied AG and by 240 tha residual AG probably by a limiting concentration of K There is potential for increased levels of K fertiliser to overcome this yield reduction AG increases the proportion of yield which is marketable so that even though total yield is reduced by 60 tha of freshly-applied AG the marketable yield is not There are no apparent problems with heavy metal contents of tubers due to amendment with AG
References Allen DG and Jeffery RC (1990) Methods for analysis of phosphorus in Western
Australian soils Chemistry Centre of WA Report of Investigation No 37
Anonymous (1977) Technicon Industrial Method 334-74WB+ Technicon Industrial Systems Tarrytown NY USA
Barrow NJ (1982) Possibility of using caustic residue from bauxite for improving the chemical and physical properties of sandy soils Australian Journal of Agricultural Research 275-285
Colwell JD (1963) The estimation of phosphorus fertiliser requirements of wheat in southern New South Wales by soil analysis Australian Journal of Experimental Agriculture and Animal Husbandry 3 190-197
Glenister DJ and Thoraber MR (1985) Alkalinity of red mud and its application for the management of acid wastes Chemeca 85 109-113
Harris PM (1992) Mineral Nutrition In The Potato Crop The scientific basis for improvement 2nd edition (ed P Harris) pp 162-213 (Chapman and Hall London UK)
Harter RD (1983) Effect of soil pH on adsorption of lead copper zinc and nickel Soil Science Society of America Journal 47 47-51
Hegney MA McPharlin IR and Jeffery RC (1997) Response of winter-grown potatoes (Solanum tuberosum L) to applied and residual phosphorus on a Karrakatta sand Australian Journal of Experimental Agriculture 37 (in press)
Maier NA Williams CMJ Potocky-Pacay K Moss D and Lomman GJ (1987) Interpretation standards for assessing the nutrient status of irrigated potato crops in South Australia Technote AGDEX 262533 September 1987 Department of Agriculture South Australia
15
The use of Red Mudgypsum in vegetable production
McArthur WM and Bettenay E (1960) The development and distribution of the soils of the Swan Coastal Plain Western Australia CSIRO Division of Soils Soils Publication No 16
McPharlin IR Jeffery RC Toussaint LF and Cooper M (1994) Phosphorus nitrogen and radionuclide retention and leaching from a Joel sand amended with red mudgypsum Communications in Soil Science and Plant Analysis 25 489-500
McQuaker NR Brown DF and Kluckner PD (1979) Digestion of environmental materials for analysis by inductively coupled plasma atomic emission spectrometry Analytica Chimica 51 1082-1084
Murphy J and Riley JP (1962) A modified single solution method for the determination of phosphate in natural waters Analytica Chimica Acta 27 31-36
NFA (National Food Authority) (1992) Australian Food Standards Code June 1992 (Australian Government Publishing Service Canberra)
ONeill P (1990) Arsenic In Heavy Metals in Soils(ed BJ Alloway) pp 83-99 (Blackie Glasgow)
Ozanne PG and Shaw TC (1967) Phosphate sorption by soils as a measure of the phosphate requirement for pasture growth Australian Journal of Agricultural Research 18 601-612
Robertson WJ McPharlin IR and Jeffery RC (1994) Final Report of investigation into the use of gypsum-amended red mud as a soil-amendment on horticultural properties on the Swan Coastal Plain Agriculture WA
Robertson WJ McPharlin IR and Jeffery RC (1997) Residues from bauxite-mining (red mud) increase phosphorus retention of a Joel sand without reducing yield of carrots Communications in Soil Science and Plant Analysis (in press)
Yuen SH and Pollard AG (1954) Determination of nitrogen in agricultural materials by the Nessler reagent II Micro-determination in plant tissue and in soil extracts Journal of Food in Agriculture 5 364-369
16
The use of Red Mudgypsum in vegetable production
300
250 -
I I
200
3
60 80
AG (tha)
140
Figure 41 Total phosphorus concentration in a yellow Karrakatta sand amended with freshly-applied Alkaloamreggypsum (AG) vs level of AG when 0 (bull) 100 (A) and 600 (bull) kg Pha was applied measured at 0-15 cm () 15-30 cm (mdash) and 30-45 cm (mdash) depth Bars are Lsds at 5 level of significance
17
The use of Red Mudgypsum in vegetable production
Z3
200
180 -
160
Q- 140
ro 120 bull 4 -
O CD X 100 CD i
3 80 CO c o
pound gt v_ CO
o CQ
AG Depth
I
0 20 40 60 80 100 120
AG (tha)
140
Figure 42 Bicarbonate-extractable phosphorus concentration in a yellow Karrakatta sand amended with freshly-applied Alkaloamreggypsum (AG) vs level of AG when 0 (bull) 100 (A) and 600 (bull) kg Pha was applied measured at 0-15 cm () 15-30 cm (mdash) and 30-45 cm (mdash) depth Bars are Lsds at 5 level of significance
18
The use of Red Mudgypsum in vegetable production
700
600
500
D)
3 400
CL
oil
300 CO
200
100
100 150
A G (tha)
250
Figure 43 Total (mdash) and Bicarbonate-extractable phosphorus () concentration in a yellow Karrakatta sand amended with residual Alkaloamreggypsum (AG) when 600 kg Pha was applied measured at 0-15 cm () 15-30 cm (A) and 30-45 cm (bull) depth Bars are Lsds at 5 level of significance
19
The use of Red Mudgypsum in vegetable production
CO
2 CD
gt-
200 300 400
Applied P (kgha)
Figure 44 (a) Total yield of potatoes cv Delaware grown on a yellow Karrakatta sand amended with freshly-applied AIkaIoamreggypsum (AG) at a level of 0 (bull) 60 (A) 90 (bull) and 120 (bull) tha vs level of applied P Lines represent the level of applied P required for 99 of maximum yield Bars are Lsds at 5 level of significance
Equations are
A
B
C
D
0 tha
60 tha
90 tha
120 tha
j - 614 - 255 x exp (-00152) (JR= 092)
y = 542 - 271 x exp (-00176) (R2= 090)
y = 552 - 274 x exp (-0021) (F= 094)
y = 566 - 229 x exp (-00092) (i^= 098)
20
The use of Red Mudgypsum in vegetable production
ro
JO
gt-
100 200 300 400
Applied P (kgha)
500 600
Figure 44 (b) Total yield of potatoes cv Delaware grown on a yellow Karrakatta sand amended with freshly-applied Alkaloamreggypsum (AG) at a level of 0 (bull) 60 (A) 90 (bull) and 120 (bull) tha vs level of applied P Lines represent the level of applied P required for 99 of maximum yield Bars are Lsds at 5 level of significance
Equations are
Otha A
B
C
D
60 tha
90 tha
120 tha
y = 547 - 216 x exp (-0021) (R2^ 088)
y = 517 - 278 x exp (-0019) (R2= 090)
y = 524 - 243 x exp (-001 to) (R2= 094)
y = 530 - 218 x exp (-001 Ox) (i^= 098)
21
The use of Red Mudgypsum in vegetable production
CO
32
gt-
80
70
60
50
40
30
20
10
0 0
Marketable yield
Marketable yield
Total yield
Total yield
_L 50 100 150 200
AG (tha)
250 300
Figure 45 Total (bull) and Marketable (bull) yield of potatoes cv Delaware grown on a yellow Karrakatta sand amended with residual AIkaloamreggypsum (AG) vs level of AG 600 kg Pha was applied Bars are Lsds at 5 level of significance
22
The use of Red Mudgypsum in vegetable production
w CO CO
a gtraquo i _
C
o 00
c CD O c o o
100 200 300 400
Applied P (kgha)
500
Figure 46 Concentration (dry basis) of phosphorus in petioles of the Youngest Mature Leaf of potatoes cv Delaware grown on a yellow Karrakatta sand amended with freshly-applied Alkaloamreggypsum (AG) at 0 (bull) 60 (A) 90 (bull) and 120 (bull) tha vs level of applied P Lines represent the level of applied P required for 99 of maximum yield Bars are Lsds at 5 level of significance
Equations are
A Otha y = 117- 079 x exp (-0020) (R2 = 096)
B 60 tha y=123- 096 x exp (-000874) (R2 - 099)
C 90 tha y = 118 - 0884 x exp (-000742) (R2 = 096)
D 120 tha y= 117 - 090 x exp (-00085) (R2 = 097)
23
The use of Red Mudgypsum in vegetable production
CO
c
53
CD
gt-
00 02 04 06 08 10
Petiole P ( dry basis)
12 14
Figure 47 Yield of potatoes cv Delaware grown on a yellow Karrakatta sand amended with freshly-applied AlkaIoamreggypsum (AG) at 0 (bull) 60 (A) 90 (bull) and 120 (bull) tha vs petiole P concentration
The equation is y = 256 + 274x (ft2 = 087)
24
The use of Red Mudgypsum in vegetable production
poundgt 3
0 100 200 300 400 500 600 700
Applied P (kgha)
Figure 48 (a) Concentration of Zinc and (B) Calcium ( dry weight) in petioles of the youngest mature leaf of potatoes cv Delaware harvested from a yellow Karrakatta sand amended with freshly-applied Alkaloamreggypsum (AG) at 0 (bull) 60 (A) 90 (bull) and 120 (bull) tha vs level of applied P Bars are Lsds at 5 level of significance
25
The use of Red Mudgypsum in vegetable production
100 200 300 400 500
Applied P (kgha)
700
Figure 48 (b) Concentration of Calcium ( dry weight) in petioles of the youngest mature leaf of potatoes cv Delaware harvested from a yellow Karrakatta sand amended with freshly-applied AlkaIoamreggypsum (AG) at 0 (bull) 60 (A) 90 (bull) and 120 (bull) tha vs level of applied P Bars are Lsds at 5 level of significance
The use of Red Mudgypsum in vegetable production
040
ogt 035 CD
gtgt bullo
w _CB O
H) CL
CO 1 _ -mdashraquo c CD O c o o Q
030 -
025 -
020
2 015
010 -
005
000 0 100 200 300 400
Applied P (kgha)
500 600
Figure 49 (a) The concentration of phosphorus in tubers ( dry weight) of potatoes cv Delaware harvested from a yellow Karrakatta sand amended with freshly-applied Alkaloamreggypsum (AG) at 0 (bull) 60 (A) 90 (bull) and 120 (bull) tha vs level of applied Pkgha Bars are Lsds at 5 level of significance
Equations are
A 0 tha
B 60 tha
C 90 tha
D 120 tha
y = 0372 - 0243 x exp (-00058) (R2 = 097)
y = 0378 - 0257 x exp (-00029x) (R2 = 098)
y = 0361 - 0216 x exp (-00029x) (i^= 095)
y = 0406 - 0279 x exp (-0002x) (R2 = 098)
27
The use of Red Mudgypsum in vegetable production
CO
3
ltD
CO Q Z5
ID
B
14
12 -^ ^
10
8 W
6
4
A G P
I
2
n I i i I I i
0 100 200 300 400
Applied P (kgha)
500 600
Figure 49 (b) Phosphorus uptake Gigha) by tubers of potatoes cv Delaware harvested from a yellow Karrakatta sand amended with freshly-applied Alkaloamreggypsum (AG) at 0 (bull) 60 (A) 90 (bull) and 120 (bull) tha vs level of applied P Bars are Lsds at 5 level of significance
Equations are
Otha A
B
C
D
60 tha
90 tha
120 tha
y = 140 - 1095 x exp (-00058r) (R2 = 096)
3= 111 - 882 x exp (-0004x) (R2 = 098)
y = 104 - 774 x exp (-00053) (R2 = 099)
3 = 127 -101 x exp (-00029x) (R2 = 0997)
28
The use of Red Mudgypsum in vegetable production
60 80
AG (tha)
Figure 410 Concentration of Arsenic (dry weight) in tubers of potatoes cv Delaware grown on a yellow Karrakatta sand amended with freshly-applied Alkaloamreggypsum (AG) Bar is Lsd at 5 level of significance
29
The use of Red Mudgypsum in vegetable production
5 RESPONSE OF CAULIFLOWERS TO FRESHLY-APPLIED RED MUD (ALKALOAMreg)GYPSUM AND PHOSPHORUS ON A YELLOW KARRAKATTA SAND
Introduction
It is important to reduce the leaching of phosphorus fertiliser from sandy soils used for vegetable production into the water systems of the Swan Coastal Plain Red Mud (AlkaloamR)gypsum (AG) a waste product from bauxite refining has been suggested as an amendment to reduce phosphorus leaching from sands of the Bassendean Association (Joel Gavin) used for agriculture and horticulture (Barrow 1982)
Experimental work in the field and pots showed amendment with AG significantly reduced P leaching from Joel and Gavin sands (Vlahos et al 1989 McPharlin ei al 1994) compared with the unamended (01 AGha) treatment
In previous work freshly-applied AG at 60 tha increased the amount of freshly-applied P required for maximum yield of cauliflowers 14 (autumn planted) but did not reduce maximum yield (20 tha) compared with the unamended (0 tha) treatment on a yellow Karrakatta sand (Robertson et al 1994) At the highest rate of applied AG (120 tha) P required for maximum yield was 32 higher than at 0 tha and maximum yield was reduced 23 (P lt 005)
Since more than 60 tha of AG may be required to significantly improve P retention by sands to enable sustainable horticultural production this yield reduction is re-examined with freshly-applied AG
Materials and methods
Site characteristics
The experiment was conducted on a yellow Karrakatta sand (McArthur and Bettenay 1960) of low P fertility at Medina Research Centre (32deg 13 S 115deg 49 E) 30 km South of Perth The site had no previous history of AG application and had been sown to pasture for several years Some relevant chemical characteristics of the topsoil (0-15 cm) and subsoil (15-30 cm) of the site after application of AG but prior to the application of fertiliser and transplanting are presented in Table 51
Red Mud (AlkaIoamreg)gypsum (AG)
Alkaloamreg (Red Mud) amended with 10 (ww) gypsum (AG) was produced by the dry mix process by ALCOA of Australia Ltd at their Kwinana Residue Treatment Plant The AG was spread manually on the site and incorporated using a rotary hoe to approximately 30 cm depth on 21 February 1996 The site was watered for 1 hour per day (8 mmday) using impact sprinklers until planting
Experimental design
The experimental design was a split-plot randomised block with 3 replicates The main plots were levels of AG (0 60 120 and 240 tha) and the sub-plots were levels of freshly-applied P (0 50 100 200 400 and 600 kgha) Main plots measured 6 x 12 m and sub-plots 12 x 6 m (excluding wheel tracks)
Crop management
The site was sprayed with Roundupreg (3 Lha) twice after application of AG and prior to planting to control weeds
The use of Red Mudgypsum in vegetable production
Six week old seedlings of cauliflowers (cv Plana) obtained from a commercial nursery were transplanted manually on 18 April 1996 in 2 rows per plot with 70 cm between rows and 50 cm between plants Seedlings were dipped in Rovralreg 1 mLL just prior to planting for control of fungi Treflanreg (14 Lha) and Dacthalreg (12 kgha) were applied immediately after transplanting to control broadleaved weeds and Sertinreg later on in the life of the crop for grass control Ambushreg (100 mLha) and Rogorreg (100 mLha) were used to control caterpillars and red legged earth-mite respectively Copper sprays were used for control of blackrot The crop was irrigated to a total application equivalent to 100 of the previous days pan evaporation using minisprinklers (Legoreg 6 x 6 m spacing 44 mmh) in 3 waterings of equal duration per day
Fertilisers
Pre-planting fertilisers were broadcast manually and rotary hoed on 17 April 1996
These were K2S04(244) Ca (N03)2 4H20 (387) MgS047H20 (504) MnS04H20 (504) FeS047H20 (18) Borax (27) CuS045H20 (36) ZnSOH20 (28) and Na2Mo042H20 (2) Single superphosphate (91 P)was applied at 0 to 600 kgha according to treatment and incorporated as before Post-planting K N and Ca were fertigated via the irrigation system as KN03 NH4NO3 and Ca (N03)2 in equal amounts per day for 12 weeks to a total of 600 kg K 423 kg N and 60 kg Caha Borax was fertigated at 20 kgha in week 3 and Mg was broadcast as MgS047H20 at 50 kgha in weeks 3 6 and 9
Measurements
Soil and soil solution
All zero P subplots were sampled 30 cores per plot just prior to planting and fertilising about 2 months after AG application to 2 depths (0-15 15-30 cm) These were oven dried at 40degC and analysed for Ec pH (CaCl2) P sorption (Ozanne and Shaw 1968) bicarbonate extractable P K (Colwell 1963) total P PRI P sorption K sorption (Allen and Jeffery 1990) and cation exchange capacity (Gillman and Sumpter 1986)
The soil water was obtained by centrifugation from soil samples (0-15 cm 30 per plot) and collected from the 0 100 200 and 600 kg Pha plots across all AG treatments on 16 May 1996 The supernatant was analysed for pH Ec Ca Mg K S and P The remaining soil was analysed for pH (H20) bicarbonate extractable P and K PRI and DTPA extractable Zn After harvest on 5 August 1996 soil samples were collected from 2 depths as for the preplanting treatment from all plots These were analysed for pH bicarbonate extractable P K total P PRI and exchangeable cations (Ca Mg K and N)
Plant
At buttoning on 13 June 1996 the younger mature leaves (YML) (4th from growing point) were collected from 16 plants in each plot (excluding 1 m buffer at each end) They were dried at 70degC in a force draught oven for 48 h and ground to pass through a 1 mm screen Sub-samples were digested with sulphuric acidhydrogen peroxide (Yuen and Pollard 1954) and the concentration of N P and K measured by an automated colorimetric process (Varley 1966) Concentration of other nutrients (B Ca Na Mg S Fe Mn Zn and Cu) were determined by inductively coupled plasma atomic emission spectroscopy (ICP-AES) after digestion with nitric-perchloric acids (McQuaker et al 1979)
Five whole plants were harvested from the middle of each plot (2 per row)at the end of the experiment on 4 July 1996 using shovels to recover as much of the root system as possible The plants were separated into four categories curds leaves stems and roots All soil was washed from the roots using tap water shaken and the excess water removed using paper towels The fresh weight of all four categories was recorded and the material was diced into small pieces (lt 8 cm3) using stainless steel knives sub-samples (300 g fresh weight) were collected at random from the diced pieces and the fresh weight recorded These were dried at
31
The use of Red Mudgypsum in vegetable production
70degC in a forced draught oven for 48 h and the dry weight recorded These samples were then analysed for P as for the youngest mature leaves Separate sub-samples (300 g fresh weight) of curds were collected and analysed for Ba Cd Cr Co Pb Mo Rb Sr Ti Th V and N using inductively coupled plasma mass spectrometry (ICP-MS) The fresh and dry weight of the curds leaves stems and roots at harvest were used to calculate P uptake in kgha)
Harvest
Harvest commenced when the leaves surrounding the head opened and exposed the curds 77-80 days after transplanting At this stage florets at the periphery of the curd had just begun to separate Sixteen curds (12 plus 4 from whole plant samples above) were collected from the central 4 m of both rows (1 m buffer) and all the leaves and stems removed according to requirements for export market Each fresh curd was weighed and rejects recorded if undersize (lt 500 g) oversize (gt 2000 g) discoloured (yellowing) overmature (separation of florets in centre of curd) diseased damaged or otherwise distorted The total marketable and reject yield were recorded for each plot
Analysis of data
Analysis of variance was carried out on level of applied AG or P versus (a) chemical characteristics of soil (bicarbonate extractable P total P etc) preplanting and harvest (b) concentrations of nutrients in soil solution at midgrowth (c) concentration of nutrients in YMLs at midgrowth (d) concentration of elements in curds at harvest (e) P uptake by plant parts and (f) total marketable and reject yield of curds at harvest Mitscherlich curves and inverse polynomials were fitted to the relationship between level of applied P and yield at each level of applied AG The level of applied P required for 95 99 and 100 (in case of inverse polynomials) of maximum yield was calculated Mitscherlich curves were fitted to the relationship between level of applied P and P in YMLs at midgrowth at all levels of AG The P in YMLs corresponding to the level of applied P required for 95 99 or 100 of maximum yield (as determined from yield versus applied P plots) was then determined
Mitscherlich curves were also fitted to the relationship between level of applied P and P uptake by curds leaves stems and roots and the P uptake corresponding to whole plants (additions of all 4) level of P required for 95-100 of maximum yield determined Phosphorus uptake by plant parts or whole plants on 0 P plots were detected from P uptake at other rates to account for non-fertiliser sources of P This was used to adjust P uptake When determining P fertiliser recovery efficiency (RE) by plant parts or whole plants (ie fertiliser P uptake by plant parts or whole plantsP applied both in kgha Novoa and Loomis 1981)
Results
Effects of fresh AG on chemical characteristics of soil and soil solution
There was a significant (P lt 005) increase in the Ec pH PRI and sorption capacity (topsoil only) of the topsoil and subsoil of a yellow Karrakatta sand with level of freshly-applied AG prior to fertiliser application and planting (Table 51) There was no significant effect of level of AG on Colwell K K sorption capacity and total P with level of freshly-applied AG (Table 51)
The use of Red Mudgypsum in vegetable production
Table 51 Some chemical characteristics of the topsoil (0-15 cm) and subsoil (15-30 cm) of a yellow Karrakatta sand after application of Alkaloam gypsum (AG)1 just prior to fertiliser application and transplanting
(a) Topsoil (0-15 cm)
AG (tha)
Ec (mSm)
pH (CaCl2)
BicP2
(Vigfe)
BicK2
(pgg) PRI3
(mLg) TP4
(Pgg) CEC5
(me ) Kads6 Pads7
0 37 74 107 153 097 507 2 0 41
60 67 82 93 197 167 473 2 043 66
120 80 82 100 277 243 607 2 044 78
240 103 84 97 290 38 637 2 058 129
Lsd8 202 037 38 136 046 1010 0 049 41
Sig9 ns ns ns ns ns
(b) Subsoil (15-30 cm)
AG Ec PH BicP2 BicK2 PRI3 TP4
(tha) (mSm) (CaCl2) (Pgg) (Pgg) (mLg) (Pgg)
0 30 72 83 227 07 507
60 63 81 73 190 15 453
120 80 81 87 220 18 540
240 107 83 83 240 27 563
Lsd8 202 037 38 136 046 101
Sig9 ns ns ns
Applied 7 weeks previously 2 After Colwell (1963) 3 Phosphorus retention index after Allen and Jeffery (1990) 4 Total phosphorus 5 Cation exchange capacity (Gillman and Sumpter 1986) 6 Slope of K adsorption isotherm from the Freundlich equation (Allen and Jeffery 1990) 7 Slope of P adsorption isotherm from the Freundlich equation (Allen and Jeffery 1990) 8 Least significant difference at P lt 005 9 Significance at lt 0001 () lt 001 () lt 005 () level or not significant (ns)
There was a significant (P lt 005) increase in the concentration of Na and a decrease in the concentration of K in the soil solution with level of freshly-applied AG one month after planting and fertilising (Table 52 (a) and Fig 51) At the same time Colwell K and PRI in the topsoil increased significantly with level of freshly-applied AG By contrast there was a significant decrease in extractable Zn with level of AG The concentration of Ca Mg S and P increased significantly with level of applied P in soil solution (Table 52 (a)) Colwell P in the topsoil increased significantly with level of P whilst Colwell K PRI and extractable Zn decreased at the same time (Table 52 (b))
33
The use of Red Mudgypsum in vegetable production
Table 52 (a) Ec (mSm) pH and concentration of nutrients (pgmL) in soil solution 1 month after planting with level of freshly-applied Alkaloamreggypsum (AG)1 and phosphorus
AG
AG (tha)
Ec (mSm)
pH Ca (pgmL)
Mg (pgmL)
Na (pgmL)
K (pgmL)
S (pgmL)
P (pgmL)
Psrp2
(VigmL)
0 112 70 175 18 110 77 101 57 56
60 132 74 164 17 137 58 92 34 31
120 172 75 166 17 152 54 97 44 34
240 166 81 130 16 198 34 75 24 11
Lsd3 19 025 33 4 16 11 26 27 32
Sig4 ns ns ns ns ns
p
AG (tha)
Ec (mSm) PH
Ca (pgmL)
Mg (pgmL)
Na (pgmL)
K (pgmL)
S (UgmL)
P (pgmL)
Psrp2
(pgmL)
0 137 78 99 15 150 46 26 10 01
100 142 76 112 15 153 54 52 23 14
200 170 74 179 19 150 62 114 39 30
600 133 72 244 19 144 60 174 89 87
Lsd3 43 022 31 24 17 15 29 25 30
Sig4 ns ns ns
Applied 11 weeks previously
Soluble reactive P 3 Least significant difference at P lt 005 4 Significance at lt 0001 () lt 001 () lt 005 () level or not significant (ns)
The use of Red Mudgypsum in vegetable production
220
200
E 180 O ) 3
^ 1fi0 _ o 3 140 O V)
oil
120 m c
100 C o CO 80 c flgt o B0 c o o 40
20
0 50 100 150 200
Freshly-applied AG(tha)
250 300
Fig51 Concentration (ugml) of Na(i ) and K ( bull ) in soil solution (0-15cm) under cauliflowers one month after planting with level of freshly-applied AlkaloamRgypsum(AG) Vertical bars indicates Lsd (Plt005) for differences in concentration betweeen levels of AG
35
The use of Red Mudgypsum in vegetable production
Table 52 (b) Extractable P K Zn and phosphorus retention index of the top soil (0-15 cm) of a yellow Karrakatta sand 1 month after transplanting with level of freshly-applied Alkaloamreggypsum (AG)1 and phosphorus (P)
AG
AG (tha)
P2
(ugg) K2
(Ugg) Zn3
(Pgg)
PRI4
(mLg)
0 47 32 67 -112
60 76 38 15 -090
120 94 42 26 -049
240 84 41 13 092
Lsd5 35 6 28 073
Sig6 ns
P P2 K2 Zn3 PRI4
(kgha) (ugg) (Hgg) (Ugg) (mLg)
0 8 42 31 201 100 35 37 45 043 200 80 39 18 -089 600 177 34 26 -313
Lsd5 39 6 27 082
Sig6 ns
Applied 11 weeks previously 2 After Colwell (1963) 3 Extracted in DTPA 4 Phosphorus retention index (Allen and Jeffery 1990) 5 Least significant difference at P lt 005 6 Significance at lt 0001 () lt 001 () lt 005 () level or not significant (ns)
Ec pH exchangeable Ca K Na in me and Colwell P K total P PRI and PRIP increased significantly (P lt 005) with level of freshly-applied AG in the topsoil and subsoil of a yellow Karrakatta sand (Table 53 (a) (b) and Fig 52) at harvest
The use of Red Mudgypsum in vegetable production
o CO
CD
E
o CO
co o
CD
X co CD ogt e co sz o X HI
50 100 150 200
Freshly-applied AG (tha)
250 300
Fig52 Exchangeable Ca() NaP) and K(A) cations (me dry soil) in topsoil (0-15cm) of Karrakatta sand amended with freshly-applied AlkaloamRgypsum(AG) after harvest of cauliflowers Vertical bars indicates Lsd (Plt005) for differences in concentration between levels of AG Lsd not shown when less than size of symbol
37
The use of Red Mudgypsum in vegetable production
Table 53 Ec (mSm) pH and exchangeable Ca Mg K and Na (me ) in the topsoil (0-15 cm) and subsoil (15-30 cm) of a yellow Karrakatta sand amended with AlkaIoamreggypsum (AG) at harvest of cauliflowers
(a) Topsoil
AG Ec PH Ca Mg K Na (tha) (mSm) (CaCl2) (me ) (me ) (me ) (me )
0 67 66 229 018 005 003
60 91 77 382 019 009 02
120 99 79 558 019 012 043
240 120 80 975 024 014 104
Lsd2 20 014 064 0033 0018 021
Sig3 ns
(b) Subsoil
AG Ec pH Ca Mg K1 Na (tha) (mSm) (CaCl2) (me ) (me ) (me ) (me )
0 44 67 225 017 005 003
60 59 74 269 019 005 008
120 66 77 300 018 005 017
240 99 79 397 02 005 029
Lsd2 075 01 029 0036 001 002
Sig3 n s ns
Extracted in 1 m NH4CI 2 Least significant difference at P lt 005 3 Significance at lt 0001 () lt 001 () lt 005 () level or not significant (ns)
However there was no effect of either level of AG or P on exchangeable Mg in the soil at harvest Colwell P total P and PRIP increased significantly whilst Colwell K and PRI decreased with level of freshly-applied P in the topsoil at harvest (Table 4 (a) (b) and Fig 53)
The use of Red Mudgypsum in vegetable production
Table 54 P (extractable P total P phosphorus retention index and P sorption) in the top soil (0-15 cm) and subsoil (15-30 cm) of a yellow Karrakatta sand at harvest of cauliflowers with level of freshly-applied Alkaloamreggypsum (AG) and phosphorus (P)
(a) Topsoil
AG
AG BicP1 BicK1 TotP2 PRI3 PRIP3
(tha) (ugg) (Pgg) (Hgg) (mLg) (mLg)
0 39 23 92 -07 28
60 50 38 110 02 50
120 59 51 135 16 75
240 58 62 157 35 99
Lsd4 5 11 15 03 06
Sig5
P BicP1 BicK1 TotP2 PRI3 PRIP3
(kgha) (ugg) (Hgg) (ngg) (mLg) (mLg)
0 10 53 57 29 40
50 15 40 66 22 38
100 25 41 78 17 44
200 53 41 128 14 71
400 87 44 186 -01 86
600 120 41 226 -12 102
Lsd4 11 8 20 09 13
Sig5
1 After Colwell (1963) 2 After Allen and Jeffery (1990) 3 After Allen and Jeffery (1990) 4 Least significant difference at P lt 005 5 Significance at lt 0001 () lt 001 () lt 005 () level or not significant (ns)
39
The use of Red Mudgypsum in vegetable production
Table 54 P (extractable P total P phosphorus retention index and P sorption) in the top soil (0-15 cm) and subsoil (15-30 cm) of a yellow Karrakatta sand at harvest of cauliflowers with level of freshly-applied Alkaloamreggypsum (AG) and phosphorus (P)
(b) Subsoil (15-30 cm)
AG
AG BicP1 BicK1 TotP2 PRI3 PRIP3
(tha) (ugg) (Ugg) (Ugg) (mLg) (mLg)
0 33 20 79 -05 26
60 30 21 73 -01 30
120 33 27 77 08 42
240 26 24 76 13 40
Lsd4 10 2 10 04 10
Sig5 ns ns
P BicP1 BicK1 TotP2 PRI3 PREP3
(kgha) (ugg) (Vigg) (Ugg) (mLg) (mLg)
0 7 25 48 15 22
50 11 22 52 09 19
100 15 24 59 10 27
200 32 23 81 06 39
400 51 22 100 -03 47
600 67 21 117 -11 52
Lsd4 8 5 8 05 09
Sig5 ns
1 After Colwell (1963) 2 After Allen and Jeffery (1990) 3 After Allen and Jeffery (1990) 4 Least significant difference at P lt 005 5 Significance at lt 0001 () lt 001 () lt 005 () level or not significant (ns)
The use of Red Mudgypsum in vegetable production
100 150 200
Freshly-applied AG (tha)
300
Fig53 Concentration of total P(A) Colwell P() or K(laquo) in topsoil (0-15cm) with level of freshly-applied AlkaloamRgypsum (AG) after harvest of cauliflowers Vertical bars indicates Lsd (Plt005) for differences in concentration between levels of AG Lsd not shown when less than size of symbol
41
The use of Red Mudgypsum in vegetable production
Nutrients in leaves at midgrowth and harvest
There was a significant decrease in concentration of K and an increase in concentration of Na S Mn and Cu in youngest mature leaves (YML) of cauliflowers at buttoning with level of freshly-applied AG (Table 55) The concentration of P in YML at 01 AGha (049) was significantly higher than at 2401 AGha (044) but not at other levels Currently-applied AG had no significant effect on concentration of N Ca Mg Fe Zn or B in YML There was a significant increase in YML in the concentration of K P and S in YML with level of applied P whilst concentration of N Mg Mn and B were variable (Fig 54 55) Level of applied P had no significant effect on the concentration of Ca and Na in the YML (Table 55)
Table 55 (a) Concentration of macro-nutrients (dry weight basis) in youngest mature leaves of cauliflowers at buttoning with level of freshly-applied Alkaloamreggypsum (AG) and phosphorus (P)
AG
AG N1 K1 Ca2 S2 P1 Na2 Mg2
(tha) () () () () () () ()
0 482 393 240 081 049 036 023
60 484 383 251 084 046 040 024
120 506 357 255 081 046 045 024
240 494 355 246 088 044 056 025
Lsd3 026 012 024 005 003 006 0013
Sig4 ns ns ns ns
p
p N1 K1 Ca2 S2 P1 Na2 Mg2
(kgha) () () () () () () ()
0 523 316 254 066 024 046 025
50 489 372 255 081 041 049 026
100 503 388 229 084 048 042 024
200 472 379 250 089 050 046 024
400 494 390 242 093 057 043 023
600 470 385 258 091 057 039 022
Lsd3 027 024 036 005 003 008 0017
Sig4 ns ns
1 After Varley (1966) 2 After McQuaker et al (1979) 3 Least significant difference at P lt 005 4 Significance at lt 0001 () lt 001 () lt 005 () level or not significant (ns)
The use of Red Mudgypsum in vegetable production
0 50 100 150 200 250 300
Freshly-applied AG (tha)
Rg54 Concentration of N() K(B) and Ca(A) in youngest mature leaf (YML) at buttoning
of cauliflowers with level of freshly-applied AlkaloamRgypsum(AG) Vertical bars
indicates Lsd (Plt005) for differences in concentration between levels of AG
10
bdquo 09 lt Q OR ^ D) 07 c
tto
06 3
X3
to 05 _ l
gtbull 04 C
i3 03 c agt bull c 02 3
-z 01 0 50 100 150 200 250 300
Freshly-applied AG (tha)
Rg55 Concentration of S() Na(B) Mg(4) and P(T) in youngest mature leaf (YML) at buttoning
of cauliflowers with level of freshly-applied AlkaloamRgypsum(AG) Vertical bars indicates Lsd (Plt005) for differences in concentration between levels of AG
43
The use of Red Mudgypsum in vegetable production
The relationship between P in YML at buttoning and level of freshly-applied P was best described by Mitscherlich relationships at all levels of applied AG (Fig 56)
en c o 3
X2
gt
06
^
bull A
05 ^ S
04
03
02
01
n n i i i
0 100 200 300 400 500 600 700
Applied P (kgha)
o
X I
5 gt
06
05
04
03
02
01
00
- bull B
- bull bull ^
o
I I I I
0 100 200 300 400 500 600 700
Applied P (kgha)
100 200 300 400 500 600 700
Applied P (kgha)
100 200 300 400 500 600 700
Applied P (kgha)
Fig56 P in YML of Cauliflowers at buttoning () corresponding to applied P required for either 95 (dashed line) or 99 (whole line) of maximum yield at 0(A) 60(B) 120(C) or240(D)t of freshly-applied AlkaloamRgypsumha
The equations for the fitted lines are
A
B
C
D
y = 056 - 030 x exp (-00182) (R2 = 097)
y = 057 - 032 x exp (-00103) (R2 = 088)
y = 055 - 031 x exp (-00126) (R2 = 099)
y = 056 - 032 x exp (-00092) (R2 = 098)
The P in YML corresponding to level of freshly-applied P required for 99 of maximum yield was 053 057 055 and 055 for 0 60 120 and 240 tha respectively
44
The use of Red Mudgypsum in vegetable production
Table 55 (b) Concentration of micro-nutrients (dry weight basis) in youngest mature leaves of cauliflowers at buttoning with freshly-applied Alkaloamreggypsum (AG) and phosphorus (P)
AG
AG (tha)
Fe (Pgg)
Zn (Ugg)
Mn (vigg)
B (Pgg)
Cu1
(Pgg)
0 1354 251 217 211 26
60 1274 248 237 213 28
120 1353 253 240 217 27
240 1394 263 260 214 29
Lsd2 153 24 15 082 02
Sig3 ns ns ns
P Fe Zn Mn B Cu (kgha) (ngg) (ugg) (Pgg) (Ugg) (Pgg)
0 1418 268 212 215 26
50 1388 253 263 220 27
100 1301 267 251 217 29
200 1336 249 250 217 28
400 1282 255 232 204 28
600 1341 233 224 210 28
Lsd2 197 29 19 08 02
Sig3 ns ns ns
1 Extracted in 1 m NH4CI 2 Least significant difference at P lt 005 3 Significance at lt 0001 () lt 001 () lt 005 () level or not significant (ns)
There was a significant (P lt 005) decrease in the concentration of P Zn and an increase in the concentration of Na in whole leaves (WL) of cauliflowers with rate of freshly-applied AG at harvest (Table 56) Level of freshly-applied AG had no significant effect on concentration of N K Ca S Mg Fe Mn B or Cu Concentration of Ca S P and Na in (WL) at harvest increased significantly (P lt 005) with level of freshly-applied P whereas Zn concentrations decreased and concentrations of Mg Mn and B were variable Level of freshly-applied P had no significant effect on concentration of N K Fe or Cu in WL at harvest
45
A O O ltyi
4x
r en 00
9 400 200 o o o copy
ns
O
kgt ON
kgt
4gt
kgt 4 4 4^
kgt
ns
O 4 4 ON 4 k)
o
i mdash t mdash raquo
4 00
4 ON
4 4^ NO Q O
o copy ON
i mdash gt
b b 1 mdash t
b o p Vcopy
O 00 ON
o ON
gtmdash 5 co 5J M
o o
O in
o 4 Ncopy
o 4 O
p 4
p kgt 1 mdash t
copy
ON
o b NO
O ON
o 00
o 00
o ON I mdash
O ON
O 3 Z 5 raquoM
o b 4
O
kgt o kgt -J
p kgt 00
O kgt 00
O
kgt NO
copy kgt ON
The use of Red Mudgypsum in vegetable production
Table 56 (b) Concentration of micro-nutrients (dry weight basis) in leaves of cauliflowers at harvest with level of freshly-applied Alkaloamreggypsum (AG) and phosphorus (P)
AG
AG (tha)
Fe1
(ugg) Zn1
(vgg) Mn1
(vgg) B1
(vgg) Cu1
(vigg)
0 762 224 214 263 42
60 700 197 227 265 38
120 811 196 216 254 38
240 842 193 236 256 37
Lsd2 132 099 21 16 06
Sig3 ns ns ns ns
P (kgha)
Fe1
(pgg) Zn1
(^gg) Mn1
(Vigg) B1
(lJgg) Cu1
(Pgg)
0 786 233 213 248 36
50 625 235 241 266 37
100 833 207 237 270 41
200 938 192 235 265 44
400 725 178 208 259 37
600 765 169 206 250 37
Lsd2 230 21 21 11 063
Sig3 ns ns
After McQuaker et al (1979)
Least significant difference at P lt 005
Significance at lt 0001 () lt 001 () lt 005 () level or not significant (ns)
47
The use of Red Mudgypsum in vegetable production
Nutrients and heavy metals in curds at harvest
There was a significant (P lt 005) decrease in the concentration of K and P and an increase in the concentration of Ca and Na in the curds at harvest with level of freshly-applied AG Concentration of N Mg Fe Zn Mn B and Cu in the curds were unaffected by level of freshly-applied AG (Table 57) As level of freshly-applied P increased there was a significant (P lt 005) decrease in concentration of N S Mg Fe Zn Mn and B and an increase in concentration of K Ca P and Na in curds at harvest Concentration of Cu in curds were unaffected by level of applied P (Table 57 (b))
Table 57 (a) Concentration of macro-nutrients (dry weight basis) in curds of cauliflowers at harvest with level of freshly-applied Alkaloamreggypsum (AG) and phosphorus (P)
AG
AG N1 K1 Ca S1 P2 Na1 Mg1
(tha) () () () () () () ()
0 392 515 040 066 047 023 018
60 384 500 040 067 045 023 017
120 404 474 043 071 043 024 018
240 402 458 041 071 041 028 018
Lsd3 022 016 001 004 002 002 0006
Sig4 ns + ns ns
P
p N1 K1 Ca1 S1 P2 Na1 Mg1
(kgha) () () () () () () ()
0 496 417 034 097 031 016 019
50 400 518 043 068 040 023 018
100 376 483 042 063 042 025 017
200 372 501 044 063 047 027 017
400 371 498 042 062 052 028 017
600 358 505 041 060 052 027 016
Lsd3 027 02 003 005 002 003 001
Sig4
1 After McQuaker et al (1979) 2 After Varley (1966) 3 Least significant difference at P lt 005 4 Significance at lt 0001 () lt 001 () lt 005 () level or not significant (ns)
The use of Red Mudgypsum in vegetable production
Table 57 (b) Concentration of micro-nutrients1 (dry weight basis) in curds Cauliflowers at harvest with level of freshly-applied Alkaloam gypsum (AG) and phosphorus (P)
AG
AG (tha)
Fe1
(Ugg)
Zn1
(vigg) Mn1
(Pgg) B1
(Pgg) Cu1
(Pgg)
0 611 279 124 188 26
60 587 247 134 191 25
120 706 299 139 192 29
240 592 268 145 186 25
Lsd2 329 57 14 08 06
Sig3 ns ns ns ns ns
p
p (kgha)
Fe1
(Ugg) Zn1
(Pgg) Mn1
(Ugg) B1
(ugg)
Cu1
(Pgg)
0 976 492 156 202 31
50 520 279 145 198 26
100 507 230 135 186 24
200 432 208 127 190 24
400 739 239 131 183 28
600 567 192 120 177 24
Lsd2 270 61 142 114 061
Sig3 a s
1 After McQuaker et al (1979) 2 Least significant difference at P lt 005 3 Significance at lt 0001 () lt 001 () lt 005 () level or not significant (ns)
49
The use of Red Mudgypsum in vegetable production
Concentration of Ba in curds at harvest decreased and concentration of Ti increased significantly in curds at harvest with level of freshly-applied P (Table 58) As level of freshly-applied P increased concentrations of Pb and Rb decreased and of Sr decreased Ba concentrations were variable with level of freshly-applied P (Table 58)
Table 58 Concentration of Ba plus heavy metals1 (fresh weight basis) in curds of cauliflowers at harvest with level of freshly-applied Alkaloamreggypsum (AG) and phosphorus (P)
AG Ba Cd Cr Co Pb Ni Rb Sr Ti Th V (tha) (ngg) (ngg) (ngg) (ngg) (ngg) (ngg) (ngg) (ngg) (ngg) (ngg) (ngg)
0 797 7 34 7 13 34 590 1219 34 39 7
60 482 7 34 7 15 34 610 1146 46 52 8
120 583 7 43 7 20 34 616 1246 45 50 8
240 355 7 34 7 15 34 637 1152 41 45 8
Lsd2 141 1 13 16 11 15 74 188 5 16 1
Sig3 ns ns ns ns ns ns ns ns ns
MRL4 50 2000
P (kgha)
Ba (ngg)
Cd (ngg)
Cr (ngg)
Co (ngg)
Pb (ngg)
Ni
(ngg)
Rb (ngg)
Sr (ngg)
Ti
(ngg)
Th
(ngg)
V (ngg)
0 556 7 34 7 25 34 650 998 39 45 9
50 670 7 34 7 18 34 657 1387 50 74 9
100 576 7 34 7 11 34 570 1206 45 50 8
200 529 7 34 7 12 34 616 1293 39 39 7
400 523 7 48 7 19 39 596 1126 39 36 7
600 476 7 34 7 11 34 603 1126 36 36 7
Lsd2 121 1 16 1 15 6 40 181 19 29 2
Sig3 ns ns ns ns ns ns ns ns
MRL4 50 2000
Inductively coupled plasma mass spectrometry 2 Least significant difference at P lt 005 3 Significance at lt 0001 () lt 001 () lt 005 () level or not significant (ns) 4 Maximum residue limit
The use of Red Mudgypsum in vegetable production
P uptake by plants P uptake by whole plants or plant parts was unaffected by level of freshly-applied AG by but increased significantly with level of freshly-applied P (Table 59)
P uptake by whole plants increased from 50 kg Pha to 19 to 21 kgha at 400 to 600 kg applied Pha respectively Curd root stem and leaf uptake was 33 5 6 and 50 respectively of total plant P uptake at the highest level of applied P (Table 59)
Table 59 P uptake (kgha) by curds roots stem leaf and whole cauliflower plants at harvest with level of freshly-applied Alkaloamreggypsum (AG) and phosphorus (P)
AG
AG Curds Roots Stem Leaf Total (tha) (kgha) (kgha) (kgha) (kgha) (kgha)
0 53 074 11 87 158
60 48 066 10 83 148
120 47 069 11 79 143
240 45 060 10 74 135
Lsd1 065 015 025 21 31
Sig-2 ns ns ns ns ns
p
p (kgha)
Curd (kgha)
Root (kgha)
Stem (kgha)
Leaf (kgha)
Total (kgha)
0 12 030 040 29 49
50 40 058 100 68 124
100 51 053 112 76 143
200 59 075 120 93 172
400 67 093 131 115 205
600 61 094 121 102 185
Ls-d1 055 017 020 18 25
Sig2
1 Least significant difference at P lt 005 2 Significance at lt 0001 () lt 001 () lt 005 () level or not significant (ns)
51
The use of Red Mudgypsum in vegetable production
Yield
There was a significant (P lt 005) increase in both total and marketable curd yield with level of freshly-applied P at all levels of freshly-applied AG (Table 510) There was no significant effect of level of freshly-applied AG on either total (Table 510 (a)) or marketable (Table 510 (b)) curd yield
Table 510 Curd yield (total marketable) of cauliflowers (tha) at harvest with level of freshly-applied Alkaloamreggypsum (AG) and phosphorus (P)
(a) Total
p (kgha)
AG (tha) p
(kgha) 0 60 120 240
0 755 468 483 177
50 1464 1675 1554 1516
100 2169 1706 1757 1985
200 2242 1737 1928 1862
400 1752 2102 2155 2136
600 1689 1764 1768 2023
Lsd1
Sig2
16 (AG)
ns 201 (P)
401 (AGP)
-
(b) Marketable
p (kgha)
AG (tha) p
(kgha) 0 60 120 240
0 274 060 000 000
50 1222 1463 1294 1152
100 2057 1416 1603 1820
200 2141 1377 1803 1752
400 1572 2020 2095 1996
600 1468 1534 1500 1974
Lsd1
Sig2
24 (AG)
ns
46 (P)
52(AGP)
ns
Least significant difference at P lt 005 2 Significance at lt 0001 () lt 001 () lt 005 () level or not significant (ns)
The relationship between total yield and level of freshly-applied P was best described by a quadratic relationship at all levels of freshly-applied AG (Fig 57) As level of AG increased the level of freshly-applied P required for 99 of maximum yield increase from 124 kg Pha at 0 t AGha to 339 kg Pha at 240 tha There was no significant effect of level of freshly-applied AG on maximum curd yield (Fig 57)
The use of Red Mudgypsum in vegetable production
26
24
22
(tha
) 20
18
Cur
d yi
eld 16
14
12
10
8
6 i ii
A=0
i i i i i
I I
0 100200300400500600700
Applied P (kgha)
24 22 20 18 16 14 12 10 8 6 4 2
- 7 I
_ bull
i i i n
mdash^ B=60
I I I
0 100200300400500600700
Applied P (kgha)
co
32 CD
gt 2 3
o
25
20
15
10
5
bull j
- bull
I I I I I
- - gt C=120
l l l
0 100200300400500600700
Applied P (kgha)
0 100200300400500600700
Applied P (kgha)
Fig57 Total curd yield (tha) of cauliflower with level of freshly-applied Alkaloam gypsum and
phosphorus (ABCD = 060120240 tha) Vertical lines represent applied P necessary
for either 95 (dashed) or 99 (whole) of maximum yield
The equations for the fitted lines are
A y = 1336 + (-577 + 01335x)(l-00088x +000007872) (Z2
B y = 89434 + 00705 - OOOOlx2 (R2 = 070)
C y = 84752 + 00810 - OOOOlx2 (B2 = 081)
D y = 733 +00871x - 00001 Ix2 (R2 = 099)
098)
53
The use of Red Mudgypsum in vegetable production
Discussion
The increase in pH Ec PRI and P sorption of Karrakatta sands with level of freshly-applied AG prior to fertiliser application is similar to that reported for the amendment of Joel (McPharlin et al 1994 and Robertson et al 1997a) and Karrakatta sands (Robertson et al 1994 and 1997b) with AG The increase in DH and Ec of the amended soil is explained by the high levels of both in the AG (ie pH (CaCr) = 94 and Ec = 623 mSm Appendix 1) The increased retentionsorption of P is explained by the addition of iron (974) and aluminium (551) in various oxides and hydroxides in the AG (Appendix 1 and Barrow 1982) to the soil After the application of P fertilisers levels of P in the soil at mid-growth and harvest as measured by total and Colwell P increased with a parallel decrease in PRI The increase in the levels of exchangeable Ca and Na in the soil at the same times with level of freshly-applied AG can be attributed to the AG itself However the increase in exchangeable and Colwell K appears to be due to improved K retention capacity of the soil due to physical properties of the AG rather any increased supply of K from the AG Whilst the overall K adsorption properties of the soil as measured by the Freundlich isotherm was not significantly increased with level of AG K sorption at 2401 AGha was significantly higher than at 01 AGha
There was no significant increase in cation exchange capacity (CEC) with level of freshly-applied AG on the Karrakatta sand in this experiment which remained about 2 me By contrast the CEC of virgin Joel sands increased from 1 to 2 me with level of freshly-applied AG (0 to 240 tha) in columns (McPharlin et al 1994) The application of AG would be expected to increase the CEC of coarse sands because (1) AG a fine textured material (10 clay 68 silt) (Ward 1983) would increase the fine fraction when applied to sands (2) AG has a much higher CEC ie 7 to 15 me depending on pH (Barrow 1982) than either Joel or Karrakatta sands ie 1 to 2 me (McPharlin et al 1994 and Table 51) and (3) application of AG to either Joel or Karrakatta sands increases the retentionreduces leaching of cations either not present in the AG such as NH4-N (McPharlin et al 1994) or only present in small quantities such as K (Tables 52 53 54 and Appendix 51)
The concentration of an element in the soil expressed as either extractable or total amounts represents the quantity or extensive factor in terms of plant nutrition as outlined by Holford and Mattingly (1976) The concentration of ions in soil solution or the intensive factor may better represent what is available to the plant A good example of this is the levels of K in the soil expressed as either Colwell or exchangeable K which increase significantly with level of applied AG However levels of K in the plant YML at buttoning and curds at harvest decrease significantly with level of AG K in soil solution 1 month after planting similarly decline significantly with level of applied AG and are therefore better correlated with K nutrition of the plant than measurements based on the dry soil Similarly P concentrations in the plant and soil solution decline whilst P retained by the soil increase in response to freshly-applied AG By contrast concentrations of Na in soil solution soil and plant all increase with levels of freshly-applied AG Similar relationships between concentrations of K Na and P in the soil soil solution and plant on a Karrakatta sand have been reported previously (Robertson et al 1997)
In previous work maximum yield (ie A value) of cauliflowers was reduced when freshly prepared AG was applied at levels gt 120 tha (Robertson et al 1994) This yield reduction was assumed not to be due to induced P deficiency resulting form high level of applied AG as it could not be alleviated by increased levels of applied P Although increased levels of applied P were needed to maximise yield as the level of freshly-applied AG increased Concentrations of K decreased and Na increased in the YML with level of applied AG and the yield reduction was assumed to be due either induced K deficiency or Na toxicity However neither the reduced concentrations of K or the increased concentrations of Na in the plant were at levels that would reduce yield according to published standards (Weir and Cresswell 1993) Antagonism between Na and K uptake by plants is common (Yeo 1983) For example increasing soil salinity resulted in increased concentrations of Na and decreased concentrations of K in the leaves of Zucchini grown in controlled greenhouses in Spain (Villora et al 1997)
The use of Red Mudgypsum in vegetable production
In this work as level of freshly-apphed AG increased level of applied P necessary for maximum yield increased as in the previous work however maximum yield was not reduced by AG up to 240 tha This is despite concentrations of K in the YML decreasing and Na increasing in response to level of freshly-applied AG However as in the previous work neither concentrations of K or Na were at levels expected to cause yield reduction By contrast the reduction in maximum yield of potatoes at high levels of freshly-applied AG (ie gt 120 tha) was correlated with a reduced concentration of K in the petioles (Robertson et al 1997b)
The level of freshly-applied P required for 99 of maximum yield in this work increased from 124 kgha at 01 AGHa to 339 kgha at 2401 AGha These levels of applied P are similar to that reported necessary for maximum yield of cauliflowers on AG-amended (Robertson et al 1994) or unamended (McPharlin et al 1995) Karrakatta sands The P required for 99 of maximum yield in this work 053 to 057 was either slightly higher - 047 (McPharlin et al 1995) or within range - 05 to 07 (Piggott 1986) 03 toO7 (Weir and Cresswell 1993) of that reported as critical or adequate for maximum yield of cauliflowers
Increased levels of freshly-applied AG did not significantly change the concentrations of Cd Co Cr Pb Ni Rb Sr Th or V in the curds of cauliflowers By contrast concentrations of Ba were significantly reduced and Ti increased in the curds with levels of freshly-applied AG Similarly there was no reported change in concentration of Cd Cr Pb or Co with level of freshly-applied AG in curds of cauliflower grown on Karrakatta sands (Robertson et al 1994) in previous work Also there was no change in Ba concentration in curds with level of AG in contrast to the previous work
References
Barrow NJ (1982) Possibility of using caustic residue from bauxite for improving the chemical and physical properties of sandy soils Australian Journal of Soil Research 33 275-285
Holford ICR and Mattingly GEG (1976) Phosphate adsorption and plant availability of phosphate Plant and Soil 44 377-89
McArthur and Bettenay (1960) The development and distribution of the soils of the Swan Coastal Plain Western Australia Soils Publication No 16 CSIRO Division of Soils CSIRO Melbourne Australia
McPharlin IR JefFery RC Toussaint LF and Cooper M (1994) Phosphorus Nitrogen and Radionuclide Retention and Leaching from a Joel Sand amended with Red Mudgypsum Communications in Soil Science and Plant Analysis 25 (17 amp 18) 2925-2944
McPharlin IR Robertson WJ JefFery RC and Weissberg R (1995) Response of cauliflower to phosphate fertiliser placement and soil test phosphorus calibration on a Karrakatta sand Communications in Soil Science and Plant Analysis 26(3amp4) 607-620
McQuaker NR Brown DF and Kluckner PD (1979) Digestion of environmental materials for analysis by inductively coupled plasma-atomic emission spectrometry Analytical Chemistry 51 1082-1084
Piggott TJ (1986) Vegetable crops pp 148-187 In DJ Reuter and JB Robinson (eds) Plant Analysis an Interpretation manual Inkata Press Melbourne Australia
Robertson WJ McPharlin IR and JefFery RC (1994) Final report of investigation into the use of gypsum-amended Red Mud as a soil-amendment on horticultural properties on the Swan Coastal Plain Report to HRDC (Project No V0039RO) Department of Agriculture Western Australia
55
The use of Red Mudgypsum in vegetable production
Robertson WJ Jeffery RC and McPharlin IR (1997a) Residues from bauxite-mining (Red Mud) increase phosphorus retention of a Joel sand without reducing yield of carrots Communications in Soil Science and Plant Analysis 28 (in press)
Robertson WJ McPharlin IR and Jeffery RC (1997b) The growth nutrition and mineral composition of potatoes (Solanum tuberosum L) cv Delaware grown on an yellow Karrakatta sand amended with freshly-applied and residual Alkaloamreggypsum (Submitted to AJEA)
Varley J A (1966) Automatic methods for the determination of nitrogen phosphorus and potassium in plant material Analyst 91 119-126
Villora G Pulgar G Moreno DA and Romero L (1997) Effect of salinity treatments on nutrient concentration in Zucchini plants (Cucurbita pepo L var Moschatd) Australian Journal of Experimental Agriculture 37 605-608
Vlahos S Summers KJ Bell DT and Gilkes RJ (1989) Reducing phosphorus leaching from sandy soils with Red Mud bauxite processing residues Australian Journal of Soil Research 27 651-662
Weir RG and Cresswell GC (1993) Plant Nutrient Disorders 3 Vegetable crops p 93 Inkata Press Melbourne Australia
Yuen SH and Pollard AG (1954) Determination of nitrogen in agricultural material by the Nessler reagent II Micro determination in plant tissue and soil extracts Journal of the Science of Food and Agriculture 5 364-369
The use of Red Mudgypsum in vegetable production
Appendix 51 Chemical and physical characteristics of Alkaloam gypsum used in cauliflower experiment (freshly-applied Alkaloamreggypsum)
Parameter Units Value Kgt
Ec mSm 623 -
pH (H 20) mSm 99 -
pH (CaCl2) mSm 94 -
PRI mLg 610 - gt 1000 -
LOI 1973 -
C a C 0 3 1290 1290
Fe (Fe203) 974 974
Al (A1203) 551 551
Si (Si0 2 ) 797 797
Ca (CaO) 45 450
Na (Na 2 0) 228 228
Ti (Ti0 2 ) 174 174
K (K 2 0) 072 72
Mg (MgO) 028 28 sect 047 47
P (P2O5) 005 05
Mn (MnO) 002 02
Total P ngg 266 -
Extractable P M-gg 58 -
Extractable K M-gg 43 -
As ngg 35 -
Ba ^gg 413 -
Cu Ugg 29 -
Sr Hgg 287 -
Nb Hgg 99 -y Hgg 866 -
Zr fAgg 1477 -
Sand 232 -
Silt 473 -
Clay 295 -
After Allen and Jeffery (1990)
Based on X-ray fluorescence (XRF) spectrometry
After Colwell (1963)
The use of Red Mudgypsum in vegetable production
Appendix 52 Concentration of Ba plus heavy metals1 (dry weight basis) in curds of cauliflowers at harvest with level of freshly-applied Alkaloamreggypsum (AG) and phosphorus (P)
(a)
AG Ba Cd Cr Co Pb Ni Rb Sr Ti Th V (tha) (Pgg) (vigg) (ugg) (ugg) (Pgg) (Pgg) (Pgg) (ugg) (Pgg) (Pgg) (Pgg)
0 119 010 050 010 020 050 88 182 050 058 010
60 72 010 050 010 022 050 91 171 069 078 012
120 87 011 064 011 030 050 92 186 067 075 012
240 53 011 05 010 023 050 95 172 061 067 012
Lsd2 21 002 02 024 016 022 11 28 008 024 002
Sig3 ns ns ns ns ns ns ns ns ns
(b)
p (kgha)
Ba (vgg)
Cd (vigg)
Cr (Pgg)
Co (ngg)
Pb (vgg)
Ni (Pgg)
Rb (Pgg)
Sr (Pgg)
Ti
(Pgg)
Th (Pgg)
V
(Pgg)
0 83 010 050 010 038 050 97 149 058 067 013
50 100 011 050 010 027 050 98 207 075 110 013
100 86 010 050 010 017 050 85 180 067 075 012
200 79 010 050 010 018 050 92 193 058 058 010
400 78 011 071 011 028 058 89 168 058 054 011
600 71 010 050 010 016 050 90 168 054 054 010
Lsd2 18 002 024 0009 022 009 06 27 028 044 003
Sig3 ns ns ns ns ns ns ns ns
Inductively coupled plasma mass spectrometry
Least significant difference at P lt 005
Significance at lt 0001 () lt 001 () lt 005 () level or not significant (ns)
The use of Red Mudgypsum in vegetable production
6 RESPONSE OF CAULIFLOWERS TO RESIDUAL RED MUD (ALKALOAMreg)GYPSUM (AG) AND PHOSPHORUS ON A YELLOW KARRAKATTA SAND
Introduction
It is important to reduce the leaching of phosphorus fertiliser from sandy soils used for vegetable production into the water systems of the Swan Coastal Plain Red Mud (Alkaloam )gypsum (AG) (ie Red Mudgypsum RMG) a waste product from bauxite refining has been suggested as an amendment to reduce phosphorus leaching from sands of the Bassendean Association (Joel Gavin) used for agriculture and horticulture (Barrow 1982)
Experimental work in the field and pots showed amendment with AG significantly reduced P leaching from Joel and Gavin sands (Vlahos et al 1989 McPharlin et al 1994) compared with the unamended (01 RMGha) treatment
Previous work showed a significant reduction in maximum yield of cauliflowers with levels of residual AG of gt 60 tha compared with 01 AGha (Robertson et al 1994) This yield reduction was not due to P deficiency as increased levels of applied P did not obviate the problem Nor was it due to K deficiency as K concentrations in the youngest mature leaves (YML) although reduced by levels of residual AG did not decline to levels expected to reduce yield The converse was true for concentrations of Na in the YML which increased with levels of residual AG but not to concentrations expected to cause toxicity
Since more than 60 tha of AG may be required to significantly improve P retention by sands to enable sustainable horticultural production this yield reduction is re-examined with residual AG
Materials and methods
Site characteristics
The experiment was conducted on a yellow Karrakatta sand (McArthur and Bettenay 1960) at Medina Research Centre (32deg 13 S 115deg 49 E) 30 km south of Perth Both Alkaloamreggypsum (AG) and phosphorus had previously been applied to the site and a potato crop grown in 1995 Prior to that the site had been sown to pasture for several years Some relevant chemical characteristics of the topsoil (0-15 cm) and subsoil (15-30 cm) of the site after application of AG but prior to the application of fertiliser (except residual P) and transplanting are presented in Table 61
Red Mud (Alkaloamreg)gypsum
Alkaloamreg (Red Mud) amended with 10 (ww) gypsum (AG) was produced by the dry mix process by ALCOA of Australia Ltd at their Kwinana Residue Treatment Plant The AG had been spread manually on the site and incorporated using a rotary hoe to approximately 30 cm depth on 22 December 1994 Residual P had been applied just before planting of the previous potato crop on 17 May 1995 and incorporated with a rotary hoe The site was watered for 1 hour per day (8 mmday) using impact sprinklers until planting
Experimental design
The experimental design was a split-plot randomised block with 3 replicates The main plots were levels of AG (0 60 90 120 and 240 tha) and the sub-plots were levels of freshly-applied P (25 50 100 300 and 600 kgha) Main plots measured 7 x 12 m and sub-plots 12 x 7 m (excluding wheel tracks)
59
The use of Red Mudgypsum in vegetable production
Crop management
The site was sprayed with Roundupreg (3 Lha) twice after application of AG and prior to planting to control weeds Six week old seedlings of cauliflowers (cv Plana) obtained from a commercial nursery were transplanted manually on 18 April 1996 in 2 rows per plot with 70 cm between rows and 50 cm between plants Seedlings were dipped in Rovralreg (1 mLL) just prior to planting for control of fungi Treflanreg (14 Lha) and Dacthalreg (12 kgha) were applied immediately after transplanting to control broadleaved weeds and Sertinreg later on in the life of the crop for grass control Ambushreg (100 mLha) and Rogorreg (100 mLha) were used to control caterpillars and red legged earth-mite respectively Copper was applied for control of blackrot The crop was irrigated to a total application equivalent to 100 of the previous days pan evaporation using minisprinklers (Legoreg 6 x 6 m spacing 44 mmh) in 3 waterings of equal duration per day
Fertilisers
Pre-planting fertilisers were broadcast manually and rotary hoed on 17 April 1996
These were K2S04(244) Ca(N03)2(387) MgS047H20 (504) MnS04H20 (504) FeS047H20 (18) Borax (27) CuS045H20 (36) ZnSOH20 (28) and Na2Mo042H20 (2) P was applied as single superphosphate (91 P) at 0 to 600 kg Pha according to treatment and incorporated as before Post-planting K N and Ca were fertigated via the irrigation system as KN03 NHUNO3 and Ca (N03)2 in equal amounts per day for 12 weeks to a total of 600 kg Kha 423 kg Nha and 60 kg Caha Borax was fertigated at 20 kgha in week 3 and Mg was broadcast as MgS047H20 at 50 kgha in weeks 3 6 and 9
Measurements
Soil and soil solution
All zero P subplots were sampled 30 cores per plot just prior to planting and fertilising about 2 months after AG application to 2 depths (0-15 15-30 cm) These were oven dried at 40degC and analysed for Ec pH (CaCl2) P sorption (Ozane and Shaw 1968) bicarbonate extractable P K (Colwell 1963) total P PRI P sorption K sorption (Allen and Jeffery 1990) and cation exchange capacity (Gillman and Sumpter 1986)
The soil water was obtained by centrifugation from soil samples (0-15 cm 30 per plot) and collected from the 0 100 200 and 600 kg Pha plots across all AG treatments on the 16 May 1996 The supernatant was analysed for pH Ec Ca Mg K S and P The remaining soil was analysed for pH (H20) bicarbonate extractable P K PRI and DTPA extractable Zn After harvest 5 August 1997 soil samples were collected from 2 depths as for the preplanting treatment from all plots These were analysed for pH bicarbonate extractable P K total P PRI and exchangeable cations (Ca Mg K and N)
Plant
At buttoning on 13 June 1996 the younger mature leaves (YML) (4th from growing point) were collected from 16 plants (excluding 1 m buffer at each end of plot) in each plot They were dried at 70degC in a force draught oven for 48 h and ground to pass through a 1 mm screen Sub-samples were digested with sulphuric acidhydrogen peroxide (Yuen and Pollard 1954) and the concentration of N P and K measured by an automated colorimetric process (Varley 1966) Concentration of other nutrients (B Ca Na Mg S Fe Mn Zn and Cu) were determined by inductively coupled plasma atomic emission spectroscopy (ICP-AES) after digestion with nitric-perchloric acids (McQuaker et al 1979) Five whole plants were harvested from the middle of each plot (2 per row) at the end of the experiment on 4 July 1996 using shovels to remove as much of the roots as possible The plants were separated into four categories curds leaves stems and roots All soil was dried and digested as for ICP-AES as above and washed from the roots using tap water shaken and the excess water removed using paper towels The fresh weight of all four categories was recorded and the material was diced
60
The use of Red Mudgypsum in vegetable production
into small pieces (lt 8 cm3) using stainless steel knifes sub-samples (300 g fresh weight) were collected at random from the diced pieces and the fresh weight recorded These were dried at 70degC in a forced draught oven for 48 h and the dry weight recorded These samples were then analysed for P as for the youngest mature leaves Separate sub-samples (300 g fresh weight) of curds were collected and analysed for Ba Cd Cr Co Pb Mo Rb Sr Ti Th V and Ni using inductively coupled plasma mass spectrometry (ICP-MS) The fresh and dry weight of the curds leaves stems and roots at harvest were used to calculate P uptake in kgha)
Harvest
Harvest commenced when the leaves surrounding the head opened and exposed the curds 77-80 days after transplanting At this stage florets at the periphery of the curd had just begun to separate Sixteen curds (12 plus 4 from whole plant samples above) were collected from the central 4 m of both rows (1 m buffer) and then all the leaves and stems removed according to requirements for export market Each fresh curd was weighed and rejects recorded if undersize (lt 500 g) oversize (gt 2000 g) discoloured (yellowing) overmature (separation of florets in the centre of curd) diseased damaged or otherwise distorted The total marketable and reject yield were recorded for each plot
Analysis of data
Analysis of variance was carried out on level of applied AG or P versus (a) chemical characteristics of soil (bicarbonate extractable P total P etc) preplanting and harvest (b) concentrations of nutrients in soil solution at midgrowth (c) concentration of nutrients in YMLs at midgrowth (d) concentration of elements in curds at harvest (e) P uptake by plant parts and (f) total marketable and reject yield of curds at harvest Mitscherlich curves and inverse polynomials were fitted to the relationship between level of applied P and yield at each level of applied AG The level of applied P required for 95 99 and 100 (in case of inverse polynomials) of maximum yield was calculated Mitscherlich curves were fitted to the relationship between level of applied P and P in YMLs at midgrowth at all levels of AG The P in YMLs corresponding to the level of applied P required for 95 99 or 100 of maximum yield (as determined from yield versus applied P plots) was then determined
Mitscherlich curves were also fitted to the relationship between level of applied P and P uptake by curds leaves stems and roots and the P uptake corresponding to whole plants (additions of all 4) level of P required for 95-100 of maximum yield determined Phosphorus uptake by plant parts or whole plants on 0 P plots were deducted from P uptake at other rates to account for non-fertiliser sources of P This was used to adjust P uptake when determining P fertiliser recovery efficiency (RE) by plant parts or whole plants ie fertiliser P uptake by plant parts or whole plantsP applied both in kgha (Novoa and Loomis 1981)
The effect of residual AG andP on chemical characteristics of the soil
Increased levels of previously-applied (residual) AG resulted in a significant increase in Ec pH (CaCl2) Colwell P and PRI in the topsoil (0-15 cm) of a Karrakatta sand prior to current the application of fertilisers and planting (Table 61 Fig 61) There was no significant effect of level of residual AG on the levels of Colwell K in the topsoil Increasing levels of previously-applied (residual) P resulted in a significant increase in Colwell P and a decrease in PRI and pH at the same time but had no effect on the levels of Colwell K in the topsoil
61
The use of Red Mudgypsum in vegetable production
Table 61 Chemical characteristics of the topsoil (0-15 cm) of a yellow Karrakatta sand 12 months after application of Alkaloamreggypsum (AG) (residual AG) and phosphorus (P) just prior to fertiliser application and transplanting
AG Ec pH BicP1 BicK1 PRI2
(tha) (mSm) (CaCl2) (H8g) (Hgg) (mLg)
0 36 70 262 199 093
60 62 78 397 308 101
90 70 80 390 378 12
120 73 80 402 391 14
Lsd3 057 018 75 122 018
Sig4 ns
P (kgha)
Ec (mSm)
pH (CaCl2)
BicP1
(M-gg) BicK1
(figg) PRI2
(mLg)
0 59 78 117 323 17
25 58 78 147 338 15
50 58 78 160 322 16
100 58 78 255 327 13
300 62 76 554 309 06
600 66 75 944 296 005
Lsd3 063 01 58 60 02
Sig4 ns ns
1 After Colwell (1963) 2 After Allen and Jeffery (1990) 3 Least significant difference at P lt 005 4 Significance at lt 0001 () lt 001 () lt 005 () level or not significant (ns)
62
The use of Red Mudgypsum in vegetable production
mdash A
8 40 gt -o deggt 35 - en =gt mdash sect 30 _raquo CO
e 25 ltD O d
5 20
1 ^ I I I
T3
C
o
c CO o c o o
0 20 40 60 80 100120140
Residual AG (tha)
u u bull B
80 l
60
40
mdash n bull 20
n i i i i
I
i i i
100 200 300 400 500 600 700
Residual P (kgha)
Figure 61 (A B) Bicarbonate extractable P (bull) and K (bull) (figg dry soil after Colwell 1963) in the top soil (0-15 cm) of a yellow Karrakatta sand prior to fertilising and planting with level of residual Alkaloamreggypsum (t AGha) (A) and P (kgha) (B) Vertical bars refer to Lsd (P lt 005) for differences between levels of AG or P
5 E Q 0 -
20 40 60 80 100120 140
Residual AG (tha)
0 100 200 300 400 500 600 700
Residual P (kgha)
Figure 61 (C D) Phosphorus retention index (PRI) after Allen and Jeffery (1990) in the topsoil (0-15 cm) of a yellow Karrakatta sand prior to fertilising and planting with level of residual Alkaloamreggypsum (t AGha) (C) and P (kgha) (D) Vertical bars refer to Lsd (P lt 005) for differences between levels of AG or P
63
The use of Red Mudgypsum in vegetable production
One month after planting there was a significant increase in concentration of Ca Na and pH and a decrease in K concentration with level of residual AG in the soil solution at 15 cm depth There was no significant effect of level of residual AG on the Ec or concentration of Mg S and soluble reactive P (Psr) in the soil solution (Table 62 (a) Fig 62) There was a significant decrease in Ec pH and concentration of Mg Na and an increase in concentration of Ca S and Psr in soil solution with level of residual P
Table 62 (a) Ec (mSm) pH and concentration of nutrients (ugmL) in soil solution 1 month after planting cauliflowers with level of residual Alkaloamreggypsum (AG) and phosphorus (P)
AG
AG (tha)
Ec (mSm)
pH Ca (ngmL)
Mg (ugmL)
Na (jigmL)
K (UgmL)
S (jigmL)
Psrp1
(pgmL)
0 129 75 91 141 105 81 28 05
60 144 77 108 131 121 64 30 06
120 147 76 123 136 120 50 33 04
Lsd2 33 01 14 09 4 7 1 02
Sig3 ns ns ns ns
P
p (kgha)
Ec (mSm)
pH Ca (UgmL)
Mg (ligmL)
Na (jigmL)
K (UgmL)
S (UgmL)
Psrp1
(VigmL)
0 171 78 107 141 121 68 23 01
100 138 77 104 144 111 58 24 02
300 120 76 103 128 110 63 31 06
600 130 73 117 133 116 71 43 13
Lsd2 20 02 10 11 10 13 7 02
Sig3 ns
Soluble reactive P 2 Least significant difference at P ^ 005 3 Significance at lt 0001 () lt 001 () lt 005 () level or not significant (ns)
64
The use of Red Mudgypsum in vegetable production
3
C
o
o (gt
o in c c o
5 c CD O
o O
3
o
c o
c ltu o c o
o 0 20 40 60 80 100 120 140
Residual AG (tha)
0 100 200 300 400 500 600 700
Residual P (kgha)
Figure 62 (A B) Concentration (figmL) of Ca (bull) Mg (bull) Na (A) K (T) and S (bull) in soil solution (0-15 cm) under cauliflower one month after planting with level P residual Alkaloamreggypsum (AG) (A) and (B) Vertical bars refer to Lsd (P lt 005) for differences in concentration between levels of AG Where bars are not shown Lsd is less than size of symbol
There was a significant increase in Colwell P K and PRI in the topsoil (0-15 cm) and no change in DTPA extractable Zn with level of residual AG one month after planting (Table 62 (b)) As level of residual P increased there was a significant increase in Colwell P and decrease in PRI with no change in Colwell K or DTPA extractable Zn in the topsoil one month after planting
The use of Red Mudgypsum in vegetable production
Table 62 (b) Extractable P K Zn and phosphorus retention index of the TopsoU (0-15 cm) of a yellow Karrakatta sand 1 month after planting of cauliflowers with level of residual Alkaloamreggypsum (AG) and phosphorus (P)
AG
Ag BicP1 BicK1 Zn2 PRI3
(tha) (Pgg) (Pgg) (Pgg) (mLg)
0 27 41 25 05
60 45 43 26 03
120 50 59 23 07
Lsd4 8 6 05 01
Sig5 ns
p
p (kgha)
BicP1
(Pgg) BicK1
(Pgg)
Zn2
(l-igg) PRI3
(mLg)
0 9 46 19 12
100 21 47 22 09
300 42 46 25 03
600 90 52 31 -03
Lsd4 7 5 10 02
Sig5 ns ns
1 After Colwell (1963) 2 Extracted in DTPA 3 After Allen and Jeffery (1990) 4 Least significant difference at P ^ 005 5 Significance at lt 0001 () lt 001 () lt 005 () level or not significant (ns)
After harvest of cauliflowers there was a significant increase in Colwell P and K total P actual and predicted PRI (PRI and PRIp) with residual AG in the topsoil and subsoil of a Karrakatta sand (Table 63 (a) (b)) There was a significant increase in Colwell P and total P and decrease in Colwell K PRI and PRIp with level of residual P in both the topsoil and subsoil after harvest (Fig 63 (A B))
66
The use of Red Mudgypsum in vegetable production
Table 63 Extractable P K total P and phosphorus retention index of the topsoil (0-15 cm) and subsoil (15-30 cm) of a yellow Karrakatta sand after harvest of cauliflowers with level of residual AIkaloamreggypsum (AG) and phosphorus (P)
(a) Topsoil
AG
AG BicP1 BicK1 TotP2 PPJ3 PPJP4
(tha) (ngg) (Hgg) (Pgg) (mLg) (mLg)
0 16 28 68 10 26
60 25 42 86 15 41
90 25 46 91 16 43
120 26 54 96 18 46
Lsd5 3 9 8 005 03
Sig6
P (kgha)
BicP1
(Pgg) BicK1
(vigg) TotP2
(ngg) PPJ3
(mLg) PPJP4
(mLg)
0 7 46 58 19 27
25 8 45 63 19 28
50 9 44 64 20 30
100 15 43 72 17 33
300 37 40 103 09 48
600 63 36 152 03 67
Lsd5 3 6 8 03 05
Sig6
1 After Colwell (1963) 2 After Allen and Jeffery (1990) 3 Phosphorus retention index (Allen and Jeffery 1990) 4 Predicted phosphorus retention index (Allen and Jeffery 1990) 5 Least significant difference at P ^ 005 6 Significance at lt 0001 () lt 001 () lt 005 () level or not significant (ns)
The use of Red Mudgypsum in vegetable production
120
o lgt 100 bull gt
TJ
rn laquon D ) 3
mdash-
on
60
^^ m i _
c 40 ltigt o c o O 20
160 A (I 140
^ ^ ^ ^ 1 o (0 ^ ^ ^ ^ 1 gtraquo 120
^plusmn bull o
^ ^ ^ ^
66
100
^ 3 80
^ mdash ^ tra
tion
60
^ ^ - ^ ^ ^ cen 40
o 20 o 20
I I I I I I I
O
10
0
0 20 40 60 80 100 120 1lt
O
10
Residual AG (tha)
0 100 200 300 400 500 600 700
Residual P (kgha)
Figure 63 (A B) Bicarbonate extractable P (bull) K (bull) and total P (A) in the topsoil (0-15 cm) of a yellow Karrakatta sand after harvest of cauliflowers with level of residual AIkaloamreggypsum (t AGha) (A) and P (kgha) (B) Vertical bars refer to Lsd (P lt 005) for difference between level of AG or P Lsd not shown when less than size of symbol
68
The use of Red Mudgypsum in vegetable production
Table 63 Extractable P K total P and phosphorus retention index of the topsoil (0-15 cm) and subsoil (15-30 cm) of a yellow Karrakatta sand after harvest of cauliflowers with level of residual Alkaloamreggypsum (AG) and phosphorus (P)
(b) Subsoil
AG
AG BicP1 BicK1 TotP2 PRI3 PRJJP4
(tha) (Pgg) (ugg) (ngg) (mLg) (mLg)
0 15 23 69 08 24
60 23 31 82 12 36
90 24 37 91 14 39
120 25 40 90 17 43
Lsd5 4 6 7 01 03
Sig6
P (kgha)
BicP1
(ngg) BicK1
(ugg) TotP2
(ugg) PRI3
(mLg) PRIP4
(mLg)
0 6 36 57 18 25
25 8 36 63 17 26
50 8 34 63 17 26
100 13 31 71 15 29
300 33 29 102 08 43
600 61 30 141 03 64
Lsd5 5 5 8 02 05
Sig6
1 After Colwell (1963) 2 After Allen and Jeffery (1990) 3 Phosphorus retention index (Allen and Jeffery 1990) 4 Predicted phosphorus retention index (Allen and Jeffery 1990) 5 Least significant difference at P ^ 005 6 Significance at lt 0001 () lt 001 () lt 005 () level or not significant (ns)
The use of Red Mudgypsum in vegetable production
100
o CO
gtlaquo
C
o CO
bull-raquo
c o o o
20 40 60 80 100 120 140
Residual AG (tha) 0 100 200 300 400 500 600 700
Residual P (kgha)
Figure 63 (A B) Bicarbonate extractable P (bull) K (bull) and total P (A) in the subsoil (0-15 cm) of a yellow Karrakatta sand after harvest of cauliflowers with level of residual Alkaloamreggypsum (t AGha) (A) and P (kgha) (B) Vertical bars refer to Lsd (P lt 005) for difference between level of AG or P Lsd not shown when less than size of symbol
Ec pH (CaCl2) and exchangeable Ca and Na in the top and subsoil after harvest increased significantly with level of residual AG whilst there was no change in exchangeable Mg (Table 64 (a) (b)) Whilst there was no change in exchangeable K with level of residual AG in the topsoil there was a significant increase in exchangeable K in the subsoil (Table 64 (b))
70
The use of Red Mudgypsum in vegetable production
Table 64 Ec (mSm) pH (CaCl2) and exchangeable cations (me) in topsoil (0-15 cm) and subsoil (15-30 cm) of a yellow Karrakatta sand with level of residual AIkaloamreggypsum (AG) and phosphorus (P) after harvest of cauliflowers
(a) Topsoil (0-15 cm)
AG
AG Ec pH Ca1 Mg1 K1 Na1
(tha) (mSm) (CaCl2) (me) (me) (me) (me)
0 29 65 24 027 006 004
60 47 73 32 025 009 010
90 59 77 36 023 015 015
120 66 78 40 025 012 018
Lsd2 07 07 06 005 006 001
Sig3 as ns
P (kgha)
Ec (mSm)
PH (CaCl2)
Ca1
(me) Mg1
(me) K1
(me) Na1
(me)
0 43 73 30 025 001 011
25 46 73 33 026 010 011
50 46 73 32 025 010 011
100 52 74 32 025 010 011
300 56 74 34 024 009 011
600 58 73 37 025 014 012
Lsd2 05 05 03 002 007 -
Sig3 ns ns ns
Exchangeable in 1 m NILt-Cl 2 Least significant difference at P ^ 005 3 Significance at lt 0001 () lt 001 () lt 005 () level or not significant (ns)
The use of Red Mudgypsum in vegetable production
soil b
A soil
dry
4 _ I dry
I ^5 CD CD
b_ 3 - E c c o o CO at
i
U o CD CD
Xgt j a CO bull| mdash CO CD ogt
m- mdashM- mmdash JZ 0 - +~ -- mdash c CJ o X X LU
i 1 I i i i i LU
0 20 40 60 80 100 120 1^ W
Residual AG (tha)
100 200 300 400 500 600 700
Residual P (kgha)
Figure 64 (A B) Exchangeable Ca (bull) Mg (bull) K (A) and Na ( bull ) (me) in the topsoil (0-15 cm) of a yellow Karrakatta sand with level of residual Alkaloamreggypsum (t AGha) or P (kgha) Vertical bars refers to Lsd (P lt 005) for differences in concentration between levels of AG or P Lsd not shown when less than size of symbol
72
The use of Red Mudgypsum in vegetable production
Table 64 Ec (mSm) pH (CaCl2) and exchangeable cations (me) in topsoil (0-15 cm) and subsoil (15-30 cm) of a yellow Karrakatta sand with level of residual AlkaIoamreggypsum (AG) and phosphorus (P) after harvest of cauliflowers
(b) Subsoil (15-30 cm)
AG
AG Ec pH Ca1 Mg1 K1 Na1
(tha) (mSm) (CaCl2) (me) (me) (me) (me)
0 34 66 24 026 006 005
60 50 75 33 024 008 010
90 64 78 38 023 01 016
120 68 79 41 024 01 019
Lsd2 05 01 07 006 001 003
Sig3 ns
P (kgha)
Ec (mSm)
pH (CaCl2)
Ca1
(me) Mg1
(me) K1
(me) Na1
(me)
0 48 75 30 023 009 011
25 51 74 33 026 009 011
50 50 75 34 025 008 013
100 61 75 35 026 008 013
300 57 75 34 022 007 013
600 58 73 38 024 008 013
Lsd2 08 01 04 003 001 003
Sig3 ns
1 Exchangeable in 1 m NH4-CI 2 Least significant difference at P ^ 005 3 Significance at lt 0001 () lt 001 () lt 005 () level or not significant (ns)
The use of Red Mudgypsum in vegetable production
o 0 oi
4 CO c CO
gt T3 4 _ bull o
0s -5 3 agt CD
fc_ 3 - g
on
o 2 CO 2 CO
u 2
o CD CD 1 X I SI
1 CD 1 CD CD CU
O
n ^ 1 CO n X bull mdashXmdash mdash 1 1 CO U J= n bull - w 1 CO U
o o X X Lil
i i 1 1 i i 1 HI
0 20 40 60 80 100 120 140
Residual AG (tha)
100 200 300 400 500 600 700
Residual P (kgha)
Figure 64 (C D) Exchangeable Ca (bull) Mg (bull) K (A) and Na (T) (me) in the subsoil (0-15 cm) of a yellow Karrakatta sand with level of residual Alkaloamreggypsum (t AGha) or P (kgha) Vertical bars refers to Lsd (P lt 005) for differences in concentration between levels of AG or P Lsd not shown when less than size of symbol
As level of residual P increased there was a significant increase in exchangeable Ca in the tbpsoil and subsoil but no significant effect on exchangeable Mg K and Na in the topsoil and variable effects on exchangeable Mg and K in the subsoil Ec increased significantly with level of residual P in both the top and subsoil whilst pH in either was effected little by level of applied P
The effect of level of residual AG andP on the concentration of nutrients in cauliflower leaves
The level of residual AG had no effect on the concentrations of N Ca S P S Mg Fe Zn Mn B and Cu in the youngest mature leaves of cauliflowers at buttoning but increased levels significantly reduced the concentration of K (Fig 65 (A B)) As level of residual P increased there was a significant increase in the concentration of K P S Cu and Mn in the YMLs whilst concentrations of N decreased and B concentrations were variable with no clear trends
74
The use of Red Mudgypsum in vegetable production
Table 65 Concentration of nutrients (dry weight basis) in youngest mature leaves of cauliflowers at buttoning with level of applied residual Alkaloamreggypsum (AG) and phosphorus (P)
(a) Macronutrients
AG
AG N1 K1 Ca2 S2 P1 Na2 Mg2
(tha) () () () () () () ()
0 49 42 23 077 040 039 027
60 51 40 23 078 042 036 025
90 51 39 23 079 043 036 025
120 49 39 24 078 042 036 025
Lsd3 03 02 08 009 007 010 004
Sig4 ns ns ns ns ns ns
P N1 K1 Ca2 S2 P1 Na2 Mg2
(kgha) () () () () () () ()
0 53 36 22 069 027 033 024
25 51 38 24 071 030 038 026
50 52 40 24 075 034 040 027
100 51 41 24 079 043 041 027
300 48 43 24 087 055 039 026
600 47 42 20 086 060 031 023
Lsd3 02 02 04 003 004 006 003
Sig4 ns ns
1 After Varley (1966) 2 After McQuakerefl (1979) 3 Least significant difference at P lt 005 4 Significance at lt 0001 () lt 001 () lt 005 () level or not significant (ns)
The use of Red Mudgypsum in vegetable production
Table 65 Concentration of nutrients (dry weight basis) in youngest mature leaves of cauliflowers at buttoning with level of applied residual AlkaIoamreggypsum (AG) and phosphorus (P)
(b) Micronutrients
AG
AG (tha)
Fe (ugg)
Zn1
(Pgg) Mn1
(ugg) B1
(ugg) Cu1
(ugg)
0 122 31 19 21 28
60 121 32 22 22 30
