Water-based color ink

Safety Data Sheet

Water-based color ink Version：V1.0.0.2

Report No.：HGNM19SBEA

Creation Date：2019/02/20

Revision Date：2019/02/26

*Prepared according to UN GHS (the 7th revised edition)

1 Identification of the chemical and supplier

| Product identifier

Product Name Water-based color ink

CAS No. Not applicable

EC No. Not applicable

Molecular Formula Not applicable

| Relevant identified uses of the substance or mixture and uses advised against

Relevant identified uses Water-based color ink.

Uses advised against Please consult manufacturer.

| Details of the supplier of the Safety Data Sheet

Officeworks Ltd. Name of the company

Address of the

company 236-262 East Boundary Road Bentleigh East VIC 3165 Australia ABN:36 004 763 526·

Post code /

Telephone number 1300 633 423

Fax number

E-mail address

/

| Emergency phone number

Emergency phone

number

2 Hazards identification

| Hazard classification according to GHS

Sensitization – Skin Category 1

Specific Target Organ

Toxicity (Repeated Category 2

Exposure)

| Label elements

Hazard pictograms

Signal word Warning

| Hazard statements

1 / 13

Australia POISONS INFORMATION CENTRE 13 11 26

Water-based color ink Version：V1.0.0.2 Revision Date：2019/02/26

H317 May cause an allergic skin reaction

H373 May cause damage to organs through prolonged or repeated exposure

| Precautionary statements

Prevention

P260 Do not breathe dust/fume/gas/mist/vapours/spray.

P272 Contaminated work clothing should not be allowed out of the workplace.

P280 Wear protective gloves/protective clothing/eye protection/face protection.

Response

P314 Get medical advice/attention if you feel unwell.

P302+P352 IF ON SKIN: Wash with plenty of water.

P333+P313 If skin irritation or rash occurs: Get medical advice/attention.

P362+P364 Take off contaminated clothing and wash it before reuse.

Storage

Disposal

Storage Not applicable

Dispose of contents/container in accordance with local/regional/national/

international regulations. P501

| Hazard description

Physical and chemical hazards

No information available

Health hazards

Inhaled Inhalation of the product may produce adverse health effects or irritation of the

respiratory tract following discomfort.

Accidental ingestion of the product may be harmful to the health of the Ingestion

Skin Contact

Eye

individual.

The product may cause an allergic skin reaction following direct contact with

the skin.

This product may cause temporary discomfort following direct contact with the

eye.

Environmental hazards

Please refer to 12th chapter of SDS.

3 Composition/information on ingredients

Concentration

(weight percent, %) Component Cas No. EC No.

