US. DEPARTMENT OF ENERGY INDUSTRIAL SOLVENT RECYCLING CONFERENCE

MAY 23-24, 1991

voc CONTROL:

CHOICES, COSTS, AND PERFORMANCE OF SYSTEMS

VICTOR S. ENGLEMAN AND LINDA L. EVEY SCIENCE APPLICATIONS INTERNATIONAL CORPORATION

10240 SORRENTO VALLEY ROAD #204 SAN DIEGO, CALIFORNIA 921 21

DEVELOPMENT OF SCREENING MODEL

ELEVEN CONTROL TECHNOLOGY COMBINATIONS IMPLEMENTED

ADDITIONAL TECHNOLOGIES PARTIALLY IMPLEMENTED

TWENTY FIVE SOLVENTS IMPLEMENTED

ADDITIONAL SOLVENTS BEING CONSIDERED FOR ADDITION

MODEL CALCULATES COSTS OF CONTROL TECHNOLOGIES MODEL FLAGS POTENTIAL PROBLEMS AND CONCERNS

MODEL ALLOWS USER INPUT FOR STREAM CONDITIONS

MODEL ALSO ALLOWS USER INPUT FOR UTILITIES, ETC. MODEL CALCULATES CAPITAL AND OPERATING COSTS MODEL CALCULATES ANNUAL COSTS

CONTROL TECHNOLOGIES IMPLEMENTED IN SCREENING MODEL

THERMAL INCINERATION

THERMAL INCINERATION WITH HEAT RECOVERY REGENERATIVE INCINERATION CATALYTIC INCINERATION ADSORPTION WITH OFF-SITE REGENERATION

ADSORPTION WITH ON-SITE STEAM REGENERATION ADSORPTION WITH ON-SITE STATIONARY RANKINE REGENERATION

ADSORPTION WITH ON-SITE STATIONARY BRAYTON REGENERATION ADSORPTION WITH ON-SITE DECOUPLED BRAYTON REGENERATION

REVERSE RANKINE CYCLE CONDENSATION REVERSE BRAYTON CYCLE CONDENSATION

CRYOGENIC LIQUID CONDENSATION (PARTIALLY IMPLEMENTED) ADSORPTION SCRUBBING (PARTIALLY IMPLEMENTED) MEMBRANE SEPARATION (PARTIALLY IMPLEMENTED) BlOFlLTRATlON (PARTIALLY IMPLEMENTED)

VOLATILE ORGANIC COMPOUNDS INCLUDED IN'THE MODEL

ACETIC ACID ACETONE BENZENE

CARBON TETRACHLORIDE CHLOROBENZENE

c.r o\ p-DICHLOROBENZENE 00

ETHYLENE ETHYLENE DICHLORIDE

FORMALDEHYDE HEPTANE METHANOL METHYL CHLORIDE

METHYL ETHYL KETONE

METHYL ISOBUTYL KETONE METHYLENE CHLORIDE PERCHLOROETHYLENE TOLUENE TRICHLOROETHYLENE

TRICHLOROFLUOROMETHANE TRICHLOROTRIFLUOROETHANE

VINYL CHLORIDE m-XYLENE 0-XYLENE p-XYLENE

METHYL CHLOROFORM

INPUTS TO THE MODEL (DEFAULT VALUES PROVIDED AS BACKUP) SOLVENTS

COMPOUNDS CONCENTRATIONS

RECOVERY VALUE STREAM CONDITIONS

FLOW RATE TEMPERATURE

PRESSURE OPERATING TIME

HR/DAY, DAYS/WK, WK/YR PERCENT RECOVERY REQUIRED

UNIT COSTS OF UTILITIES AND CHEMICALS

ELECTRICITY LABOR

STEAM INERT GAS

WATER CATALYST

FUEL CARBON

MODEL CALCULATES COSTS OF CONTROL TECHNOLOGIES

CAPITAL COSTS

EQUIPMENT COSTS INSTALLATION COSTS

OPERATING COSTS

ENERGY

WATER LABOR

MAINTENANCE INERT GAS WASTE DISPOSAL

CAPITAL RECOVERY TAXES AND INSURANCE

OVERHEAD SOLVENT RECOVERY

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LEAST-COST OPTIONS FOR CONTROL TECHNOLOGIES REACTIVE SOLVENT (INCLUDING ADSORPTION)

OTHER FACTORS AFFECTING VOC CONTROL SELECTION

o VALUE o REACTIVITY o # COMPONENTS o CONDENSATION TEMP o MISCIBILITY

o WATER CONTENT

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REGENERATION

ADSORPTION/MOBILE INERT REGENERATION I I I I

10 100 1,000 10,000 1 00,000 VOC CONCENTRATION (PPM)

LEAST-COST OPTIONS FOR CONTROL TECHNOLOGIES REACTIVE SOLVENT (INCLUDING ADSORPTION)