90 119 36 25 22 32
120 120 29 23 22 29
Lsd2 21 8 6 1 05
sig3 ns ns ns ns ns
P (kgha)
Fe1
(Pgg)
Zn1
(ugg) Mn1
Gigg)
B1
(Fgg)
Cu1
(Pgg)
0 112 33 19 22 28
25 120 32 22 22 29
50 125 32 21 23 29
100 132 38 24 23 31
300 129 30 25 22 32
600 106 29 23 21 32
Lsd2 19 6 3 1 03
Sig-3 ns ns
After McQuaker et al (1979) 2 Least significant difference at P ^ 005 3 Significance at lt 0001 () lt 001 () lt 005 () level or not significant (ns)
The relationship between residual P ie Colwell P and P in YMLs at buttoning were best described by Mitscherlich relationships at all levels of residual AG (Fig 65)
The concentration of P in YMLs corresponding to levels of Colwell P necessary for 95 of maximum yield were 047 050 054 and 048 and for 99 of maximum yield were 053 055 058 and 054 for 0 60 90 and 1201 residual AGha respectively
76
The use of Red Mudgypsum in vegetable production
Q
en
3
gt-c 0
07
06
05
04
03
02
01 0
065
060
055
050
045
040
035
030
025
020
A
if 20 40 60 80 100
Colwell P (ugg dry soil)
_ 065
Q S 055
060
tz
ro _ i
gt
120
C bull - - - mdash bull
20 40 60 80 100
Colwell P (ugg dry soil)
120
050
045
040
035
030
025
020
065
060
055
050
045
040
035
030
025
020
-B
bull
- bull I
I I
bull
i i i
20 40 60 80 100
Colwell P (ugg dry soil)
120
-bull D
I I i i i
20 40 60 80 100
Colwell P (ugg dry soil)
120
Figure 65 P in youngest mature leaves at buttoning () corresponding to Colwell P necessary for 95 (dashed) or 99 (whole) of maximum yield at 0 (A) 60 (B) 90 (C) and 120 (D) t of residual Alkaloamreggypsumha Dashed and whole horizontal lines refers to P in YML corresponding to Colwell P required for 95 and 99 of maximum yield respectively
The equations for the fitted lines are
A y = 05964 - 0763 x exp (-0068) (B2 = 089)
B y = 05855 - 05144 x exp (-00465x) (R2 = 098)
C y = 006058 - 0549 x exp (-00435x) (B2 = 096)
D y = 06399 - 05208 x exp (-00291) (R2 = 097)
77
The use of Red Mudgypsum in vegetable production
The effect of level of residual AG andP on the yield of cauliflowers
There was no significant effect of levels of residual AG on the total or marketable yield of cauliflowers However yield responded significantly to levels of applied residual P and the interaction between residual P and AG was significant (Tables 66 (a) (b))
The relationship between Colwell P and total yield was best described by Mitscherlich relationships for all levels of residual AG (Fig 66) The Colwell P required for 95 of maximum total yield was 26 40 48 and 40 ugg dry soil and for 99 35 55 71 and 58 ugg dry soil for 0 60 90 and 1201 residual AGha respectively
Table 66 Curd yield (total and marketable) of cauliflowers (tha) at harvest with level of residual Alkaloamreggypsum (AG) and phosphorus (P)
(a) Total
AG p
(kgha) (tha) p
(kgha)
0 60 90 120
0 59 64 69 100
25 134 126 123 83
50 139 133 117 143
100 163 200 164 177
300 203 236 198 204
600 215 237 208 194
Ls-d1 36 (AG) 17 (P) 48(AGP) -
Sig2 ns
(b) Marketable
p (kgha)
AG (tha) p
(kgha)
0 60 90 120
0 14 14 18 56
25 83 74 84 13
50 90 99 67 99
100 138 188 125 160
300 187 232 182 190
600 206 234 191 185
Lsd1
Sig2
48 (AG)
ns 23 (P)
62(AGP)
-
Least significant difference at P lt 005 2 Significance at lt 0001 () lt 001 () lt 005 () level or not significant (ns)
The use of Red Mudgypsum in vegetable production
0 20 40 60 80 100120140160
Colwell P (ugg dry soil)
0 20 40 60 80 100120140160
Colwell P (ugg dry soil)
lt x
UJ gt-Q
o
lt X
Q _ l UJ gt-Q rr D O
24
22
20
18
16 14
12
10
8
6
4
-D
bull
I I
I I
I I
I
^~ bull
i i i i i
20 40 60 80 100120140160
Colwell P (ugg dry soil)
20 40 60 80 100120140160
Colwell P (ugg dry soil)
Figure 66 Colwell P in topsoil (0-15 cm) at planting versus yield of cauliflowers at 0 (A) 60 (B) 90 (C) and 120 (D) tha of residual Alkaloamreggypsum (AG) Dashed and whole vertical lines represent Colwell P required for 95 and 99 of maximum yield respectively
The equations for the fitted lines are
A y = 2088 - 818 x exp (-017x) (i2 = 089)
B y = 23731 - 4578 x exp (-00949) (i2 = 099)
C y = 2051 - 286 x exp (-00697) (R2 = 086)
D y = 2002 - 354 x exp (-0090) (B2 = 086)
79
The use of Red Mudgypsum in vegetable production
Discussion
There was no significant reduction in maximum yield (ie A values) of cauliflower (cv Plana) curds grown on Karrakatta sands amended with residual AG from 0 to 120 tha in this work This is in contrast to previous work (Robertson et al 1994) in which maximum curd yields of cauliflowers were significantly reduced with levels of residual AG at 120 tha compared with 0 and 60 tha In both studies concentrations of K were reduced and concentrations of Na were increased in the YML at buttoning with increasing levels of residual AG The increase in concentration of Na and the decrease in concentration of K in the YML with level of applied AG was related to similar changes in the concentrations of these elements in the soil solution with both freshly-applied (Section 5) and residual AG one month after planting As with freshly-applied AG increasing levels of residual AG resulted in increasing levels of Na in the soil (exchangeable) or soil solution however whilst K concentrations in soil solution decreased the K retained by the soil measured as either Colwell K or exchangeable K increased Increasing levels of residual AG resulted in increased pH in the topsoil as with fresh AG but this did not reduce the concentration of Mn Cu and Zn in the YML or increase the concentration of Mo These changes would be expected with increases in soil pH (Porter 1984) The level of Colwell P required for 95 to 99 of maximum yield increased from 26 and 35 ugg dry soil at 01 AGha to 48 and 71 ugg at 901 of residual AGha The level at 1201 AGha was slightly lower ie 40 and 58 ugg These levels are similar to those reported as necessary for 95 and 99 of maximum yield of Arfak cauliflowers 40 and 55 ugg Colwell P in planted in autumn and spring on unamended Karrakatta sands (McPharlin et al 1995) It therefore does not appear that AG amendment increases the residual P as measured by Colwell P requirement of cauliflower significantly This is in contrast to the significantly higher level of applied P necessary to maximise yield when AG is freshly-applied ie from 120-160 to gt 300 kg of Pha at 0 and 1201 AGha respectively (Robertson et al 1994 and Section 5) However requirements of residual (Colwell) P and freshly-applied P are not always correlated For example the Colwell P necessary for the maximum yield of spring and winter-planted lettuce was similar ie 80 to 120 ugg dry soil whereas the level of freshly-applied P required for maximum yield of winter-planted lettuce was 50 higher than in spring (McPharlin et al 1996 McPharlin and Robertson 1997)
References
Allen DG and Jeffery RC (1990) Methods for analysis of phosphorus in Western Australian soils Chemistry Centre of Western Australia Report of Investigation No 37
Barrow NJ (1982) Possibility of using caustic residue from bauxite for improving the chemical and physical properties of sandy soils Australian Journal of Experimental Agriculture Research 33 275-285
Colwell JD (1963) The estimation of phosphorus fertiliser requirements of wheat in southern New South Wales by soil analysis Australian Journal of Experimental Agriculture Animal Husbandry 3 190-197
Gillman GP and Sumpter EA (1986) Modification to the compulsive exchange method for measuring exchange characteristics of soils Australian Journal of Soil Research 24 616
McArthur WM and Bettenay E (1960) The development and distribution of the soils of the Swan Coastal Plain Western Australia CSIRO Division of Soils Soils Publication No 16
McPharlin IR Jeffery RC and Pitman DH (1996) Phosphorus requirements of winter planted lettuce (Lactuca sativa L) on a Karrakatta sand and the residual value of phosphate as determined by soil test Australian Journal Experimental Agriculture 36 887-903
80
The use of Red Mudgypsum in vegetable production
McPharlin IR Jeffery RC and Weissberg R (1994) Determination of the residual value of phosphate and soil test phosphorus calibration for carrots on a Karrakatta sand Communications in Soil Science Plant Analysis 25 (5-6) 489-500
McPharlin IR and Robertson WJ (1997) Response of spring-planted lettuce (Lactuca sativa L) to freshly-applied and residual phosphorus and to phosphate fertiliser placement on a Karrakatta sand Australian Journal of Experimental Agriculture (in press)
McPharlin IR Robertson WJ Jeffery RC and Weissberg R (1995) Response of cauliflower to phosphate fertiliser placement and soil test phosphorus calibration on a Karrakatta sand Communications in Soil Science and Plant Analysis 26(3-4) 607-620
McQuaker NR Brown DF and Kluckner PD (1979) Digestion of environmental materials for analysis by inductively coupled plasma-atomic emission spectrometry Analytical Chemistry 51 1082-1084
Novoa R and Loomis RS (1981) Nitrogen and plant production Plant and soil 58 177-204
Ozanne PG and Shaw TC (1968) Advantages of recently developed phosphate sorption test over the older extractant methods for soil phosphate (ed JW Holmes) pp 273-280 In Transactions of the 9th International Congress of Soil Science Volume 2 Angus and Robertson Sydney Australia
Porter WM (1984) Soil acidity Agriculture Western Australia Farmnote No 6884
Robertson WJ McPharlin IR and Jeffery RC (14) Final report of investigation into the use of gypsum-amended Red Mud as a soil-amendment on horticultural properties on the Swan Coastal Plain Report to HRDC (Project No V0039RO) Department of Agriculture Western Australia
Varley J A 1966 Automatic methods for the determination of nitrogen phosphorus and potassium in plant material Analyst 91 119-126
Vlahos S Summers KJ Bell DT and Gilkes RJ (1989) Reducing phosphorus leaching from sandy soils with Red Mud bauxite processing residues Australian Journal of Soil Research 27 651-662
Yuen SH and Pollard AG (1954) Determination of nitrogen in agricultural material by the Nessler reagent IL Microdetermination in plant tissue and soil extracts Journal of Science Food Agriculture 5 364-369
The use of Red Mudgypsum in vegetable production
7 RETENTION LEACHING AND RECOVERY OF P AND OTHER NUTRIENTS BY CARROTS GROWN ON A JOEL SAND AMENDED WITH RESIDUAL RED MUD (ALKALOAMreg)GYPSUM (AG) IN LARGE POTS
Introduction
It is difficult to quantify the retention of P by sands amended with Red Mud (Alkaloamreg)gypsum (AG) in the field because of native P in the soil and soluble P in the AG (Robertson et al 1994) It is easy to quantify leaching of P and other nutrients such as N and K from AG amended sands in pots or columns by collecting leachate and measuring concentration (McPharlin et al 1995) However plants were not grown in the columns used by McPharlin et al so there was no measurement of plant uptake of P and other nutrients to complete the nutrient budget Potatoes were grown successfully in Spearwood sands in large pots (70 L) and a complete N budget (N applied N retained by soil N leached and uptake by plant) determined (Hegney et al 1996)
Freshly-applied AG may not be in equilibrium with the soil to which it is applied ie the pH Ec and concentrations of elements such as Ca and Na may change rapidly with time The age of the AG may effect its capacity to retain P on amended soils AG may improve the retention of other nutrients such as ammonium N (McPharlin et al 1995) and K (Sections 5 and 6) by amended sands AG which has been applied to sands in the field for at least 2 to 5 years should be close to equilibrium with the soil as substantial leaching would have occurred AG of this age would give the best estimate of its long term capacity to reduce leaching of P and other nutrients from poor grey sands on the Swan Coastal Plain The purpose of this work was to quantify the leaching and retention of P and other nutrients (N Ca K etc) from Joel sands which had been amended with AG at different levels in the field for 14 years Carrots a major vegetable crop grown on the Swan Coastal Plain were used as the experimental crop and grown in these AG amended sands in large pots
Materials and methods
Pots
Fibreglass pots used for the experiment were 45 cm in diameter and 50 cm deep The area of soil surface was 016 m2 and the volume was 70 L The bottom of the pots tapered to a hole (diameter) to which was attached a polyethylene hose (length and diameter) and tap The pots were painted white to reduce heat The pots were placed on a metal table (with mesh tops) and the hose passed through a hole in the centre of a lid of a plastic (20 L) bucket
Experimental design
The experimental design was a 4 (levels of residual AG ie 0 125 250 and 1000 tha) times 5 (levels of applied P ie 0 50 100 200 and 400 kgha) factorial in a randomised block with 3 replicates The level of applied AG or Pha was calculated using the area of the soil surface The total number of pots was 60
Soil and Red Mud (Alkaloamreg)gypsum (AG)
Virgin Joel sand was obtained from a commercial garden supply site in Jandakot The top 20 cm of the soil was removed and the rest sieved (15 mm) to remove debris About 20 kg of Joel sand was added to each pot (10 cm depth) Another 60 kg (30 cm depth) of sand was added to the 0 AGha pots to which had been mixed lime and preplant fertilisers (see later) so the surface of the soil was about 10 cm below the top edge of the pot AG amended sand was obtained from a field site in Hope Valley Road Kwinana managed by ALCOA where it had been applied (and incorporated using a rotary hoe) to pastures growing on a Joel sand in 1983 at 0 250 500 and 1000 tha This AG amended sand was added to pots corresponding to 250 and 1000 tha in the field after the preplant fertiliser but not lime was added and was incorporated to a similar depth as in the 01 AGha pots The 125 t AGha treatment was
82
The use of Red Mudgypsum in vegetable production
obtained by mixing AG amended sand from the 250 tha field site with an equal weight of Joel sand in a cement mixer
Fertilisers and lime
The following fertilisers (in kgha) were thoroughly mixed (using a cement mixer) with the top 25-30 cm of the soil in each pot before planting Urea (108) K2SO4Q2I) MgS047H20 (100) MnS04H20 (100) Na2B4O710 H20 (50) FeS047H20 (50) CuS045H20 (50) ZnS04H20 (50) and NaMo042H20 (4) To this was added P at 0 50 100 200 and 400 kgha as single superphosphate at each level of residual AG Hydrated lime (Ca (OH)2) was mixed with the preplanting fertilisers on the 0 kg AGha treatment at 36 gpot
N K and Ca were fertigated via the drip irrigation system at 200 200 and 52 mgL using KNO3 NH4NO3 and Ca (N03)2 from immediately after sowing to 140 days after sowing (18 August 1996) MgS047H20 was broadcast at 100 kgha to each pot at weeks 6 and 12
Irrigation
The plants were irrigated using drippers (Netafim 2 Lh pressure compensated with 4 equalisers per pot) at 15 times the average monthly pan evaporation until 160 days after sowing (7 September 1996) Adjustments were made on a daily basis if evaporation was significantly higher or lower than the long term average (Table 71)
Table 71 Irrigation requirements of carrots in pot experiments
Month DAS Lpotday Minutesday
April 1- 27 10 33
May 28- 59 065 21
June 60- 90 044 14
July 91-122 044 14
August 123-154 056 19
September 155-160
Adjusted for 90 efficiency of irrigation system
Rain was excluded from the pots using a movable rain out shelter made of perspex and aluminium This was removed at all other times
Crop management
The soil in each pot was irrigated to field capacity ie so that free drainage occurred Carrot (cv Top Pak) seeds were sown on a 9 x 9 cm spacing and 1 cm deep with 5 seeds per site on 3 April 1996 These were thinned to 14 seedlingspot (88 plantsm2) after emergence (15 April 1996) No application of fungicides or insecticides were necessary
Soil and plant measurements
Soil
Immediately before fertilising and sowing 5 cores (22 diameter x 15 cm deep) were taken from each pot and dried in a force draught oven at 40degC Each sample was analysed for extractable P and K (Colwell 1963) pH (CaCl2 and H20) total P (Allen and Jeffery 1990) PRI (Allen and Jeffery 1990) total N extractable ammonium N (KC1) extractable nitrate N (KC1) organic carbon cation exchange capacity and exchangeable cations
83
The use of Red Mudgypsum in vegetable production
Leachate
Leachate from each pot was collected in 20 L plastic buckets under the pots each week from the 4 April 1996 to 22 July 1996 PMA (phenyl mercuric acetate) was added to the leachate to prevent contamination Total water volume was measured and sub-samples (200 mL) collected and submitted for analysis of P NH4-N NO3-N K Na Ca S Mg Ec and pH analysis of concentration The quantities leached of the above elements in kgha were calculated from concentration and volume of leachate collected and surface area of soil in pot
Harvest
The plants were harvested on 7 September 1997 and the total marketable and reject root yield determined for each plot
Analysis of data
Analysis of variance (Genstattrade for Windows version 32) was carried out on level of AG and P versus yield (total marketable reject) level of chemical factors in soil after harvest concentration of nutrients in youngest mature leaves at midgrowth tops and roots at harvest and leachate on 22 April 1996 5 May 1996 and 22 July 1996 and quantities of elements leached at each sampling time
Mitscherlich or linear relationships were fitted to level of P versus yield (total) at each level of residual AG P required for 95 and 99 of maximum yield was delivered at each level of residual AG P uptake by carrots was determined from the dry weight and P in tops and roots for each treatment Fertiliser P uptake was determined by deducting uptake on 0 kg Pha treatments at each level of applied AG Fertiliser P retained in the top-soil was determined from the concentration of total P and bulk density P leached was fertiliser leached below 15 cm The P in each plant fraction soil and leached was determine at each level of applied P and AG
Results
Effect of level of residual AG on chemical characteristics of Joel sand
Soil pH (CaCl2 H20) Ec Colwell P phosphorus retention index cation exchange capacity exchangeable Ca and Na and silt and clay all increased with level of residual AG in the top soil (0-15 cm) of a Joel sand before fertilising and sowing (Table 72)
The use of Red Mudgypsum in vegetable production
Table 72 Chemical and physical characteristics of Joel sand amended with residual Alkaloam gypsum (AG) in pots before fertilising and sowing of carrots
Level of residual AG
Parameter (tha)
Parameter
0 125 250 1000
pH (H20) 69 77 85 86
pH (CaCl2) 57 71 78 78
Ec (mSm) 4 9 9 11
Ext P (ngg)1 3 9 14 9
PRI2 -02 33 44 77
Total N ()3 - 0039 0044 0060
ExtNH4-N(ngg)4 - 2 2 2
ExtN03-N(ugg)5 - 3 2 5
CEC ()6 30 30 43 35
Exch Ca ()7 133 363 51 70
Exch Mg ()7 036 024 015 021
Exch Na ()7 005 015 015 032
Exch K ()7 007 004 0035 0035
OrgC()8 131 109 092 103
Sand () 977 967 960 910
Silt () 13 15 15 37
Clay () 10 23 25 53
1 Colwell (1963) 2 Phosphorus retention index (Allen and Jeffery 1990) 3 KjeldahlReardon et al 1966 4 Extracted in 1 m KC1 (Reardon et al 1966) 5 Extracted in 1 m KC1 (Best 1976) 6 Gillman and Sumpter (1986) 7 Exchangeable in 1 m NHU-Cl 8 Walkley and Black (1934)
Level of residual AG had no effect on levels of extractable NH4-N NO3-N exchangeable Mg and K or organic carbon After harvest levels of Colwell P K total P PRI Ec pH (CaCk) exchangeable Ca Mg K and Na in the topsoil (0-15 cm) all increase significantly (P lt 005) with level of residual AG (Tables 73 74)
85
The use of Red Mudgypsum in vegetable production
Table 73 Extractable P K NH4 total P (tot P) and phosphorus retention index (PRI) of the topsoil (0-15 cm) of a Joel sand after harvest of carrots with level of residual Alkaloamreggypsum (AG) and phosphorus (P)
AG
AG BicP1 BicK tot P2 PRI3 NIL (tha) (ngg) (Hgg) (ngg) (mLg) (Mfig)
0 33 119 234 -015 137
125 200 117 743 141 27
250 275 197 1258 231 19
1000 204 420 1853 154 30
Lsd5 4 34 129 45 26
Sig6
P
P (kgha)
BicP1
(ngg) BicK1
(Mgfe) totP2
(ugg) PRI3
(mLg) NIL
(ngg)
0 91 215 896 198 58
50 151 223 937 138 54
100 144 226 1005 126 62
200 182 193 1043 128 42
400 323 210 1231 116 52
Lsd5 48 39 144 50 29
Sig6 s | e ns ns
1 Colwell 1963 2 Allen and Jeffery 1990 3 Phosphorus retention index (Allen and Jeffery 1990) 4 Extracted in 1 m KC1 (Best 1976) 5 Least significant difference at P s 005 6 Significance at lt 0001 () lt 001 () lt 005 () level or not significant (ns)
By contrast levels of extractable NH4-N decreased significantly with level of residual AG Colwell P total P Colwell K all increased significantly (P lt 005) with level of applied P whilst PRI was decreased significantly Level of applied P had no significant effect on Ec pH or level of exchangeable Ca Mg K Na Colwell K or extractable NHu-N in the topsoil after harvest (Tables 73 74)
The use of Red Mudgypsum in vegetable production
Table 74 Ec (mSm) pH (CaCl2) and exchangeable cations (me) in topsoil (0-15 cm) of a Joel sand after harvest of carrots with level of residual Alkaloamreggypsum (AG) and phosphorus (P)
AG
AG Ec pH Ca1 Mg1 K1 Na1
(tha) (mSm) (CaCl2) (me) (me) (me) (me)
0 157 44 18 016 026 010
125 147 54 23 014 026 015
250 217 66 40 017 041 027
1000 308 76 135 027 096 094
Lsd2 32 01 07 002 005 005
sig3
p
p (kgha)
Ec (mSm)
pH (CaCl2)
Ca1
(me) Mg1
(me) K1
(me) Na1
(me)
0 202 59 52 019 048 035
50 195 60 53 018 050 036
100 203 60 57 019 048 039
200 202 60 57 018 045 040
400 236 59 51 017 046 034
Lsd2 35 01 08 002 006 005
Sig3 ns ns ns ns ns ns
Exchangeable in 1 m NH4CI 2 Least significant difference at P s 005 3 Significance at lt 0001 () lt 001 () lt 005 () level or not significant (ns)
Effect of level of residual AG and P on concentration of nutrients in leachate and quantities of nutrients leached
There was a significant (P lt 005) reduction in concentration of P in leachate with level of residual AG at three times of sampling (Fig 71) P concentration in leachate increased significantly with level of applied P at 01 AGha but not in presence of AG
P concentration in leachate at 01 AGha decreased with time from 80 mgL on 16 April 1996 at 400 kg Pha to 025 mgL on 22 July 1996 To reduce P concentration in leachate 125 t AGha was as effective as 250 or 1000 tha at all sampling times and levels of applied P Similar trends were shown in quantity of leached P as total or soluble reactive P in kgha (Appendix 71 (b) 72) Level of applied AG significantly (P lt 005) reduced the concentration of NH4-N in leachate from 40 mgL at 01 AGha to 15 mgL at 250 and 1000 tha (Fig 72 (a)) on 16 April 1996 Significant reductions in concentration were recorded on the other two sampling times as NH4-N concentration declined with increased plant uptake Similar trends were shown in the quantity of NH4-N leached with level of AG (Appendix 72 (b)) By contrast level of applied AG had no significant effect on concentration of NO3-N in leachate or quantity leached at any of the three sampling times (Fig 72 (b) and Appendix 73 (b)) There was a significant (P lt 005) reduction in concentration of K in leachate and quantity of K leached with level of residual AG although the reduction was less at the later sampling times (Fig 73 Appendix 73 (a)) Concentration of K in leachate increased
87
The use of Red Mudgypsum in vegetable production
with time at all levels of residual AG except 1000 tha By contrast both the concentration of Na in leachate and quantity of Na increased with level of residual AG to a maximum at the highest level (1000 tha) There was a reduction in Na concentration in leachate with time at level of residual AG lt 1000 tha The concentration of Ca in leachate increased significantly (P lt 005) as did quantity leached with level of residual AG and with time at all levels of AG (Fig 74 Appendix 74 (a)) By contrast concentration of Mg in leachate and quantity leached decreased significantly (P lt 005) with level of residual AG and with time at all levels of AG (Fig 78 and Appendix 78 (a)) There was a significant (P lt 005) increase in S concentration in leachate and quantity leached with level of residual AG at the first sampling time a decrease at the second and a increase up to 250 tha at the third sampling (Fig 79 Appendix 79 (a)) S concentration in leachate and quantity leached varied significantly with level of applied P at all sampling times and decreased with time from 16 April 1996 to 22 July 1996 (Fig 79 and Appendix 79 (a))
The use of Red Mudgypsum in vegetable production
deg E
c o
o O
c ltD
O
c o
I O
1 0 0 2 0 0 3 0 0 4 0 0
A p p l i e d P ( k g h a )
5 0 0
1 0 0 2 0 0
A p p l ie d P
3 0 0
k g h a )
4 0 0 5 0 0
1 0 0 2 0 0 3 0 0
A p p l i e d P ( k g h a
4 0 0 5 0 0
Figure 71 Concentration of P (mgL of total P) in leachate from Joel sands sown to carrots with level of applied P and Alkaloamreggypsum (AG) at 0 (bull) 125 (bull) 250 (A) and 1000 (T) tha on 16 April 1996 (A) 6 May 1996 (B) and 22 July 1996 (C) P was applied preplanting as superphosphate and carrots were sown on 3 April 1996 Vertical bars refer to Lsd (P lt 005) for differences in concentration between level of AG (at each level of P) or P (at each level of AG) or the interaction between AG and P Where bars arent shown Lsd is less than size of symbol
89
The use of Red Mudgypsum in vegetable production
2 0 0 4 0 0 6 0 0 8 0 0 1 0 0 0 1 2 0 0
L e v e l o f r e s i d u a A G ( t ha )
2 0 0 4 0 0 6 0 0 8 0 0 1 0 0 0 1 2 0 0
L e v e l o f r e s i d u a l A G ( t h a )
Figure 72 Concentration (mgL) of NBU-N (A) and NO3-N (B) in leachate from Joel sand sown to carrots amended with residual AlkaIoamreggypsum (AG) in pots on 16 April 1996 (bull) 6 May 1996 (bull) and 22 July 1996 (A) The carrots were sown on 3 April 1996 N was fertigated at a constant concentration of 300 mgL (250 mgL of NO3-N and 50 mgL NH4-N) from sowing to harvest Vertical bars refer to Lsd (P lt 005) for differences in concentration between level of AG at each sampling time Where bars arent shown Lsd is less than size of symbol
The use of Red Mudgypsum in vegetable production
200 400 600 800 1000 1200
Level of AG (tha)
200 400 600 800
Level of AG (tha)
1 0 0 0 1 2 0 0
Figure 73 Concentration (mgL) of K (A) and Na (B) in leachate from Joel sand sown to carrots amended with residual Alkaloamreggypsum (AG) in pots on 16 April 1996 (bull) 6 May 1996 (bull) and 22 July 1996 (A) The carrots were sown on 3 April 1996 K was fertigated at a constant concentration of 200 mgL from sowing to harvest Vertical bars refer to Lsd (P lt 005) for differences in concentration between level of AG at each time Where bars arent shown Lsd is less than size of symbol
91
The use of Red Mudgypsum in vegetable production
Effect of level of residual AG and P on concentration of nutrients in plants The concentration of K P Fe Cu Mn and Mo in the youngest mature leaves (YML) of carrots at midgrowth all increased significantly with level of residual AG (Tables 75 (a) (b)) The concentration of S in YML at midgrowth was significantly reduced as level of residual AG increased whilst concentrations of Ca Na Mg Zn and B were variable
Table 75 Concentration of nutrients ( dry basis) in youngest mature leaves of carrot at midgrowth with level of residual Alkaloamreggypsum (AG) and phosphorus (P)
(a) Macronutrients
AG
AG (tha)
K1 Ca2 S2 P1 Na2 Mg2
0 486 229 061 025 050 039
125 584 186 060 033 047 034
250 585 216 058 033 044 035
1000 531 215 056 031 052 037
Lsd3 03 02 004 0017 005 003
Sig4
p
P (kgha)
K1 Ca2 S2 P1 Na2 Mg2
0 538 198 062 029 037 036
50 523 222 061 028 043 037
100 562 208 056 030 049 035
200 548 216 057 032 058 037
400 563 214 056 035 054 036
Lsd3 033 022 004 002 006 003
Sig4 ns ns ns
1 After Varley (1966) 2 After McQuaker et al (1979) 3 Least significant difference at P s 005 4 Significance at lt 0001 () lt 001 () lt 005 () level or not significant (ns)
The use of Red Mudgypsum in vegetable production
Table 75 Concentration of nutrients ( dry basis) in youngest mature leaves of carrot at midgrowth with level of residual Alkaloam gypsum (AG) and phosphorus (P)
(b) Micronutrients
AG
AG (tha)
Fe Mn1 Zn B Cu Mo
0 111 386 280 345 95 21
125 127 279 367 348 107 25
250 126 173 269 349 108 24
1000 114 60 143 337 110 31
Lsd2 20 47 40 15 05 06
Sig3 ns ns
p
p (kgha) Fe Mn Zn B Cu Mo1
0 135 243 263 356 120 28
50 122 240 268 349 111 30
100 109 191 229 343 106 25
200 116 228 268 334 99 23
400 115 221 294 341 89 20
Lsd2 23 52 45 15 051 07
Sig3 ns ns ns ns
1 After McQuaker et al (1979) 2 Least significant difference at P s 005 3 Significance at lt 0001 () lt 001 () lt 005 () level or not significant (ns)
Concentration of P S and Na in YML increased significantly (P lt 005) with level of applied P whilst concentrations of Cu and Mo decreased (Tables 75 (a) (b)) By contrast concentrations of K Ca Mg Fe Mn Zn and B were not significantly changed by level of applied P
93
The use of Red Mudgypsum in vegetable production
At harvest the concentration of P N K and Fe in whole tops increased significantly (P lt 005) with level of residual AG whilst concentration of S Mn Zn and B decreased (Table 76) The concentrations of Ca Na and Mg were variable with level of residual AG whilst there was no significant effect on the concentration of Cu
Table 76 Concentration of nutrients ( dry basis) in whole carrot tops at harvest with level of residual Alkaloamreggypsum (AG) and phosphorus (P)
(a) Macronutrients
AG
AG (tha)
N1 K1 Ca2 S2 P1 Na2 Mg2
0 300 503 269 071 016 093 039
125 348 649 239 065 024 090 035
250 395 653 251 061 022 082 033
1000 351 566 262 066 024 099 037
Lsd3 010 036 011 002 001 009 002
Sig4
p
p (kgha)
N1 K1 Ca2 S2 P1 Na2 Mg2
0 355 589 240 073 019 074 035
50 343 597 258 068 020 082 036
100 339 587 257 068 021 098 038
200 339 580 259 063 022 108 037
400 332 608 263 057 024 095 036
Lsd3 011 041 012 002 001 010 002
Sig4 ns
1 After Varley (1966) 2 After McQuakere al (1979) 3 Least significant difference at P s 005 4 Significance at lt 0001 () lt 001 () lt 005 () level or not significant (ns)
The use of Red Mudgypsum in vegetable production
Table 76 Concentration of nutrients ( dry basis) in whole carrot tops at harvest with level of residual Alkaloamreggypsum (AG) and phosphorus (P)
(b) Micronutrients
AG
AG (tha)
Fe1 Mn1 Zn1 B1 Cu1
0 299 962 234 402 109
125 316 952 184 404 107
250 331 662 110 380 110
1000 374 673 77 383 115
Lsd2 90 106 20 002 05
Sig3 ns ns
p
p (kgha) Fe1 Mn1 Zn1 B1 Cu1
0 294 969 158 409 125
50 392 837 144 393 117
100 364 747 141 396 114
200 267 712 159 387 105
400 332 bull 796 154 377 89
Lsd2 101 118 23 13 05
Sig3 ns ns
1 After McQuaker et al (1979) 2 Least significant difference at P lt 005 3 Significance at lt 0001 () lt 001 () lt 005 () level or not significant (ns)
As level of applied P increased concentration of P Ca and Na in whole tops increased significantly (P lt 005) whilst concentrations of N S Mn B and Cu decreased There was no significant effect of level of applied P on concentrations of K Fe or Zn in whole tops whilst concentration of Mg was variable
Effect oflevel of residual AG and P on carrot yield
There was a significant (P lt 005) increase in total and marketable yield with level of applied P at all levels of applied AG (Table 77) The overall effect of AG was to reduce both total and marketable yield at the highest level (1000 cf 0 to 2501 AGha) especially at low levels of applied P (ie 0 to 50 kg Pha) At higher levels of applied P yield at 2501 AGha was not significantly (P lt 005) lower than at 125 tha
95
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The use of Red Mudgypsum in vegetable production
However at 10001 AGha total and marketable yield was significantly lower than 0 tha at all levels of applied P The relationship between level of applied P and total yield was described as linear at 0 250 and 10001 AGha and Mitscherlich at 125 AG tha (Fig 76) As yield did not maximise at 0 250 and 1000 t AGha no optimal level of applied P for 95 or 99 of maximum yield could be determined At 125 t AGha the level of applied P necessary for 95 and 99 of maximum yield was 182 and 314 kg Pha respectively
Effect of level of AG and P on efficiency of P recovery by plants and retention in soil
The proportion () of P recovered in the carrot roots and tops decreased with level of applied P increasing from 8 to 12 to 5 to 8 of depending on level of AG (Table 78) There was a reduction in P recovered in roots tops and whole plant as level of AG increased For example P recovered by whole plants at 01 AGha at 400 kg Pha was 8 but this had declined to 5 at 10001 AGha
Table 78 The of applied fertiliser P taken up by carrots grown in pots (tops roots) retained in the topsoil or leached with level of residual Alkaloamreggypsum (AG) and phosphorus (P) on a Joel sand
P in Fraction AG P ( of P applied )
(tha) (kgha) TopsA Roots2 Plant(A+B) Soil2 Leached3
0 50 2 9 11 3 86
0 100 2 8 10 13 77
0 200 2 6 8 2 90
0 400 2 6 8 3 89
125 50 4 8 12 73 15
125 100 2 8 10 18 72
125 200 2 6 8 30 62
125 400 1 4 5 18 77
250 50 3 7 10 0 90
250 100 2 4 6 0 94
250 200 1 4 5 0 95
250 400 1 4 5 12 83
1000 50 2 6 8 75 17
1000 100 2 5 7 67 26
1000 200 2 5 7 45 48
1000 400 1 4 5 41 55
P in fraction expressed as of P applied as fertiliser 2 P retained in topsoil (0-15 cm) 3 P leached below 15 cm
By contrast of applied P retained in topsoil varied with level of AG For example only 3 of P was retained in topsoil at 400 kg Pha and 01 AGha where as this had increased to 41 at 10001 AGha at the same level of applied P Consequently the of P leached decreased as level of AG increased For example at 01 AGha and 400 kg Pha nearly 90 of applied P leached below 15 cm This had been reduced to 55 at 10001 AGha and the same level of applied P
97
The use of Red Mudgypsum in vegetable production
Table 79 Fertiliser P leached (kgha) and P leached as a of P applied from a Joel sand sown to carrots with level of residual Alkaloam gypsum (AG) and P after harvest The P was then applied as superphosphate prior to planting The carrots were sown on 3 April 1996 P leached is expressed as a percentage of P applied
AG (tha)
P (kgha)
P leached1
(kgha) P leached
( P applied)
0 50 41 82
0 100 78 78
0 200 158 79 0 400 311 78
125 50 2 4
125 100 3 3
125 200 10 5 125 400 27 7
250 50 1 2
250 100 3 3 250 200 4 2
250 400 7 2 1000 50 02 lt1 1000 100 05 lt1
1000 200 1 lt1
1000 400 2 lt1
1 Fertiliser P leached = total P leaclied - P leached at 0 kg Pha (ie background P) 2 (Fertiliser P leachedP applied x 100)
The use of Red Mudgypsum in vegetable production
O)
pound CD
o TO
(D
o
(0 l _
c
o c o o
pound
(0
o to
c o
TO tmdash
c 0) o c o o
0 2 0 0 4 0 0 6 0 0 8 0 0 1 0 0 0 1 2 0 0
L e v e l o f r e s i d u a l A G ( t h a )
0 2 0 0 4 0 0 6 0 0 8 0 0 1 0 0 0 1 2 0 0
L e v e l o f r e s i d u a l A G ( t h a )
Figure 74 Concentration (mgL) of Ca (A) and Mg (B) in leachate from Joel sand sown to carrots amended with residual Alkaloamreggypsum (AG) in pots on 16 April 1996 (bull) 6 May 1996 (bull) and 22 July 1996 (A) The carrots were sown on 3 April 1996 Ca was applied preplanting as superphosphate and fertigated at a constant concentration of SO mgL from sowing to harvest AG was applied preplanting and in weeks 6 (15 May 1996) and 12 (25 June 1996) Vertical bars refer to Lsd (P lt 005) for differences in concentration between level of AG at each time Where bars arent shown Lsd is less than size of symbol
99
The use of Red Mudgypsum in vegetable production
CD
CO
x o CO CD
c o
bull4-
CO
c CD O c o O
0 2 0 0 4 0 0 6 0 0 8 0 0 1 0 0 0 1 2 0 0
L e v e l of r e s i d u a l A G ( t ha )
0 100 2 0 0 3 0 0 4 0 0
L e v e l of r e s i d u a l P ( k g h a )
5 0 0
Figure 75 The concentration of S (mgL) in leachate from Joel sands sown to carrots with level of residual Alkaloamreggypsum (AG) (A) and P (B) on 16 April 1996 (bull) 6 May 1996 (bull) 22 July 1996 (A) The carrots were sown on 3 April 1996 S was applied preplanting as K2S04 and in superphosphate Vertical bars refer to Lsd (P lt 005) for differences in concentration between level of AG (A) or P (B) at each sampling time Where bars arent shown Lsd is less than size of symbol
100
The use of Red Mudgypsum in vegetable production
ID
0 100 200 300 400 500
Applied P (kgha)
lb 70
70 C
60 65 -
60
55 dt
ha 50
40
50
45 bull A
Yie
30
40 _ 20
35 i i i i 35 0 100 200 300 400 5( 50 10
Applied p (kgha)
0 100 200 300 400 500
Applied P (kgha)
0 100 200 300 400 500
Applied P (kgha)
Figure 76 Total yield of carrots with level of freshly-applied P at four levels of residual Alkaloamreggypsum (AG) (A B C D = 01252501000 tha) Vertical dashed and whole lines refer to applied P necessary to 95 (dashed) or 99 (whole) of maximum yield respectively
The equations of the fitted lines are
A y = 10943 - 9377 x exp (-00053) (R2 = 099)
B y = 6l7- 2848 x exp (-00122) (i2 = 099)
C y = 3842+ 0083x (J2 = 097)
D y = 238 + 0l07x(R2 = 096)
As level of applied P increased concentration of P Ca and Na in whole tops increased significantly (P lt 005) whilst concentrations of N S Mn B and Cu decreased There was no significant effect of level of applied P on concentrations of K Fe or Zn in whole tops whilst concentration of Mg was variable
101
The use of Red Mudgypsum in vegetable production
Discussion
The addition of residual Alkaloamreggypsum (AG) resulted in a significant reduction in the concentration of P NH4-N K and Mg in the leachate from Joel sands sown to carrots in large pots The reduction in P concentration is attributed to an increase in the level of iron and aluminium oxides when AG is applied to soils low in these minerals (Barrow 1982) Consequently all soil measurements of P status or retention such as total P Colwell P and phosphorus retention index as well as Ec and pH all increased with level of applied residual AG Similar reductions in phosphorus leaching or increases in P retention have been reported when Gavin (Vlahos et al 1989) or Joel (Sections 4 and 5 McPharlin et al 1994 Robertson et al 1997) sands were amended with fresh or residual AG (Sections 4 and 6 Robertson et al 1994)
The reduced leaching of cations such as NH4-N K and Mg is attributed to an increase in captain exchange capacity (CEC) when sands of low CEC are amended with AG (Barrow 1982 McPharlin et al 1994) Consequently NO3-N retention is not increased when soils are amended with residual (Fig 72) or freshly-applied AG (McPharlin et al 1994) The increased leaching of Na Ca and S from amended sands is attributed to the Alkaloamreg as a source of these elements either in the Alkaloamreg itself (Na2C03) or after amendment with gypsum (CaS042H20) which precipitates CaC03 and Na2S04 The Na2S04 is very soluble as is easily leached whereas Ca is only slightly soluble as gypsum and insoluble as lime Vlahos et al (1989) reported increased leaching of Na Ca and S from Gavin sands treated with copper as (FeS04) amended Alkaloamreg compared with unamended controls in the short term and a decrease in the longer term Concentrations of P in the YML at midgrowth or tops at harvest increased with level of applied P and also with level of residual AG from 025 at 0 t AGha to 031 at 10001 AGha By contrast freshly-applied AG reduced the concentration of P in the YML from 043 on unamended to 030 on amended Joel sands (Robertson et al 1997) Even at the highest level of applied P the concentration of P in the YML 035 was still lower than that shown to be necessary for maximum yield of carrots (ie 038 McPharlin et al 1992) This could explain why the yield wasnt maximised in three out of the four AG treatments On the treatment that yield was maximised 125 t AGha the highest concentration of P ie 038 was recorded The difference in trends of P in petioles with AG between the 2 studies could be explained in terms of the relative leaching of P or addition of P in the AG itself On the virgin Joel sand used in the pot study leaching of P was significant enough to reduce leaf P in the unamended versus amended treatments For example the P in YML was significantly lower in the 01 AGha than at all other levels of residual AG at all levels of applied P up to 200 kgha For example the P in YML at 01 AGha ranged from 020 to 027 at 0 and 200 kg Pha respectively whilst at 125 t AGha the P was 032 to 038 over the same levels of applied P (Appendix 71) This suggests that loss of P from the top soil is severely limiting the uptake of P by the plant in the absence of AG The phosphorus retention of virgin Joel sands is almost negligible with a PRI of close to 0 (Table 72 McPharlin et al 1994 Robertson et al 1997) By contrast the P retention of Joel sands appears to be increased following development possibly by the addition of iron in irrigation water and organic and inorganic fertilisers For example the estimate of PRI (PREM) ie PRI plus P as Colwell P measured in the developed Joel sands used by Robertson et al was 40 in the topsoil (0-15 cm) of the unamended treatment Thus in these soils P retention is high enough to reduce availability when AG is added and explains the reduced levels of P in the YML as level of AG is increased The contribution of AG to the P nutrition of the plant is an unlikely explanation as it didnt increase P levels in the plant when applied fresh (Robertson et al 1997)
Previous work showed that concentrations of K in the petioles of potatoes (Section 4 Robertson et al 1997) and youngest mature leaves in cauliflower (Robertson et al 1994 Sections 5 and 6) declined with level of freshly-applied and residual AG
With potatoes the decline in K concentrations was associated with a decrease in K concentration in the soil solution and an increase in Na concentrations in soil solution and petioles on fresh and residual AG treatments (Section 4 Robertson et al 1997) This was
102
The use of Red Mudgypsum in vegetable production
used to explain yield reductions on fresh AG sites at gt 60 tha or on residual sites at 240 tha With cauliflower the findings were variable Where yield was reduced (Robertson et al 1994) it could not be explained in terms of K nutrition as K concentrations in the YML did not decline to levels expected to result in deficiency In follow up work neither fresh or residual AG up to 240 tha resulted in yield reduction although there was a reduction in K concentrations in the YML but not below critical levels (Sections 5 and 6) By contrast concentrations of K in the YML of carrots increased with level of residual AG up to 1000 tha as did exchangeable K in the soil Similar increases in K concentration in YML of Chinese and Head cabbage with level of AG on Joel sands have been reported previously (Robertson et al 1994)
Yield response of carrots to applied P at various levels of residual AG was variable on Joel sands in this work For example yield with level of applied P reach a plateau at 125 t AGha (ie 182 and 314 kg Pha for 95 and 99 of maximum yield from the Mitscherlich regression) However at other levels of applied AG including 0 tha yield had not maximised at the highest level of applied P (400 kgha) This is surprising considering that on higher P retaining soils such as Karrakatta sands yield is maximised at much lower levels of applied P (ie 160 to 180 kgha) at a similar low P soil test (McPharlin et al 1992 1994) in the absence of AG Also on Joel sands yields of carrots at medium to low P soil test (16 to 20 ugg Colwell P) only 50 kg Pha was necessary for maximum yield (McPharlin et al Lantkze and McPharlin unpublished data) The only possible explanation is that leaching of P was significant enough in the absence of AG that increased levels of applied P were required to satisfy crop requirements The increase in P fertiliser requirement as level of applied AG increases as shown in this work above 125 tha is similar to that reported previously for Chinese and Head cabbage cauliflower lettuce onions (Robertson et al 1994) and potatoes (Robertson et al 1997) It is explained by increased P retention capacity of the soil when AG is applied and measured by PRI Colwell and Total P and similar measurements
References
Allen DG and Jeffery RC (1990) Methods for analysis of phosphorus in Western Australian soils Chemistry Centre of Western Australia Report of Investigation No 37
Barrow NJ (1982) Possibility of using caustic residue from bauxite for improving the chemical and physical properties of sandy soils Australian Journal of Agricultural Research 33 275-285
Best EK (1976) An automated method for the determination of nitrate-nitrogen in soil extracts Queensland Journal of Agriculture and Annual Science 33 161-166
Colwell JD (1963) The estimation of phosphorus fertiliser requirements of wheat in southern New South Wales by soil analysis Australian Journal of Experimental Agriculture and Animal Husbandry 3 190-197
Hegney M A McPharlin IR and Jeffery RC (1997) Response of winter-grown potatoes (Solanum tuberosum L) to freshly-applied and residual phosphorus on a Karrakatta sand Australian Journal of Experimental Agriculture 37 131-137
McPharlin IR Alymore PM and Jeffery RC (1992) Response of carrots (Daucus carota L) to applied P and P leaching on a Karrakatta sand under two irrigation regimes Australian Journal of Experimental Agriculture 32 225-232
McPharlin IR Jeffery RC and Weissberg R (1994) Determination of the residual value of phosphate and soil test phosphorus calibration for carrots on a Karrakatta sand Communications in Soil Science and Plant Analysis 25 (5-6) 489-500
103
The use of Red Mudgypsum in vegetable production
McPharlin IR Robertson WJ Jeffery RC and Weissberg R (1995) Response of cauliflower to phosphate fertiliser placement and soil test phosphorus calibration on a Karrakatta sand Communications in Soil Science and Plant Analysis 26(3amp4) 607-620
McQuaker NR Brown DF and Kluckner PD (1979) Digestion of environmental materials for analysis by inductively coupled plasma-atomic emission spectrometry Analytical Chemistry 51 1082-1084
Reardon J Foreman JA and Serai RL (1966) New reactants for the determination of ammonia Clinica Chemica Acta 14 403-405
Robertson WJ McPharlin IR and Jeffery RC (1994) Final report of investigation into the use of gypsum-amended Red Mud as a soil-amendment for horticultural properties on the Swan Coastal Plain Final Report of HRDC Project No V0039 RO
Robertson WJ Jeffery RC and McPharlin IR (1997) Residues from bauxite-mining (Red Mud) increase phosphorus retention of a Joel sand without reducing yield of carrots Communications in Soil Science and Plant Analysis 28 (13 amp 14) 1059-1079
Varley JA (1966) Automatic methods for the determination of nitrogen phosphorus and potassium in plant material Analyst 91 119-126
Vlahos S Summers KJ Bell DT and Gilkes RJ (1989) Reducing phosphorus leaching from sandy soils with Red Mud bauxite processing residues Australian Journal of Soil Research 27 651-662
Walkley A and Black I (1934) An examination of the Degtjareff method of determining soil organic matter and a proposed modification of the chromic acid titration method Soil Science 37 29-38
Yuen SH and Pollard AG (1954) Determination of nitrogen in agricultural material by the Nessler reagent II Micro determination in plant tissue and soil extracts Journal of the Science of Food and Agriculture 5 364-369
104
The use of Red Mudgypsum in vegetable production
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0 200 400 600 800
Level of residual AG(tha)
1000 1200
Appendix 71 (b) P leached (kgha) from Joel sands sown to carrots amended with residual Alkaloanrgypsum (AG) in pots on 16 April 1996 (week 3) (bull) 6 May 1996 (week 6) (bull) and 22 July 1996 (week 16) ( bull ) P was applied preplanting as superphosphate and carrots were sown on 3 April 1996 Vertical bars refer to Lsd (P lt 005) for differences in quantities of P leached between level of AG (across all levels of applied P) at each sampling time Where bars arent shown Lsd is less than size of symbol Data from Appendix 71 (a)
105
The use of Red Mudgypsum in vegetable production
200 400 600 800
Level ofresidual AG(tha)
1 000 1 200
2 00
18 0 -
~ 160
copy
deg 1 40
1 2 0
100 -
80 200 400 600 800
Level of residual AG (tha)
1000 1200
Appendix 73 (b) 74 (b) Ammonium-N (A) and Nitrate-N (B) leached (kgha) from Joel sands sown to carrots amended with residual Alkaloamreggypsum (AG) in pots on 16 April 1996 (week 3) (bull) 6 May 1996 (week 6) (bull) and 22 July 1996 (week 16) (A) N was fertigated postplanting as NH4-N and NO3-N and carrots were sown on 3 April 1996 Vertical bars refer to differences in quantities of N leached between level of AG (across all levels of applied P) at each sampling time Where bars arent shown Lsd is less than size of symbol Data from Appendices 73 (a) 74 (a)
106
The use of Red Mudgypsum in vegetable production
A 1 8 0
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2 0 0 4 0 0 6 0 0 8 0 0
L e v e l o f r e s i d u a l A G ( t h a )
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Appendix 75 76 K (A) and Na (B) in leachate from Joel sand sown to carrots amended with residual Alkaloamreggypsum (AG) in pots on 16 April 1996 (week 3) (bull) 6 May 1996 (week 6) (bull) and 22 July 1996 (week 16) (A) The carrots were sown on 3 April 1996 K was fertigated at a constant concentration of 200 mgL from sowing to harvest and Na was a constituent of AG Vertical bars refer to Lsd (P lt 005) for differences in quantities of K and Na leached between level of AG (across all levels of applied P) at each time Where bars arent shown Lsd is less than size of symbol
107
The use of Red Mudgypsum in vegetable production
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Appendix 77 78 Ca (A) and Mg (B) in leachate from Joel sand sown to carrots amended with residual Alkaloamreggypsum (AG) in pots on 16 April 1996 (bull) 6 May 1996 (bull) and 22 July 1996 (A) The carrots were sown on 3 April 1996 Ca was applied preplanting as superphosphate (and as a constituent of AG) and fertigated at a constant concentration of 50 mgL from sowing to harvest Mg was applied preplanting and in weeks 6 (15 May 1996) and 12 (25 June 1996) Vertical bars refer to Lsd (P lt 005) for differences in quantity of Ca and Mg leached between level of AG (across all levels of applied P) at each sampling time Where bars arent shown Lsd is less than size of symbol Data from Appendices 77 (a) and 78 (a)
108
The use of Red Mudgypsum in vegetable production
200 400 600 800
Level of residual AG(tha)
1000 1200
Appendix 79 S (mgL) in leachate from Joel sands sown to carrots with level of residual Alkaloamreggypsum (AG) 16 April 1996 (week 3) (bull) 6 May 1996 (week 6) (bull) 22 July 1996 (week 16) (A) The carrots were sown on 3 April 1996 S was applied preplanting as K2S04 in superphosphate and as a constituent of AG Vertical bars refer to Lsd (P lt 005) for differences in quantity of S leached between level of AG (A) or P (B) at each sampling time Where bars arent shown Lsd is less than size of symbol Data from Appendix 79 (a)
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i n r ^ c s c s c s ^ t o o o o v o i n e n o o c S i - lt o o o O i - H i i mdash ( v o v o i v o e n O N 0 0 i n c s copy 0 0 N O c s bull ^ r^ vq i-lt_ copy en M cs I-H i n p - H i n cs en -lt bull en oo copy vq vq ON vq p ltn bull vq vq en vq en en NO ON copy cs oo - NO vi vo od vo en in en ^ - i n r t cs cs mdashi en cs cs NO r- r- od ON CS CS m bull H H - lt M M H
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^ e S t ^ O N e n e s e n i n e s c O mdash i e n e n e s O O N O N gt mdash i i n o o copy T t e S - lt N O r ~ - t N O O o v o esi Tt r^ es OCi in r - ON r - ON en imdashi ON bullgt en es copy in mdashi bull NC eni vii oei copy copy en ON rt es oci r -copy oo oo r- t~~ oo ON tmdash en en copy t~- copy co vi vi oo -H t- r-- lt- ON en -H es oo es co r~- vi vi i-i o o r - - r - - r ^ r ~ - l gt e s e s c n e s e s e s v i 3 - v i i n T t - i n N O v i v o v i N O N O e n e s e n e s e s -^
t ^ O N N o r ~ v ) i n N O O N e s i n copy O N T ) - copy 0 0 N O copy e s ^ lt O N e s r ~ 0 0 ^ - gt mdash i N o e s e s e n r -ON es_ en ON NCI 00 ltmdashi mdashH lt-H ON en t~- copy ON copy -i -H OO copy vi en ON VI OCI es| r~_ r~- C- ON en 00 NO vi ON ON CO copy od ON r~ NO OO O vi mdashlt ON r- bull es copy vi es bull es ON bulllaquo vi bulllt NO en bull rt bull ON oooocooooNOO^inenenTj-t-~NONor--r--t~-r~-r--r~r--r--r--^---
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copy copy copy copy copy copy copy copy copy copy copy copy copy copy copy copy copy copy copy copy copy copy copy copy copy copy copy copy copy t - ^ O N ON co copy copy es T^ ^ copy copy r^ NO copy en en ON ON co ^ r~ ON es NO Tf ^ ^ p in co in en es en es oo NO NO en vi bullmdashi od en ON rmdash NO NO en ltmdashi oo ~ oo -H ON v i copy ON mdashlt en copy NO OO copy r- oo NO N O N O ^ O N O O ^ O e s e s e s e s e s e s e s e n f S f S e n e s copy copy - ^ mdash i bull-lt lt-HcopymdashI copy copy raquo-I mdashI
r - ~ N O i n e n o o o o copy copy - H i n copy - i N O O O e s copy gt i - copy copy i n T t N O v i e n o O N O N O O N i mdash i t ^ m T f o o O N N O ^ e s e n r ~ copy i n v i c O N O - H i n e n copy - H ^ H T r O N t ^ i n - ^ N O r - - o o i n o o o O e n r - -oo vi ON -^ vi copy en copy f- en ON OO ON r~- es copy NCi lt-lt lt- r~ vi copy copy vi copy es oo --i es bull vi copy i n N o v i N O v i N O mdash l e s mdash i e s mdash i - H - n e S - H e s e s e S mdash I O N copy copy mdash I copy O copy O N copy copy -H
copy copy copy copy copy copy copy copy copy copy copy copy copy copy copy copy copy copy copy copy copy copy copy copy copy copy copy copy copy f - N O - H co o o r-_ VTi oo en NCif- vi mdashi es oci copy i-i vi o i-i copy en es_ lt-lt in oo r- m r- rj- o es es vi vi es en es vi r- ON ON es f~ es copy 00 i-i es en vi es ON r~ t~- NO ON r-i vi t-~ en es en 00 ON OO o o o o o o o N O N O O N o r - r ^ c o o N O O N o r ^ N o r - o o r ^ e n e n e n e n i n T t - v o N O N o r - o o mdashi
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copy O copy copy copy J 3 copy o copy copy copy 0 3 copy copy copy copy copy laquo copy copy copy copy copy laquo 03 03 ca laquo TOO i bull n copy copy copy ^ i n o copy o laquo gt v i copy copy copy bull ^ copy copy copy a j i J o j a i J i J ^ ^ s N i i
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gtmdash Ln Ln to LO to 00 ~J to ~J imdash H- 00 O imdash as bullgtbull gtmdash o -4 O ^4 gtmdash Ln Ln y i as so -J O bullmdash Ln as bo to Ln as imdashraquo so gtmdashbull o so raquo so to li -a copy o LO o o so Lo to o so H- SO O bo Lo Ln bo 0 U i U M 0 0 M ( J i U M O U i U i O O t O l ( 0 0 ^ U i O - 4 U i v l ^ U M O v l 0 M v )
to
to imdashbull 0 C 0 U l U ^ l A O O 4 i - - ^ 4 ^ 0 S 0 0 0 lt y U i U i U i O U I l gt ^ - M gt 0 0 0 0 U i ^ H- O so O Os Ln O ~J 00 Os Ln -J to so to j-gt Ln gt-gt jj i-gt LO Os so Os LA t o Ln 00 4^ - 4 00 so so so bo in LO ~j Ln so bull imdash oo as so 4 so to in gt-lt -4 to so In copy Ln to raquo-gt as LO so -4 to copy S O S O - P - O O O O O O O O O O O O O O O O O O O O O O O O O O O O O
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U M ^ W ^ ^ M U O l O S ^ V O O S O gt - J f f i v l - 4 M K ) M - J J O O O V O ^ laquo M - J O to as to Lo o Ln as imdash to In so - j gt b b u K U 4 i v o u b b ^ v o ~ i i o i - - as 0 ^ - 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0
+-
gtmdash laquo 0 0 U i gt - Ln gtmdashiimdashbull so so so gt mdash copy 0 0 0 0 - O a s 0 0 O s O s L n L n 0 0 copy 0 0 0 0 lt l O s a s o o ^ H - o o t o H - s o o o s o s o a s a s o o y j s o y j y i ^ ^ o s y i mdash 4 ^ a s o s y i ^ _ u ) i ^ i t o o ~ j oo gt Ln o to as bo o LO 4-ltmdashbull Lo as - j -J o 4 to copy copy as Ln - j to so - j Lo so bullmdash raquobull o ^ ) ( gt J 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0
Ln
bullmdash 0 W W M h - 0 0 0 0 O v l ( J 0 0 O 0 0 L t i f f M j i J i I j J v l M v l 0 S 0 0 O U ^ w raquo M ^ 4 i O H - O O O i - ^ S O ^ y W ^ O O | - W ^ S O O H - v 4 0 s p O h - w to gtmdash Ln so copy copy o to copy to bo Ln oo -J bullmdash to -o to Lo bullmdash bo raquomdash imdash -j o so 4s- so gt Ln o gtmdash W M 5 0 M I H l - 0 U l ( 3 0 ^ i - U gt laquo U i - laquo J v l U l U l M O t J V O U l l - U l W O W t O U l v l
Os
imdash U i U W O laquo O 0 0 O ^ 0 0 0 0 S 0 S U i U i 4 U i ^ U O 0 0 5 0 v l 0 S 0 S ^ v i a s ^ i - gt copy t o L n s copy 4 i L n gt mdash L o t o L o o t o mdash S copy 4 i L n o s a s L O O s 4 i L n O s t O L n L o s o as ugt Ln bs Ln so Lo 4 to Lo bs o so -J bo imdash -o gt as Ln gt oo Ln o -J to to H W N O imdash t O U ) 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0
^3
gtmdashbull W M N t O t O U i W - ^ U i U i U l - e - O v - h ^ - ^ U M U U M M W O O O O O O s a ~j oo ~j 4 - j Ln o imdashbull Ln Ln as -J Os LO as Ngt 4 Ln p oo so LO Ln ygt imdash to - ygt 4 to LO to copy Ln as copy Ln copy 4 so -J copy Lo Ln to -J to to copy Ln Lo bo -J Os -4 O Lo -4 Ln copy O to bo OS tOgtmdash t O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O
00
SO gt_ ^ H M H H 4 i L n t O raquo 4 ^ L O L O N gt s gt L O t O i mdash bull imdash t o i mdash O W O O M O O N O S 0 0 s O 0 0 L 0 4 i J i t O i mdash O L O O S L O l mdash gt O s l - C S - O a s t O L o a s 0 0 t O l mdash O O t O L O O s t O L n - J L O bo 4^ 4^ - j ~j LO Ln Ln to o oo Ln LO - Lo 4= oo Ln Lo os bo as o os so bo o bo o Ln JI o t o t O L O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O
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pmdashgt L o t o t o i mdash t o L n - O L n L n L n L n 4 i L n 4 i - 4 i L O L O N 3 L o t o i o t o t o ^ o o - a ^ i a s C s to Os Ln ^1 -4 Ln so H- 00 H- Ln oo 4 - LO LO OO 4^ bullmdash to oo -J Ln oo LO ^- oo Ln LO VO OO - J as O O Lo to H- bs H- -J Os Lh o O so ^ bullmdash Ln so 00 4^ H- as 00 00 -J LO Os to to -4 so -J Ln ^ t o o o ^ J ^ ^ H - ^ ^ O O O L n a s - J t mdash L O L n O L n O O L O O O L n H - t o O N ^ - J O s - O a s
O
H- I mdash O O O O L O L O t O L O L O t O t O L O l mdash t O t O H - O i mdash 0 0 0 gt mdash O s ^ l O s O s L n L n M f f gt U i U l 4 i a i n t 0 t 0 M ^ U l 4 i S 0 ^ ^ M | - lt raquo y i p 0 W S 0 4 i 4 i O W t O U l 0 s p s so 4i- 00 OS so -J so 00 so Lo ]-i Ln so -J Lo Ln so so O O Ln so O -J bs 4 O 00 4i -J O O ~ J S O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O
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to
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pound
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The use of Red Mudgypsum in vegetable production
13 Recommendations It is recommended that AG be used as a soil amendment for vegetable crops on the grey and pale yellow sands of the SCP to reduce P fertiliser leaching However a number of guidelines should be adhered to ensure maximum benefits and minimum risks from the use of AG
bull Potatoes should not be grown on sites where fresh AG (ie 1 to 3 months after application) has been applied
bull Potatoes can be grown on sites where AG has be applied at levels up to 120 tha provided at least 12 months previously provided sufficient leaching of salts has occurred As a guide it is suggested that soil conductivity should not exceed 6 mSm and pH (water) 85 in the top 15 cm
bull Vegetable crops other than potatoes can be planted into sites where fresh AG has been applied at levels up to 120 tha without problems
bull Adjust level of P fertiliser application to account for increased P fertiliser requirements of vegetables due to higher P fixing on sites amended with AG
bull Use soil testing to manage P fertiliser applications on AG amended sites but follow recommendations for specific vegetable crops
The use of Red Mudgypsum in vegetable production
2 PROJECT STAFF
Ian McPharlin
Wendy Robertson
Bob Jeffery
Tony Shimmin
Jenny Harboard
Don Glenister
Patricia Aylmore
David Cooling
Gavin dAdhemar
Neil Lantzke
John Ferguson (Manager) and staff
Staff
COLLABORATORS AND ACKNOWLEDGMENTS
Project Manager and Principal Investigator
Research Officer
Project Collaborating Scientist (Chemistry Centre of WA)
Project Technical Officer
Project Laboratory Technician (Chemistry Centre of WA)
Residue Development Manager (Alcoa of Australia)
Environmental Scientist (Alcoa of Australia)
Senior Consultant Residue (Alcoa of Australia)
Technical Officer Medina Research Centre (for technical assistance and management of field and pot experiments)
Horticultural Extension Officer (for extension advice)
Medina Research Centre (for management of field experiments)
Chemistry Centre of WA (for advice of on soil plant and leachate chemistry)
4
The use of Red Mudgypsum in vegetable production
3 PUBLICATIONS ARISING OUT OF WORK Robertson WJ McPharlin IR and Jeffery RC (1997) The growth nutrition and
composition of potatoes (Solarium tuberosum L) cv Delaware grown on a yellow Karrakatta sand amended with freshly-applied and residual Alkaloamreggypsum Australian Journal of Experimental Agriculture (submitted)
McPharlin IR dAdhemar G and Shimmin TR (1997) The response of cauliflowers (Brassica oleraceae L) cv Plana to freshly-applied and residual Alkaloamreggypsum and phosphorus on a Karrakatta sand Australian Journal of Experimental Agriculture (in prep)
McPharlin IR Shimmin TR and dAdhemar G (1997) Leaching of P N and cations from carrots grown on Joel sands amended with residual Alkaloamreggypsum Communications in Soil Science and Plant Analysis (in prep)
The use of Red Mudgypsum in vegetable production
4 RESPONSE OF POTATOES TO FRESHLY-APPLIED AND RESIDUAL RED MUD (ALKALOAMreg)GYPSUM AND PHOSPHORUS ON A YELLOW KARRAKATTA SAND
Introduction
Previous work has shown that freshly-applied Alkaloamreggypsum (gypsum-amended red mud 10 ww) (AG) at 60 and 120 tha reduced the total yield of potatoes by 7 and 23 respectively compared with 01 AGha controls (Robertson et al 1994 Appendix 1 J) The reduction in marketable yield was almost identical to the reduction in total yield The exact cause of this reduction in yield could not be determined particularly the reduction at 120 tha It was unlikely to be a reduced availability of P Observations on commercial properties suggest that AG which has been in the soil for several seasons does not cause yield reductions in potatoes
Phosphorus was banded at planting in this experiment Subsequent work (Hegney and McPharlin unpublished data) showed that broadcasting P allowed a greater maximum yield of potatoes than banding P on Karrakatta sands of low P fertility
This experiment re-examines the response of potatoes to freshly-applied AG using broadcast P and also the effect of residual AG on growth of potatoes at unlimiting P
Materials and methods
Site characteristics
The experiment was conducted on a yellow Karrakatta sand (described by McArthur and Bettenay 1960) at Medina approximately 30 km south of Perth Two sites were used a site where pasture species had been grown several years earlier and to which no AG had ever been applied and a second (adjacent) site where AG had been applied approximately 2J2 years earlier A lettuce and a cauliflower crop had been grown previously on this site after AG amendment (Robertson et al 1994 Appendix 1H I)
Red Mud (Alkaloamreg)gypsum (AG)
Red Mud (Alkaloamreg)gypsum (10 ww) (AG) was produced by the dry mix process by ALCOA of Australia Ltd at their Kwinana Residue Treatment Plant It was spread manually on the previously unamended site on 22 December 1994 and was incorporated to a depth of approximately 30 cm using a rotary hoe The AG on the previously-amended site (residual AG) was applied using the same techniques on 24 November 1992 The freshly-applied AG was watered for 1 hour three times a week until planting
Experimental design
The freshly-applied and residual AG sites were used for separate experiments which were conducted simultaneously The experiment on the freshly-applied AG was a split-plot randomised complete block design with three replicates Main plots were levels of AG (0 60 90 and 120 tha) and sub-plots were levels of P application (0 25 50 100 300 and 600 kgha) Main plots measured 48 x 21 m and sub-plots measured 24 x 7 m (three rows of potatoes with 08 m between row centres) There was a 2 m buffer around each main plot The experiment on the residual AG site was a randomised complete block design with 4 levels of AG (0 60 120 and 240 tha) and three replicates The levels of AG were applied in November 1992 and had had several levels of P applied to them in the previous crops The AG plots measured 6 x 12 m but only an area of 34 x 8 m (4 rows of potatoes with 08 m between row centres) was cropped to allow a buffer of 1 to 2 m all around the planted area
6
The use of Red Mudgypsum in vegetable production
Crop management Both sites were initially sprayed with Roundupreg (3 Lha) to kill weeds and the sites were hoed with a rotary hoe Freshly-applied AG was applied at this stage The residual AG site was treated with metham sodium approximately two weeks before planting Potatoes cv Delaware were planted on both sites on 18 May 1995 using a single row mechanical planter Round seed was used and this was dusted with Rizolexreg (2 kgt) immediately before planting Sets were planted 15 cm apart The crops were irrigated using impact sprinklers once daily at 80 of Class A pan evaporation between planting and emergence and then at 100 of evaporation Afalonreg (15 kgha) was applied after planting and Sprayseedreg (2 Lha) was applied at 5 emergence both for weed control Nitofol (700 rnLha) was used for regular insect control Bravoreg (2 Lha) was applied every seven days from the time of 50 ground cover until blight symptoms appeared at which time it was then alternated with Rovralreg (2 Lha) at 7 day intervals Both crops were harvested on 15 November 1995
Fertilisers
Pre-planting fertilisers were broadcast by hand on 15 May 1995 on freshly-applied AG and on 16 May on residual AG These were 83 kg Kha as K2S04 10 kg Mgha as miso47H20 and a complete trace element mix containing (kgha) MnS04H20 (504) MgS047H20 (560) borax (336) FeS047H20 (336) CuS045H20 (336) ZnS04H20 (280) and Na2Mo042H20 (224) Single superphosphate (91 P) was broadcast by hand at 0 to 600 kg Pha on freshly-applied AG according to the treatment and at 600 kg Pha on all plots on residual AG Post-planting fertilisers were a total of 500 kg Nha as NH4NO2 and KN02 and 400 kg Kha as KN02 in equal amounts for 10 weeks via the irrigation system An extra 50 kgha MgS04 was applied in weeks 7 and 9
Measurements
(a) Plant
The petioles of the Youngest Mature Leaf (YML) often plants were collected at the S2 stage (longest tuber 10 mm long) (19 July 1995) on both freshly-applied and residual AG They were dried in a forced draught oven at 70degC and then analysed for P N K Na Ca Mg S B Cu Fe Mn and Zn On freshly-applied AG tubers were harvested from a 5 m length of the middle row of each plot On residual AG a 4 m length of the two middle rows of each plot was harvested Tubers were separated into the following size grades lt 30 g 30-80 g 80-250 g 250-450 g and gt 450 g Tubers between 30 g and 450 g were considered marketable except if they were green or damaged
Of the tubers in the 80-250 g category ten were sampled from each plot for P analysis They were washed in tap water and sliced thinly with a stainless steel knife Fresh and dry weights were measured before the tubers were analysed for total P
(b) Soil
All 0 kg Pha plots on freshly-applied AG were sampled to 15 cm depth (15 cores per plot) on 29 August (approximately 3 months after planting) They were analysed for Bicarbonate-extractable P (Bic-P) (Colwell 1963) total P EC pH (H20) pH (CaCl2) Phosphorus Retention Index (PRI) (Allen and Jeffery 1990) and P buffering capacity (Ozanne and Shaw 1968) Before fertilisers were applied to the residual AG site on 16 May 15 cores (0-15 cm) were sampled from each plot and analysed for Bic-P and PRI Residual AG plots were sampled again on 29 August (0-15 cm 15 cores per plot) and analysed for pH (H20) pH (CaCl2) EC and P buffering capacity All residual AG plots and 0 100 and 600 kg Pha freshly-applied AG plots were sampled to three depths (0-15 15-30 and 30-45 cm) (20 cores per plot) on 5 December (ie after harvest)
7
The use of Red Mudgypsum in vegetable production
Chemical analysis
Plant samples were ground to pass through a 1 mm screen after drying Concentrations of P N K and Na were measured by digesting the samples with sulphuric acid and hydrogen peroxide (Yuen and Pollard 1954) N and P were determined colorimetrically by indophenol blue and molybdo-vanadate methods respectively K and Na were determined by flame photometry All analysis was conducted on a 4-channel Auto-analyser system using modifications of Technicon procedures (Anon 1977) Samples for analysis of Ca Mg S Cu Fe B Mn and Zn concentrations were digested with nitricperchloric acids (McQuaker et al 1979) Concentrations were measured by inductively-coupled plasma atomic emission spectrometry (ICP-AES) Concentrations of heavy metals were determined using inductively-coupled plasma mass spectrometry (ICP-MS) with indium as an internal standard Samples were initially crushed in an agate mortar and digested using nitric and perchloric acids
All soil samples were dried at 40degC in a forced draught oven Lumps of AG and fertiliser in samples were crushed and the samples were thoroughly mixed and sieved to lt 2 mm before analysis The pH (H20) and the EC were determined on a 15 soilwater extract after shaking for 1 hour The pH (CaCl2) was determined on 15 soiksolution extract using 001 M CaCl2 after shaking for 1 hour Values for both are corrected to 25 degC Total P was determined on a Kjeldahl digest of a separate sub-sample of soil ground to less than 015 mm The concentration of phosphate was measured by the method of Murphy and Riley (1962)
Statistical analysis
All data were analysed by an Analysis of Variance (ANOVA) using Genstat v 50 Results from the two experiments were analysed separately Data from the freshly-applied AG site was analysed by a two-way ANOVA on level of Alkaloamreg and level of applied P while data from residual Alkaloamreg were analysed by a one-way ANOVA on level of AG Statistical differences were determined using a Least Significant Difference at 5 level of significance where the F value from the ANOVA was significant Mitscherlich curves were fitted to all relationships between level of applied P and yield petiole or tuber P concentration or total P uptake Maximum values of Mitscherlich equations were compared using a 5 t-test Linear relationships were fitted to the yield response on residual Alkaloam versus level of AG and also to the relationship between yield and petiole P concentration on freshly-applied AG
The amount of fertiliser P retained was calculated by subtracting total P at 0 kg Pha from the measured total P value Concentrations of P in ugg were converted to kilograms per hectare by multiplying by a factor of 225 This is based on the assumption that there are 2250 t soilha in the top 15 cm of soil
Results and discussion
Soil characteristics
The pH (H20) of the top 15 cm of soil at mid-growth when no P fertiliser was applied increased from 72 on unamended soil to 84 and 85 on amended soil (Table 41) EC also increased from 5 mSm on unamended soil to 8 and 9 mSm on amended soil (Table 41) Bic-P was approximately 10 ugg at all AG levels and total P ranged from 55 ugg on unamended soil to 76 ugg at 901 AGha (Table 41) PRI and P buffering capacity (Pbug) both increased between unamended and amended soil but there were no differences between levels of AG on amended soil PRI of amended soil was 26 to 30 and Pbuff was 24 to 30 (Table 41)
The Bic-P and PRI measurements taken two days before planting on residual AG were the same at all levels of AG Bic-P was 16 to 21 ugg and PRI was 37 to 53 (Table 42) On the other hand Pbuff measured mid-growth increased from 20 at 01 AGha to 30 and 40 at 120 and 2401 AGha The EC was 7-9 mSm on all treatments and pH (H20) increased between 0 and 120 t AGha from 73 to 84 (Table 42)
The use of Red Mudgypsum in vegetable production
Table 41 Characteristics of the top 15 cm of a Karrakatta sand amended with several levels of freshly-applied Alkaloamreggypsum (AG) when no fertiliser P was applied
AG (tha)
pH (H20)
pH (CaCl2)
EC (mSm)
Bic-P (ugg)
Total P (ugg)
PRI Pbuff
0 72 64 5 8 55 19 14
60 84 77 8 10 64 26 24
90 85 78 9 11 76 30 30
120 85 83 9 10 71 27 27
Signif NS NS $
Lsd 5 04 05 3 07 05
Table 42 Characteristics of the top 15 cm of a Karrakatta sand amended with several levels of residual Alkaloamreggypsum (AG) when 600 kg Pha was applied as superphosphate
AG (tha)
pH (H20)
pH (CaCl2)
EC (mSm)
Bic-Pa
(ugg) PRIa
Pbuff
0 73 67 7 16 37 20
60 78 71 5 17 40 23
120 84 77 9 20 44 30
240 88 80 9 21 53 40
Signif NS NS NS
Lsd 5 05 06 10
K Sampled and measured before application of fertiliser P
Total phosphorus in soil
Total P in the soil at harvest on freshly-applied AG increased significantly with level of AG averaged over all three depths sampled (P lt 005) It also increased with level of applied P on all levels of AG At 0-15 cm total P increased significantly between 0 and 601 AGha At 15-30 cm it increased significantly between 0 and 90 t AGha and at 30-45 cm there was no effect of level of AG at all (Fig 41) At all levels of AG and P which were sampled total P concentrations at 0-15 cm and 15-30 cm were not significantly different from each other and both were significantly greater than those at 30-45 cm (Fig 41)
In the top 15 cm of soil total P increased from 47 ugg on unamended soil to 62-67 ugg on amended soil when no fertiliser P was applied This increase represents the total P content of the AG itself When 100 kg Pha was applied total soil P (0-15 cm) increased from 63 ugg at 01 AGha to 83 ugg at 601 AGha and 95 and 103 ugg at 90 and 1201 AGha (Fig 41) When the increase due to the AG itself is considered this is an increase in fertiliser P retention of 6 ugg (26 kgha) between 0 and 601 AGha and a further 14 ugg (62 kgha) between 60 and 120 t AGha At 600 kg Pha the increase in fertiliser P retention was 35 ugg (15 kgha) between 0 and 601 AGha and 25 ugg (11 kgha) between 60 and 120 t AGha
Total P on residual AG increased with level of AG The increase was significant between 60 and 1201 AGha only It also decreased at increasing depth As observed on freshly-applied AG total P concentrations at 0-15 cm and 15-30 cm were not significantly different from each other and were both greater than that observed at 30-45 cm (Fig 43) At 0-15 cm total P increased by 20 ugg between 0 and 601 AGha and by a further 213 ugg between 60 and 1201 AGha when 600 kg Pha was applied These values cannot be corrected for the total content of AG itself as there was no 0 kg Pha treatment
9
The use of Red Mudgypsum in vegetable production
The addition of freshly-applied AG to the soil substantially increased the theoretical ability of the soil to sorb applied P as measured by the P buffering capacity in the top 15 cm of soil However it was reduced over time as 1201 AGha was required to increase Pbuff on residual AG compared with 601 AGha on freshly-applied AG Fertiliser P retention in the top 15 cm of soil when amended with 1201 AGha was increased by 9 at 100 kg Pha and by 4 at 600 kg Pha
The effects of residual and freshly-applied AG can be compared at 600 kgha of applied P The effect of residual AG on fertiliser P retention can be estimated from measurements made on the same site at the beginning of the first (lettuce) crop In that experiment total P before the application of P fertilisers increased from 69 and 62 ugg on 0 and 601 AGha to 91 ugg on 1201 AGha and 103 ugg on 2401 AGha (Robertson et al 1994 Appendix 1H) This makes the estimated increase in fertiliser P retention (0-15 cm) 27 ugg (12 kgha) between 0 and 601 AGha and 184 ugg (81 kgha) between 60 and 1201 AGha Therefore between 60 and 1201 AGha residual AG increased fertiliser retention by approximately 7 times as much as did freshly-applied AG
Bicarbonate-extractable P (soil-test P) in soil
On freshly-applied AG there was no overall response of Bic-P to level of AG although there was an upward trend Bic-P decreased with increasing depth averaged over all treatments following the same response as total P There was an interaction between the effects of depth and level of applied P At 0 kg Pha there was no difference in Bic-P between the three depths sampled but at 100 and 600 kg Pha Bic-P concentrations at 0-15 cm and 15-30 cm were both greater than those at 30-45 cm (Fig 42) The upward trend in Bic-P with increasing level of AG was weak on soil where no P fertiliser had been applied being from 9-10 ugg at 0 and 601 AGha to 11 and 14 ugg at 90 and 1201 AGha in the top 15 cm This suggests that the AG adds little if any plant available P to the soil The amount of fertiliser P retained as Bic-P in the top 15 cm of soil when 100 kg Pha was applied increased by 8 ugg between 0 and 601 AGha and by a further 4 ugg between 60 and 120 t AGha At 600 kg Pha Bic-P retained from fertiliser increased by 34 ugg between 0 and 601 AGha and by 16 ugg between 60 and 1201 AGha
The response of Bic-P to level of residual AG and to depth was the same as for total P (Fig 43) In the top 15 cm of soil Bic-P increased by 11 ugg between 0 and 601 AGha and by 82 ugg between 60 and 1201 AGha uncorrected for the Bic-P content of the AG itself
The increase in Bic-P retention observed on amended soil at 100 kg Pha was similar to that observed at 160 kg Pha on a crop of carrots grown on a Joel sand amended with AG (Robertson et al 1997) Using the soil-test standards published by Hegney et al (1997) these increases in Bic-P will reduce the P fertiliser requirement in the following potato crop by 10 at 601 AGha and 22 at 1201 AGha