Acid Yellow 3

107-21-1 Ethylene glycol 203-473-3 Commercial secrets

2 / 13


Glycerol 56-81-5 200-289-5

247-500-7

Commercial secrets

Commercial secrets FS-14D（Thiazoline compound） 26172-55-4

WET KL245（Oxirane, methyl, polymer with oxirane,

mono(3- (1,3,3,3-tetra methyl-1- 134180-76-0 - Commercial secrets

((trimethylsilyl)oxy)disiloxanyl)propyl)ether）

DYE 8004-92-0

7732-18-5

305-879-5

231-791-2

Commercial secrets

Commercial secrets Water

Acid Yellow 23

Ethylene glycol

Glycerol

107-21-1

56-81-5

203-473-3

200-289-5

247-500-7

Commercial secrets

Commercial secrets





DYE 1934-21-0

7732-18-5

217-699-5

231-791-2

Commercial secrets


Acid Red 18

Ethylene glycol

Glycerol

107-21-1

56-81-5

203-473-3

200-289-5

247-500-7

Commercial secrets

Commercial secrets





DYE 2611-82-7

7732-18-5

220-036-2

231-791-2

Commercial secrets


Acid Red 52

Ethylene glycol

Glycerol

107-21-1

56-81-5

203-473-3

200-289-5

247-500-7

Commercial secrets

Commercial secrets





DYE 3520-42-1

7732-18-5

222-529-8

231-791-2

Commercial secrets


Acid Red 87

Ethylene glycol

Glycerol

107-21-1

56-81-5

203-473-3

200-289-5

247-500-7

Commercial secrets

Commercial secrets



mono(3- (1,3,3,3-tetra methyl-1- 134180-76-0

17372-87-1

- Commercial secrets


DYE 241-409-6 Commercial secrets

3 / 13


Water 7732-18-5

Acid Blue 9

231-791-2 Commercial secrets

Ethylene glycol

Glycerol

107-21-1

56-81-5

203-473-3

200-289-5

247-500-7

Commercial secrets

Commercial secrets





DYE 2650-18-2

7732-18-5

220-168-0

231-791-2

Commercial secrets


Acid Blue 104

Ethylene glycol

Glycerol

107-21-1

56-81-5

203-473-3

200-289-5

247-500-7

Commercial secrets

Commercial secrets





DYE 6505-30-2

7732-18-5

229-390-2

231-791-2

Commercial secrets


Direct Black mixture

Ethylene glycol

Glycerol

107-21-1

56-81-5

203-473-3

200-289-5

247-500-7

Commercial secrets

Commercial secrets





Black SP - 305-879-5

231-791-2

Commercial secrets

Commercial secrets Water 7732-18-5

Acid Voilet 17

Ethylene glycol

Glycerol

107-21-1

56-81-5

203-473-3

200-289-5

247-500-7

Commercial secrets

Commercial secrets





DYE 4129-84-4

7732-18-5

223-942-6

231-791-2

Commercial secrets


Acid Red 92

Ethylene glycol

Glycerol

107-21-1

56-81-5

203-473-3

200-289-5

Commercial secrets

Commercial secrets

4 / 13


FS-14D（Thiazoline compound） 26172-55-4 247-500-7

-

Commercial secrets

Commercial secrets


mono(3- (1,3,3,3-tetra methyl-1- 134180-76-0 ((trimethylsilyl)oxy)disiloxanyl)propyl)ether）

DYE 18472-87-2

7732-18-5

242-355-6

231-791-2

Commercial secrets


4 First aid measures

|Description of first aid measures

Immediate medical attention is required. Show this safety data sheet (SDS) to

the doctor in attendance.

Rinse thoroughly with plenty of water for at least 15 minutes and consult a

physician if feel uncomfortable.

Take off contaminated clothing and shoes immediately. Wash off with plenty of

water for at least 15 minutes and consult a physician if feel uncomfortable.

Do not induce vomiting. Never give anything by mouth to an unconscious

person. Call a physician or Poison Control Center immediately.

Move victim into fresh air. If breathing is difficult, give oxygen. Do not use

General advice

Eye contact

Skin contact

Ingestion

Inhalation mouth to mouth resuscitation if victim ingested or inhaled the substance. If not

breathing, give artificial respiration and consult a physician immediately.

Ensure that medical personnel are aware of the substance involved. Take

precautions to protect themselves and prevent spread of contamination. Protecting of first-aiders

| Most important symptoms and effects, both acute and delayed

1 Please see section 11.

| Indication of any immediate medical attention and special treatment needed

1

2

Treat symptomatically.

Symptoms may be delayed.

5 Firefighting measures

| Extinguishing media

Suitable extinguishing Use extinguishing media suitable for surrounding area.

There is no restriction on the type of extinguisher which may be used.

media

Unsuitable extinguishing

media

| Specific hazards arising from the substance or mixture

1

2

Not combustible, not considered a significant fire risk, however containers may burn.

Development of hazardous combustion gases or vapor possible in the event of fire.

| Advice for firefighters

As in any fire, wear self-contained breathing apparatus（MSHA/NIOSH approved or equivalent) and full

protective gear. 1

2

3

Fight fire from a safe distance, with adequate cover.

Suppress（knock down) gases/vapor/mists with water spray.

6 Accidental release measures

| Personal precautions, protective equipment and emergency procedures

5 / 13


Ensure adequate ventilation. Remove all sources of ignition. Ta ke precautionary measures against static

discharges. 1

2

3

Evacuate personnel to safe areas. Keep people away from and upwind of spill/leak.

Use personal protective equipment. Avoid breathing vapours, mist or gas.

| Environmental precautions

1

2

Prevent further leakage or spillage if safe to do so.

