Water Treatment Final 2

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    School of Process, Environmental

    & Materials Engineering

    PEME2020

    Safety, Health & Environment

    2012-2013

    Student Name Raja Aneece Ahmed

    Student ID 200564028

    Title Water Treatment

    FAO Dr. Tim Hunter

    Date 08/03/2013

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    Content Page

    Introduction......................................................................................3

    Present and future

    Requirements for recycling water..................................................4-7

    Recycled water uses and regulations

    for potable water and grey water...................................................7-9

    Current technologies and methods

    implemented for water recycling.................................................9-11

    Advances in water

    recycling technologies..................................................................11-13

    Alternative methods for

    recycling water..................................................................................13

    Conclusion.........................................................................................14

    References....................................................................................14-15

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    Introduction

    Water can be considered as the foundation of life, without water our existence would not be

    possible. Water has such great importance to this earth and to every living being that is an

    inhabitant of this planet that it is considered as the driving force of all nature. Even the

    location for the development of cities was decided upon depending on the water reserves that

    area of the land had to offer. All living creations depend on this important commodity which

    in todays society, especially in the developed nations of the world, has lost its superiority

    and people have forgotten its importance. The reason for this is mainly due to the incorrect

    public perception as many believe that water is an infinitely available commodity. The ease

    of obtaining water is also a reason to why many people have forgotten the importance of it, as

    all it takes to obtain it, is to rotate a tap. However, water is not available at an infinite quantity

    and suppliers are struggling with providing water to the masses as it is in more demand in

    todays modern world than it ever has been in the past history. This is due to the growing

    population and increasing industrialisation and because of this, demand for clean water isincreasing and suppliers are struggling to keep up with the demand (Richard 2010).

    What many people also do not realise is that a complex system and technique is used to

    obtain pure quality water safe enough for consumption. It has been reported that an estimated

    800 million people throughout the world have not been granted the opportunity of having

    clean, safe drinking water and this has resulted in the death of almost 3.5 million per year

    from water related illnesses. These figures mostly reflect the current situation in developing

    nations; nevertheless, even developed countries are showing signs of emergency measures.

    America, the richest country in the world, is finding it difficult to supply hygienic water to

    the citizens of Los Angles, a city that was built in the desert. This goes to show that, on aglobal scale, the supply of clean water is a concern and requires to be corrected by

    introducing changes to the current system that is used to obtain clean water to ultimately

    reduce the death toll of the suffering people (Richard 2010).

    As our soul existence depends on water it can be described as one of the most precious

    commodities on the face of this earth. A human body cannot function or survive without

    water for even a couple of weeks without resulting in serious health consequences and most

    likely death. For this reason this commodity needs to be preserved and must be used in a way

    that would result in minimal wastage. One way of achieving this is by recycling the water.

    The definition of recycling is to recover useful materials from garbage or waste and to extractuseful material and reuse them. This has great importance and is a topic mostly discussed in

    the media and various government campaigns are preceded so that governments promote the

    increase of this practice. People are becoming more aware of this problem due to the

    alarming rate at which global warming is taking its affect on this planet which is causing

    rising sea levels to unexplained weather conditions resulting in draught in many areas. The

    advance in technology has created the opportunity for the recycling of many materials such as

    metals and plastics, which are vital processes that need to become more popular amongst

    nations throughout the world to help sustain this planet for future generations to come. Even

    though methods have been established to create perfectly safe drinking water through themeans of recycling it, this process is still avoided by the majority of society. Sorely the

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    mentioning of consumable recycled water is congregated with great hostility by the general

    public, even though on a scientific level, research has made it clear that even natural water is

    in fact to some extent recycled but through natural methods. Activists, leaders and

    environmentalists across the globe have realised the scale at which water reserves are

    consumed and that they are being used at a higher level than they are being replenishedleading to a decrease in the reserves and plans are being made for the investment into

    research for new water recycling technologies as a way of overcoming this problem and most

    importantly the general public is being educated about the benefits recycling water has to

    offer.

    This report will explore this matter in greater detail by explaining the current and future

    trends of water recycling technologies and a description upon the advantages and

    disadvantages of recycling water will be made.

    Present and future requirements for recycling water

    The earth contains a total of 1.4 billion km3of water out of which 97.5% is salt water and

    only 2.5% is fresh water. This amount of water covers an astonishing 70% of the earth and

    the remainder is landmass. The total volume of fresh water has been calculated to be 35

    million km3 out of which only an estimated 90,000 km3 is readily available for human

    consumption being safe and clean enough to drink without treatment. The readily available

    water accounts for only 0.036% of all the water found on earth. These figures clearly prove

    that water availability even at a global scale is remarkably low and these reserves are being

    consumed at a record high rate. These figures give a further indication upon the requirementof the importance of the conservation of water through the process of recycling it (Barlour

    2010).