Using the Bic-P concentrations observed on the residual site at the beginning of the lettuce crop (Robertson et al 1994 Appendix 1H) the increase in fertiliser P retained as Bic-P (0-15 cm) on residual AG was 15 ugg between 0 and 601 AGha and 79 ugg between 60 and 1201 AGha This is half the increase observed on freshly-applied AG between 0 and 60 t AGha and approximately 5 times that observed on freshly-applied AG between 60 and 1201 AGha
The reduced P retention at low levels of residual AG compared with freshly-applied AG was probably because of the higher initial Bic-P levels on residual AG For both total and Bic-P it is difficult to explain why the apparent retention of fertiliser P between 60 and 120 t AGha should have been so much greater on residual than on freshly-applied AG It may have been caused by changes to the chemical properties of the AG as it aged in the ground
10
The use of Red Mudgypsum in vegetable production
Yield
Total and marketable yields on freshly-applied AG both increased with level of applied P following a Mitscherlich response (Fig 44 (a) (b)) An ANOVA did not indicate any response to level of AG in either total or marketable yields However maximum total yield on unamended soil (61 tha) was significantly greater than that on AG-amended soil - 54 to 57 tha (Fig 44 (a)) On the other hand there were no differences in maximum marketable yields Maximum marketable yield values ranged from 52 to 55 tha (Fig 44 (b)) When marketable yield was calculated as a percentage of total yield an ANOVA indicated a significant interaction between level of AG and level of applied P At 400 kg Pha marketable yield was 88 of total yield on unamended soil compared with approximately 95 on amended soil (significant according to 5 Lsd) A similar trend was observed at 600 kg Pha where marketable yield was 90 of total yield on unamended soil and 93 to 96 on amended soil
The levels of applied P required for 99 of maximum total yield were 245 222 183 and 400 kg Pha on 0 60 90 and 1201 AGha and for 95 of maximum yield were 139 130 108 and 226 kg Pha (Fig 44 (a)) A similar trend can be seen for marketable yield where 99 of maximum yield required 178 206 208 and 356 kg Pha (Fig 44 (b))
Total yield on residual AG showed an almost significant response to level of AG (P = 0067) (Fig 45) Total yield was 68 to 72 tha on 0 60 and 120 t AGha and 62 tha on 2401 AGha Marketable yield was 65 to 68 tha on 0 to 1201 AGha and 58 tha on 2401 AGha Therefore 2401 AGha appears to reduce yields even when it has been in the ground for 2 years or more and even when 600 kg Pha is applied As only one level of P fertiliser was applied it is not possible to determine the effect of residual AG on the critical levels of P application required for 99 and 95 of maximum yield
Concentration of nutrients in petioles
Phosphorus
Phosphorus concentration in petioles of the YML sampled at the S2 stage on freshly-applied AG increased with level of applied P following a Mitscherlich response (Fig 46) Maximum petiole P concentrations were approximately 12 (dry basis) on all AG levels Values at 99 of maximum petiole P concentration were 116 122 117 and 116 at 0 60 90 and 1201 AGha There was a significant interaction between levels of AG and applied P (P lt 005) At low levels of applied P (25 50 and 100 kgha) P concentrations on amended soil were significantly less than those on unamended soil but there was no difference between them at 300 or 600 kg Pha This is reflected in the levels of applied P required for 99 of maximum petiole P concentration which were 209 499 581 and 508 kg Pha at 0 60 90 and 1201 AGha This is an increase of 138 on amended soil relative to unamended soil AG at levels of between 60 and 120 tha therefore reduces the availability of P to plants As there was no difference in the maximum P concentration in petioles between amended and unamended soil a reduction in P availability to plants cannot explain the reduced maximum yield on amended soil Another factor was therefore involved in reducing maximum yield on amended soil Despite this yield difference between amended and unamended soil which was not related to differences in P concentration total yield for all AG levels combined was linearly correlated with petiole P concentration at the S2 stage (y = 256 + 274x R2 = 087) (Fig 47)
The petiole P concentration at 99 of maximum total yield was 116 109 095 and 114o at 0 60 90 and 1201 AGha At 01 AGha this was the same as 99 of maximum petiole P concentration implying that the yield response on unamended soil was controlled principally by P availability On the other hand petiole P concentrations at 99 of maximum yield on amended soil especially 60 and 901 AGha were less than 99 of maximum petiole P concentration In other words yield stopped increasing even though P concentration in the plant kept increasing This supports the previous observation that some factor other than P was limiting yield in these treatments Petiole P concentration in YMLs sampled at S2 stage on residual AG did not change with level of AG Overall mean P concentration was 12 dry
11
The use of Red Mudgypsum in vegetable production
basis This is in keeping with the results observed on freshly-applied AG at 600 kg Pha It also means that the lower yield at 2401 AGha on residual AG could not be explained by a reduced P concentration in the plant As on freshly-applied AG another factor was involved which reduced yield on amended soil although at a higher level on residual than on freshly-applied AG
Hegney et al (1997) found that maximum petiole P concentration at S2 in potatoes grown on Karrakatta sand was 114 dry basis and that 109 was required for 99 of maximum yield in good agreement with the results observed here
Other nutrients
The responses of nutrients other than P were very similar on both freshly-applied and residual AG Concentrations of K (Tables 43 45) and Zn (Fig 48 (a) Table 45) decreased as level of AG increased and concentrations of Mg Fe and Ca increased with level of AG in both experiments (Tables 43 45 Fig 48 (b)) Zn concentrations also decreased with increasing level of applied P (Fig 49 (a)) while Ca concentrations increased with level of applied P (Fig 48 (b)) Concentrations of Na also showed an upward trend on both freshly-applied and residual AG (Tables 43 45) On freshly-applied AG K concentrations decreased significantly from 119 dry basis on unamended soil to 110 at 601 AGha and to 102 at 1201 AGha (Table 43) On residual AG it decreased from 11-12 at 0-1201 AGha to 103 at 2401 AGha (Table 45) No other nutrients showed any response to level of AG although concentrations of N Mn S and B increased with level of applied P on freshly-applied AG (Table 44)
Concentrations of all nutrients except K were adequate or more than adequate for maximum yield (Maier et al 1987) on both freshly-applied and residual AG Potatoes require concentrations of approximately 12 to 14 K (dry basis) in petioles of YML for maximum yield (Maier et al 1987) On freshly-apphed AG concentrations were adequate at 01 AGha but were less than adequate on amended soil On residual AG concentrations were adequate at 0 60 and 1201 AGha but less than adequate at 2401 AGha As less than adequate K concentrations correspond with those treatments which had low yield it is likely that K concentration was the limiting factor in yield on both freshly-applied and residual AG
Uptake of K may have been reduced at higher levels of AG due to an increased Cation Exchange Capacity (Barrow 1982 McPharlin et al 1994) or to the increased soil pH (Harris 1992) The reduction in Zn availability on amended soil is most likely to be a result of the increase in soil pH due to the AG (Harter 1983)
Table 43 Concentrations of several nutrients in the petioles of the Youngest Mature Leaf of potato plants sampled at the 10 mm tuber stage at several levels of freshly-applied Alkaloamreggypsum (AG) on a yellow Karrakatta sand
AG K Na Mg Fe (tha) () () () (ngg)
0 119 018 059 382
60 110 020 065 553
90 106 021 066 597
120 102 021 069 697
Signif NS
Lsd 5 04 004 119
12
The use of Red Mudgypsum in vegetable production
Table 44 Concentrations of several nutrients in the petioles of the Youngest Mature Leaf of potato plants sampled at the 10 mm tuber stage at two levels of applied P when grown on a yellow Karrakatta sand amended with freshly-applied Alkaloamreggypsum (AG)
Applied P N S Cu Mn B (kgha) () () (ngg) (ngg) (M-gg)
0 44 028 74 293 267
600 48 032 62 342 248
Signif NS NS
Table 45 Concentrations of several nutrients in the petioles of the Youngest Mature Leaf of potato plants sampled at the 10 mm tuber stage at several levels of residual Alkaloamreggypsum (AG) on a yellow Karrakatta sand
AG N K Na Ca S Mg Cu Fe Mn Zn B (tha) () () () () () () (l-igg) (ngg) (ngg) Ws) (^gg)
0 51 116 016 23 030 050 77 453 46 96 26
60 48 127 015 21 027 045 61 457 45 67 25
120 49 120 016 26 029 051 66 643 59 59 25
240 49 103 019 29 030 067 54 977 53 53 24
Signif NS NS NS NS NS NS
Lsd5 05 04 013 164 24
Tuber P and Crop P removal P concentration in tubers
The concentration of P in tubers on freshly-applied Alkaloamreg increased with level of applied P (P lt 0001) The response at each level of Alkaloamreg was best described by a Mitscherlich curve although none of the curves reached a maximum within the range of fertiliser P levels used (Fig 49 (a)) There was a trend for an overall response to level of AG (P = 0081) P concentrations were generally higher on unamended soil than on amended soil For example at 300 kg Pha P concentration was 033 on unamended soil and 026-028 on amended soil and at 600 kg Pha P concentrations were 036 and 032-033 on unamended and amended soil respectively At P levels corresponding to 99 of maximum yield tuber P concentration was 031 024 023 and 028 at 0 60 90 and 1201 AGha
On residual AG tuber P concentration did not change with level of AG The overall mean was 036 dry basis
Total P uptake
Total P uptake by tubers on freshly-applied AG showed a significant response to level of AG (P lt 005) and level of applied P (P lt 0001) The response to applied P at each level of AG was best described by a Mitscherlich curve although as for tuber P concentration none of the curves reached a maximum within the range of P levels applied P uptake by tubers on unamended soil was significantly greater than on amended soil regardless of AG level (Lsd 5) (Fig 49 (b)) At levels of applied P corresponding to 99 of maximum yield P uptake by tubers was 113 75 75 and 95 kgha at 0 60 90 and 1201 AGha These figures are lower than results reported by Hegney et al (1997) who found a P uptake by tubers grown on yellow Karrakatta sand of 204 kgha at 99 of maximum yield even though yields were similar to those observed on unamended soil in this experiment
13
The use of Red Mudgypsum in vegetable production
Total P uptake by tubers was not significantly different between AG levels on residual AG Overall mean P uptake was 110 kgha This is different from the situation observed at 600 kg Pha on freshly-applied AG As only one level of P was applied the response curve for tuber P concentration on residual AG cannot be compared with that on freshly-applied AG It is possible that less applied P is required on residual than on freshly-applied AG to reach maximum tuber P concentration
Metals in tubers
The concentration of As in tubers harvested from freshly-applied AG showed a trend to increase with level of AG from 5 x 104 mgkg (fresh weight) on unamended soil to 8 x 104 mgkg at 60 and 901 AGha (Fig 410) Concentrations of all other metals measured showed no response to level of AG either on residual or freshly-applied AG (Table 46 47) On freshly-applied AG concentrations of Ni and Cd increased and concentrations of Cu decreased with increasing level of applied P (Table 48)
Table 46 Mean concentrations (mgkg fresh weight) of metals in tubers of potato cv Delaware harvested from a yellow Karrakatta sand amended with freshly-applied Alkaloam^gypsum (AG)
Cr Co Sn Sb Hg
mean
se
0007
61 xlO5
60 x 104
50 x 106
15 x 103
10 x 104
90 x 105
10 xlO5
34 x 104
14 x 105
Table 47 Mean concentrations (mgkg fresh weight) of metals in tubers of potato cv Delaware harvested from a yellow Karrakatta sand amended with residual Alkaloamreggypsum (AG)
Cr Co Ni Cu As Cd Sn Sb Hg Pb
mean
se
001
68X104
72xl(f 29xia5
55xia3
17x1a4
010
35xia3
L2X103
0
58xia3
17X104
LOxlO3
29X104
30X1O4
43xl05
84X1G4
ii xia5
l ixia3
70xia5
Table 48 Mean concentrations (mgkg fresh weight) of metals in tubers of potato cv Delaware harvested from a yellow Karrakatta sand amended with freshly-applied Alkaloamreggypsum (AG) at various levels of applied P
Applied P (kgha)
Ni Cd Cu
0 0006 0002 018
100 0006 0002 016
300 0007 0004 015
600 0008 0006 013
Signif
Lsd (5) 00014 0001 002
The concentrations of As observed in tubers from freshly-applied AG regardless of the level of AG were less than 10 of the legal limit (10 mgkg fresh weight NFA 1992) The concentrations of all metals measured were between 3 and 33 of those measured in potato tubers in a previous experiment (Robertson et al 1994 Appendix 1 J) The concentrations on residual AG were also lower than the concentrations previously observed in lettuce and cauliflowers on the same site (Robertson et al 1994 Appendix IH I) As different batches of
14
The use of Red Mudgypsum in vegetable production
AG were used on the two sites they cannot be compared to determine the effect of time on metal availability and uptake Overall metal uptake by potato tubers grown on AG-amended yellow Karrakatta sand does not appear to pose any greater health risk than that on unamended yellow Karrakatta sand The observed increase in As concentration in potato tubers on freshly-applied AG was probably due to the increase in soil pH with level of AG (ONeill 1990)
Conclusions
Freshly-applied AG reduces the availability of fertiliser P so that approximately 25 times the level of applied P is required on 60 to 1201 AGha relative to unamended soil in order to attain maximum P concentration in plant tissues AG at 120 tha also increases the retention of fertiliser P sufficiently to reduce fertiliser requirements for a following potato crop by approximately 20 The effect of AG on the level of fertiliser P required for 99 of maximum yield was confounded in this experiment by the decrease in maximum yield between unamended and amended soil Total yield of potatoes will be reduced on 60 tha freshly-applied AG and by 240 tha residual AG probably by a limiting concentration of K There is potential for increased levels of K fertiliser to overcome this yield reduction AG increases the proportion of yield which is marketable so that even though total yield is reduced by 60 tha of freshly-applied AG the marketable yield is not There are no apparent problems with heavy metal contents of tubers due to amendment with AG
References Allen DG and Jeffery RC (1990) Methods for analysis of phosphorus in Western
Australian soils Chemistry Centre of WA Report of Investigation No 37
Anonymous (1977) Technicon Industrial Method 334-74WB+ Technicon Industrial Systems Tarrytown NY USA
Barrow NJ (1982) Possibility of using caustic residue from bauxite for improving the chemical and physical properties of sandy soils Australian Journal of Agricultural Research 275-285
Colwell JD (1963) The estimation of phosphorus fertiliser requirements of wheat in southern New South Wales by soil analysis Australian Journal of Experimental Agriculture and Animal Husbandry 3 190-197
Glenister DJ and Thoraber MR (1985) Alkalinity of red mud and its application for the management of acid wastes Chemeca 85 109-113
Harris PM (1992) Mineral Nutrition In The Potato Crop The scientific basis for improvement 2nd edition (ed P Harris) pp 162-213 (Chapman and Hall London UK)
Harter RD (1983) Effect of soil pH on adsorption of lead copper zinc and nickel Soil Science Society of America Journal 47 47-51
Hegney MA McPharlin IR and Jeffery RC (1997) Response of winter-grown potatoes (Solanum tuberosum L) to applied and residual phosphorus on a Karrakatta sand Australian Journal of Experimental Agriculture 37 (in press)
Maier NA Williams CMJ Potocky-Pacay K Moss D and Lomman GJ (1987) Interpretation standards for assessing the nutrient status of irrigated potato crops in South Australia Technote AGDEX 262533 September 1987 Department of Agriculture South Australia
15
The use of Red Mudgypsum in vegetable production
McArthur WM and Bettenay E (1960) The development and distribution of the soils of the Swan Coastal Plain Western Australia CSIRO Division of Soils Soils Publication No 16
McPharlin IR Jeffery RC Toussaint LF and Cooper M (1994) Phosphorus nitrogen and radionuclide retention and leaching from a Joel sand amended with red mudgypsum Communications in Soil Science and Plant Analysis 25 489-500
McQuaker NR Brown DF and Kluckner PD (1979) Digestion of environmental materials for analysis by inductively coupled plasma atomic emission spectrometry Analytica Chimica 51 1082-1084
Murphy J and Riley JP (1962) A modified single solution method for the determination of phosphate in natural waters Analytica Chimica Acta 27 31-36
NFA (National Food Authority) (1992) Australian Food Standards Code June 1992 (Australian Government Publishing Service Canberra)
ONeill P (1990) Arsenic In Heavy Metals in Soils(ed BJ Alloway) pp 83-99 (Blackie Glasgow)
Ozanne PG and Shaw TC (1967) Phosphate sorption by soils as a measure of the phosphate requirement for pasture growth Australian Journal of Agricultural Research 18 601-612
Robertson WJ McPharlin IR and Jeffery RC (1994) Final Report of investigation into the use of gypsum-amended red mud as a soil-amendment on horticultural properties on the Swan Coastal Plain Agriculture WA
Robertson WJ McPharlin IR and Jeffery RC (1997) Residues from bauxite-mining (red mud) increase phosphorus retention of a Joel sand without reducing yield of carrots Communications in Soil Science and Plant Analysis (in press)
Yuen SH and Pollard AG (1954) Determination of nitrogen in agricultural materials by the Nessler reagent II Micro-determination in plant tissue and in soil extracts Journal of Food in Agriculture 5 364-369
16
The use of Red Mudgypsum in vegetable production
300
250 -
I I
200
3
60 80
AG (tha)
140
Figure 41 Total phosphorus concentration in a yellow Karrakatta sand amended with freshly-applied Alkaloamreggypsum (AG) vs level of AG when 0 (bull) 100 (A) and 600 (bull) kg Pha was applied measured at 0-15 cm () 15-30 cm (mdash) and 30-45 cm (mdash) depth Bars are Lsds at 5 level of significance
17
The use of Red Mudgypsum in vegetable production
Z3
200
180 -
160
Q- 140
ro 120 bull 4 -
O CD X 100 CD i
3 80 CO c o
pound gt v_ CO
o CQ
AG Depth
I
0 20 40 60 80 100 120
AG (tha)
140
Figure 42 Bicarbonate-extractable phosphorus concentration in a yellow Karrakatta sand amended with freshly-applied Alkaloamreggypsum (AG) vs level of AG when 0 (bull) 100 (A) and 600 (bull) kg Pha was applied measured at 0-15 cm () 15-30 cm (mdash) and 30-45 cm (mdash) depth Bars are Lsds at 5 level of significance
18
The use of Red Mudgypsum in vegetable production
700
600
500
D)
3 400
CL
oil
300 CO
200
100
100 150
A G (tha)
250
Figure 43 Total (mdash) and Bicarbonate-extractable phosphorus () concentration in a yellow Karrakatta sand amended with residual Alkaloamreggypsum (AG) when 600 kg Pha was applied measured at 0-15 cm () 15-30 cm (A) and 30-45 cm (bull) depth Bars are Lsds at 5 level of significance
19
The use of Red Mudgypsum in vegetable production
CO
2 CD
gt-
200 300 400
Applied P (kgha)
Figure 44 (a) Total yield of potatoes cv Delaware grown on a yellow Karrakatta sand amended with freshly-applied AIkaIoamreggypsum (AG) at a level of 0 (bull) 60 (A) 90 (bull) and 120 (bull) tha vs level of applied P Lines represent the level of applied P required for 99 of maximum yield Bars are Lsds at 5 level of significance
Equations are
A
B
C
D
0 tha
60 tha
90 tha
120 tha
j - 614 - 255 x exp (-00152) (JR= 092)
y = 542 - 271 x exp (-00176) (R2= 090)
y = 552 - 274 x exp (-0021) (F= 094)
y = 566 - 229 x exp (-00092) (i^= 098)
20
The use of Red Mudgypsum in vegetable production
ro
JO
gt-
100 200 300 400
Applied P (kgha)
500 600
Figure 44 (b) Total yield of potatoes cv Delaware grown on a yellow Karrakatta sand amended with freshly-applied Alkaloamreggypsum (AG) at a level of 0 (bull) 60 (A) 90 (bull) and 120 (bull) tha vs level of applied P Lines represent the level of applied P required for 99 of maximum yield Bars are Lsds at 5 level of significance
Equations are
Otha A
B
C
D
60 tha
90 tha
120 tha
y = 547 - 216 x exp (-0021) (R2^ 088)
y = 517 - 278 x exp (-0019) (R2= 090)
y = 524 - 243 x exp (-001 to) (R2= 094)
y = 530 - 218 x exp (-001 Ox) (i^= 098)
21
The use of Red Mudgypsum in vegetable production
CO
32
gt-
80
70
60
50
40
30
20
10
0 0
Marketable yield
Marketable yield
Total yield
Total yield
_L 50 100 150 200
AG (tha)
250 300
Figure 45 Total (bull) and Marketable (bull) yield of potatoes cv Delaware grown on a yellow Karrakatta sand amended with residual AIkaloamreggypsum (AG) vs level of AG 600 kg Pha was applied Bars are Lsds at 5 level of significance
22
The use of Red Mudgypsum in vegetable production
w CO CO
a gtraquo i _
C
o 00
c CD O c o o
100 200 300 400
Applied P (kgha)
500
Figure 46 Concentration (dry basis) of phosphorus in petioles of the Youngest Mature Leaf of potatoes cv Delaware grown on a yellow Karrakatta sand amended with freshly-applied Alkaloamreggypsum (AG) at 0 (bull) 60 (A) 90 (bull) and 120 (bull) tha vs level of applied P Lines represent the level of applied P required for 99 of maximum yield Bars are Lsds at 5 level of significance
Equations are
A Otha y = 117- 079 x exp (-0020) (R2 = 096)
B 60 tha y=123- 096 x exp (-000874) (R2 - 099)
C 90 tha y = 118 - 0884 x exp (-000742) (R2 = 096)
D 120 tha y= 117 - 090 x exp (-00085) (R2 = 097)
23
The use of Red Mudgypsum in vegetable production
CO
c
53
CD
gt-
00 02 04 06 08 10
Petiole P ( dry basis)
12 14
Figure 47 Yield of potatoes cv Delaware grown on a yellow Karrakatta sand amended with freshly-applied AlkaIoamreggypsum (AG) at 0 (bull) 60 (A) 90 (bull) and 120 (bull) tha vs petiole P concentration
The equation is y = 256 + 274x (ft2 = 087)
24
The use of Red Mudgypsum in vegetable production
poundgt 3
0 100 200 300 400 500 600 700
Applied P (kgha)
Figure 48 (a) Concentration of Zinc and (B) Calcium ( dry weight) in petioles of the youngest mature leaf of potatoes cv Delaware harvested from a yellow Karrakatta sand amended with freshly-applied Alkaloamreggypsum (AG) at 0 (bull) 60 (A) 90 (bull) and 120 (bull) tha vs level of applied P Bars are Lsds at 5 level of significance
25
The use of Red Mudgypsum in vegetable production
100 200 300 400 500
Applied P (kgha)
700
Figure 48 (b) Concentration of Calcium ( dry weight) in petioles of the youngest mature leaf of potatoes cv Delaware harvested from a yellow Karrakatta sand amended with freshly-applied AlkaIoamreggypsum (AG) at 0 (bull) 60 (A) 90 (bull) and 120 (bull) tha vs level of applied P Bars are Lsds at 5 level of significance
The use of Red Mudgypsum in vegetable production
040
ogt 035 CD
gtgt bullo
w _CB O
H) CL
CO 1 _ -mdashraquo c CD O c o o Q
030 -
025 -
020
2 015
010 -
005
000 0 100 200 300 400
Applied P (kgha)
500 600
Figure 49 (a) The concentration of phosphorus in tubers ( dry weight) of potatoes cv Delaware harvested from a yellow Karrakatta sand amended with freshly-applied Alkaloamreggypsum (AG) at 0 (bull) 60 (A) 90 (bull) and 120 (bull) tha vs level of applied Pkgha Bars are Lsds at 5 level of significance
Equations are
A 0 tha
B 60 tha
C 90 tha
D 120 tha
y = 0372 - 0243 x exp (-00058) (R2 = 097)
y = 0378 - 0257 x exp (-00029x) (R2 = 098)
y = 0361 - 0216 x exp (-00029x) (i^= 095)
y = 0406 - 0279 x exp (-0002x) (R2 = 098)
27
The use of Red Mudgypsum in vegetable production
CO
3
ltD
CO Q Z5
ID
B
14
12 -^ ^
10
8 W
6
4
A G P
I
2
n I i i I I i
0 100 200 300 400
Applied P (kgha)
500 600
Figure 49 (b) Phosphorus uptake Gigha) by tubers of potatoes cv Delaware harvested from a yellow Karrakatta sand amended with freshly-applied Alkaloamreggypsum (AG) at 0 (bull) 60 (A) 90 (bull) and 120 (bull) tha vs level of applied P Bars are Lsds at 5 level of significance
Equations are
Otha A
B
C
D
60 tha
90 tha
120 tha
y = 140 - 1095 x exp (-00058r) (R2 = 096)
3= 111 - 882 x exp (-0004x) (R2 = 098)
y = 104 - 774 x exp (-00053) (R2 = 099)
3 = 127 -101 x exp (-00029x) (R2 = 0997)
28
The use of Red Mudgypsum in vegetable production
60 80
AG (tha)
Figure 410 Concentration of Arsenic (dry weight) in tubers of potatoes cv Delaware grown on a yellow Karrakatta sand amended with freshly-applied Alkaloamreggypsum (AG) Bar is Lsd at 5 level of significance
29
The use of Red Mudgypsum in vegetable production
5 RESPONSE OF CAULIFLOWERS TO FRESHLY-APPLIED RED MUD (ALKALOAMreg)GYPSUM AND PHOSPHORUS ON A YELLOW KARRAKATTA SAND
Introduction
It is important to reduce the leaching of phosphorus fertiliser from sandy soils used for vegetable production into the water systems of the Swan Coastal Plain Red Mud (AlkaloamR)gypsum (AG) a waste product from bauxite refining has been suggested as an amendment to reduce phosphorus leaching from sands of the Bassendean Association (Joel Gavin) used for agriculture and horticulture (Barrow 1982)
Experimental work in the field and pots showed amendment with AG significantly reduced P leaching from Joel and Gavin sands (Vlahos et al 1989 McPharlin ei al 1994) compared with the unamended (01 AGha) treatment
In previous work freshly-applied AG at 60 tha increased the amount of freshly-applied P required for maximum yield of cauliflowers 14 (autumn planted) but did not reduce maximum yield (20 tha) compared with the unamended (0 tha) treatment on a yellow Karrakatta sand (Robertson et al 1994) At the highest rate of applied AG (120 tha) P required for maximum yield was 32 higher than at 0 tha and maximum yield was reduced 23 (P lt 005)
Since more than 60 tha of AG may be required to significantly improve P retention by sands to enable sustainable horticultural production this yield reduction is re-examined with freshly-applied AG
Materials and methods
Site characteristics
The experiment was conducted on a yellow Karrakatta sand (McArthur and Bettenay 1960) of low P fertility at Medina Research Centre (32deg 13 S 115deg 49 E) 30 km South of Perth The site had no previous history of AG application and had been sown to pasture for several years Some relevant chemical characteristics of the topsoil (0-15 cm) and subsoil (15-30 cm) of the site after application of AG but prior to the application of fertiliser and transplanting are presented in Table 51
Red Mud (AlkaIoamreg)gypsum (AG)
Alkaloamreg (Red Mud) amended with 10 (ww) gypsum (AG) was produced by the dry mix process by ALCOA of Australia Ltd at their Kwinana Residue Treatment Plant The AG was spread manually on the site and incorporated using a rotary hoe to approximately 30 cm depth on 21 February 1996 The site was watered for 1 hour per day (8 mmday) using impact sprinklers until planting
Experimental design
The experimental design was a split-plot randomised block with 3 replicates The main plots were levels of AG (0 60 120 and 240 tha) and the sub-plots were levels of freshly-applied P (0 50 100 200 400 and 600 kgha) Main plots measured 6 x 12 m and sub-plots 12 x 6 m (excluding wheel tracks)
Crop management
The site was sprayed with Roundupreg (3 Lha) twice after application of AG and prior to planting to control weeds
The use of Red Mudgypsum in vegetable production
Six week old seedlings of cauliflowers (cv Plana) obtained from a commercial nursery were transplanted manually on 18 April 1996 in 2 rows per plot with 70 cm between rows and 50 cm between plants Seedlings were dipped in Rovralreg 1 mLL just prior to planting for control of fungi Treflanreg (14 Lha) and Dacthalreg (12 kgha) were applied immediately after transplanting to control broadleaved weeds and Sertinreg later on in the life of the crop for grass control Ambushreg (100 mLha) and Rogorreg (100 mLha) were used to control caterpillars and red legged earth-mite respectively Copper sprays were used for control of blackrot The crop was irrigated to a total application equivalent to 100 of the previous days pan evaporation using minisprinklers (Legoreg 6 x 6 m spacing 44 mmh) in 3 waterings of equal duration per day
Fertilisers
Pre-planting fertilisers were broadcast manually and rotary hoed on 17 April 1996
These were K2S04(244) Ca (N03)2 4H20 (387) MgS047H20 (504) MnS04H20 (504) FeS047H20 (18) Borax (27) CuS045H20 (36) ZnSOH20 (28) and Na2Mo042H20 (2) Single superphosphate (91 P)was applied at 0 to 600 kgha according to treatment and incorporated as before Post-planting K N and Ca were fertigated via the irrigation system as KN03 NH4NO3 and Ca (N03)2 in equal amounts per day for 12 weeks to a total of 600 kg K 423 kg N and 60 kg Caha Borax was fertigated at 20 kgha in week 3 and Mg was broadcast as MgS047H20 at 50 kgha in weeks 3 6 and 9
Measurements
Soil and soil solution
All zero P subplots were sampled 30 cores per plot just prior to planting and fertilising about 2 months after AG application to 2 depths (0-15 15-30 cm) These were oven dried at 40degC and analysed for Ec pH (CaCl2) P sorption (Ozanne and Shaw 1968) bicarbonate extractable P K (Colwell 1963) total P PRI P sorption K sorption (Allen and Jeffery 1990) and cation exchange capacity (Gillman and Sumpter 1986)
The soil water was obtained by centrifugation from soil samples (0-15 cm 30 per plot) and collected from the 0 100 200 and 600 kg Pha plots across all AG treatments on 16 May 1996 The supernatant was analysed for pH Ec Ca Mg K S and P The remaining soil was analysed for pH (H20) bicarbonate extractable P and K PRI and DTPA extractable Zn After harvest on 5 August 1996 soil samples were collected from 2 depths as for the preplanting treatment from all plots These were analysed for pH bicarbonate extractable P K total P PRI and exchangeable cations (Ca Mg K and N)
Plant
At buttoning on 13 June 1996 the younger mature leaves (YML) (4th from growing point) were collected from 16 plants in each plot (excluding 1 m buffer at each end) They were dried at 70degC in a force draught oven for 48 h and ground to pass through a 1 mm screen Sub-samples were digested with sulphuric acidhydrogen peroxide (Yuen and Pollard 1954) and the concentration of N P and K measured by an automated colorimetric process (Varley 1966) Concentration of other nutrients (B Ca Na Mg S Fe Mn Zn and Cu) were determined by inductively coupled plasma atomic emission spectroscopy (ICP-AES) after digestion with nitric-perchloric acids (McQuaker et al 1979)
Five whole plants were harvested from the middle of each plot (2 per row)at the end of the experiment on 4 July 1996 using shovels to recover as much of the root system as possible The plants were separated into four categories curds leaves stems and roots All soil was washed from the roots using tap water shaken and the excess water removed using paper towels The fresh weight of all four categories was recorded and the material was diced into small pieces (lt 8 cm3) using stainless steel knives sub-samples (300 g fresh weight) were collected at random from the diced pieces and the fresh weight recorded These were dried at
31
The use of Red Mudgypsum in vegetable production
70degC in a forced draught oven for 48 h and the dry weight recorded These samples were then analysed for P as for the youngest mature leaves Separate sub-samples (300 g fresh weight) of curds were collected and analysed for Ba Cd Cr Co Pb Mo Rb Sr Ti Th V and N using inductively coupled plasma mass spectrometry (ICP-MS) The fresh and dry weight of the curds leaves stems and roots at harvest were used to calculate P uptake in kgha)
Harvest
Harvest commenced when the leaves surrounding the head opened and exposed the curds 77-80 days after transplanting At this stage florets at the periphery of the curd had just begun to separate Sixteen curds (12 plus 4 from whole plant samples above) were collected from the central 4 m of both rows (1 m buffer) and all the leaves and stems removed according to requirements for export market Each fresh curd was weighed and rejects recorded if undersize (lt 500 g) oversize (gt 2000 g) discoloured (yellowing) overmature (separation of florets in centre of curd) diseased damaged or otherwise distorted The total marketable and reject yield were recorded for each plot
Analysis of data
Analysis of variance was carried out on level of applied AG or P versus (a) chemical characteristics of soil (bicarbonate extractable P total P etc) preplanting and harvest (b) concentrations of nutrients in soil solution at midgrowth (c) concentration of nutrients in YMLs at midgrowth (d) concentration of elements in curds at harvest (e) P uptake by plant parts and (f) total marketable and reject yield of curds at harvest Mitscherlich curves and inverse polynomials were fitted to the relationship between level of applied P and yield at each level of applied AG The level of applied P required for 95 99 and 100 (in case of inverse polynomials) of maximum yield was calculated Mitscherlich curves were fitted to the relationship between level of applied P and P in YMLs at midgrowth at all levels of AG The P in YMLs corresponding to the level of applied P required for 95 99 or 100 of maximum yield (as determined from yield versus applied P plots) was then determined
Mitscherlich curves were also fitted to the relationship between level of applied P and P uptake by curds leaves stems and roots and the P uptake corresponding to whole plants (additions of all 4) level of P required for 95-100 of maximum yield determined Phosphorus uptake by plant parts or whole plants on 0 P plots were detected from P uptake at other rates to account for non-fertiliser sources of P This was used to adjust P uptake When determining P fertiliser recovery efficiency (RE) by plant parts or whole plants (ie fertiliser P uptake by plant parts or whole plantsP applied both in kgha Novoa and Loomis 1981)
Results
Effects of fresh AG on chemical characteristics of soil and soil solution
There was a significant (P lt 005) increase in the Ec pH PRI and sorption capacity (topsoil only) of the topsoil and subsoil of a yellow Karrakatta sand with level of freshly-applied AG prior to fertiliser application and planting (Table 51) There was no significant effect of level of AG on Colwell K K sorption capacity and total P with level of freshly-applied AG (Table 51)
The use of Red Mudgypsum in vegetable production
Table 51 Some chemical characteristics of the topsoil (0-15 cm) and subsoil (15-30 cm) of a yellow Karrakatta sand after application of Alkaloam gypsum (AG)1 just prior to fertiliser application and transplanting
(a) Topsoil (0-15 cm)
AG (tha)
Ec (mSm)
pH (CaCl2)
BicP2
(Vigfe)
BicK2
(pgg) PRI3
(mLg) TP4
(Pgg) CEC5
(me ) Kads6 Pads7
0 37 74 107 153 097 507 2 0 41
60 67 82 93 197 167 473 2 043 66
120 80 82 100 277 243 607 2 044 78
240 103 84 97 290 38 637 2 058 129
Lsd8 202 037 38 136 046 1010 0 049 41
Sig9 ns ns ns ns ns
(b) Subsoil (15-30 cm)
AG Ec PH BicP2 BicK2 PRI3 TP4
(tha) (mSm) (CaCl2) (Pgg) (Pgg) (mLg) (Pgg)
0 30 72 83 227 07 507
60 63 81 73 190 15 453
120 80 81 87 220 18 540
240 107 83 83 240 27 563
Lsd8 202 037 38 136 046 101
Sig9 ns ns ns
Applied 7 weeks previously 2 After Colwell (1963) 3 Phosphorus retention index after Allen and Jeffery (1990) 4 Total phosphorus 5 Cation exchange capacity (Gillman and Sumpter 1986) 6 Slope of K adsorption isotherm from the Freundlich equation (Allen and Jeffery 1990) 7 Slope of P adsorption isotherm from the Freundlich equation (Allen and Jeffery 1990) 8 Least significant difference at P lt 005 9 Significance at lt 0001 () lt 001 () lt 005 () level or not significant (ns)
There was a significant (P lt 005) increase in the concentration of Na and a decrease in the concentration of K in the soil solution with level of freshly-applied AG one month after planting and fertilising (Table 52 (a) and Fig 51) At the same time Colwell K and PRI in the topsoil increased significantly with level of freshly-applied AG By contrast there was a significant decrease in extractable Zn with level of AG The concentration of Ca Mg S and P increased significantly with level of applied P in soil solution (Table 52 (a)) Colwell P in the topsoil increased significantly with level of P whilst Colwell K PRI and extractable Zn decreased at the same time (Table 52 (b))
33
The use of Red Mudgypsum in vegetable production
Table 52 (a) Ec (mSm) pH and concentration of nutrients (pgmL) in soil solution 1 month after planting with level of freshly-applied Alkaloamreggypsum (AG)1 and phosphorus
AG
AG (tha)
Ec (mSm)
pH Ca (pgmL)
Mg (pgmL)
Na (pgmL)
K (pgmL)
S (pgmL)
P (pgmL)
Psrp2
(VigmL)
0 112 70 175 18 110 77 101 57 56
60 132 74 164 17 137 58 92 34 31
120 172 75 166 17 152 54 97 44 34
240 166 81 130 16 198 34 75 24 11
Lsd3 19 025 33 4 16 11 26 27 32
Sig4 ns ns ns ns ns
p
AG (tha)
Ec (mSm) PH
Ca (pgmL)
Mg (pgmL)
Na (pgmL)
K (pgmL)
S (UgmL)
P (pgmL)
Psrp2
(pgmL)
0 137 78 99 15 150 46 26 10 01
100 142 76 112 15 153 54 52 23 14
200 170 74 179 19 150 62 114 39 30
600 133 72 244 19 144 60 174 89 87
Lsd3 43 022 31 24 17 15 29 25 30
Sig4 ns ns ns
Applied 11 weeks previously
Soluble reactive P 3 Least significant difference at P lt 005 4 Significance at lt 0001 () lt 001 () lt 005 () level or not significant (ns)
The use of Red Mudgypsum in vegetable production
220
200
E 180 O ) 3
^ 1fi0 _ o 3 140 O V)
oil
120 m c
100 C o CO 80 c flgt o B0 c o o 40
20
0 50 100 150 200
Freshly-applied AG(tha)
250 300
Fig51 Concentration (ugml) of Na(i ) and K ( bull ) in soil solution (0-15cm) under cauliflowers one month after planting with level of freshly-applied AlkaloamRgypsum(AG) Vertical bars indicates Lsd (Plt005) for differences in concentration betweeen levels of AG
35
The use of Red Mudgypsum in vegetable production
Table 52 (b) Extractable P K Zn and phosphorus retention index of the top soil (0-15 cm) of a yellow Karrakatta sand 1 month after transplanting with level of freshly-applied Alkaloamreggypsum (AG)1 and phosphorus (P)
AG
AG (tha)
P2
(ugg) K2
(Ugg) Zn3
(Pgg)
PRI4
(mLg)
0 47 32 67 -112
60 76 38 15 -090
120 94 42 26 -049
240 84 41 13 092
Lsd5 35 6 28 073
Sig6 ns
P P2 K2 Zn3 PRI4
(kgha) (ugg) (Hgg) (Ugg) (mLg)
0 8 42 31 201 100 35 37 45 043 200 80 39 18 -089 600 177 34 26 -313
Lsd5 39 6 27 082
Sig6 ns
Applied 11 weeks previously 2 After Colwell (1963) 3 Extracted in DTPA 4 Phosphorus retention index (Allen and Jeffery 1990) 5 Least significant difference at P lt 005 6 Significance at lt 0001 () lt 001 () lt 005 () level or not significant (ns)
Ec pH exchangeable Ca K Na in me and Colwell P K total P PRI and PRIP increased significantly (P lt 005) with level of freshly-applied AG in the topsoil and subsoil of a yellow Karrakatta sand (Table 53 (a) (b) and Fig 52) at harvest
The use of Red Mudgypsum in vegetable production
o CO
CD
E
o CO
co o
CD
X co CD ogt e co sz o X HI
50 100 150 200
Freshly-applied AG (tha)
250 300
Fig52 Exchangeable Ca() NaP) and K(A) cations (me dry soil) in topsoil (0-15cm) of Karrakatta sand amended with freshly-applied AlkaloamRgypsum(AG) after harvest of cauliflowers Vertical bars indicates Lsd (Plt005) for differences in concentration between levels of AG Lsd not shown when less than size of symbol
37
The use of Red Mudgypsum in vegetable production
Table 53 Ec (mSm) pH and exchangeable Ca Mg K and Na (me ) in the topsoil (0-15 cm) and subsoil (15-30 cm) of a yellow Karrakatta sand amended with AlkaIoamreggypsum (AG) at harvest of cauliflowers
(a) Topsoil
AG Ec PH Ca Mg K Na (tha) (mSm) (CaCl2) (me ) (me ) (me ) (me )
0 67 66 229 018 005 003
60 91 77 382 019 009 02
120 99 79 558 019 012 043
240 120 80 975 024 014 104
Lsd2 20 014 064 0033 0018 021
Sig3 ns
(b) Subsoil
AG Ec pH Ca Mg K1 Na (tha) (mSm) (CaCl2) (me ) (me ) (me ) (me )
0 44 67 225 017 005 003
60 59 74 269 019 005 008
120 66 77 300 018 005 017
240 99 79 397 02 005 029
Lsd2 075 01 029 0036 001 002
Sig3 n s ns
Extracted in 1 m NH4CI 2 Least significant difference at P lt 005 3 Significance at lt 0001 () lt 001 () lt 005 () level or not significant (ns)
However there was no effect of either level of AG or P on exchangeable Mg in the soil at harvest Colwell P total P and PRIP increased significantly whilst Colwell K and PRI decreased with level of freshly-applied P in the topsoil at harvest (Table 4 (a) (b) and Fig 53)
The use of Red Mudgypsum in vegetable production
Table 54 P (extractable P total P phosphorus retention index and P sorption) in the top soil (0-15 cm) and subsoil (15-30 cm) of a yellow Karrakatta sand at harvest of cauliflowers with level of freshly-applied Alkaloamreggypsum (AG) and phosphorus (P)
(a) Topsoil
AG
AG BicP1 BicK1 TotP2 PRI3 PRIP3
(tha) (ugg) (Pgg) (Hgg) (mLg) (mLg)
0 39 23 92 -07 28
60 50 38 110 02 50
120 59 51 135 16 75
240 58 62 157 35 99
Lsd4 5 11 15 03 06
Sig5
P BicP1 BicK1 TotP2 PRI3 PRIP3
(kgha) (ugg) (Hgg) (ngg) (mLg) (mLg)
0 10 53 57 29 40
50 15 40 66 22 38
100 25 41 78 17 44
200 53 41 128 14 71
400 87 44 186 -01 86
600 120 41 226 -12 102
Lsd4 11 8 20 09 13
Sig5
1 After Colwell (1963) 2 After Allen and Jeffery (1990) 3 After Allen and Jeffery (1990) 4 Least significant difference at P lt 005 5 Significance at lt 0001 () lt 001 () lt 005 () level or not significant (ns)
39
The use of Red Mudgypsum in vegetable production
Table 54 P (extractable P total P phosphorus retention index and P sorption) in the top soil (0-15 cm) and subsoil (15-30 cm) of a yellow Karrakatta sand at harvest of cauliflowers with level of freshly-applied Alkaloamreggypsum (AG) and phosphorus (P)
(b) Subsoil (15-30 cm)
AG
AG BicP1 BicK1 TotP2 PRI3 PRIP3
(tha) (ugg) (Ugg) (Ugg) (mLg) (mLg)
0 33 20 79 -05 26
60 30 21 73 -01 30
120 33 27 77 08 42
240 26 24 76 13 40
Lsd4 10 2 10 04 10
Sig5 ns ns
P BicP1 BicK1 TotP2 PRI3 PREP3
(kgha) (ugg) (Vigg) (Ugg) (mLg) (mLg)
0 7 25 48 15 22
50 11 22 52 09 19
100 15 24 59 10 27
200 32 23 81 06 39
400 51 22 100 -03 47
600 67 21 117 -11 52
Lsd4 8 5 8 05 09
Sig5 ns
1 After Colwell (1963) 2 After Allen and Jeffery (1990) 3 After Allen and Jeffery (1990) 4 Least significant difference at P lt 005 5 Significance at lt 0001 () lt 001 () lt 005 () level or not significant (ns)
The use of Red Mudgypsum in vegetable production
100 150 200
Freshly-applied AG (tha)
300
Fig53 Concentration of total P(A) Colwell P() or K(laquo) in topsoil (0-15cm) with level of freshly-applied AlkaloamRgypsum (AG) after harvest of cauliflowers Vertical bars indicates Lsd (Plt005) for differences in concentration between levels of AG Lsd not shown when less than size of symbol
41
The use of Red Mudgypsum in vegetable production
Nutrients in leaves at midgrowth and harvest
There was a significant decrease in concentration of K and an increase in concentration of Na S Mn and Cu in youngest mature leaves (YML) of cauliflowers at buttoning with level of freshly-applied AG (Table 55) The concentration of P in YML at 01 AGha (049) was significantly higher than at 2401 AGha (044) but not at other levels Currently-applied AG had no significant effect on concentration of N Ca Mg Fe Zn or B in YML There was a significant increase in YML in the concentration of K P and S in YML with level of applied P whilst concentration of N Mg Mn and B were variable (Fig 54 55) Level of applied P had no significant effect on the concentration of Ca and Na in the YML (Table 55)
Table 55 (a) Concentration of macro-nutrients (dry weight basis) in youngest mature leaves of cauliflowers at buttoning with level of freshly-applied Alkaloamreggypsum (AG) and phosphorus (P)
AG
AG N1 K1 Ca2 S2 P1 Na2 Mg2
(tha) () () () () () () ()
0 482 393 240 081 049 036 023
60 484 383 251 084 046 040 024
120 506 357 255 081 046 045 024
240 494 355 246 088 044 056 025
Lsd3 026 012 024 005 003 006 0013
Sig4 ns ns ns ns
p
p N1 K1 Ca2 S2 P1 Na2 Mg2
(kgha) () () () () () () ()
0 523 316 254 066 024 046 025
50 489 372 255 081 041 049 026
100 503 388 229 084 048 042 024
200 472 379 250 089 050 046 024
400 494 390 242 093 057 043 023
600 470 385 258 091 057 039 022
Lsd3 027 024 036 005 003 008 0017
Sig4 ns ns
1 After Varley (1966) 2 After McQuaker et al (1979) 3 Least significant difference at P lt 005 4 Significance at lt 0001 () lt 001 () lt 005 () level or not significant (ns)
The use of Red Mudgypsum in vegetable production
0 50 100 150 200 250 300
Freshly-applied AG (tha)
Rg54 Concentration of N() K(B) and Ca(A) in youngest mature leaf (YML) at buttoning
of cauliflowers with level of freshly-applied AlkaloamRgypsum(AG) Vertical bars
indicates Lsd (Plt005) for differences in concentration between levels of AG
10
bdquo 09 lt Q OR ^ D) 07 c
tto
06 3
X3
to 05 _ l
gtbull 04 C
i3 03 c agt bull c 02 3
-z 01 0 50 100 150 200 250 300
Freshly-applied AG (tha)
Rg55 Concentration of S() Na(B) Mg(4) and P(T) in youngest mature leaf (YML) at buttoning
of cauliflowers with level of freshly-applied AlkaloamRgypsum(AG) Vertical bars indicates Lsd (Plt005) for differences in concentration between levels of AG
43
The use of Red Mudgypsum in vegetable production
The relationship between P in YML at buttoning and level of freshly-applied P was best described by Mitscherlich relationships at all levels of applied AG (Fig 56)
en c o 3
X2
gt
06
^
bull A
05 ^ S
04
03
02
01
n n i i i
0 100 200 300 400 500 600 700
Applied P (kgha)
o
X I
5 gt
06
05
04
03
02
01
00
- bull B
- bull bull ^
o
I I I I
0 100 200 300 400 500 600 700
Applied P (kgha)
100 200 300 400 500 600 700
Applied P (kgha)
100 200 300 400 500 600 700
Applied P (kgha)
Fig56 P in YML of Cauliflowers at buttoning () corresponding to applied P required for either 95 (dashed line) or 99 (whole line) of maximum yield at 0(A) 60(B) 120(C) or240(D)t of freshly-applied AlkaloamRgypsumha
The equations for the fitted lines are
A
B
C
D
y = 056 - 030 x exp (-00182) (R2 = 097)
y = 057 - 032 x exp (-00103) (R2 = 088)
y = 055 - 031 x exp (-00126) (R2 = 099)
y = 056 - 032 x exp (-00092) (R2 = 098)
The P in YML corresponding to level of freshly-applied P required for 99 of maximum yield was 053 057 055 and 055 for 0 60 120 and 240 tha respectively
44
The use of Red Mudgypsum in vegetable production
Table 55 (b) Concentration of micro-nutrients (dry weight basis) in youngest mature leaves of cauliflowers at buttoning with freshly-applied Alkaloamreggypsum (AG) and phosphorus (P)
AG
AG (tha)
Fe (Pgg)
Zn (Ugg)
Mn (vigg)
B (Pgg)
Cu1
(Pgg)
0 1354 251 217 211 26
60 1274 248 237 213 28
120 1353 253 240 217 27
240 1394 263 260 214 29
Lsd2 153 24 15 082 02
Sig3 ns ns ns
P Fe Zn Mn B Cu (kgha) (ngg) (ugg) (Pgg) (Ugg) (Pgg)
0 1418 268 212 215 26
50 1388 253 263 220 27
100 1301 267 251 217 29
200 1336 249 250 217 28
400 1282 255 232 204 28
600 1341 233 224 210 28
Lsd2 197 29 19 08 02
Sig3 ns ns ns
1 Extracted in 1 m NH4CI 2 Least significant difference at P lt 005 3 Significance at lt 0001 () lt 001 () lt 005 () level or not significant (ns)
There was a significant (P lt 005) decrease in the concentration of P Zn and an increase in the concentration of Na in whole leaves (WL) of cauliflowers with rate of freshly-applied AG at harvest (Table 56) Level of freshly-applied AG had no significant effect on concentration of N K Ca S Mg Fe Mn B or Cu Concentration of Ca S P and Na in (WL) at harvest increased significantly (P lt 005) with level of freshly-applied P whereas Zn concentrations decreased and concentrations of Mg Mn and B were variable Level of freshly-applied P had no significant effect on concentration of N K Fe or Cu in WL at harvest
45
A O O ltyi
4x
r en 00
9 400 200 o o o copy
ns
O
kgt ON
kgt
4gt
kgt 4 4 4^
kgt
ns
O 4 4 ON 4 k)
o
i mdash t mdash raquo
4 00
4 ON
4 4^ NO Q O
o copy ON
i mdash gt
b b 1 mdash t
b o p Vcopy
O 00 ON
o ON
gtmdash 5 co 5J M
o o
O in
o 4 Ncopy
o 4 O
p 4
p kgt 1 mdash t
copy
ON
o b NO
O ON
o 00
o 00
o ON I mdash
O ON
O 3 Z 5 raquoM
o b 4
O
kgt o kgt -J
p kgt 00
O kgt 00
O
kgt NO
copy kgt ON
The use of Red Mudgypsum in vegetable production
Table 56 (b) Concentration of micro-nutrients (dry weight basis) in leaves of cauliflowers at harvest with level of freshly-applied Alkaloamreggypsum (AG) and phosphorus (P)
AG
AG (tha)
Fe1
(ugg) Zn1
(vgg) Mn1
(vgg) B1
(vgg) Cu1
(vigg)
0 762 224 214 263 42
60 700 197 227 265 38
120 811 196 216 254 38
240 842 193 236 256 37
Lsd2 132 099 21 16 06
Sig3 ns ns ns ns
P (kgha)
Fe1
(pgg) Zn1
(^gg) Mn1
(Vigg) B1
(lJgg) Cu1
(Pgg)
0 786 233 213 248 36
50 625 235 241 266 37
100 833 207 237 270 41
200 938 192 235 265 44
400 725 178 208 259 37
600 765 169 206 250 37
Lsd2 230 21 21 11 063
Sig3 ns ns
After McQuaker et al (1979)
Least significant difference at P lt 005
Significance at lt 0001 () lt 001 () lt 005 () level or not significant (ns)
47
The use of Red Mudgypsum in vegetable production
Nutrients and heavy metals in curds at harvest
There was a significant (P lt 005) decrease in the concentration of K and P and an increase in the concentration of Ca and Na in the curds at harvest with level of freshly-applied AG Concentration of N Mg Fe Zn Mn B and Cu in the curds were unaffected by level of freshly-applied AG (Table 57) As level of freshly-applied P increased there was a significant (P lt 005) decrease in concentration of N S Mg Fe Zn Mn and B and an increase in concentration of K Ca P and Na in curds at harvest Concentration of Cu in curds were unaffected by level of applied P (Table 57 (b))
Table 57 (a) Concentration of macro-nutrients (dry weight basis) in curds of cauliflowers at harvest with level of freshly-applied Alkaloamreggypsum (AG) and phosphorus (P)
AG
AG N1 K1 Ca S1 P2 Na1 Mg1
(tha) () () () () () () ()
0 392 515 040 066 047 023 018
60 384 500 040 067 045 023 017
120 404 474 043 071 043 024 018
240 402 458 041 071 041 028 018
Lsd3 022 016 001 004 002 002 0006
Sig4 ns + ns ns
P
p N1 K1 Ca1 S1 P2 Na1 Mg1
(kgha) () () () () () () ()
0 496 417 034 097 031 016 019
50 400 518 043 068 040 023 018
100 376 483 042 063 042 025 017
200 372 501 044 063 047 027 017
400 371 498 042 062 052 028 017
600 358 505 041 060 052 027 016
Lsd3 027 02 003 005 002 003 001
Sig4
1 After McQuaker et al (1979) 2 After Varley (1966) 3 Least significant difference at P lt 005 4 Significance at lt 0001 () lt 001 () lt 005 () level or not significant (ns)
The use of Red Mudgypsum in vegetable production
Table 57 (b) Concentration of micro-nutrients1 (dry weight basis) in curds Cauliflowers at harvest with level of freshly-applied Alkaloam gypsum (AG) and phosphorus (P)
AG
AG (tha)
Fe1
(Ugg)
Zn1
(vigg) Mn1
(Pgg) B1
(Pgg) Cu1
(Pgg)
0 611 279 124 188 26
60 587 247 134 191 25
120 706 299 139 192 29
240 592 268 145 186 25
Lsd2 329 57 14 08 06
Sig3 ns ns ns ns ns
p
p (kgha)
Fe1
(Ugg) Zn1
(Pgg) Mn1
(Ugg) B1
(ugg)
Cu1
(Pgg)
0 976 492 156 202 31
50 520 279 145 198 26
100 507 230 135 186 24
200 432 208 127 190 24
400 739 239 131 183 28
600 567 192 120 177 24
Lsd2 270 61 142 114 061
Sig3 a s
1 After McQuaker et al (1979) 2 Least significant difference at P lt 005 3 Significance at lt 0001 () lt 001 () lt 005 () level or not significant (ns)
49
The use of Red Mudgypsum in vegetable production
Concentration of Ba in curds at harvest decreased and concentration of Ti increased significantly in curds at harvest with level of freshly-applied P (Table 58) As level of freshly-applied P increased concentrations of Pb and Rb decreased and of Sr decreased Ba concentrations were variable with level of freshly-applied P (Table 58)
Table 58 Concentration of Ba plus heavy metals1 (fresh weight basis) in curds of cauliflowers at harvest with level of freshly-applied Alkaloamreggypsum (AG) and phosphorus (P)
AG Ba Cd Cr Co Pb Ni Rb Sr Ti Th V (tha) (ngg) (ngg) (ngg) (ngg) (ngg) (ngg) (ngg) (ngg) (ngg) (ngg) (ngg)
0 797 7 34 7 13 34 590 1219 34 39 7
60 482 7 34 7 15 34 610 1146 46 52 8
120 583 7 43 7 20 34 616 1246 45 50 8
240 355 7 34 7 15 34 637 1152 41 45 8
Lsd2 141 1 13 16 11 15 74 188 5 16 1
Sig3 ns ns ns ns ns ns ns ns ns
MRL4 50 2000
P (kgha)
Ba (ngg)
Cd (ngg)
Cr (ngg)
Co (ngg)
Pb (ngg)
Ni
(ngg)
Rb (ngg)
Sr (ngg)
Ti
(ngg)
Th
(ngg)
V (ngg)
0 556 7 34 7 25 34 650 998 39 45 9
50 670 7 34 7 18 34 657 1387 50 74 9
100 576 7 34 7 11 34 570 1206 45 50 8
200 529 7 34 7 12 34 616 1293 39 39 7
400 523 7 48 7 19 39 596 1126 39 36 7
600 476 7 34 7 11 34 603 1126 36 36 7
Lsd2 121 1 16 1 15 6 40 181 19 29 2
Sig3 ns ns ns ns ns ns ns ns
MRL4 50 2000
Inductively coupled plasma mass spectrometry 2 Least significant difference at P lt 005 3 Significance at lt 0001 () lt 001 () lt 005 () level or not significant (ns) 4 Maximum residue limit
The use of Red Mudgypsum in vegetable production
P uptake by plants P uptake by whole plants or plant parts was unaffected by level of freshly-applied AG by but increased significantly with level of freshly-applied P (Table 59)
P uptake by whole plants increased from 50 kg Pha to 19 to 21 kgha at 400 to 600 kg applied Pha respectively Curd root stem and leaf uptake was 33 5 6 and 50 respectively of total plant P uptake at the highest level of applied P (Table 59)
Table 59 P uptake (kgha) by curds roots stem leaf and whole cauliflower plants at harvest with level of freshly-applied Alkaloamreggypsum (AG) and phosphorus (P)
AG
AG Curds Roots Stem Leaf Total (tha) (kgha) (kgha) (kgha) (kgha) (kgha)
0 53 074 11 87 158
60 48 066 10 83 148
120 47 069 11 79 143
240 45 060 10 74 135
Lsd1 065 015 025 21 31
Sig-2 ns ns ns ns ns
p
p (kgha)
Curd (kgha)
Root (kgha)
Stem (kgha)
Leaf (kgha)
Total (kgha)
0 12 030 040 29 49
50 40 058 100 68 124
100 51 053 112 76 143
200 59 075 120 93 172
400 67 093 131 115 205
600 61 094 121 102 185
Ls-d1 055 017 020 18 25
Sig2
1 Least significant difference at P lt 005 2 Significance at lt 0001 () lt 001 () lt 005 () level or not significant (ns)
51
The use of Red Mudgypsum in vegetable production
Yield
There was a significant (P lt 005) increase in both total and marketable curd yield with level of freshly-applied P at all levels of freshly-applied AG (Table 510) There was no significant effect of level of freshly-applied AG on either total (Table 510 (a)) or marketable (Table 510 (b)) curd yield
Table 510 Curd yield (total marketable) of cauliflowers (tha) at harvest with level of freshly-applied Alkaloamreggypsum (AG) and phosphorus (P)
(a) Total
p (kgha)
AG (tha) p
(kgha) 0 60 120 240
0 755 468 483 177
50 1464 1675 1554 1516
100 2169 1706 1757 1985
200 2242 1737 1928 1862
400 1752 2102 2155 2136
600 1689 1764 1768 2023
Lsd1
Sig2
16 (AG)
ns 201 (P)
401 (AGP)
-
(b) Marketable
p (kgha)
AG (tha) p
(kgha) 0 60 120 240
0 274 060 000 000
50 1222 1463 1294 1152
100 2057 1416 1603 1820
200 2141 1377 1803 1752
400 1572 2020 2095 1996
600 1468 1534 1500 1974
Lsd1
Sig2
24 (AG)
ns
46 (P)
52(AGP)
ns
Least significant difference at P lt 005 2 Significance at lt 0001 () lt 001 () lt 005 () level or not significant (ns)
The relationship between total yield and level of freshly-applied P was best described by a quadratic relationship at all levels of freshly-applied AG (Fig 57) As level of AG increased the level of freshly-applied P required for 99 of maximum yield increase from 124 kg Pha at 0 t AGha to 339 kg Pha at 240 tha There was no significant effect of level of freshly-applied AG on maximum curd yield (Fig 57)
The use of Red Mudgypsum in vegetable production
26
24
22
(tha
) 20
18
Cur
d yi
eld 16
14
12
10
8
6 i ii
A=0
i i i i i
I I
0 100200300400500600700
Applied P (kgha)
24 22 20 18 16 14 12 10 8 6 4 2
- 7 I
_ bull
i i i n
mdash^ B=60
I I I
0 100200300400500600700
Applied P (kgha)
co
32 CD
gt 2 3
o
25
20
15
10
5
bull j
- bull
I I I I I
- - gt C=120
l l l
0 100200300400500600700
Applied P (kgha)
0 100200300400500600700
Applied P (kgha)
Fig57 Total curd yield (tha) of cauliflower with level of freshly-applied Alkaloam gypsum and
phosphorus (ABCD = 060120240 tha) Vertical lines represent applied P necessary
for either 95 (dashed) or 99 (whole) of maximum yield
The equations for the fitted lines are
A y = 1336 + (-577 + 01335x)(l-00088x +000007872) (Z2
B y = 89434 + 00705 - OOOOlx2 (R2 = 070)
C y = 84752 + 00810 - OOOOlx2 (B2 = 081)
D y = 733 +00871x - 00001 Ix2 (R2 = 099)
098)
53
The use of Red Mudgypsum in vegetable production
Discussion
The increase in pH Ec PRI and P sorption of Karrakatta sands with level of freshly-applied AG prior to fertiliser application is similar to that reported for the amendment of Joel (McPharlin et al 1994 and Robertson et al 1997a) and Karrakatta sands (Robertson et al 1994 and 1997b) with AG The increase in DH and Ec of the amended soil is explained by the high levels of both in the AG (ie pH (CaCr) = 94 and Ec = 623 mSm Appendix 1) The increased retentionsorption of P is explained by the addition of iron (974) and aluminium (551) in various oxides and hydroxides in the AG (Appendix 1 and Barrow 1982) to the soil After the application of P fertilisers levels of P in the soil at mid-growth and harvest as measured by total and Colwell P increased with a parallel decrease in PRI The increase in the levels of exchangeable Ca and Na in the soil at the same times with level of freshly-applied AG can be attributed to the AG itself However the increase in exchangeable and Colwell K appears to be due to improved K retention capacity of the soil due to physical properties of the AG rather any increased supply of K from the AG Whilst the overall K adsorption properties of the soil as measured by the Freundlich isotherm was not significantly increased with level of AG K sorption at 2401 AGha was significantly higher than at 01 AGha
There was no significant increase in cation exchange capacity (CEC) with level of freshly-applied AG on the Karrakatta sand in this experiment which remained about 2 me By contrast the CEC of virgin Joel sands increased from 1 to 2 me with level of freshly-applied AG (0 to 240 tha) in columns (McPharlin et al 1994) The application of AG would be expected to increase the CEC of coarse sands because (1) AG a fine textured material (10 clay 68 silt) (Ward 1983) would increase the fine fraction when applied to sands (2) AG has a much higher CEC ie 7 to 15 me depending on pH (Barrow 1982) than either Joel or Karrakatta sands ie 1 to 2 me (McPharlin et al 1994 and Table 51) and (3) application of AG to either Joel or Karrakatta sands increases the retentionreduces leaching of cations either not present in the AG such as NH4-N (McPharlin et al 1994) or only present in small quantities such as K (Tables 52 53 54 and Appendix 51)
The concentration of an element in the soil expressed as either extractable or total amounts represents the quantity or extensive factor in terms of plant nutrition as outlined by Holford and Mattingly (1976) The concentration of ions in soil solution or the intensive factor may better represent what is available to the plant A good example of this is the levels of K in the soil expressed as either Colwell or exchangeable K which increase significantly with level of applied AG However levels of K in the plant YML at buttoning and curds at harvest decrease significantly with level of AG K in soil solution 1 month after planting similarly decline significantly with level of applied AG and are therefore better correlated with K nutrition of the plant than measurements based on the dry soil Similarly P concentrations in the plant and soil solution decline whilst P retained by the soil increase in response to freshly-applied AG By contrast concentrations of Na in soil solution soil and plant all increase with levels of freshly-applied AG Similar relationships between concentrations of K Na and P in the soil soil solution and plant on a Karrakatta sand have been reported previously (Robertson et al 1997)
In previous work maximum yield (ie A value) of cauliflowers was reduced when freshly prepared AG was applied at levels gt 120 tha (Robertson et al 1994) This yield reduction was assumed not to be due to induced P deficiency resulting form high level of applied AG as it could not be alleviated by increased levels of applied P Although increased levels of applied P were needed to maximise yield as the level of freshly-applied AG increased Concentrations of K decreased and Na increased in the YML with level of applied AG and the yield reduction was assumed to be due either induced K deficiency or Na toxicity However neither the reduced concentrations of K or the increased concentrations of Na in the plant were at levels that would reduce yield according to published standards (Weir and Cresswell 1993) Antagonism between Na and K uptake by plants is common (Yeo 1983) For example increasing soil salinity resulted in increased concentrations of Na and decreased concentrations of K in the leaves of Zucchini grown in controlled greenhouses in Spain (Villora et al 1997)
The use of Red Mudgypsum in vegetable production
In this work as level of freshly-apphed AG increased level of applied P necessary for maximum yield increased as in the previous work however maximum yield was not reduced by AG up to 240 tha This is despite concentrations of K in the YML decreasing and Na increasing in response to level of freshly-applied AG However as in the previous work neither concentrations of K or Na were at levels expected to cause yield reduction By contrast the reduction in maximum yield of potatoes at high levels of freshly-applied AG (ie gt 120 tha) was correlated with a reduced concentration of K in the petioles (Robertson et al 1997b)
The level of freshly-applied P required for 99 of maximum yield in this work increased from 124 kgha at 01 AGHa to 339 kgha at 2401 AGha These levels of applied P are similar to that reported necessary for maximum yield of cauliflowers on AG-amended (Robertson et al 1994) or unamended (McPharlin et al 1995) Karrakatta sands The P required for 99 of maximum yield in this work 053 to 057 was either slightly higher - 047 (McPharlin et al 1995) or within range - 05 to 07 (Piggott 1986) 03 toO7 (Weir and Cresswell 1993) of that reported as critical or adequate for maximum yield of cauliflowers
Increased levels of freshly-applied AG did not significantly change the concentrations of Cd Co Cr Pb Ni Rb Sr Th or V in the curds of cauliflowers By contrast concentrations of Ba were significantly reduced and Ti increased in the curds with levels of freshly-applied AG Similarly there was no reported change in concentration of Cd Cr Pb or Co with level of freshly-applied AG in curds of cauliflower grown on Karrakatta sands (Robertson et al 1994) in previous work Also there was no change in Ba concentration in curds with level of AG in contrast to the previous work
References
Barrow NJ (1982) Possibility of using caustic residue from bauxite for improving the chemical and physical properties of sandy soils Australian Journal of Soil Research 33 275-285
Holford ICR and Mattingly GEG (1976) Phosphate adsorption and plant availability of phosphate Plant and Soil 44 377-89
McArthur and Bettenay (1960) The development and distribution of the soils of the Swan Coastal Plain Western Australia Soils Publication No 16 CSIRO Division of Soils CSIRO Melbourne Australia
McPharlin IR JefFery RC Toussaint LF and Cooper M (1994) Phosphorus Nitrogen and Radionuclide Retention and Leaching from a Joel Sand amended with Red Mudgypsum Communications in Soil Science and Plant Analysis 25 (17 amp 18) 2925-2944
McPharlin IR Robertson WJ JefFery RC and Weissberg R (1995) Response of cauliflower to phosphate fertiliser placement and soil test phosphorus calibration on a Karrakatta sand Communications in Soil Science and Plant Analysis 26(3amp4) 607-620
McQuaker NR Brown DF and Kluckner PD (1979) Digestion of environmental materials for analysis by inductively coupled plasma-atomic emission spectrometry Analytical Chemistry 51 1082-1084
Piggott TJ (1986) Vegetable crops pp 148-187 In DJ Reuter and JB Robinson (eds) Plant Analysis an Interpretation manual Inkata Press Melbourne Australia
Robertson WJ McPharlin IR and JefFery RC (1994) Final report of investigation into the use of gypsum-amended Red Mud as a soil-amendment on horticultural properties on the Swan Coastal Plain Report to HRDC (Project No V0039RO) Department of Agriculture Western Australia
55
The use of Red Mudgypsum in vegetable production
Robertson WJ Jeffery RC and McPharlin IR (1997a) Residues from bauxite-mining (Red Mud) increase phosphorus retention of a Joel sand without reducing yield of carrots Communications in Soil Science and Plant Analysis 28 (in press)
Robertson WJ McPharlin IR and Jeffery RC (1997b) The growth nutrition and mineral composition of potatoes (Solanum tuberosum L) cv Delaware grown on an yellow Karrakatta sand amended with freshly-applied and residual Alkaloamreggypsum (Submitted to AJEA)
Varley J A (1966) Automatic methods for the determination of nitrogen phosphorus and potassium in plant material Analyst 91 119-126
Villora G Pulgar G Moreno DA and Romero L (1997) Effect of salinity treatments on nutrient concentration in Zucchini plants (Cucurbita pepo L var Moschatd) Australian Journal of Experimental Agriculture 37 605-608
Vlahos S Summers KJ Bell DT and Gilkes RJ (1989) Reducing phosphorus leaching from sandy soils with Red Mud bauxite processing residues Australian Journal of Soil Research 27 651-662
Weir RG and Cresswell GC (1993) Plant Nutrient Disorders 3 Vegetable crops p 93 Inkata Press Melbourne Australia
Yuen SH and Pollard AG (1954) Determination of nitrogen in agricultural material by the Nessler reagent II Micro determination in plant tissue and soil extracts Journal of the Science of Food and Agriculture 5 364-369
The use of Red Mudgypsum in vegetable production
Appendix 51 Chemical and physical characteristics of Alkaloam gypsum used in cauliflower experiment (freshly-applied Alkaloamreggypsum)
Parameter Units Value Kgt
Ec mSm 623 -
pH (H 20) mSm 99 -
pH (CaCl2) mSm 94 -
PRI mLg 610 - gt 1000 -
LOI 1973 -
C a C 0 3 1290 1290
Fe (Fe203) 974 974
Al (A1203) 551 551
Si (Si0 2 ) 797 797
Ca (CaO) 45 450
Na (Na 2 0) 228 228
Ti (Ti0 2 ) 174 174
K (K 2 0) 072 72
Mg (MgO) 028 28 sect 047 47
P (P2O5) 005 05
Mn (MnO) 002 02
Total P ngg 266 -
Extractable P M-gg 58 -
Extractable K M-gg 43 -
As ngg 35 -
Ba ^gg 413 -
Cu Ugg 29 -
Sr Hgg 287 -
Nb Hgg 99 -y Hgg 866 -
Zr fAgg 1477 -
Sand 232 -
Silt 473 -
Clay 295 -
After Allen and Jeffery (1990)
Based on X-ray fluorescence (XRF) spectrometry
After Colwell (1963)
The use of Red Mudgypsum in vegetable production
Appendix 52 Concentration of Ba plus heavy metals1 (dry weight basis) in curds of cauliflowers at harvest with level of freshly-applied Alkaloamreggypsum (AG) and phosphorus (P)
(a)
AG Ba Cd Cr Co Pb Ni Rb Sr Ti Th V (tha) (Pgg) (vigg) (ugg) (ugg) (Pgg) (Pgg) (Pgg) (ugg) (Pgg) (Pgg) (Pgg)
0 119 010 050 010 020 050 88 182 050 058 010
60 72 010 050 010 022 050 91 171 069 078 012
120 87 011 064 011 030 050 92 186 067 075 012
240 53 011 05 010 023 050 95 172 061 067 012
Lsd2 21 002 02 024 016 022 11 28 008 024 002
Sig3 ns ns ns ns ns ns ns ns ns
(b)
p (kgha)
Ba (vgg)
Cd (vigg)
Cr (Pgg)
Co (ngg)
Pb (vgg)
Ni (Pgg)
Rb (Pgg)
Sr (Pgg)
Ti
(Pgg)
Th (Pgg)
V
(Pgg)
0 83 010 050 010 038 050 97 149 058 067 013
50 100 011 050 010 027 050 98 207 075 110 013
100 86 010 050 010 017 050 85 180 067 075 012
200 79 010 050 010 018 050 92 193 058 058 010
400 78 011 071 011 028 058 89 168 058 054 011
600 71 010 050 010 016 050 90 168 054 054 010
Lsd2 18 002 024 0009 022 009 06 27 028 044 003
Sig3 ns ns ns ns ns ns ns ns
Inductively coupled plasma mass spectrometry
Least significant difference at P lt 005
Significance at lt 0001 () lt 001 () lt 005 () level or not significant (ns)
The use of Red Mudgypsum in vegetable production
6 RESPONSE OF CAULIFLOWERS TO RESIDUAL RED MUD (ALKALOAMreg)GYPSUM (AG) AND PHOSPHORUS ON A YELLOW KARRAKATTA SAND
Introduction
It is important to reduce the leaching of phosphorus fertiliser from sandy soils used for vegetable production into the water systems of the Swan Coastal Plain Red Mud (Alkaloam )gypsum (AG) (ie Red Mudgypsum RMG) a waste product from bauxite refining has been suggested as an amendment to reduce phosphorus leaching from sands of the Bassendean Association (Joel Gavin) used for agriculture and horticulture (Barrow 1982)
Experimental work in the field and pots showed amendment with AG significantly reduced P leaching from Joel and Gavin sands (Vlahos et al 1989 McPharlin et al 1994) compared with the unamended (01 RMGha) treatment
Previous work showed a significant reduction in maximum yield of cauliflowers with levels of residual AG of gt 60 tha compared with 01 AGha (Robertson et al 1994) This yield reduction was not due to P deficiency as increased levels of applied P did not obviate the problem Nor was it due to K deficiency as K concentrations in the youngest mature leaves (YML) although reduced by levels of residual AG did not decline to levels expected to reduce yield The converse was true for concentrations of Na in the YML which increased with levels of residual AG but not to concentrations expected to cause toxicity
Since more than 60 tha of AG may be required to significantly improve P retention by sands to enable sustainable horticultural production this yield reduction is re-examined with residual AG
Materials and methods
Site characteristics
The experiment was conducted on a yellow Karrakatta sand (McArthur and Bettenay 1960) at Medina Research Centre (32deg 13 S 115deg 49 E) 30 km south of Perth Both Alkaloamreggypsum (AG) and phosphorus had previously been applied to the site and a potato crop grown in 1995 Prior to that the site had been sown to pasture for several years Some relevant chemical characteristics of the topsoil (0-15 cm) and subsoil (15-30 cm) of the site after application of AG but prior to the application of fertiliser (except residual P) and transplanting are presented in Table 61
Red Mud (Alkaloamreg)gypsum
Alkaloamreg (Red Mud) amended with 10 (ww) gypsum (AG) was produced by the dry mix process by ALCOA of Australia Ltd at their Kwinana Residue Treatment Plant The AG had been spread manually on the site and incorporated using a rotary hoe to approximately 30 cm depth on 22 December 1994 Residual P had been applied just before planting of the previous potato crop on 17 May 1995 and incorporated with a rotary hoe The site was watered for 1 hour per day (8 mmday) using impact sprinklers until planting
Experimental design
The experimental design was a split-plot randomised block with 3 replicates The main plots were levels of AG (0 60 90 120 and 240 tha) and the sub-plots were levels of freshly-applied P (25 50 100 300 and 600 kgha) Main plots measured 7 x 12 m and sub-plots 12 x 7 m (excluding wheel tracks)
59
The use of Red Mudgypsum in vegetable production
Crop management
The site was sprayed with Roundupreg (3 Lha) twice after application of AG and prior to planting to control weeds Six week old seedlings of cauliflowers (cv Plana) obtained from a commercial nursery were transplanted manually on 18 April 1996 in 2 rows per plot with 70 cm between rows and 50 cm between plants Seedlings were dipped in Rovralreg (1 mLL) just prior to planting for control of fungi Treflanreg (14 Lha) and Dacthalreg (12 kgha) were applied immediately after transplanting to control broadleaved weeds and Sertinreg later on in the life of the crop for grass control Ambushreg (100 mLha) and Rogorreg (100 mLha) were used to control caterpillars and red legged earth-mite respectively Copper was applied for control of blackrot The crop was irrigated to a total application equivalent to 100 of the previous days pan evaporation using minisprinklers (Legoreg 6 x 6 m spacing 44 mmh) in 3 waterings of equal duration per day
Fertilisers
Pre-planting fertilisers were broadcast manually and rotary hoed on 17 April 1996
These were K2S04(244) Ca(N03)2(387) MgS047H20 (504) MnS04H20 (504) FeS047H20 (18) Borax (27) CuS045H20 (36) ZnSOH20 (28) and Na2Mo042H20 (2) P was applied as single superphosphate (91 P) at 0 to 600 kg Pha according to treatment and incorporated as before Post-planting K N and Ca were fertigated via the irrigation system as KN03 NHUNO3 and Ca (N03)2 in equal amounts per day for 12 weeks to a total of 600 kg Kha 423 kg Nha and 60 kg Caha Borax was fertigated at 20 kgha in week 3 and Mg was broadcast as MgS047H20 at 50 kgha in weeks 3 6 and 9
Measurements
Soil and soil solution
All zero P subplots were sampled 30 cores per plot just prior to planting and fertilising about 2 months after AG application to 2 depths (0-15 15-30 cm) These were oven dried at 40degC and analysed for Ec pH (CaCl2) P sorption (Ozane and Shaw 1968) bicarbonate extractable P K (Colwell 1963) total P PRI P sorption K sorption (Allen and Jeffery 1990) and cation exchange capacity (Gillman and Sumpter 1986)
The soil water was obtained by centrifugation from soil samples (0-15 cm 30 per plot) and collected from the 0 100 200 and 600 kg Pha plots across all AG treatments on the 16 May 1996 The supernatant was analysed for pH Ec Ca Mg K S and P The remaining soil was analysed for pH (H20) bicarbonate extractable P K PRI and DTPA extractable Zn After harvest 5 August 1997 soil samples were collected from 2 depths as for the preplanting treatment from all plots These were analysed for pH bicarbonate extractable P K total P PRI and exchangeable cations (Ca Mg K and N)
Plant
At buttoning on 13 June 1996 the younger mature leaves (YML) (4th from growing point) were collected from 16 plants (excluding 1 m buffer at each end of plot) in each plot They were dried at 70degC in a force draught oven for 48 h and ground to pass through a 1 mm screen Sub-samples were digested with sulphuric acidhydrogen peroxide (Yuen and Pollard 1954) and the concentration of N P and K measured by an automated colorimetric process (Varley 1966) Concentration of other nutrients (B Ca Na Mg S Fe Mn Zn and Cu) were determined by inductively coupled plasma atomic emission spectroscopy (ICP-AES) after digestion with nitric-perchloric acids (McQuaker et al 1979) Five whole plants were harvested from the middle of each plot (2 per row) at the end of the experiment on 4 July 1996 using shovels to remove as much of the roots as possible The plants were separated into four categories curds leaves stems and roots All soil was dried and digested as for ICP-AES as above and washed from the roots using tap water shaken and the excess water removed using paper towels The fresh weight of all four categories was recorded and the material was diced
60
The use of Red Mudgypsum in vegetable production
into small pieces (lt 8 cm3) using stainless steel knifes sub-samples (300 g fresh weight) were collected at random from the diced pieces and the fresh weight recorded These were dried at 70degC in a forced draught oven for 48 h and the dry weight recorded These samples were then analysed for P as for the youngest mature leaves Separate sub-samples (300 g fresh weight) of curds were collected and analysed for Ba Cd Cr Co Pb Mo Rb Sr Ti Th V and Ni using inductively coupled plasma mass spectrometry (ICP-MS) The fresh and dry weight of the curds leaves stems and roots at harvest were used to calculate P uptake in kgha)
Harvest
Harvest commenced when the leaves surrounding the head opened and exposed the curds 77-80 days after transplanting At this stage florets at the periphery of the curd had just begun to separate Sixteen curds (12 plus 4 from whole plant samples above) were collected from the central 4 m of both rows (1 m buffer) and then all the leaves and stems removed according to requirements for export market Each fresh curd was weighed and rejects recorded if undersize (lt 500 g) oversize (gt 2000 g) discoloured (yellowing) overmature (separation of florets in the centre of curd) diseased damaged or otherwise distorted The total marketable and reject yield were recorded for each plot
Analysis of data
Analysis of variance was carried out on level of applied AG or P versus (a) chemical characteristics of soil (bicarbonate extractable P total P etc) preplanting and harvest (b) concentrations of nutrients in soil solution at midgrowth (c) concentration of nutrients in YMLs at midgrowth (d) concentration of elements in curds at harvest (e) P uptake by plant parts and (f) total marketable and reject yield of curds at harvest Mitscherlich curves and inverse polynomials were fitted to the relationship between level of applied P and yield at each level of applied AG The level of applied P required for 95 99 and 100 (in case of inverse polynomials) of maximum yield was calculated Mitscherlich curves were fitted to the relationship between level of applied P and P in YMLs at midgrowth at all levels of AG The P in YMLs corresponding to the level of applied P required for 95 99 or 100 of maximum yield (as determined from yield versus applied P plots) was then determined
Mitscherlich curves were also fitted to the relationship between level of applied P and P uptake by curds leaves stems and roots and the P uptake corresponding to whole plants (additions of all 4) level of P required for 95-100 of maximum yield determined Phosphorus uptake by plant parts or whole plants on 0 P plots were deducted from P uptake at other rates to account for non-fertiliser sources of P This was used to adjust P uptake when determining P fertiliser recovery efficiency (RE) by plant parts or whole plants ie fertiliser P uptake by plant parts or whole plantsP applied both in kgha (Novoa and Loomis 1981)
The effect of residual AG andP on chemical characteristics of the soil
Increased levels of previously-applied (residual) AG resulted in a significant increase in Ec pH (CaCl2) Colwell P and PRI in the topsoil (0-15 cm) of a Karrakatta sand prior to current the application of fertilisers and planting (Table 61 Fig 61) There was no significant effect of level of residual AG on the levels of Colwell K in the topsoil Increasing levels of previously-applied (residual) P resulted in a significant increase in Colwell P and a decrease in PRI and pH at the same time but had no effect on the levels of Colwell K in the topsoil