Discharge into the environment must be avoided.

| Methods and materials for containment and cleaning up

Absorb spilled material in dry sand or inert absorbent. In case of large amount of spillage, contain a 1

spill by bunding.

Adhered or collected material should be promptly disposed of, in accordance with appropriate laws

and regulations. 2

3 Remove all sources of ignition. Use spark-proof tools and explosion-proof equipment.

7 Handling and storage

| Precautions for handling

1

2

3

4

Handling is performed in a well ventilated place.

Wear suitable protective equipment.

Avoid contact with skin and eyes.

Keep away from heat/sparks/open flames/ hot surfaces.

| Precautions for storage

1

2

3

4

5

Keep containers tightly closed.

Keep containers in a dry, cool and well-ventilated place.

Keep away from heat/sparks/open flames/hot surfaces.

Store away from incompatible materials and foodstuff containers.

Containers which are opened must be carefully resealed and kept upright to prevent leakage.

8 Exposure controls/personal protection

| Control parameters

Occupational Exposure limit values

Limit value - Eight hours Limit value - Short term Component Country/Region

ppm

-

mg/m³ ppm

40

50

40

20

20

40

-

mg/m³

100

127

104

52

South Korea

New Zealand

Ireland

-

- -

20

10

10

20

-

52

26

26

52

15

Ethylene glycol

107-21-1 Germany (AGS)

Denmark 52

Australia 104

- Glycerol USA - OSHA

6 / 13

Water-based color ink

56-81-5

Version：V1.0.0.2 Revision Date：2019/02/26

South Korea -

-

-

-

-

10

10

50

10

10

-

-

-

-

-

-

- Ireland

Germany (DFG)

Belgium

100

-

Australia -

Biological limit values

Biological limit values No information available

Monitoring methods

EN 14042 Workplace atmospheres. Guide for the application and use of procedures for the assessment

of exposure to chemical and biological agents.

GBZ/T 160.1~GBZ/T 160.81-2004 Determination of toxic substances in workplace air（Series standard）.

1

2

| Engineering controls

1

2

3

4

5

Ensure adequate ventilation, especially in confined areas.

Ensure that eyewash stations and safety showers are close to the workstation location.

Use explosion-proof electrical/ventilating/lighting/equipment.

Set up emergency exit and necessary risk-elimination area.

Handle in accordance with good industrial hygiene and safety practice.

| Personal protection equipment

General requirement

Eye protection Tightly fitting safety goggles (approved by EN 166(EU) or NIOSH (US).

Wear protective glove（s such as butyl rubber）, passing the tests according to EN

374(EU), US F739 or AS/NZS 2161.1 standard. Hand protection

If exposure limits are exceeded or if irritation or other symptoms are

Respiratory protection experienced, use a full-face respirator with multi-purpose combination (US) or

type AXBEK (EN 14387) respirator cartridges.

Skin and body protection Wear fire/flame resistant/retardant clothing and antistatic boots.

9 Physical and chemical properties

| Physical and chemical properties

Appearance Colored liquids

Odor No special odor

Odor threshold No information available

pH No information available

Melting point/freezing ＜20

point(℃)

Initial boiling point and >35

boiling range(℃)

Flash point(Closed The flash point above 93 ℃

cup,℃)

Evaporation rate No information available

7 / 13


Flammability Not flammable

Upper/lower explosive

limits[%(v/v)] Upper limit：No information available；Lower limit：No information available

Vapor pressure No information available

Relative vapour

density(Air＝1)

Relative

＞1

No information available density(Water=1)

Solubility(mg/L) Soluble in water

n-octanol/water

partition coefficient

Auto-ignition




temperature(℃)

Decomposition

temperature(℃)

Kinematic viscosity No information available

Particle characteristics Not applicable

10 Stability and reactivity

| Stability and reactivity

Contact with incompatible substances can cause decomposition or other

chemical reactions.

Chemical stability Stable under proper operation and storage conditions.

Reactivity

In contact with oxidants causes severe reactions, and may cause a fire or

explosion. In contact with active metals (alkali metals, Na, Ca etc.) causes a

reaction and release hydrogen.

