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Victor Zhirnov April 10, 2011 Potsdam, Germany ERD Memory Discussion

Victor Zhirnov April 10, 2011 Potsdam, Germany ERD Memory Discussion

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Page 1: Victor Zhirnov April 10, 2011 Potsdam, Germany ERD Memory Discussion

Victor Zhirnov

April 10, 2011

Potsdam, Germany

ERD Memory Discussion

Page 2: Victor Zhirnov April 10, 2011 Potsdam, Germany ERD Memory Discussion

ERD Memory Tasks

Update Memory Tables and Text Implement the decisions made at the 2010 ERD FFM as well

as at the 2010 workshops in Barza and Tsukuba Status: work in progress 1st draft (tables): April 2011 Final draft (tables + text): July 1, 2011

Create new section on Storage Class Memory Status: 1st draft completed Final draft: April 2011

Create new section on Select Device Status: 1st draft completed A fundamental study is underway develop an analysis of nanoscale selector

devices for memory Final draft: July 1, 2011 Research paper: November 2011

2

Page 3: Victor Zhirnov April 10, 2011 Potsdam, Germany ERD Memory Discussion

Decisions for Memory Section (Dec. 2 & 5, 2010 ERD Meetings)

3

Action Items for Memory (Dec. 2 & 5, 2010, ERD Meetings)

1. Should Storage Class Memory drive a new architecture discussion in the Architecture Section? Explore a definition of SCM

Zhirnov and Schechtman

5. Develop a table of Devices mapped onto materiel and their critical property required to demonstrate the key attribute of the device.

BourianoffGarner and Zhirnov

6. Rename the FeFET to include the Fe-barrier device. Zhirnov8. Change “Nanobridge Cantilever” to just “Nanobridge” Zhirnov

•Put Vertical MOSFET in the Memory Section•Include new section on Storage Class Memory•Include new section on Select Device

Page 4: Victor Zhirnov April 10, 2011 Potsdam, Germany ERD Memory Discussion

ERD Memory Tables

Page 5: Victor Zhirnov April 10, 2011 Potsdam, Germany ERD Memory Discussion

5

Page 6: Victor Zhirnov April 10, 2011 Potsdam, Germany ERD Memory Discussion

6

2010 Important Events

Emerging Research Memory Devices Workshop Barza, Italy, April 2, 2010

Emerging Memory Materials workshop   Tsukuba, Japan, November 30, 2010

Page 7: Victor Zhirnov April 10, 2011 Potsdam, Germany ERD Memory Discussion

2009 ERD Memory Table

7

  Ferroelectric FET memory

Nanomechanical Memory

Spin Torque Transfer Memory

Nano-thermal Memory

Nanoionic Memory

Electronic Effects

Memory

MacromolecularMolecular MemoriesMemory

Storage Mechanism

Remnant polarization on a ferroelectric gate

dielectric

Electrostatically-controlled

mechanical switch

Magnetization of the

ferromagnetic layer

Thermo-chemical

redox process, 2) Thermal

phase transformati

ons

Ion transport

andMultiple

mechanismsMultiple

mechanisms

Multiple mechanis

msredox reaction

Cell Elements 1T 1T1R or 1D1R 1T1R1T1R or 1D1R

1T1R or 1D1R

1T1R or 1D1R

1T1R or 1D1R1T1R or 1D1R

Device Types FET with FE gate insulator

1) nanobridge/ cantilever

Magnetization change by spin transfer torque

1) Fuse/Antifuse Memory

1) cation migration

1) Charge trapping

M-I-M (nc)-I-MBi-stable

switch2) telescoping

CNT2) nanowire PCM

2) anion migration

2) Mott transition

3) Nanoparticle    3) FE barrier effects

Redox Memory

Mott Memory

PIDS

Page 8: Victor Zhirnov April 10, 2011 Potsdam, Germany ERD Memory Discussion

Summary : STT RAM – 1st Place in voting Pros Well defined physical Model and

simulation tool. Very fast improvement. Many chip level papers on IEDM, VLSI and ISSCC

No control device needed (for apple to apple comp. STT RAM vs. Other ReRAM w/ control device)

CMOS compatible and No HV ease of front end integration.

Extendibility : ~1uA Writing current @ 50ns speed ( 50nm diameter P –MTJ @IEDM2009) Even In plane MTJ can be extendible)

Scalable than PCRAM, Nanothermal and Nano electronic memory w.r.t write speed, endurance(>1E12) and retention.

4F2 possible by vertical tr.(Currently ~21F2, 40nm and chip level)

MTJ can be extended to logic devices as an nonvolatile unit.