61
The use of Red Mudgypsum in vegetable production
Table 61 Chemical characteristics of the topsoil (0-15 cm) of a yellow Karrakatta sand 12 months after application of Alkaloamreggypsum (AG) (residual AG) and phosphorus (P) just prior to fertiliser application and transplanting
AG Ec pH BicP1 BicK1 PRI2
(tha) (mSm) (CaCl2) (H8g) (Hgg) (mLg)
0 36 70 262 199 093
60 62 78 397 308 101
90 70 80 390 378 12
120 73 80 402 391 14
Lsd3 057 018 75 122 018
Sig4 ns
P (kgha)
Ec (mSm)
pH (CaCl2)
BicP1
(M-gg) BicK1
(figg) PRI2
(mLg)
0 59 78 117 323 17
25 58 78 147 338 15
50 58 78 160 322 16
100 58 78 255 327 13
300 62 76 554 309 06
600 66 75 944 296 005
Lsd3 063 01 58 60 02
Sig4 ns ns
1 After Colwell (1963) 2 After Allen and Jeffery (1990) 3 Least significant difference at P lt 005 4 Significance at lt 0001 () lt 001 () lt 005 () level or not significant (ns)
62
The use of Red Mudgypsum in vegetable production
mdash A
8 40 gt -o deggt 35 - en =gt mdash sect 30 _raquo CO
e 25 ltD O d
5 20
1 ^ I I I
T3
C
o
c CO o c o o
0 20 40 60 80 100120140
Residual AG (tha)
u u bull B
80 l
60
40
mdash n bull 20
n i i i i
I
i i i
100 200 300 400 500 600 700
Residual P (kgha)
Figure 61 (A B) Bicarbonate extractable P (bull) and K (bull) (figg dry soil after Colwell 1963) in the top soil (0-15 cm) of a yellow Karrakatta sand prior to fertilising and planting with level of residual Alkaloamreggypsum (t AGha) (A) and P (kgha) (B) Vertical bars refer to Lsd (P lt 005) for differences between levels of AG or P
5 E Q 0 -
20 40 60 80 100120 140
Residual AG (tha)
0 100 200 300 400 500 600 700
Residual P (kgha)
Figure 61 (C D) Phosphorus retention index (PRI) after Allen and Jeffery (1990) in the topsoil (0-15 cm) of a yellow Karrakatta sand prior to fertilising and planting with level of residual Alkaloamreggypsum (t AGha) (C) and P (kgha) (D) Vertical bars refer to Lsd (P lt 005) for differences between levels of AG or P
63
The use of Red Mudgypsum in vegetable production
One month after planting there was a significant increase in concentration of Ca Na and pH and a decrease in K concentration with level of residual AG in the soil solution at 15 cm depth There was no significant effect of level of residual AG on the Ec or concentration of Mg S and soluble reactive P (Psr) in the soil solution (Table 62 (a) Fig 62) There was a significant decrease in Ec pH and concentration of Mg Na and an increase in concentration of Ca S and Psr in soil solution with level of residual P
Table 62 (a) Ec (mSm) pH and concentration of nutrients (ugmL) in soil solution 1 month after planting cauliflowers with level of residual Alkaloamreggypsum (AG) and phosphorus (P)
AG
AG (tha)
Ec (mSm)
pH Ca (ngmL)
Mg (ugmL)
Na (jigmL)
K (UgmL)
S (jigmL)
Psrp1
(pgmL)
0 129 75 91 141 105 81 28 05
60 144 77 108 131 121 64 30 06
120 147 76 123 136 120 50 33 04
Lsd2 33 01 14 09 4 7 1 02
Sig3 ns ns ns ns
P
p (kgha)
Ec (mSm)
pH Ca (UgmL)
Mg (ligmL)
Na (jigmL)
K (UgmL)
S (UgmL)
Psrp1
(VigmL)
0 171 78 107 141 121 68 23 01
100 138 77 104 144 111 58 24 02
300 120 76 103 128 110 63 31 06
600 130 73 117 133 116 71 43 13
Lsd2 20 02 10 11 10 13 7 02
Sig3 ns
Soluble reactive P 2 Least significant difference at P ^ 005 3 Significance at lt 0001 () lt 001 () lt 005 () level or not significant (ns)
64
The use of Red Mudgypsum in vegetable production
3
C
o
o (gt
o in c c o
5 c CD O
o O
3
o
c o
c ltu o c o
o 0 20 40 60 80 100 120 140
Residual AG (tha)
0 100 200 300 400 500 600 700
Residual P (kgha)
Figure 62 (A B) Concentration (figmL) of Ca (bull) Mg (bull) Na (A) K (T) and S (bull) in soil solution (0-15 cm) under cauliflower one month after planting with level P residual Alkaloamreggypsum (AG) (A) and (B) Vertical bars refer to Lsd (P lt 005) for differences in concentration between levels of AG Where bars are not shown Lsd is less than size of symbol
There was a significant increase in Colwell P K and PRI in the topsoil (0-15 cm) and no change in DTPA extractable Zn with level of residual AG one month after planting (Table 62 (b)) As level of residual P increased there was a significant increase in Colwell P and decrease in PRI with no change in Colwell K or DTPA extractable Zn in the topsoil one month after planting
The use of Red Mudgypsum in vegetable production
Table 62 (b) Extractable P K Zn and phosphorus retention index of the TopsoU (0-15 cm) of a yellow Karrakatta sand 1 month after planting of cauliflowers with level of residual Alkaloamreggypsum (AG) and phosphorus (P)
AG
Ag BicP1 BicK1 Zn2 PRI3
(tha) (Pgg) (Pgg) (Pgg) (mLg)
0 27 41 25 05
60 45 43 26 03
120 50 59 23 07
Lsd4 8 6 05 01
Sig5 ns
p
p (kgha)
BicP1
(Pgg) BicK1
(Pgg)
Zn2
(l-igg) PRI3
(mLg)
0 9 46 19 12
100 21 47 22 09
300 42 46 25 03
600 90 52 31 -03
Lsd4 7 5 10 02
Sig5 ns ns
1 After Colwell (1963) 2 Extracted in DTPA 3 After Allen and Jeffery (1990) 4 Least significant difference at P ^ 005 5 Significance at lt 0001 () lt 001 () lt 005 () level or not significant (ns)
After harvest of cauliflowers there was a significant increase in Colwell P and K total P actual and predicted PRI (PRI and PRIp) with residual AG in the topsoil and subsoil of a Karrakatta sand (Table 63 (a) (b)) There was a significant increase in Colwell P and total P and decrease in Colwell K PRI and PRIp with level of residual P in both the topsoil and subsoil after harvest (Fig 63 (A B))
66
The use of Red Mudgypsum in vegetable production
Table 63 Extractable P K total P and phosphorus retention index of the topsoil (0-15 cm) and subsoil (15-30 cm) of a yellow Karrakatta sand after harvest of cauliflowers with level of residual AIkaloamreggypsum (AG) and phosphorus (P)
(a) Topsoil
AG
AG BicP1 BicK1 TotP2 PPJ3 PPJP4
(tha) (ngg) (Hgg) (Pgg) (mLg) (mLg)
0 16 28 68 10 26
60 25 42 86 15 41
90 25 46 91 16 43
120 26 54 96 18 46
Lsd5 3 9 8 005 03
Sig6
P (kgha)
BicP1
(Pgg) BicK1
(vigg) TotP2
(ngg) PPJ3
(mLg) PPJP4
(mLg)
0 7 46 58 19 27
25 8 45 63 19 28
50 9 44 64 20 30
100 15 43 72 17 33
300 37 40 103 09 48
600 63 36 152 03 67
Lsd5 3 6 8 03 05
Sig6
1 After Colwell (1963) 2 After Allen and Jeffery (1990) 3 Phosphorus retention index (Allen and Jeffery 1990) 4 Predicted phosphorus retention index (Allen and Jeffery 1990) 5 Least significant difference at P ^ 005 6 Significance at lt 0001 () lt 001 () lt 005 () level or not significant (ns)
The use of Red Mudgypsum in vegetable production
120
o lgt 100 bull gt
TJ
rn laquon D ) 3
mdash-
on
60
^^ m i _
c 40 ltigt o c o O 20
160 A (I 140
^ ^ ^ ^ 1 o (0 ^ ^ ^ ^ 1 gtraquo 120
^plusmn bull o
^ ^ ^ ^
66
100
^ 3 80
^ mdash ^ tra
tion
60
^ ^ - ^ ^ ^ cen 40
o 20 o 20
I I I I I I I
O
10
0
0 20 40 60 80 100 120 1lt
O
10
Residual AG (tha)
0 100 200 300 400 500 600 700
Residual P (kgha)
Figure 63 (A B) Bicarbonate extractable P (bull) K (bull) and total P (A) in the topsoil (0-15 cm) of a yellow Karrakatta sand after harvest of cauliflowers with level of residual AIkaloamreggypsum (t AGha) (A) and P (kgha) (B) Vertical bars refer to Lsd (P lt 005) for difference between level of AG or P Lsd not shown when less than size of symbol
68
The use of Red Mudgypsum in vegetable production
Table 63 Extractable P K total P and phosphorus retention index of the topsoil (0-15 cm) and subsoil (15-30 cm) of a yellow Karrakatta sand after harvest of cauliflowers with level of residual Alkaloamreggypsum (AG) and phosphorus (P)
(b) Subsoil
AG
AG BicP1 BicK1 TotP2 PRI3 PRJJP4
(tha) (Pgg) (ugg) (ngg) (mLg) (mLg)
0 15 23 69 08 24
60 23 31 82 12 36
90 24 37 91 14 39
120 25 40 90 17 43
Lsd5 4 6 7 01 03
Sig6
P (kgha)
BicP1
(ngg) BicK1
(ugg) TotP2
(ugg) PRI3
(mLg) PRIP4
(mLg)
0 6 36 57 18 25
25 8 36 63 17 26
50 8 34 63 17 26
100 13 31 71 15 29
300 33 29 102 08 43
600 61 30 141 03 64
Lsd5 5 5 8 02 05
Sig6
1 After Colwell (1963) 2 After Allen and Jeffery (1990) 3 Phosphorus retention index (Allen and Jeffery 1990) 4 Predicted phosphorus retention index (Allen and Jeffery 1990) 5 Least significant difference at P ^ 005 6 Significance at lt 0001 () lt 001 () lt 005 () level or not significant (ns)
The use of Red Mudgypsum in vegetable production
100
o CO
gtlaquo
C
o CO
bull-raquo
c o o o
20 40 60 80 100 120 140
Residual AG (tha) 0 100 200 300 400 500 600 700
Residual P (kgha)
Figure 63 (A B) Bicarbonate extractable P (bull) K (bull) and total P (A) in the subsoil (0-15 cm) of a yellow Karrakatta sand after harvest of cauliflowers with level of residual Alkaloamreggypsum (t AGha) (A) and P (kgha) (B) Vertical bars refer to Lsd (P lt 005) for difference between level of AG or P Lsd not shown when less than size of symbol
Ec pH (CaCl2) and exchangeable Ca and Na in the top and subsoil after harvest increased significantly with level of residual AG whilst there was no change in exchangeable Mg (Table 64 (a) (b)) Whilst there was no change in exchangeable K with level of residual AG in the topsoil there was a significant increase in exchangeable K in the subsoil (Table 64 (b))
70
The use of Red Mudgypsum in vegetable production
Table 64 Ec (mSm) pH (CaCl2) and exchangeable cations (me) in topsoil (0-15 cm) and subsoil (15-30 cm) of a yellow Karrakatta sand with level of residual AIkaloamreggypsum (AG) and phosphorus (P) after harvest of cauliflowers
(a) Topsoil (0-15 cm)
AG
AG Ec pH Ca1 Mg1 K1 Na1
(tha) (mSm) (CaCl2) (me) (me) (me) (me)
0 29 65 24 027 006 004
60 47 73 32 025 009 010
90 59 77 36 023 015 015
120 66 78 40 025 012 018
Lsd2 07 07 06 005 006 001
Sig3 as ns
P (kgha)
Ec (mSm)
PH (CaCl2)
Ca1
(me) Mg1
(me) K1
(me) Na1
(me)
0 43 73 30 025 001 011
25 46 73 33 026 010 011
50 46 73 32 025 010 011
100 52 74 32 025 010 011
300 56 74 34 024 009 011
600 58 73 37 025 014 012
Lsd2 05 05 03 002 007 -
Sig3 ns ns ns
Exchangeable in 1 m NILt-Cl 2 Least significant difference at P ^ 005 3 Significance at lt 0001 () lt 001 () lt 005 () level or not significant (ns)
The use of Red Mudgypsum in vegetable production
soil b
A soil
dry
4 _ I dry
I ^5 CD CD
b_ 3 - E c c o o CO at
i
U o CD CD
Xgt j a CO bull| mdash CO CD ogt
m- mdashM- mmdash JZ 0 - +~ -- mdash c CJ o X X LU
i 1 I i i i i LU
0 20 40 60 80 100 120 1^ W
Residual AG (tha)
100 200 300 400 500 600 700
Residual P (kgha)
Figure 64 (A B) Exchangeable Ca (bull) Mg (bull) K (A) and Na ( bull ) (me) in the topsoil (0-15 cm) of a yellow Karrakatta sand with level of residual Alkaloamreggypsum (t AGha) or P (kgha) Vertical bars refers to Lsd (P lt 005) for differences in concentration between levels of AG or P Lsd not shown when less than size of symbol
72
The use of Red Mudgypsum in vegetable production
Table 64 Ec (mSm) pH (CaCl2) and exchangeable cations (me) in topsoil (0-15 cm) and subsoil (15-30 cm) of a yellow Karrakatta sand with level of residual AlkaIoamreggypsum (AG) and phosphorus (P) after harvest of cauliflowers
(b) Subsoil (15-30 cm)
AG
AG Ec pH Ca1 Mg1 K1 Na1
(tha) (mSm) (CaCl2) (me) (me) (me) (me)
0 34 66 24 026 006 005
60 50 75 33 024 008 010
90 64 78 38 023 01 016
120 68 79 41 024 01 019
Lsd2 05 01 07 006 001 003
Sig3 ns
P (kgha)
Ec (mSm)
pH (CaCl2)
Ca1
(me) Mg1
(me) K1
(me) Na1
(me)
0 48 75 30 023 009 011
25 51 74 33 026 009 011
50 50 75 34 025 008 013
100 61 75 35 026 008 013
300 57 75 34 022 007 013
600 58 73 38 024 008 013
Lsd2 08 01 04 003 001 003
Sig3 ns
1 Exchangeable in 1 m NH4-CI 2 Least significant difference at P ^ 005 3 Significance at lt 0001 () lt 001 () lt 005 () level or not significant (ns)
The use of Red Mudgypsum in vegetable production
o 0 oi
4 CO c CO
gt T3 4 _ bull o
0s -5 3 agt CD
fc_ 3 - g
on
o 2 CO 2 CO
u 2
o CD CD 1 X I SI
1 CD 1 CD CD CU
O
n ^ 1 CO n X bull mdashXmdash mdash 1 1 CO U J= n bull - w 1 CO U
o o X X Lil
i i 1 1 i i 1 HI
0 20 40 60 80 100 120 140
Residual AG (tha)
100 200 300 400 500 600 700
Residual P (kgha)
Figure 64 (C D) Exchangeable Ca (bull) Mg (bull) K (A) and Na (T) (me) in the subsoil (0-15 cm) of a yellow Karrakatta sand with level of residual Alkaloamreggypsum (t AGha) or P (kgha) Vertical bars refers to Lsd (P lt 005) for differences in concentration between levels of AG or P Lsd not shown when less than size of symbol
As level of residual P increased there was a significant increase in exchangeable Ca in the tbpsoil and subsoil but no significant effect on exchangeable Mg K and Na in the topsoil and variable effects on exchangeable Mg and K in the subsoil Ec increased significantly with level of residual P in both the top and subsoil whilst pH in either was effected little by level of applied P
The effect of level of residual AG andP on the concentration of nutrients in cauliflower leaves
The level of residual AG had no effect on the concentrations of N Ca S P S Mg Fe Zn Mn B and Cu in the youngest mature leaves of cauliflowers at buttoning but increased levels significantly reduced the concentration of K (Fig 65 (A B)) As level of residual P increased there was a significant increase in the concentration of K P S Cu and Mn in the YMLs whilst concentrations of N decreased and B concentrations were variable with no clear trends
74
The use of Red Mudgypsum in vegetable production
Table 65 Concentration of nutrients (dry weight basis) in youngest mature leaves of cauliflowers at buttoning with level of applied residual Alkaloamreggypsum (AG) and phosphorus (P)
(a) Macronutrients
AG
AG N1 K1 Ca2 S2 P1 Na2 Mg2
(tha) () () () () () () ()
0 49 42 23 077 040 039 027
60 51 40 23 078 042 036 025
90 51 39 23 079 043 036 025
120 49 39 24 078 042 036 025
Lsd3 03 02 08 009 007 010 004
Sig4 ns ns ns ns ns ns
P N1 K1 Ca2 S2 P1 Na2 Mg2
(kgha) () () () () () () ()
0 53 36 22 069 027 033 024
25 51 38 24 071 030 038 026
50 52 40 24 075 034 040 027
100 51 41 24 079 043 041 027
300 48 43 24 087 055 039 026
600 47 42 20 086 060 031 023
Lsd3 02 02 04 003 004 006 003
Sig4 ns ns
1 After Varley (1966) 2 After McQuakerefl (1979) 3 Least significant difference at P lt 005 4 Significance at lt 0001 () lt 001 () lt 005 () level or not significant (ns)
The use of Red Mudgypsum in vegetable production
Table 65 Concentration of nutrients (dry weight basis) in youngest mature leaves of cauliflowers at buttoning with level of applied residual AlkaIoamreggypsum (AG) and phosphorus (P)
(b) Micronutrients
AG
AG (tha)
Fe (ugg)
Zn1
(Pgg) Mn1
(ugg) B1
(ugg) Cu1
(ugg)
0 122 31 19 21 28
60 121 32 22 22 30
90 119 36 25 22 32
120 120 29 23 22 29
Lsd2 21 8 6 1 05
sig3 ns ns ns ns ns
P (kgha)
Fe1
(Pgg)
Zn1
(ugg) Mn1
Gigg)
B1
(Fgg)
Cu1
(Pgg)
0 112 33 19 22 28
25 120 32 22 22 29
50 125 32 21 23 29
100 132 38 24 23 31
300 129 30 25 22 32
600 106 29 23 21 32
Lsd2 19 6 3 1 03
Sig-3 ns ns
After McQuaker et al (1979) 2 Least significant difference at P ^ 005 3 Significance at lt 0001 () lt 001 () lt 005 () level or not significant (ns)
The relationship between residual P ie Colwell P and P in YMLs at buttoning were best described by Mitscherlich relationships at all levels of residual AG (Fig 65)
The concentration of P in YMLs corresponding to levels of Colwell P necessary for 95 of maximum yield were 047 050 054 and 048 and for 99 of maximum yield were 053 055 058 and 054 for 0 60 90 and 1201 residual AGha respectively
76
The use of Red Mudgypsum in vegetable production
Q
en
3
gt-c 0
07
06
05
04
03
02
01 0
065
060
055
050
045
040
035
030
025
020
A
if 20 40 60 80 100
Colwell P (ugg dry soil)
_ 065
Q S 055
060
tz
ro _ i
gt
120
C bull - - - mdash bull
20 40 60 80 100
Colwell P (ugg dry soil)
120
050
045
040
035
030
025
020
065
060
055
050
045
040
035
030
025
020
-B
bull
- bull I
I I
bull
i i i
20 40 60 80 100
Colwell P (ugg dry soil)
120
-bull D
I I i i i
20 40 60 80 100
Colwell P (ugg dry soil)
120
Figure 65 P in youngest mature leaves at buttoning () corresponding to Colwell P necessary for 95 (dashed) or 99 (whole) of maximum yield at 0 (A) 60 (B) 90 (C) and 120 (D) t of residual Alkaloamreggypsumha Dashed and whole horizontal lines refers to P in YML corresponding to Colwell P required for 95 and 99 of maximum yield respectively
The equations for the fitted lines are
A y = 05964 - 0763 x exp (-0068) (B2 = 089)
B y = 05855 - 05144 x exp (-00465x) (R2 = 098)
C y = 006058 - 0549 x exp (-00435x) (B2 = 096)
D y = 06399 - 05208 x exp (-00291) (R2 = 097)
77
The use of Red Mudgypsum in vegetable production
The effect of level of residual AG andP on the yield of cauliflowers
There was no significant effect of levels of residual AG on the total or marketable yield of cauliflowers However yield responded significantly to levels of applied residual P and the interaction between residual P and AG was significant (Tables 66 (a) (b))
The relationship between Colwell P and total yield was best described by Mitscherlich relationships for all levels of residual AG (Fig 66) The Colwell P required for 95 of maximum total yield was 26 40 48 and 40 ugg dry soil and for 99 35 55 71 and 58 ugg dry soil for 0 60 90 and 1201 residual AGha respectively
Table 66 Curd yield (total and marketable) of cauliflowers (tha) at harvest with level of residual Alkaloamreggypsum (AG) and phosphorus (P)
(a) Total
AG p
(kgha) (tha) p
(kgha)
0 60 90 120
0 59 64 69 100
25 134 126 123 83
50 139 133 117 143
100 163 200 164 177
300 203 236 198 204
600 215 237 208 194
Ls-d1 36 (AG) 17 (P) 48(AGP) -
Sig2 ns
(b) Marketable
p (kgha)
AG (tha) p
(kgha)
0 60 90 120
0 14 14 18 56
25 83 74 84 13
50 90 99 67 99
100 138 188 125 160
300 187 232 182 190
600 206 234 191 185
Lsd1
Sig2
48 (AG)
ns 23 (P)
62(AGP)
-
Least significant difference at P lt 005 2 Significance at lt 0001 () lt 001 () lt 005 () level or not significant (ns)
The use of Red Mudgypsum in vegetable production
0 20 40 60 80 100120140160
Colwell P (ugg dry soil)
0 20 40 60 80 100120140160
Colwell P (ugg dry soil)
lt x
UJ gt-Q
o
lt X
Q _ l UJ gt-Q rr D O
24
22
20
18
16 14
12
10
8
6
4
-D
bull
I I
I I
I I
I
^~ bull
i i i i i
20 40 60 80 100120140160
Colwell P (ugg dry soil)
20 40 60 80 100120140160
Colwell P (ugg dry soil)
Figure 66 Colwell P in topsoil (0-15 cm) at planting versus yield of cauliflowers at 0 (A) 60 (B) 90 (C) and 120 (D) tha of residual Alkaloamreggypsum (AG) Dashed and whole vertical lines represent Colwell P required for 95 and 99 of maximum yield respectively
The equations for the fitted lines are
A y = 2088 - 818 x exp (-017x) (i2 = 089)
B y = 23731 - 4578 x exp (-00949) (i2 = 099)
C y = 2051 - 286 x exp (-00697) (R2 = 086)
D y = 2002 - 354 x exp (-0090) (B2 = 086)
79
The use of Red Mudgypsum in vegetable production
Discussion
There was no significant reduction in maximum yield (ie A values) of cauliflower (cv Plana) curds grown on Karrakatta sands amended with residual AG from 0 to 120 tha in this work This is in contrast to previous work (Robertson et al 1994) in which maximum curd yields of cauliflowers were significantly reduced with levels of residual AG at 120 tha compared with 0 and 60 tha In both studies concentrations of K were reduced and concentrations of Na were increased in the YML at buttoning with increasing levels of residual AG The increase in concentration of Na and the decrease in concentration of K in the YML with level of applied AG was related to similar changes in the concentrations of these elements in the soil solution with both freshly-applied (Section 5) and residual AG one month after planting As with freshly-applied AG increasing levels of residual AG resulted in increasing levels of Na in the soil (exchangeable) or soil solution however whilst K concentrations in soil solution decreased the K retained by the soil measured as either Colwell K or exchangeable K increased Increasing levels of residual AG resulted in increased pH in the topsoil as with fresh AG but this did not reduce the concentration of Mn Cu and Zn in the YML or increase the concentration of Mo These changes would be expected with increases in soil pH (Porter 1984) The level of Colwell P required for 95 to 99 of maximum yield increased from 26 and 35 ugg dry soil at 01 AGha to 48 and 71 ugg at 901 of residual AGha The level at 1201 AGha was slightly lower ie 40 and 58 ugg These levels are similar to those reported as necessary for 95 and 99 of maximum yield of Arfak cauliflowers 40 and 55 ugg Colwell P in planted in autumn and spring on unamended Karrakatta sands (McPharlin et al 1995) It therefore does not appear that AG amendment increases the residual P as measured by Colwell P requirement of cauliflower significantly This is in contrast to the significantly higher level of applied P necessary to maximise yield when AG is freshly-applied ie from 120-160 to gt 300 kg of Pha at 0 and 1201 AGha respectively (Robertson et al 1994 and Section 5) However requirements of residual (Colwell) P and freshly-applied P are not always correlated For example the Colwell P necessary for the maximum yield of spring and winter-planted lettuce was similar ie 80 to 120 ugg dry soil whereas the level of freshly-applied P required for maximum yield of winter-planted lettuce was 50 higher than in spring (McPharlin et al 1996 McPharlin and Robertson 1997)
References
Allen DG and Jeffery RC (1990) Methods for analysis of phosphorus in Western Australian soils Chemistry Centre of Western Australia Report of Investigation No 37
Barrow NJ (1982) Possibility of using caustic residue from bauxite for improving the chemical and physical properties of sandy soils Australian Journal of Experimental Agriculture Research 33 275-285
Colwell JD (1963) The estimation of phosphorus fertiliser requirements of wheat in southern New South Wales by soil analysis Australian Journal of Experimental Agriculture Animal Husbandry 3 190-197
Gillman GP and Sumpter EA (1986) Modification to the compulsive exchange method for measuring exchange characteristics of soils Australian Journal of Soil Research 24 616
McArthur WM and Bettenay E (1960) The development and distribution of the soils of the Swan Coastal Plain Western Australia CSIRO Division of Soils Soils Publication No 16
McPharlin IR Jeffery RC and Pitman DH (1996) Phosphorus requirements of winter planted lettuce (Lactuca sativa L) on a Karrakatta sand and the residual value of phosphate as determined by soil test Australian Journal Experimental Agriculture 36 887-903
80
The use of Red Mudgypsum in vegetable production
McPharlin IR Jeffery RC and Weissberg R (1994) Determination of the residual value of phosphate and soil test phosphorus calibration for carrots on a Karrakatta sand Communications in Soil Science Plant Analysis 25 (5-6) 489-500
McPharlin IR and Robertson WJ (1997) Response of spring-planted lettuce (Lactuca sativa L) to freshly-applied and residual phosphorus and to phosphate fertiliser placement on a Karrakatta sand Australian Journal of Experimental Agriculture (in press)
McPharlin IR Robertson WJ Jeffery RC and Weissberg R (1995) Response of cauliflower to phosphate fertiliser placement and soil test phosphorus calibration on a Karrakatta sand Communications in Soil Science and Plant Analysis 26(3-4) 607-620
McQuaker NR Brown DF and Kluckner PD (1979) Digestion of environmental materials for analysis by inductively coupled plasma-atomic emission spectrometry Analytical Chemistry 51 1082-1084
Novoa R and Loomis RS (1981) Nitrogen and plant production Plant and soil 58 177-204
Ozanne PG and Shaw TC (1968) Advantages of recently developed phosphate sorption test over the older extractant methods for soil phosphate (ed JW Holmes) pp 273-280 In Transactions of the 9th International Congress of Soil Science Volume 2 Angus and Robertson Sydney Australia
Porter WM (1984) Soil acidity Agriculture Western Australia Farmnote No 6884
Robertson WJ McPharlin IR and Jeffery RC (14) Final report of investigation into the use of gypsum-amended Red Mud as a soil-amendment on horticultural properties on the Swan Coastal Plain Report to HRDC (Project No V0039RO) Department of Agriculture Western Australia
Varley J A 1966 Automatic methods for the determination of nitrogen phosphorus and potassium in plant material Analyst 91 119-126
Vlahos S Summers KJ Bell DT and Gilkes RJ (1989) Reducing phosphorus leaching from sandy soils with Red Mud bauxite processing residues Australian Journal of Soil Research 27 651-662
Yuen SH and Pollard AG (1954) Determination of nitrogen in agricultural material by the Nessler reagent IL Microdetermination in plant tissue and soil extracts Journal of Science Food Agriculture 5 364-369
The use of Red Mudgypsum in vegetable production
7 RETENTION LEACHING AND RECOVERY OF P AND OTHER NUTRIENTS BY CARROTS GROWN ON A JOEL SAND AMENDED WITH RESIDUAL RED MUD (ALKALOAMreg)GYPSUM (AG) IN LARGE POTS
Introduction
It is difficult to quantify the retention of P by sands amended with Red Mud (Alkaloamreg)gypsum (AG) in the field because of native P in the soil and soluble P in the AG (Robertson et al 1994) It is easy to quantify leaching of P and other nutrients such as N and K from AG amended sands in pots or columns by collecting leachate and measuring concentration (McPharlin et al 1995) However plants were not grown in the columns used by McPharlin et al so there was no measurement of plant uptake of P and other nutrients to complete the nutrient budget Potatoes were grown successfully in Spearwood sands in large pots (70 L) and a complete N budget (N applied N retained by soil N leached and uptake by plant) determined (Hegney et al 1996)
Freshly-applied AG may not be in equilibrium with the soil to which it is applied ie the pH Ec and concentrations of elements such as Ca and Na may change rapidly with time The age of the AG may effect its capacity to retain P on amended soils AG may improve the retention of other nutrients such as ammonium N (McPharlin et al 1995) and K (Sections 5 and 6) by amended sands AG which has been applied to sands in the field for at least 2 to 5 years should be close to equilibrium with the soil as substantial leaching would have occurred AG of this age would give the best estimate of its long term capacity to reduce leaching of P and other nutrients from poor grey sands on the Swan Coastal Plain The purpose of this work was to quantify the leaching and retention of P and other nutrients (N Ca K etc) from Joel sands which had been amended with AG at different levels in the field for 14 years Carrots a major vegetable crop grown on the Swan Coastal Plain were used as the experimental crop and grown in these AG amended sands in large pots
Materials and methods
Pots
Fibreglass pots used for the experiment were 45 cm in diameter and 50 cm deep The area of soil surface was 016 m2 and the volume was 70 L The bottom of the pots tapered to a hole (diameter) to which was attached a polyethylene hose (length and diameter) and tap The pots were painted white to reduce heat The pots were placed on a metal table (with mesh tops) and the hose passed through a hole in the centre of a lid of a plastic (20 L) bucket
Experimental design
The experimental design was a 4 (levels of residual AG ie 0 125 250 and 1000 tha) times 5 (levels of applied P ie 0 50 100 200 and 400 kgha) factorial in a randomised block with 3 replicates The level of applied AG or Pha was calculated using the area of the soil surface The total number of pots was 60
Soil and Red Mud (Alkaloamreg)gypsum (AG)
Virgin Joel sand was obtained from a commercial garden supply site in Jandakot The top 20 cm of the soil was removed and the rest sieved (15 mm) to remove debris About 20 kg of Joel sand was added to each pot (10 cm depth) Another 60 kg (30 cm depth) of sand was added to the 0 AGha pots to which had been mixed lime and preplant fertilisers (see later) so the surface of the soil was about 10 cm below the top edge of the pot AG amended sand was obtained from a field site in Hope Valley Road Kwinana managed by ALCOA where it had been applied (and incorporated using a rotary hoe) to pastures growing on a Joel sand in 1983 at 0 250 500 and 1000 tha This AG amended sand was added to pots corresponding to 250 and 1000 tha in the field after the preplant fertiliser but not lime was added and was incorporated to a similar depth as in the 01 AGha pots The 125 t AGha treatment was
82
The use of Red Mudgypsum in vegetable production
obtained by mixing AG amended sand from the 250 tha field site with an equal weight of Joel sand in a cement mixer
Fertilisers and lime
The following fertilisers (in kgha) were thoroughly mixed (using a cement mixer) with the top 25-30 cm of the soil in each pot before planting Urea (108) K2SO4Q2I) MgS047H20 (100) MnS04H20 (100) Na2B4O710 H20 (50) FeS047H20 (50) CuS045H20 (50) ZnS04H20 (50) and NaMo042H20 (4) To this was added P at 0 50 100 200 and 400 kgha as single superphosphate at each level of residual AG Hydrated lime (Ca (OH)2) was mixed with the preplanting fertilisers on the 0 kg AGha treatment at 36 gpot
N K and Ca were fertigated via the drip irrigation system at 200 200 and 52 mgL using KNO3 NH4NO3 and Ca (N03)2 from immediately after sowing to 140 days after sowing (18 August 1996) MgS047H20 was broadcast at 100 kgha to each pot at weeks 6 and 12
Irrigation
The plants were irrigated using drippers (Netafim 2 Lh pressure compensated with 4 equalisers per pot) at 15 times the average monthly pan evaporation until 160 days after sowing (7 September 1996) Adjustments were made on a daily basis if evaporation was significantly higher or lower than the long term average (Table 71)
Table 71 Irrigation requirements of carrots in pot experiments
Month DAS Lpotday Minutesday
April 1- 27 10 33
May 28- 59 065 21
June 60- 90 044 14
July 91-122 044 14
August 123-154 056 19
September 155-160
Adjusted for 90 efficiency of irrigation system
Rain was excluded from the pots using a movable rain out shelter made of perspex and aluminium This was removed at all other times
Crop management
The soil in each pot was irrigated to field capacity ie so that free drainage occurred Carrot (cv Top Pak) seeds were sown on a 9 x 9 cm spacing and 1 cm deep with 5 seeds per site on 3 April 1996 These were thinned to 14 seedlingspot (88 plantsm2) after emergence (15 April 1996) No application of fungicides or insecticides were necessary
Soil and plant measurements
Soil
Immediately before fertilising and sowing 5 cores (22 diameter x 15 cm deep) were taken from each pot and dried in a force draught oven at 40degC Each sample was analysed for extractable P and K (Colwell 1963) pH (CaCl2 and H20) total P (Allen and Jeffery 1990) PRI (Allen and Jeffery 1990) total N extractable ammonium N (KC1) extractable nitrate N (KC1) organic carbon cation exchange capacity and exchangeable cations
83
The use of Red Mudgypsum in vegetable production
Leachate
Leachate from each pot was collected in 20 L plastic buckets under the pots each week from the 4 April 1996 to 22 July 1996 PMA (phenyl mercuric acetate) was added to the leachate to prevent contamination Total water volume was measured and sub-samples (200 mL) collected and submitted for analysis of P NH4-N NO3-N K Na Ca S Mg Ec and pH analysis of concentration The quantities leached of the above elements in kgha were calculated from concentration and volume of leachate collected and surface area of soil in pot
Harvest
The plants were harvested on 7 September 1997 and the total marketable and reject root yield determined for each plot
Analysis of data
Analysis of variance (Genstattrade for Windows version 32) was carried out on level of AG and P versus yield (total marketable reject) level of chemical factors in soil after harvest concentration of nutrients in youngest mature leaves at midgrowth tops and roots at harvest and leachate on 22 April 1996 5 May 1996 and 22 July 1996 and quantities of elements leached at each sampling time
Mitscherlich or linear relationships were fitted to level of P versus yield (total) at each level of residual AG P required for 95 and 99 of maximum yield was delivered at each level of residual AG P uptake by carrots was determined from the dry weight and P in tops and roots for each treatment Fertiliser P uptake was determined by deducting uptake on 0 kg Pha treatments at each level of applied AG Fertiliser P retained in the top-soil was determined from the concentration of total P and bulk density P leached was fertiliser leached below 15 cm The P in each plant fraction soil and leached was determine at each level of applied P and AG
Results
Effect of level of residual AG on chemical characteristics of Joel sand
Soil pH (CaCl2 H20) Ec Colwell P phosphorus retention index cation exchange capacity exchangeable Ca and Na and silt and clay all increased with level of residual AG in the top soil (0-15 cm) of a Joel sand before fertilising and sowing (Table 72)
The use of Red Mudgypsum in vegetable production
Table 72 Chemical and physical characteristics of Joel sand amended with residual Alkaloam gypsum (AG) in pots before fertilising and sowing of carrots
Level of residual AG
Parameter (tha)
Parameter
0 125 250 1000
pH (H20) 69 77 85 86
pH (CaCl2) 57 71 78 78
Ec (mSm) 4 9 9 11
Ext P (ngg)1 3 9 14 9
PRI2 -02 33 44 77
Total N ()3 - 0039 0044 0060
ExtNH4-N(ngg)4 - 2 2 2
ExtN03-N(ugg)5 - 3 2 5
CEC ()6 30 30 43 35
Exch Ca ()7 133 363 51 70
Exch Mg ()7 036 024 015 021
Exch Na ()7 005 015 015 032
Exch K ()7 007 004 0035 0035
OrgC()8 131 109 092 103
Sand () 977 967 960 910
Silt () 13 15 15 37
Clay () 10 23 25 53
1 Colwell (1963) 2 Phosphorus retention index (Allen and Jeffery 1990) 3 KjeldahlReardon et al 1966 4 Extracted in 1 m KC1 (Reardon et al 1966) 5 Extracted in 1 m KC1 (Best 1976) 6 Gillman and Sumpter (1986) 7 Exchangeable in 1 m NHU-Cl 8 Walkley and Black (1934)
Level of residual AG had no effect on levels of extractable NH4-N NO3-N exchangeable Mg and K or organic carbon After harvest levels of Colwell P K total P PRI Ec pH (CaCk) exchangeable Ca Mg K and Na in the topsoil (0-15 cm) all increase significantly (P lt 005) with level of residual AG (Tables 73 74)
85
The use of Red Mudgypsum in vegetable production
Table 73 Extractable P K NH4 total P (tot P) and phosphorus retention index (PRI) of the topsoil (0-15 cm) of a Joel sand after harvest of carrots with level of residual Alkaloamreggypsum (AG) and phosphorus (P)
AG
AG BicP1 BicK tot P2 PRI3 NIL (tha) (ngg) (Hgg) (ngg) (mLg) (Mfig)
0 33 119 234 -015 137
125 200 117 743 141 27
250 275 197 1258 231 19
1000 204 420 1853 154 30
Lsd5 4 34 129 45 26
Sig6
P
P (kgha)
BicP1
(ngg) BicK1
(Mgfe) totP2
(ugg) PRI3
(mLg) NIL
(ngg)
0 91 215 896 198 58
50 151 223 937 138 54
100 144 226 1005 126 62
200 182 193 1043 128 42
400 323 210 1231 116 52
Lsd5 48 39 144 50 29
Sig6 s | e ns ns
1 Colwell 1963 2 Allen and Jeffery 1990 3 Phosphorus retention index (Allen and Jeffery 1990) 4 Extracted in 1 m KC1 (Best 1976) 5 Least significant difference at P s 005 6 Significance at lt 0001 () lt 001 () lt 005 () level or not significant (ns)
By contrast levels of extractable NH4-N decreased significantly with level of residual AG Colwell P total P Colwell K all increased significantly (P lt 005) with level of applied P whilst PRI was decreased significantly Level of applied P had no significant effect on Ec pH or level of exchangeable Ca Mg K Na Colwell K or extractable NHu-N in the topsoil after harvest (Tables 73 74)
The use of Red Mudgypsum in vegetable production
Table 74 Ec (mSm) pH (CaCl2) and exchangeable cations (me) in topsoil (0-15 cm) of a Joel sand after harvest of carrots with level of residual Alkaloamreggypsum (AG) and phosphorus (P)
AG
AG Ec pH Ca1 Mg1 K1 Na1
(tha) (mSm) (CaCl2) (me) (me) (me) (me)
0 157 44 18 016 026 010
125 147 54 23 014 026 015
250 217 66 40 017 041 027
1000 308 76 135 027 096 094
Lsd2 32 01 07 002 005 005
sig3
p
p (kgha)
Ec (mSm)
pH (CaCl2)
Ca1
(me) Mg1
(me) K1
(me) Na1
(me)
0 202 59 52 019 048 035
50 195 60 53 018 050 036
100 203 60 57 019 048 039
200 202 60 57 018 045 040
400 236 59 51 017 046 034
Lsd2 35 01 08 002 006 005
Sig3 ns ns ns ns ns ns
Exchangeable in 1 m NH4CI 2 Least significant difference at P s 005 3 Significance at lt 0001 () lt 001 () lt 005 () level or not significant (ns)
Effect of level of residual AG and P on concentration of nutrients in leachate and quantities of nutrients leached
There was a significant (P lt 005) reduction in concentration of P in leachate with level of residual AG at three times of sampling (Fig 71) P concentration in leachate increased significantly with level of applied P at 01 AGha but not in presence of AG
P concentration in leachate at 01 AGha decreased with time from 80 mgL on 16 April 1996 at 400 kg Pha to 025 mgL on 22 July 1996 To reduce P concentration in leachate 125 t AGha was as effective as 250 or 1000 tha at all sampling times and levels of applied P Similar trends were shown in quantity of leached P as total or soluble reactive P in kgha (Appendix 71 (b) 72) Level of applied AG significantly (P lt 005) reduced the concentration of NH4-N in leachate from 40 mgL at 01 AGha to 15 mgL at 250 and 1000 tha (Fig 72 (a)) on 16 April 1996 Significant reductions in concentration were recorded on the other two sampling times as NH4-N concentration declined with increased plant uptake Similar trends were shown in the quantity of NH4-N leached with level of AG (Appendix 72 (b)) By contrast level of applied AG had no significant effect on concentration of NO3-N in leachate or quantity leached at any of the three sampling times (Fig 72 (b) and Appendix 73 (b)) There was a significant (P lt 005) reduction in concentration of K in leachate and quantity of K leached with level of residual AG although the reduction was less at the later sampling times (Fig 73 Appendix 73 (a)) Concentration of K in leachate increased
87
The use of Red Mudgypsum in vegetable production
with time at all levels of residual AG except 1000 tha By contrast both the concentration of Na in leachate and quantity of Na increased with level of residual AG to a maximum at the highest level (1000 tha) There was a reduction in Na concentration in leachate with time at level of residual AG lt 1000 tha The concentration of Ca in leachate increased significantly (P lt 005) as did quantity leached with level of residual AG and with time at all levels of AG (Fig 74 Appendix 74 (a)) By contrast concentration of Mg in leachate and quantity leached decreased significantly (P lt 005) with level of residual AG and with time at all levels of AG (Fig 78 and Appendix 78 (a)) There was a significant (P lt 005) increase in S concentration in leachate and quantity leached with level of residual AG at the first sampling time a decrease at the second and a increase up to 250 tha at the third sampling (Fig 79 Appendix 79 (a)) S concentration in leachate and quantity leached varied significantly with level of applied P at all sampling times and decreased with time from 16 April 1996 to 22 July 1996 (Fig 79 and Appendix 79 (a))
The use of Red Mudgypsum in vegetable production
deg E
c o
o O
c ltD
O
c o
I O
1 0 0 2 0 0 3 0 0 4 0 0
A p p l i e d P ( k g h a )
5 0 0
1 0 0 2 0 0
A p p l ie d P
3 0 0
k g h a )
4 0 0 5 0 0
1 0 0 2 0 0 3 0 0
A p p l i e d P ( k g h a
4 0 0 5 0 0
Figure 71 Concentration of P (mgL of total P) in leachate from Joel sands sown to carrots with level of applied P and Alkaloamreggypsum (AG) at 0 (bull) 125 (bull) 250 (A) and 1000 (T) tha on 16 April 1996 (A) 6 May 1996 (B) and 22 July 1996 (C) P was applied preplanting as superphosphate and carrots were sown on 3 April 1996 Vertical bars refer to Lsd (P lt 005) for differences in concentration between level of AG (at each level of P) or P (at each level of AG) or the interaction between AG and P Where bars arent shown Lsd is less than size of symbol
89
The use of Red Mudgypsum in vegetable production
2 0 0 4 0 0 6 0 0 8 0 0 1 0 0 0 1 2 0 0
L e v e l o f r e s i d u a A G ( t ha )
2 0 0 4 0 0 6 0 0 8 0 0 1 0 0 0 1 2 0 0
L e v e l o f r e s i d u a l A G ( t h a )
Figure 72 Concentration (mgL) of NBU-N (A) and NO3-N (B) in leachate from Joel sand sown to carrots amended with residual AlkaIoamreggypsum (AG) in pots on 16 April 1996 (bull) 6 May 1996 (bull) and 22 July 1996 (A) The carrots were sown on 3 April 1996 N was fertigated at a constant concentration of 300 mgL (250 mgL of NO3-N and 50 mgL NH4-N) from sowing to harvest Vertical bars refer to Lsd (P lt 005) for differences in concentration between level of AG at each sampling time Where bars arent shown Lsd is less than size of symbol
The use of Red Mudgypsum in vegetable production
200 400 600 800 1000 1200
Level of AG (tha)
200 400 600 800
Level of AG (tha)
1 0 0 0 1 2 0 0
Figure 73 Concentration (mgL) of K (A) and Na (B) in leachate from Joel sand sown to carrots amended with residual Alkaloamreggypsum (AG) in pots on 16 April 1996 (bull) 6 May 1996 (bull) and 22 July 1996 (A) The carrots were sown on 3 April 1996 K was fertigated at a constant concentration of 200 mgL from sowing to harvest Vertical bars refer to Lsd (P lt 005) for differences in concentration between level of AG at each time Where bars arent shown Lsd is less than size of symbol
91
The use of Red Mudgypsum in vegetable production
Effect of level of residual AG and P on concentration of nutrients in plants The concentration of K P Fe Cu Mn and Mo in the youngest mature leaves (YML) of carrots at midgrowth all increased significantly with level of residual AG (Tables 75 (a) (b)) The concentration of S in YML at midgrowth was significantly reduced as level of residual AG increased whilst concentrations of Ca Na Mg Zn and B were variable
Table 75 Concentration of nutrients ( dry basis) in youngest mature leaves of carrot at midgrowth with level of residual Alkaloamreggypsum (AG) and phosphorus (P)
(a) Macronutrients
AG
AG (tha)
K1 Ca2 S2 P1 Na2 Mg2
0 486 229 061 025 050 039
125 584 186 060 033 047 034
250 585 216 058 033 044 035
1000 531 215 056 031 052 037
Lsd3 03 02 004 0017 005 003
Sig4
p
P (kgha)
K1 Ca2 S2 P1 Na2 Mg2
0 538 198 062 029 037 036
50 523 222 061 028 043 037
100 562 208 056 030 049 035
200 548 216 057 032 058 037
400 563 214 056 035 054 036
Lsd3 033 022 004 002 006 003
Sig4 ns ns ns
1 After Varley (1966) 2 After McQuaker et al (1979) 3 Least significant difference at P s 005 4 Significance at lt 0001 () lt 001 () lt 005 () level or not significant (ns)
The use of Red Mudgypsum in vegetable production
Table 75 Concentration of nutrients ( dry basis) in youngest mature leaves of carrot at midgrowth with level of residual Alkaloam gypsum (AG) and phosphorus (P)
(b) Micronutrients
AG
AG (tha)
Fe Mn1 Zn B Cu Mo
0 111 386 280 345 95 21
125 127 279 367 348 107 25
250 126 173 269 349 108 24
1000 114 60 143 337 110 31
Lsd2 20 47 40 15 05 06
Sig3 ns ns
p
p (kgha) Fe Mn Zn B Cu Mo1
0 135 243 263 356 120 28
50 122 240 268 349 111 30
100 109 191 229 343 106 25
200 116 228 268 334 99 23
400 115 221 294 341 89 20
Lsd2 23 52 45 15 051 07
Sig3 ns ns ns ns
1 After McQuaker et al (1979) 2 Least significant difference at P s 005 3 Significance at lt 0001 () lt 001 () lt 005 () level or not significant (ns)
Concentration of P S and Na in YML increased significantly (P lt 005) with level of applied P whilst concentrations of Cu and Mo decreased (Tables 75 (a) (b)) By contrast concentrations of K Ca Mg Fe Mn Zn and B were not significantly changed by level of applied P
93
The use of Red Mudgypsum in vegetable production
At harvest the concentration of P N K and Fe in whole tops increased significantly (P lt 005) with level of residual AG whilst concentration of S Mn Zn and B decreased (Table 76) The concentrations of Ca Na and Mg were variable with level of residual AG whilst there was no significant effect on the concentration of Cu
Table 76 Concentration of nutrients ( dry basis) in whole carrot tops at harvest with level of residual Alkaloamreggypsum (AG) and phosphorus (P)
(a) Macronutrients
AG
AG (tha)
N1 K1 Ca2 S2 P1 Na2 Mg2
0 300 503 269 071 016 093 039
125 348 649 239 065 024 090 035
250 395 653 251 061 022 082 033
1000 351 566 262 066 024 099 037
Lsd3 010 036 011 002 001 009 002
Sig4
p
p (kgha)
N1 K1 Ca2 S2 P1 Na2 Mg2
0 355 589 240 073 019 074 035
50 343 597 258 068 020 082 036
100 339 587 257 068 021 098 038
200 339 580 259 063 022 108 037
400 332 608 263 057 024 095 036
Lsd3 011 041 012 002 001 010 002
Sig4 ns
1 After Varley (1966) 2 After McQuakere al (1979) 3 Least significant difference at P s 005 4 Significance at lt 0001 () lt 001 () lt 005 () level or not significant (ns)
The use of Red Mudgypsum in vegetable production
Table 76 Concentration of nutrients ( dry basis) in whole carrot tops at harvest with level of residual Alkaloamreggypsum (AG) and phosphorus (P)
(b) Micronutrients
AG
AG (tha)
Fe1 Mn1 Zn1 B1 Cu1
0 299 962 234 402 109
125 316 952 184 404 107
250 331 662 110 380 110
1000 374 673 77 383 115
Lsd2 90 106 20 002 05
Sig3 ns ns
p
p (kgha) Fe1 Mn1 Zn1 B1 Cu1
0 294 969 158 409 125
50 392 837 144 393 117
100 364 747 141 396 114
200 267 712 159 387 105
400 332 bull 796 154 377 89
Lsd2 101 118 23 13 05
Sig3 ns ns
1 After McQuaker et al (1979) 2 Least significant difference at P lt 005 3 Significance at lt 0001 () lt 001 () lt 005 () level or not significant (ns)
As level of applied P increased concentration of P Ca and Na in whole tops increased significantly (P lt 005) whilst concentrations of N S Mn B and Cu decreased There was no significant effect of level of applied P on concentrations of K Fe or Zn in whole tops whilst concentration of Mg was variable
Effect oflevel of residual AG and P on carrot yield
There was a significant (P lt 005) increase in total and marketable yield with level of applied P at all levels of applied AG (Table 77) The overall effect of AG was to reduce both total and marketable yield at the highest level (1000 cf 0 to 2501 AGha) especially at low levels of applied P (ie 0 to 50 kg Pha) At higher levels of applied P yield at 2501 AGha was not significantly (P lt 005) lower than at 125 tha
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The use of Red Mudgypsum in vegetable production
However at 10001 AGha total and marketable yield was significantly lower than 0 tha at all levels of applied P The relationship between level of applied P and total yield was described as linear at 0 250 and 10001 AGha and Mitscherlich at 125 AG tha (Fig 76) As yield did not maximise at 0 250 and 1000 t AGha no optimal level of applied P for 95 or 99 of maximum yield could be determined At 125 t AGha the level of applied P necessary for 95 and 99 of maximum yield was 182 and 314 kg Pha respectively
Effect of level of AG and P on efficiency of P recovery by plants and retention in soil
The proportion () of P recovered in the carrot roots and tops decreased with level of applied P increasing from 8 to 12 to 5 to 8 of depending on level of AG (Table 78) There was a reduction in P recovered in roots tops and whole plant as level of AG increased For example P recovered by whole plants at 01 AGha at 400 kg Pha was 8 but this had declined to 5 at 10001 AGha
Table 78 The of applied fertiliser P taken up by carrots grown in pots (tops roots) retained in the topsoil or leached with level of residual Alkaloamreggypsum (AG) and phosphorus (P) on a Joel sand
P in Fraction AG P ( of P applied )
(tha) (kgha) TopsA Roots2 Plant(A+B) Soil2 Leached3
0 50 2 9 11 3 86
0 100 2 8 10 13 77
0 200 2 6 8 2 90
0 400 2 6 8 3 89
125 50 4 8 12 73 15
125 100 2 8 10 18 72
125 200 2 6 8 30 62
125 400 1 4 5 18 77
250 50 3 7 10 0 90
250 100 2 4 6 0 94
250 200 1 4 5 0 95
250 400 1 4 5 12 83
1000 50 2 6 8 75 17
1000 100 2 5 7 67 26
1000 200 2 5 7 45 48
1000 400 1 4 5 41 55
P in fraction expressed as of P applied as fertiliser 2 P retained in topsoil (0-15 cm) 3 P leached below 15 cm
By contrast of applied P retained in topsoil varied with level of AG For example only 3 of P was retained in topsoil at 400 kg Pha and 01 AGha where as this had increased to 41 at 10001 AGha at the same level of applied P Consequently the of P leached decreased as level of AG increased For example at 01 AGha and 400 kg Pha nearly 90 of applied P leached below 15 cm This had been reduced to 55 at 10001 AGha and the same level of applied P
97
The use of Red Mudgypsum in vegetable production
Table 79 Fertiliser P leached (kgha) and P leached as a of P applied from a Joel sand sown to carrots with level of residual Alkaloam gypsum (AG) and P after harvest The P was then applied as superphosphate prior to planting The carrots were sown on 3 April 1996 P leached is expressed as a percentage of P applied
AG (tha)
P (kgha)
P leached1
(kgha) P leached
( P applied)
0 50 41 82
0 100 78 78
0 200 158 79 0 400 311 78
125 50 2 4
125 100 3 3
125 200 10 5 125 400 27 7
250 50 1 2
250 100 3 3 250 200 4 2
250 400 7 2 1000 50 02 lt1 1000 100 05 lt1
1000 200 1 lt1
1000 400 2 lt1
1 Fertiliser P leached = total P leaclied - P leached at 0 kg Pha (ie background P) 2 (Fertiliser P leachedP applied x 100)
The use of Red Mudgypsum in vegetable production
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0 2 0 0 4 0 0 6 0 0 8 0 0 1 0 0 0 1 2 0 0
L e v e l o f r e s i d u a l A G ( t h a )
Figure 74 Concentration (mgL) of Ca (A) and Mg (B) in leachate from Joel sand sown to carrots amended with residual Alkaloamreggypsum (AG) in pots on 16 April 1996 (bull) 6 May 1996 (bull) and 22 July 1996 (A) The carrots were sown on 3 April 1996 Ca was applied preplanting as superphosphate and fertigated at a constant concentration of SO mgL from sowing to harvest AG was applied preplanting and in weeks 6 (15 May 1996) and 12 (25 June 1996) Vertical bars refer to Lsd (P lt 005) for differences in concentration between level of AG at each time Where bars arent shown Lsd is less than size of symbol
99
The use of Red Mudgypsum in vegetable production
CD
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c o
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c CD O c o O
0 2 0 0 4 0 0 6 0 0 8 0 0 1 0 0 0 1 2 0 0
L e v e l of r e s i d u a l A G ( t ha )
0 100 2 0 0 3 0 0 4 0 0
L e v e l of r e s i d u a l P ( k g h a )
5 0 0
Figure 75 The concentration of S (mgL) in leachate from Joel sands sown to carrots with level of residual Alkaloamreggypsum (AG) (A) and P (B) on 16 April 1996 (bull) 6 May 1996 (bull) 22 July 1996 (A) The carrots were sown on 3 April 1996 S was applied preplanting as K2S04 and in superphosphate Vertical bars refer to Lsd (P lt 005) for differences in concentration between level of AG (A) or P (B) at each sampling time Where bars arent shown Lsd is less than size of symbol
100
The use of Red Mudgypsum in vegetable production
ID
0 100 200 300 400 500
Applied P (kgha)
lb 70
70 C
60 65 -
60
55 dt
ha 50
40
50
45 bull A
Yie
30
40 _ 20
35 i i i i 35 0 100 200 300 400 5( 50 10
Applied p (kgha)
0 100 200 300 400 500
Applied P (kgha)
0 100 200 300 400 500
Applied P (kgha)
Figure 76 Total yield of carrots with level of freshly-applied P at four levels of residual Alkaloamreggypsum (AG) (A B C D = 01252501000 tha) Vertical dashed and whole lines refer to applied P necessary to 95 (dashed) or 99 (whole) of maximum yield respectively
The equations of the fitted lines are
A y = 10943 - 9377 x exp (-00053) (R2 = 099)
B y = 6l7- 2848 x exp (-00122) (i2 = 099)
C y = 3842+ 0083x (J2 = 097)
D y = 238 + 0l07x(R2 = 096)
As level of applied P increased concentration of P Ca and Na in whole tops increased significantly (P lt 005) whilst concentrations of N S Mn B and Cu decreased There was no significant effect of level of applied P on concentrations of K Fe or Zn in whole tops whilst concentration of Mg was variable
101
The use of Red Mudgypsum in vegetable production
Discussion
The addition of residual Alkaloamreggypsum (AG) resulted in a significant reduction in the concentration of P NH4-N K and Mg in the leachate from Joel sands sown to carrots in large pots The reduction in P concentration is attributed to an increase in the level of iron and aluminium oxides when AG is applied to soils low in these minerals (Barrow 1982) Consequently all soil measurements of P status or retention such as total P Colwell P and phosphorus retention index as well as Ec and pH all increased with level of applied residual AG Similar reductions in phosphorus leaching or increases in P retention have been reported when Gavin (Vlahos et al 1989) or Joel (Sections 4 and 5 McPharlin et al 1994 Robertson et al 1997) sands were amended with fresh or residual AG (Sections 4 and 6 Robertson et al 1994)
The reduced leaching of cations such as NH4-N K and Mg is attributed to an increase in captain exchange capacity (CEC) when sands of low CEC are amended with AG (Barrow 1982 McPharlin et al 1994) Consequently NO3-N retention is not increased when soils are amended with residual (Fig 72) or freshly-applied AG (McPharlin et al 1994) The increased leaching of Na Ca and S from amended sands is attributed to the Alkaloamreg as a source of these elements either in the Alkaloamreg itself (Na2C03) or after amendment with gypsum (CaS042H20) which precipitates CaC03 and Na2S04 The Na2S04 is very soluble as is easily leached whereas Ca is only slightly soluble as gypsum and insoluble as lime Vlahos et al (1989) reported increased leaching of Na Ca and S from Gavin sands treated with copper as (FeS04) amended Alkaloamreg compared with unamended controls in the short term and a decrease in the longer term Concentrations of P in the YML at midgrowth or tops at harvest increased with level of applied P and also with level of residual AG from 025 at 0 t AGha to 031 at 10001 AGha By contrast freshly-applied AG reduced the concentration of P in the YML from 043 on unamended to 030 on amended Joel sands (Robertson et al 1997) Even at the highest level of applied P the concentration of P in the YML 035 was still lower than that shown to be necessary for maximum yield of carrots (ie 038 McPharlin et al 1992) This could explain why the yield wasnt maximised in three out of the four AG treatments On the treatment that yield was maximised 125 t AGha the highest concentration of P ie 038 was recorded The difference in trends of P in petioles with AG between the 2 studies could be explained in terms of the relative leaching of P or addition of P in the AG itself On the virgin Joel sand used in the pot study leaching of P was significant enough to reduce leaf P in the unamended versus amended treatments For example the P in YML was significantly lower in the 01 AGha than at all other levels of residual AG at all levels of applied P up to 200 kgha For example the P in YML at 01 AGha ranged from 020 to 027 at 0 and 200 kg Pha respectively whilst at 125 t AGha the P was 032 to 038 over the same levels of applied P (Appendix 71) This suggests that loss of P from the top soil is severely limiting the uptake of P by the plant in the absence of AG The phosphorus retention of virgin Joel sands is almost negligible with a PRI of close to 0 (Table 72 McPharlin et al 1994 Robertson et al 1997) By contrast the P retention of Joel sands appears to be increased following development possibly by the addition of iron in irrigation water and organic and inorganic fertilisers For example the estimate of PRI (PREM) ie PRI plus P as Colwell P measured in the developed Joel sands used by Robertson et al was 40 in the topsoil (0-15 cm) of the unamended treatment Thus in these soils P retention is high enough to reduce availability when AG is added and explains the reduced levels of P in the YML as level of AG is increased The contribution of AG to the P nutrition of the plant is an unlikely explanation as it didnt increase P levels in the plant when applied fresh (Robertson et al 1997)
Previous work showed that concentrations of K in the petioles of potatoes (Section 4 Robertson et al 1997) and youngest mature leaves in cauliflower (Robertson et al 1994 Sections 5 and 6) declined with level of freshly-applied and residual AG
With potatoes the decline in K concentrations was associated with a decrease in K concentration in the soil solution and an increase in Na concentrations in soil solution and petioles on fresh and residual AG treatments (Section 4 Robertson et al 1997) This was
102
The use of Red Mudgypsum in vegetable production
used to explain yield reductions on fresh AG sites at gt 60 tha or on residual sites at 240 tha With cauliflower the findings were variable Where yield was reduced (Robertson et al 1994) it could not be explained in terms of K nutrition as K concentrations in the YML did not decline to levels expected to result in deficiency In follow up work neither fresh or residual AG up to 240 tha resulted in yield reduction although there was a reduction in K concentrations in the YML but not below critical levels (Sections 5 and 6) By contrast concentrations of K in the YML of carrots increased with level of residual AG up to 1000 tha as did exchangeable K in the soil Similar increases in K concentration in YML of Chinese and Head cabbage with level of AG on Joel sands have been reported previously (Robertson et al 1994)
Yield response of carrots to applied P at various levels of residual AG was variable on Joel sands in this work For example yield with level of applied P reach a plateau at 125 t AGha (ie 182 and 314 kg Pha for 95 and 99 of maximum yield from the Mitscherlich regression) However at other levels of applied AG including 0 tha yield had not maximised at the highest level of applied P (400 kgha) This is surprising considering that on higher P retaining soils such as Karrakatta sands yield is maximised at much lower levels of applied P (ie 160 to 180 kgha) at a similar low P soil test (McPharlin et al 1992 1994) in the absence of AG Also on Joel sands yields of carrots at medium to low P soil test (16 to 20 ugg Colwell P) only 50 kg Pha was necessary for maximum yield (McPharlin et al Lantkze and McPharlin unpublished data) The only possible explanation is that leaching of P was significant enough in the absence of AG that increased levels of applied P were required to satisfy crop requirements The increase in P fertiliser requirement as level of applied AG increases as shown in this work above 125 tha is similar to that reported previously for Chinese and Head cabbage cauliflower lettuce onions (Robertson et al 1994) and potatoes (Robertson et al 1997) It is explained by increased P retention capacity of the soil when AG is applied and measured by PRI Colwell and Total P and similar measurements
References
Allen DG and Jeffery RC (1990) Methods for analysis of phosphorus in Western Australian soils Chemistry Centre of Western Australia Report of Investigation No 37
Barrow NJ (1982) Possibility of using caustic residue from bauxite for improving the chemical and physical properties of sandy soils Australian Journal of Agricultural Research 33 275-285
Best EK (1976) An automated method for the determination of nitrate-nitrogen in soil extracts Queensland Journal of Agriculture and Annual Science 33 161-166
Colwell JD (1963) The estimation of phosphorus fertiliser requirements of wheat in southern New South Wales by soil analysis Australian Journal of Experimental Agriculture and Animal Husbandry 3 190-197
Hegney M A McPharlin IR and Jeffery RC (1997) Response of winter-grown potatoes (Solanum tuberosum L) to freshly-applied and residual phosphorus on a Karrakatta sand Australian Journal of Experimental Agriculture 37 131-137
McPharlin IR Alymore PM and Jeffery RC (1992) Response of carrots (Daucus carota L) to applied P and P leaching on a Karrakatta sand under two irrigation regimes Australian Journal of Experimental Agriculture 32 225-232
McPharlin IR Jeffery RC and Weissberg R (1994) Determination of the residual value of phosphate and soil test phosphorus calibration for carrots on a Karrakatta sand Communications in Soil Science and Plant Analysis 25 (5-6) 489-500
103
The use of Red Mudgypsum in vegetable production
McPharlin IR Robertson WJ Jeffery RC and Weissberg R (1995) Response of cauliflower to phosphate fertiliser placement and soil test phosphorus calibration on a Karrakatta sand Communications in Soil Science and Plant Analysis 26(3amp4) 607-620
McQuaker NR Brown DF and Kluckner PD (1979) Digestion of environmental materials for analysis by inductively coupled plasma-atomic emission spectrometry Analytical Chemistry 51 1082-1084
Reardon J Foreman JA and Serai RL (1966) New reactants for the determination of ammonia Clinica Chemica Acta 14 403-405
Robertson WJ McPharlin IR and Jeffery RC (1994) Final report of investigation into the use of gypsum-amended Red Mud as a soil-amendment for horticultural properties on the Swan Coastal Plain Final Report of HRDC Project No V0039 RO
Robertson WJ Jeffery RC and McPharlin IR (1997) Residues from bauxite-mining (Red Mud) increase phosphorus retention of a Joel sand without reducing yield of carrots Communications in Soil Science and Plant Analysis 28 (13 amp 14) 1059-1079
Varley JA (1966) Automatic methods for the determination of nitrogen phosphorus and potassium in plant material Analyst 91 119-126
Vlahos S Summers KJ Bell DT and Gilkes RJ (1989) Reducing phosphorus leaching from sandy soils with Red Mud bauxite processing residues Australian Journal of Soil Research 27 651-662
Walkley A and Black I (1934) An examination of the Degtjareff method of determining soil organic matter and a proposed modification of the chromic acid titration method Soil Science 37 29-38
Yuen SH and Pollard AG (1954) Determination of nitrogen in agricultural material by the Nessler reagent II Micro determination in plant tissue and soil extracts Journal of the Science of Food and Agriculture 5 364-369
104
The use of Red Mudgypsum in vegetable production
CO JC
5)
CD
sz o CD CD
0 200 400 600 800
Level of residual AG(tha)
1000 1200
Appendix 71 (b) P leached (kgha) from Joel sands sown to carrots amended with residual Alkaloanrgypsum (AG) in pots on 16 April 1996 (week 3) (bull) 6 May 1996 (week 6) (bull) and 22 July 1996 (week 16) ( bull ) P was applied preplanting as superphosphate and carrots were sown on 3 April 1996 Vertical bars refer to Lsd (P lt 005) for differences in quantities of P leached between level of AG (across all levels of applied P) at each sampling time Where bars arent shown Lsd is less than size of symbol Data from Appendix 71 (a)
105
The use of Red Mudgypsum in vegetable production
200 400 600 800
Level ofresidual AG(tha)
1 000 1 200
2 00
18 0 -
~ 160
copy
deg 1 40
1 2 0
100 -
80 200 400 600 800
Level of residual AG (tha)
1000 1200
Appendix 73 (b) 74 (b) Ammonium-N (A) and Nitrate-N (B) leached (kgha) from Joel sands sown to carrots amended with residual Alkaloamreggypsum (AG) in pots on 16 April 1996 (week 3) (bull) 6 May 1996 (week 6) (bull) and 22 July 1996 (week 16) (A) N was fertigated postplanting as NH4-N and NO3-N and carrots were sown on 3 April 1996 Vertical bars refer to differences in quantities of N leached between level of AG (across all levels of applied P) at each sampling time Where bars arent shown Lsd is less than size of symbol Data from Appendices 73 (a) 74 (a)
106
The use of Red Mudgypsum in vegetable production
A 1 8 0
1 6 0
1 4 0
1 2 0 -
1 0 0
8 0
6 0 -
4 0 - I~~ - ^ gt ^
2 0
I
^ - ^ 1 0
I i i i i i
2 0 0 4 0 0 6 0 0 8 0 0
L e v e l o f r e s i d u a l AG (th a )
1 0 0 0 1 2 0 0
2 0 0 4 0 0 6 0 0 8 0 0
L e v e l o f r e s i d u a l A G ( t h a )
1 0 0 0 12 00
Appendix 75 76 K (A) and Na (B) in leachate from Joel sand sown to carrots amended with residual Alkaloamreggypsum (AG) in pots on 16 April 1996 (week 3) (bull) 6 May 1996 (week 6) (bull) and 22 July 1996 (week 16) (A) The carrots were sown on 3 April 1996 K was fertigated at a constant concentration of 200 mgL from sowing to harvest and Na was a constituent of AG Vertical bars refer to Lsd (P lt 005) for differences in quantities of K and Na leached between level of AG (across all levels of applied P) at each time Where bars arent shown Lsd is less than size of symbol
107
The use of Red Mudgypsum in vegetable production
40
ha
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30 bull o
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^ 1 5
1 0
5
200 400 600 800 1000 1 2 0 0
L e v e l of r e s i d u a l AG ( t ha)
200 4 0 0 600 800 1000 1 2 0 0
L e v e l of r e s i d u a l AG ( t ha)
Appendix 77 78 Ca (A) and Mg (B) in leachate from Joel sand sown to carrots amended with residual Alkaloamreggypsum (AG) in pots on 16 April 1996 (bull) 6 May 1996 (bull) and 22 July 1996 (A) The carrots were sown on 3 April 1996 Ca was applied preplanting as superphosphate (and as a constituent of AG) and fertigated at a constant concentration of 50 mgL from sowing to harvest Mg was applied preplanting and in weeks 6 (15 May 1996) and 12 (25 June 1996) Vertical bars refer to Lsd (P lt 005) for differences in quantity of Ca and Mg leached between level of AG (across all levels of applied P) at each sampling time Where bars arent shown Lsd is less than size of symbol Data from Appendices 77 (a) and 78 (a)
108
The use of Red Mudgypsum in vegetable production
200 400 600 800
Level of residual AG(tha)
1000 1200
Appendix 79 S (mgL) in leachate from Joel sands sown to carrots with level of residual Alkaloamreggypsum (AG) 16 April 1996 (week 3) (bull) 6 May 1996 (week 6) (bull) 22 July 1996 (week 16) (A) The carrots were sown on 3 April 1996 S was applied preplanting as K2S04 in superphosphate and as a constituent of AG Vertical bars refer to Lsd (P lt 005) for differences in quantity of S leached between level of AG (A) or P (B) at each sampling time Where bars arent shown Lsd is less than size of symbol Data from Appendix 79 (a)
109
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The use of Red Mudgypsum in vegetable production
2 PROJECT STAFF
Ian McPharlin
Wendy Robertson
Bob Jeffery
Tony Shimmin
Jenny Harboard
Don Glenister
Patricia Aylmore
David Cooling
Gavin dAdhemar
Neil Lantzke
John Ferguson (Manager) and staff
Staff
COLLABORATORS AND ACKNOWLEDGMENTS
Project Manager and Principal Investigator
Research Officer
Project Collaborating Scientist (Chemistry Centre of WA)
Project Technical Officer
Project Laboratory Technician (Chemistry Centre of WA)
Residue Development Manager (Alcoa of Australia)
Environmental Scientist (Alcoa of Australia)
Senior Consultant Residue (Alcoa of Australia)
Technical Officer Medina Research Centre (for technical assistance and management of field and pot experiments)
Horticultural Extension Officer (for extension advice)
Medina Research Centre (for management of field experiments)
Chemistry Centre of WA (for advice of on soil plant and leachate chemistry)
4
The use of Red Mudgypsum in vegetable production
3 PUBLICATIONS ARISING OUT OF WORK Robertson WJ McPharlin IR and Jeffery RC (1997) The growth nutrition and
composition of potatoes (Solarium tuberosum L) cv Delaware grown on a yellow Karrakatta sand amended with freshly-applied and residual Alkaloamreggypsum Australian Journal of Experimental Agriculture (submitted)
McPharlin IR dAdhemar G and Shimmin TR (1997) The response of cauliflowers (Brassica oleraceae L) cv Plana to freshly-applied and residual Alkaloamreggypsum and phosphorus on a Karrakatta sand Australian Journal of Experimental Agriculture (in prep)
McPharlin IR Shimmin TR and dAdhemar G (1997) Leaching of P N and cations from carrots grown on Joel sands amended with residual Alkaloamreggypsum Communications in Soil Science and Plant Analysis (in prep)
The use of Red Mudgypsum in vegetable production
4 RESPONSE OF POTATOES TO FRESHLY-APPLIED AND RESIDUAL RED MUD (ALKALOAMreg)GYPSUM AND PHOSPHORUS ON A YELLOW KARRAKATTA SAND
Introduction
Previous work has shown that freshly-applied Alkaloamreggypsum (gypsum-amended red mud 10 ww) (AG) at 60 and 120 tha reduced the total yield of potatoes by 7 and 23 respectively compared with 01 AGha controls (Robertson et al 1994 Appendix 1 J) The reduction in marketable yield was almost identical to the reduction in total yield The exact cause of this reduction in yield could not be determined particularly the reduction at 120 tha It was unlikely to be a reduced availability of P Observations on commercial properties suggest that AG which has been in the soil for several seasons does not cause yield reductions in potatoes
Phosphorus was banded at planting in this experiment Subsequent work (Hegney and McPharlin unpublished data) showed that broadcasting P allowed a greater maximum yield of potatoes than banding P on Karrakatta sands of low P fertility
This experiment re-examines the response of potatoes to freshly-applied AG using broadcast P and also the effect of residual AG on growth of potatoes at unlimiting P
Materials and methods
Site characteristics
The experiment was conducted on a yellow Karrakatta sand (described by McArthur and Bettenay 1960) at Medina approximately 30 km south of Perth Two sites were used a site where pasture species had been grown several years earlier and to which no AG had ever been applied and a second (adjacent) site where AG had been applied approximately 2J2 years earlier A lettuce and a cauliflower crop had been grown previously on this site after AG amendment (Robertson et al 1994 Appendix 1H I)
Red Mud (Alkaloamreg)gypsum (AG)
Red Mud (Alkaloamreg)gypsum (10 ww) (AG) was produced by the dry mix process by ALCOA of Australia Ltd at their Kwinana Residue Treatment Plant It was spread manually on the previously unamended site on 22 December 1994 and was incorporated to a depth of approximately 30 cm using a rotary hoe The AG on the previously-amended site (residual AG) was applied using the same techniques on 24 November 1992 The freshly-applied AG was watered for 1 hour three times a week until planting
Experimental design
The freshly-applied and residual AG sites were used for separate experiments which were conducted simultaneously The experiment on the freshly-applied AG was a split-plot randomised complete block design with three replicates Main plots were levels of AG (0 60 90 and 120 tha) and sub-plots were levels of P application (0 25 50 100 300 and 600 kgha) Main plots measured 48 x 21 m and sub-plots measured 24 x 7 m (three rows of potatoes with 08 m between row centres) There was a 2 m buffer around each main plot The experiment on the residual AG site was a randomised complete block design with 4 levels of AG (0 60 120 and 240 tha) and three replicates The levels of AG were applied in November 1992 and had had several levels of P applied to them in the previous crops The AG plots measured 6 x 12 m but only an area of 34 x 8 m (4 rows of potatoes with 08 m between row centres) was cropped to allow a buffer of 1 to 2 m all around the planted area
6
The use of Red Mudgypsum in vegetable production
Crop management Both sites were initially sprayed with Roundupreg (3 Lha) to kill weeds and the sites were hoed with a rotary hoe Freshly-applied AG was applied at this stage The residual AG site was treated with metham sodium approximately two weeks before planting Potatoes cv Delaware were planted on both sites on 18 May 1995 using a single row mechanical planter Round seed was used and this was dusted with Rizolexreg (2 kgt) immediately before planting Sets were planted 15 cm apart The crops were irrigated using impact sprinklers once daily at 80 of Class A pan evaporation between planting and emergence and then at 100 of evaporation Afalonreg (15 kgha) was applied after planting and Sprayseedreg (2 Lha) was applied at 5 emergence both for weed control Nitofol (700 rnLha) was used for regular insect control Bravoreg (2 Lha) was applied every seven days from the time of 50 ground cover until blight symptoms appeared at which time it was then alternated with Rovralreg (2 Lha) at 7 day intervals Both crops were harvested on 15 November 1995
Fertilisers
Pre-planting fertilisers were broadcast by hand on 15 May 1995 on freshly-applied AG and on 16 May on residual AG These were 83 kg Kha as K2S04 10 kg Mgha as miso47H20 and a complete trace element mix containing (kgha) MnS04H20 (504) MgS047H20 (560) borax (336) FeS047H20 (336) CuS045H20 (336) ZnS04H20 (280) and Na2Mo042H20 (224) Single superphosphate (91 P) was broadcast by hand at 0 to 600 kg Pha on freshly-applied AG according to the treatment and at 600 kg Pha on all plots on residual AG Post-planting fertilisers were a total of 500 kg Nha as NH4NO2 and KN02 and 400 kg Kha as KN02 in equal amounts for 10 weeks via the irrigation system An extra 50 kgha MgS04 was applied in weeks 7 and 9
Measurements
(a) Plant
The petioles of the Youngest Mature Leaf (YML) often plants were collected at the S2 stage (longest tuber 10 mm long) (19 July 1995) on both freshly-applied and residual AG They were dried in a forced draught oven at 70degC and then analysed for P N K Na Ca Mg S B Cu Fe Mn and Zn On freshly-applied AG tubers were harvested from a 5 m length of the middle row of each plot On residual AG a 4 m length of the two middle rows of each plot was harvested Tubers were separated into the following size grades lt 30 g 30-80 g 80-250 g 250-450 g and gt 450 g Tubers between 30 g and 450 g were considered marketable except if they were green or damaged
Of the tubers in the 80-250 g category ten were sampled from each plot for P analysis They were washed in tap water and sliced thinly with a stainless steel knife Fresh and dry weights were measured before the tubers were analysed for total P
(b) Soil
All 0 kg Pha plots on freshly-applied AG were sampled to 15 cm depth (15 cores per plot) on 29 August (approximately 3 months after planting) They were analysed for Bicarbonate-extractable P (Bic-P) (Colwell 1963) total P EC pH (H20) pH (CaCl2) Phosphorus Retention Index (PRI) (Allen and Jeffery 1990) and P buffering capacity (Ozanne and Shaw 1968) Before fertilisers were applied to the residual AG site on 16 May 15 cores (0-15 cm) were sampled from each plot and analysed for Bic-P and PRI Residual AG plots were sampled again on 29 August (0-15 cm 15 cores per plot) and analysed for pH (H20) pH (CaCl2) EC and P buffering capacity All residual AG plots and 0 100 and 600 kg Pha freshly-applied AG plots were sampled to three depths (0-15 15-30 and 30-45 cm) (20 cores per plot) on 5 December (ie after harvest)
7
The use of Red Mudgypsum in vegetable production
Chemical analysis
Plant samples were ground to pass through a 1 mm screen after drying Concentrations of P N K and Na were measured by digesting the samples with sulphuric acid and hydrogen peroxide (Yuen and Pollard 1954) N and P were determined colorimetrically by indophenol blue and molybdo-vanadate methods respectively K and Na were determined by flame photometry All analysis was conducted on a 4-channel Auto-analyser system using modifications of Technicon procedures (Anon 1977) Samples for analysis of Ca Mg S Cu Fe B Mn and Zn concentrations were digested with nitricperchloric acids (McQuaker et al 1979) Concentrations were measured by inductively-coupled plasma atomic emission spectrometry (ICP-AES) Concentrations of heavy metals were determined using inductively-coupled plasma mass spectrometry (ICP-MS) with indium as an internal standard Samples were initially crushed in an agate mortar and digested using nitric and perchloric acids
All soil samples were dried at 40degC in a forced draught oven Lumps of AG and fertiliser in samples were crushed and the samples were thoroughly mixed and sieved to lt 2 mm before analysis The pH (H20) and the EC were determined on a 15 soilwater extract after shaking for 1 hour The pH (CaCl2) was determined on 15 soiksolution extract using 001 M CaCl2 after shaking for 1 hour Values for both are corrected to 25 degC Total P was determined on a Kjeldahl digest of a separate sub-sample of soil ground to less than 015 mm The concentration of phosphate was measured by the method of Murphy and Riley (1962)
Statistical analysis
All data were analysed by an Analysis of Variance (ANOVA) using Genstat v 50 Results from the two experiments were analysed separately Data from the freshly-applied AG site was analysed by a two-way ANOVA on level of Alkaloamreg and level of applied P while data from residual Alkaloamreg were analysed by a one-way ANOVA on level of AG Statistical differences were determined using a Least Significant Difference at 5 level of significance where the F value from the ANOVA was significant Mitscherlich curves were fitted to all relationships between level of applied P and yield petiole or tuber P concentration or total P uptake Maximum values of Mitscherlich equations were compared using a 5 t-test Linear relationships were fitted to the yield response on residual Alkaloam versus level of AG and also to the relationship between yield and petiole P concentration on freshly-applied AG
The amount of fertiliser P retained was calculated by subtracting total P at 0 kg Pha from the measured total P value Concentrations of P in ugg were converted to kilograms per hectare by multiplying by a factor of 225 This is based on the assumption that there are 2250 t soilha in the top 15 cm of soil
Results and discussion
Soil characteristics
The pH (H20) of the top 15 cm of soil at mid-growth when no P fertiliser was applied increased from 72 on unamended soil to 84 and 85 on amended soil (Table 41) EC also increased from 5 mSm on unamended soil to 8 and 9 mSm on amended soil (Table 41) Bic-P was approximately 10 ugg at all AG levels and total P ranged from 55 ugg on unamended soil to 76 ugg at 901 AGha (Table 41) PRI and P buffering capacity (Pbug) both increased between unamended and amended soil but there were no differences between levels of AG on amended soil PRI of amended soil was 26 to 30 and Pbuff was 24 to 30 (Table 41)
The Bic-P and PRI measurements taken two days before planting on residual AG were the same at all levels of AG Bic-P was 16 to 21 ugg and PRI was 37 to 53 (Table 42) On the other hand Pbuff measured mid-growth increased from 20 at 01 AGha to 30 and 40 at 120 and 2401 AGha The EC was 7-9 mSm on all treatments and pH (H20) increased between 0 and 120 t AGha from 73 to 84 (Table 42)
The use of Red Mudgypsum in vegetable production