Possibility of hazardous

reactions

Conditions to avoid Incompatible materials, heat, flame and spark.

Oxidants, alkali, sodium, calcium, and other active metal, halogen, metal oxide,

nonmetal oxide, acyl halide and metal phosphide. Incompatible materials

Hazardous Under normal conditions of storage and use, hazardous decomposition

decomposition products products should not be produced.

11 Toxicological information

| Acute toxicity

Component Cas No. LD50(oral) LD50(dermal) LC50(inhalation,4h)

No information

available

No information

available DYE 1934-21-0 12750mg/kg(Mouse)

No information

available Glycerol

DYE

56-81-5

3520-42-1

8004-92-0

2611-82-7

26172-55-4

12600mg/kg(Rat)

10300mg/kg(Mouse)

2000mg/kg(Rat)

> 8000mg/kg(Rat)

53mg/kg(Rat)

> 10000mg/kg(Rabbit)

No information

available

No information

available

No information

available

No information

available DYE

No information

available

No information

available DYE

FS-14D（Thiazoline

compound）

No information

available

No information

available

8 / 13


Ethylene glycol

Version：V1.0.0.2 Revision Date：2019/02/26

No information 10600mg/kg(Rabbit) 107-21-1

18472-87-2

17372-87-1

4700mg/kg(Rat)

8400mg/kg(Rat)

available

No information

available

No information

available DYE

No information

available

No information

available DYE 2344mg/kg(Mouse)

| Carcinogenicity

ID

1

Cas No.

107-21-1

56-81-5

Component

Ethylene glycol

Glycerol

IARC NTP

Not Listed

Not Listed

Not Listed

Not Listed

Not Listed

Not Listed

2

3 26172-55-4 FS-14D（Thiazoline compound）

WET KL245（Oxirane, methyl, polymer with

oxirane, mono(3- (1,3,3,3-tetra methyl-1-


4 134180-76-0 Not Listed Not Listed

5

6

8004-92-0

7732-18-5

1934-21-0

2611-82-7

3520-42-1

17372-87-1

2650-18-2

6505-30-2

-

DYE

Water

DYE

Not Listed

Not Listed

Not Listed

Not Listed

Not Listed

Not Listed

Not Listed

Not Listed

Not Listed

Not Listed

Not Listed

Not Listed

Not Listed

Not Listed

Not Listed

Not Listed

Not Listed

Not Listed

Not Listed

Not Listed

Not Listed

Not Listed

7

8 DYE

9 DYE

10

11

12

13

14

15

DYE

DYE

DYE

Black SP

DYE 4129-84-4

18472-87-2 DYE

| Others


Skin corrosion/irritation Based on available data, the classification criteria are not met

Serious eye

damage/irritation Based on available data, the classification criteria are not met

Skin sensitization May cause an allergic skin reaction

Respiratory sensitization Based on available data, the classification criteria are not met

Reproductive toxicity Based on available data, the classification criteria are not met

STOT-single exposure Based on available data, the classification criteria are not met

STOT-repeated exposure May cause damage to organs through prolonged or repeated exposure

Aspiration hazard Based on available data, the classification criteria are not met

Germ cell mutagenicity Based on available data, the classification criteria are not met

Reproductive Based on available data, the classification criteria are not met

toxicity(additional)

12 Ecological information 9 / 13


| Acute aquatic toxicity

Component Cas No. Fish Crustaceans Algae

LC50：68100mg/L No information

available

No information

available Glycerol 56-81-5

(96h)(Fish)

FS-14D（Thiazoline

compound）

LC50：0.36mg/L EC50：1.07mg/L ErC50：0.13mg/L 26172-55-4

107-21-1

(96h)(Fish) (48h)(Crustaceans) (96h)(Algae)

LC50：54700mg/L EC50：41000mg/L ErC50：>1100mg/L Ethylene glycol

(96h)(Fish) (48h)(Crustaceans) (72h)(Algae)

| Chronic aquatic toxicity

Component Cas No. Fish Crustaceans Algae

NOEC： Ecx：1000mg/L No information

available Ethylene glycol

Glycerol

107-21-1 100mg/L(Fish) (Crustaceans)