Cons MLC operation and stacking is

difficult Very much process dependent : - MgO dielectric Reliability

( subsequent temp. and etching ) - Thermal instability(< 150C) ,

different from single cell results. - Even endurance as low as

1E7(chip level) - Hc shift and stuck at 1 or 0 status. - Variation All parameters are related each

other. Need to decouple(ex. retention , programming current, RA, TMR , endurance, speed), Keeping in mind memory is simple device.)

Much better developed technology than other ERD memory entries – time to migrate to PIDS

Page 9: Victor Zhirnov April 10, 2011 Potsdam, Germany ERD Memory Discussion

Nanothermal and Nanoionic Resistive Switching Memories: A Summary – 2nd place

Classification ‘Nanothermal’ and ‘Nanoinic’ often refer to the same

mechanisms of resistive switching Decision: To merge ‘Nanothermal’ and ‘Nanoionic’ in one

category – RedOx Memory Scaling properties

Based on fundamental physics, Nanothermal/Nanoionic memories may be scalable to 10 nm (and below), capable to fast (~ns) operation

Current Application Prospects Unclear in the context of existing memory hierarchy Incomplete understanding of operation mechanisms Lack of predictive models etc.

9

Page 10: Victor Zhirnov April 10, 2011 Potsdam, Germany ERD Memory Discussion

2009 ERD: Electronic Effect Resistive Switching Memories

Charge trapping induced resistive switching

Resistive switching induced by Mott-transition

Ferroelectric resistive switching Ferroelectric tunnel junction (FTJ)

10

Page 11: Victor Zhirnov April 10, 2011 Potsdam, Germany ERD Memory Discussion

Electronic Effect Resistive Switching Memories: A Summary

Charge trapping induced resistive switching A non-workable concept Should not be considered in the future

Resistive switching induced by Mott-transition Needs to be investigated under benchmark values

Ferroelectric resistive switching Needs to be investigated under benchmark values Issues: Retention, endurance fatigue, scalability

11

Page 12: Victor Zhirnov April 10, 2011 Potsdam, Germany ERD Memory Discussion

Ferroelectric resistive switching

Interesting concept Ferroelectric tunnel junction - FTJ

Not really “electronic effects memory” Operation principle is based on ferroelectric polarization,

similar to e.g. FeFET Same difficult problems as in FeFET

Retention, endurance fatigue, scalability

Much smaller number of research papers compared to other types of ReRAM

12

Page 13: Victor Zhirnov April 10, 2011 Potsdam, Germany ERD Memory Discussion

Changes in the 2011 ERD Memory section

To take out the “electronic effect memories” entry from the ERD memory table

The Ferroelectric Tunel Junction memory could be covered along with FeFET as a subcategory Action Item: A new name for ERD ferroelectric

memory entry is needed

Mott Memory will form a stand-alone entry

13

Page 14: Victor Zhirnov April 10, 2011 Potsdam, Germany ERD Memory Discussion

Resistive switching induced by Mott-transition: An optimistic view

Very interesting concept (believed by enthusiasts to be the ultimate solution for nanodevices)

14

Silicon-based contemporary electronic devices based on a naive electrostatic charging are reaching their miniaturization limits... Alternative ideas are craved: for example, using phase transitions rather than the charge storage…The ultimate resistance-change device is believed to exploit a purely electronic phase change such as the Mott transition…

I. H. Inoue and M. J. Rozenberg ,”Taming the Mott Transition for a Novel Mott Transistor”, Adv. Funct. Mater. 2008, 18, 2289–2292

Page 15: Victor Zhirnov April 10, 2011 Potsdam, Germany ERD Memory Discussion

Mott memory issues: I- Research Activity

Much smaller number of research papers compared to other types of ReRAM Most of the papers are theoretical

In experiments, different conductive mechanisms may contribute to the resistive switching Only a few experimental works presenting evidences for Mott

transition

15

R. Fors, S. I. Khartsev, and A. M. Grishin, ‘Giant resistance switching in metal-insulator-manganite junctions: Evidence for Mott transition’ , PHYS. REV. B 71, 045305 (2005)

Page 16: Victor Zhirnov April 10, 2011 Potsdam, Germany ERD Memory Discussion

Mott memory issues: II – Scaling

Scaling of Mott devices might be a problem What is the minimum number of atoms in a Mott memory

element to provide retention and sensing properties?

Needs to be investigated under benchmark values

16

An Chen: Although switching devices on the scale of 200 nm has been shown to have the characteristics similar to these observed in larger devices, this size is far from being competitive to existing memory technologies. More research on the size effect of the Mott transition properties is needed to address the fundamental scaling limit of this type of devices.