Table 41 Characteristics of the top 15 cm of a Karrakatta sand amended with several levels of freshly-applied Alkaloamreggypsum (AG) when no fertiliser P was applied
AG (tha)
pH (H20)
pH (CaCl2)
EC (mSm)
Bic-P (ugg)
Total P (ugg)
PRI Pbuff
0 72 64 5 8 55 19 14
60 84 77 8 10 64 26 24
90 85 78 9 11 76 30 30
120 85 83 9 10 71 27 27
Signif NS NS $
Lsd 5 04 05 3 07 05
Table 42 Characteristics of the top 15 cm of a Karrakatta sand amended with several levels of residual Alkaloamreggypsum (AG) when 600 kg Pha was applied as superphosphate
AG (tha)
pH (H20)
pH (CaCl2)
EC (mSm)
Bic-Pa
(ugg) PRIa
Pbuff
0 73 67 7 16 37 20
60 78 71 5 17 40 23
120 84 77 9 20 44 30
240 88 80 9 21 53 40
Signif NS NS NS
Lsd 5 05 06 10
K Sampled and measured before application of fertiliser P
Total phosphorus in soil
Total P in the soil at harvest on freshly-applied AG increased significantly with level of AG averaged over all three depths sampled (P lt 005) It also increased with level of applied P on all levels of AG At 0-15 cm total P increased significantly between 0 and 601 AGha At 15-30 cm it increased significantly between 0 and 90 t AGha and at 30-45 cm there was no effect of level of AG at all (Fig 41) At all levels of AG and P which were sampled total P concentrations at 0-15 cm and 15-30 cm were not significantly different from each other and both were significantly greater than those at 30-45 cm (Fig 41)
In the top 15 cm of soil total P increased from 47 ugg on unamended soil to 62-67 ugg on amended soil when no fertiliser P was applied This increase represents the total P content of the AG itself When 100 kg Pha was applied total soil P (0-15 cm) increased from 63 ugg at 01 AGha to 83 ugg at 601 AGha and 95 and 103 ugg at 90 and 1201 AGha (Fig 41) When the increase due to the AG itself is considered this is an increase in fertiliser P retention of 6 ugg (26 kgha) between 0 and 601 AGha and a further 14 ugg (62 kgha) between 60 and 120 t AGha At 600 kg Pha the increase in fertiliser P retention was 35 ugg (15 kgha) between 0 and 601 AGha and 25 ugg (11 kgha) between 60 and 120 t AGha
Total P on residual AG increased with level of AG The increase was significant between 60 and 1201 AGha only It also decreased at increasing depth As observed on freshly-applied AG total P concentrations at 0-15 cm and 15-30 cm were not significantly different from each other and were both greater than that observed at 30-45 cm (Fig 43) At 0-15 cm total P increased by 20 ugg between 0 and 601 AGha and by a further 213 ugg between 60 and 1201 AGha when 600 kg Pha was applied These values cannot be corrected for the total content of AG itself as there was no 0 kg Pha treatment
9
The use of Red Mudgypsum in vegetable production
The addition of freshly-applied AG to the soil substantially increased the theoretical ability of the soil to sorb applied P as measured by the P buffering capacity in the top 15 cm of soil However it was reduced over time as 1201 AGha was required to increase Pbuff on residual AG compared with 601 AGha on freshly-applied AG Fertiliser P retention in the top 15 cm of soil when amended with 1201 AGha was increased by 9 at 100 kg Pha and by 4 at 600 kg Pha
The effects of residual and freshly-applied AG can be compared at 600 kgha of applied P The effect of residual AG on fertiliser P retention can be estimated from measurements made on the same site at the beginning of the first (lettuce) crop In that experiment total P before the application of P fertilisers increased from 69 and 62 ugg on 0 and 601 AGha to 91 ugg on 1201 AGha and 103 ugg on 2401 AGha (Robertson et al 1994 Appendix 1H) This makes the estimated increase in fertiliser P retention (0-15 cm) 27 ugg (12 kgha) between 0 and 601 AGha and 184 ugg (81 kgha) between 60 and 1201 AGha Therefore between 60 and 1201 AGha residual AG increased fertiliser retention by approximately 7 times as much as did freshly-applied AG
Bicarbonate-extractable P (soil-test P) in soil
On freshly-applied AG there was no overall response of Bic-P to level of AG although there was an upward trend Bic-P decreased with increasing depth averaged over all treatments following the same response as total P There was an interaction between the effects of depth and level of applied P At 0 kg Pha there was no difference in Bic-P between the three depths sampled but at 100 and 600 kg Pha Bic-P concentrations at 0-15 cm and 15-30 cm were both greater than those at 30-45 cm (Fig 42) The upward trend in Bic-P with increasing level of AG was weak on soil where no P fertiliser had been applied being from 9-10 ugg at 0 and 601 AGha to 11 and 14 ugg at 90 and 1201 AGha in the top 15 cm This suggests that the AG adds little if any plant available P to the soil The amount of fertiliser P retained as Bic-P in the top 15 cm of soil when 100 kg Pha was applied increased by 8 ugg between 0 and 601 AGha and by a further 4 ugg between 60 and 120 t AGha At 600 kg Pha Bic-P retained from fertiliser increased by 34 ugg between 0 and 601 AGha and by 16 ugg between 60 and 1201 AGha
The response of Bic-P to level of residual AG and to depth was the same as for total P (Fig 43) In the top 15 cm of soil Bic-P increased by 11 ugg between 0 and 601 AGha and by 82 ugg between 60 and 1201 AGha uncorrected for the Bic-P content of the AG itself
The increase in Bic-P retention observed on amended soil at 100 kg Pha was similar to that observed at 160 kg Pha on a crop of carrots grown on a Joel sand amended with AG (Robertson et al 1997) Using the soil-test standards published by Hegney et al (1997) these increases in Bic-P will reduce the P fertiliser requirement in the following potato crop by 10 at 601 AGha and 22 at 1201 AGha
Using the Bic-P concentrations observed on the residual site at the beginning of the lettuce crop (Robertson et al 1994 Appendix 1H) the increase in fertiliser P retained as Bic-P (0-15 cm) on residual AG was 15 ugg between 0 and 601 AGha and 79 ugg between 60 and 1201 AGha This is half the increase observed on freshly-applied AG between 0 and 60 t AGha and approximately 5 times that observed on freshly-applied AG between 60 and 1201 AGha
The reduced P retention at low levels of residual AG compared with freshly-applied AG was probably because of the higher initial Bic-P levels on residual AG For both total and Bic-P it is difficult to explain why the apparent retention of fertiliser P between 60 and 120 t AGha should have been so much greater on residual than on freshly-applied AG It may have been caused by changes to the chemical properties of the AG as it aged in the ground
10
The use of Red Mudgypsum in vegetable production
Yield
Total and marketable yields on freshly-applied AG both increased with level of applied P following a Mitscherlich response (Fig 44 (a) (b)) An ANOVA did not indicate any response to level of AG in either total or marketable yields However maximum total yield on unamended soil (61 tha) was significantly greater than that on AG-amended soil - 54 to 57 tha (Fig 44 (a)) On the other hand there were no differences in maximum marketable yields Maximum marketable yield values ranged from 52 to 55 tha (Fig 44 (b)) When marketable yield was calculated as a percentage of total yield an ANOVA indicated a significant interaction between level of AG and level of applied P At 400 kg Pha marketable yield was 88 of total yield on unamended soil compared with approximately 95 on amended soil (significant according to 5 Lsd) A similar trend was observed at 600 kg Pha where marketable yield was 90 of total yield on unamended soil and 93 to 96 on amended soil
The levels of applied P required for 99 of maximum total yield were 245 222 183 and 400 kg Pha on 0 60 90 and 1201 AGha and for 95 of maximum yield were 139 130 108 and 226 kg Pha (Fig 44 (a)) A similar trend can be seen for marketable yield where 99 of maximum yield required 178 206 208 and 356 kg Pha (Fig 44 (b))
Total yield on residual AG showed an almost significant response to level of AG (P = 0067) (Fig 45) Total yield was 68 to 72 tha on 0 60 and 120 t AGha and 62 tha on 2401 AGha Marketable yield was 65 to 68 tha on 0 to 1201 AGha and 58 tha on 2401 AGha Therefore 2401 AGha appears to reduce yields even when it has been in the ground for 2 years or more and even when 600 kg Pha is applied As only one level of P fertiliser was applied it is not possible to determine the effect of residual AG on the critical levels of P application required for 99 and 95 of maximum yield
Concentration of nutrients in petioles
Phosphorus
Phosphorus concentration in petioles of the YML sampled at the S2 stage on freshly-applied AG increased with level of applied P following a Mitscherlich response (Fig 46) Maximum petiole P concentrations were approximately 12 (dry basis) on all AG levels Values at 99 of maximum petiole P concentration were 116 122 117 and 116 at 0 60 90 and 1201 AGha There was a significant interaction between levels of AG and applied P (P lt 005) At low levels of applied P (25 50 and 100 kgha) P concentrations on amended soil were significantly less than those on unamended soil but there was no difference between them at 300 or 600 kg Pha This is reflected in the levels of applied P required for 99 of maximum petiole P concentration which were 209 499 581 and 508 kg Pha at 0 60 90 and 1201 AGha This is an increase of 138 on amended soil relative to unamended soil AG at levels of between 60 and 120 tha therefore reduces the availability of P to plants As there was no difference in the maximum P concentration in petioles between amended and unamended soil a reduction in P availability to plants cannot explain the reduced maximum yield on amended soil Another factor was therefore involved in reducing maximum yield on amended soil Despite this yield difference between amended and unamended soil which was not related to differences in P concentration total yield for all AG levels combined was linearly correlated with petiole P concentration at the S2 stage (y = 256 + 274x R2 = 087) (Fig 47)
The petiole P concentration at 99 of maximum total yield was 116 109 095 and 114o at 0 60 90 and 1201 AGha At 01 AGha this was the same as 99 of maximum petiole P concentration implying that the yield response on unamended soil was controlled principally by P availability On the other hand petiole P concentrations at 99 of maximum yield on amended soil especially 60 and 901 AGha were less than 99 of maximum petiole P concentration In other words yield stopped increasing even though P concentration in the plant kept increasing This supports the previous observation that some factor other than P was limiting yield in these treatments Petiole P concentration in YMLs sampled at S2 stage on residual AG did not change with level of AG Overall mean P concentration was 12 dry
11
The use of Red Mudgypsum in vegetable production
basis This is in keeping with the results observed on freshly-applied AG at 600 kg Pha It also means that the lower yield at 2401 AGha on residual AG could not be explained by a reduced P concentration in the plant As on freshly-applied AG another factor was involved which reduced yield on amended soil although at a higher level on residual than on freshly-applied AG
Hegney et al (1997) found that maximum petiole P concentration at S2 in potatoes grown on Karrakatta sand was 114 dry basis and that 109 was required for 99 of maximum yield in good agreement with the results observed here
Other nutrients
The responses of nutrients other than P were very similar on both freshly-applied and residual AG Concentrations of K (Tables 43 45) and Zn (Fig 48 (a) Table 45) decreased as level of AG increased and concentrations of Mg Fe and Ca increased with level of AG in both experiments (Tables 43 45 Fig 48 (b)) Zn concentrations also decreased with increasing level of applied P (Fig 49 (a)) while Ca concentrations increased with level of applied P (Fig 48 (b)) Concentrations of Na also showed an upward trend on both freshly-applied and residual AG (Tables 43 45) On freshly-applied AG K concentrations decreased significantly from 119 dry basis on unamended soil to 110 at 601 AGha and to 102 at 1201 AGha (Table 43) On residual AG it decreased from 11-12 at 0-1201 AGha to 103 at 2401 AGha (Table 45) No other nutrients showed any response to level of AG although concentrations of N Mn S and B increased with level of applied P on freshly-applied AG (Table 44)
Concentrations of all nutrients except K were adequate or more than adequate for maximum yield (Maier et al 1987) on both freshly-applied and residual AG Potatoes require concentrations of approximately 12 to 14 K (dry basis) in petioles of YML for maximum yield (Maier et al 1987) On freshly-apphed AG concentrations were adequate at 01 AGha but were less than adequate on amended soil On residual AG concentrations were adequate at 0 60 and 1201 AGha but less than adequate at 2401 AGha As less than adequate K concentrations correspond with those treatments which had low yield it is likely that K concentration was the limiting factor in yield on both freshly-applied and residual AG
Uptake of K may have been reduced at higher levels of AG due to an increased Cation Exchange Capacity (Barrow 1982 McPharlin et al 1994) or to the increased soil pH (Harris 1992) The reduction in Zn availability on amended soil is most likely to be a result of the increase in soil pH due to the AG (Harter 1983)
Table 43 Concentrations of several nutrients in the petioles of the Youngest Mature Leaf of potato plants sampled at the 10 mm tuber stage at several levels of freshly-applied Alkaloamreggypsum (AG) on a yellow Karrakatta sand
AG K Na Mg Fe (tha) () () () (ngg)
0 119 018 059 382
60 110 020 065 553
90 106 021 066 597
120 102 021 069 697
Signif NS
Lsd 5 04 004 119
12
The use of Red Mudgypsum in vegetable production
Table 44 Concentrations of several nutrients in the petioles of the Youngest Mature Leaf of potato plants sampled at the 10 mm tuber stage at two levels of applied P when grown on a yellow Karrakatta sand amended with freshly-applied Alkaloamreggypsum (AG)
Applied P N S Cu Mn B (kgha) () () (ngg) (ngg) (M-gg)
0 44 028 74 293 267
600 48 032 62 342 248
Signif NS NS
Table 45 Concentrations of several nutrients in the petioles of the Youngest Mature Leaf of potato plants sampled at the 10 mm tuber stage at several levels of residual Alkaloamreggypsum (AG) on a yellow Karrakatta sand
AG N K Na Ca S Mg Cu Fe Mn Zn B (tha) () () () () () () (l-igg) (ngg) (ngg) Ws) (^gg)
0 51 116 016 23 030 050 77 453 46 96 26
60 48 127 015 21 027 045 61 457 45 67 25
120 49 120 016 26 029 051 66 643 59 59 25
240 49 103 019 29 030 067 54 977 53 53 24
Signif NS NS NS NS NS NS
Lsd5 05 04 013 164 24
Tuber P and Crop P removal P concentration in tubers
The concentration of P in tubers on freshly-applied Alkaloamreg increased with level of applied P (P lt 0001) The response at each level of Alkaloamreg was best described by a Mitscherlich curve although none of the curves reached a maximum within the range of fertiliser P levels used (Fig 49 (a)) There was a trend for an overall response to level of AG (P = 0081) P concentrations were generally higher on unamended soil than on amended soil For example at 300 kg Pha P concentration was 033 on unamended soil and 026-028 on amended soil and at 600 kg Pha P concentrations were 036 and 032-033 on unamended and amended soil respectively At P levels corresponding to 99 of maximum yield tuber P concentration was 031 024 023 and 028 at 0 60 90 and 1201 AGha
On residual AG tuber P concentration did not change with level of AG The overall mean was 036 dry basis
Total P uptake
Total P uptake by tubers on freshly-applied AG showed a significant response to level of AG (P lt 005) and level of applied P (P lt 0001) The response to applied P at each level of AG was best described by a Mitscherlich curve although as for tuber P concentration none of the curves reached a maximum within the range of P levels applied P uptake by tubers on unamended soil was significantly greater than on amended soil regardless of AG level (Lsd 5) (Fig 49 (b)) At levels of applied P corresponding to 99 of maximum yield P uptake by tubers was 113 75 75 and 95 kgha at 0 60 90 and 1201 AGha These figures are lower than results reported by Hegney et al (1997) who found a P uptake by tubers grown on yellow Karrakatta sand of 204 kgha at 99 of maximum yield even though yields were similar to those observed on unamended soil in this experiment
13
The use of Red Mudgypsum in vegetable production
Total P uptake by tubers was not significantly different between AG levels on residual AG Overall mean P uptake was 110 kgha This is different from the situation observed at 600 kg Pha on freshly-applied AG As only one level of P was applied the response curve for tuber P concentration on residual AG cannot be compared with that on freshly-applied AG It is possible that less applied P is required on residual than on freshly-applied AG to reach maximum tuber P concentration
Metals in tubers
The concentration of As in tubers harvested from freshly-applied AG showed a trend to increase with level of AG from 5 x 104 mgkg (fresh weight) on unamended soil to 8 x 104 mgkg at 60 and 901 AGha (Fig 410) Concentrations of all other metals measured showed no response to level of AG either on residual or freshly-applied AG (Table 46 47) On freshly-applied AG concentrations of Ni and Cd increased and concentrations of Cu decreased with increasing level of applied P (Table 48)
Table 46 Mean concentrations (mgkg fresh weight) of metals in tubers of potato cv Delaware harvested from a yellow Karrakatta sand amended with freshly-applied Alkaloam^gypsum (AG)
Cr Co Sn Sb Hg
mean
se
0007
61 xlO5
60 x 104
50 x 106
15 x 103
10 x 104
90 x 105
10 xlO5
34 x 104
14 x 105
Table 47 Mean concentrations (mgkg fresh weight) of metals in tubers of potato cv Delaware harvested from a yellow Karrakatta sand amended with residual Alkaloamreggypsum (AG)
Cr Co Ni Cu As Cd Sn Sb Hg Pb
mean
se
001
68X104
72xl(f 29xia5
55xia3
17x1a4
010
35xia3
L2X103
0
58xia3
17X104
LOxlO3
29X104
30X1O4
43xl05
84X1G4
ii xia5
l ixia3
70xia5
Table 48 Mean concentrations (mgkg fresh weight) of metals in tubers of potato cv Delaware harvested from a yellow Karrakatta sand amended with freshly-applied Alkaloamreggypsum (AG) at various levels of applied P
Applied P (kgha)
Ni Cd Cu
0 0006 0002 018
100 0006 0002 016
300 0007 0004 015
600 0008 0006 013
Signif
Lsd (5) 00014 0001 002
The concentrations of As observed in tubers from freshly-applied AG regardless of the level of AG were less than 10 of the legal limit (10 mgkg fresh weight NFA 1992) The concentrations of all metals measured were between 3 and 33 of those measured in potato tubers in a previous experiment (Robertson et al 1994 Appendix 1 J) The concentrations on residual AG were also lower than the concentrations previously observed in lettuce and cauliflowers on the same site (Robertson et al 1994 Appendix IH I) As different batches of
14
The use of Red Mudgypsum in vegetable production
AG were used on the two sites they cannot be compared to determine the effect of time on metal availability and uptake Overall metal uptake by potato tubers grown on AG-amended yellow Karrakatta sand does not appear to pose any greater health risk than that on unamended yellow Karrakatta sand The observed increase in As concentration in potato tubers on freshly-applied AG was probably due to the increase in soil pH with level of AG (ONeill 1990)
Conclusions
Freshly-applied AG reduces the availability of fertiliser P so that approximately 25 times the level of applied P is required on 60 to 1201 AGha relative to unamended soil in order to attain maximum P concentration in plant tissues AG at 120 tha also increases the retention of fertiliser P sufficiently to reduce fertiliser requirements for a following potato crop by approximately 20 The effect of AG on the level of fertiliser P required for 99 of maximum yield was confounded in this experiment by the decrease in maximum yield between unamended and amended soil Total yield of potatoes will be reduced on 60 tha freshly-applied AG and by 240 tha residual AG probably by a limiting concentration of K There is potential for increased levels of K fertiliser to overcome this yield reduction AG increases the proportion of yield which is marketable so that even though total yield is reduced by 60 tha of freshly-applied AG the marketable yield is not There are no apparent problems with heavy metal contents of tubers due to amendment with AG
References Allen DG and Jeffery RC (1990) Methods for analysis of phosphorus in Western
Australian soils Chemistry Centre of WA Report of Investigation No 37
Anonymous (1977) Technicon Industrial Method 334-74WB+ Technicon Industrial Systems Tarrytown NY USA
Barrow NJ (1982) Possibility of using caustic residue from bauxite for improving the chemical and physical properties of sandy soils Australian Journal of Agricultural Research 275-285
Colwell JD (1963) The estimation of phosphorus fertiliser requirements of wheat in southern New South Wales by soil analysis Australian Journal of Experimental Agriculture and Animal Husbandry 3 190-197
Glenister DJ and Thoraber MR (1985) Alkalinity of red mud and its application for the management of acid wastes Chemeca 85 109-113
Harris PM (1992) Mineral Nutrition In The Potato Crop The scientific basis for improvement 2nd edition (ed P Harris) pp 162-213 (Chapman and Hall London UK)
Harter RD (1983) Effect of soil pH on adsorption of lead copper zinc and nickel Soil Science Society of America Journal 47 47-51
Hegney MA McPharlin IR and Jeffery RC (1997) Response of winter-grown potatoes (Solanum tuberosum L) to applied and residual phosphorus on a Karrakatta sand Australian Journal of Experimental Agriculture 37 (in press)
Maier NA Williams CMJ Potocky-Pacay K Moss D and Lomman GJ (1987) Interpretation standards for assessing the nutrient status of irrigated potato crops in South Australia Technote AGDEX 262533 September 1987 Department of Agriculture South Australia
15
The use of Red Mudgypsum in vegetable production
McArthur WM and Bettenay E (1960) The development and distribution of the soils of the Swan Coastal Plain Western Australia CSIRO Division of Soils Soils Publication No 16
McPharlin IR Jeffery RC Toussaint LF and Cooper M (1994) Phosphorus nitrogen and radionuclide retention and leaching from a Joel sand amended with red mudgypsum Communications in Soil Science and Plant Analysis 25 489-500
McQuaker NR Brown DF and Kluckner PD (1979) Digestion of environmental materials for analysis by inductively coupled plasma atomic emission spectrometry Analytica Chimica 51 1082-1084
Murphy J and Riley JP (1962) A modified single solution method for the determination of phosphate in natural waters Analytica Chimica Acta 27 31-36
NFA (National Food Authority) (1992) Australian Food Standards Code June 1992 (Australian Government Publishing Service Canberra)
ONeill P (1990) Arsenic In Heavy Metals in Soils(ed BJ Alloway) pp 83-99 (Blackie Glasgow)
Ozanne PG and Shaw TC (1967) Phosphate sorption by soils as a measure of the phosphate requirement for pasture growth Australian Journal of Agricultural Research 18 601-612
Robertson WJ McPharlin IR and Jeffery RC (1994) Final Report of investigation into the use of gypsum-amended red mud as a soil-amendment on horticultural properties on the Swan Coastal Plain Agriculture WA
Robertson WJ McPharlin IR and Jeffery RC (1997) Residues from bauxite-mining (red mud) increase phosphorus retention of a Joel sand without reducing yield of carrots Communications in Soil Science and Plant Analysis (in press)
Yuen SH and Pollard AG (1954) Determination of nitrogen in agricultural materials by the Nessler reagent II Micro-determination in plant tissue and in soil extracts Journal of Food in Agriculture 5 364-369
16
The use of Red Mudgypsum in vegetable production
300
250 -
I I
200
3
60 80
AG (tha)
140
Figure 41 Total phosphorus concentration in a yellow Karrakatta sand amended with freshly-applied Alkaloamreggypsum (AG) vs level of AG when 0 (bull) 100 (A) and 600 (bull) kg Pha was applied measured at 0-15 cm () 15-30 cm (mdash) and 30-45 cm (mdash) depth Bars are Lsds at 5 level of significance
17
The use of Red Mudgypsum in vegetable production
Z3
200
180 -
160
Q- 140
ro 120 bull 4 -
O CD X 100 CD i
3 80 CO c o
pound gt v_ CO
o CQ
AG Depth
I
0 20 40 60 80 100 120
AG (tha)
140
Figure 42 Bicarbonate-extractable phosphorus concentration in a yellow Karrakatta sand amended with freshly-applied Alkaloamreggypsum (AG) vs level of AG when 0 (bull) 100 (A) and 600 (bull) kg Pha was applied measured at 0-15 cm () 15-30 cm (mdash) and 30-45 cm (mdash) depth Bars are Lsds at 5 level of significance
18
The use of Red Mudgypsum in vegetable production
700
600
500
D)
3 400
CL
oil
300 CO
200
100
100 150
A G (tha)
250
Figure 43 Total (mdash) and Bicarbonate-extractable phosphorus () concentration in a yellow Karrakatta sand amended with residual Alkaloamreggypsum (AG) when 600 kg Pha was applied measured at 0-15 cm () 15-30 cm (A) and 30-45 cm (bull) depth Bars are Lsds at 5 level of significance
19
The use of Red Mudgypsum in vegetable production
CO
2 CD
gt-
200 300 400
Applied P (kgha)
Figure 44 (a) Total yield of potatoes cv Delaware grown on a yellow Karrakatta sand amended with freshly-applied AIkaIoamreggypsum (AG) at a level of 0 (bull) 60 (A) 90 (bull) and 120 (bull) tha vs level of applied P Lines represent the level of applied P required for 99 of maximum yield Bars are Lsds at 5 level of significance
Equations are
A
B
C
D
0 tha
60 tha
90 tha
120 tha
j - 614 - 255 x exp (-00152) (JR= 092)
y = 542 - 271 x exp (-00176) (R2= 090)
y = 552 - 274 x exp (-0021) (F= 094)
y = 566 - 229 x exp (-00092) (i^= 098)
20
The use of Red Mudgypsum in vegetable production
ro
JO
gt-
100 200 300 400
Applied P (kgha)
500 600
Figure 44 (b) Total yield of potatoes cv Delaware grown on a yellow Karrakatta sand amended with freshly-applied Alkaloamreggypsum (AG) at a level of 0 (bull) 60 (A) 90 (bull) and 120 (bull) tha vs level of applied P Lines represent the level of applied P required for 99 of maximum yield Bars are Lsds at 5 level of significance
Equations are
Otha A
B
C
D
60 tha
90 tha
120 tha
y = 547 - 216 x exp (-0021) (R2^ 088)
y = 517 - 278 x exp (-0019) (R2= 090)
y = 524 - 243 x exp (-001 to) (R2= 094)
y = 530 - 218 x exp (-001 Ox) (i^= 098)
21
The use of Red Mudgypsum in vegetable production
CO
32
gt-
80
70
60
50
40
30
20
10
0 0
Marketable yield
Marketable yield
Total yield
Total yield
_L 50 100 150 200
AG (tha)
250 300
Figure 45 Total (bull) and Marketable (bull) yield of potatoes cv Delaware grown on a yellow Karrakatta sand amended with residual AIkaloamreggypsum (AG) vs level of AG 600 kg Pha was applied Bars are Lsds at 5 level of significance
22
The use of Red Mudgypsum in vegetable production
w CO CO
a gtraquo i _
C
o 00
c CD O c o o
100 200 300 400
Applied P (kgha)
500
Figure 46 Concentration (dry basis) of phosphorus in petioles of the Youngest Mature Leaf of potatoes cv Delaware grown on a yellow Karrakatta sand amended with freshly-applied Alkaloamreggypsum (AG) at 0 (bull) 60 (A) 90 (bull) and 120 (bull) tha vs level of applied P Lines represent the level of applied P required for 99 of maximum yield Bars are Lsds at 5 level of significance
Equations are
A Otha y = 117- 079 x exp (-0020) (R2 = 096)
B 60 tha y=123- 096 x exp (-000874) (R2 - 099)
C 90 tha y = 118 - 0884 x exp (-000742) (R2 = 096)
D 120 tha y= 117 - 090 x exp (-00085) (R2 = 097)
23
The use of Red Mudgypsum in vegetable production
CO
c
53
CD
gt-
00 02 04 06 08 10
Petiole P ( dry basis)
12 14
Figure 47 Yield of potatoes cv Delaware grown on a yellow Karrakatta sand amended with freshly-applied AlkaIoamreggypsum (AG) at 0 (bull) 60 (A) 90 (bull) and 120 (bull) tha vs petiole P concentration
The equation is y = 256 + 274x (ft2 = 087)
24
The use of Red Mudgypsum in vegetable production
poundgt 3
0 100 200 300 400 500 600 700
Applied P (kgha)
Figure 48 (a) Concentration of Zinc and (B) Calcium ( dry weight) in petioles of the youngest mature leaf of potatoes cv Delaware harvested from a yellow Karrakatta sand amended with freshly-applied Alkaloamreggypsum (AG) at 0 (bull) 60 (A) 90 (bull) and 120 (bull) tha vs level of applied P Bars are Lsds at 5 level of significance
25
The use of Red Mudgypsum in vegetable production
100 200 300 400 500
Applied P (kgha)
700
Figure 48 (b) Concentration of Calcium ( dry weight) in petioles of the youngest mature leaf of potatoes cv Delaware harvested from a yellow Karrakatta sand amended with freshly-applied AlkaIoamreggypsum (AG) at 0 (bull) 60 (A) 90 (bull) and 120 (bull) tha vs level of applied P Bars are Lsds at 5 level of significance
The use of Red Mudgypsum in vegetable production
040
ogt 035 CD
gtgt bullo
w _CB O
H) CL
CO 1 _ -mdashraquo c CD O c o o Q
030 -
025 -
020
2 015
010 -
005
000 0 100 200 300 400
Applied P (kgha)
500 600
Figure 49 (a) The concentration of phosphorus in tubers ( dry weight) of potatoes cv Delaware harvested from a yellow Karrakatta sand amended with freshly-applied Alkaloamreggypsum (AG) at 0 (bull) 60 (A) 90 (bull) and 120 (bull) tha vs level of applied Pkgha Bars are Lsds at 5 level of significance
Equations are
A 0 tha
B 60 tha
C 90 tha
D 120 tha
y = 0372 - 0243 x exp (-00058) (R2 = 097)
y = 0378 - 0257 x exp (-00029x) (R2 = 098)
y = 0361 - 0216 x exp (-00029x) (i^= 095)
y = 0406 - 0279 x exp (-0002x) (R2 = 098)
27
The use of Red Mudgypsum in vegetable production
CO
3
ltD
CO Q Z5
ID
B
14
12 -^ ^
10
8 W
6
4
A G P
I
2
n I i i I I i
0 100 200 300 400
Applied P (kgha)
500 600
Figure 49 (b) Phosphorus uptake Gigha) by tubers of potatoes cv Delaware harvested from a yellow Karrakatta sand amended with freshly-applied Alkaloamreggypsum (AG) at 0 (bull) 60 (A) 90 (bull) and 120 (bull) tha vs level of applied P Bars are Lsds at 5 level of significance
Equations are
Otha A
B
C
D
60 tha
90 tha
120 tha
y = 140 - 1095 x exp (-00058r) (R2 = 096)
3= 111 - 882 x exp (-0004x) (R2 = 098)
y = 104 - 774 x exp (-00053) (R2 = 099)
3 = 127 -101 x exp (-00029x) (R2 = 0997)
28
The use of Red Mudgypsum in vegetable production
60 80
AG (tha)
Figure 410 Concentration of Arsenic (dry weight) in tubers of potatoes cv Delaware grown on a yellow Karrakatta sand amended with freshly-applied Alkaloamreggypsum (AG) Bar is Lsd at 5 level of significance
29
The use of Red Mudgypsum in vegetable production
5 RESPONSE OF CAULIFLOWERS TO FRESHLY-APPLIED RED MUD (ALKALOAMreg)GYPSUM AND PHOSPHORUS ON A YELLOW KARRAKATTA SAND
Introduction
It is important to reduce the leaching of phosphorus fertiliser from sandy soils used for vegetable production into the water systems of the Swan Coastal Plain Red Mud (AlkaloamR)gypsum (AG) a waste product from bauxite refining has been suggested as an amendment to reduce phosphorus leaching from sands of the Bassendean Association (Joel Gavin) used for agriculture and horticulture (Barrow 1982)
Experimental work in the field and pots showed amendment with AG significantly reduced P leaching from Joel and Gavin sands (Vlahos et al 1989 McPharlin ei al 1994) compared with the unamended (01 AGha) treatment
In previous work freshly-applied AG at 60 tha increased the amount of freshly-applied P required for maximum yield of cauliflowers 14 (autumn planted) but did not reduce maximum yield (20 tha) compared with the unamended (0 tha) treatment on a yellow Karrakatta sand (Robertson et al 1994) At the highest rate of applied AG (120 tha) P required for maximum yield was 32 higher than at 0 tha and maximum yield was reduced 23 (P lt 005)
Since more than 60 tha of AG may be required to significantly improve P retention by sands to enable sustainable horticultural production this yield reduction is re-examined with freshly-applied AG
Materials and methods
Site characteristics
The experiment was conducted on a yellow Karrakatta sand (McArthur and Bettenay 1960) of low P fertility at Medina Research Centre (32deg 13 S 115deg 49 E) 30 km South of Perth The site had no previous history of AG application and had been sown to pasture for several years Some relevant chemical characteristics of the topsoil (0-15 cm) and subsoil (15-30 cm) of the site after application of AG but prior to the application of fertiliser and transplanting are presented in Table 51
Red Mud (AlkaIoamreg)gypsum (AG)
Alkaloamreg (Red Mud) amended with 10 (ww) gypsum (AG) was produced by the dry mix process by ALCOA of Australia Ltd at their Kwinana Residue Treatment Plant The AG was spread manually on the site and incorporated using a rotary hoe to approximately 30 cm depth on 21 February 1996 The site was watered for 1 hour per day (8 mmday) using impact sprinklers until planting
Experimental design
The experimental design was a split-plot randomised block with 3 replicates The main plots were levels of AG (0 60 120 and 240 tha) and the sub-plots were levels of freshly-applied P (0 50 100 200 400 and 600 kgha) Main plots measured 6 x 12 m and sub-plots 12 x 6 m (excluding wheel tracks)
Crop management
The site was sprayed with Roundupreg (3 Lha) twice after application of AG and prior to planting to control weeds
The use of Red Mudgypsum in vegetable production
Six week old seedlings of cauliflowers (cv Plana) obtained from a commercial nursery were transplanted manually on 18 April 1996 in 2 rows per plot with 70 cm between rows and 50 cm between plants Seedlings were dipped in Rovralreg 1 mLL just prior to planting for control of fungi Treflanreg (14 Lha) and Dacthalreg (12 kgha) were applied immediately after transplanting to control broadleaved weeds and Sertinreg later on in the life of the crop for grass control Ambushreg (100 mLha) and Rogorreg (100 mLha) were used to control caterpillars and red legged earth-mite respectively Copper sprays were used for control of blackrot The crop was irrigated to a total application equivalent to 100 of the previous days pan evaporation using minisprinklers (Legoreg 6 x 6 m spacing 44 mmh) in 3 waterings of equal duration per day
Fertilisers
Pre-planting fertilisers were broadcast manually and rotary hoed on 17 April 1996
These were K2S04(244) Ca (N03)2 4H20 (387) MgS047H20 (504) MnS04H20 (504) FeS047H20 (18) Borax (27) CuS045H20 (36) ZnSOH20 (28) and Na2Mo042H20 (2) Single superphosphate (91 P)was applied at 0 to 600 kgha according to treatment and incorporated as before Post-planting K N and Ca were fertigated via the irrigation system as KN03 NH4NO3 and Ca (N03)2 in equal amounts per day for 12 weeks to a total of 600 kg K 423 kg N and 60 kg Caha Borax was fertigated at 20 kgha in week 3 and Mg was broadcast as MgS047H20 at 50 kgha in weeks 3 6 and 9
Measurements
Soil and soil solution
All zero P subplots were sampled 30 cores per plot just prior to planting and fertilising about 2 months after AG application to 2 depths (0-15 15-30 cm) These were oven dried at 40degC and analysed for Ec pH (CaCl2) P sorption (Ozanne and Shaw 1968) bicarbonate extractable P K (Colwell 1963) total P PRI P sorption K sorption (Allen and Jeffery 1990) and cation exchange capacity (Gillman and Sumpter 1986)
The soil water was obtained by centrifugation from soil samples (0-15 cm 30 per plot) and collected from the 0 100 200 and 600 kg Pha plots across all AG treatments on 16 May 1996 The supernatant was analysed for pH Ec Ca Mg K S and P The remaining soil was analysed for pH (H20) bicarbonate extractable P and K PRI and DTPA extractable Zn After harvest on 5 August 1996 soil samples were collected from 2 depths as for the preplanting treatment from all plots These were analysed for pH bicarbonate extractable P K total P PRI and exchangeable cations (Ca Mg K and N)
Plant
At buttoning on 13 June 1996 the younger mature leaves (YML) (4th from growing point) were collected from 16 plants in each plot (excluding 1 m buffer at each end) They were dried at 70degC in a force draught oven for 48 h and ground to pass through a 1 mm screen Sub-samples were digested with sulphuric acidhydrogen peroxide (Yuen and Pollard 1954) and the concentration of N P and K measured by an automated colorimetric process (Varley 1966) Concentration of other nutrients (B Ca Na Mg S Fe Mn Zn and Cu) were determined by inductively coupled plasma atomic emission spectroscopy (ICP-AES) after digestion with nitric-perchloric acids (McQuaker et al 1979)
Five whole plants were harvested from the middle of each plot (2 per row)at the end of the experiment on 4 July 1996 using shovels to recover as much of the root system as possible The plants were separated into four categories curds leaves stems and roots All soil was washed from the roots using tap water shaken and the excess water removed using paper towels The fresh weight of all four categories was recorded and the material was diced into small pieces (lt 8 cm3) using stainless steel knives sub-samples (300 g fresh weight) were collected at random from the diced pieces and the fresh weight recorded These were dried at
31
The use of Red Mudgypsum in vegetable production
70degC in a forced draught oven for 48 h and the dry weight recorded These samples were then analysed for P as for the youngest mature leaves Separate sub-samples (300 g fresh weight) of curds were collected and analysed for Ba Cd Cr Co Pb Mo Rb Sr Ti Th V and N using inductively coupled plasma mass spectrometry (ICP-MS) The fresh and dry weight of the curds leaves stems and roots at harvest were used to calculate P uptake in kgha)
Harvest
Harvest commenced when the leaves surrounding the head opened and exposed the curds 77-80 days after transplanting At this stage florets at the periphery of the curd had just begun to separate Sixteen curds (12 plus 4 from whole plant samples above) were collected from the central 4 m of both rows (1 m buffer) and all the leaves and stems removed according to requirements for export market Each fresh curd was weighed and rejects recorded if undersize (lt 500 g) oversize (gt 2000 g) discoloured (yellowing) overmature (separation of florets in centre of curd) diseased damaged or otherwise distorted The total marketable and reject yield were recorded for each plot
Analysis of data
Analysis of variance was carried out on level of applied AG or P versus (a) chemical characteristics of soil (bicarbonate extractable P total P etc) preplanting and harvest (b) concentrations of nutrients in soil solution at midgrowth (c) concentration of nutrients in YMLs at midgrowth (d) concentration of elements in curds at harvest (e) P uptake by plant parts and (f) total marketable and reject yield of curds at harvest Mitscherlich curves and inverse polynomials were fitted to the relationship between level of applied P and yield at each level of applied AG The level of applied P required for 95 99 and 100 (in case of inverse polynomials) of maximum yield was calculated Mitscherlich curves were fitted to the relationship between level of applied P and P in YMLs at midgrowth at all levels of AG The P in YMLs corresponding to the level of applied P required for 95 99 or 100 of maximum yield (as determined from yield versus applied P plots) was then determined
Mitscherlich curves were also fitted to the relationship between level of applied P and P uptake by curds leaves stems and roots and the P uptake corresponding to whole plants (additions of all 4) level of P required for 95-100 of maximum yield determined Phosphorus uptake by plant parts or whole plants on 0 P plots were detected from P uptake at other rates to account for non-fertiliser sources of P This was used to adjust P uptake When determining P fertiliser recovery efficiency (RE) by plant parts or whole plants (ie fertiliser P uptake by plant parts or whole plantsP applied both in kgha Novoa and Loomis 1981)
Results
Effects of fresh AG on chemical characteristics of soil and soil solution
There was a significant (P lt 005) increase in the Ec pH PRI and sorption capacity (topsoil only) of the topsoil and subsoil of a yellow Karrakatta sand with level of freshly-applied AG prior to fertiliser application and planting (Table 51) There was no significant effect of level of AG on Colwell K K sorption capacity and total P with level of freshly-applied AG (Table 51)
The use of Red Mudgypsum in vegetable production
Table 51 Some chemical characteristics of the topsoil (0-15 cm) and subsoil (15-30 cm) of a yellow Karrakatta sand after application of Alkaloam gypsum (AG)1 just prior to fertiliser application and transplanting
(a) Topsoil (0-15 cm)
AG (tha)
Ec (mSm)
pH (CaCl2)
BicP2
(Vigfe)
BicK2
(pgg) PRI3
(mLg) TP4
(Pgg) CEC5
(me ) Kads6 Pads7
0 37 74 107 153 097 507 2 0 41
60 67 82 93 197 167 473 2 043 66
120 80 82 100 277 243 607 2 044 78
240 103 84 97 290 38 637 2 058 129
Lsd8 202 037 38 136 046 1010 0 049 41
Sig9 ns ns ns ns ns
(b) Subsoil (15-30 cm)
AG Ec PH BicP2 BicK2 PRI3 TP4
(tha) (mSm) (CaCl2) (Pgg) (Pgg) (mLg) (Pgg)
0 30 72 83 227 07 507
60 63 81 73 190 15 453
120 80 81 87 220 18 540
240 107 83 83 240 27 563
Lsd8 202 037 38 136 046 101
Sig9 ns ns ns
Applied 7 weeks previously 2 After Colwell (1963) 3 Phosphorus retention index after Allen and Jeffery (1990) 4 Total phosphorus 5 Cation exchange capacity (Gillman and Sumpter 1986) 6 Slope of K adsorption isotherm from the Freundlich equation (Allen and Jeffery 1990) 7 Slope of P adsorption isotherm from the Freundlich equation (Allen and Jeffery 1990) 8 Least significant difference at P lt 005 9 Significance at lt 0001 () lt 001 () lt 005 () level or not significant (ns)
There was a significant (P lt 005) increase in the concentration of Na and a decrease in the concentration of K in the soil solution with level of freshly-applied AG one month after planting and fertilising (Table 52 (a) and Fig 51) At the same time Colwell K and PRI in the topsoil increased significantly with level of freshly-applied AG By contrast there was a significant decrease in extractable Zn with level of AG The concentration of Ca Mg S and P increased significantly with level of applied P in soil solution (Table 52 (a)) Colwell P in the topsoil increased significantly with level of P whilst Colwell K PRI and extractable Zn decreased at the same time (Table 52 (b))
33
The use of Red Mudgypsum in vegetable production
Table 52 (a) Ec (mSm) pH and concentration of nutrients (pgmL) in soil solution 1 month after planting with level of freshly-applied Alkaloamreggypsum (AG)1 and phosphorus
AG
AG (tha)
Ec (mSm)
pH Ca (pgmL)
Mg (pgmL)
Na (pgmL)
K (pgmL)
S (pgmL)
P (pgmL)
Psrp2
(VigmL)
0 112 70 175 18 110 77 101 57 56
60 132 74 164 17 137 58 92 34 31
120 172 75 166 17 152 54 97 44 34
240 166 81 130 16 198 34 75 24 11
Lsd3 19 025 33 4 16 11 26 27 32
Sig4 ns ns ns ns ns
p
AG (tha)
Ec (mSm) PH
Ca (pgmL)
Mg (pgmL)
Na (pgmL)
K (pgmL)
S (UgmL)
P (pgmL)
Psrp2
(pgmL)
0 137 78 99 15 150 46 26 10 01
100 142 76 112 15 153 54 52 23 14
200 170 74 179 19 150 62 114 39 30
600 133 72 244 19 144 60 174 89 87
Lsd3 43 022 31 24 17 15 29 25 30
Sig4 ns ns ns
Applied 11 weeks previously
Soluble reactive P 3 Least significant difference at P lt 005 4 Significance at lt 0001 () lt 001 () lt 005 () level or not significant (ns)
The use of Red Mudgypsum in vegetable production
220
200
E 180 O ) 3
^ 1fi0 _ o 3 140 O V)
oil
120 m c
100 C o CO 80 c flgt o B0 c o o 40
20
0 50 100 150 200
Freshly-applied AG(tha)
250 300
Fig51 Concentration (ugml) of Na(i ) and K ( bull ) in soil solution (0-15cm) under cauliflowers one month after planting with level of freshly-applied AlkaloamRgypsum(AG) Vertical bars indicates Lsd (Plt005) for differences in concentration betweeen levels of AG
35
The use of Red Mudgypsum in vegetable production
Table 52 (b) Extractable P K Zn and phosphorus retention index of the top soil (0-15 cm) of a yellow Karrakatta sand 1 month after transplanting with level of freshly-applied Alkaloamreggypsum (AG)1 and phosphorus (P)
AG
AG (tha)
P2
(ugg) K2
(Ugg) Zn3
(Pgg)
PRI4
(mLg)
0 47 32 67 -112
60 76 38 15 -090
120 94 42 26 -049
240 84 41 13 092
Lsd5 35 6 28 073
Sig6 ns
P P2 K2 Zn3 PRI4
(kgha) (ugg) (Hgg) (Ugg) (mLg)
0 8 42 31 201 100 35 37 45 043 200 80 39 18 -089 600 177 34 26 -313
Lsd5 39 6 27 082
Sig6 ns
Applied 11 weeks previously 2 After Colwell (1963) 3 Extracted in DTPA 4 Phosphorus retention index (Allen and Jeffery 1990) 5 Least significant difference at P lt 005 6 Significance at lt 0001 () lt 001 () lt 005 () level or not significant (ns)
Ec pH exchangeable Ca K Na in me and Colwell P K total P PRI and PRIP increased significantly (P lt 005) with level of freshly-applied AG in the topsoil and subsoil of a yellow Karrakatta sand (Table 53 (a) (b) and Fig 52) at harvest
The use of Red Mudgypsum in vegetable production
o CO
CD
E
o CO
co o
CD
X co CD ogt e co sz o X HI
50 100 150 200
Freshly-applied AG (tha)
250 300
Fig52 Exchangeable Ca() NaP) and K(A) cations (me dry soil) in topsoil (0-15cm) of Karrakatta sand amended with freshly-applied AlkaloamRgypsum(AG) after harvest of cauliflowers Vertical bars indicates Lsd (Plt005) for differences in concentration between levels of AG Lsd not shown when less than size of symbol
37
The use of Red Mudgypsum in vegetable production
Table 53 Ec (mSm) pH and exchangeable Ca Mg K and Na (me ) in the topsoil (0-15 cm) and subsoil (15-30 cm) of a yellow Karrakatta sand amended with AlkaIoamreggypsum (AG) at harvest of cauliflowers
(a) Topsoil
AG Ec PH Ca Mg K Na (tha) (mSm) (CaCl2) (me ) (me ) (me ) (me )
0 67 66 229 018 005 003
60 91 77 382 019 009 02
120 99 79 558 019 012 043
240 120 80 975 024 014 104
Lsd2 20 014 064 0033 0018 021
Sig3 ns
(b) Subsoil
AG Ec pH Ca Mg K1 Na (tha) (mSm) (CaCl2) (me ) (me ) (me ) (me )
0 44 67 225 017 005 003
60 59 74 269 019 005 008
120 66 77 300 018 005 017
240 99 79 397 02 005 029
Lsd2 075 01 029 0036 001 002
Sig3 n s ns
Extracted in 1 m NH4CI 2 Least significant difference at P lt 005 3 Significance at lt 0001 () lt 001 () lt 005 () level or not significant (ns)
However there was no effect of either level of AG or P on exchangeable Mg in the soil at harvest Colwell P total P and PRIP increased significantly whilst Colwell K and PRI decreased with level of freshly-applied P in the topsoil at harvest (Table 4 (a) (b) and Fig 53)
The use of Red Mudgypsum in vegetable production
Table 54 P (extractable P total P phosphorus retention index and P sorption) in the top soil (0-15 cm) and subsoil (15-30 cm) of a yellow Karrakatta sand at harvest of cauliflowers with level of freshly-applied Alkaloamreggypsum (AG) and phosphorus (P)
(a) Topsoil
AG
AG BicP1 BicK1 TotP2 PRI3 PRIP3
(tha) (ugg) (Pgg) (Hgg) (mLg) (mLg)
0 39 23 92 -07 28
60 50 38 110 02 50
120 59 51 135 16 75
240 58 62 157 35 99
Lsd4 5 11 15 03 06
Sig5
P BicP1 BicK1 TotP2 PRI3 PRIP3
(kgha) (ugg) (Hgg) (ngg) (mLg) (mLg)
0 10 53 57 29 40
50 15 40 66 22 38
100 25 41 78 17 44
200 53 41 128 14 71
400 87 44 186 -01 86
600 120 41 226 -12 102
Lsd4 11 8 20 09 13
Sig5
1 After Colwell (1963) 2 After Allen and Jeffery (1990) 3 After Allen and Jeffery (1990) 4 Least significant difference at P lt 005 5 Significance at lt 0001 () lt 001 () lt 005 () level or not significant (ns)
39
The use of Red Mudgypsum in vegetable production
Table 54 P (extractable P total P phosphorus retention index and P sorption) in the top soil (0-15 cm) and subsoil (15-30 cm) of a yellow Karrakatta sand at harvest of cauliflowers with level of freshly-applied Alkaloamreggypsum (AG) and phosphorus (P)
(b) Subsoil (15-30 cm)
AG
AG BicP1 BicK1 TotP2 PRI3 PRIP3
(tha) (ugg) (Ugg) (Ugg) (mLg) (mLg)
0 33 20 79 -05 26
60 30 21 73 -01 30
120 33 27 77 08 42
240 26 24 76 13 40
Lsd4 10 2 10 04 10
Sig5 ns ns
P BicP1 BicK1 TotP2 PRI3 PREP3
(kgha) (ugg) (Vigg) (Ugg) (mLg) (mLg)
0 7 25 48 15 22
50 11 22 52 09 19
100 15 24 59 10 27
200 32 23 81 06 39
400 51 22 100 -03 47
600 67 21 117 -11 52
Lsd4 8 5 8 05 09
Sig5 ns
1 After Colwell (1963) 2 After Allen and Jeffery (1990) 3 After Allen and Jeffery (1990) 4 Least significant difference at P lt 005 5 Significance at lt 0001 () lt 001 () lt 005 () level or not significant (ns)
The use of Red Mudgypsum in vegetable production
100 150 200
Freshly-applied AG (tha)
300
Fig53 Concentration of total P(A) Colwell P() or K(laquo) in topsoil (0-15cm) with level of freshly-applied AlkaloamRgypsum (AG) after harvest of cauliflowers Vertical bars indicates Lsd (Plt005) for differences in concentration between levels of AG Lsd not shown when less than size of symbol
41
The use of Red Mudgypsum in vegetable production
Nutrients in leaves at midgrowth and harvest
There was a significant decrease in concentration of K and an increase in concentration of Na S Mn and Cu in youngest mature leaves (YML) of cauliflowers at buttoning with level of freshly-applied AG (Table 55) The concentration of P in YML at 01 AGha (049) was significantly higher than at 2401 AGha (044) but not at other levels Currently-applied AG had no significant effect on concentration of N Ca Mg Fe Zn or B in YML There was a significant increase in YML in the concentration of K P and S in YML with level of applied P whilst concentration of N Mg Mn and B were variable (Fig 54 55) Level of applied P had no significant effect on the concentration of Ca and Na in the YML (Table 55)
Table 55 (a) Concentration of macro-nutrients (dry weight basis) in youngest mature leaves of cauliflowers at buttoning with level of freshly-applied Alkaloamreggypsum (AG) and phosphorus (P)
AG
AG N1 K1 Ca2 S2 P1 Na2 Mg2
(tha) () () () () () () ()
0 482 393 240 081 049 036 023
60 484 383 251 084 046 040 024
120 506 357 255 081 046 045 024
240 494 355 246 088 044 056 025
Lsd3 026 012 024 005 003 006 0013
Sig4 ns ns ns ns
p
p N1 K1 Ca2 S2 P1 Na2 Mg2
(kgha) () () () () () () ()
0 523 316 254 066 024 046 025
50 489 372 255 081 041 049 026
100 503 388 229 084 048 042 024
200 472 379 250 089 050 046 024
400 494 390 242 093 057 043 023
600 470 385 258 091 057 039 022
Lsd3 027 024 036 005 003 008 0017
Sig4 ns ns
1 After Varley (1966) 2 After McQuaker et al (1979) 3 Least significant difference at P lt 005 4 Significance at lt 0001 () lt 001 () lt 005 () level or not significant (ns)
The use of Red Mudgypsum in vegetable production
0 50 100 150 200 250 300
Freshly-applied AG (tha)
Rg54 Concentration of N() K(B) and Ca(A) in youngest mature leaf (YML) at buttoning
of cauliflowers with level of freshly-applied AlkaloamRgypsum(AG) Vertical bars
indicates Lsd (Plt005) for differences in concentration between levels of AG
10
bdquo 09 lt Q OR ^ D) 07 c
tto
06 3
X3
to 05 _ l
gtbull 04 C
i3 03 c agt bull c 02 3
-z 01 0 50 100 150 200 250 300
Freshly-applied AG (tha)
Rg55 Concentration of S() Na(B) Mg(4) and P(T) in youngest mature leaf (YML) at buttoning
of cauliflowers with level of freshly-applied AlkaloamRgypsum(AG) Vertical bars indicates Lsd (Plt005) for differences in concentration between levels of AG
43
The use of Red Mudgypsum in vegetable production
The relationship between P in YML at buttoning and level of freshly-applied P was best described by Mitscherlich relationships at all levels of applied AG (Fig 56)
en c o 3
X2
gt
06
^
bull A
05 ^ S
04
03
02
01
n n i i i
0 100 200 300 400 500 600 700
Applied P (kgha)
o
X I
5 gt
06
05
04
03
02
01
00
- bull B
- bull bull ^
o
I I I I
0 100 200 300 400 500 600 700
Applied P (kgha)
100 200 300 400 500 600 700
Applied P (kgha)
100 200 300 400 500 600 700
Applied P (kgha)
Fig56 P in YML of Cauliflowers at buttoning () corresponding to applied P required for either 95 (dashed line) or 99 (whole line) of maximum yield at 0(A) 60(B) 120(C) or240(D)t of freshly-applied AlkaloamRgypsumha
The equations for the fitted lines are
A
B
C
D
y = 056 - 030 x exp (-00182) (R2 = 097)
y = 057 - 032 x exp (-00103) (R2 = 088)
y = 055 - 031 x exp (-00126) (R2 = 099)
y = 056 - 032 x exp (-00092) (R2 = 098)
The P in YML corresponding to level of freshly-applied P required for 99 of maximum yield was 053 057 055 and 055 for 0 60 120 and 240 tha respectively
44
The use of Red Mudgypsum in vegetable production
Table 55 (b) Concentration of micro-nutrients (dry weight basis) in youngest mature leaves of cauliflowers at buttoning with freshly-applied Alkaloamreggypsum (AG) and phosphorus (P)
AG
AG (tha)
Fe (Pgg)
Zn (Ugg)
Mn (vigg)
B (Pgg)
Cu1
(Pgg)
0 1354 251 217 211 26
60 1274 248 237 213 28
120 1353 253 240 217 27
240 1394 263 260 214 29
Lsd2 153 24 15 082 02
Sig3 ns ns ns
P Fe Zn Mn B Cu (kgha) (ngg) (ugg) (Pgg) (Ugg) (Pgg)
0 1418 268 212 215 26
50 1388 253 263 220 27
100 1301 267 251 217 29
200 1336 249 250 217 28
400 1282 255 232 204 28
600 1341 233 224 210 28
Lsd2 197 29 19 08 02
Sig3 ns ns ns
1 Extracted in 1 m NH4CI 2 Least significant difference at P lt 005 3 Significance at lt 0001 () lt 001 () lt 005 () level or not significant (ns)
There was a significant (P lt 005) decrease in the concentration of P Zn and an increase in the concentration of Na in whole leaves (WL) of cauliflowers with rate of freshly-applied AG at harvest (Table 56) Level of freshly-applied AG had no significant effect on concentration of N K Ca S Mg Fe Mn B or Cu Concentration of Ca S P and Na in (WL) at harvest increased significantly (P lt 005) with level of freshly-applied P whereas Zn concentrations decreased and concentrations of Mg Mn and B were variable Level of freshly-applied P had no significant effect on concentration of N K Fe or Cu in WL at harvest
45
A O O ltyi
4x
r en 00
9 400 200 o o o copy
ns
O
kgt ON
kgt
4gt
kgt 4 4 4^
kgt
ns
O 4 4 ON 4 k)
o
i mdash t mdash raquo
4 00
4 ON
4 4^ NO Q O
o copy ON
i mdash gt
b b 1 mdash t
b o p Vcopy
O 00 ON
o ON
gtmdash 5 co 5J M
o o
O in
o 4 Ncopy
o 4 O
p 4
p kgt 1 mdash t
copy
ON
o b NO
O ON
o 00
o 00
o ON I mdash
O ON
O 3 Z 5 raquoM
o b 4
O
kgt o kgt -J
p kgt 00
O kgt 00
O
kgt NO
copy kgt ON
The use of Red Mudgypsum in vegetable production
Table 56 (b) Concentration of micro-nutrients (dry weight basis) in leaves of cauliflowers at harvest with level of freshly-applied Alkaloamreggypsum (AG) and phosphorus (P)
AG
AG (tha)
Fe1
(ugg) Zn1
(vgg) Mn1
(vgg) B1
(vgg) Cu1
(vigg)
0 762 224 214 263 42
60 700 197 227 265 38
120 811 196 216 254 38
240 842 193 236 256 37
Lsd2 132 099 21 16 06
Sig3 ns ns ns ns
P (kgha)
Fe1
(pgg) Zn1
(^gg) Mn1
(Vigg) B1
(lJgg) Cu1
(Pgg)
0 786 233 213 248 36
50 625 235 241 266 37
100 833 207 237 270 41
200 938 192 235 265 44
400 725 178 208 259 37
600 765 169 206 250 37
Lsd2 230 21 21 11 063
Sig3 ns ns
After McQuaker et al (1979)
Least significant difference at P lt 005
Significance at lt 0001 () lt 001 () lt 005 () level or not significant (ns)
47
The use of Red Mudgypsum in vegetable production
Nutrients and heavy metals in curds at harvest
There was a significant (P lt 005) decrease in the concentration of K and P and an increase in the concentration of Ca and Na in the curds at harvest with level of freshly-applied AG Concentration of N Mg Fe Zn Mn B and Cu in the curds were unaffected by level of freshly-applied AG (Table 57) As level of freshly-applied P increased there was a significant (P lt 005) decrease in concentration of N S Mg Fe Zn Mn and B and an increase in concentration of K Ca P and Na in curds at harvest Concentration of Cu in curds were unaffected by level of applied P (Table 57 (b))
Table 57 (a) Concentration of macro-nutrients (dry weight basis) in curds of cauliflowers at harvest with level of freshly-applied Alkaloamreggypsum (AG) and phosphorus (P)
AG
AG N1 K1 Ca S1 P2 Na1 Mg1
(tha) () () () () () () ()
0 392 515 040 066 047 023 018
60 384 500 040 067 045 023 017
120 404 474 043 071 043 024 018
240 402 458 041 071 041 028 018
Lsd3 022 016 001 004 002 002 0006
Sig4 ns + ns ns
P
p N1 K1 Ca1 S1 P2 Na1 Mg1
(kgha) () () () () () () ()
0 496 417 034 097 031 016 019
50 400 518 043 068 040 023 018
100 376 483 042 063 042 025 017
200 372 501 044 063 047 027 017
400 371 498 042 062 052 028 017
600 358 505 041 060 052 027 016
Lsd3 027 02 003 005 002 003 001
Sig4
1 After McQuaker et al (1979) 2 After Varley (1966) 3 Least significant difference at P lt 005 4 Significance at lt 0001 () lt 001 () lt 005 () level or not significant (ns)
The use of Red Mudgypsum in vegetable production
Table 57 (b) Concentration of micro-nutrients1 (dry weight basis) in curds Cauliflowers at harvest with level of freshly-applied Alkaloam gypsum (AG) and phosphorus (P)
AG
AG (tha)
Fe1
(Ugg)
Zn1
(vigg) Mn1
(Pgg) B1
(Pgg) Cu1
(Pgg)
0 611 279 124 188 26
60 587 247 134 191 25
120 706 299 139 192 29
240 592 268 145 186 25
Lsd2 329 57 14 08 06
Sig3 ns ns ns ns ns
p
p (kgha)
Fe1
(Ugg) Zn1
(Pgg) Mn1
(Ugg) B1
(ugg)
Cu1
(Pgg)
0 976 492 156 202 31
50 520 279 145 198 26
100 507 230 135 186 24
200 432 208 127 190 24
400 739 239 131 183 28
600 567 192 120 177 24
Lsd2 270 61 142 114 061
Sig3 a s
1 After McQuaker et al (1979) 2 Least significant difference at P lt 005 3 Significance at lt 0001 () lt 001 () lt 005 () level or not significant (ns)
49
The use of Red Mudgypsum in vegetable production
Concentration of Ba in curds at harvest decreased and concentration of Ti increased significantly in curds at harvest with level of freshly-applied P (Table 58) As level of freshly-applied P increased concentrations of Pb and Rb decreased and of Sr decreased Ba concentrations were variable with level of freshly-applied P (Table 58)
Table 58 Concentration of Ba plus heavy metals1 (fresh weight basis) in curds of cauliflowers at harvest with level of freshly-applied Alkaloamreggypsum (AG) and phosphorus (P)
AG Ba Cd Cr Co Pb Ni Rb Sr Ti Th V (tha) (ngg) (ngg) (ngg) (ngg) (ngg) (ngg) (ngg) (ngg) (ngg) (ngg) (ngg)
0 797 7 34 7 13 34 590 1219 34 39 7
60 482 7 34 7 15 34 610 1146 46 52 8
120 583 7 43 7 20 34 616 1246 45 50 8
240 355 7 34 7 15 34 637 1152 41 45 8
Lsd2 141 1 13 16 11 15 74 188 5 16 1
Sig3 ns ns ns ns ns ns ns ns ns
MRL4 50 2000
P (kgha)
Ba (ngg)
Cd (ngg)
Cr (ngg)
Co (ngg)
Pb (ngg)
Ni
(ngg)
Rb (ngg)
Sr (ngg)
Ti
(ngg)
Th
(ngg)
V (ngg)
0 556 7 34 7 25 34 650 998 39 45 9
50 670 7 34 7 18 34 657 1387 50 74 9
100 576 7 34 7 11 34 570 1206 45 50 8
200 529 7 34 7 12 34 616 1293 39 39 7
400 523 7 48 7 19 39 596 1126 39 36 7
600 476 7 34 7 11 34 603 1126 36 36 7
Lsd2 121 1 16 1 15 6 40 181 19 29 2
Sig3 ns ns ns ns ns ns ns ns
MRL4 50 2000
Inductively coupled plasma mass spectrometry 2 Least significant difference at P lt 005 3 Significance at lt 0001 () lt 001 () lt 005 () level or not significant (ns) 4 Maximum residue limit
The use of Red Mudgypsum in vegetable production
P uptake by plants P uptake by whole plants or plant parts was unaffected by level of freshly-applied AG by but increased significantly with level of freshly-applied P (Table 59)
P uptake by whole plants increased from 50 kg Pha to 19 to 21 kgha at 400 to 600 kg applied Pha respectively Curd root stem and leaf uptake was 33 5 6 and 50 respectively of total plant P uptake at the highest level of applied P (Table 59)
Table 59 P uptake (kgha) by curds roots stem leaf and whole cauliflower plants at harvest with level of freshly-applied Alkaloamreggypsum (AG) and phosphorus (P)
AG
AG Curds Roots Stem Leaf Total (tha) (kgha) (kgha) (kgha) (kgha) (kgha)
0 53 074 11 87 158
60 48 066 10 83 148
120 47 069 11 79 143
240 45 060 10 74 135
Lsd1 065 015 025 21 31
Sig-2 ns ns ns ns ns
p
p (kgha)
Curd (kgha)
Root (kgha)
Stem (kgha)
Leaf (kgha)
Total (kgha)
0 12 030 040 29 49
50 40 058 100 68 124
100 51 053 112 76 143
200 59 075 120 93 172
400 67 093 131 115 205
600 61 094 121 102 185
Ls-d1 055 017 020 18 25
Sig2
1 Least significant difference at P lt 005 2 Significance at lt 0001 () lt 001 () lt 005 () level or not significant (ns)
51
The use of Red Mudgypsum in vegetable production
Yield
There was a significant (P lt 005) increase in both total and marketable curd yield with level of freshly-applied P at all levels of freshly-applied AG (Table 510) There was no significant effect of level of freshly-applied AG on either total (Table 510 (a)) or marketable (Table 510 (b)) curd yield
Table 510 Curd yield (total marketable) of cauliflowers (tha) at harvest with level of freshly-applied Alkaloamreggypsum (AG) and phosphorus (P)
(a) Total
p (kgha)
AG (tha) p
(kgha) 0 60 120 240
0 755 468 483 177
50 1464 1675 1554 1516
100 2169 1706 1757 1985
200 2242 1737 1928 1862
400 1752 2102 2155 2136
600 1689 1764 1768 2023
Lsd1
Sig2
16 (AG)
ns 201 (P)
401 (AGP)
-
(b) Marketable
p (kgha)
AG (tha) p
(kgha) 0 60 120 240
0 274 060 000 000
50 1222 1463 1294 1152
100 2057 1416 1603 1820
200 2141 1377 1803 1752
400 1572 2020 2095 1996
600 1468 1534 1500 1974
Lsd1
Sig2
24 (AG)
ns
46 (P)
52(AGP)
ns
Least significant difference at P lt 005 2 Significance at lt 0001 () lt 001 () lt 005 () level or not significant (ns)
The relationship between total yield and level of freshly-applied P was best described by a quadratic relationship at all levels of freshly-applied AG (Fig 57) As level of AG increased the level of freshly-applied P required for 99 of maximum yield increase from 124 kg Pha at 0 t AGha to 339 kg Pha at 240 tha There was no significant effect of level of freshly-applied AG on maximum curd yield (Fig 57)
The use of Red Mudgypsum in vegetable production
26
24
22
(tha
) 20
18
Cur
d yi
eld 16
14
12
10
8
6 i ii
A=0
i i i i i
I I
0 100200300400500600700
Applied P (kgha)
24 22 20 18 16 14 12 10 8 6 4 2
- 7 I
_ bull
i i i n
mdash^ B=60
I I I
0 100200300400500600700
Applied P (kgha)
co
32 CD
gt 2 3
o
25
20
15
10
5
bull j
- bull
I I I I I
- - gt C=120
l l l
0 100200300400500600700
Applied P (kgha)
0 100200300400500600700
Applied P (kgha)
Fig57 Total curd yield (tha) of cauliflower with level of freshly-applied Alkaloam gypsum and
phosphorus (ABCD = 060120240 tha) Vertical lines represent applied P necessary
for either 95 (dashed) or 99 (whole) of maximum yield
The equations for the fitted lines are
A y = 1336 + (-577 + 01335x)(l-00088x +000007872) (Z2
B y = 89434 + 00705 - OOOOlx2 (R2 = 070)
C y = 84752 + 00810 - OOOOlx2 (B2 = 081)
D y = 733 +00871x - 00001 Ix2 (R2 = 099)
098)
53
The use of Red Mudgypsum in vegetable production
Discussion
The increase in pH Ec PRI and P sorption of Karrakatta sands with level of freshly-applied AG prior to fertiliser application is similar to that reported for the amendment of Joel (McPharlin et al 1994 and Robertson et al 1997a) and Karrakatta sands (Robertson et al 1994 and 1997b) with AG The increase in DH and Ec of the amended soil is explained by the high levels of both in the AG (ie pH (CaCr) = 94 and Ec = 623 mSm Appendix 1) The increased retentionsorption of P is explained by the addition of iron (974) and aluminium (551) in various oxides and hydroxides in the AG (Appendix 1 and Barrow 1982) to the soil After the application of P fertilisers levels of P in the soil at mid-growth and harvest as measured by total and Colwell P increased with a parallel decrease in PRI The increase in the levels of exchangeable Ca and Na in the soil at the same times with level of freshly-applied AG can be attributed to the AG itself However the increase in exchangeable and Colwell K appears to be due to improved K retention capacity of the soil due to physical properties of the AG rather any increased supply of K from the AG Whilst the overall K adsorption properties of the soil as measured by the Freundlich isotherm was not significantly increased with level of AG K sorption at 2401 AGha was significantly higher than at 01 AGha
There was no significant increase in cation exchange capacity (CEC) with level of freshly-applied AG on the Karrakatta sand in this experiment which remained about 2 me By contrast the CEC of virgin Joel sands increased from 1 to 2 me with level of freshly-applied AG (0 to 240 tha) in columns (McPharlin et al 1994) The application of AG would be expected to increase the CEC of coarse sands because (1) AG a fine textured material (10 clay 68 silt) (Ward 1983) would increase the fine fraction when applied to sands (2) AG has a much higher CEC ie 7 to 15 me depending on pH (Barrow 1982) than either Joel or Karrakatta sands ie 1 to 2 me (McPharlin et al 1994 and Table 51) and (3) application of AG to either Joel or Karrakatta sands increases the retentionreduces leaching of cations either not present in the AG such as NH4-N (McPharlin et al 1994) or only present in small quantities such as K (Tables 52 53 54 and Appendix 51)
The concentration of an element in the soil expressed as either extractable or total amounts represents the quantity or extensive factor in terms of plant nutrition as outlined by Holford and Mattingly (1976) The concentration of ions in soil solution or the intensive factor may better represent what is available to the plant A good example of this is the levels of K in the soil expressed as either Colwell or exchangeable K which increase significantly with level of applied AG However levels of K in the plant YML at buttoning and curds at harvest decrease significantly with level of AG K in soil solution 1 month after planting similarly decline significantly with level of applied AG and are therefore better correlated with K nutrition of the plant than measurements based on the dry soil Similarly P concentrations in the plant and soil solution decline whilst P retained by the soil increase in response to freshly-applied AG By contrast concentrations of Na in soil solution soil and plant all increase with levels of freshly-applied AG Similar relationships between concentrations of K Na and P in the soil soil solution and plant on a Karrakatta sand have been reported previously (Robertson et al 1997)
In previous work maximum yield (ie A value) of cauliflowers was reduced when freshly prepared AG was applied at levels gt 120 tha (Robertson et al 1994) This yield reduction was assumed not to be due to induced P deficiency resulting form high level of applied AG as it could not be alleviated by increased levels of applied P Although increased levels of applied P were needed to maximise yield as the level of freshly-applied AG increased Concentrations of K decreased and Na increased in the YML with level of applied AG and the yield reduction was assumed to be due either induced K deficiency or Na toxicity However neither the reduced concentrations of K or the increased concentrations of Na in the plant were at levels that would reduce yield according to published standards (Weir and Cresswell 1993) Antagonism between Na and K uptake by plants is common (Yeo 1983) For example increasing soil salinity resulted in increased concentrations of Na and decreased concentrations of K in the leaves of Zucchini grown in controlled greenhouses in Spain (Villora et al 1997)
The use of Red Mudgypsum in vegetable production
In this work as level of freshly-apphed AG increased level of applied P necessary for maximum yield increased as in the previous work however maximum yield was not reduced by AG up to 240 tha This is despite concentrations of K in the YML decreasing and Na increasing in response to level of freshly-applied AG However as in the previous work neither concentrations of K or Na were at levels expected to cause yield reduction By contrast the reduction in maximum yield of potatoes at high levels of freshly-applied AG (ie gt 120 tha) was correlated with a reduced concentration of K in the petioles (Robertson et al 1997b)
The level of freshly-applied P required for 99 of maximum yield in this work increased from 124 kgha at 01 AGHa to 339 kgha at 2401 AGha These levels of applied P are similar to that reported necessary for maximum yield of cauliflowers on AG-amended (Robertson et al 1994) or unamended (McPharlin et al 1995) Karrakatta sands The P required for 99 of maximum yield in this work 053 to 057 was either slightly higher - 047 (McPharlin et al 1995) or within range - 05 to 07 (Piggott 1986) 03 toO7 (Weir and Cresswell 1993) of that reported as critical or adequate for maximum yield of cauliflowers
Increased levels of freshly-applied AG did not significantly change the concentrations of Cd Co Cr Pb Ni Rb Sr Th or V in the curds of cauliflowers By contrast concentrations of Ba were significantly reduced and Ti increased in the curds with levels of freshly-applied AG Similarly there was no reported change in concentration of Cd Cr Pb or Co with level of freshly-applied AG in curds of cauliflower grown on Karrakatta sands (Robertson et al 1994) in previous work Also there was no change in Ba concentration in curds with level of AG in contrast to the previous work
References
Barrow NJ (1982) Possibility of using caustic residue from bauxite for improving the chemical and physical properties of sandy soils Australian Journal of Soil Research 33 275-285
Holford ICR and Mattingly GEG (1976) Phosphate adsorption and plant availability of phosphate Plant and Soil 44 377-89
McArthur and Bettenay (1960) The development and distribution of the soils of the Swan Coastal Plain Western Australia Soils Publication No 16 CSIRO Division of Soils CSIRO Melbourne Australia
McPharlin IR JefFery RC Toussaint LF and Cooper M (1994) Phosphorus Nitrogen and Radionuclide Retention and Leaching from a Joel Sand amended with Red Mudgypsum Communications in Soil Science and Plant Analysis 25 (17 amp 18) 2925-2944
McPharlin IR Robertson WJ JefFery RC and Weissberg R (1995) Response of cauliflower to phosphate fertiliser placement and soil test phosphorus calibration on a Karrakatta sand Communications in Soil Science and Plant Analysis 26(3amp4) 607-620
McQuaker NR Brown DF and Kluckner PD (1979) Digestion of environmental materials for analysis by inductively coupled plasma-atomic emission spectrometry Analytical Chemistry 51 1082-1084
Piggott TJ (1986) Vegetable crops pp 148-187 In DJ Reuter and JB Robinson (eds) Plant Analysis an Interpretation manual Inkata Press Melbourne Australia
Robertson WJ McPharlin IR and JefFery RC (1994) Final report of investigation into the use of gypsum-amended Red Mud as a soil-amendment on horticultural properties on the Swan Coastal Plain Report to HRDC (Project No V0039RO) Department of Agriculture Western Australia
55
The use of Red Mudgypsum in vegetable production
Robertson WJ Jeffery RC and McPharlin IR (1997a) Residues from bauxite-mining (Red Mud) increase phosphorus retention of a Joel sand without reducing yield of carrots Communications in Soil Science and Plant Analysis 28 (in press)
Robertson WJ McPharlin IR and Jeffery RC (1997b) The growth nutrition and mineral composition of potatoes (Solanum tuberosum L) cv Delaware grown on an yellow Karrakatta sand amended with freshly-applied and residual Alkaloamreggypsum (Submitted to AJEA)
Varley J A (1966) Automatic methods for the determination of nitrogen phosphorus and potassium in plant material Analyst 91 119-126
Villora G Pulgar G Moreno DA and Romero L (1997) Effect of salinity treatments on nutrient concentration in Zucchini plants (Cucurbita pepo L var Moschatd) Australian Journal of Experimental Agriculture 37 605-608
Vlahos S Summers KJ Bell DT and Gilkes RJ (1989) Reducing phosphorus leaching from sandy soils with Red Mud bauxite processing residues Australian Journal of Soil Research 27 651-662
Weir RG and Cresswell GC (1993) Plant Nutrient Disorders 3 Vegetable crops p 93 Inkata Press Melbourne Australia
Yuen SH and Pollard AG (1954) Determination of nitrogen in agricultural material by the Nessler reagent II Micro determination in plant tissue and soil extracts Journal of the Science of Food and Agriculture 5 364-369
The use of Red Mudgypsum in vegetable production
Appendix 51 Chemical and physical characteristics of Alkaloam gypsum used in cauliflower experiment (freshly-applied Alkaloamreggypsum)
Parameter Units Value Kgt
Ec mSm 623 -
pH (H 20) mSm 99 -
pH (CaCl2) mSm 94 -
PRI mLg 610 - gt 1000 -
LOI 1973 -
C a C 0 3 1290 1290
Fe (Fe203) 974 974
Al (A1203) 551 551
Si (Si0 2 ) 797 797
Ca (CaO) 45 450
Na (Na 2 0) 228 228
Ti (Ti0 2 ) 174 174
K (K 2 0) 072 72
Mg (MgO) 028 28 sect 047 47
P (P2O5) 005 05
Mn (MnO) 002 02
Total P ngg 266 -
Extractable P M-gg 58 -
Extractable K M-gg 43 -
As ngg 35 -
Ba ^gg 413 -
Cu Ugg 29 -
Sr Hgg 287 -
Nb Hgg 99 -y Hgg 866 -
Zr fAgg 1477 -
Sand 232 -
Silt 473 -
Clay 295 -
After Allen and Jeffery (1990)
Based on X-ray fluorescence (XRF) spectrometry
After Colwell (1963)
The use of Red Mudgypsum in vegetable production
Appendix 52 Concentration of Ba plus heavy metals1 (dry weight basis) in curds of cauliflowers at harvest with level of freshly-applied Alkaloamreggypsum (AG) and phosphorus (P)
(a)
AG Ba Cd Cr Co Pb Ni Rb Sr Ti Th V (tha) (Pgg) (vigg) (ugg) (ugg) (Pgg) (Pgg) (Pgg) (ugg) (Pgg) (Pgg) (Pgg)
0 119 010 050 010 020 050 88 182 050 058 010
60 72 010 050 010 022 050 91 171 069 078 012
120 87 011 064 011 030 050 92 186 067 075 012
240 53 011 05 010 023 050 95 172 061 067 012
Lsd2 21 002 02 024 016 022 11 28 008 024 002
Sig3 ns ns ns ns ns ns ns ns ns
(b)
p (kgha)
Ba (vgg)
Cd (vigg)
Cr (Pgg)
Co (ngg)
Pb (vgg)
Ni (Pgg)
Rb (Pgg)
Sr (Pgg)
Ti
(Pgg)
Th (Pgg)
V
(Pgg)
0 83 010 050 010 038 050 97 149 058 067 013
50 100 011 050 010 027 050 98 207 075 110 013
100 86 010 050 010 017 050 85 180 067 075 012
200 79 010 050 010 018 050 92 193 058 058 010
400 78 011 071 011 028 058 89 168 058 054 011
600 71 010 050 010 016 050 90 168 054 054 010
Lsd2 18 002 024 0009 022 009 06 27 028 044 003
Sig3 ns ns ns ns ns ns ns ns
Inductively coupled plasma mass spectrometry
Least significant difference at P lt 005
Significance at lt 0001 () lt 001 () lt 005 () level or not significant (ns)
The use of Red Mudgypsum in vegetable production
6 RESPONSE OF CAULIFLOWERS TO RESIDUAL RED MUD (ALKALOAMreg)GYPSUM (AG) AND PHOSPHORUS ON A YELLOW KARRAKATTA SAND
Introduction
It is important to reduce the leaching of phosphorus fertiliser from sandy soils used for vegetable production into the water systems of the Swan Coastal Plain Red Mud (Alkaloam )gypsum (AG) (ie Red Mudgypsum RMG) a waste product from bauxite refining has been suggested as an amendment to reduce phosphorus leaching from sands of the Bassendean Association (Joel Gavin) used for agriculture and horticulture (Barrow 1982)
Experimental work in the field and pots showed amendment with AG significantly reduced P leaching from Joel and Gavin sands (Vlahos et al 1989 McPharlin et al 1994) compared with the unamended (01 RMGha) treatment
Previous work showed a significant reduction in maximum yield of cauliflowers with levels of residual AG of gt 60 tha compared with 01 AGha (Robertson et al 1994) This yield reduction was not due to P deficiency as increased levels of applied P did not obviate the problem Nor was it due to K deficiency as K concentrations in the youngest mature leaves (YML) although reduced by levels of residual AG did not decline to levels expected to reduce yield The converse was true for concentrations of Na in the YML which increased with levels of residual AG but not to concentrations expected to cause toxicity
Since more than 60 tha of AG may be required to significantly improve P retention by sands to enable sustainable horticultural production this yield reduction is re-examined with residual AG
Materials and methods
Site characteristics
The experiment was conducted on a yellow Karrakatta sand (McArthur and Bettenay 1960) at Medina Research Centre (32deg 13 S 115deg 49 E) 30 km south of Perth Both Alkaloamreggypsum (AG) and phosphorus had previously been applied to the site and a potato crop grown in 1995 Prior to that the site had been sown to pasture for several years Some relevant chemical characteristics of the topsoil (0-15 cm) and subsoil (15-30 cm) of the site after application of AG but prior to the application of fertiliser (except residual P) and transplanting are presented in Table 61
Red Mud (Alkaloamreg)gypsum
Alkaloamreg (Red Mud) amended with 10 (ww) gypsum (AG) was produced by the dry mix process by ALCOA of Australia Ltd at their Kwinana Residue Treatment Plant The AG had been spread manually on the site and incorporated using a rotary hoe to approximately 30 cm depth on 22 December 1994 Residual P had been applied just before planting of the previous potato crop on 17 May 1995 and incorporated with a rotary hoe The site was watered for 1 hour per day (8 mmday) using impact sprinklers until planting
Experimental design
The experimental design was a split-plot randomised block with 3 replicates The main plots were levels of AG (0 60 90 120 and 240 tha) and the sub-plots were levels of freshly-applied P (25 50 100 300 and 600 kgha) Main plots measured 7 x 12 m and sub-plots 12 x 7 m (excluding wheel tracks)
59
The use of Red Mudgypsum in vegetable production
Crop management
The site was sprayed with Roundupreg (3 Lha) twice after application of AG and prior to planting to control weeds Six week old seedlings of cauliflowers (cv Plana) obtained from a commercial nursery were transplanted manually on 18 April 1996 in 2 rows per plot with 70 cm between rows and 50 cm between plants Seedlings were dipped in Rovralreg (1 mLL) just prior to planting for control of fungi Treflanreg (14 Lha) and Dacthalreg (12 kgha) were applied immediately after transplanting to control broadleaved weeds and Sertinreg later on in the life of the crop for grass control Ambushreg (100 mLha) and Rogorreg (100 mLha) were used to control caterpillars and red legged earth-mite respectively Copper was applied for control of blackrot The crop was irrigated to a total application equivalent to 100 of the previous days pan evaporation using minisprinklers (Legoreg 6 x 6 m spacing 44 mmh) in 3 waterings of equal duration per day
Fertilisers
Pre-planting fertilisers were broadcast manually and rotary hoed on 17 April 1996
These were K2S04(244) Ca(N03)2(387) MgS047H20 (504) MnS04H20 (504) FeS047H20 (18) Borax (27) CuS045H20 (36) ZnSOH20 (28) and Na2Mo042H20 (2) P was applied as single superphosphate (91 P) at 0 to 600 kg Pha according to treatment and incorporated as before Post-planting K N and Ca were fertigated via the irrigation system as KN03 NHUNO3 and Ca (N03)2 in equal amounts per day for 12 weeks to a total of 600 kg Kha 423 kg Nha and 60 kg Caha Borax was fertigated at 20 kgha in week 3 and Mg was broadcast as MgS047H20 at 50 kgha in weeks 3 6 and 9