NOEC： No information

available

No information

available 56-81-5

68100mg/L(Fish)

FS-14D（Thiazoline

compound）

NOEC： No information

available

No information

available 26172-55-4

0.06mg/L(Fish)

| Persistence and degradability

Component Cas No. Persistence (water/soil) Persistence (air)

Ethylene glycol 107-21-1

17372-87-1

1934-21-0

2611-82-7

26172-55-4

2650-18-2

4129-84-4

7732-18-5

Low(Half-life = 24 days) Low(Half-life = 3.46 days)

DYE High

High

High

High

High

High

Low

High

High

High

High

High

High

Low

DYE

DYE

FS-14D（Thiazoline compound）

DYE

DYE

Water

| Bioaccumulative potential

Component Cas No.

107-21-1

Bioaccumulative potential comments

BCF=200 Ethylene glycol Low

High

Low

DYE 17372-87-1

1934-21-0

2611-82-7

26172-55-4

2650-18-2

4129-84-4

7732-18-5

Log KOW=4.8032

BCF=3 DYE

DYE Low Log KOW=1.6301

Log KOW=0.0444

Log KOW=2.0459

Log KOW=4.1531

Log KOW=-1.38

FS-14D（Thiazoline compound） Low

DYE

DYE

Low

Medium

Low Water

10 / 13


| Mobility in soil

Soil Organic Carbon-Water

Partitioning Coefficient (Koc) Component Cas No. Mobility in soil

Ethylene glycol 107-21-1

17372-87-1

1934-21-0

2611-82-7

26172-55-4

2650-18-2

4129-84-4

7732-18-5

High

Low

Low

Low

Low

Low

Low

Low

1

DYE 18860

79.38 DYE

DYE 1572000

45.15 FS-14D（Thiazoline compound）

DYE

DYE

10000000000

10000000000

14.3 Water

| Results of PBT and vPvB assessment

Results of PBT and vPvB assessment

（according to (EC) No 1907/2006) Component Cas No.

Ethylene glycol

Glycerol

107-21-1

56-81-5

not PBT/vPvB

not PBT/vPvB

not PBT/vPvB FS-14D（Thiazoline compound） 26172-55-4

WET KL245（Oxirane, methyl, polymer with

oxirane, mono(3- (1,3,3,3-tetra methyl-1-

((trimethylsilyl)oxy)disiloxanyl)propyl)ether） 134180-76-0 not PBT/vPvB

DYE

Water

DYE

DYE

DYE

DYE

DYE

DYE

DYE

DYE

8004-92-0

7732-18-5

1934-21-0

2611-82-7

3520-42-1

17372-87-1

2650-18-2

6505-30-2

4129-84-4

18472-87-2

not PBT/vPvB

not PBT/vPvB

not PBT/vPvB

not PBT/vPvB

not PBT/vPvB

not PBT/vPvB

not PBT/vPvB

not PBT/vPvB

not PBT/vPvB

not PBT/vPvB

13 Disposal considerations

| Disposal considerations

Before disposal should refer to the relevant national and local laws and

regulation. Recommend the use of incineration disposal. Waste chemicals

Contaminated Containers may still present chemical hazard when empty. Keep away from hot

packaging and ignition source of fire. Return to supplier for recycling if possible.

Disposal Refer to section 13.1and 13.2.