Page 17: Victor Zhirnov April 10, 2011 Potsdam, Germany ERD Memory Discussion

2011 ERD Memory Table

17

 Ferroelectric

effects memoryNanomechanical

MemoryRedox

MemoryMott

MemoryMacromolecular

MemoryMolecular Memories

Storage MechanismRemnant polarization on

a ferroelectric gate dielectric

Electrostatically-controlled mechanical

switch

Ion transport and

Multiple mechanisms

Multiple mechanismsMultiple

mechanisms

redox reaction

Cell Elements 1T or 1T1R 1T1R or 1D1R 1T1R or 1D1R1T1R or 1D1R

1T1R or 1D1R 1T1R or 1D1R

Device Types

FET with FE gate insulator

FTJ

1) nanobridge/ cantilever

1) cation migration

M-I-M (nc)-I-MBi-stable

switch2) telescoping CNT2) anion migration

Mott transition

3) Nanoparticle  

Page 18: Victor Zhirnov April 10, 2011 Potsdam, Germany ERD Memory Discussion

Action Item: A new name for ERD ferroelectric memory entry is needed

Combines two subcategories: Ferroelectric FET Ferroelectric tunnel junction

Should not be confused with conventional ferroelectric memory or FeRAM Based on FE capacitor Is currently in PIDS

Temporary working name: Ferroelectric effects memory Suggestions are welcome

18

Page 19: Victor Zhirnov April 10, 2011 Potsdam, Germany ERD Memory Discussion

Memory Select Device

Page 20: Victor Zhirnov April 10, 2011 Potsdam, Germany ERD Memory Discussion

Memory Select Device TWG:

20

Dirk Wouters (IMEC)Rainer Waser (U Aachen) Thomas Vogelsang (RAMBUS) Zoran Krivokapic(GLOBALFND) Al Fazio (Intel)Kyu Min (Intel)U-In Chung (Samsung)Matthew Marinella (Sandia Labs)

Wei Lu (U Michigan)An Chen (GLOBALFND)Kwok Ng (SRC)Victor Zhirnov (SRC)

The fundamental study team

Page 21: Victor Zhirnov April 10, 2011 Potsdam, Germany ERD Memory Discussion

ReRAM

n p n

Gate

FET

Resistor

Cint

Sense Amplifier

WL

BL

Rcell Rint

RL

D

Critical bridge

a

b

Select Device:Transistor Conventional approach

DiodeOther 2-terminal non-linear element?

Enables cell scaling to 4F2

Supports 3D-stackingPotentially lower cost etc.

Page 22: Victor Zhirnov April 10, 2011 Potsdam, Germany ERD Memory Discussion

General remarks on Memory Select Device

The select device is a non-linear element, which can operate as a switch. Typical examples: transistors (e.g. FET or BJT) or

diodes. Up to now, FET is commonly used as select device in

practical memory arrays, such as DRAM or flash. In order to achieve the highest planar array density of

4F2, without considerable overheads associated with vertical select FETs, passive memory arrays with two-terminal select device are currently actively investigated where two-terminal devices with switch-type behavior (e.g. diodes) are integrated in series with resistive storage nodes in a cross-bar array.

22

Page 23: Victor Zhirnov April 10, 2011 Potsdam, Germany ERD Memory Discussion

Suggested select device categories (An Chen/GF)

Page 24: Victor Zhirnov April 10, 2011 Potsdam, Germany ERD Memory Discussion

Transistor-type select devices

In order to reach the highest possible 2-D memory density of 4F2, a vertical select transistor needs to be used the approach being currently actively pursuit.

While vertical select transistor allows for the highest planar array density, this 4F2 technology is more difficult to integrate into stacked 3D memory, than the conventional 8F2 technology using planar FETs to avoid thermal stress on the memory elements on the existing

layers, the processing temperature of the vertical transistor as selection devices in 3D stacks has to be low, which is not available for high-quality transistors).

Also, making contact to the third terminal (gate) of vertical FET constitutes additional integration challenge.

24

Page 25: Victor Zhirnov April 10, 2011 Potsdam, Germany ERD Memory Discussion

Decisions for Memory Section (Dec. 2 & 5, 2010 ERD Meetings)

25

Action Items for Memory (Dec. 2 & 5, 2010, ERD Meetings)

1. Should Storage Class Memory drive a new architecture discussion in the Architecture Section? Explore a definition of SCM

Zhirnov and Schechtman

5. Develop a table of Devices mapped onto materiel and their critical property required to demonstrate the key attribute of the device.

BourianoffGarner and Zhirnov

6. Rename the FeFET to include the Fe-barrier device. Zhirnov8. Change “Nanobridge Cantilever” to just “Nanobridge” Zhirnov

•Put Vertical MOSFET in the Memory Section•Include new section on Storage Class Memory•Include new section on Select Device

OK

Page 26: Victor Zhirnov April 10, 2011 Potsdam, Germany ERD Memory Discussion

Two-terminal Select Device

Diode-type select devices pn-diode, Schottky diode and heterojunction diode Zener or avalanche diodes.