Measurements
Soil and soil solution
All zero P subplots were sampled 30 cores per plot just prior to planting and fertilising about 2 months after AG application to 2 depths (0-15 15-30 cm) These were oven dried at 40degC and analysed for Ec pH (CaCl2) P sorption (Ozane and Shaw 1968) bicarbonate extractable P K (Colwell 1963) total P PRI P sorption K sorption (Allen and Jeffery 1990) and cation exchange capacity (Gillman and Sumpter 1986)
The soil water was obtained by centrifugation from soil samples (0-15 cm 30 per plot) and collected from the 0 100 200 and 600 kg Pha plots across all AG treatments on the 16 May 1996 The supernatant was analysed for pH Ec Ca Mg K S and P The remaining soil was analysed for pH (H20) bicarbonate extractable P K PRI and DTPA extractable Zn After harvest 5 August 1997 soil samples were collected from 2 depths as for the preplanting treatment from all plots These were analysed for pH bicarbonate extractable P K total P PRI and exchangeable cations (Ca Mg K and N)
Plant
At buttoning on 13 June 1996 the younger mature leaves (YML) (4th from growing point) were collected from 16 plants (excluding 1 m buffer at each end of plot) in each plot They were dried at 70degC in a force draught oven for 48 h and ground to pass through a 1 mm screen Sub-samples were digested with sulphuric acidhydrogen peroxide (Yuen and Pollard 1954) and the concentration of N P and K measured by an automated colorimetric process (Varley 1966) Concentration of other nutrients (B Ca Na Mg S Fe Mn Zn and Cu) were determined by inductively coupled plasma atomic emission spectroscopy (ICP-AES) after digestion with nitric-perchloric acids (McQuaker et al 1979) Five whole plants were harvested from the middle of each plot (2 per row) at the end of the experiment on 4 July 1996 using shovels to remove as much of the roots as possible The plants were separated into four categories curds leaves stems and roots All soil was dried and digested as for ICP-AES as above and washed from the roots using tap water shaken and the excess water removed using paper towels The fresh weight of all four categories was recorded and the material was diced
60
The use of Red Mudgypsum in vegetable production
into small pieces (lt 8 cm3) using stainless steel knifes sub-samples (300 g fresh weight) were collected at random from the diced pieces and the fresh weight recorded These were dried at 70degC in a forced draught oven for 48 h and the dry weight recorded These samples were then analysed for P as for the youngest mature leaves Separate sub-samples (300 g fresh weight) of curds were collected and analysed for Ba Cd Cr Co Pb Mo Rb Sr Ti Th V and Ni using inductively coupled plasma mass spectrometry (ICP-MS) The fresh and dry weight of the curds leaves stems and roots at harvest were used to calculate P uptake in kgha)
Harvest
Harvest commenced when the leaves surrounding the head opened and exposed the curds 77-80 days after transplanting At this stage florets at the periphery of the curd had just begun to separate Sixteen curds (12 plus 4 from whole plant samples above) were collected from the central 4 m of both rows (1 m buffer) and then all the leaves and stems removed according to requirements for export market Each fresh curd was weighed and rejects recorded if undersize (lt 500 g) oversize (gt 2000 g) discoloured (yellowing) overmature (separation of florets in the centre of curd) diseased damaged or otherwise distorted The total marketable and reject yield were recorded for each plot
Analysis of data
Analysis of variance was carried out on level of applied AG or P versus (a) chemical characteristics of soil (bicarbonate extractable P total P etc) preplanting and harvest (b) concentrations of nutrients in soil solution at midgrowth (c) concentration of nutrients in YMLs at midgrowth (d) concentration of elements in curds at harvest (e) P uptake by plant parts and (f) total marketable and reject yield of curds at harvest Mitscherlich curves and inverse polynomials were fitted to the relationship between level of applied P and yield at each level of applied AG The level of applied P required for 95 99 and 100 (in case of inverse polynomials) of maximum yield was calculated Mitscherlich curves were fitted to the relationship between level of applied P and P in YMLs at midgrowth at all levels of AG The P in YMLs corresponding to the level of applied P required for 95 99 or 100 of maximum yield (as determined from yield versus applied P plots) was then determined
Mitscherlich curves were also fitted to the relationship between level of applied P and P uptake by curds leaves stems and roots and the P uptake corresponding to whole plants (additions of all 4) level of P required for 95-100 of maximum yield determined Phosphorus uptake by plant parts or whole plants on 0 P plots were deducted from P uptake at other rates to account for non-fertiliser sources of P This was used to adjust P uptake when determining P fertiliser recovery efficiency (RE) by plant parts or whole plants ie fertiliser P uptake by plant parts or whole plantsP applied both in kgha (Novoa and Loomis 1981)
The effect of residual AG andP on chemical characteristics of the soil
Increased levels of previously-applied (residual) AG resulted in a significant increase in Ec pH (CaCl2) Colwell P and PRI in the topsoil (0-15 cm) of a Karrakatta sand prior to current the application of fertilisers and planting (Table 61 Fig 61) There was no significant effect of level of residual AG on the levels of Colwell K in the topsoil Increasing levels of previously-applied (residual) P resulted in a significant increase in Colwell P and a decrease in PRI and pH at the same time but had no effect on the levels of Colwell K in the topsoil
61
The use of Red Mudgypsum in vegetable production
Table 61 Chemical characteristics of the topsoil (0-15 cm) of a yellow Karrakatta sand 12 months after application of Alkaloamreggypsum (AG) (residual AG) and phosphorus (P) just prior to fertiliser application and transplanting
AG Ec pH BicP1 BicK1 PRI2
(tha) (mSm) (CaCl2) (H8g) (Hgg) (mLg)
0 36 70 262 199 093
60 62 78 397 308 101
90 70 80 390 378 12
120 73 80 402 391 14
Lsd3 057 018 75 122 018
Sig4 ns
P (kgha)
Ec (mSm)
pH (CaCl2)
BicP1
(M-gg) BicK1
(figg) PRI2
(mLg)
0 59 78 117 323 17
25 58 78 147 338 15
50 58 78 160 322 16
100 58 78 255 327 13
300 62 76 554 309 06
600 66 75 944 296 005
Lsd3 063 01 58 60 02
Sig4 ns ns
1 After Colwell (1963) 2 After Allen and Jeffery (1990) 3 Least significant difference at P lt 005 4 Significance at lt 0001 () lt 001 () lt 005 () level or not significant (ns)
62
The use of Red Mudgypsum in vegetable production
mdash A
8 40 gt -o deggt 35 - en =gt mdash sect 30 _raquo CO
e 25 ltD O d
5 20
1 ^ I I I
T3
C
o
c CO o c o o
0 20 40 60 80 100120140
Residual AG (tha)
u u bull B
80 l
60
40
mdash n bull 20
n i i i i
I
i i i
100 200 300 400 500 600 700
Residual P (kgha)
Figure 61 (A B) Bicarbonate extractable P (bull) and K (bull) (figg dry soil after Colwell 1963) in the top soil (0-15 cm) of a yellow Karrakatta sand prior to fertilising and planting with level of residual Alkaloamreggypsum (t AGha) (A) and P (kgha) (B) Vertical bars refer to Lsd (P lt 005) for differences between levels of AG or P
5 E Q 0 -
20 40 60 80 100120 140
Residual AG (tha)
0 100 200 300 400 500 600 700
Residual P (kgha)
Figure 61 (C D) Phosphorus retention index (PRI) after Allen and Jeffery (1990) in the topsoil (0-15 cm) of a yellow Karrakatta sand prior to fertilising and planting with level of residual Alkaloamreggypsum (t AGha) (C) and P (kgha) (D) Vertical bars refer to Lsd (P lt 005) for differences between levels of AG or P
63
The use of Red Mudgypsum in vegetable production
One month after planting there was a significant increase in concentration of Ca Na and pH and a decrease in K concentration with level of residual AG in the soil solution at 15 cm depth There was no significant effect of level of residual AG on the Ec or concentration of Mg S and soluble reactive P (Psr) in the soil solution (Table 62 (a) Fig 62) There was a significant decrease in Ec pH and concentration of Mg Na and an increase in concentration of Ca S and Psr in soil solution with level of residual P
Table 62 (a) Ec (mSm) pH and concentration of nutrients (ugmL) in soil solution 1 month after planting cauliflowers with level of residual Alkaloamreggypsum (AG) and phosphorus (P)
AG
AG (tha)
Ec (mSm)
pH Ca (ngmL)
Mg (ugmL)
Na (jigmL)
K (UgmL)
S (jigmL)
Psrp1
(pgmL)
0 129 75 91 141 105 81 28 05
60 144 77 108 131 121 64 30 06
120 147 76 123 136 120 50 33 04
Lsd2 33 01 14 09 4 7 1 02
Sig3 ns ns ns ns
P
p (kgha)
Ec (mSm)
pH Ca (UgmL)
Mg (ligmL)
Na (jigmL)
K (UgmL)
S (UgmL)
Psrp1
(VigmL)
0 171 78 107 141 121 68 23 01
100 138 77 104 144 111 58 24 02
300 120 76 103 128 110 63 31 06
600 130 73 117 133 116 71 43 13
Lsd2 20 02 10 11 10 13 7 02
Sig3 ns
Soluble reactive P 2 Least significant difference at P ^ 005 3 Significance at lt 0001 () lt 001 () lt 005 () level or not significant (ns)
64
The use of Red Mudgypsum in vegetable production
3
C
o
o (gt
o in c c o
5 c CD O
o O
3
o
c o
c ltu o c o
o 0 20 40 60 80 100 120 140
Residual AG (tha)
0 100 200 300 400 500 600 700
Residual P (kgha)
Figure 62 (A B) Concentration (figmL) of Ca (bull) Mg (bull) Na (A) K (T) and S (bull) in soil solution (0-15 cm) under cauliflower one month after planting with level P residual Alkaloamreggypsum (AG) (A) and (B) Vertical bars refer to Lsd (P lt 005) for differences in concentration between levels of AG Where bars are not shown Lsd is less than size of symbol
There was a significant increase in Colwell P K and PRI in the topsoil (0-15 cm) and no change in DTPA extractable Zn with level of residual AG one month after planting (Table 62 (b)) As level of residual P increased there was a significant increase in Colwell P and decrease in PRI with no change in Colwell K or DTPA extractable Zn in the topsoil one month after planting
The use of Red Mudgypsum in vegetable production
Table 62 (b) Extractable P K Zn and phosphorus retention index of the TopsoU (0-15 cm) of a yellow Karrakatta sand 1 month after planting of cauliflowers with level of residual Alkaloamreggypsum (AG) and phosphorus (P)
AG
Ag BicP1 BicK1 Zn2 PRI3
(tha) (Pgg) (Pgg) (Pgg) (mLg)
0 27 41 25 05
60 45 43 26 03
120 50 59 23 07
Lsd4 8 6 05 01
Sig5 ns
p
p (kgha)
BicP1
(Pgg) BicK1
(Pgg)
Zn2
(l-igg) PRI3
(mLg)
0 9 46 19 12
100 21 47 22 09
300 42 46 25 03
600 90 52 31 -03
Lsd4 7 5 10 02
Sig5 ns ns
1 After Colwell (1963) 2 Extracted in DTPA 3 After Allen and Jeffery (1990) 4 Least significant difference at P ^ 005 5 Significance at lt 0001 () lt 001 () lt 005 () level or not significant (ns)
After harvest of cauliflowers there was a significant increase in Colwell P and K total P actual and predicted PRI (PRI and PRIp) with residual AG in the topsoil and subsoil of a Karrakatta sand (Table 63 (a) (b)) There was a significant increase in Colwell P and total P and decrease in Colwell K PRI and PRIp with level of residual P in both the topsoil and subsoil after harvest (Fig 63 (A B))
66
The use of Red Mudgypsum in vegetable production
Table 63 Extractable P K total P and phosphorus retention index of the topsoil (0-15 cm) and subsoil (15-30 cm) of a yellow Karrakatta sand after harvest of cauliflowers with level of residual AIkaloamreggypsum (AG) and phosphorus (P)
(a) Topsoil
AG
AG BicP1 BicK1 TotP2 PPJ3 PPJP4
(tha) (ngg) (Hgg) (Pgg) (mLg) (mLg)
0 16 28 68 10 26
60 25 42 86 15 41
90 25 46 91 16 43
120 26 54 96 18 46
Lsd5 3 9 8 005 03
Sig6
P (kgha)
BicP1
(Pgg) BicK1
(vigg) TotP2
(ngg) PPJ3
(mLg) PPJP4
(mLg)
0 7 46 58 19 27
25 8 45 63 19 28
50 9 44 64 20 30
100 15 43 72 17 33
300 37 40 103 09 48
600 63 36 152 03 67
Lsd5 3 6 8 03 05
Sig6
1 After Colwell (1963) 2 After Allen and Jeffery (1990) 3 Phosphorus retention index (Allen and Jeffery 1990) 4 Predicted phosphorus retention index (Allen and Jeffery 1990) 5 Least significant difference at P ^ 005 6 Significance at lt 0001 () lt 001 () lt 005 () level or not significant (ns)
The use of Red Mudgypsum in vegetable production
120
o lgt 100 bull gt
TJ
rn laquon D ) 3
mdash-
on
60
^^ m i _
c 40 ltigt o c o O 20
160 A (I 140
^ ^ ^ ^ 1 o (0 ^ ^ ^ ^ 1 gtraquo 120
^plusmn bull o
^ ^ ^ ^
66
100
^ 3 80
^ mdash ^ tra
tion
60
^ ^ - ^ ^ ^ cen 40
o 20 o 20
I I I I I I I
O
10
0
0 20 40 60 80 100 120 1lt
O
10
Residual AG (tha)
0 100 200 300 400 500 600 700
Residual P (kgha)
Figure 63 (A B) Bicarbonate extractable P (bull) K (bull) and total P (A) in the topsoil (0-15 cm) of a yellow Karrakatta sand after harvest of cauliflowers with level of residual AIkaloamreggypsum (t AGha) (A) and P (kgha) (B) Vertical bars refer to Lsd (P lt 005) for difference between level of AG or P Lsd not shown when less than size of symbol
68
The use of Red Mudgypsum in vegetable production
Table 63 Extractable P K total P and phosphorus retention index of the topsoil (0-15 cm) and subsoil (15-30 cm) of a yellow Karrakatta sand after harvest of cauliflowers with level of residual Alkaloamreggypsum (AG) and phosphorus (P)
(b) Subsoil
AG
AG BicP1 BicK1 TotP2 PRI3 PRJJP4
(tha) (Pgg) (ugg) (ngg) (mLg) (mLg)
0 15 23 69 08 24
60 23 31 82 12 36
90 24 37 91 14 39
120 25 40 90 17 43
Lsd5 4 6 7 01 03
Sig6
P (kgha)
BicP1
(ngg) BicK1
(ugg) TotP2
(ugg) PRI3
(mLg) PRIP4
(mLg)
0 6 36 57 18 25
25 8 36 63 17 26
50 8 34 63 17 26
100 13 31 71 15 29
300 33 29 102 08 43
600 61 30 141 03 64
Lsd5 5 5 8 02 05
Sig6
1 After Colwell (1963) 2 After Allen and Jeffery (1990) 3 Phosphorus retention index (Allen and Jeffery 1990) 4 Predicted phosphorus retention index (Allen and Jeffery 1990) 5 Least significant difference at P ^ 005 6 Significance at lt 0001 () lt 001 () lt 005 () level or not significant (ns)
The use of Red Mudgypsum in vegetable production
100
o CO
gtlaquo
C
o CO
bull-raquo
c o o o
20 40 60 80 100 120 140
Residual AG (tha) 0 100 200 300 400 500 600 700
Residual P (kgha)
Figure 63 (A B) Bicarbonate extractable P (bull) K (bull) and total P (A) in the subsoil (0-15 cm) of a yellow Karrakatta sand after harvest of cauliflowers with level of residual Alkaloamreggypsum (t AGha) (A) and P (kgha) (B) Vertical bars refer to Lsd (P lt 005) for difference between level of AG or P Lsd not shown when less than size of symbol
Ec pH (CaCl2) and exchangeable Ca and Na in the top and subsoil after harvest increased significantly with level of residual AG whilst there was no change in exchangeable Mg (Table 64 (a) (b)) Whilst there was no change in exchangeable K with level of residual AG in the topsoil there was a significant increase in exchangeable K in the subsoil (Table 64 (b))
70
The use of Red Mudgypsum in vegetable production
Table 64 Ec (mSm) pH (CaCl2) and exchangeable cations (me) in topsoil (0-15 cm) and subsoil (15-30 cm) of a yellow Karrakatta sand with level of residual AIkaloamreggypsum (AG) and phosphorus (P) after harvest of cauliflowers
(a) Topsoil (0-15 cm)
AG
AG Ec pH Ca1 Mg1 K1 Na1
(tha) (mSm) (CaCl2) (me) (me) (me) (me)
0 29 65 24 027 006 004
60 47 73 32 025 009 010
90 59 77 36 023 015 015
120 66 78 40 025 012 018
Lsd2 07 07 06 005 006 001
Sig3 as ns
P (kgha)
Ec (mSm)
PH (CaCl2)
Ca1
(me) Mg1
(me) K1
(me) Na1
(me)
0 43 73 30 025 001 011
25 46 73 33 026 010 011
50 46 73 32 025 010 011
100 52 74 32 025 010 011
300 56 74 34 024 009 011
600 58 73 37 025 014 012
Lsd2 05 05 03 002 007 -
Sig3 ns ns ns
Exchangeable in 1 m NILt-Cl 2 Least significant difference at P ^ 005 3 Significance at lt 0001 () lt 001 () lt 005 () level or not significant (ns)
The use of Red Mudgypsum in vegetable production
soil b
A soil
dry
4 _ I dry
I ^5 CD CD
b_ 3 - E c c o o CO at
i
U o CD CD
Xgt j a CO bull| mdash CO CD ogt
m- mdashM- mmdash JZ 0 - +~ -- mdash c CJ o X X LU
i 1 I i i i i LU
0 20 40 60 80 100 120 1^ W
Residual AG (tha)
100 200 300 400 500 600 700
Residual P (kgha)
Figure 64 (A B) Exchangeable Ca (bull) Mg (bull) K (A) and Na ( bull ) (me) in the topsoil (0-15 cm) of a yellow Karrakatta sand with level of residual Alkaloamreggypsum (t AGha) or P (kgha) Vertical bars refers to Lsd (P lt 005) for differences in concentration between levels of AG or P Lsd not shown when less than size of symbol
72
The use of Red Mudgypsum in vegetable production
Table 64 Ec (mSm) pH (CaCl2) and exchangeable cations (me) in topsoil (0-15 cm) and subsoil (15-30 cm) of a yellow Karrakatta sand with level of residual AlkaIoamreggypsum (AG) and phosphorus (P) after harvest of cauliflowers
(b) Subsoil (15-30 cm)
AG
AG Ec pH Ca1 Mg1 K1 Na1
(tha) (mSm) (CaCl2) (me) (me) (me) (me)
0 34 66 24 026 006 005
60 50 75 33 024 008 010
90 64 78 38 023 01 016
120 68 79 41 024 01 019
Lsd2 05 01 07 006 001 003
Sig3 ns
P (kgha)
Ec (mSm)
pH (CaCl2)
Ca1
(me) Mg1
(me) K1
(me) Na1
(me)
0 48 75 30 023 009 011
25 51 74 33 026 009 011
50 50 75 34 025 008 013
100 61 75 35 026 008 013
300 57 75 34 022 007 013
600 58 73 38 024 008 013
Lsd2 08 01 04 003 001 003
Sig3 ns
1 Exchangeable in 1 m NH4-CI 2 Least significant difference at P ^ 005 3 Significance at lt 0001 () lt 001 () lt 005 () level or not significant (ns)
The use of Red Mudgypsum in vegetable production
o 0 oi
4 CO c CO
gt T3 4 _ bull o
0s -5 3 agt CD
fc_ 3 - g
on
o 2 CO 2 CO
u 2
o CD CD 1 X I SI
1 CD 1 CD CD CU
O
n ^ 1 CO n X bull mdashXmdash mdash 1 1 CO U J= n bull - w 1 CO U
o o X X Lil
i i 1 1 i i 1 HI
0 20 40 60 80 100 120 140
Residual AG (tha)
100 200 300 400 500 600 700
Residual P (kgha)
Figure 64 (C D) Exchangeable Ca (bull) Mg (bull) K (A) and Na (T) (me) in the subsoil (0-15 cm) of a yellow Karrakatta sand with level of residual Alkaloamreggypsum (t AGha) or P (kgha) Vertical bars refers to Lsd (P lt 005) for differences in concentration between levels of AG or P Lsd not shown when less than size of symbol
As level of residual P increased there was a significant increase in exchangeable Ca in the tbpsoil and subsoil but no significant effect on exchangeable Mg K and Na in the topsoil and variable effects on exchangeable Mg and K in the subsoil Ec increased significantly with level of residual P in both the top and subsoil whilst pH in either was effected little by level of applied P
The effect of level of residual AG andP on the concentration of nutrients in cauliflower leaves
The level of residual AG had no effect on the concentrations of N Ca S P S Mg Fe Zn Mn B and Cu in the youngest mature leaves of cauliflowers at buttoning but increased levels significantly reduced the concentration of K (Fig 65 (A B)) As level of residual P increased there was a significant increase in the concentration of K P S Cu and Mn in the YMLs whilst concentrations of N decreased and B concentrations were variable with no clear trends
74
The use of Red Mudgypsum in vegetable production
Table 65 Concentration of nutrients (dry weight basis) in youngest mature leaves of cauliflowers at buttoning with level of applied residual Alkaloamreggypsum (AG) and phosphorus (P)
(a) Macronutrients
AG
AG N1 K1 Ca2 S2 P1 Na2 Mg2
(tha) () () () () () () ()
0 49 42 23 077 040 039 027
60 51 40 23 078 042 036 025
90 51 39 23 079 043 036 025
120 49 39 24 078 042 036 025
Lsd3 03 02 08 009 007 010 004
Sig4 ns ns ns ns ns ns
P N1 K1 Ca2 S2 P1 Na2 Mg2
(kgha) () () () () () () ()
0 53 36 22 069 027 033 024
25 51 38 24 071 030 038 026
50 52 40 24 075 034 040 027
100 51 41 24 079 043 041 027
300 48 43 24 087 055 039 026
600 47 42 20 086 060 031 023
Lsd3 02 02 04 003 004 006 003
Sig4 ns ns
1 After Varley (1966) 2 After McQuakerefl (1979) 3 Least significant difference at P lt 005 4 Significance at lt 0001 () lt 001 () lt 005 () level or not significant (ns)
The use of Red Mudgypsum in vegetable production
Table 65 Concentration of nutrients (dry weight basis) in youngest mature leaves of cauliflowers at buttoning with level of applied residual AlkaIoamreggypsum (AG) and phosphorus (P)
(b) Micronutrients
AG
AG (tha)
Fe (ugg)
Zn1
(Pgg) Mn1
(ugg) B1
(ugg) Cu1
(ugg)
0 122 31 19 21 28
60 121 32 22 22 30
90 119 36 25 22 32
120 120 29 23 22 29
Lsd2 21 8 6 1 05
sig3 ns ns ns ns ns
P (kgha)
Fe1
(Pgg)
Zn1
(ugg) Mn1
Gigg)
B1
(Fgg)
Cu1
(Pgg)
0 112 33 19 22 28
25 120 32 22 22 29
50 125 32 21 23 29
100 132 38 24 23 31
300 129 30 25 22 32
600 106 29 23 21 32
Lsd2 19 6 3 1 03
Sig-3 ns ns
After McQuaker et al (1979) 2 Least significant difference at P ^ 005 3 Significance at lt 0001 () lt 001 () lt 005 () level or not significant (ns)
The relationship between residual P ie Colwell P and P in YMLs at buttoning were best described by Mitscherlich relationships at all levels of residual AG (Fig 65)
The concentration of P in YMLs corresponding to levels of Colwell P necessary for 95 of maximum yield were 047 050 054 and 048 and for 99 of maximum yield were 053 055 058 and 054 for 0 60 90 and 1201 residual AGha respectively
76
The use of Red Mudgypsum in vegetable production
Q
en
3
gt-c 0
07
06
05
04
03
02
01 0
065
060
055
050
045
040
035
030
025
020
A
if 20 40 60 80 100
Colwell P (ugg dry soil)
_ 065
Q S 055
060
tz
ro _ i
gt
120
C bull - - - mdash bull
20 40 60 80 100
Colwell P (ugg dry soil)
120
050
045
040
035
030
025
020
065
060
055
050
045
040
035
030
025
020
-B
bull
- bull I
I I
bull
i i i
20 40 60 80 100
Colwell P (ugg dry soil)
120
-bull D
I I i i i
20 40 60 80 100
Colwell P (ugg dry soil)
120
Figure 65 P in youngest mature leaves at buttoning () corresponding to Colwell P necessary for 95 (dashed) or 99 (whole) of maximum yield at 0 (A) 60 (B) 90 (C) and 120 (D) t of residual Alkaloamreggypsumha Dashed and whole horizontal lines refers to P in YML corresponding to Colwell P required for 95 and 99 of maximum yield respectively
The equations for the fitted lines are
A y = 05964 - 0763 x exp (-0068) (B2 = 089)
B y = 05855 - 05144 x exp (-00465x) (R2 = 098)
C y = 006058 - 0549 x exp (-00435x) (B2 = 096)
D y = 06399 - 05208 x exp (-00291) (R2 = 097)
77
The use of Red Mudgypsum in vegetable production
The effect of level of residual AG andP on the yield of cauliflowers
There was no significant effect of levels of residual AG on the total or marketable yield of cauliflowers However yield responded significantly to levels of applied residual P and the interaction between residual P and AG was significant (Tables 66 (a) (b))
The relationship between Colwell P and total yield was best described by Mitscherlich relationships for all levels of residual AG (Fig 66) The Colwell P required for 95 of maximum total yield was 26 40 48 and 40 ugg dry soil and for 99 35 55 71 and 58 ugg dry soil for 0 60 90 and 1201 residual AGha respectively
Table 66 Curd yield (total and marketable) of cauliflowers (tha) at harvest with level of residual Alkaloamreggypsum (AG) and phosphorus (P)
(a) Total
AG p
(kgha) (tha) p
(kgha)
0 60 90 120
0 59 64 69 100
25 134 126 123 83
50 139 133 117 143
100 163 200 164 177
300 203 236 198 204
600 215 237 208 194
Ls-d1 36 (AG) 17 (P) 48(AGP) -
Sig2 ns
(b) Marketable
p (kgha)
AG (tha) p
(kgha)
0 60 90 120
0 14 14 18 56
25 83 74 84 13
50 90 99 67 99
100 138 188 125 160
300 187 232 182 190
600 206 234 191 185
Lsd1
Sig2
48 (AG)
ns 23 (P)
62(AGP)
-
Least significant difference at P lt 005 2 Significance at lt 0001 () lt 001 () lt 005 () level or not significant (ns)
The use of Red Mudgypsum in vegetable production
0 20 40 60 80 100120140160
Colwell P (ugg dry soil)
0 20 40 60 80 100120140160
Colwell P (ugg dry soil)
lt x
UJ gt-Q
o
lt X
Q _ l UJ gt-Q rr D O
24
22
20
18
16 14
12
10
8
6
4
-D
bull
I I
I I
I I
I
^~ bull
i i i i i
20 40 60 80 100120140160
Colwell P (ugg dry soil)
20 40 60 80 100120140160
Colwell P (ugg dry soil)
Figure 66 Colwell P in topsoil (0-15 cm) at planting versus yield of cauliflowers at 0 (A) 60 (B) 90 (C) and 120 (D) tha of residual Alkaloamreggypsum (AG) Dashed and whole vertical lines represent Colwell P required for 95 and 99 of maximum yield respectively
The equations for the fitted lines are
A y = 2088 - 818 x exp (-017x) (i2 = 089)
B y = 23731 - 4578 x exp (-00949) (i2 = 099)
C y = 2051 - 286 x exp (-00697) (R2 = 086)
D y = 2002 - 354 x exp (-0090) (B2 = 086)
79
The use of Red Mudgypsum in vegetable production
Discussion
There was no significant reduction in maximum yield (ie A values) of cauliflower (cv Plana) curds grown on Karrakatta sands amended with residual AG from 0 to 120 tha in this work This is in contrast to previous work (Robertson et al 1994) in which maximum curd yields of cauliflowers were significantly reduced with levels of residual AG at 120 tha compared with 0 and 60 tha In both studies concentrations of K were reduced and concentrations of Na were increased in the YML at buttoning with increasing levels of residual AG The increase in concentration of Na and the decrease in concentration of K in the YML with level of applied AG was related to similar changes in the concentrations of these elements in the soil solution with both freshly-applied (Section 5) and residual AG one month after planting As with freshly-applied AG increasing levels of residual AG resulted in increasing levels of Na in the soil (exchangeable) or soil solution however whilst K concentrations in soil solution decreased the K retained by the soil measured as either Colwell K or exchangeable K increased Increasing levels of residual AG resulted in increased pH in the topsoil as with fresh AG but this did not reduce the concentration of Mn Cu and Zn in the YML or increase the concentration of Mo These changes would be expected with increases in soil pH (Porter 1984) The level of Colwell P required for 95 to 99 of maximum yield increased from 26 and 35 ugg dry soil at 01 AGha to 48 and 71 ugg at 901 of residual AGha The level at 1201 AGha was slightly lower ie 40 and 58 ugg These levels are similar to those reported as necessary for 95 and 99 of maximum yield of Arfak cauliflowers 40 and 55 ugg Colwell P in planted in autumn and spring on unamended Karrakatta sands (McPharlin et al 1995) It therefore does not appear that AG amendment increases the residual P as measured by Colwell P requirement of cauliflower significantly This is in contrast to the significantly higher level of applied P necessary to maximise yield when AG is freshly-applied ie from 120-160 to gt 300 kg of Pha at 0 and 1201 AGha respectively (Robertson et al 1994 and Section 5) However requirements of residual (Colwell) P and freshly-applied P are not always correlated For example the Colwell P necessary for the maximum yield of spring and winter-planted lettuce was similar ie 80 to 120 ugg dry soil whereas the level of freshly-applied P required for maximum yield of winter-planted lettuce was 50 higher than in spring (McPharlin et al 1996 McPharlin and Robertson 1997)
References
Allen DG and Jeffery RC (1990) Methods for analysis of phosphorus in Western Australian soils Chemistry Centre of Western Australia Report of Investigation No 37
Barrow NJ (1982) Possibility of using caustic residue from bauxite for improving the chemical and physical properties of sandy soils Australian Journal of Experimental Agriculture Research 33 275-285
Colwell JD (1963) The estimation of phosphorus fertiliser requirements of wheat in southern New South Wales by soil analysis Australian Journal of Experimental Agriculture Animal Husbandry 3 190-197
Gillman GP and Sumpter EA (1986) Modification to the compulsive exchange method for measuring exchange characteristics of soils Australian Journal of Soil Research 24 616
McArthur WM and Bettenay E (1960) The development and distribution of the soils of the Swan Coastal Plain Western Australia CSIRO Division of Soils Soils Publication No 16
McPharlin IR Jeffery RC and Pitman DH (1996) Phosphorus requirements of winter planted lettuce (Lactuca sativa L) on a Karrakatta sand and the residual value of phosphate as determined by soil test Australian Journal Experimental Agriculture 36 887-903
80
The use of Red Mudgypsum in vegetable production
McPharlin IR Jeffery RC and Weissberg R (1994) Determination of the residual value of phosphate and soil test phosphorus calibration for carrots on a Karrakatta sand Communications in Soil Science Plant Analysis 25 (5-6) 489-500
McPharlin IR and Robertson WJ (1997) Response of spring-planted lettuce (Lactuca sativa L) to freshly-applied and residual phosphorus and to phosphate fertiliser placement on a Karrakatta sand Australian Journal of Experimental Agriculture (in press)
McPharlin IR Robertson WJ Jeffery RC and Weissberg R (1995) Response of cauliflower to phosphate fertiliser placement and soil test phosphorus calibration on a Karrakatta sand Communications in Soil Science and Plant Analysis 26(3-4) 607-620
McQuaker NR Brown DF and Kluckner PD (1979) Digestion of environmental materials for analysis by inductively coupled plasma-atomic emission spectrometry Analytical Chemistry 51 1082-1084
Novoa R and Loomis RS (1981) Nitrogen and plant production Plant and soil 58 177-204
Ozanne PG and Shaw TC (1968) Advantages of recently developed phosphate sorption test over the older extractant methods for soil phosphate (ed JW Holmes) pp 273-280 In Transactions of the 9th International Congress of Soil Science Volume 2 Angus and Robertson Sydney Australia
Porter WM (1984) Soil acidity Agriculture Western Australia Farmnote No 6884
Robertson WJ McPharlin IR and Jeffery RC (14) Final report of investigation into the use of gypsum-amended Red Mud as a soil-amendment on horticultural properties on the Swan Coastal Plain Report to HRDC (Project No V0039RO) Department of Agriculture Western Australia
Varley J A 1966 Automatic methods for the determination of nitrogen phosphorus and potassium in plant material Analyst 91 119-126
Vlahos S Summers KJ Bell DT and Gilkes RJ (1989) Reducing phosphorus leaching from sandy soils with Red Mud bauxite processing residues Australian Journal of Soil Research 27 651-662
Yuen SH and Pollard AG (1954) Determination of nitrogen in agricultural material by the Nessler reagent IL Microdetermination in plant tissue and soil extracts Journal of Science Food Agriculture 5 364-369
The use of Red Mudgypsum in vegetable production
7 RETENTION LEACHING AND RECOVERY OF P AND OTHER NUTRIENTS BY CARROTS GROWN ON A JOEL SAND AMENDED WITH RESIDUAL RED MUD (ALKALOAMreg)GYPSUM (AG) IN LARGE POTS
Introduction
It is difficult to quantify the retention of P by sands amended with Red Mud (Alkaloamreg)gypsum (AG) in the field because of native P in the soil and soluble P in the AG (Robertson et al 1994) It is easy to quantify leaching of P and other nutrients such as N and K from AG amended sands in pots or columns by collecting leachate and measuring concentration (McPharlin et al 1995) However plants were not grown in the columns used by McPharlin et al so there was no measurement of plant uptake of P and other nutrients to complete the nutrient budget Potatoes were grown successfully in Spearwood sands in large pots (70 L) and a complete N budget (N applied N retained by soil N leached and uptake by plant) determined (Hegney et al 1996)
Freshly-applied AG may not be in equilibrium with the soil to which it is applied ie the pH Ec and concentrations of elements such as Ca and Na may change rapidly with time The age of the AG may effect its capacity to retain P on amended soils AG may improve the retention of other nutrients such as ammonium N (McPharlin et al 1995) and K (Sections 5 and 6) by amended sands AG which has been applied to sands in the field for at least 2 to 5 years should be close to equilibrium with the soil as substantial leaching would have occurred AG of this age would give the best estimate of its long term capacity to reduce leaching of P and other nutrients from poor grey sands on the Swan Coastal Plain The purpose of this work was to quantify the leaching and retention of P and other nutrients (N Ca K etc) from Joel sands which had been amended with AG at different levels in the field for 14 years Carrots a major vegetable crop grown on the Swan Coastal Plain were used as the experimental crop and grown in these AG amended sands in large pots
Materials and methods
Pots
Fibreglass pots used for the experiment were 45 cm in diameter and 50 cm deep The area of soil surface was 016 m2 and the volume was 70 L The bottom of the pots tapered to a hole (diameter) to which was attached a polyethylene hose (length and diameter) and tap The pots were painted white to reduce heat The pots were placed on a metal table (with mesh tops) and the hose passed through a hole in the centre of a lid of a plastic (20 L) bucket
Experimental design
The experimental design was a 4 (levels of residual AG ie 0 125 250 and 1000 tha) times 5 (levels of applied P ie 0 50 100 200 and 400 kgha) factorial in a randomised block with 3 replicates The level of applied AG or Pha was calculated using the area of the soil surface The total number of pots was 60
Soil and Red Mud (Alkaloamreg)gypsum (AG)
Virgin Joel sand was obtained from a commercial garden supply site in Jandakot The top 20 cm of the soil was removed and the rest sieved (15 mm) to remove debris About 20 kg of Joel sand was added to each pot (10 cm depth) Another 60 kg (30 cm depth) of sand was added to the 0 AGha pots to which had been mixed lime and preplant fertilisers (see later) so the surface of the soil was about 10 cm below the top edge of the pot AG amended sand was obtained from a field site in Hope Valley Road Kwinana managed by ALCOA where it had been applied (and incorporated using a rotary hoe) to pastures growing on a Joel sand in 1983 at 0 250 500 and 1000 tha This AG amended sand was added to pots corresponding to 250 and 1000 tha in the field after the preplant fertiliser but not lime was added and was incorporated to a similar depth as in the 01 AGha pots The 125 t AGha treatment was
82
The use of Red Mudgypsum in vegetable production
obtained by mixing AG amended sand from the 250 tha field site with an equal weight of Joel sand in a cement mixer
Fertilisers and lime
The following fertilisers (in kgha) were thoroughly mixed (using a cement mixer) with the top 25-30 cm of the soil in each pot before planting Urea (108) K2SO4Q2I) MgS047H20 (100) MnS04H20 (100) Na2B4O710 H20 (50) FeS047H20 (50) CuS045H20 (50) ZnS04H20 (50) and NaMo042H20 (4) To this was added P at 0 50 100 200 and 400 kgha as single superphosphate at each level of residual AG Hydrated lime (Ca (OH)2) was mixed with the preplanting fertilisers on the 0 kg AGha treatment at 36 gpot
N K and Ca were fertigated via the drip irrigation system at 200 200 and 52 mgL using KNO3 NH4NO3 and Ca (N03)2 from immediately after sowing to 140 days after sowing (18 August 1996) MgS047H20 was broadcast at 100 kgha to each pot at weeks 6 and 12
Irrigation
The plants were irrigated using drippers (Netafim 2 Lh pressure compensated with 4 equalisers per pot) at 15 times the average monthly pan evaporation until 160 days after sowing (7 September 1996) Adjustments were made on a daily basis if evaporation was significantly higher or lower than the long term average (Table 71)
Table 71 Irrigation requirements of carrots in pot experiments
Month DAS Lpotday Minutesday
April 1- 27 10 33
May 28- 59 065 21
June 60- 90 044 14
July 91-122 044 14
August 123-154 056 19
September 155-160
Adjusted for 90 efficiency of irrigation system
Rain was excluded from the pots using a movable rain out shelter made of perspex and aluminium This was removed at all other times
Crop management
The soil in each pot was irrigated to field capacity ie so that free drainage occurred Carrot (cv Top Pak) seeds were sown on a 9 x 9 cm spacing and 1 cm deep with 5 seeds per site on 3 April 1996 These were thinned to 14 seedlingspot (88 plantsm2) after emergence (15 April 1996) No application of fungicides or insecticides were necessary
Soil and plant measurements
Soil
Immediately before fertilising and sowing 5 cores (22 diameter x 15 cm deep) were taken from each pot and dried in a force draught oven at 40degC Each sample was analysed for extractable P and K (Colwell 1963) pH (CaCl2 and H20) total P (Allen and Jeffery 1990) PRI (Allen and Jeffery 1990) total N extractable ammonium N (KC1) extractable nitrate N (KC1) organic carbon cation exchange capacity and exchangeable cations
83
The use of Red Mudgypsum in vegetable production
Leachate
Leachate from each pot was collected in 20 L plastic buckets under the pots each week from the 4 April 1996 to 22 July 1996 PMA (phenyl mercuric acetate) was added to the leachate to prevent contamination Total water volume was measured and sub-samples (200 mL) collected and submitted for analysis of P NH4-N NO3-N K Na Ca S Mg Ec and pH analysis of concentration The quantities leached of the above elements in kgha were calculated from concentration and volume of leachate collected and surface area of soil in pot
Harvest
The plants were harvested on 7 September 1997 and the total marketable and reject root yield determined for each plot
Analysis of data
Analysis of variance (Genstattrade for Windows version 32) was carried out on level of AG and P versus yield (total marketable reject) level of chemical factors in soil after harvest concentration of nutrients in youngest mature leaves at midgrowth tops and roots at harvest and leachate on 22 April 1996 5 May 1996 and 22 July 1996 and quantities of elements leached at each sampling time
Mitscherlich or linear relationships were fitted to level of P versus yield (total) at each level of residual AG P required for 95 and 99 of maximum yield was delivered at each level of residual AG P uptake by carrots was determined from the dry weight and P in tops and roots for each treatment Fertiliser P uptake was determined by deducting uptake on 0 kg Pha treatments at each level of applied AG Fertiliser P retained in the top-soil was determined from the concentration of total P and bulk density P leached was fertiliser leached below 15 cm The P in each plant fraction soil and leached was determine at each level of applied P and AG
Results
Effect of level of residual AG on chemical characteristics of Joel sand
Soil pH (CaCl2 H20) Ec Colwell P phosphorus retention index cation exchange capacity exchangeable Ca and Na and silt and clay all increased with level of residual AG in the top soil (0-15 cm) of a Joel sand before fertilising and sowing (Table 72)
The use of Red Mudgypsum in vegetable production
Table 72 Chemical and physical characteristics of Joel sand amended with residual Alkaloam gypsum (AG) in pots before fertilising and sowing of carrots
Level of residual AG
Parameter (tha)
Parameter
0 125 250 1000
pH (H20) 69 77 85 86
pH (CaCl2) 57 71 78 78
Ec (mSm) 4 9 9 11
Ext P (ngg)1 3 9 14 9
PRI2 -02 33 44 77
Total N ()3 - 0039 0044 0060
ExtNH4-N(ngg)4 - 2 2 2
ExtN03-N(ugg)5 - 3 2 5
CEC ()6 30 30 43 35
Exch Ca ()7 133 363 51 70
Exch Mg ()7 036 024 015 021
Exch Na ()7 005 015 015 032
Exch K ()7 007 004 0035 0035
OrgC()8 131 109 092 103
Sand () 977 967 960 910
Silt () 13 15 15 37
Clay () 10 23 25 53
1 Colwell (1963) 2 Phosphorus retention index (Allen and Jeffery 1990) 3 KjeldahlReardon et al 1966 4 Extracted in 1 m KC1 (Reardon et al 1966) 5 Extracted in 1 m KC1 (Best 1976) 6 Gillman and Sumpter (1986) 7 Exchangeable in 1 m NHU-Cl 8 Walkley and Black (1934)
Level of residual AG had no effect on levels of extractable NH4-N NO3-N exchangeable Mg and K or organic carbon After harvest levels of Colwell P K total P PRI Ec pH (CaCk) exchangeable Ca Mg K and Na in the topsoil (0-15 cm) all increase significantly (P lt 005) with level of residual AG (Tables 73 74)
85
The use of Red Mudgypsum in vegetable production
Table 73 Extractable P K NH4 total P (tot P) and phosphorus retention index (PRI) of the topsoil (0-15 cm) of a Joel sand after harvest of carrots with level of residual Alkaloamreggypsum (AG) and phosphorus (P)
AG
AG BicP1 BicK tot P2 PRI3 NIL (tha) (ngg) (Hgg) (ngg) (mLg) (Mfig)
0 33 119 234 -015 137
125 200 117 743 141 27
250 275 197 1258 231 19
1000 204 420 1853 154 30
Lsd5 4 34 129 45 26
Sig6
P
P (kgha)
BicP1
(ngg) BicK1
(Mgfe) totP2
(ugg) PRI3
(mLg) NIL
(ngg)
0 91 215 896 198 58
50 151 223 937 138 54
100 144 226 1005 126 62
200 182 193 1043 128 42
400 323 210 1231 116 52
Lsd5 48 39 144 50 29
Sig6 s | e ns ns
1 Colwell 1963 2 Allen and Jeffery 1990 3 Phosphorus retention index (Allen and Jeffery 1990) 4 Extracted in 1 m KC1 (Best 1976) 5 Least significant difference at P s 005 6 Significance at lt 0001 () lt 001 () lt 005 () level or not significant (ns)
By contrast levels of extractable NH4-N decreased significantly with level of residual AG Colwell P total P Colwell K all increased significantly (P lt 005) with level of applied P whilst PRI was decreased significantly Level of applied P had no significant effect on Ec pH or level of exchangeable Ca Mg K Na Colwell K or extractable NHu-N in the topsoil after harvest (Tables 73 74)
The use of Red Mudgypsum in vegetable production
Table 74 Ec (mSm) pH (CaCl2) and exchangeable cations (me) in topsoil (0-15 cm) of a Joel sand after harvest of carrots with level of residual Alkaloamreggypsum (AG) and phosphorus (P)
AG
AG Ec pH Ca1 Mg1 K1 Na1
(tha) (mSm) (CaCl2) (me) (me) (me) (me)
0 157 44 18 016 026 010
125 147 54 23 014 026 015
250 217 66 40 017 041 027
1000 308 76 135 027 096 094
Lsd2 32 01 07 002 005 005
sig3
p
p (kgha)
Ec (mSm)
pH (CaCl2)
Ca1
(me) Mg1
(me) K1
(me) Na1
(me)
0 202 59 52 019 048 035
50 195 60 53 018 050 036
100 203 60 57 019 048 039
200 202 60 57 018 045 040
400 236 59 51 017 046 034
Lsd2 35 01 08 002 006 005
Sig3 ns ns ns ns ns ns
Exchangeable in 1 m NH4CI 2 Least significant difference at P s 005 3 Significance at lt 0001 () lt 001 () lt 005 () level or not significant (ns)
Effect of level of residual AG and P on concentration of nutrients in leachate and quantities of nutrients leached
There was a significant (P lt 005) reduction in concentration of P in leachate with level of residual AG at three times of sampling (Fig 71) P concentration in leachate increased significantly with level of applied P at 01 AGha but not in presence of AG
P concentration in leachate at 01 AGha decreased with time from 80 mgL on 16 April 1996 at 400 kg Pha to 025 mgL on 22 July 1996 To reduce P concentration in leachate 125 t AGha was as effective as 250 or 1000 tha at all sampling times and levels of applied P Similar trends were shown in quantity of leached P as total or soluble reactive P in kgha (Appendix 71 (b) 72) Level of applied AG significantly (P lt 005) reduced the concentration of NH4-N in leachate from 40 mgL at 01 AGha to 15 mgL at 250 and 1000 tha (Fig 72 (a)) on 16 April 1996 Significant reductions in concentration were recorded on the other two sampling times as NH4-N concentration declined with increased plant uptake Similar trends were shown in the quantity of NH4-N leached with level of AG (Appendix 72 (b)) By contrast level of applied AG had no significant effect on concentration of NO3-N in leachate or quantity leached at any of the three sampling times (Fig 72 (b) and Appendix 73 (b)) There was a significant (P lt 005) reduction in concentration of K in leachate and quantity of K leached with level of residual AG although the reduction was less at the later sampling times (Fig 73 Appendix 73 (a)) Concentration of K in leachate increased
87
The use of Red Mudgypsum in vegetable production
with time at all levels of residual AG except 1000 tha By contrast both the concentration of Na in leachate and quantity of Na increased with level of residual AG to a maximum at the highest level (1000 tha) There was a reduction in Na concentration in leachate with time at level of residual AG lt 1000 tha The concentration of Ca in leachate increased significantly (P lt 005) as did quantity leached with level of residual AG and with time at all levels of AG (Fig 74 Appendix 74 (a)) By contrast concentration of Mg in leachate and quantity leached decreased significantly (P lt 005) with level of residual AG and with time at all levels of AG (Fig 78 and Appendix 78 (a)) There was a significant (P lt 005) increase in S concentration in leachate and quantity leached with level of residual AG at the first sampling time a decrease at the second and a increase up to 250 tha at the third sampling (Fig 79 Appendix 79 (a)) S concentration in leachate and quantity leached varied significantly with level of applied P at all sampling times and decreased with time from 16 April 1996 to 22 July 1996 (Fig 79 and Appendix 79 (a))
The use of Red Mudgypsum in vegetable production
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o O
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Figure 71 Concentration of P (mgL of total P) in leachate from Joel sands sown to carrots with level of applied P and Alkaloamreggypsum (AG) at 0 (bull) 125 (bull) 250 (A) and 1000 (T) tha on 16 April 1996 (A) 6 May 1996 (B) and 22 July 1996 (C) P was applied preplanting as superphosphate and carrots were sown on 3 April 1996 Vertical bars refer to Lsd (P lt 005) for differences in concentration between level of AG (at each level of P) or P (at each level of AG) or the interaction between AG and P Where bars arent shown Lsd is less than size of symbol
89
The use of Red Mudgypsum in vegetable production
2 0 0 4 0 0 6 0 0 8 0 0 1 0 0 0 1 2 0 0
L e v e l o f r e s i d u a A G ( t ha )
2 0 0 4 0 0 6 0 0 8 0 0 1 0 0 0 1 2 0 0
L e v e l o f r e s i d u a l A G ( t h a )
Figure 72 Concentration (mgL) of NBU-N (A) and NO3-N (B) in leachate from Joel sand sown to carrots amended with residual AlkaIoamreggypsum (AG) in pots on 16 April 1996 (bull) 6 May 1996 (bull) and 22 July 1996 (A) The carrots were sown on 3 April 1996 N was fertigated at a constant concentration of 300 mgL (250 mgL of NO3-N and 50 mgL NH4-N) from sowing to harvest Vertical bars refer to Lsd (P lt 005) for differences in concentration between level of AG at each sampling time Where bars arent shown Lsd is less than size of symbol
The use of Red Mudgypsum in vegetable production
200 400 600 800 1000 1200
Level of AG (tha)
200 400 600 800
Level of AG (tha)
1 0 0 0 1 2 0 0
Figure 73 Concentration (mgL) of K (A) and Na (B) in leachate from Joel sand sown to carrots amended with residual Alkaloamreggypsum (AG) in pots on 16 April 1996 (bull) 6 May 1996 (bull) and 22 July 1996 (A) The carrots were sown on 3 April 1996 K was fertigated at a constant concentration of 200 mgL from sowing to harvest Vertical bars refer to Lsd (P lt 005) for differences in concentration between level of AG at each time Where bars arent shown Lsd is less than size of symbol
91
The use of Red Mudgypsum in vegetable production
Effect of level of residual AG and P on concentration of nutrients in plants The concentration of K P Fe Cu Mn and Mo in the youngest mature leaves (YML) of carrots at midgrowth all increased significantly with level of residual AG (Tables 75 (a) (b)) The concentration of S in YML at midgrowth was significantly reduced as level of residual AG increased whilst concentrations of Ca Na Mg Zn and B were variable
Table 75 Concentration of nutrients ( dry basis) in youngest mature leaves of carrot at midgrowth with level of residual Alkaloamreggypsum (AG) and phosphorus (P)
(a) Macronutrients
AG
AG (tha)
K1 Ca2 S2 P1 Na2 Mg2
0 486 229 061 025 050 039
125 584 186 060 033 047 034
250 585 216 058 033 044 035
1000 531 215 056 031 052 037
Lsd3 03 02 004 0017 005 003
Sig4
p
P (kgha)
K1 Ca2 S2 P1 Na2 Mg2
0 538 198 062 029 037 036
50 523 222 061 028 043 037
100 562 208 056 030 049 035
200 548 216 057 032 058 037
400 563 214 056 035 054 036
Lsd3 033 022 004 002 006 003
Sig4 ns ns ns
1 After Varley (1966) 2 After McQuaker et al (1979) 3 Least significant difference at P s 005 4 Significance at lt 0001 () lt 001 () lt 005 () level or not significant (ns)
The use of Red Mudgypsum in vegetable production
Table 75 Concentration of nutrients ( dry basis) in youngest mature leaves of carrot at midgrowth with level of residual Alkaloam gypsum (AG) and phosphorus (P)
(b) Micronutrients
AG
AG (tha)
Fe Mn1 Zn B Cu Mo
0 111 386 280 345 95 21
125 127 279 367 348 107 25
250 126 173 269 349 108 24
1000 114 60 143 337 110 31
Lsd2 20 47 40 15 05 06
Sig3 ns ns
p
p (kgha) Fe Mn Zn B Cu Mo1
0 135 243 263 356 120 28
50 122 240 268 349 111 30
100 109 191 229 343 106 25
200 116 228 268 334 99 23
400 115 221 294 341 89 20
Lsd2 23 52 45 15 051 07
Sig3 ns ns ns ns
1 After McQuaker et al (1979) 2 Least significant difference at P s 005 3 Significance at lt 0001 () lt 001 () lt 005 () level or not significant (ns)
Concentration of P S and Na in YML increased significantly (P lt 005) with level of applied P whilst concentrations of Cu and Mo decreased (Tables 75 (a) (b)) By contrast concentrations of K Ca Mg Fe Mn Zn and B were not significantly changed by level of applied P
93
The use of Red Mudgypsum in vegetable production
At harvest the concentration of P N K and Fe in whole tops increased significantly (P lt 005) with level of residual AG whilst concentration of S Mn Zn and B decreased (Table 76) The concentrations of Ca Na and Mg were variable with level of residual AG whilst there was no significant effect on the concentration of Cu
Table 76 Concentration of nutrients ( dry basis) in whole carrot tops at harvest with level of residual Alkaloamreggypsum (AG) and phosphorus (P)
(a) Macronutrients
AG
AG (tha)
N1 K1 Ca2 S2 P1 Na2 Mg2
0 300 503 269 071 016 093 039
125 348 649 239 065 024 090 035
250 395 653 251 061 022 082 033
1000 351 566 262 066 024 099 037
Lsd3 010 036 011 002 001 009 002
Sig4
p
p (kgha)
N1 K1 Ca2 S2 P1 Na2 Mg2
0 355 589 240 073 019 074 035
50 343 597 258 068 020 082 036
100 339 587 257 068 021 098 038
200 339 580 259 063 022 108 037
400 332 608 263 057 024 095 036
Lsd3 011 041 012 002 001 010 002
Sig4 ns
1 After Varley (1966) 2 After McQuakere al (1979) 3 Least significant difference at P s 005 4 Significance at lt 0001 () lt 001 () lt 005 () level or not significant (ns)
The use of Red Mudgypsum in vegetable production
Table 76 Concentration of nutrients ( dry basis) in whole carrot tops at harvest with level of residual Alkaloamreggypsum (AG) and phosphorus (P)
(b) Micronutrients
AG
AG (tha)
Fe1 Mn1 Zn1 B1 Cu1
0 299 962 234 402 109
125 316 952 184 404 107
250 331 662 110 380 110
1000 374 673 77 383 115
Lsd2 90 106 20 002 05
Sig3 ns ns
p
p (kgha) Fe1 Mn1 Zn1 B1 Cu1
0 294 969 158 409 125
50 392 837 144 393 117
100 364 747 141 396 114
200 267 712 159 387 105
400 332 bull 796 154 377 89
Lsd2 101 118 23 13 05
Sig3 ns ns
1 After McQuaker et al (1979) 2 Least significant difference at P lt 005 3 Significance at lt 0001 () lt 001 () lt 005 () level or not significant (ns)
As level of applied P increased concentration of P Ca and Na in whole tops increased significantly (P lt 005) whilst concentrations of N S Mn B and Cu decreased There was no significant effect of level of applied P on concentrations of K Fe or Zn in whole tops whilst concentration of Mg was variable
Effect oflevel of residual AG and P on carrot yield
There was a significant (P lt 005) increase in total and marketable yield with level of applied P at all levels of applied AG (Table 77) The overall effect of AG was to reduce both total and marketable yield at the highest level (1000 cf 0 to 2501 AGha) especially at low levels of applied P (ie 0 to 50 kg Pha) At higher levels of applied P yield at 2501 AGha was not significantly (P lt 005) lower than at 125 tha
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The use of Red Mudgypsum in vegetable production
However at 10001 AGha total and marketable yield was significantly lower than 0 tha at all levels of applied P The relationship between level of applied P and total yield was described as linear at 0 250 and 10001 AGha and Mitscherlich at 125 AG tha (Fig 76) As yield did not maximise at 0 250 and 1000 t AGha no optimal level of applied P for 95 or 99 of maximum yield could be determined At 125 t AGha the level of applied P necessary for 95 and 99 of maximum yield was 182 and 314 kg Pha respectively
Effect of level of AG and P on efficiency of P recovery by plants and retention in soil
The proportion () of P recovered in the carrot roots and tops decreased with level of applied P increasing from 8 to 12 to 5 to 8 of depending on level of AG (Table 78) There was a reduction in P recovered in roots tops and whole plant as level of AG increased For example P recovered by whole plants at 01 AGha at 400 kg Pha was 8 but this had declined to 5 at 10001 AGha
Table 78 The of applied fertiliser P taken up by carrots grown in pots (tops roots) retained in the topsoil or leached with level of residual Alkaloamreggypsum (AG) and phosphorus (P) on a Joel sand
P in Fraction AG P ( of P applied )
(tha) (kgha) TopsA Roots2 Plant(A+B) Soil2 Leached3
0 50 2 9 11 3 86
0 100 2 8 10 13 77
0 200 2 6 8 2 90
0 400 2 6 8 3 89
125 50 4 8 12 73 15
125 100 2 8 10 18 72
125 200 2 6 8 30 62
125 400 1 4 5 18 77
250 50 3 7 10 0 90
250 100 2 4 6 0 94
250 200 1 4 5 0 95
250 400 1 4 5 12 83
1000 50 2 6 8 75 17
1000 100 2 5 7 67 26
1000 200 2 5 7 45 48
1000 400 1 4 5 41 55
P in fraction expressed as of P applied as fertiliser 2 P retained in topsoil (0-15 cm) 3 P leached below 15 cm
By contrast of applied P retained in topsoil varied with level of AG For example only 3 of P was retained in topsoil at 400 kg Pha and 01 AGha where as this had increased to 41 at 10001 AGha at the same level of applied P Consequently the of P leached decreased as level of AG increased For example at 01 AGha and 400 kg Pha nearly 90 of applied P leached below 15 cm This had been reduced to 55 at 10001 AGha and the same level of applied P
97
The use of Red Mudgypsum in vegetable production
Table 79 Fertiliser P leached (kgha) and P leached as a of P applied from a Joel sand sown to carrots with level of residual Alkaloam gypsum (AG) and P after harvest The P was then applied as superphosphate prior to planting The carrots were sown on 3 April 1996 P leached is expressed as a percentage of P applied
AG (tha)
P (kgha)
P leached1
(kgha) P leached
( P applied)
0 50 41 82
0 100 78 78
0 200 158 79 0 400 311 78
125 50 2 4
125 100 3 3
125 200 10 5 125 400 27 7
250 50 1 2
250 100 3 3 250 200 4 2
250 400 7 2 1000 50 02 lt1 1000 100 05 lt1
1000 200 1 lt1
1000 400 2 lt1
1 Fertiliser P leached = total P leaclied - P leached at 0 kg Pha (ie background P) 2 (Fertiliser P leachedP applied x 100)
The use of Red Mudgypsum in vegetable production
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0 2 0 0 4 0 0 6 0 0 8 0 0 1 0 0 0 1 2 0 0
L e v e l o f r e s i d u a l A G ( t h a )
0 2 0 0 4 0 0 6 0 0 8 0 0 1 0 0 0 1 2 0 0
L e v e l o f r e s i d u a l A G ( t h a )
Figure 74 Concentration (mgL) of Ca (A) and Mg (B) in leachate from Joel sand sown to carrots amended with residual Alkaloamreggypsum (AG) in pots on 16 April 1996 (bull) 6 May 1996 (bull) and 22 July 1996 (A) The carrots were sown on 3 April 1996 Ca was applied preplanting as superphosphate and fertigated at a constant concentration of SO mgL from sowing to harvest AG was applied preplanting and in weeks 6 (15 May 1996) and 12 (25 June 1996) Vertical bars refer to Lsd (P lt 005) for differences in concentration between level of AG at each time Where bars arent shown Lsd is less than size of symbol
99
The use of Red Mudgypsum in vegetable production
CD
CO
x o CO CD
c o
bull4-
CO
c CD O c o O
0 2 0 0 4 0 0 6 0 0 8 0 0 1 0 0 0 1 2 0 0
L e v e l of r e s i d u a l A G ( t ha )
0 100 2 0 0 3 0 0 4 0 0
L e v e l of r e s i d u a l P ( k g h a )
5 0 0
Figure 75 The concentration of S (mgL) in leachate from Joel sands sown to carrots with level of residual Alkaloamreggypsum (AG) (A) and P (B) on 16 April 1996 (bull) 6 May 1996 (bull) 22 July 1996 (A) The carrots were sown on 3 April 1996 S was applied preplanting as K2S04 and in superphosphate Vertical bars refer to Lsd (P lt 005) for differences in concentration between level of AG (A) or P (B) at each sampling time Where bars arent shown Lsd is less than size of symbol
100
The use of Red Mudgypsum in vegetable production
ID
0 100 200 300 400 500
Applied P (kgha)
lb 70
70 C
60 65 -
60
55 dt
ha 50
40
50
45 bull A
Yie
30
40 _ 20
35 i i i i 35 0 100 200 300 400 5( 50 10
Applied p (kgha)
0 100 200 300 400 500
Applied P (kgha)
0 100 200 300 400 500
Applied P (kgha)
Figure 76 Total yield of carrots with level of freshly-applied P at four levels of residual Alkaloamreggypsum (AG) (A B C D = 01252501000 tha) Vertical dashed and whole lines refer to applied P necessary to 95 (dashed) or 99 (whole) of maximum yield respectively
The equations of the fitted lines are
A y = 10943 - 9377 x exp (-00053) (R2 = 099)
B y = 6l7- 2848 x exp (-00122) (i2 = 099)
C y = 3842+ 0083x (J2 = 097)
D y = 238 + 0l07x(R2 = 096)
As level of applied P increased concentration of P Ca and Na in whole tops increased significantly (P lt 005) whilst concentrations of N S Mn B and Cu decreased There was no significant effect of level of applied P on concentrations of K Fe or Zn in whole tops whilst concentration of Mg was variable
101
The use of Red Mudgypsum in vegetable production
Discussion
The addition of residual Alkaloamreggypsum (AG) resulted in a significant reduction in the concentration of P NH4-N K and Mg in the leachate from Joel sands sown to carrots in large pots The reduction in P concentration is attributed to an increase in the level of iron and aluminium oxides when AG is applied to soils low in these minerals (Barrow 1982) Consequently all soil measurements of P status or retention such as total P Colwell P and phosphorus retention index as well as Ec and pH all increased with level of applied residual AG Similar reductions in phosphorus leaching or increases in P retention have been reported when Gavin (Vlahos et al 1989) or Joel (Sections 4 and 5 McPharlin et al 1994 Robertson et al 1997) sands were amended with fresh or residual AG (Sections 4 and 6 Robertson et al 1994)
The reduced leaching of cations such as NH4-N K and Mg is attributed to an increase in captain exchange capacity (CEC) when sands of low CEC are amended with AG (Barrow 1982 McPharlin et al 1994) Consequently NO3-N retention is not increased when soils are amended with residual (Fig 72) or freshly-applied AG (McPharlin et al 1994) The increased leaching of Na Ca and S from amended sands is attributed to the Alkaloamreg as a source of these elements either in the Alkaloamreg itself (Na2C03) or after amendment with gypsum (CaS042H20) which precipitates CaC03 and Na2S04 The Na2S04 is very soluble as is easily leached whereas Ca is only slightly soluble as gypsum and insoluble as lime Vlahos et al (1989) reported increased leaching of Na Ca and S from Gavin sands treated with copper as (FeS04) amended Alkaloamreg compared with unamended controls in the short term and a decrease in the longer term Concentrations of P in the YML at midgrowth or tops at harvest increased with level of applied P and also with level of residual AG from 025 at 0 t AGha to 031 at 10001 AGha By contrast freshly-applied AG reduced the concentration of P in the YML from 043 on unamended to 030 on amended Joel sands (Robertson et al 1997) Even at the highest level of applied P the concentration of P in the YML 035 was still lower than that shown to be necessary for maximum yield of carrots (ie 038 McPharlin et al 1992) This could explain why the yield wasnt maximised in three out of the four AG treatments On the treatment that yield was maximised 125 t AGha the highest concentration of P ie 038 was recorded The difference in trends of P in petioles with AG between the 2 studies could be explained in terms of the relative leaching of P or addition of P in the AG itself On the virgin Joel sand used in the pot study leaching of P was significant enough to reduce leaf P in the unamended versus amended treatments For example the P in YML was significantly lower in the 01 AGha than at all other levels of residual AG at all levels of applied P up to 200 kgha For example the P in YML at 01 AGha ranged from 020 to 027 at 0 and 200 kg Pha respectively whilst at 125 t AGha the P was 032 to 038 over the same levels of applied P (Appendix 71) This suggests that loss of P from the top soil is severely limiting the uptake of P by the plant in the absence of AG The phosphorus retention of virgin Joel sands is almost negligible with a PRI of close to 0 (Table 72 McPharlin et al 1994 Robertson et al 1997) By contrast the P retention of Joel sands appears to be increased following development possibly by the addition of iron in irrigation water and organic and inorganic fertilisers For example the estimate of PRI (PREM) ie PRI plus P as Colwell P measured in the developed Joel sands used by Robertson et al was 40 in the topsoil (0-15 cm) of the unamended treatment Thus in these soils P retention is high enough to reduce availability when AG is added and explains the reduced levels of P in the YML as level of AG is increased The contribution of AG to the P nutrition of the plant is an unlikely explanation as it didnt increase P levels in the plant when applied fresh (Robertson et al 1997)
Previous work showed that concentrations of K in the petioles of potatoes (Section 4 Robertson et al 1997) and youngest mature leaves in cauliflower (Robertson et al 1994 Sections 5 and 6) declined with level of freshly-applied and residual AG
With potatoes the decline in K concentrations was associated with a decrease in K concentration in the soil solution and an increase in Na concentrations in soil solution and petioles on fresh and residual AG treatments (Section 4 Robertson et al 1997) This was
102
The use of Red Mudgypsum in vegetable production
used to explain yield reductions on fresh AG sites at gt 60 tha or on residual sites at 240 tha With cauliflower the findings were variable Where yield was reduced (Robertson et al 1994) it could not be explained in terms of K nutrition as K concentrations in the YML did not decline to levels expected to result in deficiency In follow up work neither fresh or residual AG up to 240 tha resulted in yield reduction although there was a reduction in K concentrations in the YML but not below critical levels (Sections 5 and 6) By contrast concentrations of K in the YML of carrots increased with level of residual AG up to 1000 tha as did exchangeable K in the soil Similar increases in K concentration in YML of Chinese and Head cabbage with level of AG on Joel sands have been reported previously (Robertson et al 1994)
Yield response of carrots to applied P at various levels of residual AG was variable on Joel sands in this work For example yield with level of applied P reach a plateau at 125 t AGha (ie 182 and 314 kg Pha for 95 and 99 of maximum yield from the Mitscherlich regression) However at other levels of applied AG including 0 tha yield had not maximised at the highest level of applied P (400 kgha) This is surprising considering that on higher P retaining soils such as Karrakatta sands yield is maximised at much lower levels of applied P (ie 160 to 180 kgha) at a similar low P soil test (McPharlin et al 1992 1994) in the absence of AG Also on Joel sands yields of carrots at medium to low P soil test (16 to 20 ugg Colwell P) only 50 kg Pha was necessary for maximum yield (McPharlin et al Lantkze and McPharlin unpublished data) The only possible explanation is that leaching of P was significant enough in the absence of AG that increased levels of applied P were required to satisfy crop requirements The increase in P fertiliser requirement as level of applied AG increases as shown in this work above 125 tha is similar to that reported previously for Chinese and Head cabbage cauliflower lettuce onions (Robertson et al 1994) and potatoes (Robertson et al 1997) It is explained by increased P retention capacity of the soil when AG is applied and measured by PRI Colwell and Total P and similar measurements
References
Allen DG and Jeffery RC (1990) Methods for analysis of phosphorus in Western Australian soils Chemistry Centre of Western Australia Report of Investigation No 37
Barrow NJ (1982) Possibility of using caustic residue from bauxite for improving the chemical and physical properties of sandy soils Australian Journal of Agricultural Research 33 275-285
Best EK (1976) An automated method for the determination of nitrate-nitrogen in soil extracts Queensland Journal of Agriculture and Annual Science 33 161-166
Colwell JD (1963) The estimation of phosphorus fertiliser requirements of wheat in southern New South Wales by soil analysis Australian Journal of Experimental Agriculture and Animal Husbandry 3 190-197
Hegney M A McPharlin IR and Jeffery RC (1997) Response of winter-grown potatoes (Solanum tuberosum L) to freshly-applied and residual phosphorus on a Karrakatta sand Australian Journal of Experimental Agriculture 37 131-137
McPharlin IR Alymore PM and Jeffery RC (1992) Response of carrots (Daucus carota L) to applied P and P leaching on a Karrakatta sand under two irrigation regimes Australian Journal of Experimental Agriculture 32 225-232
McPharlin IR Jeffery RC and Weissberg R (1994) Determination of the residual value of phosphate and soil test phosphorus calibration for carrots on a Karrakatta sand Communications in Soil Science and Plant Analysis 25 (5-6) 489-500
103
The use of Red Mudgypsum in vegetable production
McPharlin IR Robertson WJ Jeffery RC and Weissberg R (1995) Response of cauliflower to phosphate fertiliser placement and soil test phosphorus calibration on a Karrakatta sand Communications in Soil Science and Plant Analysis 26(3amp4) 607-620
McQuaker NR Brown DF and Kluckner PD (1979) Digestion of environmental materials for analysis by inductively coupled plasma-atomic emission spectrometry Analytical Chemistry 51 1082-1084
Reardon J Foreman JA and Serai RL (1966) New reactants for the determination of ammonia Clinica Chemica Acta 14 403-405
Robertson WJ McPharlin IR and Jeffery RC (1994) Final report of investigation into the use of gypsum-amended Red Mud as a soil-amendment for horticultural properties on the Swan Coastal Plain Final Report of HRDC Project No V0039 RO
Robertson WJ Jeffery RC and McPharlin IR (1997) Residues from bauxite-mining (Red Mud) increase phosphorus retention of a Joel sand without reducing yield of carrots Communications in Soil Science and Plant Analysis 28 (13 amp 14) 1059-1079
Varley JA (1966) Automatic methods for the determination of nitrogen phosphorus and potassium in plant material Analyst 91 119-126
Vlahos S Summers KJ Bell DT and Gilkes RJ (1989) Reducing phosphorus leaching from sandy soils with Red Mud bauxite processing residues Australian Journal of Soil Research 27 651-662
Walkley A and Black I (1934) An examination of the Degtjareff method of determining soil organic matter and a proposed modification of the chromic acid titration method Soil Science 37 29-38
Yuen SH and Pollard AG (1954) Determination of nitrogen in agricultural material by the Nessler reagent II Micro determination in plant tissue and soil extracts Journal of the Science of Food and Agriculture 5 364-369
104
The use of Red Mudgypsum in vegetable production
CO JC
5)
CD
sz o CD CD
0 200 400 600 800
Level of residual AG(tha)
1000 1200
Appendix 71 (b) P leached (kgha) from Joel sands sown to carrots amended with residual Alkaloanrgypsum (AG) in pots on 16 April 1996 (week 3) (bull) 6 May 1996 (week 6) (bull) and 22 July 1996 (week 16) ( bull ) P was applied preplanting as superphosphate and carrots were sown on 3 April 1996 Vertical bars refer to Lsd (P lt 005) for differences in quantities of P leached between level of AG (across all levels of applied P) at each sampling time Where bars arent shown Lsd is less than size of symbol Data from Appendix 71 (a)
105
The use of Red Mudgypsum in vegetable production
200 400 600 800
Level ofresidual AG(tha)
1 000 1 200
2 00
18 0 -
~ 160
copy
deg 1 40
1 2 0
100 -
80 200 400 600 800
Level of residual AG (tha)
1000 1200
Appendix 73 (b) 74 (b) Ammonium-N (A) and Nitrate-N (B) leached (kgha) from Joel sands sown to carrots amended with residual Alkaloamreggypsum (AG) in pots on 16 April 1996 (week 3) (bull) 6 May 1996 (week 6) (bull) and 22 July 1996 (week 16) (A) N was fertigated postplanting as NH4-N and NO3-N and carrots were sown on 3 April 1996 Vertical bars refer to differences in quantities of N leached between level of AG (across all levels of applied P) at each sampling time Where bars arent shown Lsd is less than size of symbol Data from Appendices 73 (a) 74 (a)
106
The use of Red Mudgypsum in vegetable production
A 1 8 0
1 6 0
1 4 0
1 2 0 -
1 0 0
8 0
6 0 -
4 0 - I~~ - ^ gt ^
2 0
I
^ - ^ 1 0
I i i i i i
2 0 0 4 0 0 6 0 0 8 0 0
L e v e l o f r e s i d u a l AG (th a )
1 0 0 0 1 2 0 0
2 0 0 4 0 0 6 0 0 8 0 0
L e v e l o f r e s i d u a l A G ( t h a )
1 0 0 0 12 00
Appendix 75 76 K (A) and Na (B) in leachate from Joel sand sown to carrots amended with residual Alkaloamreggypsum (AG) in pots on 16 April 1996 (week 3) (bull) 6 May 1996 (week 6) (bull) and 22 July 1996 (week 16) (A) The carrots were sown on 3 April 1996 K was fertigated at a constant concentration of 200 mgL from sowing to harvest and Na was a constituent of AG Vertical bars refer to Lsd (P lt 005) for differences in quantities of K and Na leached between level of AG (across all levels of applied P) at each time Where bars arent shown Lsd is less than size of symbol
107
The use of Red Mudgypsum in vegetable production
40
ha
)
35 ^ D )
30 bull o
25 o CD jD 20 O )
^ 1 5
1 0
5
200 400 600 800 1000 1 2 0 0
L e v e l of r e s i d u a l AG ( t ha)
200 4 0 0 600 800 1000 1 2 0 0
L e v e l of r e s i d u a l AG ( t ha)
Appendix 77 78 Ca (A) and Mg (B) in leachate from Joel sand sown to carrots amended with residual Alkaloamreggypsum (AG) in pots on 16 April 1996 (bull) 6 May 1996 (bull) and 22 July 1996 (A) The carrots were sown on 3 April 1996 Ca was applied preplanting as superphosphate (and as a constituent of AG) and fertigated at a constant concentration of 50 mgL from sowing to harvest Mg was applied preplanting and in weeks 6 (15 May 1996) and 12 (25 June 1996) Vertical bars refer to Lsd (P lt 005) for differences in quantity of Ca and Mg leached between level of AG (across all levels of applied P) at each sampling time Where bars arent shown Lsd is less than size of symbol Data from Appendices 77 (a) and 78 (a)
108
The use of Red Mudgypsum in vegetable production
200 400 600 800
Level of residual AG(tha)
1000 1200
Appendix 79 S (mgL) in leachate from Joel sands sown to carrots with level of residual Alkaloamreggypsum (AG) 16 April 1996 (week 3) (bull) 6 May 1996 (week 6) (bull) 22 July 1996 (week 16) (A) The carrots were sown on 3 April 1996 S was applied preplanting as K2S04 in superphosphate and as a constituent of AG Vertical bars refer to Lsd (P lt 005) for differences in quantity of S leached between level of AG (A) or P (B) at each sampling time Where bars arent shown Lsd is less than size of symbol Data from Appendix 79 (a)
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t ^ O N N o r ~ v ) i n N O O N e s i n copy O N T ) - copy 0 0 N O copy e s ^ lt O N e s r ~ 0 0 ^ - gt mdash i N o e s e s e n r -ON es_ en ON NCI 00 ltmdashi mdashH lt-H ON en t~- copy ON copy -i -H OO copy vi en ON VI OCI es| r~_ r~- C- ON en 00 NO vi ON ON CO copy od ON r~ NO OO O vi mdashlt ON r- bull es copy vi es bull es ON bulllaquo vi bulllt NO en bull rt bull ON oooocooooNOO^inenenTj-t-~NONor--r--t~-r~-r--r~r--r--r--^---
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r - ~ N O i n e n o o o o copy copy - H i n copy - i N O O O e s copy gt i - copy copy i n T t N O v i e n o O N O N O O N i mdash i t ^ m T f o o O N N O ^ e s e n r ~ copy i n v i c O N O - H i n e n copy - H ^ H T r O N t ^ i n - ^ N O r - - o o i n o o o O e n r - -oo vi ON -^ vi copy en copy f- en ON OO ON r~- es copy NCi lt-lt lt- r~ vi copy copy vi copy es oo --i es bull vi copy i n N o v i N O v i N O mdash l e s mdash i e s mdash i - H - n e S - H e s e s e S mdash I O N copy copy mdash I copy O copy O N copy copy -H
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The use of Red Mudgypsum in vegetable production
3 PUBLICATIONS ARISING OUT OF WORK Robertson WJ McPharlin IR and Jeffery RC (1997) The growth nutrition and
composition of potatoes (Solarium tuberosum L) cv Delaware grown on a yellow Karrakatta sand amended with freshly-applied and residual Alkaloamreggypsum Australian Journal of Experimental Agriculture (submitted)
McPharlin IR dAdhemar G and Shimmin TR (1997) The response of cauliflowers (Brassica oleraceae L) cv Plana to freshly-applied and residual Alkaloamreggypsum and phosphorus on a Karrakatta sand Australian Journal of Experimental Agriculture (in prep)
McPharlin IR Shimmin TR and dAdhemar G (1997) Leaching of P N and cations from carrots grown on Joel sands amended with residual Alkaloamreggypsum Communications in Soil Science and Plant Analysis (in prep)
The use of Red Mudgypsum in vegetable production
4 RESPONSE OF POTATOES TO FRESHLY-APPLIED AND RESIDUAL RED MUD (ALKALOAMreg)GYPSUM AND PHOSPHORUS ON A YELLOW KARRAKATTA SAND
Introduction
Previous work has shown that freshly-applied Alkaloamreggypsum (gypsum-amended red mud 10 ww) (AG) at 60 and 120 tha reduced the total yield of potatoes by 7 and 23 respectively compared with 01 AGha controls (Robertson et al 1994 Appendix 1 J) The reduction in marketable yield was almost identical to the reduction in total yield The exact cause of this reduction in yield could not be determined particularly the reduction at 120 tha It was unlikely to be a reduced availability of P Observations on commercial properties suggest that AG which has been in the soil for several seasons does not cause yield reductions in potatoes
Phosphorus was banded at planting in this experiment Subsequent work (Hegney and McPharlin unpublished data) showed that broadcasting P allowed a greater maximum yield of potatoes than banding P on Karrakatta sands of low P fertility
This experiment re-examines the response of potatoes to freshly-applied AG using broadcast P and also the effect of residual AG on growth of potatoes at unlimiting P
Materials and methods
Site characteristics
The experiment was conducted on a yellow Karrakatta sand (described by McArthur and Bettenay 1960) at Medina approximately 30 km south of Perth Two sites were used a site where pasture species had been grown several years earlier and to which no AG had ever been applied and a second (adjacent) site where AG had been applied approximately 2J2 years earlier A lettuce and a cauliflower crop had been grown previously on this site after AG amendment (Robertson et al 1994 Appendix 1H I)
Red Mud (Alkaloamreg)gypsum (AG)
Red Mud (Alkaloamreg)gypsum (10 ww) (AG) was produced by the dry mix process by ALCOA of Australia Ltd at their Kwinana Residue Treatment Plant It was spread manually on the previously unamended site on 22 December 1994 and was incorporated to a depth of approximately 30 cm using a rotary hoe The AG on the previously-amended site (residual AG) was applied using the same techniques on 24 November 1992 The freshly-applied AG was watered for 1 hour three times a week until planting
Experimental design
The freshly-applied and residual AG sites were used for separate experiments which were conducted simultaneously The experiment on the freshly-applied AG was a split-plot randomised complete block design with three replicates Main plots were levels of AG (0 60 90 and 120 tha) and sub-plots were levels of P application (0 25 50 100 300 and 600 kgha) Main plots measured 48 x 21 m and sub-plots measured 24 x 7 m (three rows of potatoes with 08 m between row centres) There was a 2 m buffer around each main plot The experiment on the residual AG site was a randomised complete block design with 4 levels of AG (0 60 120 and 240 tha) and three replicates The levels of AG were applied in November 1992 and had had several levels of P applied to them in the previous crops The AG plots measured 6 x 12 m but only an area of 34 x 8 m (4 rows of potatoes with 08 m between row centres) was cropped to allow a buffer of 1 to 2 m all around the planted area
6
The use of Red Mudgypsum in vegetable production
Crop management Both sites were initially sprayed with Roundupreg (3 Lha) to kill weeds and the sites were hoed with a rotary hoe Freshly-applied AG was applied at this stage The residual AG site was treated with metham sodium approximately two weeks before planting Potatoes cv Delaware were planted on both sites on 18 May 1995 using a single row mechanical planter Round seed was used and this was dusted with Rizolexreg (2 kgt) immediately before planting Sets were planted 15 cm apart The crops were irrigated using impact sprinklers once daily at 80 of Class A pan evaporation between planting and emergence and then at 100 of evaporation Afalonreg (15 kgha) was applied after planting and Sprayseedreg (2 Lha) was applied at 5 emergence both for weed control Nitofol (700 rnLha) was used for regular insect control Bravoreg (2 Lha) was applied every seven days from the time of 50 ground cover until blight symptoms appeared at which time it was then alternated with Rovralreg (2 Lha) at 7 day intervals Both crops were harvested on 15 November 1995
Fertilisers
Pre-planting fertilisers were broadcast by hand on 15 May 1995 on freshly-applied AG and on 16 May on residual AG These were 83 kg Kha as K2S04 10 kg Mgha as miso47H20 and a complete trace element mix containing (kgha) MnS04H20 (504) MgS047H20 (560) borax (336) FeS047H20 (336) CuS045H20 (336) ZnS04H20 (280) and Na2Mo042H20 (224) Single superphosphate (91 P) was broadcast by hand at 0 to 600 kg Pha on freshly-applied AG according to the treatment and at 600 kg Pha on all plots on residual AG Post-planting fertilisers were a total of 500 kg Nha as NH4NO2 and KN02 and 400 kg Kha as KN02 in equal amounts for 10 weeks via the irrigation system An extra 50 kgha MgS04 was applied in weeks 7 and 9