recommendations

11 / 13


14 Transport information

| Label and Mark

Not applicable Transporting Label

| IMDG-CODE

IMDG-CODE NOT REGULATED FOR TRANSPORT OF DANGEROUS GOODS

| ICAO/IATA-DGR

ICAO/IATA-DGR NOT REGULATED FOR TRANSPORT OF DANGEROUS GOODS

| UN-ADR

UN-ADR NOT REGULATED FOR TRANSPORT OF DANGEROUS GOODS

15 Regulatory information

| International chemical inventory

Component

Ethylene glycol

Glycerol

EINECS TSCA DSL IECSC NZIoC PICCS KECI AICS ENCS

√

√

√

√

√

√

√

√

√

√

√

√

√

√

√

√

√

√

FS-14D（Thiazoline

compound） √ √ √ √ √ √ √ √ √

WET KL245（Oxirane, methyl,

polymer with oxirane,

mono(3- (1,3,3,3-tetra

methyl-1- × √ × √ √ √ √ √ ×

((trimethylsilyl)oxy)disiloxanyl

)propyl)ether）

DYE

Water

DYE

×

√

√

√

√

√

√

√

×

√

√

√

√

√

√

√

√

√

√

×

√

√

√

√

√

√

√

√

√

×

×

√

√

√

√

√

√

√

√

√

√

×

√

√

√

√

√

√

√

√

√

×

×

√

√

√

√

√

√

√

√

√

×

×

√

√

√

√

√

√

√

√

√

√

×

√

√

√

√

√

√

√

√

√

×

×

√

√

√

×

√

√

√

√

√

×

×

√

√

DYE

DYE

DYE

DYE

DYE

Black SP

DYE

DYE

【EINECS】 European Inventory of Existing Commercial Chemical Substances

【TSCA】 United States Toxic Substances Control Act Inventory

【DSL】 Canadian Domestic Substances List

【IECSC】 China Inventory of Existing Chemical Substances

12 / 13


【NZIoC】 New Zealand Inventory of Chemicals

【PICCS】 Philippines Inventory of Chemicals and Chemical Substances

【KECI】

【AICS】

Existing and Evaluated Chemical Substances

Australia Inventory of Chemical Substances

Existing And New Chemical Substances 【ENCS】

Note

“√” Indicates that the substance included in the regulations

“×” That no data or included in the regulations

16 Others

| Information on revision

Creation Date 2019/02/20

Revision Date 2019/02/26

Reason for revision -

| Reference

[1]IPCS: The International Chemical Safety Cards (ICSC), website: http://www.ilo.org/dyn/icsc/showcard.home.

[2]IARC，website: http://www.iarc.fr/.

[3]OECD: The Global Portal to Information on Chemical Substances, website:

http://www.echemportal.org/echemportal/index?pageID=0&request_locale=en.

[4]CAMEO Chemicals, website: http://cameochemicals.noaa.gov/search/simple.

[5]NLM: ChemIDplus, website: http://chem.sis.nlm.nih.gov/chemidplus/chemidlite.jsp.

[6]EPA: Integrated Risk Information System, website: http://cfpub.epa.gov/iris/.

[7]U.S. Department of Transportation: ERG, website: http://www.phmsa.dot.gov/hazmat/library/erg.

[8]Germany GESTIS-database on hazard substance, website: http://gestis-en.itrust.de/.

| Abbreviations and acronyms

CAS –Chemical Abstracts Service CMR - Carcinogens, mutagens or substances toxic to reproduction

PC-TWA - Time Weighted Average PC-STEL- Short term exposure limit

DNEL - Derived No Effect Level IARC - International Agency for Research on Cancer

PNEC –Predicted No Effect Concentration RPE - Respiratory Protective Equipment

LC50 - Lethal Concentration 50% LD50 - Lethal Dose 50%

NOEC -No Observed Effect Concentration

PBT - Persistent, Bioaccumulative, Toxic

BCF - Bioconcentration factor (BCF)

IMDG-International Maritime Dangerous Goods

EC50 - Effective Concentration 50%

POW - Partition coefficient Octanol: Water

vPvB - very Persistent, very Bioaccumulative

ICAO/IATA-International Civil Aviation Organization/International Air

Transportation Association

UN-The United Nations ACGIH-American Conference of Governmental Industrial Hygienists

OECD-Organization for Economic Co-operation and Development NFPA-National Fire Protection Association

| Disclaimer

This Safety Data Sheet (SDS) was prepared according to UN GHS (the 7th revised edition). The data included

was derived from international authoritative database and provided by the enterprise. Other information was

based on the present state of our knowledge. We try to ensure the correctness of all information. However,

due to the diversity of information sources and the limitations of our knowledge, this document is only for

user’s reference. Users should make their independent judgment of suitability of this information for their

particular purposes. We do not assume responsibility for loss, damage or expense arising out of or in any way

connected with the handling, storage, use or disposal of the product.

13 / 13

Documents

Water-based color ink