OTHER FACTORS AFFECTING VOC CONTROL SELECTION

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WHEN ADSORPTION IS INCLUDED FOR THIS CASE,

USING THE GIVEN ASSUMPTIONS INCINERATION IS NOT COST-COMPETITIVE

SEE THE EXAMPLE WHICH ELIMINATES ADSORPTION

10 100 1,000 1 0,000 1 00,000

VOC CONCENTRATION (PPM)

LEAST-COST OPTIONS FOR CONTROL TECHNOLOGIES REACTIVE SOLVENT (INCLUDING ADSORPTION)

OTHER FACTORS AFFECTING VOC CONTROL SELECTION

o VALUE o REACTIVITY o # COMPONENTS o CONDENSATION TEMP o MISCIBILITY

o WATER CONTENT

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VOC CONCENTRATION (PPM)

LEAST-COST OPTIONS FOR CONTROL TECHNOLOGIES REACTIVE SOLVENT (ELIMINATING ADSORPTION)

OTHER FACTORS AFFECTING VOC CONTROL SELECTION

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3 0 -I

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o VALUE o REACTIVITY o # COMPONENTS o CONDENSATION TEMP o MISCIBILITY

o WATER CONTENT

REGENERATIVE INCINERATION

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10 100 1,000 1 0,000 1 00,000

VOC CONCENTRATION (PPM)

LEAST-COST OPTIONS FOR CONTROL TECHNOLOGIES REACTIVE SOLVENT (ELIMINATING ADSORPTION)

OTHER FACTORS AFFECTING VOC CONTROL SELECTION

o VALUE o REACTIVITY o # COMPONENTS o CONDENSATION TEMP o MISCIBILITY

o WATER CONTENT

100,000

10,000

1,000

100

/ I / INDIRECT RANKINE

10 100 1,000 10,Ooo 1 00,000

VOC CONCENTRATION (PPM)

Office of lndust I I

J

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DOEflndustry INDUSTRIAL SOLVENT RECYCLING CONFERENCE

Sun Diego, California May 23-24, 1991

SPEAKERS

Mr. Gregory E. Albert Product Marketing Manager E.I. Du Pont De Nemours & Company

Wilmington, D E 19880-0030 BMP 30-2220, P.O. BOX 80030

(302) 992-5303

Mr. Geoff R. Bales Manager of Research Southern California Edison 2244 Walnut Grove Avenue, Room 467 Rosemead, CA 91770 (818) 302-9510

Ms. Yvonne I. Cadwallader Process Development Supervisor 3M Company Building 518-1-01 St. Paul, MN 55144 (612) 736-5755 FAX: (612) 736-3122

Dr. Victor Engleman Division Manager Science Applications Int'l Corporation (SAIC) 10240 Sorrento Valley Road, #204 San Diego, CA 92121 (619) 587-9071, ~ 1 6 9 FAX: (619) 457-5481

Mr. Joseph C. Enneking Vice President Nucon International Corporation 7000 Huntley Road, P.O. Box 29151 Columbus, OH 43229 (614) 843-5716 FAX: (614) 431-0858

Mr. Jesper Gronvaldt General Manager Munters Zeol 79 Monroe Street Amesbury, MA 01913 (508) 388-2666 FAX: (508) 388-2666

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Mr. Adel Hakki Senior Consultant Chem Systems, Inc. 303 S Broadway Tarrytown, NY 10591-5487 (914) 631-2828 FAX: (914) 631-8851

Ms. Alcmene Haloftis U.S. Occupational Safety & Health Admin. Office of Risk Reduction Technologies U.S. Department of Labor 200 Constitution Ave. NW, Rm. N-3718 Washington, D C 20210 (202) 523-7174

Mr. Fayez Hanna Director, Risk Reduction Technologies U.S. Occupational Safety & Health Admin. Office of Risk Reduction Technologies U.S. Department of Labor 200 Constitution Ave. NW, Rm. N-3718 Washington, DC 20210 (202) 523-7174

Mr. Nirmal IC Jain Specialist 3M Company Building 42-1E-01, P.O. Box 33331 St. Paul, MN 55133 (612) 778-4723 FAX: (612) 778-7149

Dr. Robert E. Kenson Development Director Met-Pro Corporation Box 144 Harleysville, PA 19438 (215) 723-6751 FAX: (215) 723-6758

Mr. Al Koett Technical Manager Safety-Kleen Corporation 777 Big Timber Road Elgin, IL 60123 (708) 697-8460 FAX: (708) 697-2783

Mr. Edward Laird President A i r Quality Consultants 15541 Commerce Lane Huntington Beach, CA 92649 (714) 894-5252 FAX: (714) 893-2322

Mr. John Lappin, Sr. Program Coordinator, Clean Air Coating Customer Technology Application Center 6090 N INsindale Avenue Ifindale, CA 91702 (818) 812-7381