Resistive-Switch-type select devices innovative device concepts that exhibit resistive switching behavior. in some of these concepts the device structure/physics of operation is

similar to the structure of the storage node. A modified memory element could act as select device!

a ‘nonvolatile’ switch is required for the storage node, while for select device depending on the approaches non-volatility may not be necessary and can sometimes be detrimental.

26

Unipolar cell

Bipolar cell

Page 27: Victor Zhirnov April 10, 2011 Potsdam, Germany ERD Memory Discussion

Selection Device Benchmarking

‘Waser 2010’ (individual cell-based)

Von ~ 1 Volt

Ion min ~ 1 A

Jon ~106 A/cm2 for L~10 nm

‘Hwang 2010’( cross bar array with a 1-100 Mb block density)

Von ~ 1-5 Volt

Jon ~ 105 – 106 A/cm2

ON/OFF > 107-108

27

G. H. Kim, K. M. Kim, J. Y. Seok, H. J. Lee, D-Y. Cho, J. H. Han and C. S. Hwang, “A theoretical model for Schottky diodes for excluding the sneak current in cross bar array resistive memory”, Nanotechnology 21 (2010) 385202

H. Schroeder, V. V. Zhirnov, R. K. Cavin, and R. Waser, “Voltage-time dilemma of pure electronic mechanisms in resistive switching memory cells ”, J. Appl. Phys. 107 (2010) 054517

Page 28: Victor Zhirnov April 10, 2011 Potsdam, Germany ERD Memory Discussion

Resistive-Switch-type select devices I

Mott-transition switch is based on the Mott Metal-Insulator transition a volatile resistive switch, A VO2-based Mott-transition device has been demonstrated as a selection

device for NiOx RRAM element [Ref: M.J. Lee, “Two Series Oxide Resistors Applicable to High

Speed and High Density Nonvolatile Memory,” Adv. Mater. 19, 3919 (2007).]. The feasibility of the Mott-transition switch as selection devices still needs

further research.

Threshold switch is based the threshold switching in MIM structures caused by electronic

charge injection/trapping Significant resistance reduction can occur at a threshold voltage and this

low-resistance state quickly recovers to the original high-resistance state when the applied voltage falls below a holding voltage.

28

Page 29: Victor Zhirnov April 10, 2011 Potsdam, Germany ERD Memory Discussion

Resistive-Switch-type select devices II

MIEC switch observed in materials that conduct both ions and electronic charges – so

called mixed ionic electronic conduction materials (MIEC). The resistive switching mechanism is similar to the ionic memories.

Complementary resistive switch the memory cell is composed of two identical non-volatile ReRAM

switches connected back-to-back. Example: Pt/GeSe/Cu/GeSe/Pt structure Electrically, it can be represented by a antiserial connections of two

intrinsic Schottky diodes, which are formed at the contact sides of both cells

Can be placed into the category of Diode-type select devices

29

Page 30: Victor Zhirnov April 10, 2011 Potsdam, Germany ERD Memory Discussion

30

Selector type Material System

Von1 Ion1 Von2 Ion2 ON/OFF F REF

Unipolar cellpn-diode Poly-Si (E) 1 20 A

2×104 A/cm2

- - 105 0.3 m van Duuren 2007

Schottky diode

n-ZnO (E) 1 45 A500 A/cm2

- - 105 3 m Huby 2008

Ge NW (E) 1 1 A500 A/cm2

- - 102 0.5 m Wong 2008

a-Si (I) 1 100 nA1000 A/cm2

- - 106 100 nm Lu 2010

p-Si (E) 1 10 A1000 A/cm2

- - 103 1 m Lee 2010

Pt/TiO2 1 6 mA10 A/cm2

- - 109 245 m Hwang 2010

Heterojunction diode

n-ZnO/p-Si 3 25 mA250 A/cm2

- - 103 100m Choi 2010

CuO/InZnO 1 2.5 A1000 A/cm2

- - 103 0.5 m Park 2009

Bipolar cellZener diode (E) Toda 2009

Reverse breakdown

Schottky diode

Cu/n-Si 1 10 A -3 10 A 103 2 m Kozicky 2010

Complementary resistive switch

Pt/GeSe/Cu/GeSe/Pt

1 600 A2400 A/cm2

-1 600 A2400 A/cm

5 m Waser 2010

Diode-type select devices

Page 31: Victor Zhirnov April 10, 2011 Potsdam, Germany ERD Memory Discussion

31

Select Device Material System Von1 Ion1

(Jon1)ON/OFF F REF

Mott transition switch

Pt/VO2/Pt 0.4/0.6V

(400 A/cm2) 103 Lee 2007

Threshold switch

Chalcogenide alloy (undisclosed)