    Figure 1: Fresh water availability across the World (Hawken 2008)

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    The map shown in figure 1 gives an indication on fresh water availability in different areas

    around the world. From the map it is clearly evident that most of the fresh water is found in

    the northern and southern hemispheres which are mostly uninhabitable areas of the world.

    The most densely populated areas do not have a sufficient quantity of water reserves and an

    estimated 80% of the worlds total population lives in areas that do not have a secure freshwater supply. One method that is used to overcome this problem is by the construction of

    pipelines and canals which are an expensive process that mostly only developed nations can

    afford to make. With the financial circumstances across the world which is being experienced

    by many nations, and the dramatic rise in water supply, the need for recycling water has

    never been greater than it has in todays circumstances (Hawken 2008).

    There are numerous benefits involved in recycling water and one of the most important ones

    being is that it spectacularly aids in the conservation of the drinking water supplies. This

    process assists the reuse of a precious and limited resource and lightens the heavy burden on

    the decreasing water reserves. Recycling water is especially important were water supply isvery limited and in drought inflicted areas (Marcus 1998).

    This process is also beneficial to the environment as it helps in ecosystem restoration and

    reduces pollution. Many ecosystems are very sensitive to a change in the environment and

    greatly depend on the water quantity available to that ecosystem. An ecosystem with a large

    water reserve has been known to flourish and expand mainly because the wildlife has greater

    chance of survival. Plants, animals and fish like us depend on water and require a sufficient

    water flow to their habitats for their survival and reproduction. Recycling water would result

    in the reduction on the amount of water we extract from the ecosystems (Marcus 1998).

    A lot of the wastewater is diverted back into waterways. This wastewater has potential risks ifconsumed as it contains many harmful effluents and nutrients. Recycling water would

    significantly reduce if not totally diminish the amount of wastewater that travels back to the

    waterways and in doing so would increase the waters quality and reduce the harmful effects

    from the content of wastewater which clearly indicates another advantage of recycling water.

    Furthermore, the amount of water taken out of wildlife for human use would be reduced if the

    water we use was recycled leaving good quality water in an large enough quantity for the

    wildlife to survive off (Marcus 1998).

    In addition, recycling water has the benefit of saving energy. An increased demand of water

    has meant that there has been an increase in the process of extracting, treating andtransporting water, sometimes over great distances. These processes require a lot of energy to

    occur. Water is pumped up from the ground and as it gets used up; water requires to be

    pumped deeper within the ground. The deeper within the ground that is required to be gone

    the more energy that is needed to extract the water. Recycling water on site overcomes these

    problems and reduces the need to transport the water as well as the need to pump water from

    deep within aquifers. Other ways recycling water helps save energy is that the water that is

    used to flush toilets or for gardening purposes needs to be less stringent as compared to the

    water that is needed for consumption which requires less energy to achieve when recycled.

    Using recycled water made to have lower quality for such purposes requires less energy toachieve. (Reifsheinder 2009).

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    Like many process recycling water has its downsides. Recycled water requires several

    financial investments to be made mainly done by governments which include cost of labour

    and basic maintenance. Pipes need to be built and installed in order to collect the wastewater

    and to transport it to the recycling facility and once the recycling process is complete more

    pipes would subsequently need to be developed to transport the water to the public.Established cities would require tearing up road to create ways for the installation of these

    pipes however undeveloped areas do not have this problem as they do not have many

    buildings and roads (Jenkins 2005).

    The public perception of recycled water is a downside on its own. Once water exits a

    household for example by flushing it down the toilet or through pours down the sink; many

    people do not like the idea of re-using and drinking that same water. This is mainly due to the

    lack of knowledge the public has on the treatment recycled water undergoes and therefore

    there has been a general misconception which has lead people to believe that this type of

    water is not safe to be used again. Governments have launched several campaigns to helpeducate people on what goes on during the recycling process and how this in not the case.

    Nevertheless, many people still vote against this forcing governments not practice this

    procedure (Jenkins 2005).

    Even though the recycling of water involves an intense treatment process, some health

    concerns still exist. Studies conducted have found that recycled water still contains some

    dangerous impurities even after treatment. Some toxic chemical that were found included

    components found in medication and estragon. From the research done it was concluded that

    the traditional method of recycling water was not sufficient enough in removing some

    medication found within the wastewater to safe enough levels as there was still 16 differenttypes of contaminants present within the water. Further studies were conducted and results

    from these studies gave an indication that only 92% of antibiotics were able to be removed

    with the remainder still present even after treatment. This presence in the water could be

    disastrous not only to the consumer but also to the effectiveness of the actual antibiotic.