Dr. Wendy Longley-Cook Manager of Corporate Environment Rohr Industries, Inc. P.O. Box 878, MC 2% Chula Vista, CA 92012

Mr. Robert McCormick Supervisor, Resource Recovery Unit Califomia State Dept. of Health Services Toxic Substance Control Program Alternative Technology Division P.O. Box 942732 Sacramento, CA 94234-7320 (916) 322-1-366

Cr. Roland 0. Meyer President Vaco-Solv Chicago, Inc. P.O. Box 1544 Bamngton, !L 60011

FAX: (708) 381-4079 (708) 381-4079

Mr. Henry P. Morse Marketinmajor Accounts San Diego Gas & Electric San Diego, CA (619) 696-4612

Ms. Pang Mueller Senior Enforcement Manager South Coast A i r Quality Mgt. District 9150 Flair Drive El Monte, CA 91731 (818) 572-6200 FAX: (818) 571-7650

Mr. Al Nassralla ChemicaVEnvironmentaI Engineer Aerochem, Inc. 1885 N Batavia Orange, CA 92665 (714) 921-5325 FAX: (714) 974-2462

Mr. Stephen P. Risotto Executive Director Center for Emissions Control 1225 19th Street NW, Suite 300 Washington, DC 20036 (202) 223-5890

Mr. Joel E. Rodgers VP & General Mgr., Engineered Solvent Systems Allied Signal, Inc. 101 Columbia Road Morristom, NJ 07%2-1139 (201) 455-4848 FAX: (201) 455-2745

Mr. Paul Scheihing Program Manager, CE-221 Office of Industrial Technologies U.S. Department of Energy loo0 Independence Ave. SW, Rm 5F-035 Washington, DC 20585

FAX: (202) 586-5053 (202) 586-7234

Mr. Pete Schneider Treasurer, Nat’l Association of Solvent Recyclers President Romic Chemical Corporation 2081 Bay Road E Palo Alto, CA 94303 (415) 324-1638

Mr. Gary Schrebe Project Mgr, Chemicals & Metals Dept. Dow Chemical Company 2020 Willard H. Dow Center Midland, MI 40674 (517) 636-8149

Mr. John Schroeder Nucon International, Inc. 7000 Huntley Road, P.O. Box 29151 Columbus, OH 43229 (614) 846-5716 FAX: (614) 431-0858

60

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I

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Mr. Lynn E. Shugarman Director of Engineering Terra-Aqua Enviro Systems, Inc. Fontana, CA (714) 350-9131

Ms. Vicki Simmons Marketing Director Membrane Technology & Research, Inc. 1360 Willow Road, Suite 103 Menlo Park, CA 94025

FAX: (415) 328-6580 (415) 328-2228

Mr. Steve W. Smith Program Mgr., Electrotechnology Sales Duke Power Company P.O. Box 1006 Charlotte, NC 28201 (704) 373-5859 FAX: (704) 373-4210

Mr. Robert J. Spencer Mana’ger, Cryogenic Applications Liquid Carbonic Industries Corporation 3740 W 74th Street Chicago, IL 60629 (312) 838-6911 FAX: (312) 838-6308

Dr. Roger D. Sung Senior Research Engineer Southern California Edison Company 2244 Walnut Grove Avenue, Room 449, GO1 P.O. Box 800 Rosemead, CA 91770 (818) 302-9551

Mr. Ken Suzuh Technical Director Printing Industries Association 5800 S Easton Avenue, Suite 400 Los Angela, CA 9O040 (213) 728-9500 FAX: (213) 724-2327

Mr. Kevin Whitall Sales Engineer Darr Industries 4O600 Plymouth Road Plymouth, MI 48170-4297 (313) 459-6800 FAX: (313) 459-5837

Mr. Michael Wilson Sales Specialist Luwa Corporation P.O. B o x 16348 Charlotte, NC 28297-6348 (704) 394-8341 FAX: (704) 392-8507

Dr. Katy Wolf Director IRTA 3727 W 6th Street, Suite 505 Los Angela, CA 90020 (213) 480-0222 FAX: (213) 480-0027

MODERATORS:

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Coating, Painting & Finishing Mr. Adel Hakki Senior Consultant Chem Systems, Inc. 303 S Broadway Tarrytown, NY 10591-5487 (914) 631-2828 FAX: (914) 631-8851

Aerospace Dr. Katy Wolf Director IRTA 3727 W 6th Street, Suite 505 Los Angela, CA 90020 (213) 480-0222 FAX: (213) 480-0027

Printing Mr. Ken Suzuki Technical Director Printing Industries Association 5800 S Easton Avenue, Suite 400 Los Angela, CA 9O040 (213) 728-9500 FAX: (213) 724-2327

Furniture Mr. Edward Laird President A i r Quality Consultants 15541 Commerce Lane Huntington Beach, CA 92649 (714) 894-5252 FAX: (714) 893-2322