Measurements
(a) Plant
The petioles of the Youngest Mature Leaf (YML) often plants were collected at the S2 stage (longest tuber 10 mm long) (19 July 1995) on both freshly-applied and residual AG They were dried in a forced draught oven at 70degC and then analysed for P N K Na Ca Mg S B Cu Fe Mn and Zn On freshly-applied AG tubers were harvested from a 5 m length of the middle row of each plot On residual AG a 4 m length of the two middle rows of each plot was harvested Tubers were separated into the following size grades lt 30 g 30-80 g 80-250 g 250-450 g and gt 450 g Tubers between 30 g and 450 g were considered marketable except if they were green or damaged
Of the tubers in the 80-250 g category ten were sampled from each plot for P analysis They were washed in tap water and sliced thinly with a stainless steel knife Fresh and dry weights were measured before the tubers were analysed for total P
(b) Soil
All 0 kg Pha plots on freshly-applied AG were sampled to 15 cm depth (15 cores per plot) on 29 August (approximately 3 months after planting) They were analysed for Bicarbonate-extractable P (Bic-P) (Colwell 1963) total P EC pH (H20) pH (CaCl2) Phosphorus Retention Index (PRI) (Allen and Jeffery 1990) and P buffering capacity (Ozanne and Shaw 1968) Before fertilisers were applied to the residual AG site on 16 May 15 cores (0-15 cm) were sampled from each plot and analysed for Bic-P and PRI Residual AG plots were sampled again on 29 August (0-15 cm 15 cores per plot) and analysed for pH (H20) pH (CaCl2) EC and P buffering capacity All residual AG plots and 0 100 and 600 kg Pha freshly-applied AG plots were sampled to three depths (0-15 15-30 and 30-45 cm) (20 cores per plot) on 5 December (ie after harvest)
7
The use of Red Mudgypsum in vegetable production
Chemical analysis
Plant samples were ground to pass through a 1 mm screen after drying Concentrations of P N K and Na were measured by digesting the samples with sulphuric acid and hydrogen peroxide (Yuen and Pollard 1954) N and P were determined colorimetrically by indophenol blue and molybdo-vanadate methods respectively K and Na were determined by flame photometry All analysis was conducted on a 4-channel Auto-analyser system using modifications of Technicon procedures (Anon 1977) Samples for analysis of Ca Mg S Cu Fe B Mn and Zn concentrations were digested with nitricperchloric acids (McQuaker et al 1979) Concentrations were measured by inductively-coupled plasma atomic emission spectrometry (ICP-AES) Concentrations of heavy metals were determined using inductively-coupled plasma mass spectrometry (ICP-MS) with indium as an internal standard Samples were initially crushed in an agate mortar and digested using nitric and perchloric acids
All soil samples were dried at 40degC in a forced draught oven Lumps of AG and fertiliser in samples were crushed and the samples were thoroughly mixed and sieved to lt 2 mm before analysis The pH (H20) and the EC were determined on a 15 soilwater extract after shaking for 1 hour The pH (CaCl2) was determined on 15 soiksolution extract using 001 M CaCl2 after shaking for 1 hour Values for both are corrected to 25 degC Total P was determined on a Kjeldahl digest of a separate sub-sample of soil ground to less than 015 mm The concentration of phosphate was measured by the method of Murphy and Riley (1962)
Statistical analysis
All data were analysed by an Analysis of Variance (ANOVA) using Genstat v 50 Results from the two experiments were analysed separately Data from the freshly-applied AG site was analysed by a two-way ANOVA on level of Alkaloamreg and level of applied P while data from residual Alkaloamreg were analysed by a one-way ANOVA on level of AG Statistical differences were determined using a Least Significant Difference at 5 level of significance where the F value from the ANOVA was significant Mitscherlich curves were fitted to all relationships between level of applied P and yield petiole or tuber P concentration or total P uptake Maximum values of Mitscherlich equations were compared using a 5 t-test Linear relationships were fitted to the yield response on residual Alkaloam versus level of AG and also to the relationship between yield and petiole P concentration on freshly-applied AG
The amount of fertiliser P retained was calculated by subtracting total P at 0 kg Pha from the measured total P value Concentrations of P in ugg were converted to kilograms per hectare by multiplying by a factor of 225 This is based on the assumption that there are 2250 t soilha in the top 15 cm of soil
Results and discussion
Soil characteristics
The pH (H20) of the top 15 cm of soil at mid-growth when no P fertiliser was applied increased from 72 on unamended soil to 84 and 85 on amended soil (Table 41) EC also increased from 5 mSm on unamended soil to 8 and 9 mSm on amended soil (Table 41) Bic-P was approximately 10 ugg at all AG levels and total P ranged from 55 ugg on unamended soil to 76 ugg at 901 AGha (Table 41) PRI and P buffering capacity (Pbug) both increased between unamended and amended soil but there were no differences between levels of AG on amended soil PRI of amended soil was 26 to 30 and Pbuff was 24 to 30 (Table 41)
The Bic-P and PRI measurements taken two days before planting on residual AG were the same at all levels of AG Bic-P was 16 to 21 ugg and PRI was 37 to 53 (Table 42) On the other hand Pbuff measured mid-growth increased from 20 at 01 AGha to 30 and 40 at 120 and 2401 AGha The EC was 7-9 mSm on all treatments and pH (H20) increased between 0 and 120 t AGha from 73 to 84 (Table 42)
The use of Red Mudgypsum in vegetable production
Table 41 Characteristics of the top 15 cm of a Karrakatta sand amended with several levels of freshly-applied Alkaloamreggypsum (AG) when no fertiliser P was applied
AG (tha)
pH (H20)
pH (CaCl2)
EC (mSm)
Bic-P (ugg)
Total P (ugg)
PRI Pbuff
0 72 64 5 8 55 19 14
60 84 77 8 10 64 26 24
90 85 78 9 11 76 30 30
120 85 83 9 10 71 27 27
Signif NS NS $
Lsd 5 04 05 3 07 05
Table 42 Characteristics of the top 15 cm of a Karrakatta sand amended with several levels of residual Alkaloamreggypsum (AG) when 600 kg Pha was applied as superphosphate
AG (tha)
pH (H20)
pH (CaCl2)
EC (mSm)
Bic-Pa
(ugg) PRIa
Pbuff
0 73 67 7 16 37 20
60 78 71 5 17 40 23
120 84 77 9 20 44 30
240 88 80 9 21 53 40
Signif NS NS NS
Lsd 5 05 06 10
K Sampled and measured before application of fertiliser P
Total phosphorus in soil
Total P in the soil at harvest on freshly-applied AG increased significantly with level of AG averaged over all three depths sampled (P lt 005) It also increased with level of applied P on all levels of AG At 0-15 cm total P increased significantly between 0 and 601 AGha At 15-30 cm it increased significantly between 0 and 90 t AGha and at 30-45 cm there was no effect of level of AG at all (Fig 41) At all levels of AG and P which were sampled total P concentrations at 0-15 cm and 15-30 cm were not significantly different from each other and both were significantly greater than those at 30-45 cm (Fig 41)
In the top 15 cm of soil total P increased from 47 ugg on unamended soil to 62-67 ugg on amended soil when no fertiliser P was applied This increase represents the total P content of the AG itself When 100 kg Pha was applied total soil P (0-15 cm) increased from 63 ugg at 01 AGha to 83 ugg at 601 AGha and 95 and 103 ugg at 90 and 1201 AGha (Fig 41) When the increase due to the AG itself is considered this is an increase in fertiliser P retention of 6 ugg (26 kgha) between 0 and 601 AGha and a further 14 ugg (62 kgha) between 60 and 120 t AGha At 600 kg Pha the increase in fertiliser P retention was 35 ugg (15 kgha) between 0 and 601 AGha and 25 ugg (11 kgha) between 60 and 120 t AGha
Total P on residual AG increased with level of AG The increase was significant between 60 and 1201 AGha only It also decreased at increasing depth As observed on freshly-applied AG total P concentrations at 0-15 cm and 15-30 cm were not significantly different from each other and were both greater than that observed at 30-45 cm (Fig 43) At 0-15 cm total P increased by 20 ugg between 0 and 601 AGha and by a further 213 ugg between 60 and 1201 AGha when 600 kg Pha was applied These values cannot be corrected for the total content of AG itself as there was no 0 kg Pha treatment
9
The use of Red Mudgypsum in vegetable production
The addition of freshly-applied AG to the soil substantially increased the theoretical ability of the soil to sorb applied P as measured by the P buffering capacity in the top 15 cm of soil However it was reduced over time as 1201 AGha was required to increase Pbuff on residual AG compared with 601 AGha on freshly-applied AG Fertiliser P retention in the top 15 cm of soil when amended with 1201 AGha was increased by 9 at 100 kg Pha and by 4 at 600 kg Pha
The effects of residual and freshly-applied AG can be compared at 600 kgha of applied P The effect of residual AG on fertiliser P retention can be estimated from measurements made on the same site at the beginning of the first (lettuce) crop In that experiment total P before the application of P fertilisers increased from 69 and 62 ugg on 0 and 601 AGha to 91 ugg on 1201 AGha and 103 ugg on 2401 AGha (Robertson et al 1994 Appendix 1H) This makes the estimated increase in fertiliser P retention (0-15 cm) 27 ugg (12 kgha) between 0 and 601 AGha and 184 ugg (81 kgha) between 60 and 1201 AGha Therefore between 60 and 1201 AGha residual AG increased fertiliser retention by approximately 7 times as much as did freshly-applied AG
Bicarbonate-extractable P (soil-test P) in soil
On freshly-applied AG there was no overall response of Bic-P to level of AG although there was an upward trend Bic-P decreased with increasing depth averaged over all treatments following the same response as total P There was an interaction between the effects of depth and level of applied P At 0 kg Pha there was no difference in Bic-P between the three depths sampled but at 100 and 600 kg Pha Bic-P concentrations at 0-15 cm and 15-30 cm were both greater than those at 30-45 cm (Fig 42) The upward trend in Bic-P with increasing level of AG was weak on soil where no P fertiliser had been applied being from 9-10 ugg at 0 and 601 AGha to 11 and 14 ugg at 90 and 1201 AGha in the top 15 cm This suggests that the AG adds little if any plant available P to the soil The amount of fertiliser P retained as Bic-P in the top 15 cm of soil when 100 kg Pha was applied increased by 8 ugg between 0 and 601 AGha and by a further 4 ugg between 60 and 120 t AGha At 600 kg Pha Bic-P retained from fertiliser increased by 34 ugg between 0 and 601 AGha and by 16 ugg between 60 and 1201 AGha
The response of Bic-P to level of residual AG and to depth was the same as for total P (Fig 43) In the top 15 cm of soil Bic-P increased by 11 ugg between 0 and 601 AGha and by 82 ugg between 60 and 1201 AGha uncorrected for the Bic-P content of the AG itself
The increase in Bic-P retention observed on amended soil at 100 kg Pha was similar to that observed at 160 kg Pha on a crop of carrots grown on a Joel sand amended with AG (Robertson et al 1997) Using the soil-test standards published by Hegney et al (1997) these increases in Bic-P will reduce the P fertiliser requirement in the following potato crop by 10 at 601 AGha and 22 at 1201 AGha
Using the Bic-P concentrations observed on the residual site at the beginning of the lettuce crop (Robertson et al 1994 Appendix 1H) the increase in fertiliser P retained as Bic-P (0-15 cm) on residual AG was 15 ugg between 0 and 601 AGha and 79 ugg between 60 and 1201 AGha This is half the increase observed on freshly-applied AG between 0 and 60 t AGha and approximately 5 times that observed on freshly-applied AG between 60 and 1201 AGha
The reduced P retention at low levels of residual AG compared with freshly-applied AG was probably because of the higher initial Bic-P levels on residual AG For both total and Bic-P it is difficult to explain why the apparent retention of fertiliser P between 60 and 120 t AGha should have been so much greater on residual than on freshly-applied AG It may have been caused by changes to the chemical properties of the AG as it aged in the ground
10
The use of Red Mudgypsum in vegetable production
Yield
Total and marketable yields on freshly-applied AG both increased with level of applied P following a Mitscherlich response (Fig 44 (a) (b)) An ANOVA did not indicate any response to level of AG in either total or marketable yields However maximum total yield on unamended soil (61 tha) was significantly greater than that on AG-amended soil - 54 to 57 tha (Fig 44 (a)) On the other hand there were no differences in maximum marketable yields Maximum marketable yield values ranged from 52 to 55 tha (Fig 44 (b)) When marketable yield was calculated as a percentage of total yield an ANOVA indicated a significant interaction between level of AG and level of applied P At 400 kg Pha marketable yield was 88 of total yield on unamended soil compared with approximately 95 on amended soil (significant according to 5 Lsd) A similar trend was observed at 600 kg Pha where marketable yield was 90 of total yield on unamended soil and 93 to 96 on amended soil
The levels of applied P required for 99 of maximum total yield were 245 222 183 and 400 kg Pha on 0 60 90 and 1201 AGha and for 95 of maximum yield were 139 130 108 and 226 kg Pha (Fig 44 (a)) A similar trend can be seen for marketable yield where 99 of maximum yield required 178 206 208 and 356 kg Pha (Fig 44 (b))
Total yield on residual AG showed an almost significant response to level of AG (P = 0067) (Fig 45) Total yield was 68 to 72 tha on 0 60 and 120 t AGha and 62 tha on 2401 AGha Marketable yield was 65 to 68 tha on 0 to 1201 AGha and 58 tha on 2401 AGha Therefore 2401 AGha appears to reduce yields even when it has been in the ground for 2 years or more and even when 600 kg Pha is applied As only one level of P fertiliser was applied it is not possible to determine the effect of residual AG on the critical levels of P application required for 99 and 95 of maximum yield
Concentration of nutrients in petioles
Phosphorus
Phosphorus concentration in petioles of the YML sampled at the S2 stage on freshly-applied AG increased with level of applied P following a Mitscherlich response (Fig 46) Maximum petiole P concentrations were approximately 12 (dry basis) on all AG levels Values at 99 of maximum petiole P concentration were 116 122 117 and 116 at 0 60 90 and 1201 AGha There was a significant interaction between levels of AG and applied P (P lt 005) At low levels of applied P (25 50 and 100 kgha) P concentrations on amended soil were significantly less than those on unamended soil but there was no difference between them at 300 or 600 kg Pha This is reflected in the levels of applied P required for 99 of maximum petiole P concentration which were 209 499 581 and 508 kg Pha at 0 60 90 and 1201 AGha This is an increase of 138 on amended soil relative to unamended soil AG at levels of between 60 and 120 tha therefore reduces the availability of P to plants As there was no difference in the maximum P concentration in petioles between amended and unamended soil a reduction in P availability to plants cannot explain the reduced maximum yield on amended soil Another factor was therefore involved in reducing maximum yield on amended soil Despite this yield difference between amended and unamended soil which was not related to differences in P concentration total yield for all AG levels combined was linearly correlated with petiole P concentration at the S2 stage (y = 256 + 274x R2 = 087) (Fig 47)
The petiole P concentration at 99 of maximum total yield was 116 109 095 and 114o at 0 60 90 and 1201 AGha At 01 AGha this was the same as 99 of maximum petiole P concentration implying that the yield response on unamended soil was controlled principally by P availability On the other hand petiole P concentrations at 99 of maximum yield on amended soil especially 60 and 901 AGha were less than 99 of maximum petiole P concentration In other words yield stopped increasing even though P concentration in the plant kept increasing This supports the previous observation that some factor other than P was limiting yield in these treatments Petiole P concentration in YMLs sampled at S2 stage on residual AG did not change with level of AG Overall mean P concentration was 12 dry
11
The use of Red Mudgypsum in vegetable production
basis This is in keeping with the results observed on freshly-applied AG at 600 kg Pha It also means that the lower yield at 2401 AGha on residual AG could not be explained by a reduced P concentration in the plant As on freshly-applied AG another factor was involved which reduced yield on amended soil although at a higher level on residual than on freshly-applied AG
Hegney et al (1997) found that maximum petiole P concentration at S2 in potatoes grown on Karrakatta sand was 114 dry basis and that 109 was required for 99 of maximum yield in good agreement with the results observed here
Other nutrients
The responses of nutrients other than P were very similar on both freshly-applied and residual AG Concentrations of K (Tables 43 45) and Zn (Fig 48 (a) Table 45) decreased as level of AG increased and concentrations of Mg Fe and Ca increased with level of AG in both experiments (Tables 43 45 Fig 48 (b)) Zn concentrations also decreased with increasing level of applied P (Fig 49 (a)) while Ca concentrations increased with level of applied P (Fig 48 (b)) Concentrations of Na also showed an upward trend on both freshly-applied and residual AG (Tables 43 45) On freshly-applied AG K concentrations decreased significantly from 119 dry basis on unamended soil to 110 at 601 AGha and to 102 at 1201 AGha (Table 43) On residual AG it decreased from 11-12 at 0-1201 AGha to 103 at 2401 AGha (Table 45) No other nutrients showed any response to level of AG although concentrations of N Mn S and B increased with level of applied P on freshly-applied AG (Table 44)
Concentrations of all nutrients except K were adequate or more than adequate for maximum yield (Maier et al 1987) on both freshly-applied and residual AG Potatoes require concentrations of approximately 12 to 14 K (dry basis) in petioles of YML for maximum yield (Maier et al 1987) On freshly-apphed AG concentrations were adequate at 01 AGha but were less than adequate on amended soil On residual AG concentrations were adequate at 0 60 and 1201 AGha but less than adequate at 2401 AGha As less than adequate K concentrations correspond with those treatments which had low yield it is likely that K concentration was the limiting factor in yield on both freshly-applied and residual AG
Uptake of K may have been reduced at higher levels of AG due to an increased Cation Exchange Capacity (Barrow 1982 McPharlin et al 1994) or to the increased soil pH (Harris 1992) The reduction in Zn availability on amended soil is most likely to be a result of the increase in soil pH due to the AG (Harter 1983)
Table 43 Concentrations of several nutrients in the petioles of the Youngest Mature Leaf of potato plants sampled at the 10 mm tuber stage at several levels of freshly-applied Alkaloamreggypsum (AG) on a yellow Karrakatta sand
AG K Na Mg Fe (tha) () () () (ngg)
0 119 018 059 382
60 110 020 065 553
90 106 021 066 597
120 102 021 069 697
Signif NS
Lsd 5 04 004 119
12
The use of Red Mudgypsum in vegetable production
Table 44 Concentrations of several nutrients in the petioles of the Youngest Mature Leaf of potato plants sampled at the 10 mm tuber stage at two levels of applied P when grown on a yellow Karrakatta sand amended with freshly-applied Alkaloamreggypsum (AG)
Applied P N S Cu Mn B (kgha) () () (ngg) (ngg) (M-gg)
0 44 028 74 293 267
600 48 032 62 342 248
Signif NS NS
Table 45 Concentrations of several nutrients in the petioles of the Youngest Mature Leaf of potato plants sampled at the 10 mm tuber stage at several levels of residual Alkaloamreggypsum (AG) on a yellow Karrakatta sand
AG N K Na Ca S Mg Cu Fe Mn Zn B (tha) () () () () () () (l-igg) (ngg) (ngg) Ws) (^gg)
0 51 116 016 23 030 050 77 453 46 96 26
60 48 127 015 21 027 045 61 457 45 67 25
120 49 120 016 26 029 051 66 643 59 59 25
240 49 103 019 29 030 067 54 977 53 53 24
Signif NS NS NS NS NS NS
Lsd5 05 04 013 164 24
Tuber P and Crop P removal P concentration in tubers
The concentration of P in tubers on freshly-applied Alkaloamreg increased with level of applied P (P lt 0001) The response at each level of Alkaloamreg was best described by a Mitscherlich curve although none of the curves reached a maximum within the range of fertiliser P levels used (Fig 49 (a)) There was a trend for an overall response to level of AG (P = 0081) P concentrations were generally higher on unamended soil than on amended soil For example at 300 kg Pha P concentration was 033 on unamended soil and 026-028 on amended soil and at 600 kg Pha P concentrations were 036 and 032-033 on unamended and amended soil respectively At P levels corresponding to 99 of maximum yield tuber P concentration was 031 024 023 and 028 at 0 60 90 and 1201 AGha
On residual AG tuber P concentration did not change with level of AG The overall mean was 036 dry basis
Total P uptake
Total P uptake by tubers on freshly-applied AG showed a significant response to level of AG (P lt 005) and level of applied P (P lt 0001) The response to applied P at each level of AG was best described by a Mitscherlich curve although as for tuber P concentration none of the curves reached a maximum within the range of P levels applied P uptake by tubers on unamended soil was significantly greater than on amended soil regardless of AG level (Lsd 5) (Fig 49 (b)) At levels of applied P corresponding to 99 of maximum yield P uptake by tubers was 113 75 75 and 95 kgha at 0 60 90 and 1201 AGha These figures are lower than results reported by Hegney et al (1997) who found a P uptake by tubers grown on yellow Karrakatta sand of 204 kgha at 99 of maximum yield even though yields were similar to those observed on unamended soil in this experiment
13
The use of Red Mudgypsum in vegetable production
Total P uptake by tubers was not significantly different between AG levels on residual AG Overall mean P uptake was 110 kgha This is different from the situation observed at 600 kg Pha on freshly-applied AG As only one level of P was applied the response curve for tuber P concentration on residual AG cannot be compared with that on freshly-applied AG It is possible that less applied P is required on residual than on freshly-applied AG to reach maximum tuber P concentration
Metals in tubers
The concentration of As in tubers harvested from freshly-applied AG showed a trend to increase with level of AG from 5 x 104 mgkg (fresh weight) on unamended soil to 8 x 104 mgkg at 60 and 901 AGha (Fig 410) Concentrations of all other metals measured showed no response to level of AG either on residual or freshly-applied AG (Table 46 47) On freshly-applied AG concentrations of Ni and Cd increased and concentrations of Cu decreased with increasing level of applied P (Table 48)
Table 46 Mean concentrations (mgkg fresh weight) of metals in tubers of potato cv Delaware harvested from a yellow Karrakatta sand amended with freshly-applied Alkaloam^gypsum (AG)
Cr Co Sn Sb Hg
mean
se
0007
61 xlO5
60 x 104
50 x 106
15 x 103
10 x 104
90 x 105
10 xlO5
34 x 104
14 x 105
Table 47 Mean concentrations (mgkg fresh weight) of metals in tubers of potato cv Delaware harvested from a yellow Karrakatta sand amended with residual Alkaloamreggypsum (AG)
Cr Co Ni Cu As Cd Sn Sb Hg Pb
mean
se
001
68X104
72xl(f 29xia5
55xia3
17x1a4
010
35xia3
L2X103
0
58xia3
17X104
LOxlO3
29X104
30X1O4
43xl05
84X1G4
ii xia5
l ixia3
70xia5
Table 48 Mean concentrations (mgkg fresh weight) of metals in tubers of potato cv Delaware harvested from a yellow Karrakatta sand amended with freshly-applied Alkaloamreggypsum (AG) at various levels of applied P
Applied P (kgha)
Ni Cd Cu
0 0006 0002 018
100 0006 0002 016
300 0007 0004 015
600 0008 0006 013
Signif
Lsd (5) 00014 0001 002
The concentrations of As observed in tubers from freshly-applied AG regardless of the level of AG were less than 10 of the legal limit (10 mgkg fresh weight NFA 1992) The concentrations of all metals measured were between 3 and 33 of those measured in potato tubers in a previous experiment (Robertson et al 1994 Appendix 1 J) The concentrations on residual AG were also lower than the concentrations previously observed in lettuce and cauliflowers on the same site (Robertson et al 1994 Appendix IH I) As different batches of
14
The use of Red Mudgypsum in vegetable production
AG were used on the two sites they cannot be compared to determine the effect of time on metal availability and uptake Overall metal uptake by potato tubers grown on AG-amended yellow Karrakatta sand does not appear to pose any greater health risk than that on unamended yellow Karrakatta sand The observed increase in As concentration in potato tubers on freshly-applied AG was probably due to the increase in soil pH with level of AG (ONeill 1990)
Conclusions
Freshly-applied AG reduces the availability of fertiliser P so that approximately 25 times the level of applied P is required on 60 to 1201 AGha relative to unamended soil in order to attain maximum P concentration in plant tissues AG at 120 tha also increases the retention of fertiliser P sufficiently to reduce fertiliser requirements for a following potato crop by approximately 20 The effect of AG on the level of fertiliser P required for 99 of maximum yield was confounded in this experiment by the decrease in maximum yield between unamended and amended soil Total yield of potatoes will be reduced on 60 tha freshly-applied AG and by 240 tha residual AG probably by a limiting concentration of K There is potential for increased levels of K fertiliser to overcome this yield reduction AG increases the proportion of yield which is marketable so that even though total yield is reduced by 60 tha of freshly-applied AG the marketable yield is not There are no apparent problems with heavy metal contents of tubers due to amendment with AG
References Allen DG and Jeffery RC (1990) Methods for analysis of phosphorus in Western
Australian soils Chemistry Centre of WA Report of Investigation No 37
Anonymous (1977) Technicon Industrial Method 334-74WB+ Technicon Industrial Systems Tarrytown NY USA
Barrow NJ (1982) Possibility of using caustic residue from bauxite for improving the chemical and physical properties of sandy soils Australian Journal of Agricultural Research 275-285
Colwell JD (1963) The estimation of phosphorus fertiliser requirements of wheat in southern New South Wales by soil analysis Australian Journal of Experimental Agriculture and Animal Husbandry 3 190-197
Glenister DJ and Thoraber MR (1985) Alkalinity of red mud and its application for the management of acid wastes Chemeca 85 109-113
Harris PM (1992) Mineral Nutrition In The Potato Crop The scientific basis for improvement 2nd edition (ed P Harris) pp 162-213 (Chapman and Hall London UK)
Harter RD (1983) Effect of soil pH on adsorption of lead copper zinc and nickel Soil Science Society of America Journal 47 47-51
Hegney MA McPharlin IR and Jeffery RC (1997) Response of winter-grown potatoes (Solanum tuberosum L) to applied and residual phosphorus on a Karrakatta sand Australian Journal of Experimental Agriculture 37 (in press)
Maier NA Williams CMJ Potocky-Pacay K Moss D and Lomman GJ (1987) Interpretation standards for assessing the nutrient status of irrigated potato crops in South Australia Technote AGDEX 262533 September 1987 Department of Agriculture South Australia
15
The use of Red Mudgypsum in vegetable production
McArthur WM and Bettenay E (1960) The development and distribution of the soils of the Swan Coastal Plain Western Australia CSIRO Division of Soils Soils Publication No 16
McPharlin IR Jeffery RC Toussaint LF and Cooper M (1994) Phosphorus nitrogen and radionuclide retention and leaching from a Joel sand amended with red mudgypsum Communications in Soil Science and Plant Analysis 25 489-500
McQuaker NR Brown DF and Kluckner PD (1979) Digestion of environmental materials for analysis by inductively coupled plasma atomic emission spectrometry Analytica Chimica 51 1082-1084
Murphy J and Riley JP (1962) A modified single solution method for the determination of phosphate in natural waters Analytica Chimica Acta 27 31-36
NFA (National Food Authority) (1992) Australian Food Standards Code June 1992 (Australian Government Publishing Service Canberra)
ONeill P (1990) Arsenic In Heavy Metals in Soils(ed BJ Alloway) pp 83-99 (Blackie Glasgow)
Ozanne PG and Shaw TC (1967) Phosphate sorption by soils as a measure of the phosphate requirement for pasture growth Australian Journal of Agricultural Research 18 601-612
Robertson WJ McPharlin IR and Jeffery RC (1994) Final Report of investigation into the use of gypsum-amended red mud as a soil-amendment on horticultural properties on the Swan Coastal Plain Agriculture WA
Robertson WJ McPharlin IR and Jeffery RC (1997) Residues from bauxite-mining (red mud) increase phosphorus retention of a Joel sand without reducing yield of carrots Communications in Soil Science and Plant Analysis (in press)
Yuen SH and Pollard AG (1954) Determination of nitrogen in agricultural materials by the Nessler reagent II Micro-determination in plant tissue and in soil extracts Journal of Food in Agriculture 5 364-369
16
The use of Red Mudgypsum in vegetable production
300
250 -
I I
200
3
60 80
AG (tha)
140
Figure 41 Total phosphorus concentration in a yellow Karrakatta sand amended with freshly-applied Alkaloamreggypsum (AG) vs level of AG when 0 (bull) 100 (A) and 600 (bull) kg Pha was applied measured at 0-15 cm () 15-30 cm (mdash) and 30-45 cm (mdash) depth Bars are Lsds at 5 level of significance
17
The use of Red Mudgypsum in vegetable production
Z3
200
180 -
160
Q- 140
ro 120 bull 4 -
O CD X 100 CD i
3 80 CO c o
pound gt v_ CO
o CQ
AG Depth
I
0 20 40 60 80 100 120
AG (tha)
140
Figure 42 Bicarbonate-extractable phosphorus concentration in a yellow Karrakatta sand amended with freshly-applied Alkaloamreggypsum (AG) vs level of AG when 0 (bull) 100 (A) and 600 (bull) kg Pha was applied measured at 0-15 cm () 15-30 cm (mdash) and 30-45 cm (mdash) depth Bars are Lsds at 5 level of significance
18
The use of Red Mudgypsum in vegetable production
700
600
500
D)
3 400
CL
oil
300 CO
200
100
100 150
A G (tha)
250
Figure 43 Total (mdash) and Bicarbonate-extractable phosphorus () concentration in a yellow Karrakatta sand amended with residual Alkaloamreggypsum (AG) when 600 kg Pha was applied measured at 0-15 cm () 15-30 cm (A) and 30-45 cm (bull) depth Bars are Lsds at 5 level of significance
19
The use of Red Mudgypsum in vegetable production
CO
2 CD
gt-
200 300 400
Applied P (kgha)
Figure 44 (a) Total yield of potatoes cv Delaware grown on a yellow Karrakatta sand amended with freshly-applied AIkaIoamreggypsum (AG) at a level of 0 (bull) 60 (A) 90 (bull) and 120 (bull) tha vs level of applied P Lines represent the level of applied P required for 99 of maximum yield Bars are Lsds at 5 level of significance
Equations are
A
B
C
D
0 tha
60 tha
90 tha
120 tha
j - 614 - 255 x exp (-00152) (JR= 092)
y = 542 - 271 x exp (-00176) (R2= 090)
y = 552 - 274 x exp (-0021) (F= 094)
y = 566 - 229 x exp (-00092) (i^= 098)
20
The use of Red Mudgypsum in vegetable production
ro
JO
gt-
100 200 300 400
Applied P (kgha)
500 600
Figure 44 (b) Total yield of potatoes cv Delaware grown on a yellow Karrakatta sand amended with freshly-applied Alkaloamreggypsum (AG) at a level of 0 (bull) 60 (A) 90 (bull) and 120 (bull) tha vs level of applied P Lines represent the level of applied P required for 99 of maximum yield Bars are Lsds at 5 level of significance
Equations are
Otha A
B
C
D
60 tha
90 tha
120 tha
y = 547 - 216 x exp (-0021) (R2^ 088)
y = 517 - 278 x exp (-0019) (R2= 090)
y = 524 - 243 x exp (-001 to) (R2= 094)
y = 530 - 218 x exp (-001 Ox) (i^= 098)
21
The use of Red Mudgypsum in vegetable production
CO
32
gt-
80
70
60
50
40
30
20
10
0 0
Marketable yield
Marketable yield
Total yield
Total yield
_L 50 100 150 200
AG (tha)
250 300
Figure 45 Total (bull) and Marketable (bull) yield of potatoes cv Delaware grown on a yellow Karrakatta sand amended with residual AIkaloamreggypsum (AG) vs level of AG 600 kg Pha was applied Bars are Lsds at 5 level of significance
22
The use of Red Mudgypsum in vegetable production
w CO CO
a gtraquo i _
C
o 00
c CD O c o o
100 200 300 400
Applied P (kgha)
500
Figure 46 Concentration (dry basis) of phosphorus in petioles of the Youngest Mature Leaf of potatoes cv Delaware grown on a yellow Karrakatta sand amended with freshly-applied Alkaloamreggypsum (AG) at 0 (bull) 60 (A) 90 (bull) and 120 (bull) tha vs level of applied P Lines represent the level of applied P required for 99 of maximum yield Bars are Lsds at 5 level of significance
Equations are
A Otha y = 117- 079 x exp (-0020) (R2 = 096)
B 60 tha y=123- 096 x exp (-000874) (R2 - 099)
C 90 tha y = 118 - 0884 x exp (-000742) (R2 = 096)
D 120 tha y= 117 - 090 x exp (-00085) (R2 = 097)
23
The use of Red Mudgypsum in vegetable production
CO
c
53
CD
gt-
00 02 04 06 08 10
Petiole P ( dry basis)
12 14
Figure 47 Yield of potatoes cv Delaware grown on a yellow Karrakatta sand amended with freshly-applied AlkaIoamreggypsum (AG) at 0 (bull) 60 (A) 90 (bull) and 120 (bull) tha vs petiole P concentration
The equation is y = 256 + 274x (ft2 = 087)
24
The use of Red Mudgypsum in vegetable production
poundgt 3
0 100 200 300 400 500 600 700
Applied P (kgha)
Figure 48 (a) Concentration of Zinc and (B) Calcium ( dry weight) in petioles of the youngest mature leaf of potatoes cv Delaware harvested from a yellow Karrakatta sand amended with freshly-applied Alkaloamreggypsum (AG) at 0 (bull) 60 (A) 90 (bull) and 120 (bull) tha vs level of applied P Bars are Lsds at 5 level of significance
25
The use of Red Mudgypsum in vegetable production
100 200 300 400 500
Applied P (kgha)
700
Figure 48 (b) Concentration of Calcium ( dry weight) in petioles of the youngest mature leaf of potatoes cv Delaware harvested from a yellow Karrakatta sand amended with freshly-applied AlkaIoamreggypsum (AG) at 0 (bull) 60 (A) 90 (bull) and 120 (bull) tha vs level of applied P Bars are Lsds at 5 level of significance
The use of Red Mudgypsum in vegetable production
040
ogt 035 CD
gtgt bullo
w _CB O
H) CL
CO 1 _ -mdashraquo c CD O c o o Q
030 -
025 -
020
2 015
010 -
005
000 0 100 200 300 400
Applied P (kgha)
500 600
Figure 49 (a) The concentration of phosphorus in tubers ( dry weight) of potatoes cv Delaware harvested from a yellow Karrakatta sand amended with freshly-applied Alkaloamreggypsum (AG) at 0 (bull) 60 (A) 90 (bull) and 120 (bull) tha vs level of applied Pkgha Bars are Lsds at 5 level of significance
Equations are
A 0 tha
B 60 tha
C 90 tha
D 120 tha
y = 0372 - 0243 x exp (-00058) (R2 = 097)
y = 0378 - 0257 x exp (-00029x) (R2 = 098)
y = 0361 - 0216 x exp (-00029x) (i^= 095)
y = 0406 - 0279 x exp (-0002x) (R2 = 098)
27
The use of Red Mudgypsum in vegetable production
CO
3
ltD
CO Q Z5
ID
B
14
12 -^ ^
10
8 W
6
4
A G P
I
2
n I i i I I i
0 100 200 300 400
Applied P (kgha)
500 600
Figure 49 (b) Phosphorus uptake Gigha) by tubers of potatoes cv Delaware harvested from a yellow Karrakatta sand amended with freshly-applied Alkaloamreggypsum (AG) at 0 (bull) 60 (A) 90 (bull) and 120 (bull) tha vs level of applied P Bars are Lsds at 5 level of significance
Equations are
Otha A
B
C
D
60 tha
90 tha
120 tha
y = 140 - 1095 x exp (-00058r) (R2 = 096)
3= 111 - 882 x exp (-0004x) (R2 = 098)
y = 104 - 774 x exp (-00053) (R2 = 099)
3 = 127 -101 x exp (-00029x) (R2 = 0997)
28
The use of Red Mudgypsum in vegetable production
60 80
AG (tha)
Figure 410 Concentration of Arsenic (dry weight) in tubers of potatoes cv Delaware grown on a yellow Karrakatta sand amended with freshly-applied Alkaloamreggypsum (AG) Bar is Lsd at 5 level of significance
29
The use of Red Mudgypsum in vegetable production
5 RESPONSE OF CAULIFLOWERS TO FRESHLY-APPLIED RED MUD (ALKALOAMreg)GYPSUM AND PHOSPHORUS ON A YELLOW KARRAKATTA SAND
Introduction
It is important to reduce the leaching of phosphorus fertiliser from sandy soils used for vegetable production into the water systems of the Swan Coastal Plain Red Mud (AlkaloamR)gypsum (AG) a waste product from bauxite refining has been suggested as an amendment to reduce phosphorus leaching from sands of the Bassendean Association (Joel Gavin) used for agriculture and horticulture (Barrow 1982)
Experimental work in the field and pots showed amendment with AG significantly reduced P leaching from Joel and Gavin sands (Vlahos et al 1989 McPharlin ei al 1994) compared with the unamended (01 AGha) treatment
In previous work freshly-applied AG at 60 tha increased the amount of freshly-applied P required for maximum yield of cauliflowers 14 (autumn planted) but did not reduce maximum yield (20 tha) compared with the unamended (0 tha) treatment on a yellow Karrakatta sand (Robertson et al 1994) At the highest rate of applied AG (120 tha) P required for maximum yield was 32 higher than at 0 tha and maximum yield was reduced 23 (P lt 005)
Since more than 60 tha of AG may be required to significantly improve P retention by sands to enable sustainable horticultural production this yield reduction is re-examined with freshly-applied AG
Materials and methods
Site characteristics
The experiment was conducted on a yellow Karrakatta sand (McArthur and Bettenay 1960) of low P fertility at Medina Research Centre (32deg 13 S 115deg 49 E) 30 km South of Perth The site had no previous history of AG application and had been sown to pasture for several years Some relevant chemical characteristics of the topsoil (0-15 cm) and subsoil (15-30 cm) of the site after application of AG but prior to the application of fertiliser and transplanting are presented in Table 51
Red Mud (AlkaIoamreg)gypsum (AG)
Alkaloamreg (Red Mud) amended with 10 (ww) gypsum (AG) was produced by the dry mix process by ALCOA of Australia Ltd at their Kwinana Residue Treatment Plant The AG was spread manually on the site and incorporated using a rotary hoe to approximately 30 cm depth on 21 February 1996 The site was watered for 1 hour per day (8 mmday) using impact sprinklers until planting
Experimental design
The experimental design was a split-plot randomised block with 3 replicates The main plots were levels of AG (0 60 120 and 240 tha) and the sub-plots were levels of freshly-applied P (0 50 100 200 400 and 600 kgha) Main plots measured 6 x 12 m and sub-plots 12 x 6 m (excluding wheel tracks)
Crop management
The site was sprayed with Roundupreg (3 Lha) twice after application of AG and prior to planting to control weeds
The use of Red Mudgypsum in vegetable production
Six week old seedlings of cauliflowers (cv Plana) obtained from a commercial nursery were transplanted manually on 18 April 1996 in 2 rows per plot with 70 cm between rows and 50 cm between plants Seedlings were dipped in Rovralreg 1 mLL just prior to planting for control of fungi Treflanreg (14 Lha) and Dacthalreg (12 kgha) were applied immediately after transplanting to control broadleaved weeds and Sertinreg later on in the life of the crop for grass control Ambushreg (100 mLha) and Rogorreg (100 mLha) were used to control caterpillars and red legged earth-mite respectively Copper sprays were used for control of blackrot The crop was irrigated to a total application equivalent to 100 of the previous days pan evaporation using minisprinklers (Legoreg 6 x 6 m spacing 44 mmh) in 3 waterings of equal duration per day
Fertilisers
Pre-planting fertilisers were broadcast manually and rotary hoed on 17 April 1996
These were K2S04(244) Ca (N03)2 4H20 (387) MgS047H20 (504) MnS04H20 (504) FeS047H20 (18) Borax (27) CuS045H20 (36) ZnSOH20 (28) and Na2Mo042H20 (2) Single superphosphate (91 P)was applied at 0 to 600 kgha according to treatment and incorporated as before Post-planting K N and Ca were fertigated via the irrigation system as KN03 NH4NO3 and Ca (N03)2 in equal amounts per day for 12 weeks to a total of 600 kg K 423 kg N and 60 kg Caha Borax was fertigated at 20 kgha in week 3 and Mg was broadcast as MgS047H20 at 50 kgha in weeks 3 6 and 9
Measurements
Soil and soil solution
All zero P subplots were sampled 30 cores per plot just prior to planting and fertilising about 2 months after AG application to 2 depths (0-15 15-30 cm) These were oven dried at 40degC and analysed for Ec pH (CaCl2) P sorption (Ozanne and Shaw 1968) bicarbonate extractable P K (Colwell 1963) total P PRI P sorption K sorption (Allen and Jeffery 1990) and cation exchange capacity (Gillman and Sumpter 1986)
The soil water was obtained by centrifugation from soil samples (0-15 cm 30 per plot) and collected from the 0 100 200 and 600 kg Pha plots across all AG treatments on 16 May 1996 The supernatant was analysed for pH Ec Ca Mg K S and P The remaining soil was analysed for pH (H20) bicarbonate extractable P and K PRI and DTPA extractable Zn After harvest on 5 August 1996 soil samples were collected from 2 depths as for the preplanting treatment from all plots These were analysed for pH bicarbonate extractable P K total P PRI and exchangeable cations (Ca Mg K and N)
Plant
At buttoning on 13 June 1996 the younger mature leaves (YML) (4th from growing point) were collected from 16 plants in each plot (excluding 1 m buffer at each end) They were dried at 70degC in a force draught oven for 48 h and ground to pass through a 1 mm screen Sub-samples were digested with sulphuric acidhydrogen peroxide (Yuen and Pollard 1954) and the concentration of N P and K measured by an automated colorimetric process (Varley 1966) Concentration of other nutrients (B Ca Na Mg S Fe Mn Zn and Cu) were determined by inductively coupled plasma atomic emission spectroscopy (ICP-AES) after digestion with nitric-perchloric acids (McQuaker et al 1979)
Five whole plants were harvested from the middle of each plot (2 per row)at the end of the experiment on 4 July 1996 using shovels to recover as much of the root system as possible The plants were separated into four categories curds leaves stems and roots All soil was washed from the roots using tap water shaken and the excess water removed using paper towels The fresh weight of all four categories was recorded and the material was diced into small pieces (lt 8 cm3) using stainless steel knives sub-samples (300 g fresh weight) were collected at random from the diced pieces and the fresh weight recorded These were dried at
31
The use of Red Mudgypsum in vegetable production
70degC in a forced draught oven for 48 h and the dry weight recorded These samples were then analysed for P as for the youngest mature leaves Separate sub-samples (300 g fresh weight) of curds were collected and analysed for Ba Cd Cr Co Pb Mo Rb Sr Ti Th V and N using inductively coupled plasma mass spectrometry (ICP-MS) The fresh and dry weight of the curds leaves stems and roots at harvest were used to calculate P uptake in kgha)
Harvest
Harvest commenced when the leaves surrounding the head opened and exposed the curds 77-80 days after transplanting At this stage florets at the periphery of the curd had just begun to separate Sixteen curds (12 plus 4 from whole plant samples above) were collected from the central 4 m of both rows (1 m buffer) and all the leaves and stems removed according to requirements for export market Each fresh curd was weighed and rejects recorded if undersize (lt 500 g) oversize (gt 2000 g) discoloured (yellowing) overmature (separation of florets in centre of curd) diseased damaged or otherwise distorted The total marketable and reject yield were recorded for each plot
Analysis of data
Analysis of variance was carried out on level of applied AG or P versus (a) chemical characteristics of soil (bicarbonate extractable P total P etc) preplanting and harvest (b) concentrations of nutrients in soil solution at midgrowth (c) concentration of nutrients in YMLs at midgrowth (d) concentration of elements in curds at harvest (e) P uptake by plant parts and (f) total marketable and reject yield of curds at harvest Mitscherlich curves and inverse polynomials were fitted to the relationship between level of applied P and yield at each level of applied AG The level of applied P required for 95 99 and 100 (in case of inverse polynomials) of maximum yield was calculated Mitscherlich curves were fitted to the relationship between level of applied P and P in YMLs at midgrowth at all levels of AG The P in YMLs corresponding to the level of applied P required for 95 99 or 100 of maximum yield (as determined from yield versus applied P plots) was then determined
Mitscherlich curves were also fitted to the relationship between level of applied P and P uptake by curds leaves stems and roots and the P uptake corresponding to whole plants (additions of all 4) level of P required for 95-100 of maximum yield determined Phosphorus uptake by plant parts or whole plants on 0 P plots were detected from P uptake at other rates to account for non-fertiliser sources of P This was used to adjust P uptake When determining P fertiliser recovery efficiency (RE) by plant parts or whole plants (ie fertiliser P uptake by plant parts or whole plantsP applied both in kgha Novoa and Loomis 1981)
Results
Effects of fresh AG on chemical characteristics of soil and soil solution
There was a significant (P lt 005) increase in the Ec pH PRI and sorption capacity (topsoil only) of the topsoil and subsoil of a yellow Karrakatta sand with level of freshly-applied AG prior to fertiliser application and planting (Table 51) There was no significant effect of level of AG on Colwell K K sorption capacity and total P with level of freshly-applied AG (Table 51)
The use of Red Mudgypsum in vegetable production
Table 51 Some chemical characteristics of the topsoil (0-15 cm) and subsoil (15-30 cm) of a yellow Karrakatta sand after application of Alkaloam gypsum (AG)1 just prior to fertiliser application and transplanting
(a) Topsoil (0-15 cm)
AG (tha)
Ec (mSm)
pH (CaCl2)
BicP2
(Vigfe)
BicK2
(pgg) PRI3
(mLg) TP4
(Pgg) CEC5
(me ) Kads6 Pads7
0 37 74 107 153 097 507 2 0 41
60 67 82 93 197 167 473 2 043 66
120 80 82 100 277 243 607 2 044 78
240 103 84 97 290 38 637 2 058 129
Lsd8 202 037 38 136 046 1010 0 049 41
Sig9 ns ns ns ns ns
(b) Subsoil (15-30 cm)
AG Ec PH BicP2 BicK2 PRI3 TP4
(tha) (mSm) (CaCl2) (Pgg) (Pgg) (mLg) (Pgg)
0 30 72 83 227 07 507
60 63 81 73 190 15 453
120 80 81 87 220 18 540
240 107 83 83 240 27 563
Lsd8 202 037 38 136 046 101
Sig9 ns ns ns
Applied 7 weeks previously 2 After Colwell (1963) 3 Phosphorus retention index after Allen and Jeffery (1990) 4 Total phosphorus 5 Cation exchange capacity (Gillman and Sumpter 1986) 6 Slope of K adsorption isotherm from the Freundlich equation (Allen and Jeffery 1990) 7 Slope of P adsorption isotherm from the Freundlich equation (Allen and Jeffery 1990) 8 Least significant difference at P lt 005 9 Significance at lt 0001 () lt 001 () lt 005 () level or not significant (ns)
There was a significant (P lt 005) increase in the concentration of Na and a decrease in the concentration of K in the soil solution with level of freshly-applied AG one month after planting and fertilising (Table 52 (a) and Fig 51) At the same time Colwell K and PRI in the topsoil increased significantly with level of freshly-applied AG By contrast there was a significant decrease in extractable Zn with level of AG The concentration of Ca Mg S and P increased significantly with level of applied P in soil solution (Table 52 (a)) Colwell P in the topsoil increased significantly with level of P whilst Colwell K PRI and extractable Zn decreased at the same time (Table 52 (b))
33
The use of Red Mudgypsum in vegetable production
Table 52 (a) Ec (mSm) pH and concentration of nutrients (pgmL) in soil solution 1 month after planting with level of freshly-applied Alkaloamreggypsum (AG)1 and phosphorus
AG
AG (tha)
Ec (mSm)
pH Ca (pgmL)
Mg (pgmL)
Na (pgmL)
K (pgmL)
S (pgmL)
P (pgmL)
Psrp2
(VigmL)
0 112 70 175 18 110 77 101 57 56
60 132 74 164 17 137 58 92 34 31
120 172 75 166 17 152 54 97 44 34
240 166 81 130 16 198 34 75 24 11
Lsd3 19 025 33 4 16 11 26 27 32
Sig4 ns ns ns ns ns
p
AG (tha)
Ec (mSm) PH
Ca (pgmL)
Mg (pgmL)
Na (pgmL)
K (pgmL)
S (UgmL)
P (pgmL)
Psrp2
(pgmL)
0 137 78 99 15 150 46 26 10 01
100 142 76 112 15 153 54 52 23 14
200 170 74 179 19 150 62 114 39 30
600 133 72 244 19 144 60 174 89 87
Lsd3 43 022 31 24 17 15 29 25 30
Sig4 ns ns ns
Applied 11 weeks previously
Soluble reactive P 3 Least significant difference at P lt 005 4 Significance at lt 0001 () lt 001 () lt 005 () level or not significant (ns)
The use of Red Mudgypsum in vegetable production
220
200
E 180 O ) 3
^ 1fi0 _ o 3 140 O V)
oil
120 m c
100 C o CO 80 c flgt o B0 c o o 40
20
0 50 100 150 200
Freshly-applied AG(tha)
250 300
Fig51 Concentration (ugml) of Na(i ) and K ( bull ) in soil solution (0-15cm) under cauliflowers one month after planting with level of freshly-applied AlkaloamRgypsum(AG) Vertical bars indicates Lsd (Plt005) for differences in concentration betweeen levels of AG
35
The use of Red Mudgypsum in vegetable production
Table 52 (b) Extractable P K Zn and phosphorus retention index of the top soil (0-15 cm) of a yellow Karrakatta sand 1 month after transplanting with level of freshly-applied Alkaloamreggypsum (AG)1 and phosphorus (P)
AG
AG (tha)
P2
(ugg) K2
(Ugg) Zn3
(Pgg)
PRI4
(mLg)
0 47 32 67 -112
60 76 38 15 -090
120 94 42 26 -049
240 84 41 13 092
Lsd5 35 6 28 073
Sig6 ns
P P2 K2 Zn3 PRI4
(kgha) (ugg) (Hgg) (Ugg) (mLg)
0 8 42 31 201 100 35 37 45 043 200 80 39 18 -089 600 177 34 26 -313
Lsd5 39 6 27 082
Sig6 ns
Applied 11 weeks previously 2 After Colwell (1963) 3 Extracted in DTPA 4 Phosphorus retention index (Allen and Jeffery 1990) 5 Least significant difference at P lt 005 6 Significance at lt 0001 () lt 001 () lt 005 () level or not significant (ns)
Ec pH exchangeable Ca K Na in me and Colwell P K total P PRI and PRIP increased significantly (P lt 005) with level of freshly-applied AG in the topsoil and subsoil of a yellow Karrakatta sand (Table 53 (a) (b) and Fig 52) at harvest
The use of Red Mudgypsum in vegetable production
o CO
CD
E
o CO
co o
CD
X co CD ogt e co sz o X HI
50 100 150 200
Freshly-applied AG (tha)
250 300
Fig52 Exchangeable Ca() NaP) and K(A) cations (me dry soil) in topsoil (0-15cm) of Karrakatta sand amended with freshly-applied AlkaloamRgypsum(AG) after harvest of cauliflowers Vertical bars indicates Lsd (Plt005) for differences in concentration between levels of AG Lsd not shown when less than size of symbol
37
The use of Red Mudgypsum in vegetable production
Table 53 Ec (mSm) pH and exchangeable Ca Mg K and Na (me ) in the topsoil (0-15 cm) and subsoil (15-30 cm) of a yellow Karrakatta sand amended with AlkaIoamreggypsum (AG) at harvest of cauliflowers
(a) Topsoil
AG Ec PH Ca Mg K Na (tha) (mSm) (CaCl2) (me ) (me ) (me ) (me )
0 67 66 229 018 005 003
60 91 77 382 019 009 02
120 99 79 558 019 012 043
240 120 80 975 024 014 104
Lsd2 20 014 064 0033 0018 021
Sig3 ns
(b) Subsoil
AG Ec pH Ca Mg K1 Na (tha) (mSm) (CaCl2) (me ) (me ) (me ) (me )
0 44 67 225 017 005 003
60 59 74 269 019 005 008
120 66 77 300 018 005 017
240 99 79 397 02 005 029
Lsd2 075 01 029 0036 001 002
Sig3 n s ns
Extracted in 1 m NH4CI 2 Least significant difference at P lt 005 3 Significance at lt 0001 () lt 001 () lt 005 () level or not significant (ns)
However there was no effect of either level of AG or P on exchangeable Mg in the soil at harvest Colwell P total P and PRIP increased significantly whilst Colwell K and PRI decreased with level of freshly-applied P in the topsoil at harvest (Table 4 (a) (b) and Fig 53)
The use of Red Mudgypsum in vegetable production
Table 54 P (extractable P total P phosphorus retention index and P sorption) in the top soil (0-15 cm) and subsoil (15-30 cm) of a yellow Karrakatta sand at harvest of cauliflowers with level of freshly-applied Alkaloamreggypsum (AG) and phosphorus (P)
(a) Topsoil
AG
AG BicP1 BicK1 TotP2 PRI3 PRIP3
(tha) (ugg) (Pgg) (Hgg) (mLg) (mLg)
0 39 23 92 -07 28
60 50 38 110 02 50
120 59 51 135 16 75
240 58 62 157 35 99
Lsd4 5 11 15 03 06
Sig5
P BicP1 BicK1 TotP2 PRI3 PRIP3
(kgha) (ugg) (Hgg) (ngg) (mLg) (mLg)
0 10 53 57 29 40
50 15 40 66 22 38
100 25 41 78 17 44
200 53 41 128 14 71
400 87 44 186 -01 86
600 120 41 226 -12 102
Lsd4 11 8 20 09 13
Sig5
1 After Colwell (1963) 2 After Allen and Jeffery (1990) 3 After Allen and Jeffery (1990) 4 Least significant difference at P lt 005 5 Significance at lt 0001 () lt 001 () lt 005 () level or not significant (ns)
39
The use of Red Mudgypsum in vegetable production
Table 54 P (extractable P total P phosphorus retention index and P sorption) in the top soil (0-15 cm) and subsoil (15-30 cm) of a yellow Karrakatta sand at harvest of cauliflowers with level of freshly-applied Alkaloamreggypsum (AG) and phosphorus (P)
(b) Subsoil (15-30 cm)
AG
AG BicP1 BicK1 TotP2 PRI3 PRIP3
(tha) (ugg) (Ugg) (Ugg) (mLg) (mLg)
0 33 20 79 -05 26
60 30 21 73 -01 30
120 33 27 77 08 42
240 26 24 76 13 40
Lsd4 10 2 10 04 10
Sig5 ns ns
P BicP1 BicK1 TotP2 PRI3 PREP3
(kgha) (ugg) (Vigg) (Ugg) (mLg) (mLg)
0 7 25 48 15 22
50 11 22 52 09 19
100 15 24 59 10 27
200 32 23 81 06 39
400 51 22 100 -03 47
600 67 21 117 -11 52
Lsd4 8 5 8 05 09
Sig5 ns
1 After Colwell (1963) 2 After Allen and Jeffery (1990) 3 After Allen and Jeffery (1990) 4 Least significant difference at P lt 005 5 Significance at lt 0001 () lt 001 () lt 005 () level or not significant (ns)
The use of Red Mudgypsum in vegetable production
100 150 200
Freshly-applied AG (tha)
300
Fig53 Concentration of total P(A) Colwell P() or K(laquo) in topsoil (0-15cm) with level of freshly-applied AlkaloamRgypsum (AG) after harvest of cauliflowers Vertical bars indicates Lsd (Plt005) for differences in concentration between levels of AG Lsd not shown when less than size of symbol
41
The use of Red Mudgypsum in vegetable production
Nutrients in leaves at midgrowth and harvest
There was a significant decrease in concentration of K and an increase in concentration of Na S Mn and Cu in youngest mature leaves (YML) of cauliflowers at buttoning with level of freshly-applied AG (Table 55) The concentration of P in YML at 01 AGha (049) was significantly higher than at 2401 AGha (044) but not at other levels Currently-applied AG had no significant effect on concentration of N Ca Mg Fe Zn or B in YML There was a significant increase in YML in the concentration of K P and S in YML with level of applied P whilst concentration of N Mg Mn and B were variable (Fig 54 55) Level of applied P had no significant effect on the concentration of Ca and Na in the YML (Table 55)
Table 55 (a) Concentration of macro-nutrients (dry weight basis) in youngest mature leaves of cauliflowers at buttoning with level of freshly-applied Alkaloamreggypsum (AG) and phosphorus (P)
AG
AG N1 K1 Ca2 S2 P1 Na2 Mg2
(tha) () () () () () () ()
0 482 393 240 081 049 036 023
60 484 383 251 084 046 040 024
120 506 357 255 081 046 045 024
240 494 355 246 088 044 056 025
Lsd3 026 012 024 005 003 006 0013
Sig4 ns ns ns ns
p
p N1 K1 Ca2 S2 P1 Na2 Mg2
(kgha) () () () () () () ()
0 523 316 254 066 024 046 025
50 489 372 255 081 041 049 026
100 503 388 229 084 048 042 024
200 472 379 250 089 050 046 024
400 494 390 242 093 057 043 023
600 470 385 258 091 057 039 022
Lsd3 027 024 036 005 003 008 0017
Sig4 ns ns
1 After Varley (1966) 2 After McQuaker et al (1979) 3 Least significant difference at P lt 005 4 Significance at lt 0001 () lt 001 () lt 005 () level or not significant (ns)
The use of Red Mudgypsum in vegetable production
0 50 100 150 200 250 300
Freshly-applied AG (tha)
Rg54 Concentration of N() K(B) and Ca(A) in youngest mature leaf (YML) at buttoning
of cauliflowers with level of freshly-applied AlkaloamRgypsum(AG) Vertical bars
indicates Lsd (Plt005) for differences in concentration between levels of AG
10
bdquo 09 lt Q OR ^ D) 07 c
tto
06 3
X3
to 05 _ l
gtbull 04 C
i3 03 c agt bull c 02 3
-z 01 0 50 100 150 200 250 300
Freshly-applied AG (tha)
Rg55 Concentration of S() Na(B) Mg(4) and P(T) in youngest mature leaf (YML) at buttoning
of cauliflowers with level of freshly-applied AlkaloamRgypsum(AG) Vertical bars indicates Lsd (Plt005) for differences in concentration between levels of AG
43
The use of Red Mudgypsum in vegetable production
The relationship between P in YML at buttoning and level of freshly-applied P was best described by Mitscherlich relationships at all levels of applied AG (Fig 56)
en c o 3
X2
gt
06
^
bull A
05 ^ S
04
03
02
01
n n i i i
0 100 200 300 400 500 600 700
Applied P (kgha)
o
X I
5 gt
06
05
04
03
02
01
00
- bull B
- bull bull ^
o
I I I I
0 100 200 300 400 500 600 700
Applied P (kgha)
100 200 300 400 500 600 700
Applied P (kgha)
100 200 300 400 500 600 700
Applied P (kgha)
Fig56 P in YML of Cauliflowers at buttoning () corresponding to applied P required for either 95 (dashed line) or 99 (whole line) of maximum yield at 0(A) 60(B) 120(C) or240(D)t of freshly-applied AlkaloamRgypsumha
The equations for the fitted lines are
A
B
C
D
y = 056 - 030 x exp (-00182) (R2 = 097)
y = 057 - 032 x exp (-00103) (R2 = 088)
y = 055 - 031 x exp (-00126) (R2 = 099)
y = 056 - 032 x exp (-00092) (R2 = 098)
The P in YML corresponding to level of freshly-applied P required for 99 of maximum yield was 053 057 055 and 055 for 0 60 120 and 240 tha respectively
44
The use of Red Mudgypsum in vegetable production
Table 55 (b) Concentration of micro-nutrients (dry weight basis) in youngest mature leaves of cauliflowers at buttoning with freshly-applied Alkaloamreggypsum (AG) and phosphorus (P)
AG
AG (tha)
Fe (Pgg)
Zn (Ugg)
Mn (vigg)
B (Pgg)
Cu1
(Pgg)
0 1354 251 217 211 26
60 1274 248 237 213 28
120 1353 253 240 217 27
240 1394 263 260 214 29
Lsd2 153 24 15 082 02
Sig3 ns ns ns
P Fe Zn Mn B Cu (kgha) (ngg) (ugg) (Pgg) (Ugg) (Pgg)
0 1418 268 212 215 26
50 1388 253 263 220 27
100 1301 267 251 217 29
200 1336 249 250 217 28
400 1282 255 232 204 28
600 1341 233 224 210 28
Lsd2 197 29 19 08 02
Sig3 ns ns ns
1 Extracted in 1 m NH4CI 2 Least significant difference at P lt 005 3 Significance at lt 0001 () lt 001 () lt 005 () level or not significant (ns)
There was a significant (P lt 005) decrease in the concentration of P Zn and an increase in the concentration of Na in whole leaves (WL) of cauliflowers with rate of freshly-applied AG at harvest (Table 56) Level of freshly-applied AG had no significant effect on concentration of N K Ca S Mg Fe Mn B or Cu Concentration of Ca S P and Na in (WL) at harvest increased significantly (P lt 005) with level of freshly-applied P whereas Zn concentrations decreased and concentrations of Mg Mn and B were variable Level of freshly-applied P had no significant effect on concentration of N K Fe or Cu in WL at harvest
45
A O O ltyi
4x
r en 00
9 400 200 o o o copy
ns
O
kgt ON
kgt
4gt
kgt 4 4 4^
kgt
ns
O 4 4 ON 4 k)
o
i mdash t mdash raquo
4 00
4 ON
4 4^ NO Q O
o copy ON
i mdash gt
b b 1 mdash t
b o p Vcopy
O 00 ON
o ON
gtmdash 5 co 5J M
o o
O in
o 4 Ncopy
o 4 O
p 4
p kgt 1 mdash t
copy
ON
o b NO
O ON
o 00
o 00
o ON I mdash
O ON
O 3 Z 5 raquoM
o b 4
O
kgt o kgt -J
p kgt 00
O kgt 00
O
kgt NO
copy kgt ON
The use of Red Mudgypsum in vegetable production
Table 56 (b) Concentration of micro-nutrients (dry weight basis) in leaves of cauliflowers at harvest with level of freshly-applied Alkaloamreggypsum (AG) and phosphorus (P)
AG
AG (tha)
Fe1
(ugg) Zn1
(vgg) Mn1
(vgg) B1
(vgg) Cu1
(vigg)
0 762 224 214 263 42
60 700 197 227 265 38
120 811 196 216 254 38
240 842 193 236 256 37
Lsd2 132 099 21 16 06
Sig3 ns ns ns ns
P (kgha)
Fe1
(pgg) Zn1
(^gg) Mn1
(Vigg) B1
(lJgg) Cu1
(Pgg)
0 786 233 213 248 36
50 625 235 241 266 37
100 833 207 237 270 41
200 938 192 235 265 44
400 725 178 208 259 37
600 765 169 206 250 37
Lsd2 230 21 21 11 063
Sig3 ns ns
After McQuaker et al (1979)
Least significant difference at P lt 005
Significance at lt 0001 () lt 001 () lt 005 () level or not significant (ns)
47
The use of Red Mudgypsum in vegetable production
Nutrients and heavy metals in curds at harvest
There was a significant (P lt 005) decrease in the concentration of K and P and an increase in the concentration of Ca and Na in the curds at harvest with level of freshly-applied AG Concentration of N Mg Fe Zn Mn B and Cu in the curds were unaffected by level of freshly-applied AG (Table 57) As level of freshly-applied P increased there was a significant (P lt 005) decrease in concentration of N S Mg Fe Zn Mn and B and an increase in concentration of K Ca P and Na in curds at harvest Concentration of Cu in curds were unaffected by level of applied P (Table 57 (b))
Table 57 (a) Concentration of macro-nutrients (dry weight basis) in curds of cauliflowers at harvest with level of freshly-applied Alkaloamreggypsum (AG) and phosphorus (P)
AG
AG N1 K1 Ca S1 P2 Na1 Mg1
(tha) () () () () () () ()
0 392 515 040 066 047 023 018
60 384 500 040 067 045 023 017
120 404 474 043 071 043 024 018
240 402 458 041 071 041 028 018
Lsd3 022 016 001 004 002 002 0006
Sig4 ns + ns ns
P
p N1 K1 Ca1 S1 P2 Na1 Mg1
(kgha) () () () () () () ()
0 496 417 034 097 031 016 019
50 400 518 043 068 040 023 018
100 376 483 042 063 042 025 017
200 372 501 044 063 047 027 017
400 371 498 042 062 052 028 017
600 358 505 041 060 052 027 016
Lsd3 027 02 003 005 002 003 001
Sig4
1 After McQuaker et al (1979) 2 After Varley (1966) 3 Least significant difference at P lt 005 4 Significance at lt 0001 () lt 001 () lt 005 () level or not significant (ns)
The use of Red Mudgypsum in vegetable production
Table 57 (b) Concentration of micro-nutrients1 (dry weight basis) in curds Cauliflowers at harvest with level of freshly-applied Alkaloam gypsum (AG) and phosphorus (P)
AG
AG (tha)
Fe1
(Ugg)
Zn1
(vigg) Mn1
(Pgg) B1
(Pgg) Cu1
(Pgg)
0 611 279 124 188 26
60 587 247 134 191 25
120 706 299 139 192 29
240 592 268 145 186 25
Lsd2 329 57 14 08 06
Sig3 ns ns ns ns ns
p
p (kgha)
Fe1
(Ugg) Zn1
(Pgg) Mn1
(Ugg) B1
(ugg)
Cu1
(Pgg)
0 976 492 156 202 31
50 520 279 145 198 26
100 507 230 135 186 24
200 432 208 127 190 24
400 739 239 131 183 28
600 567 192 120 177 24
Lsd2 270 61 142 114 061
Sig3 a s
1 After McQuaker et al (1979) 2 Least significant difference at P lt 005 3 Significance at lt 0001 () lt 001 () lt 005 () level or not significant (ns)
49
The use of Red Mudgypsum in vegetable production
Concentration of Ba in curds at harvest decreased and concentration of Ti increased significantly in curds at harvest with level of freshly-applied P (Table 58) As level of freshly-applied P increased concentrations of Pb and Rb decreased and of Sr decreased Ba concentrations were variable with level of freshly-applied P (Table 58)
Table 58 Concentration of Ba plus heavy metals1 (fresh weight basis) in curds of cauliflowers at harvest with level of freshly-applied Alkaloamreggypsum (AG) and phosphorus (P)
AG Ba Cd Cr Co Pb Ni Rb Sr Ti Th V (tha) (ngg) (ngg) (ngg) (ngg) (ngg) (ngg) (ngg) (ngg) (ngg) (ngg) (ngg)
0 797 7 34 7 13 34 590 1219 34 39 7
60 482 7 34 7 15 34 610 1146 46 52 8
120 583 7 43 7 20 34 616 1246 45 50 8
240 355 7 34 7 15 34 637 1152 41 45 8
Lsd2 141 1 13 16 11 15 74 188 5 16 1
Sig3 ns ns ns ns ns ns ns ns ns
MRL4 50 2000
P (kgha)
Ba (ngg)
Cd (ngg)
Cr (ngg)
Co (ngg)
Pb (ngg)
Ni
(ngg)
Rb (ngg)
Sr (ngg)
Ti
(ngg)
Th
(ngg)
V (ngg)
0 556 7 34 7 25 34 650 998 39 45 9
50 670 7 34 7 18 34 657 1387 50 74 9
100 576 7 34 7 11 34 570 1206 45 50 8
200 529 7 34 7 12 34 616 1293 39 39 7
400 523 7 48 7 19 39 596 1126 39 36 7
600 476 7 34 7 11 34 603 1126 36 36 7
Lsd2 121 1 16 1 15 6 40 181 19 29 2
Sig3 ns ns ns ns ns ns ns ns
MRL4 50 2000
Inductively coupled plasma mass spectrometry 2 Least significant difference at P lt 005 3 Significance at lt 0001 () lt 001 () lt 005 () level or not significant (ns) 4 Maximum residue limit
The use of Red Mudgypsum in vegetable production
P uptake by plants P uptake by whole plants or plant parts was unaffected by level of freshly-applied AG by but increased significantly with level of freshly-applied P (Table 59)
P uptake by whole plants increased from 50 kg Pha to 19 to 21 kgha at 400 to 600 kg applied Pha respectively Curd root stem and leaf uptake was 33 5 6 and 50 respectively of total plant P uptake at the highest level of applied P (Table 59)
Table 59 P uptake (kgha) by curds roots stem leaf and whole cauliflower plants at harvest with level of freshly-applied Alkaloamreggypsum (AG) and phosphorus (P)
AG
AG Curds Roots Stem Leaf Total (tha) (kgha) (kgha) (kgha) (kgha) (kgha)
0 53 074 11 87 158
60 48 066 10 83 148
120 47 069 11 79 143
240 45 060 10 74 135
Lsd1 065 015 025 21 31
Sig-2 ns ns ns ns ns
p
p (kgha)
Curd (kgha)
Root (kgha)
Stem (kgha)
Leaf (kgha)
Total (kgha)
0 12 030 040 29 49
50 40 058 100 68 124
100 51 053 112 76 143
200 59 075 120 93 172
400 67 093 131 115 205
600 61 094 121 102 185
Ls-d1 055 017 020 18 25
Sig2
1 Least significant difference at P lt 005 2 Significance at lt 0001 () lt 001 () lt 005 () level or not significant (ns)
51
The use of Red Mudgypsum in vegetable production
Yield
There was a significant (P lt 005) increase in both total and marketable curd yield with level of freshly-applied P at all levels of freshly-applied AG (Table 510) There was no significant effect of level of freshly-applied AG on either total (Table 510 (a)) or marketable (Table 510 (b)) curd yield
Table 510 Curd yield (total marketable) of cauliflowers (tha) at harvest with level of freshly-applied Alkaloamreggypsum (AG) and phosphorus (P)
(a) Total
p (kgha)
AG (tha) p
(kgha) 0 60 120 240
0 755 468 483 177
50 1464 1675 1554 1516
100 2169 1706 1757 1985
200 2242 1737 1928 1862
400 1752 2102 2155 2136
600 1689 1764 1768 2023
Lsd1
Sig2
16 (AG)
ns 201 (P)
401 (AGP)
-
(b) Marketable
p (kgha)
AG (tha) p
(kgha) 0 60 120 240
0 274 060 000 000
50 1222 1463 1294 1152
100 2057 1416 1603 1820
200 2141 1377 1803 1752
400 1572 2020 2095 1996
600 1468 1534 1500 1974
Lsd1
Sig2
24 (AG)
ns
46 (P)
52(AGP)
ns
Least significant difference at P lt 005 2 Significance at lt 0001 () lt 001 () lt 005 () level or not significant (ns)
The relationship between total yield and level of freshly-applied P was best described by a quadratic relationship at all levels of freshly-applied AG (Fig 57) As level of AG increased the level of freshly-applied P required for 99 of maximum yield increase from 124 kg Pha at 0 t AGha to 339 kg Pha at 240 tha There was no significant effect of level of freshly-applied AG on maximum curd yield (Fig 57)
The use of Red Mudgypsum in vegetable production
26
24
22
(tha
) 20
18
Cur
d yi
eld 16
14
12
10
8
6 i ii
A=0
i i i i i
I I
0 100200300400500600700
Applied P (kgha)
24 22 20 18 16 14 12 10 8 6 4 2
- 7 I
_ bull
i i i n
mdash^ B=60
I I I
0 100200300400500600700
Applied P (kgha)
co
32 CD
gt 2 3
o
25
20
15
10
5
bull j
- bull
I I I I I
- - gt C=120
l l l
0 100200300400500600700
Applied P (kgha)
0 100200300400500600700
Applied P (kgha)
Fig57 Total curd yield (tha) of cauliflower with level of freshly-applied Alkaloam gypsum and
phosphorus (ABCD = 060120240 tha) Vertical lines represent applied P necessary
for either 95 (dashed) or 99 (whole) of maximum yield
The equations for the fitted lines are
A y = 1336 + (-577 + 01335x)(l-00088x +000007872) (Z2
B y = 89434 + 00705 - OOOOlx2 (R2 = 070)
C y = 84752 + 00810 - OOOOlx2 (B2 = 081)
D y = 733 +00871x - 00001 Ix2 (R2 = 099)
098)
53
The use of Red Mudgypsum in vegetable production
Discussion
The increase in pH Ec PRI and P sorption of Karrakatta sands with level of freshly-applied AG prior to fertiliser application is similar to that reported for the amendment of Joel (McPharlin et al 1994 and Robertson et al 1997a) and Karrakatta sands (Robertson et al 1994 and 1997b) with AG The increase in DH and Ec of the amended soil is explained by the high levels of both in the AG (ie pH (CaCr) = 94 and Ec = 623 mSm Appendix 1) The increased retentionsorption of P is explained by the addition of iron (974) and aluminium (551) in various oxides and hydroxides in the AG (Appendix 1 and Barrow 1982) to the soil After the application of P fertilisers levels of P in the soil at mid-growth and harvest as measured by total and Colwell P increased with a parallel decrease in PRI The increase in the levels of exchangeable Ca and Na in the soil at the same times with level of freshly-applied AG can be attributed to the AG itself However the increase in exchangeable and Colwell K appears to be due to improved K retention capacity of the soil due to physical properties of the AG rather any increased supply of K from the AG Whilst the overall K adsorption properties of the soil as measured by the Freundlich isotherm was not significantly increased with level of AG K sorption at 2401 AGha was significantly higher than at 01 AGha
There was no significant increase in cation exchange capacity (CEC) with level of freshly-applied AG on the Karrakatta sand in this experiment which remained about 2 me By contrast the CEC of virgin Joel sands increased from 1 to 2 me with level of freshly-applied AG (0 to 240 tha) in columns (McPharlin et al 1994) The application of AG would be expected to increase the CEC of coarse sands because (1) AG a fine textured material (10 clay 68 silt) (Ward 1983) would increase the fine fraction when applied to sands (2) AG has a much higher CEC ie 7 to 15 me depending on pH (Barrow 1982) than either Joel or Karrakatta sands ie 1 to 2 me (McPharlin et al 1994 and Table 51) and (3) application of AG to either Joel or Karrakatta sands increases the retentionreduces leaching of cations either not present in the AG such as NH4-N (McPharlin et al 1994) or only present in small quantities such as K (Tables 52 53 54 and Appendix 51)
The concentration of an element in the soil expressed as either extractable or total amounts represents the quantity or extensive factor in terms of plant nutrition as outlined by Holford and Mattingly (1976) The concentration of ions in soil solution or the intensive factor may better represent what is available to the plant A good example of this is the levels of K in the soil expressed as either Colwell or exchangeable K which increase significantly with level of applied AG However levels of K in the plant YML at buttoning and curds at harvest decrease significantly with level of AG K in soil solution 1 month after planting similarly decline significantly with level of applied AG and are therefore better correlated with K nutrition of the plant than measurements based on the dry soil Similarly P concentrations in the plant and soil solution decline whilst P retained by the soil increase in response to freshly-applied AG By contrast concentrations of Na in soil solution soil and plant all increase with levels of freshly-applied AG Similar relationships between concentrations of K Na and P in the soil soil solution and plant on a Karrakatta sand have been reported previously (Robertson et al 1997)
In previous work maximum yield (ie A value) of cauliflowers was reduced when freshly prepared AG was applied at levels gt 120 tha (Robertson et al 1994) This yield reduction was assumed not to be due to induced P deficiency resulting form high level of applied AG as it could not be alleviated by increased levels of applied P Although increased levels of applied P were needed to maximise yield as the level of freshly-applied AG increased Concentrations of K decreased and Na increased in the YML with level of applied AG and the yield reduction was assumed to be due either induced K deficiency or Na toxicity However neither the reduced concentrations of K or the increased concentrations of Na in the plant were at levels that would reduce yield according to published standards (Weir and Cresswell 1993) Antagonism between Na and K uptake by plants is common (Yeo 1983) For example increasing soil salinity resulted in increased concentrations of Na and decreased concentrations of K in the leaves of Zucchini grown in controlled greenhouses in Spain (Villora et al 1997)
The use of Red Mudgypsum in vegetable production
In this work as level of freshly-apphed AG increased level of applied P necessary for maximum yield increased as in the previous work however maximum yield was not reduced by AG up to 240 tha This is despite concentrations of K in the YML decreasing and Na increasing in response to level of freshly-applied AG However as in the previous work neither concentrations of K or Na were at levels expected to cause yield reduction By contrast the reduction in maximum yield of potatoes at high levels of freshly-applied AG (ie gt 120 tha) was correlated with a reduced concentration of K in the petioles (Robertson et al 1997b)
The level of freshly-applied P required for 99 of maximum yield in this work increased from 124 kgha at 01 AGHa to 339 kgha at 2401 AGha These levels of applied P are similar to that reported necessary for maximum yield of cauliflowers on AG-amended (Robertson et al 1994) or unamended (McPharlin et al 1995) Karrakatta sands The P required for 99 of maximum yield in this work 053 to 057 was either slightly higher - 047 (McPharlin et al 1995) or within range - 05 to 07 (Piggott 1986) 03 toO7 (Weir and Cresswell 1993) of that reported as critical or adequate for maximum yield of cauliflowers
Increased levels of freshly-applied AG did not significantly change the concentrations of Cd Co Cr Pb Ni Rb Sr Th or V in the curds of cauliflowers By contrast concentrations of Ba were significantly reduced and Ti increased in the curds with levels of freshly-applied AG Similarly there was no reported change in concentration of Cd Cr Pb or Co with level of freshly-applied AG in curds of cauliflower grown on Karrakatta sands (Robertson et al 1994) in previous work Also there was no change in Ba concentration in curds with level of AG in contrast to the previous work
References
Barrow NJ (1982) Possibility of using caustic residue from bauxite for improving the chemical and physical properties of sandy soils Australian Journal of Soil Research 33 275-285
Holford ICR and Mattingly GEG (1976) Phosphate adsorption and plant availability of phosphate Plant and Soil 44 377-89
McArthur and Bettenay (1960) The development and distribution of the soils of the Swan Coastal Plain Western Australia Soils Publication No 16 CSIRO Division of Soils CSIRO Melbourne Australia
McPharlin IR JefFery RC Toussaint LF and Cooper M (1994) Phosphorus Nitrogen and Radionuclide Retention and Leaching from a Joel Sand amended with Red Mudgypsum Communications in Soil Science and Plant Analysis 25 (17 amp 18) 2925-2944
McPharlin IR Robertson WJ JefFery RC and Weissberg R (1995) Response of cauliflower to phosphate fertiliser placement and soil test phosphorus calibration on a Karrakatta sand Communications in Soil Science and Plant Analysis 26(3amp4) 607-620
McQuaker NR Brown DF and Kluckner PD (1979) Digestion of environmental materials for analysis by inductively coupled plasma-atomic emission spectrometry Analytical Chemistry 51 1082-1084
Piggott TJ (1986) Vegetable crops pp 148-187 In DJ Reuter and JB Robinson (eds) Plant Analysis an Interpretation manual Inkata Press Melbourne Australia
Robertson WJ McPharlin IR and JefFery RC (1994) Final report of investigation into the use of gypsum-amended Red Mud as a soil-amendment on horticultural properties on the Swan Coastal Plain Report to HRDC (Project No V0039RO) Department of Agriculture Western Australia
55
The use of Red Mudgypsum in vegetable production
Robertson WJ Jeffery RC and McPharlin IR (1997a) Residues from bauxite-mining (Red Mud) increase phosphorus retention of a Joel sand without reducing yield of carrots Communications in Soil Science and Plant Analysis 28 (in press)
Robertson WJ McPharlin IR and Jeffery RC (1997b) The growth nutrition and mineral composition of potatoes (Solanum tuberosum L) cv Delaware grown on an yellow Karrakatta sand amended with freshly-applied and residual Alkaloamreggypsum (Submitted to AJEA)
Varley J A (1966) Automatic methods for the determination of nitrogen phosphorus and potassium in plant material Analyst 91 119-126
Villora G Pulgar G Moreno DA and Romero L (1997) Effect of salinity treatments on nutrient concentration in Zucchini plants (Cucurbita pepo L var Moschatd) Australian Journal of Experimental Agriculture 37 605-608
Vlahos S Summers KJ Bell DT and Gilkes RJ (1989) Reducing phosphorus leaching from sandy soils with Red Mud bauxite processing residues Australian Journal of Soil Research 27 651-662
Weir RG and Cresswell GC (1993) Plant Nutrient Disorders 3 Vegetable crops p 93 Inkata Press Melbourne Australia
Yuen SH and Pollard AG (1954) Determination of nitrogen in agricultural material by the Nessler reagent II Micro determination in plant tissue and soil extracts Journal of the Science of Food and Agriculture 5 364-369
The use of Red Mudgypsum in vegetable production
Appendix 51 Chemical and physical characteristics of Alkaloam gypsum used in cauliflower experiment (freshly-applied Alkaloamreggypsum)
Parameter Units Value Kgt
Ec mSm 623 -
pH (H 20) mSm 99 -
pH (CaCl2) mSm 94 -
PRI mLg 610 - gt 1000 -
LOI 1973 -
C a C 0 3 1290 1290
Fe (Fe203) 974 974
Al (A1203) 551 551
Si (Si0 2 ) 797 797
Ca (CaO) 45 450
Na (Na 2 0) 228 228
Ti (Ti0 2 ) 174 174
K (K 2 0) 072 72
Mg (MgO) 028 28 sect 047 47
P (P2O5) 005 05
Mn (MnO) 002 02
Total P ngg 266 -
Extractable P M-gg 58 -
Extractable K M-gg 43 -
As ngg 35 -
Ba ^gg 413 -
Cu Ugg 29 -
Sr Hgg 287 -
Nb Hgg 99 -y Hgg 866 -