106 Kau 2009

MIEC switch ~1 40 nm Gopalakrishnan2010

Complementary resistive switch

Pt/GeSe/Cu/GeSe/Pt 1 600 A 2400 A/cm2

5 m Waser 2010

Resistive-Switch-type select devicesSource: Philip Wong / Stanford

Page 32: Victor Zhirnov April 10, 2011 Potsdam, Germany ERD Memory Discussion

Criteria for the evaluation of selection devices (An Chen/GF)Parameters Explanations

Blocking state resistance

• Measure the resistance from the selection devices in the blocking state; it is generally a voltage-dependent value

• The higher the blocking state resistance the better

Conductive state resistance

• Measure the resistance from the selection devices in the conductive state; it is generally a voltage-dependent value

• The smaller the blocking state resistance the better

Turn-on voltage • The voltage where the selection devices become sufficiently conductive

Turn-on speed • How fast the selection devices turn on, which affect switching dynamics

Turn-off voltage • The voltage where the selection devices become nonconductive (high resistance)

Turn-off speed • How fast the selection devices turn off, which affect switching dynamics

Operation polarity • Blocking/conductive states exist in both polarities (suitable for bipolar switching devices) or each in different polarity (suitable for unipolar switching devices)

Scalability • How scalable is the selection devices

Linearity • Linear or nonlinear I-V characteristics in blocking and conductive states

Processing temperature • Low processing temperature is preferred

Materials • What materials are required? How available are they? Are they compatible with the processing of the resistive switching devices?

Structures • Two terminal or three terminal

Page 33: Victor Zhirnov April 10, 2011 Potsdam, Germany ERD Memory Discussion

Scaling limits of two-terminal semiconductor non-linear elements

Victor Zhirnov1, Kwok Ng1, An Chen2, Wei Lu3

1Semiconductor Research Corporation2GlobalFoundaries3University of Michigan

Page 34: Victor Zhirnov April 10, 2011 Potsdam, Germany ERD Memory Discussion

2-terminal selector devices

External selecting device OR storage element with inherent rectifying/isolation properties 2-terminal structure with non-linear characteristics

e.g. switching diode-type behavior for unipolar memory cells for bipolar cells, selectors with two-way switching behavior are

needed, e.g. Zener diode, avalanche diode etc.

34

I

VOFF

ION

ION1

ON1

ON2

OFF

unipolar bipolar

Page 35: Victor Zhirnov April 10, 2011 Potsdam, Germany ERD Memory Discussion

Selection Device Benchmarking

‘Waser 2010’ (individual cell-based)

Von ~ 1 Volt

Ion min ~ 1 A

Jon ~106 A/cm2 for L~10 nm

‘Hwang 2010’( cross bar array with a 1-100 Mb block density)

Von ~ 1-5 Volt

Jon ~ 105 – 106 A/cm2

ON/OFF > 107-108

35

G. H. Kim, K. M. Kim, J. Y. Seok, H. J. Lee, D-Y. Cho, J. H. Han and C. S. Hwang, “A theoretical model for Schottky diodes for excluding the sneak current in cross bar array resistive memory”, Nanotechnology 21 (2010) 385202

H. Schroeder, V. V. Zhirnov, R. K. Cavin, and R. Waser, “Voltage-time dilemma of pure electronic mechanisms in resistive switching memory cells ”, J. Appl. Phys. 107 (2010) 054517

Page 36: Victor Zhirnov April 10, 2011 Potsdam, Germany ERD Memory Discussion

I. Scaling Limits of the Schottky Diodes

Fig. 8. Potential distribution near metal-semiconductor interface

W

Metal Semiconductor

Energy barriers (Schottky barriers) are formed at the metal-semiconductor (insulator) interfaces

space charge formation in the interface region

02

2 B

D

We N

If the barrier profile is known, the calculation of the current passing through the barrier is straightforward based on the thermionic and tunneling equations

Page 37: Victor Zhirnov April 10, 2011 Potsdam, Germany ERD Memory Discussion

Excel-based home-made diode model: A calibration

1.00E-081.00E-071.00E-061.00E-051.00E-041.00E-031.00E-021.00E-011.00E+001.00E+011.00E+02

1.00E+19 1.00E+20 1.00E+21

R c, O

hm·c

m2

Nd, cm-3

Sze at al.(Si)

This work (Si)

C.Y. Chang, Y. K. Fang, and S. M. Sze, “Specific contact resistance of metal-semiconductor barriers”, Soli-State Electron. 14 (1971) 541-550

Page 38: Victor Zhirnov April 10, 2011 Potsdam, Germany ERD Memory Discussion

Scaling limitation: Reduction of the effective conduction area due to side depletion

If finite lateral dimensions of a 3-dimensional semiconductor structure are considered, the side interfaces can also effect the current flow.