    Pathogens are well known to develop immunity towards antibiotics and this would aid them

    into doing so meaning further treatment with the same antibiotics would be ineffective.

    According Richard Gerseberg, a researcher and professor at San Diego state university, has

    found that even deadly microbial pathogens such as bacteria like salmonella and E. coli and

    viruses such as the hepatitis virus to name a few, can also present in wastewater. Despite the

    vigorous treatment that is undergone before water is released to the public and the checkups

    made by environmental protection agencies, these microbial contaminants have the potential

    risk of still being present in potable water sources, which is the water used for drinking and

    bathing (Smith 2008).

    If population and industrialisation growth continues in the same manner in the future as it has

    in the past century; the demand for water will only increase at a momentous rate which calls

    out for changes that are needed to be made to the current system of acquiring drinkable water

    to help prevent the total collapse of the existing system which itself signifies the importance

    of recycling water. An increase in industrialisation has been shown the most in the far east,

    and many of these industries that are being built require huge amounts of water for their

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    process to transpire. This will result in the exhaustion of the current supply of water as well

    as pollute existing supplies which would ultimately result in reducing the amount of fresh

    water for both nature and human use. Due to the advances made in medication, which has

    allowed the treatment for many illnesses and diseases possible, human populations have

    increased. This is because the fatality rate has decreased because of the many medicationsavailable for a whole range of diseases and illness. More humans means that there is an

    increased need for water as every individual uses and consumes water. Even the food we eat

    such as fruit and vegetation uses a vast quantity of water to produce. It is believed that by

    2050 the population will increase to 9.2 billion people while the amount of people moving

    into cities would also rise which would put further strains on water infrastructure and reserves

    in the coming future (Asano 1999).

    Recycled water uses and regulations for potable water and grey

    water

    Potable water is defined as water sufficiently sterile for human consumption. Gray water is

    waste water obtained from certain domestic activities such as showers, washing clothes,

    washing dishes, baths and wash basins. This water does not require vigorous treatment and

    can very easily be recycled with little treatment for landscape irrigation and other non-potable

    uses. Using grey water is very beneficial to the environment but can have certain harmful

    effects. Some of the benefits included in using grey water is that it contains nutrients that

    promote the growth of plants. Grey water also requires very little filtration which saves costs

    in the treatment process. However, grey water contains microbes in the form of viruses andpathogens which if used can have harmful effects on the environment. Grey water can also

    contain chemicals used in households such as the chemicals found in cleaning agents and in

    shampoo for example which also have the potential to have detrimental effects on the

    environment. It can also be used for the cleansing of toilets via flushing which is a process

    that requires a large amount of water as it accounts for 50% of the total indoor water use. Due

    to the large amounts of water required for these processes it is possible to save enormous

    amounts of water by making the use of grey water more popular especially in the flushing of

    toilets (Casey 2009).

    As explained earlier recycled water do carry some risks when used. May it be in the form ofgrey water or recycled water if they are not treated and used in a correct manner they could

    entail serious consequences to both the health of the individual that gets in contact with this

    water and the environment. To prevent this from occurring environmental agencies have put

    together a vast amount of strict rules and regulations which are required to be followed.

    Below are some of these regulations made by the UK Environmental agencies

    (Environmental Agency 2011):

    Water quality: This describes the physical, biological and chemical characteristics of

    the water. When looking at the water from a physical perspective it includes on how

    clear the water is and its colour, total suspended solids and its temperature. Thebiological qualities relates to the presence of any microbes such as bacteria and

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    viruses which further indicates, by looking into the type of microbes and its

    abundance, if there are signs of any faecal contamination. Finally, the chemical

    characteristics of the water looks into things like the pH of the water, the quantity of

    disinfectants present such as residuals of chlorine and bromine and measurements are

    taken to see the amount of organic material present in the water Type of contamination: Grey water obtained from showers, baths and washbasins

    has potentially been contaminated with intestinal bacterial or dead skin particles and

    hair. Chemicals found in shampoos, detergents and other cosmetic products contain

    nutrients together with other organic matter present and the high temperature provide

    ideal conditions for the growth of bacteria. This is why rules have been set out so that

    this water cannot be stored and then used for more than a few hours

    Potential risk: The most prominent risk to grey water is derived from microbes

    present from faecal contamination. The physical and chemical risks need also to be

    considered if correct levels are not reached they can interfere with treatment and make

    the water unsuitable for its intended use. This means that the grey water quality must

    be good enough for its intended use

    The required cleanliness of the water: While drinking water needs to meet very

    high standards, however, the UK regulation for the quality of grey water has no

    known regulatory standards. Many groups have advised that set standards must be

    met before the release of this water to help overcome concerns of potentially

    hazardous situation and to help bolster the confidence of the publics use and

    conception of non-potable water

    Water quality: Guidelines for the monitoring arrangements are represented by the

    tables below:

    Table 1: Guidlines needed to be met for bacterial monitoring (Enviromental Agency 2011)

    Table 2: Interpretation of results obtained in Table 2 (Environmental agency 2011)

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    Water fittings: the water supply (water fittings) is governed by the regulations set out

    in 1999 are used to indicate the efficient use and protection to drinking water in

    England and Wales. The rules and regulations apply to all plumbing systems, water

    fittings and equipment which are used to supply water from the public water supply.

    These are mandatory and require a correct level of backflow prevention to be attained.In grey water systems this is usually controlled by an air gap, which is used to prevent

    any of the grey water from mixing with the public potable water.

    Labelling water supply equipment:To prevent any cross-connection between grey

    water and the potable water supply from the mains all pipes installed must be labelled

    and marked accordingly. These guidelines can be found on the WRAS (Water

    Regulation Advisory Scheme).

    Providers of recycled potable water are required to abide by the law and entail to meet the

    mandatory requirements set by the UK environmental agency as listed below (EnviromentalAgency 2011):

    It is compulsory according to the regulations that before using indirect potable

    water that it must be treated by putting it back into a water cycle before

    mandatory requirements are met and therefore water can be collected for potable

    use

    Most importantly, any recycled potable water must meet the same quality

    standards and be free from any contamination as normally treated non-recycled

    water is

    Current technologies and methods implemented for water recycling

    There are several different methods implemented in todays water treatment systems to

    achieve clean potable water. These include biological, chemical and physical methods.

    Biological methods that are used to treat wastewater apply the use of microorganisms which

    decompose most of the contamination found in the wastewater to produce sludge or convert

    waste materials into products such as carbon dioxide, other gases or even water itself. The

    following list outlines some of the biological methods used by many water treatment

    industries (Zhou 2002):

    Activated sludge process

    Anaerobic Digestion

    Aerated lagoon

    Trickling filters

    Rotating biological contactors

    Anaerobic digestion

    Biological nutrient removal

    The activated sludge process is the most common biological method used world-wide. Theprocess involves the use of a tank or basin in which a population of biological microorganism

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    are suspended. To help increase the population of the suspended microorganisms nutrients

    and oxygen are fed into the tank making this process aerobic. These microorganisms are in

    the form of bacteria or single celled eukaryotic protozoa. The system is continuous and uses

    these activated microorganisms to stabilize organic matter and other waste materials. The

    process involves delivering the wastewater to the aeration tank where these activemicroorganisms are allowed to come into contact with the wastewater. The degradation

    process begins once this occurs where the microorganism aerobically convert the organic

    matter into carbon dioxide through the process of degradation. Other side-products are also

    formed in this process which include: new cells, water and other end products (Zhou 2002).

    Chemical methods are the most common methods applied for wastewater treatment. They

    involve chemical reactions to help generate pure water. The following are some examples of

    chemical methods used for treating wastewater (Zhou 2002):

    Chlorination

    Ion exchange

    Dechlorination

    Chemical precipitation

    Chemical coagulation

    Adsorption

    Disinfection

    Out of the above list one of the most common chemical methods applied for wastewater

    treatment is chlorination. This process involves using chlorine to kill bacteria present in the

    wastewater. Addition of chlorine also has the benefit of reducing the rate of decomposition of

    the wastewater. Another strong oxidizing disinfectant that also works similar to chlorine and

    which can also be used is ozone.

    In industry, combinations of all three methods are applied to the treatment of the wastewater.