Zr fAgg 1477 -
Sand 232 -
Silt 473 -
Clay 295 -
After Allen and Jeffery (1990)
Based on X-ray fluorescence (XRF) spectrometry
After Colwell (1963)
The use of Red Mudgypsum in vegetable production
Appendix 52 Concentration of Ba plus heavy metals1 (dry weight basis) in curds of cauliflowers at harvest with level of freshly-applied Alkaloamreggypsum (AG) and phosphorus (P)
(a)
AG Ba Cd Cr Co Pb Ni Rb Sr Ti Th V (tha) (Pgg) (vigg) (ugg) (ugg) (Pgg) (Pgg) (Pgg) (ugg) (Pgg) (Pgg) (Pgg)
0 119 010 050 010 020 050 88 182 050 058 010
60 72 010 050 010 022 050 91 171 069 078 012
120 87 011 064 011 030 050 92 186 067 075 012
240 53 011 05 010 023 050 95 172 061 067 012
Lsd2 21 002 02 024 016 022 11 28 008 024 002
Sig3 ns ns ns ns ns ns ns ns ns
(b)
p (kgha)
Ba (vgg)
Cd (vigg)
Cr (Pgg)
Co (ngg)
Pb (vgg)
Ni (Pgg)
Rb (Pgg)
Sr (Pgg)
Ti
(Pgg)
Th (Pgg)
V
(Pgg)
0 83 010 050 010 038 050 97 149 058 067 013
50 100 011 050 010 027 050 98 207 075 110 013
100 86 010 050 010 017 050 85 180 067 075 012
200 79 010 050 010 018 050 92 193 058 058 010
400 78 011 071 011 028 058 89 168 058 054 011
600 71 010 050 010 016 050 90 168 054 054 010
Lsd2 18 002 024 0009 022 009 06 27 028 044 003
Sig3 ns ns ns ns ns ns ns ns
Inductively coupled plasma mass spectrometry
Least significant difference at P lt 005
Significance at lt 0001 () lt 001 () lt 005 () level or not significant (ns)
The use of Red Mudgypsum in vegetable production
6 RESPONSE OF CAULIFLOWERS TO RESIDUAL RED MUD (ALKALOAMreg)GYPSUM (AG) AND PHOSPHORUS ON A YELLOW KARRAKATTA SAND
Introduction
It is important to reduce the leaching of phosphorus fertiliser from sandy soils used for vegetable production into the water systems of the Swan Coastal Plain Red Mud (Alkaloam )gypsum (AG) (ie Red Mudgypsum RMG) a waste product from bauxite refining has been suggested as an amendment to reduce phosphorus leaching from sands of the Bassendean Association (Joel Gavin) used for agriculture and horticulture (Barrow 1982)
Experimental work in the field and pots showed amendment with AG significantly reduced P leaching from Joel and Gavin sands (Vlahos et al 1989 McPharlin et al 1994) compared with the unamended (01 RMGha) treatment
Previous work showed a significant reduction in maximum yield of cauliflowers with levels of residual AG of gt 60 tha compared with 01 AGha (Robertson et al 1994) This yield reduction was not due to P deficiency as increased levels of applied P did not obviate the problem Nor was it due to K deficiency as K concentrations in the youngest mature leaves (YML) although reduced by levels of residual AG did not decline to levels expected to reduce yield The converse was true for concentrations of Na in the YML which increased with levels of residual AG but not to concentrations expected to cause toxicity
Since more than 60 tha of AG may be required to significantly improve P retention by sands to enable sustainable horticultural production this yield reduction is re-examined with residual AG
Materials and methods
Site characteristics
The experiment was conducted on a yellow Karrakatta sand (McArthur and Bettenay 1960) at Medina Research Centre (32deg 13 S 115deg 49 E) 30 km south of Perth Both Alkaloamreggypsum (AG) and phosphorus had previously been applied to the site and a potato crop grown in 1995 Prior to that the site had been sown to pasture for several years Some relevant chemical characteristics of the topsoil (0-15 cm) and subsoil (15-30 cm) of the site after application of AG but prior to the application of fertiliser (except residual P) and transplanting are presented in Table 61
Red Mud (Alkaloamreg)gypsum
Alkaloamreg (Red Mud) amended with 10 (ww) gypsum (AG) was produced by the dry mix process by ALCOA of Australia Ltd at their Kwinana Residue Treatment Plant The AG had been spread manually on the site and incorporated using a rotary hoe to approximately 30 cm depth on 22 December 1994 Residual P had been applied just before planting of the previous potato crop on 17 May 1995 and incorporated with a rotary hoe The site was watered for 1 hour per day (8 mmday) using impact sprinklers until planting
Experimental design
The experimental design was a split-plot randomised block with 3 replicates The main plots were levels of AG (0 60 90 120 and 240 tha) and the sub-plots were levels of freshly-applied P (25 50 100 300 and 600 kgha) Main plots measured 7 x 12 m and sub-plots 12 x 7 m (excluding wheel tracks)
59
The use of Red Mudgypsum in vegetable production
Crop management
The site was sprayed with Roundupreg (3 Lha) twice after application of AG and prior to planting to control weeds Six week old seedlings of cauliflowers (cv Plana) obtained from a commercial nursery were transplanted manually on 18 April 1996 in 2 rows per plot with 70 cm between rows and 50 cm between plants Seedlings were dipped in Rovralreg (1 mLL) just prior to planting for control of fungi Treflanreg (14 Lha) and Dacthalreg (12 kgha) were applied immediately after transplanting to control broadleaved weeds and Sertinreg later on in the life of the crop for grass control Ambushreg (100 mLha) and Rogorreg (100 mLha) were used to control caterpillars and red legged earth-mite respectively Copper was applied for control of blackrot The crop was irrigated to a total application equivalent to 100 of the previous days pan evaporation using minisprinklers (Legoreg 6 x 6 m spacing 44 mmh) in 3 waterings of equal duration per day
Fertilisers
Pre-planting fertilisers were broadcast manually and rotary hoed on 17 April 1996
These were K2S04(244) Ca(N03)2(387) MgS047H20 (504) MnS04H20 (504) FeS047H20 (18) Borax (27) CuS045H20 (36) ZnSOH20 (28) and Na2Mo042H20 (2) P was applied as single superphosphate (91 P) at 0 to 600 kg Pha according to treatment and incorporated as before Post-planting K N and Ca were fertigated via the irrigation system as KN03 NHUNO3 and Ca (N03)2 in equal amounts per day for 12 weeks to a total of 600 kg Kha 423 kg Nha and 60 kg Caha Borax was fertigated at 20 kgha in week 3 and Mg was broadcast as MgS047H20 at 50 kgha in weeks 3 6 and 9
Measurements
Soil and soil solution
All zero P subplots were sampled 30 cores per plot just prior to planting and fertilising about 2 months after AG application to 2 depths (0-15 15-30 cm) These were oven dried at 40degC and analysed for Ec pH (CaCl2) P sorption (Ozane and Shaw 1968) bicarbonate extractable P K (Colwell 1963) total P PRI P sorption K sorption (Allen and Jeffery 1990) and cation exchange capacity (Gillman and Sumpter 1986)
The soil water was obtained by centrifugation from soil samples (0-15 cm 30 per plot) and collected from the 0 100 200 and 600 kg Pha plots across all AG treatments on the 16 May 1996 The supernatant was analysed for pH Ec Ca Mg K S and P The remaining soil was analysed for pH (H20) bicarbonate extractable P K PRI and DTPA extractable Zn After harvest 5 August 1997 soil samples were collected from 2 depths as for the preplanting treatment from all plots These were analysed for pH bicarbonate extractable P K total P PRI and exchangeable cations (Ca Mg K and N)
Plant
At buttoning on 13 June 1996 the younger mature leaves (YML) (4th from growing point) were collected from 16 plants (excluding 1 m buffer at each end of plot) in each plot They were dried at 70degC in a force draught oven for 48 h and ground to pass through a 1 mm screen Sub-samples were digested with sulphuric acidhydrogen peroxide (Yuen and Pollard 1954) and the concentration of N P and K measured by an automated colorimetric process (Varley 1966) Concentration of other nutrients (B Ca Na Mg S Fe Mn Zn and Cu) were determined by inductively coupled plasma atomic emission spectroscopy (ICP-AES) after digestion with nitric-perchloric acids (McQuaker et al 1979) Five whole plants were harvested from the middle of each plot (2 per row) at the end of the experiment on 4 July 1996 using shovels to remove as much of the roots as possible The plants were separated into four categories curds leaves stems and roots All soil was dried and digested as for ICP-AES as above and washed from the roots using tap water shaken and the excess water removed using paper towels The fresh weight of all four categories was recorded and the material was diced
60
The use of Red Mudgypsum in vegetable production
into small pieces (lt 8 cm3) using stainless steel knifes sub-samples (300 g fresh weight) were collected at random from the diced pieces and the fresh weight recorded These were dried at 70degC in a forced draught oven for 48 h and the dry weight recorded These samples were then analysed for P as for the youngest mature leaves Separate sub-samples (300 g fresh weight) of curds were collected and analysed for Ba Cd Cr Co Pb Mo Rb Sr Ti Th V and Ni using inductively coupled plasma mass spectrometry (ICP-MS) The fresh and dry weight of the curds leaves stems and roots at harvest were used to calculate P uptake in kgha)
Harvest
Harvest commenced when the leaves surrounding the head opened and exposed the curds 77-80 days after transplanting At this stage florets at the periphery of the curd had just begun to separate Sixteen curds (12 plus 4 from whole plant samples above) were collected from the central 4 m of both rows (1 m buffer) and then all the leaves and stems removed according to requirements for export market Each fresh curd was weighed and rejects recorded if undersize (lt 500 g) oversize (gt 2000 g) discoloured (yellowing) overmature (separation of florets in the centre of curd) diseased damaged or otherwise distorted The total marketable and reject yield were recorded for each plot
Analysis of data
Analysis of variance was carried out on level of applied AG or P versus (a) chemical characteristics of soil (bicarbonate extractable P total P etc) preplanting and harvest (b) concentrations of nutrients in soil solution at midgrowth (c) concentration of nutrients in YMLs at midgrowth (d) concentration of elements in curds at harvest (e) P uptake by plant parts and (f) total marketable and reject yield of curds at harvest Mitscherlich curves and inverse polynomials were fitted to the relationship between level of applied P and yield at each level of applied AG The level of applied P required for 95 99 and 100 (in case of inverse polynomials) of maximum yield was calculated Mitscherlich curves were fitted to the relationship between level of applied P and P in YMLs at midgrowth at all levels of AG The P in YMLs corresponding to the level of applied P required for 95 99 or 100 of maximum yield (as determined from yield versus applied P plots) was then determined
Mitscherlich curves were also fitted to the relationship between level of applied P and P uptake by curds leaves stems and roots and the P uptake corresponding to whole plants (additions of all 4) level of P required for 95-100 of maximum yield determined Phosphorus uptake by plant parts or whole plants on 0 P plots were deducted from P uptake at other rates to account for non-fertiliser sources of P This was used to adjust P uptake when determining P fertiliser recovery efficiency (RE) by plant parts or whole plants ie fertiliser P uptake by plant parts or whole plantsP applied both in kgha (Novoa and Loomis 1981)
The effect of residual AG andP on chemical characteristics of the soil
Increased levels of previously-applied (residual) AG resulted in a significant increase in Ec pH (CaCl2) Colwell P and PRI in the topsoil (0-15 cm) of a Karrakatta sand prior to current the application of fertilisers and planting (Table 61 Fig 61) There was no significant effect of level of residual AG on the levels of Colwell K in the topsoil Increasing levels of previously-applied (residual) P resulted in a significant increase in Colwell P and a decrease in PRI and pH at the same time but had no effect on the levels of Colwell K in the topsoil
61
The use of Red Mudgypsum in vegetable production
Table 61 Chemical characteristics of the topsoil (0-15 cm) of a yellow Karrakatta sand 12 months after application of Alkaloamreggypsum (AG) (residual AG) and phosphorus (P) just prior to fertiliser application and transplanting
AG Ec pH BicP1 BicK1 PRI2
(tha) (mSm) (CaCl2) (H8g) (Hgg) (mLg)
0 36 70 262 199 093
60 62 78 397 308 101
90 70 80 390 378 12
120 73 80 402 391 14
Lsd3 057 018 75 122 018
Sig4 ns
P (kgha)
Ec (mSm)
pH (CaCl2)
BicP1
(M-gg) BicK1
(figg) PRI2
(mLg)
0 59 78 117 323 17
25 58 78 147 338 15
50 58 78 160 322 16
100 58 78 255 327 13
300 62 76 554 309 06
600 66 75 944 296 005
Lsd3 063 01 58 60 02
Sig4 ns ns
1 After Colwell (1963) 2 After Allen and Jeffery (1990) 3 Least significant difference at P lt 005 4 Significance at lt 0001 () lt 001 () lt 005 () level or not significant (ns)
62
The use of Red Mudgypsum in vegetable production
mdash A
8 40 gt -o deggt 35 - en =gt mdash sect 30 _raquo CO
e 25 ltD O d
5 20
1 ^ I I I
T3
C
o
c CO o c o o
0 20 40 60 80 100120140
Residual AG (tha)
u u bull B
80 l
60
40
mdash n bull 20
n i i i i
I
i i i
100 200 300 400 500 600 700
Residual P (kgha)
Figure 61 (A B) Bicarbonate extractable P (bull) and K (bull) (figg dry soil after Colwell 1963) in the top soil (0-15 cm) of a yellow Karrakatta sand prior to fertilising and planting with level of residual Alkaloamreggypsum (t AGha) (A) and P (kgha) (B) Vertical bars refer to Lsd (P lt 005) for differences between levels of AG or P
5 E Q 0 -
20 40 60 80 100120 140
Residual AG (tha)
0 100 200 300 400 500 600 700
Residual P (kgha)
Figure 61 (C D) Phosphorus retention index (PRI) after Allen and Jeffery (1990) in the topsoil (0-15 cm) of a yellow Karrakatta sand prior to fertilising and planting with level of residual Alkaloamreggypsum (t AGha) (C) and P (kgha) (D) Vertical bars refer to Lsd (P lt 005) for differences between levels of AG or P
63
The use of Red Mudgypsum in vegetable production
One month after planting there was a significant increase in concentration of Ca Na and pH and a decrease in K concentration with level of residual AG in the soil solution at 15 cm depth There was no significant effect of level of residual AG on the Ec or concentration of Mg S and soluble reactive P (Psr) in the soil solution (Table 62 (a) Fig 62) There was a significant decrease in Ec pH and concentration of Mg Na and an increase in concentration of Ca S and Psr in soil solution with level of residual P
Table 62 (a) Ec (mSm) pH and concentration of nutrients (ugmL) in soil solution 1 month after planting cauliflowers with level of residual Alkaloamreggypsum (AG) and phosphorus (P)
AG
AG (tha)
Ec (mSm)
pH Ca (ngmL)
Mg (ugmL)
Na (jigmL)
K (UgmL)
S (jigmL)
Psrp1
(pgmL)
0 129 75 91 141 105 81 28 05
60 144 77 108 131 121 64 30 06
120 147 76 123 136 120 50 33 04
Lsd2 33 01 14 09 4 7 1 02
Sig3 ns ns ns ns
P
p (kgha)
Ec (mSm)
pH Ca (UgmL)
Mg (ligmL)
Na (jigmL)
K (UgmL)
S (UgmL)
Psrp1
(VigmL)
0 171 78 107 141 121 68 23 01
100 138 77 104 144 111 58 24 02
300 120 76 103 128 110 63 31 06
600 130 73 117 133 116 71 43 13
Lsd2 20 02 10 11 10 13 7 02
Sig3 ns
Soluble reactive P 2 Least significant difference at P ^ 005 3 Significance at lt 0001 () lt 001 () lt 005 () level or not significant (ns)
64
The use of Red Mudgypsum in vegetable production
3
C
o
o (gt
o in c c o
5 c CD O
o O
3
o
c o
c ltu o c o
o 0 20 40 60 80 100 120 140
Residual AG (tha)
0 100 200 300 400 500 600 700
Residual P (kgha)
Figure 62 (A B) Concentration (figmL) of Ca (bull) Mg (bull) Na (A) K (T) and S (bull) in soil solution (0-15 cm) under cauliflower one month after planting with level P residual Alkaloamreggypsum (AG) (A) and (B) Vertical bars refer to Lsd (P lt 005) for differences in concentration between levels of AG Where bars are not shown Lsd is less than size of symbol
There was a significant increase in Colwell P K and PRI in the topsoil (0-15 cm) and no change in DTPA extractable Zn with level of residual AG one month after planting (Table 62 (b)) As level of residual P increased there was a significant increase in Colwell P and decrease in PRI with no change in Colwell K or DTPA extractable Zn in the topsoil one month after planting
The use of Red Mudgypsum in vegetable production
Table 62 (b) Extractable P K Zn and phosphorus retention index of the TopsoU (0-15 cm) of a yellow Karrakatta sand 1 month after planting of cauliflowers with level of residual Alkaloamreggypsum (AG) and phosphorus (P)
AG
Ag BicP1 BicK1 Zn2 PRI3
(tha) (Pgg) (Pgg) (Pgg) (mLg)
0 27 41 25 05
60 45 43 26 03
120 50 59 23 07
Lsd4 8 6 05 01
Sig5 ns
p
p (kgha)
BicP1
(Pgg) BicK1
(Pgg)
Zn2
(l-igg) PRI3
(mLg)
0 9 46 19 12
100 21 47 22 09
300 42 46 25 03
600 90 52 31 -03
Lsd4 7 5 10 02
Sig5 ns ns
1 After Colwell (1963) 2 Extracted in DTPA 3 After Allen and Jeffery (1990) 4 Least significant difference at P ^ 005 5 Significance at lt 0001 () lt 001 () lt 005 () level or not significant (ns)
After harvest of cauliflowers there was a significant increase in Colwell P and K total P actual and predicted PRI (PRI and PRIp) with residual AG in the topsoil and subsoil of a Karrakatta sand (Table 63 (a) (b)) There was a significant increase in Colwell P and total P and decrease in Colwell K PRI and PRIp with level of residual P in both the topsoil and subsoil after harvest (Fig 63 (A B))
66
The use of Red Mudgypsum in vegetable production
Table 63 Extractable P K total P and phosphorus retention index of the topsoil (0-15 cm) and subsoil (15-30 cm) of a yellow Karrakatta sand after harvest of cauliflowers with level of residual AIkaloamreggypsum (AG) and phosphorus (P)
(a) Topsoil
AG
AG BicP1 BicK1 TotP2 PPJ3 PPJP4
(tha) (ngg) (Hgg) (Pgg) (mLg) (mLg)
0 16 28 68 10 26
60 25 42 86 15 41
90 25 46 91 16 43
120 26 54 96 18 46
Lsd5 3 9 8 005 03
Sig6
P (kgha)
BicP1
(Pgg) BicK1
(vigg) TotP2
(ngg) PPJ3
(mLg) PPJP4
(mLg)
0 7 46 58 19 27
25 8 45 63 19 28
50 9 44 64 20 30
100 15 43 72 17 33
300 37 40 103 09 48
600 63 36 152 03 67
Lsd5 3 6 8 03 05
Sig6
1 After Colwell (1963) 2 After Allen and Jeffery (1990) 3 Phosphorus retention index (Allen and Jeffery 1990) 4 Predicted phosphorus retention index (Allen and Jeffery 1990) 5 Least significant difference at P ^ 005 6 Significance at lt 0001 () lt 001 () lt 005 () level or not significant (ns)
The use of Red Mudgypsum in vegetable production
120
o lgt 100 bull gt
TJ
rn laquon D ) 3
mdash-
on
60
^^ m i _
c 40 ltigt o c o O 20
160 A (I 140
^ ^ ^ ^ 1 o (0 ^ ^ ^ ^ 1 gtraquo 120
^plusmn bull o
^ ^ ^ ^
66
100
^ 3 80
^ mdash ^ tra
tion
60
^ ^ - ^ ^ ^ cen 40
o 20 o 20
I I I I I I I
O
10
0
0 20 40 60 80 100 120 1lt
O
10
Residual AG (tha)
0 100 200 300 400 500 600 700
Residual P (kgha)
Figure 63 (A B) Bicarbonate extractable P (bull) K (bull) and total P (A) in the topsoil (0-15 cm) of a yellow Karrakatta sand after harvest of cauliflowers with level of residual AIkaloamreggypsum (t AGha) (A) and P (kgha) (B) Vertical bars refer to Lsd (P lt 005) for difference between level of AG or P Lsd not shown when less than size of symbol
68
The use of Red Mudgypsum in vegetable production
Table 63 Extractable P K total P and phosphorus retention index of the topsoil (0-15 cm) and subsoil (15-30 cm) of a yellow Karrakatta sand after harvest of cauliflowers with level of residual Alkaloamreggypsum (AG) and phosphorus (P)
(b) Subsoil
AG
AG BicP1 BicK1 TotP2 PRI3 PRJJP4
(tha) (Pgg) (ugg) (ngg) (mLg) (mLg)
0 15 23 69 08 24
60 23 31 82 12 36
90 24 37 91 14 39
120 25 40 90 17 43
Lsd5 4 6 7 01 03
Sig6
P (kgha)
BicP1
(ngg) BicK1
(ugg) TotP2
(ugg) PRI3
(mLg) PRIP4
(mLg)
0 6 36 57 18 25
25 8 36 63 17 26
50 8 34 63 17 26
100 13 31 71 15 29
300 33 29 102 08 43
600 61 30 141 03 64
Lsd5 5 5 8 02 05
Sig6
1 After Colwell (1963) 2 After Allen and Jeffery (1990) 3 Phosphorus retention index (Allen and Jeffery 1990) 4 Predicted phosphorus retention index (Allen and Jeffery 1990) 5 Least significant difference at P ^ 005 6 Significance at lt 0001 () lt 001 () lt 005 () level or not significant (ns)
The use of Red Mudgypsum in vegetable production
100
o CO
gtlaquo
C
o CO
bull-raquo
c o o o
20 40 60 80 100 120 140
Residual AG (tha) 0 100 200 300 400 500 600 700
Residual P (kgha)
Figure 63 (A B) Bicarbonate extractable P (bull) K (bull) and total P (A) in the subsoil (0-15 cm) of a yellow Karrakatta sand after harvest of cauliflowers with level of residual Alkaloamreggypsum (t AGha) (A) and P (kgha) (B) Vertical bars refer to Lsd (P lt 005) for difference between level of AG or P Lsd not shown when less than size of symbol
Ec pH (CaCl2) and exchangeable Ca and Na in the top and subsoil after harvest increased significantly with level of residual AG whilst there was no change in exchangeable Mg (Table 64 (a) (b)) Whilst there was no change in exchangeable K with level of residual AG in the topsoil there was a significant increase in exchangeable K in the subsoil (Table 64 (b))
70
The use of Red Mudgypsum in vegetable production
Table 64 Ec (mSm) pH (CaCl2) and exchangeable cations (me) in topsoil (0-15 cm) and subsoil (15-30 cm) of a yellow Karrakatta sand with level of residual AIkaloamreggypsum (AG) and phosphorus (P) after harvest of cauliflowers
(a) Topsoil (0-15 cm)
AG
AG Ec pH Ca1 Mg1 K1 Na1
(tha) (mSm) (CaCl2) (me) (me) (me) (me)
0 29 65 24 027 006 004
60 47 73 32 025 009 010
90 59 77 36 023 015 015
120 66 78 40 025 012 018
Lsd2 07 07 06 005 006 001
Sig3 as ns
P (kgha)
Ec (mSm)
PH (CaCl2)
Ca1
(me) Mg1
(me) K1
(me) Na1
(me)
0 43 73 30 025 001 011
25 46 73 33 026 010 011
50 46 73 32 025 010 011
100 52 74 32 025 010 011
300 56 74 34 024 009 011
600 58 73 37 025 014 012
Lsd2 05 05 03 002 007 -
Sig3 ns ns ns
Exchangeable in 1 m NILt-Cl 2 Least significant difference at P ^ 005 3 Significance at lt 0001 () lt 001 () lt 005 () level or not significant (ns)
The use of Red Mudgypsum in vegetable production
soil b
A soil
dry
4 _ I dry
I ^5 CD CD
b_ 3 - E c c o o CO at
i
U o CD CD
Xgt j a CO bull| mdash CO CD ogt
m- mdashM- mmdash JZ 0 - +~ -- mdash c CJ o X X LU
i 1 I i i i i LU
0 20 40 60 80 100 120 1^ W
Residual AG (tha)
100 200 300 400 500 600 700
Residual P (kgha)
Figure 64 (A B) Exchangeable Ca (bull) Mg (bull) K (A) and Na ( bull ) (me) in the topsoil (0-15 cm) of a yellow Karrakatta sand with level of residual Alkaloamreggypsum (t AGha) or P (kgha) Vertical bars refers to Lsd (P lt 005) for differences in concentration between levels of AG or P Lsd not shown when less than size of symbol
72
The use of Red Mudgypsum in vegetable production
Table 64 Ec (mSm) pH (CaCl2) and exchangeable cations (me) in topsoil (0-15 cm) and subsoil (15-30 cm) of a yellow Karrakatta sand with level of residual AlkaIoamreggypsum (AG) and phosphorus (P) after harvest of cauliflowers
(b) Subsoil (15-30 cm)
AG
AG Ec pH Ca1 Mg1 K1 Na1
(tha) (mSm) (CaCl2) (me) (me) (me) (me)
0 34 66 24 026 006 005
60 50 75 33 024 008 010
90 64 78 38 023 01 016
120 68 79 41 024 01 019
Lsd2 05 01 07 006 001 003
Sig3 ns
P (kgha)
Ec (mSm)
pH (CaCl2)
Ca1
(me) Mg1
(me) K1
(me) Na1
(me)
0 48 75 30 023 009 011
25 51 74 33 026 009 011
50 50 75 34 025 008 013
100 61 75 35 026 008 013
300 57 75 34 022 007 013
600 58 73 38 024 008 013
Lsd2 08 01 04 003 001 003
Sig3 ns
1 Exchangeable in 1 m NH4-CI 2 Least significant difference at P ^ 005 3 Significance at lt 0001 () lt 001 () lt 005 () level or not significant (ns)
The use of Red Mudgypsum in vegetable production
o 0 oi
4 CO c CO
gt T3 4 _ bull o
0s -5 3 agt CD
fc_ 3 - g
on
o 2 CO 2 CO
u 2
o CD CD 1 X I SI
1 CD 1 CD CD CU
O
n ^ 1 CO n X bull mdashXmdash mdash 1 1 CO U J= n bull - w 1 CO U
o o X X Lil
i i 1 1 i i 1 HI
0 20 40 60 80 100 120 140
Residual AG (tha)
100 200 300 400 500 600 700
Residual P (kgha)
Figure 64 (C D) Exchangeable Ca (bull) Mg (bull) K (A) and Na (T) (me) in the subsoil (0-15 cm) of a yellow Karrakatta sand with level of residual Alkaloamreggypsum (t AGha) or P (kgha) Vertical bars refers to Lsd (P lt 005) for differences in concentration between levels of AG or P Lsd not shown when less than size of symbol
As level of residual P increased there was a significant increase in exchangeable Ca in the tbpsoil and subsoil but no significant effect on exchangeable Mg K and Na in the topsoil and variable effects on exchangeable Mg and K in the subsoil Ec increased significantly with level of residual P in both the top and subsoil whilst pH in either was effected little by level of applied P
The effect of level of residual AG andP on the concentration of nutrients in cauliflower leaves
The level of residual AG had no effect on the concentrations of N Ca S P S Mg Fe Zn Mn B and Cu in the youngest mature leaves of cauliflowers at buttoning but increased levels significantly reduced the concentration of K (Fig 65 (A B)) As level of residual P increased there was a significant increase in the concentration of K P S Cu and Mn in the YMLs whilst concentrations of N decreased and B concentrations were variable with no clear trends
74
The use of Red Mudgypsum in vegetable production
Table 65 Concentration of nutrients (dry weight basis) in youngest mature leaves of cauliflowers at buttoning with level of applied residual Alkaloamreggypsum (AG) and phosphorus (P)
(a) Macronutrients
AG
AG N1 K1 Ca2 S2 P1 Na2 Mg2
(tha) () () () () () () ()
0 49 42 23 077 040 039 027
60 51 40 23 078 042 036 025
90 51 39 23 079 043 036 025
120 49 39 24 078 042 036 025
Lsd3 03 02 08 009 007 010 004
Sig4 ns ns ns ns ns ns
P N1 K1 Ca2 S2 P1 Na2 Mg2
(kgha) () () () () () () ()
0 53 36 22 069 027 033 024
25 51 38 24 071 030 038 026
50 52 40 24 075 034 040 027
100 51 41 24 079 043 041 027
300 48 43 24 087 055 039 026
600 47 42 20 086 060 031 023
Lsd3 02 02 04 003 004 006 003
Sig4 ns ns
1 After Varley (1966) 2 After McQuakerefl (1979) 3 Least significant difference at P lt 005 4 Significance at lt 0001 () lt 001 () lt 005 () level or not significant (ns)
The use of Red Mudgypsum in vegetable production
Table 65 Concentration of nutrients (dry weight basis) in youngest mature leaves of cauliflowers at buttoning with level of applied residual AlkaIoamreggypsum (AG) and phosphorus (P)
(b) Micronutrients
AG
AG (tha)
Fe (ugg)
Zn1
(Pgg) Mn1
(ugg) B1
(ugg) Cu1
(ugg)
0 122 31 19 21 28
60 121 32 22 22 30
90 119 36 25 22 32
120 120 29 23 22 29
Lsd2 21 8 6 1 05
sig3 ns ns ns ns ns
P (kgha)
Fe1
(Pgg)
Zn1
(ugg) Mn1
Gigg)
B1
(Fgg)
Cu1
(Pgg)
0 112 33 19 22 28
25 120 32 22 22 29
50 125 32 21 23 29
100 132 38 24 23 31
300 129 30 25 22 32
600 106 29 23 21 32
Lsd2 19 6 3 1 03
Sig-3 ns ns
After McQuaker et al (1979) 2 Least significant difference at P ^ 005 3 Significance at lt 0001 () lt 001 () lt 005 () level or not significant (ns)
The relationship between residual P ie Colwell P and P in YMLs at buttoning were best described by Mitscherlich relationships at all levels of residual AG (Fig 65)
The concentration of P in YMLs corresponding to levels of Colwell P necessary for 95 of maximum yield were 047 050 054 and 048 and for 99 of maximum yield were 053 055 058 and 054 for 0 60 90 and 1201 residual AGha respectively
76
The use of Red Mudgypsum in vegetable production
Q
en
3
gt-c 0
07
06
05
04
03
02
01 0
065
060
055
050
045
040
035
030
025
020
A
if 20 40 60 80 100
Colwell P (ugg dry soil)
_ 065
Q S 055
060
tz
ro _ i
gt
120
C bull - - - mdash bull
20 40 60 80 100
Colwell P (ugg dry soil)
120
050
045
040
035
030
025
020
065
060
055
050
045
040
035
030
025
020
-B
bull
- bull I
I I
bull
i i i
20 40 60 80 100
Colwell P (ugg dry soil)
120
-bull D
I I i i i
20 40 60 80 100
Colwell P (ugg dry soil)
120
Figure 65 P in youngest mature leaves at buttoning () corresponding to Colwell P necessary for 95 (dashed) or 99 (whole) of maximum yield at 0 (A) 60 (B) 90 (C) and 120 (D) t of residual Alkaloamreggypsumha Dashed and whole horizontal lines refers to P in YML corresponding to Colwell P required for 95 and 99 of maximum yield respectively
The equations for the fitted lines are
A y = 05964 - 0763 x exp (-0068) (B2 = 089)
B y = 05855 - 05144 x exp (-00465x) (R2 = 098)
C y = 006058 - 0549 x exp (-00435x) (B2 = 096)
D y = 06399 - 05208 x exp (-00291) (R2 = 097)
77
The use of Red Mudgypsum in vegetable production
The effect of level of residual AG andP on the yield of cauliflowers
There was no significant effect of levels of residual AG on the total or marketable yield of cauliflowers However yield responded significantly to levels of applied residual P and the interaction between residual P and AG was significant (Tables 66 (a) (b))
The relationship between Colwell P and total yield was best described by Mitscherlich relationships for all levels of residual AG (Fig 66) The Colwell P required for 95 of maximum total yield was 26 40 48 and 40 ugg dry soil and for 99 35 55 71 and 58 ugg dry soil for 0 60 90 and 1201 residual AGha respectively
Table 66 Curd yield (total and marketable) of cauliflowers (tha) at harvest with level of residual Alkaloamreggypsum (AG) and phosphorus (P)
(a) Total
AG p
(kgha) (tha) p
(kgha)
0 60 90 120
0 59 64 69 100
25 134 126 123 83
50 139 133 117 143
100 163 200 164 177
300 203 236 198 204
600 215 237 208 194
Ls-d1 36 (AG) 17 (P) 48(AGP) -
Sig2 ns
(b) Marketable
p (kgha)
AG (tha) p
(kgha)
0 60 90 120
0 14 14 18 56
25 83 74 84 13
50 90 99 67 99
100 138 188 125 160
300 187 232 182 190
600 206 234 191 185
Lsd1
Sig2
48 (AG)
ns 23 (P)
62(AGP)
-
Least significant difference at P lt 005 2 Significance at lt 0001 () lt 001 () lt 005 () level or not significant (ns)
The use of Red Mudgypsum in vegetable production
0 20 40 60 80 100120140160
Colwell P (ugg dry soil)
0 20 40 60 80 100120140160
Colwell P (ugg dry soil)
lt x
UJ gt-Q
o
lt X
Q _ l UJ gt-Q rr D O
24
22
20
18
16 14
12
10
8
6
4
-D
bull
I I
I I
I I
I
^~ bull
i i i i i
20 40 60 80 100120140160
Colwell P (ugg dry soil)
20 40 60 80 100120140160
Colwell P (ugg dry soil)
Figure 66 Colwell P in topsoil (0-15 cm) at planting versus yield of cauliflowers at 0 (A) 60 (B) 90 (C) and 120 (D) tha of residual Alkaloamreggypsum (AG) Dashed and whole vertical lines represent Colwell P required for 95 and 99 of maximum yield respectively
The equations for the fitted lines are
A y = 2088 - 818 x exp (-017x) (i2 = 089)
B y = 23731 - 4578 x exp (-00949) (i2 = 099)
C y = 2051 - 286 x exp (-00697) (R2 = 086)
D y = 2002 - 354 x exp (-0090) (B2 = 086)
79
The use of Red Mudgypsum in vegetable production
Discussion
There was no significant reduction in maximum yield (ie A values) of cauliflower (cv Plana) curds grown on Karrakatta sands amended with residual AG from 0 to 120 tha in this work This is in contrast to previous work (Robertson et al 1994) in which maximum curd yields of cauliflowers were significantly reduced with levels of residual AG at 120 tha compared with 0 and 60 tha In both studies concentrations of K were reduced and concentrations of Na were increased in the YML at buttoning with increasing levels of residual AG The increase in concentration of Na and the decrease in concentration of K in the YML with level of applied AG was related to similar changes in the concentrations of these elements in the soil solution with both freshly-applied (Section 5) and residual AG one month after planting As with freshly-applied AG increasing levels of residual AG resulted in increasing levels of Na in the soil (exchangeable) or soil solution however whilst K concentrations in soil solution decreased the K retained by the soil measured as either Colwell K or exchangeable K increased Increasing levels of residual AG resulted in increased pH in the topsoil as with fresh AG but this did not reduce the concentration of Mn Cu and Zn in the YML or increase the concentration of Mo These changes would be expected with increases in soil pH (Porter 1984) The level of Colwell P required for 95 to 99 of maximum yield increased from 26 and 35 ugg dry soil at 01 AGha to 48 and 71 ugg at 901 of residual AGha The level at 1201 AGha was slightly lower ie 40 and 58 ugg These levels are similar to those reported as necessary for 95 and 99 of maximum yield of Arfak cauliflowers 40 and 55 ugg Colwell P in planted in autumn and spring on unamended Karrakatta sands (McPharlin et al 1995) It therefore does not appear that AG amendment increases the residual P as measured by Colwell P requirement of cauliflower significantly This is in contrast to the significantly higher level of applied P necessary to maximise yield when AG is freshly-applied ie from 120-160 to gt 300 kg of Pha at 0 and 1201 AGha respectively (Robertson et al 1994 and Section 5) However requirements of residual (Colwell) P and freshly-applied P are not always correlated For example the Colwell P necessary for the maximum yield of spring and winter-planted lettuce was similar ie 80 to 120 ugg dry soil whereas the level of freshly-applied P required for maximum yield of winter-planted lettuce was 50 higher than in spring (McPharlin et al 1996 McPharlin and Robertson 1997)
References
Allen DG and Jeffery RC (1990) Methods for analysis of phosphorus in Western Australian soils Chemistry Centre of Western Australia Report of Investigation No 37
Barrow NJ (1982) Possibility of using caustic residue from bauxite for improving the chemical and physical properties of sandy soils Australian Journal of Experimental Agriculture Research 33 275-285
Colwell JD (1963) The estimation of phosphorus fertiliser requirements of wheat in southern New South Wales by soil analysis Australian Journal of Experimental Agriculture Animal Husbandry 3 190-197
Gillman GP and Sumpter EA (1986) Modification to the compulsive exchange method for measuring exchange characteristics of soils Australian Journal of Soil Research 24 616
McArthur WM and Bettenay E (1960) The development and distribution of the soils of the Swan Coastal Plain Western Australia CSIRO Division of Soils Soils Publication No 16
McPharlin IR Jeffery RC and Pitman DH (1996) Phosphorus requirements of winter planted lettuce (Lactuca sativa L) on a Karrakatta sand and the residual value of phosphate as determined by soil test Australian Journal Experimental Agriculture 36 887-903
80
The use of Red Mudgypsum in vegetable production
McPharlin IR Jeffery RC and Weissberg R (1994) Determination of the residual value of phosphate and soil test phosphorus calibration for carrots on a Karrakatta sand Communications in Soil Science Plant Analysis 25 (5-6) 489-500
McPharlin IR and Robertson WJ (1997) Response of spring-planted lettuce (Lactuca sativa L) to freshly-applied and residual phosphorus and to phosphate fertiliser placement on a Karrakatta sand Australian Journal of Experimental Agriculture (in press)
McPharlin IR Robertson WJ Jeffery RC and Weissberg R (1995) Response of cauliflower to phosphate fertiliser placement and soil test phosphorus calibration on a Karrakatta sand Communications in Soil Science and Plant Analysis 26(3-4) 607-620
McQuaker NR Brown DF and Kluckner PD (1979) Digestion of environmental materials for analysis by inductively coupled plasma-atomic emission spectrometry Analytical Chemistry 51 1082-1084
Novoa R and Loomis RS (1981) Nitrogen and plant production Plant and soil 58 177-204
Ozanne PG and Shaw TC (1968) Advantages of recently developed phosphate sorption test over the older extractant methods for soil phosphate (ed JW Holmes) pp 273-280 In Transactions of the 9th International Congress of Soil Science Volume 2 Angus and Robertson Sydney Australia
Porter WM (1984) Soil acidity Agriculture Western Australia Farmnote No 6884
Robertson WJ McPharlin IR and Jeffery RC (14) Final report of investigation into the use of gypsum-amended Red Mud as a soil-amendment on horticultural properties on the Swan Coastal Plain Report to HRDC (Project No V0039RO) Department of Agriculture Western Australia
Varley J A 1966 Automatic methods for the determination of nitrogen phosphorus and potassium in plant material Analyst 91 119-126
Vlahos S Summers KJ Bell DT and Gilkes RJ (1989) Reducing phosphorus leaching from sandy soils with Red Mud bauxite processing residues Australian Journal of Soil Research 27 651-662
Yuen SH and Pollard AG (1954) Determination of nitrogen in agricultural material by the Nessler reagent IL Microdetermination in plant tissue and soil extracts Journal of Science Food Agriculture 5 364-369
The use of Red Mudgypsum in vegetable production
7 RETENTION LEACHING AND RECOVERY OF P AND OTHER NUTRIENTS BY CARROTS GROWN ON A JOEL SAND AMENDED WITH RESIDUAL RED MUD (ALKALOAMreg)GYPSUM (AG) IN LARGE POTS
Introduction
It is difficult to quantify the retention of P by sands amended with Red Mud (Alkaloamreg)gypsum (AG) in the field because of native P in the soil and soluble P in the AG (Robertson et al 1994) It is easy to quantify leaching of P and other nutrients such as N and K from AG amended sands in pots or columns by collecting leachate and measuring concentration (McPharlin et al 1995) However plants were not grown in the columns used by McPharlin et al so there was no measurement of plant uptake of P and other nutrients to complete the nutrient budget Potatoes were grown successfully in Spearwood sands in large pots (70 L) and a complete N budget (N applied N retained by soil N leached and uptake by plant) determined (Hegney et al 1996)
Freshly-applied AG may not be in equilibrium with the soil to which it is applied ie the pH Ec and concentrations of elements such as Ca and Na may change rapidly with time The age of the AG may effect its capacity to retain P on amended soils AG may improve the retention of other nutrients such as ammonium N (McPharlin et al 1995) and K (Sections 5 and 6) by amended sands AG which has been applied to sands in the field for at least 2 to 5 years should be close to equilibrium with the soil as substantial leaching would have occurred AG of this age would give the best estimate of its long term capacity to reduce leaching of P and other nutrients from poor grey sands on the Swan Coastal Plain The purpose of this work was to quantify the leaching and retention of P and other nutrients (N Ca K etc) from Joel sands which had been amended with AG at different levels in the field for 14 years Carrots a major vegetable crop grown on the Swan Coastal Plain were used as the experimental crop and grown in these AG amended sands in large pots
Materials and methods
Pots
Fibreglass pots used for the experiment were 45 cm in diameter and 50 cm deep The area of soil surface was 016 m2 and the volume was 70 L The bottom of the pots tapered to a hole (diameter) to which was attached a polyethylene hose (length and diameter) and tap The pots were painted white to reduce heat The pots were placed on a metal table (with mesh tops) and the hose passed through a hole in the centre of a lid of a plastic (20 L) bucket
Experimental design
The experimental design was a 4 (levels of residual AG ie 0 125 250 and 1000 tha) times 5 (levels of applied P ie 0 50 100 200 and 400 kgha) factorial in a randomised block with 3 replicates The level of applied AG or Pha was calculated using the area of the soil surface The total number of pots was 60
Soil and Red Mud (Alkaloamreg)gypsum (AG)
Virgin Joel sand was obtained from a commercial garden supply site in Jandakot The top 20 cm of the soil was removed and the rest sieved (15 mm) to remove debris About 20 kg of Joel sand was added to each pot (10 cm depth) Another 60 kg (30 cm depth) of sand was added to the 0 AGha pots to which had been mixed lime and preplant fertilisers (see later) so the surface of the soil was about 10 cm below the top edge of the pot AG amended sand was obtained from a field site in Hope Valley Road Kwinana managed by ALCOA where it had been applied (and incorporated using a rotary hoe) to pastures growing on a Joel sand in 1983 at 0 250 500 and 1000 tha This AG amended sand was added to pots corresponding to 250 and 1000 tha in the field after the preplant fertiliser but not lime was added and was incorporated to a similar depth as in the 01 AGha pots The 125 t AGha treatment was
82
The use of Red Mudgypsum in vegetable production
obtained by mixing AG amended sand from the 250 tha field site with an equal weight of Joel sand in a cement mixer
Fertilisers and lime
The following fertilisers (in kgha) were thoroughly mixed (using a cement mixer) with the top 25-30 cm of the soil in each pot before planting Urea (108) K2SO4Q2I) MgS047H20 (100) MnS04H20 (100) Na2B4O710 H20 (50) FeS047H20 (50) CuS045H20 (50) ZnS04H20 (50) and NaMo042H20 (4) To this was added P at 0 50 100 200 and 400 kgha as single superphosphate at each level of residual AG Hydrated lime (Ca (OH)2) was mixed with the preplanting fertilisers on the 0 kg AGha treatment at 36 gpot
N K and Ca were fertigated via the drip irrigation system at 200 200 and 52 mgL using KNO3 NH4NO3 and Ca (N03)2 from immediately after sowing to 140 days after sowing (18 August 1996) MgS047H20 was broadcast at 100 kgha to each pot at weeks 6 and 12
Irrigation
The plants were irrigated using drippers (Netafim 2 Lh pressure compensated with 4 equalisers per pot) at 15 times the average monthly pan evaporation until 160 days after sowing (7 September 1996) Adjustments were made on a daily basis if evaporation was significantly higher or lower than the long term average (Table 71)
Table 71 Irrigation requirements of carrots in pot experiments
Month DAS Lpotday Minutesday
April 1- 27 10 33
May 28- 59 065 21
June 60- 90 044 14
July 91-122 044 14
August 123-154 056 19
September 155-160
Adjusted for 90 efficiency of irrigation system
Rain was excluded from the pots using a movable rain out shelter made of perspex and aluminium This was removed at all other times
Crop management
The soil in each pot was irrigated to field capacity ie so that free drainage occurred Carrot (cv Top Pak) seeds were sown on a 9 x 9 cm spacing and 1 cm deep with 5 seeds per site on 3 April 1996 These were thinned to 14 seedlingspot (88 plantsm2) after emergence (15 April 1996) No application of fungicides or insecticides were necessary
Soil and plant measurements
Soil
Immediately before fertilising and sowing 5 cores (22 diameter x 15 cm deep) were taken from each pot and dried in a force draught oven at 40degC Each sample was analysed for extractable P and K (Colwell 1963) pH (CaCl2 and H20) total P (Allen and Jeffery 1990) PRI (Allen and Jeffery 1990) total N extractable ammonium N (KC1) extractable nitrate N (KC1) organic carbon cation exchange capacity and exchangeable cations
83
The use of Red Mudgypsum in vegetable production
Leachate
Leachate from each pot was collected in 20 L plastic buckets under the pots each week from the 4 April 1996 to 22 July 1996 PMA (phenyl mercuric acetate) was added to the leachate to prevent contamination Total water volume was measured and sub-samples (200 mL) collected and submitted for analysis of P NH4-N NO3-N K Na Ca S Mg Ec and pH analysis of concentration The quantities leached of the above elements in kgha were calculated from concentration and volume of leachate collected and surface area of soil in pot
Harvest
The plants were harvested on 7 September 1997 and the total marketable and reject root yield determined for each plot
Analysis of data
Analysis of variance (Genstattrade for Windows version 32) was carried out on level of AG and P versus yield (total marketable reject) level of chemical factors in soil after harvest concentration of nutrients in youngest mature leaves at midgrowth tops and roots at harvest and leachate on 22 April 1996 5 May 1996 and 22 July 1996 and quantities of elements leached at each sampling time
Mitscherlich or linear relationships were fitted to level of P versus yield (total) at each level of residual AG P required for 95 and 99 of maximum yield was delivered at each level of residual AG P uptake by carrots was determined from the dry weight and P in tops and roots for each treatment Fertiliser P uptake was determined by deducting uptake on 0 kg Pha treatments at each level of applied AG Fertiliser P retained in the top-soil was determined from the concentration of total P and bulk density P leached was fertiliser leached below 15 cm The P in each plant fraction soil and leached was determine at each level of applied P and AG
Results
Effect of level of residual AG on chemical characteristics of Joel sand
Soil pH (CaCl2 H20) Ec Colwell P phosphorus retention index cation exchange capacity exchangeable Ca and Na and silt and clay all increased with level of residual AG in the top soil (0-15 cm) of a Joel sand before fertilising and sowing (Table 72)
The use of Red Mudgypsum in vegetable production
Table 72 Chemical and physical characteristics of Joel sand amended with residual Alkaloam gypsum (AG) in pots before fertilising and sowing of carrots
Level of residual AG
Parameter (tha)
Parameter
0 125 250 1000
pH (H20) 69 77 85 86
pH (CaCl2) 57 71 78 78
Ec (mSm) 4 9 9 11
Ext P (ngg)1 3 9 14 9
PRI2 -02 33 44 77
Total N ()3 - 0039 0044 0060
ExtNH4-N(ngg)4 - 2 2 2
ExtN03-N(ugg)5 - 3 2 5
CEC ()6 30 30 43 35
Exch Ca ()7 133 363 51 70
Exch Mg ()7 036 024 015 021
Exch Na ()7 005 015 015 032
Exch K ()7 007 004 0035 0035
OrgC()8 131 109 092 103
Sand () 977 967 960 910
Silt () 13 15 15 37
Clay () 10 23 25 53
1 Colwell (1963) 2 Phosphorus retention index (Allen and Jeffery 1990) 3 KjeldahlReardon et al 1966 4 Extracted in 1 m KC1 (Reardon et al 1966) 5 Extracted in 1 m KC1 (Best 1976) 6 Gillman and Sumpter (1986) 7 Exchangeable in 1 m NHU-Cl 8 Walkley and Black (1934)
Level of residual AG had no effect on levels of extractable NH4-N NO3-N exchangeable Mg and K or organic carbon After harvest levels of Colwell P K total P PRI Ec pH (CaCk) exchangeable Ca Mg K and Na in the topsoil (0-15 cm) all increase significantly (P lt 005) with level of residual AG (Tables 73 74)
85
The use of Red Mudgypsum in vegetable production
Table 73 Extractable P K NH4 total P (tot P) and phosphorus retention index (PRI) of the topsoil (0-15 cm) of a Joel sand after harvest of carrots with level of residual Alkaloamreggypsum (AG) and phosphorus (P)
AG
AG BicP1 BicK tot P2 PRI3 NIL (tha) (ngg) (Hgg) (ngg) (mLg) (Mfig)
0 33 119 234 -015 137
125 200 117 743 141 27
250 275 197 1258 231 19
1000 204 420 1853 154 30
Lsd5 4 34 129 45 26
Sig6
P
P (kgha)
BicP1
(ngg) BicK1
(Mgfe) totP2
(ugg) PRI3
(mLg) NIL
(ngg)
0 91 215 896 198 58
50 151 223 937 138 54
100 144 226 1005 126 62
200 182 193 1043 128 42
400 323 210 1231 116 52
Lsd5 48 39 144 50 29
Sig6 s | e ns ns
1 Colwell 1963 2 Allen and Jeffery 1990 3 Phosphorus retention index (Allen and Jeffery 1990) 4 Extracted in 1 m KC1 (Best 1976) 5 Least significant difference at P s 005 6 Significance at lt 0001 () lt 001 () lt 005 () level or not significant (ns)
By contrast levels of extractable NH4-N decreased significantly with level of residual AG Colwell P total P Colwell K all increased significantly (P lt 005) with level of applied P whilst PRI was decreased significantly Level of applied P had no significant effect on Ec pH or level of exchangeable Ca Mg K Na Colwell K or extractable NHu-N in the topsoil after harvest (Tables 73 74)
The use of Red Mudgypsum in vegetable production
Table 74 Ec (mSm) pH (CaCl2) and exchangeable cations (me) in topsoil (0-15 cm) of a Joel sand after harvest of carrots with level of residual Alkaloamreggypsum (AG) and phosphorus (P)
AG
AG Ec pH Ca1 Mg1 K1 Na1
(tha) (mSm) (CaCl2) (me) (me) (me) (me)
0 157 44 18 016 026 010
125 147 54 23 014 026 015
250 217 66 40 017 041 027
1000 308 76 135 027 096 094
Lsd2 32 01 07 002 005 005
sig3
p
p (kgha)
Ec (mSm)
pH (CaCl2)
Ca1
(me) Mg1
(me) K1
(me) Na1
(me)
0 202 59 52 019 048 035
50 195 60 53 018 050 036
100 203 60 57 019 048 039
200 202 60 57 018 045 040
400 236 59 51 017 046 034
Lsd2 35 01 08 002 006 005
Sig3 ns ns ns ns ns ns
Exchangeable in 1 m NH4CI 2 Least significant difference at P s 005 3 Significance at lt 0001 () lt 001 () lt 005 () level or not significant (ns)
Effect of level of residual AG and P on concentration of nutrients in leachate and quantities of nutrients leached
There was a significant (P lt 005) reduction in concentration of P in leachate with level of residual AG at three times of sampling (Fig 71) P concentration in leachate increased significantly with level of applied P at 01 AGha but not in presence of AG
P concentration in leachate at 01 AGha decreased with time from 80 mgL on 16 April 1996 at 400 kg Pha to 025 mgL on 22 July 1996 To reduce P concentration in leachate 125 t AGha was as effective as 250 or 1000 tha at all sampling times and levels of applied P Similar trends were shown in quantity of leached P as total or soluble reactive P in kgha (Appendix 71 (b) 72) Level of applied AG significantly (P lt 005) reduced the concentration of NH4-N in leachate from 40 mgL at 01 AGha to 15 mgL at 250 and 1000 tha (Fig 72 (a)) on 16 April 1996 Significant reductions in concentration were recorded on the other two sampling times as NH4-N concentration declined with increased plant uptake Similar trends were shown in the quantity of NH4-N leached with level of AG (Appendix 72 (b)) By contrast level of applied AG had no significant effect on concentration of NO3-N in leachate or quantity leached at any of the three sampling times (Fig 72 (b) and Appendix 73 (b)) There was a significant (P lt 005) reduction in concentration of K in leachate and quantity of K leached with level of residual AG although the reduction was less at the later sampling times (Fig 73 Appendix 73 (a)) Concentration of K in leachate increased
87
The use of Red Mudgypsum in vegetable production
with time at all levels of residual AG except 1000 tha By contrast both the concentration of Na in leachate and quantity of Na increased with level of residual AG to a maximum at the highest level (1000 tha) There was a reduction in Na concentration in leachate with time at level of residual AG lt 1000 tha The concentration of Ca in leachate increased significantly (P lt 005) as did quantity leached with level of residual AG and with time at all levels of AG (Fig 74 Appendix 74 (a)) By contrast concentration of Mg in leachate and quantity leached decreased significantly (P lt 005) with level of residual AG and with time at all levels of AG (Fig 78 and Appendix 78 (a)) There was a significant (P lt 005) increase in S concentration in leachate and quantity leached with level of residual AG at the first sampling time a decrease at the second and a increase up to 250 tha at the third sampling (Fig 79 Appendix 79 (a)) S concentration in leachate and quantity leached varied significantly with level of applied P at all sampling times and decreased with time from 16 April 1996 to 22 July 1996 (Fig 79 and Appendix 79 (a))
The use of Red Mudgypsum in vegetable production
deg E
c o
o O
c ltD
O
c o
I O
1 0 0 2 0 0 3 0 0 4 0 0
A p p l i e d P ( k g h a )
5 0 0
1 0 0 2 0 0
A p p l ie d P
3 0 0
k g h a )
4 0 0 5 0 0
1 0 0 2 0 0 3 0 0
A p p l i e d P ( k g h a
4 0 0 5 0 0
Figure 71 Concentration of P (mgL of total P) in leachate from Joel sands sown to carrots with level of applied P and Alkaloamreggypsum (AG) at 0 (bull) 125 (bull) 250 (A) and 1000 (T) tha on 16 April 1996 (A) 6 May 1996 (B) and 22 July 1996 (C) P was applied preplanting as superphosphate and carrots were sown on 3 April 1996 Vertical bars refer to Lsd (P lt 005) for differences in concentration between level of AG (at each level of P) or P (at each level of AG) or the interaction between AG and P Where bars arent shown Lsd is less than size of symbol
89
The use of Red Mudgypsum in vegetable production
2 0 0 4 0 0 6 0 0 8 0 0 1 0 0 0 1 2 0 0
L e v e l o f r e s i d u a A G ( t ha )
2 0 0 4 0 0 6 0 0 8 0 0 1 0 0 0 1 2 0 0
L e v e l o f r e s i d u a l A G ( t h a )
Figure 72 Concentration (mgL) of NBU-N (A) and NO3-N (B) in leachate from Joel sand sown to carrots amended with residual AlkaIoamreggypsum (AG) in pots on 16 April 1996 (bull) 6 May 1996 (bull) and 22 July 1996 (A) The carrots were sown on 3 April 1996 N was fertigated at a constant concentration of 300 mgL (250 mgL of NO3-N and 50 mgL NH4-N) from sowing to harvest Vertical bars refer to Lsd (P lt 005) for differences in concentration between level of AG at each sampling time Where bars arent shown Lsd is less than size of symbol
The use of Red Mudgypsum in vegetable production
200 400 600 800 1000 1200
Level of AG (tha)
200 400 600 800
Level of AG (tha)
1 0 0 0 1 2 0 0
Figure 73 Concentration (mgL) of K (A) and Na (B) in leachate from Joel sand sown to carrots amended with residual Alkaloamreggypsum (AG) in pots on 16 April 1996 (bull) 6 May 1996 (bull) and 22 July 1996 (A) The carrots were sown on 3 April 1996 K was fertigated at a constant concentration of 200 mgL from sowing to harvest Vertical bars refer to Lsd (P lt 005) for differences in concentration between level of AG at each time Where bars arent shown Lsd is less than size of symbol
91
The use of Red Mudgypsum in vegetable production
Effect of level of residual AG and P on concentration of nutrients in plants The concentration of K P Fe Cu Mn and Mo in the youngest mature leaves (YML) of carrots at midgrowth all increased significantly with level of residual AG (Tables 75 (a) (b)) The concentration of S in YML at midgrowth was significantly reduced as level of residual AG increased whilst concentrations of Ca Na Mg Zn and B were variable
Table 75 Concentration of nutrients ( dry basis) in youngest mature leaves of carrot at midgrowth with level of residual Alkaloamreggypsum (AG) and phosphorus (P)
(a) Macronutrients
AG
AG (tha)
K1 Ca2 S2 P1 Na2 Mg2
0 486 229 061 025 050 039
125 584 186 060 033 047 034
250 585 216 058 033 044 035
1000 531 215 056 031 052 037
Lsd3 03 02 004 0017 005 003
Sig4
p
P (kgha)
K1 Ca2 S2 P1 Na2 Mg2
0 538 198 062 029 037 036
50 523 222 061 028 043 037
100 562 208 056 030 049 035
200 548 216 057 032 058 037
400 563 214 056 035 054 036
Lsd3 033 022 004 002 006 003
Sig4 ns ns ns
1 After Varley (1966) 2 After McQuaker et al (1979) 3 Least significant difference at P s 005 4 Significance at lt 0001 () lt 001 () lt 005 () level or not significant (ns)
The use of Red Mudgypsum in vegetable production
Table 75 Concentration of nutrients ( dry basis) in youngest mature leaves of carrot at midgrowth with level of residual Alkaloam gypsum (AG) and phosphorus (P)
(b) Micronutrients
AG
AG (tha)
Fe Mn1 Zn B Cu Mo
0 111 386 280 345 95 21
125 127 279 367 348 107 25
250 126 173 269 349 108 24
1000 114 60 143 337 110 31
Lsd2 20 47 40 15 05 06
Sig3 ns ns
p
p (kgha) Fe Mn Zn B Cu Mo1
0 135 243 263 356 120 28
50 122 240 268 349 111 30
100 109 191 229 343 106 25
200 116 228 268 334 99 23
400 115 221 294 341 89 20
Lsd2 23 52 45 15 051 07
Sig3 ns ns ns ns
1 After McQuaker et al (1979) 2 Least significant difference at P s 005 3 Significance at lt 0001 () lt 001 () lt 005 () level or not significant (ns)
Concentration of P S and Na in YML increased significantly (P lt 005) with level of applied P whilst concentrations of Cu and Mo decreased (Tables 75 (a) (b)) By contrast concentrations of K Ca Mg Fe Mn Zn and B were not significantly changed by level of applied P
93
The use of Red Mudgypsum in vegetable production
At harvest the concentration of P N K and Fe in whole tops increased significantly (P lt 005) with level of residual AG whilst concentration of S Mn Zn and B decreased (Table 76) The concentrations of Ca Na and Mg were variable with level of residual AG whilst there was no significant effect on the concentration of Cu
Table 76 Concentration of nutrients ( dry basis) in whole carrot tops at harvest with level of residual Alkaloamreggypsum (AG) and phosphorus (P)
(a) Macronutrients
AG
AG (tha)
N1 K1 Ca2 S2 P1 Na2 Mg2
0 300 503 269 071 016 093 039
125 348 649 239 065 024 090 035
250 395 653 251 061 022 082 033
1000 351 566 262 066 024 099 037
Lsd3 010 036 011 002 001 009 002
Sig4
p
p (kgha)
N1 K1 Ca2 S2 P1 Na2 Mg2
0 355 589 240 073 019 074 035
50 343 597 258 068 020 082 036
100 339 587 257 068 021 098 038
200 339 580 259 063 022 108 037
400 332 608 263 057 024 095 036
Lsd3 011 041 012 002 001 010 002
Sig4 ns
1 After Varley (1966) 2 After McQuakere al (1979) 3 Least significant difference at P s 005 4 Significance at lt 0001 () lt 001 () lt 005 () level or not significant (ns)
The use of Red Mudgypsum in vegetable production
Table 76 Concentration of nutrients ( dry basis) in whole carrot tops at harvest with level of residual Alkaloamreggypsum (AG) and phosphorus (P)
(b) Micronutrients
AG
AG (tha)
Fe1 Mn1 Zn1 B1 Cu1
0 299 962 234 402 109
125 316 952 184 404 107
250 331 662 110 380 110
1000 374 673 77 383 115
Lsd2 90 106 20 002 05
Sig3 ns ns
p
p (kgha) Fe1 Mn1 Zn1 B1 Cu1
0 294 969 158 409 125
50 392 837 144 393 117
100 364 747 141 396 114
200 267 712 159 387 105
400 332 bull 796 154 377 89
Lsd2 101 118 23 13 05
Sig3 ns ns
1 After McQuaker et al (1979) 2 Least significant difference at P lt 005 3 Significance at lt 0001 () lt 001 () lt 005 () level or not significant (ns)
As level of applied P increased concentration of P Ca and Na in whole tops increased significantly (P lt 005) whilst concentrations of N S Mn B and Cu decreased There was no significant effect of level of applied P on concentrations of K Fe or Zn in whole tops whilst concentration of Mg was variable
Effect oflevel of residual AG and P on carrot yield
There was a significant (P lt 005) increase in total and marketable yield with level of applied P at all levels of applied AG (Table 77) The overall effect of AG was to reduce both total and marketable yield at the highest level (1000 cf 0 to 2501 AGha) especially at low levels of applied P (ie 0 to 50 kg Pha) At higher levels of applied P yield at 2501 AGha was not significantly (P lt 005) lower than at 125 tha
95
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The use of Red Mudgypsum in vegetable production
However at 10001 AGha total and marketable yield was significantly lower than 0 tha at all levels of applied P The relationship between level of applied P and total yield was described as linear at 0 250 and 10001 AGha and Mitscherlich at 125 AG tha (Fig 76) As yield did not maximise at 0 250 and 1000 t AGha no optimal level of applied P for 95 or 99 of maximum yield could be determined At 125 t AGha the level of applied P necessary for 95 and 99 of maximum yield was 182 and 314 kg Pha respectively
Effect of level of AG and P on efficiency of P recovery by plants and retention in soil
The proportion () of P recovered in the carrot roots and tops decreased with level of applied P increasing from 8 to 12 to 5 to 8 of depending on level of AG (Table 78) There was a reduction in P recovered in roots tops and whole plant as level of AG increased For example P recovered by whole plants at 01 AGha at 400 kg Pha was 8 but this had declined to 5 at 10001 AGha
Table 78 The of applied fertiliser P taken up by carrots grown in pots (tops roots) retained in the topsoil or leached with level of residual Alkaloamreggypsum (AG) and phosphorus (P) on a Joel sand
P in Fraction AG P ( of P applied )
(tha) (kgha) TopsA Roots2 Plant(A+B) Soil2 Leached3
0 50 2 9 11 3 86
0 100 2 8 10 13 77
0 200 2 6 8 2 90
0 400 2 6 8 3 89
125 50 4 8 12 73 15
125 100 2 8 10 18 72
125 200 2 6 8 30 62
125 400 1 4 5 18 77
250 50 3 7 10 0 90
250 100 2 4 6 0 94
250 200 1 4 5 0 95
250 400 1 4 5 12 83
1000 50 2 6 8 75 17
1000 100 2 5 7 67 26
1000 200 2 5 7 45 48
1000 400 1 4 5 41 55
P in fraction expressed as of P applied as fertiliser 2 P retained in topsoil (0-15 cm) 3 P leached below 15 cm
By contrast of applied P retained in topsoil varied with level of AG For example only 3 of P was retained in topsoil at 400 kg Pha and 01 AGha where as this had increased to 41 at 10001 AGha at the same level of applied P Consequently the of P leached decreased as level of AG increased For example at 01 AGha and 400 kg Pha nearly 90 of applied P leached below 15 cm This had been reduced to 55 at 10001 AGha and the same level of applied P
97
The use of Red Mudgypsum in vegetable production
Table 79 Fertiliser P leached (kgha) and P leached as a of P applied from a Joel sand sown to carrots with level of residual Alkaloam gypsum (AG) and P after harvest The P was then applied as superphosphate prior to planting The carrots were sown on 3 April 1996 P leached is expressed as a percentage of P applied
AG (tha)
P (kgha)
P leached1
(kgha) P leached
( P applied)
0 50 41 82
0 100 78 78
0 200 158 79 0 400 311 78
125 50 2 4
125 100 3 3
125 200 10 5 125 400 27 7
250 50 1 2
250 100 3 3 250 200 4 2
250 400 7 2 1000 50 02 lt1 1000 100 05 lt1
1000 200 1 lt1
1000 400 2 lt1
1 Fertiliser P leached = total P leaclied - P leached at 0 kg Pha (ie background P) 2 (Fertiliser P leachedP applied x 100)
The use of Red Mudgypsum in vegetable production
O)
pound CD
o TO
(D
o
(0 l _
c
o c o o
pound
(0
o to
c o
TO tmdash
c 0) o c o o
0 2 0 0 4 0 0 6 0 0 8 0 0 1 0 0 0 1 2 0 0
L e v e l o f r e s i d u a l A G ( t h a )
0 2 0 0 4 0 0 6 0 0 8 0 0 1 0 0 0 1 2 0 0
L e v e l o f r e s i d u a l A G ( t h a )
Figure 74 Concentration (mgL) of Ca (A) and Mg (B) in leachate from Joel sand sown to carrots amended with residual Alkaloamreggypsum (AG) in pots on 16 April 1996 (bull) 6 May 1996 (bull) and 22 July 1996 (A) The carrots were sown on 3 April 1996 Ca was applied preplanting as superphosphate and fertigated at a constant concentration of SO mgL from sowing to harvest AG was applied preplanting and in weeks 6 (15 May 1996) and 12 (25 June 1996) Vertical bars refer to Lsd (P lt 005) for differences in concentration between level of AG at each time Where bars arent shown Lsd is less than size of symbol
99
The use of Red Mudgypsum in vegetable production
CD
CO
x o CO CD
c o
bull4-
CO
c CD O c o O
0 2 0 0 4 0 0 6 0 0 8 0 0 1 0 0 0 1 2 0 0
L e v e l of r e s i d u a l A G ( t ha )
0 100 2 0 0 3 0 0 4 0 0
L e v e l of r e s i d u a l P ( k g h a )
5 0 0
Figure 75 The concentration of S (mgL) in leachate from Joel sands sown to carrots with level of residual Alkaloamreggypsum (AG) (A) and P (B) on 16 April 1996 (bull) 6 May 1996 (bull) 22 July 1996 (A) The carrots were sown on 3 April 1996 S was applied preplanting as K2S04 and in superphosphate Vertical bars refer to Lsd (P lt 005) for differences in concentration between level of AG (A) or P (B) at each sampling time Where bars arent shown Lsd is less than size of symbol
100
The use of Red Mudgypsum in vegetable production
ID
0 100 200 300 400 500
Applied P (kgha)
lb 70
70 C
60 65 -
60
55 dt
ha 50
40
50
45 bull A
Yie
30
40 _ 20
35 i i i i 35 0 100 200 300 400 5( 50 10
Applied p (kgha)
0 100 200 300 400 500
Applied P (kgha)
0 100 200 300 400 500
Applied P (kgha)
Figure 76 Total yield of carrots with level of freshly-applied P at four levels of residual Alkaloamreggypsum (AG) (A B C D = 01252501000 tha) Vertical dashed and whole lines refer to applied P necessary to 95 (dashed) or 99 (whole) of maximum yield respectively
The equations of the fitted lines are
A y = 10943 - 9377 x exp (-00053) (R2 = 099)
B y = 6l7- 2848 x exp (-00122) (i2 = 099)
C y = 3842+ 0083x (J2 = 097)
D y = 238 + 0l07x(R2 = 096)
As level of applied P increased concentration of P Ca and Na in whole tops increased significantly (P lt 005) whilst concentrations of N S Mn B and Cu decreased There was no significant effect of level of applied P on concentrations of K Fe or Zn in whole tops whilst concentration of Mg was variable
101
The use of Red Mudgypsum in vegetable production
Discussion
The addition of residual Alkaloamreggypsum (AG) resulted in a significant reduction in the concentration of P NH4-N K and Mg in the leachate from Joel sands sown to carrots in large pots The reduction in P concentration is attributed to an increase in the level of iron and aluminium oxides when AG is applied to soils low in these minerals (Barrow 1982) Consequently all soil measurements of P status or retention such as total P Colwell P and phosphorus retention index as well as Ec and pH all increased with level of applied residual AG Similar reductions in phosphorus leaching or increases in P retention have been reported when Gavin (Vlahos et al 1989) or Joel (Sections 4 and 5 McPharlin et al 1994 Robertson et al 1997) sands were amended with fresh or residual AG (Sections 4 and 6 Robertson et al 1994)
The reduced leaching of cations such as NH4-N K and Mg is attributed to an increase in captain exchange capacity (CEC) when sands of low CEC are amended with AG (Barrow 1982 McPharlin et al 1994) Consequently NO3-N retention is not increased when soils are amended with residual (Fig 72) or freshly-applied AG (McPharlin et al 1994) The increased leaching of Na Ca and S from amended sands is attributed to the Alkaloamreg as a source of these elements either in the Alkaloamreg itself (Na2C03) or after amendment with gypsum (CaS042H20) which precipitates CaC03 and Na2S04 The Na2S04 is very soluble as is easily leached whereas Ca is only slightly soluble as gypsum and insoluble as lime Vlahos et al (1989) reported increased leaching of Na Ca and S from Gavin sands treated with copper as (FeS04) amended Alkaloamreg compared with unamended controls in the short term and a decrease in the longer term Concentrations of P in the YML at midgrowth or tops at harvest increased with level of applied P and also with level of residual AG from 025 at 0 t AGha to 031 at 10001 AGha By contrast freshly-applied AG reduced the concentration of P in the YML from 043 on unamended to 030 on amended Joel sands (Robertson et al 1997) Even at the highest level of applied P the concentration of P in the YML 035 was still lower than that shown to be necessary for maximum yield of carrots (ie 038 McPharlin et al 1992) This could explain why the yield wasnt maximised in three out of the four AG treatments On the treatment that yield was maximised 125 t AGha the highest concentration of P ie 038 was recorded The difference in trends of P in petioles with AG between the 2 studies could be explained in terms of the relative leaching of P or addition of P in the AG itself On the virgin Joel sand used in the pot study leaching of P was significant enough to reduce leaf P in the unamended versus amended treatments For example the P in YML was significantly lower in the 01 AGha than at all other levels of residual AG at all levels of applied P up to 200 kgha For example the P in YML at 01 AGha ranged from 020 to 027 at 0 and 200 kg Pha respectively whilst at 125 t AGha the P was 032 to 038 over the same levels of applied P (Appendix 71) This suggests that loss of P from the top soil is severely limiting the uptake of P by the plant in the absence of AG The phosphorus retention of virgin Joel sands is almost negligible with a PRI of close to 0 (Table 72 McPharlin et al 1994 Robertson et al 1997) By contrast the P retention of Joel sands appears to be increased following development possibly by the addition of iron in irrigation water and organic and inorganic fertilisers For example the estimate of PRI (PREM) ie PRI plus P as Colwell P measured in the developed Joel sands used by Robertson et al was 40 in the topsoil (0-15 cm) of the unamended treatment Thus in these soils P retention is high enough to reduce availability when AG is added and explains the reduced levels of P in the YML as level of AG is increased The contribution of AG to the P nutrition of the plant is an unlikely explanation as it didnt increase P levels in the plant when applied fresh (Robertson et al 1997)
Previous work showed that concentrations of K in the petioles of potatoes (Section 4 Robertson et al 1997) and youngest mature leaves in cauliflower (Robertson et al 1994 Sections 5 and 6) declined with level of freshly-applied and residual AG
With potatoes the decline in K concentrations was associated with a decrease in K concentration in the soil solution and an increase in Na concentrations in soil solution and petioles on fresh and residual AG treatments (Section 4 Robertson et al 1997) This was
102
The use of Red Mudgypsum in vegetable production
used to explain yield reductions on fresh AG sites at gt 60 tha or on residual sites at 240 tha With cauliflower the findings were variable Where yield was reduced (Robertson et al 1994) it could not be explained in terms of K nutrition as K concentrations in the YML did not decline to levels expected to result in deficiency In follow up work neither fresh or residual AG up to 240 tha resulted in yield reduction although there was a reduction in K concentrations in the YML but not below critical levels (Sections 5 and 6) By contrast concentrations of K in the YML of carrots increased with level of residual AG up to 1000 tha as did exchangeable K in the soil Similar increases in K concentration in YML of Chinese and Head cabbage with level of AG on Joel sands have been reported previously (Robertson et al 1994)
Yield response of carrots to applied P at various levels of residual AG was variable on Joel sands in this work For example yield with level of applied P reach a plateau at 125 t AGha (ie 182 and 314 kg Pha for 95 and 99 of maximum yield from the Mitscherlich regression) However at other levels of applied AG including 0 tha yield had not maximised at the highest level of applied P (400 kgha) This is surprising considering that on higher P retaining soils such as Karrakatta sands yield is maximised at much lower levels of applied P (ie 160 to 180 kgha) at a similar low P soil test (McPharlin et al 1992 1994) in the absence of AG Also on Joel sands yields of carrots at medium to low P soil test (16 to 20 ugg Colwell P) only 50 kg Pha was necessary for maximum yield (McPharlin et al Lantkze and McPharlin unpublished data) The only possible explanation is that leaching of P was significant enough in the absence of AG that increased levels of applied P were required to satisfy crop requirements The increase in P fertiliser requirement as level of applied AG increases as shown in this work above 125 tha is similar to that reported previously for Chinese and Head cabbage cauliflower lettuce onions (Robertson et al 1994) and potatoes (Robertson et al 1997) It is explained by increased P retention capacity of the soil when AG is applied and measured by PRI Colwell and Total P and similar measurements
References
Allen DG and Jeffery RC (1990) Methods for analysis of phosphorus in Western Australian soils Chemistry Centre of Western Australia Report of Investigation No 37
Barrow NJ (1982) Possibility of using caustic residue from bauxite for improving the chemical and physical properties of sandy soils Australian Journal of Agricultural Research 33 275-285
Best EK (1976) An automated method for the determination of nitrate-nitrogen in soil extracts Queensland Journal of Agriculture and Annual Science 33 161-166
Colwell JD (1963) The estimation of phosphorus fertiliser requirements of wheat in southern New South Wales by soil analysis Australian Journal of Experimental Agriculture and Animal Husbandry 3 190-197
Hegney M A McPharlin IR and Jeffery RC (1997) Response of winter-grown potatoes (Solanum tuberosum L) to freshly-applied and residual phosphorus on a Karrakatta sand Australian Journal of Experimental Agriculture 37 131-137
McPharlin IR Alymore PM and Jeffery RC (1992) Response of carrots (Daucus carota L) to applied P and P leaching on a Karrakatta sand under two irrigation regimes Australian Journal of Experimental Agriculture 32 225-232
McPharlin IR Jeffery RC and Weissberg R (1994) Determination of the residual value of phosphate and soil test phosphorus calibration for carrots on a Karrakatta sand Communications in Soil Science and Plant Analysis 25 (5-6) 489-500
103
The use of Red Mudgypsum in vegetable production
McPharlin IR Robertson WJ Jeffery RC and Weissberg R (1995) Response of cauliflower to phosphate fertiliser placement and soil test phosphorus calibration on a Karrakatta sand Communications in Soil Science and Plant Analysis 26(3amp4) 607-620
McQuaker NR Brown DF and Kluckner PD (1979) Digestion of environmental materials for analysis by inductively coupled plasma-atomic emission spectrometry Analytical Chemistry 51 1082-1084
Reardon J Foreman JA and Serai RL (1966) New reactants for the determination of ammonia Clinica Chemica Acta 14 403-405
Robertson WJ McPharlin IR and Jeffery RC (1994) Final report of investigation into the use of gypsum-amended Red Mud as a soil-amendment for horticultural properties on the Swan Coastal Plain Final Report of HRDC Project No V0039 RO
Robertson WJ Jeffery RC and McPharlin IR (1997) Residues from bauxite-mining (Red Mud) increase phosphorus retention of a Joel sand without reducing yield of carrots Communications in Soil Science and Plant Analysis 28 (13 amp 14) 1059-1079
Varley JA (1966) Automatic methods for the determination of nitrogen phosphorus and potassium in plant material Analyst 91 119-126
Vlahos S Summers KJ Bell DT and Gilkes RJ (1989) Reducing phosphorus leaching from sandy soils with Red Mud bauxite processing residues Australian Journal of Soil Research 27 651-662
Walkley A and Black I (1934) An examination of the Degtjareff method of determining soil organic matter and a proposed modification of the chromic acid titration method Soil Science 37 29-38
Yuen SH and Pollard AG (1954) Determination of nitrogen in agricultural material by the Nessler reagent II Micro determination in plant tissue and soil extracts Journal of the Science of Food and Agriculture 5 364-369
104
The use of Red Mudgypsum in vegetable production
CO JC
5)
CD
sz o CD CD
0 200 400 600 800
Level of residual AG(tha)
1000 1200
Appendix 71 (b) P leached (kgha) from Joel sands sown to carrots amended with residual Alkaloanrgypsum (AG) in pots on 16 April 1996 (week 3) (bull) 6 May 1996 (week 6) (bull) and 22 July 1996 (week 16) ( bull ) P was applied preplanting as superphosphate and carrots were sown on 3 April 1996 Vertical bars refer to Lsd (P lt 005) for differences in quantities of P leached between level of AG (across all levels of applied P) at each sampling time Where bars arent shown Lsd is less than size of symbol Data from Appendix 71 (a)
105
The use of Red Mudgypsum in vegetable production
200 400 600 800
Level ofresidual AG(tha)
1 000 1 200
2 00
18 0 -
~ 160
copy
deg 1 40
1 2 0
100 -
80 200 400 600 800
Level of residual AG (tha)
1000 1200
Appendix 73 (b) 74 (b) Ammonium-N (A) and Nitrate-N (B) leached (kgha) from Joel sands sown to carrots amended with residual Alkaloamreggypsum (AG) in pots on 16 April 1996 (week 3) (bull) 6 May 1996 (week 6) (bull) and 22 July 1996 (week 16) (A) N was fertigated postplanting as NH4-N and NO3-N and carrots were sown on 3 April 1996 Vertical bars refer to differences in quantities of N leached between level of AG (across all levels of applied P) at each sampling time Where bars arent shown Lsd is less than size of symbol Data from Appendices 73 (a) 74 (a)
106
The use of Red Mudgypsum in vegetable production
A 1 8 0
1 6 0
1 4 0
1 2 0 -
1 0 0
8 0
6 0 -
4 0 - I~~ - ^ gt ^
2 0
I
^ - ^ 1 0
I i i i i i
2 0 0 4 0 0 6 0 0 8 0 0
L e v e l o f r e s i d u a l AG (th a )
1 0 0 0 1 2 0 0
2 0 0 4 0 0 6 0 0 8 0 0
L e v e l o f r e s i d u a l A G ( t h a )
1 0 0 0 12 00
Appendix 75 76 K (A) and Na (B) in leachate from Joel sand sown to carrots amended with residual Alkaloamreggypsum (AG) in pots on 16 April 1996 (week 3) (bull) 6 May 1996 (week 6) (bull) and 22 July 1996 (week 16) (A) The carrots were sown on 3 April 1996 K was fertigated at a constant concentration of 200 mgL from sowing to harvest and Na was a constituent of AG Vertical bars refer to Lsd (P lt 005) for differences in quantities of K and Na leached between level of AG (across all levels of applied P) at each time Where bars arent shown Lsd is less than size of symbol
107
The use of Red Mudgypsum in vegetable production
40
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200 400 600 800 1000 1 2 0 0
L e v e l of r e s i d u a l AG ( t ha)
200 4 0 0 600 800 1000 1 2 0 0
L e v e l of r e s i d u a l AG ( t ha)
Appendix 77 78 Ca (A) and Mg (B) in leachate from Joel sand sown to carrots amended with residual Alkaloamreggypsum (AG) in pots on 16 April 1996 (bull) 6 May 1996 (bull) and 22 July 1996 (A) The carrots were sown on 3 April 1996 Ca was applied preplanting as superphosphate (and as a constituent of AG) and fertigated at a constant concentration of 50 mgL from sowing to harvest Mg was applied preplanting and in weeks 6 (15 May 1996) and 12 (25 June 1996) Vertical bars refer to Lsd (P lt 005) for differences in quantity of Ca and Mg leached between level of AG (across all levels of applied P) at each sampling time Where bars arent shown Lsd is less than size of symbol Data from Appendices 77 (a) and 78 (a)
108
The use of Red Mudgypsum in vegetable production
200 400 600 800
Level of residual AG(tha)
1000 1200
Appendix 79 S (mgL) in leachate from Joel sands sown to carrots with level of residual Alkaloamreggypsum (AG) 16 April 1996 (week 3) (bull) 6 May 1996 (week 6) (bull) 22 July 1996 (week 16) (A) The carrots were sown on 3 April 1996 S was applied preplanting as K2S04 in superphosphate and as a constituent of AG Vertical bars refer to Lsd (P lt 005) for differences in quantity of S leached between level of AG (A) or P (B) at each sampling time Where bars arent shown Lsd is less than size of symbol Data from Appendix 79 (a)
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o o n t ^ t r i O N O H O O ( S n i ( i o O N O r n v ) H O M ^ f N i o N m m N O N D laquo i ( s m v o o o N o o c ^ m o N ^ O N o o N O T f o o N O v i ^ ^ ^ i n ^ N ^ N O o w c ^ H N o e o T t O N O p o of mdashJ of oo of bull m en m m en of of ON of of of of of of oo oo oo rn m m c-i o i o raquo-i lts
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to 1mdash 1mdash t o 44 to 0 00 44 imdash LO to to copy 44 44 ON to copy 00 Ln ON ON to copy 00 copy 00 gt-gt vo ON Ln LO imdash copy ~ j 44 0 copy t o copy to 44 vo Ln to ON VO copy vo O ON copy ON ON 00 Ln ~4 bull - u i b u u i -t O O N 4 4 0 0 t O l mdash gt 4 4 H - v O t O gt mdash gt L O ~ 4 V O 0 N L n 4 4 L 0 0 0 t O 0 0 L 0 k - gt 0 0 t O - 4 L n F - LOraquo-4h- ON
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