Band bending/barrier formation usually occurs at these interfaces, and they need to be taken into account.

The band bending results in either depletion (bent up) or accumulation (bent down), and correspondingly, a layer with lower (depletion) or higher (accumulation) conductivity of width WSV is formed.

Therefore, in addition to the depletion WMS layer aligned with the direction of current (‘active’ interface, modulated by external stimulus), there is a lateral depletion layer WSV perpendicular to the current flow (‘passive’ interface, which remains more or less stable during device operation).

This ‘passive’ side interface may also effect the total current. If a depletion high-resistive layer of width WSV is formed, the effective cross-sectional area for modulated current flow is decreased.

In the case of an accumulation low-resistive layer, a parasitic surface resistor will be formed in parallel with the resistive memory element.

Page 39: Victor Zhirnov April 10, 2011 Potsdam, Germany ERD Memory Discussion

Reduction of the effective conduction area due to side depletion

202WLJAJI

Imin=1 AWSV

WSV

02

2 B

D

We N

L Nd

Lmin>2W0

Page 40: Victor Zhirnov April 10, 2011 Potsdam, Germany ERD Memory Discussion

Scaling Limits of Diodes

40

Me

0.00

0.10

0.20

0.30

0.40

0.50

0.60

0 5 10 15 20

Me Si

nmN

VW

D

bi 10~2 0

Nd≤NC

pn-diode Esaki tunnel diode

Schottky diode Ohmic contactNdNC

NC – effective density of states in the conduction band, for Si NC=2.8x1019 cm-3

Page 41: Victor Zhirnov April 10, 2011 Potsdam, Germany ERD Memory Discussion

Schottky diode reverse current

41

-6.00E-01

-4.00E-01

-2.00E-01

0.00E+00

2.00E-01

4.00E-01

6.00E-01

8.00E-01

0 5 10 15 20

-6.00E-01

-4.00E-01

-2.00E-01

0.00E+00

2.00E-01

4.00E-01

6.00E-01

8.00E-01

0 5 10 15 20

-6.00E-01

-4.00E-01

-2.00E-01

0.00E+00

2.00E-01

4.00E-01

6.00E-01

8.00E-01

0 5 10 15 20

V=1 Volt N=5×1018 cm-3

Page 42: Victor Zhirnov April 10, 2011 Potsdam, Germany ERD Memory Discussion

Schottky diode reverse current

42

-6.00E-01

-4.00E-01

-2.00E-01

0.00E+00

2.00E-01

4.00E-01

6.00E-01

8.00E-01

0 5 10 15 20

-6.00E-01

-4.00E-01

-2.00E-01

0.00E+00

2.00E-01

4.00E-01

6.00E-01

8.00E-01

0 5 10 15 20

V=1 Volt N=1019 cm-3

Page 43: Victor Zhirnov April 10, 2011 Potsdam, Germany ERD Memory Discussion

Schottky diode reverse current

43

-6.00E-01

-4.00E-01

-2.00E-01

0.00E+00

2.00E-01

4.00E-01

6.00E-01

8.00E-01

0 5 10 15 20

V=1 Volt N=2.8×1019 cm-3

OFF current increases with doping

OFF current increases with scaling

Page 44: Victor Zhirnov April 10, 2011 Potsdam, Germany ERD Memory Discussion

Germanium Schottky diodes

NC=1.04x1019 cm-3

Nd=NC and Von= 1 volt

W0=8.7 nm

Lmin=20 nm (Ion~ 1A)

ON/OFF ~ 105

Extreme scaling: ‘Relaxed’ case:

Nd=1018 cm-3

L=500 nm

W0=31 nm

Ion~ 2 mA

ON/OFF ~ 105 Voff= 1 volt

Page 45: Victor Zhirnov April 10, 2011 Potsdam, Germany ERD Memory Discussion

Silicon Schottky diodes

NC=2.8x1019 cm-3

Nd=NC and Von= 1 volt

W0=6.2 nm

Lmin=14 nm (Ion~ 1A)

ON/OFF ~ 107

Extreme scaling: ‘Relaxed’ case:

Nd=1018 cm-3

L=300 nm

W0=31 nm

Ion~ 260 A

ON/OFF ~ 1010 Voff= 1 volt

Page 46: Victor Zhirnov April 10, 2011 Potsdam, Germany ERD Memory Discussion

46

Selector type Material System

Von1 Ion1 Von2 Ion2 ON/OFF F REF

Unipolar cellpn-diode Poly-Si (E) 1 20 A

2×104 A/cm2

- - 105 0.3 m van Duuren 2007

Schottky diode

n-ZnO (E) 1 45 A500 A/cm2

- - 105 3 m Huby 2008

Ge NW (E) 1 1 A500 A/cm2

- - 102 0.5 m Wong 2008

a-Si (I) 1 100 nA1000 A/cm2

- - 106 100 nm Lu 2010

p-Si (E) 1 10 A1000 A/cm2

- - 103 1 m Lee 2010

Pt/TiO2 1 6 mA10 A/cm2

- - 109 245 m Hwang 2010

Heterojunction diode

n-ZnO/p-Si 3 25 mA250 A/cm2

- - 103 100m Choi 2010

CuO/InZnO 1 2.5 A1000 A/cm2

- - 103 0.5 m Park 2009

Bipolar cellZener diode (E) Toda 2009

Reverse breakdown

Schottky diode

Cu/n-Si 1 10 A -3 10 A 103 2 m Kozicky 2010

Complementary resistive switch

Pt/GeSe/Cu/GeSe/Pt

1 600 A2400 A/cm2

-1 600 A2400 A/cm

5 m Waser 2010

Lmin=20 nmON/OFFmax=105

ON/OFFmax=107 Lmin=14 nm

Page 47: Victor Zhirnov April 10, 2011 Potsdam, Germany ERD Memory Discussion

Action Items for April 2011

To complete assessments for pn-diodes, Schottky diodes, and heterojucntion diodes To find experimental reports on smallest diodes

To begin studies of Zener and avalanche diodes and other concepts

To begin studies of the resistive switch-type select devices May have better scaling properties than diode-type devices

Page 48: Victor Zhirnov April 10, 2011 Potsdam, Germany ERD Memory Discussion

Selection Devices Summary

Experimental selecting devices have yet to meet the benchmark specifications Hence, outstanding research issues persist 2011 SD table and text will reflect both target parameters

and experimental status

More detailed benchmarking and further analysis is currently underway

48

Page 49: Victor Zhirnov April 10, 2011 Potsdam, Germany ERD Memory Discussion

Timeline & Milestones

April 5 – A draft section (~ 2 paragraphs + 1 Table) for the ITRS ERD chapter

April 10 – ITRS meeting in Potsdam, Germany July 1 - presentation draft for the ITRS meeting in SF July 9 – ITRS meeting in SF Wei Lu will present a technical presentation with a summary of our findings Aug. 1 – Final materials on SD for ITRS ERD Chapter Nov. 1 – Research paper manuscript draft complete

49

Page 50: Victor Zhirnov April 10, 2011 Potsdam, Germany ERD Memory Discussion

Solid-State Storage Class Memory

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SCM Team:

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Barry Schechtman (INSIC)Rod Bowman (Seagate)Geoff Burr (IBM)Bob Fontana (IBM)Michele Franceschini (IBM)Rich Freitas (IBM)Kevin Gomez (Seagate)Mark Kryder (CMU)Yale Ma (Seagate)Kroum Stoev (Western Digital)Winfried Wilcke (IBM)

Thomas Vogelsang (RAMBUS)Matthew Marinella (Sandia Labs)Jim Hutchby (SRC)Victor Zhirnov (SRC)

Page 52: Victor Zhirnov April 10, 2011 Potsdam, Germany ERD Memory Discussion

Storage-class memory (SCM)

Research and development efforts are underway worldwide on several nonvolatile memory technologies that not only complement the existing memory but also reduce the distinction between memory and storage1

Memory: fast, evanescent, random-access, expensive Storage: slow, permanent, sequential-access, inexpensive

Storage-class memory (SCM): Emerging solid-state technologies with (some) attributes of both memory and storage devices May eventually replace discs and (perhaps) DRAM1

1 “Storage-class memory: The next storage system technology”, by R. F. Freitas and W. W. Wilcke, IBM J. Res. & Dev. 52 (2008) 439

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SCM candidates2 and their relation to ITRS ERD chapter

FeFET ReRAM Solid Electrolyte Organic …

2“Overview of candidate device technologies for storage-class memory”, by G. W. Burr et al, IBM J. Res. & Dev. 52 (2008) 449

Many of the current SCM candidates are currently present in the ITRS as memory technologies. Their potential for SCM could be included within the existing framework, e.g. as an additional table row and corresponding discussion in text.

2009 Decision: ITRS ERD will include storage-class memory (SCM) in ERD chapter

Page 54: Victor Zhirnov April 10, 2011 Potsdam, Germany ERD Memory Discussion

Draft section on SCM is Available

Storage-class memory (SCM) describes a device category that combines the benefits of solid-state memory, such as high performance and robustness, with the archival capabilities and low cost of conventional hard-disk magnetic storage. Such a device requires a nonvolatile memory technology that could

be manufactured at a very low cost per bit.

As the scalability of flash is approaching its limit, emerging technologies for non-volatile memories need to be investigated for a potential “take over” of the scaling roadmap for flash.