    In the majority of occasions governments have delegated responsibility for the treatment of

    wastewater to their provenances and territories. Australia is primary example of a country

    struggling with meeting demand of fresh water supply due to high demand and shortages of

    the freshwater supply. To overcome this problem the government have set-up schemes such

    as recycling water. Coliban water providers is a company based in Australia that deals with

    recycling wastewater obtained mainly from domestic sources. They have a specified system

    that delivers water good in enough in quality to be termed potable water. The underline

    principle Coliban water uses in the recycling process is described below (Zhou 2002):

    1) Source control: Ensures that the wastewater entering the recycling system is

    liberated from any harmful contamination such as chemicals. This is achieved by

    preventing wastewater from being released from non-domestic sources such as

    industries, hospitals and other places that deal with high chemical waste

    2) Water reclamation plant: The plant used in the recycling process consists of

    biological reactors and sand filters which are used to remove and even destroy solids,

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    nutrients and organic matter. This process is also capable of destroying some of the

    microorganisms that are present

    3) Advanced oxidation and Disinfection: The industry uses the chemical sodium

    hypochlorite to carry out the advanced oxidation and exposes its content to UV lightfor the purpose of disinfecting it to destroy the remaining bacteria and any other

    microorganism that may be present

    4) Ultra filtration: this process uses a low pressure membrane to remove the remaining

    suspended bacteria, particles and other materials

    5) Reverse osmosis: this process is very effective and is capable of removing 98% of

    biological matter and 99% of minerals. The process involves forcing the water

    through a thin plastic membrane

    6) Deliver: This is the final stage of the industrial process where the water is either sent

    to the consumer or sent to a reservoir to increase purity via natural filtration

    Advances in water recycling technologies

    Since the last century technology has greatly advanced. With the new technology there are

    many advantages as recycling water has become an increasingly efficient way of obtaining

    potable water. One example of such a process includes the Actiflo process. This is a modern

    wastewater recycling process which is a common technique applied for the treatment ofmunicipal and industrial wastewater. The Actiflo method is a clarification process which uses

    micro sand particles (ballast). The micro sand particles aid in the accumulation of suspended

    solids in the water. This process is suitable for the treatment of combined sewer flow,

    primary treatment before bio filtration or for the tertiary treatment which require the removal

    of suspend solids and phosphorus. At the start of the process a coagulant is added which has

    the role of destabilizing suspend matter within the flow. The coagulation of the flow occurs

    when it is introduced to a high speed mixing tank which contains chemicals reagents to aid

    the process. The flow of the material required to be treated is then transported into a second

    chamber which is also a mixing tank but here the speed of the mixer is reduced, at this stage

    the micro sand is added which has a large surface area to volume ratio. The suspended solid

    matter attaches to the micro sand producing flocs. This facilitates the gravitational settling of

    the flocs thus producing a smaller footprint than conventional clarification methods would do

    (Pizzi 2005).

    The next step of the process includes adding polymers to the maturation tank were the

    content flows. In some occasions it is also added to the second tank were the slower mixing

    of the material that requires being treated proceeds. In this maturation tank mixing also

    occurs at a slower rate allowing viable conditions to be created to induce bonding between

    micro sand and suspended matter. Once the floc settles, it is removed from the settling tank

    using plate settlers reducing the content in the tank. The treated clarified water exits the tank

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    through the overflowing lamellas which are positioned above the plate settlers while the

    sludge and sand is collected at the inclined lamellas at the bottom of the tank and are

    transported using conveyors to the hydro-cyclone. The fast rotation of the hydro-cyclone

    separates the solid material according to density where the high density sand settles to the

    bottom and the low density sludge to the top. The sludge is separated and discarded as it hasno further useful function while the sand can be re-used and re-circulated for the next process

    (Pizzi 2005).

    Figure 2: Actiflo process industrial operation ( CESCO 2011)

    Table 2: Summery of the process (Techcommentary 2006)

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    Conclusion

    Technological advancements have made it possible to obtain high purity water through

    method of recycling wastewater. However, much more work needs to be done to make this

    process more successful and more popular. The work that needs to be carried should not just

    be concentrated at developing industrial operations that function to treat used water, but also

    at convincing the general population that this method is safe and the water obtained can

    benefit mankind in years to come if procedures are carried out according to strict rules and

    regulations. The initial investment required to allow such processes to occur is high and for

    this reason only developed nations of the world could benefit from this. For this reason

    undeveloped countries who are struggling financially have not got the funding to operate

    such industries. Furthermore, negligence and lack of care from local authorities and the

    corruption in leadership establishments; make the chances of opening recycled water

    facilities and overcoming their water shortage issues less likely. Therefore people indeveloping countries will continue to suffer even though opportunities and technologies like

    this exist. The increasing advancement of technology would undoubtedly only result in

    improved quality of water and this process has even got the potential of cleansing used water

    to such an extent that it creates water purer than currently used methods. I myself believe,

    that the pleasures purified and clean water bring to societies should not only be for those that

    live in developed countries but should be a commodity accessible to all of mankind especially

    those that are suffering the most. A global strategy should be derived, where nations work

    together so more recycling facilities are opened so that recycled water technology can benefit

    all.

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