In principle, such new SCM technology could engender two entirely new and distinct levels within the memory and storage hierarchy, located below off-chip DRAM and above mechanical storage, and differentiated from each other by access time.

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Page 55: Victor Zhirnov April 10, 2011 Potsdam, Germany ERD Memory Discussion

I. S-type storage-class memory

The first new level, identified as S-type storage-class memory (S-SCM), would serve as a high-performance solid-state drive accessed by the system I/O controller much like an HDD. S-SCM would need to provide at least the same data retention as

flash, offering new direct overwrite and random access capabilities

(which can lead to improved performance and simpler systems) However, it would be absolutely critical that the device cost for S-

SCM be no more than 1.5-2x higher than NAND flash If the cost per bit could be driven low enough through ultrahigh

memory density, ultimately such an S-SCM device could potentially replace magnetic hard-disk drives in enterprise storage server systems.

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Page 56: Victor Zhirnov April 10, 2011 Potsdam, Germany ERD Memory Discussion

II. M-type storage-class memory

M-SCM: should offer a read/write latency of less than 1 s.

would allow it to remain synchronous with a memory system, allowing direct connection from a memory controller and bypassing the inefficiencies of access through the I/O controller.

Would be to augment a small amount of DRAM to provide the same overall system performance as a DRAM-only system, while providing Moderate retention, Lower power-per-GB and lower cost-per-GB than DRAM. Endurance is particularly critical

the time available for wear-leveling, error-correction, and other similar techniques is limited

> 109 cycles

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Target device and system specifications for SCM

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[1] The endurance of the chip shouldn't be confused with the endurance of an entire SSDisk, once wear-level is employed.[2] Power was not covered in any detail: TBD

Action item: All numbers need to be carefully reviewed

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SCM section in 2011 ERD

2011: Additional rows in the Emerging Research Memory Table

Potential of current technology entries for storage-class memory

Corresponding discussion in text Critical parameters:

Scalability Multilevel Cell - MLC (MLC vs extreme scaling dilemma) 3D integration (stacking) Fabrications costs Endurance (for M-SCM) Power

The driving issue is to minimize the cost per bit

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Page 59: Victor Zhirnov April 10, 2011 Potsdam, Germany ERD Memory Discussion

Potential of the current emerging research memory candidates for SCM applications

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Parameter Ferroelectric memory

Nanomechanical memory

Redox memory

Mott Memory

Macromolecular memory

Molecular Memory

Scalability

MLC

3D integration

Fabrication cost

Endurance

Action item 1: Corresponding discussion needs to be added to the memory text

Action item 2: Decision is needed on how inclusive the SCM section should be:

Should it be limited by ERD devices (table above)?OR

It should include other, more matured devices, e.g.PCM, STT-MRAM, etc.?

Page 60: Victor Zhirnov April 10, 2011 Potsdam, Germany ERD Memory Discussion

Action Items for Memory (Dec. 2 & 5, 2010, ERD Meetings) Should Storage Class Memory drive a new architecture

discussion in the Architecture Section? Advances in SCM could drive the emerging data-centric chip

architectures Nanostores

Nanostores architectures could be an important direction for the future of information processing.

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Computer, Jan. 2011

Page 61: Victor Zhirnov April 10, 2011 Potsdam, Germany ERD Memory Discussion

Decisions for Memory Section (Dec. 2 & 5, 2010 ERD Meetings)

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Action Items for Memory (Dec. 2 & 5, 2010, ERD Meetings)

1. Should Storage Class Memory drive a new architecture discussion in the Architecture Section? Explore a definition of SCM

Zhirnov and Schechtman

5. Develop a table of Devices mapped onto materiel and their critical property required to demonstrate the key attribute of the device.

BourianoffGarner and Zhirnov

6. Rename the FeFET to include the Fe-barrier device. Zhirnov8. Change “Nanobridge Cantilever” to just “Nanobridge” Zhirnov

•Put Vertical MOSFET in the Memory Section•Include new section on Storage Class Memory•Include new section on Select Device

OK

OK

OK

OK

OKOK

Page 62: Victor Zhirnov April 10, 2011 Potsdam, Germany ERD Memory Discussion

ERD Memory Tasks

Update Memory Tables and Text Implement the decisions made at the 2010 ERD FFMa s wel

as at the 2010 workshops in Barza and Tsukuba Status: work in progress 1st draft (tables): April 2011 Final draft (tables + text): July 1, 2011

Create new section on Storage Class Memory Status: 1st draft completed Final draft: April 2011

Create new section on Select Device Status: A fundamental study is underway develop an analysis of nanoscale selector

devices for memory 1st draft: April 2011 Final draft: July 1, 2011 Research paper: November 2011

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